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Anthony J. Metrano, Ph.D.

Affiliations: 
2007-2011 Chemistry College of the Holy Cross, Worcester, MA, United States 
 2011-2017 Chemistry Yale University, New Haven, CT 
 2017- Chemistry Princeton University, Princeton, NJ 
Area:
Organic Chemistry, Physical Organic Chemistry, Computational Chemistry
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Parents

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Brian R. Linton research assistant 2009-2011 College of the Holy Cross
Scott Joseph Miller grad student 2011-2017 Yale
Robert R. Knowles post-doc 2017- Princeton

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Publications

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Stone EA, Hosseinzadeh P, Craven TW, et al. (2021) Isolating Conformers to Assess Dynamics of Peptidic Catalysts Using Computationally Designed Macrocyclic Peptides. Acs Catalysis. 11: 4395-4400
Metrano AJ, Chinn AJ, Shugrue CR, et al. (2020) Asymmetric Catalysis Mediated by Synthetic Peptides, Version 2.0: Expansion of Scope and Mechanisms. Chemical Reviews
Tsui E, Metrano AJ, Tsuchiya Y, et al. (2020) Catalytic Hydroetherification of Unactivated Alkenes Enabled by Proton-Coupled Electron Transfer. Angewandte Chemie (International Ed. in English)
Hirsch DR, Metrano AJ, Stone EA, et al. (2019) Troponoid Atropisomerism: Studies on the Configurational Stability of Tropone-Amide Chiral Axes. Organic Letters
Yan XC, Metrano AJ, Robertson MJ, et al. (2018) Molecular Dynamics Simulations of a Conformationally Mobile Peptide-Based Catalyst for Atroposelective Bromination. Acs Catalysis. 8: 9968-9979
Metrano AJ, Miller SJ. (2018) Peptide-Based Catalysts Reach the Outer Sphere through Remote Desymmetrization and Atroposelectivity. Accounts of Chemical Research
Crawford JM, Stone E, Metrano AJ, et al. (2018) Parameterization and Analysis of Peptide-Based Catalysts for the At-roposelective Bromination of 3-Arylquinazolin-4(3H)-ones. Journal of the American Chemical Society
Hurtley AE, Stone E, Metrano AJ, et al. (2017) Desymmetrization of Diarylmethylamido Bis(phenols) through Peptide-Catalyzed Bromination: Enantiodivergence as a Consequence of a 2 amu Alteration at an Achiral Residue within the Catalyst. The Journal of Organic Chemistry
Metrano AJ, Abascal NC, Mercado BQ, et al. (2017) Diversity of Secondary Structure in Catalytic Peptides with β-Turn-Biased Sequences. Journal of the American Chemical Society. 139: 492-516
Metrano AJ, Abascal NC, Mercado BQ, et al. (2016) Structural studies of β-turn-containing peptide catalysts for atroposelective quinazolinone bromination. Chemical Communications (Cambridge, England)
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