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James M. Tanko, Ph.D.

Affiliations: 
1986- Chemistry Virginia Polytechnic Institute and State University, Blacksburg, VA, United States 
Area:
Kinetics and mechanism, electron transfer reactions, the structure and chemistry of free radicals and radical ions, radical ion rearrangements, oxygen-centered radicals
Website:
https://www.chem.vt.edu/general.php?page=jtanko
Google:
"Tanko, James M." OR "James M. Tanko" OR "James Michael Tanko"
Bio:

https://vtnews.vt.edu/articles/2010/09/091010-science-tanko.html
http://www.scribd.com/doc/46369291/cyclopropane
Tanko, James Michael, Reactions of radicals with nucleophiles: the nature of the aryl radical intermediate in the aromatic SRN1 reaction (1985). Retrospective Theses and Dissertations. 12112.
https://lib.dr.iastate.edu/rtd/12112

Mean distance: 8.36
 
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Parents

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Glen A. Russell grad student 1985 Iowa State
 (Reactions of radicals with nucleophiles : the nature of the aryl radical intermediate in the aromatic SRN1 reaction)
Philip S. Skell post-doc 1984-1986 Penn State
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Publications

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Paradzinsky M, Ponukumati A, Tanko JM. (2022) Mechanism and Kinetics of the Reaction of Nitrate Radicals with Carboxylic Acids. Chempluschem. e202200213
Paradzinsky M, Troya D, Tanko JM. (2021) Insight into Hydrogen Abstractions by Nitrate Radical: Structural, Solvent Effects, and Evidence for a Polar Transition State. The Journal of Physical Chemistry. A. 125: 5471-5480
Paradzinsky M, Troya D, Tanko JM. (2021) Insight into Hydrogen Abstractions by Nitrate Radical: Structural, Solvent Effects, and Evidence for a Polar Transition State. The Journal of Physical Chemistry. A. 125: 5471-5480
Grimm M, Suleman NK, Hancock AN, et al. (2020) Stereoelectronic and Resonance Effects on the Rate of Ring Opening of N-Cyclopropyl-Based Single Electron Transfer Probes. Journal of the American Chemical Society
Nakamura A, Latif MA, Deck PA, et al. (2020) Frontispiece: Evidence for a Proton‐Coupled Electron Transfer Mechanism in a Biomimetic System for Monoamine Oxidase B Catalysis Chemistry – a European Journal. 26
Tanko J, Nakamura A, Latif MA, et al. (2019) Evidence for a Proton-Coupled Electron Transfer Mechanism in a Biomimetic System for Monoamine Oxidase B Catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany)
Abdel Latif MK, Spencer JN, Paradzinsky M, et al. (2017) Does Metal Ion Complexation Make Radical Clocks Run Fast? An Experimental Perspective. The Journal of Physical Chemistry. A. 121: 9682-9686
Rycek L, Hayward JJ, Latif MA, et al. (2016) Chemoenzymatic total synthesis of hydromorphone by an oxidative dearomatization/intramolecular [4+2] cycloaddition sequence: a 2nd generation approach. The Journal of Organic Chemistry
Patil SV, Tanko JM. (2016) Radical additions of acyclic and cyclic ethers to alkenes via an allyl transfer reaction involving phthalimido-N-oxyl radical Tetrahedron. 72: 7849-7858
Patil S, Chen L, Tanko JM. (2014) Effect of Lewis acids and low temperature initiators on the allyl transfer reaction involving phthalimido-N-oxyl radical Tetrahedron Letters. 55: 7029-7033
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