Igor V. Alabugin - Publications

Affiliations: 
Florida State University, Tallahassee, FL, United States 
Area:
Organic Chemistry, Biochemistry

149 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Kos M, Žádný J, Storch J, Církva V, Cuřínová P, Sýkora J, Císařová I, Kuriakose F, Alabugin IV. Oxidative Photocyclization of Aromatic Schiff Bases in Synthesis of Phenanthridines and Other Aza-PAHs. International Journal of Molecular Sciences. 21. PMID 32824231 DOI: 10.3390/ijms21165868  0.44
2020 Kawade RK, Hu C, Dos Santos NR, Watson N, Lin X, Hanson K, Alabugin I. "Phenalenannulations: Three-Point Double Annulation Reactions that Convert Benzenes into Pyrenes". Angewandte Chemie (International Ed. in English). PMID 32495480 DOI: 10.1002/anie.202006087  0.32
2020 Gonzalez-Rodriguez E, Abdo MA, Dos Passos Gomes G, Ayad S, White FD, Tsvetkov NP, Hanson K, Alabugin I. Twofold π-Extension of Polyarenes via Double and Triple Radical Alkyne peri-Annulations: Radical Cascades Converging on the Same Aromatic Core. Journal of the American Chemical Society. PMID 32249571 DOI: 10.1021/jacs.0c01856  1
2019 Zhou Z, Kawade RK, Wei Z, Kuriakose F, Üngör Ö, Jo M, Shatruk M, Gershoni-Poranne R, Petrukhina MA, Alabugin I. Negative charge as a lens for concentrating antiaromatiicty in twisted polyaromatics: taking advantage of a pentagonal "defect" and helicene strain for reductive annulation. Angewandte Chemie (International Ed. in English). PMID 31715065 DOI: 10.1002/anie.201911319  0.44
2019 Vil' VA, Barsegyan YA, Barsukov DV, Korlyukov AA, Alabugin IV, Terent'ev AO. Peroxycarbenium Ions as the "Gatekeepers" in Reaction Design: Assistance from Inverse Alpha-Effect in Three-Component β-Alkoxy-β-peroxylactones Synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31487079 DOI: 10.1002/chem.201903752  0.32
2019 Dos Passos Gomes G, Wimmer A, Smith JM, König B, Alabugin IV. CO or SO: Should It Stay, or Should It Go? The Journal of Organic Chemistry. PMID 30993995 DOI: 10.1021/acs.joc.9b00503  1
2019 Alabugin IV, Gonzalez-Rodriguez E, Kawade RK, Stepanov AA, Vasilevsky SF. Alkynes as Synthetic Equivalents of Ketones and Aldehydes: A Hidden Entry into Carbonyl Chemistry. Molecules (Basel, Switzerland). 24. PMID 30875972 DOI: 10.3390/molecules24061036  0.64
2019 Hughes AM, Dos Passos Gomes G, Alabugin IV. Stereoelectronic Influence of a "Spectator" Propargylic Substituent Can Override Aromaticity Effects in Radical Peri-cyclizations on Route to Expanded Polyaromatics. The Journal of Organic Chemistry. PMID 30701976 DOI: 10.1021/acs.joc.8b02779  1
2018 Vil' VA, Gomes GDP, Ekimova MV, Lyssenko KA, Syroeshkin MA, Nikishin GI, Alabugin IV, Terent'ev AO. Five Roads That Converge at the Cyclic Peroxy-Criegee Intermediates: BF-Catalyzed Synthesis of β-Hydroperoxy-β-peroxylactones. The Journal of Organic Chemistry. PMID 30351948 DOI: 10.1021/acs.joc.8b02218  0.44
2018 Gomes GDP, Loginova Y, Vatsadze SZ, Alabugin IV. Isonitriles as Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy in Radical Additions. Journal of the American Chemical Society. PMID 30270623 DOI: 10.1021/jacs.8b08513  1
2018 Syroeshkin MA, Kuriakose F, Saverina EA, Timofeeva VA, Egorov MP, Alabugin IV. Upconversion of Reductants. Angewandte Chemie (International Ed. in English). PMID 30063285 DOI: 10.1002/anie.201807247  0.44
2018 Alabugin IV, Gonzalez-Rodriguez E. Alkyne Origami: Folding Oligoalkynes into Polyaromatics. Accounts of Chemical Research. PMID 29676896 DOI: 10.1021/acs.accounts.8b00026  0.44
2018 Yaremenko IA, Gomes GDP, Radulov PS, Belyakova YY, Vilikotskiy AE, Vil' VA, Korlyukov AA, Nikishin GI, Alabugin IV, Terent'ev AO. Ozone-free synthesis of ozonides: Assembling bicyclic structures from 1,5-diketones and hydrogen peroxide. The Journal of Organic Chemistry. PMID 29533620 DOI: 10.1021/acs.joc.8b00130  0.44
2018 Tsvetkov N, Gonzalez-Rodriguez E, Hughes A, Dos Passos Gomes G, White FD, Kuriakose F, Alabugin I. Radical Alkyne Peri-annulations for Synthesis of Functionalized Phenalenes, Benzanthrenes, and Olympicene. Angewandte Chemie (International Ed. in English). PMID 29405588 DOI: 10.1002/anie.201712783  1
2018 Vil' VA, Dos Passos Gomes G, Bityukov OV, Lyssenko KA, Nikishin GI, Alabugin IV, Terent'ev AO. Interrupted Baeyer-Villiger Rearrangement: Building A Stereoelectronic Trap for the Criegee Intermediate. Angewandte Chemie (International Ed. in English). PMID 29385307 DOI: 10.1002/anie.201712651  1
2017 Park NH, Gomes GDP, Fevre M, Jones GO, Alabugin IV, Hedrick JL. Erratum: Organocatalyzed synthesis of fluorinated poly(aryl thioethers). Nature Communications. 8: 1553. PMID 29133869 DOI: 10.1038/s41467-017-01129-8  0.44
2017 Sedenkova KN, Averina EB, Grishin YK, Kolodyazhnaya JV, Rybakov VB, Kuznetsova TS, Hughes A, Gomes GDP, Alabugin IV, Zefirov NS. Substituent effects on stereoselectivity of dihalocarbene reactions with cyclohexadiene and on the reactivity of bis-dihalocyclopropanes in electrophilic nitrations en route to pyrimidine N-oxides. Organic & Biomolecular Chemistry. PMID 29095467 DOI: 10.1039/c7ob02463k  0.76
2017 Evoniuk CJ, Gomes GDP, Hill SP, Satoshi F, Hanson K, Alabugin IV. Coupling N-H deprotonation, C-H activation and oxidation: metal-free C(sp3)-H aminations with unprotected anilines. Journal of the American Chemical Society. PMID 29037029 DOI: 10.1021/jacs.7b07519  0.44
2017 Park NH, Gomes GDP, Fevre M, Jones GO, Alabugin IV, Hedrick JL. Organocatalyzed synthesis of fluorinated poly(aryl thioethers). Nature Communications. 8: 166. PMID 28761127 DOI: 10.1038/s41467-017-00186-3  0.44
2017 Juaristi E, Gomes GDP, Terent'ev AO, Notario R, Alabugin IV. Stereoelectronic Interactions as a Probe for the Existence of the Intramolecular α-Effect. Journal of the American Chemical Society. PMID 28701041 DOI: 10.1021/jacs.7b05367  0.44
2017 Gomes GD, Evoniuk CJ, Ly M, Alabugin IV. Changing the path of least resistance, or access to endo-dig products via a sequence of three exo-trig transition states: electronic effects in homoallyic ring expansion cascades of alkenyl isonitriles. Organic & Biomolecular Chemistry. PMID 28398443 DOI: 10.1039/c7ob00527j  0.32
2017 Dos Passos Gomes G, Yaremenko IA, Radulov PS, Novikov RA, Chernyshev VV, Korlyukov AA, Nikishin GI, Alabugin IV, Terent'ev AO. Stereoelectronic Control in the Ozone-Free Synthesis of Ozonides. Angewandte Chemie (International Ed. in English). PMID 28378382 DOI: 10.1002/anie.201610699  1
2017 Evoniuk CJ, Gomes GD, Ly M, White FD, Alabugin IV. Coupling radical homoallylic expansions with C-C fragmentations for the synthesis of heteroaromatics: Quinolines from reactions of o-alkenylarylisonitriles with aryl, alkyl and perfluoroalkyl radicals. The Journal of Organic Chemistry. PMID 28357857 DOI: 10.1021/acs.joc.7b00262  0.44
2016 Umezu S, Dos Passos Gomes G, Yoshinaga T, Sakae M, Matsumoto K, Iwata T, Alabugin I, Shindo M. Regioselective One-Pot Synthesis of Triptycenes via Triple-Cycloadditions of Arynes to Ynolates. Angewandte Chemie (International Ed. in English). PMID 28029205 DOI: 10.1002/anie.201609111  1
2016 Peterson PW, Shevchenko N, Breiner B, Manoharan M, Lufti F, Delaune J, Kingsley M, Kovnir K, Alabugin IV. Orbital Crossings Activated through Electron Injection: Opening Communication between Orthogonal Orbitals in Anionic C1-C5 Cyclizations of Enediynes. Journal of the American Chemical Society. 138: 15617-15628. PMID 27934008 DOI: 10.1021/jacs.6b08540  0.84
2016 Vatsadze SZ, Loginova YD, Dos Passos Gomes G, Alabugin IV. Stereoelectronic Chameleons: The Donor-Acceptor Dichotomy of Functional Groups. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27862399 DOI: 10.1002/chem.201603491  1
2016 Mohamed RK, Mondal S, Guerrera JV, Eaton TM, Albrecht-Schmitt TE, Shatruk M, Alabugin IV. Alkynes as Linchpins for the Additive Annulation of Biphenyls: Convergent Construction of Functionalized Fused Helicenes. Angewandte Chemie (International Ed. in English). PMID 27535022 DOI: 10.1002/anie.201606330  1
2016 Pati K, Dos Passos Gomes G, Alabugin IV. Combining Traceless Directing Groups with Hybridization Control of Radical Reactivity: From Skipped Enynes to Defect-Free Hexagonal Frameworks. Angewandte Chemie (International Ed. in English). PMID 27534837 DOI: 10.1002/anie.201605799  1
2016 Kaya K, Roy S, Nogues JC, Rojas JC, Sokolikj Z, Zorio DA, Alabugin IV. Optimizing Protonation States for Selective Double Strand DNA Photocleavage in Hypoxic Tumors: pH-Gated Transitions of Lysine Dipeptides. Journal of Medicinal Chemistry. PMID 27526786 DOI: 10.1021/acs.jmedchem.6b01164  1
2016 Harris T, Gomes GD, Clark RJ, Alabugin IV. Domino Fragmentations in Traceless Directing Groups of Radical Cascades: Evidence for the Formation of Alkoxy Radicals via C-O Scission. The Journal of Organic Chemistry. PMID 27304982 DOI: 10.1021/acs.joc.6b01052  1
2016 Evoniuk CJ, Hill SP, Hanson K, Alabugin IV. Double C-H amination by consecutive SET oxidations. Chemical Communications (Cambridge, England). PMID 27170275 DOI: 10.1039/c6cc03106d  1
2016 Pati K, Gomes Gdos P, Harris T, Alabugin IV. Fused Catechol Ethers from Gold(I)-Catalyzed Intramolecular Reaction of Propargyl Ethers with Acetals. Organic Letters. 18: 928-31. PMID 26886747 DOI: 10.1021/acs.orglett.5b03522  1
2016 Vidhani DV, Krafft ME, Alabugin IV. Gold(I)-catalyzed allenyl Cope rearrangement: evolution from asynchronicity to trappable intermediates assisted by stereoelectronic switching. Journal of the American Chemical Society. PMID 26850567 DOI: 10.1021/jacs.5b12920  1
2016 Pati K, Dos Passos Gomes G, Harris T, Alabugin IV. Fused Catechol Ethers from Gold(I)-Catalyzed Intramolecular Reaction of Propargyl Ethers with Acetals Organic Letters. 18: 928-931. DOI: 10.1021/acs.orglett.5b03522  1
2016 Bresch S, Wandell R, Wang H, Alabugin I, Locke BR. Oxidized Derivatives of n-Hexane from a Water/Argon Continuous Flow Electrical Discharge Plasma Reactor Plasma Chemistry and Plasma Processing. 36: 553-584. DOI: 10.1007/s11090-015-9686-x  1
2016 Gilmore K, Mohamed RK, Alabugin IV. The Baldwin rules: Revised and extended Wiley Interdisciplinary Reviews: Computational Molecular Science. DOI: 10.1002/wcms.1261  1
2015 Gomes GDP, Vil' V, Terent'ev A, Alabugin IV. Stereoelectronic source of the anomalous stability of bis-peroxides. Chemical Science. 6: 6783-6791. PMID 28757970 DOI: 10.1039/c5sc02402a  0.44
2015 Mohamed RK, Mondal S, Jorner K, Faria Delgado T, Lobodin VV, Ottosson H, Alabugin IV. The Missing C1-C5 Cycloaromatization Reaction: Triplet State Antiaromaticity Relief and Self-terminating Photorelease of Formal-dehyde for Synthesis of Fulvenes from Enynes. Journal of the American Chemical Society. PMID 26536479 DOI: 10.1021/jacs.5b07448  1
2015 Pati K, Michas C, Allenger D, Piskun I, Coutros PS, Gomes Gdos P, Alabugin IV. Synthesis of Functionalized Phenanthrenes via Regioselective Oxidative Radical Cyclization. The Journal of Organic Chemistry. 80: 11706-17. PMID 26248062 DOI: 10.1021/acs.joc.5b01014  1
2015 Evoniuk CJ, Ly M, Alabugin IV. Coupling cyclizations with fragmentations for the preparation of heteroaromatics: quinolines from o-alkenyl arylisocyanides and boronic acids. Chemical Communications (Cambridge, England). 51: 12831-4. PMID 26165765 DOI: 10.1039/c5cc04391c  1
2015 Mohamed RK, Mondal S, Gold B, Evoniuk CJ, Banerjee T, Hanson K, Alabugin IV. Alkenes as alkyne equivalents in radical cascades terminated by fragmentations: overcoming stereoelectronic restrictions on ring expansions for the preparation of expanded polyaromatics. Journal of the American Chemical Society. 137: 6335-49. PMID 25906261 DOI: 10.1021/jacs.5b02373  1
2015 Aldeek F, Hawkins D, Palomo V, Safi M, Palui G, Dawson PE, Alabugin I, Mattoussi H. UV and sunlight driven photoligation of quantum dots: understanding the photochemical transformation of the ligands. Journal of the American Chemical Society. 137: 2704-14. PMID 25612193 DOI: 10.1021/ja512802x  1
2015 Vasilevsky SF, Baranov DS, Mamatyuk VI, Fadeev DS, Gatilov YV, Stepanov AA, Vasilieva NV, Alabugin IV. Conformational flexibility of fused tetracenedione propellers obtained from one-pot reductive dimerization of acetylenic quinones. The Journal of Organic Chemistry. 80: 1618-31. PMID 25575160 DOI: 10.1021/jo502543b  1
2015 Kaya K, Johnson M, Alabugin IV. Opening Enediyne Scissors Wider: pH-Dependent DNA Photocleavage by meta-Diyne Lysine Conjugates. Photochemistry and Photobiology. 91: 748-58. PMID 25545396 DOI: 10.1111/php.12412  1
2015 Pati K, dos Passos Gomes G, Harris T, Hughes A, Phan H, Banerjee T, Hanson K, Alabugin IV. Traceless directing groups in radical cascades: from oligoalkynes to fused helicenes without tethered initiators. Journal of the American Chemical Society. 137: 1165-80. PMID 25539142 DOI: 10.1021/ja510563d  1
2015 Wandell RJ, Locke BR, Bresch S, Alabugin IV. Organic synthesis with continuous flow water film pulsed plasma discharge Icops/Beams 2014 - 41st Ieee International Conference On Plasma Science and the 20th International Conference On High-Power Particle Beams. DOI: 10.1109/PLASMA.2014.7012662  1
2015 Gomes GDP, Vil V, Terent'Ev A, Alabugin IV. Stereoelectronic source of the anomalous stability of bis-peroxides Chemical Science. 6: 6783-6791. DOI: 10.1039/c5sc02402a  1
2015 Vasilevsky SF, Davydova MP, Mamatuyk VI, Pleshkova NV, Fadeev DS, Alabugin IV. Reaction of α,β-alkynylketones with β-amino alcohols: Pseudoephedrine- assisted cleavage of triple bond via formal internal redox process Mendeleev Communications. 25: 377-379. DOI: 10.1016/j.mencom.2015.09.021  1
2015 Alabugin IV, Bresch S, Dos Passos Gomes G. Orbital hybridization: A key electronic factor in control of structure and reactivity Journal of Physical Organic Chemistry. 28: 147-162. DOI: 10.1002/poc.3382  1
2014 Mondal S, Gold B, Mohamed RK, Phan H, Alabugin IV. Rerouting radical cascades: intercepting the homoallyl ring expansion in enyne cyclizations via C-S scission. The Journal of Organic Chemistry. 79: 7491-501. PMID 25011054 DOI: 10.1021/jo5012043  1
2014 Gold B, Batsomboon P, Dudley GB, Alabugin IV. Alkynyl crown ethers as a scaffold for hyperconjugative assistance in noncatalyzed azide-alkyne click reactions: ion sensing through enhanced transition-state stabilization. The Journal of Organic Chemistry. 79: 6221-32. PMID 24927131 DOI: 10.1021/jo500958n  1
2014 Mondal S, Gold B, Mohamed RK, Alabugin IV. Design of leaving groups in radical C-C fragmentations: through-bond 2c-3e interactions in self-terminating radical cascades. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 8664-9. PMID 24898770 DOI: 10.1002/chem.201402843  1
2014 Alabugin IV, Bresch S, Manoharan M. Hybridization trends for main group elements and expanding the Bent's rule beyond carbon: more than electronegativity. The Journal of Physical Chemistry. A. 118: 3663-77. PMID 24773162 DOI: 10.1021/jp502472u  1
2014 Vidhani DV, Krafft ME, Alabugin IV. Rh(I)-catalyzed transformation of propargyl vinyl ethers into (E,Z)-dienals: stereoelectronic role of trans effect in a metal-mediated pericyclic process and a shift from homogeneous to heterogeneous catalysis during a one-pot reaction. The Journal of Organic Chemistry. 79: 352-64. PMID 24304338 DOI: 10.1021/jo402505f  1
2014 Pati K, Hughes AM, Phan H, Alabugin IV. Exo-dig radical cascades of skipped enediynes: building a naphthalene moiety within a polycyclic framework. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 390-3. PMID 24273130 DOI: 10.1002/chem.201304092  1
2014 Vasilevsky SF, Baranov DS, Govdi AI, Sorokina IV, Tolstikova TG, Tolstikov GA, Alabugin IV. Click chemistry on diterpenes: Anti-inflammatory activity of the acetylenic derivatives of levopimaric acid and products of their transformations Arkivoc. 2014: 145-157. DOI: 10.3998/ark.5550190.p008.471  1
2014 Wandell RJ, Bresch S, Hsieh K, Alabugin IV, Locke BR. Formation of alcohols and carbonyl compounds from hexane and cyclohexane with water in a liquid film plasma reactor Ieee Transactions On Plasma Science. 42: 1195-1205. DOI: 10.1109/TPS.2014.2304183  1
2014 Pati K, Alabugin IV. Synthesis of substituted biaryls through gold-catalyzed petasis-ferrier rearrangement of propargyl ethers European Journal of Organic Chemistry. 2014: 3986-3990. DOI: 10.1002/ejoc.201402469  1
2013 Mondal S, Mohamed RK, Manoharan M, Phan H, Alabugin IV. Drawing from a pool of radicals for the design of selective enyne cyclizations. Organic Letters. 15: 5650-3. PMID 24188522 DOI: 10.1021/ol4028072  1
2013 Alabugin IV, Gilmore K. Finding the right path: Baldwin "rules for ring closure" and stereoelectronic control of cyclizations. Chemical Communications (Cambridge, England). 49: 11246-50. PMID 24162562 DOI: 10.1039/c3cc43872d  1
2013 Vidhani DV, Krafft ME, Alabugin IV. Stereocontrolled synthesis of (E,Z)-dienals via tandem Rh(I)-catalyzed rearrangement of propargyl vinyl ethers. Organic Letters. 15: 4462-5. PMID 23968534 DOI: 10.1021/ol4019985  1
2013 Alabugin IV, Gold B. "Two functional groups in one package": using both alkyne Ï€-bonds in cascade transformations. The Journal of Organic Chemistry. 78: 7777-84. PMID 23829276 DOI: 10.1021/jo401091w  1
2013 Peterson PW, Shevchenko N, Alabugin IV. "Stereoelectronic umpolung": converting a p-donor into a σ-acceptor via electron injection and a conformational change. Organic Letters. 15: 2238-41. PMID 23639080 DOI: 10.1021/ol400813d  1
2013 Mohamed RK, Peterson PW, Alabugin IV. Concerted reactions that produce diradicals and zwitterions: electronic, steric, conformational, and kinetic control of cycloaromatization processes. Chemical Reviews. 113: 7089-129. PMID 23600723 DOI: 10.1021/cr4000682  1
2013 Shatruk M, Alabugin IV. Reinvestigation of "Single-crystal X-ray structure of 1,3-dimethylcyclobutadiene". Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 4942-5. PMID 23504714 DOI: 10.1002/chem.201103017  1
2013 Zhan N, Palui G, Grise H, Tang H, Alabugin I, Mattoussi H. Combining ligand design with photoligation to provide compact, colloidally stable, and easy to conjugate quantum dots. Acs Applied Materials & Interfaces. 5: 2861-9. PMID 23421991 DOI: 10.1021/am302788q  1
2013 Vidhani DV, Cran JW, Krafft ME, Alabugin IV. Overriding the alkynophilicity of gold: catalytic pathways from higher energy Au(I)-substrate complexes and reactant deactivation via unproductive complexation in the gold(I)-catalyzed propargyl Claisen rearrangement. Organic & Biomolecular Chemistry. 11: 1624-30. PMID 23307145 DOI: 10.1039/c2ob27231h  1
2013 Gold B, Dudley GB, Alabugin IV. Moderating strain without sacrificing reactivity: design of fast and tunable noncatalyzed alkyne-azide cycloadditions via stereoelectronically controlled transition state stabilization. Journal of the American Chemical Society. 135: 1558-69. PMID 23272641 DOI: 10.1021/ja3114196  1
2013 Vidhani DV, Cran JW, Krafft ME, Manoharan M, Alabugin IV. Gold(I)-catalyzed Claisen rearrangement of allenyl vinyl ethers: missing transition states revealed through evolution of aromaticity, Au(I) as an oxophilic Lewis acid, and lower energy barriers from a high energy complex. The Journal of Organic Chemistry. 78: 2059-73. PMID 23167800 DOI: 10.1021/jo302152j  1
2013 Baranov DS, Gold B, Vasilevsky SF, Alabugin IV. Divergent cyclizations of 1-R-ethynyl-9,10-anthraquinones: use of thiourea as a "S2-" equivalent in an "anchor-relay" addition mediated by formal C-H activation. The Journal of Organic Chemistry. 78: 2074-82. PMID 23163879 DOI: 10.1021/jo302146r  1
2013 Gilmore K, Gold B, Clark RJ, Alabugin IV. Convenient ambient temperature generation of sulfonyl radicals Australian Journal of Chemistry. 66: 336-340. DOI: 10.1071/CH12499  1
2013 Peterson PW, Mohamed RK, Alabugin IV. How to lose a bond in two ways - The diradical/zwitterion dichotomy in cycloaromatization reactions European Journal of Organic Chemistry. 2505-2527. DOI: 10.1002/ejoc.201201656  1
2012 Byers PM, Rashid JI, Mohamed RK, Alabugin IV. Polyaromatic ribbon/benzofuran fusion via consecutive endo cyclizations of enediynes. Organic Letters. 14: 6032-5. PMID 23190310 DOI: 10.1021/ol302922t  1
2012 Palui G, Avellini T, Zhan N, Pan F, Gray D, Alabugin I, Mattoussi H. Photoinduced phase transfer of luminescent quantum dots to polar and aqueous media. Journal of the American Chemical Society. 134: 16370-8. PMID 22938162 DOI: 10.1021/ja306621n  1
2012 Byers PM, Alabugin IV. Polyaromatic ribbons from oligo-alkynes via selective radical cascade: stitching aromatic rings with polyacetylene bridges. Journal of the American Chemical Society. 134: 9609-14. PMID 22616674 DOI: 10.1021/ja3023626  1
2012 Gilmore K, Manoharan M, Wu JI, Schleyer Pv, Alabugin IV. Aromatic transition states in nonpericyclic reactions: anionic 5-endo cyclizations are aborted sigmatropic shifts. Journal of the American Chemical Society. 134: 10584-94. PMID 22594586 DOI: 10.1021/ja303341b  1
2012 Breiner B, Kaya K, Roy S, Yang WY, Alabugin IV. Hybrids of amino acids and acetylenic DNA-photocleavers: optimising efficiency and selectivity for cancer phototherapy. Organic & Biomolecular Chemistry. 10: 3974-87. PMID 22495230 DOI: 10.1039/c2ob00052k  1
2012 Tummatorn J, Batsomboon P, Clark RJ, Alabugin IV, Dudley GB. Strain-promoted azide-alkyne cycloadditions of benzocyclononynes. The Journal of Organic Chemistry. 77: 2093-7. PMID 22316100 DOI: 10.1021/jo300188y  1
2012 Gold B, Shevchenko NE, Bonus N, Dudley GB, Alabugin IV. Selective transition state stabilization via hyperconjugative and conjugative assistance: stereoelectronic concept for copper-free click chemistry. The Journal of Organic Chemistry. 77: 75-89. PMID 22077877 DOI: 10.1021/jo201434w  1
2012 Batsomboon P, Gold BA, Alabugin IV, Dudley GB. Tandem nucleophilic addition/fragmentation of vinylogous acyl nonaflates for the synthesis of functionalized alkynes, with new mechanistic insight Synthesis (Germany). 44: 1818-1824. DOI: 10.1055/s-0031-1290945  1
2012 Vasilevsky SF, Gold B, Mikhailovskaya TF, Alabugin IV. Strain control in nucleophilic cyclizations: Reversal of exo-selectivity in cyclizations of hydrazides of acetylenyl carboxylic acids by annealing to a pyrazole scaffold Journal of Physical Organic Chemistry. 25: 998-1005. DOI: 10.1002/poc.2990  1
2011 Yang WY, Roy S, Phrathep B, Rengert Z, Kenworthy R, Zorio DA, Alabugin IV. Engineering pH-gated transitions for selective and efficient double-strand DNA photocleavage in hypoxic tumors. Journal of Medicinal Chemistry. 54: 8501-16. PMID 22050291 DOI: 10.1021/jm2010282  1
2011 Stepanov AA, Gornostaev LM, Vasilevsky SF, Arnold EV, Mamatyuk VI, Fadeev DS, Gold B, Alabugin IV. Chameleonic reactivity of vicinal diazonium salt of acetylenyl-9,10-anthraquinones: synthetic application toward two heterocyclic targets. The Journal of Organic Chemistry. 76: 8737-48. PMID 21910478 DOI: 10.1021/jo2014214  1
2011 Gilmore K, Alabugin IV. Cyclizations of alkynes: revisiting Baldwin's rules for ring closure. Chemical Reviews. 111: 6513-56. PMID 21861478 DOI: 10.1021/cr200164y  1
2011 Roy S, Davydova MP, Pal R, Gilmore K, Tolstikov GA, Vasilevsky SF, Alabugin IV. Dissecting alkynes: full cleavage of polarized C≡C moiety via sequential bis-Michael addition/retro-Mannich cascade. The Journal of Organic Chemistry. 76: 7482-90. PMID 21806030 DOI: 10.1021/jo201259j  1
2011 Yang WY, Marrone SA, Minors N, Zorio DA, Alabugin IV. Fine-tuning alkyne cycloadditions: Insights into photochemistry responsible for the double-strand DNA cleavage via structural perturbations in diaryl alkyne conjugates. Beilstein Journal of Organic Chemistry. 7: 813-23. PMID 21804877 DOI: 10.3762/bjoc.7.93  1
2011 Alabugin IV, Gilmore K, Manoharan M. Rules for anionic and radical ring closure of alkynes. Journal of the American Chemical Society. 133: 12608-23. PMID 21675773 DOI: 10.1021/ja203191f  1
2011 Baroudi A, Alicea J, Flack P, Kirincich J, Alabugin IV. Radical O→C transposition: a metal-free process for conversion of phenols into benzoates and benzamides. The Journal of Organic Chemistry. 76: 1521-37. PMID 21344894 DOI: 10.1021/jo102467j  1
2011 Vasilevsky SF, Govdi AI, Sorokina IV, Tolstikova TG, Baev DS, Tolstikov GA, Mamatuyk VI, Alabugin IV. Rapid access to new bioconjugates of betulonic acid via click chemistry. Bioorganic & Medicinal Chemistry Letters. 21: 62-5. PMID 21159508 DOI: 10.1016/j.bmcl.2010.11.072  1
2011 Baranov DS, Vasilevsky SF, Gold B, Alabugin IV. Urea as an organic solvent and reagent for the addition/cyclization/ fragmentation cascades leading to 2-R-7H-dibenzo[de,h]quinolin-7-one analogues of Aporphinoid alkaloids Rsc Advances. 1: 1745-1750. DOI: 10.1039/c1ra00622c  1
2011 Alabugin IV, Gilmore KM, Peterson PW. Hyperconjugation Wiley Interdisciplinary Reviews: Computational Molecular Science. 1: 109-141. DOI: 10.1002/wcms.6  1
2010 Alabugin IV, Gold B, Shatruk M, Kovnir K. Comment on "Single-crystal X-ray structure of 1,3-dimethylcyclobutadiene by confinement in a crystalline matrix". Science (New York, N.Y.). 330: 1047; author reply 1. PMID 21097920 DOI: 10.1126/science.1196188  1
2010 Pal R, Clark RJ, Manoharan M, Alabugin IV. Fast oxy-cope rearrangements of bis-alkynes: competition with central C-C bond fragmentation and incorporation in tunable cascades diverging from a common bis-allenic intermediate. The Journal of Organic Chemistry. 75: 8689-92. PMID 21090737 DOI: 10.1021/jo101838a  1
2010 Baroudi A, Flack P, Alabugin IV. Metal-free transformation of phenols into substituted benzamides: a highly selective radical 1,2-O→C transposition in O-aryl-N-phenylthiocarbamates. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 12316-20. PMID 20853301 DOI: 10.1002/chem.201002303  1
2010 Yang WY, Cao Q, Callahan C, Galvis C, Sang QX, Alabugin IV. Intracellular DNA damage by lysine-acetylene conjugates. Journal of Nucleic Acids. 2010. PMID 20814583 DOI: 10.4061/2010/931394  1
2010 Baroudi A, Alicea J, Alabugin IV. Radical 1,2-O-->C transposition for conversion of phenols into benzoates by O-neophyl rearrangement/fragmentation cascade. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 7683-7. PMID 20521289 DOI: 10.1002/chem.201001056  0.68
2010 Baroudi A, Mauldin J, Alabugin IV. Conformationally gated fragmentations and rearrangements promoted by interception of the Bergman cyclization through intramolecular H-abstraction: a possible mechanism of auto-resistance to natural enediyne antibiotics? Journal of the American Chemical Society. 132: 967-79. PMID 20041688 DOI: 10.1021/ja905100u  1
2010 Velizhanin KA, Zeidan TA, Alabugin IV, Smirnov S. Single molecule conductance of bipyridyl ethynes: the role of surface binding modes. The Journal of Physical Chemistry. B. 114: 14189-93. PMID 19908893 DOI: 10.1021/jp9083579  1
2009 Vasilevsky SF, Mikhailovskaya TF, Mamatyuk VI, Salnikov GE, Bogdanchikov GA, Manoharan M, Alabugin IV. Tuning selectivity of anionic cyclizations: competition between 5-exo and 6-endo-dig closures of hydrazides of o-acetylenyl benzoic acids and based-catalyzed fragmentation/recyclization of the initial 5-exo-dig products. The Journal of Organic Chemistry. 74: 8106-17. PMID 19780573 DOI: 10.1021/jo901551g  1
2009 Yang WY, Breiner B, Kovalenko SV, Ben C, Singh M, LeGrand SN, Sang QXA, Strouse GF, Copland JA, Alabugin IV. C-lysine conjugates: pH-controlled light-activated reagents for efficient double-stranded DNA cleavage with implications for cancer therapy Journal of the American Chemical Society. 131: 11458-11470. PMID 19637922 DOI: 10.1021/ja902140m  1
2009 Vasilevsky SF, Baranov DS, Mamatyuk VI, Gatilov YV, Alabugin IV. An unexpected rearrangement that disassembles alkyne moiety through formal nitrogen atom insertion between two acetylenic carbons and related cascade transformations: new approach to Sampangine derivatives and polycyclic aromatic amides. The Journal of Organic Chemistry. 74: 6143-50. PMID 19585968 DOI: 10.1021/jo9008904  1
2009 Vasilevsky SF, Govdi AI, Shults EE, Shakirov MM, Sorokina IV, Tolstikova TG, Baev DS, Tolstikov GA, Alabugin IV. Efficient synthesis of the first betulonic acid-acetylene hybrids and their hepatoprotective and anti-inflammatory activity. Bioorganic & Medicinal Chemistry. 17: 5164-9. PMID 19524443 DOI: 10.1016/j.bmc.2009.05.059  1
2009 Vasilevskii SF, Govdi AI, Shul'Ts EE, Shakirov MM, Alabugin IV, Tolstikov GA. Synthesis of the first acetylene derivatives of betulonic acid Doklady Chemistry. 424: 39-42. DOI: 10.1134/S0012500809020050  1
2008 Alabugin IV, Gilmore K, Patil S, Manoharan M, Kovalenko SV, Clark RJ, Ghiviriga I. Radical cascade transformations of tris(o-aryleneethynylenes) into substituted benzo[a]indeno[2,1-c]fluorenes. Journal of the American Chemical Society. 130: 11535-45. PMID 18680260 DOI: 10.1021/ja8038213  1
2008 Alabugin IV, Timokhin VI, Abrams JN, Manoharan M, Abrams R, Ghiviriga I. In search of efficient 5-endo-dig cyclization of a carbon-centered radical: 40 years from a prediction to another success for the Baldwin rules. Journal of the American Chemical Society. 130: 10984-95. PMID 18661995 DOI: 10.1021/ja801478n  1
2008 Vasilevsky SF, Krivenko OL, Gorelik VR, Alabugin IV. Synthetic and mechanistic aspects of cross-coupling of nitroxyl radicals of 3-imidazoline series with terminal alkynes Tetrahedron. 64: 8807-8814. DOI: 10.1016/j.tet.2008.06.088  1
2007 Breiner B, Schlatterer JC, Alabugin IV, Kovalenko SV, Greenbaum NL. DNA damage-site recognition by lysine conjugates. Proceedings of the National Academy of Sciences of the United States of America. 104: 13016-21. PMID 17664419 DOI: 10.1073/pnas.0705701104  1
2007 Alabugin IV, Manoharan M. Rehybridization as a general mechanism for maximizing chemical and supramolecular bonding and a driving force for chemical reactions. Journal of Computational Chemistry. 28: 373-90. PMID 17143865 DOI: 10.1002/jcc.20524  1
2007 Alabugin I, Breiner B, Manoharan M. Cycloaromatization reactions: the testing ground for theory and experiment Advances in Physical Organic Chemistry. 42: 1-33. DOI: 10.1016/S0065-3160(07)42001-9  1
2007 Alabugin IV, Manoharan M, Buck M, Clark RJ. Substituted anilines: The tug-of-war between pyramidalization and resonance inside and outside of crystal cavities Journal of Molecular Structure: Theochem. 813: 21-27. DOI: 10.1016/j.theochem.2007.02.016  1
2007 Vasilevsky SF, Krivenko OL, Alabugin IV. Oxidative coupling of alkynes mediated by nitroxyl radicals under Sonogashira conditions and Pd-free catalytic approach to stable radicals of 3-imidazoline family with triple bonds Tetrahedron Letters. 48: 8246-8249. DOI: 10.1016/j.tetlet.2007.09.031  1
2007 Vasilevsky SF, Gornostaev LM, Stepanov AA, Arnold EV, Alabugin IV. Unmasking of aminoanthroquinone moiety through a ring opening in the presence of copper salts and a subsequent cross-coupling/recyclization cascade Tetrahedron Letters. 48: 1867-1870. DOI: 10.1016/j.tetlet.2006.12.129  1
2006 Breiner B, Schlatterer JC, Kovalenko SV, Greenbaum NL, Alabugin IV. Protected 32P-labels in deoxyribonucleotides: investigation of sequence selectivity of DNA photocleavage by enediyne-, fulvene-, and acetylene-lysine conjugates. Angewandte Chemie (International Ed. in English). 45: 3666-70. PMID 16642539 DOI: 10.1002/anie.200504479  1
2006 Pickard FC, Shepherd RL, Gillis AE, Dunn ME, Feldgus S, Kirschner KN, Shields GC, Manoharan M, Alabugin IV. Ortho effect in the Bergman cyclization: electronic and steric effects in hydrogen abstraction by 1-substituted naphthalene 5,8-diradicals. The Journal of Physical Chemistry. A. 110: 2517-26. PMID 16480313 DOI: 10.1021/jp0562835  1
2006 Zeidan TA, Kovalenko SV, Manoharan M, Alabugin IV. Ortho effect in the Bergman cyclization: comparison of experimental approaches and dissection of cycloaromatization kinetics. The Journal of Organic Chemistry. 71: 962-75. PMID 16438508 DOI: 10.1021/jo0520801  1
2006 Zeidan TA, Manoharan M, Alabugin IV. Ortho effect in the Bergman cyclization: interception of p-benzyne intermediate by intramolecular hydrogen abstraction. The Journal of Organic Chemistry. 71: 954-61. PMID 16438507 DOI: 10.1021/jo051857n  1
2006 Kauffman JF, Turner JM, Alabugin IV, Breiner B, Kovalenko SV, Badaeva EA, Masunov A, Tretiak S. Two-photon excitation of substituted enediynes. The Journal of Physical Chemistry. A. 110: 241-51. PMID 16392861 DOI: 10.1021/jp056127y  1
2005 Alabugin IV, Manoharan M. Thermodynamic and strain effects in the competition between 5-exo-dig and 6-endo-dig cyclizations of vinyl and aryl radicals. Journal of the American Chemical Society. 127: 12583-94. PMID 16144406 DOI: 10.1021/ja052677y  1
2005 Alabugin IV, Manoharan M. 5-endo-dig radical cyclizations: "the poor cousins" of the radical cyclizations family. Journal of the American Chemical Society. 127: 9534-45. PMID 15984880 DOI: 10.1021/ja050976h  1
2005 Zeidan TA, Clark RJ, Ghiviriga I, Kovalenko SV, Alabugin IV. Triplet acetylenes as synthetic equivalents of 1,2-bicarbenes, part II: new supramolecular scaffolds from photochemical cycloaddition of diarylacetylenes to 1,4-cyclohexadienes. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 4953-60. PMID 15966030 DOI: 10.1002/chem.200500180  1
2005 Zeidan TA, Kovalenko SV, Manoharan M, Clark RJ, Ghiviriga I, Alabugin IV. Triplet acetylenes as synthetic equivalents of 1,2-bicarbenes: phantom n,pi state controls reactivity in triplet photocycloaddition. Journal of the American Chemical Society. 127: 4270-85. PMID 15783209 DOI: 10.1021/ja043803l  1
2005 Kovalenko SV, Alabugin IV. Lysine-enediyne conjugates as photochemically triggered DNA double-strand cleavage agents. Chemical Communications (Cambridge, England). 1444-6. PMID 15756330 DOI: 10.1039/b417012a  1
2005 Peabody SW, Breiner B, Kovalenko SV, Patil S, Alabugin IV. Synthesis of selectively deuterated fulvenes and indenes from enediynes. Organic & Biomolecular Chemistry. 3: 218-21. PMID 15632961 DOI: 10.1039/b417493n  1
2004 Alabugin IV, Manoharan M. Effect of double-hyperconjugation on the apparent donor ability of sigma-bonds: insights from the relative stability of delta-substituted cyclohexyl cations. The Journal of Organic Chemistry. 69: 9011-24. PMID 15609933 DOI: 10.1021/jo048287w  1
2004 Kovalenko SV, Peabody S, Manoharan M, Clark RJ, Alabugin IV. 5-Exo-dig radical cyclization of enediynes: the first synthesis of tin-substituted benzofulvenes. Organic Letters. 6: 2457-60. PMID 15228303 DOI: 10.1021/ol049122c  1
2004 Alabugin IV, Manoharan M, Weinhold FA. Blue-shifted and red-shifted hydrogen bonds in hypervalent rare-gas FRg-H⋯Y sandwiches Journal of Physical Chemistry A. 108: 4720-4730. DOI: 10.1021/jp049723l  1
2003 Alabugin IV, Manoharan M, Zeidan TA. Homoanomeric effects in six-membered heterocycles. Journal of the American Chemical Society. 125: 14014-31. PMID 14611238 DOI: 10.1021/ja037304g  1
2003 Alabugin IV, Manoharan M, Breiner B, Lewis FD. Control of kinetics and thermodynamics of [1,5]-shifts by aromaticity: a view through the prism of Marcus theory. Journal of the American Chemical Society. 125: 9329-42. PMID 12889962 DOI: 10.1021/ja035729x  1
2003 Alabugin IV, Manoharan M, Peabody S, Weinhold F. Electronic basis of improper hydrogen bonding: a subtle balance of hyperconjugation and rehybridization. Journal of the American Chemical Society. 125: 5973-87. PMID 12733938 DOI: 10.1021/ja034656e  1
2003 Alabugin IV, Manoharan M. Radical-anionic cyclizations of enediynes: remarkable effects of benzannelation and remote substituents on cyclorearomatization reactions. Journal of the American Chemical Society. 125: 4495-509. PMID 12683820 DOI: 10.1021/ja029664u  1
2003 Nenajdenko VG, Shevchenko NE, Balenkova ES, Alabugin IV. 1,2-Dications in organic main group systems. Chemical Reviews. 103: 229-82. PMID 12517185 DOI: 10.1021/cr0000628  1
2003 Alabugin IV, Manoharan M. Reactant destabilization in the Bergman cyclization and rational design of light- and pH-activated enediynes Journal of Physical Chemistry A. 107: 3363-3371. DOI: 10.1021/jp026754c  1
2002 Alabugin IV, Kovalenko SV. C1-c5 photochemical cyclization of enediynes. Journal of the American Chemical Society. 124: 9052-3. PMID 12149000 DOI: 10.1021/ja026630d  1
2002 Alabugin IV, Manoharan M, Kovalenko SV. Tuning rate of the bergman cyclization of benzannelated enediynes with ortho substituents. Organic Letters. 4: 1119-22. PMID 11922797 DOI: 10.1021/ol0255054  1
2002 Alabugin IV, Zeidan TA. Stereoelectronic effects and general trends in hyperconjugative acceptor ability of sigma bonds. Journal of the American Chemical Society. 124: 3175-85. PMID 11902907 DOI: 10.1021/ja012633z  1
2001 Zimmerman HE, Alabugin IV. Energy distribution and redistribution and chemical reactivity. The generalized delta overlap-density method for ground state and electron transfer reactions: a new quantitative counterpart of electron-pushing. Journal of the American Chemical Society. 123: 2265-70. PMID 11456873 DOI: 10.1021/ja002402c  1
2000 Alabugin IV. Stereoelectronic interactions in cyclohexane, 1,3-dioxane, 1,3-oxathiane, and 1,3-dithiane: W-effect, σC-X ↔ σ *C-H interactions, anomeric effect - What is really important? Journal of Organic Chemistry. 65: 3910-3919. DOI: 10.1021/jo991622+  1
2000 Zimmerman HE, Alabugin IV. Excited state energy distribution and redistribution and chemical reactivity; mechanistic and exploratory organic photochemistry [2] Journal of the American Chemical Society. 122: 952-953. DOI: 10.1021/ja9933801  1
2000 Zimmerman HE, Alabugin IV, Smolenskaya VN. Experimental and theoretical host-guest photochemistry; control of reactivity with host variation and theoretical treatment with a stress shaped reaction cavity; mechanistic and exploratory organic photochemistry Tetrahedron. 56: 6821-6831.  1
1999 Zimmerman HE, Alabugin IV, Chen W, Zhu Z. Dramatic effects of crystal morphology on solid state reaction course; control by crystal disorder; mechanistic and exploratory organic photochemistry [19] Journal of the American Chemical Society. 121: 11930-11931. DOI: 10.1021/ja992208u  1
1997 Nenajdenko VG, Vertelezkij PV, Koldobskij AB, Alabugin IV, Balenkova ES. Oxidative Properties of Triflic Anhydride. Oxidation of Alcohols and Sulfides. The Journal of Organic Chemistry. 62: 2483-2486. PMID 11671586  0.12
1997 Alabugin IV, Brel VK. The phosphorus-containing allenes: The structure and reactions with electrophilic reagents Uspekhi Khimii. 66: 242-245.  1
1997 Nenajdenko VG, Vertelezkij PV, Koldobskij AB, Alabugin IV, Balenkova ES. Properties of Triflic Anhydride. Oxidation of Alcohols and Sulfides Journal of Organic Chemistry. 62: 2483-2486.  1
1996 Alabugin IV, Brel VK. Alkenylsulfenylchlorides. II. Interaction of -γ,-γ-disubstituted phosphorus-containing allenes with sulfur bichloride Phosphorus, Sulfur and Silicon and Related Elements. 119: 61-75.  1
1996 Alabugin IV, Brel' VK, Zyk NV, Zefirov NS. SO3-mediated reaction of phenylselenenylamide with 1,2-alkadienylphosphonates Russian Chemical Bulletin. 45: 739-740.  1
1996 Zyk NV, Beloglazkina EK, Alabugin IV, Kutateladze AG, Zefirov NS. S - tosylthiosulfenamides as electrophilic sulfo - sulfenylating reagent Vestnik Moskovskogo Universiteta Seriya 2 Khimiya. 37: 68-70.  1
1996 Alabugin IV, Sereda GA, Abramkin EV, Brel' VK, Zyk NV, Zefirov NS. Synthesis of Heterocyclic and Acyclic Derivatives of 1,2-Alkadienephosphonic Acids with the Use of Potassium Dichloroiodate(I) Russian Journal of Organic Chemistry. 32: 1353-1356.  1
1994 Alabugin IV, Brel VK, Chekhlov AN, Zefirov NS, Stang PJ. Alkenylsulfenylchlorides : Synthesis and AdE reactions of 2-alkoxy-2-oxo-3-R-4-chlorothio-1,2-oxaphosphol-3-enes Tetrahedron Letters. 35: 8275-8278. DOI: 10.1016/0040-4039(94)88301-7  1
1994 Chekhlov AN, Alabugin IV, Brel' VK, Zefirov NS. Molecular structure of crystalline product and stereochemistry of 5,5-dimethyl-2-methoxy-2-oxo-4-chlorothio-1,2-oxaphosphol-3-ene addition to cyclohexene Doklady Akademii Nauk Sssr. 335: 753-756.  1
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