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Deepa Janardanan, Ph. D

Affiliations: 
Chemistry Central University of Kerala 
Area:
Computational Chemistry
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"Deepa Janardanan"
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Parents

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Raghavan B. Sunoj grad student 2009 IIT Bombay
Sason S. Shaik post-doc 2009-2012 Hebrew University

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Publications

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Mandal D, Ramanan R, Usharani D, et al. (2015) How does tunneling contribute to counterintuitive H-abstraction reactivity of nonheme Fe(IV)O oxidants with alkanes? Journal of the American Chemical Society. 137: 722-33
Mandal D, Ramanan R, Usharani D, et al. (2015) How does tunneling contribute to counterintuitive H-abstraction reactivity of nonheme Fe(IV)O oxidants with alkanes? Journal of the American Chemical Society. 137: 722-733
Usharani D, Janardanan D, Li C, et al. (2013) A theory for bioinorganic chemical reactivity of oxometal complexes and analogous oxidants: The exchange and orbital-selection rules Accounts of Chemical Research. 46: 471-482
Wang Y, Janardanan D, Usharani D, et al. (2013) Nonheme iron oxidant formed in the presence of H2O2 and acetic acid is the cyclic ferric peracetate complex, not a perferryloxo complex Acs Catalysis. 3: 1334-1341
Janardanan D, Usharani D, Shaik S. (2012) The origins of dramatic axial ligand effects: Closed-shell Mn VO complexes use exchange-enhanced open-shell states to mediate efficient H abstraction reactions Angewandte Chemie - International Edition. 51: 4421-4425
Cho KB, Chen H, Janardanan D, et al. (2012) Nonheme iron-oxo and -superoxo reactivities: O 2 binding and spin inversion probability matter Chemical Communications. 48: 2189-2191
Janardanan D, Sunoj RB. (2011) Chemo-, regio-, and diastereoselectivity preferences in the reaction of a sulfur ylide with a dienal and an enone Organic and Biomolecular Chemistry. 9: 1642-1652
Usharani D, Janardanan D, Shaik S. (2011) Does the TauD enzyme always hydroxylate alkanes, while an analogous synthetic non-heme reagent always desaturates them? Journal of the American Chemical Society. 133: 176-179
Shaik S, Chen H, Janardanan D. (2011) Exchange-enhanced reactivity in bond activation by metal-oxo enzymes and synthetic reagents Nature Chemistry. 3: 19-27
Janardanan D, Usharani D, Chen H, et al. (2011) Modeling C-H abstraction reactivity of nonheme Fe(IV)O oxidants with alkanes: What role do counter ions play? Journal of Physical Chemistry Letters. 2: 2610-2617
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