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T. Keith Hollis, Ph.D. - Publications

Affiliations: 
1998-2006 Chemistry University of California, Riverside, Riverside, CA, United States 
 2006-2013 Chemistry and Biochemistry University of Mississippi, Oxford, MS, United States 
 2013- Chemistry Mississippi State University 
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Year Citation  Score
2018 Liang G, Hollis TK, Webster CE. Computational Analysis of the Intramolecular Oxidative Amination of an Alkene Catalyzed by the Extreme π-Loading N-Heterocyclic Carbene Pincer Tantalum(V) Bis(imido) Complex Organometallics. 37: 1671-1681. DOI: 10.1021/Acs.Organomet.8B00097  0.482
2018 Denny JA, Lamb RW, Reilly SW, Donnadieu B, Webster CE, Hollis TK. Investigation of metallation/transmetallation reactions to synthesize a series of CCC–NHC Co pincer complexes and their X-ray structures Polyhedron. 151: 568-574. DOI: 10.1016/J.Poly.2018.05.040  0.528
2018 Helgert TR, Webster CE, Hollis TK, Valle HU, Hillesheim P, Oliver AG. Free methylidyne? CCC-NHC tantalum bis(imido) reactivity: protonation, rearrangement to a mixed unsymmetrical CCC-N-heterocyclic carbene/N-heterocyclic dicarbene (CCC-NHC/NHDC) pincer tantalum bis(imido) complex Inorganica Chimica Acta. 469: 164-172. DOI: 10.1016/J.Ica.2017.08.050  0.807
2017 Cope JD, Liyanage NP, Kelley PJ, Denny JA, Valente EJ, Webster CE, Delcamp JH, Hollis TK. Electrocatalytic reduction of CO2 with CCC-NHC pincer nickel complexes. Chemical Communications (Cambridge, England). PMID 28792548 DOI: 10.1039/C6Cc06537F  0.495
2017 Box HK, Howell TO, Kennon WE, Burk GA, Valle HU, Hollis TK. An efficient route to unsymmetrical bis(azolium) salts: CCC-NHC pincer ligand complex precursors Tetrahedron. 73: 2191-2195. DOI: 10.1016/J.Tet.2017.02.020  0.801
2017 Cope JD, Denny JA, Lamb RW, McNamara LE, Hammer NI, Webster CE, Hollis TK. Synthesis, characterization, photophysics, and a ligand rearrangement of CCC-NHC pincer nickel complexes: Colors, polymorphs, emission, and Raman spectra Journal of Organometallic Chemistry. 845: 258-265. DOI: 10.1016/J.Jorganchem.2017.05.046  0.569
2016 Clark WD, Akurathi G, Valle HU, Hollis TK. Crystal structure of tris-(di-methyl-amido-κN)-bis-(di-methyl-amine-κN)-zirconium(IV) iodide. Acta Crystallographica. Section E, Crystallographic Communications. 72: 73-5. PMID 26870590 DOI: 10.1107/S2056989015023919  0.751
2016 Reilly SW, Webster CE, Hollis TK, Valle HU. Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials. Dalton Transactions (Cambridge, England : 2003). PMID 26814468 DOI: 10.1039/C5Dt04752H  0.793
2016 Valle HU, Akurathi G, Cho J, Clark WD, Chakraborty A, Hollis TK. CCC-NHC Pincer Zr Diamido Complexes: Synthesis, Characterisation, and Catalytic Activity in Hydroamination/Cyclisation of Unactivated Amino-Alkenes,-Alkynes, and Allenes Australian Journal of Chemistry. 69: 565-572. DOI: 10.1071/Ch15795  0.807
2016 Clark WD, Leigh KN, Webster CE, Hollis TK. Experimental and Computational Studies of the Mechanisms of Hydroamination/Cyclisation of Unactivated α,ω-Amino-alkenes with CCC-NHC Pincer Zr Complexes Australian Journal of Chemistry. 69: 573-582. DOI: 10.1071/Ch15779  0.514
2016 Helgert TR, Zhang X, Box HK, Denny JA, Valle HU, Oliver AG, Akurathi G, Webster CE, Hollis TK. Extreme π-Loading as a Design Element for Accessing Imido Ligand Reactivity. A CCC-NHC Pincer Tantalum Bis(imido) Complex: Synthesis, Characterization, and Catalytic Oxidative Amination of Alkenes Organometallics. 35: 3452-3460. DOI: 10.1021/Acs.Organomet.6B00216  0.82
2016 Reilly SW, Akurathi G, Box HK, Valle HU, Hollis TK, Webster CE. β-Boration of α,β-unsaturated carbonyl compounds in ethanol and methanol catalyzed by CCC-NHC pincer Rh complexes Journal of Organometallic Chemistry. 802: 32-38. DOI: 10.1016/J.Jorganchem.2015.11.010  0.765
2015 Tyson GE, Tokmic K, Oian CS, Rabinovich D, Valle HU, Hollis TK, Kelly JT, Cuellar KA, McNamara LE, Hammer NI, Webster CE, Oliver AG, Zhang M. Synthesis, characterization, photophysical properties, and catalytic activity of an SCS bis(N-heterocyclic thione) (SCS-NHT) Pd pincer complex. Dalton Transactions (Cambridge, England : 2003). PMID 26205732 DOI: 10.1039/C4Dt03324H  0.813
2014 Howell TO, Huckaba AJ, Hollis TK. An efficient synthesis of bis-1,3-(3'-aryl-N-heterocycl-1'-yl)arenes as CCC-NHC pincer ligand precursors. Organic Letters. 16: 2570-2. PMID 24735022 DOI: 10.1021/Ol5007407  0.51
2014 Helgert TR, Hollis TK, Oliver AG, Valle HU, Wu Y, Webster CE. Synthesis, characterization, and X-ray molecular structure of tantalum CCC-N-heterocyclic carbene (CCC-NHC) pincer complexes with imidazole- and triazole-based ligands Organometallics. 33: 952-958. DOI: 10.1021/Om401063E  0.795
2014 Reilly SW, Box HK, Kuchenbeiser GR, Rubio RJ, Letko CS, Cousineau KD, Hollis TK. 1,4-Addition of aryl boronic acids to α,β-unsaturated ketones catalyzed by a CCC-NHC pincer rhodium complex Tetrahedron Letters. 55: 6738-6742. DOI: 10.1016/J.Tetlet.2014.09.107  0.406
2014 Clark WD, Cho J, Valle HU, Hollis TK, Valente EJ. Metal and halogen dependence of the rate effect in hydroamination/ cyclization of unactivated aminoalkenes: Synthesis, characterization, and catalytic rates of CCC-NHC hafnium and zirconium pincer complexes Journal of Organometallic Chemistry. 751: 534-540. DOI: 10.1016/J.Jorganchem.2013.11.001  0.807
2014 Howell TO, Huckaba AJ, Hollis TK. ChemInform Abstract: An Efficient Synthesis of Bis-1,3-(3′-aryl-N-heterocycl-1′-yl)arenes as CCC-NHC Pincer Ligand Precursors. Cheminform. 45: no-no. DOI: 10.1002/chin.201446155  0.405
2013 Huckaba AJ, Cao B, Hollis TK, Valle HU, Kelly JT, Hammer NI, Oliver AG, Webster CE. Platinum CCC-NHC benzimidazolyl pincer complexes: synthesis, characterization, photostability, and theoretical investigation of a blue-green emitter. Dalton Transactions (Cambridge, England : 2003). 42: 8820-6. PMID 23640268 DOI: 10.1039/C3Dt50438G  0.766
2013 Clark WD, Tyson GE, Hollis TK, Valle HU, Valente EJ, Oliver AG, Dukes MP. Toward molecular rotors: tetra-N-heterocyclic carbene Ag(I)-halide cubane-type clusters. Dalton Transactions (Cambridge, England : 2003). 42: 7338-44. PMID 23389555 DOI: 10.1039/C3Dt32862G  0.747
2013 Huckaba AJ, Hollis TK, Reilly SW. Homobimetallic rhodium NHC complexes as versatile catalysts for hydrosilylation of a multitude of substrates in the presence of ambient air Organometallics. 32: 6248-6256. DOI: 10.1021/Om400452Q  0.539
2013 Huckaba AJ, Hollis TK, Howell TO, Valle HU, Wu Y. Synthesis and characterization of a 1,3-phenylene-bridged N-alkyl bis(benzimidazole) CCC-NHC pincer ligand precursor: Homobimetallic silver and rhodium complexes and the catalytic hydrosilylation of phenylacetylene Organometallics. 32: 63-69. DOI: 10.1021/Om3008037  0.814
2013 Zhang X, Cao B, Valente EJ, Hollis TK. Synthesis, characterization, photoluminescence, and simulations of a CCC-NHC-supported Pt2Ag2 mixed-metal cluster containing a PtAg2 metallacyclopropane Organometallics. 32: 752-761. DOI: 10.1021/Om300330Y  0.454
2012 Helgert TR, Hollis TK, Valente EJ. Synthesis of titanium CCC-NHC pincer complexes and catalytic hydroamination of unactivated alkenes Organometallics. 31: 3002-3009. DOI: 10.1021/Om2010436  0.564
2012 Zhang X, Wright AM, Deyonker NJ, Hollis TK, Hammer NI, Webster CE, Valente EJ. Synthesis, air stability, photobleaching, and DFT modeling of blue light emitting platinum CCC-N-heterocyclic carbene pincer complexes Organometallics. 31: 1664-1672. DOI: 10.1021/Om200687W  0.485
2011 Cho J, Hollis TK, Valente EJ, Trate JM. CCC-N-heterocyclic carbene pincer complexes: Synthesis, characterization and hydroamination activity of a hafnium complex Journal of Organometallic Chemistry. 696: 373-377. DOI: 10.1016/J.Jorganchem.2010.10.004  0.579
2010 Hollis TK, Overman LE. ChemInform Abstract: Palladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides Cheminform. 30: no-no. DOI: 10.1002/chin.199932290  0.554
2010 HOLLIS TK, OVERMAN LE. ChemInform Abstract: Cyclopalladated Ferrocenyl Amines as Enantioselective Catalysts for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 29: no-no. DOI: 10.1002/chin.199811042  0.569
2010 CALTER M, HOLLIS TK, OVERMAN LE, ZILLER J, ZIPP GG. ChemInform Abstract: First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 28: no-no. DOI: 10.1002/chin.199728055  0.779
2010 HOLLIS TK, ROBINSON NP, BOSNICH B. ChemInform Abstract: Homogeneous Catalysis. (Ti(Cp)2(CF3SO3)2) and (Zr(Cp)2(CF3SO3)2THF), Efficient Catalysts for the Diels-Alder Reaction. Cheminform. 23: no-no. DOI: 10.1002/chin.199247073  0.375
2010 HOLLIS TK, ROBINSON NP, BOSNICH B. ChemInform Abstract: Homogeneous Catalysis. (Ti(Cp*)2(H2O)2)2+: An Air-Stable, Water- Tolerant Diels-Alder Catalyst. Cheminform. 23: no-no. DOI: 10.1002/chin.199241109  0.592
2008 Cho J, Hollis TK, Helgert TR, Valente EJ. An improved method for the synthesis of zirconium (CCC-N-heterocyclic carbene) pincer complexes and applications in hydroamination. Chemical Communications (Cambridge, England). 5001-3. PMID 18931766 DOI: 10.1039/B805174G  0.543
2008 Bauer EB, Andavan GT, Hollis TK, Rubio RJ, Cho J, Kuchenbeiser GR, Helgert TR, Letko CS, Tham FS. Air- and water-stable catalysts for hydroamination/cyclization. Synthesis and application of CCC-NHC pincer complexes of Rh and Ir. Organic Letters. 10: 1175-8. PMID 18293992 DOI: 10.1021/Ol8000766  0.774
2008 Cho J, Hollis TK, Helgert TR, Valente EJ. An improved method for the synthesis of zirconium (CCC-N-heterocyclic carbene) pincer complexes and applications in hydroamination Chemical Communications. 5001-5003. DOI: 10.1039/b805174g  0.355
2008 Freeman WP, Ahn YJ, Hollis TK, Whitaker JA, Vargas VC, Rubio RJ, Alingog KD, Bauer EB, Tham FS. Isomerization in bent phosphametallocenes: Combining rotational barriers and the intramolecular slip-inversion-slip mechanism to control stereo-conformation Journal of Organometallic Chemistry. 693: 2415-2423. DOI: 10.1016/J.Jorganchem.2008.04.021  0.667
2006 Ravindran S, Andavan GT, Tsai C, Ozkan CS, Hollis TK. Perforated organometallic nanotubes prepared from a Rh N-heterocyclic carbene using a porous alumina membrane. Chemical Communications (Cambridge, England). 1616-8. PMID 16582997 DOI: 10.1039/B515332H  0.365
2006 Ahn YJ, Rubio RJ, Hollis TK, Tham FS, Donnadieu B. Slip - Inversion - Slip mechanism of phosphametallocene isomerization. Spectroscopic characterization of an (η 1-phospholyl)titanium complex. Synthesis and structures of chiral mono(phospholyl)titanium complexes Organometallics. 25: 1079-1083. DOI: 10.1021/Om050357H  0.542
2005 Andavan GTS, Bauer EB, Letko CS, Hollis TK, Tham FS. Synthesis and characterization of a free phenylene bis(N-heterocyclic carbene) and its di-Rh complex: Catalytic activity of the di-Rh and CCC-NHC Rh pincer complexes in intermolecular hydrosilylation of alkynes Journal of Organometallic Chemistry. 690: 5938-5947. DOI: 10.1016/J.Jorganchem.2005.07.088  0.802
2005 Rubio RJ, Andavan GTS, Bauer EB, Hollis TK, Cho J, Tham FS, Donnadieu B. Toward a general method for CCC N-heterocyclic carbene pincer synthesis: Metallation and transmetallation strategies for concurrent activation of three C-H bonds Journal of Organometallic Chemistry. 690: 5353-5364. DOI: 10.1016/J.Jorganchem.2005.05.007  0.76
2003 Vargas VC, Rubio RJ, Hollis TK, Salcido ME. Efficient route to 1,3-Di-N-imidazolylbenzene. A comparison of monodentate vs bidentate carbenes in Pd-catalyzed cross coupling. Organic Letters. 5: 4847-9. PMID 14653689 DOI: 10.1021/Ol035906Z  0.366
2003 Wang LS, Hollis TK. Demonstration of a phosphazirconocene as a catalyst for the ring opening of epoxides with TMSCl. Organic Letters. 5: 2543-5. PMID 12841776 DOI: 10.1021/Ol034816R  0.485
2003 Hollis TK, Ahn YJ, Tham FS. Low-valent titanium bis(phospholyl) chemistry: A configurationally stable chiral phosphatitanocene Organometallics. 22: 1432-1436. DOI: 10.1021/Om020961H  0.48
2000 Hollis TK, Wang LS, Tham F. Dynamic resolution of a metallocene: Diastereoselective assembly of an early-late heterobimetallic metal-bridged ansa-metallocene opening a route to parallel catalyst synthesis [7] Journal of the American Chemical Society. 122: 11737-11738. DOI: 10.1021/Ja002411L  0.425
1997 Calter M, Hollis TK, Overman LE, Ziller J, Zipp GG. First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides Journal of Organic Chemistry. 62: 1449-1456. DOI: 10.1021/Jo962090P  0.798
1997 Hollis TK, Overman LE. Cyclopalladated ferrocenyl amines as enantioselective catalysts for the rearrangement of allylic imidates to allylic amides Tetrahedron Letters. 38: 8837-8840. DOI: 10.1016/S0040-4039(97)10385-9  0.652
1995 Doman TN, Hollis TK, Bosnich B. Molecular mechanics force fields for bent metallocenes of the type [M(Cp)2Cl2] Journal of the American Chemical Society. 117: 1352-1368. DOI: 10.1021/Ja00109A020  0.515
1995 Hollis TK, Bosnich B. Homogeneous catalysis. Mechanisms of the catalytic mukaiyama aldol and sakurai allylation reactions Journal of the American Chemical Society. 117: 4570-4581.  0.583
1993 Ellis WW, Hollis TK, Odenkirk W, Whelan J, Ostrander R, Rheingold AL, Bosnich B. Synthesis, structure, and properties of chiral titanium and zirconium complexes bearing biaryl strapped substituted cyclopentadienyl ligands Organometallics. 12: 4391-4401. DOI: 10.1021/om00035a026  0.423
1993 Hollis TK, Robinson NP, Whelan J, Bosnich B. Homogeneous catalysis. Use of the [TiCp2(CF3SO3)2] catalyst for the sakurai reaction of allylic silanes with orthoesters, acetals, ketals and carbonyl compounds. Tetrahedron Letters. 34: 4309-4312. DOI: 10.1016/S0040-4039(00)79336-1  0.671
1992 Hollis TK, Rheingold AL, Robinson NP, Whelan J, Bosnich B. Preparation and properties of (S,S)-[Ti((R,R)-cyclacene)Cl2], a chiral strapped bent metallocene Organometallics. 11: 2812-2816. DOI: 10.1021/Om00044A020  0.544
1992 Hollis TK, Robinson NP, Bosnich B. Homogeneous catalysis. Titanium complex [Ti(Cp)2(CF3SO3)2] and zirconium complex [Zr(Cp)2(CF3SO3)2THF], efficient catalysts for the Diels-Alder reaction Organometallics. 11: 2745-2748. DOI: 10.1021/Om00044A004  0.726
1992 Hollis TK, Robinson NP, Bosnich B. Homogeneous catalysis. [Ti(Cp*)2(H2O)2]2+: An air-stable, water-tolerant diels-alder catalyst Journal of the American Chemical Society. 114: 5464-5466. DOI: 10.1021/Ja00039A090  0.62
1992 Hollis TK, Robinson NP, Bosnich B. Homogeneous catalysis. [TiCp2(CF3SO3)2] and [ZrCp2(CF3SO3)2THF], fast and efficient catalysts for the Mukaiyama cross-aldol reaction Tetrahedron Letters. 33: 6423-6426. DOI: 10.1016/S0040-4039(00)79005-8  0.672
1992 Hollis TK, Robinson NP, Bosnich B. Homogeneous catalysis. [Ti(Cp)2(CF3SO3)2] and [Zr(Cp)2(CF3SO3)2THF], efficient catalysts for the Diels-Alder reaction Organometallics. 11: 2745-2748.  0.624
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