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Mark G. Steinmetz - Publications

Affiliations: 
Chemistry Marquette University, Milwaukee, WI, United States 
Area:
Organic Chemistry
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35 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Steinmetz MG, Givens RS. The Discovery, Development and Demonstration of Three Caged Compounds. Photochemistry and Photobiology. PMID 34101860 DOI: 10.1111/php.13462  0.309
2019 Li L, Ndzeidze GN, Steinmetz MG. Photochemical electrocyclization and leaving group expulsion with a naphthothiophene-2-carboxanilide linked to a chromophore Tetrahedron. 75: 70-83. DOI: 10.1016/J.Tet.2018.11.013  0.535
2018 Ndzeidze GN, Li L, Steinmetz MG. Reversible Triplet Excitation Transfer in a Trimethylene - Linked Thioxanthone and Benzothiophene-2-carboxanilide that Photochemically Expels Leaving Group Anions. The Journal of Organic Chemistry. PMID 29949359 DOI: 10.1021/Acs.Joc.8B01173  0.479
2013 Sarker MI, Shahrin T, Steinmetz MG, Timerghazin QK. Photochemical electrocyclic ring closure and leaving group expulsion from N-(9-oxothioxanthenyl)benzothiophene carboxamides. Photochemical & Photobiological Sciences : Official Journal of the European Photochemistry Association and the European Society For Photobiology. 12: 309-22. PMID 23038069 DOI: 10.1039/C2Pp25051A  0.737
2011 Sarker M, Shahrin T, Steinmetz MG. Photochemical eliminations involving zwitterionic intermediates generated via electrocyclic ring closure of benzothiophene carboxanilides. Organic Letters. 13: 872-5. PMID 21268593 DOI: 10.1021/Ol102932Y  0.733
2008 Jia J, Sarker M, Steinmetz MG, Shukla R, Rathore R. Photochemical elimination of leaving groups from zwitterionic intermediates generated via electrocyclic ring closure of alpha,beta-unsaturated anilides. The Journal of Organic Chemistry. 73: 8867-79. PMID 18939880 DOI: 10.1021/Jo8017445  0.739
2008 Jia J, Steinmetz MG, Shukla R, Rathore R. Photochemical electrocyclization of α,β-unsaturated anilides to give zwitterionic intermediates which eliminate carboxylate and phenolate leaving groups Tetrahedron Letters. 49: 4621-4623. DOI: 10.1016/J.Tetlet.2008.05.079  0.377
2006 Chen Y, Steinmetz MG. Photoactivation of amino-substituted 1,4-benzoquinones for release of carboxylate and phenolate leaving groups using visible light. The Journal of Organic Chemistry. 71: 6053-60. PMID 16872188 DOI: 10.1021/Jo060790G  0.64
2006 Ma C, Chen Y, Steinmetz MG. Photochemical cleavage and release of para-substituted phenols from alpha-keto amides. The Journal of Organic Chemistry. 71: 4206-15. PMID 16709062 DOI: 10.1021/Jo060338X  0.682
2005 Chen Y, Steinmetz MG. Photochemical cyclization with release of carboxylic acids and phenol from pyrrolidino-substituted 1,4-benzoquinones using visible light. Organic Letters. 7: 3729-32. PMID 16092861 DOI: 10.1021/Ol051362K  0.61
2005 Ma C, Steinmetz MG, Kopatz EJ, Rathore R. Photochemical cleavage and release of carboxylic acids from alpha-keto amides. The Journal of Organic Chemistry. 70: 4431-42. PMID 15903322 DOI: 10.1021/Jo050246S  0.601
2005 Ma C, Steinmetz MG, Kopatz EJ, Rathore R. Time-resolved pH jump study of photochemical cleavage and release of carboxylic acids from α-keto amides Tetrahedron Letters. 46: 1045-1048. DOI: 10.1016/J.Tetlet.2004.11.167  0.567
2004 Ma C, Steinmetz MG. Substituent effects on competitive release of phenols and 1,3-rearrangement in alpha-keto amide photochemistry. Organic Letters. 6: 629-32. PMID 14961640 DOI: 10.1021/Ol036459Q  0.649
2003 Ma C, Steinmetz MG, Cheng Q, Jayaraman V. Photochemical cleavage and release of carboxylic acids from alpha-keto amides. Organic Letters. 5: 71-4. PMID 12509893 DOI: 10.1021/Ol020227U  0.598
2002 Cheng Q, Steinmetz MG, Jayaraman V. Photolysis of gamma-(alpha-carboxy-2-nitrobenzyl)-L-glutamic acid investigated in the mcrosecond time scale by time-resolved FTIR. Journal of the American Chemical Society. 124: 7676-7. PMID 12083919 DOI: 10.1021/Ja0259988  0.34
1999 Steinmetz MG, Luo C, Liu G. Photochemistry of a Trisilane Substituted by a Pendant p-Cyanostilbene Electron Acceptor Chromophore. The Journal of Organic Chemistry. 64: 2057-2065. PMID 11674300 DOI: 10.1021/Jo982378+  0.378
1997 Heisler L, Hossenlopp JM, Yuping N, Steinmetz MG, Zhang Y. Quenching of aromatic ketone triplet excited states by polysilanes Journal of Photochemistry and Photobiology a: Chemistry. 107: 125-136. DOI: 10.1016/S1010-6030(96)04582-0  0.346
1996 Liu G, Heisler L, Li L, Steinmetz MG. Photochemistry of locally excited and intramolecular charge transfer states of (E)-4-cyano-4'-(pentamethyldisilanyl)stilbene Journal of the American Chemical Society. 118: 11412-11422. DOI: 10.1021/Ja962218K  0.302
1996 Steinmetz MG, Chen Q, Zheng Y. The exploratory far-UV photochemistry of 1-methyl-1-silabicyclo[2.2.1]hept-2-ene and 2-trimethylsilylbicyclo[2.2.1]hept-2-ene Journal of Organometallic Chemistry. 516: 25-40. DOI: 10.1016/0022-328X(95)06087-D  0.417
1995 Steinmetz MG, Chen Q. Photochemical [1,3-C] migration of a bridgehead silanorbornene Journal of the Chemical Society, Chemical Communications. 133-134. DOI: 10.1039/C39950000133  0.318
1994 Steinmetz MG, Yu C, Li L. Photochemistry of locally excited and intramolecular charge transfer states of a disilane bearing a cyclic arylethenyl electron acceptor substituent Journal of the American Chemical Society. 116: 932-943. DOI: 10.1021/Ja00082A014  0.454
1992 Steinmetz MG, Yu C. Far-UV photochemistry of 1,1-dimethyl-1-silacyclopent-3-ene: Photoextrusion of dimethylsilylene and stereoselective 1,4-addition of methanol to an intermediate vinylsilirane Organometallics. 11: 2686-2690. DOI: 10.1021/Om00043A062  0.394
1992 Steinmetz MG, Yu C. The Far-UV photochemistry of five- and six-membered-ring monosilacycloalkenes in alcohols: Stereospecific β-cleavage to silyl ethers and stereoselective formation of silacycloalkyl ethers Journal of Organic Chemistry. 57: 3107-3120. DOI: 10.1021/Jo00037A030  0.322
1990 Steinmetz MG, Seguin KJ, Udayakumar BS, Behnke JS. Evidence for a metastable trans-cycloalkene intermediate in the photochemistry of 1,1,4,4-tetramethyl-1,4-disilacyclohept-2-ene Journal of the American Chemical Society. 112: 6601-6608. DOI: 10.1021/Ja00174A022  0.382
1989 Steinmetz MG, Bai H. Regioselective one- and two-bond cleavages in the solution-phase 185-nm photochemistry of (E)- and (Z)-1,1,2,3-tetramethylsilacyclobutane Organometallics. 8: 1112-1113. DOI: 10.1021/Om00106A038  0.344
1989 Steinmetz MG, Udayakumar BS, Gordon MS. Mechanistic Studies of the Far-UV Photochemical Ring-Opening and Cleavage Reactions of 1, 1-Dimethyl-1-silacyclobut-2-ene Organometallics. 8: 530-541. DOI: 10.1021/Om00104A039  0.373
1989 Steinmetz MG, Udayakumar BS. Chloroplatinic acid catalyzed cyclization of silanes bearing pendant acetylenic groups Journal of Organometallic Chemistry. 378: 1-15. DOI: 10.1016/0022-328X(89)85001-6  0.422
1987 Steinmetz MG, Mayes RT, Udayakumar BS. Solution phase photochemical hydrosilylation of silylacetylenes Journal of the Chemical Society, Chemical Communications. 759-761. DOI: 10.1039/C39870000759  0.303
1986 Steinmetz MG, Langston MA, Mayes RT, Udayakumar BS. Solution-phase far-UV photochemistry of unsaturated organosilanes: Dehydrosilylation, dyotropic rearrangement, and protodesilylation Journal of Organic Chemistry. 51: 5051-5063. DOI: 10.1021/Jo00376A002  0.44
1985 Steinmetz MG, Mayes RT. Mechanisms for interconversions among C3H4 hydrocarbons: Deuterium isotope effects and independent generation of vinylmethylene intermediates in photoisomerizations of allenes and cyclopropenes Journal of the American Chemical Society. 107: 2111-2121. DOI: 10.1002/Chin.198533125  0.378
1984 STEINMETZ MG, SRINIVASAN R, LEIGH WJ. ChemInform Abstract: Reactive Intermediates in the Interconversions of C3H4Hydrocarbons Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198433357  0.318
1983 Steinmetz MG, Yen YP, Poch GK. Comparison between ground and excited state reactivity of cyclopropenes: Thermolysis and far-u.v. (185 nm) photolysis of spiro[2.4]hept-1-ene Journal of the Chemical Society, Chemical Communications. 1504-1505. DOI: 10.1039/C39830001504  0.361
1983 Steinmetz MG, Stark EJ, Yen YP, Mayes RT, Srinivasan R. Far-UV (185-nm) photochemistry of allenes: Photoisomerization and cycloreversion reactions of vinylidenecyclobutane Journal of the American Chemical Society. 105: 7209-7210. DOI: 10.1002/Chin.198409108  0.342
1978 Zimmerman HE, Steinmetz MG. A new theoretical approach in photochemistry. Minimization of excited state-ground state surface separation by selected molecular deformation. Vibrational dissipation of local contributions to excitation energies Journal of the Chemical Society, Chemical Communications. 230-232. DOI: 10.1039/C39780000230  0.336
1978 Zimmerman HE, Gruenbaum WT, Klun RT, Steinmetz MG, Welter TR. Differing substituent effects on rates and regioselectivities in the di-π-methane rearrangement. New photochemical theory: Excitation distribution (the ΔP matrix), reaction inhibition by vertical excited state stabilisation, ground Vs. excited state control Journal of the Chemical Society, Chemical Communications. 228-230. DOI: 10.1039/C39780000228  0.409
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