John R. Stille, Ph.D.

1987-1994 Chemistry Michigan State University, East Lansing, MI 
"John Stille"
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Benovsky P, Stephenson GA, Stille JR. (1998) Asymmetric formation of quaternary centers through aza-annulation of chiral β-enamino amides with acrylate derivatives Journal of the American Chemical Society. 120: 2493-2500
Beholz LG, Benovsky P, Ward DL, et al. (1997) Formation of dihydropyridone- and pyridone-based peptide analogs through aza-annulation of β-enamino ester and amide substrates with α-amido acrylate derivatives Journal of Organic Chemistry. 62: 1033-1042
Benovsky P, Stille JR. (1997) Aza-annulation as a versatile approach to the synthesis of non-benzodiazepene compounds for the treatment of sleep disorders Tetrahedron Letters. 38: 8475-8478
Stille JR, Barta NS. (1995) Aza-annulation of enamine related substrates with a,b-unsaturated carboxylate derivatives as a route to the selective synthesis of d-lactams and pyridones Studies in Natural Products Chemistry. 18: 315-389
Barta NS, Kirk BA, Stille JR. (1995) Competitive intramolecular TiC versus AlC alkene insertions: Examining the role of Lewis acid cocatalysts in Ziegler-Natta alkene insertion and chain transfer reactions Journal of Organometallic Chemistry. 487: 47-53
Barta NS, Paulvannan K, Schwarz JB, et al. (1994) An apparatus for the efficient removal of H2O from reaction mixtures Synthetic Communications. 24: 583-590
Harms AE, Stille JR, Taylor SK. (1994) Ring formation through intramolecular SN′ displacement of an allylic methoxy substituent Organometallics. 13: 1456-1464
Cook GR, Beholz LG, Stille JR. (1994) Construction of Hydroxylated Alkaloids (.+-.)-Mannonolactam, (.+-.)-Deoxymannojirimycin, and (.+-.)-Prosopinine through Aza-Annulation The Journal of Organic Chemistry. 59: 3575-3584
Paulvannan K, Stille JR. (1994) Heterocycle formation through aza-annulation: Stereochemically controlled syntheses of (±)-5-epitashiromine and (±)-tashiromine Journal of Organic Chemistry. 59: 1613-1620
Barta NS, Kirk BA, Stille JR. (1994) .alpha.- and .beta.-Deuterium Isotope Effects in the MgX2 and Methylaluminoxane Promoted Intramolecular Olefin Insertion of Cp2TiClR Complexes. Insight into Cocatalyst Dependence and Chain End Control in Ziegler-Natta Polymerization Journal of the American Chemical Society. 116: 8912-8919
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