Year |
Citation |
Score |
2017 |
Algera RF, Gupta L, Hoepker AC, Liang J, Ma Y, Singh KJ, Collum DB. Lithium Diisopropylamide: Nonequilibrium Kinetics and Lessons Learned about Rate Limitation. The Journal of Organic Chemistry. PMID 28368117 DOI: 10.1021/Acs.Joc.6B03083 |
0.752 |
|
2014 |
Liang J, Hoepker AC, Bruneau AM, Ma Y, Gupta L, Collum DB. Lithium diisopropylamide-mediated lithiation of 1,4-difluorobenzene under nonequilibrium conditions: role of monomer-, dimer-, and tetramer-based intermediates and lessons about rate limitation. The Journal of Organic Chemistry. 79: 11885-902. PMID 25000303 DOI: 10.1021/Jo501392R |
0.75 |
|
2013 |
Gupta L, Hoepker AC, Ma Y, Viciu MS, Faggin MF, Collum DB. Lithium diisopropylamide-mediated ortholithiation of 2-fluoropyridines: rates, mechanisms, and the role of autocatalysis. The Journal of Organic Chemistry. 78: 4214-30. PMID 23270408 DOI: 10.1021/Jo302408R |
0.76 |
|
2011 |
Hoepker AC, Gupta L, Ma Y, Faggin MF, Collum DB. Regioselective lithium diisopropylamide-mediated ortholithiation of 1-chloro-3-(trifluoromethyl)benzene: role of autocatalysis, lithium chloride catalysis, and reversibility. Journal of the American Chemical Society. 133: 7135-51. PMID 21500823 DOI: 10.1021/Ja200906Z |
0.737 |
|
2010 |
Gupta L, Ramírez A, Collum DB. Reaction of lithium diethylamide with an alkyl bromide and alkyl benzenesulfonate: origins of alkylation, elimination, and sulfonation. The Journal of Organic Chemistry. 75: 8392-9. PMID 21077695 DOI: 10.1021/Jo101505X |
0.633 |
|
2010 |
Ma Y, Hoepker AC, Gupta L, Faggin MF, Collum DB. 1,4-addition of lithium diisopropylamide to unsaturated esters: role of rate-limiting deaggregation, autocatalysis, lithium chloride catalysis, and other mixed aggregation effects. Journal of the American Chemical Society. 132: 15610-23. PMID 20961095 DOI: 10.1021/Ja105855V |
0.767 |
|
2010 |
Viciu MS, Gupta L, Collum DB. Mechanism of lithium diisopropylamide-mediated substitution of 2,6-difluoropyridine. Journal of the American Chemical Society. 132: 6361-5. PMID 20397635 DOI: 10.1021/Ja910834B |
0.622 |
|
2009 |
Gupta L, Hoepker AC, Singh KJ, Collum DB. Lithium diisopropylamide-mediated ortholithiations: lithium chloride catalysis. The Journal of Organic Chemistry. 74: 2231-3. PMID 19191711 DOI: 10.1021/Jo802713Y |
0.733 |
|
2007 |
Chadwick ST, Ramirez A, Gupta L, Collum DB. n-Butyllithium/N,N,N',N'-tetramethylethylenediamine-mediated ortholithiations of aryl oxazolines: substrate-dependent mechanisms. Journal of the American Chemical Society. 129: 2259-68. PMID 17269777 DOI: 10.1021/Ja068057U |
0.567 |
|
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