John Ralph - Publications

University of Wisconsin, Madison, Madison, WI 
Wood Technology Agriculture, Organic Chemistry, Chemical Engineering

335 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Bourmaud CL, Bertella S, Rico AB, Karlen SD, Ralph J, Luterbacher J. Quantification of native lignin structural features with gel-phase 2D-HSQC0 reveals lignin structural changes during extraction. Angewandte Chemie (International Ed. in English). e202404442. PMID 38738591 DOI: 10.1002/anie.202404442  0.635
2024 Karlen SD, Timokhin VI, Sener C, Mobley JK, Runge T, Ralph J. Production of biomass-derived p-hydroxybenzamide: Synthesis of p-aminophenol and paracetamol. Chemsuschem. e202400234. PMID 38441462 DOI: 10.1002/cssc.202400234  0.613
2023 Lam LPY, Tobimatsu Y, Suzuki S, Tanaka T, Yamamoto S, Takeda-Kimura Y, Osakabe Y, Osakabe K, Ralph J, Bartley LE, Umezawa T. Disruption of p-Coumaroyl-CoA:monolignol transferases in rice drastically alters lignin composition. Plant Physiology. PMID 37831082 DOI: 10.1093/plphys/kiad549  0.311
2023 Yoshioka K, Kim H, Lu F, De Ridder N, Vanholme R, Kajita S, Boerjan W, Ralph J. Hydroxycinnamaldehyde-derived benzofuran components in lignins. Plant Physiology. PMID 37773018 DOI: 10.1093/plphys/kiad514  0.315
2023 Chen M, Li Y, Lu F, Luterbacher JS, Ralph J. Lignin Hydrogenolysis: Phenolic Monomers from Lignin and Associated Phenolates across Plant Clades. Acs Sustainable Chemistry & Engineering. 11: 10001-10017. PMID 37448721 DOI: 10.1021/acssuschemeng.3c01320  0.334
2023 Li H, Kang X, Yang M, Kasseney BD, Zhou X, Liang S, Zhang X, Wen JL, Yu B, Liu N, Zhao Y, Mo J, Currie CR, Ralph J, Yelle DJ. Molecular insights into the evolution of woody plant decay in the gut of termites. Science Advances. 9: eadg1258. PMID 37224258 DOI: 10.1126/sciadv.adg1258  0.731
2023 Chaudhury D, Torkelson ER, Meyers KA, Acheson JF, Landucci LM, Pu Y, Sun Z, Tonelli M, Bingman CA, Smith RA, Karlen SD, Mansfield SD, Ralph J, Fox BG. Rapid Biocatalytic Synthesis of Aromatic Acid CoA Thioesters utilizing Microbial Aromatic Acid CoA Ligases. Chembiochem : a European Journal of Chemical Biology. e202300001. PMID 36821718 DOI: 10.1002/cbic.202300001  0.642
2022 Hellinger J, Kim H, Ralph J, Karlen SD. p-Coumaroylation of lignin occurs outside of commelinid monocots in the eudicot genus Morus (mulberry). Plant Physiology. PMID 36269202 DOI: 10.1093/plphys/kiac485  0.638
2022 Mottiar Y, Smith RA, Karlen SD, Ralph J, Mansfield SD. Evolution of p-coumaroylated lignin in eudicots provides new tools for cell wall engineering. The New Phytologist. PMID 36196006 DOI: 10.1111/nph.18518  0.668
2022 Mottiar Y, Karlen SD, Goacher RE, Ralph J, Mansfield SD. Metabolic engineering of p-hydroxybenzoate in poplar lignin. Plant Biotechnology Journal. PMID 36161690 DOI: 10.1111/pbi.13935  0.638
2022 Unda F, Mottiar Y, Mahon EL, Karlen SD, Kim KH, Loqué D, Eudes A, Ralph J, Mansfield SD. A new approach to zip-lignin? 3,4-Dihydroxybenzoate is compatible with lignification. The New Phytologist. PMID 35377486 DOI: 10.1111/nph.18136  0.671
2022 Smith RA, Lu F, Muro Villanueva F, Cusumano JC, Chapple C, Ralph J. Manipulation of Lignin Monomer Composition Combined with the Introduction of Monolignol Conjugate Biosynthesis Leads to Synergistic Changes in Lignin Structure. Plant & Cell Physiology. PMID 35275214 DOI: 10.1093/pcp/pcac031  0.338
2022 Smith RA, Beebe ET, Bingman CA, Vander Meulen K, Eugene A, Steiner AJ, Karlen SD, Ralph J, Fox BG. Identification and Characterization of a Set of Monocot BAHD Monolignol Transferases. Plant Physiology. PMID 35134228 DOI: 10.1093/plphys/kiac035  0.63
2022 Hu S, Kamimura N, Sakamoto S, Nagano S, Takata N, Liu S, Goeminne G, Vanholme R, Uesugi M, Yamamoto M, Hishiyama S, Kim H, Boerjan W, Ralph J, Masai E, et al. Rerouting of the lignin biosynthetic pathway by inhibition of cytosolic shikimate recycling in transgenic hybrid aspen. The Plant Journal : For Cell and Molecular Biology. PMID 35044002 DOI: 10.1111/tpj.15674  0.321
2021 de Vries L, MacKay HA, Smith RA, Mottiar Y, Karlen SD, Unda F, Muirragui E, Bingman C, Vander Meulen K, Beebe ET, Fox BG, Ralph J, Mansfield SD. pHBMT1, a BAHD-family monolignol acyltransferase, mediates lignin acylation in poplar. Plant Physiology. PMID 34977949 DOI: 10.1093/plphys/kiab546  0.612
2021 Mahon EL, de Vries L, Jang SK, Middar S, Kim H, Unda F, Ralph J, Mansfield SD. Exogenous chalcone synthase expression in developing poplar xylem incorporates naringenin into lignins. Plant Physiology. PMID 34718804 DOI: 10.1093/plphys/kiab499  0.324
2021 Fanelli A, Rancour DM, Sullivan M, Karlen SD, Ralph J, Riaño-Pachón DM, Vicentini R, Silva TDF, Ferraz A, Hatfield RD, Romanel E. Overexpression of a Sugarcane BAHD Acyltransferase Alters Hydroxycinnamate Content in Maize Cell Wall. Frontiers in Plant Science. 12: 626168. PMID 33995431 DOI: 10.3389/fpls.2021.626168  0.601
2021 Smith RA, Cass CL, Petrik DL, Padmakshan D, Ralph J, Sedbrook JC, Karlen SD. Stacking AsFMT overexpression with BdPMT loss of function enhances monolignol ferulate production in Brachypodium distachyon. Plant Biotechnology Journal. PMID 33949064 DOI: 10.1111/pbi.13606  0.616
2020 Liu X, Zhu R, Chen T, Song P, Lu F, Xu F, Ralph J, Zhang X. Mild Acetylation and Solubilization of Ground Whole Plant Cell Walls in EmimAc: A Method for Solution-State NMR in DMSO-d6. Analytical Chemistry. PMID 32885955 DOI: 10.1021/Acs.Analchem.0C02124  0.429
2020 Ralph J. Tricin and tricin-lignins in Medicago versus in monocots. The New Phytologist. PMID 32777096 DOI: 10.1111/Nph.16827  0.304
2020 Lemke RAS, Olson SM, Morse K, Karlen SD, Higbee A, Beebe ET, Ralph J, Coon JJ, Fox BG, Donohue TJ. A bacterial biosynthetic pathway for methylated furan fatty acids. The Journal of Biological Chemistry. PMID 32434926 DOI: 10.1074/Jbc.Ra120.013697  0.64
2020 Karlen SD, Fasahati P, Mazaheri M, Serate J, Smith RA, Sirobhushanam S, Chen M, Tymokhin VI, Cass CL, Liu S, Padmakshan D, Xie D, Zhang Y, McGee MA, Russell JD, ... ... Ralph J, et al. Assessing the Viability of Recovery of Hydroxycinnamic Acids from Lignocellulosic Biorefinery Alkaline Pretreatment Waste Streams. Chemsuschem. PMID 32285625 DOI: 10.1002/Cssc.202000820  0.607
2020 Li Y, Karlen SD, Demir B, Kim H, Luterbacher J, Dumesic JA, Stahl SS, Ralph J. Mechanistic study of diaryl ether bond cleavage during palladium-catalyzed lignin hydrogenolysis. Chemsuschem. PMID 32202385 DOI: 10.1002/Cssc.202000753  0.664
2020 Tsai CJ, Xu P, Xue LJ, Hu H, Nyamdari B, Naran R, Zhou X, Goeminne G, Gao R, Gjersing E, Dahlen J, Pattathil S, Hahn MG, Davis M, Ralph J, et al. Compensatory guaiacyl lignin biosynthesis at the expense of syringyl lignin in 4CL1-knockout poplar. Plant Physiology. PMID 32139476 DOI: 10.1104/Pp.19.01550  0.342
2020 Yamamoto M, Tomiyama H, Koyama A, Okuizumi H, Liu S, Vanholme R, Goeminne G, Hirai Y, Shi H, Nuoendagula N, Takata N, Ikeda T, Uesugi M, Kim H, Sakamoto S, ... ... Ralph J, et al. A century-old mystery unveiled: Sekizaisou is a natural lignin mutant. Plant Physiology. PMID 32051179 DOI: 10.1104/Pp.19.01467  0.355
2020 Karlen SD, Fasahati P, Mazaheri M, Serate J, Smith RA, Sirobhushanam S, Chen M, Tymkhin VI, Cass CL, Liu S, Padmakshan D, Xie D, Zhang Y, McGee MA, Russell JD, ... ... Ralph J, et al. Assessing the viability of recovering hydroxycinnamic acids from lignocellulosic biorefinery alkaline pretreatment waste streams. Chemsuschem. PMID 31984673 DOI: 10.1002/cssc.201903345  0.624
2020 Río JCd, Rencoret J, Gutiérrez A, Elder T, Kim H, Ralph J. Lignin monomers from beyond the canonical monolignol biosynthetic pathway: Another brick in the wall Acs Sustainable Chemistry & Engineering. 8: 4997-5012. DOI: 10.1021/Acssuschemeng.0C01109  0.42
2019 Vermaas JV, Dixon RA, Chen F, Mansfield SD, Boerjan W, Ralph J, Crowley MF, Beckham GT. Passive membrane transport of lignin-related compounds. Proceedings of the National Academy of Sciences of the United States of America. PMID 31659054 DOI: 10.1073/Pnas.1904643116  0.332
2019 Lapierre C, Voxeur A, Boutet-Mercey S, Ralph J. Arabinose Conjugates Diagnostic of Ferulate-Ferulate and Ferulate-Monolignol Cross-Coupling are Released by Mild Acidolysis of Grass Cell Walls. Journal of Agricultural and Food Chemistry. PMID 31644281 DOI: 10.1021/Acs.Jafc.9B05840  0.405
2019 Lee MH, Jeon HS, Kim SH, Chung JH, Roppolo D, Lee HJ, Cho HJ, Tobimatsu Y, Ralph J, Park OK. Lignin-based barrier restricts pathogens to the infection site and confers resistance in plants. The Embo Journal. e101948. PMID 31559647 DOI: 10.15252/Embj.2019101948  0.312
2019 Vanholme R, Sundin L, Seetso KC, Kim H, Liu X, Li J, De Meester B, Hoengenaert L, Goeminne G, Morreel K, Haustraete J, Tsai HH, Schmidt W, Vanholme B, Ralph J, et al. COSY catalyses trans-cis isomerization and lactonization in the biosynthesis of coumarins. Nature Plants. PMID 31501530 DOI: 10.1038/S41477-019-0510-0  0.365
2019 Grabber JH, Davidson C, Tobimatsu Y, Kim H, Lu F, Zhu Y, Opietnik M, Santoro N, Foster CE, Yue F, Ress D, Pan X, Ralph J. Structural features of alternative lignin monomers associated with improved digestibility of artificially lignified maize cell walls. Plant Science : An International Journal of Experimental Plant Biology. 287. PMID 31481197 DOI: 10.1016/J.Plantsci.2019.02.004  0.455
2019 Lam PY, Tobimatsu Y, Matsumoto N, Suzuki S, Lan W, Takeda Y, Yamamura M, Sakamoto M, Ralph J, Lo C, Umezawa T. OsCAldOMT1 is a bifunctional O-methyltransferase involved in the biosynthesis of tricin-lignins in rice cell walls. Scientific Reports. 9: 11597. PMID 31406182 DOI: 10.1038/S41598-019-47957-0  0.465
2019 Abbas M, Peszlen I, Shi R, Kim H, Katahira R, Kafle K, Xiang Z, Huang X, Min D, Mohamadamin M, Yang C, Dai X, Yan X, Park S, Li Y, ... ... Ralph J, et al. Involvement of CesA4, CesA7-A/B and CesA8-A/B in secondary wall formation in Populus trichocarpa wood. Tree Physiology. PMID 31211386 DOI: 10.1093/Treephys/Tpz020  0.37
2019 Rencoret J, Neiva D, Marques G, Gutiérrez A, Kim H, Gominho J, Pereira H, Ralph J, Del Río JC. Hydroxystilbene glucosides are incorporated into Norway spruce bark lignin. Plant Physiology. PMID 31023874 DOI: 10.1104/Pp.19.00344  0.414
2019 Boerjan W, Ralph J. Editorial overview: Plant biotechnology - lignin engineering. Current Opinion in Biotechnology. 56: iii-v. PMID 30979379 DOI: 10.1016/J.Copbio.2019.04.001  0.314
2019 Ralph J, Lapierre C, Boerjan W. Lignin structure and its engineering. Current Opinion in Biotechnology. 56: 240-249. PMID 30921563 DOI: 10.1016/J.Copbio.2019.02.019  0.362
2019 Vanholme R, De Meester B, Ralph J, Boerjan W. Lignin biosynthesis and its integration into metabolism. Current Opinion in Biotechnology. 56: 230-239. PMID 30913460 DOI: 10.1016/J.Copbio.2019.02.018  0.408
2019 Kellock M, Maaheimo H, Marjamaa K, Rahikainen J, Zhang H, Holopainen-Mantila U, Ralph J, Tamminen T, Felby C, Kruus K. Effect of hydrothermal pretreatment severity on lignin inhibition in enzymatic hydrolysis. Bioresource Technology. 280: 303-312. PMID 30776657 DOI: 10.1016/J.Biortech.2019.02.051  0.307
2019 Oyarce P, De Meester B, Fonseca F, de Vries L, Goeminne G, Pallidis A, De Rycke R, Tsuji Y, Li Y, Van den Bosch S, Sels B, Ralph J, Vanholme R, Boerjan W. Introducing curcumin biosynthesis in Arabidopsis enhances lignocellulosic biomass processing. Nature Plants. PMID 30692678 DOI: 10.1038/S41477-018-0350-3  0.431
2019 Ando D, Ralph J. Method to Regioselectively Iodine-Tag Free-Phenolic Aromatic End-Groups in Lignin for 1H–13C-HSQC NMR Analysis Acs Sustainable Chemistry & Engineering. 7: 18624-18629. DOI: 10.1021/Acssuschemeng.9B04981  0.302
2019 Liu X, Li Y, Ewulonu CM, Ralph J, Xu F, Zhang Q, Wu M, Huang Y. Mild Alkaline Pretreatment for Isolation of Native-LikeLignin and Lignin-Containing Cellulose Nanofibers (LCNF) from CropWaste Acs Sustainable Chemistry & Engineering. 7: 14135-14142. DOI: 10.1021/Acssuschemeng.9B02800  0.358
2019 Shen W, Collings C, Li M, Markovicz J, Ralph J, Mansfield SD, Ding S. Imaging Changes in Cell Walls of Engineered Poplar by Stimulated Raman Scattering and Atomic Force Microscopy Acs Sustainable Chemistry & Engineering. 7: 10616-10622. DOI: 10.1021/Acssuschemeng.9B01166  0.312
2018 Lan W, Yue F, Rencoret J, Del Río JC, Boerjan W, Lu F, Ralph J. Elucidating Tricin-Lignin Structures: Assigning Correlations in HSQC Spectra of Monocot Lignins. Polymers. 10. PMID 30960841 DOI: 10.3390/Polym10080916  0.363
2018 Song Y, Mobley JK, Motagamwala AH, Isaacs M, Dumesic JA, Ralph J, Lee AF, Wilson K, Crocker M. Gold-catalyzed conversion of lignin to low molecular weight aromatics. Chemical Science. 9: 8127-8133. PMID 30542563 DOI: 10.1039/C8Sc03208D  0.307
2018 Yan X, Liu J, Kim H, Liu B, Huang X, Yang Z, Lin YC, Chen H, Yang C, Wang JP, Muddiman DC, Ralph J, Sederoff RR, Li Q, Chiang VL. CAD1 and CCR2 protein complex formation in monolignol biosynthesis in Populus trichocarpa. The New Phytologist. PMID 30276825 DOI: 10.1111/Nph.15505  0.342
2018 Li Y, Shuai L, Kim H, Motagamwala AH, Mobley JK, Yue F, Tobimatsu Y, Havkin-Frenkel D, Chen F, Dixon RA, Luterbacher JS, Dumesic JA, Ralph J. An "ideal lignin" facilitates full biomass utilization. Science Advances. 4: eaau2968. PMID 30276267 DOI: 10.1126/Sciadv.Aau2968  0.409
2018 Daly P, McClellan C, Maluk M, Oakey H, Lapierre C, Waugh R, Stephens J, Marshall D, Barakate A, Tsuji Y, Goeminne G, Vanholme R, Boerjan W, Ralph J, Halpin C. RNAi-suppression of barley caffeic acid O-methyltransferase modifies lignin despite redundancy in the gene family. Plant Biotechnology Journal. PMID 30133138 DOI: 10.1111/Pbi.13001  0.378
2018 Dou J, Kim H, Li Y, Padmakshan D, Yue F, Ralph J, Vuorinen T. Structural characterization of willow bark lignin. Journal of Agricultural and Food Chemistry. PMID 29932676 DOI: 10.1021/Acs.Jafc.8B02014  0.435
2018 Takeda Y, Tobimatsu Y, Karlen SD, Koshiba T, Suzuki S, Yamamura M, Murakami S, Mukai M, Hattori T, Osakabe K, Ralph J, Sakamoto M, Umezawa T. Downregulation of p-COUMAROYL ESTER 3-HYDROXYLASE in rice leads to altered cell wall structures and improves biomass saccharification. The Plant Journal : For Cell and Molecular Biology. PMID 29890017 DOI: 10.1111/Tpj.13988  0.662
2018 Lapierre C, Voxeur A, Karlen SD, Helm RF, Ralph J. Evaluation of Feruloylated and p-Coumaroylated Arabinosyl Units in Grass Arabinoxylans by Acidolysis in Dioxane/Methanol. Journal of Agricultural and Food Chemistry. PMID 29763561 DOI: 10.1021/Acs.Jafc.8B01618  0.671
2018 Karlen SD, Free HC, Padmakshan D, Smith BG, Ralph J, Harris PJ. Commelinid Monocotyledon Lignins are Acylated by p-Coumarate. Plant Physiology. PMID 29724771 DOI: 10.1104/Pp.18.00298  0.64
2018 Gao R, Li Y, Kim H, Mobley JK, Ralph J. Selective Oxidation of Lignin Model Compounds. Chemsuschem. PMID 29719142 DOI: 10.1002/Cssc.201800598  0.331
2018 McKinley BA, Olson SN, Ritter KB, Herb DW, Karlen SD, Lu F, Ralph J, Rooney WL, Mullet JE. Variation in energy sorghum hybrid TX08001 biomass composition and lignin chemistry during development under irrigated and non-irrigated field conditions. Plos One. 13: e0195863. PMID 29684037 DOI: 10.1371/Journal.Pone.0195863  0.627
2018 Wang JP, Matthews ML, Williams CM, Shi R, Yang C, Tunlaya-Anukit S, Chen HC, Li Q, Liu J, Lin CY, Naik P, Sun YH, Loziuk PL, Yeh TF, Kim H, ... ... Ralph J, et al. Improving wood properties for wood utilization through multi-omics integration in lignin biosynthesis. Nature Communications. 9: 1579. PMID 29679008 DOI: 10.1038/S41467-018-03863-Z  0.31
2018 MacMillan CP, Birke H, Chuah A, Brill E, Tsuji Y, Ralph J, Dennis ES, Llewellyn D, Pettolino FA. Correction to: Tissue and cell-specific transcriptomes in cotton reveal the subtleties of gene regulation underlying the diversity of plant secondary cell walls. Bmc Genomics. 19: 261. PMID 29665776 DOI: 10.1186/S12864-018-4634-9  0.336
2018 Del Río JCC, Rencoret J, Gutierrez A, Kim H, Ralph J. Structural characterization of lignin from maize (Zea mays L.) fibers: evidences for diferuloylputrescine incorporated into the lignin polymer in maize kernels. Journal of Agricultural and Food Chemistry. PMID 29665690 DOI: 10.1021/Acs.Jafc.8B00880  0.421
2018 Regner M, Bartuce A, Padmakshan D, Ralph J, Karlen S. Reductive cleavage method for quantitation of monolignols and low-abundance monolignol conjugates. Chemsuschem. PMID 29603658 DOI: 10.1002/Cssc.201800617  0.644
2018 de Souza WR, Martins PK, Freeman J, Pellny TK, Michaelson LV, Sampaio BL, Vinecky F, Ribeiro AP, da Cunha BADB, Kobayashi AK, de Oliveira PA, Campanha RB, Pacheco TF, Martarello DCI, Marchiosi R, ... ... Ralph J, et al. Suppression of a single BAHD gene in Setaria viridis causes large, stable decreases in cell wall feruloylation and increases biomass digestibility. The New Phytologist. PMID 29315591 DOI: 10.1111/Nph.14970  0.382
2018 Bunzel M, Ralph J, Steinhart H. Phenolic Compounds as Cross-Links of Plant Derived Polysaccharides Czech Journal of Food Sciences. 22: 64-67. DOI: 10.17221/10613-Cjfs  0.405
2018 Dou J, Xu W, Koivisto JJ, Mobley JK, Padmakshan D, Kögler M, Xu C, Willför S, Ralph J, Vuorinen T. Characteristics of Hot Water Extracts from the Bark of Cultivated Willow (Salix sp.) Acs Sustainable Chemistry & Engineering. 6: 5566-5573. DOI: 10.1021/Acssuschemeng.8B00498  0.338
2018 Das A, Rahimi A, Ulbrich A, Alherech M, Motagamwala AH, Bhalla A, da Costa Sousa L, Balan V, Dumesic JA, Hegg EL, Dale BE, Ralph J, Coon JJ, Stahl SS. Lignin Conversion to Low-Molecular-Weight Aromatics via an Aerobic Oxidation-Hydrolysis Sequence: Comparison of Different Lignin Sources Acs Sustainable Chemistry & Engineering. 6: 3367-3374. DOI: 10.1021/Acssuschemeng.7B03541  0.341
2018 Bhalla A, Bansal N, Pattathil S, Li M, Shen W, Particka CA, Karlen SD, Phongpreecha T, Semaan RR, Gonzales-Vigil E, Ralph J, Mansfield SD, Ding S, Hodge DB, Hegg EL. Engineered Lignin in Poplar Biomass Facilitates Cu-Catalyzed Alkaline-Oxidative Pretreatment Acs Sustainable Chemistry & Engineering. 6: 2932-2941. DOI: 10.1021/Acssuschemeng.7B02067  0.303
2017 Nuoendagula, Tsuji Y, Takata N, Sakamoto S, Nakagawa-Izumi A, Taniguchi T, Ralph J, Mitsuda N, Kajita S. Change in lignin structure, but not in lignin content, in transgenic poplar overexpressing the rice master regulator of secondary cell wall biosynthesis. Physiologia Plantarum. PMID 29266248 DOI: 10.1111/Ppl.12684  0.403
2017 Rencoret J, Kim H, Evaristo AB, Gutierrez A, Ralph J, Del Río JCC. Variability in Lignin Composition and Structure in Cell Walls of Different Parts of Macaúba (Acrocomia aculeata) Palm Fruit. Journal of Agricultural and Food Chemistry. PMID 29241332 DOI: 10.1021/Acs.Jafc.7B04638  0.383
2017 Gall DL, Kontur WS, Lan W, Kim H, Li Y, Ralph J, Donohue TJ, Noguera DR. In vitro enzymatic depolymerization of lignin with release of syringyl, guaiacyl, and tricin units. Applied and Environmental Microbiology. PMID 29180366 DOI: 10.1128/Aem.02076-17  0.39
2017 Kim H, Padmakshan D, Li Y, Rencoret J, Hatfield RD, Ralph J. Characterization and elimination of undesirable protein residues in plant cell wall materials for enhancing lignin analysis by solution-state NMR. Biomacromolecules. PMID 29064677 DOI: 10.1021/Acs.Biomac.7B01223  0.412
2017 Lin Y, Karlen SD, Ralph J, King JY. Short-term facilitation of microbial litter decomposition by ultraviolet radiation. The Science of the Total Environment. 615: 838-848. PMID 29017126 DOI: 10.1016/J.Scitotenv.2017.09.239  0.61
2017 Karlen SD, Smith RA, Kim H, Padmakshan D, Bartuce A, Mobley JK, Free HC, Smith BG, Harris PJ, Ralph J. Highly decorated lignins in leaf tissues of the Canary Island date palm Phoenix canariensis. Plant Physiology. PMID 28894022 DOI: 10.1104/Pp.17.01172  0.63
2017 Saleme MLS, Cesarino I, Vargas L, Kim H, Vanholme R, Goeminne G, Van Acker R, Fonseca FCA, Pallidis A, Voorend W, Nicomedes J, Padmakshan D, Van Doorsseleare J, Ralph J, Boerjan WA. Silencing CAFFEOYL SHIKIMATE ESTERASE affects lignification and improves saccharification. Plant Physiology. PMID 28878037 DOI: 10.1104/Pp.17.00920  0.44
2017 Van Acker R, Déjardin A, Desmet S, Hoengenaert L, Vanholme R, Morreel K, Laurans F, Kim H, Santoro N, Foster C, Goeminne G, Legee F, Lapierre C, Pilate G, Ralph J, et al. Different metabolic routes for coniferaldehyde and sinapaldehyde with CINNAMYL ALCOHOL DEHYDROGENASE1 deficiency. Plant Physiology. PMID 28878036 DOI: 10.1104/Pp.17.00834  0.429
2017 Zhou S, Runge T, Karlen S, Ralph J, Gonzales-Vigil E, Mansfield S. Chemical Pulping Advantages of Zip-lignin Hybrid Poplar. Chemsuschem. PMID 28768066 DOI: 10.1002/Cssc.201701317  0.646
2017 Jun SY, Walker AM, Kim H, Ralph J, Vermerris W, Sattler SE, Kang C. Enzyme activity and substrate specificity of the major cinnamyl alcohol dehydrogenases in sorghum. Plant Physiology. PMID 28606901 DOI: 10.1104/Pp.17.00576  0.379
2017 Del Río JC, Rencoret J, Gutiérrez A, Kim H, Ralph J. Hydroxystilbenes are Monomers in Palm Fruit Endocarp Lignins. Plant Physiology. PMID 28588115 DOI: 10.1104/Pp.17.00362  0.429
2017 Smith RA, Cass CL, Mazaheri M, Sekhon RS, Heckwolf M, Kaeppler H, de Leon N, Mansfield SD, Kaeppler SM, Sedbrook JC, Karlen SD, Ralph J. Suppression of CINNAMOYL-CoA REDUCTASE increases the level of monolignol ferulates incorporated into maize lignins. Biotechnology For Biofuels. 10: 109. PMID 28469705 DOI: 10.1186/S13068-017-0793-1  0.691
2017 Kim KH, Dutta T, Ralph J, Mansfield SD, Simmons BA, Singh S. Impact of lignin polymer backbone esters on ionic liquid pretreatment of poplar. Biotechnology For Biofuels. 10: 101. PMID 28439294 DOI: 10.1186/S13068-017-0784-2  0.375
2017 Li H, Yelle DJ, Li C, Yang M, Ke J, Zhang R, Liu Y, Zhu N, Liang S, Mo X, Ralph J, Currie CR, Mo J. Lignocellulose pretreatment in a fungus-cultivating termite. Proceedings of the National Academy of Sciences of the United States of America. PMID 28424249 DOI: 10.1073/Pnas.1618360114  0.761
2017 Smith RA, Schuetz M, Karlen SD, Bird DA, Tokunaga N, Sato Y, Mansfield SD, Ralph J, Samuels AL. Defining the Diverse Cell Populations Contributing to Lignification in Arabidopsis thaliana Stems. Plant Physiology. PMID 28416705 DOI: 10.1104/Pp.17.00434  0.632
2017 Gall DL, Ralph J, Donohue TJ, Noguera DR. Biochemical transformation of lignin for deriving valued commodities from lignocellulose. Current Opinion in Biotechnology. 45: 120-126. PMID 28346893 DOI: 10.1016/J.Copbio.2017.02.015  0.394
2017 Novo M, Silvar C, Merino F, Martínez-Cortés T, Lu F, Ralph J, Pomar F. Deciphering the role of the phenylpropanoid metabolism in the tolerance of Capsicum annuum L. to Verticillium dahliae Kleb. Plant Science : An International Journal of Experimental Plant Biology. 258: 12-20. PMID 28330555 DOI: 10.1016/J.Plantsci.2017.01.014  0.308
2017 Johnson AM, Kim H, Ralph J, Mansfield SD. Natural acetylation impacts carbohydrate recovery during deconstruction of Populus trichocarpa wood. Biotechnology For Biofuels. 10: 48. PMID 28250816 DOI: 10.1186/S13068-017-0734-Z  0.376
2017 Singh R, Hu J, Regner MR, Round JW, Ralph J, Saddler JN, Eltis LD. Enhanced delignification of steam-pretreated poplar by a bacterial laccase. Scientific Reports. 7: 42121. PMID 28169340 DOI: 10.1038/Srep42121  0.38
2017 Yue F, Lu F, Regner M, Sun R, Ralph J. Lignin-Derived Thioacidolysis Dimers: Reevaluation, New Products, Authentication, and Quantification. Chemsuschem. PMID 28125766 DOI: 10.1002/Cssc.201700101  0.353
2017 Jensen A, Cabrera Y, Hsieh C, Nielsen J, Ralph J, Felby C. 2D NMR characterization of wheat straw residual lignin after dilute acid pretreatment with different severities Holzforschung. 71: 461-469. DOI: 10.1515/Hf-2016-0112  0.354
2017 Yue F, Gao R, Piotrowski JS, Kabbage M, Lu F, Ralph J. Scaled-up production of poacic acid, a plant-derived antifungal agent Industrial Crops and Products. 103: 240-243. DOI: 10.1016/J.Indcrop.2017.03.045  0.364
2016 Bewg WP, Poovaiah C, Lan W, Ralph J, Coleman HD. RNAi downregulation of three key lignin genes in sugarcane improves glucose release without reduction in sugar production. Biotechnology For Biofuels. 9: 270. PMID 28031745 DOI: 10.1186/S13068-016-0683-Y  0.355
2016 Unda F, Kim H, Hefer C, Ralph J, Mansfield SD. Altering carbon allocation in hybrid poplar (Populus alba × grandidentata) impacts cell wall growth and development. Plant Biotechnology Journal. PMID 27998032 DOI: 10.1111/Pbi.12682  0.424
2016 Eloy N, Voorend W, Lan W, Saleme ML, Cesarino I, Vanholme R, Smith RA, Goeminne G, Pallidis A, Morreel K, Nicomedes J, Ralph J, Boerjan WA. Silencing Chalcone Synthase Impedes the Incorporation of Tricin In Lignin and Increases Lignin Content. Plant Physiology. PMID 27940492 DOI: 10.1104/Pp.16.01108  0.424
2016 Shuai L, Amiri MT, Questell-Santiago YM, Héroguel F, Li Y, Kim H, Meilan R, Chapple C, Ralph J, Luterbacher JS. Formaldehyde stabilization facilitates lignin monomer production during biomass depolymerization. Science (New York, N.Y.). 354: 329-333. PMID 27846566 DOI: 10.1126/Science.Aaf7810  0.372
2016 Mnich E, Vanholme R, Oyarce P, Liu S, Lu F, Goeminne G, Jørgensen B, Motawie MS, Boerjan W, Ralph J, Ulvskov P, Møller BL, Bjarnholt N, Harholt J. Degradation of lignin β-aryl ether units in Arabidopsis thaliana expressing LigD, LigF and LigG from Sphingomonas paucimobilis SYK-6. Plant Biotechnology Journal. PMID 27775869 DOI: 10.1111/Pbi.12655  0.433
2016 Karlen SD, Zhang C, Peck ML, Smith RA, Padmakshan D, Helmich KE, Free HC, Lee S, Smith BG, Lu F, Sedbrook JC, Sibout R, Grabber JH, Runge TM, Mysore KS, ... ... Ralph J, et al. Monolignol ferulate conjugates are naturally incorporated into plant lignins. Science Advances. 2: e1600393. PMID 27757415 DOI: 10.1126/Sciadv.1600393  0.675
2016 Gao R, Lu F, Zhu Y, Hahn MG, Ralph J. Flexible Method for Conjugation of Phenol Lignin Model Compounds to Carrier Proteins. Journal of Agricultural and Food Chemistry. PMID 27690421 DOI: 10.1021/Acs.Jafc.6B04273  0.328
2016 Lan W, Rencoret J, Lu F, Karlen SD, Smith BG, Harris PJ, Del Río JC, Ralph J. Tricin-Lignins: Occurrence and Quantitation of Tricin in Relation to Phylogeny. The Plant Journal : For Cell and Molecular Biology. PMID 27553717 DOI: 10.1111/Tpj.13315  0.662
2016 Walker AM, Sattler SA, Regner MR, Jones JP, Ralph J, Vermerris W, Sattler SE, Kang C. Determination of the structure and catalytic mechanism of Sorghum bicolor caffeoyl-CoA O-methyltransferase. Plant Physiology. PMID 27457122 DOI: 10.1104/Pp.16.00845  0.356
2016 Poovaiah CR, Bewg WP, Lan W, Ralph J, Coleman HD. Sugarcane transgenics expressing MYB transcription factors show improved glucose release. Biotechnology For Biofuels. 9: 143. PMID 27429646 DOI: 10.1186/S13068-016-0559-1  0.3
2016 Cai Y, Zhang K, Kim H, Hou G, Zhang X, Yang H, Feng H, Miller L, Ralph J, Liu CJ. Enhancing digestibility and ethanol yield of Populus wood via expression of an engineered monolignol 4-O-methyltransferase. Nature Communications. 7: 11989. PMID 27349324 DOI: 10.1038/Ncomms11989  0.428
2016 Rinaldi R, Jastrzebski R, Clough MT, Ralph J, Kennema M, Bruijnincx PC, Weckhuysen BM. Paving the Way for Lignin Valorisation: Recent Advances in Bioengineering, Biorefining and Catalysis. Angewandte Chemie (International Ed. in English). PMID 27311348 DOI: 10.1002/Anie.201510351  0.327
2016 Cass CL, Lavell AA, Santoro N, Foster CE, Karlen SD, Smith RA, Ralph J, Garvin DF, Sedbrook JC. Cell Wall Composition and Biomass Recalcitrance Differences Within a Genotypically Diverse Set of Brachypodium distachyon Inbred Lines. Frontiers in Plant Science. 7: 708. PMID 27303415 DOI: 10.3389/Fpls.2016.00708  0.661
2016 Lan W, Morreel K, Lu F, Rencoret J, Del Río JC, Voorend W, Vermerris W, Boerjan WA, Ralph J. Maize Tricin-Oligolignol Metabolites and their Implications for Monocot Lignification. Plant Physiology. PMID 27208246 DOI: 10.1104/Pp.16.02012  0.419
2016 Yue F, Lu F, Ralph SA, Ralph J. Identification of 4-O-5-units in Softwood Lignins via Definitive Lignin Models and NMR. Biomacromolecules. PMID 27078826 DOI: 10.1021/Acs.Biomac.6B00256  0.362
2016 Ha CM, Escamilla-Trevino L, Serrani Yarce JC, Kim H, Ralph J, Chen F, Dixon RA. An essential role of caffeoyl shikimate esterase in monolignol biosynthesis in Medicago truncatula. The Plant Journal : For Cell and Molecular Biology. PMID 27037613 DOI: 10.1111/Tpj.13177  0.355
2016 Pereira JH, Heins RA, Gall DL, McAndrew RP, Deng K, Holland KC, Donohue TJ, Noguera DR, Simmons BA, Sale KL, Ralph J, Adams PD. Structural and Biochemical Characterization of the Early and Late Enzymes in the Lignin β-aryl Ether Cleavage Pathway from Sphingobium sp SYK-6. The Journal of Biological Chemistry. PMID 26940872 DOI: 10.1074/Jbc.M115.700427  0.374
2016 Petrik DL, Cass CL, Padmakshan D, Foster CE, Vogel JP, Karlen SD, Ralph J, Sedbrook JC. BdCESA7, BdCESA8, and BdPMT Utility Promoter Constructs for Targeted Expression to Secondary Cell-Wall-Forming Cells of Grasses. Frontiers in Plant Science. 7: 55. PMID 26870070 DOI: 10.3389/Fpls.2016.00055  0.632
2016 Mottiar Y, Vanholme R, Boerjan W, Ralph J, Mansfield SD. Designer lignins: harnessing the plasticity of lignification. Current Opinion in Biotechnology. 37: 190-200. PMID 26775114 DOI: 10.1016/J.Copbio.2015.10.009  0.415
2016 Da Costa Sousa L, Foston M, Bokade V, Azarpira A, Lu F, Ragauskas AJ, Ralph J, Dale B, Balan V. Isolation and characterization of new lignin streams derived from extractive-ammonia (EA) pretreatment Green Chemistry. 18: 4205-4215. DOI: 10.1039/C6Gc00298F  0.374
2016 Da Costa Sousa L, Jin M, Chundawat SPS, Bokade V, Tang X, Azarpira A, Lu F, Avci U, Humpula J, Uppugundla N, Gunawan C, Pattathil S, Cheh AM, Kothari N, Kumar R, ... Ralph J, et al. Next-generation ammonia pretreatment enhances cellulosic biofuel production Energy and Environmental Science. 9: 1215-1223. DOI: 10.1039/C5Ee03051J  0.316
2016 Rencoret J, Del Río JC, Nierop KGJ, Gutiérrez A, Ralph J. Rapid Py-GC/MS assessment of the structural alterations of lignins in genetically modified plants Journal of Analytical and Applied Pyrolysis. 121: 155-164. DOI: 10.1016/J.Jaap.2016.07.016  0.404
2016 Yelle DJ, Ralph J. Characterizing phenol-formaldehyde adhesive cure chemistry within the wood cell wall International Journal of Adhesion and Adhesives. 70: 26-36. DOI: 10.1016/J.Ijadhadh.2016.05.002  0.75
2015 Helmich KE, Pereira JH, Gall DL, Heins RA, McAndrew RP, Bingman CA, Deng K, Holland KC, Noguera DR, Simmons BA, Sale KL, Ralph J, Donohue TJ, Adams PD, Phillips GN. Structural basis of stereospecificity in the bacterial enzymatic cleavage of β-aryl ether bonds in lignin. The Journal of Biological Chemistry. PMID 26637355 DOI: 10.1074/Jbc.M115.694307  0.347
2015 Smith RA, Gonzales-Vigil E, Karlen SD, Park JY, Lu F, Wilkerson C, Samuels AL, Ralph J, Mansfield SD. Engineering monolignol p-coumarate conjugates into Poplar and Arabidopsis lignins. Plant Physiology. PMID 26511914 DOI: 10.1104/Pp.15.00815  0.67
2015 Li Z, Bansal N, Azarpira A, Bhalla A, Chen CH, Ralph J, Hegg EL, Hodge DB. Chemical and structural changes associated with Cu-catalyzed alkaline-oxidative delignification of hybrid poplar. Biotechnology For Biofuels. 8: 123. PMID 26300970 DOI: 10.1186/S13068-015-0300-5  0.36
2015 Anderson NA, Tobimatsu Y, Ciesielski PN, Ximenes E, Ralph J, Donohoe BS, Ladisch M, Chapple C. Manipulation of Guaiacyl and Syringyl Monomer Biosynthesis in an Arabidopsis Cinnamyl Alcohol Dehydrogenase Mutant Results in Atypical Lignin Biosynthesis and Modified Cell Wall Structure. The Plant Cell. 27: 2195-209. PMID 26265762 DOI: 10.1105/Tpc.15.00373  0.448
2015 Guzzo de Carli Poelking V, Giordano A, Ricci-Silva ME, Rhys Williams TC, Alves Peçanha D, Contin Ventrella M, Rencoret J, Ralph J, Pereira Barbosa MH, Loureiro M. Analysis of a Modern Hybrid and an Ancient Sugarcane Implicates a Complex Interplay of Factors in Affecting Recalcitrance to Cellulosic Ethanol Production. Plos One. 10: e0134964. PMID 26252208 DOI: 10.1371/Journal.Pone.0134964  0.358
2015 Cass CL, Peraldi A, Dowd PF, Mottiar Y, Santoro N, Karlen SD, Bukhman YV, Foster CE, Thrower N, Bruno LC, Moskvin OV, Johnson ET, Willhoit ME, Phutane M, Ralph J, et al. Effects of PHENYLALANINE AMMONIA LYASE (PAL) knockdown on cell wall composition, biomass digestibility, and biotic and abiotic stress responses in Brachypodium. Journal of Experimental Botany. PMID 26093023 DOI: 10.1093/Jxb/Erv269  0.673
2015 Wagner A, Tobimatsu Y, Phillips L, Flint H, Geddes B, Lu F, Ralph J. Syringyl lignin production in conifers: Proof of concept in a Pine tracheary element system. Proceedings of the National Academy of Sciences of the United States of America. 112: 6218-23. PMID 25902506 DOI: 10.1073/Pnas.1411926112  0.39
2015 Piotrowski JS, Okada H, Lu F, Li SC, Hinchman L, Ranjan A, Smith DL, Higbee AJ, Ulbrich A, Coon JJ, Deshpande R, Bukhman YV, McIlwain S, Ong IM, Myers CL, ... ... Ralph J, et al. Plant-derived antifungal agent poacic acid targets β-1,3-glucan. Proceedings of the National Academy of Sciences of the United States of America. 112: E1490-7. PMID 25775513 DOI: 10.1073/Pnas.1410400112  0.37
2015 Dima O, Morreel K, Vanholme B, Kim H, Ralph J, Boerjan W. Small glycosylated lignin oligomers are stored in Arabidopsis leaf vacuoles. The Plant Cell. 27: 695-710. PMID 25700483 DOI: 10.1105/Tpc.114.134643  0.404
2015 Lan W, Lu F, Regner M, Zhu Y, Rencoret J, Ralph SA, Zakai UI, Morreel K, Boerjan W, Ralph J. Tricin, a flavonoid monomer in monocot lignification. Plant Physiology. 167: 1284-95. PMID 25667313 DOI: 10.1104/Pp.114.253757  0.417
2015 Tsuji Y, Vanholme R, Tobimatsu Y, Ishikawa Y, Foster CE, Kamimura N, Hishiyama S, Hashimoto S, Shino A, Hara H, Sato-Izawa K, Oyarce P, Goeminne G, Morreel K, Kikuchi J, ... ... Ralph J, et al. Introduction of chemically labile substructures into Arabidopsis lignin through the use of LigD, the Cα-dehydrogenase from Sphingobium sp. strain SYK-6. Plant Biotechnology Journal. 13: 821-32. PMID 25580543 DOI: 10.1111/Pbi.12316  0.426
2015 Chen W, McClelland DJ, Azarpira A, Ralph J, Luo Z, Huber GW. Low temperature hydrogenation of pyrolytic lignin over Ru/TiO2: 2D HSQC and 13C NMR study of reactants and products Green Chemistry. 18: 271-281. DOI: 10.1039/C5Gc02286J  0.305
2015 Luterbacher JS, Azarpira A, Motagamwala AH, Lu F, Ralph J, Dumesic JA. Lignin monomer production integrated into the γ-valerolactone sugar platform Energy and Environmental Science. 8: 2657-2663. DOI: 10.1039/C5Ee01322D  0.383
2015 Yoo CG, Kim H, Lu F, Azarpira A, Pan X, Oh KK, Kim JS, Ralph J, Kim TH. Understanding the Physicochemical Characteristics and the Improved Enzymatic Saccharification of Corn Stover Pretreated with Aqueous and Gaseous Ammonia Bioenergy Research. DOI: 10.1007/S12155-015-9662-6  0.377
2015 Grabber JH, Santoro N, Foster CE, Elumalai S, Ralph J, Pan X. Incorporation of Flavonoid Derivatives or Pentagalloyl Glucose into Lignin Enhances Cell Wall Saccharification Following Mild Alkaline or Acidic Pretreatments Bioenergy Research. DOI: 10.1007/S12155-015-9605-2  0.403
2015 Lu F, Karlen SD, Regner M, Kim H, Ralph SA, Sun RC, Kuroda Ki, Augustin MA, Mawson R, Sabarez H, Singh T, Jimenez-Monteon G, Zakaria S, Hill S, Harris PJ, ... ... Ralph J, et al. Naturally p-Hydroxybenzoylated Lignins in Palms Bioenergy Research. DOI: 10.1007/S12155-015-9583-4  0.659
2015 Lin Y, King JY, Karlen SD, Ralph J. Using 2D NMR spectroscopy to assess effects of UV radiation on cell wall chemistry during litter decomposition Biogeochemistry. 125: 427-436. DOI: 10.1007/S10533-015-0132-1  0.644
2014 Sundin L, Vanholme R, Geerinck J, Goeminne G, Höfer R, Kim H, Ralph J, Boerjan W. Mutation of the inducible ARABIDOPSIS THALIANA CYTOCHROME P450 REDUCTASE2 alters lignin composition and improves saccharification. Plant Physiology. 166: 1956-71. PMID 25315601 DOI: 10.1104/Pp.114.245548  0.359
2014 Yelle DJ, Kapich AN, Houtman CJ, Lu F, Timokhin VI, Fort RC, Ralph J, Hammel KE. A highly diastereoselective oxidant contributes to Ligninolysis by the white rot basidiomycete Ceriporiopsis subvermispora. Applied and Environmental Microbiology. 80: 7536-44. PMID 25261514 DOI: 10.1128/Aem.02111-14  0.74
2014 Niculaes C, Morreel K, Kim H, Lu F, McKee LS, Ivens B, Haustraete J, Vanholme B, Rycke RD, Hertzberg M, Fromm J, Bulone V, Polle A, Ralph J, Boerjan W. Phenylcoumaran benzylic ether reductase prevents accumulation of compounds formed under oxidative conditions in poplar xylem. The Plant Cell. 26: 3775-91. PMID 25238751 DOI: 10.1105/Tpc.114.125260  0.389
2014 Tobimatsu Y, Van de Wouwer D, Allen E, Kumpf R, Vanholme B, Boerjan W, Ralph J. A click chemistry strategy for visualization of plant cell wall lignification. Chemical Communications (Cambridge, England). 50: 12262-5. PMID 25180250 DOI: 10.1039/C4Cc04692G  0.339
2014 Gaskell J, Marty A, Mozuch M, Kersten PJ, Splinter BonDurant S, Sabat G, Azarpira A, Ralph J, Skyba O, Mansfield SD, Blanchette RA, Cullen D. Influence of Populus genotype on gene expression by the wood decay fungus Phanerochaete chrysosporium. Applied and Environmental Microbiology. 80: 5828-35. PMID 25015893 DOI: 10.1128/Aem.01604-14  0.309
2014 Green AR, Lewis KM, Barr JT, Jones JP, Lu F, Ralph J, Vermerris W, Sattler SE, Kang C. Determination of the Structure and Catalytic Mechanism of Sorghum bicolor Caffeic Acid O-Methyltransferase and the Structural Impact of Three brown midrib12 Mutations. Plant Physiology. 165: 1440-1456. PMID 24948836 DOI: 10.1104/Pp.114.241729  0.356
2014 Wilkerson CG, Mansfield SD, Lu F, Withers S, Park JY, Karlen SD, Gonzales-Vigil E, Padmakshan D, Unda F, Rencoret J, Ralph J. Monolignol ferulate transferase introduces chemically labile linkages into the lignin backbone. Science (New York, N.Y.). 344: 90-3. PMID 24700858 DOI: 10.1126/Science.1250161  0.695
2014 Morreel K, Saeys Y, Dima O, Lu F, Van de Peer Y, Vanholme R, Ralph J, Vanholme B, Boerjan W. Systematic structural characterization of metabolites in Arabidopsis via candidate substrate-product pair networks. The Plant Cell. 26: 929-45. PMID 24685999 DOI: 10.1105/Tpc.113.122242  0.35
2014 Bonawitz ND, Kim JI, Tobimatsu Y, Ciesielski PN, Anderson NA, Ximenes E, Maeda J, Ralph J, Donohoe BS, Ladisch M, Chapple C. Disruption of Mediator rescues the stunted growth of a lignin-deficient Arabidopsis mutant. Nature. 509: 376-80. PMID 24670657 DOI: 10.1038/Nature13084  0.361
2014 Vanholme B, Vanholme R, Turumtay H, Goeminne G, Cesarino I, Goubet F, Morreel K, Rencoret J, Bulone V, Hooijmaijers C, De Rycke R, Gheysen G, Ralph J, De Block M, Meulewaeter F, et al. Accumulation of N-acetylglucosamine oligomers in the plant cell wall affects plant architecture in a dose-dependent and conditional manner. Plant Physiology. 165: 290-308. PMID 24664205 DOI: 10.1104/Pp.113.233742  0.393
2014 Van Acker R, Leplé JC, Aerts D, Storme V, Goeminne G, Ivens B, Légée F, Lapierre C, Piens K, Van Montagu MC, Santoro N, Foster CE, Ralph J, Soetaert W, Pilate G, et al. Improved saccharification and ethanol yield from field-grown transgenic poplar deficient in cinnamoyl-CoA reductase. Proceedings of the National Academy of Sciences of the United States of America. 111: 845-50. PMID 24379366 DOI: 10.1073/Pnas.1321673111  0.309
2014 Petrik DL, Karlen SD, Cass CL, Padmakshan D, Lu F, Liu S, Le Bris P, Antelme S, Santoro N, Wilkerson CG, Sibout R, Lapierre C, Ralph J, Sedbrook JC. p-Coumaroyl-CoA:monolignol transferase (PMT) acts specifically in the lignin biosynthetic pathway in Brachypodium distachyon. The Plant Journal : For Cell and Molecular Biology. 77: 713-26. PMID 24372757 DOI: 10.1111/Tpj.12420  0.693
2014 Takasuka TE, Bianchetti CM, Tobimatsu Y, Bergeman LF, Ralph J, Fox BG. Structure-guided analysis of catalytic specificity of the abundantly secreted chitosanase SACTE_5457 from Streptomyces sp. SirexAA-E Proteins: Structure, Function and Bioinformatics. 82: 1245-1257. PMID 24338856 DOI: 10.1002/Prot.24491  0.31
2014 Kim H, Ralph J. A gel-state 2D-NMR method for plant cell wall profiling and analysis: A model study with the amorphous cellulose and xylan from ball-milled cotton linters Rsc Advances. 4: 7549-7560. DOI: 10.1039/C3Ra46338A  0.402
2014 Azarpira A, Ralph J, Lu F. Catalytic Alkaline Oxidation of Lignin and its Model Compounds: A Pathway to Aromatic Biochemicals Bioenergy Research. 7: 78-86. DOI: 10.1007/S12155-013-9348-X  0.357
2014 Diehl BG, Watts HD, Kubicki JD, Regner MR, Ralph J, Brown NR. Towards lignin-protein crosslinking: Amino acid adducts of a lignin model quinone methide Cellulose. 21: 1395-1407. DOI: 10.1007/S10570-014-0181-Y  0.408
2014 Lu F, Ralph J. The DFRC (Derivatization Followed by Reductive Cleavage) method and its applications for lignin characterization Lignin: Structural Analysis, Applications in Biomaterials and Ecological Significance. 27-66.  0.315
2013 Vismeh R, Lu F, Chundawat SP, Humpula JF, Azarpira A, Balan V, Dale BE, Ralph J, Jones AD. Profiling of diferulates (plant cell wall cross-linkers) using ultrahigh-performance liquid chromatography-tandem mass spectrometry. The Analyst. 138: 6683-92. PMID 24040649 DOI: 10.1039/C3An36709F  0.426
2013 Vanholme R, Cesarino I, Rataj K, Xiao Y, Sundin L, Goeminne G, Kim H, Cross J, Morreel K, Araujo P, Welsh L, Haustraete J, McClellan C, Vanholme B, Ralph J, et al. Caffeoyl shikimate esterase (CSE) is an enzyme in the lignin biosynthetic pathway in Arabidopsis. Science (New York, N.Y.). 341: 1103-6. PMID 23950498 DOI: 10.1126/Science.1241602  0.371
2013 Tobimatsu Y, Chen F, Nakashima J, Escamilla-Treviño LL, Jackson L, Dixon RA, Ralph J. Coexistence but independent biosynthesis of catechyl and guaiacyl/syringyl lignin polymers in seed coats. The Plant Cell. 25: 2587-600. PMID 23903315 DOI: 10.1105/Tpc.113.113142  0.403
2013 Zhao Q, Tobimatsu Y, Zhou R, Pattathil S, Gallego-Giraldo L, Fu C, Jackson LA, Hahn MG, Kim H, Chen F, Ralph J, Dixon RA. Loss of function of cinnamyl alcohol dehydrogenase 1 leads to unconventional lignin and a temperature-sensitive growth defect in Medicago truncatula. Proceedings of the National Academy of Sciences of the United States of America. 110: 13660-5. PMID 23901113 DOI: 10.1073/Pnas.1312234110  0.42
2013 Tobimatsu Y, Wagner A, Donaldson L, Mitra P, Niculaes C, Dima O, Kim JI, Anderson N, Loque D, Boerjan W, Chapple C, Ralph J. Visualization of plant cell wall lignification using fluorescence-tagged monolignols. The Plant Journal : For Cell and Molecular Biology. 76: 357-66. PMID 23889038 DOI: 10.1111/Tpj.12299  0.374
2013 Gall DL, Ralph J, Donohue TJ, Noguera DR. Benzoyl coenzyme a pathway-mediated metabolism of meta-hydroxy-aromatic acids in Rhodopseudomonas palustris. Journal of Bacteriology. 195: 4112-20. PMID 23852864 DOI: 10.1128/Jb.00634-13  0.315
2013 Chylla RA, Van Acker R, Kim H, Azapira A, Mukerjee P, Markley JL, Storme V, Boerjan W, Ralph J. Plant cell wall profiling by fast maximum likelihood reconstruction (FMLR) and region-of-interest (ROI) segmentation of solution-state 2D 1H-13C NMR spectra. Biotechnology For Biofuels. 6: 45. PMID 23622232 DOI: 10.1186/1754-6834-6-45  0.399
2013 Vanholme B, Cesarino I, Goeminne G, Kim H, Marroni F, Van Acker R, Vanholme R, Morreel K, Ivens B, Pinosio S, Morgante M, Ralph J, Bastien C, Boerjan W. Breeding with rare defective alleles (BRDA): a natural Populus nigra HCT mutant with modified lignin as a case study. The New Phytologist. 198: 765-76. PMID 23432219 DOI: 10.1111/Nph.12179  0.316
2013 Rencoret J, Ralph J, Marques G, Gutiérrez A, Martínez Á, del Río JC. Structural characterization of lignin isolated from coconut (Cocos nucifera) coir fibers. Journal of Agricultural and Food Chemistry. 61: 2434-45. PMID 23398235 DOI: 10.1021/Jf304686X  0.377
2013 Wagner A, Tobimatsu Y, Goeminne G, Phillips L, Flint H, Steward D, Torr K, Donaldson L, Boerjan W, Ralph J. Suppression of CCR impacts metabolite profile and cell wall composition in Pinus radiata tracheary elements. Plant Molecular Biology. 81: 105-17. PMID 23131896 DOI: 10.1007/S11103-012-9985-Z  0.39
2013 Chen F, Tobimatsu Y, Jackson L, Nakashima J, Ralph J, Dixon RA. Novel seed coat lignins in the Cactaceae: structure, distribution and implications for the evolution of lignin diversity. The Plant Journal : For Cell and Molecular Biology. 73: 201-11. PMID 22957702 DOI: 10.1111/Tpj.12012  0.339
2013 Zhu Y, Regner M, Lu F, Kim H, Mohammadi A, Pearson TJ, Ralph J. Preparation of monolignol γ-acetate, γ-p-hydroxycinnamate, and γ-p-hydroxybenzoate conjugates: Selective deacylation of phenolic acetates with hydrazine acetate Rsc Advances. 3: 21964-21971. DOI: 10.1039/C3Ra42818D  0.336
2013 Yelle DJ, Kaparaju P, Hunt CG, Hirth K, Kim H, Ralph J, Felby C. Two-Dimensional NMR Evidence for Cleavage of Lignin and Xylan Substituents in Wheat Straw Through Hydrothermal Pretreatment and Enzymatic Hydrolysis Bioenergy Research. 6: 211-221. DOI: 10.1007/S12155-012-9247-6  0.764
2012 Ralph J, Akiyama T, Coleman HD, Mansfield SD. Effects on Lignin Structure of Coumarate 3-Hydroxylase Downregulation in Poplar. Bioenergy Research. 5: 1009-1019. PMID 26366246 DOI: 10.1007/S12155-012-9218-Y  0.323
2012 Yue F, Lu F, Sun R, Ralph J. Synthesis and characterization of new 5-linked pinoresinol lignin models. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 16402-10. PMID 23109283 DOI: 10.1002/Chem.201201506  0.4
2012 Vanholme R, Morreel K, Darrah C, Oyarce P, Grabber JH, Ralph J, Boerjan W. Metabolic engineering of novel lignin in biomass crops. The New Phytologist. 196: 978-1000. PMID 23035778 DOI: 10.1111/J.1469-8137.2012.04337.X  0.412
2012 Elumalai S, Tobimatsu Y, Grabber JH, Pan X, Ralph J. Epigallocatechin gallate incorporation into lignin enhances the alkaline delignification and enzymatic saccharification of cell walls. Biotechnology For Biofuels. 5: 59. PMID 22889353 DOI: 10.1186/1754-6834-5-59  0.391
2012 Mansfield SD, Kim H, Lu F, Ralph J. Whole plant cell wall characterization using solution-state 2D NMR. Nature Protocols. 7: 1579-89. PMID 22864199 DOI: 10.1038/Nprot.2012.064  0.405
2012 Zhang K, Bhuiya MW, Pazo JR, Miao Y, Kim H, Ralph J, Liu CJ. An engineered monolignol 4-o-methyltransferase depresses lignin biosynthesis and confers novel metabolic capability in Arabidopsis. The Plant Cell. 24: 3135-52. PMID 22851762 DOI: 10.1105/Tpc.112.101287  0.443
2012 Lu F, Wei L, Azarpira A, Ralph J. Rapid syntheses of dehydrodiferulates via biomimetic radical coupling reactions of ethyl ferulate. Journal of Agricultural and Food Chemistry. 60: 8272-7. PMID 22846085 DOI: 10.1021/Jf302140K  0.38
2012 Kaur H, Shaker K, Heinzel N, Ralph J, Gális I, Baldwin IT. Environmental stresses of field growth allow cinnamyl alcohol dehydrogenase-deficient Nicotiana attenuata plants to compensate for their structural deficiencies. Plant Physiology. 159: 1545-70. PMID 22645069 DOI: 10.1104/Pp.112.196717  0.377
2012 del Río JC, Rencoret J, Prinsen P, Martínez ÁT, Ralph J, Gutiérrez A. Structural characterization of wheat straw lignin as revealed by analytical pyrolysis, 2D-NMR, and reductive cleavage methods. Journal of Agricultural and Food Chemistry. 60: 5922-35. PMID 22607527 DOI: 10.1021/Jf301002N  0.413
2012 Grabber JH, Ress D, Ralph J. Identifying new lignin bioengineering targets: impact of epicatechin, quercetin glycoside, and gallate derivatives on the lignification and fermentation of maize cell walls. Journal of Agricultural and Food Chemistry. 60: 5152-60. PMID 22475000 DOI: 10.1021/Jf203986A  0.353
2012 Eudes A, George A, Mukerjee P, Kim JS, Pollet B, Benke PI, Yang F, Mitra P, Sun L, Cetinkol OP, Chabout S, Mouille G, Soubigou-Taconnat L, Balzergue S, Singh S, ... ... Ralph J, et al. Biosynthesis and incorporation of side-chain-truncated lignin monomers to reduce lignin polymerization and enhance saccharification. Plant Biotechnology Journal. 10: 609-20. PMID 22458713 DOI: 10.1111/J.1467-7652.2012.00692.X  0.446
2012 del Río JC, Prinsen P, Rencoret J, Nieto L, Jiménez-Barbero J, Ralph J, Martínez AT, Gutiérrez A. Structural characterization of the lignin in the cortex and pith of elephant grass (Pennisetum purpureum) stems. Journal of Agricultural and Food Chemistry. 60: 3619-34. PMID 22414389 DOI: 10.1021/Jf300099G  0.377
2012 Tobimatsu Y, Elumalai S, Grabber JH, Davidson CL, Pan X, Ralph J. Hydroxycinnamate conjugates as potential monolignol replacements: in vitro lignification and cell wall studies with rosmarinic acid. Chemsuschem. 5: 676-86. PMID 22359379 DOI: 10.1002/Cssc.201100573  0.36
2012 Chen F, Tobimatsu Y, Havkin-Frenkel D, Dixon RA, Ralph J. A polymer of caffeyl alcohol in plant seeds. Proceedings of the National Academy of Sciences of the United States of America. 109: 1772-7. PMID 22307645 DOI: 10.1073/Pnas.1120992109  0.383
2012 Withers S, Lu F, Kim H, Zhu Y, Ralph J, Wilkerson CG. Identification of grass-specific enzyme that acylates monolignols with p-coumarate. The Journal of Biological Chemistry. 287: 8347-55. PMID 22267741 DOI: 10.1074/Jbc.M111.284497  0.442
2012 Wagner A, Donaldson L, Ralph J. Lignification and Lignin Manipulations in Conifers Advances in Botanical Research. 61: 37-76. DOI: 10.1016/B978-0-12-416023-1.00002-1  0.398
2012 Brennan M, McLean JP, Altaner CM, Ralph J, Harris PJ. Cellulose microfibril angles and cell-wall polymers in different wood types of Pinus radiata Cellulose. 19: 1385-1404. DOI: 10.1007/S10570-012-9697-1  0.352
2012 Tobimatsu Y, Elumalai S, Grabber JH, Davidson CL, Pan X, Ralph J. Cover Picture: Hydroxycinnamate Conjugates as Potential Monolignol Replacements: In vitro Lignification and Cell Wall Studies with Rosmarinic Acid (ChemSusChem 4/2012) Chemsuschem. 5: 601-601. DOI: 10.1002/Cssc.201290013  0.324
2011 Azarpira A, Lu F, Ralph J. Reactions of dehydrodiferulates with ammonia. Organic & Biomolecular Chemistry. 9: 6779-87. PMID 21853208 DOI: 10.1039/C1Ob05677H  0.372
2011 Weng JK, Akiyama T, Ralph J, Chapple C. Independent recruitment of an O-methyltransferase for syringyl lignin biosynthesis in Selaginella moellendorffii. The Plant Cell. 23: 2708-24. PMID 21742988 DOI: 10.1105/Tpc.110.081547  0.406
2011 Sørensen I, Pettolino FA, Bacic A, Ralph J, Lu F, O'Neill MA, Fei Z, Rose JK, Domozych DS, Willats WG. The charophycean green algae provide insights into the early origins of plant cell walls. The Plant Journal : For Cell and Molecular Biology. 68: 201-11. PMID 21707800 DOI: 10.1111/J.1365-313X.2011.04686.X  0.415
2011 Vanden Wymelenberg A, Gaskell J, Mozuch M, BonDurant SS, Sabat G, Ralph J, Skyba O, Mansfield SD, Blanchette RA, Grigoriev IV, Kersten PJ, Cullen D. Significant alteration of gene expression in wood decay fungi Postia placenta and Phanerochaete chrysosporium by plant species. Applied and Environmental Microbiology. 77: 4499-507. PMID 21551287 DOI: 10.1128/Aem.00508-11  0.359
2011 Wagner A, Tobimatsu Y, Phillips L, Flint H, Torr K, Donaldson L, Pears L, Ralph J. CCoAOMT suppression modifies lignin composition in Pinus radiata. The Plant Journal : For Cell and Molecular Biology. 67: 119-29. PMID 21426426 DOI: 10.1111/J.1365-313X.2011.04580.X  0.424
2011 Tobimatsu Y, Davidson CL, Grabber JH, Ralph J. Fluorescence-tagged monolignols: synthesis, and application to studying in vitro lignification. Biomacromolecules. 12: 1752-61. PMID 21410250 DOI: 10.1021/Bm200136X  0.312
2011 Jensen JK, Kim H, Cocuron JC, Orler R, Ralph J, Wilkerson CG. The DUF579 domain containing proteins IRX15 and IRX15-L affect xylan synthesis in Arabidopsis. The Plant Journal : For Cell and Molecular Biology. 66: 387-400. PMID 21288268 DOI: 10.1111/J.1365-313X.2010.04475.X  0.347
2011 Yelle DJ, Wei D, Ralph J, Hammel KE. Multidimensional NMR analysis reveals truncated lignin structures in wood decayed by the brown rot basidiomycete Postia placenta. Environmental Microbiology. 13: 1091-100. PMID 21261800 DOI: 10.1111/J.1462-2920.2010.02417.X  0.761
2011 Rencoret J, Gutiérrez A, Nieto L, Jiménez-Barbero J, Faulds CB, Kim H, Ralph J, Martínez AT, Del Río JC. Lignin composition and structure in young versus adult Eucalyptus globulus plants. Plant Physiology. 155: 667-82. PMID 21098672 DOI: 10.1104/Pp.110.167254  0.409
2011 Yelle DJ, Ralph J, Frihart CR. Delineating pMDI model reactions with loblolly pine via solution-state NMR spectroscopy. Part 2. Non-catalyzed reactions with the wood cell wall Holzforschung. 65: 145-154. DOI: 10.1515/Hf.2011.029  0.75
2011 Yelle DJ, Ralph J, Frihart CR. Delineating pMDI model reactions with loblolly pine via solution-state NMR spectroscopy. Part 1. Catalyzed reactions with wood models and wood polymers Holzforschung. 65: 131-143. DOI: 10.1515/Hf.2011.028  0.73
2011 Chundawat SPS, Donohoe BS, Da Costa Sousa L, Elder T, Agarwal UP, Lu F, Ralph J, Himmel ME, Balan V, Dale BE. Multi-scale visualization and characterization of lignocellulosic plant cell wall deconstruction during thermochemical pretreatment Energy and Environmental Science. 4: 973-984. DOI: 10.1039/C0Ee00574F  0.369
2011 Zhu Y, Ralph J. Stereoselective synthesis of 1-O-β-feruloyl and 1-O-β-sinapoyl glucopyranoses Tetrahedron Letters. 52: 3729-3731. DOI: 10.1016/J.Tetlet.2011.05.038  0.308
2011 Zhu Y, Mohammadi A, Ralph J. Facile Synthesis of 4-Hydroxycinnamaldehydes Bioenergy Research. 5: 407-411. DOI: 10.1007/S12155-011-9151-5  0.373
2010 Vanholme R, Ralph J, Akiyama T, Lu F, Pazo JR, Kim H, Christensen JH, Van Reusel B, Storme V, De Rycke R, Rohde A, Morreel K, Boerjan W. Engineering traditional monolignols out of lignin by concomitant up-regulation of F5H1 and down-regulation of COMT in Arabidopsis. The Plant Journal : For Cell and Molecular Biology. 64: 885-97. PMID 20822504 DOI: 10.1111/J.1365-313X.2010.04353.X  0.35
2010 Morreel K, Kim H, Lu F, Dima O, Akiyama T, Vanholme R, Niculaes C, Goeminne G, Inzé D, Messens E, Ralph J, Boerjan W. Mass spectrometry-based fragmentation as an identification tool in lignomics. Analytical Chemistry. 82: 8095-105. PMID 20795635 DOI: 10.1021/Ac100968G  0.351
2010 Grabber JH, Schatz PF, Kim H, Lu F, Ralph J. Identifying new lignin bioengineering targets: 1. Monolignol-substitute impacts on lignin formation and cell wall fermentability. Bmc Plant Biology. 10: 114. PMID 20565789 DOI: 10.1186/1471-2229-10-114  0.419
2010 Morreel K, Dima O, Kim H, Lu F, Niculaes C, Vanholme R, Dauwe R, Goeminne G, Inzé D, Messens E, Ralph J, Boerjan W. Mass spectrometry-based sequencing of lignin oligomers. Plant Physiology. 153: 1464-78. PMID 20554692 DOI: 10.1104/Pp.110.156489  0.358
2010 van Parijs FR, Morreel K, Ralph J, Boerjan W, Merks RM. Modeling lignin polymerization. I. Simulation model of dehydrogenation polymers. Plant Physiology. 153: 1332-44. PMID 20472753 DOI: 10.1104/Pp.110.154468  0.358
2010 Lu F, Marita JM, Lapierre C, Jouanin L, Morreel K, Boerjan W, Ralph J. Sequencing around 5-hydroxyconiferyl alcohol-derived units in caffeic acid O-methyltransferase-deficient poplar lignins. Plant Physiology. 153: 569-79. PMID 20427467 DOI: 10.1104/Pp.110.154278  0.738
2010 Vanden Wymelenberg A, Gaskell J, Mozuch M, Sabat G, Ralph J, Skyba O, Mansfield SD, Blanchette RA, Martinez D, Grigoriev I, Kersten PJ, Cullen D. Comparative transcriptome and secretome analysis of wood decay fungi Postia placenta and Phanerochaete chrysosporium. Applied and Environmental Microbiology. 76: 3599-610. PMID 20400566 DOI: 10.1128/Aem.00058-10  0.333
2010 Weng JK, Akiyama T, Bonawitz ND, Li X, Ralph J, Chapple C. Convergent evolution of syringyl lignin biosynthesis via distinct pathways in the lycophyte Selaginella and flowering plants. The Plant Cell. 22: 1033-45. PMID 20371642 DOI: 10.1105/Tpc.109.073528  0.406
2010 Simmons BA, Loqué D, Ralph J. Advances in modifying lignin for enhanced biofuel production. Current Opinion in Plant Biology. 13: 313-20. PMID 20359939 DOI: 10.1016/J.Pbi.2010.03.001  0.403
2010 Zhang A, Lu F, Sun RC, Ralph J. Isolation of cellulolytic enzyme lignin from wood preswollen/dissolved in dimethyl sulfoxide/n-methylimidazole. Journal of Agricultural and Food Chemistry. 58: 3446-50. PMID 20158201 DOI: 10.1021/Jf903998D  0.356
2010 Kim H, Ralph J. Solution-state 2D NMR of ball-milled plant cell wall gels in DMSO-d(6)/pyridine-d(5). Organic & Biomolecular Chemistry. 8: 576-91. PMID 20090974 DOI: 10.1039/B916070A  0.431
2010 Shuai L, Yang Q, Zhu JY, Lu FC, Weimer PJ, Ralph J, Pan XJ. Comparative study of SPORL and dilute-acid pretreatments of spruce for cellulosic ethanol production. Bioresource Technology. 101: 3106-14. PMID 20061141 DOI: 10.1016/J.Biortech.2009.12.044  0.31
2009 Hedenström M, Wiklund-Lindström S, Oman T, Lu F, Gerber L, Schatz P, Sundberg B, Ralph J. Identification of lignin and polysaccharide modifications in Populus wood by chemometric analysis of 2D NMR spectra from dissolved cell walls. Molecular Plant. 2: 933-42. PMID 19825670 DOI: 10.1093/Mp/Ssp047  0.365
2009 Tranquet O, Saulnier L, Utille JP, Ralph J, Guillon F. Monoclonal antibodies to p-coumarate. Phytochemistry. 70: 1366-73. PMID 19712948 DOI: 10.1016/J.Phytochem.2009.06.019  0.348
2009 Stewart JJ, Akiyama T, Chapple C, Ralph J, Mansfield SD. The effects on lignin structure of overexpression of ferulate 5-hydroxylase in hybrid poplar. Plant Physiology. 150: 621-35. PMID 19386808 DOI: 10.1104/Pp.109.137059  0.387
2009 Hatfield RD, Marita JM, Frost K, Grabber J, Ralph J, Lu F, Kim H. Grass lignin acylation: p-coumaroyl transferase activity and cell wall characteristics of C3 and C4 grasses. Planta. 229: 1253-67. PMID 19288269 DOI: 10.1007/S00425-009-0900-Z  0.725
2009 Zhang A, Lu F, Sun R, Ralph J. Ferulate-coniferyl alcohol cross-coupled products formed by radical coupling reactions. Planta. 229: 1099-108. PMID 19234718 DOI: 10.1007/S00425-009-0894-6  0.362
2009 Martone PT, Estevez JM, Lu F, Ruel K, Denny MW, Somerville C, Ralph J. Discovery of lignin in seaweed reveals convergent evolution of cell-wall architecture. Current Biology : Cb. 19: 169-75. PMID 19167225 DOI: 10.1016/J.Cub.2008.12.031  0.384
2009 Wagner A, Donaldson L, Kim H, Phillips L, Flint H, Steward D, Torr K, Koch G, Schmitt U, Ralph J. Suppression of 4-coumarate-CoA ligase in the coniferous gymnosperm Pinus radiata. Plant Physiology. 149: 370-83. PMID 18971431 DOI: 10.1104/Pp.108.125765  0.391
2009 Terashima N, Akiyama T, Ralph S, Evtuguin D, Neto CP, Parkås J, Paulsson M, Westermark U, Ralph J. 2D-NMR (HSQC) difference spectra between specifically 13C-enriched and unenriched protolignin of Ginkgo biloba obtained in the solution state of whole cell wall material Holzforschung. 63. DOI: 10.1515/Hf.2009.074  0.34
2009 Ralph J. Hydroxycinnamates in lignification Phytochemistry Reviews. 9: 65-83. DOI: 10.1007/S11101-009-9141-9  0.433
2009 Grabber JH, Mertens DR, Kim H, Funk C, Lu F, Ralph J. Cell wall fermentation kinetics are impacted more by lignin content and ferulate cross-linking than by lignin composition Journal of the Science of Food and Agriculture. 89: 122-129. DOI: 10.1002/Jsfa.3418  0.437
2008 Lu F, Ralph J. Novel tetrahydrofuran structures derived from beta-beta-coupling reactions involving sinapyl acetate in Kenaf lignins. Organic & Biomolecular Chemistry. 6: 3681-94. PMID 18843398 DOI: 10.1039/B809464K  0.381
2008 Bunzel M, Heuermann B, Kim H, Ralph J. Peroxidase-catalyzed oligomerization of ferulic acid esters. Journal of Agricultural and Food Chemistry. 56: 10368-75. PMID 18841901 DOI: 10.1021/Jf801825Z  0.35
2008 Grabber JH, Hatfield RD, Lu F, Ralph J. Coniferyl ferulate incorporation into lignin enhances the alkaline delignification and enzymatic degradation of cell walls. Biomacromolecules. 9: 2510-6. PMID 18712922 DOI: 10.1021/Bm800528F  0.433
2008 Hatfield R, Ralph J, Grabber JH. A potential role for sinapyl p-coumarate as a radical transfer mechanism in grass lignin formation. Planta. 228: 919-28. PMID 18654797 DOI: 10.1007/S00425-008-0791-4  0.352
2008 Gniechwitz D, Reichardt N, Meiss E, Ralph J, Steinhart H, Blaut M, Bunzel M. Characterization and fermentability of an ethanol soluble high molecular weight coffee fraction. Journal of Agricultural and Food Chemistry. 56: 5960-9. PMID 18558695 DOI: 10.1021/Jf800231Q  0.355
2008 Yelle DJ, Ralph J, Frihart CR. Characterization of nonderivatized plant cell walls using high-resolution solution-state NMR spectroscopy. Magnetic Resonance in Chemistry : Mrc. 46: 508-17. PMID 18383438 DOI: 10.1002/Mrc.2201  0.753
2008 Yelle DJ, Ralph J, Lu F, Hammel KE. Evidence for cleavage of lignin by a brown rot basidiomycete. Environmental Microbiology. 10: 1844-9. PMID 18363712 DOI: 10.1111/J.1462-2920.2008.01605.X  0.729
2008 Ralph J, Kim H, Lu F, Grabber JH, Leplé JC, Berrio-Sierra J, Derikvand MM, Jouanin L, Boerjan W, Lapierre C. Identification of the structure and origin of a thioacidolysis marker compound for ferulic acid incorporation into angiosperm lignins (and an indicator for cinnamoyl CoA reductase deficiency). The Plant Journal : For Cell and Molecular Biology. 53: 368-79. PMID 18184422 DOI: 10.1111/J.1365-313X.2007.03345.X  0.42
2008 Bunzel M, Allerdings E, Ralph J, Steinhart H. Cross-linking of arabinoxylans via 8-8-coupled diferulates as demonstrated by isolation and identification of diarabinosyl 8-8(cyclic)-dehydrodiferulate from maize bran Journal of Cereal Science. 47: 29-40. DOI: 10.1016/J.Jcs.2006.12.005  0.374
2008 Kim H, Ralph J, Akiyama T. Solution-state 2D NMR of Ball-milled Plant Cell Wall Gels in DMSO-d 6 Bioenergy Research. 1: 56-66. DOI: 10.1007/S12155-008-9004-Z  0.391
2008 Gniechwitz D, Reichardt N, Ralph J, Blaut M, Steinhart H, Bunzel M. Isolation and characterisation of a coffee melanoidin fraction Journal of the Science of Food and Agriculture. 88: 2153-2160. DOI: 10.1002/Jsfa.3327  0.329
2007 Leplé JC, Dauwe R, Morreel K, Storme V, Lapierre C, Pollet B, Naumann A, Kang KY, Kim H, Ruel K, Lefèbvre A, Joseleau JP, Grima-Pettenati J, De Rycke R, Andersson-Gunnerås S, ... ... Ralph J, et al. Downregulation of cinnamoyl-coenzyme A reductase in poplar: multiple-level phenotyping reveals effects on cell wall polymer metabolism and structure. The Plant Cell. 19: 3669-91. PMID 18024569 DOI: 10.1105/Tpc.107.054148  0.422
2007 Dauwe R, Morreel K, Goeminne G, Gielen B, Rohde A, Van Beeumen J, Ralph J, Boudet AM, Kopka J, Rochange SF, Halpin C, Messens E, Boerjan W. Molecular phenotyping of lignin-modified tobacco reveals associated changes in cell-wall metabolism, primary metabolism, stress metabolism and photorespiration. The Plant Journal : For Cell and Molecular Biology. 52: 263-85. PMID 17727617 DOI: 10.1111/J.1365-313X.2007.03233.X  0.341
2007 Wagner A, Ralph J, Akiyama T, Flint H, Phillips L, Torr K, Nanayakkara B, Te Kiri L. Exploring lignification in conifers by silencing hydroxycinnamoyl-CoA:shikimate hydroxycinnamoyltransferase in Pinus radiata. Proceedings of the National Academy of Sciences of the United States of America. 104: 11856-61. PMID 17609384 DOI: 10.1073/Pnas.0701428104  0.409
2007 Fraser CM, Thompson MG, Shirley AM, Ralph J, Schoenherr JA, Sinlapadech T, Hall MC, Chapple C. Related Arabidopsis serine carboxypeptidase-like sinapoylglucose acyltransferases display distinct but overlapping substrate specificities. Plant Physiology. 144: 1986-99. PMID 17600138 DOI: 10.1104/Pp.107.098970  0.328
2006 Holmgren A, Brunow G, Henriksson G, Zhang L, Ralph J. Non-enzymatic reduction of quinone methides during oxidative coupling of monolignols: implications for the origin of benzyl structures in lignins. Organic & Biomolecular Chemistry. 4: 3456-61. PMID 17036140 DOI: 10.1039/B606369A  0.342
2006 Bunzel M, Ralph J. NMR characterization of lignins isolated from fruit and vegetable insoluble dietary fiber. Journal of Agricultural and Food Chemistry. 54: 8352-61. PMID 17032051 DOI: 10.1021/Jf061525Z  0.343
2006 Bunzel M, Ralph J, Brüning P, Steinhart H. Structural identification of dehydrotriferulic and dehydrotetraferulic acids isolated from insoluble maize bran fiber. Journal of Agricultural and Food Chemistry. 54: 6409-18. PMID 16910738 DOI: 10.1021/Jf061196A  0.4
2006 Schatz PF, Ralph J, Lu F, Guzei IA, Bunzel M. Synthesis and identification of 2,5-bis-(4-hydroxy-3-methoxyphenyl)-tetrahydrofuran-3,4-dicarboxylic acid, an unanticipated ferulate 8-8-coupling product acylating cereal plant cell walls. Organic & Biomolecular Chemistry. 4: 2801-6. PMID 16826306 DOI: 10.1039/B605918J  0.405
2006 Allerdings E, Ralph J, Steinhart H, Bunzel M. Isolation and structural identification of complex feruloylated heteroxylan side-chains from maize bran. Phytochemistry. 67: 1276-86. PMID 16777153 DOI: 10.1016/J.Phytochem.2006.04.018  0.318
2006 Morreel K, Goeminne G, Storme V, Sterck L, Ralph J, Coppieters W, Breyne P, Steenackers M, Georges M, Messens E, Boerjan W. Genetical metabolomics of flavonoid biosynthesis in Populus: a case study. The Plant Journal : For Cell and Molecular Biology. 47: 224-37. PMID 16774647 DOI: 10.1111/J.1365-313X.2006.02786.X  0.305
2006 Ralph J, Akiyama T, Kim H, Lu F, Schatz PF, Marita JM, Ralph SA, Reddy MS, Chen F, Dixon RA. Effects of coumarate 3-hydroxylase down-regulation on lignin structure. The Journal of Biological Chemistry. 281: 8843-53. PMID 16421107 DOI: 10.1074/Jbc.M511598200  0.744
2006 Zhang L, Gellerstedt G, Ralph J, Lu F. NMR Studies on the Occurrence of Spirodienone Structures in Lignins Journal of Wood Chemistry and Technology. 26: 65-79. DOI: 10.1080/02773810600580271  0.33
2005 Bunzel M, Ralph J, Steinhart H. Association of non-starch polysaccharides and ferulic acid in grain amaranth (Amaranthus caudatus L.) dietary fiber. Molecular Nutrition & Food Research. 49: 551-9. PMID 15864784 DOI: 10.1002/Mnfr.200500030  0.305
2005 Funk C, Ralph J, Steinhart H, Bunzel M. Isolation and structural characterisation of 8-O-4/8-O-4- and 8-8/8-O-4-coupled dehydrotriferulic acids from maize bran. Phytochemistry. 66: 363-71. PMID 15680993 DOI: 10.1016/J.Phytochem.2004.12.008  0.369
2005 Allerdings E, Ralph J, Schatz PF, Gniechwitz D, Steinhart H, Bunzel M. Isolation and structural identification of diarabinosyl 8-O-4-dehydrodiferulate from maize bran insoluble fibre. Phytochemistry. 66: 113-24. PMID 15649518 DOI: 10.1016/J.Phytochem.2004.10.026  0.373
2005 Bunzel M, Ralph J, Funk C, Steinhart H. Structural elucidation of new ferulic acid-containing phenolic dimers and trimers isolated from maize bran Tetrahedron Letters. 46: 5845-5850. DOI: 10.1016/J.Tetlet.2005.06.140  0.378
2004 Barrière Y, Ralph J, Méchin V, Guillaumie S, Grabber JH, Argillier O, Chabbert B, Lapierre C. Genetic and molecular basis of grass cell wall biosynthesis and degradability. II. Lessons from brown-midrib mutants. Comptes Rendus Biologies. 327: 847-860. PMID 15587076 DOI: 10.1016/J.Crvi.2004.05.010  0.36
2004 Morreel K, Ralph J, Lu F, Goeminne G, Busson R, Herdewijn P, Goeman JL, Van der Eycken J, Boerjan W, Messens E. Phenolic profiling of caffeic acid O-methyltransferase-deficient poplar reveals novel benzodioxane oligolignols. Plant Physiology. 136: 4023-36. PMID 15563622 DOI: 10.1104/Pp.104.049312  0.421
2004 Morreel K, Ralph J, Kim H, Lu F, Goeminne G, Ralph S, Messens E, Boerjan W. Profiling of Oligolignols Reveals Monolignol Coupling Conditions in Lignifying Poplar Xylem Plant Physiology. 136: 3537-3549. PMID 15516504 DOI: 10.1104/Pp.104.049304  0.42
2004 Lu F, Ralph J, Morreel K, Messens E, Boerjan W. Preparation and relevance of a cross-coupling product between sinapyl alcohol and sinapyl p-hydroxybenzoate Organic and Biomolecular Chemistry. 2: 2888-2890. PMID 15480449 DOI: 10.1039/B411428K  0.326
2004 Bunzel M, Ralph J, Lu F, Hatfield RD, Steinhart H. Lignins and ferulate-coniferyl alcohol cross-coupling products in cereal grains. Journal of Agricultural and Food Chemistry. 52: 6496-502. PMID 15479013 DOI: 10.1021/Jf040204P  0.344
2004 Ralph J, Lu F. Cryoprobe 3D NMR of acetylated ball-milled pine cell walls Organic and Biomolecular Chemistry. 2: 2714-2715. PMID 15455138 DOI: 10.1039/B412633E  0.348
2004 Rohde A, Morreel K, Ralph J, Goeminne G, Hostyn V, Rycke RD, Kushnir S, Doorsselaere JV, Joseleau J, Vuylsteke M, Driessche GV, Beeumen JV, Messens E, Boerjan W. Molecular Phenotyping of the pal1 and pal2 Mutants of Arabidopsis thaliana Reveals Far-Reaching Consequences on Phenylpropanoid, Amino Acid, and Carbohydrate Metabolism The Plant Cell. 16: 2749-2771. PMID 15377757 DOI: 10.1105/Tpc.104.023705  0.359
2004 Fischer MH, Yu N, Gray GR, Ralph J, Anderson L, Marlett JA. The gel-forming polysaccharide of psyllium husk (Plantago ovata Forsk). Carbohydrate Research. 339: 2009-17. PMID 15261594 DOI: 10.1016/J.Carres.2004.05.023  0.342
2004 Ralph J, Guillaumie S, Grabber JH, Lapierre C, Barrière Y. Genetic and molecular basis of grass cell-wall biosynthesis and degradability. III. Towards a forage grass ideotype. Comptes Rendus Biologies. 327: 467-479. PMID 15255477 DOI: 10.1016/J.Crvi.2004.03.004  0.32
2004 Grabber JH, Ralph J, Lapierre C, Barrière Y. Genetic and molecular basis of grass cell-wall degradability. I. Lignin-cell wall matrix interactions. Comptes Rendus Biologies. 327: 455-465. PMID 15255476 DOI: 10.1016/J.Crvi.2004.02.009  0.396
2004 Guerra A, Mendonça R, Ferraz A, Lu F, Ralph J. Structural characterization of lignin during Pinus taeda wood treatment with Ceriporiopsis subvermispora. Applied and Environmental Microbiology. 70: 4073-4078. PMID 15240285 DOI: 10.1128/Aem.70.7.4073-4078.2004  0.356
2004 Lapierre C, Pilate G, Pollet B, Mila I, Leplé J, Jouanin L, Kim H, Ralph J. Signatures of cinnamyl alcohol dehydrogenase deficiency in poplar lignins Phytochemistry. 65: 313-321. PMID 14751302 DOI: 10.1016/J.Phytochem.2003.11.007  0.365
2004 Ralph J, Bunzel M, Marita JM, Hatfield RD, Lu F, Kim H, Schatz PF, Grabber JH, Steinhart H. Peroxidase-dependent cross-linking reactions of p-hydroxycinnamates in plant cell walls Phytochemistry Reviews. 3: 79-96. DOI: 10.1023/B:Phyt.0000047811.13837.Fb  0.723
2004 Ralph J, Lundquist K, Brunow G, Lu F, Kim H, Schatz PF, Marita JM, Hatfield RD, Ralph SA, Christensen JH, Boerjan W. Lignins: Natural polymers from oxidative coupling of 4-hydroxyphenyl- propanoids Phytochemistry Reviews. 3: 29-60. DOI: 10.1023/B:Phyt.0000047809.65444.A4  0.741
2003 Ferguson LR, Lim IF, Pearson AE, Ralph J, Harris PJ. Bacterial antimutagenesis by hydroxycinnamic acids from plant cell walls. Mutation Research. 542: 49-58. PMID 14644353 DOI: 10.1016/J.Mrgentox.2003.08.005  0.377
2003 Kim H, Ralph J, Lu F, Ralph SA, Boudet AM, MacKay JJ, Sederoff RR, Ito T, Kawai S, Ohashi H, Higuchi T. NMR analysis of lignins in CAD-deficient plants. Part 1. Incorporation of hydroxycinnamaldehydes and hydroxybenzaldehydes into lignins. Organic & Biomolecular Chemistry. 1: 268-81. PMID 12929422 DOI: 10.1039/B209686B  0.4
2003 Lu F, Ralph J. Non-degradative dissolution and acetylation of ball-milled plant cell walls: high-resolution solution-state NMR. The Plant Journal : For Cell and Molecular Biology. 35: 535-44. PMID 12904215 DOI: 10.1046/J.1365-313X.2003.01817.X  0.395
2003 Grabber JH, Hatfield RD, Ralph J. Apoplastic pH and monolignol addition rate effects on lignin formation and cell wall degradability in maize. Journal of Agricultural and Food Chemistry. 51: 4984-9. PMID 12903957 DOI: 10.1021/Jf030027C  0.313
2003 Goujon T, Sibout R, Pollet B, Maba B, Nussaume L, Bechtold N, Lu F, Ralph J, Mila I, Barrière Y, Lapierre C, Jouanin L. A new Arabidopsis thaliana mutant deficient in the expression of O-methyltransferase impacts lignins and sinapoyl esters. Plant Molecular Biology. 51: 973-89. PMID 12777055 DOI: 10.1023/A:1023022825098  0.383
2003 Li L, Zhou Y, Cheng X, Sun J, Marita JM, Ralph J, Chiang VL. Combinatorial modification of multiple lignin traits in trees through multigene cotransformation. Proceedings of the National Academy of Sciences of the United States of America. 100: 4939-44. PMID 12668766 DOI: 10.1073/Pnas.0831166100  0.734
2003 Bunzel M, Ralph J, Kim H, Lu F, Ralph SA, Marita JM, Hatfield RD, Steinhart H. Sinapate dehydrodimers and sinapate-ferulate heterodimers in cereal dietary fiber. Journal of Agricultural and Food Chemistry. 51: 1427-34. PMID 12590493 DOI: 10.1021/Jf020910V  0.727
2003 Marita JM, Vermerris W, Ralph J, Hatfield RD. Variations in the cell wall composition of maize brown midrib mutants. Journal of Agricultural and Food Chemistry. 51: 1313-21. PMID 12590475 DOI: 10.1021/Jf0260592  0.717
2003 Marita JM, Ralph J, Hatfield RD, Guo D, Chen F, Dixon RA. Structural and compositional modifications in lignin of transgenic alfalfa down-regulated in caffeic acid 3-O-methyltransferase and caffeoyl coenzyme A 3-O-methyltransferase. Phytochemistry. 62: 53-65. PMID 12475619 DOI: 10.1016/S0031-9422(02)00434-X  0.737
2003 Bunzel M, Ralph J, Funk C, Steinhart H. Isolation and identification of a ferulic acid dehydrotrimer from saponified maize bran insoluble fiber European Food Research and Technology. 217: 128-133. DOI: 10.1007/S00217-003-0709-0  0.374
2002 Grabber JH, Ralph J, Hatfield RD. Model studies of ferulate-coniferyl alcohol cross-product formation in primary maize walls: implications for lignification in grasses. Journal of Agricultural and Food Chemistry. 50: 6008-16. PMID 12358473 DOI: 10.1021/Jf0205312  0.36
2002 Kim H, Ralph J, Lu F, Pilate G, Leplé J, Pollet B, Lapierre C. Identification of the Structure and Origin of Thioacidolysis Marker Compounds for Cinnamyl Alcohol Dehydrogenase Deficiency in Angiosperms Journal of Biological Chemistry. 277: 47412-47419. PMID 12351655 DOI: 10.1074/Jbc.M208860200  0.381
2002 Lu F, Ralph J. Preliminary evidence for sinapyl acetate as a lignin monomer in kenaf. Chemical Communications (Cambridge, England). 90-1. PMID 12120325 DOI: 10.1039/B109876D  0.323
2002 Bunzel M, Allerdings E, Sinwell V, Ralph J, Steinhart H. Cell wall hydroxycinnamates in wild rice ( Zizania aquatica L.) insoluble dietary fibre European Food Research and Technology. 214: 482-488. DOI: 10.1007/S00217-002-0512-3  0.382
2001 Chabannes M, Barakate A, Lapierre C, Marita JM, Ralph J, Pean M, Danoun S, Halpin C, Grima-Pettenati J, Boudet AM. Strong decrease in lignin content without significant alteration of plant development is induced by simultaneous down-regulation of cinnamoyl CoA reductase (CCR) and cinnamyl alcohol dehydrogenase (CAD) in tobacco plants. The Plant Journal : For Cell and Molecular Biology. 28: 257-70. PMID 11722769 DOI: 10.1046/J.1365-313X.2001.01140.X  0.729
2001 Stange RR, Ralph J, Peng J, Sims JJ, Midland SL, McDonald RE. Acidolysis and hot water extraction provide new insights into the composition of the induced "lignin-like" material from squash fruit. Phytochemistry. 57: 1005-1011. PMID 11423147 DOI: 10.1016/S0031-9422(01)00096-6  0.365
2001 Ralph J, Lapierre C, Marita JM, Kim H, Lu F, Hatfield RD, Ralph S, Chapple C, Franke R, Hemm MR, Van Doorsselaere J, Sederoff RR, O'Malley DM, Scott JT, MacKay JJ, et al. Elucidation of new structures in lignins of CAD- and COMT-deficient plants by NMR. Phytochemistry. 57: 993-1003. PMID 11423146 DOI: 10.1016/S0031-9422(01)00109-1  0.765
2001 Grabber JH, Ralph J, Hatfield RD. Cross-linking of maize walls by ferulate dimerization and incorporation into lignin. Journal of Agricultural and Food Chemistry. 48: 6106-13. PMID 11312783 DOI: 10.1021/Jf0006978  0.368
2001 Ralph J, Lapierre C, Lu F, Marita JM, Pilate G, Van Doorsselaere J, Boerjan W, Jouanin L. NMR evidence for benzodioxane structures resulting from incorporation of 5-hydroxyconiferyl alcohol into Lignins of O-methyltransferase-deficient poplars. Journal of Agricultural and Food Chemistry. 49: 86-91. PMID 11302112 DOI: 10.1021/JF001042+  0.74
2001 Marita JM, Ralph J, Lapierre C, Jouanin L, Boerjan W. NMR characterization of lignins from transgenic poplars with suppressed caffeic acid O-methyltransferase activity Journal of the Chemical Society. Perkin Transactions 1. 22: 2939-2945. DOI: 10.1039/B107219F  0.75
2001 Boerjan W, Meyermans H, Chen C, Baucher M, Doorsselaere JV, Morreel K, Messens E, Lapierre C, Pollet B, Jouanin L, Leplé J, Ralph J, Marita J, Guiney E, Schuch W, et al. Lignin Biosynthesis in Poplar: Genetic Engineering and Effects on Kraft Pulping Progress in Biotechnology. 18: 187-194. DOI: 10.1016/S0921-0423(01)80072-1  0.738
2001 Bunzel M, Ralph J, Marita JM, Hatfield RD, Steinhart H. Diferulates as structural components in soluble and insoluble cereal dietary fibre Journal of the Science of Food and Agriculture. 81: 653-660. DOI: 10.1002/Jsfa.861  0.701
2000 Bunzel M, Ralph J, Marita J, Steinhart H. Identification of 4-O-5'-coupled diferulic acid from insoluble cereal fiber. Journal of Agricultural and Food Chemistry. 48: 3166-9. PMID 10956086 DOI: 10.1021/Jf000125N  0.714
2000 Meyermans H, Morreel K, Lapierre C, Pollet B, De Bruyn A, Busson R, Herdewijn P, Devreese B, Van Beeumen J, Marita JM, Ralph J, Chen C, Burggraeve B, Van Montagu M, Messens E, et al. Modifications in lignin and accumulation of phenolic glucosides in poplar xylem upon down-regulation of caffeoyl-coenzyme A O-methyltransferase, an enzyme involved in lignin biosynthesis. The Journal of Biological Chemistry. 275: 36899-909. PMID 10934215 DOI: 10.1074/Jbc.M006915200  0.712
2000 Kim H, Ralph J, Yahiaoui N, Pean M, Boudet A. Cross-coupling of hydroxycinnamyl aldehydes into lignins. Organic Letters. 2: 2197-2200. PMID 10930242 DOI: 10.1021/Ol005906O  0.396
2000 Hatfield RD, Grabber J, Ralph J, Brei K. Using the acetyl bromide assay to determine lignin concentrations in herbaceous plants: some cautionary notes. Journal of Agricultural and Food Chemistry. 47: 628-32. PMID 10563943 DOI: 10.1021/Jf9808776  0.343
2000 Lu F, Ralph J. Detection and determination of p-coumaroylated units in lignins. Journal of Agricultural and Food Chemistry. 47: 1988-92. PMID 10552483 DOI: 10.1021/Jf981140J  0.349
2000 Lu F, Ralph J. The DFRC method for lignin analysis. 7. Behavior of cinnamyl end groups. Journal of Agricultural and Food Chemistry. 47: 1981-7. PMID 10552482 DOI: 10.1021/Jf981138S  0.312
1999 Ralph J, Kim H, Peng J, Lu F. Arylpropane-1,3-diols in lignins from normal and CAD-deficient pines. Organic Letters. 1: 323-326. PMID 10905871 DOI: 10.1021/Ol9906559  0.363
1999 Garcia-Conesa MT, Kroon PA, Ralph J, Mellon FA, Colquhoun IJ, Saulnier L, Thibault JF, Williamson G. A cinnamoyl esterase from Aspergillus niger can break plant cell wall cross-links without release of free diferulic acids. European Journal of Biochemistry. 266: 644-52. PMID 10561608 DOI: 10.1046/J.1432-1327.1999.00910.X  0.414
1999 Marita JM, Ralph J, Hatfield RD, Chapple C. NMR characterization of lignins in Arabidopsis altered in the activity of ferulate 5-hydroxylase Proceedings of the National Academy of Sciences of the United States of America. 96: 12328-12332. PMID 10535921 DOI: 10.1073/Pnas.96.22.12328  0.721
1999 Hu WJ, Harding SA, Lung J, Popko JL, Ralph J, Stokke DD, Tsai CJ, Chiang VL. Repression of lignin biosynthesis promotes cellulose accumulation and growth in transgenic trees. Nature Biotechnology. 17: 808-12. PMID 10429249 DOI: 10.1038/11758  0.36
1999 Sederoff RR, MacKay JJ, Ralph J, Hatfield RD. Unexpected variation in lignin Current Opinion in Plant Biology. 2: 145-152. PMID 10322194 DOI: 10.1016/S1369-5266(99)80029-6  0.346
1999 Hatfield RD, Ralph J, Grabber JH. Cell Wall Structural Foundations: Molecular Basis for Improving Forage Digestibilities Crop Science. 39: 27-37. DOI: 10.2135/Cropsci1999.0011183X003900010005X  0.381
1999 Peng J, Lu F, Ralph J. Isochroman lignin trimers from DFRC-degraded Pinus taeda Phytochemistry. 50: 659-666. DOI: 10.1016/S0031-9422(98)00572-X  0.359
1999 Hatfield RD, Ralph J. Modelling the feasibility of intramolecular dehydrodiferulate formation in grass walls Journal of the Science of Food and Agriculture. 79: 425-427. DOI: 10.1002/(Sici)1097-0010(19990301)79:3<425::Aid-Jsfa282>3.0.Co;2-U  0.319
1999 Hatfield RD, Ralph J, Grabber JH. Cell wall cross‐linking by ferulates and diferulates in grasses Journal of the Science of Food and Agriculture. 79: 403-407. DOI: 10.1002/(Sici)1097-0010(19990301)79:3<403::Aid-Jsfa263>3.0.Co;2-0  0.361
1999 Garcia-Conesa M, Wilson P, Plumb G, Ralph J, Williamson G. Antioxidant properties of 4,4′‐dihydroxy‐3,3′‐dimethoxy‐β,β′‐bicinnamic acid (8‐8‐diferulic acid, non‐cyclic form) Journal of the Science of Food and Agriculture. 79: 379-384. DOI: 10.1002/(Sici)1097-0010(19990301)79:3<379::Aid-Jsfa259>3.0.Co;2-V  0.335
1998 Peng J, Lu F, Ralph J. The DFRC Method for Lignin Analysis. 4. Lignin Dimers Isolated from DFRC-Degraded Loblolly Pine Wood. Journal of Agricultural and Food Chemistry. 46: 553-560. PMID 10554276 DOI: 10.1021/Jf970802M  0.323
1998 Lu F, Ralph J. The DFRC method for lignin analysis. 2. Monomers from isolated lignins Journal of Agricultural and Food Chemistry. 46: 547-552. PMID 10554275 DOI: 10.1021/Jf970676M  0.36
1998 Lu F, Ralph J. The DFRC Method for Lignin Analysis. Part 3. NMR Studies Journal of Wood Chemistry and Technology. 18: 219-233. DOI: 10.1080/02773819809349578  0.335
1998 Ralph J, Hatfield RD, Piquemal J, Yahiaoui N, Pean M, Lapierre C, Boudet AM. NMR characterization of altered lignins extracted from tobacco plants down-regulated for lignification enzymes cinnamyl-alcohol dehydrogenase and cinnamoyl-CoA reductase Proceedings of the National Academy of Sciences of the United States of America. 95: 12803-12808. DOI: 10.1073/Pnas.95.22.12803  0.389
1998 Ralph J, Zhang Y, Ede RM. Preparation of synthetic lignins with superior NMR characteristics via isotopically labeled monolignols Journal of the Chemical Society-Perkin Transactions 1. 2609-2614. DOI: 10.1039/A803281E  0.386
1998 Lu F, Ralph J. Facile Synthesis of 4-Hydroxycinnamylp-Coumarates Journal of Agricultural and Food Chemistry. 46: 2911-2913. DOI: 10.1021/Jf980440Y  0.304
1998 Ralph J, Conesa MTG, Williamson G. Simple Preparation of 8−5-Coupled Diferulate Journal of Agricultural and Food Chemistry. 46: 2531-2532. DOI: 10.1021/Jf980123R  0.359
1998 Grabber JH, Ralph J, Hatfield RD. Ferulate Cross-Links Limit the Enzymatic Degradation of Synthetically Lignified Primary Walls of Maize Journal of Agricultural and Food Chemistry. 46: 2609-2614. DOI: 10.1021/Jf9800099  0.389
1998 Ralph J, Peng J, Lua F. Isochroman structures in lignin: a new β-1 pathway Tetrahedron Letters. 39: 4963-4964. DOI: 10.1016/S0040-4039(98)00968-X  0.341
1998 Ralph J, Zhang Y. A new synthesis of (Z)-coniferyl alcohol, and characterization of its derived synthetic lignin Tetrahedron. 54: 1349-1354. DOI: 10.1016/S0040-4020(97)10361-1  0.361
1998 Grabber JH, Ralph J, Hatfield RD. Severe inhibition of maize wall degradation by synthetic lignins formed with coniferaldehyde Journal of the Science of Food and Agriculture. 78: 81-87. DOI: 10.1002/(Sici)1097-0010(199809)78:1<81::Aid-Jsfa86>3.0.Co;2-N  0.433
1998 Grabber JH, Hatfield RD, Ralph J. Diferulate cross-links impede the enzymatic degradation of non-lignified maize walls Journal of the Science of Food and Agriculture. 77: 193-200. DOI: 10.1002/(Sici)1097-0010(199806)77:2<193::Aid-Jsfa25>3.0.Co;2-A  0.345
1997 Garcia-Conesa MT, Plumb GW, Waldron KW, Ralph J, Williamson G. Ferulic acid dehydrodimers from wheat bran: Isolation, purification and antioxidant properties of 8-O-4-diferulic acid Redox Report. 3: 319-323. PMID 9754331 DOI: 10.1080/13510002.1997.11747129  0.353
1997 Shi Y, Weimer PJ, Ralph J. Formation of formate and hydrogen, and flux of reducing equivalents and carbon in Ruminococcus flavefaciens FD-1 Antonie Van Leeuwenhoek, International Journal of General and Molecular Microbiology. 72: 101-109. PMID 9298188 DOI: 10.1023/A:1000256221938  0.312
1997 Ralph J, MacKay JJ, Hatfield RD, O'Malley DM, Whetten RW, Sederoff RR. Abnormal lignin in a loblolly pine mutant. Science (New York, N.Y.). 277: 235-9. PMID 9211851 DOI: 10.1126/Science.277.5323.235  0.327
1997 Quideau S, Ralph J. Lignin–ferulate cross-links in grasses. Part 4.1–3 Incorporation of 5–5-coupled dehydrodiferulate into synthetic lignin Journal of the Chemical Society-Perkin Transactions 1. 2351-2358. DOI: 10.1039/A701808H  0.331
1997 Lu F, Ralph J. DFRC Method for Lignin Analysis. 1. New Method for β-Aryl Ether Cleavage:  Lignin Model Studies Journal of Agricultural and Food Chemistry. 45: 4655-4660. DOI: 10.1021/Jf970539P  0.318
1997 Lu F, Ralph J. Derivatization Followed by Reductive Cleavage (DFRC Method), a New Method for Lignin Analysis:  Protocol for Analysis of DFRC Monomers Journal of Agricultural and Food Chemistry. 45: 2590-2592. DOI: 10.1021/Jf970258H  0.358
1997 Grabber JH, Ralph J, Hatfield RD, Quideau S. p-Hydroxyphenyl, Guaiacyl, and Syringyl Lignins Have Similar Inhibitory Effects on Wall Degradability Journal of Agricultural and Food Chemistry. 45: 2530-2532. DOI: 10.1021/Jf970029V  0.429
1997 Micard V, Grabber JH, Ralph J, Renard CMGC, Thibault J-. Dehydrodiferulic acids from sugar-beet pulp Phytochemistry. 44: 1365-1368. DOI: 10.1016/S0031-9422(96)00699-1  0.361
1997 Oosterveld A, Grabber JH, Beldman G, Ralph J, Voragen AGJ. Formation of ferulic acid dehydrodimers through oxidative cross-linking of sugar beet pectin Carbohydrate Research. 300: 179-181. DOI: 10.1016/S0008-6215(97)00041-4  0.328
1996 Ralph J, Grabber JH. Dimeric ß-Ether Thioacidolysis Products Resulting from Incomplete Ether Cleavage Holzforschung. 50: 425-428. DOI: 10.1515/Hfsg.1996.50.5.425  0.346
1996 Lu F, Ralph J. Reactions of Lignin Model ß-Aryl Ethers with Acetyl Bromide Holzforschung. 50: 360-364. DOI: 10.1515/Hfsg.1996.50.4.360  0.32
1996 Ralph J. An unusual lignin from kenaf Journal of Natural Products. 59: 341-342. DOI: 10.1021/Np960143S  0.318
1996 Grabber JH, Ralph J, Hatfield RD, Quideau S, Kuster T, Pell AN. Dehydrogenation Polymer−Cell Wall Complexes as a Model for Lignified Grass Walls Journal of Agricultural and Food Chemistry. 44: 1453-1459. DOI: 10.1021/Jf9502717  0.378
1996 Grabber JH, Quideau S, Ralph J. p-coumaroylated syringyl units in maize lignin: Implications for β-ether cleavage by thioacidolysis Phytochemistry. 43: 1189-1194. DOI: 10.1016/S0031-9422(96)00431-1  0.356
1996 Waldron KW, Parr AJ, Ng A, Ralph J. Cell Wall Esterified Phenolic Dimers: Identification and Quantification by Reverse Phase High Performance Liquid Chromatography and Diode Array Detection Phytochemical Analysis. 7: 305-312. DOI: 10.1002/(Sici)1099-1565(199611)7:6<305::Aid-Pca320>3.0.Co;2-A  0.329
1995 Grabber JH, Hatfield RD, Ralph J, Zoń J, Amrhein N. Ferulate cross-linking in cell walls isolated from maize cell suspensions Phytochemistry. 40: 1077-1082. DOI: 10.1016/0031-9422(95)00413-2  0.385
1995 Ralph J, Grabber JH, Hatfield RD. Lignin-ferulate cross-links in grasses: active incorporation of ferulate polysaccharide esters into ryegrass lignins Carbohydrate Research. 275: 167-178. DOI: 10.1016/0008-6215(95)00237-N  0.407
1994 Ralph J, Quideau S, Grabber JH, Hatfield RD. Identification and synthesis of new ferulic acid dehydrodimers present in grass cell walls Journal of the Chemical Society-Perkin Transactions 1. 3485-3498. DOI: 10.1039/P19940003485  0.318
1994 Ralph J, Hatfield RD, Quideau S, Helm RF, Grabber JH, Jung HG. Pathway of p-Coumaric Acid Incorporation into Maize Lignin As Revealed by NMR Journal of the American Chemical Society. 116: 9448-9456. DOI: 10.1021/Ja00100A006  0.347
1994 Hatfield RD, Jung HG, Ralph J, Buxton DR, Weimer PJ. A comparison of the insoluble residues produced by the Klason lignin and acid detergent lignin procedures Journal of the Science of Food and Agriculture. 65: 51-58. DOI: 10.1002/Jsfa.2740650109  0.333
1993 Helm RF, Ralph J. Synthesis and spectroscopic characterization of hydroxycinnamoylated methyl alpha-L-arabinofuranosyl-(1-->2)- and (1-->3)-beta-D-xylopyranosides. Carbohydrate Research. 240: 23-38. PMID 8458010 DOI: 10.1016/0008-6215(93)84168-6  0.317
1993 Ralph J. 1H NMR of acetylated β-ether/β-ether lignin model trimers Magnetic Resonance in Chemistry. 31: 357-363. DOI: 10.1002/Mrc.1260310409  0.328
1993 Deetz DA, Jung HG, Helm RF, Hatfield RD, Ralph J. Impact of methyl 5-O-(E)-feruloyl-α-L-arabinofuranoside on in-vitro degradation of cellulose and xylan Journal of the Science of Food and Agriculture. 61: 423-427. DOI: 10.1002/Jsfa.2740610407  0.347
1992 Ralph J, Helm RF, Quideau S. Lignin–feruloyl ester cross-links in grasses. Part 2. Model compound syntheses Journal of the Chemical Society-Perkin Transactions 1. 2971-2980. DOI: 10.1039/P19920002971  0.358
1992 Ralph J, Helm RF, Quideau S, Hatfield RD. Lignin–feruloyl ester cross-links in grasses. Part 1. Incorporation of feruloyl esters into coniferyl alcohol dehydrogenation polymers Journal of the Chemical Society-Perkin Transactions 1. 1: 2961-2969. DOI: 10.1039/P19920002961  0.417
1992 Helm RF, Ralph J. Lignin-hydroxycinnamyl model compounds related to forage cell wall structure. 1. Ether-linked structures Journal of Agricultural and Food Chemistry. 40: 2167-2175. DOI: 10.1021/Jf00023A025  0.391
1992 Quideau S, Ralph J. Facile large-scale synthesis of coniferyl, sinapyl, and p-coumaryl alcohol Journal of Agricultural and Food Chemistry. 40: 1108-1110. DOI: 10.1021/Jf00019A003  0.31
1991 Hatfield RD, Helm RF, Ralph J. Synthesis of methyl 5-O-trans-feruloyl-alpha-L-arabinofuranoside and its use as a substrate to assess feruloyl esterase activity. Analytical Biochemistry. 194: 25-33. PMID 1867381 DOI: 10.1016/0003-2697(91)90146-K  0.341
1991 Ralph J, Hatfield RD. Pyrolysis-GC-MS characterization of forage materials Journal of Agricultural and Food Chemistry. 39: 1426-1437. DOI: 10.1021/Jf00008A014  0.311
1991 Ralph J, Helm RF. Rapid proton NMR method for determination of threo:erythro ratios in lignin model compounds and examination of reduction stereochemistry Journal of Agricultural and Food Chemistry. 39: 705-709. DOI: 10.1021/Jf00004A016  0.31
1991 Jung HG, Ralph J, Hatfield RD. Degradability of phenolic acid-hemicellulose esters: A model system Journal of the Science of Food and Agriculture. 56: 469-478. DOI: 10.1002/Jsfa.2740560407  0.342
1990 Jina AN, Ralph J, Ballou CE. Synthesis of affinity ligands and radioactive probes for isolation and study of myo-inositol 1,4,5-trisphosphate binding proteins. Biochemistry. 29: 5203-9. PMID 2165805 DOI: 10.1021/Bi00473A029  0.304
1984 Landucci LL, Ralph J. Anthraquinone Losses During Alkaline Pulping Journal of Wood Chemistry and Technology. 4: 149-161. DOI: 10.1080/02773818408081149  0.347
1983 Ralph J, Adams BR. Determination of the Conformation and Isomeric Composition of Lignin Model Quinone Methides By NMR Journal of Wood Chemistry and Technology. 3: 183-194. DOI: 10.1080/02773818308085159  0.335
1983 Ralph J, Young RA. Stereochemical Aspects Op Addition Reactions Involving Lignin Model Quinone Methides Journal of Wood Chemistry and Technology. 3: 161-181. DOI: 10.1080/02773818308085158  0.323
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