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Herbert Mayr, Ph.D. - Publications

Affiliations: 
1984-1991 University of Lübeck, Lübeck, Schleswig-Holstein, Germany 
 1991-1996 Technische Universität Darmstadt 
 1996-2015 Ludwig-Maximilians-Universität München, München, Bayern, Germany 
Website:
http://www.cup.uni-muenchen.de/oc/mayr/CDmayrcv.html
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Year Citation  Score
2023 Eitzinger A, Reitz J, Antoni PW, Mayr H, Ofial AR, Hansmann MM. Pushing the Upper Limit of Nucleophilicity Scales by Mesoionic N-Heterocyclic Olefins. Angewandte Chemie (International Ed. in English). e202309790. PMID 37540606 DOI: 10.1002/anie.202309790  0.828
2023 Li L, Mayer RJ, Ofial AR, Mayr H. One-Bond-Nucleophilicity and -Electrophilicity Parameters: An Efficient Ordering System for 1,3-Dipolar Cycloadditions. Journal of the American Chemical Society. PMID 36952671 DOI: 10.1021/jacs.2c13872  0.817
2022 Li L, Mayer RJ, Stephenson DS, Mayer P, Ofial AR, Mayr H. Quantification of the Electrophilicities of Diazoalkanes: Kinetics and Mechanism of Azo Couplings with Enamines and Sulfonium Ylides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 35758555 DOI: 10.1002/chem.202201376  0.844
2022 Li L, Mayer P, Stephenson DS, Ofial AR, Mayer RJ, Mayr H. An Overlooked Pathway in 1,3-Dipolar Cycloadditions of Diazoalkanes with Enamines. Angewandte Chemie (International Ed. in English). PMID 35023245 DOI: 10.1002/anie.202117047  0.818
2021 Maji B, Duan XH, Jüstel PM, Byrne PA, Ofial AR, Mayr H. Nucleophilicities and Nucleofugalities of Thio- and Selenoethers. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34002899 DOI: 10.1002/chem.202100977  0.83
2020 Giese B, Mayr H, Reissig HU. Rolf Huisgen (1920-2020). Angewandte Chemie (International Ed. in English). PMID 32627904 DOI: 10.1002/Anie.202008137  0.529
2020 Li Z, Mayer RJ, Ofial AR, Mayr H. From Carbodiimides to Carbon Dioxide: Quantification of the Electrophilic Reactivities of Heteroallenes. Journal of the American Chemical Society. PMID 32338511 DOI: 10.1021/Jacs.0C01960  0.812
2020 Zhang J, Chen Q, Mayer RJ, Yang JD, Ofial AR, Cheng JP, Mayr H. Predicting Absolute Rate Constants for Huisgen Reactions of Unsaturated Iminium Ions with Diazoalkanes. Angewandte Chemie (International Ed. in English). PMID 32259362 DOI: 10.1002/Anie.202003029  0.842
2020 Mayer RJ, Ofial AR, Mayr H, Legault CY. Lewis Acidity Scale of Diaryliodonium Ions toward Oxygen, Nitrogen, and Halogen Lewis Bases. Journal of the American Chemical Society. 142: 5221-5233. PMID 32125154 DOI: 10.1021/Jacs.9B12998  0.813
2020 An F, Maji B, Min E, Ofial AR, Mayr H. Basicities and Nucleophilicities of Pyrrolidines and Imidazolidinones Used as Organocatalysts. Journal of the American Chemical Society. PMID 31913030 DOI: 10.1021/Jacs.9B11877  0.841
2019 Hussein MA, Tran UPN, Huynh VT, Ho J, Bhadbhade M, Mayr H, Nguyen TV. Halide Anion Triggered Reactions of Michael Acceptors with Tropylium Ion. Angewandte Chemie (International Ed. in English). PMID 31573717 DOI: 10.1002/Anie.201910578  0.471
2019 Mayer RJ, Breugst M, Hampel N, Ofial AR, Mayr H. Ambident Reactivity of Phenolate Anions Revisited: A Quantitative Approach to Phenolate Reactivities. The Journal of Organic Chemistry. PMID 31241938 DOI: 10.1021/Acs.Joc.9B01485  0.833
2019 Leonov A, Timofeeva D, Ofial A, Mayr H. Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity? Synthesis. 51: 1157-1170. DOI: 10.1055/S-0037-1611634  0.511
2019 Timofeeva DS, Ofial AR, Mayr H. Nucleophilic reactivities of Schiff base derivatives of amino acids Tetrahedron. 75: 459-463. DOI: 10.1016/J.Tet.2018.11.075  0.512
2018 Jangra H, Chen Q, Fuks E, Zenz I, Mayer P, Ofial AR, Zipse H, Mayr H. Nucleophilicity and Electrophilicity Parameters for Predicting Absolute Rate Constants of Highly Asynchronous 1,3-Dipolar Cycloadditions of Aryldiazomethanes. Journal of the American Chemical Society. PMID 30444361 DOI: 10.1021/Jacs.8B09995  0.834
2018 Timofeeva DS, Ofial AR, Mayr H. Kinetics of Electrophilic Fluorinations of Enamines and Carbanions: Comparison of the Fluorinating Power of N-F Reagents. Journal of the American Chemical Society. PMID 30156412 DOI: 10.1021/Jacs.8B07147  0.835
2018 Xue XS, Zhang J, Yang JD, Zheng H, Mayr H, Cheng JP. Exploration of the Synthetic Potential of Electrophilic Trifluoromethylthiolating and Difluoromethylthiolating Reagents. Angewandte Chemie (International Ed. in English). PMID 29989309 DOI: 10.1002/Anie.201805859  0.471
2018 Li Z, Jangra H, Chen Q, Mayer P, Ofial AR, Zipse H, Mayr H. Kinetics and Mechanism of Oxirane Formation by Darzens Condensation of Ketones: Quantification of the Electrophilicities of Ketones. Journal of the American Chemical Society. PMID 29659264 DOI: 10.1021/Jacs.8B01657  0.828
2018 Timofeeva DS, Mayer R, Mayer P, Ofial A, Mayr H. Which Factors Control the Nucleophilic Reactivities of Enamines? Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29388720 DOI: 10.1002/Chem.201705962  0.81
2018 Levens A, An F, Fernando JEM, Ofial AR, Lupton DW, Mayr H. Quantification of the Michael-Acceptor Reactivity of α,β-Unsaturated Acyl Azolium Ions Topics in Catalysis. 61: 585-590. DOI: 10.1007/S11244-018-0914-5  0.51
2018 Mayer RJ, Hampel N, Mayer P, Ofial AR, Mayr H. Synthesis, Structure, and Properties of Amino-Substituted Benzhydrylium Ions - A Link between Ordinary Carbocations and Neutral Electrophiles European Journal of Organic Chemistry. 2019: 412-421. DOI: 10.1002/Ejoc.201800835  0.36
2017 García-Ruiz C, Chen JL, Sandford C, Feeney K, Lorenzo P, Berionni G, Mayr H, Aggarwal VK. Stereospecific Allylic Functionalization: The Reactivity of Allylboronate Complexes with Electrophiles. Journal of the American Chemical Society. PMID 29028321 DOI: 10.1021/Jacs.7B10240  0.691
2017 Allgäuer DS, Jangra H, Asahara H, Li Z, Chen Q, Zipse H, Ofial AR, Mayr H. Quantification and Theoretical Analysis of the Electrophilicities of Michael Acceptors. Journal of the American Chemical Society. PMID 28921959 DOI: 10.1021/Jacs.7B05106  0.837
2017 Mayer R, Tokuyasu T, Mayer P, Gomar J, Sabelle S, Mennucci B, Mayr H, Ofial AR. Solvation Accounts for the Counter-Intuitive Nucleophilicity Ordering of Peroxide Anions. Angewandte Chemie (International Ed. in English). PMID 28815833 DOI: 10.1002/Anie.201707086  0.848
2017 Li Z, Chen Q, Mayer P, Mayr H. Nucleophilicity parameters of arylsulfonyl substituted halomethyl anions. The Journal of Organic Chemistry. PMID 28106995 DOI: 10.1021/Acs.Joc.6B02844  0.468
2017 Byrne PA, Kobayashi S, Würthwein EU, Ammer J, Mayr H. Why are Vinyl Cations Sluggish Electrophiles? Journal of the American Chemical Society. PMID 28040896 DOI: 10.1021/Jacs.6B10889  0.45
2017 Mayr H, Ofial AR. Philicity, fugality, and equilibrium constants: when do rate-equilibrium relationships break down? Pure and Applied Chemistry. 89: 729-744. DOI: 10.1515/Pac-2017-0107  0.459
2017 Puente Á, Ofial AR, Mayr H. Nucleophilic Reactivities of Bis-Acceptor-Substituted Benzyl Anions European Journal of Organic Chemistry. 2017: 1196-1202. DOI: 10.1002/Ejoc.201601513  0.519
2016 Zhang Z, Puente Á, Wang F, Rahm M, Mei Y, Mayr H, Prakash GK. Corrigendum: The Nucleophilicity of Persistent α-Monofluoromethide Anions. Angewandte Chemie (International Ed. in English). 55: 14494. PMID 27870465 DOI: 10.1002/Anie.201609842  0.443
2016 Zhang Z, Puente Á, Wang F, Rahm M, Mei Y, Mayr H, Prakash GK. The Nucleophilicity of Persistent α-Monofluoromethide Anions. Angewandte Chemie (International Ed. in English). PMID 27628935 DOI: 10.1002/Anie.201605616  0.489
2016 Byrne PA, Karaghiosoff K, Mayr H. Ambident Reactivity of Acetyl- and Formyl-Stabilized Phosphonium Ylides. Journal of the American Chemical Society. PMID 27499510 DOI: 10.1021/Jacs.6B06264  0.519
2016 Fine Nathel NF, Morrill LA, Mayr H, Garg NK. Quantification of the Electrophilicity of Benzyne and Related Intermediates. Journal of the American Chemical Society. PMID 27480639 DOI: 10.1021/Jacs.6B06216  0.333
2016 Levens A, An F, Breugst M, Mayr H, Lupton DW. Influence of the N-Substituents on the Nucleophilicity and Lewis Basicity of N-Heterocyclic Carbenes. Organic Letters. PMID 27434216 DOI: 10.1021/Acs.Orglett.6B01525  0.353
2016 Chelli S, Troshin K, Mayer P, Lakhdar S, Ofial AR, Mayr H. Nucleophilicity Parameters of Stabilized Iodonium Ylides for Characterizing their Synthetic Potential. Journal of the American Chemical Society. PMID 27428876 DOI: 10.1021/Jacs.6B05768  0.849
2016 Berionni G, Kurouchi H, Eisenburger L, Mayr H. Nucleophilicity of Alkyl Zirconocene and Titanocene Precatalysts and Kinetics of Activation by Carbenium Ions and by B(C₆F₅)₃. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27245119 DOI: 10.1002/Chem.201602452  0.727
2016 Chen Q, Mayer P, Mayr H. Ethenesulfonyl Fluoride: The Most Perfect Michael Acceptor Ever Found? Angewandte Chemie (International Ed. in English). PMID 27159425 DOI: 10.1002/Anie.201601875  0.493
2016 Mayr H, Ofial AR. Philicities, Fugalities, and Equilibrium Constants. Accounts of Chemical Research. PMID 27108991 DOI: 10.1021/Acs.Accounts.6B00071  0.829
2016 Chelli S, Troshin K, Lakhdar S, Mayr H, Mayer P. Crystal structure of 2-[chloro-(4-meth-oxy-phen-yl)meth-yl]-2-(4-meth-oxy-phen-yl)-5,5-di-methyl-cyclo-hexane-1,3-dione. Acta Crystallographica. Section E, Crystallographic Communications. 72: 300-3. PMID 27006792 DOI: 10.1107/S2056989016002085  0.633
2016 Chelli S, Troshin K, Lakhdar S, Mayr H, Mayer P. Crystal structure of (1S,2R)-6,6-dimethyl-4,8-dioxo-2-phenyl-spiro-[2.5]octane-1-carbaldehyde. Acta Crystallographica. Section E, Crystallographic Communications. 72: 266-8. PMID 26958403 DOI: 10.1107/S205698901600164X  0.623
2016 Byrne PA, Kobayashi S, Breugst M, Laub H, Mayr H. Quantification of the nucleophilic reactivity of nicotine Journal of Physical Organic Chemistry. 29: 759-767. DOI: 10.1002/Poc.3580  0.375
2016 Follet E, Mayer P, Mayr H. Lewis Acidities of Indol-3-ylmethylium Ions and Intrinsic Barriers of Their Reactions with Phosphines and Pyridines European Journal of Organic Chemistry. 2016: 4050-4058. DOI: 10.1002/Ejoc.201600572  0.52
2016 Puente Á, He S, Corral-Bautista F, Ofial AR, Mayr H. Nucleophilic Reactivities of 2-Substituted Malonates European Journal of Organic Chemistry. DOI: 10.1002/Ejoc.201600107  0.519
2016 Chen Q, Mayer P, Mayr H. Ethensulfonylfluorid: der beste je entdeckte Michael-Akzeptor? Angewandte Chemie. 128: 12854-12858. DOI: 10.1002/Ange.201601875  0.34
2015 Mayr H, Ofial AR. A quantitative approach to polar organic reactivity. Sar and Qsar in Environmental Research. 1-28. PMID 26315811 DOI: 10.1080/1062936X.2015.1078409  0.449
2015 Follet E, Berionni G, Mayer P, Mayr H. Structure and Reactivity of Indolylmethylium Ions: Scope and Limitations in Synthetic Applications. The Journal of Organic Chemistry. 80: 8643-56. PMID 26218059 DOI: 10.1021/Acs.Joc.5B01298  0.768
2015 Feeney K, Berionni G, Mayr H, Aggarwal VK. Structure and reactivity of boron-ate complexes derived from primary and secondary boronic esters. Organic Letters. 17: 2614-7. PMID 25973673 DOI: 10.1021/Acs.Orglett.5B00918  0.719
2015 Corral-Bautista F, Klier L, Knochel P, Mayr H. From Carbanions to Organometallic Compounds: Quantification of Metal Ion Effects on Nucleophilic Reactivities. Angewandte Chemie (International Ed. in English). PMID 25951612 DOI: 10.1002/Anie.201501385  0.49
2015 Moriya K, Didier D, Simon M, Hammann JM, Berionni G, Karaghiosoff K, Zipse H, Mayr H, Knochel P. Stereoselective synthesis and reactions of secondary alkyllithium reagents functionalized at the 3-position. Angewandte Chemie (International Ed. in English). 54: 2754-7. PMID 25640227 DOI: 10.1002/Anie.201409165  0.731
2015 Berionni G, Leonov AI, Mayer P, Ofial AR, Mayr H. Fine-tuning the nucleophilic reactivities of boron ate complexes derived from aryl and heteroaryl boronic esters. Angewandte Chemie (International Ed. in English). 54: 2780-3. PMID 25604646 DOI: 10.1002/Anie.201410562  0.833
2015 Mayr H, Ammer J, Baidya M, Maji B, Nigst TA, Ofial AR, Singer T. Scales of Lewis basicities toward C-centered Lewis acids (carbocations). Journal of the American Chemical Society. 137: 2580-99. PMID 25555037 DOI: 10.1021/Ja511639B  0.824
2015 Corral-Bautista F, Appel R, Frickel JS, Mayr H. Quantification of ion-pairing effects on the nucleophilic reactivities of benzoyl- and phenyl-substituted carbanions in dimethylsulfoxide. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 875-84. PMID 25384456 DOI: 10.1002/Chem.201404500  0.499
2015 Corral-Bautista F, Mayr H. Quantification of the Nucleophilic Reactivities of Cyclic β-Keto Ester Anions European Journal of Organic Chemistry. 2015: 7594-7601. DOI: 10.1002/Ejoc.201501107  0.49
2015 Corral-Bautista F, Klier L, Knochel P, Mayr H. Von Carbanionen zu metallorganischen Verbindungen: Quantifizierung des Metallionen-Effekts auf die nucleophile Reaktivität Angewandte Chemie. 127: 12676-12680. DOI: 10.1002/Ange.201501385  0.406
2015 Berionni G, Leonov AI, Mayer P, Ofial AR, Mayr H. Feineinstellung der nucleophilen Reaktivität von Bor-at-Komplexen aus Aryl- und Heteroarylboronsäureestern Angewandte Chemie. 127: 2820-2824. DOI: 10.1002/Ange.201410562  0.671
2015 Moriya K, Didier D, Simon M, Hammann JM, Berionni G, Karaghiosoff K, Zipse H, Mayr H, Knochel P. Stereoselektive Synthese und Reaktionen von in Position 3 funktionalisierten sekundären Alkyllithiumverbindungen Angewandte Chemie. 127: 2793-2796. DOI: 10.1002/Ange.201409165  0.664
2014 Erdmann H, An F, Mayer P, Ofial AR, Lakhdar S, Mayr H. Structures and reactivities of 2-Trityl- and 2-(Triphenylsilyl)pyrrolidine-derived enamines: evidence for negative hyperconjugation with the trityl group. Journal of the American Chemical Society. 136: 14263-9. PMID 25220171 DOI: 10.1021/Ja508065E  0.793
2014 Guo X, Zipse H, Mayr H. Mechanisms of hydride abstractions by quinones. Journal of the American Chemical Society. 136: 13863-73. PMID 25196576 DOI: 10.1021/Ja507598Y  0.483
2014 Chen X, Tan Y, Berionni G, Ofial AR, Mayr H. Di- and triarylmethylium ions as probes for the ambident reactivities of carbanions derived from 5-benzylated Meldrum's acid. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 11069-77. PMID 25099696 DOI: 10.1002/Chem.201403161  0.836
2014 Guo X, Mayr H. Quantification of the ambident electrophilicities of halogen-substituted quinones. Journal of the American Chemical Society. 136: 11499-512. PMID 25053179 DOI: 10.1021/Ja505613B  0.481
2014 Frischmuth A, Fernández M, Barl NM, Achrainer F, Zipse H, Berionni G, Mayr H, Karaghiosoff K, Knochel P. New in situ trapping metalations of functionalized arenes and heteroarenes with TMPLi in the presence of ZnCl2 and other metal salts. Angewandte Chemie (International Ed. in English). 53: 7928-32. PMID 24923789 DOI: 10.1002/Anie.201403688  0.668
2014 Laub HA, Evano G, Mayr H. Hydrocarbation of C≡C bonds: quantification of the nucleophilic reactivity of ynamides. Angewandte Chemie (International Ed. in English). 53: 4968-71. PMID 24715471 DOI: 10.1002/Anie.201402055  0.47
2014 Laub HA, Mayr H. Electrophilic alkylations of vinylsilanes: a comparison of α- and β-silyl effects. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 1103-10. PMID 24357501 DOI: 10.1002/Chem.201303215  0.422
2014 Allgäuer DS, Mayr H. Electrophilicities of 1,2-disubstituted ethylenes European Journal of Organic Chemistry. 2014: 2956-2963. DOI: 10.1002/Ejoc.201301779  0.472
2014 Mayr H. Modern Nucleophilic Aromatic Substitution. Von Francois Terrier. Angewandte Chemie. 126: 7245-7245. DOI: 10.1002/Ange.201404183  0.386
2014 Frischmuth A, Fernández M, Barl NM, Achrainer F, Zipse H, Berionni G, Mayr H, Karaghiosoff K, Knochel P. In-situ-Abfangmethode zur Metallierung funktionalisierter Arene und Heteroarene mit TMPLi in Gegenwart von ZnCl2und anderen Metallsalzen Angewandte Chemie. 126: 8062-8066. DOI: 10.1002/Ange.201403688  0.654
2014 An F, Paul S, Ammer J, Ofial AR, Mayer P, Lakhdar S, Mayr H. Structures and reactivities of iminium ions derived from substituted cinnamaldehydes and various chiral imidazolidin-4-ones Asian Journal of Organic Chemistry. 3: 550-555. DOI: 10.1002/Ajoc.201402009  0.734
2013 Maji B, Troshin K, Mayr H. Ambident reactivities of formaldehyde N,N-dialkylhydrazones. Angewandte Chemie (International Ed. in English). 52: 11900-4. PMID 24105976 DOI: 10.1002/Anie.201305092  0.586
2013 Allgäuer DS, Mayer P, Mayr H. Nucleophilicity parameters of pyridinium ylides and their use in mechanistic analyses. Journal of the American Chemical Society. 135: 15216-24. PMID 24020381 DOI: 10.1021/Ja407885H  0.533
2013 Ammer J, Nolte C, Karaghiosoff K, Thallmair S, Mayer P, de Vivie-Riedle R, Mayr H. Ion-pairing of phosphonium salts in solution: C-H⋅⋅⋅halogen and C-H⋅⋅⋅π hydrogen bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 14612-30. PMID 24014323 DOI: 10.1002/Chem.201204561  0.349
2013 Guo X, Mayr H. Manifestation of polar reaction pathways of 2,3-dichloro-5,6-dicyano-p-benzoquinone. Journal of the American Chemical Society. 135: 12377-87. PMID 23937562 DOI: 10.1021/Ja405890D  0.424
2013 Maji B, Mayr H. Structures and ambident reactivities of azolium enolates. Angewandte Chemie (International Ed. in English). 52: 11163-7. PMID 23897657 DOI: 10.1002/Anie.201303524  0.622
2013 Holland MC, Paul S, Schweizer WB, Bergander K, Mück-Lichtenfeld C, Lakhdar S, Mayr H, Gilmour R. Noncovalent interactions in organocatalysis: modulating conformational diversity and reactivity in the MacMillan catalyst. Angewandte Chemie (International Ed. in English). 52: 7967-71. PMID 23794233 DOI: 10.1002/Anie.201301864  0.593
2013 Appel R, Chelli S, Tokuyasu T, Troshin K, Mayr H. Electrophilicities of benzaldehyde-derived iminium ions: quantification of the electrophilic activation of aldehydes by iminium formation. Journal of the American Chemical Society. 135: 6579-87. PMID 23570344 DOI: 10.1021/Ja401106X  0.512
2013 Sailer CF, Thallmair S, Fingerhut BP, Nolte C, Ammer J, Mayr H, Pugliesi I, de Vivie-Riedle R, Riedle E. A comprehensive microscopic picture of the benzhydryl radical and cation photogeneration and interconversion through electron transfer. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 14: 1423-37. PMID 23554328 DOI: 10.1002/Cphc.201201057  0.358
2013 Berionni G, Morozova V, Heininger M, Mayer P, Knochel P, Mayr H. Electrophilic aromatic substitutions of aryltrifluoroborates with retention of the BF3- group: quantification of the activating and directing effects of the trifluoroborate group. Journal of the American Chemical Society. 135: 6317-24. PMID 23534556 DOI: 10.1021/Ja4017655  0.724
2013 Troshin K, Mayr H. Electrofugalities of 1,3-diarylallyl cations. The Journal of Organic Chemistry. 78: 2649-60. PMID 23368714 DOI: 10.1021/Jo302766K  0.437
2013 Horn M, Schappele LH, Lang-Wittkowski G, Mayr H, Ofial AR. Towards a comprehensive hydride donor ability scale. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 249-63. PMID 23203839 DOI: 10.1002/Chem.201202839  0.81
2013 Troshin K, Mayr H. Ion pair dynamics: solvolyses of chiral 1,3-diarylallyl carboxylates as a case study. Journal of the American Chemical Society. 135: 252-65. PMID 23186244 DOI: 10.1021/Ja308670G  0.433
2013 Maji B, Mayr H. Nucleophilic reactivities of Schiff bases Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 68: 693-699. DOI: 10.5560/Znb.2013-3085  0.597
2013 Ammer J, Mayr H. Photogeneration of carbocations: Applications in physical organic chemistry and the design of suitable precursors Journal of Physical Organic Chemistry. 26: 956-969. DOI: 10.1002/Poc.3132  0.331
2013 Ammer J, Mayr H. Solvent nucleophilicities of hexafluoroisopropanol/water mixtures Journal of Physical Organic Chemistry. 26: 59-63. DOI: 10.1002/Poc.3064  0.418
2013 Allgäuer DS, Mayr H. One-pot two-step synthesis of 1-(ethoxycarbonyl)indolizines via pyridinium ylides European Journal of Organic Chemistry. 6379-6388. DOI: 10.1002/Ejoc.201300784  0.357
2013 Corral-Bautista F, Mayr H. Quantification of the nucleophilic reactivities of ethyl arylacetate anions European Journal of Organic Chemistry. 4255-4261. DOI: 10.1002/Ejoc.201300265  0.479
2013 Maji B, Baidya M, Ammer J, Kobayashi S, Mayer P, Ofial AR, Mayr H. Nucleophilic reactivities and Lewis basicities of 2-imidazolines and related N-heterocyclic compounds European Journal of Organic Chemistry. 3369-3377. DOI: 10.1002/Ejoc.201300213  0.696
2013 Nigst TA, Mayr H. Comparison of the Electrophilic Reactivities ofN-Acylpyridinium Ions and Other Acylating Agents European Journal of Organic Chemistry. 2013: 2155-2163. DOI: 10.1002/Ejoc.201201540  0.511
2013 Maji B, Troshin K, Mayr H. Ambidente Reaktivität von Formaldehyd-N,N-dialkylhydrazonen Angewandte Chemie. 125: 12116-12120. DOI: 10.1002/Ange.201305092  0.579
2013 Maji B, Mayr H. Struktur und ambidente Reaktivität von Azolium-Enolaten Angewandte Chemie. 125: 11370-11374. DOI: 10.1002/Ange.201303524  0.528
2013 Holland MC, Paul S, Schweizer WB, Bergander K, Mück-Lichtenfeld C, Lakhdar S, Mayr H, Gilmour R. Nichtbindende Wechselwirkungen in der Organokatalyse: Modulierung konformativer Diversität und Reaktivität im MacMillan-Katalysator Angewandte Chemie. 125: 8125-8129. DOI: 10.1002/Ange.201301864  0.593
2012 Maji B, Berionni G, Mayr H, Mayer P. 5-[(E)-Meth-oxy(phen-yl)methyl-idene]-1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazole. Acta Crystallographica. Section E, Structure Reports Online. 68: o3307. PMID 23468812 DOI: 10.1107/S1600536812045692  0.735
2012 Mayr H, Lakhdar S, Maji B, Ofial AR. A quantitative approach to nucleophilic organocatalysis. Beilstein Journal of Organic Chemistry. 8: 1458-78. PMID 23019481 DOI: 10.3762/Bjoc.8.166  0.85
2012 Maji B, Mayr H, Mayer P. (Z)-2-[Meth-oxy(phen-yl)methyl-idene]-3,4,5-trimethyl-2,3-dihydro-1,3-thia-zole. Acta Crystallographica. Section E, Structure Reports Online. 68: o2644. PMID 22969543 DOI: 10.1107/S1600536812034137  0.567
2012 Maji B, Mayr H. Structures and reactivities of O-methylated Breslow intermediates. Angewandte Chemie (International Ed. in English). 51: 10408-12. PMID 22968992 DOI: 10.1002/Anie.201204524  0.557
2012 Nigst TA, Antipova A, Mayr H. Nucleophilic reactivities of hydrazines and amines: the futile search for the α-effect in hydrazine reactivities. The Journal of Organic Chemistry. 77: 8142-55. PMID 22950800 DOI: 10.1021/Jo301497G  0.478
2012 Nigst TA, Ammer J, Mayr H. Photogeneration of benzhydryl cations by near-UV laser flash photolysis of pyridinium salts. The Journal of Physical Chemistry. A. 116: 8494-9. PMID 22849534 DOI: 10.1021/Jp3049247  0.468
2012 Ammer J, Nolte C, Mayr H. Free energy relationships for reactions of substituted benzhydrylium ions: from enthalpy over entropy to diffusion control. Journal of the American Chemical Society. 134: 13902-11. PMID 22839678 DOI: 10.1021/Ja306522B  0.502
2012 Laub HA, Gladow D, Reissig HU, Mayr H. The influence of perfluorinated substituents on the nucleophilic reactivities of silyl enol ethers Organic Letters. 14: 3990-3993. PMID 22830316 DOI: 10.1021/Ol301766W  0.563
2012 Ammer J, Sailer CF, Riedle E, Mayr H. Photolytic generation of benzhydryl cations and radicals from quaternary phosphonium salts: how highly reactive carbocations survive their first nanoseconds. Journal of the American Chemical Society. 134: 11481-94. PMID 22591218 DOI: 10.1021/Ja3017522  0.316
2012 Berionni G, Mayer P, Mayr H. Potassium [1-(tert-but-oxy-carbon-yl)-1H-indol-3-yl]trifluoro-borate hemihydrate. Acta Crystallographica. Section E, Structure Reports Online. 68: m551-2. PMID 22590073 DOI: 10.1107/S1600536812014225  0.671
2012 Maji B, Horn M, Mayr H. Nucleophilic reactivities of deoxy Breslow intermediates: how does aromaticity affect the catalytic activities of N-heterocyclic carbenes? Angewandte Chemie (International Ed. in English). 51: 6231-5. PMID 22573542 DOI: 10.1002/Anie.201202327  0.639
2012 Shi L, Chu Y, Knochel P, Mayr H. Leaving group dependence of the rates of halogen-magnesium exchange reactions. Organic Letters. 14: 2602-5. PMID 22571332 DOI: 10.1021/Ol300906A  0.483
2012 Lakhdar S, Maji B, Mayr H. Imidazolidinone-derived enamines: nucleophiles with low reactivity. Angewandte Chemie (International Ed. in English). 51: 5739-42. PMID 22535655 DOI: 10.1002/Anie.201201240  0.739
2012 Samanta RC, Maji B, De Sarkar S, Bergander K, Fröhlich R, Mück-Lichtenfeld C, Mayr H, Studer A. Nucleophilic addition of enols and enamines to α,β-unsaturated acyl azoliums: mechanistic studies. Angewandte Chemie (International Ed. in English). 51: 5234-8. PMID 22505234 DOI: 10.1002/Anie.201109042  0.561
2012 Maji B, Lakhdar S, Mayr H. Nucleophilicity parameters of enamides and their implications for organocatalytic transformations. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 5732-40. PMID 22461320 DOI: 10.1002/Chem.201103519  0.81
2012 Asahara H, Mayr H. Electrophilicities of bissulfonyl ethylenes. Chemistry, An Asian Journal. 7: 1401-7. PMID 22454302 DOI: 10.1002/Asia.201101046  0.458
2012 Lakhdar S, Baidya M, Mayr H. Kinetics and mechanism of organocatalytic aza-Michael additions: direct observation of enamine intermediates. Chemical Communications (Cambridge, England). 48: 4504-6. PMID 22453687 DOI: 10.1039/C2Cc31224G  0.704
2012 Nolte C, Ammer J, Mayr H. Nucleofugality and nucleophilicity of fluoride in protic solvents. The Journal of Organic Chemistry. 77: 3325-35. PMID 22339036 DOI: 10.1021/Jo300141Z  0.461
2012 Breugst M, Corral Bautista F, Mayr H. Nucleophilic reactivities of the anions of nucleobases and their subunits. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 127-37. PMID 22161734 DOI: 10.1002/Chem.201102411  0.497
2012 Horn M, Mayr H, Lacôte E, Merling E, Deaner J, Wells S, McFadden T, Curran DP. N-Heterocyclic carbene boranes are good hydride donors. Organic Letters. 14: 82-5. PMID 22149270 DOI: 10.1021/Ol202836P  0.371
2012 Berionni G, Maji B, Knochel P, Mayr H. Nucleophilicity parameters for designing transition metal-free C-C bond forming reactions of organoboron compounds Chemical Science. 3: 878-882. DOI: 10.1039/C2Sc00883A  0.79
2012 Troshin K, Mayer P, Mayr H. How does palladium coordination affect the electrophilicities of allyl cations? Development of a robust kinetic method for following reactions of [(η 3-diarylallyl)Pd(PPh 3) 2] + with nucleophiles Organometallics. 31: 2416-2424. DOI: 10.1021/Om3000357  0.46
2012 Horn M, Mayr H. A comprehensive view on stabilities and reactivities of triarylmethyl cations (tritylium ions) Journal of Physical Organic Chemistry. 25: 979-988. DOI: 10.1002/Poc.2979  0.457
2012 Maji B, Stephenson DS, Mayr H. Guanidines: Highly Nucleophilic Organocatalysts Chemcatchem. 4: 993-999. DOI: 10.1002/Cctc.201200143  0.698
2012 Maji B, Mayr H. Struktur und Reaktivität O-methylierter Breslow-Intermediate Angewandte Chemie. 124: 10554-10558. DOI: 10.1002/Ange.201204524  0.535
2012 Maji B, Horn M, Mayr H. Nucleophile Reaktivitäten von Desoxy-Breslow-Intermediaten: Wie beeinflusst Aromatizität die katalytische Aktivität N-heterocyclischer Carbene? Angewandte Chemie. 124: 6335-6339. DOI: 10.1002/Ange.201202327  0.607
2012 Lakhdar S, Maji B, Mayr H. Enamine aus Imidazolidinonen: Nucleophile mit geringer Reaktivität Angewandte Chemie. 124: 5837-5840. DOI: 10.1002/Ange.201201240  0.712
2012 Samanta RC, Maji B, De Sarkar S, Bergander K, Fröhlich R, Mück-Lichtenfeld C, Mayr H, Studer A. Nukleophile Addition von Enolen und Enaminen an α,β-ungesättigte Acylazoliumionen: Mechanistische Studien Angewandte Chemie. 124: 5325-5329. DOI: 10.1002/Ange.201109042  0.534
2011 Zenz I, Mayr H. Electrophilicities of trans-β-nitrostyrenes. The Journal of Organic Chemistry. 76: 9370-8. PMID 21978126 DOI: 10.1021/Jo201678U  0.439
2011 Duan XH, Maji B, Mayr H. Characterization of the nucleophilic reactivities of thiocarboxylate, dithiocarbonate and dithiocarbamate anions. Organic & Biomolecular Chemistry. 9: 8046-50. PMID 21975968 DOI: 10.1039/C1Ob06245J  0.692
2011 Troshin K, Schindele C, Mayr H. Electrophilicities of symmetrically substituted 1,3-diarylallyl cations. The Journal of Organic Chemistry. 76: 9391-408. PMID 21939207 DOI: 10.1021/Jo201668W  0.516
2011 Lakhdar S, Ammer J, Mayr H. Generation of α,β-unsaturated iminium ions by laser flash photolysis. Angewandte Chemie (International Ed. in English). 50: 9953-6. PMID 21898728 DOI: 10.1002/Anie.201103683  0.68
2011 Mayr H, Breugst M, Ofial AR. Farewell to the HSAB treatment of ambident reactivity. Angewandte Chemie (International Ed. in English). 50: 6470-505. PMID 21726020 DOI: 10.1002/Anie.201007100  0.774
2011 Maji B, Breugst M, Mayr H. N-heterocyclic carbenes: organocatalysts with moderate nucleophilicity but extraordinarily high Lewis basicity. Angewandte Chemie (International Ed. in English). 50: 6915-9. PMID 21714052 DOI: 10.1002/Anie.201102435  0.618
2011 Maji B, Joannesse C, Nigst TA, Smith AD, Mayr H. Nucleophilicities and Lewis basicities of isothiourea derivatives. The Journal of Organic Chemistry. 76: 5104-12. PMID 21568333 DOI: 10.1021/Jo200803X  0.684
2011 Appel R, Mayr H. Quantification of the electrophilic reactivities of aldehydes, imines, and enones. Journal of the American Chemical Society. 133: 8240-51. PMID 21553901 DOI: 10.1021/Ja200820M  0.506
2011 De Rycke N, Berionni G, Couty F, Mayr H, Goumont R, David OR. Synthesis and reactivity of highly nucleophilic pyridines. Organic Letters. 13: 530-3. PMID 21186828 DOI: 10.1021/Ol1029589  0.687
2011 Lakhdar S, Mayr H. Counterion effects in iminium-activated electrophilic aromatic substitutions of pyrroles. Chemical Communications (Cambridge, England). 47: 1866-8. PMID 21135973 DOI: 10.1039/C0Cc04295A  0.748
2011 Lakhdar S, Ammer J, Mayr H. Electrophilic Reactivities of Photo-Generated α,β-UnsaturatedIminium Ions Synfacts. 2011: 1246-1246. DOI: 10.1055/S-0031-1289264  0.636
2011 Horn M, Metz C, Mayr H. Electrofugalities of acceptor-substituted tritylium ions European Journal of Organic Chemistry. 6476-6485. DOI: 10.1002/Ejoc.201100912  0.426
2011 Horn M, Mayr H. Electrophilicities of acceptor-substituted tritylium ions European Journal of Organic Chemistry. 6470-6475. DOI: 10.1002/Ejoc.201100910  0.443
2011 Streidl N, Mayr H. Ionizing power of aprotic solvents European Journal of Organic Chemistry. 2498-2506. DOI: 10.1002/Ejoc.201001700  0.434
2011 Lakhdar S, Ammer J, Mayr H. Laserblitzphotolytische Erzeugung α,β-ungesättigter Iminium-Ionen Angewandte Chemie. 123: 10127-10130. DOI: 10.1002/Ange.201103683  0.589
2011 Maji B, Breugst M, Mayr H. N-Heterocyclische Carbene: Organokatalysatoren mit mäßiger Nucleophilie, aber außerordentlich hoher Lewis-Basizität Angewandte Chemie. 123: 7047-7052. DOI: 10.1002/Ange.201102435  0.593
2010 Appel R, Hartmann N, Mayr H. Scope and limitations of cyclopropanations with sulfur ylides. Journal of the American Chemical Society. 132: 17894-900. PMID 21114316 DOI: 10.1021/Ja1084749  0.493
2010 Streidl N, Denegri B, Kronja O, Mayr H. A practical guide for estimating rates of heterolysis reactions. Accounts of Chemical Research. 43: 1537-49. PMID 21082867 DOI: 10.1021/Ar100091M  0.354
2010 Kanzian T, Lakhdar S, Mayr H. Kinetic evidence for the formation of oxazolidinones in the stereogenic step of proline-catalyzed reactions. Angewandte Chemie (International Ed. in English). 49: 9526-9. PMID 21053224 DOI: 10.1002/Anie.201004344  0.696
2010 Laub HA, Yamamoto H, Mayr H. Effect of the "supersilyl" group on the reactivities of allylsilanes and silyl enol ethers. Organic Letters. 12: 5206-9. PMID 20977255 DOI: 10.1021/Ol102220E  0.515
2010 Breugst M, Mayr H. Ambident reactivities of pyridone anions. Journal of the American Chemical Society. 132: 15380-9. PMID 20942421 DOI: 10.1021/Ja106962U  0.523
2010 Kanzian T, Mayr H. Electrophilic reactivities of azodicarboxylates. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 11670-7. PMID 20836096 DOI: 10.1002/Chem.201001598  0.523
2010 Kanzian T, Nicolini S, De Crescentini L, Attanasi OA, Ofial AR, Mayr H. Electrophilic reactivities of 1,2-diaza-1,3-dienes. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 12008-16. PMID 20836093 DOI: 10.1002/Chem.201000828  0.829
2010 Breugst M, Tokuyasu T, Mayr H. Nucleophilic reactivities of imide and amide anions. The Journal of Organic Chemistry. 75: 5250-8. PMID 20670031 DOI: 10.1021/Jo1009883  0.473
2010 Horn M, Mayr H. Stabilities of trityl-protected substrates: the wide mechanistic spectrum of trityl ester hydrolyses. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 7469-77. PMID 20564285 DOI: 10.1002/Chem.200902669  0.427
2010 Horn M, Mayr H. Electrophilicity versus electrofugality of tritylium ions in aqueous acetonitrile. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 7478-87. PMID 20496349 DOI: 10.1002/Chem.200902670  0.427
2010 Baidya M, Brotzel F, Mayr H. Nucleophilicities and Lewis basicities of imidazoles, benzimidazoles, and benzotriazoles. Organic & Biomolecular Chemistry. 8: 1929-35. PMID 20449500 DOI: 10.1039/C000965B  0.536
2010 Duan XH, Mayr H. Electrophilicities of alpha-chlorinating agents used in organocatalysis. Organic Letters. 12: 2238-41. PMID 20408599 DOI: 10.1021/Ol100592J  0.336
2010 Baidya M, Kobayashi S, Mayr H. Nucleophilicity and nucleofugality of phenylsulfinate (PhSO(2)(-)): a key to understanding its ambident reactivity. Journal of the American Chemical Society. 132: 4796-805. PMID 20225879 DOI: 10.1021/Ja9102056  0.463
2010 Baidya M, Remennikov GY, Mayer P, Mayr H. SN2' versus SN2 reactivity: control of regioselectivity in conversions of Baylis-Hillman adducts. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 1365-71. PMID 19957319 DOI: 10.1002/Chem.200902487  0.537
2010 Dong ZB, Manolikakes G, Shi L, Knochel P, Mayr H. Structure-reactivity relationships in negishi cross-coupling reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 248-53. PMID 19904779 DOI: 10.1002/Chem.200902132  0.481
2010 Mayr H, Kanzian T, Lakhdar S. The Increased Reactivity of the Proline Carboxylate Derived Enamine Synfacts. 2011: 0091-0091. DOI: 10.1055/S-0030-1259189  0.647
2010 Ammer J, Mayr H. Electrophilic Reactivity of the α,α-Dimethylbenzyl (Cumyl) Cation Macromolecules. 43: 1719-1723. DOI: 10.1021/Ma9024569  0.462
2010 Lakhdar S, Ofial AR, Mayr H. Reactivity parameters for rationalizing iminium-catalyzed reactions Journal of Physical Organic Chemistry. 23: 886-892. DOI: 10.1002/Poc.1737  0.759
2010 Ammer J, Baidya M, Kobayashi S, Mayr H. Nucleophilic reactivities of tertiary alkylamines Journal of Physical Organic Chemistry. 23: 1029-1035. DOI: 10.1002/Poc.1707  0.486
2010 Streidl N, Branzan R, Mayr H. Nucleophilicities and nucleofugalities of organic carbonates European Journal of Organic Chemistry. 4205-4210. DOI: 10.1002/Ejoc.201000414  0.452
2010 Nolte C, Mayr H. Kinetics of the Solvolyses of Fluoro-Substituted Benzhydryl Derivatives: Reference Electrofuges for the Development of a Comprehensive Nucleofugality Scale European Journal of Organic Chemistry. 2010: 01435-1439. DOI: 10.1002/Ejoc.200901400  0.35
2010 MAYR H. ChemInform Abstract: Fundamentals of the Reactions of Carbocations with Nucleophiles Cheminform. 28: no-no. DOI: 10.1002/chin.199704306  0.308
2010 Kanzian T, Lakhdar S, Mayr H. Kinetischer Nachweis der Bildung von Oxazolidinonen im stereogenen Schritt prolinkatalysierter Reaktionen Angewandte Chemie. 122: 9717-9720. DOI: 10.1002/Ange.201004344  0.595
2009 Hampel N, Richter D, Ofial AR, Mayr H, Mayer P. 4-[4-(Dimethyl-amino)benzyl-idene]-2,6-dimethyl-cyclo-hexa-2,5-dienone. Acta Crystallographica. Section E, Structure Reports Online. 65: o2102. PMID 21577517 DOI: 10.1107/S1600536809030748  0.758
2009 Richter D, Tan Y, Antipova A, Zhu XQ, Mayr H. Kinetics of hydride abstractions from 2-arylbenzimidazolines. Chemistry, An Asian Journal. 4: 1824-9. PMID 19839024 DOI: 10.1002/Asia.200900322  0.45
2009 Streidl N, Antipova A, Mayr H. Suppression of common-ion return by amines: a method to measure rates of fast S(N)1 reactions. The Journal of Organic Chemistry. 74: 7328-34. PMID 19736921 DOI: 10.1021/Jo901410B  0.462
2009 Baidya M, Horn M, Zipse H, Mayr H. Organocatalytic activity of cinchona alkaloids: which nitrogen is more nucleophilic? The Journal of Organic Chemistry. 74: 7157-64. PMID 19697899 DOI: 10.1021/Jo901670W  0.466
2009 Phan TB, Nolte C, Kobayashi S, Ofial AR, Mayr H. Can one predict changes from S(N)1 to S(N)2 mechanisms? Journal of the American Chemical Society. 131: 11392-401. PMID 19634906 DOI: 10.1021/Ja903207B  0.824
2009 Shi L, Horn M, Kobayashi S, Mayr H. Carbocationic n-endo-trig cyclizations. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8533-41. PMID 19630020 DOI: 10.1002/Chem.200901246  0.321
2009 Shi L, Chu Y, Knochel P, Mayr H. Kinetics of bromine-magnesium exchange reactions in heteroaryl bromides. Organic Letters. 11: 3502-5. PMID 19601592 DOI: 10.1021/Ol9013393  0.47
2009 Lakhdar S, Appel R, Mayr H. How does electrostatic activation control iminium-catalyzed cyclopropanations? Angewandte Chemie (International Ed. in English). 48: 5034-7. PMID 19492379 DOI: 10.1002/Anie.200900933  0.691
2009 Shi L, Chu Y, Knochel P, Mayr H. Kinetics of bromine-magnesium exchange reactions in substituted bromobenzenes. The Journal of Organic Chemistry. 74: 2760-4. PMID 19281194 DOI: 10.1021/Jo802770H  0.542
2009 Richter D, Mayr H. Hydride-donor abilities of 1,4-dihydropyridines: a comparison with pi nucleophiles and borohydride anions. Angewandte Chemie (International Ed. in English). 48: 1958-61. PMID 19185030 DOI: 10.1002/Anie.200804263  0.473
2009 Manolikakes G, Dong Z, Mayr H, Li J, Knochel P. Negishi cross-couplings compatible with unprotected amide functions. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 1324-8. PMID 19115290 DOI: 10.1002/Chem.200802349  0.318
2009 Appel R, Loos R, Mayr H. Nucleophilicity parameters for phosphoryl-stabilized carbanions and phosphorus ylides: implications for Wittig and related olefination reactions. Journal of the American Chemical Society. 131: 704-14. PMID 19105684 DOI: 10.1021/Ja8056216  0.465
2009 Kaumanns O, Appel R, Lemek T, Seeliger F, Mayr H. Nucleophilicities of the anions of arylacetonitriles and arylpropionitriles in dimethyl sulfoxide. The Journal of Organic Chemistry. 74: 75-81. PMID 19032115 DOI: 10.1021/Jo802241X  0.413
2009 Mayr H, Ofial AR. How to predict changes in solvolysis mechanisms Pure and Applied Chemistry. 81: 667-683. DOI: 10.1351/Pac-Con-08-08-26  0.487
2009 Lakhdar S, Appel R, Mayr H. Strong Directed Electrostatic Activation Synfacts. 2009: 918-918. DOI: 10.1055/S-0029-1217595  0.593
2009 Lakhdar S, Tokuyasu T, Mayr H. Insights into Iminium Catalysis Synfacts. 2009: 208-208. DOI: 10.1055/S-0028-1087590  0.625
2009 Kanzian T, Nigst TA, Maier A, Pichl S, Mayr H. Nucleophilic Reactivities of Primary and Secondary Amines in Acetonitrile European Journal of Organic Chemistry. 2009: 6379-6385. DOI: 10.1002/Ejoc.200900925  0.519
2009 Richter D, Hampel N, Singer T, Ofial AR, Mayr H. Synthesis and characterization of novel quinone methides: Reference electrophiles for the construction of nucleophilicity scales European Journal of Organic Chemistry. 3203-3211. DOI: 10.1002/Ejoc.200900299  0.458
2009 Kędziorek M, Mayer P, Mayr H. Nucleophilic Reactivities of Azulene and Fulvenes European Journal of Organic Chemistry. 2009: 1202-1206. DOI: 10.1002/Ejoc.200801099  0.523
2009 Lakhdar S, Appel R, Mayr H. Wie werden Iminium-katalysierte Cyclopropanierungen durch elektrostatische Aktivierung gesteuert? Angewandte Chemie. 121: 5134-5137. DOI: 10.1002/Ange.200900933  0.636
2009 Richter D, Mayr H. Hydrid-Donor-Stärke von 1,4-Dihydropyridinen: ein Vergleich mit π-Nucleophilen und Borhydrid-Anionen Angewandte Chemie. 121: 1992-1995. DOI: 10.1002/Ange.200804263  0.343
2008 Lakhdar S, Tokuyasu T, Mayr H. Electrophilic reactivities of alpha,beta-unsaturated iminium ions. Angewandte Chemie (International Ed. in English). 47: 8723-6. PMID 18798186 DOI: 10.1002/Anie.200802889  0.62
2008 Kaumanns O, Lucius R, Mayr H. Determination of the electrophilicity parameters of diethyl benzylidenemalonates in dimethyl sulfoxide: reference electrophiles for characterizing strong nucleophiles. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 9675-82. PMID 18792024 DOI: 10.1002/Chem.200801277  0.475
2008 Seeliger F, Mayr H. Nucleophilic reactivities of benzenesulfonyl-substituted carbanions. Organic & Biomolecular Chemistry. 6: 3052-8. PMID 18698462 DOI: 10.1039/B805604H  0.465
2008 Manolikakes G, Schade MA, Hernandez CM, Mayr H, Knochel P. Negishi cross-couplings of unsaturated halides bearing relatively acidic hydrogen atoms with organozinc reagents. Organic Letters. 10: 2765-8. PMID 18529011 DOI: 10.1021/Ol8009013  0.406
2008 Seeliger F, Błazej S, Bernhardt S, Makosza M, Mayr H. Reactions of nitroheteroarenes with carbanions: bridging aromatic, heteroaromatic, and vinylic electrophilicity. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 6108-18. PMID 18512691 DOI: 10.1002/Chem.200800329  0.457
2008 Schaller HF, Mayr H. "Carbocation watching" in solvolysis reactions. Angewandte Chemie (International Ed. in English). 47: 3958-61. PMID 18442027 DOI: 10.1002/Anie.200800354  0.398
2008 Schaller HF, Schmidhammer U, Riedle E, Mayr H. Ambident reactivity of the cyanate anion. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 3866-8. PMID 18381723 DOI: 10.1002/Chem.200800314  0.327
2008 Baidya M, Mayr H. Nucleophilicities and carbon basicities of DBU and DBN. Chemical Communications (Cambridge, England). 1792-4. PMID 18379695 DOI: 10.1039/B801811A  0.313
2008 Kaumanns O, Mayr H. Electrophilicity parameters of 5-benzylidene-2,2-dimethyl[1,3]dioxane-4,6-diones (benzylidene Meldrum's acids). The Journal of Organic Chemistry. 73: 2738-45. PMID 18315007 DOI: 10.1021/Jo702590S  0.482
2008 Schaller HF, Tishkov AA, Feng X, Mayr H. Direct observation of the ionization step in solvolysis reactions: electrophilicity versus electrofugality of carbocations. Journal of the American Chemical Society. 130: 3012-22. PMID 18281983 DOI: 10.1021/Ja0765464  0.457
2008 Westermaier M, Mayr H. Regio- and stereoselective ring-opening reactions of epoxides with indoles and pyrroles in 2,2,2-trifluoroethanol. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 1638-47. PMID 18064625 DOI: 10.1002/Chem.200701366  0.393
2008 Shi L, Chu Y, Knochel P, Mayr H. Relative rates of bromine-magnesium exchange reactions in substituted bromobenzene derivatives. Angewandte Chemie (International Ed. in English). 47: 202-4. PMID 18038441 DOI: 10.1002/Anie.200704100  0.531
2008 Berger STA, Lemek T, Mayr H. Nucleophilicity of the bis-(4-nitrophenyl)-methyl anion Arkivoc. 2008. DOI: 10.3998/Ark.5550190.0009.A05  0.448
2008 Manolikakes G, Schade MA, Hernandez CM, Mayr H, Knochel P. Negishi Cross-Couplings of Unprotected Phenols, Anilines,and Alcohols Synfacts. 2008: 971-971. DOI: 10.1055/S-2008-1078619  0.312
2008 Mayr H, Ofial AR. Do general nucleophilicity scales exist? Journal of Physical Organic Chemistry. 21: 584-595. DOI: 10.1002/Poc.1325  0.434
2008 Nigst TA, Westermaier M, Ofial AR, Mayr H. Nucleophilic Reactivities of Pyrroles (Eur. J. Org. Chem. 14/2008) European Journal of Organic Chemistry. 2008: 2343-2343. DOI: 10.1002/Ejoc.200890033  0.467
2008 Nigst TA, Westermaier M, Ofial AR, Mayr H. Nucleophilic Reactivities of Pyrroles European Journal of Organic Chemistry. 2008: 2369-2374. DOI: 10.1002/Ejoc.200800092  0.543
2008 Lakhdar S, Tokuyasu T, Mayr H. Elektrophile Reaktivität α,β-ungesättigter Iminiumionen Angewandte Chemie. 120: 8851-8854. DOI: 10.1002/Ange.200802889  0.588
2008 Shi L, Chu Y, Knochel P, Mayr H. Relative Geschwindigkeiten der Brom-Magnesium-Austauschreaktionen an substituierten Brombenzolderivaten Angewandte Chemie. 120: 208-210. DOI: 10.1002/Ange.200704100  0.37
2007 Brotzel F, Mayr H. Nucleophilicities of amino acids and peptides. Organic & Biomolecular Chemistry. 5: 3814-20. PMID 18004461 DOI: 10.1039/B713778H  0.369
2007 Khomutova YA, Smirnov VO, Mayr H, Ioffe SL. Thermodynamic stability and reactivity of silylated bis(oxy)iminium ions. The Journal of Organic Chemistry. 72: 9134-40. PMID 17973425 DOI: 10.1021/Jo070633X  0.419
2007 Seeliger F, Berger ST, Remennikov GY, Polborn K, Mayr H. Electrophilicity of 5-benzylidene-1,3-dimethylbarbituric and -thiobarbituric acids. The Journal of Organic Chemistry. 72: 9170-80. PMID 17963402 DOI: 10.1021/Jo071273G  0.419
2007 Dubbaka SR, Kienle M, Mayr H, Knochel P. Copper(I)-mediated oxidative cross-coupling between functionalized alkynyl lithium and aryl magnesium reagents. Angewandte Chemie (International Ed. in English). 46: 9093-6. PMID 17943941 DOI: 10.1002/Anie.200703097  0.356
2007 Berger ST, Seeliger FH, Hofbauer F, Mayr H. Electrophilicity parameters for 2-benzylidene-indan-1,3-diones--a systematic extension of the benzhydrylium based electrophilicity scale. Organic & Biomolecular Chemistry. 5: 3020-6. PMID 17728869 DOI: 10.1039/B708025E  0.458
2007 Schröder D, Roithová J, Gruene P, Schwarz H, Mayr H, Koszinowski K. Unexpected gas-phase reactivity of the CH3OH adduct of Michler's hydrol blue: proton-shuttle catalysis and stepwise radical expulsions. The Journal of Physical Chemistry. A. 111: 8925-33. PMID 17718550 DOI: 10.1021/Jp073950G  0.353
2007 Berger ST, Ofial AR, Mayr H. Inverse solvent effects in carbocation carbanion combination reactions: the unique behavior of trifluoromethylsulfonyl stabilized carbanions. Journal of the American Chemical Society. 129: 9753-61. PMID 17636911 DOI: 10.1021/Ja072135B  0.825
2007 Brotzel F, Chu YC, Mayr H. Nucleophilicities of primary and secondary amines in water. The Journal of Organic Chemistry. 72: 3679-88. PMID 17411095 DOI: 10.1021/Jo062586Z  0.516
2007 Tumanov VV, Tishkov AA, Mayr H. Nucleophilicity parameters for alkyl and aryl isocyanides. Angewandte Chemie (International Ed. in English). 46: 3563-6. PMID 17394269 DOI: 10.1002/Anie.200605205  0.368
2007 Westermaier M, Mayr H. Electrophilic allylations and benzylations of indoles in neutral aqueous or alcoholic solutions. Organic Letters. 8: 4791-4. PMID 17020304 DOI: 10.1021/Ol0618555  0.37
2007 Brotzel F, Kempf B, Singer T, Zipse H, Mayr H. Nucleophilicities and carbon basicities of pyridines. Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 336-45. PMID 17009366 DOI: 10.1002/Chem.200600941  0.49
2007 Krasovskiy A, Tishkov A, Del Amo V, Mayr H, Knochel P. Transition-metal-free homocoupling of organomagnesium compounds. Angewandte Chemie (International Ed. in English). 45: 5010-4. PMID 16819745 DOI: 10.1002/Anie.200600772  0.335
2007 Mayr H, Ofial AR. The reactivity-selectivity principle: an imperishable myth in organic chemistry. Angewandte Chemie (International Ed. in English). 45: 1844-54. PMID 16470749 DOI: 10.1002/Anie.200503273  0.75
2007 Denegri B, Ofial AR, Jurić S, Streiter A, Kronja O, Mayr H. How fast do R-X bonds ionize? A semiquantitative approach. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 1657-66. PMID 16331713 DOI: 10.1002/Chem.200500847  0.768
2007 Denegri B, Streiter A, Jurić S, Ofial AR, Kronja O, Mayr H. Kinetics of the solvolyses of benzhydryl derivatives: basis for the construction of a comprehensive nucleofugality scale. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 1648-56. PMID 16320366 DOI: 10.1002/Chem.200500845  0.796
2007 Mayr H. The Investigation of Organic Reactions and their Mechanisms. Edited by Howard Maskill. Angewandte Chemie International Edition. 46: 5053-5053. DOI: 10.1002/Anie.200685497  0.349
2007 Mayr H. The Investigation of Organic Reactions and their Mechanisms. Herausgegeben von Howard Maskill. Angewandte Chemie. 119: 5141-5142. DOI: 10.1002/Ange.200685497  0.351
2007 Tumanov V, Tishkov A, Mayr H. Nucleophilie-Parameter von Alkyl- und Arylisocyaniden Angewandte Chemie. 119: 3633-3636. DOI: 10.1002/Ange.200605205  0.308
2006 Lakhdar S, Westermaier M, Terrier F, Goumont R, Boubaker T, Ofial AR, Mayr H. Nucleophilic reactivities of indoles. The Journal of Organic Chemistry. 71: 9088-95. PMID 17109534 DOI: 10.1021/Jo0614339  0.828
2006 Kempf B, Mayr H. Rates and equilibria of the reactions of tertiary phosphanes and phosphites with benzhydrylium ions. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 917-27. PMID 15593116 DOI: 10.1002/Chem.200400696  0.508
2006 Phan TB, Mayr H. Nucleophilic reactivity of the azide ion in various solvents Journal of Physical Organic Chemistry. 19: 706-713. DOI: 10.1002/Poc.1063  0.458
2006 Binh Phan T, Mayr H. Nucleophilicity Parameters for Carbanions in Methanol European Journal of Organic Chemistry. 2006: 2530-2537. DOI: 10.1002/Ejoc.200500769  0.501
2006 Krasovskiy A, Tishkov A, del Amo V, Mayr H, Knochel P. Übergangsmetall-freie Homokupplungen von Organomagnesiumverbindungen Angewandte Chemie. 118: 5132-5136. DOI: 10.1002/Ange.200600772  0.312
2005 Tishkov AA, Schmidhammer U, Roth S, Riedle E, Mayr H. Ambident reactivity of the nitrite ion revisited. Angewandte Chemie (International Ed. in English). 44: 4623-6. PMID 16003794 DOI: 10.1002/Anie.200501274  0.372
2005 Xu S, Held I, Kempf B, Mayr H, Steglich W, Zipse H. The DMAP-catalyzed acetylation of alcohols--a mechanistic study (DMAP = 4-(dimethylamino)pyridine). Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 4751-7. PMID 15924289 DOI: 10.1002/Chem.200500398  0.456
2005 Minegishi S, Loos R, Kobayashi S, Mayr H. Kinetics of the reactions of halide anions with carbocations: quantitative energy profiles for s(n)1 reactions. Journal of the American Chemical Society. 127: 2641-9. PMID 15725021 DOI: 10.1021/Ja045562N  0.52
2005 Tishkov AA, Mayr H. Ambident reactivity of the cyanide ion: a failure of the HSAB principle. Angewandte Chemie (International Ed. in English). 44: 142-5. PMID 15599920 DOI: 10.1002/Anie.200461640  0.304
2005 Mayr H, Ofial AR. Kinetics of electrophile-nucleophile combinations: A general approach to polar organic reactivity Pure and Applied Chemistry. 77: 1807-1821. DOI: 10.1351/Pac200577111807  0.454
2005 Phan TB, Mayr H. Comparison of the nucleophilicities of alcohols and alkoxides Canadian Journal of Chemistry. 83: 1554-1560. DOI: 10.1139/V05-170  0.334
2005 Mayr H, Ofial AR, Schimmel H. Propagation Rate of the Cationic Polymerization of 2,4,6-Trimethylstyrene:  A Linear Free Energy Approach Macromolecules. 38: 33-40. DOI: 10.1021/Ma048389O  0.502
2005 Dulich F, Müller K, Ofial A, Mayr H. Quantification of theβ-Stabilizing Effect of the Dicarbonyl(η5-cyclopentadienyl)iron Group Helvetica Chimica Acta. 88: 1754-1768. DOI: 10.1002/Hlca.200590137  0.382
2005 Dilman AD, Mayr H. Nucleophilic Reactivities of Silyl Ketene Acetals and Silyl Enol Ethers Containing (C6F5)3SiO and (C6H5)3SiO Groups European Journal of Organic Chemistry. 2005: 1760-1764. DOI: 10.1002/Ejoc.200400706  0.437
2004 Bug T, Lemek T, Mayr H. Nucleophilicities of nitroalkyl anions. The Journal of Organic Chemistry. 69: 7565-76. PMID 15497983 DOI: 10.1021/Jo048773J  0.52
2004 Denegri B, Minegishi S, Kronja O, Mayr H. S(N)1 reactions with inverse rate profiles. Angewandte Chemie (International Ed. in English). 43: 2302-5. PMID 15108152 DOI: 10.1002/Anie.200353468  0.357
2004 Minegishi S, Kobayashi S, Mayr H. Solvent nucleophilicity. Journal of the American Chemical Society. 126: 5174-81. PMID 15099100 DOI: 10.1021/ja031828z  0.365
2004 Loos R, Kobayashi S, Mayr H. Ambident reactivity of the thiocyanate anion revisited: can the product ratio be explained by the hard soft acid base principle? Journal of the American Chemical Society. 125: 14126-32. PMID 14611250 DOI: 10.1021/Ja037317U  0.469
2004 Bug T, Hartnagel M, Schlierf C, Mayr H. How nucleophilic are diazo compounds? Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 4068-76. PMID 12953192 DOI: 10.1002/Chem.200304913  0.49
2004 Ofial AR, Ohkubo K, Fukuzumi S, Lucius R, Mayr H. Role of electron-transfer processes in reactions of diarylcarbenium ions and related quinone methides with nucleophiles. Journal of the American Chemical Society. 125: 10906-12. PMID 12952471 DOI: 10.1021/Ja035191V  0.803
2004 Lemek T, Mayr H. Electrophilicity parameters for benzylidenemalononitriles. The Journal of Organic Chemistry. 68: 6880-6. PMID 12946126 DOI: 10.1021/Jo0344182  0.437
2004 Lemek T, Makosza M, Stephenson DS, Mayr H. Direct observation of the intermediate in vicarious nucleophilic substitutions of hydrogen. Angewandte Chemie (International Ed. in English). 42: 2793-5. PMID 12820270 DOI: 10.1002/Anie.200351352  0.32
2004 Rehn S, Ofial AR, Polborn K, Mayr H. Stereoselective synthesis of cis-fused hexahydro-isoindolones Arkivoc. 2004. DOI: 10.3998/Ark.5550190.0005.312  0.409
2004 Rehn S, Ofial AR, Mayr H. Synthesis of Allylamines from Alkynes and Iminium Ions. Cheminform. 35. DOI: 10.1055/S-2003-41028  0.348
2004 De P, Faust R, Schimmel H, Ofial AR, Mayr H. Determination of Rate Constants in the Carbocationic Polymerization of Styrene:  Effect of Temperature, Solvent Polarity, and Lewis Acid1 Macromolecules. 37: 4422-4433. DOI: 10.1021/Ma0498262  0.388
2004 Ofial AR, Mayr H. Reactivities of Carbocations and Carbanions Macromolecular Symposia. 215: 353-368. DOI: 10.1002/Masy.200451127  0.405
2004 Tokuyasu T, Mayr H. Nucleophilic Reactivities of Ketene Acetals European Journal of Organic Chemistry. 2004: 2791-2796. DOI: 10.1002/Ejoc.200400134  0.508
2004 Tishkov AA, Mayr H. Die ambidente Reaktivität des Cyanid-Ions: ein Versagen des HSAB-Prinzips Angewandte Chemie. 117: 145-148. DOI: 10.1002/Ange.200461640  0.303
2003 Bug T, Mayr H. Nucleophilic reactivities of carbanions in water: the unique behavior of the malodinitrile anion. Journal of the American Chemical Society. 125: 12980-6. PMID 14558847 DOI: 10.1021/Ja036838E  0.514
2003 Kempf B, Hampel N, Ofial AR, Mayr H. Structure-nucleophilicity relationships for enamines. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 2209-18. PMID 12772295 DOI: 10.1002/Chem.200204666  0.836
2003 Mayr H, Kempf B, Ofial AR. Pi-nucleophilicity in carbon-carbon bond-forming reactions. Accounts of Chemical Research. 36: 66-77. PMID 12534306 DOI: 10.1021/Ar020094C  0.823
2003 Minegishi S, Mayr H. How constant are Ritchie's "constant selectivity relationships"? A general reactivity scale for n-, pi-, and sigma-nucleophiles. Journal of the American Chemical Society. 125: 286-95. PMID 12515531 DOI: 10.1021/Ja021010Y  0.505
2003 Mayr H, Minegishi S. First direct observation of the two distinct steps in an S(N)1 reaction. Angewandte Chemie (International Ed. in English). 41: 4493-5. PMID 12458516 DOI: 10.1002/1521-3773(20021202)41:23<4493::Aid-Anie4493>3.0.Co;2-U  0.426
2003 Remennikov GY, Kempf B, Ofial AR, Polborn K, Mayr H. 5-Methoxyfuroxano[3,4-d]pyrimidine: a highly reactive neutral electrophile Journal of Physical Organic Chemistry. 16: 431-437. DOI: 10.1002/Poc.606  0.458
2003 Kempf B, Hampel N, Ofial AR, Mayr H. Cover Picture: Structure–Nucleophilicity Relationships for Enamines (Chem. Eur. J. 10/2003) Chemistry - a European Journal. 9: 2133-2133. DOI: 10.1002/Chem.200390220  0.422
2002 Schindele C, Houk KN, Mayr H. Relationships between carbocation stabilities and electrophilic reactivity parameters, E: quantum mechanical studies of benzhydryl cation structures and stabilities. Journal of the American Chemical Society. 124: 11208-14. PMID 12224969 DOI: 10.1021/Ja020617B  0.399
2002 Würthwein EU, Lang G, Schappele LH, Mayr H. Rate-equilibrium relationships in hydride transfer reactions: the role of intrinsic barriers. Journal of the American Chemical Society. 124: 4084-92. PMID 11942847 DOI: 10.1021/Ja0121540  0.361
2002 Mayr H, Lang G, Ofial AR. Reactions of carbocations with unsaturated hydrocarbons: electrophilic alkylation or hydride abstraction? Journal of the American Chemical Society. 124: 4076-83. PMID 11942846 DOI: 10.1021/Ja0121538  0.839
2002 Mayr H, Bug T, Gotta MF, Hering N, Irrgang B, Janker B, Kempf B, Loos R, Ofial AR, Remennikov G, Schimmel H. Reference scales for the characterization of cationic electrophiles and neutral nucleophiles. Journal of the American Chemical Society. 123: 9500-12. PMID 11572670 DOI: 10.1021/Ja010890Y  0.502
2002 Fichtner C, Mayr H. Diels–Alder reactions of 1,1,3-triarylallyl cations: determination of the free energy of concert Journal of the Chemical Society-Perkin Transactions 1. 1441-1444. DOI: 10.1039/B203555C  0.473
2002 Mayr H, Fichtner C, Ofial AR. Determination of the electrophilic reactivities of 1,1,3-triarylallyl cations Journal of the Chemical Society-Perkin Transactions 1. 1435-1440. DOI: 10.1039/B203554E  0.351
2002 Schimmel H, Ofial AR, Mayr H. Initiation and Propagation Rate Constants for the Cationic Polymerization ofN-Vinylcarbazole Macromolecules. 35: 5454-5458. DOI: 10.1021/Ma020306L  0.496
2002 Mayr H, Schimmel H, Kobayashi S, Kotani M, Prabakaran TR, Sipos L, Faust R. Influence of Chain Length on the Electrophilic Reactivity of Carbocations Macromolecules. 35: 4611-4615. DOI: 10.1021/Ma0120299  0.383
2001 Herrlich M, Mayr H, Faust R. Nucleophilic reactivities of tributylstannyl-substituted furans and thiophenes. Organic Letters. 3: 1633-5. PMID 11405673 DOI: 10.1021/Ol0158112  0.408
2001 Herrlich M, Hampel N, Mayr H. Electrophilic Aromatic Substitutions of Silylated Furans and Thiophenes with Retention of the Organosilyl Group Organic Letters. 3: 1629-1632. PMID 11405672 DOI: 10.1021/Ol015810+  0.344
2001 Dilman AD, Ioffe SL, Mayr H. Determination of the nucleophilicities of N,N-bis(silyloxy)enamines. The Journal of Organic Chemistry. 66: 3196-200. PMID 11325288 DOI: 10.1021/Jo0015927  0.327
2001 Fichtner C, Remennikov G, Mayr H. Kinetics of the Reactions of Flavylium Ions with π-Nucleophiles European Journal of Organic Chemistry. 2001: 4451-4456. DOI: 10.1002/1099-0690(200112)2001:23<4451::Aid-Ejoc4451>3.0.Co;2-F  0.442
2000 Lucius R, Mayr H. Constant Selectivity Relationships of Addition Reactions of Carbanions Angewandte Chemie. 39: 1995-1997. PMID 10941008 DOI: 10.1002/1521-3773(20000602)39:11<1995::Aid-Anie1995>3.0.Co;2-E  0.41
2000 Henninger J, Polborn K, Mayr H. A novel heterobicyclic framework by successive ene reactions Journal of Organic Chemistry. 65: 3569-3570. PMID 10843652 DOI: 10.1021/Jo000079Q  0.394
2000 Schlaad H, Kwon Y, Faust R, Mayr H. Kinetic study on the capping reaction of living polyisobutylene with 1, 1-diarylethylenes. 2. effect of chain length Macromolecules. 33: 754-759. DOI: 10.1021/Ma991555L  0.422
2000 Mayr H, Kuhn O, Schlierf C, Ofial AR. Reactions of Carbon Electrophiles with Cobalt-Coordinated Enynes: Scope and Limitations Tetrahedron. 56: 4219-4229. DOI: 10.1016/S0040-4020(00)00347-1  0.496
2000 Mayr H, Ofial A, Sauer J, Schmied B. [2++4] Cycloadditions of Iminium Ions − Concerted or Stepwise Mechanism of Aza Diels−Alder Reactions? European Journal of Organic Chemistry. 2000: 2013-2020. DOI: 10.1002/1099-0690(200006)2000:11<2013::Aid-Ejoc2013>3.0.Co;2-A  0.507
1999 Kuhn O, Mayr H. Kinetics and Mechanisms of the Reactions of π-Allylpalladium Complexes with Nucleophiles. Angewandte Chemie (International Ed. in English). 38: 343-346. PMID 29711646 DOI: 10.1002/(Sici)1521-3773(19990201)38:3<343::Aid-Anie343>3.0.Co;2-X  0.385
1999 Mayr H, Müller K. Determination of the Nucleophilicity of Tricarbonyliron Coordinated Cyclohepta-1,3,5-triene Collection of Czechoslovak Chemical Communications. 64: 1770-1779. DOI: 10.1135/Cccc19991770  0.441
1999 Nonami Y, Baran J, Sosnicki J, Mayr H, Masuyama aA, Nojima M. Reaction of Highly Methylated 2-Methylenecycloalkyl Hydroperoxides with FeSO4/CuCl2. Remarkably Efficient 5-endo-trig or 6-endo-trig Cyclization of the Intermediate Carbon Radicals Journal of Organic Chemistry. 64: 4060-4063. DOI: 10.1021/Jo990127A  0.395
1999 Mayr H, Müller K, Ofial AR, Bühl M. Comparison of the Electrophilicities of the Free and the (Tricarbonyl)iron-Coordinated Tropylium Ion Journal of the American Chemical Society. 121: 2418-2424. DOI: 10.1021/Ja982072K  0.423
1998 Mayr H, Patz M, Gotta MF, Ofial AR. Reactivities and selectivities of free and metal-coordinated carbocations Pure and Applied Chemistry. 70: 1993-2000. DOI: 10.1351/Pac199870101993  0.44
1998 Schlaad H, Erentova K, Faust R, Charleux B, Moreau M, Vairon JP, Mayr H. Kinetic study on the capping reaction of living polyisobutylene with 1,1-diphenylethylene. 1. effect of temperature and comparison to the model compound 2-chloro-2,4,4-trimethylpentane Macromolecules. 31: 8058-8062. DOI: 10.1021/Ma9809738  0.443
1998 and MFG, Mayr H. Kinetics of the Friedel−Crafts Alkylations of Heterocyclic Arenes: Comparison of the Nucleophilic Reactivities of Aromatic and Nonaromatic π-Systems Journal of Organic Chemistry. 63: 9769-9775. DOI: 10.1021/Jo981373+  0.5
1998 Burfeindt J, Patz M, Müller M, Mayr H. Determination of the Nucleophilicities of Silyl and Alkyl Enol Ethers Journal of the American Chemical Society. 120: 3629-3634. DOI: 10.1021/Ja974003W  0.479
1998 Kuhn O, Rau D, Mayr H. How Electrophilic Are Cobalt Carbonyl Stabilized Propargylium Ions? Journal of the American Chemical Society. 120: 900-907. DOI: 10.1021/Ja9726264  0.492
1998 Mayr H, Roth M. Alkyl chloride-boron trichloride initiated polymerizations of isobutylene: Detailed analysis of the initial propagation steps Macromolecular Symposia. 132: 103-116. DOI: 10.1002/Masy.19981320112  0.311
1998 Mayr H, Kuhn O, Gotta MF, Patz M. Linear free enthalpy relationships: a powerful tool for the design of organic and organometallic synthesis Journal of Physical Organic Chemistry. 11: 642-654. DOI: 10.1002/(Sici)1099-1395(199808/09)11:8/9<642::Aid-Poc65>3.0.Co;2-2  0.513
1998 Mayr H, Henninger J. Kinetics of the [2+ + 4]-Cycloaddition Reactions of 1,3-Dithian-2-ylium Ions with 1,3-Dienes European Journal of Organic Chemistry. 1998: 1919-1922. DOI: 10.1002/(Sici)1099-0690(199809)1998:9<1919::Aid-Ejoc1919>3.0.Co;2-E  0.509
1997 Mayr H, Roth M, Deters M. Living Oligomerization of Isobutylene Initiated by Cumyl Chloride/BCl3Mixtures:  Kinetic Analysis of the Initiation and the Early Propagation Steps Macromolecules. 30: 3965-3970. DOI: 10.1021/Ma961852F  0.317
1997 Roth M, Patz M, Freter H, Mayr H. Living Oligomerization of Isobutylene Using Di- and Triisobutylene Hydrochlorides as Initiators Macromolecules. 30: 722-725. DOI: 10.1021/Ma9614151  0.338
1997 Mayr H, Ofial AR, Würthwein E, Aust NC. NMR Spectroscopic Evidence for the Structure of Iminium Ion Pairs Journal of the American Chemical Society. 119: 12727-12733. DOI: 10.1021/Ja972860U  0.38
1997 Mayr H, Ofial AR. Electrophilicities of iminium ions Tetrahedron Letters. 38: 3503-3506. DOI: 10.1016/S0040-4039(97)00675-8  0.395
1997 Mayr H, Dogan B. Selectivities in ionic reductions of alcohols and ketones with triethylsilane/trifluoroacetic acid Tetrahedron Letters. 38: 1013-1016. DOI: 10.1016/S0040-4039(96)02484-7  0.325
1997 Ofial AR, Mayr H. A Novel Pentaannulation Reaction of Iminium Ions Liebigs Annalen. 1997: 333-335. DOI: 10.1002/Jlac.199719970210  0.396
1997 Hartnagel M, Grimm K, Mayr H. Addition and Cycloaddition Reactions of Arenediazonium Ions with 1,3-Dienes: A Shift From a Concerted to a Stepwise Mechanism Liebigs Annalen. 1997: 71-80. DOI: 10.1002/Jlac.199719970112  0.496
1997 Mayr H, Hartnagel M, Grimm K. Quantification of the Electrophilicities of Diazonium Ions Liebigs Annalen. 1997: 55-69. DOI: 10.1002/Jlac.199719970111  0.515
1997 Funke MA, Mayr H. Kinetics and Mechanism of the Reactions of Amine Boranes with Carbenium Ions Chemistry - a European Journal. 3: 1214-1222. DOI: 10.1002/Chem.19970030808  0.517
1997 Ofial AR, Mayr H. Ene Reactions of Alkynes for the Stereoselective Synthesis of Allylamines Angewandte Chemie International Edition in English. 36: 143-145. DOI: 10.1002/Anie.199701431  0.405
1996 Mayr H, Henninger J, Siegmund T. Quantification of the electrophilicities of dithiocarbenium ions Research On Chemical Intermediates. 22: 821-838. DOI: 10.1163/156856796X00502  0.422
1996 Roth M, Mayr H. A Novel Method for the Determination of Propagation Rate Constants:  Carbocationic Oligomerization of Isobutylene† Macromolecules. 29: 6104-6109. DOI: 10.1021/Ma960236G  0.377
1996 Ofial AR, Mayr H. Reactions Of Allylsilanes With Iminium Salts : Ene Reactions With Inverse Electron Demand Journal of Organic Chemistry. 61: 5823-5830. DOI: 10.1021/Jo960516U  0.447
1996 Yamakoshi H, Kawamura S, Nojima M, Mayr H, Baran J. Ozonolysis Of Highly Methylated 1,2-Bis(Methylene)Cycloalkanes. Influence Of The Methyl Substituents On The Course Of The Reaction Journal of Organic Chemistry. 61: 5939-5943. DOI: 10.1021/Jo960397I  0.332
1996 Mayr H, Patz M. Modelling carbocationic polymerizations: Kinetics of the reactions of carbocations with alkenes Macromolecular Symposia. 107: 99-110. DOI: 10.1002/Masy.19961070111  0.505
1996 Mayr H, Hartnagel M. Comparison of the One-Bond Nucleophilicities of Monomethyl- and Dimethyl-Substituted 1,3-Butadienes Liebigs Annalen. 1996: 2015-2018. DOI: 10.1002/Jlac.199619961211  0.467
1995 Mayr H, Gorath G. Kinetics of the Reactions of Carboxonium Ions and Aldehyde Boron Trihalide Complexes with Alkenes and Allylsilanes Journal of the American Chemical Society. 117: 7862-7868. DOI: 10.1021/Ja00135A002  0.441
1995 Henninger J, Mayr H, Patz M, Stanescu MD. Electrophilic reactions of the dibenzo[a,d]tropylium ion Liebigs Annalen. 1995: 2005-2009. DOI: 10.1002/Jlac.1995199511281  0.468
1995 Mayr H, Gabriel AO, Schumacher R. Synthesis of β,γ-unsaturated phenyl esters by aluminium chloride initiated reactions of allylsilanes with aryl chloroformates Liebigs Annalen. 1995: 1583-1586. DOI: 10.1002/Jlac.1995199509220  0.41
1995 Patz M, Mayr H, Maruta J, Fukuzumi S. Reactions of Carbocations withπ Nucleophiles: Polar Mechanism and No Outer Sphere Electron Transfer Angewandte Chemie International Edition in English. 34: 1225-1227. DOI: 10.1002/Anie.199512251  0.336
1995 Patz M, Mayr H, Bartl J, Steenken S. Common Origin of Enthalpic and Entropic Substituent Effects in Reactions of Benzhydryl Cations with Nucleophiles Angewandte Chemie International Edition in English. 34: 490-492. DOI: 10.1002/Anie.199504901  0.448
1994 Mayr H, Baran J, Will E, Yamakoshi H, Teshima K, Nojima M. Exceptionally Stable Ozonides. Influence of Methyl Substituents on the Course of Cyclopentene Ozonolyses and on the Reactivities of Ozonides The Journal of Organic Chemistry. 59: 5055-5058. DOI: 10.1021/Jo00096A059  0.306
1994 Roth M, Schade C, Mayr H. Kinetics of carbenium ion additions to methylenecycloalkanes: cycloalkyl cation stabilities are not predominantly controlled by strain The Journal of Organic Chemistry. 59: 169-172. DOI: 10.1021/Jo00080A027  0.403
1994 Mayr H, Rau D. How Electrophilic are Ferrocenylmethyl Cations? Kinetics of their Reactions with π Nucleophiles and Hydride Donors Chemische Berichte. 127: 2493-2498. DOI: 10.1002/Cber.19941271221  0.44
1994 Mayr H, Gonzalez JL, Lüdtke K. Comparison of the Nucleophilicities of Alkynes and Alkenes. Quantitative Determination of the Nucleophilicities of Alkynes toward Carbenium Ions Chemische Berichte. 127: 525-531. DOI: 10.1002/Cber.19941270311  0.455
1994 Mayr H, Dau-Schmidt J. Relative reactivities of acetals and ethers under Friedel-Crafts conditions Chemische Berichte. 127: 213-217. DOI: 10.1002/Cber.19941270130  0.32
1994 Dau-Schmidt J, Mayr H. Relative Reactivities of Alkyl Chlorides under Friedel‐Crafts Conditions Chemische Berichte. 127: 205-212. DOI: 10.1002/Cber.19941270129  0.437
1994 Mayr H, Patz M. Scales of Nucleophilicity and Electrophilicity: A System for Ordering Polar Organic and Organometallic Reactions Angewandte Chemie International Edition in English. 33: 938-957. DOI: 10.1002/Anie.199409381  0.477
1993 Basso N, Goers S, Popowski E, Mayr H. Hyperconjugative stabilization of silicenium ions: kinetics of hydride abstractions from .beta.-element-substituted silanes Journal of the American Chemical Society. 115: 6025-6028. DOI: 10.1021/Ja00067A018  0.385
1993 Patz M, Mayr H. How nucleophilic are silyl enol ethers? Kinetics of the reactions of electron rich CC-double bonded systems with carbenium ions Tetrahedron Letters. 34: 3393-3396. DOI: 10.1016/S0040-4039(00)79164-7  0.439
1993 Mayr H, Heigl UW, Baran J. A Stepwise [4 + 3] Cycloaddition Reaction of the 1,3-Diphenyl-2-azaallyl Anion Chemische Berichte. 126: 1913-1916. DOI: 10.1002/Cber.19931260823  0.445
1993 Mayr H, Müller K, Rau D. Comparison of the Electrophilicities of Cationic Metalπ Complexes and of Ordinary Carbenium Ions Angewandte Chemie International Edition in English. 32: 1630-1632. DOI: 10.1002/Anie.199316301  0.335
1992 Bentley TW, Dau-Schmidt JP, Llewellyn G, Mayr H. Solvation effects adjacent to the reaction site. Differences in solvation between alkyl, alkenyl or alkynyl, and aryl groups in binary aqueous mixtures The Journal of Organic Chemistry. 57: 2387-2392. DOI: 10.1021/Jo00034A035  0.379
1992 Mayr H, Grimm K. Synthesis of allylazo compounds by reactions of aryldiazonium salts with allylsilanes Journal of Organic Chemistry. 57: 1057-1059. DOI: 10.1021/Jo00030A001  0.371
1992 Mayr H, Baeuml E, Cibura G, Koschinsky R. Synthesis of cyclopentenes via [3 + 2]-cycloadditions of silylated propargyl .tautm. allenyl cations with alkenes Journal of Organic Chemistry. 57: 768-772. DOI: 10.1021/Jo00028A073  0.355
1992 Mayr H, Basso N, Hagen G. Kinetics of hydride transfer reactions from hydrosilanes to carbenium ions. Substituent effects in silicenium ions Journal of the American Chemical Society. 114: 3060-3066. DOI: 10.1021/Ja00034A044  0.428
1992 Mayr H, Bartl J, Hagen G. Rate Constants for the Attack of Carbenium Ions at Arenes—A Link between the Chemistry of Aliphatic and Aromaticπ Systems Angewandte Chemie International Edition in English. 31: 1613-1615. DOI: 10.1002/Anie.199216131  0.359
1992 Mayr H, Basso N. Kinetics of Hydride Transfers from CH, SiH, GeH, and SnH Groups to Carbenium Ions Angewandte Chemie International Edition in English. 31: 1046-1048. DOI: 10.1002/Anie.199210461  0.32
1991 Bartl J, Steenken S, Mayr H. Kinetics of the reactions of laser-flash photolytically generated carbenium ions with alkyl and silyl enol ethers. Comparison with the reactivity toward alkenes, allylsilanes and alcohols Journal of the American Chemical Society. 113: 7710-7716. DOI: 10.1021/Ja00020A038  0.448
1991 Hagen G, Mayr H. Kinetics of the reactions of allylsilanes, allylgermanes, and allylstannanes with carbenium ions Journal of the American Chemical Society. 113: 4954-4961. DOI: 10.1021/Ja00013A035  0.488
1991 Irrgang B, Mayr H. Additions of carbenium ions to nonconjugated dienes. The retarding (−I)-effect of the second double bond. Tetrahedron. 47: 219-228. DOI: 10.1016/S0040-4020(01)80918-2  0.342
1991 Ohm S, Bäuml E, Mayr H. A Versatile Synthesis of 1,4-Dienes: Use of Vinyl Ethers as Vinyl Cation Equivalents Chemische Berichte. 124: 2785-2790. DOI: 10.1002/Cber.19911241222  0.32
1991 Mayr H, Heilmann W, Bäuml E, Vorbrüggen H. Synthesis of 2,2,5,5-Tetramethylcyclopentanecarboxylic Acid – A Building Block of an Amino Acid Based Sweetener Chemische Berichte. 124: 203-206. DOI: 10.1002/Cber.19911240130  0.358
1990 Bartl J, Steenken S, Mayr H, McClelland RA. Photo-heterolysis and -homolysis of substituted diphenylmethyl halides, acetates, and phenyl ethers in acetonitrile : characterization of diphenylmethyl cations and radicals generated by 248-nm laser flash photolysis Journal of the American Chemical Society. 112: 6918-6928. DOI: 10.1021/Ja00175A028  0.397
1990 Mayr H, Schneider R, Grabis U. Linear free energy and reactivity-selectivity relationships in reactions of diarylcarbenium ions with .pi.-nucleophiles Journal of the American Chemical Society. 112: 4460-4467. DOI: 10.1021/Ja00167A051  0.414
1990 Mayr H, Schneider R, Irrgang B, Schade C. Kinetics of the reactions of the p-methoxy-substituted benzhydryl cation with various alkenes and 1,3-dienes Journal of the American Chemical Society. 112: 4454-4459. DOI: 10.1021/Ja00167A050  0.434
1990 Mayr H, Schneider R, Schade C, Bartl J, Bederke R. Addition reactions of diarylcarbenium ions to 2-methyl-1-pentene: kinetic method and reaction mechanism Journal of the American Chemical Society. 112: 4446-4454. DOI: 10.1021/Ja00167A049  0.442
1990 Musigmann K, Mayr H, Meijere Ad. Regio- and stereoselective ring-opening reactions of cyclopropenones: α-methylene-γ-butyrolactones via additions of trichlorocyclopropenylium ions to alkenes Tetrahedron Letters. 31: 1261-1264. DOI: 10.1016/S0040-4039(00)88780-8  0.432
1990 Mayr H. CC Bond Formation by Addition of Carbenium Ions to Alkenes: Kinetics and Mechanism Angewandte Chemie International Edition in English. 29: 1371-1384. DOI: 10.1002/Anie.199013713  0.491
1989 Cambanis A, Bäuml E, Mayr H. Formylation of Allylsilanes: A Synthesis of β,γ-Unsaturated Aldehyde Acetals Synthesis. 1989: 128-129. DOI: 10.1055/S-1989-27171  0.305
1989 Mayr H, Hagen G. Quantitative determination of the nucleophilicity of allylsilanes Journal of the Chemical Society, Chemical Communications. 91-92. DOI: 10.1039/C39890000091  0.403
1989 Baran J, Mayr H, Ruster V, Klaerner FG. Stepwise [4 + 2]- and [4 + 4]-cyclodimerizations of 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane The Journal of Organic Chemistry. 54: 5016-5019. DOI: 10.1021/Jo00282A013  0.303
1989 Mayr H, Koschinsky R. Stereoselective circumambulatory methyl migrations in the nonamethylcyclopentylium ion Journal of the American Chemical Society. 111: 2305-2306. DOI: 10.1021/Ja00188A056  0.329
1989 Baran J, Mayr H. Acceleration of diels-alder reactions by remote methyl groups Tetrahedron. 45: 3347-3350. DOI: 10.1016/S0040-4020(01)81013-9  0.359
1988 Mayr H, Cambanis A, Bäuml E. Synthesis of β,γ-Unsaturated Carboxylic Acid Esters via Aryloxycarbonylation of Allylsilanes Synthesis. 1988: 962-963. DOI: 10.1055/S-1988-27766  0.35
1988 Cambanis A, Bäuml E, Mayr H. Synthesis of Bis(aryloxy)chloromethanes via Radical-Induced Chlorinations of Formaldehyde Diaryl Acetals Synthesis. 1988: 961-961. DOI: 10.1055/S-1988-27765  0.324
1988 Bentley TW, Irrgang B, Mayr H, Schleyer PvR. Inductive effects in neighboring-group participation. Destabilization of carbocations by CC double bonds in solvolyses of 2,2,5,5-tetramethylcyclopent-3-en-1-yl tosylates Journal of Organic Chemistry. 53: 3492-3498. DOI: 10.1021/Jo00250A015  0.375
1988 Von der Brueggen U, Lammers R, Mayr H. Relative reactivities of acetals and orthoesters in Lewis acid catalyzed reactions with vinyl ethers. A systematic investigation of the synthetic potential of acetals and orthoesters in electrophilic alkoxyalkylations of enol ethers The Journal of Organic Chemistry. 53: 2920-2925. DOI: 10.1021/Jo00248A006  0.42
1988 Bäuml E, Tscheschlok K, Pock R, Mayr H. Synthesis of γ-lactones from alkenes employing p-methoxybenzyl chloride as +CH2CO−2 equivalent Tetrahedron Letters. 29: 6925-6926. DOI: 10.1016/S0040-4039(00)88476-2  0.372
1988 Koschinsky R, Köhli T, Mayr H. Synthesis of highly alkylated functionalized cyclopentadienes Tetrahedron Letters. 29: 5641-5644. DOI: 10.1016/S0040-4039(00)80833-3  0.332
1988 Heilmann W, Azizur-Rahman, Ba¨uml E, Mayr H. Carbocationic cyclisations and rearrangements in the damascone series Tetrahedron. 44: 6047-6054. DOI: 10.1016/S0040-4020(01)89793-3  0.341
1988 Baran J, Klein H, Schade C, Will E, Koschinsky R, Bäuml E, Mayr H. Synthesis of 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane Tetrahedron. 44: 2181-2184. DOI: 10.1016/S0040-4020(01)81725-7  0.345
1988 Schade C, Mayr H. Solvolyses of diarylmethyl chlorides. A comprehensive stability scale for diarylcarbenium ions. Tetrahedron. 44: 5761-5770. DOI: 10.1016/S0040-4020(01)81435-6  0.407
1988 Mayr H, Schneider R, Schade C. Kinetic and Thermodynamic Studies of Carbenium Ion Additions Towards Alkenes Macromolecular Symposia. 13: 43-59. DOI: 10.1002/Masy.19880130106  0.44
1988 Mayr H, Von Der Brüggen U. Electrophilic carboxylation of alkenes Chemische Berichte. 121: 339-345. DOI: 10.1002/Cber.19881210221  0.379
1988 Brüggen Uvd, Mayr H. Comment of the use of dichloromethyl methyl ether as formylating agent Chemische Berichte. 121: 191-193. DOI: 10.1002/Cber.19881210127  0.364
1987 Mayr H, Heigl UW. [4 + 2] Cycloadditions of diphenylketene with a highly substituted 1,3-diene Journal of the Chemical Society, Chemical Communications. 1804-1805. DOI: 10.1039/C39870001804  0.313
1987 Heilmann W, Koschinsky R, Mayr H. The [3 + 2]- and [5 + 2]-cycloadditions of the cyclohepta-2,4-dienyl cation The Journal of Organic Chemistry. 52: 1989-1993. DOI: 10.1021/Jo00386A017  0.364
1987 Mayr H, Koschinsky R, Will E, Bauml E. Acid- and base-catalyzed ring-opening reactions or a sterically hindered epoxide The Journal of Organic Chemistry. 52: 1342-1344. DOI: 10.1021/Jo00383A033  0.398
1987 Baran J, Mayr H. First [4 + 3]-cycloaddition of a 1,3-dipole with a 1,3-diene Journal of the American Chemical Society. 109: 6519-6521. DOI: 10.1021/Ja00255A052  0.336
1987 Musigmann K, Mayr H, de Meijere A. Addition reactions of the trichlorocyclopropenylium ion with alkenes: A novel access to cyclopropene and cyclopropenone derivatives Tetrahedron Letters. 28: 4517-4520. DOI: 10.1016/S0040-4039(00)96552-3  0.421
1987 Bäuml E, Kolberg G, Mayr H. A carbocationic 1,3-alkenyl shift Tetrahedron Letters. 28: 387-390. DOI: 10.1016/S0040-4039(00)95735-6  0.338
1987 Azizur-Rahman, Bäuml E, Klein H, Mayr H. Prenyaticn of camphene - a carbocationic route to isosantalene and its derivatives Tetrahedron. 43: 4119-4124. DOI: 10.1016/S0040-4020(01)83451-7  0.368
1987 Mayr H, Schade C, Rubow M, Schneider R. Steuerung der relativen Elektrophilie von Alkylierungsmitteln durch Variation der Lewis-Säure-Konzentration Angewandte Chemie. 99: 1059-1060. DOI: 10.1002/Ange.19870991022  0.349
1986 Mayr H, Schneider R, Pock R. Addition Reactions of Carbocations with Alkenes Macromolecular Symposia. DOI: 10.5282/Ubm/Epub.3920  0.411
1986 Mayr H, Hellmann W, Lammers R. A carbocationic route to 3-substituted 1,4-cycloheptadienes Tetrahedron. 42: 6663-6668. DOI: 10.1016/S0040-4020(01)82105-0  0.437
1986 Mayr H, Heilmann W. Steric control of regiochemistry in the reactions of methyl substituted pentadienyl cations with isobutene Tetrahedron. 42: 6657-6662. DOI: 10.1016/S0040-4020(01)82104-9  0.388
1986 Mayr H, Will E, Heigl UW, Schade C. Bromination of octmethylcyclopentene - the irregular reactivity of a sterically hindered cycloalkene Tetrahedron. 42: 2519-2522. DOI: 10.1016/0040-4020(86)80016-3  0.323
1986 Mayr H, Pock R, Schneider R. Addition reactions of carbocations with alkenes: Studies on the mechanism of carbocationic polymerization Makromolekulare Chemie. Macromolecular Symposia. 3: 19-31. DOI: 10.1002/Masy.19860030104  0.326
1986 POCK R, KLEIN H, MAYR H. ChemInform Abstract: Electrophilic Alkylations of Norbornene. Syntheses of 7-Substituted Norbornenes. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198627160  0.377
1986 SCHNEIDER R, GRABIS U, MAYR H. ChemInform Abstract: Direct Determination of Rates of Addition of Carbenium Ions to Alkenes. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198618134  0.377
1986 Pock R, Mayr H. Relative Reaktivität konjugierter Alkene gegenüber Diarylcarbenium-Ionen Chemische Berichte. 119: 2497-2509. DOI: 10.1002/Cber.19861190809  0.304
1986 Mayr H, Schneider R, Grabis U. Linear Reactivity-Selectivity Correlations in Additions of Diarylcarbenium Ions to Alkenes; a Rebuttal of the Reactivity-Selectivity Principle Angewandte Chemie International Edition in English. 25: 1017-1018. DOI: 10.1002/Anie.198610171  0.326
1986 Schneider R, Mayr H. Direct Measurement of the ?Isokinetic Rate Constant? in Additions of Diarylcarbenium Ions to 2-Methyl-2-butene Angewandte Chemie International Edition in English. 25: 1016-1017. DOI: 10.1002/Anie.198610161  0.366
1986 Schneider R, Grabis U, Mayr H. Direct Determination of Rate Constants for the Addition of Carbenium Ions to Alkenes Angewandte Chemie International Edition in English. 25: 89-90. DOI: 10.1002/Anie.198600892  0.382
1986 Schneider R, Grabis U, Mayr H. Direkte Bestimmung der Additionsgeschwindigkeiten von Carbenium-Ionen an Alkene Angewandte Chemie. 98: 94-95. DOI: 10.1002/Ange.19860980119  0.343
1985 Mayr H, Striepe W. Modification of the catalytic activity of zinc chloride. A kinetic investigation in zinc chloride-ether-dichloromethane mixtures The Journal of Organic Chemistry. 50: 2995-2998. DOI: 10.1002/Chin.198552183  0.323
1984 Mayr H, Bäuml E. [2+2]-cycloadditions of alkenes with the triphenylallenyl cation Tetrahedron Letters. 25: 1127-1130. DOI: 10.1016/S0040-4039(01)91540-0  0.451
1984 MAYR H, KLEIN H, KOLBERG G. ChemInform Abstract: LEWIS ACID CATALYZED ADDITIONS OF 1,3-ALKYL SUBSTITUTED ALLYL CHLORIDES TO ALKENES Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198446109  0.381
1984 MAYR H, KLEIN H, SIPPEL E. ChemInform Abstract: SYNTHESIS OF 1,2,3,3,6,6-HEXAMETHYL-1-CYCLOHEXENE - A CASCADE OF C12H23+ CARBENIUM ION REARRANGEMENTS Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198406117  0.324
1983 Mayr H, Pock R. Relative reactivities of alkenes toward the diphenylmethyl cation Tetrahedron Letters. 24: 2155-2158. DOI: 10.1016/S0040-4039(00)81869-9  0.357
1983 Mayr H, Bäuml E. Concerted [4+2] and stepwise [2+2]cycloadditions of the triphenylallenyl cation with cyclopentadiene Tetrahedron Letters. 24: 357-360. DOI: 10.1016/S0040-4039(00)81406-9  0.436
1983 Baeuml E, Mayr H. Diels-Alder reactions of 2-alkynoyl chlorides with cyclopentadiene: a reinvestigation The Journal of Organic Chemistry. 48: 2600-2601. DOI: 10.1002/Chin.198351091  0.409
1983 Mayr H, Striepe W. Scope and limitations of aliphatic Friedel-Crafts alkylations. Lewis acid catalyzed addition reactions of alkyl chlorides to carbon-carbon double bonds The Journal of Organic Chemistry. 48: 1159-1165. DOI: 10.1002/Chin.198337111  0.364
1983 KLEIN H, FREYBERGER G, MAYR H. ChemInform Abstract: (2+2) CYCLOADDITIONS OF ALLYL CATIONS Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198316140  0.373
1983 MAYR H, KLEIN H. ChemInform Abstract: ADDITION AND CYCLOADDITION REACTIONS OF ALLENYL CATIONS WITH ACYCLIC 1,3-DIENES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198304102  0.342
1983 Klein H, Freyberger G, Mayr H. [2+2]-Cycloadditions of Allyl Cations Angewandte Chemie International Edition in English. 22: 49-49. DOI: 10.1002/Anie.198300491  0.385
1982 Siehl HU, Mayr H. Stable vinyl cations. Direct spectroscopic observation of vinyl-substituted vinyl cations Journal of the American Chemical Society. 104: 909-910. DOI: 10.1002/Chin.198221118  0.383
1982 Klein H, Erbe A, Mayr H. Cationic Prenylation of Olefins Angewandte Chemie International Edition in English. 21: 82-82. DOI: 10.1002/Chin.198217133  0.357
1982 KLEIN H, MAYR H. ChemInform Abstract: (3 + 2)-CYCLOADDITIONS OF ALLYL CATIONS - SYNTHESIS OF PERMETHYLCYCLOPENTENE AND OTHER HIGHLY SUBSTITUTED CYCLOPENTENES Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198216168  0.372
1982 MAYR H, KLEIN H. ChemInform Abstract: ZINC CHLORIDE CATALYZED ADDITION REACTIONS OF PROPARGYL CHLORIDES WITH ACYCLIC 1,3-DIENES Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198210187  0.317
1982 Mayr H, Halberstadt-Kausch IK. Cycloadditionsreaktionen von Allenyl‐Kationen mit Cyclopentadien Chemische Berichte. 115: 3479-3515. DOI: 10.1002/Cber.19821151104  0.426
1982 Mayr H, Schneider R. Ab-initio-MO-Studie Methyl- und Phenyl-substituierter Allenyl-Kationen Chemische Berichte. 115: 3470-3478. DOI: 10.1002/Cber.19821151103  0.31
1981 Mayr H, Wilhelm E, Kaliba C. [2 + 2]-Cycloaddition of a stabilised vinyl cation with cyclopentadiene; X-ray crystal structure of the 2 : 1 addition product Journal of the Chemical Society, Chemical Communications. 683-684. DOI: 10.1039/C39810000683  0.355
1981 Mayr H, Seitz B, Halberstadt-Kausch IK. Stepwise [2 + 2] and [3 + 2] "cycloaddition" reactions of allenyl cations with olefins Journal of Organic Chemistry. 46: 1041-1043. DOI: 10.1021/Jo00318A046  0.44
1981 Mayr H, Schütz F. Addition and cycloaddition reactions of allenyl cations with various cycloalka-1,3-dienes Tetrahedron Letters. 22: 925-928. DOI: 10.1016/0040-4039(81)89010-7  0.377
1981 Mayr H, Klein H. Zinc chloride catalyzed addition reactions of propargyl chlorides with acyclic 1,3-dienes The Journal of Organic Chemistry. 46: 4097-4100. DOI: 10.1002/Chin.198210187  0.426
1981 Mayr H, Seitz B, Halberstadt-Kausch IK. Stepwise (2 + 2) And (3 + 2) “Cycloaddition” Reactions Of Allenyl Cations With Olefins Cheminform. 12. DOI: 10.1002/Chin.198129130  0.436
1981 Klein H, Mayr H. [3+2]-Cycloadditions of Allyl Cations - Synthesis of Permethylcyclopentene and Other Highly Substituted Cyclopentenes Angewandte Chemie International Edition in English. 20: 1027-1029. DOI: 10.1002/Anie.198110271  0.369
1980 Mayr H, Förner W, Schleyer PvR. Additions and Corrections - Methyl-Substituted Allyl Cations. A Comparison of Experimental Stability, Rotational Barrier, and Solvolysis Data with ab Initio Calculations Journal of the American Chemical Society. 102: 3663-3663. DOI: 10.1021/Ja00530A603  0.309
1980 Mayr H, Halberstadt IK. Competing [3+4]- and [2+4]-Cycloadditions of Allenyl Cations Angewandte Chemie International Edition in English. 19: 814-816. DOI: 10.1002/Anie.198008141  0.337
1979 Mayr H, Foerner W, Schleyer PvR. Methyl-substituted allyl cations. A comparison of experimental stability, rotational barrier, and solvolysis data with ab initio calculations Journal of the American Chemical Society. 101: 6032-6040. DOI: 10.1021/Ja00514A028  0.396
1979 Mayr H, Grubmüller B, Halberstadt IK. Orientation effects in reactions of allenyl cations with styrene Tetrahedron Letters. 20: 1749-1752. DOI: 10.1016/S0040-4039(01)86208-0  0.381
1978 Olah GA, Donovan DJ, Lin HC, Mayr H, Andreozzi P, Klopman G. Onium ions. 18. Static protonated and exchanging diprotonated ambivalent heteroorganic systems: hydroxylamines, acetone oxime, and dimethyl sulfoxide The Journal of Organic Chemistry. 43: 2268-2272. DOI: 10.1002/Chin.197842125  0.449
1978 Olah GA, Asensio G, Mayr H, Schleyer PvR. Carbanions. 3. Nuclear magnetic resonance spectroscopic and theoretical study of homoaromaticity in cyclohexadienyl anions Journal of the American Chemical Society. 100: 4347-4352. DOI: 10.1002/Chin.197842064  0.355
1978 Olah GA, Asensio G, Mayr H. Stable carbocations. 211. 1-Phenylallyl cations and their rearrangement to indanyl cations in superacidic media The Journal of Organic Chemistry. 43: 1518-1520. DOI: 10.1002/Chin.197835132  0.431
1978 Mayr H, Grubmüller B. [4 + 3]-Cycloadditions of Allenyl Cations Angewandte Chemie International Edition in English. 17: 130-131. DOI: 10.1002/Anie.197801301  0.364
1977 Mayr H, Olah GA. Stable carbocations. 202. Ring closure reactions of allyl to cyclopropylcarbinyl cations Journal of the American Chemical Society. 99: 510-513. DOI: 10.1002/Chin.197715122  0.527
1976 Mayr H, Huisgen R. Kinetics and mechanism of the conversion of cyclobutenones to vinylketens Journal of the Chemical Society, Chemical Communications. 57-58. DOI: 10.1039/C39760000057  0.468
1976 Olah GA, Mayr H. Carbanions. II. Carbon-13 nuclear magnetic resonance study of Meisenheimer complexes and their charge distribution pattern The Journal of Organic Chemistry. 41: 3448-3451. DOI: 10.1021/Jo00883A028  0.356
1976 Olah G, Mayr H. Stable Carbocations. 198. Formation of Allyl Cations via Protonation of Alkynes in Magic Acid Solution. Evidence for 1,2-Hydrogen and Alkyl Shifts in the Intermediate Vinyl Cations Journal of the American Chemical Society. 98: 7333-7340. DOI: 10.1021/Ja00439A600  0.463
1976 Huisgen R, Mayr H. Reactions of cyclobutenones with nucleophilic reagents via vinylketen intermediates Journal of the Chemical Society, Chemical Communications. 55-56. DOI: 10.1002/Chin.197618115  0.562
1975 Huisgen R, Mayr H. Steric course, kinetics and mechanism of the 2+2 cycloadditions of alkylphenylketenes to ethyl cis- and trans-propenyl ether Tetrahedron Letters. 16: 2969-2972. DOI: 10.1016/S0040-4039(00)75046-5  0.462
1975 Huisgen R, Mayr H. Kinetics of 2+2 cycloadditions of diphenylketene to enol ethers; The structure of the orientation complexes Tetrahedron Letters. 16: 2965-2968. DOI: 10.1016/S0040-4039(00)75045-3  0.461
1975 Mayr H, Huisgen R. Structural assignments of stereoisomeric cyclobutanones by substituent increments on chemical shifts Tetrahedron Letters. 16: 1349-1352. DOI: 10.1016/S0040-4039(00)72139-3  0.435
1975 Mayr H, Huisgen R. A New Synthesis of Cyclobutenones Angewandte Chemie International Edition in English. 14: 499-500. DOI: 10.1002/Anie.197504991  0.415
1975 Mayr H, Huisgen R. Eine neue Synthese von Cyclobutenonen Angewandte Chemie. 87: 491-491. DOI: 10.1002/Ange.19750871312  0.443
Low-probability matches (unlikely to be authored by this person)
1984 Mayr H, Klein H, Kolberg G. Lewis-Säure-katalysierte Additionen 1,3-Alkyl-substituierter Allylchloride an Alkene Chemische Berichte. 117: 2555-2579. DOI: 10.1002/Cber.19841170803  0.299
1990 Mayr H, Cambanis A, Bäuml E. Notizen/Notes Synthesis of β-Oxo Esters from Silyl Enol Ethers and Dichlorobis(phenoxy)methane Chemische Berichte. 123: 1571-1574. DOI: 10.1002/Cber.19901230718  0.299
2001 Borowiak T, Wolska I, Mayr H, Baran J. X-Ray Structure of 6(E)-[2(Z)-(Hydroxyimino)-2-phenylethyIidene]- 7,7,8,8,9,9-hexamethyl-3-phenyl-1,2-oxazaspiro[4.4]non-2-ene Zeitschrift FüR Naturforschung B. 56: 354-358. DOI: 10.1515/Znb-2001-4-505  0.297
2009 Baidya M, Mayr H, Mayer P. 4,4'-Bis(dimethyl-amino)benzhydryl phenyl sulfone. Acta Crystallographica. Section E, Structure Reports Online. 65: o3035. PMID 21578770 DOI: 10.1107/S160053680904642X  0.295
1996 Mayr H, Roth M, Faust R. Examination of Models for Carbocationic Polymerization:  Influence of Chain Length on Carbocation Reactivities Macromolecules. 29: 6110-6113. DOI: 10.1021/Ma9602379  0.295
1981 Mayr H. Lewis Acid Catalyzed Alkylations of CC-Multiple Bonds; Rules for Selective Enlargements of Carbon Skeletons Angewandte Chemie International Edition in English. 20: 184-186. DOI: 10.1002/Anie.198101841  0.293
2007 Dubbaka S, Kienle M, Mayr H, Knochel P. Kupfer(I)-vermittelte oxidative Kreuzkupplung funktionalisierter Alkinyllithiumverbindungen mit Arylmagnesiumreagentien Angewandte Chemie. 119: 9251-9255. DOI: 10.1002/Ange.200703097  0.293
1988 Schade C, Mayr H, Arnett EM. Thermochemical study of the addition of carbenium ions to alkenes Journal of the American Chemical Society. 110: 567-571. DOI: 10.1021/Ja00210A042  0.293
2012 Pock R, Mayr H, Rubow M, Wilhelm E. Do carbenium ion additions toward alkenes proceed via .pi. complexes? A stereochemical investigation. Journal of the American Chemical Society. 108: 7767-72. PMID 22283284 DOI: 10.1021/Ja00284A046  0.292
1991 Mayr H, Baran J, Heigl UW. 3,3,4,4,5,5-Hexamethyl-1,2-bis(methylene)cyclopentane Gazzetta Chimica Italiana. DOI: 10.5282/Ubm/Epub.3939  0.292
1986 Mayr H, Pock R. Relative Reaktivität Alkyl-substituierter Alkene und Cycloalkene gegenüber Diarylcarbenium-Ionen Chemische Berichte. 119: 2473-2496. DOI: 10.1002/Cber.19861190808  0.291
1986 Mayr H, Pock R. Electrophilic attack at allylsilanes: a quantitative determination of the β-silyl effect Tetrahedron. 42: 4211-4214. DOI: 10.1016/S0040-4020(01)87645-6  0.29
1988 Azizur-Rahman, Klein H, Dressel J, Mayr H. Diastereoselective synthesis of β- and γ2-muurolene: a carbocationic pathway from mono- to sesquiterpenes Tetrahedron. 44: 6041-6045. DOI: 10.1016/S0040-4020(01)89792-1  0.29
2005 Wagler J, Böhme U, Brendler E, Thomas B, Goutal S, Mayr H, Kempf B, Remennikov GY, Roewer G. Switching between penta- and hexacoordination with salen-silicon-complexes Inorganica Chimica Acta. 358: 4270-4286. DOI: 10.1016/J.Ica.2005.03.036  0.287
1986 Pock R, Klein H, Mayr H. Elektrophile Alkylierungen von Norbornen – Synthese 7-substituierter Norbornene Chemische Berichte. 119: 929-942. DOI: 10.1002/Cber.19861190316  0.286
2011 Mayr H. Reply to T.W. Bentley: Limitations of the s(E+N) and related equations Angewandte Chemie - International Edition. 50: 3612-3618. DOI: 10.1002/Anie.201007923  0.282
1997 Ofial AR, Mayr H. En-Reaktionen von Alkinen zur stereoselektiven Synthese von Allylaminen Angewandte Chemie. 109: 145-147. DOI: 10.1002/Ange.19971090147  0.28
2012 Asahara H, Mayer P, Mayr H. 2-(4-Meth-oxy-benzyl-idene)-2H-1,3-benzodithiole 1,1,3,3-tetra-oxide. Acta Crystallographica. Section E, Structure Reports Online. 68: o567. PMID 22412485 DOI: 10.1107/S1600536812002826  0.28
1985 Mayr H, Heigl UW. 1,4-Additions of Dihalocarbenes Angewandte Chemie International Edition in English. 24: 579-580. DOI: 10.1002/Anie.198505791  0.279
2016 Zhang Z, Puente Á, Wang F, Rahm M, Mei Y, Mayr H, Prakash GKS. Berichtigung: The Nucleophilicity of Persistent α-Monofluoromethide Anions Angewandte Chemie. 128: 14710-14710. DOI: 10.1002/Ange.201609842  0.279
2010 Appel R, Mayr H. Nucleophilic reactivities of sulfur ylides and related carbanions: comparison with structurally related organophosphorus compounds. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 8610-4. PMID 20593449 DOI: 10.1002/Chem.201001455  0.279
1981 Kaufmann E, Mayr H, Chandrasekhar J, Schleyer PvR. Elusiveness of bishomoaromaticity in anionic systems: the bicyclo[3.2.1]octa-3,6-dien-2-yl anion Journal of the American Chemical Society. 103: 1375-1380. DOI: 10.1002/Chin.198127053  0.279
1989 Baran J, Mayr H. Competing [2 + 3] and [4 + 3] cycloadditions of C,N-diphenylnitrone with 1,3-dienes. Evidence for thermally nonequilibrated intermediates The Journal of Organic Chemistry. 54: 5774-5783. DOI: 10.1021/Jo00285A026  0.278
2010 Zenz I, Mayr H, Mayer P. trans-2-(2-Nitro-1-phenyl-eth-yl)cyclo-hexa-none. Acta Crystallographica. Section E, Structure Reports Online. 66: o3136. PMID 21589437 DOI: 10.1107/S1600536810045423  0.277
2012 Asahara H, Mayer P, Mayr H. 1-[2,2-Bis(phenyl-sulfon-yl)ethen-yl]-4-meth-oxy-benzene. Acta Crystallographica. Section E, Structure Reports Online. 68: o470. PMID 22347078 DOI: 10.1107/S1600536812001961  0.276
2012 Joannesse C, Johnston CP, Morrill LC, Woods PA, Kieffer M, Nigst TA, Mayr H, Lebl T, Philp D, Bragg RA, Smith AD. Isothiourea-mediated asymmetric O- to C-carboxyl transfer of oxazolyl carbonates: structure-selectivity profiles and mechanistic studies. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 2398-408. PMID 22262624 DOI: 10.1002/Chem.201102847  0.276
1994 Mayr H, Gorath G, Bauer B. Liquid Sulfur Dioxide as a Lewis-Acidic Solvent for the Alkylation and Alkoxyalkylation of Allylsilanes Angewandte Chemie International Edition in English. 33: 788-789. DOI: 10.1002/Anie.199407881  0.273
1988 Baran J, Mayr H. Synthesis of hexamethylglutaric acid: an approach to compounds with adjacent quaternary carbon centers The Journal of Organic Chemistry. 53: 4626-4628. DOI: 10.1021/Jo00254A052  0.27
2012 Nigst TA, Ammer J, Mayr H. Ambident reactivities of methylhydrazines. Angewandte Chemie (International Ed. in English). 51: 1353-6. PMID 22223457 DOI: 10.1002/Anie.201107315  0.269
2012 Troshin K, Mayer P, Mayr H. (R,E)-3-(4-Chloro-phen-yl)-1-phenyl-allyl 4-nitro-benzoate. Acta Crystallographica. Section E, Structure Reports Online. 68: o2549. PMID 22904981 DOI: 10.1107/S1600536812032813  0.267
1988 Mayr H, Schade C. Die Makromolekulare Chemie, Rapid Communications. 9: 483-488. DOI: 10.1002/Marc.1988.030090706  0.266
1988 Schade C, Mayr H. Die Makromolekulare Chemie, Rapid Communications. 9: 477-482. DOI: 10.1002/Marc.1988.030090705  0.266
2009 Baidya M, Mayr H, Mayer P. Benzhydryl phenyl sulfone. Acta Crystallographica. Section E, Structure Reports Online. 65: o3224. PMID 21578931 DOI: 10.1107/S1600536809050363  0.265
2003 Lucius R, Loos R, Mayr H. Kinetic studies of carbocation-carbanion combinations: key to a general concept of polar organic reactivity. Angewandte Chemie (International Ed. in English). 41: 92-5. PMID 12491448 DOI: 10.1002/1521-3773(20020104)41:1<91::Aid-Anie91>3.0.Co;2-P  0.264
1983 Mayr H, Klein H, Sippel E. Synthese von 1,2,3,3,6,6-Hexamethyl-1-cyclohexen – Eine Umlagerungskaskade von C12H23+-Kationen Chemische Berichte. 116: 3624-3630. DOI: 10.1002/Cber.19831161111  0.264
1987 Mayr H, Schade C, Rubow M, Schneider R. Control of the Relative Electrophilicity of Alkylating Agents by Variation of the Lewis Acid Concentration Angewandte Chemie International Edition in English. 26: 1029-1030. DOI: 10.1002/Anie.198710291  0.261
2008 Wei Y, Singer T, Mayr H, Sastry GN, Zipse H. Assessment of theoretical methods for the calculation of methyl cation affinities. Journal of Computational Chemistry. 29: 291-7. PMID 17570129 DOI: 10.1002/Jcc.20790  0.26
1986 Schleyer PvR, Kaufmann E, Kos AJ, Mayr H, Chandrasekhar J. Stabilization of the alleged ‘bishomoromatic’ bicyclo[3.2.1]octa-2,6-dienyl anion by counterion interactions and by hyperconjugation Journal of the Chemical Society, Chemical Communications. 1583-1585. DOI: 10.1039/C39860001583  0.256
1994 Mayr H, Patz M. Nucleophilie- und Elektrophilieskalen als Ordnungsprinzipien polarer organischer und metallorganischer Reaktionen Angewandte Chemie. 106: 990-1010. DOI: 10.1002/Ange.19941060905  0.255
1984 Mayr H, Schneider R. Die Makromolekulare Chemie, Rapid Communications. 5: 43-46. DOI: 10.1002/Marc.1984.030050107  0.255
1982 Mayr H, Klein H. Additions- und Cycloadditionsreaktionen von Allenyl-Kationen mit acyclischen 1,3-Dienen Chemische Berichte. 115: 3528-3546. DOI: 10.1002/Cber.19821151105  0.254
1989 Baran J, Mayr H. Mechanistic impact of oxime formation accompanying 1,3-dipolar cycloadditions of nitrile oxides The Journal of Organic Chemistry. 54: 5012-5016. DOI: 10.1021/Jo00282A012  0.254
2014 Wilcken R, Mayr H, Riedle E. Bimolecular reactions on a timescale below 1 ps Optics Infobase Conference Papers.  0.253
1995 Roth M, Mayr H. The Coexistence of the Reactivity–Selectivity Principle and of Linear Free Energy Relationships: A Diffusion Clock for Determining Carbocation Reactivities Angewandte Chemie International Edition in English. 34: 2250-2252. DOI: 10.1002/Anie.199522501  0.249
2002 Mayr H, Minegishi S. Erstmalige direkte Beobachtung der beiden Einzelschritte einer SN1-Reaktion Angewandte Chemie. 114: 4674-4676. DOI: 10.1002/1521-3757(20021202)114:23<4674::Aid-Ange4674>3.0.Co;2-Y  0.246
2017 Mayr H. Nachruf: George A. Olah Nachrichten Aus Der Chemie. 65: 582-582. DOI: 10.1002/Nadc.20174064078  0.246
2015 Mayr H. Physical Organic Chemistry-Development and Perspectives Israel Journal of Chemistry. DOI: 10.1002/Ijch.201400200  0.246
1986 Mayr H, Schneider R, Grabis U. Lineare Reaktivitäts-Selektivitäts-Korrelationen bei Additionen von Diarylcarbenium-Ionen an Alkene; eine Widerlegung des Reaktivitäts-Selektivitäts-Prinzips Angewandte Chemie. 98: 1034-1036. DOI: 10.1002/Ange.19860981134  0.244
2003 Mayr H. Buchbesprechung: Aromatic Chemistry. Von John D. Hepworth, David R. Waring und Michael J. Waring Angewandte Chemie. 115: 3981-3981. DOI: 10.1002/Ange.200390587  0.243
1981 Klein H, Mayr H, Klein H. [3 + 2]-Cycloadditionen von Allylkationen – Synthese von Permethylcyclopenten und anderen hochsubstituierten Cyclopentenen Angewandte Chemie. 93: 1069-1070. DOI: 10.1002/Ange.19810931207  0.243
1975 Mayr H. Vinylketenes from Cyclobutenones by Electrocyclic Ring Opening Angewandte Chemie International Edition in English. 14: 500-501. DOI: 10.1002/Anie.197505001  0.242
1999 Kuhn O, Mayr H. Kinetik und Mechanismen der Reaktionen von π-Allylpalladiumkomplexen mit Nucleophilen Angewandte Chemie. 111: 356-358. DOI: 10.1002/(Sici)1521-3757(19990201)111:3<356::Aid-Ange356>3.0.Co;2-I  0.24
1990 Mayr H. Knüpfung von CC-Bindungen durch Addition von Carbenium-Ionen an Alkene: Kinetik und Mechanismus Angewandte Chemie. 102: 1415-1428. DOI: 10.1002/Ange.19901021204  0.239
2020 Zhang J, Chen Q, Mayer RJ, Yang J, Ofial AR, Cheng J, Mayr H. Voraussage absoluter Geschwindigkeitskonstanten von Huisgen‐ Reaktionen ungesättigter Iminium‐Ionen mit Diazoalkanen Angewandte Chemie. 132: 12628-12634. DOI: 10.1002/Ange.202003029  0.238
1997 Mayr H. Stable Carbocation Chemistry Edited by G. K. Surya Prakash (University of Southern California) and Paul v. R. Schleyer (University of Erlangen Nürnberg, Germany). Wiley:  New York, 1996. xvi + 587 pp. $79.95. ISBN 0-471-59462-8. Journal of the American Chemical Society. 119: 12026-12027. DOI: 10.1021/Ja965784O  0.238
2003 Heinrich MR, Klisa HS, Mayr H, Steglich W, Zipse H. Enhancing the catalytic activity of 4-(dialkylamino)pyridines by conformational fixation. Angewandte Chemie (International Ed. in English). 42: 4826-8. PMID 14562361 DOI: 10.1002/Anie.200352289  0.237
1981 Mayr H, Wilhelm E, Kaliba C. (2+2)-Cycloaddition Of A Stabilized Vinyl Cation With Cyclopentadiene: X-Ray Crystal Structure Of The 2:1 Addition Product Cheminform. 12. DOI: 10.1002/Chin.198144140  0.237
2015 Mayr H. Reactivity scales for quantifying polar organic reactivity: the benzhydrylium methodology Tetrahedron. 71: 5095-5111. DOI: 10.1016/J.Tet.2015.05.055  0.237
1985 Bäuml E, Mayr H. Cycloadditionen des Triphenylallenyl-Kations mit Cyclopentadien — Studium des Reaktionsmechanismus unter stabilen Ionen-Bedingungen Chemische Berichte. 118: 694-703. DOI: 10.1002/Cber.19851180229  0.235
2005 Hofmann M, Hampel N, Kanzian T, Mayr H. Electrophilic alkylations in neutral aqueous or alcoholic solutions. Angewandte Chemie (International Ed. in English). 43: 5402-5. PMID 15468080 DOI: 10.1002/Anie.200460812  0.235
2010 Breugst M, Zipse H, Guthrie JP, Mayr H. Marcus analysis of ambident reactivity. Angewandte Chemie (International Ed. in English). 49: 5165-9. PMID 20568073 DOI: 10.1002/Anie.201001574  0.234
2010 Sailer CF, Fingerhut BP, Ammer J, Nolte C, Pugliesi I, Mayr H, Vivie-Riedle RD, Riedle E. The first picoseconds in the life of benzhydryl cations: Ultrafast generation and chemical reactions Optics Infobase Conference Papers.  0.234
2003 Mayr H. Book Review: Aromatic Chemistry. By John D. Hepworth, David R. Waring, and Michael J. Waring Angewandte Chemie International Edition. 42: 3851-3851. DOI: 10.1002/Anie.200390558  0.234
1981 Mayr H, Schneider R, Wilhelm D, Schleyer PVR. Vinyl cations. Comparison of gas-phase thermodynamic and solvolysis data with ab initio MO calculations The Journal of Organic Chemistry. 46: 5336-5340. DOI: 10.1002/Chin.198218080  0.233
2004 Denegri B, Minegishi S, Kronja O, Mayr H. SN1-Reaktionen mit inversen Geschwindigkeitsprofilen Angewandte Chemie. 116: 2353-2356. DOI: 10.1002/Ange.200353468  0.232
1985 Bäuml E, Mayr H. Silbertrifluoracetat-initiierte Reaktionen von Chlortriphenylallen mit Cyclopentadien — Vinylkation-analoge Cycloadditionen von Allenylkationen Chemische Berichte. 118: 683-693. DOI: 10.1002/Cber.19851180228  0.232
1981 Mayr H. Lewis-Säure-katalysierte Alkylierungen von CC-Mehrfachbindungen: Eine Möglichkeit zum gezielten Aufbau von Kohlenstoffgerüsten Angewandte Chemie. 93: 202-204. DOI: 10.1002/Ange.19810930218  0.231
1992 Mayr H, Bartl J, Hagen G. Geschwindigkeitskonstanten für den Angriff von Carbenium-Ionen an Arene — eine Brücke zwischen der Chemie aliphatischer und aromatischer π-Systeme Angewandte Chemie. 104: 1689-1691. DOI: 10.1002/Ange.19921041241  0.231
2000 Schlaad H, Kwon Y, Faust R, Mayr H. Kinetic study on the capping reaction of living polyisobutylene with 1,1-diarylethylenes. 2. Effect of chain length Macromolecules. 33: 743-747. DOI: 10.1021/ma991555l  0.226
2007 Phan TB, Breugst M, Mayr H. Towards a general scale of nucleophilicity? Angewandte Chemie (International Ed. in English). 45: 3869-74. PMID 16646102 DOI: 10.1002/Anie.200600542  0.224
1987 Mayr H. Carbocation Chemistry. Von P. Vogel. Elsevier Science Publishers, Amsterdam 1985. XIV, 596 S., geb. Hfl. 350.00. – ISBN 0-444-42522-5 Angewandte Chemie. 99: 282-282. DOI: 10.1002/Ange.19870990338  0.224
2003 Heinrich MR, Klisa HS, Mayr H, Steglich W, Zipse H. Steigerung der katalytischen Aktivität von 4-(Dialkylamino)pyridinen durch konformative Fixierung Angewandte Chemie. 115: 4975-4977. DOI: 10.1002/Ange.200352289  0.222
1978 MAYR H, GRUBMUELLER B. ChemInform Abstract: (4 + 3)-CYCLOADDITIONS OF ALLENYL CATIONS Chemischer Informationsdienst. 9. DOI: 10.1002/chin.197818082  0.221
1982 KLEIN H, ERBE A, MAYR H. ChemInform Abstract: CATIONIC PRENYLATION OF OLEFINS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198217133  0.22
1985 Mayr H, Heigl UW. 1,4-Addition von Dihalogencarbenen an 1,3-Diene Angewandte Chemie. 97: 567-568. DOI: 10.1002/Ange.19850970707  0.219
1994 Mayr H, Gorath G, Bauer B. Flüssiges Schwefeldioxid als Lewis-acides Solvens für die Alkylierung und Alkoxyalkylierung von Allylsilanen Angewandte Chemie. 106: 793-794. DOI: 10.1002/Ange.19941060716  0.219
2008 Schaller H, Mayr H. “Carbokationen-Watching” bei Solvolyse-Reaktionen Angewandte Chemie. 120: 4022-4025. DOI: 10.1002/Ange.200800354  0.219
1992 Mayr H, Basso N. Kinetik der Hydrid-Übertragungen von CH-, SiH-, GeH- und SnH-Gruppen auf Carbenium-Ionen Angewandte Chemie. 104: 1103-1105. DOI: 10.1002/Ange.19921040843  0.218
2008 Mayr H, Ofial AR. Und es geht doch: Nucleophilieskalen für die Syntheseplanung Nachrichten Aus Der Chemie. 56: 871-877. DOI: 10.1002/Nadc.200858379  0.217
2006 Mayr H. Unverzichtbar im Praktikum: Arbeitsmethoden in der Organischen Chemie. Von S. Hünig, P. Kreitmeier, G. Märkl, J. Sauer. Lehmanns Media, Berlin, 2006. 375 Seiten. 19,95 Euro (im Internet kostenlos unter ioc-praktikum.de). ISBN 3-86541-148-7 Nachrichten Aus Der Chemie. 54: 1239-1239. DOI: 10.1002/Nadc.20060541224  0.215
2011 Mayr H, Breugst M, Ofial AR. Abschied vom HSAB-Modell ambidenter Reaktivität Angewandte Chemie. 123: 6598-6634. DOI: 10.1002/Ange.201007100  0.215
1981 MAYR H, HALBERSTADT IK. ChemInform Abstract: CONCURRENCE BETWEEN (3 + 4)- AND (2 + 4)-CYCLOADDITIONS OF ALLENYL CATIONS Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198103110  0.215
2014 Laub HA, Evano G, Mayr H. Hydrocarbierung von CC-Bindungen: Quantifizierung der nucleophilen Reaktivität von Inamiden Angewandte Chemie. 126: 5068-5072. DOI: 10.1002/Ange.201402055  0.214
1993 Mayr H, Müller K, Rau D. Vergleich der Elektrophilie von kationischen Metall-π-Komplexen und gewöhnlichen Carbenium-Ionen Angewandte Chemie. 105: 1732-1734. DOI: 10.1002/Ange.19931051140  0.212
1995 Roth M, Mayr H. Coexistenz von Reaktivitäts-Selektivitäts-Prinzip und Linearer-Freier-Enthalpie-Beziehung: eine Diffusions-Uhr zur Bestimmung von Carbokationen-Reaktivitäten Angewandte Chemie. 107: 2428-2430. DOI: 10.1002/Ange.19951072015  0.211
2005 Tishkov AA, Schmidhammer U, Roth S, Riedle E, Mayr H. Die ambidente Reaktivität von Nitrit-Ionen neu aufgerollt Angewandte Chemie. 117: 4699-4703. DOI: 10.1002/Ange.200501274  0.211
1988 Schade C, Mayr H, Arnett EM. Thermochemical study of the addition of carbenium ions to alkenes Journal of the American Chemical Society. 110: 567-571. DOI: 10.1021/ja00210a042  0.211
2003 Lemek T, Mąkosza M, Stephenson DS, Mayr H. Direkte Beobachtung der Zwischenstufe bei stellvertretenden (vicarious) nucleophilen Substitutionen von Wasserstoff Angewandte Chemie. 115: 2899-2901. DOI: 10.1002/Ange.200351352  0.211
2005 Schmidhammer U, Roth S, Riedle E, Tishkov AA, Mayr H. Compact laser flash photolysis techniques compatible with ultrafast pump-probe setups Review of Scientific Instruments. 76: 093111. DOI: 10.1063/1.2047828  0.21
1995 Patz M, Mayr H, Maruta J, Fukuzumi S. Reaktionen von Carbokationen mit π-Nucleophilen: polarer Mechanismus statt Outersphere-Elektronentransfer Angewandte Chemie. 107: 1351-1353. DOI: 10.1002/Ange.19951071123  0.208
1980 Mayr H, Halberstadt IK. Konkurrenz zwischen [3+4]- und [2+4]-Cycloadditionen von Allenylkationen Angewandte Chemie. 92: 840-841. DOI: 10.1002/Ange.19800921014  0.207
2011 Nigst TA, Ammer J, Mayr H. Ambidente Reaktivität von Methylhydrazinen Angewandte Chemie. 124: 1381-1385. DOI: 10.1002/Ange.201107315  0.202
1983 Klein H, Freyberger G, Mayr H. [2+2]-Cycloadditionen von Allylkationen Angewandte Chemie. 95: 62-63. DOI: 10.1002/Ange.19830950127  0.202
1978 Mayr H, Grubmüller B. [4 + 3]-Cycloadditionen von Allenylkationen Angewandte Chemie. 90: 129-130. DOI: 10.1002/Ange.19780900213  0.202
2007 Baidya M, Kobayashi S, Brotzel F, Schmidhammer U, Riedle E, Mayr H. DABCO oder DMAP – worauf beruht ihr Unterschied in der Organokatalyse? Angewandte Chemie. 119: 6288-6292. DOI: 10.1002/Ange.200701489  0.202
1995 Patz M, Mayr H, Bartl J, Steenken S. Gemeinsame Ursache enthalpischer und entropischer Substituenteneffekte bei Reaktionen von Benzhydryl-Kationen mit Nucleophilen Angewandte Chemie. 107: 519-521. DOI: 10.1002/Ange.19951070424  0.2
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