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Rehan A. Basta, Ph.D.

Affiliations: 
2004 University of Utah, Salt Lake City, UT 
Area:
Inorganic Chemistry
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Richard Dale Ernst grad student 2004 University of Utah
 (Syntheses and reactivity patterns of edge -bridged open and half-open metallocenes.)

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Publications

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Basta R, Arif AM, Ernst RD. (2013) Syntheses and Structural Studies of the Coupling Products of the Zr(6,6-dimethylcyclohexadienyl)2 Fragment with the Diimines (CH2)n[N=CH(C6H5)]2 (n = 3,4) Journal of Chemical Crystallography. 43: 91-95
Basta R, Arif AM, Ernst RD. (2011) Structural Studies of Coupling Products Formed Between (C6H5)CH=N(C6H5) and the M(C5H5)(6,6-dmch) Fragments (M = Ti, Zr; dmch = dimethylcyclohexadienyl) Journal of Chemical Crystallography. 41: 1433-1437
Harvey BG, Basta R, Arif AM, et al. (2008) Reactions of the 6,6-dimethylcyclohexadienyl anion with MCl4(PMe3)2 complexes (M = Hf, Nb) – Isolation of complex intramolecular coupling products Journal of Organometallic Chemistry. 693: 1420-1425
Ernst RD, Basta R, Arif AM. (2007) Crystal structure of bis(η5-6,6-dimethylcyclohexadienyl)chromium, Cr(C8H11)2 Zeitschrift Fur Kristallographie-New Crystal Structures. 222: 335-336
Rajapakshe A, Basta R, Arif AM, et al. (2007) Silyl substitution effects on metal-pentadienyl bonding: Synthesis, structure, photoelectron spectroscopy, and electronic structure of a high-valent half-open zirconocene Organometallics. 26: 2867-2871
Ernst RD, Basta R, Arif AM. (2006) Crystal structure of bis(6,6-dimethylcyclohexadienyl)vanadium, V(C8H11)2 Zeitschrift Fur Kristallographie-New Crystal Structures. 221: 289-290
Arif AM, Basta R, Ernst RD. (2006) Syntheses and characterization of mono(6,6-dimethylcyclohexadienyl) complexes of titanium and zirconium Polyhedron. 25: 876-880
Basta R, Harvey BG, Arif AM, et al. (2005) Reactions of SF6 with organotitanium and organozirconium complexes: the "inert" SF6 as a reactive fluorinating agent. Journal of the American Chemical Society. 127: 11924-5
Basta R, Arif aAM, Ernst RD. (2005) Origin of 1,4-Regiochemistry in the Dicouplings of Ketones with 6,6-Dimethylcyclohexadienyl Complexes of Titanium and Zirconium: A Mechanism Arising from Five-Electron Donation by Alkoxide Ligands Organometallics. 24: 3982-3986
Basta R, Arif aAM, Ernst RD. (2005) Higher Valent Metal Pentadienyl Chemistry: Syntheses, Structures, and Reactions of Zr(6,6-dmch)2X2 Complexes (dmch = dimethylcyclohexadienyl; X = Cl, Br, I) and Related Species Organometallics. 24: 3974-3981
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