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Scott E. Denmark - Publications

Affiliations: 
University of Illinois, Urbana-Champaign, Urbana-Champaign, IL 
Area:
synthesis of complex molecular structures
Website:
http://www.scs.illinois.edu/denmark/sed/index.html

245 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Zahrt AF, Henle JJ, Denmark SE. Cautionary Guidelines for Machine Learning Studies with Combinatorial Datasets. Acs Combinatorial Science. PMID 33000621 DOI: 10.1021/acscombsci.0c00118  0.4
2020 Henle JJ, Zahrt AF, Rose BT, Darrow WT, Wang Y, Denmark SE. Development of a Computer-Guided Workflow for Catalyst Optimization. Descriptor Validation, Subset Selection, and Training Set Analysis. Journal of the American Chemical Society. PMID 32568531 DOI: 10.1021/jacs.0c04715  0.4
2020 Athavale SV, Simon A, Houk KN, Denmark SE. Demystifying the asymmetry-amplifying, autocatalytic behaviour of the Soai reaction through structural, mechanistic and computational studies. Nature Chemistry. PMID 32203445 DOI: 10.1038/s41557-020-0421-8  0.36
2019 Zahrt AF, Denmark SE. Evaluating continuous chirality measure as a 3D descriptor in chemoinformatics applied to asymmetric catalysis. Tetrahedron Letters. 75: 1841-1851. PMID 31983782 DOI: 10.1016/j.tet.2019.02.007  0.4
2019 Zahrt AF, Athavale SV, Denmark SE. Quantitative Structure-Selectivity Relationships in Enantioselective Catalysis: Past, Present, and Future. Chemical Reviews. PMID 31886649 DOI: 10.1021/acs.chemrev.9b00425  0.4
2019 Bigler R, Mack KA, Shen J, Tosatti P, Han C, Zhang H, Scalone M, Pfaltz A, Denmark SE, Hildbrand S, Gosselin F. Asymmetric Hydrogenation of Unfunctionalized, Tetrasubstituted, Acyclic Olefins. Angewandte Chemie (International Ed. in English). PMID 31794118 DOI: 10.1002/anie.201912640  0.68
2019 Zhukhovitskiy AV, Kobylianskii IJ, Thomas AA, Evans AM, Delaney CP, Flanders NC, Denmark SE, Dichtel WR, Toste FD. A Dinuclear Mechanism Implicated in Controlled Carbene Polymerization. Journal of the American Chemical Society. PMID 30964670 DOI: 10.1021/jacs.9b01532  0.4
2019 Zahrt AF, Henle JJ, Rose BT, Wang Y, Darrow WT, Denmark SE. Prediction of higher-selectivity catalysts by computer-driven workflow and machine learning. Science (New York, N.Y.). 363. PMID 30655414 DOI: 10.1126/science.aau5631  0.4
2018 Thomas AA, Zahrt AF, Delaney CP, Denmark SE. Elucidating the Role of the Boronic Esters in the Suzuki-Miyaura Reaction: Structural, Kinetic, and Computational Investigations. Journal of the American Chemical Society. PMID 29543441 DOI: 10.1021/jacs.8b00400  0.4
2017 Denmark SE, Ambrosi A. Understanding Site Selectivity in the Palladium-Catalyzed Cross-Coupling of Allenylsilanolates. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 28: 2415-2420. PMID 29904234 DOI: 10.1055/s-0036-1588471  0.76
2017 Hartmann E, Denmark SE. Structural, Mechanistic, Spectroscopic, and Preparative Studies on the Lewis Base Catalyzed, Enantioselective Sulfenofunctionalization of Alkenes. Helvetica Chimica Acta. 100. PMID 29311750 DOI: 10.1002/hlca.201700158  0.88
2017 Denmark SE, Matesich ZD, Nguyen ST, Milicevic Sephton S. Catalytic Nucleophilic Allylation Driven by the Water-Gas Shift Reaction. The Journal of Organic Chemistry. PMID 29220183 DOI: 10.1021/acs.joc.7b02658  0.52
2017 Thomas AA, Wang H, Zahrt AF, Denmark SE. Structural, Kinetic, and Computational Characterization of the Elusive Arylpalladium(II)boronate Complexes in the Suzuki-Miyaura Reaction. Journal of the American Chemical Society. PMID 28266847 DOI: 10.1021/jacs.6b13384  0.76
2016 Ambrosi A, Denmark SE. Harnessing the Power of the Water-Gas Shift Reaction for Organic Synthesis. Angewandte Chemie (International Ed. in English). PMID 27595612 DOI: 10.1002/anie.201601803  0.76
2016 Denmark SE, Ryabchuk P, Burk MT, Gilbert BB. Toward Catalytic, Enantioselective Chlorolactonization of 1,2-Disubstituted Styrenyl Carboxylic Acids. The Journal of Organic Chemistry. PMID 27555101 DOI: 10.1021/acs.joc.6b01455  0.56
2016 Thomas AA, Denmark SE. Pre-transmetalation intermediates in the Suzuki-Miyaura reaction revealed: The missing link. Science (New York, N.Y.). 352: 329-32. PMID 27081068 DOI: 10.1126/science.aad6981  1
2015 Cresswell AJ, Eey ST, Denmark SE. Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities. Angewandte Chemie (International Ed. in English). PMID 26630449 DOI: 10.1002/anie.201507152  1
2015 Denmark SE, Carson N. Reinvestigation of a Catalytic, Enantioselective Alkene Dibromination and Chlorohydroxylation. Organic Letters. PMID 26566099 DOI: 10.1021/acs.orglett.5b02650  1
2015 Denmark SE, Ambrosi A. Why You Really Should Consider Using Palladium-Catalyzed Cross-Coupling of Silanols and Silanolates. Organic Process Research & Development. 19: 982-994. PMID 26478695 DOI: 10.1021/acs.oprd.5b00201  1
2015 Denmark SE, Cullen LR. Development of a Phase-Transfer-Catalyzed, [2,3]-Wittig Rearrangement. The Journal of Organic Chemistry. PMID 26431154 DOI: 10.1021/acs.joc.5b01759  1
2015 Tymonko SA, Smith RC, Ambrosi A, Ober MH, Wang H, Denmark SE. Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of arylsilanolates. Journal of the American Chemical Society. 137: 6200-18. PMID 25945516 DOI: 10.1021/jacs.5b02518  1
2015 Tymonko SA, Smith RC, Ambrosi A, Denmark SE. Mechanistic significance of the si-o-pd bond in the palladium-catalyzed cross-coupling reactions of alkenylsilanolates. Journal of the American Chemical Society. 137: 6192-9. PMID 25945390 DOI: 10.1021/jacs.5b02515  1
2015 Denmark SE, Chang WT, Houk KN, Liu P. Development of Chiral Bis-hydrazone Ligands for the Enantioselective Cross-Coupling Reactions of Aryldimethylsilanolates. The Journal of Organic Chemistry. 80: 313-66. PMID 25494058 DOI: 10.1021/jo502388r  0.36
2015 Denmark SE, Henle JJ. Redefining q: Quaternary ammonium cross sectional area (XSA) as a general descriptor for transport-limiting PTC rate approximations Chemical Science. 6: 2211-2218. DOI: 10.1039/c5sc00071h  1
2014 Cresswell AJ, Eey ST, Denmark SE. Catalytic, stereospecific syn-dichlorination of alkenes. Nature Chemistry. 7: 146-52. PMID 25615668 DOI: 10.1038/nchem.2141  1
2014 Denmark SE, Hartmann E, Kornfilt DJ, Wang H. Mechanistic, crystallographic, and computational studies on the catalytic, enantioselective sulfenofunctionalization of alkenes. Nature Chemistry. 6: 1056-64. PMID 25411883 DOI: 10.1038/nchem.2109  1
2014 Denmark SE, Rossi S, Webster MP, Wang H. Catalytic, enantioselective sulfenylation of ketone-derived enoxysilanes. Journal of the American Chemical Society. 136: 13016-28. PMID 25192220 DOI: 10.1021/ja506133z  1
2014 Denmark SE, Wilson TW, Burk MT. Enantioselective construction of quaternary stereogenic carbon atoms by the Lewis base catalyzed additions of silyl ketene imines to aldehydes. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 9268-79. PMID 25043283 DOI: 10.1002/chem.201403342  1
2014 Dale EJ, Vermeulen NA, Thomas AA, Barnes JC, Jurí?ek M, Blackburn AK, Strutt NL, Sarjeant AA, Stern CL, Denmark SE, Stoddart JF. ExCage. Journal of the American Chemical Society. 136: 10669-82. PMID 24967502 DOI: 10.1021/ja5041557  1
2014 Denmark SE, Matesich ZD. Catalytic, nucleophilic allylation of aldehydes with 2-substituted allylic acetates: carbon-carbon bond formation driven by the water-gas shift reaction. The Journal of Organic Chemistry. 79: 5970-86. PMID 24927196 DOI: 10.1021/jo501004j  1
2014 Denmark SE, Chi HM. Lewis base catalyzed, enantioselective, intramolecular sulfenoamination of olefins. Journal of the American Chemical Society. 136: 8915-8. PMID 24926794 DOI: 10.1021/ja5046296  1
2014 Denmark SE, Chi HM. Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. Mechanistic aspects: a remarkable case of negative catalysis. Journal of the American Chemical Society. 136: 3655-63. PMID 24548006 DOI: 10.1021/ja413270h  1
2014 Denmark SE, Burk MT. Development and mechanism of an enantioselective bromocycloetherification reaction via Lewis base/chiral Brønsted acid cooperative catalysis. Chirality. 26: 344-55. PMID 24395341 DOI: 10.1002/chir.22259  1
2014 Denmark SE, Cullen LR. Catalytic conjugate addition of acyl anion equivalents promoted by fluorodesilylation. Organic Letters. 16: 70-3. PMID 24328533 DOI: 10.1021/ol403041k  1
2014 Denmark SE, Jaunet A. Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. Preparative and stereochemical aspects. The Journal of Organic Chemistry. 79: 140-71. PMID 24328051 DOI: 10.1021/jo4023765  1
2014 West R, Samedov K, Percival PW, Jutzi P, Denmark SE, Wilson TW, Burk MT, Pinkert D, Limberg C, Büchner C, Lichtenstein L, Yu X, Boscoboinik JA, Yang B, Kaden WE, et al. Cover Picture: Silicon Meets Cyclotron: Muon Spin Resonance of Organosilicon Radicals / The Pentamethylcyclopentadienylsilicon(II) Cation: Synthesis, Characterization, and Reactivity / Enantioselective Construction of Quaternary Stereogenic Carbon Atoms b Chemistry - a European Journal. 20: 9141-9141. DOI: 10.1002/chem.201490122  1
2014 Baiazitov RY, Denmark SE. Tandem [4+2]/[3+2] Cycloadditions Methods and Applications of Cycloaddition Reactions in Organic Syntheses. 471-550. DOI: 10.1002/9781118778173.ch16  1
2013 Denmark SE, Ueki Y. Lewis Base Activation of Lewis Acids - Group 13. In Situ Generation and Reaction of Borenium Ions. Organometallics. 32. PMID 24347789 DOI: 10.1021/om400582k  1
2013 Denmark SE, Cresswell AJ. Iron-catalyzed cross-coupling of unactivated secondary alkyl thio ethers and sulfones with aryl Grignard reagents. The Journal of Organic Chemistry. 78: 12593-628. PMID 24256193 DOI: 10.1021/jo402246h  1
2013 Beutner GL, Denmark SE. Lewis base catalysis of the Mukaiyama directed aldol reaction: 40 years of inspiration and advances. Angewandte Chemie (International Ed. in English). 52: 9086-96. PMID 23843275 DOI: 10.1002/anie.201302084  1
2013 Denmark SE, Jaunet A. Catalytic, enantioselective, intramolecular carbosulfenylation of olefins. Journal of the American Chemical Society. 135: 6419-22. PMID 23597174 DOI: 10.1021/ja401867b  1
2013 Wolf LM, Denmark SE. A theoretical investigation on the mechanism and stereochemical course of the addition of (E)-2-butenyltrimethylsilane to acetaldehyde by electrophilic and nucleophilic activation. Journal of the American Chemical Society. 135: 4743-56. PMID 23484480 DOI: 10.1021/ja311889v  1
2013 Denmark SE, Marlin JE, Rajendra G. Carbanion-accelerated Claisen rearrangements: asymmetric induction with chiral phosphorus-stabilized anions. The Journal of Organic Chemistry. 78: 66-82. PMID 23101563 DOI: 10.1021/jo301919e  1
2013 Beutner GL, Denmark SE. The interplay of invention, observation, and discovery in the development of lewis base activation of lewis acids for catalytic enantioselective synthesis Topics in Organometallic Chemistry. 44: 55-89. DOI: 10.1007/3418-2012-43  1
2012 Denmark SE, Kuester WE, Burk MT. Catalytic, asymmetric halofunctionalization of alkenes--a critical perspective. Angewandte Chemie (International Ed. in English). 51: 10938-53. PMID 23011853 DOI: 10.1002/anie.201204347  1
2012 Denmark SE, Wilson TW. Silyl ketene imines: highly versatile nucleophiles for catalytic, asymmetric synthesis. Angewandte Chemie (International Ed. in English). 51: 9980-92. PMID 22968901 DOI: 10.1002/anie.201202139  1
2012 Denmark SE, Weintraub RC, Gould ND. Effects of charge separation, effective concentration, and aggregate formation on the phase transfer catalyzed alkylation of phenol. Journal of the American Chemical Society. 134: 13415-29. PMID 22856542 DOI: 10.1021/ja304808u  1
2012 Denmark SE, Wilson TW. Lewis base catalyzed enantioselective additions of an N-silyl vinylketene imine. Angewandte Chemie (International Ed. in English). 51: 3236-9. PMID 22351382 DOI: 10.1002/anie.201108795  1
2012 Denmark SE, Burk MT. Enantioselective bromocycloetherification by Lewis base/chiral Brønsted acid cooperative catalysis. Organic Letters. 14: 256-9. PMID 22145621 DOI: 10.1021/ol203033k  1
2012 Denmark SE, Weber EJ, Almstead NG, Wolf LM. On the stereochemical course of the addition of allylsilanes to aldehydes Tetrahedron. 68: 7701-7718. DOI: 10.1016/j.tet.2012.05.084  1
2011 Denmark SE, Kornfilt DJ, Vogler T. Catalytic asymmetric thiofunctionalization of unactivated alkenes. Journal of the American Chemical Society. 133: 15308-11. PMID 21859086 DOI: 10.1021/ja2064395  1
2011 Denmark SE, Werner NS. γ-Selective cross-coupling of allylic silanolate salts with aromatic bromides using trialkylphosphonium tetrafluoroborate salts prepared directly from phosphine•borane adducts. Organic Letters. 13: 4596-9. PMID 21830766 DOI: 10.1021/ol2017998  1
2011 Denmark SE, Smith RC, Chang WT. Probing the Electronic Demands of Transmetalation in the Palladium-Catalyzed Cross-Coupling of Arylsilanolates. Tetrahedron. 67: 4391-4396. PMID 21731114 DOI: 10.1016/j.tet.2011.03.066  1
2011 Denmark SE, Regens CS. Cross-Coupling Reactions of Alkenylsilanols with Fluoroalkylsulfonates: Development and Optimization of a Mild and Stereospecific Coupling Process. Tetrahedron Letters. 52: 2165-2168. PMID 21516201 DOI: 10.1016/j.tetlet.2010.11.133  1
2011 Denmark SE, Gould ND, Wolf LM. A systematic investigation of quaternary ammonium ions as asymmetric phase-transfer catalysts. Application of quantitative structure activity/selectivity relationships. The Journal of Organic Chemistry. 76: 4337-57. PMID 21446723 DOI: 10.1021/jo2005457  1
2011 Denmark SE, Gould ND, Wolf LM. A systematic investigation of quaternary ammonium ions as asymmetric phase-transfer catalysts. Synthesis of catalyst libraries and evaluation of catalyst activity. The Journal of Organic Chemistry. 76: 4260-336. PMID 21446721 DOI: 10.1021/jo2005445  1
2011 Denmark SE, Liu JH, Muhuhi JM. Stereocontrolled total syntheses of isodomoic acids G and H via a unified strategy. The Journal of Organic Chemistry. 76: 201-15. PMID 21121685 DOI: 10.1021/jo101790z  1
2011 Chang WTT, Smith RC, Regens CS, Bailey AD, Werner NS, Denmark SE. Cross-coupling with organosilicon compounds Organic Reactions. 75: 213-745. DOI: 10.1002/0471264180.or075.03  1
2010 Denmark SE, Liu JH. Sequential Processes in Palladium-Catalyzed Silicon-Based Cross-Coupling. Israel Journal of Chemistry. 50: 577-587. PMID 23293392 DOI: 10.1002/ijch.201000036  1
2010 Denmark SE, Wilson TW. N-silyl oxyketene imines are underused yet highly versatile reagents for catalytic asymmetric synthesis. Nature Chemistry. 2: 937-43. PMID 20966949 DOI: 10.1038/nchem.857  1
2010 Denmark SE, Kalyani D, Collins WR. Preparative and mechanistic studies toward the rational development of catalytic, enantioselective selenoetherification reactions. Journal of the American Chemical Society. 132: 15752-65. PMID 20961070 DOI: 10.1021/ja106837b  1
2010 Denmark SE, Kobayashi T, Regens CS. Total Synthesis of (+)-Papulacandin D. Tetrahedron. 66: 4745-4759. PMID 20711516 DOI: 10.1016/j.tet.2010.03.093  1
2010 Denmark SE, Burk MT. Lewis base catalysis of bromo- and iodolactonization, and cycloetherification. Proceedings of the National Academy of Sciences of the United States of America. 107: 20655-60. PMID 20705900 DOI: 10.1073/pnas.1005296107  1
2010 Denmark SE, Williams BJ, Eklov BM, Pham SM, Beutner GL. Design, validation, and implementation of a rapid-injection NMR system. The Journal of Organic Chemistry. 75: 5558-72. PMID 20672809 DOI: 10.1021/jo100837a  1
2010 Denmark SE, Muhuhi JM. Development of a general, sequential, ring-closing metathesis/intramolecular cross-coupling reaction for the synthesis of polyunsaturated macrolactones. Journal of the American Chemical Society. 132: 11768-78. PMID 20666473 DOI: 10.1021/ja1047363  1
2010 Denmark SE, Liu JH. Silicon-based cross-coupling reactions in the total synthesis of natural products. Angewandte Chemie (International Ed. in English). 49: 2978-86. PMID 20333628 DOI: 10.1002/anie.200905657  1
2010 Denmark SE, Werner NS. On the stereochemical course of palladium-catalyzed cross-coupling of allylic silanolate salts with aromatic bromides. Journal of the American Chemical Society. 132: 3612-20. PMID 20163185 DOI: 10.1021/ja910804u  1
2010 Denmark SE, Burk MT, Hoover AJ. On the absolute configurational stability of bromonium and chloronium ions. Journal of the American Chemical Society. 132: 1232-3. PMID 20058922 DOI: 10.1021/ja909965h  1
2010 Denmark SE, Smith RC. Mechanistic duality in palladium-catalyzed cross-coupling reactions of aryldimethylsilanolates. intermediacy of an 8-Si-4 arylpalladium(II) silanolate. Journal of the American Chemical Society. 132: 1243-5. PMID 20058920 DOI: 10.1021/ja907049y  1
2010 Denmark SE, Sorensen EJ. Preface to special issue of heterocycles honoring the 85th birthday of prof. Dr. Albert eschenmoser Heterocycles. 82: 5-10. DOI: 10.3987/COM-10-S(E)Foreword_2  1
2010 Denmark SE, Weintraub RC. Deconstructing quinine. Part 1. Toward an understanding of the remarkable performance of cinchona alkaloids in asymmetric phase transfer catalysis Heterocycles. 82: 1527-1540. DOI: 10.3987/COM-10-S(E)108  1
2010 Denmark SE, Wilson TW. Construction of quaternary stereogenic carbon centers by the Lewis base catalyzed conjugate addition of silyl ketene imines to α,β- unsaturated aldehydes and ketones Synlett. 1723-1728. DOI: 10.1055/s-0029-1219963  1
2010 Denmark SE, Edwards JP, Weber T, Piotrowski DW. Organocerium additions to proline-derived hydrazones: Synthesis of enantiomerically enriched amines Tetrahedron Asymmetry. 21: 1278-1302. DOI: 10.1016/j.tetasy.2010.04.042  1
2009 Denmark SE, Baiazitov RY, Nguyen ST. Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes: construction of the pentacyclic core structure of daphnilactone B. Tetrahedron. 65: 6535-6548. PMID 22180670 DOI: 10.1016/j.tet.2009.05.060  1
2009 Denmark SE, Liu JH, Muhuhi JM. Total syntheses of isodomoic acids G and H. Journal of the American Chemical Society. 131: 14188-9. PMID 19807173 DOI: 10.1021/ja9063475  1
2009 Denmark SE, Baird JD. Preparation of 2,3-Disubstituted Indoles by Sequential Larock Heteroannulation and Silicon-Based Cross-Coupling Reactions. Tetrahedron. 65: 3120-3129. PMID 19784400 DOI: 10.1016/j.tet.2008.10.043  1
2009 Denmark SE, Vogler T. Synthesis and reactivity of enantiomerically enriched thiiranium ions. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 11737-45. PMID 19760721 DOI: 10.1002/chem.200901377  1
2009 Denmark SE, Eklov BM, Yao PJ, Eastgate MD. On the mechanism of Lewis base catalyzed aldol addition reactions: kinetic and spectroscopic investigations using rapid-injection NMR. Journal of the American Chemical Society. 131: 11770-87. PMID 19642696 DOI: 10.1021/ja902474j  1
2009 Denmark SE. The interplay of invention, discovery, development, and application in organic synthetic methodology: a case study. The Journal of Organic Chemistry. 74: 2915-27. PMID 19278233 DOI: 10.1021/jo900032x  1
2009 Denmark SE, Collins WR, Cullen MD. Observation of direct sulfenium and selenenium group transfer from thiiranium and seleniranium ions to alkenes. Journal of the American Chemical Society. 131: 3490-2. PMID 19227982 DOI: 10.1021/ja900187y  1
2009 Denmark SE, Smith RC, Chang WT, Muhuhi JM. Cross-coupling reactions of aromatic and heteroaromatic silanolates with aromatic and heteroaromatic halides. Journal of the American Chemical Society. 131: 3104-18. PMID 19199785 DOI: 10.1021/ja8091449  1
2009 Denmark SE, Nguyen ST. Catalytic, nucleophilic allylation of aldehydes with allyl acetate. Organic Letters. 11: 781-4. PMID 19175354 DOI: 10.1021/ol8028725  1
2009 Denmark SE, Butler CR. Palladium- (and nickel-) catalyzed vinylation of aryl halides. Chemical Communications (Cambridge, England). 20-33. PMID 19081992 DOI: 10.1039/b809676g  1
2009 Denmark SE, Almstead NG. Stereochemical studies on the addition of allylsilanes to aldehydes. The SE' component Journal of the Mexican Chemical Society. 53: 174-192. DOI: 10.1021/jo00097a009  1
2009 Denmark SE, Butler CR, Pfaltz A, Woodmansee DH. Vinylation with inexpensive silicon-based reagents: Preparation of 3-vinylquinoline and 4-vinylbenzophenone Organic Syntheses. 86: 274-286.  1
2009 Kuethe JT, Beutner GL, Denmark SE, Muhuhi JM. Synthesis of 2-arylindole-4-carboxylic amides: [2(4-Fluorophenyl)-1H-indol- 4-yl]-1-pyrrolidinylmethanone Organic Syntheses. 86: 92-104.  1
2009 Kramer JW, Treitler DS, Coates GW, Denmark SE, Hoover AJ. Low pressure carbonylation of epoxides to β-lactones Organic Syntheses. 86: 287-297.  1
2009 Osajima H, Fujiwara H, Okano K, Tokuyama H, Fukuyama T, Denmark SE, Chang WTT. Protection of diols with 4-(tert-Butyldimethylsilyloxy)Benzylidene acetal and its deprotection: (4-((4R,5R)-4,5-diphenyl-1,3-dioxolan-2-yl)phenoxy) (tertbutyl)dimethylsilane Organic Syntheses. 86: 130-140.  1
2008 Denmark SE, Nguyen ST, Baiazitov RY. ASYMMETRIC SYNTHESIS OF THE ABCD RING SYSTEM OF DAPHNILACTONE B VIA A TANDEM, DOUBLE INTRAMOLECULAR, [4+2]/[3+2] CYCLOADDITION STRATEGY. Heterocycles. 76: 143. PMID 20151037 DOI: 10.3987/COM-08-S(N)15  1
2008 Denmark SE, Nakajima N, Stiff CM, Nicaise OJ, Kranz M. Studies on the Bisoxazoline and (-)-Sparteine Mediated Enantioselective Addition of Organolithium Reagents to Imines. Advanced Synthesis & Catalysis. 350: 1023-1045. PMID 19809587 DOI: 10.1002/adsc.200800017  1
2008 Smith CR, Zhang A, Mans DJ, Rajanbabu TV, Denmark SE, Xie M. (R)-3-METHYL-3-PHENYL-1-PENTENE VIA CATALYTIC ASYMMETRIC HYDROVINYLATION. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 85: 248-266. PMID 19672483  1
2008 Smith CR, Mans DJ, Rajanbabu TV, Denmark SE, Nguyen ST. (R)-2,2'-BINAPHTHOYL-(S,S)-DI(1-PHENYLETHYL) AMINOPHOSPHINE. SCALABLE PROTOCOLS FOR THE SYNTHESES OF PHOSPHORAMIDITE (FERINGA) LIGANDS. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 85: 238-247. PMID 19655040 DOI: 10.15227/orgsyn.085.0238  0.52
2008 Denmark SE, Werner NS. Cross-coupling of aromatic bromides with allylic silanolate salts. Journal of the American Chemical Society. 130: 16382-93. PMID 18998687 DOI: 10.1021/ja805951j  1
2008 Denmark SE, Ares JJ. Stereoselective alkylations of chiral nitro imine and nitro hydrazone dianions. Synthesis of enantiomerically enriched 3-substituted 1-nitrocyclohexenes. The Journal of Organic Chemistry. 73: 9647-56. PMID 18855478 DOI: 10.1021/jo801790r  1
2008 Denmark SE, Regens CS. Palladium-catalyzed cross-coupling reactions of organosilanols and their salts: practical alternatives to boron- and tin-based methods. Accounts of Chemical Research. 41: 1486-99. PMID 18681465 DOI: 10.1021/ar800037p  1
2008 Denmark SE, Chung WJ. Lewis base activation of Lewis acids: catalytic, enantioselective addition of glycolate-derived silyl ketene acetals to aldehydes. The Journal of Organic Chemistry. 73: 4582-95. PMID 18505296 DOI: 10.1021/jo8006539  1
2008 Denmark SE, Butler CR. Vinylation of aromatic halides using inexpensive organosilicon reagents. Illustration of design of experiment protocols. Journal of the American Chemical Society. 130: 3690-704. PMID 18303892 DOI: 10.1021/ja7100888  1
2008 Denmark SE, Beutner GL. Lewis base catalysis in organic synthesis. Angewandte Chemie (International Ed. in English). 47: 1560-638. PMID 18236505 DOI: 10.1002/anie.200604943  1
2008 Denmark SE, Chung WJ. Lewis base activation of Lewis acids: catalytic enantioselective glycolate aldol reactions. Angewandte Chemie (International Ed. in English). 47: 1890-2. PMID 18236504 DOI: 10.1002/anie.200705499  1
2008 Denmark SE, Baird JD, Regens CS. Palladium-catalyzed cross-coupling of five-membered heterocyclic silanolates. The Journal of Organic Chemistry. 73: 1440-55. PMID 18205384 DOI: 10.1021/jo7023784  1
2008 Denmark SE, Lee W. Investigations into transition-state geometry in the Mukaiyama directed aldol reaction. Chemistry, An Asian Journal. 3: 327-41. PMID 18022982 DOI: 10.1002/asia.200700300  1
2008 Denmark SE, Eklov BM. Neutral and cationic phosphoramide adducts of silicon tetrachloride: synthesis and characterization of their solution and solid-state structures. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 234-9. PMID 17968868 DOI: 10.1002/chem.200701466  1
2008 Denmark SE. Asymmetrie catalysis with Chiral Lewis bases: A new frontier in main group chemistry Chimia. 62: 37-40. DOI: 10.2533/chimia.2008.37  1
2008 Denmark SE, Fujimori S. Chapter 1 Total synthesis of RK-397 Strategies and Tactics in Organic Synthesis. 7: 1-34. DOI: 10.1016/S1874-6004(08)80005-6  1
2008 Denmark SE. Organic Syntheses: Preface Organic Syntheses. 85: xxxix-xlii.  1
2007 Denmark SE, Smith RC, Tymonko SA. Phosphine Oxides as Stabilizing Ligands for the Palladium-Catalyzed Cross-Coupling of Potassium Aryldimethylsilanolates. Tetrahedron. 63: 5730-5738. PMID 23162169 DOI: 10.1016/j.tet.2007.02.017  1
2007 Denmark SE, Ahmad M. Carbonylative ring opening of terminal epoxides at atmospheric pressure. The Journal of Organic Chemistry. 72: 9630-4. PMID 17988145 DOI: 10.1021/jo7014455  1
2007 Denmark SE, Wilson TW, Burk MT, Heemstra JR. Enantioselective construction of quaternary stereogenic carbons by the Lewis base catalyzed additions of silyl ketene imines to aldehydes. Journal of the American Chemical Society. 129: 14864-5. PMID 17988135 DOI: 10.1021/ja077134y  1
2007 Denmark SE, Collins WR. Lewis base activation of Lewis acids: development of a Lewis base catalyzed selenolactonization. Organic Letters. 9: 3801-4. PMID 17705396 DOI: 10.1021/ol701617d  1
2007 Denmark SE, Xie M. Lewis acid-promoted conjugate addition of dienol silyl ethers to nitroalkenes: synthesis of 3-substituted azepanes. The Journal of Organic Chemistry. 72: 7050-3. PMID 17676807 DOI: 10.1021/jo071126i  1
2007 Denmark SE, Heemstra JR. Lewis base activation of Lewis acids: catalytic, enantioselective vinylogous aldol addition reactions. The Journal of Organic Chemistry. 72: 5668-88. PMID 17583959 DOI: 10.1002/chin.200750048  1
2007 Denmark SE, Liu JH. Sequential silylcarbocyclization/silicon-based cross-coupling reactions. Journal of the American Chemical Society. 129: 3737-44. PMID 17335205 DOI: 10.1002/chin.200736167  1
2007 Denmark SE, Regens CS, Kobayashi T. Total synthesis of papulacandin D. Journal of the American Chemical Society. 129: 2774-6. PMID 17305346 DOI: 10.5059/yukigoseikyokaishi.66.616  1
2007 Denmark SE, Ghosh SK. Unexpected ambidoselectivity in crossed-aldol reactions of α-oxy aldehyde trichlorosilyl enolates Tetrahedron. 63: 8636-8644. DOI: 10.1016/j.tet.2007.04.009  1
2007 Denmark SE, Barsanti PA, Beutner GL, Wilson TW. Enantioselective ring opening of epoxides with silicon tetrachloride in the presence of a chiral lewis base: Mechanism studies Advanced Synthesis and Catalysis. 349: 566-582. DOI: 10.1002/adsc.200600551  1
2006 Denmark SE, Kallemeyn JM. Stereospecific palladium-catalyzed cross-coupling of (E)- and (Z)-alkenylsilanolates with aryl chlorides. Journal of the American Chemical Society. 128: 15958-9. PMID 17165708 DOI: 10.1021/ja065988x  1
2006 Denmark SE, Neuville L, Christy ME, Tymonko SA. A qualitative examination of the effects of silicon substituents on the efficiency of cross-coupling reactions. The Journal of Organic Chemistry. 71: 8500-9. PMID 17064026 DOI: 10.1021/jo061481t  1
2006 Denmark SE, Edwards MG. On the mechanism of the selenolactonization reaction with selenenyl halides. The Journal of Organic Chemistry. 71: 7293-306. PMID 16958523 DOI: 10.1021/jo0610457  1
2006 Denmark SE. Organic chemistry: catalysts break symmetry. Nature. 443: 40-1. PMID 16957721 DOI: 10.1038/443040b  1
2006 Denmark SE, Montgomery JI, Kramps LA. Synthesis, X-ray crystallography, and computational analysis of 1-azafenestranes. Journal of the American Chemical Society. 128: 11620-30. PMID 16939287 DOI: 10.1021/ja0632759  1
2006 Denmark SE, Montgomery JI. A general synthesis of N-vinyl nitrones. The Journal of Organic Chemistry. 71: 6211-20. PMID 16872207 DOI: 10.1002/chin.200649061  1
2006 Denmark SE, Chung WJ. Lewis base catalyzed addition of trimethylsilyl cyanide to aldehydes. The Journal of Organic Chemistry. 71: 4002-5. PMID 16674085 DOI: 10.1021/jo060153q  1
2006 Denmark SE, Pham SM, Stavenger RA, Su X, Wong KT, Nishigaichi Y. Chiral phosphoramide-catalyzed aldol additions of ketone trichlorosilyl enolates. Mechanistic aspects. The Journal of Organic Chemistry. 71: 3904-22. PMID 16674067 DOI: 10.1021/jo060243v  1
2006 Denmark SE, Baird JD. Palladium-catalyzed cross-coupling reactions of silanolates: a paradigm shift in silicon-based cross-coupling reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 4954-63. PMID 16671045 DOI: 10.1002/chem.200600034  1
2006 Denmark SE, Venkatraman S. On the mechanism of the Skraup-Doebner-Von Miller quinoline synthesis. The Journal of Organic Chemistry. 71: 1668-76. PMID 16468822 DOI: 10.1021/jo052410h  1
2006 Denmark SE, Fu J, Lawler MJ. Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative studies with bidentate phosphorus-based amides. The Journal of Organic Chemistry. 71: 1523-36. PMID 16468801 DOI: 10.1021/jo052203h  1
2006 Denmark SE, Fu J, Coe DM, Su X, Pratt NE, Griedel BD. Chiral phosphoramide-catalyzed enantioselective addition of allylic trichlorosilanes to aldehydes. Preparative and mechanistic studies with monodentate phosphorus-based amides. The Journal of Organic Chemistry. 71: 1513-22. PMID 16468800 DOI: 10.1021/jo052202p  1
2006 Denmark SE, Baird JD. Palladium-catalyzed cross-coupling reactions of heterocyclic silanolates with substituted aryl iodides and bromides. Organic Letters. 8: 793-5. PMID 16468769 DOI: 10.1021/ol053165r  1
2006 Denmark SE, Heemstra JR. Lewis base activation of Lewis acids. Vinylogous aldol addition reactions of conjugated N,O-silyl ketene acetals to aldehydes. Journal of the American Chemical Society. 128: 1038-9. PMID 16433495 DOI: 10.1021/ja056747c  1
2006 Denmark SE, Baiazitov RY. Tandem double-intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. Studies toward a total synthesis of daphnilactone B: piperidine ring construction. The Journal of Organic Chemistry. 71: 593-605. PMID 16408969 DOI: 10.1021/jo052001l  1
2006 Denmark SE, Butler CR. Vinylation of aryl bromides using an inexpensive vinylpolysiloxane. Organic Letters. 8: 63-6. PMID 16381568 DOI: 10.1021/ol052517r  1
2006 Denmark SE, Smith RC. Reduction of allylpalladium(II)chloride dimer by formation of allyloxysilanes Synlett. 2921-2928. DOI: 10.1055/s-2006-951516  1
2006 Denmark SE, Fan Y. Preparation of chiral bipyridine bis-N-oxides by oxidative dimerization of chiral pyridine N-oxides Tetrahedron Asymmetry. 17: 687-707. DOI: 10.1016/j.tetasy.2005.12.039  1
2006 Denmark SE, Cottell JJ. A tandem, nitroalkene conjugate addition/[3+2] cycloaddition approach to the synthesis of the pentacyclic core of (±)-scandine Advanced Synthesis and Catalysis. 348: 2397-2402. DOI: 10.1002/adsc.200600301  1
2006 Denmark SE, Fu J, Lawler MJ. (R,R)-2,2′-bispyrrolidine and (S,S)-2,2′-bispyrrolidine: Useful ligands for asymmetric synthesis Organic Syntheses. 83: 121-130.  1
2006 Denmark SE, Siegel JS. Topics in Stereochemistry: Introduction to the series Topics in Stereochemistry. 25: v.  1
2005 Denmark SE, Fujimori S, Pham SM. Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates and silyl enol ethers. The Journal of Organic Chemistry. 70: 10823-40. PMID 16356006 DOI: 10.1021/jo051930+  1
2005 Denmark SE, Bui T. Mechanistic insights into the chiral phosphoramide-catalyzed, enantioselective crossed-aldol reactions of aldehydes. The Journal of Organic Chemistry. 70: 10393-9. PMID 16323849 DOI: 10.1021/jo051680x  1
2005 Denmark SE, Baiazitov RY. Intramolecular [4 + 2] cycloaddition of nitroalkenes for construction of vicinal quaternary stereocenters. Organic Letters. 7: 5617-20. PMID 16321005 DOI: 10.1021/ol052316n  1
2005 Denmark SE, Bui T. Lewis base catalyzed enantioselective aldol addition of acetaldehyde-derived silyl enol ether to aldehydes. The Journal of Organic Chemistry. 70: 10190-3. PMID 16292871 DOI: 10.1021/jo0517500  1
2005 Denmark SE, Fan Y. Catalytic, enantioselective alpha-additions of isocyanides: Lewis base catalyzed Passerini-type reactions. The Journal of Organic Chemistry. 70: 9667-76. PMID 16292793 DOI: 10.1002/chin.200614034  1
2005 Denmark SE, Fujimori S. Total synthesis of RK-397. Journal of the American Chemical Society. 127: 8971-3. PMID 15969572 DOI: 10.1002/chin.200546200  1
2005 Denmark SE, Fan Y, Eastgate MD. Lewis base catalyzed, enantioselective aldol addition of methyl trichlorosilyl ketene acetal to ketones. The Journal of Organic Chemistry. 70: 5235-48. PMID 15960528 DOI: 10.1021/jo0506276  1
2005 Denmark SE, Heemstra JR, Beutner GL. Catalytic, enantioselective, vinylogous aldol reactions. Angewandte Chemie (International Ed. in English). 44: 4682-98. PMID 15940727 DOI: 10.1002/chin.200545234  1
2005 Denmark SE, Tymonko SA. Sequential cross-coupling of 1,4-bissilylbutadienes: synthesis of unsymmetrical 1,4-disubstituted 1,3-butadienes. Journal of the American Chemical Society. 127: 8004-5. PMID 15926811 DOI: 10.1021/ja0518373  1
2005 Denmark SE, Montgomery JI. Synthesis of cis,cis,cis,cis-[5.5.5.4]-1-azafenestrane with discovery of an unexpected dyotropic rearrangement. Angewandte Chemie (International Ed. in English). 44: 3732-6. PMID 15887203 DOI: 10.1002/anie.200500367  1
2005 Denmark SE, Kallemeyn JM. Synthesis of 3,4,5-trisubstituted isoxazoles via sequential [3 + 2] cycloaddition/silicon-based cross-coupling reactions. The Journal of Organic Chemistry. 70: 2839-42. PMID 15787583 DOI: 10.1021/jo047755z  1
2005 Denmark SE, Beutner GL, Wynn T, Eastgate MD. Lewis base activation of Lewis acids: catalytic, enantioselective addition of silyl ketene acetals to aldehydes. Journal of the American Chemical Society. 127: 3774-89. PMID 15771512 DOI: 10.1002/chin.200532045  1
2005 Denmark SE, Wang Z. Platinum catalyzed hydrosilylation and palladium catalyzed cross-coupling: One-pot hydroarylation of 1-heptyne to (E)-1-(1-heptenyl)-4methoxybenzene Organic Syntheses. 81. DOI: 10.15227/orgsyn.081.0054  1
2005 Denmark SE, Yang SM. Chapter 4 Application of silicon-assisted intramolecular cross-coupling in total synthesis of (+)-brasilenyne Strategies and Tactics in Organic Synthesis. 6: 100-136. DOI: 10.1016/S1874-6004(05)80027-9  1
2005 Denmark SE, Wang Z. Palladium catalyzed cross-coupling of (Z)-1heptenyldimethylsilanol with 4-iodoanisole: (Z)-1heptenyl-4-methoxybenzene Organic Syntheses. 81.  1
2004 Denmark SE, Yang SM. Total synthesis of (+)-brasilenyne. Application of an intramolecular silicon-assisted cross-coupling reaction. Journal of the American Chemical Society. 126: 12432-40. PMID 15453777 DOI: 10.1021/ja0466863  1
2004 Denmark SE, Baird JD. Palladium-catalyzed cross-coupling reactions of 2-indolyldimethylsilanols with substituted aryl halides. Organic Letters. 6: 3649-52. PMID 15387570 DOI: 10.1021/ol048328a  1
2004 Denmark SE, Sweis RF. Cross-coupling reactions of alkenylsilanolates. Investigation of the mechanism and identification of key intermediates through kinetic analysis. Journal of the American Chemical Society. 126: 4876-82. PMID 15080692 DOI: 10.1021/ja0372356  1
2004 Denmark SE, Sweis RF, Wehrli D. Fluoride-promoted cross-coupling reactions of alkenylsilanols. Elucidation of the mechanism through spectroscopic and kinetic analysis. Journal of the American Chemical Society. 126: 4865-75. PMID 15080691 DOI: 10.1021/ja037234d  1
2004 Denmark SE, Bui T. Chiral phosphoramide-catalyzed, enantioselective, directed cross-aldol reactions of aldehydes. Proceedings of the National Academy of Sciences of the United States of America. 101: 5439-44. PMID 15067133 DOI: 10.1073/pnas.0307212101  1
2004 Denmark SE, Heemstra JR. Lewis base activation of Lewis acids: Vinylogous aldol additions of silyl dienol ethers to aldehydes Synlett. 2411-2416. DOI: 10.1055/s-2004-834789  1
2004 Denmark SE, Yang SM. Sequential ring-closing metathesis/Pd-catalyzed, Si-assisted cross-coupling reactions: General synthesis of highly substituted unsaturated alcohols and medium-sized rings containing a 1,3-cis-cis diene unit Tetrahedron. 60: 9695-9708. DOI: 10.1016/j.tet.2004.06.149  1
2004 Denmark SE, Ober MH. Palladium-catalyzed cross-coupling reactions of substituted aryl(dimethyl)silanols Advanced Synthesis and Catalysis. 346: 1703-1714. DOI: 10.1002/adsc.200404204  1
2003 Tishkov AA, Lesiv AV, Khomutova YA, Strelenko YA, Nesterov ID, Antipin MY, Ioffe SL, Denmark SE. 2-silyloxy-1,2-oxazines, a new type of acetals of conjugated nitroso alkenes. The Journal of Organic Chemistry. 68: 9477-80. PMID 14629175 DOI: 10.1002/chin.200415148  1
2003 Denmark SE, Tymonko SA. Cross-coupling of alkynylsilanols with aryl halides promoted by potassium trimethylsilanolate. The Journal of Organic Chemistry. 68: 9151-4. PMID 14604401 DOI: 10.1002/chin.200413065  1
2003 Denmark SE, Gomez L. Tandem double intramolecular [4+2]/[3+2] cycloadditions of nitroalkenes. The fused/bridged mode. The Journal of Organic Chemistry. 68: 8015-24. PMID 14535778 DOI: 10.1021/jo034853w  1
2003 Denmark SE, Kallemeyn JM. Palladium-catalyzed silylation of aryl bromides leading to functionalized aryldimethylsilanols. Organic Letters. 5: 3483-6. PMID 12967305 DOI: 10.1002/chin.200405134  1
2003 Denmark SE, Amishiro N. Palladium-catalyzed conjugate addition of organosiloxanes to alpha,beta-unsaturated carbonyl compounds and nitroalkenes. The Journal of Organic Chemistry. 68: 6997-7003. PMID 12946140 DOI: 10.1021/jo034763r  1
2003 Denmark SE, Fu J. Catalytic enantioselective addition of allylic organometallic reagents to aldehydes and ketones. Chemical Reviews. 103: 2763-94. PMID 12914480 DOI: 10.1021/cr020050h  1
2003 Denmark SE, Fan Y. The first catalytic, asymmetric alpha-additions of isocyanides. Lewis-base-catalyzed, enantioselective Passerini-type reactions. Journal of the American Chemical Society. 125: 7825-7. PMID 12823000 DOI: 10.1002/chin.200344041  1
2003 Denmark SE, Beutner GL. Lewis base activation of Lewis acids. Vinylogous aldol reactions. Journal of the American Chemical Society. 125: 7800-1. PMID 12822988 DOI: 10.1002/chin.200344040  1
2003 Denmark SE, Kobayashi T. Tandem intramolecular silylformylation and silicon-assisted cross-coupling reactions. synthesis of geometrically defined alpha,beta-unsaturated aldehydes. The Journal of Organic Chemistry. 68: 5153-9. PMID 12816470 DOI: 10.1021/jo034064e  1
2003 Denmark SE, Pham SM. Stereoselective aldol additions of achiral ethyl ketone-derived trichlorosilyl enolates. The Journal of Organic Chemistry. 68: 5045-55. PMID 12816457 DOI: 10.1021/jo034092x  1
2003 Denmark SE, Heemstra JR. Lewis base activation of Lewis acids. Catalytic enantioselective addition of silyl enol ethers of achiral methyl ketones to aldehydes. Organic Letters. 5: 2303-6. PMID 12816434 DOI: 10.1021/ol034641l  1
2003 Denmark SE, Ober MH. Cross-coupling reactions of arylsilanols with substituted aryl halides. Organic Letters. 5: 1357-60. PMID 12688758 DOI: 10.1021/ol034328j  1
2003 Denmark SE, Pan W. Intramolecular syn and anti hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted allylic alcohols. Organic Letters. 5: 1119-22. PMID 12659588 DOI: 10.1021/ol0342002  1
2003 Denmark SE, Fu J. Understanding the correlation of structure and selectivity in the chiral-phosphoramide-catalyzed enantioselective allylation reactions: solution and solid-state structural studies of bisphosphoramide.SnCl(4) complexes. Journal of the American Chemical Society. 125: 2208-16. PMID 12590549 DOI: 10.1021/ja021280g  1
2003 Denmark SE, Fu J. Catalytic enantioselective allylation with chiral Lewis bases. Chemical Communications (Cambridge, England). 167-70. PMID 12585378 DOI: 10.1039/B208065F  1
2003 Denmark SE, Ober MH. Organosilicon Reagents: Synthesis and Application to Palladium-Catalyzed Cross-Coupling Reactions Aldrichimica Acta. 36: 75-85. DOI: 10.1002/chin.200436264  1
2002 Denmark SE, Sweis RF. Cross-coupling reactions of organosilicon compounds: new concepts and recent advances. Chemical & Pharmaceutical Bulletin. 50: 1531-41. PMID 12499586 DOI: 10.1248/cpb.50.1531  1
2002 Denmark SE, Yang SM. Intramolecular silicon-assisted cross-coupling: total synthesis of (+)-brasilenyne. Journal of the American Chemical Society. 124: 15196-7. PMID 12487594 DOI: 10.1002/chin.200319207  1
2002 Denmark SE, Pan W. Intramolecular anti-hydrosilylation and silicon-assisted cross-coupling: highly regio- and stereoselective synthesis of trisubstituted homoallylic alcohols. Organic Letters. 4: 4163-6. PMID 12423112 DOI: 10.1002/chin.200313081  1
2002 Denmark SE, Wynn T, Beutner GL. Lewis base activation of lewis acids. Addition of silyl ketene acetals to aldehydes. Journal of the American Chemical Society. 124: 13405-7. PMID 12418891 DOI: 10.1021/ja0282947  1
2002 Denmark SE, Kramps LA, Montgomery JI. Synthesis of cis,cis,cis,cis-[5.5.5.5]-1-azafenestrane. Angewandte Chemie (International Ed. in English). 41: 4122-5. PMID 12412102 DOI: 10.1002/1521-3773(20021104)41:21<4122::AID-ANIE4122>3.0.CO;2-W  1
2002 Denmark SE, Sweis RF. Design and implementation of new, silicon-based, cross-coupling reactions: importance of silicon-oxygen bonds. Accounts of Chemical Research. 35: 835-46. PMID 12379136 DOI: 10.1021/ar020001r  1
2002 Denmark SE, Sweis RF. Cross-coupling reactions of alkenylsilanols with fluoroalkylsulfonates. Organic Letters. 4: 3771-4. PMID 12375940 DOI: 10.1002/chin.200311053  1
2002 Denmark SE, Fujimori S. The effects of a remote stereogenic center in the Lewis base catalyzed aldol additions of chiral trichlorosilyl enolates. Organic Letters. 4: 3477-80. PMID 12323048 DOI: 10.1002/chin.200311081  1
2002 Denmark SE, Fujimori S. Diastereoselective aldol additions of chiral beta-hydroxy ethyl ketone enolates catalyzed by Lewis bases. Organic Letters. 4: 3473-6. PMID 12323047 DOI: 10.1002/chin.200311080  1
2002 Denmark SE, Fu J. Asymmetric construction of quaternary centers by enantioselective allylation: application to the synthesis of the serotonin antagonist LY426965. Organic Letters. 4: 1951-3. PMID 12027655 DOI: 10.1021/ol025971t  1
2002 Denmark SE, Matsuhashi H. Chiral fluoro ketones for catalytic asymmetric epoxidation of alkenes with oxone. The Journal of Organic Chemistry. 67: 3479-86. PMID 12003563 DOI: 10.1021/jo020050h  1
2002 Denmark SE, Fan Y. Catalytic, enantioselective aldol additions to ketones. Journal of the American Chemical Society. 124: 4233-5. PMID 11960451 DOI: 10.1021/ja025670e  1
2002 Denmark SE, Yang SM. Intramolecular silicon-assisted cross-coupling reactions: general synthesis of medium-sized rings containing a 1,3-cis-cis diene unit. Journal of the American Chemical Society. 124: 2102-3. PMID 11878949 DOI: 10.1021/ja0178158  1
2002 Denmark SE, Dorow RL. Stereospecific cleavage of carbon-phosphorus bonds: stereochemical course of the phosphinoyl curtius (Harger) reaction. Chirality. 14: 241-57. PMID 11835571 DOI: 10.1002/chir.10062  1
2002 Denmark SE, Gomez L. Inter- and intramolecular [4+2] cycloaddition of nitroalkenes with allenylsilanes. A case of unexpected regioselectivity Heterocycles. 58: 129-136. DOI: 10.3987/com-02-s(m)58  1
2002 Ronsheim MD, Hilgenkamp RK, Zercher CK, Denmark SE, Beutner GL. Formation of γ-keto esters from -keto esters: Methyl 5.5-dimethyl-4-oxohexanoate Organic Syntheses. 79: 146-152. DOI: 10.15227/orgsyn.079.0146  1
2002 Kitamura M, Oka H, Suga S, Noyori R, Kaelin DE, Martin SF, Beutner GL, Denmark SE. Catalytic enantioselective addition of dialkylzincs to aldehydes using (2s)-(-)-3-exo-(dimethylamino)isoborneol [(2S)DAIB]: (S)-1-phenyl-1-propanol Organic Syntheses. 79: 139-145. DOI: 10.15227/orgsyn.079.0139  1
2002 Denmark SE, Pan W. Efficient and stereoselective cross-coupling with highly substituted alkenylsilanols Journal of Organometallic Chemistry. 653: 98-104. DOI: 10.1016/S0022-328X(02)01268-8  1
2002 Denmark SE, Juhl M. Tandem inter [4+2]/intra [3+2] cycloadditions of nitroalkenes. Application to the synthesis of aminocarbasugars Helvetica Chimica Acta. 85: 3712-3736. DOI: 10.1002/1522-2675(200211)85:11<3712::AID-HLCA3712>3.0.CO;2-5  1
2002 Gonzalez J, Aurigemma C, Truesdale L, Denmark SE, Tymonko SA, Cottell JJ, Gomez L. Synthesis of (+)-(1S,2R)- and (-)-(! R,2S)-trans-2-phenylcyclohexanol via sharpless asymmetric dihydroxylation (AD) Organic Syntheses. 79: 93-102.  1
2002 Christopher McWilliams J, Fleitz FJ, Zheng N, Armstrong JD, Denmark SE, Sweis RF. Preparation of n-butyl 4-chlorophenyl sulfide Organic Syntheses. 79: 43-49.  1
2001 Denmark SE, Wynn T, Jellerichs BG. Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases Response to the Communication by G. Buono et al. Angewandte Chemie (International Ed. in English). 40: 2255-2256. PMID 29711813 DOI: 10.1002/1521-3773(20010618)40:12<2255::AID-ANIE2255>3.0.CO;2-3  0.52
2001 Denmark SE, Ghosh SK. The First Catalytic, Diastereoselective, and Enantioselective Crossed-Aldol Reactions of Aldehydes We are grateful to the National Science Foundation for generous financial support (NSF CHE 9803124). Angewandte Chemie (International Ed. in English). 40: 4759-4762. PMID 12404409 DOI: 10.1002/1521-3773(20011217)40:24<4759::AID-ANIE4759>3.0.CO;2-G  1
2001 Denmark SE, Fu J. Catalytic, enantioselective addition of substituted allylic trichlorosilanes using a rationally-designed 2,2'-bispyrrolidine-based bisphosphoramide. Journal of the American Chemical Society. 123: 9488-9. PMID 11562250 DOI: 10.1021/ja016552e  1
2001 Denmark SE, Gomez L. Tandem double intramolecular [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. Organic Letters. 3: 2907-10. PMID 11529787 DOI: 10.1021/ol016385n  1
2001 Denmark SE, Pham SM. Highly diastereoselective aldol additions of a chiral ethyl ketone enolate under Lewis base catalysis. Organic Letters. 3: 2201-4. PMID 11440579 DOI: 10.1021/ol0160497  1
2001 Denmark SE, Wynn T, Jellerichs BG. Beneficial Effect of ortho-Methoxy Groups in the Asymmetric Ring Opening of meso Epoxides with Silicon Tetrachloride Catalyzed by Chiral ortho-Methoxyphenyldiazaphosphonamide Lewis Bases Response to the Communication by G. Buono et al. We are grateful to the National Science Foundation (CHE-9803124) for generous financial support. Cory M. Stiff is thanked for preliminary experiments. Angewandte Chemie (International Ed. in English). 40: 2255-2256. PMID 11433486 DOI: 10.1002/1521-3773(20010618)40:12<2255::AID-ANIE2255>3.0.CO;2-3  1
2001 Denmark SE, Pan W. Intramolecular hydrosilylation and silicon-assisted cross-coupling: an efficient route to trisubstituted homoallylic alcohols. Organic Letters. 3: 61-4. PMID 11429872 DOI: 10.1021/ol006769y  1
2001 Denmark SE, Sweis RF. Fluoride-free cross-coupling of organosilanols. Journal of the American Chemical Society. 123: 6439-40. PMID 11427080 DOI: 10.1021/ja016021q  1
2001 Denmark SE, Wynn T. Lewis base activation of Lewis acids: catalytic enantioselective allylation and propargylation of aldehydes. Journal of the American Chemical Society. 123: 6199-200. PMID 11414863 DOI: 10.1021/ja016017e  1
2001 Denmark SE, Yang SM. Sequential ring-closing metathesis and silicon-assisted cross-coupling reactions: stereocontrolled synthesis of highly substituted unsaturated alcohols. Organic Letters. 3: 1749-52. PMID 11405702 DOI: 10.1021/ol015950j  1
2001 Denmark SE, Cottell JJ. Synthesis of (+)-1-epiaustraline. The Journal of Organic Chemistry. 66: 4276-84. PMID 11397164 DOI: 10.1021/jo0101510  1
2001 Denmark SE, Wang Z. Highly stereoselective hydrocarbation of terminal alkynes via Pt-catalyzed hydrosilylation/Pd-catalyzed cross-coupling reactions. Organic Letters. 3: 1073-6. PMID 11277798 DOI: 10.1021/ol0156751  1
2001 Denmark SE, Guagnano V, Vaugeois J. Studies on the reduction and hydrolysis of nitroso acetals Canadian Journal of Chemistry. 79: 1606-1616. DOI: 10.1139/v01-132  1
2001 Denmark SE, Fujimori S. Diastereoselective aldol addition reactions of a chiral methyl ketone trichlorosilyl enolate under lewis base catalysis Synlett. 1024-1029. DOI: 10.1055/s-2001-14652  1
2001 Denmark SE, Wang Z. 1-Methyl-1-vinyl- and 1-Methyl-1-(prop-2-enyl)silacyclobutane: Reagents for palladium-catalyzed cross-coupling reactions of aryl halides Synthesis. 999-1003. DOI: 10.1055/s-2000-6292  1
2001 Denmark SE, Wang Z. Cross-coupling of vinylpolysiloxanes with aryl iodides Journal of Organometallic Chemistry. 624: 372-375. DOI: 10.1016/S0022-328X(00)00894-9  1
2000 Denmark SE, Neuville L. Mild and general cross-coupling of (alpha-Alkoxyvinyl)silanols and -silyl hydrides Organic Letters. 2: 3221-4. PMID 11009386 DOI: 10.1021/ol0064112  0.52
2000 Denmark SE, Stiff CM. Effect of ligand structure in the bisoxazoline mediated asymmetric addition of methyllithium to imines The Journal of Organic Chemistry. 65: 5875-8. PMID 10970343 DOI: 10.1021/jo0007175  1
2000 Denmark SE, Wehrli D, Choi JY. Convergence of mechanistic pathways in the Palladium(0)-catalyzed cross-coupling of alkenylsilacyclobutanes and alkenylsilanols Organic Letters. 2: 2491-4. PMID 10956529  1
2000 Denmark SE, Stavenger RA. Asymmetric catalysis of aldol reactions with chiral lewis bases. Accounts of Chemical Research. 33: 432-40. PMID 10891061 DOI: 10.1021/ar960027g  1
2000 Denmark SE, Wehrli D. Highly stereospecific, palladium-catalyzed cross-coupling of alkenylsilanols Organic Letters. 2: 565-8. PMID 10814378  0.44
2000 Denmark SE, Herbert B. Synthesis of (-)-7-epiaustraline and (-)-1-epicastanospermine. The Journal of Organic Chemistry. 65: 2887-96. PMID 10814174 DOI: 10.1021/jo991990d  0.01
2000 Denmark SE, Hurd AR. Synthesis of (+)-casuarine. The Journal of Organic Chemistry. 65: 2875-86. PMID 10814173 DOI: 10.1021/jo991680v  1
2000 Denmark SE, Kim JH. Diastereoselective alkylations of chiral, phosphorus-stabilized carbanions: N-alkyl substituent effects in P-alkyl-1,3,2-diazaphosphorinane 2-oxides Canadian Journal of Chemistry. 78: 673-688. DOI: 10.1139/v99-251  1
2000 Denmark SE, Fu J. On the mechanism of catalytic, enantioselective allylation of aldehydes with chlorosilanes and chiral Lewis bases [14] Journal of the American Chemical Society. 122: 12021-12022. DOI: 10.1021/ja002060a  1
2000 Denmark SE, Stavenger RA. The chemistry of trichlorosilyl enolates. Aldol addition reactions of methyl ketones Journal of the American Chemical Society. 122: 8837-8847. DOI: 10.1021/ja001023g  1
2000 Denmark SE, Pham SM. Kinetic analysis of the divergence of reaction pathways in the chiral Lewis base promoted aldol additions of trichlorosilyl enol ethers: A Rapid-injection NMR study Helvetica Chimica Acta. 83: 1846-1853. DOI: 10.1002/1522-2675(20000809)83:8<1846::AID-HLCA1846>3.0.CO;2-V  1
2000 Denmark SE, Neuville L. Mild and general cross-coupling of (α-alkoxyvinyl)silanols and -silyl hydrides Organic Letters. 2: 3221-3224.  1
1999 Denmark SE, Su X, Nishigaichi Y, Coe DM, Wong KT, Winter SB, Choi JY. Synthesis of Phosphoramides for the Lewis Base-Catalyzed Allylation and Aldol Addition Reactions. The Journal of Organic Chemistry. 64: 1958-1967. PMID 11674289 DOI: 10.1021/jo9820723  0.64
1999 Denmark SE, Hurd AR. Synthesis of (+)-casuarine. Organic Letters. 1: 1311-4. PMID 10825980 DOI: 10.1021/ol9909886  1
1999 Denmark SE, Choi JY. Highly stereospecific, cross-coupling reactions of alkenylsilacyclobutanes Journal of the American Chemical Society. 121: 5821-5822. DOI: 10.1021/ja9908117  1
1999 Denmark SE, Stavenger RA, Wong KT, Su X. Chiral phosphoramide-catalyzed aldol additions of ketone enolates. Preparative aspects Journal of the American Chemical Society. 121: 4982-4991. DOI: 10.1021/ja984123j  1
1998 Denmark SE, Barsanti PA, Wong KT, Stavenger RA. Enantioselective Ring Opening of Epoxides with Silicon Tetrachloride in the Presence of a Chiral Lewis Base. The Journal of Organic Chemistry. 63: 2428-2429. PMID 11672098 DOI: 10.1021/jo9801420  0.92
1998 Denmark SE, Stavenger RA, Winter SBD, Wong KT, Barsanti PA. Preparation of chlorosilyl enolates Journal of Organic Chemistry. 63: 9517-9523. DOI: 10.1021/jo981740h  1
1998 Denmark SE, Stavenger RA. Highly 1,4-syn diastereoselective, phosphoramide-catalyzed aldol additions of chiral methyl ketone enolates Journal of Organic Chemistry. 63: 9524-9527. DOI: 10.1021/jo981739i  1
1998 Denmark SE, Stavenger RA, Wong KT. Asymmetric aldol additions catalyzed by chiral phosphoramides: Electronic effects of the aldehyde component Tetrahedron. 54: 10389-10402. DOI: 10.1016/S0040-4020(98)00493-1  1
1997 Denmark SE, Wu Z, Crudden CM, Matsuhashi H. Catalytic Epoxidation of Alkenes with Oxone. 2. Fluoro Ketones. The Journal of Organic Chemistry. 62: 8288-8289. PMID 11671961 DOI: 10.1021/jo971781y  0.64
1997 Denmark SE, Dixon JA. Tandem Inter [4 + 2]/Intra [3 + 2] Cycloadditions of Nitroalkenes. A Versatile Asymmetric Synthesis of Highly Functionalized Aminocyclopentanes. The Journal of Organic Chemistry. 62: 7086-7087. PMID 11671805 DOI: 10.1021/jo9713215  0.01
1997 Denmark SE, Stavenger RA, Faucher AM, Edwards JP. Cyclopropanation with Diazomethane and Bis(oxazoline)palladium(II) Complexes. The Journal of Organic Chemistry. 62: 3375-3389. PMID 11671727 DOI: 10.1021/jo970044z  0.68
1997 Denmark SE, Hurd AR, Sacha HJ. Tandem [4 + 2]/[3 + 2] cycloadditions of nitroalkenes. 13. The synthesis of (-)-detoxinine Journal of Organic Chemistry. 62: 1668-1674. DOI: 10.1021/jo962306n  1
1997 Denmark SE, Wong KT, Stavenger RA. The chemistry of trichlorosilyl enolates. 2. Highly-selective asymmetric aldol additions of ketone enolates Journal of the American Chemical Society. 119: 2333-2334. DOI: 10.1021/ja9636698  1
1996 Denmark SE, Thorarensen A. Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes. 10. trans-2-(1-Methyl-1-phenylethyl)cyclohexanol as a New Auxiliary. The Journal of Organic Chemistry. 61: 6727-6729. PMID 11667549 DOI: 10.1021/jo960912c  0.12
1995 Denmark SE, Christenson BL, O'Connor SP. Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. II. The effect of promoter structure on selectivity Tetrahedron Letters. 36: 2219-2222. DOI: 10.1016/0040-4039(95)00259-F  1
1995 Denmark SE, Christenson BL, Coe DM, O'Connor SP. Catalytic enantioselective cyclopropanation with bis(halomethyl)zinc reagents. I. Optimization of reaction protocol Tetrahedron Letters. 36: 2215-2218. DOI: 10.1016/0040-4039(95)00258-E  1
1992 Denmark SE, Forbes DC. A stereochemical study on the intramolecular hydrosilylation of α,β-unsaturated esters Tetrahedron Letters. 33: 5037-5040. DOI: 10.1016/S0040-4039(00)61182-6  1
1992 Denmark SE, Chatani N, Pansare SV. Asymmetric electrophilic amination of chiral phosphorus-stabilized anions Tetrahedron. 48: 2191-2208. DOI: 10.1016/S0040-4020(01)88883-9  1
1989 Denmark SE, Weber EJ, Wilson TM, Willson TM. Stereochemical and spectroscopic studies on the reaction of allylstannanes with aldehydes Tetrahedron. 45: 1053-1065. DOI: 10.1016/0040-4020(89)80016-X  1
1987 Cramer CJ, Dykstra CE, Denmark SE. An AB initio study of the [1,2] proton transfer from phosphine oxide to phosphinic acid Chemical Physics Letters. 136: 17-21. DOI: 10.1016/0009-2614(87)87290-1  1
1984 Denmark SE, Harmata MA. Carbanion-accelerated Claisen rearrangements 3. Vicinal quaternary centers Tetrahedron Letters. 25: 1543-1546. DOI: 10.1016/S0040-4039(01)90005-X  1
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