Leonid Sheps, Ph.D. - Publications

Affiliations: 
2005 University of Wisconsin, Madison, Madison, WI 
Area:
chemical reaction dynamics

39 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Demireva M, Au K, Hansen N, Sheps L. Time-resolved quantification of key species and mechanistic insights in low-temperature tetrahydrofuran oxidation. Physical Chemistry Chemical Physics : Pccp. 26: 10357-10368. PMID 38502092 DOI: 10.1039/d3cp06227a  0.3
2023 Cho J, Rösch D, Tao Y, Osborn DL, Klippenstein SJ, Sheps L, Sivaramakrishnan R. Modeling-Experiment-Theory Analysis of Reactions Initiated from Cl + Methyl Formate. The Journal of Physical Chemistry. A. PMID 37937747 DOI: 10.1021/acs.jpca.3c05085  0.38
2023 Zou M, Liu T, Vansco MF, Sojdak CA, Markus CR, Almeida R, Au K, Sheps L, Osborn DL, Winiberg FAF, Percival CJ, Taatjes CA, Klippenstein SJ, Lester MI, Caravan RL. Bimolecular Reaction of Methyl-Ethyl-Substituted Criegee Intermediate with SO. The Journal of Physical Chemistry. A. PMID 37870411 DOI: 10.1021/acs.jpca.3c04648  0.334
2023 Liu T, Elliott SN, Zou M, Vansco MF, Sojdak CA, Markus CR, Almeida R, Au K, Sheps L, Osborn DL, Winiberg FAF, Percival CJ, Taatjes CA, Caravan RL, Klippenstein SJ, et al. OH Roaming and Beyond in the Unimolecular Decay of the Methyl-Ethyl-Substituted Criegee Intermediate: Observations and Predictions. Journal of the American Chemical Society. PMID 37623926 DOI: 10.1021/jacs.3c07126  0.332
2022 Couch DE, Mulvihill CR, Sivaramakrishnan R, Au K, Taatjes CA, Sheps L. Quantification of Key Peroxy and Hydroperoxide Intermediates in the Low-Temperature Oxidation of Dimethyl Ether. The Journal of Physical Chemistry. A. PMID 36480708 DOI: 10.1021/acs.jpca.2c06959  0.327
2022 Robinson C, Onel L, Newman J, Lade R, Au K, Sheps L, Heard DE, Seakins PW, Blitz MA, Stone D. Unimolecular Kinetics of Stabilized CHCHOO Criegee Intermediates: -CHCHOO Decomposition and -CHCHOO Isomerization. The Journal of Physical Chemistry. A. 126: 6984-6994. PMID 36146923 DOI: 10.1021/acs.jpca.2c05461  0.309
2020 Caravan RL, Vansco MF, Au K, Khan MAH, Li YL, Winiberg FAF, Zuraski K, Lin YH, Chao W, Trongsiriwat N, Walsh PJ, Osborn DL, Percival CJ, Lin JJ, Shallcross DE, ... Sheps L, et al. Direct kinetic measurements and theoretical predictions of an isoprene-derived Criegee intermediate. Proceedings of the National Academy of Sciences of the United States of America. PMID 32321826 DOI: 10.1073/Pnas.1916711117  0.425
2019 Sheps L, Antonov IO, Au K. A Sensitive Mass Spectrometer for Time-Resolved Gas-Phase Chemistry Studies at High Pressures. The Journal of Physical Chemistry. A. PMID 31710494 DOI: 10.1021/Acs.Jpca.9B08393  0.375
2019 Antonov I, Voronova K, Chen MW, Sztáray B, Hemberger P, Bodi A, Osborn DL, Sheps L. To Boldly Look Where No One Has Looked Before: Identifying the Primary Photoproducts of Acetylacetone. The Journal of Physical Chemistry. A. PMID 31241939 DOI: 10.1021/Acs.Jpca.9B04640  0.434
2019 Davis JC, Koritzke AL, Caravan RL, Antonov IO, Christianson MG, Doner AC, Osborn DL, Sheps L, Taatjes CA, Rotavera B. Influence of Ether Functional Group on Ketohydroperoxide Formation in Cyclic Hydrocarbons: Tetrahydropyran and Cyclohexane. The Journal of Physical Chemistry. A. PMID 30865470 DOI: 10.1021/Acs.Jpca.8B12510  0.441
2018 Caravan RL, Khan MAH, Zádor J, Sheps L, Antonov IO, Rotavera B, Ramasesha K, Au K, Chen MW, Rösch D, Osborn DL, Fittschen C, Schoemaecker C, Duncianu M, Grira A, et al. The reaction of hydroxyl and methylperoxy radicals is not a major source of atmospheric methanol. Nature Communications. 9: 4343. PMID 30341291 DOI: 10.1038/S41467-018-06716-X  0.46
2018 Stone D, Au K, Sime S, Medeiros DJ, Blitz M, Seakins PW, Decker Z, Sheps L. Unimolecular decomposition kinetics of the stabilised Criegee intermediates CHOO and CDOO. Physical Chemistry Chemical Physics : Pccp. PMID 30238099 DOI: 10.1039/C8Cp05332D  0.366
2017 Sheps L, Rotavera B, Eskola AJ, Osborn DL, Taatjes CA, Au K, Shallcross DE, Khan MAH, Percival CJ. The reaction of Criegee intermediate CH2OO with water dimer: primary products and atmospheric impact. Physical Chemistry Chemical Physics : Pccp. PMID 28805226 DOI: 10.1039/C7Cp03265J  0.415
2017 Eskola AJ, Antonov IO, Sheps L, Savee JD, Osborn DL, Taatjes CA. Time-resolved measurements of product formation in the low-temperature (550-675 K) oxidation of neopentane: a probe to investigate chain-branching mechanism. Physical Chemistry Chemical Physics : Pccp. PMID 28503692 DOI: 10.1039/C7Cp01366C  0.427
2017 Decker ZC, Au K, Vereecken L, Sheps L. Direct experimental probing and theoretical analysis of the reaction between the simplest Criegee intermediate CH2OO and isoprene. Physical Chemistry Chemical Physics : Pccp. PMID 28288212 DOI: 10.1039/C6Cp08602K  0.483
2017 Assaf E, Sheps L, Whalley LK, Heard DE, Tomas A, Schoemaecker C, Fittschen C. The Reaction between CH3O2 and OH Radicals: Product Yields and Atmospheric Implications. Environmental Science & Technology. PMID 28121426 DOI: 10.1021/Acs.Est.6B06265  0.448
2016 Scheer AM, Eskola AJ, Osborn DL, Sheps L, Taatjes CA. Resonance Stabilization Effects on Ketone Autoxidation: Isomer-Specific Cyclic Ether and Ketohydroperoxide Formation in the Low-Temperature (400 - 625 K) Oxidation of Diethyl Ketone. The Journal of Physical Chemistry. A. PMID 27726367 DOI: 10.1021/Acs.Jpca.6B07370  0.398
2016 Antonov IO, Zádor J, Rotavera B, Papajak E, Osborn DL, Taatjes CA, Sheps L. Pressure-Dependent Competition among Reaction Pathways from First- and Second-O2 Additions in the Low-Temperature Oxidation of Tetrahydrofuran. The Journal of Physical Chemistry. A. PMID 27441526 DOI: 10.1021/Acs.Jpca.6B05411  0.413
2015 Burke MP, Goldsmith CF, Klippenstein SJ, Welz O, Huang H, Antonov IO, Savee JD, Osborn DL, Zádor J, Taatjes CA, Sheps L. Multiscale Informatics for Low-Temperature Propane Oxidation: Further Complexities in Studies of Complex Reactions. The Journal of Physical Chemistry. A. PMID 25946172 DOI: 10.1021/Acs.Jpca.5B01003  0.4
2015 Welz O, Burke MP, Antonov IO, Goldsmith CF, Savee JD, Osborn DL, Taatjes CA, Klippenstein SJ, Sheps L. New Insights into Low-Temperature Oxidation of Propane from Synchrotron Photoionization Mass Spectrometry and Multiscale Informatics Modeling. The Journal of Physical Chemistry. A. 119: 7116-29. PMID 25860187 DOI: 10.1021/Acs.Jpca.5B01008  0.45
2015 Antonov IO, Kwok J, Zádor J, Sheps L. A Combined Experimental and Theoretical Study of the Reaction OH + 2-Butene in the 400-800 K Temperature Range. The Journal of Physical Chemistry. A. 119: 7742-52. PMID 25860092 DOI: 10.1021/Acs.Jpca.5B01012  0.435
2015 Savee JD, Papajak E, Rotavera B, Huang H, Eskola AJ, Welz O, Sheps L, Taatjes CA, Zádor J, Osborn DL. Carbon radicals. Direct observation and kinetics of a hydroperoxyalkyl radical (QOOH). Science (New York, N.Y.). 347: 643-6. PMID 25657245 DOI: 10.1126/Science.Aaa1495  0.393
2014 Sheps L, Scully AM, Au K. UV absorption probing of the conformer-dependent reactivity of a Criegee intermediate CH3CHOO. Physical Chemistry Chemical Physics : Pccp. 16: 26701-6. PMID 25372899 DOI: 10.1039/C4Cp04408H  0.394
2014 Rotavera B, Zádor J, Welz O, Sheps L, Scheer AM, Savee JD, Akbar Ali M, Lee TS, Simmons BA, Osborn DL, Violi A, Taatjes CA. Photoionization mass spectrometric measurements of initial reaction pathways in low-temperature oxidation of 2,5-dimethylhexane. The Journal of Physical Chemistry. A. 118: 10188-200. PMID 25234586 DOI: 10.1021/Jp507811D  0.485
2014 Osborn DL, Vogelhuber KM, Wren SW, Miller EM, Lu YJ, Case AS, Sheps L, McMahon RJ, Stanton JF, Harding LB, Ruscic B, Lineberger WC. Electronic states of the quasilinear molecule propargylene (HCCCH) from negative ion photoelectron spectroscopy. Journal of the American Chemical Society. 136: 10361-72. PMID 25009990 DOI: 10.1021/Ja5039984  0.656
2014 Welz O, Eskola AJ, Sheps L, Rotavera B, Savee JD, Scheer AM, Osborn DL, Lowe D, Murray Booth A, Xiao P, Anwar H Khan M, Percival CJ, Shallcross DE, Taatjes CA. Rate coefficients of C(1) and C(2) Criegee intermediate reactions with formic and acetic Acid near the collision limit: direct kinetics measurements and atmospheric implications. Angewandte Chemie (International Ed. in English). 53: 4547-50. PMID 24668781 DOI: 10.1002/Anie.201400964  0.369
2013 Sheps L. Absolute Ultraviolet Absorption Spectrum of a Criegee Intermediate CH2OO. The Journal of Physical Chemistry Letters. 4: 4201-5. PMID 26296165 DOI: 10.1021/Jz402191W  0.451
2013 Welz O, Zádor J, Savee JD, Sheps L, Osborn DL, Taatjes CA. Low-temperature combustion chemistry of n-butanol: principal oxidation pathways of hydroxybutyl radicals. The Journal of Physical Chemistry. A. 117: 11983-2001. PMID 23808372 DOI: 10.1021/Jp403792T  0.465
2012 Wren SW, Vogelhuber KM, Garver JM, Kato S, Sheps L, Bierbaum VM, Lineberger WC. C-H bond strengths and acidities in aromatic systems: effects of nitrogen incorporation in mono-, di-, and triazines. Journal of the American Chemical Society. 134: 6584-95. PMID 22468558 DOI: 10.1021/Ja209566Q  0.337
2012 Miller EM, Sheps L, Lu YJ, Case AS, McCoy AB, Lineberger WC. New view of the ICN A continuum using photoelectron spectroscopy of ICN-. The Journal of Chemical Physics. 136: 044313. PMID 22299877 DOI: 10.1063/1.3679170  0.694
2012 Case AS, Miller EM, Martin JP, Lu YJ, Sheps L, McCoy AB, Lineberger WC. Dynamic mapping of CN rotation following photoexcitation of ICN-. Angewandte Chemie (International Ed. in English). 51: 2651-3. PMID 22298354 DOI: 10.1002/Anie.201108025  0.681
2012 Welz O, Zádor J, Savee JD, Ng MY, Meloni G, Fernandes RX, Sheps L, Simmons BA, Lee TS, Osborn DL, Taatjes CA. Low-temperature combustion chemistry of biofuels: pathways in the initial low-temperature (550 K-750 K) oxidation chemistry of isopentanol. Physical Chemistry Chemical Physics : Pccp. 14: 3112-27. PMID 22286869 DOI: 10.1039/C2Cp23248K  0.379
2011 Sheps L, Miller EM, Horvath S, Thompson MA, Parson R, McCoy AB, Lineberger WC. Solvent-mediated charge redistribution in photodissociation of IBr(-) and IBr(-)(CO2). The Journal of Chemical Physics. 134: 184311. PMID 21568510 DOI: 10.1063/1.3584203  0.473
2011 Vogelhuber KM, Wren SW, Sheps L, Lineberger WC. The C-H bond dissociation energy of furan: photoelectron spectroscopy of the furanide anion. The Journal of Chemical Physics. 134: 064302. PMID 21322675 DOI: 10.1063/1.3548873  0.481
2010 Sheps L, Miller EM, Horvath S, Thompson MA, Parson R, McCoy AB, Lineberger WC. Solvent-mediated electron hopping: long-range charge transfer in IBr-(CO2) photodissociation. Science (New York, N.Y.). 328: 220-4. PMID 20203015 DOI: 10.1126/Science.1184616  0.432
2009 Sheps L, Miller EM, Lineberger WC. Photoelectron spectroscopy of small IBr-(CO2)n (n=0-3) cluster anions. The Journal of Chemical Physics. 131: 064304. PMID 19691385 DOI: 10.1063/1.3200941  0.39
2006 Sheps L, Crowther AC, Carrier SL, Crim FF. Time-resolved spectroscopic study of the reaction Cl + n-C5H12 --> HCl + C5H11 in solution. The Journal of Physical Chemistry. A. 110: 3087-92. PMID 16509630 DOI: 10.1021/Jp0543835  0.638
2005 Sheps L, Crowther AC, Elles CG, Crim FF. Recombination dynamics and hydrogen abstraction reactions of chlorine radicals in solution. The Journal of Physical Chemistry. A. 109: 4296-302. PMID 16833759 DOI: 10.1021/Jp051072L  0.722
2002 Heckscher MM, Sheps L, Bingemann D, Crim FF. Relaxation of the C-H stretching fundamental vibrations of CHI3, CH2I2, and CH3I in solution Journal of Chemical Physics. 117: 8917-8925. DOI: 10.1063/1.1510668  0.673
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