Aaron David Sadow

Affiliations:	2003		University of California, Berkeley, Berkeley, CA, United States
	2005-	Chemistry	Iowa State University, Ames, IA, United States

Area:

organometallic chemistry, catalysis

Website:

https://sadow.chem.iastate.edu/directory/aaron-sadow/

Google:

"Aaron Sadow"

Bio:

My interest in organometallic chemistry and catalysis began in Ayusman Sen's research group. As an undergraduate at Penn State, I worked on synthesis of polyesters, using CO and activated alcohols as co-monomers. I continued to study organometallics in Don Tilley's group as a graduate student at UC Berkeley, working first on catalysts for polymerization of silanes to make long chains with silicon-only backbones, synthesizing possible intermediates containing reactive metal-silicon bonds, and then on related CH activation reactions and hydrocarbon functionalization catalysis. We developed two new catalytic reactions that used methane as a source for methyl groups, hydromethylation of propene and dehydrogenative simulation of methane. I then moved to ETH Zürich, where I worked with Antonio Togni on enantioselective hydroamination and hydrophosphination for the synthesis of chiral amines and phosphines.

Mean distance: 7.63

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Parents

Ayusman Sen	research assistant		Penn State
T. Don Tilley	grad student	2003	UC Berkeley
(Early transition metal complexes in sigma-bond methathesis: The activation of silicon-hydrogen, silicon-carbon, and carbon-hydrogen bonds.)
Antonio Togni	post-doc		ETH Zürich

Children

Kuntal Manna	grad student	2007-2012	Iowa State
Debabrata Mukherjee	grad student	2007-2013	Iowa State

Collaborators

BETA: Related publications

Publications

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Luo Z, Li L, Nguyen VT, et al. (2024) Catalytic Hydrogenolysis by Atomically Dispersed Iron Sites Embedded in Chemically and Redox Non-innocent N-Doped Carbon. Journal of the American Chemical Society
Kanbur U, Paterson AL, Rodriguez J, et al. (2023) Zirconium-Catalyzed C-H Alumination of Polyolefins, Paraffins, and Methane. Journal of the American Chemical Society
Patnaik S, Kanbur U, Ellern A, et al. (2021) Hydrosilane σ-Adduct Intermediates in an Adaptive Zinc-Catalyzed Cross-dehydrocoupling of Si-H and O-H Bonds. Chemistry (Weinheim An Der Bergstrasse, Germany)
Luo Z, Nie R, Nguyen VT, et al. (2020) Transition metal-like carbocatalyst. Nature Communications. 11: 4091
Kanbur U, Sadow AD. (2020) Rare-Earth Catalyzed C-H Bond Alumination of Terminal Alkynes. Chemistry (Weinheim An Der Bergstrasse, Germany)
Wang Z, Patnaik S, Eedugurala N, et al. (2020) Silica-supported Organolanthanum Catalysts for C-O Bond Cleavage in Epoxides. Journal of the American Chemical Society
Zhou H, Wang H, Sadow AD, et al. (2020) Erratum to “Toward hydrogen economy: Selective guaiacol hydrogenolysis under ambient hydrogen pressure” [Appl. Catal. B: Environ. 270 (2020) 118890] Applied Catalysis B: Environmental. 273: 119018
Zhou H, Wang H, Sadow AD, et al. (2020) Toward hydrogen economy: Selective guaiacol hydrogenolysis under ambient hydrogen pressure Applied Catalysis B: Environmental. 270: 118890
Celik G, Kennedy RM, Hackler RA, et al. (2019) Upcycling Single-Use Polyethylene into High-Quality Liquid Products. Acs Central Science. 5: 1795-1803
Reinig RR, Ellern A, Sadow AD. (2019) Heteroleptic Four-Coordinate Tris(oxazolinyl)borato Iron(II) Compounds. Inorganic Chemistry