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Gary W. Breton, Ph.D.

Affiliations: 
1987-1992 Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
 1992-1994 Chemistry University of North Carolina, Chapel Hill, Chapel Hill, NC 
 1994- Chemistry Berry College, Rome, GA, United States 
Area:
Physical organic chemistry
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Parents

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Frederick Davis Greene grad student 1987-1992 MIT
Paul J. Kropp post-doc 1992-1994 UNC Chapel Hill

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Publications

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Breton GW, Martin KL. (2020) Probing the Dynamic Covalent Chemistry Behavior of Nitrogen-Centered Di and Tri-Urazole Radicals. The Journal of Organic Chemistry
Doiron JE, Le CA, Bacsa J, et al. (2020) Structural Consequences of the 1,2,3-Triazole as an Amide Bioisostere in Analogs of Cystic Fibrosis Drugs VX-809 and VX-770. Chemmedchem
Breton GW, Hahn LA, Martin KL. (2019) Structural verification of a tetrahydrotetrazole compound. Acta Crystallographica. Section C, Structural Chemistry. 75: 1208-1212
Breton GW, Martin KL. (2018) Unanticipated formation of a novel octaazacyclodecane ring upon oxidation of a 1,1-bis-urazole. Acta Crystallographica. Section C, Structural Chemistry. 74: 558-563
Martin KL, Breton GW. (2017) Computational, (1)H NMR, and X-ray structural studies on 1-arylurazole tetrazane dimers. Acta Crystallographica. Section C, Structural Chemistry. 73: 660-666
Singh SK, Das A, Breton GW. (2016) An Ab Initio Study of the Effect of Substituents on the n→π* Interactions Between 7-Azaindole and 2,6-Difluorosubstituted Pyridines. The Journal of Physical Chemistry. A
Breton GW, Suroviec AH. (2015) Intermediacy of a Persistent Urazole Radical and an Electrophilic Diazenium Species in the Acid-Catalyzed Reaction of MeTAD with Anisole. The Journal of Organic Chemistry
Breton GW, Crasto CJ. (2015) Substituted 2-(Dimethylamino)biphenyl-2'-carboxaldehydes as Substrates for Studying n→π* Interactions and as a Promising Framework for Tracing the Bürgi-Dunitz Trajectory. The Journal of Organic Chemistry. 80: 7375-84
Breton GW, Hughes JS, Pitchko TJ, et al. (2014) Unexpected σ bond rupture during the reaction of N-methyl-1,2,4-triazoline-3,5-dione with acenaphthylene and indene. The Journal of Organic Chemistry. 79: 8212-20
Breton GW, Hoke KR. (2013) Application of radical cation spin density maps toward the prediction of photochemical reactivity between N-methyl-1,2,4-triazoline-3,5-dione and substituted benzenes. The Journal of Organic Chemistry. 78: 4697-707
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