George C. Fortman, Ph.D. - Publications

University of Miami, Coral Gables, FL 
Organometallic Chemistry

32 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2016 Cai X, Majumdar S, Fortman GC, Koppaka A, Serafim L, Captain B, Temprado M, Hoff CD. Thermodynamic, Kinetic, Structural, and Computational Studies of the Ph3Sn-H, Ph3Sn-SnPh3, and Ph3Sn-Cr(CO)3C5Me5 Bond Dissociation Enthalpies. Inorganic Chemistry. PMID 27704803 DOI: 10.1021/acs.inorgchem.6b01978  1
2015 Koppaka A, Yempally V, Zhu L, Fortman GC, Temprado M, Hoff CD, Captain B. Synthesis of [Pt(SnBu(t)3)(IBu(t))(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear Pt-Sn Complexes. Inorganic Chemistry. PMID 26673480 DOI: 10.1021/acs.inorgchem.5b02441  1
2015 Kalman SE, Munz D, Fortman GC, Boaz NC, Groves JT, Gunnoe TB. Partial oxidation of light alkanes by periodate and chloride salts. Dalton Transactions (Cambridge, England : 2003). 44: 5294-8. PMID 25708552 DOI: 10.1039/c5dt00558b  1
2015 Webster-Gardiner MS, Fu R, Fortman GC, Nielsen RJ, Gunnoe TB, Goddard WA. Arene C-H activation using Rh(I) catalysts supported by bidentate nitrogen chelates Catalysis Science and Technology. 5: 96-100. DOI: 10.1039/c4cy00972j  1
2014 Fortman GC, Boaz NC, Munz D, Konnick MM, Periana RA, Groves JT, Gunnoe TB. Selective monooxidation of light alkanes using chloride and iodate. Journal of the American Chemical Society. 136: 8393-401. PMID 24866148 DOI: 10.1021/ja502657g  1
2014 Fu R, Nielsen RJ, Goddard WA, Fortman GC, Gunnoe TB. DFT virtual screening identifies rhodium-amidinate complexes as potential homogeneous catalysts for methane-to-methanol oxidation Acs Catalysis. 4: 4455-4465. DOI: 10.1021/cs5005322  1
2012 Lamberti M, Fortman GC, Poater A, Broggi J, Slawin AMZ, Cavallo L, Nolan SP. Coordinatively unsaturated ruthenium complexes as efficient alkyneazide cycloaddition catalysts Organometallics. 31: 756-767. DOI: 10.1021/om2012425  1
2012 Pouy MJ, Delp SA, Uddin J, Ramdeen VM, Cochrane NA, Fortman GC, Gunnoe TB, Cundari TR, Sabat M, Myers WH. Intramolecular hydroalkoxylation and hydroamination of alkynes catalyzed by Cu(I) complexes supported by N-heterocyclic carbene ligands Acs Catalysis. 2: 2182-2193. DOI: 10.1021/cs300544w  1
2011 Cai X, Majumdar S, Fortman GC, Frutos LM, Temprado M, Clough CR, Cummins CC, Germain ME, Palluccio T, Rybak-Akimova EV, Captain B, Hoff CD. Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. Inorganic Chemistry. 50: 9620-30. PMID 21875050 DOI: 10.1021/ic2013599  1
2011 Truscott BJ, Fortman GC, Slawin AM, Nolan SP. Well-defined [Rh(NHC)(OH)] complexes enabling the conjugate addition of arylboronic acids to α,β-unsaturated ketones. Organic & Biomolecular Chemistry. 9: 7038-41. PMID 21858324 DOI: 10.1039/c1ob06112g  1
2011 Fortman GC, Jacobsen H, Cavallo L, Nolan SP. Catalytic deuteration of silanes mediated by N-heterocyclic carbene-Ir(III) complexes. Chemical Communications (Cambridge, England). 47: 9723-5. PMID 21779584 DOI: 10.1039/c1cc13492b  1
2011 Fortman GC, Nolan SP. N-Heterocyclic carbene (NHC) ligands and palladium in homogeneous cross-coupling catalysis: a perfect union. Chemical Society Reviews. 40: 5151-69. PMID 21731956 DOI: 10.1039/c1cs15088j  1
2011 Cai X, Majumdar S, Fortman GC, Cazin CS, Slawin AM, Lhermitte C, Prabhakar R, Germain ME, Palluccio T, Nolan SP, Rybak-Akimova EV, Temprado M, Captain B, Hoff CD. Oxygen binding to [Pd(L)(L')] (L= NHC, L' = NHC or PR3, NHC = N-heterocyclic carbene). synthesis and structure of a paramagnetic trans-[Pd(NHC)2(η(1)-O2)2] complex. Journal of the American Chemical Society. 133: 1290-3. PMID 21204538 DOI: 10.1021/ja1103348  1
2011 Nun P, Fortman GC, Slawin AMZ, Nolan SP. Ruthenium hydroxide complexes in the racemization of secondary alcohols Organometallics. 30: 6347-6350. DOI: 10.1021/om200956r  1
2011 Fortman GC, Slawin AMZ, Nolan SP. Highly active iridium(III)-NHC system for the catalytic B-N bond activation and subsequent solvolysis of ammonia-borane Organometallics. 30: 5487-5492. DOI: 10.1021/om2007437  1
2011 Diebolt O, Fortman GC, Clavier H, Slawin AMZ, Escudero-Adán EC, Benet-Buchholz J, Nolan SP. Steric and electronic parameters characterizing bulky and electron-rich dialkylbiarylphosphines Organometallics. 30: 1668-1676. DOI: 10.1021/om101174x  1
2010 Fortman GC, Poater A, Levell JW, Gaillard S, Slawin AM, Samuel ID, Cavallo L, Nolan SP. A versatile gold synthon for acetylene C-H bond activation. Dalton Transactions (Cambridge, England : 2003). 39: 10382-90. PMID 20922211 DOI: 10.1039/c0dt00276c  1
2010 Boogaerts II, Fortman GC, Furst MR, Cazin CS, Nolan SP. Carboxylation of N-H/C-H bonds using N-heterocyclic carbene copper(I) complexes. Angewandte Chemie (International Ed. in English). 49: 8674-7. PMID 20886489 DOI: 10.1002/anie.201004153  1
2010 Fortman GC, Slawin AM, Nolan SP. Flexible cycloalkyl-substituted N-heterocyclic carbenes. Dalton Transactions (Cambridge, England : 2003). 39: 3923-30. PMID 20372717 DOI: 10.1039/c003214j  1
2010 Fortman GC, Scott NM, Linden A, Stevens ED, Dorta R, Nolan SP. Unusual reactivities of N-heterocyclic carbenes upon coordination to the platinum(II)-dimethyl moiety. Chemical Communications (Cambridge, England). 46: 1050-2. PMID 20126709 DOI: 10.1039/b920482b  1
2010 Fortman GC, Slawin AMZ, Nolan SP. A versatile cuprous synthon: [Cu(IPr)(OH)] (IPr = 1,3 bis(diisopropylphenyl)imidazol-2-ylidene) Organometallics. 29: 3966-3972. DOI: 10.1021/om100733n  1
2010 Fortman GC, Nolan SP. Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite) Organometallics. 29: 4579-4583. DOI: 10.1021/om1007049  1
2010 Kégl T, Fortman GC, Temprado M, Hoff CD. Organometallic Radicals: Thermodynamics, Kinetics, and Reaction Mechanisms Physical Inorganic Chemistry: Reactions, Processes, and Applications. 429-494. DOI: 10.1002/9780470602577.ch10  1
2009 Achord P, Fujita E, Muckerman JT, Scott B, Fortman GC, Temprado M, Cai X, Captain B, Isrow D, Weir JJ, McDonough JE, Hoff CD. Experimental and computational studies of binding of dinitrogen, nitriles, azides, diazoalkanes, pyridine, and pyrazines to M(PR(3))(2)(CO)(3) (M = Mo, W; R = Me, (i)Pr). Inorganic Chemistry. 48: 7891-904. PMID 19621935 DOI: 10.1021/ic900764e  1
2009 Fortman GC, Captain B, Hoff CD. Thermodynamic investigations of the staudinger reaction of trialkylphosphines with 1-adamantyl azide and the isolation of an unusual s-cis phosphazide. Inorganic Chemistry. 48: 1808-10. PMID 19235943 DOI: 10.1021/ic8024205  1
2009 Fortman GC, Captain B, Hoff CD. Stoichiometric and catalytic conversion of 1-adamantyl azide to 1-adamantyl isocyanate by [Cr(CO) 3Cp] 2 and reaction with Mo(CO) 3(P iPr 3) 2 to form Mo(κ 2- iPr 3P=NN=NAd)(CO) 3(P iPr 3) Organometallics. 28: 3587-3590. DOI: 10.1021/om900004k  1
2008 Temprado M, McDonough JE, Mendiratta A, Tsai YC, Fortman GC, Cummins CC, Rybak-Akimova EV, Hoff CD. Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. Inorganic Chemistry. 47: 9380-9. PMID 18788794 DOI: 10.1021/ic800945m  1
2008 McDonough JE, Mendiratta A, Curley JJ, Fortman GC, Fantasia S, Cummins CC, Rybak-Akimova EV, Nolan SP, Hoff CD. Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorganic Chemistry. 47: 2133-41. PMID 18260626 DOI: 10.1021/ic701611p  1
2008 Fortman GC, Kégl T, Hoff CD. Kinetic, thermodynamic, and mechanistic aspects of oxidative addition reactions of RE-ER (E = S, Se, Te) and transition metal complexes Current Organic Chemistry. 12: 1279-1297. DOI: 10.2174/138527208785909574  1
2008 Fortman GC, Isrow D, McDonough JE, Von Ragué Schleyer P, Schaefer HF, Scott B, Kubas GJ, Kégl T, Ungváry F, Hoff CD. Kinetic and thermodynamic studies of the reactivity of (trimethylsilyl) diazomethane with HMo(CO)3(C5R5) (R = H, Me). Estimation of the Mo-N2CH2SiMe3 bond strength and experimental determination of the enthalpy of formation of (trimethylsilyl)diazomethane Organometallics. 27: 4873-4884. DOI: 10.1021/om800336p  1
2007 Fortman GC, Kégl T, Li QS, Zhang X, Schaefer HF, Xie Y, King RB, Telser J, Hoff CD. Spectroscopic detection and theoretical confirmation of the role of Cr2(CO)5(C5R5)2 and .Cr(CO)2(ketene)(C5R5) as intermediates in carbonylation of N=N=CHSiMe3 to O=C=CHSiMe3 by .Cr(CO)3(C5R5) (R = H, CH3). Journal of the American Chemical Society. 129: 14388-400. PMID 17960906 DOI: 10.1021/ja075008o  1
2007 Weir JJ, McDonough JE, Fortman G, Isrow D, Hoff CD, Scott B, Kubas GJ. Synthesis, structure, and thermochemistry of the formation of the metal-metal bonded dimers [Mo(mu-TeAr)(CO)3(PiP3)]2 (Ar = phenyl, naphthyl) by phosphine elimination from *Mo(TePh)(CO)3(PiPr3)2. Inorganic Chemistry. 46: 652-9. PMID 17257007 DOI: 10.1021/ic061654x  1
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