Richard Royce Schrock - Publications

Affiliations: 
Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
Organic chemistry
Website:
https://www.nobelprize.org/prizes/chemistry/2005/schrock/auto-biography/

208 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Copéret C, Pucino M, Zhai F, Gordon CP, Mance D, Hoveyda AH, Schrock RR. Silica-Supported Molybdenum-Oxo alkylidenes: Bridging the Gap between Internal and Terminal Olefin Metathesis. Angewandte Chemie (International Ed. in English). PMID 31099940 DOI: 10.1002/anie.201903325  0.56
2019 Mu Y, Nguyen TT, Koh MJ, Schrock RR, Hoveyda AH. E- and Z-, di- and tri-substituted alkenyl nitriles through catalytic cross-metathesis. Nature Chemistry. PMID 30936524 DOI: 10.1038/s41557-019-0233-x  0.56
2019 Hickey AK, Wickramasinghe LA, Schrock RR, Tsay C, Müller P. Protonation Studies of Molybdenum(VI) Nitride Complexes That Contain the [2,6-(ArNCH)NCH] Ligand (Ar = 2,6-Diisopropylphenyl). Inorganic Chemistry. PMID 30807124 DOI: 10.1021/acs.inorgchem.8b03346  0.76
2019 Hoveyda AH, Mu Y, Nguyen TT, van der Mei FW, Schrock RR. Traceless Protection for More Broadly Applicable Olefin Metathesis. Angewandte Chemie (International Ed. in English). PMID 30747464 DOI: 10.1002/anie.201901132  0.56
2018 VenkatRamami S, Schrock RR, Hoveyda A, Müller P, Tsay C. Synthesis of High-Oxidation-State Mo═CHX Complexes, Where X = Cl, CF, Phosphonium, CN. Organometallics. 37: 1641-1644. PMID 30655653 DOI: 10.1021/acs.organomet.8b00168  0.76
2018 Wickramasinghe LA, Schrock RR, Tsay C, Müller P. Molybdenum Complexes that Contain a Calix[6]azacryptand Ligand as Catalysts for Reduction of N to Ammonia. Inorganic Chemistry. PMID 30516366 DOI: 10.1021/acs.inorgchem.8b02903  0.76
2018 Zhai F, Bukhryakov KV, Schrock RR, Hoveyda AH, Tsay C, Müller P. Syntheses of Molybdenum Oxo Benzylidene Complexes. Journal of the American Chemical Society. PMID 30296371 DOI: 10.1021/jacs.8b09616  0.76
2018 Bukhryakov KV, Schrock RR, Hoveyda AH, Tsay C, Müller P. Syntheses of Molybdenum Oxo Alkylidene Complexes Through Addition of Water to an Alkylidyne Complex. Journal of the American Chemical Society. PMID 29432003 DOI: 10.1021/jacs.8b00499  0.76
2017 Bukhryakov KV, VenkatRamani S, Tsay C, Hoveyda A, Schrock RR. Syntheses of Molybdenum Adamantylimido and -Butylimido Alkylidene Chloride Complexes Using HCI and Diphenylmethylphosphine. Organometallics. 36: 4208-4214. PMID 31659999 DOI: 10.1021/acs.organomet.7b00647  0.48
2017 Nguyen TT, Koh MJ, Mann TJ, Schrock RR, Hoveyda AH. Synthesis of E- and Z-trisubstituted alkenes by catalytic cross-metathesis. Nature. 552: 347-354. PMID 29293209 DOI: 10.1038/nature25002  0.56
2017 Townsend EM, Schrock RR, Hoveyda AH. Correction to "Z-Selective Metathesis Homocoupling of 1,3-Dienes by Molybdenum and Tungsten Monoaryloxide Pyrrolide (MAP) Complexes". Journal of the American Chemical Society. 139: 16430. PMID 29112412 DOI: 10.1021/jacs.7b11214  0.56
2017 Wickramasinghe LA, Schrock RR, Müller P, Ogawa T. Reduction of Dinitrogen to Ammonia Catalyzed by Molybdenum Diamido Complexes. Journal of the American Chemical Society. PMID 28640615 DOI: 10.1021/jacs.7b04800  0.76
2017 Sharma A, Roemelt M, Reithofer M, Schrock RR, Hoffman B, Neese F. EPR/ENDOR and Theoretical Study of the Jahn-Teller-Active [HIPTN3N]Mo(V)L Complexes (L = N(-), NH). Inorganic Chemistry. PMID 28571321 DOI: 10.1021/acs.inorgchem.7b00364  0.68
2017 Bukhryakov KV, Schrock RR, Hoveyda AH, Müller P, Becker J. Synthesis of 2,6-Hexa-tert-butylterphenyl Derivatives, 2,6-(2,4,6-t-Bu3C6H2)2C6H3X, where X = I, Li, OH, SH, N3, or NH2. Organic Letters. PMID 28459588 DOI: 10.1021/acs.orglett.7b01062  0.76
2017 Jang ES, John JM, Schrock RR. Synthesis of Cis,syndiotactic-A-alt-B Copolymers from Enantiomerically Pure Endo-2-Substituted-5,6-Norbornenes. Journal of the American Chemical Society. PMID 28355081 DOI: 10.1021/jacs.7b01747  0.32
2017 Koh MJ, Nguyen TT, Lam JK, Torker S, Hyvl J, Schrock RR, Hoveyda AH. Molybdenum chloride catalysts for Z-selective olefin metathesis reactions. Nature. PMID 28114300 DOI: 10.1038/nature21043  0.56
2017 Shen X, Nguyen TT, Koh MJ, Xu D, Speed AW, Schrock RR, Hoveyda AH. Kinetically E-selective macrocyclic ring-closing metathesis. Nature. PMID 28068669 DOI: 10.1038/nature20800  0.56
2016 Lam JK, Zhu C, Bukhryakov KV, Müller P, Hoveyda A, Schrock RR. Synthesis and Evaluation of Molybdenum and Tungsten Monoaryloxide Halide Alkylidene Complexes for Z-Selective Cross-Metathesis of Cyclooctene and Z-1,2-Dichloroethylene. Journal of the American Chemical Society. 138: 15774-15783. PMID 27934034 DOI: 10.1021/jacs.6b10499  0.76
2016 Jang ES, John JM, Schrock RR. Synthesis of Cis,syndiotactic A-alt-B Copolymers from Two Enantiomerically Pure Trans-2,3-Disubstituted-5,6-Norbornenes. Acs Central Science. 2: 631-636. PMID 27725961 DOI: 10.1021/acscentsci.6b00200  0.32
2016 Yu EC, Johnson BM, Townsend EM, Schrock RR, Hoveyda AH. Synthesis of Linear (Z)-α,β-Unsaturated Esters by Catalytic Cross-Metathesis. The Influence of Acetonitrile. Angewandte Chemie (International Ed. in English). PMID 27634213 DOI: 10.1002/anie.201608087  1
2016 Nguyen TT, Koh MJ, Shen X, Romiti F, Schrock RR, Hoveyda AH. Kinetically controlled E-selective catalytic olefin metathesis. Science (New York, N.Y.). 352: 569-75. PMID 27126041 DOI: 10.1126/science.aaf4622  0.56
2016 Koh MJ, Nguyen TT, Zhang H, Schrock RR, Hoveyda AH. Direct synthesis of Z-alkenyl halides through catalytic cross-metathesis. Nature. 531: 459-65. PMID 27008965 DOI: 10.1038/nature17396  0.56
2016 Zahim S, Wickramasinghe LA, Evano G, Jabin I, Schrock RR, Müller P. Calix[6]azacryptand Ligand with a Sterically Protected Tren-Based Coordination Site for Metal Ions. Organic Letters. PMID 26999005 DOI: 10.1021/acs.orglett.6b00410  0.76
2015 Schrock RR. Metathesis by Molybdenum and Tungsten Catalysts. Chimia. 69: 388-92. PMID 26507590 DOI: 10.2533/chimia.2015.388  1
2015 Jeong H, John JM, Schrock RR, Hoveyda AH. Synthesis of alternating trans-AB copolymers through ring-opening metathesis polymerization initiated by molybdenum alkylidenes. Journal of the American Chemical Society. 137: 2239-42. PMID 25642845 DOI: 10.1021/jacs.5b00221  1
2015 Yu M, Schrock RR, Hoveyda AH. Catalyst-controlled stereoselective olefin metathesis as a principal strategy in multistep synthesis design: a concise route to (+)-neopeltolide. Angewandte Chemie (International Ed. in English). 54: 215-20. PMID 25377347 DOI: 10.1002/anie.201409120  0.56
2015 Axtell JC, Schrock RR, Müller P, Hoveyda AH. Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand Organometallics. 34: 2110-2113. DOI: 10.1021/om501213x  1
2015 Jeong H, John JM, Schrock RR. Formation of Alternating trans- A -alt- B Copolymers through Ring-Opening Metathesis Polymerization Initiated by Molybdenum Imido Alkylidene Complexes Organometallics. 34: 5136-5145. DOI: 10.1021/acs.organomet.5b00709  1
2015 Jeong H, Schrock RR, Müller P. Synthesis of Molybdenum and Tungsten Alkylidene Complexes that Contain a tert-Butylimido Ligand Organometallics. 34: 4408-4418. DOI: 10.1021/acs.organomet.5b00633  1
2015 Hyvl J, Autenrieth B, Schrock RR. Proof of tacticity of stereoregular ROMP polymers through post polymerization modification Macromolecules. 48: 3148-3152. DOI: 10.1021/acs.macromol.5b00477  1
2015 Jeong H, Ng VWL, Börner J, Schrock RR. Stereoselective ring-opening metathesis polymerization (ROMP) of methyl- N -(1-phenylethyl)-2-azabicyclo[2.2.1]hept-5-ene-3-carboxylate by molybdenum and tungsten initiators Macromolecules. 48: 2006-2012. DOI: 10.1021/acs.macromol.5b00264  1
2015 Autenrieth B, Schrock RR. Stereospecific Ring-Opening Metathesis Polymerization (ROMP) of norbornene and tetracyclododecene by Mo and W initiators Macromolecules. 48: 2493-2503. DOI: 10.1021/acs.macromol.5b00161  1
2015 Autenrieth B, Jeong H, Forrest WP, Axtell JC, Ota A, Lehr T, Buchmeiser MR, Schrock RR. Stereospecific ring-opening metathesis polymerization (ROMP) of endo-dicyclopentadiene by molybdenum and tungsten catalysts Macromolecules. 48: 2480-2492. DOI: 10.1021/acs.macromol.5b00123  1
2014 Zhang H, Yu EC, Torker S, Schrock RR, Hoveyda AH. Preparation of macrocyclic Z-enoates and (E,Z)- or (Z,E)-dienoates through catalytic stereoselective ring-closing metathesis. Journal of the American Chemical Society. 136: 16493-6. PMID 25402822 DOI: 10.1021/ja510768c  1
2014 Speed AW, Mann TJ, O'Brien RV, Schrock RR, Hoveyda AH. Catalytic Z-selective cross-metathesis in complex molecule synthesis: a convergent stereoselective route to disorazole C1. Journal of the American Chemical Society. 136: 16136-9. PMID 25379808 DOI: 10.1021/ja509973r  1
2014 Axtell JC, Schrock RR, Müller P, Smith SJ, Hoveyda AH. Synthesis of Tungsten Imido Alkylidene Complexes that Contain an Electron-Withdrawing Imido Ligand. Organometallics. 33: 5342-5348. PMID 25328268 DOI: 10.1021/om5006676  1
2014 Townsend EM, Hyvl J, Forrest WP, Schrock RR, Müller P, Hoveyda AH. Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain Sterically Demanding Arenethiolate Ligands. Organometallics. 33: 5334-5341. PMID 25328267 DOI: 10.1021/om500655n  1
2014 Conley MP, Forrest WP, Mougel V, Copéret C, Schrock RR. Bulky aryloxide ligand stabilizes a heterogeneous metathesis catalyst. Angewandte Chemie (International Ed. in English). 53: 14221-4. PMID 25320050 DOI: 10.1002/anie.201408880  1
2014 Forrest WP, Weis JG, John JM, Axtell JC, Simpson JH, Swager TM, Schrock RR. Stereospecific ring-opening metathesis polymerization of norbornadienes employing tungsten oxo alkylidene initiators. Journal of the American Chemical Society. 136: 10910-3. PMID 25036528 DOI: 10.1021/ja506446n  1
2014 Schrock RR. Synthesis of stereoregular polymers through ring-opening metathesis polymerization. Accounts of Chemical Research. 47: 2457-66. PMID 24905960 DOI: 10.1021/ar500139s  1
2014 Schrock RR, Eagling R, Hordern J, Ross P. Happy 50th Birthday ChemComm! Chemical Communications. 50: 13-15. DOI: 10.1039/c3cc90386a  1
2014 Forrest WP, Axtell JC, Schrock RR. Tungsten oxo alkylidene complexes as initiators for the stereoregular polymerization of 2,3-dicarbomethoxynorbornadiene Organometallics. 33: 2313-2325. DOI: 10.1021/om5002364  1
2014 Dobereiner GE, Erdogan G, Larsen CR, Grotjahn DB, Schrock RR. A one-pot tandem olefin isomerization/metathesis-coupling (ISOMET) reaction Acs Catalysis. 4: 3069-3076. DOI: 10.1021/cs500889x  1
2014 Sun J, Simpson CK, Hopkins MD, Hock AS, Schrock RR. Tungsten Benzylidyne Complexes Inorganic Syntheses. 36: 137-141. DOI: 10.1002/9781118744994.ch25  1
2013 Conley MP, Mougel V, Peryshkov DV, Forrest WP, Gajan D, Lesage A, Emsley L, Copéret C, Schrock RR. A well-defined silica-supported tungsten oxo alkylidene is a highly active alkene metathesis catalyst. Journal of the American Chemical Society. 135: 19068-70. PMID 24304004 DOI: 10.1021/ja410052u  1
2013 Schrock R. Q&A: A sustainable chemist. Interview by Jonathan Moerdyk. Nature. 502: S59. PMID 24132336  1
2013 Townsend EM, Kilyanek SM, Schrock RR, Müller P, Smith SJ, Hoveyda AH. Synthesis of High Oxidation State Molybdenum Imido Heteroatom-Substituted Alkylidene Complexes. Organometallics. 32: 4612-4617. PMID 24082360 DOI: 10.1021/om400584f  1
2013 Cain MF, Forrest WP, Peryshkov DV, Schrock RR, Müller P. Synthesis of a TREN in which the aryl substituents are part of a 45 atom macrocycle. Journal of the American Chemical Society. 135: 15338-41. PMID 24074292 DOI: 10.1021/ja408964g  1
2013 Dobereiner GE, Yuan J, Schrock RR, Goldman AS, Hackenberg JD. Catalytic synthesis of n-alkyl arenes through alkyl group cross-metathesis. Journal of the American Chemical Society. 135: 12572-5. PMID 23909821 DOI: 10.1021/ja4066392  1
2013 Reithofer MR, Dobereiner GE, Schrock RR, Müller P. Monoaryloxide Pyrrolide (MAP) Imido Alkylidene Complexes of Molybdenum and Tungsten That Contain 2,6-Bis(2,5-R2-pyrrolyl)phenoxide (R = i-Pr, Ph) Ligands and an Unsubstituted Metallacyclobutane on Its Way to Losing Ethylene. Organometallics. 32: 2489-2492. PMID 23794779 DOI: 10.1021/om400114h  1
2013 Mann TJ, Speed AW, Schrock RR, Hoveyda AH. Catalytic Z-selective cross-metathesis with secondary silyl- and benzyl-protected allylic ethers: mechanistic aspects and applications to natural product synthesis. Angewandte Chemie (International Ed. in English). 52: 8395-400. PMID 23794384 DOI: 10.1002/anie.201302538  1
2013 Schrock RR. Alkyne metathesis by molybdenum and tungsten alkylidyne complexes. Chemical Communications (Cambridge, England). 49: 5529-31. PMID 23673995 DOI: 10.1039/c3cc42609b  1
2013 Kiesewetter ET, O'Brien RV, Yu EC, Meek SJ, Schrock RR, Hoveyda AH. Synthesis of Z-(pinacolato)allylboron and Z-(pinacolato)alkenylboron compounds through stereoselective catalytic cross-metathesis. Journal of the American Chemical Society. 135: 6026-9. PMID 23586708 DOI: 10.1021/ja403188t  1
2013 Wang C, Yu M, Kyle AF, Jakubec P, Dixon DJ, Schrock RR, Hoveyda AH. Efficient and selective formation of macrocyclic disubstituted Z alkenes by ring-closing metathesis (RCM) reactions catalyzed by Mo- or W-based monoaryloxide pyrrolide (MAP) complexes: applications to total syntheses of epilachnene, yuzu lactone, ambrettolide, epothilone C, and nakadomarin A. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 2726-40. PMID 23345004 DOI: 10.1002/chem.201204045  1
2013 Christensen RL, Enriquez MM, Wagner NL, Peacock-Villada AY, Scriban C, Schrock RR, Polívka T, Frank HA, Birge RR. Energetics and dynamics of the low-lying electronic states of constrained polyenes: implications for infinite polyenes. The Journal of Physical Chemistry. A. 117: 1449-65. PMID 23330819 DOI: 10.1021/jp310592s  1
2013 Wang C, Haeffner F, Schrock RR, Hoveyda AH. Molybdenum-based complexes with two aryloxides and a pentafluoroimido ligand: catalysts for efficient Z-selective synthesis of a macrocyclic trisubstituted alkene by ring-closing metathesis. Angewandte Chemie (International Ed. in English). 52: 1939-43. PMID 23307513 DOI: 10.1002/anie.201209180  1
2013 Schrock R. A sustainable chemist Nature. 502: S59. DOI: 10.1038/502S59a  1
2013 Gerber LCH, Schrock RR. Synthesis of methylidene complexes that contain a 2,6-Dimesitylphenylimido ligand and ethenolysis of 2,3-dicarbomethoxynorbornadiene Organometallics. 32: 5573-5580. DOI: 10.1021/om400844k  1
2013 Peryshkov DV, Forrest WP, Schrock RR, Smith SJ, Müller P. B(C6F5)3 activation of oxo tungsten complexes that are relevant to olefin metathesis Organometallics. 32: 5256-5259. DOI: 10.1021/om4007906  1
2013 Jeong H, Kozera DJ, Schrock RR, Smith SJ, Zhang J, Ren N, Hillmyer MA. Z-selective ring-opening metathesis polymerization of 3-substituted cyclooctenes by monoaryloxide pyrrolide imido alkylidene (MAP) catalysts of molybdenum and Tungsten Organometallics. 32: 4843-4850. DOI: 10.1021/om400583t  1
2013 Yuan J, Schrock RR, Gerber LCH, Müller P, Smith S. Synthesis and ROMP chemistry of decafluoroterphenoxide molybdenum imido alkylidene and ethylene complexes Organometallics. 32: 2983-2992. DOI: 10.1021/om400199u  1
2013 Gerber LCH, Schrock RR, Müller P. Molybdenum and tungsten monoalkoxide pyrrolide (MAP) alkylidene complexes that contain a 2,6-dimesitylphenylimido ligand Organometallics. 32: 2373-2378. DOI: 10.1021/om4000693  1
2013 Nawara-Hultzsch AJ, Hackenberg JD, Punji B, Supplee C, Emge TJ, Bailey BC, Schrock RR, Brookhart M, Goldman AS. Rational design of highly active "hybrid" phosphine-phosphinite pincer iridium catalysts for alkane metathesis Acs Catalysis. 3: 2505-2514. DOI: 10.1021/cs400624c  1
2012 Lichtscheidl AG, Ng VW, Müller P, Takase MK, Schrock RR, Malcolmson SJ, Meek SJ, Li B, Kiesewetter ET, Hoveyda AH. Bipyridine Adducts of Molybdenum Imido Alkylidene and Imido Alkylidyne Complexes. Organometallics. 31: 4558-4564. PMID 22899875 DOI: 10.1021/om300353e  1
2012 Townsend EM, Schrock RR, Hoveyda AH. Z-selective metathesis homocoupling of 1,3-dienes by molybdenum and tungsten monoaryloxide pyrrolide (MAP) complexes. Journal of the American Chemical Society. 134: 11334-7. PMID 22734508 DOI: 10.1021/ja303220j  1
2012 Yu M, Ibrahem I, Hasegawa M, Schrock RR, Hoveyda AH. Enol ethers as substrates for efficient Z- and enantioselective ring-opening/cross-metathesis reactions promoted by stereogenic-at-Mo complexes: utility in chemical synthesis and mechanistic attributes. Journal of the American Chemical Society. 134: 2788-99. PMID 22272931 DOI: 10.1021/ja210946z  1
2012 Hebden TJ, Schrock RR, Takase MK, Müller P. Cleavage of dinitrogen to yield a (t-BuPOCOP)molybdenum(IV) nitride. Chemical Communications (Cambridge, England). 48: 1851-3. PMID 22222763 DOI: 10.1039/c2cc17634c  1
2012 Schrock RR. A message from the new ChemComm chair. Chemical Communications (Cambridge, England). 48: 18. PMID 22105233 DOI: 10.1039/c1cc90183d  1
2012 Munisamy T, Schrock RR. An electrochemical investigation of intermediates and processes involved in the catalytic reduction of dinitrogen by [HIPTN3N]Mo (HIPTN3N = (3,5-(2,4,6-i-Pr3C6H2)2C6H3NCH2CH2)3N). Dalton Transactions (Cambridge, England : 2003). 41: 130-7. PMID 22031021 DOI: 10.1039/c1dt11287b  1
2012 Peryshkov DV, Schrock RR. Synthesis of tungsten oxo alkylidene complexes Organometallics. 31: 7278-7286. DOI: 10.1021/om3008579  1
2012 Jeong H, Axtell JC, Török B, Schrock RR, Müller P. Syntheses of tungsten tert -butylimido and adamantylimido alkylidene complexes employing pyridinium chloride as the acid Organometallics. 31: 6522-6525. DOI: 10.1021/om300799q  1
2012 Marinescu SC, Ng VWL, Lichtscheidl AG, Schrock RR, Müller P, Takase MK. Syntheses of variations of stereogenic-at-metal imido alkylidene complexes of molybdenum Organometallics. 31: 6336-6343. DOI: 10.1021/om300585s  1
2012 Flook MM, Börner J, Kilyanek SM, Gerber LCH, Schrock RR. Five-coordinate rearrangements of metallacyclobutane intermediates during ring-opening metathesis polymerization of 2,3-dicarboalkoxynorbornenes by molybdenum and tungsten monoalkoxide pyrrolide initiators Organometallics. 31: 6231-6243. DOI: 10.1021/om300530p  1
2012 Yuan J, Schrock RR, Müller P, Axtell JC, Dobereiner GE. Pentafluorophenylimido alkylidene complexes of molybdenum and tungsten Organometallics. 31: 4650-4653. DOI: 10.1021/om300408n  1
2012 Lichtscheidl AG, Ng VWL, Müller P, Takase MK, Schrock RR. Molybdenum monoaryloxide pyrrolide alkylidene complexes that contain mono-ortho-substituted phenyl imido ligands Organometallics. 31: 2388-2394. DOI: 10.1021/om3000289  1
2012 Zhu L, Flook MM, Lee SL, Chan LW, Huang SL, Chiu CW, Chen CH, Schrock RR, Luh TY. Cis, isotactic selective ROMP of norbornenes fused with N-arylpyrrolidines. double stranded polynorbornene-based ladderphanes with Z-double bonds Macromolecules. 45: 8166-8171. DOI: 10.1021/ma301686f  1
2011 Peryshkov DV, Schrock RR, Takase MK, Müller P, Hoveyda AH. Z-Selective olefin metathesis reactions promoted by tungsten oxo alkylidene complexes. Journal of the American Chemical Society. 133: 20754-7. PMID 22107254 DOI: 10.1021/ja210349m  1
2011 Yu M, Wang C, Kyle AF, Jakubec P, Dixon DJ, Schrock RR, Hoveyda AH. Synthesis of macrocyclic natural products by catalyst-controlled stereoselective ring-closing metathesis. Nature. 479: 88-93. PMID 22051677 DOI: 10.1038/nature10563  1
2011 Gerber LC, Schrock RR, Müller P, Takase MK. Synthesis of molybdenum alkylidene complexes that contain the 2,6-dimesitylphenylimido ligand. Journal of the American Chemical Society. 133: 18142-4. PMID 21999823 DOI: 10.1021/ja208936s  1
2011 Marinescu SC, Levine DS, Zhao Y, Schrock RR, Hoveyda AH. Isolation of pure disubstituted E olefins through Mo-catalyzed Z-selective ethenolysis of stereoisomeric mixtures. Journal of the American Chemical Society. 133: 11512-4. PMID 21718001 DOI: 10.1021/ja205002v  1
2011 Marinescu SC, Schrock RR, Müller P, Takase MK, Hoveyda AH. Room Temperature Z-Selective Homocoupling of α Olefins by Tungsten Catalysts. Organometallics. 30: 1780-1782. PMID 21686089 DOI: 10.1021/om200150c  1
2011 Schrock RR. Synthesis of stereoregular ROMP polymers using molybdenum and tungsten imido alkylidene initiators. Dalton Transactions (Cambridge, England : 2003). 40: 7484-95. PMID 21547311 DOI: 10.1039/c1dt10215j  1
2011 Meek SJ, O'Brien RV, Llaveria J, Schrock RR, Hoveyda AH. Catalytic Z-selective olefin cross-metathesis for natural product synthesis. Nature. 471: 461-6. PMID 21430774 DOI: 10.1038/nature09957  1
2011 Flook MM, Ng VW, Schrock RR. Synthesis of cis,syndiotactic ROMP polymers containing alternating enantiomers. Journal of the American Chemical Society. 133: 1784-6. PMID 21265524 DOI: 10.1021/ja110949f  1
2011 Schrock RR. Nitrogen reduction: Molybdenum does it again. Nature Chemistry. 3: 95-6. PMID 21258376 DOI: 10.1038/nchem.977  1
2011 Zhao Y, Hoveyda AH, Schrock RR. Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-W mono-pyrrolide complexes. Organic Letters. 13: 784-7. PMID 21250754 DOI: 10.1021/ol1030525  1
2011 Kinney RA, McNaughton RL, Chin JM, Schrock RR, Hoffman BM. Protonation of the dinitrogen-reduction catalyst [HIPTN3N]Mo(III) investigated by ENDOR spectroscopy. Inorganic Chemistry. 50: 418-20. PMID 21155580 DOI: 10.1021/ic102127v  1
2011 Yuan J, Townsend EM, Schrock RR, Goldman AS, Müller P, Takase MK. Preparation of tungsten-based olefin metathesis catalysts supported on alumina Advanced Synthesis and Catalysis. 353: 1985-1992. DOI: 10.1002/adsc.201100200  1
2010 Flook MM, Gerber LC, Debelouchina GT, Schrock RR. Z-Selective and Syndioselective Ring-Opening Metathesis Polymerization (ROMP) Initiated by MonoAryloxidePyrrolide (MAP) Catalysts. Macromolecules. 43: 7515-7522. PMID 21499508 DOI: 10.1021/ma101375v  1
2010 Chin JM, Schrock RR, Müller P. Synthesis of diamidopyrrolyl molybdenum complexes relevant to reduction of dinitrogen to ammonia. Inorganic Chemistry. 49: 7904-16. PMID 20799738 DOI: 10.1021/ic100856n  1
2010 Gajan D, Rendón N, Wampler KM, Jean-Marie Basset, Copéret C, Lesage A, Emsley L, Schrock RR. Synthesis and reactivity of molybdenum imido alkylidene bis-pyrazolide complexes. Dalton Transactions (Cambridge, England : 2003). 39: 8547-51. PMID 20640248 DOI: 10.1039/c0dt00315h  1
2010 Reithofer MR, Schrock RR, Müller P. Synthesis of [(DPPNCH2CH2)3N]3- molybdenum complexes (DPP = 3,5-(2,5-Diisopropylpyrrolyl)2C6H3) and studies relevant to catalytic reduction of dinitrogen. Journal of the American Chemical Society. 132: 8349-58. PMID 20499910 DOI: 10.1021/ja1008213  1
2010 McNaughton RL, Roemelt M, Chin JM, Schrock RR, Neese F, Hoffman BM. Experimental and theoretical EPR study of Jahn-Teller-active [HIPTN(3)N]MoL complexes (L = N(2), CO, NH(3)). Journal of the American Chemical Society. 132: 8645-56. PMID 20429559 DOI: 10.1021/ja1004619  1
2010 Kinney RA, Hetterscheid DG, Hanna BS, Schrock RR, Hoffman BM. Formation of {[HIPTN(3)N]Mo(III)H}(-) by heterolytic cleavage of H(2) as established by EPR and ENDOR spectroscopy. Inorganic Chemistry. 49: 704-13. PMID 20000748 DOI: 10.1021/ic902006v  1
2010 Marinescu SC, King AJ, Schrock RR, Singh R, Müller P, Takase MK. Simple molybdenum(IV) olefin complexes of the type Mo(NR)(X)(Y)(olefin) Organometallics. 29: 6816-6828. DOI: 10.1021/om101003v  1
2010 Bochmann M, Brookhart M, Gladysz JA, Lichtenberger DL, Liebeskind LS, Marks TJ, Schrock RR, Sweigart DA, Whitmire KH. Dedication to the special volume for Dietmar Seyferth Organometallics. 29: 4647. DOI: 10.1021/om100975m  1
2010 Schrock RR, Jiang AJ, Marinescu SC, Simpson JH, Müller P. Fundamental studies of molybdenum and tungsten methylidene and metallacyclobutane complexes Organometallics. 29: 5241-5251. DOI: 10.1021/om100363g  1
2010 Antognazza MR, Lüer L, Polli D, Christensen RL, Schrock RR, Lanzani G, Cerullo G. Ultrafast excited state relaxation in long-chain polyenes Chemical Physics. 373: 115-121. DOI: 10.1016/j.chemphys.2010.03.002  1
2010 Munisamy T, Schrock RR. Electrochemical reduction of dinitrogen to ammonia using the [HIPTN3N]Mo catalyst Acs National Meeting Book of Abstracts 1
2010 Schrock RR, Hanna B, Chin J, Reithofer M. Catalytic reduction of dinitrogen to ammonia with molybdenum under mild conditions Acs National Meeting Book of Abstracts 1
2010 Hanna BS, Schrock RR. Studies of the effects of hydrogen with the hopes of improving the catalytic reduction of dinitrogen to ammonia at a single molybdenum center Acs National Meeting Book of Abstracts 1
2009 Jiang AJ, Zhao Y, Schrock RR, Hoveyda AH. Highly Z-selective metathesis homocoupling of terminal olefins. Journal of the American Chemical Society. 131: 16630-1. PMID 19919135 DOI: 10.1021/ja908098t  1
2009 Meek SJ, Malcolmson SJ, Li B, Schrock RR, Hoveyda AH. The significance of degenerate processes to enantioselective olefin metathesis reactions promoted by stereogenic-at-Mo complexes. Journal of the American Chemical Society. 131: 16407-9. PMID 19842640 DOI: 10.1021/ja907805f  1
2009 Scriban C, Amagai BS, Stemmler EA, Christensen RL, Schrock RR. Synthesis and optical spectroscopy of oligo(1,6-heptadiynes) with a single basic structure prepared through adamantylimido-based molybdenum Wittig and metathesis chemistry. Journal of the American Chemical Society. 131: 13441-52. PMID 19754190 DOI: 10.1021/ja904541b  1
2009 Kupfer T, Schrock RR. Alkylation of dinitrogen in [(HIPTNCH(2)CH(2))(3)N]Mo complexes (HIPT = 3,5-(2,4,6-i-Pr(3)C(6)H(2))(2)C(6)H(3)). Journal of the American Chemical Society. 131: 12829-37. PMID 19673523 DOI: 10.1021/ja904535f  1
2009 Hetterscheid DG, Hanna BS, Schrock RR. Molybdenum triamidoamine systems. Reactions involving dihydrogen relevant to catalytic reduction of dinitrogen. Inorganic Chemistry. 48: 8569-77. PMID 19639973 DOI: 10.1021/ic900468n  1
2009 Marinescu SC, Schrock RR, Müller P, Hoveyda AH. Ethenolysis reactions catalyzed by imido alkylidene monoaryloxide monopyrrolide (MAP) complexes of molybdenum. Journal of the American Chemical Society. 131: 10840-1. PMID 19618951 DOI: 10.1021/ja904786y  1
2009 Lee YJ, Schrock RR, Hoveyda AH. Endo-selective enyne ring-closing metathesis promoted by stereogenic-at-Mo monoalkoxide and monoaryloxide complexes. Efficient synthesis of cyclic dienes not accessible through reactions with Ru carbenes. Journal of the American Chemical Society. 131: 10652-61. PMID 19580318 DOI: 10.1021/ja904098h  1
2009 Jiang AJ, Simpson JH, Müller P, Schrock RR. Fundamental studies of tungsten alkylidene imido monoalkoxidepyrrolide complexes. Journal of the American Chemical Society. 131: 7770-80. PMID 19489647 DOI: 10.1021/ja9012694  1
2009 Flook MM, Jiang AJ, Schrock RR, Müller P, Hoveyda AH. Z-selective olefin metathesis processes catalyzed by a molybdenum hexaisopropylterphenoxide monopyrrolide complex. Journal of the American Chemical Society. 131: 7962-3. PMID 19462947 DOI: 10.1021/ja902738u  1
2009 Rendón N, Berthoud R, Blanc F, Gajan D, Maishal T, Basset JM, Copéret C, Lesage A, Emsley L, Marinescu SC, Singh R, Schrock RR. Well-defined silica-supported Mo-alkylidene catalyst precursors containing one or substituent: methods of preparation and structure-reactivity relationship in alkene metathesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 5083-9. PMID 19343757 DOI: 10.1002/chem.200802465  1
2009 Schrock RR. Recent advances in high oxidation state Mo and W imido alkylidene chemistry. Chemical Reviews. 109: 3211-26. PMID 19284732 DOI: 10.1021/cr800502p  1
2009 Ibrahem I, Yu M, Schrock RR, Hoveyda AH. Highly Z- and enantioselective ring-opening/cross-metathesis reactions catalyzed by stereogenic-at-Mo adamantylimido complexes. Journal of the American Chemical Society. 131: 3844-5. PMID 19249833 DOI: 10.1021/ja900097n  1
2009 Sattely ES, Meek SJ, Malcolmson SJ, Schrock RR, Hoveyda AH. Design and stereoselective preparation of a new class of chiral olefin metathesis catalysts and application to enantioselective synthesis of quebrachamine: catalyst development inspired by natural product synthesis. Journal of the American Chemical Society. 131: 943-53. PMID 19113867 DOI: 10.1021/ja8084934  1
2009 Harvey JS, Malcolmson SJ, Dunne KS, Meek SJ, Thompson AL, Schrock RR, Hoveyda AH, Gouverneur V. Enantioselective synthesis of P-stereogenic phosphinates and phosphine oxides by molybdenum-catalyzed asymmetric ring-closing metathesis. Angewandte Chemie (International Ed. in English). 48: 762-6. PMID 19101976 DOI: 10.1002/anie.200805066  1
2009 Marinescu SC, Schrock RR, Li B, Hoveyda AH. Inversion of configuration at the metal in diastereomeric imido alkylidene monoaryloxide monopyrrolide complexes of molybdenum. Journal of the American Chemical Society. 131: 58-9. PMID 19086901 DOI: 10.1021/ja808308e  1
2009 Bailey BC, Schrock RR, Kundu S, Goldman AS, Huang Z, Brookhart M. Evaluation of molybdenum and tungsten metathesis catalysts for homogeneous tandem alkane metathesis Organometallics. 28: 355-360. DOI: 10.1021/om800877q  1
2009 Schrock RR, Bailey BC, Miranescu S, Jiang AJ. Olefin metathesis catalysts of molybdenum and tungsten for the metathesis of alkanes Acs National Meeting Book of Abstracts 1
2009 Schrock RR. Recent advances in olefin metathesis chemistry Chimica Oggi. 27: 2-5.  1
2008 Malcolmson SJ, Meek SJ, Sattely ES, Schrock RR, Hoveyda AH. Highly efficient molybdenum-based catalysts for enantioselective alkene metathesis. Nature. 456: 933-7. PMID 19011612 DOI: 10.1038/nature07594  1
2008 Wampler KM, Schrock RR. Molybdenum tris(2,5-dimethylpyrrolide), a rare homoleptic molybdenum(III) monomer. Inorganic Chemistry. 47: 10226-8. PMID 18925739 DOI: 10.1021/ic801695j  1
2008 Blanc F, Berthoud R, Copéret C, Lesage A, Emsley L, Singh R, Kreickmann T, Schrock RR. Direct observation of reaction intermediates for a well defined heterogeneous alkene metathesis catalyst. Proceedings of the National Academy of Sciences of the United States of America. 105: 12123-7. PMID 18723685 DOI: 10.1073/pnas.0802147105  1
2008 Blanc F, Rendón N, Berthoud R, Basset JM, Copéret C, Tonzetich ZJ, Schrock RR. Dramatic enhancement of the alkene metathesis activity of Mo imido alkylidene complexes upon replacement of one tBuO by a surface siloxy ligand. Dalton Transactions (Cambridge, England : 2003). 3156-8. PMID 18688413 DOI: 10.1039/b805686m  1
2008 Gabert AJ, Schrock RR, Müller P. Synthesis of bifunctional imido alkylidene bispyrrolide complexes of molybdenum and their conversion into bifunctional imido alkylidene diolate complexes that can be employed as ROMP initiators. Chemistry, An Asian Journal. 3: 1535-43. PMID 18604823 DOI: 10.1002/asia.200800076  1
2008 Schrock RR. Catalytic reduction of dinitrogen to ammonia by molybdenum: theory versus experiment. Angewandte Chemie (International Ed. in English). 47: 5512-22. PMID 18537212 DOI: 10.1002/anie.200705246  1
2008 Blanc F, Basset JM, Copéret C, Sinha A, Tonzetich ZJ, Schrock RR, Solans-Monfort X, Clot E, Eisenstein O, Lesage A, Emsley L. Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations. Journal of the American Chemical Society. 130: 5886-900. PMID 18402450 DOI: 10.1021/ja077749v  1
2008 Tonzetich ZJ, Schrock RR, Wampler KM, Bailey BC, Cummins CC, Müller P. A tungstenVI nitride having a W2(mu-N)2 core. Inorganic Chemistry. 47: 1560-7. PMID 18257522 DOI: 10.1021/ic701913q  1
2008 Marinescu SC, Singh R, Hock AS, Wampler KM, Schrock RR, Müller P. Syntheses and structures of molybdenum imido alkylidene pyrrolide and indolide complexes Organometallics. 27: 6570-6578. DOI: 10.1021/om800816q  1
2008 Scriban C, Schrock RR, Müller P. Synthesis of oligo(1,6-heptadiynes) with a single structure and terminal methylene groups using molybdenum-based wittig and metathesis chemistry. 1. 2,6-dimethylphenylimido systems Organometallics. 27: 6202-6214. DOI: 10.1021/om8007585  1
2008 Schrock RR, Tonzetich ZJ, Lichtscheidl AG, Müller P, Schattenmann FJ. Carboxylate-based molybdenum alkylidene catalysts: Synthesis, characterization, and use as initiators for 1,6-heptadiyne cyclopolymerizations Organometallics. 27: 3986-3995. DOI: 10.1021/om800314y  1
2008 Jiang AJ, Schrock RR, Müller P. Cationic molybdenum imido alkylidene complexes Organometallics. 27: 4428-4438. DOI: 10.1021/om800209b  1
2008 Lopez LPH, Schrock RR, Müller P. Some reactions involving [W(N-2,6-Me2C6H 3)(OCMe2CF3)2]2, a symmetric d2/d2 dimer that contains no bridging ligands Organometallics. 27: 3857-3865. DOI: 10.1021/om800182g  1
2008 Singh R, Schrock RR. Stereospecific ring-opening metathesis polymerization of 3-methyl-3-phenylcylopropene by molybdenum alkylidene initiators Macromolecules. 41: 2990-2993. DOI: 10.1021/ma800280q  1
2008 Blanc F, Salameh A, Thivolle-Cazat J, Basset JM, Copéret C, Sinha A, Schrock RR. Grafting mechanism and olefin metathesis activity of well-defined silica-supported Mo imido alkyl alkylidene complexes Comptes Rendus Chimie. 11: 137-146. DOI: 10.1016/j.crci.2007.02.017  1
2008 Chi SH, Hales JM, Fuentes-Hernandez C, Tseng SY, Cho JY, Odom SA, Zhang Q, Barlow S, Schrock RR, Marder SR, Kippelen B, Perry JW. Thick optical-quality films of substituted polyacetylenes with large, ultrafast third-order nonlinearities and application to image correlation Advanced Materials. 20: 3199-3203. DOI: 10.1002/adma.200800664  1
2008 Hoveyda AH, Schrock RR. Catalytic Asymmetric Olefin Metathesis Organic Synthesis Set. 210-229. DOI: 10.1002/9783527620784.ch22d  1
2007 Pilyugina TS, Schrock RR, Müller P, Hoveyda AH. New Enantiomerically Pure Alkylimido Mo-Based Complexes. Synthesis, Characterization, and Activity as Chiral Olefin Metathesis Catalysts. Organometallics. 26: 831-837. PMID 19079732 DOI: 10.1021/om061001o  1
2007 Singh R, Czekelius C, Schrock RR, Müller P, Hoveyda AH. Molybdenum Imido Alkylidene Metathesis Catalysts that Contain Electron Withdrawing Biphenolates or Binaphtholates. Organometallics. 26: 2528-2539. PMID 18953421 DOI: 10.1021/om061134+  1
2007 Singh R, Schrock RR, Müller P, Hoveyda AH. Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR')(OR'')(pyrrolyl): enyne metathesis with high oxidation state catalysts. Journal of the American Chemical Society. 129: 12654-5. PMID 17902675 DOI: 10.1021/ja075569f  1
2007 Wampler KM, Schrock RR. Tris(pyrrolyl-alpha-methyl)amines that sterically protect a trigonal metal site. Inorganic Chemistry. 46: 8463-5. PMID 17854184 DOI: 10.1021/ic701472y  1
2007 Cortez GA, Baxter CA, Schrock RR, Hoveyda AH. Comparison of Ru- and Mo-based chiral olefin metathesis catalysts. Complementarity in asymmetric ring-opening/cross-metathesis reactions of oxa- and azabicycles. Organic Letters. 9: 2871-4. PMID 17585770 DOI: 10.1021/ol071008h  1
2007 Blanc F, Berthoud R, Salameh A, Basset JM, Copéret C, Singh R, Schrock RR. Dramatic improvements of well-defined silica supported Mo-based olefin metathesis catalysts by tuning the N-containing ligands. Journal of the American Chemical Society. 129: 8434-5. PMID 17571893 DOI: 10.1021/ja073095e  1
2007 Hock AS, Schrock RR. Oxidative reactions of the Mo(IV) dialkyl complex [{(3-CF3C6H4NCH2CH2)2NMe}Mo(CH2SiMe3)2]. Chemistry, An Asian Journal. 2: 867-74. PMID 17569091 DOI: 10.1002/asia.200700093  1
2007 Cortez GA, Schrock RR, Hoveyda AH. Efficient enantioselective synthesis of piperidines through catalytic asymmetric ring-opening/cross-metathesis reactions. Angewandte Chemie (International Ed. in English). 46: 4534-8. PMID 17492808 DOI: 10.1002/anie.200605130  1
2007 McNaughton RL, Chin JM, Weare WW, Schrock RR, Hoffman BM. EPR study of the low-spin [d(3); S =(1)/(2)], Jahn-Teller-active, dinitrogen complex of a molybdenum trisamidoamine. Journal of the American Chemical Society. 129: 3480-1. PMID 17341079 DOI: 10.1021/ja068546u  1
2007 Blanc F, Thivolle-Cazat J, Basset JM, Copéret C, Hock AS, Tonzetich ZJ, Sinha A, Schrock RR. Highly active, stable, and selective well-defined silica supported mo imido olefin metathesis catalysts. Journal of the American Chemical Society. 129: 1044-5. PMID 17263381 DOI: 10.1021/ja068249p  1
2007 Chi SH, Hales JM, Cho JY, Odom S, Zhang Q, Schrock RR, Marder SR, Perry JW. Processible polyacetylene-based χ(3) materials for photonic applications Conference On Lasers and Electro-Optics, 2007, Cleo 2007. DOI: 10.1109/CLEO.2007.4452708  1
2007 Kreickmann T, Arndt S, Schrock RR, Müller P. Imido alkylidene bispyrrolyl complexes of tungsten (Organometallics (2007) 26 (5702)) Organometallics. 26: 6684. DOI: 10.1021/om701081n  1
2007 Wampler KM, Schrock RR, Hock AS. Synthesis of molybdenum imido alkylidene complexes that contain siloxides Organometallics. 26: 6674-6680. DOI: 10.1021/om700864u  1
2007 Tonzetich ZJ, Jiang AJ, Schrock RR, Müller P. Molybdenum imido alkylidene complexes that contain a β-diketiminate ligand Organometallics. 26: 3771-3783. DOI: 10.1021/om7003207  1
2007 Tonzetich ZJ, Lam YC, Müller P, Schrock RR. Facile synthesis of a tungsten alkylidyne catalyst for alkyne metathesis Organometallics. 26: 475-477. DOI: 10.1021/om0610647  1
2007 Arndt S, Schrock RR, Müller P. Synthesis and reactions of tungsten alkylidene complexes that contain the 2,6-dichlorophenylimido ligand Organometallics. 26: 1279-1290. DOI: 10.1021/om061000w  1
2007 Singh R, Schrock RR, Müller P, Hoveyda AH. Synthesis of monoalkoxide monopyrrolyl complexes Mo(NR)(CHR′) (OR″)(pyrrolyl): Enyne metathesis with high oxidation state catalysts (Journal of American Chemical Society (2007) 129, (12654-12655)) Journal of the American Chemical Society. 129: 16278. DOI: 10.1021/ja078211s  1
2007 Schrock RR. High oxidation state molybdenum and tungsten alkene and alkyne metathesis catalysts: Where we are and where we want to go Advanced Synthesis and Catalysis. 349: 25. DOI: 10.1002/adsc.200600619  1
2007 Schrock RR. Multiple metal-carbon bonds for catalytic metathesis reactions (Nobel Lecture 2005) Advanced Synthesis and Catalysis. 349: 41-53. DOI: 10.1002/adsc.200600524  1
2007 Schrock RR, Czekelius C. Recent advances in the syntheses and applications of molybdenum and tungsten alkylidene and alkylidyne catalysts for the metathesis of alkenes and alkynes Advanced Synthesis and Catalysis. 349: 55-77. DOI: 10.1002/adsc.200600459  1
2006 Sinha A, Schrock RR, Müller P, Hoveyda AH. Diphenylamido Precursors to Bisalkoxide Molybdenum Olefin Metathesis Catalysts. Organometallics. 25: 4621-4626. PMID 19030118 DOI: 10.1021/om060430j  1
2006 Czekelius C, Hafer J, Tonzetich ZJ, Schrock RR, Christensen RL, Müller P. Synthesis of oligoenes that contain up to 15 double bonds from 1,6-heptadiynes. Journal of the American Chemical Society. 128: 16664-75. PMID 17177416 DOI: 10.1021/ja0656705  1
2006 Hock AS, Schrock RR, Hoveyda AH. Dipyrrolyl precursors to bisalkoxide molybdenum olefin metathesis catalysts. Journal of the American Chemical Society. 128: 16373-5. PMID 17165793 DOI: 10.1021/ja0665904  1
2006 Schrock RR. Reduction of dinitrogen. Proceedings of the National Academy of Sciences of the United States of America. 103: 17087. PMID 17088548 DOI: 10.1073/pnas.0603633103  1
2006 Weare WW, Dai X, Byrnes MJ, Chin JM, Schrock RR, Müller P. Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Proceedings of the National Academy of Sciences of the United States of America. 103: 17099-106. PMID 17085586 DOI: 10.1073/pnas.0602778103  1
2006 Blanc F, Copéret C, Thivolle-Cazat J, Basset JM, Lesage A, Emsley L, Sinha A, Schrock RR. Better characterization of surface organometallic catalysts through resolution enhancement in proton solid state NMR spectra. Inorganic Chemistry. 45: 9587-92. PMID 17083261 DOI: 10.1021/ic061222m  1
2006 Smythe NC, Schrock RR, Müller P, Weare WW. Synthesis of [(HIPTNCH2CH2)3N]V compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of vanadium for the reduction of dinitrogen to ammonia. Inorganic Chemistry. 45: 9197-205. PMID 17083217 DOI: 10.1021/ic061554r  1
2006 Weare WW, Schrock RR, Hock AS, Müller P. Synthesis of molybdenum complexes that contain "hybrid" triamidoamine ligands, [(hexaisopropylterphenyl-NCH2CH2)2NCH2CH2N-aryl]3-, and studies relevant to catalytic reduction of dinitrogen. Inorganic Chemistry. 45: 9185-96. PMID 17083216 DOI: 10.1021/ic0613457  1
2006 Smythe NC, Schrock RR, Müller P, Weare WW. Synthesis of [(HIPTNCH2CH2)3N]Cr Compounds (HIPT = 3,5-(2,4,6-i-Pr3C6H2)2C6H3) and an evaluation of chromium for the reduction of dinitrogen to ammonia. Inorganic Chemistry. 45: 7111-8. PMID 16933911 DOI: 10.1021/ic060549k  1
2006 Schrock RR. Multiple metal-carbon bonds for catalytic metathesis reactions (Nobel Lecture). Angewandte Chemie (International Ed. in English). 45: 3748-59. PMID 16703641 DOI: 10.1002/anie.200600085  1
2006 Puglisi A, Lee AL, Schrock RR, Hoveyda AH. Operationally simple, efficient, and diastereoselective synthesis of cis-2,6-disubstituted-4-methylene tetrahydropyrans catalyzed by triflic acid. Organic Letters. 8: 1871-4. PMID 16623572 DOI: 10.1021/ol060430f  1
2006 Lee AL, Malcolmson SJ, Puglisi A, Schrock RR, Hoveyda AH. Enantioselective synthesis of cyclic enol ethers and all-carbon quaternary stereogenic centers through catalytic asymmetric ring-closing metathesis. Journal of the American Chemical Society. 128: 5153-7. PMID 16608351 DOI: 10.1021/ja058428r  1
2006 Blanc F, Copéret C, Thivolle-Cazat J, Basset JM, Lesage A, Emsley L, Sinha A, Schrock RR. Surface versus molecular siloxy ligands in well-defined olefin metathesis catalysts: [{(RO)3SiO}Mo(=NAr)(=CHtBu)(CH2tBu)]. Angewandte Chemie (International Ed. in English). 45: 1216-20. PMID 16416453 DOI: 10.1002/anie.200503205  1
2006 Hales JM, Chi SH, Cho JY, Odom S, Zhang Q, Schrock RR, Screen TEO, Anderson HL, Marder SR, Perry JW. Toward the realization of practicable materials for χ(3) based photonic applications Conference On Lasers and Electro-Optics and 2006 Quantum Electronics and Laser Science Conference, Cleo/Qels 2006. DOI: 10.1109/CLEO.2006.4628067  1
2006 Tonzetich ZJ, Jiang AJ, Schrock RR, Müller P. Cationic imido alkylidene complexes of molybdenum supported by β-diketonate and β-diketiminate ligands Organometallics. 25: 4725-4727. DOI: 10.1021/om060518x  1
2006 Tonzetich ZJ, Schrock RR, Müller P. Reaction of phosphoranes with Mo(N-2,6-i-Pr 2C 6H 3) (CHCMe 3)[OCMe(CF 3) 2] 2: Synthesis and reactivity of an anionic imido alkylidyne complex Organometallics. 25: 4301-4306. DOI: 10.1021/om060501e  1
2006 Rhers B, Salameh A, Baudouin A, Quadrelli EA, Taoufik M, Copéret C, Lefebvre F, Basset JM, Solans-Monfort X, Eisenstein O, Lukens WW, Lopez LPH, Sinha A, Schrock RR. A well-defined, silica-supported tungsten imido alkylidene olefin metathesis catalyst Organometallics. 25: 3554-3557. DOI: 10.1021/om060279d  1
2006 Adamchuk J, Schrock RR, Tonzetich ZJ, Müller P. Initiators of the type Mo(NAr)(CHR′)(OR″) 2 for the controlled polymerization of diethyldipropargylmalonate Organometallics. 25: 2364-2373. DOI: 10.1021/om060029x  1
2006 Sinha A, Lopez LPH, Schrock RR, Hock AS, Müller P. Reactions of M(N-2,6-i Pr 2C 6H 3)(CHR) (CH 2R′) 2 (M = Mo, W) complexes with alcohols to give olefin metathesis catalysts of the type M(N-2,6-i-Pr 2C 6H 3)(CHR)(CH 2R′)(OR″) Organometallics. 25: 1412-1423. DOI: 10.1021/om050978a  1
2006 Lopez LPH, Schrock RR, Müller P. Dimers that contain unbridged W(IV)/W(IV) double bonds Organometallics. 25: 1978-1986. DOI: 10.1021/om050961s  1
2006 Singh R, Verploegen E, Hammond PT, Schrock RR. Synthesis of ABA triblock copolymers via ring opening metathesis polymerization using a bimetallic initiator: Influence of a flexible spacer in the side chain liquid crystalline block Macromolecules. 39: 8241-8249. DOI: 10.1021/ma0613180  1
2006 Gabert AJ, Verploegen E, Hammond PT, Schrock RR. Synthesis and characterization of ABA triblock copolymers containing smectic C* liquid crystal side chains via ring-opening metathesis polymerization using a bimetallic molybdenum initiator Macromolecules. 39: 3993-4000. DOI: 10.1021/ma060243x  1
2006 Singh R, Czekelius C, Schrock RR. Living ring-opening metathesis polymerization of cyclopropenes Macromolecules. 39: 1316-1317. DOI: 10.1021/ma052560u  1
2006 Tonzetich ZJ, Schrock RR. Potential Group IV olefin polymerization catalysts that contain a diamido ligand substituted with hexaisopropylterphenyl groups Polyhedron. 25: 469-476. DOI: 10.1016/j.poly.2005.09.005  1
2006 Rhers B, Quadrelli EA, Baudouin A, Taoufik M, Copéret C, Lefebvre F, Basset JM, Fenet B, Sinha A, Schrock RR. Understanding the reactivity of [W{double bond, long}NAr(CH2tBu)2({double bond, long}CHtBu)] (Ar = 2,6-iPrC6H3) with silica partially dehydroxylated at low temperatures through a combined use of molecular and surface organometallic chemistry Journal of Organometallic Chemistry. 691: 5448-5455. DOI: 10.1016/j.jorganchem.2006.09.019  1
2006 Lopez LPH, Schrock RR, Bonitatebus PJ. Synthesis of tantalum and niobium complexes that contain the diamidoamine ligand, [(3,4,5-F3C6H2NCH2CH2)2NMe]2-, and the triamidoamine ligand, [(3,5-Cl2C6H3NCH2CH2)3N]3- Inorganica Chimica Acta. 359: 4730-4740. DOI: 10.1016/j.ica.2006.03.044  1
2006 Weare WW, Schrock R. Insights into the catalytic system provided by measuring the hydrogen evolved during fixation of dinitrogen at bulky hexaisopropylterphenyl triamidoamine (TREN) molybdenum complexes Acs National Meeting Book of Abstracts. 231.  1
2005 Schrock RR. Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Accounts of Chemical Research. 38: 955-62. PMID 16359167 DOI: 10.1021/ar0501121  1
2005 Sattely ES, Cortez GA, Moebius DC, Schrock RR, Hoveyda AH. Enantioselective synthesis of cyclic amides and amines through mo-catalyzed asymmetric ring-closing metathesis. Journal of the American Chemical Society. 127: 8526-33. PMID 15941288 DOI: 10.1021/ja051330s  1
2005 Yandulov DV, Schrock RR. Studies relevant to catalytic reduction of dinitrogen to ammonia by molybdenum triamidoamine complexes. Inorganic Chemistry. 44: 1103-17. PMID 15859292 DOI: 10.1021/ic040095w  0.52
2005 Schrock RR, Gabert AJ, Singh R, Hock AS. Synthesis of high oxidation state bimetallic alkylidene complexes for controlled ROMP synthesis of triblock copolymers Organometallics. 24: 5058-5066. DOI: 10.1021/om058022n  1
2005 Schrock RR, Lopez LPH, Hafer J, Singh R, Sinha A, Müller P. Olefin metathesis reactions initiated by d 2 molybdenum or tungsten complexes Organometallics. 24: 5211-5213. DOI: 10.1021/om050583r  1
2005 Byrnes MJ, Dai X, Schrock RR, Hock AS, Müller P. Some organometallic chemistry of molybdenum complexes that contain the [HIPTN 3N] 3- triamidoamine ligand, {[3,5-(2,4,6.i.Pr 3C 6H 2) 2C 6H 3NCH 2CH 2] 3N} 3- Organometallics. 24: 4437-4450. DOI: 10.1021/om050373e  1
2004 Dolman SJ, Hultzsch KC, Pezet F, Teng X, Hoveyda AH, Schrock RR. Supported chiral Mo-based complexes as efficient catalysts for enantioselective olefin metathesis. Journal of the American Chemical Society. 126: 10945-53. PMID 15339179 DOI: 10.1021/ja047663r  1
2004 Ritleng V, Yandulov DV, Weare WW, Schrock RR, Hock AS, Davis WM. Molybdenum triamidoamine complexes that contain hexa-tert-butylterphenyl, hexamethylterphenyl, or p-bromohexaisopropylterphenyl substituents. An examination of some catalyst variations for the catalytic reduction of dinitrogen. Journal of the American Chemical Society. 126: 6150-63. PMID 15137780 DOI: 10.1021/ja0306415  1
2004 Weatherhead GS, Cortez GA, Schrock RR, Hoveyda AH. Mo-catalyzed asymmetric olefin metathesis in target-oriented synthesis: enantioselective synthesis of (+)-africanol. Proceedings of the National Academy of Sciences of the United States of America. 101: 5805-9. PMID 15056762 DOI: 10.1073/pnas.0307589101  1
2004 Schrock RR, Duval-Lungulescu M, Tsang WC, Hoveyda AH. Catalytic homologation of vinyltributylstannane to allyltributylstannane by Mo(IV) complexes in the presence of ethylene. Journal of the American Chemical Society. 126: 1948-9. PMID 14971923 DOI: 10.1021/ja039173p  1
2003 Dolman SJ, Schrock RR, Hoveyda AH. Enantioselective synthesis of cyclic secondary amines through Mo-catalyzed asymmetric ring-closing metathesis (ARCM). Organic Letters. 5: 4899-902. PMID 14653702 DOI: 10.1021/ol036026n  1
2003 Schrock RR, Hoveyda AH. Molybdenum and tungsten imido alkylidene complexes as efficient olefin-metathesis catalysts. Angewandte Chemie (International Ed. in English). 42: 4592-633. PMID 14533149 DOI: 10.1002/anie.200300576  1
2003 Yandulov DV, Schrock RR. Catalytic reduction of dinitrogen to ammonia at a single molybdenum center. Science (New York, N.Y.). 301: 76-8. PMID 12843387 DOI: 10.1126/science.1085326  0.52
2003 Tsang WC, Hultzsch KC, Alexander JB, Bonitatebus PJ, Schrock RR, Hoveyda AH. Alkylidene and metalacyclic complexes of tungsten that contain a chiral biphenoxide ligand. synthesis, asymmetric ring-closing metathesis, and mechanistic investigations. Journal of the American Chemical Society. 125: 2652-66. PMID 12603153 DOI: 10.1021/ja0210603  1
2003 Tsang WC, Jernelius JA, Cortez GA, Weatherhead GS, Schrock RR, Hoveyda AH. An enantiomerically pure adamantylimido molybdenum alkylidene complex. An effective new catalyst for enantioselective olefin metathesis. Journal of the American Chemical Society. 125: 2591-6. PMID 12603147 DOI: 10.1021/ja021204d  1
2003 Yandulov DV, Schrock RR, Rheingold AL, Ceccarelli C, Davis WM. Synthesis and reactions of molybdenum triamidoamine complexes containing hexaisopropylterphenyl substituents. Inorganic Chemistry. 42: 796-813. PMID 12562193 DOI: 10.1021/ic020505l  0.52
2002 Teng X, Cefalo DR, Schrock RR, Hoveyda AH. Enhancement of enantioselectivity by THF in asymmetric mo-catalyzed olefin metathesis. Catalytic enantioselective synthesis of cyclic tertiary ethers and spirocycles. Journal of the American Chemical Society. 124: 10779-84. PMID 12207534 DOI: 10.1021/ja020671s  1
2002 Dolman SJ, Sattely ES, Hoveyda AH, Schrock RR. Efficient catalytic enantioselective synthesis of unsaturated amines: preparation of small- and medium-ring cyclic amines through mo-catalyzed asymmetric ring-closing metathesis in the absence of solvent. Journal of the American Chemical Society. 124: 6991-7. PMID 12059222 DOI: 10.1021/ja012534l  1
2002 Yandulov DV, Schrock RR. Reduction of dinitrogen to ammonia at a well-protected reaction site in a molybdenum triamidoamine complex. Journal of the American Chemical Society. 124: 6252-3. PMID 12033849 DOI: 10.1021/ja020186x  0.52
2002 Kiely AF, Jernelius JA, Schrock RR, Hoveyda AH. Enantioselective synthesis of medium-ring heterocycles, tertiary ethers, and tertiary alcohols by Mo-catalyzed ring-closing metathesis. Journal of the American Chemical Society. 124: 2868-9. PMID 11902866 DOI: 10.1021/ja012679s  1
2001 Aeilts SL, Cefalo DR, Bonitatebus PJ, Houser JH, Hoveyda AH, Schrock RR. A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis. Angewandte Chemie (International Ed. in English). 40: 1452-1456. PMID 29712343 DOI: 10.1002/1521-3773(20010417)40:8<1452::AID-ANIE1452>3.0.CO;2-G  0.56
2001 Mehrkhodavandi P, Schrock RR. Cationic hafnium alkyl complexes that are stable toward beta-hydride elimination below 10 degrees C and active as initiators for the living polymerization of 1-hexene. Journal of the American Chemical Society. 123: 10746-7. PMID 11674011 DOI: 10.1021/ja0114198  1
2001 La DS, Sattely ES, Ford JG, Schrock RR, Hoveyda AH. Catalytic asymmetric ring-opening metathesis/cross metathesis (AROM/CM) reactions. Mechanism and application to enantioselective synthesis of functionalized cyclopentanes. Journal of the American Chemical Society. 123: 7767-78. PMID 11493050 DOI: 10.1021/ja010684q  1
2001 Aeilts SL, Cefalo DR, Bonitatebus Jr PJ, Houser JH, Hoveyda AH, Schrock RR. A Readily Available and User-Friendly Chiral Catalyst for Efficient Enantioselective Olefin Metathesis This research was supported by the National Institutes of Health (GM-59426) and the National Science Foundation (CHE-9905806 to A. H. H. and CHE-9988766 to R. R. S.). Angewandte Chemie (International Ed. in English). 40: 1452-1456. PMID 11317300 DOI: 10.1002/1521-3773(20010417)40:8<1452::AID-ANIE1452>3.0.CO;2-G  1
1996 Freundlich JS, Schrock RR. Synthesis of Triamidoamine Complexes of Niobium. Inorganic Chemistry. 35: 7459-7461. PMID 11666947  1
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