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Alexander Constantin Filippou, Dr.

Affiliations: 
Chemistry Rheinische Friedrich-Wilhelms-Universität Bonn, Bonn, Nordrhein-Westfalen, Germany 
Area:
Organometallic Chemistry
Website:
http://www.filippou.chemie.uni-bonn.de/group/members/filippou
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"Alexander Filippou"
Mean distance: 8.47
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Parents

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Ernst Otto Fischer grad student 1984 Technical University of Munich
 (New ways to anionic ketenyl- and carbyne complexes of group 6 transition metals starting from neutral carbyne-carbonyl complexes)

Children

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Sven Schneider grad student 1999-2003 HU Berlin
Burgert Blom grad student 2007-2011 Bonn University
Priyabrata Ghana grad student 2011-2017 University of Bonn

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Publications

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Karwasara S, Maurer LR, Peerless B, et al. (2021) (NHC)Si═C═N-R: A Two-Coordinated Si-Isocyanide Compound as Si(NHC) Transfer Reagent. Journal of the American Chemical Society
Ghana P, Rump J, Schnakenburg G, et al. (2020) Planar Tetracoordinated Silicon (ptSi): Room-Temperature Stable Compounds Containing Anti-van't Hoff/Le Bel Silicon. Journal of the American Chemical Society
Ghana P, Arz MI, Chakraborty U, et al. (2018) Linearly Two-Coordinated Silicon: Transition Metal Complexes with the Functional Groups M≡Si-M and M=Si=M. Journal of the American Chemical Society
Filippou AC, Hoffmann D, Schnakenburg G. (2017) Triple bonds of niobium with silicon, germaniun and tin: the tetrylidyne complexes [(κ-tmps)(CO)Nb 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 1111111111111111111111111111111111 1111111111111111111111111111111111 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 0000000000000000000000000000000000 E-R] (E = Si, Ge, Sn; tmps = MeSi(CHPMe); R = aryl). Chemical Science. 8: 6290-6299
Ghana P, Arz MI, Schnakenburg G, et al. (2017) Metal–Silicon Triple Bonds: Access to [Si(η5-C5Me5)]+from SiX2(NHC) and its Conversion to the Silylidyne Complex [TpMe(CO)2MoSi(η3-C5Me5)] (TpMe= κ3-N,N′,N″-hydridotris(3,5-dimethyl-1-pyrazolyl)borate) Organometallics. 37: 772-780
Arz MI, Schnakenburg G, Meyer A, et al. (2016) The SiH radical supported by two N-heterocyclic carbenes. Chemical Science. 7: 4973-4979
Arz MI, Straßmann M, Geiß D, et al. (2016) Addition of Small Electrophiles to NHC-stabilized Disilicon(0): A Revisit of the Isolobal Concept in Low-Valent Silicon Chemistry. Journal of the American Chemical Society
Arz MI, Geiß D, Straßmann M, et al. (2015) Silicon(i) chemistry: the NHC-stabilised silicon(i) halides SiX(Idipp) (X = Br, I) and the disilicon(i)-iodido cation [Si(I)(Idipp)]. Chemical Science. 6: 6515-6524
Ghana P, Arz MI, Das U, et al. (2015) Si=Si Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene. Angewandte Chemie (International Ed. in English). 54: 9980-5
Lebedev YN, Das U, Chernov O, et al. (2014) [2+2+1] cycloadditions of bis(dialkylamino)acetylenes with SiI2(Idip): syntheses and reactivity studies of unprecedented 2,3,4,5-tetraamino-1 H-siloles. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9280-9
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