| Year |
Citation |
Score |
| 2020 |
Wu K, Pudasaini B, Park JY, Top S, Jaouen G, Baik M, Geiger WE. Oxidation of Cymantrene-Tagged Tamoxifen Analogues: Effect of Diphenyl Functionalization on the Redox Mechanism Organometallics. 39: 679-687. DOI: 10.1021/Acs.Organomet.9B00822 |
0.369 |
|
| 2019 |
Gamm P, Sheridan MV, Van Wyck SJ, Meindl A, Senge MO, Geiger WE. Ethynylphenyl-derivatized Free Base Porphyrins: Anodic Oxidation Processes and Covalent Grafting onto Glassy Carbon Electrodes. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 31847520 DOI: 10.1021/Acs.Langmuir.9B03452 |
0.734 |
|
| 2019 |
Wu K, Conger MA, Waterman R, Liptak M, Geiger WE. Electrochemical and structural characterization of a radical cation formed by one-electron oxidation of a cymantrene complex containing an N-heterocyclic carbene ligand Polyhedron. 157: 442-448. DOI: 10.1016/J.Poly.2018.10.039 |
0.49 |
|
| 2019 |
Sheridan MV, Lam K, Waterman R, Geiger WE. Anodic Oxidation of Ethynylferrocene Derivatives in Homogeneous Solution and Following Anodic Deposition onto Glassy Carbon Electrodes Chemelectrochem. 6: 5880-5887. DOI: 10.1002/celc.201901545 |
0.686 |
|
| 2018 |
Hall EA, Ramsey JE, Peng Z, Hayrapetyan D, Shkepu V, O'Rourke B, Geiger W, Lam K, Verschraegen CF. Novel organometallic chloroquine derivative inhibits tumor growth. Journal of Cellular Biochemistry. PMID 29575007 DOI: 10.1002/Jcb.26787 |
0.514 |
|
| 2018 |
Sheridan MV, Gamm P, Schneebeli ST, Breuer R, Schmittel M, Geiger WE. The Effect of Large Electrolyte Anions on the Sequential Oxidations of Bis(fulvalene)diiron Attached to Glassy Carbon by an Ethynyl Linkage. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 29309154 DOI: 10.1021/Acs.Langmuir.7B03649 |
0.745 |
|
| 2018 |
Wu K, Park JY, Al-Saadon R, Nam H, Lee Y, Top S, Jaouen G, Baik M, Geiger WE. Oxidation of Cymantrene Analogues of Ferrocifen: Electrochemical, Spectroscopic, and Computational Studies of the Parent Complex 1,1′-Diphenyl-2-cymantrenylbutene Organometallics. 37: 1910-1918. DOI: 10.1021/Acs.Organomet.8B00186 |
0.457 |
|
| 2018 |
Geiger WE. Complementary Use of Electrochemistry and Synthetic Redox Chemistry in the Oxidation of Decamethylferrocene: An Integrated Advanced Laboratory Experiment Journal of Chemical Education. 95: 1648-1653. DOI: 10.1021/Acs.Jchemed.8B00021 |
0.319 |
|
| 2017 |
Lam K, Van Wyck SJ, Geiger WE. One-electron oxidation of chloroquine, cymanquine, and related aminoquinolines in nonaqueous media Journal of Electroanalytical Chemistry. 799: 531-537. DOI: 10.1016/J.Jelechem.2017.06.041 |
0.661 |
|
| 2016 |
Sheridan MV, Lam K, Sharafi M, Schneebeli ST, Geiger WE. Anodic Methods for Covalent Attachment of Ethynylferrocenes to Electrode Surfaces: Comparison of Ethynyl Activation Processes. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 26756403 DOI: 10.1021/Acs.Langmuir.6B00012 |
0.782 |
|
| 2016 |
Lam K, Geiger WE. Synthesis and anodic electrochemistry of cymanquine and related complexes Journal of Organometallic Chemistry. 817: 15-20. DOI: 10.1016/J.Jorganchem.2016.05.009 |
0.606 |
|
| 2016 |
Wu K, Van Wyck SJ, Geiger WE. Nonaqueous electrochemical oxidation of tamoxifen Journal of Electroanalytical Chemistry. 783: 140-145. DOI: 10.1016/J.Jelechem.2016.11.033 |
0.453 |
|
| 2015 |
Donovan ES, Barry BM, Larsen CA, Wirtz MN, Geiger WE, Kemp RA. Facilitated carbon dioxide reduction using a Zn(ii) complex. Chemical Communications (Cambridge, England). PMID 26660087 DOI: 10.1039/C5Cc07318A |
0.339 |
|
| 2015 |
Stewart MP, Lam K, Chong D, Geiger WE. Electron-transfer catalyzed cycloaddition reactions of unactivated cyclic olefins in weakly coordinating anion electrolyte Journal of Electroanalytical Chemistry. 743: 68-77. DOI: 10.1016/J.Jelechem.2015.02.001 |
0.661 |
|
| 2015 |
Sheridan MV, Lam K, Geiger WE. Spontaneous attachment of lithium-activated ferrocenylalkynes to carbon and gold Electrochemistry Communications. 52: 63-66. DOI: 10.1016/J.Elecom.2015.01.024 |
0.755 |
|
| 2014 |
Russell AD, Gilroy JB, Lam K, Haddow MF, Harvey JN, Geiger WE, Manners I. Influence of cyclopentadienyl ring-tilt on electron-transfer reactions: redox-induced reactivity of strained [2] and [3]ruthenocenophanes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 16216-27. PMID 25298226 DOI: 10.1002/Chem.201403512 |
0.609 |
|
| 2014 |
Shen J, Yap GP, Barker WE, Geiger WE, Theopold KH. An electron transfer series of octahedral chromium complexes containing a redox non-innocent α-diimine ligand. Chemical Communications (Cambridge, England). 50: 10626-9. PMID 25073609 DOI: 10.1039/C4Cc03332A |
0.34 |
|
| 2014 |
Erhard M, Lam K, Haddow M, Whittell GR, Geiger WE, Manners I. Polyferrocenylsilane homopolymers and diblock copolymers with pendant ruthenocenyl groups by photocontrolled ring-opening polymerisation Polymer Chemistry. 5: 1264-1274. DOI: 10.1039/C3Py01232H |
0.592 |
|
| 2014 |
Laws DR, Bullock RM, Lee R, Huang KW, Geiger WE. Comparison of the one-electron oxidations of CO-bridged vs unbridged bimetallic complexes: Electron-transfer chemistry of Os2Cp2(CO)4 and Os2Cp∗2(μ-CO)2(CO)2 (Cp = η5-C5H5, Cp∗ = η5-C5Me5) Organometallics. 33: 4716-4728. DOI: 10.1021/Om401213Y |
0.469 |
|
| 2014 |
Chong D, Teixeira VH, Calhorda MJ, Geiger WE. One-electron oxidation of ReCp(CO)2L (L = PPh3, η2-2-Butene, η-Diphenylacetylene): Electrochemical, spectroscopic, and computational studies of the electronic properties and dimerization tendencies of 17-electron rhenium complexes Organometallics. 33: 4706-4715. DOI: 10.1021/Om401198J |
0.475 |
|
| 2014 |
Wu K, Laws DR, Nafady A, Geiger WE. Substitution of CO Ligand by P(OPh)<inf>3</inf> in Radical Cations of the Cymantrene Family: Relationships of Substitution Rates to E<inf>1/2</inf> Values and Carbonyl IR Frequencies Journal of Inorganic and Organometallic Polymers and Materials. 24: 137-144. DOI: 10.1007/S10904-013-9976-9 |
0.395 |
|
| 2013 |
Sheridan MV, Lam K, Geiger WE. Covalent attachment of porphyrins and ferrocenes to electrode surfaces through direct anodic oxidation of terminal ethynyl groups. Angewandte Chemie (International Ed. in English). 52: 12897-900. PMID 24127205 DOI: 10.1002/Anie.201307453 |
0.766 |
|
| 2013 |
Barry BM, Stein BW, Larsen CA, Wirtz MN, Geiger WE, Waterman R, Kemp RA. Metal complexes (M = Zn, Sn, and Pb) of 2-phosphinobenzenethiolates: insights into ligand folding and hemilability. Inorganic Chemistry. 52: 9875-84. PMID 23937328 DOI: 10.1021/Ic400990N |
0.323 |
|
| 2013 |
Lam K, Geiger WE. Anodic oxidation of disulfides: detection and reactions of disulfide radical cations. The Journal of Organic Chemistry. 78: 8020-7. PMID 23855600 DOI: 10.1021/Jo401263Z |
0.644 |
|
| 2013 |
Sheridan MV, Lam K, Geiger WE. An anodic method for covalent attachment of molecules to electrodes through an ethynyl linkage. Journal of the American Chemical Society. 135: 2939-42. PMID 23384093 DOI: 10.1021/Ja312405H |
0.774 |
|
| 2013 |
Geiger WE. One-electron electrochemistry of parent piano-stool complexes Coordination Chemistry Reviews. 257: 1459-1471. DOI: 10.1016/J.Ccr.2012.07.004 |
0.502 |
|
| 2012 |
Russell AD, Gilroy JB, Lam K, Haddow MF, Harvey JN, Geiger WE, Manners I. Metal-metal bond formation between [n]metallocenophanes: synthesis and characterisation of a dicarba[2]ruthenocenophanium dimer. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 8000-3. PMID 22639440 DOI: 10.1002/Chem.201201129 |
0.582 |
|
| 2012 |
Trupia S, Bitterwolf TE, Geiger WE. Role of a metal-metal bonded dimer dication in the one-electron oxidation of Rh(η 5-C 5H 5)(CO)(PPh 3) and related compounds Organometallics. 31: 6063-6070. DOI: 10.1021/Om3003976 |
0.453 |
|
| 2011 |
Wu K, Top S, Hillard EA, Jaouen G, Geiger WE. Anodic properties of diarylethene derivatives having organometallic piano-stool tags. Chemical Communications (Cambridge, England). 47: 10109-11. PMID 21833396 DOI: 10.1039/C1Cc13787E |
0.37 |
|
| 2011 |
Wu K, Mukherjee D, Ellern A, Sadow AD, Geiger WE. Anodic electrochemistry of Mn and Re tricarbonyl complexes of tris(oxazolinyl)phenyl borate ligands: Comparison to tris(pyrazolyl) borate complexes New Journal of Chemistry. 35: 2169-2178. DOI: 10.1039/C1Nj20222G |
0.444 |
|
| 2011 |
Geiger WE. Reflections on future directions in organometallic electrochemistry Organometallics. 30: 28-31. DOI: 10.1021/Om1010758 |
0.371 |
|
| 2011 |
Trupia S, Classen J, Gleiter R, Geiger WE. Electrochemical studies of the oxidation and reduction of dicobalta-superphane complexes Inorganica Chimica Acta. 374: 88-93. DOI: 10.1016/J.Ica.2011.01.092 |
0.459 |
|
| 2010 |
Laws DR, Sheats J, Rheingold AL, Geiger WE. Organometallic electrodes: modification of electrode surfaces through cathodic reduction of cyclopentadienyldiazonium complexes of cobalt and manganese. Langmuir : the Acs Journal of Surfaces and Colloids. 26: 15010-21. PMID 20726537 DOI: 10.1021/La102579T |
0.431 |
|
| 2010 |
Geiger WE, Barrière F. Organometallic electrochemistry based on electrolytes containing weakly-coordinating fluoroarylborate anions. Accounts of Chemical Research. 43: 1030-9. PMID 20345126 DOI: 10.1021/Ar1000023 |
0.456 |
|
| 2010 |
Nafady A, Geiger WE. Anodic reaction of CO(η5-C5H5)(CO) (PPh3): An oxidatively induced ligand exchange involving a 17 e -/18 e- redox pair Organometallics. 29: 4276-4281. DOI: 10.1021/Om100631K |
0.462 |
|
| 2010 |
Ohrenberg NC, Paradee LM, Dewitte RJ, Chong D, Geiger WE. Spectra and synthetic-time-scale substitution reactions of electrochemically produced [Cr(CO)3(η6-arene)] + complexes Organometallics. 29: 3179-3186. DOI: 10.1021/Om100318Q |
0.46 |
|
| 2010 |
Stewart MP, Paradee LM, Raabe I, Trapp N, Slattery JS, Krossing I, Geiger WE. Anodic oxidation of organometallic sandwich complexes using [Al(OC(CF 3)3)4]- or [AsF6] - as the supporting electrolyte anion Journal of Fluorine Chemistry. 131: 1091-1095. DOI: 10.1016/J.Jfluchem.2010.03.001 |
0.396 |
|
| 2010 |
Stewart MP, Butterick R, Sneddon LG, Matsuo Y, Geiger WE. Voltammetry of half-sandwich manganese group complexes of η6-PhC3B7H9 and η5-C60Bn2PhH2, two ligands that are cyclopentadienyl mimicks Inorganica Chimica Acta. 364: 251-254. DOI: 10.1016/J.Ica.2010.05.040 |
0.488 |
|
| 2009 |
LeSuer RJ, Geiger WE. Ligand-solvent interactions in a highly reduced metal chelate complex: medium dependence of the one-electron reduction of the bis(maleonitriledithiolato)gold dianion. Inorganic Chemistry. 48: 10826-36. PMID 19894771 DOI: 10.1021/Ic901547F |
0.448 |
|
| 2009 |
Chong D, Stewart M, Geiger WE. Cycloaddition reactions of unactivated olefins catalyzed by an organorhenium electron-transfer mediator. Journal of the American Chemical Society. 131: 7968-9. PMID 19462973 DOI: 10.1021/Ja9032296 |
0.385 |
|
| 2009 |
Swarts JC, Nafady A, Roudebush JH, Trupia S, Geiger WE. One-electron oxidation of ruthenocene: reactions of the ruthenocenium ion in gentle electrolyte media. Inorganic Chemistry. 48: 2156-65. PMID 19235975 DOI: 10.1021/Ic802105B |
0.45 |
|
| 2009 |
Fortin D, Clément S, Gagnon K, Bérubé JF, Stewart MP, Geiger WE, Harvey PD. Conjugated organometallic polymer containing a redox-active center. Inorganic Chemistry. 48: 446-54. PMID 19053345 DOI: 10.1021/Ic800857V |
0.316 |
|
| 2009 |
Shaw MJ, Eilers JE, Geiger WE. Consequences of the protonation of the 19-electron anion [Co(η 5-C 5H 5)(l,5-C 8H 12)] - Organometallics. 28: 5349-5357. DOI: 10.1021/Om9003847 |
0.405 |
|
| 2009 |
Chong D, Slote J, Geiger WE. The role of solvent in the stepwise electrochemical oxidation of nickelocene to the nickelocenium dication Journal of Electroanalytical Chemistry. 630: 28-34. DOI: 10.1016/J.Jelechem.2009.02.009 |
0.394 |
|
| 2008 |
Laws DR, Chong D, Nash K, Rheingold AL, Geiger WE. Cymantrene radical cation family: spectral and structural characterization of the half-sandwich analogues of ferrocenium ion. Journal of the American Chemical Society. 130: 9859-70. PMID 18597460 DOI: 10.1021/Ja801930Q |
0.424 |
|
| 2008 |
Chong D, Laws DR, Nafady A, Costa PJ, Rheingold AL, Calhorda MJ, Geiger WE. [Re(eta(5)-C5H5)(CO)3]+ family of 17-electron compounds: monomer/dimer equilibria and other reactions. Journal of the American Chemical Society. 130: 2692-703. PMID 18247617 DOI: 10.1021/Ja710513N |
0.505 |
|
| 2008 |
Nafady A, Geiger WE. Characterization of the successive one-electron oxidation products of the dicobalt fulvalenediyl (Fv) compound Co2Fv(CO)4 and its phosphine-substituted product Organometallics. 27: 5624-5631. DOI: 10.1021/Om800546D |
0.518 |
|
| 2008 |
Daesung C, Geiger WE, Davis NA, Weisbrich A, Yifan S, Arif AM, Ernst RD. Synthetic, structural, and electrochemical studies of edge-bridged open ferrocenes Organometallics. 27: 430-436. DOI: 10.1021/Om700886K |
0.402 |
|
| 2007 |
Kokatam S, Ray K, Pap J, Bill E, Geiger WE, LeSuer RJ, Rieger PH, Weyhermüller T, Neese F, Wieghardt K. Molecular and electronic structure of square-planar gold complexes containing two 1,2-Di(4-tert-butylphenyl)ethylene-1,2-dithiolato ligands: [Au(2L)2]1+/0/1-/2-. A combined experimental and computational study. Inorganic Chemistry. 46: 1100-11. PMID 17291110 DOI: 10.1021/Ic061181U |
0.317 |
|
| 2007 |
Brownie JH, Baird MC, Laws DR, Geiger WE. One-electron oxidations of the methyldiphenylphosphonium cyclopentadienylide complexes M(η 5-C 5H 4PMePh 2)(CO) 3 (M = Cr, Mo, W): Formation and dimerization of the 17-electron, metal-centered radicals [M(η 5- C 5H 4PMePh 2)(CO) 3] + Organometallics. 26: 5890-5901. DOI: 10.1021/Om700688P |
0.412 |
|
| 2007 |
Geiger WE. Organometallic electrochemistry: Origins, development, and future Organometallics. 26: 5738-5765. DOI: 10.1021/Om700558K |
0.361 |
|
| 2007 |
Volcheck WM, Tocher DA, Geiger WE. Electrochemical reduction of Ru(η6-arene)(κ3-tris(pyrazolyl)methane) dicationic complexes Journal of Organometallic Chemistry. 692: 3300-3305. DOI: 10.1016/J.Jorganchem.2006.12.016 |
0.462 |
|
| 2007 |
Geiger WE. Structural Changes Accompanying Metal Complex Electrode Reactions Progress in Inorganic Chemistry. 33: 275-352. DOI: 10.1002/9780470166345.Ch6 |
0.36 |
|
| 2006 |
Nafady A, Costa PJ, Calhorda MJ, Geiger WE. Electrochemical oxidation of CoCp(CO)2: radical-substrate reaction of a 17 e-/18 e- pair and production of a unique dimer radical. Journal of the American Chemical Society. 128: 16587-99. PMID 17177408 DOI: 10.1021/Ja0653775 |
0.457 |
|
| 2006 |
Barrière F, Geiger WE. Use of weakly coordinating anions to develop an integrated approach to the tuning of deltaE(1/2) values by medium effects. Journal of the American Chemical Society. 128: 3980-9. PMID 16551106 DOI: 10.1021/Ja058171X |
0.41 |
|
| 2006 |
Garg A, Nemer DM, Choi H, Sheridan JB, Geiger WE. On the question of redox-induced haptotropic rearrangements in the electrochemical reduction of η 6-triolefin chromium complexes having nonaromatic ligands Organometallics. 25: 275-282. DOI: 10.1021/Om058046U |
0.414 |
|
| 2006 |
Nafady A, Chin TT, Geiger WE. Manipulating the electrolyte medium to favor either one-electron or two-electron oxidation pathways for (fulvalendiyl)dirhodium complexes Organometallics. 25: 1654-1663. DOI: 10.1021/Om051101E |
0.452 |
|
| 2006 |
LeSuer RJ, Geiger WE. Approaches to analytical and synthetic electrochemistry in fluorous solvent-containing media Journal of Electroanalytical Chemistry. 594: 20-26. DOI: 10.1016/J.Jelechem.2006.05.016 |
0.333 |
|
| 2005 |
Chong D, Nafady A, Costa PJ, Calhorda MJ, Geiger WE. Anodic preparation of [Re2Cp2(CO)6]2+: a dimeric dication that provides the powerful one-electron oxidant [ReCp(CO)3]+. Journal of the American Chemical Society. 127: 15676-7. PMID 16277489 DOI: 10.1021/Ja055045K |
0.468 |
|
| 2005 |
Swarts JC, Laws D, Geiger WE. An organometallic electrode based on covalent attachment of the cobaltocenium group to carbon Organometallics. 24: 341-343. DOI: 10.1021/Om040124A |
0.376 |
|
| 2005 |
Barrière F, Kirss RU, Geiger WE. Anodic electrochemistry of multiferrocenyl phosphine and phosphine chalcogenide complexes in weakly nucleophilic electrolytes Organometallics. 24: 48-52. DOI: 10.1021/Om040123I |
0.454 |
|
| 2004 |
LeSuer RJ, Buttolph C, Geiger WE. Comparison of the conductivity properties of the tetrabutylammonium salt of tetrakis(pentafluorophenyl)borate anion with those of traditional supporting electrolyte anions in nonaqueous solvents. Analytical Chemistry. 76: 6395-401. PMID 15516133 DOI: 10.1021/Ac040087X |
0.301 |
|
| 2004 |
Stoll ME, Geiger WE. In-situ IR spectroelectrochemistry study of one-electron oxidations of bis(cyclopentadienyl) molybdenum(II)-alkyne or -alkene compounds Organometallics. 23: 5818-5823. DOI: 10.1021/Om040093J |
0.445 |
|
| 2004 |
Shaw MJ, Hyde J, White C, Geiger WE. Ligand-based reduction and electron-transfer-induced tub-to-chair isomerization of cyclooctatetraene ligand in Rh(η 5-C 5Ph 5)(η 4-C 8H 8) Organometallics. 23: 2205-2208. DOI: 10.1021/Om030661F |
0.43 |
|
| 2003 |
Trupia S, Nafady A, Geiger WE. Electrochemical preparation of the bis(ruthenocenium) dication. Inorganic Chemistry. 42: 5480-2. PMID 12950192 DOI: 10.1021/Ic030146+ |
0.367 |
|
| 2003 |
Geiger WE, Ohrenberg NC, Yeomans B, Connelly NG, Emslie DJ. Reversible sequence of intramolecular associative and dissociative electron-transfer reactions in hydrotris(pyrazolylborate) complexes of rhodium. Journal of the American Chemical Society. 125: 8680-8. PMID 12848576 DOI: 10.1021/Ja0302073 |
0.446 |
|
| 2003 |
LeSuer R, Basta R, Arif AM, Geiger WE, Ernst RD. Structural, spectroscopic, and electrochemical studies of edge-bridged open ferrocenes Organometallics. 22: 1487-1493. DOI: 10.1021/Om020779G |
0.377 |
|
| 2003 |
Winter RF, Geiger WE. One-electron oxidation of heterodinuclear organometallic compounds having polyphosphido bridges Organometallics. 22: 1948-1952. DOI: 10.1021/Om020778O |
0.411 |
|
| 2002 |
Barrière F, Camire N, Geiger WE, Mueller-Westerhoff UT, Sanders R. Use of medium effects to tune the Delta E(1/2) values of bimetallic and oligometallic compounds. Journal of the American Chemical Society. 124: 7262-3. PMID 12071722 DOI: 10.1021/Ja020309D |
0.436 |
|
| 2002 |
Camire N, Nafady A, Geiger WE. Characterization and reactions of previously elusive 17-electron cations: electrochemical oxidations of (C(6)H(6))Cr(CO)(3) and (C(5)H(5))Co(CO)(2) in the presence of [B(C(6)F(5))(4)](-). Journal of the American Chemical Society. 124: 7260-1. PMID 12071721 DOI: 10.1021/Ja012641F |
0.474 |
|
| 2002 |
Geiger WE. Electrochemistry of cycloaddition products of olefins with nickel dithiolenes: a reinvestigation of the reduction of the 1:1 adduct between Ni(S(2)C(2)(CF(3))(2))(2) and norbornadiene. Inorganic Chemistry. 41: 136-9. PMID 11782153 DOI: 10.1021/Ic010968B |
0.37 |
|
| 2002 |
Bahadur M, Allen CW, Geiger WE, Bridges A. Organophosphazenes. 25. The synthesis and electrochemistry of the dicobalt hexacarbonyl complexes of phenylethynylcyclophosphazenes Canadian Journal of Chemistry. 80: 1393-1397. DOI: 10.1139/v02-138 |
0.493 |
|
| 2002 |
Ramachandran BM, Trupia SM, Geiger WE, Carroll PJ, Sneddon LG. Synthetic, structural, chemical, and electrochemical studies of the metallatricarbadecaboranyl analogues of ferrocene, ruthenocene, and osmocene and the observation of a reversible η6-η4 tricarbadecaboranyl coordination that is analogous to the η5-η3 cyclopentadienyl ring-slippage process Organometallics. 21: 5078-5090. DOI: 10.1021/Om020757U |
0.34 |
|
| 2002 |
Morneau A, Geiger WE, Richmond MG, Don MJ, Watson WH, Nagl A. Reduction and oxidation of the arachno clusters Fe2(CO)6(μ-S)2PtL2: Characterization of distinct one-and two-electron transfer sites in heteropolynuclear compounds Organometallics. 21: 1247-1256. DOI: 10.1021/Om010838A |
0.448 |
|
| 2001 |
Stoll ME, Belanzoni P, Calhorda MJ, Drew MGB, Félix V, Geiger WE, Gamelas CA, Gonçalves IS, Romão CC, Veiros LF. Stepwise hapticity changes in sequential one-electron redox reactions of indenyl-molybdenum complexes: Combined electrochemical, ESR, X-ray, and theoretical studies Journal of the American Chemical Society. 123: 10595-10606. PMID 11673991 DOI: 10.1021/Ja0109951 |
0.411 |
|
| 2001 |
Geiger WE, Barrière F, LeSuer RJ, Trupia S. On the electrochemical preparation of the neutral complexes M[S4C4(CN)4], M(mnt)2, M = Ni, Pd, Pt Inorganic Chemistry. 40: 2472-2473. PMID 11350219 DOI: 10.1021/Ic015514T |
0.326 |
|
| 2001 |
Connelly NG, Emslie DJH, Geiger WE, Hayward OD, Linehan EB, Orpen AG, Quayle MJ, Rieger PH. Redox-induced κ2-κ3 isomerisation in hydrotris(pyrazolyl)-boratorhodium complexes: Synthesis, structure and ESR spectroscopy of stabilised rhodium(II) species Journal of the Chemical Society, Dalton Transactions. 512-514. DOI: 10.1039/B008131K |
0.412 |
|
| 2001 |
Barrière F, Geiger WE. Generation of the 15-electron rhodium(II) complex [RhCl(PPh3)3]+ by 1-electron oxidation of wilkinson's catalyst Organometallics. 20: 2133-2135. DOI: 10.1021/Om010077B |
0.444 |
|
| 2001 |
Camire N, Mueller-Westerhoff UT, Geiger WE. Improved electrochemistry of multi-ferrocenyl compounds: Investigation of biferrocene, terferrocene, bis(fulvalene)diiron and diferrocenylethane in dichloromethane using [NBu4][B(C6F5)4] as supporting electrolyte Journal of Organometallic Chemistry. 637: 823-826. DOI: 10.1016/S0022-328X(01)00956-1 |
0.392 |
|
| 2000 |
Ohrenberg C, Geiger WE. Electrochemistry in benzotrifluoride: Redox studies in a 'noncoordinating' solvent capable of bridging the organic and fluorous phases Inorganic Chemistry. 39: 2948-2950. PMID 11232836 DOI: 10.1021/Ic000007H |
0.304 |
|
| 2000 |
Atwood CG, Geiger WE. Investigations of time-dependent delocalization and the correlation of carbonyl IR shifts with ΔE(1/2) values for hydrocarbon-linked class II and class III mixed-valent complexes Journal of the American Chemical Society. 122: 5477-5485. DOI: 10.1021/Ja994064P |
0.377 |
|
| 2000 |
MacLachlan MJ, Zheng J, Thieme K, Lough AJ, Manners I, Mordas C, LeSuer R, Geiger WE, Liable-Sands LM, Rheingold AL. Synthesis, characterization, and ring-opening polymerization of a novel [1] silaferrocenophane with two ferrocenyl substituents at silicon Polyhedron. 19: 275-289. DOI: 10.1016/S0277-5387(99)00357-5 |
0.336 |
|
| 2000 |
Morneau A, Donovan-Merkert BT, Geiger WE. An electron-transfer induced migratory insertion reaction originating from a 19-electron cobaltacyclic anion Inorganica Chimica Acta. 300: 96-101. DOI: 10.1016/S0020-1693(99)00533-2 |
0.456 |
|
| 1999 |
Donovan-Merkert BT, Rieger PH, Geiger WE. Reactions of odd-electron cobaltacycles: Characterization of a persistent 17-electron anionic intermediate in electron-transfer-catalyzed (ETC) substitution reactions Organometallics. 18: 3194-3200. DOI: 10.1021/Om990246G |
0.408 |
|
| 1999 |
Connelly NG, Geiger WE, Lovelace SR, Metz B, Paget TJ, Winter R. Reduction of [ML(alkyne)2(η-C5R′5)]+ (M = Mo or W, L = MeCN or CO, R′ = H or Me, C5R′5 = C5HPh4): Characterization of radical intermediates in the reductive coupling of coordinated alkynes Organometallics. 18: 3201-3207. DOI: 10.1021/Om990089L |
0.385 |
|
| 1999 |
Orsini J, Geiger WE. Electrochemical Characterization of Equilibria Involving Catalyst Precursors: Cyclic Voltammetry of Labile Organorhodium Complexes in Coordinating Solvents Organometallics. 18: 1854-1861. DOI: 10.1021/Om9900566 |
0.403 |
|
| 1999 |
Winter RF, Geiger WE. Electron-Transfer Properties of Cp*FeP5: Evidence for Dimerization Reactions following both Oxidation and Reduction Organometallics. 18: 1827-1833. DOI: 10.1021/Om9809724 |
0.478 |
|
| 1999 |
Stoll ME, Lovelace SR, Geiger WE, Schimanke H, Hyla-Kryspin I, Gleiter R. Transannular effects in dicobalta-superphane complexes on the mixed- valence class II/class III interface: Distinguishing between spin and charge delocalization by electrochemistry, spectroscopy, and ab initio calculations Journal of the American Chemical Society. 121: 9343-9351. DOI: 10.1021/Ja9914792 |
0.413 |
|
| 1999 |
Robben MP, Rieger PH, Geiger WE. Geometric preferences of tricobalt clusters having 47-49 valence electron counts: Deceptively simple cyclic voltammetric responses and EPR evidence for exchange-coupled dimers in frozen solutions Journal of the American Chemical Society. 121: 367-375. DOI: 10.1021/Ja983341+ |
0.396 |
|
| 1999 |
Chin TT, Grimes RN, Geiger WE. A delocalized analogue of the bicobaltocene cation derived from reduction of a d6d6 (fulvalenediyl)bis(cobaltacarborane) complex: Electrochemistry, ESR, optical spectroscopy, and IR spectroscopy of the carborane group Inorganic Chemistry. 38: 93-99. DOI: 10.1021/Ic980382Y |
0.43 |
|
| 1999 |
Quarmby IC, Hemond RC, Feher FJ, Green M, Geiger WE. Redox properties of the 17-electron sandwich (η5-C5H5)Mo(η6-C6Ph6): electrochemical characterization of the 16 e− Lewis acid monocation and its PF6− adduct Journal of Organometallic Chemistry. 577: 189-196. DOI: 10.1016/S0022-328X(98)01038-9 |
0.462 |
|
| 1998 |
Shaw MJ, Geiger WE, Hyde J, White C. 16-Electron through 19-Electron Complexes of the 1,5-COD and 1,3-COD Isomers of (η5-C5Ph5)Rh(η4-C8H12): Electrochemical Evidence for an Oxidatively Induced Agostic Interaction† Organometallics. 17: 5486-5491. DOI: 10.1021/Om980788I |
0.472 |
|
| 1998 |
DiMaio A, Rheingold AL, Chin TT, Pierce DT, Geiger WE. Electrochemical and Structural Characterization ofcis- andtrans-[Cp(CO)Ru(μ-As(C6H5)2)]2, Isomers That Undergo Two-Electron-Transfer Oxidations† Organometallics. 17: 1169-1176. DOI: 10.1021/Om9709998 |
0.482 |
|
| 1998 |
DiMaio AJ, Rheingold AL, Chin TT, Pierce DT, Geiger WE. Electrochemical and structural characterization of cis-and trans-[Cp(CO)Ru(μ-As(C6H5)2)]2, isomers that undergo two-electron-transfer oxidations Organometallics. 17: 1169-1176. |
0.395 |
|
| 1997 |
Geiger WE, Shaw MJ, Wünsch M, Barnes CE, Foersterling FH. Comparison of isomerization rates of the metal carbonyl cluster Cp*IrCp2Co2(CO)3 in three oxidation states (47e, 48e, 49e): Dramatic rate enhancements in the odd-electron species Journal of the American Chemical Society. 119: 2804-2811. DOI: 10.1021/Ja963476K |
0.397 |
|
| 1996 |
Connelly NG, Geiger WE. Chemical Redox Agents for Organometallic Chemistry. Chemical Reviews. 96: 877-910. PMID 11848774 DOI: 10.1021/Cr940053X |
0.439 |
|
| 1996 |
Koeslag MA, Baird MC, Lovelace S, Geiger WE. Synthesis and Properties of the 17-Electron, Tantalum-Centered Radical Ta(CO)4(Ph2PCH2CH2PPh2) Organometallics. 15: 3289-3302. DOI: 10.1021/Om960133M |
0.451 |
|
| 1996 |
Mevs JM, Geiger WE. Nineteen-Electron Radicals of the Type (η6-C6Me6)Co(η4-diolefin): Electrochemistry and ESR Results Organometallics. 15: 2350-2353. DOI: 10.1021/Om9600194 |
0.433 |
|
| 1996 |
Wooster TT, Gamm PR, Geiger WE, Oliver AM, Black AJ, Craig DC, Paddon-Row MN. Synthesis and surface-confined electrochemistry of dimethoxynaphthalene fused through rigid norbornylogous spacers to thiolate, dithiolate, and bisulfide groups Langmuir. 12: 6616-6626. DOI: 10.1021/La9609027 |
0.422 |
|
| 1996 |
Rulkens R, Lough AJ, Manners I, Lovelace SR, Grant C, Geiger WE. Linear oligo(ferrocenyldimethylsilanes) with between two and nine ferrocene units: Electrochemical and structural models for poly(ferrocenylsilane) high polymers Journal of the American Chemical Society. 118: 12683-12695. DOI: 10.1021/Ja962470S |
0.386 |
|
| 1996 |
Chin TT, Geiger WE, Rheingold AL. Relation of structural changes to electron-transfer parameters in fulvalenediyl dirhodium complexes demonstrating quasi-reversible two-electron voltammetry Journal of the American Chemical Society. 118: 5002-5010. DOI: 10.1021/Ja960259A |
0.435 |
|
| 1996 |
Koeslag MA, Baird MC, Lovelace S, Geiger WE. Synthesis and properties of the 17-electron, tantalum-centered radical Ta(CO)4(Ph2PCH2CH2PPb2) Organometallics. 15: 3289-3302. |
0.359 |
|
| 1996 |
Mevs JM, Geiger WE. Nineteen-electron radicals of the type (η6-C6Me6)Co(η4-diolefin): Electrochemistry and ESR results Organometallics. 15: 2350-2353. |
0.328 |
|
| 1995 |
Wooster TT, Geiger WE, Ernst RD. Quantitative study of the interconversion of S and U isomers of Cp(η5-pentadienyl)Cr(CO) in 18- and 17-electron complexes: Cyclic voltammetric study of an organometallic square scheme Organometallics. 14: 3455-3460. DOI: 10.1021/Om00007A053 |
0.392 |
|
| 1995 |
Chin TT, Sharp LI, Geiger WE, Rieger PH. Characterization of the 17-electron radical cation [CpCo(1,5-COD)]+ by ESR spectroscopy Organometallics. 14: 1322-1326. DOI: 10.1021/Om00003A037 |
0.337 |
|
| 1995 |
Chin TT, Geiger WE. Organometallic mixed-valent ions with d7d8 and d8d9 electronic configurations derived from (fulvalenediyl)Co2(COD)2 Organometallics. 14: 1316-1321. DOI: 10.1021/Om00003A036 |
0.418 |
|
| 1995 |
Connelly NG, Geiger WE, Lagunas MC, Metz B, Rieger AL, Rieger PH, Shaw MJ. Electron-transfer-induced interconversion of alkyne and vinylidene chromium complexes: A quantitative study Journal of the American Chemical Society. 117: 12202-12208. DOI: 10.1021/Ja00154A021 |
0.371 |
|
| 1995 |
Geiger WE. Deducing Structures of 19-Electron Complexes from Studies of Metal Polyolefin Radicals Accounts of Chemical Research. 28: 351-357. DOI: 10.1021/Ar00056A005 |
0.4 |
|
| 1995 |
Atwood CG, Geiger WE, Bitterwolf TE. Anodic infrared spectroelectrochemistry of mono- and dinuclear complexes containing the (η5-C5H4R) Mn(CO)2L moiety (L = CO or PR3) Journal of Electroanalytical Chemistry. 397: 279-285. DOI: 10.1016/0022-0728(95)04201-X |
0.397 |
|
| 1995 |
Orsini J, Geiger WE. Electrochemical reduction of the bis(cyclo-octadiene)rhodium monocation: generation and fate of the 17-electron radical Journal of Electroanalytical Chemistry. 380: 83-90. DOI: 10.1016/0022-0728(94)03602-Y |
0.432 |
|
| 1995 |
Lichtenberger DL, Gruhn NE, Rempe ME, Geiger WE, Chin TT. Ligand-mediated metal-metal interactions in (ν5:ν5-fulvalene) bis (dicarbonylcobalt) and rhodium complexes Inorganica Chimica Acta. 240: 623-629. DOI: 10.1016/0020-1693(95)04591-0 |
0.42 |
|
| 1994 |
Winter R, Pierce DT, Geiger WE, Lynch TJ. Stepwise oxidation of three communicating metal centres: Electrochemistry of trinuclear trindenyl complexes of manganese or rhodium Journal of the Chemical Society, Chemical Communications. 1949-1950. DOI: 10.1039/C39940001949 |
0.425 |
|
| 1994 |
Richards TC, Geiger WE, Baird MC. Measurement Of Fast Dimerization Rates By Cyclic Voltammetry : Comparison Of The 17E Radicals (Eta 5-C5R5(Cr(Co)3 (R=H, Ch3) At Low Temperatures Organometallics. 13: 4494-4500. DOI: 10.1021/Om00023A060 |
0.306 |
|
| 1994 |
Atwood CG, Geiger WE. Low-energy electronic absorptions in 17-electron organometallic piano stool radicals Journal of the American Chemical Society. 116: 10849-10850. DOI: 10.1021/Ja00102A086 |
0.326 |
|
| 1994 |
Richards TC, Geiger WE. Competition between homogeneous and heterogeneous electron-transfer pathways in an electrochemical square scheme Journal of the American Chemical Society. 116: 2028-2033. DOI: 10.1021/Ja00084A049 |
0.393 |
|
| 1994 |
Pierce DT, Geiger WE. Mixed-valent interactions in rigid dinuclear systems: Electrochemical and spectroscopic studies of CrICr0 ions with controlled torsion of the biphenyl bridge Inorganic Chemistry. 33: 373-381. |
0.303 |
|
| 1993 |
Richardson DE, Ryan MF, Geiger WE, Chin TT, Hughes RP, Curnow OJ. Gas-phase and solution studies of the oxidation of the first perfluorocyclopentadienyl complex, [Ru(.eta.5-C5Me5)(.eta.5-C5F5)] Organometallics. 12: 613-615. DOI: 10.1021/Om00027A007 |
0.342 |
|
| 1993 |
Hoobler RJ, Hutton MA, Dillard MM, Castellani MP, Rheingold AL, Rieger AL, Rieger PH, Richards TC, Geiger WE. Synthesis, characterization, and crystal structure of the (η5-C5Ph5)Cr(CO)3 radical Organometallics. 12: 116-123. DOI: 10.1021/Om00025A023 |
0.321 |
|
| 1993 |
Atwood CG, Geiger WE, Rheingold AL. Structural consequences of electron-transfer reactions. 26. Evidence for time-dependent valence detrapping in a mixed-valent dimanganese fulvalenyl cation Journal of the American Chemical Society. 115: 5310-5311. DOI: 10.1021/Ja00065A059 |
0.356 |
|
| 1993 |
Katz TJ, Sudhakar A, Teasley MF, Gilbert AM, Geiger WE, Robben MP, Wuensch M, Ward MD. Synthesis and properties of optically active helical metallocene oligomers Journal of the American Chemical Society. 115: 3182-3198. DOI: 10.1021/Ja00061A018 |
0.318 |
|
| 1993 |
Geiger WE, Rieger PH, Corbato C, Edwin J, Fonseca E, Lane GA, Mevs JM. Structural consequences of electron-transfer reactions. 25. Electron-transfer-induced isomerizations of cobalt-, nickel-, and palladium-cyclooctatetraene complexes: the role played by the ligand vs. metal composition of the redox orbital Journal of the American Chemical Society. 115: 2314-2323. DOI: 10.1021/Ja00059A028 |
0.396 |
|
| 1992 |
Merkert JW, Geiger WE, Paddon-Row MN, Oliver AM, Rheingold AL. Complexes with two (arene)chromium tricarbonyl moieties separated by rigid spacers: Preparation, X-ray structures, and oxidative voltammetry Organometallics. 11: 4109-4116. DOI: 10.1021/Om00060A030 |
0.401 |
|
| 1992 |
Quarmby IC, Geiger WE. Oxidation of syn-dirhodium complexes of cyclohepta- and cyclooctatriene: Influence of C-H bond activation in multiple electron-transfer reactions Organometallics. 11: 436-442. DOI: 10.1021/Om00037A070 |
0.5 |
|
| 1992 |
Merkert JW, Davis JH, Geiger WE, Grimes RN. Delocalization in bimetallic triple-decker complexes: Electrochemistry, ESR spectroscopy, and spectroelectrochemistry of (p-MeC6H4CHMe2)2Ru 2(Et2C2B3H3) and CpCo(Et2C2B3H3)Ru(p-MeC 6H4CHMe2) and derived ions Journal of the American Chemical Society. 114: 9846-9851. DOI: 10.1021/Ja00051A017 |
0.36 |
|
| 1992 |
Pierce DT, Geiger WE. Electrochemical kinetic discrimination of the single-electron-transfer events of a two-electron-transfer reaction: Cyclic voltammetry of the reduction of the bis(hexamethylbenzene)ruthenium dication Journal of the American Chemical Society. 114: 6063-6073. DOI: 10.1021/Ja00041A026 |
0.429 |
|
| 1991 |
Connelly NG, Geiger WE, Orpen AG, Orsini JJ, Richardson KE. Synthesis of asymmetric alkyne-bridged dipalladium complexes from the paramagnetic cation [Pd2(μ-PhC2Ph)(η-C5Ph5) 2]+; Crystal structures of [Pd2(bipy)(μ-PhC2Ph)(η-C5Ph 5)][Pd2(NCMe)(bipy)(μ-PhC2Ph)(η-C 5Ph5)].. Journal of the Chemical Society, Dalton Transactions. 2967-2977. DOI: 10.1039/Dt9910002967 |
0.31 |
|
| 1991 |
Geiger WE, Van Order N, Pierce DT, Bitterwolf TE, Rheingold AL, Chasteen ND. Class II mixed-valent complexes from oxidation of doubly linked (arene)chromium compounds Organometallics. 10: 2403-2411. DOI: 10.1021/Om00053A051 |
0.372 |
|
| 1991 |
Mevs JM, Gennett T, Geiger WE. Cp3M3(CO)3 clusters: electrocatalytic isomerization and effect of changes in metal and carbon monoxide bonding mode on electron-transfer properties Organometallics. 10: 1229-1236. DOI: 10.1021/Om00051A006 |
0.335 |
|
| 1991 |
DeGray JA, Geiger WE, Lane GA, Rieger PH. Palladium(I) π complexes: An ESR study of (pentaphenylcyclopentadienyl)palladium dibenzocyclooctatetraene Inorganic Chemistry. 30: 4100-4102. DOI: 10.1021/Ic00021A027 |
0.336 |
|
| 1990 |
Donovan BT, Geiger WE. Reductive acceleration of the migratory insertion reaction: evidence that insertion occurs in a 19-electron intermediate Organometallics. 9: 865-866. DOI: 10.1021/Om00117A054 |
0.316 |
|
| 1990 |
Geiger WE, Salzer A, Edwin J, Von Philipsborn W, Piantini U, Rheingold AL. Structural consequences of electron-transfer reactions. Part 22. Electrochemically induced insertion of ruthenium atoms into a carbon-carbon bond: reversible slicing of a cyclooctatetraene ligand Journal of the American Chemical Society. 112: 7113-7121. DOI: 10.1021/Ja00176A005 |
0.413 |
|
| 1990 |
Edwin J, Geiger WE. Structural changes coupled to two-electron-transfer reactions: Oxidation mechanism of pseudo-triple-decker complexes of Co and Rh Journal of the American Chemical Society. 112: 7104-7112. DOI: 10.1021/Ja00176A004 |
0.477 |
|
| 1990 |
Plitzko KD, Rapko B, Gollas B, Wehrle G, Weakley T, Pierce DT, Geiger WE, Haddon RC, Boekelheide V. Bis(.eta.6-hexamethylbenzene)(.eta.6,.eta.6-[2n]cyclophane)diruthenium(II,II) complexes and their two-electron reduction to [2n]cyclophane derivatives having two cyclohexadienyl anion decks joined by an extremely long carbon-carbon bond Journal of the American Chemical Society. 112: 6545-6556. DOI: 10.1021/Ja00174A015 |
0.352 |
|
| 1989 |
Merkert JM, Geiger WE, Davis JH, Attwood MD, Grimes RN. Carborane-stabilized M(III) complexes of mononuclear and dinuclear arene complexes (M = iron, ruthenium) Organometallics. 8: 1580-1581. DOI: 10.1021/Om00108A041 |
0.317 |
|
| 1989 |
Pufahl D, Geiger WE, Connelly NG. Confirmation of a radical mechanism in the alkyne-linkage reduction reaction of the [(.eta.5-C5H5)Mo(C2Me2)2(NCMe)]+ cation Organometallics. 8: 412-415. DOI: 10.1021/Om00104A022 |
0.353 |
|
| 1989 |
Bowyer WJ, Merkert JW, Geiger WE, Rheingold AL. Structural consequences of electron-transfer reactions. Part 18. Redox-induced hapticity changes: effect of substituents on arene bending in a series of rhodium complexes Organometallics. 8: 191-198. DOI: 10.1021/Om00103A025 |
0.399 |
|
| 1989 |
Pierce DT, Geiger WE. Structural consequences of electron-transfer reactions. Part XX. Splitting of a two-electron cyclic voltammetric wave into its one-electron components: the (.eta.-C6Me6)2Ru2+/+/0) couples Journal of the American Chemical Society. 111: 7636-7638. DOI: 10.1021/Ja00201A067 |
0.366 |
|
| 1989 |
Merkert J, Nielson RM, Weaver MJ, Geiger WE. Structural consequences of electron-transfer reactions. 19. NMR evidence for a planar arene intermediate in the electron-transfer-induced .eta.6 to .eta.4 hapticity change of a rhodium arene complex Journal of the American Chemical Society. 111: 7084-7087. DOI: 10.1021/Ja00200A029 |
0.409 |
|
| 1989 |
Merkert J, Nielson RM, Weaver MJ, Geiger WE. NMR evidence for a planar arene intermediate in the electron-transfer-induced η6 to η4 hapticity change of a rhodium arene complex Journal of the American Chemical Society. 111: 7084-7087. |
0.311 |
|
| 1988 |
Edwin J, Geiger WE, Hackett Bushweller C. Rearrangement mechanisms in slipped triple-decker complexes of cobalt and rhodium Organometallics. 7: 1486-1490. DOI: 10.1021/Om00097A006 |
0.308 |
|
| 1988 |
Brammer L, Connelly NG, Edwin J, Geiger WE, Orpen AG, Sheridan JB. Structural consequences of electron transfer reactions. Pt. 17. One-electron oxidation of (N4-cot)RhCp: rearrangements of the radicalcation and of the resulting dimerization product Organometallics. 7: 1259-1265. DOI: 10.1021/Om00096A004 |
0.402 |
|
| 1988 |
Fonseca E, Geiger WE, Bitterwolf TE, Rheingold AL. Dimerization of a 17-electron cation radical by formation of a rhodium-rhodium bond Organometallics. 7: 567-568. DOI: 10.1021/Om00092A057 |
0.416 |
|
| 1988 |
Donovan BT, Geiger WE. A model for the unsaturated intermediate in dissociative electron-transfer-catalyzed substitution reactions of organometallic compounds Journal of the American Chemical Society. 110: 2335-2337. DOI: 10.1021/Ja00215A073 |
0.353 |
|
| 1988 |
Bowyer WJ, Geiger WE. Analysis of a quasi-reversible two-electron cyclic voltammetric wave for an organometallic ir(III)/ir(I) couple at platinum and mercury electrodes Journal of Electroanalytical Chemistry. 239: 253-271. DOI: 10.1016/0022-0728(88)80284-5 |
0.396 |
|
| 1988 |
Brammer L, Connelly NG, Edwin J, Geiger WE, Orpen AG, Sheridan JB. One-electron oxidation of (η4-cot)RhCp: Rearrangements of the radical cation and of the resulting dimerization product Organometallics. 7: 1259-1265. |
0.317 |
|
| 1987 |
Connelly NG, Raven SJ, Geiger WE. Reduction-oxidation properties of organotransition-metal complexes. Part 25. The one-electron reduction of cationic cyclopentadienyl-cobalt and -rhodium nitrosyl derivatives Journal of the Chemical Society, Dalton Transactions. 467-472. DOI: 10.1039/Dt9870000467 |
0.454 |
|
| 1987 |
Geiger WE, Gennett T, McVicar WK, Herrmann WA. Transition metal methylene complexes. 65. Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium Organometallics. 6: 1634-1639. DOI: 10.1021/Om00151A007 |
0.418 |
|
| 1987 |
Kelly RS, Geiger WE. Cobaltacycles in three oxidation states: Redox properties and reaction routes Organometallics. 6: 1432-1439. DOI: 10.1021/Om00150A012 |
0.507 |
|
| 1987 |
Carl RT, Doig SJ, Geiger WE, Hemond RC, Hughes RP, Kelly RS, Samkoff DE. Pentamethylcyclopentadienyl cobalt and rhodium complexes of octafluorocyclooctatetraene. Photochemical and thermal interconversion of 1,2,5,6-.eta.- and 1,2,3,6-.eta.-C8F8 isomers. Electrochemical and ESR characterization of the 19-electron radical anion [Co(.eta.-C5Me5)(1,2,5,6-.eta.-C8F8)]- Organometallics. 6: 611-616. DOI: 10.1021/Om00146A029 |
0.414 |
|
| 1987 |
Edwin J, Geiger WE, Salzer A, Ruppli U, Rheingold AL. Structural consequences of electron-transfer reactions 17. Electrochemically induced reversible insertion of ruthenium atoms into an eight-carbon chain Journal of the American Chemical Society. 109: 7893-7894. DOI: 10.1021/Ja00259A054 |
0.356 |
|
| 1987 |
Van Order N, Geiger WE, Bitterwolf TE, Rheingold AL. Mixed-valent cations of dinuclear chromium aryl complexes: Electrochemical, spectroscopic, and structural considerations Journal of the American Chemical Society. 109: 5680-5690. DOI: 10.1021/Ja00253A019 |
0.372 |
|
| 1987 |
Gennett T, Geiger WE, Willett B, Anson FC. Structural consequences of electron-transfer reactions. Part XIV. Fast charge-transfer reactions of binuclear complexes undergoing large changes in metalmetal bond lengths Journal of Electroanalytical Chemistry. 222: 151-160. DOI: 10.1016/0022-0728(87)80283-8 |
0.445 |
|
| 1987 |
Geiger WE, Gennett T, McVicar WK, Herrmann WA. Electrochemical oxidation and reduction of methylene-bridged complexes of manganese, cobalt, and rhodium Organometallics. 6: 1634-1639. |
0.37 |
|
| 1987 |
Carl RT, Doig SJ, Geiger WE, Hemond RC, Hughes RP, Kelly RS, Samkoff DE. Pentamethylcyclopentadienyl cobalt and rhodium complexes of octafluorocyclooctatetraene. Photochemical and thermal interconversion of 1,2,5,6-μ- and 1,2,3,6-η-C8F8 isomers. Electrochemical and ESR characterization of the 19-electron radical anion [Co(η-C5Me5)(1,2,5,6-η-C8F 8)]- Organometallics. 6: 611-616. |
0.306 |
|
| 1986 |
Broadley K, Connelly NG, Lane GA, Geiger WE. The electron-transfer properties of alkyne-bridged dipalladium complexes: Synthesis and reactions of [Pd2(μ-PhC2Ph)(η-C5Ph5) 2][PF6], and comments on the mechanism of the oxidative cleavage of binuclear organotransition-metal complexes Journal of the Chemical Society, Dalton Transactions. 373-376. DOI: 10.1039/Dt9860000373 |
0.445 |
|
| 1986 |
Geiger WE, Gennett T, Lane GA, Salzer A, Rheingold AL. Radicals of C7-polyolefin cobalt complexes: Electrochemistry, reaction routes, and structure of a resulting dimer Organometallics. 5: 1352-1359. DOI: 10.1021/Om00138A010 |
0.454 |
|
| 1986 |
Geiger WE, Gennett T, Grzeszczuk M, Lane GA, Moraczewski J, Salzer A, Smith DE. Interconversion of conjugated and nonconjugated polyolefin-cobalt complexes in two oxidation states: An electrochemical and NMR study Journal of the American Chemical Society. 108: 7454-7461. DOI: 10.1021/Ja00284A002 |
0.358 |
|
| 1986 |
Connelly NG, Geiger WE, Lane GA, Raven SJ, Rieger PH. Stabilization of anion radicals by the pentaphenylcyclopentadienyl ligand. Evidence for symmetrical metal-C5R5 bonding in [(.eta.-C5Ph5)M(CO2)]- (M = Co, Rh). Journal of the American Chemical Society. 108: 6219-6224. DOI: 10.1021/Ja00280A018 |
0.327 |
|
| 1986 |
Broadley K, Connelly NG, Lane GA, Geiger WE. The Electron-transfer Properties of Alkyne-bridged Dipalladium Complexes: Synthesis and Reactions of [Pd2(μ-PhC2Ph)(η-C5Ph5)2][PF6], and Comments on the Mechanism of the Oxidative Cleavage of Binuclear Organotransition-metal Complexes Cheminform. 17. DOI: 10.1002/Chin.198623301 |
0.425 |
|
| 1985 |
Tulyathan B, Geiger WE. Structural consequences of electron-transfer reactions. Part 12. Multi electron processes involving structural changes. The two-electron reduction of hexaosmium carbonyl cluster (Os6(CO)18) Journal of the American Chemical Society. 107: 5960-5967. DOI: 10.1021/Ja00307A022 |
0.352 |
|
| 1985 |
Bowyer WJ, Geiger WE. Structural consequences of electron-transfer reactions. 11. Electrochemically induced changes in hapticity in mixed-sandwich compounds of iridium and rhodium Journal of the American Chemical Society. 107: 5657-5663. DOI: 10.1021/Ja00306A011 |
0.384 |
|
| 1985 |
Geiger WE, Rieger PH, Tulyathan B, Rausch MD. Structural Consequences Of Electron-Transfer Reactions. 10. Evidence For Bending Of A Nitrosyl Group During One-Electron Reduction Of Cyclopentadienyl Metal Nitrosyl Compounds Cheminform. 16. DOI: 10.1002/Chin.198510312 |
0.388 |
|
| 1985 |
Bowyer WJ, Geiger WE. Electrochemically induced changes in hapticity in mixed-sandwich compounds of iridium and rhodium Journal of the American Chemical Society. 107: 5657-5663. |
0.353 |
|
| 1984 |
Clamp S, Connelly NG, Howard JAK, Manners I, Payne JD, Geiger WE. Synthesis and reactivity of binuclear cyclopentadienylrhodium nitrosyl cations, and the X-ray structure of [Rh2(μ-CO)(μ-NO)(η- C5Me5)2][PF6] Journal of the Chemical Society, Dalton Transactions. 1659-1665. DOI: 10.1039/Dt9840001659 |
0.394 |
|
| 1984 |
Edwin J, Geiger WE. Electrochemical studies of the preparation and one-electron reduction of half-sandwich cobalt-arene cations Organometallics. 3: 1910-1911. DOI: 10.1021/Om00090A020 |
0.363 |
|
| 1984 |
Bowyer WJ, Geiger WE, Boekelheide V. An electrochemical study of the reduction of mono- and bis(iron) cyclophane complexes Organometallics. 3: 1079-1086. DOI: 10.1021/Om00085A020 |
0.375 |
|
| 1984 |
Geiger WE, Rieger PH, Tulyathan B, Rausch MD. Structural consequences of electron-transfer reactions. 10. Evidence for bending of a nitrosyl group during one-electron reduction of cyclopentadienyl metal nitrosyl compounds Journal of the American Chemical Society. 106: 7000-7006. DOI: 10.1021/Ja00335A023 |
0.385 |
|
| 1984 |
Edwin J, Geiger WE, Rheingold AL. Structural rearrangements in the two-electron oxidations of dimetal cyclooctatetraene compounds. Structure of the 34-electron triple-decker dication Journal of the American Chemical Society. 106: 3052-3053. DOI: 10.1021/Ja00322A061 |
0.416 |
|
| 1984 |
Connelly NG, Geiger WE. The Electron-Transfer Reactions of Mononuclear Organotransition Metal Complexes Advances in Organometallic Chemistry. 23: 1-93. DOI: 10.1016/S0065-3055(08)60414-1 |
0.433 |
|
| 1983 |
Connelly NG, Lucy AR, Payne JD, Galas AMR, Geiger WE. Reduction-oxidation properties of organotransition-metal complexes. Part 17. The reaction of [Rh(CO)(PPh3)(η-C5H5)] with one-electron oxidants: Fulvalene complex and silver adduct formation, and the x-ray crystal structure of [Ag{Rh(CO)(PPh3)(η-C5H5)} 2][PF6]·C6H5Me Journal of the Chemical Society, Dalton Transactions. 1879-1885. DOI: 10.1039/Dt9830001879 |
0.414 |
|
| 1983 |
Connelly NG, Payne JD, Geiger WE. Reduction-oxidation properties of organotransition-metal complexes. Part 16. Nitrosyl-bridged dicobalt complexes [{Co(η-NO)(η-C5R5)}2]z (R = H or Me, z = 0 to +2) and [Co2(μ-CO)(μ-NO)(η-C5Me5) 2]z (z = 0 or +1): Synthesis, electrochemistry, and relative reactivity Journal of the Chemical Society, Dalton Transactions. 295-299. DOI: 10.1039/Dt9830000295 |
0.405 |
|
| 1983 |
Broadley K, Connelly NG, Geiger WE. Reduction-oxidation properties of organotransition-metal complexes. Part 15. Synthesis, electrochemistry, and reactivity of the radical cations [Co(CO)2-nLn(η-C5R5)] + (n = 1 or 2, L = phosphine, R = H or Me) Journal of the Chemical Society, Dalton Transactions. 121-125. DOI: 10.1039/Dt9830000121 |
0.36 |
|
| 1983 |
Edwin J, Bochmann M, Boehm MC, Brennan DE, Geiger WE, Krueger C, Pebler J, Pritzkow H, Siebert W. Triple-decker complexes. 8. Triple-decker sandwiches. Syntheses, reactivity, electrochemistry, and x-ray crystal and electronic structures of bis(cyclopentadienylmetal)-.mu.-1,3-diborolenyl complexes with 29-34 valence electrons Journal of the American Chemical Society. 105: 2582-2598. DOI: 10.1021/Ja00347A013 |
0.364 |
|
| 1983 |
Broadley K, Lane GA, Connelly NG, Geiger WE. Electrochemical routes to paramagnetic dinuclear and mononuclear palladium π complexes stabilized by the pentaphenylcyclopentadienyl ligand Journal of the American Chemical Society. 105: 2486-2487. DOI: 10.1021/Ja00346A070 |
0.354 |
|
| 1983 |
Grzeszczuk M, Smith DE, Geiger WE. Structural consequences of electron-transfer reactions. 8. Elucidation of isomerization mechanism of the radical anion of (η4-cyclooctatetraene)cyclopentadienylcobalt with FFT faradaic admittance measurements Journal of the American Chemical Society. 105: 1772-1776. DOI: 10.1021/Ja00345A013 |
0.382 |
|
| 1983 |
CONNELLY NG, LUCY AR, PAYNE JD, GALAS AMR, GEIGER WE. ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 17. THE REACTION OF (RH(CO)(PPH3)(η-C5H5)) WITH ONE-ELECTRON OXIDANTS: FULVALENE COMPLEX AND SILVER ADDUCT FORMATION, AND THE X-RAY CRYSTAL STRUCTURE OF BIS(CARB Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198351306 |
0.463 |
|
| 1983 |
CONNELLY NG, PAYNE JD, GEIGER WE. ChemInform Abstract: REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 16. NITROSYL-BRIDGED DICOBALT COMPLEXES ((CO(μ-NO)(η-C5R5))2)Z (R = H OR ME, Z = 0 TO +2) AND (CO2(μ-CO)(μ-NO)(η-C5ME5)2)Z (Z = 0 OR +1): SYNTHESIS, ELECTROCHEMI Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198320279 |
0.388 |
|
| 1983 |
Broadley K, Connelly NG, Geiger WE. REDUCTION-OXIDATION PROPERTIES OF ORGANOTRANSITION METAL COMPLEXES. PART 15. SYNTHESIS, ELECTROCHEMISTRY, AND REACTIVITY OF THE RADICAL CATIONS (CO(CO)2-NLN(η-C5R5))+ (N = 1 OR 2, L = PHOSPHINE, R = H OR ME) Cheminform. 14. DOI: 10.1002/Chin.198317286 |
0.403 |
|
| 1982 |
Geiger WE. Electrochemical study of the oxidative cleavage of cobalt-polyolefin compounds in strongly and weakly coordinating solvents Organometallics. 1: 1385-1389. DOI: 10.1021/Om00070A023 |
0.432 |
|
| 1982 |
Lane G, Geiger WE. Cyclopentadienylnickel cyclooctadiene: a stable organometallic .pi.-radical containing a nonconjugated polyolefin Organometallics. 1: 401-402. DOI: 10.1021/Om00062A030 |
0.324 |
|
| 1982 |
Geiger WE, Brennan DE, Little JL. Electrochemical study of high and low cobalt oxidation states in Group V substituted borane clusters Inorganic Chemistry. 21: 2529-2531. DOI: 10.1021/Ic00137A001 |
0.343 |
|
| 1982 |
Geiger WE, Brennan DE. Comparison of the redox properties of small metallacarboranes with those of metallocenes and large metallacarborane clusters Inorganic Chemistry. 21: 1963-1966. DOI: 10.1021/Ic00135A050 |
0.403 |
|
| 1982 |
Geiger WE, Brennan DE, Little JL. Electrochemical Study Of High And Low Cobalt Oxidation States In Group V Substituted Borane Clusters Cheminform. 13. DOI: 10.1002/Chin.198240298 |
0.343 |
|
| 1981 |
Albright TA, Geiger WE, Moraczewski J, Tulyathan B. Structural consequences of electron-transfer reactions. 6. Electronic structures and structural preferences of cyclooctatetraene and cyclooctadiene iron and cobalt compounds and their radical anions Journal of the American Chemical Society. 103: 4787-4794. DOI: 10.1021/Ja00406A020 |
0.377 |
|
| 1981 |
Moraczewski J, Geiger WE. Structural consequences of electron-transfer reactions. 5. Electrochemically induced isomerizations of (cyclooctadiene)- and (cyclooctatetraene)cobalt compounds Journal of the American Chemical Society. 103: 4779-4787. DOI: 10.1021/Ja00406A019 |
0.454 |
|
| 1980 |
Tulyathan B, Geiger WE. Structural consequences of electron-transfer reactions Journal of Electroanalytical Chemistry. 109: 325-331. DOI: 10.1016/S0022-0728(80)80129-X |
0.343 |
|
| 1979 |
Moraczewski J, Geiger WE. Structural consequences of electron-transfer reactions. 3. Electrochemical isomerization of a metal-hydrocarbon bond in the reduction of cyclopentadienylcobalt cyclooctatetraene [22] Journal of the American Chemical Society. 101: 3407-3408. DOI: 10.1021/Ja00506A059 |
0.402 |
|
| 1979 |
Holloway JDL, Geiger WE. Electron-transfer reactions of metallocenes. Influence of metal oxidation state on structure and reactivity Journal of the American Chemical Society. 101: 2038-2044. DOI: 10.1021/Ja00502A018 |
0.457 |
|
| 1979 |
Geiger WE, Bowden WL, El Murr N. An electrochemical study of the protonation site of the cobaltocene anion and of cyclopentadienylcobalt(I) dicarbollides Inorganic Chemistry. 18: 2358-2361. DOI: 10.1021/Ic50199A006 |
0.405 |
|
| 1979 |
El Murr N, Sheats JE, Geiger WE, Holloway JDL. Electrochemical reduction pathways of the rhodocenium ion. Dimerization and reduction of rhodocene Inorganic Chemistry. 18: 1443-1446. DOI: 10.1021/Ic50196A007 |
0.384 |
|
| 1978 |
Moraczewski J, Geiger WE. Electrochemical properties of bis(cyclopentadienylcobalt)cyclooctatetraene. Formation of a 34-electron triple-decker compound [17] Journal of the American Chemical Society. 100: 7429-7431. DOI: 10.1021/Ja00491A059 |
0.366 |
|
| 1978 |
Senftleber FC, Geiger WE. Comparison of the electrochemical properties and electron spin resonance spectra of thio and imino chelates Inorganic Chemistry. 17: 3615-3622. DOI: 10.1021/Ic50190A056 |
0.43 |
|
| 1978 |
Bowden WL, Holloway JDL, Geiger WE. Electrochemical study of the reduction pathways of metal 1,3-dithioketonate complexes Inorganic Chemistry. 17: 256-260. DOI: 10.1021/Ic50180A013 |
0.395 |
|
| 1978 |
Holloway JDL, Senftleber FC, Geiger WE. Vacuum electrochemical cell applied to the oxidation of bis(cyclopentadienyl)chromium Analytical Chemistry. 50: 1010-1013. DOI: 10.1021/Ac50029A049 |
0.386 |
|
| 1977 |
Holloway JDL, Bowden WL, Geiger WE. Unusual electron-transfer processes involving electron-rich and electron-deficient metallocenes Journal of the American Chemical Society. 99: 7089-7090. DOI: 10.1021/Ja00463A066 |
0.321 |
|
| 1977 |
Geiger WE, Allen CS, Mines TE, Senftleber FC. Paramagnetic M(I) complexes generated by the electrochemical reduction of M(II) nickel, palladium, and platinum 1,2-dithiolates Inorganic Chemistry. 16: 2003-2008. DOI: 10.1021/Ic50174A035 |
0.409 |
|
| 1977 |
Willigen HV, Geiger WE, Rausch MD. Paramagnetic complexes produced in the electrochemical and chemical reduction of cyclopentadienyl-cobalt- and -rhodium-cyclopentadienone complexes Inorganic Chemistry. 16: 581-584. DOI: 10.1021/Ic50169A016 |
0.376 |
|
| 1977 |
Bowden WL, Bonnar P, Brown DB, Geiger WE. Electrochemistry of the nitroprusside ion in nonaqueous solvents Inorganic Chemistry. 16: 41-43. DOI: 10.1021/Ic50167A010 |
0.425 |
|
| 1977 |
Willigen HV, Geiger WE, Rausch MD. Paramagnetic complexes produced in the electrochemical and chemical reduction of cyclopentadienyl-cobalt- and -rhodium-cyclopentadienone complexes Cheminform. 8. DOI: 10.1002/Chin.197720176 |
0.376 |
|
| 1977 |
Van Willigen H, Geiger WE, Rausch MD. Paramagnetic complexes produced in the electrochemical and chemical reduction of cyclopentadienyl-cobalt- and -rhodium-cyclopentadienone complexes Inorganic Chemistry. 16: 581-584. |
0.363 |
|
| 1975 |
Senftleber FC, Geiger WE. Stabilization of paramagnetic metal(I) complexes of the nickel subgroup. Electrochemical and electron spin resonance studies of metal dithiolene complexes and their amino analogs [9] Journal of the American Chemical Society. 97: 5018-5020. DOI: 10.1021/Ja00850A048 |
0.363 |
|
| 1975 |
Geiger WE, Mines TE, Senftleber FC. Vacuum electrochemical studies of nickel(I) products and intermediates produced in the reduction of nickel dithiolenes Inorganic Chemistry. 14: 2141-2147. DOI: 10.1021/Ic50151A024 |
0.454 |
|
| 1975 |
Shkolnik GM, Geiger WE. Molecular charge-transfer complexes of metalloporphyrins with bis(cis-1,2-trifluoromethylethylene-1,2-dithiolato)nickel Inorganic Chemistry. 14: 313-317. DOI: 10.1021/Ic50144A021 |
0.36 |
|
| 1974 |
Geiger WE. Electroreduction of cobaltocene. Evidence for a metallocene anion Journal of the American Chemical Society. 96: 2632-2634. DOI: 10.1021/Ja00815A062 |
0.312 |
|
| 1973 |
Geiger WE. Tetrathiotetracene cation radical The Journal of Physical Chemistry. 77: 1862-1864. DOI: 10.1021/J100634A009 |
0.315 |
|
| 1973 |
Mines TE, Geiger WE. Electrochemical generation and spectral characterization of the bis(maleonitriledithiolato)nickel trianion Inorganic Chemistry. 12: 1189-1191. DOI: 10.1021/Ic50123A043 |
0.341 |
|
| 1973 |
Geiger WE. The tetrathiotetracene cation radical Journal of Physical Chemistry. 77: 1862-1864. |
0.351 |
|
| 1971 |
Geiger WE, Smith DE. Electrochemical indications of new oxidation states in transition-metal dicarbollide complexes Journal of the Chemical Society D: Chemical Communications. 8-9. DOI: 10.1039/C29710000008 |
0.376 |
|
| 1971 |
Geiger WE, Maki AH. Donor-Acceptor complexes of phenothiazine and phenoxazine with nickel thiete Journal of Physical Chemistry. 75: 2387-2394. DOI: 10.1021/J100684A027 |
0.564 |
|
| 1970 |
Sullivan PD, Bolton JR, Geiger WE. Oxygen-17 and carbon-13 hyperfine interactions in the electron paramagnetic resonance spectrum of the hydroquinone cation radical Journal of the American Chemical Society. 92: 4176-4180. DOI: 10.1021/Ja00717A006 |
0.3 |
|
| Show low-probability matches. |