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Lawrence F. Dahl

University of Wisconsin, Madison, Madison, WI 
transition metal clusters
"Lawrence Dahl"

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Robert Eugene Rundle grad student 1957 Iowa State
 (Structures of some polynuclear metal carbonyls)
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Erickson JD, Mednikov EG, Ivanov SA, et al. (2016) Isolation and Structural Characterization of a Mackay 55 Metal-Atom Two-Shell Icosahedron of Pseudo-Ih Symmetry, Pd55L12(μ3-CO)20 (L=PR3, R = isopropyl): Comparative Analysis with Interior Two-Shell Icosahedral Geometries in Capped 3-Shell Pd145, Pt-Centered 4-Shell Pd-Pt M165, and 4-Shell Au133 Nanoclusters. Journal of the American Chemical Society
Mednikov EG, Ivanov SA, Dahl LF. (2015) Nanosized {Pd4(μ4-C)}Pd32(CO)28(PMe3)14 Containing Tetrahedrally Deformed Pd4 Cage with Encapsulated Carbide Atom: Formal Substitution of Geometrically Analogous Interior Au4 Entity in Isostructural Au4Pd32(CO)28(PMe3)14 by Electronically Equivalent Pd4(μ4-C) and Computational/Catalytic Implications. Inorganic Chemistry
Mednikov EG, Dahl LF. (2015) Acid/base-controlled AuI/Au0 reductive transformations of the monogold [(μ14-Au)Pd22(CO)20(PEt3)8]+ monocation into three different neutral digold nanoclusters: Au2Pd21(CO)20(PEt3)10, Au2Pd28(CO)26(PEt3)10, and new five-layer hexagonal close-packed (μ12-Au)2Pd42(CO)30(PEt3)12 with a trigonal-bipyramidal AuPd3Au kernel. Inorganic Chemistry. 54: 1145-51
Mednikov EG, Ivanov SA, Dahl LF. (2015) Stabilization of thallium(I) Pd9TlPd3 sandwich monocation with octahedral-based [Pd9(CO)9(PMe3)6] and [Pd3(CO)3(PMe3)3] entities versus unstable Pd3Tl(I)Pd3 sandwich monocation with [Pd3(CO)3(PEt3)3] entities: Comparative co Journal of Organometallic Chemistry
Campana CF, Guzei IA, Mednikov EG, et al. (2014) Sixty-Year Saga (1952-2013) of the Solid-State Structure of Triiron Dodecacarbonyl Journal of Cluster Science. 25: 205-224
Mednikov EG, Dahl LF. (2013) Ion exchange of protons by coinage metals to give gold and silver encapsulation within a pseudo-D2d distorted face-capped Pd14 cubic kernel: [(μ14-M)Pd22(CO)20(PEt3)8]+ (M = Au, Ag). Angewandte Chemie (International Ed. in English). 52: 7813-7
Mednikov EG, Dahl LF. (2013) How innocent is thallium(I)? Corrected formulations of [Tl2Pd14(CO)9(PMe3)11][PF6]2 and [TlPd9(CO)9(PPh3)6][PF6] clusters previously reported as corresponding Au2Pd14 and AuPd9 clusters. Chemical Communications (Cambridge, England). 49: 1085-7
Mednikov EG, Vo N, Fry CG, et al. (2012) High-yield synthesis of PPh 3-ligated decanuclear Tl-Pd cluster, Pd 9[Tl(acac)](CO) 9(PPh 3) 6: Comparative analysis of Tl(I)-Pd(0) bonding connectivities with known Tl-Pd clusters and resulting insight concerning their dissimilar dynamic solution behavior Organometallics. 31: 2878-2886
Mednikov EG, Ivanov SA, Dahl LF. (2011) CO-induced formation of an interpenetrating bicuboctahedral Au2Pd18 kernel in nanosized Au2Pd28(CO)26(PEt3)10: formal replacement of an interior (μ12-Pd)2 fragment in the corresponding known isostructural homopalladium Pd30(CO)26(PEt3)10 with nonisovalent (μ12-Au)2 and resulting experimental/theoretical implications. Inorganic Chemistry. 50: 11795-806
Mednikov EG, Dahl LF. (2010) Syntheses, structures and properties of primarily nanosized homo/heterometallic palladium CO/PR3-ligated clusters. Philosophical Transactions. Series a, Mathematical, Physical, and Engineering Sciences. 368: 1301-32
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