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Paul G. Williard

Affiliations: 
Chemistry Brown University, Providence, RI 
Area:
total synthesis of several marine natural products as well as vitamin D derivatives, characterization of reactive intermediates such as enolate anions and amide bases
Website:
http://research.brown.edu/research/profile.php?id=1106970163&r=1
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"Paul Williard"
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Parents

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Harold W. Heine grad student 1972 Bucknell University
 (BS/MS at Bucknell)
Gilbert Stork grad student 1976 Columbia
 (Investigation of a Novel Carbon-Carbon Bond Forming Reaction)
George H. Büchi post-doc 1976-1979 MIT

Children

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Nancy E. Lee grad student 1994 Brown
Chengzao Sun grad student 2001 Brown
Madeleine A. Jacobson grad student 2002 Brown
Ivan Keresztes grad student 2002 Brown
Joanna L. Turteltaub grad student 2007 Brown
Maria R. Rella grad student 2008 Brown
Deyu Li grad student 2009 Brown
Chi Cheung Su grad student 2010-2015 Brown
Onkei Tai grad student 2017 Brown
Kenneth W. Henderson post-doc Brown

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Publications

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Pang H, Williard PG. (2020) Solid state aldol reactions of solvated and unsolvated lithium pinacolone enolate aggregates Tetrahedron. 76: 130913
Seo J, Shearer J, Williard PG, et al. (2019) Reactivity of a biomimetic W(iv) bis-dithiolene complex with CO leading to formate production and structural rearrangement. Dalton Transactions (Cambridge, England : 2003)
Berton M, Mello R, Williard PG, et al. (2017) On the Reactivity of Lithium β-ketocarboxylates: the Role of Lithium salts. Journal of the American Chemical Society
Tai O, Hopson R, Williard PG. (2017) Aggregation and Solvation of n-Butyllithium. Organic Letters
Tai O, Hopson R, Williard PG. (2017) Ligand Binding Constants to Lithium Hexamethyldisilazide (LiHMDS) Determined by Diffusion-ordered NMR Spectroscopy (DOSY). The Journal of Organic Chemistry
Guang J, Liu QP, Hopson R, et al. (2016) Conformational Polymorphism of Lithium Pinacolone Enolate. Journal of the American Chemical Society
Guang J, Hopson R, Williard PG, et al. (2016) Perfluoroalkyl Grignard Reagents: NMR Study of 1-Heptafluoropropylmagnesium Chloride in Solution. The Journal of Organic Chemistry
Zhang Y, Williard PG, Bernskoetter WH. (2016) Synthesis and Characterization of Pincer-Molybdenum Precatalysts for CO2 Hydrogenation Organometallics. 35: 860-865
Zhang Y, MacIntosh AD, Wong JL, et al. (2015) Iron catalyzed CO2 hydrogenation to formate enhanced by Lewis acid co-catalysts. Chemical Science. 6: 4291-4299
Fujiu M, Negishi K, Guang J, et al. (2015) Chemo-, regio-, and stereo-selective perfluoroalkylations by a Grignard complex with zirconocene. Dalton Transactions (Cambridge, England : 2003). 44: 19464-8
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