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Larry E. Overman - Publications

Affiliations: 
University of California, Irvine, Irvine, CA 
Area:
synthesis of natural products
Website:
http://www.chem.uci.edu/faculty/leoverma/

500 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Lin M, Kowolik CM, Xie J, Yadav S, Overman LE, Horne DA. Correction: Lin et al. Potent Anticancer Effects of Epidithiodiketopiperazine NT1721 in Cutaneous T Cell Lymphoma. 2021, , 3367. Cancers. 13. PMID 34945012 DOI: 10.3390/cancers13246151  1
2021 Allred TK, Shaghafi MB, Chen PP, Tran Q, Houk KN, Overman LE. Constructing Saturated Guanidinum Heterocycles by Cycloaddition of -Amidinyliminium Ions with Indoles. Organic Letters. PMID 34546759 DOI: 10.1021/acs.orglett.1c02832  1
2021 Pitre SP, Overman LE. Strategic Use of Visible-Light Photoredox Catalysis in Natural Product Synthesis. Chemical Reviews. PMID 34232019 DOI: 10.1021/acs.chemrev.1c00247  1
2021 Pitre SP, Allred TK, Overman LE. Lewis Acid Activation of Fragment-Coupling Reactions of Tertiary Carbon Radicals Promoted by Visible-Light Irradiation of EDA Complexes. Organic Letters. PMID 33492152 DOI: 10.1021/acs.orglett.1c00023  0.01
2020 Allred TK, Dieskau AP, Zhao P, Lackner GL, Overman LE. General Access to Concave-Substituted -Dioxabicyclo[3.3.0]octanones: Enantioselective Total Syntheses of Macfarlandin C and Dendrillolide A. The Journal of Organic Chemistry. PMID 33197184 DOI: 10.1021/acs.joc.0c02273  1
2020 Overman LE, Allred TK, Dieskau AP, Zhao P, Lackner GL. Enantioselective Total Synthesis of Macfarlandin C, a Spongian Diterpenoid Harboring a Concave-Substituted cis-Dioxabicyclo[3.3.0]octanone Fragment. Angewandte Chemie (International Ed. in English). PMID 31965671 DOI: 10.1002/Anie.201916753  1
2019 Kowolik CM, Lin M, Xie J, Overman LE, Horne DA. Attenuation of hedgehog/GLI signaling by NT1721 extends survival in pancreatic cancer. Journal of Experimental & Clinical Cancer Research : Cr. 38: 431. PMID 31661013 DOI: 10.1186/S13046-019-1445-Z  1
2019 Overman LE, Weires NA, Slutskyy Y. Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization Cross-Coupling Cascade. Angewandte Chemie (International Ed. in English). PMID 30989757 DOI: 10.1002/Anie.201903353  1
2019 Pitre SP, Muuronen M, Fishman DA, Overman LE. Tertiary Alcohols as Radical Precursors for the Introduction of Tertiary Substituents into Heteroarenes Acs Catalysis. 9: 3413-3418. DOI: 10.1021/Acscatal.9B00405  0.01
2018 Kearney SE, Zahoránszky-Kőhalmi G, Brimacombe KR, Henderson MJ, Lynch C, Zhao T, Wan KK, Itkin Z, Dillon C, Shen M, Cheff DM, Lee TD, Bougie D, Cheng K, Coussens NP, ... ... Overman LE, et al. Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space. Acs Central Science. 4: 1727-1741. PMID 30648156 DOI: 10.1021/Acscentsci.8B00747  1
2018 Tao DJ, Slutskyy Y, Muuronen M, Le A, Kohler P, Overman LE. Correction to "Total Synthesis of (-)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade". Journal of the American Chemical Society. PMID 30582805 DOI: 10.1021/Jacs.8B13203  1
2018 Overman LE, Pitre SP, Weires NA. Forging C(sp3)-C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules. Journal of the American Chemical Society. PMID 30566838 DOI: 10.1021/Jacs.8B11790  1
2018 Becker MH, Chua P, Downham R, Douglas CJ, Garg NK, Hiebert S, Jaroch S, Matsuoka RT, Middleton JA, Ng FW, Overman LE. Correction to "Total Synthesis of (-)-Sarain A". Journal of the American Chemical Society. PMID 29620879 DOI: 10.1021/Jacs.8B03357  1
2018 Tao D, Slutskyy Y, Muuronen M, Le A, Kohler P, Overman LE. Total Synthesis of (-)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade. Journal of the American Chemical Society. PMID 29412658 DOI: 10.1021/Jacs.7B13799  1
2018 Abbas SY, Zhao P, Overman LE. 1,6-Addition of Tertiary Carbon Radicals Generated From Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis. Organic Letters. PMID 29360373 DOI: 10.1021/Acs.Orglett.7B04034  1
2018 Cannon JS, Overman LE. Discussion Addendum for: Preparation of the COP Catalysts: [( S )‐COP‐OAc] 2 , [( S )‐COP‐Cl] 2 , and ( S )‐COP‐hfacac Organic Syntheses. 95: 500-511. DOI: 10.1002/0471264229.Os095.33  1
2017 Garnsey MR, Slutskyy Y, Jamison CR, Zhao P, Lee J, Rhee YH, Overman LE. Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical. The Journal of Organic Chemistry. PMID 29130687 DOI: 10.1021/Acs.Joc.7B02458  1
2017 Slutskyy Y, Jamison CR, Zhao P, Lee J, Rhee YH, Overman LE. Versatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones. Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C. Journal of the American Chemical Society. PMID 28514145 DOI: 10.1021/Jacs.7B04265  1
2017 Jamison CR, Slutskyy Y, Overman LE. Fragment Coupling and Formation of Quaternary Carbons by Visible‐Light Photoredox Catalyzed Reaction of tert‐Alkyl Hemioxalate Salts and Michael Acceptors Organic Syntheses. 94: 167-183. DOI: 10.1002/0471264229.Os094.13  1
2016 Kowolik CM, Lin M, Xie J, Overman LE, Horne DA. NT1721, a novel epidithiodiketopiperazine, exhibits potent in vitro and in vivo efficacy against acute myeloid leukemia. Oncotarget. PMID 27863389 DOI: 10.18632/Oncotarget.13364  1
2016 Cannon JS, Overman LE. Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts. Accounts of Chemical Research. PMID 27689745 DOI: 10.1021/Acs.Accounts.6B00398  1
2016 Martins LF, Mesquita JT, Pinto EG, Costa-Silva TA, Borborema SE, Galisteo Junior AJ, Neves BJ, Andrade CH, Shuhaib ZA, Bennett EL, Black GP, Harper PM, Evans DM, Fituri HS, Leyland JP, ... ... Overman LE, et al. Analogues of Marine Guanidine Alkaloids Are in Vitro Effective against Trypanosoma cruzi and Selectively Eliminate Leishmania (L.) infantum Intracellular Amastigotes. Journal of Natural Products. PMID 27586460 DOI: 10.1021/Acs.Jnatprod.6B00256  1
2016 Jamison CR, Overman LE. Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis. Accounts of Chemical Research. PMID 27491019 DOI: 10.1021/Acs.Accounts.6B00284  1
2016 Slutskyy Y, Jamison CR, Lackner GL, Müller DS, Dieskau AP, Unteidt NL, Overman LE. Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor. The Journal of Organic Chemistry. PMID 27254137 DOI: 10.1021/Acs.Joc.6B00697  1
2016 Slutskyy Y, Overman LE. Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins. Organic Letters. PMID 27186995 DOI: 10.1021/Acs.Orglett.6B00895  1
2016 Tao D, Muuronen M, Slutskyy Y, Le A, Furche F, Overman LE. Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27128888 DOI: 10.1002/Chem.201601957  1
2016 Snigdha S, Prieto GA, Petrosyan A, Loertscher BM, Dieskau AP, Overman LE, Cotman CW. H3K9me3 Inhibition Improves Memory, Promotes Spine Formation, and Increases BDNF Levels in the Aged Hippocampus. The Journal of Neuroscience : the Official Journal of the Society For Neuroscience. 36: 3611-22. PMID 27013689 DOI: 10.1523/JNEUROSCI.2693-15.2016  1
2016 Tao DJ, Slutskyy Y, Overman LE. Total Synthesis of (-)-Chromodorolide B. Journal of the American Chemical Society. 138: 2186-9. PMID 26880210 DOI: 10.1021/Jacs.6B00541  1
2016 Büschleb M, Dorich S, Hanessian S, Tao D, Schenthal KB, Overman LE. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms. Angewandte Chemie (International Ed. in English). PMID 26836448 DOI: 10.1002/Anie.201507549  1
2016 Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DW, Overman LE. Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling". Journal of the American Chemical Society. PMID 26820773 DOI: 10.1021/jacs.6b00456  1
2016 Cannon JS, Overman LE. ChemInform Abstract: Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts Cheminform. 47. DOI: 10.1002/chin.201650208  0.01
2016 Slutskyy Y, Overman LE. ChemInform Abstract: Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins Cheminform. 47. DOI: 10.1002/chin.201642072  0.01
2016 Tao DJ, Slutskyy Y, Overman LE. ChemInform Abstract: Total Synthesis of (-)-Chromodorolide B. Cheminform. 47. DOI: 10.1002/chin.201632201  0.01
2016 Bueschleb M, Dorich S, Hanessian S, Tao D, Schenthal KB, Overman LE. ChemInform Abstract: Synthetic Strategies Toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms Cheminform. 47. DOI: 10.1002/chin.201619225  0.01
2016 Walton MC, Yang Y, Hong X, Houk KN, Overman LE. ChemInform Abstract: Ligand-Controlled Diastereoselective 1,3-Dipolar Cycloadditions of Azomethine Ylides with Methacrylonitrile. Cheminform. 47. DOI: 10.1002/chin.201618032  0.01
2016 Pratsch G, Overman LE. ChemInform Abstract: Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis. Cheminform. 47. DOI: 10.1002/chin.201614058  0.01
2016 Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DWC, Overman LE. ChemInform Abstract: Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. Cheminform. 47: no-no. DOI: 10.1002/chin.201608055  0.01
2016 Büschleb M, Dorich S, Hanessian S, Tao D, Schenthal KB, Overman LE. Strategien für die Synthese von Naturstoffen mit benachbarten stereogenen quartären Kohlenstoffatomen Angewandte Chemie. 128: 4226-4258. DOI: 10.1002/Ange.201507549  0.01
2015 Walton MC, Yang YF, Hong X, Houk KN, Overman LE. Ligand-Controlled Diastereoselective 1,3-Dipolar Cycloadditions of Azomethine Ylides with Methacrylonitrile. Organic Letters. PMID 26605985 DOI: 10.1021/Acs.Orglett.5B03171  1
2015 Pratsch G, Overman LE. Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis. The Journal of Organic Chemistry. PMID 26514061 DOI: 10.1021/Acs.Joc.5B01962  1
2015 Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DW, Overman LE. Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. Journal of the American Chemical Society. 137: 11270-3. PMID 26322524 DOI: 10.1021/Jacs.5B07678  1
2015 Baumann M, Dieskau AP, Loertscher BM, Walton MC, Nam S, Xie J, Horne D, Overman LE. Tricyclic Analogues of Epidithiodioxopiperazine Alkaloids with Promising In Vitro and In Vivo Antitumor Activity. Chemical Science (Royal Society of Chemistry : 2010). 6: 4451-4457. PMID 26301062 DOI: 10.1039/C5Sc01536G  1
2015 Canham SM, Hafensteiner BD, Lebsack AD, May-Dracka TL, Nam S, Stearns BA, Overman LE. Stereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids. Tetrahedron. 71: 6424-6436. PMID 26257440 DOI: 10.1016/J.Tet.2015.02.080  1
2015 Pratsch G, Lackner GL, Overman LE. Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis. The Journal of Organic Chemistry. 80: 6025-36. PMID 26030520 DOI: 10.1021/Acs.Joc.5B00795  1
2015 Lackner GL, Quasdorf KW, Pratsch G, Overman LE. Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis. The Journal of Organic Chemistry. 80: 6012-24. PMID 26030387 DOI: 10.1021/Acs.Joc.5B00794  1
2015 Müller DS, Untiedt NL, Dieskau AP, Lackner GL, Overman LE. Correction to "constructing quaternary stereogenic centers using tertiary organocuprates and tertiary radicals. total synthesis of trans-clerodane natural products". Journal of the American Chemical Society. 137: 4874. PMID 25837968 DOI: 10.1021/jacs.5b01078  1
2015 Müller DS, Untiedt NL, Dieskau AP, Lackner GL, Overman LE. Constructing quaternary stereogenic centers using tertiary organocuprates and tertiary radicals. Total synthesis of trans-clerodane natural products. Journal of the American Chemical Society. 137: 660-3. PMID 25563555 DOI: 10.1021/Ja512527S  1
2015 Baumann M, Dieskau AP, Loertscher BM, Walton MC, Nam S, Xie J, Horne D, Overman LE. Tricyclic analogues of epidithiodioxopiperazine alkaloids with promising in vitro and in vivo antitumor activity Chemical Science. 6: 4451-4457. DOI: 10.1039/c5sc01536g  1
2015 Canham SM, Hafensteiner BD, Lebsack AD, May-Dracka TL, Nam S, Stearns BA, Overman LE. Stereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids Tetrahedron. DOI: 10.1016/j.tet.2015.02.080  1
2015 Pratsch G, Lackner GL, Overman LE. ChemInform Abstract: Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis. Cheminform. 46: no-no. DOI: 10.1002/chin.201544051  0.01
2015 Lackner GL, Quasdorf KW, Pratsch G, Overman LE. ChemInform Abstract: Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates by Visible-Light Photocatalysis. Cheminform. 46: no-no. DOI: 10.1002/chin.201544040  0.01
2015 Quasdorf KW, Overman LE. ChemInform Abstract: Catalytic Enantioselective Synthesis of Quaternary Carbon Stereocentres Cheminform. 46: no-no. DOI: 10.1002/chin.201510326  0.01
2014 Quasdorf KW, Overman LE. Catalytic enantioselective synthesis of quaternary carbon stereocentres. Nature. 516: 181-91. PMID 25503231 DOI: 10.1038/Nature14007  1
2014 Shaghafi MB, Barrett DG, Willard FS, Overman LE. The insulin secretory action of novel polycyclic guanidines: discovery through open innovation phenotypic screening, and exploration of structure-activity relationships. Bioorganic & Medicinal Chemistry Letters. 24: 1031-6. PMID 24484900 DOI: 10.1016/J.Bmcl.2014.01.021  1
2014 Aron ZD, Ito T, May TL, Overman LE, Wang J. ChemInform Abstract: Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Rings: Coupled Dynamic Kinetic Epimerization and Chirality Transfer. Cheminform. 45: no-no. DOI: 10.1002/chin.201410134  0.01
2014 Lackner GL, Quasdorf KW, Overman LE. ChemInform Abstract: Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates. Cheminform. 45: no-no. DOI: 10.1002/chin.201410051  0.01
2014 Jabri SY, Overman LE. ChemInform Abstract: Enantioselective Total Syntheses of Plectosphaeroic Acids B (Ia) and C (Ib). Cheminform. 45: no-no. DOI: 10.1002/chin.201406223  0.01
2014 Schnermann MJ, Overman LE. Corrigendum: A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition Angewandte Chemie International Edition. 53: 2527-2527. DOI: 10.1002/Anie.201308558  0.01
2013 Aron ZD, Ito T, May TL, Overman LE, Wang J. Enantioselective synthesis of angularly substituted 1-azabicylic rings: coupled dynamic kinetic epimerization and chirality transfer. The Journal of Organic Chemistry. 78: 9929-48. PMID 24090405 DOI: 10.1021/Jo4018099  1
2013 Lackner GL, Quasdorf KW, Overman LE. Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates. Journal of the American Chemical Society. 135: 15342-5. PMID 24074152 DOI: 10.1021/Ja408971T  1
2013 Jabri SY, Overman LE. Enantioselective total syntheses of plectosphaeroic acids B and C. The Journal of Organic Chemistry. 78: 8766-88. PMID 24007470 DOI: 10.1021/Jo4015479  1
2013 DeLorbe JE, Horne D, Jove R, Mennen SM, Nam S, Zhang FL, Overman LE. General approach for preparing epidithiodioxopiperazines from trioxopiperazine precursors: enantioselective total syntheses of (+)- and (-)-gliocladine C, (+)-leptosin D, (+)-T988C, (+)-bionectin A, and (+)-gliocladin A. Journal of the American Chemical Society. 135: 4117-28. PMID 23452236 DOI: 10.1021/Ja400315Y  1
2013 Jabri SY, Overman LE. Enantioselective total synthesis of plectosphaeroic acid B. Journal of the American Chemical Society. 135: 4231-4. PMID 23452064 DOI: 10.1021/Ja401423J  1
2013 Canham SM, France DJ, Overman LE. Total synthesis of (+)-sieboldine a: evolution of a pinacol-terminated cyclization strategy. The Journal of Organic Chemistry. 78: 9-34. PMID 22734821 DOI: 10.1021/Jo300872Y  1
2013 Ragozzino D, Woodward RM, Murata Y, Eusebi F, Overman LE, Miledi R. Erratum: Design and in vitro pharmacology of a selective γ-aminobutyric acidc receptor antagonist (Molecular Pharmacology (1996) 50 (1024-1030)) Molecular Pharmacology. 83. DOI: 10.1124/Mol.113.06Er13  1
2013 Schnermann MJ, Untiedt NL, Jimenez-Oses G, Houk KN, Overman LE. ChemInform Abstract: Forming Tertiary Organolithiums and Organocuprates from Nitrile Precursors and Their Bimolecular Reactions with Carbon Electrophiles to Form Quaternary Carbon Stereocenters. Cheminform. 44: no-no. DOI: 10.1002/chin.201308040  0.01
2012 Wang H, Kohler P, Overman LE, Houk KN. Origins of stereoselectivities of dihydroxylations of cis-bicyclo[3.3.0]octenes. Journal of the American Chemical Society. 134: 16054-8. PMID 22954350 DOI: 10.1021/Ja3075538  1
2012 Schnermann MJ, Untiedt NL, Jiménez-Osés G, Houk KN, Overman LE. Forming tertiary organolithiums and organocuprates from nitrile precursors and their bimolecular reactions with carbon electrophiles to form quaternary carbon stereocenters. Angewandte Chemie (International Ed. in English). 51: 9581-6. PMID 22927041 DOI: 10.1002/Anie.201205001  1
2012 Schnermann MJ, Overman LE. A concise synthesis of (-)-aplyviolene facilitated by a strategic tertiary radical conjugate addition. Angewandte Chemie (International Ed. in English). 51: 9576-80. PMID 22926995 DOI: 10.1002/Anie.201204977  1
2012 Cannon JS, Overman LE. Is there no end to the total syntheses of strychnine? Lessons learned in strategy and tactics in total synthesis. Angewandte Chemie (International Ed. in English). 51: 4288-311. PMID 22431197 DOI: 10.1002/Anie.201107385  1
2012 Cannon JS, Olson AC, Overman LE, Solomon NS. Palladium(II)-catalyzed enantioselective synthesis of 2-vinyl oxygen heterocycles. The Journal of Organic Chemistry. 77: 1961-73. PMID 22316285 DOI: 10.1021/Jo202553A  1
2012 Cannon JS, Frederich JH, Overman LE. Palladacyclic imidazoline-naphthalene complexes: synthesis and catalytic performance in Pd(II)-catalyzed enantioselective reactions of allylic trichloroacetimidates. The Journal of Organic Chemistry. 77: 1939-51. PMID 22288535 DOI: 10.1021/Jo2025724  1
2012 Cannon JS, Overman LE. ChemInform Abstract: Is There No End to the Total Syntheses of Strychnine? Lessons Learned in Strategy and Tactics in Total Synthesis Cheminform. 43: no-no. DOI: 10.1002/chin.201234207  0.01
2012 Cannon JS, Olson AC, Overman LE, Solomon NS. ChemInform Abstract: Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles. Cheminform. 43: no-no. DOI: 10.1002/chin.201225148  0.01
2012 Cannon JS, Overman LE. Kein Ende für Totalsynthesen von Strychnin in Sicht? Lektionen für Strategien und Methoden in der Totalsynthese Angewandte Chemie. 124: 4362-4386. DOI: 10.1002/Ange.201107385  0.01
2011 Canham SM, Overman LE, Tanis PS. Identification of an Unexpected 2-Oxonia[3,3]sigmatropic Rearrangement/Aldol Pathway in the Formation of Oxacyclic Rings. Total Synthesis of (+)-Aspergillin PZ. Tetrahedron. 67: 9837-9843. PMID 22518066 DOI: 10.1016/J.Tet.2011.09.079  1
2011 Schnermann MJ, Beaudry CM, Genung NE, Canham SM, Untiedt NL, Karanikolas BD, Sütterlin C, Overman LE. Divergent synthesis and chemical reactivity of bicyclic lactone fragments of complex rearranged spongian diterpenes. Journal of the American Chemical Society. 133: 17494-503. PMID 21988207 DOI: 10.1021/Ja207727H  1
2011 Schnermann MJ, Overman LE. Enantioselective total synthesis of aplyviolene. Journal of the American Chemical Society. 133: 16425-7. PMID 21936525 DOI: 10.1021/Ja208018S  1
2011 DeLorbe JE, Jabri SY, Mennen SM, Overman LE, Zhang FL. Enantioselective total synthesis of (+)-gliocladine C: convergent construction of cyclotryptamine-fused polyoxopiperazines and a general approach for preparing epidithiodioxopiperazines from trioxopiperazine precursors. Journal of the American Chemical Society. 133: 6549-52. PMID 21473649 DOI: 10.1021/Ja201789V  1
2011 Martin CL, Nakamura S, Otte R, Overman LE. Total synthesis of (+)-condylocarpine, (+)-isocondylocarpine, and (+)-tubotaiwine. Organic Letters. 13: 138-41. PMID 21133399 DOI: 10.1021/Ol102709S  1
2011 Cannon JS, Kirsch SF, Overman LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Chiral Allylic Esters. Cheminform. 42: no-no. DOI: 10.1002/chin.201112045  0.01
2011 Overman LE, Humphreys PG, Welmaker GS. The aza-cope/mannich reaction Organic Reactions. 75: 747-820. DOI: 10.1002/0471264180.Or075.04  1
2010 Altman RA, Nilsson BL, Overman LE, Read de Alaniz J, Rohde JM, Taupin V. Total synthesis of (+)-nankakurines A and B and (±)-5-epi-nankakurine A. The Journal of Organic Chemistry. 75: 7519-34. PMID 20958075 DOI: 10.1021/Jo101619D  1
2010 Cannon JS, Kirsch SF, Overman LE, Sneddon HF. Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters. Journal of the American Chemical Society. 132: 15192-203. PMID 20942424 DOI: 10.1021/Ja106688J  1
2010 Cannon JS, Kirsch SF, Overman LE. Catalytic asymmetric synthesis of chiral allylic esters. Journal of the American Chemical Society. 132: 15185-91. PMID 20942420 DOI: 10.1055/S-2005-869916  1
2010 Overman LE, Rosen MD. Terminating Catalytic Asymmetric Heck Cyclizations by Stereoselective Intramolecular Capture of η-Allylpalladium Intermediates: Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers. Tetrahedron. 66: 6514-6525. PMID 20725641 DOI: 10.1016/J.Tet.2010.05.048  1
2010 Canham SM, France DJ, Overman LE. Total synthesis of (+)-sieboldine A. Journal of the American Chemical Society. 132: 7876-7. PMID 20527933 DOI: 10.1021/Ja103666N  1
2010 Schnermann MJ, Beaudry CM, Egorova AV, Polishchuk RS, Sütterlin C, Overman LE. Golgi-modifying properties of macfarlandin E and the synthesis and evaluation of its 2,7-dioxabicyclo[3.2.1]octan-3-one core. Proceedings of the National Academy of Sciences of the United States of America. 107: 6158-63. PMID 20332207 DOI: 10.1073/Pnas.1001421107  1
2010 Martin CL, Overman LE, Rohde JM. Total synthesis of (+/-)- and (-)-actinophyllic acid. Journal of the American Chemical Society. 132: 4894-906. PMID 20218696 DOI: 10.1021/Ja100178U  1
2010 Ito T, Overman LE, Wang J. Enantioselective synthesis of angularly substituted 1-azabicyclic ring systems: dynamic kinetic resolution using aza-Cope rearrangements. Journal of the American Chemical Society. 132: 3272-3. PMID 20175519 DOI: 10.1021/Ja100607Z  1
2010 Overman LE, Tanis PS. Origin of stereocontrol in the construction of the 12-oxatricyclo[6.3.1.0(2,7)]dodecane ring system by Prins-pinacol reactions. The Journal of Organic Chemistry. 75: 455-63. PMID 20000652 DOI: 10.1021/Jo9024144  1
2010 Overman LE. Cluster preface: Stereoselective synthesis of stereogenic quaternary carbons: A formidable challenge and remarkable recent progress Synlett. 1692-1693. DOI: 10.1055/S-0030-1258097  1
2010 Overman L, Canham S, France D. Synthesis of (+)-Sieboldine A Synfacts. 2010: 0983-0983. DOI: 10.1055/S-0030-1257929  0.01
2010 Ito T, Overman LE, Wang J. Dynamic Kinetic Resolution via Aza-Cope Rearrangement Synfacts. 2010: 689-689. DOI: 10.1055/S-0029-1219869  1
2010 Olson AC, Overman LE, Sneddon HF, Ziller JW. Enantioselective Allylic Etherification Using a Novel COPCatalyst Synfacts. 2010: 442-442. DOI: 10.1055/S-0029-1219483  1
2010 Corminboeuf O, Overman LE, Pennington LD. Synthesis of Briarellins E and F Synfacts. 2010: 135-135. DOI: 10.1055/S-0029-1219024  1
2010 Canham SM, France DJ, Overman LE. ChemInform Abstract: Total Synthesis of (+)-Sieboldine A. Cheminform. 41. DOI: 10.1002/chin.201042201  0.01
2010 Martin CL, Overman LE, Rohde JM. ChemInform Abstract: Total Synthesis of (.+-.)- and (-)-Actinophyllic Acid. Cheminform. 41: no-no. DOI: 10.1002/chin.201031204  0.01
2010 Ito T, Overman LE, Wang J. ChemInform Abstract: Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Ring Systems: Dynamic Kinetic Resolution Using Aza-Cope Rearrangements. Cheminform. 41: no-no. DOI: 10.1002/chin.201031125  0.01
2010 Olson AC, Overman LE, Sneddon HF, Ziller JW. ChemInform Abstract: Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols. Cheminform. 41. DOI: 10.1002/chin.201018073  0.01
2010 Gahman TC, Overman LE. ChemInform Abstract: Stereoselective Synthesis of Carbocyclic Ring Systems by Pinacol-Terminated Prins Cyclizations. Cheminform. 33: no-no. DOI: 10.1002/chin.200250061  0.01
2010 Overman LE, Remarchuk TP. ChemInform Abstract: Catalytic Asymmetric Intramolecular Aminopalladation: Enantioselective Synthesis of Vinyl-Substituted 2-Oxazolidinones, 2-Imidazolidinones, and 2-Pyrrolidinones. Cheminform. 33: no-no. DOI: 10.1002/chin.200224035  0.01
2010 Kamenecka TM, Overman LE, Ly Sakata SK. ChemInform Abstract: Construction of Substituted Cyclohexanones by Reductive Cyclization of 7-Oxo-2,8-alkadienyl Esters. Cheminform. 33: no-no. DOI: 10.1002/chin.200222082  0.08
2010 Govek SP, Overman LE. ChemInform Abstract: Total Synthesis of Asperazine. Cheminform. 33: no-no. DOI: 10.1002/chin.200204218  0.01
2010 Overman LE, Paone DV. ChemInform Abstract: Enantioselective Total Syntheses of Ditryptophenaline and ent-WIN 64821. Cheminform. 33: no-no. DOI: 10.1002/chin.200204217  0.01
2010 MacMillan DWC, Overman LE, Pennington LD. ChemInform Abstract: A General Strategy for the Synthesis of Cladiellin Diterpenes: Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (Deacetoxyalcyonin Acetate) (I), Cladiell-11-ene-3,6,7-triol (II), Sclerophytin A (III), and the I Cheminform. 33: no-no. DOI: 10.1002/chin.200204186  0.01
2010 O'Connor SJ, Overman LE, Rucker PV. ChemInform Abstract: Use of Sequential Intramolecular Heck Cyclizations for Preparing Bicyclo[3.2.1]octane Fragments of Tetracyclic Stemodane and Stemarane Diterpenes. Cheminform. 32: no-no. DOI: 10.1002/chin.200142213  0.01
2010 Lebsack AD, Overman LE, Valentekovich RJ. ChemInform Abstract: Enantioselective Total Synthesis of Shahamin K. Cheminform. 32: no-no. DOI: 10.1002/chin.200137182  0.01
2010 Overman LE, Wolfe JP. ChemInform Abstract: Synthesis of Polycyclic Guanidines by Cyclocondensation Reactions of N-Amidinyliminium Ions. Cheminform. 32: no-no. DOI: 10.1002/chin.200137152  0.01
2010 Cohen F, MacMillan DWC, Overman LE, Romero A. ChemInform Abstract: Stereoselection in the Prins-Pinacol Synthesis of Acyltetrahydrofurans. Cheminform. 32: no-no. DOI: 10.1002/chin.200133121  0.01
2010 Kamatani A, Overman LE. ChemInform Abstract: A New Asymmetric Synthesis of trans-Hydroisoquinolones. Cheminform. 32: no-no. DOI: 10.1002/chin.200131146  0.01
2010 Donde Y, Overman LE. ChemInform Abstract: Asymmetric Intramolecular Heck Reactions Cheminform. 32: no-no. DOI: 10.1002/chin.200129263  0.01
2010 Hanaki N, Link JT, MacMillian DWC, Overman LE, Trankle WG, Wurster JA. ChemInform Abstract: Stereoselection in the Prins-Pinacol Synthesis of 2,2-Disubstituted 4-Acyltetrahydrofurans. Enantioselective Synthesis of (-)-Citreoviral (XII). Cheminform. 31: no-no. DOI: 10.1002/chin.200016259  0.01
2010 Bogenstaetter M, Limberg A, Overman LE, Tomasi AL. ChemInform Abstract: Enantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1. Cheminform. 31: no-no. DOI: 10.1002/chin.200013150  0.01
2010 Kamatani A, Overman LE. ChemInform Abstract: A Suzuki Coupling Method for Directly Introducing a Protected β-Aminoethyl Group into Arenes and Alkenes. Convenient Synthesis of Phenethyl and Homoallylic Amines. Cheminform. 31: no-no. DOI: 10.1002/chin.200012089  0.01
2010 Coffey DS, McDonald AI, Overman LE. ChemInform Abstract: Preparation of (3S)-N,N-1,7-Bis-tert-butoxycarbonyl-3-hydroxyspermidine in High Enantiomeric Purity. Cheminform. 31: no-no. DOI: 10.1002/chin.200011221  0.01
2010 Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. ChemInform Abstract: Total Synthesis of (.+-.)-Gelsemine. Cheminform. 31: no-no. DOI: 10.1002/chin.200003222  0.01
2010 Overman LE, Paone DV, Stearns BA. ChemInform Abstract: Direct Stereo- and Enantiocontrolled Synthesis of Vicinal Stereogenic Quaternary Carbon Centers. Total Syntheses of meso- and (-)-Chimonanthine and (+)-Calycanthine. Cheminform. 30: no-no. DOI: 10.1002/chin.199952217  0.01
2010 Coffey DS, McDonald AI, Overman LE, Stappenbeck F. ChemInform Abstract: Enantioselective Total Synthesis of 13,14,15-Isocrambescidin 800 (I). Cheminform. 30: no-no. DOI: 10.1002/chin.199950216  0.01
2010 Fox ME, Li C, Marino Jr. JP, Overman LE. ChemInform Abstract: Enantiodivergent Total Syntheses of (+)- and (-)-Scopadulcic Acid A. Cheminform. 30: no-no. DOI: 10.1002/chin.199939161  0.01
2010 McDonald AI, Overman LE. ChemInform Abstract: Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis- or trans-1-Oxo- and 1-Iminohexahydropyrrolo[1,2-c]pyrimidines. Cheminform. 30: no-no. DOI: 10.1002/chin.199933173  0.01
2010 Hollis TK, Overman LE. ChemInform Abstract: Palladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides Cheminform. 30: no-no. DOI: 10.1002/chin.199932290  0.01
2010 Donde Y, Overman LE. ChemInform Abstract: High Enantioselection in the Rearrangement of Allylic Imidates with Ferrocenyl Oxazoline Catalysts. Cheminform. 30: no-no. DOI: 10.1002/chin.199931030  0.01
2010 Franklin AS, Ly SK, Mackin GH, Overman LE, Shaka AJ. ChemInform Abstract: Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B. Cheminform. 30: no-no. DOI: 10.1002/chin.199929206  0.01
2010 Cloninger MJ, Overman LE. ChemInform Abstract: Stereocontrolled Synthesis of Trisubstituted Tetrahydropyrans. Cheminform. 30: no-no. DOI: 10.1002/chin.199928167  0.01
2010 Brosius AD, Overman LE, Schwink L. ChemInform Abstract: Total Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels-Alder Reaction. Cheminform. 30: no-no. DOI: 10.1002/chin.199926233  0.01
2010 Downham R, Ng FW, Overman LE. ChemInform Abstract: Asymmetric Construction of the Diazatricyclic Core of the Marine Alkaloids Sarains A-C. Cheminform. 30: no-no. DOI: 10.1002/chin.199914250  0.01
2010 Cohen F, Overman LE. ChemInform Abstract: Planar-Chiral Cyclopalladated Ferrocenyl Amines and Imines as Enantioselective Catalysts for Allylic Imidate Rearrangements. Cheminform. 30: no-no. DOI: 10.1002/chin.199910096  0.01
2010 ASHIMORI A, BACHAND B, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-α,β-Unsaturated 2-Haloanilides and Analogues to Form Enantioenriched Spirocyclic Products. Cheminform. 29: no-no. DOI: 10.1002/chin.199846130  0.01
2010 ASHIMORI A, BACHAND B, CALTER MA, GOVEK SP, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-α,β-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Inter Cheminform. 29: no-no. DOI: 10.1002/chin.199845139  0.01
2010 LINK JT, OVERMAN LE. ChemInform Abstract: Forming Cyclics with the Intramolecular Heck Reaction Cheminform. 29: no-no. DOI: 10.1002/chin.199839310  0.01
2010 HYNES JJ, OVERMAN LE, NASSER T, RUCKER PV. ChemInform Abstract: Intramolecular Heck Cyclization of α-Sulfenyl Enol Triflates. Asymmetric Synthesis of a Pentacyclic Cardenolide Precursor Having Functionality at C-11. Cheminform. 29: no-no. DOI: 10.1002/chin.199838229  0.01
2010 OVERMAN LE, RUCKER PV. ChemInform Abstract: Enantioselective Synthesis of Cardenolide Precursors Using an Intramolecular Heck Reaction. Cheminform. 29: no-no. DOI: 10.1002/chin.199838228  0.01
2010 ANDO K, CONDROSKI KR, HOUK KN, WU Y, LY SK, OVERMAN LE. ChemInform Abstract: Stereoselectivities of Nucleophilic Additions to Cycloheptanones. Experimental and Theoretical Studies and General Purpose Force Field for the Prediction of Nucleophilic Addition Stereoselectivities. Cheminform. 29: no-no. DOI: 10.1002/chin.199836124  0.01
2010 OVERMAN LE, TOMASI AL. ChemInform Abstract: Enantioselective Total Synthesis of Hispidospermidin. Cheminform. 29: no-no. DOI: 10.1002/chin.199833260  0.01
2010 OVERMAN LE, RICCA DJ, TRAN VD. ChemInform Abstract: Total Synthesis of (.+-.)-Scopadulcic Acid B. Cheminform. 29: no-no. DOI: 10.1002/chin.199817203  0.01
2010 ABELMAN MM, KADO N, OVERMAN LE, SARKAR AK. ChemInform Abstract: Synthesis of a Phenolic Analogue of Aphidicolin. Diminished Stereoselection in Intramolecular 6-Exo Heck Reactions of Substrates Having a Hydrocarbon Tether. Cheminform. 29: no-no. DOI: 10.1002/chin.199814094  0.01
2010 HOLLIS TK, OVERMAN LE. ChemInform Abstract: Cyclopalladated Ferrocenyl Amines as Enantioselective Catalysts for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 29: no-no. DOI: 10.1002/chin.199811042  0.01
2010 JOE D, OVERMAN LE. ChemInform Abstract: An Unexpected Product Arising from Metal Alkylidene Mediated Ring-Closing Diene Metathesis. Cheminform. 29: no-no. DOI: 10.1002/chin.199809186  0.01
2010 ANDO S, MINOR KP, OVERMAN LE. ChemInform Abstract: Ring-Enlarging Cyclohexane Annulations. Cheminform. 29: no-no. DOI: 10.1002/chin.199803051  0.01
2010 OVERMAN LE, ROGERS BN, TELLEW JE, TRENKLE WC. ChemInform Abstract: Stereocontrolled Synthesis of the Tetracyclic Core of the Bisguanidine Alkaloids Palau′amine and Styloguanidine. Cheminform. 28: no-no. DOI: 10.1002/chin.199748259  0.01
2010 OVERMAN LE, ZIPP GG. ChemInform Abstract: Allylic Transposition of Alcohol and Amine Functionality by Thermal or Palladium(II)-Catalyzed Rearrangements of Allylic N- Benzoylbenzimidates. Cheminform. 28: no-no. DOI: 10.1002/chin.199735096  0.01
2010 CALTER M, HOLLIS TK, OVERMAN LE, ZILLER J, ZIPP GG. ChemInform Abstract: First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 28: no-no. DOI: 10.1002/chin.199728055  0.01
2010 BERGER D, OVERMAN LE, RENHOWE PA. ChemInform Abstract: Total Synthesis of (+)-Isolaurepinnacin. Use of Acetal-Alkene Cyclizations to Prepare Highly Functionalized Seven-Membered Cyclic Ethers. Cheminform. 28: no-no. DOI: 10.1002/chin.199725184  0.01
2010 BROSIUS AD, OVERMAN LE. ChemInform Abstract: Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration. Cheminform. 28: no-no. DOI: 10.1002/chin.199723249  0.01
2010 OVERMAN LE, POON DJ. ChemInform Abstract: Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights. Cheminform. 28: no-no. DOI: 10.1002/chin.199723143  0.01
2010 OVERMAN LE, TELLEW JE. ChemInform Abstract: Synthesis of 2-Azatricyclo(5.2.1.04,10)decanes and 2,5-Diazatricyclo(5. 2.1.04,10)decanes by Intramolecular Azomethine Ylide Cycloadditions. Cheminform. 28: no-no. DOI: 10.1002/chin.199716153  0.01
2010 DENG W, JENSEN MS, OVERMAN LE, RUCKER PV, VIONNET J. ChemInform Abstract: A Strategy for Total Synthesis of Complex Cardenolides. Cheminform. 28: no-no. DOI: 10.1002/chin.199705222  0.01
2010 CADERAS C, LETT R, OVERMAN LE, RABINOWITZ MH, ROBINSON LA, SHARP MJ, ZABLOCKI J. ChemInform Abstract: Enantioselective Total Syntheses of Allopumiliotoxins 267A, 323B′, and 339A. Application of Iodide-Promoted Iminium Ion-Alkyne Cyclizations for Forming Allopumiliotoxin A Alkaloids. Cheminform. 28: no-no. DOI: 10.1002/chin.199703269  0.01
2010 MURATA Y, WOODWARD RM, MILEDI R, OVERMAN LE. ChemInform Abstract: The First Selective Antagonist for a GABAC Receptor. Cheminform. 27: no-no. DOI: 10.1002/chin.199652202  0.01
2010 LINK JT, OVERMAN LE. ChemInform Abstract: Stereocontrolled Total Syntheses of meso-Chimonanthine (I) and meso- Calycanthine (II) via a Novel Samarium Mediated Reductive Dialkylation. Cheminform. 27: no-no. DOI: 10.1002/chin.199651194  0.01
2010 MACMILLAN DWC, OVERMAN LE. ChemInform Abstract: Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene. Cheminform. 27: no-no. DOI: 10.1002/chin.199608204  0.01
2010 BRATZ M, BULLOCK WH, OVERMAN LE, TAKEMOTO T. ChemInform Abstract: Total Synthesis of (+)-Laurencin. Use of Acetal-Vinyl Sulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers. Cheminform. 26: no-no. DOI: 10.1002/chin.199539259  0.01
2010 KNIGHT SD, OVERMAN LE, PAIRAUDEAU G. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 28. Asymmetric Total Syntheses of (-)- and (+)-Strychnine (IX) and the Wieland-Gumlich Aldehyde (VII). Cheminform. 26: no-no. DOI: 10.1002/chin.199538266  0.01
2010 OVERMAN LE, RABINOWITZ MH, RENHOWE PA. ChemInform Abstract: Enantioselective Total Synthesis of (-)-Ptilomycalin A. Cheminform. 26: no-no. DOI: 10.1002/chin.199531218  0.01
2010 KNIGHT SD, OVERMAN LE. ChemInform Abstract: Preparation of Spirocyclic Polyethers by Intramolecular Heck Reactions. Cheminform. 26: no-no. DOI: 10.1002/chin.199526146  0.01
2010 OVERMAN LE, RENHOWE PA. ChemInform Abstract: Regioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl) allyl Organometallic Reagents. Cheminform. 26: no-no. DOI: 10.1002/chin.199504070  0.01
2010 KAMENECKA TM, OVERMAN LE. ChemInform Abstract: An Enantioselective Approach to the Synthesis of Manzamine A. Cheminform. 25: no-no. DOI: 10.1002/chin.199445217  0.2
2010 HONG CY, OVERMAN LE. ChemInform Abstract: Preparation of Opium Alkaloids by Palladium-Catalyzed Bis-Cyclizations. Formal Total Synthesis of Morphine. Cheminform. 25: no-no. DOI: 10.1002/chin.199442242  0.16
2010 OVERMAN LE. ChemInform Abstract: Application of Intramolecular Heck Reactions for Forming Congested Quaternary Carbon Centers in Complex Molecule Total Synthesis Cheminform. 25: no-no. DOI: 10.1002/chin.199441287  0.01
2010 LASCHAT S, NARJES F, OVERMAN LE. ChemInform Abstract: Application of Intramolecular Heck Reactions to the Preparation of Steroid and Terpene Intermediates Having cis A-B Ring Fusions. Model Studies for the Total Synthesis of Complex Cardenolides. Cheminform. 25: no-no. DOI: 10.1002/chin.199419059  0.01
2010 HEERDING DA, HONG CY, KADO N, LOOK GC, OVERMAN LE. ChemInform Abstract: Simple Method for Controlling Stereoselection in Mannich Cyclization Reactions of Aldehydes. Cheminform. 25: no-no. DOI: 10.1002/chin.199416181  0.08
2010 ASHIMORI A, MATSUURA T, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Either Enantiomer of Physostigmine. Formation of Quaternary Carbon Centers with High Enantioselection by Intramolecular Heck Reactions of (Z)-2-Butenanilides. Cheminform. 25: no-no. DOI: 10.1002/chin.199416046  0.01
2010 HONG CY, KADO N, OVERMAN LE. ChemInform Abstract: Asymmetric Synthesis of Either Enantiomer of Opium Alkaloids and Morphinans. Total Synthesis of (-)- and (+)-Dihydrocodeinone and (-)- and (+)-Morphine. Cheminform. 25: no-no. DOI: 10.1002/chin.199409257  0.04
2010 MONTGOMERY J, OVERMAN LE. ChemInform Abstract: Introduction of the 2-(Phenylthio)ethyl, 2-(Phenylsulfinyl)ethyl, and 2,2-Bis(phenylthio)ethyl Substituents into Cyclic Ketones. Cheminform. 25: no-no. DOI: 10.1002/chin.199409098  0.01
2010 KUCERA DJ, O'CONNOR SJ, OVERMAN LE. ChemInform Abstract: Total Synthesis of (.+-.)-Scopadulcic Acid A. An Illustration of the Utility of Palladium-Catalyzed Polyene Cyclizations. Cheminform. 25: no-no. DOI: 10.1002/chin.199406209  0.01
2010 KNIGHT SD, OVERMAN LE, PAIRAUDEAU G. ChemInform Abstract: Applications of Cationic Aza-Cope Rearrangements. Part 26. Enantioselective Total Synthesis of (-)-Strychnine. Cheminform. 25: no-no. DOI: 10.1002/chin.199404253  0.01
2010 BERGER D, OVERMAN LE, RENHOWE PA. ChemInform Abstract: Enantioselective Total Synthesis of (+)-Isolaurepinnacin. Cheminform. 25: no-no. DOI: 10.1002/chin.199403229  0.01
2010 CASTRO P, OVERMAN LE, ZHANG X, MARIANO PS. ChemInform Abstract: Preparation of Enantioenriched Tetrahydropyridines by Iminium Ion- Vinylsilane Cyclizations. Cheminform. 24: no-no. DOI: 10.1002/chin.199352192  0.01
2010 OVERMAN LE, SHIM J. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 25. Total Synthesis of Amaryllidaceae Alkaloids of the 5,11- Methanomorphanthridine Type. Efficient Total Synthesis of (-)- Pancracine (-)-(I) and (.+-.)-Pancracine. Cheminform. 24: no-no. DOI: 10.1002/chin.199351268  0.01
2010 OVERMAN LE, RODRIGUEZ-CAMPOS IM. ChemInform Abstract: Preparation of Unsaturated Seven- and Eight-Membered Nitrogen Heterocycles by Iodide-Promoted Alkyne-Iminium Ion Cyclization. Cheminform. 24: no-no. DOI: 10.1002/chin.199342207  0.01
2010 OVERMAN LE, RABINOWITZ MH. ChemInform Abstract: Studies Toward the Total Synthesis of (+)-Ptilomycalin A. Use of a Tethered Biginelli Condensation for the Preparation of an Advanced Tricyclic Intermediate. Cheminform. 24: no-no. DOI: 10.1002/chin.199339285  0.01
2010 HIRST GC, JOHNSON TOJ, OVERMAN LE. ChemInform Abstract: First Total Synthesis of Lycopodium Alkaloids of the Magellanane Group. Enantioselective Total Syntheses of (-)-Magellanine and (+)- Magellaninone. Cheminform. 24: no-no. DOI: 10.1002/chin.199335295  0.01
2010 OVERMAN LE, RICCA DJ, TRAN VD. ChemInform Abstract: First Total Synthesis of Scopadulcic Acid B. Cheminform. 24: no-no. DOI: 10.1002/chin.199330248  0.01
2010 BURK RM, OVERMAN LE. ChemInform Abstract: Total Synthesis of the Amaryllidaceae Alkaloid (.+-.)-Epielwesine. The Importance of Vinylsilane Stereochemistry in Iminium Ion-Vinylsilane Cyclizations. Cheminform. 24: no-no. DOI: 10.1002/chin.199328278  0.01
2010 BERGER D, OVERMAN LE. ChemInform Abstract: Preparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal - Alkene Cyclizations. Cheminform. 24: no-no. DOI: 10.1002/chin.199322213  0.01
2010 OVERMAN LE, ABELMAN MM, KUCERA DJ, TRAN VD, RICCA DJ. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations Cheminform. 24: no-no. DOI: 10.1002/chin.199311323  0.01
2010 OVERMAN LE, SARKAR AK. ChemInform Abstract: Iodide-Promoted Aldiminium Ion-Alkyne Cyclizations. A Convenient Synthesis of Substituted Tetrahydropyridines and 3- Alkylidenepiperidines. Cheminform. 24: no-no. DOI: 10.1002/chin.199302196  0.01
2010 ASHIMORI A, OVERMAN LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quarternary Carbon Centers. Palladium-Catalyzed Formation of Either Enantiomer of Spirooxindoles and Related Spirocyclics Using a Single Enantiomer of a Chiral Diphosphine Ligand. Cheminform. 24: no-no. DOI: 10.1002/chin.199302176  0.01
2010 MADIN A, OVERMAN LE. ChemInform Abstract: Controlling Stereoselection in Intramolecular Heck Reactions by Tailoring the Palladium Catalyst. Cheminform. 24: no-no. DOI: 10.1002/chin.199301094  0.01
2010 OVERMAN LE. ChemInform Abstract: Charge as a Key Component in Reaction Design. The Invention of Cationic Cyclization Reactions of Importance in Synthesis Cheminform. 23: no-no. DOI: 10.1002/chin.199247305  0.01
2010 FLANN CJ, OVERMAN LE, SARKAR AK. ChemInform Abstract: Synthesis of 3-Acyl-3-alkyloxindoles. Cheminform. 23: no-no. DOI: 10.1002/chin.199230144  0.01
2010 OVERMAN LE, SHIM J. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangement. Part 24. First Total Synthesis of Amaryllidaceae Alkaloids of the 5,11- Methanomorphanthridine Type. An Efficient Total Synthesis of (.+-.)- Pancracine (I). Cheminform. 23: no-no. DOI: 10.1002/chin.199203253  0.01
2010 BROWN MJ, HARRISON T, OVERMAN LE. ChemInform Abstract: General Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. Total Synthesis of (.+-.)-trans- Kumausyne and Demonstration of an Asymmetric Synthesis Strategy. Cheminform. 22: no-no. DOI: 10.1002/chin.199142159  0.01
2010 BROWN MJ, HARRISON T, HERRINTON PM, HOPKINS MH, HUTCHINSON KD, MISHRA P, OVERMAN LE. ChemInform Abstract: Acid-Promoted Reaction of Cyclic Allylic Diols with Carbonyl Compounds. Stereoselective Ring-Enlarging Tetrahydrofuran Annulations. Cheminform. 22: no-no. DOI: 10.1002/chin.199142158  0.01
2010 HOPKINS MH, OVERMAN LE, RISHTON GM. ChemInform Abstract: Stereocontrolled Preparation of Tetrahydrofurans from Acid-Promoted Rearrangements of Allylic Acetals. Cheminform. 22: no-no. DOI: 10.1002/chin.199142157  0.01
2010 BROWN MJ, OVERMAN LE. ChemInform Abstract: Preparation of 3-Amino-4-(hydroxymethyl)azetidin-2-ones from the Reaction of Glycine Enolates with Imines of a Glycoaldehyde. Cheminform. 22: no-no. DOI: 10.1002/chin.199130155  0.01
2009 Olson AC, Overman LE, Sneddon HF, Ziller JW. Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols. Advanced Synthesis & Catalysis. 351: 3186-3192. PMID 23795152 DOI: 10.1002/Adsc.200900678  1
2009 Overman LE. Molecular Rearrangements in the Construction of Complex Molecules. Tetrahedron. 65: 6432-6446. PMID 20640042 DOI: 10.1016/J.Tet.2009.05.067  1
2009 Dunn TB, Ellis JM, Kofink CC, Manning JR, Overman LE. Asymmetric construction of rings A-D of daphnicyclidin-type alkaloids. Organic Letters. 11: 5658-61. PMID 19904991 DOI: 10.1021/Ol902373M  1
2009 Corminboeuf O, Overman LE, Pennington LD. A unified strategy for enantioselective total synthesis of cladiellin and briarellin diterpenes: total synthesis of briarellins E and F and the putative structure of alcyonin and revision of its structure assignment. The Journal of Organic Chemistry. 74: 5458-70. PMID 19534538 DOI: 10.1021/Jo9010156  1
2009 Taniguchi T, Martin CL, Monde K, Nakanishi K, Berova N, Overman LE. Absolute configuration of actinophyllic acid as determined through chiroptical data. Journal of Natural Products. 72: 430-2. PMID 19220031 DOI: 10.1021/Np800665S  1
2009 Overman L, Nilsson B, de Alaniz J, Rohde J. Synthesis of Nankakurines A and B Synfacts. 2009: 0246-0246. DOI: 10.1055/S-0028-1087692  0.01
2009 Ellis JM, Overman LE, Tanner HR, Wang J. ChemInform Abstract: A Versatile Synthesis of Unsymmetrical 3,3′-Bioxindoles: Stereoselective Mukaiyama Aldol Reactions of 2-Siloxyindoles with Isatins. Cheminform. 40. DOI: 10.1002/chin.200915115  0.04
2009 Dounay AB, Overman LE. The Asymmetric Intramolecular Mizoroki-Heck Reaction in Natural Product Total Synthesis The Mizoroki-Heck Reaction. 533-568. DOI: 10.1002/9780470716076.ch16  1
2008 Ellis JM, Overman LE, Tanner HR, Wang J. A versatile synthesis of unsymmetrical 3,3'-bioxindoles: stereoselective Mukaiyama aldol reactions of 2-siloxyindoles with isatins. The Journal of Organic Chemistry. 73: 9151-4. PMID 18855482 DOI: 10.1021/Jo801867W  1
2008 Nilsson BL, Overman LE, Read de Alaniz J, Rohde JM. Enantioselective total syntheses of nankakurines A and B: confirmation of structure and establishment of absolute configuration. Journal of the American Chemical Society. 130: 11297-9. PMID 18680252 DOI: 10.1021/Ja804624U  1
2008 Martin CL, Overman LE, Rohde JM. Total synthesis of (+/-)-actinophyllic acid. Journal of the American Chemical Society. 130: 7568-9. PMID 18491907 DOI: 10.1021/Ja803158Y  1
2008 Overman LE, Roberts SW, Sneddon HF. Catalytic asymmetric synthesis of allylic thiol derivatives. Organic Letters. 10: 1485-8. PMID 18336036 DOI: 10.1021/Ol8002942  1
2008 Dounay AB, Humphreys PG, Overman LE, Wrobleski AD. Total synthesis of the strychnos alkaloid (+)-minfiensine: tandem enantioselective intramolecular Heck-iminium ion cyclization. Journal of the American Chemical Society. 130: 5368-77. PMID 18303837 DOI: 10.1021/Ja800163V  1
2008 Overman LE, Roberts SW, Sneddon HF. Palladium-Catalyzed Enantioselective Synthesis of Allylic Thiol Derivatives Synfacts. 2008: 612-612. DOI: 10.1055/S-2008-1072626  1
2008 Martin CL, Overman LE, Rohde JM. Synthesis of (±)-Actinophyllic Acid Synfacts. 2010: 862-862. DOI: 10.1055/S-0030-1257764  1
2008 Overman L, Dounay A, Humphreys P, Wrobleski A. Synthesis of (+)-Minfiensine Synfacts. 2008: 1128-1128. DOI: 10.1055/S-0028-1083414  0.01
2008 Martin CL, Overman LE, Rohde JM. ChemInform Abstract: Total Synthesis of (.+-.)-Actinophyllic Acid. Cheminform. 39. DOI: 10.1002/chin.200842198  0.01
2008 Dounay AB, Humphreys PG, Overman LE, Wrobleski AD. ChemInform Abstract: Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck-Iminium Ion Cyclization. Cheminform. 39. DOI: 10.1002/chin.200835188  0.01
2008 Overman LE, Roberts SW, Sneddon HF. ChemInform Abstract: Catalytic Asymmetric Synthesis of Allylic Thiol Derivatives. Cheminform. 39. DOI: 10.1002/chin.200832058  0.01
2008 Overman LE, Sato T. ChemInform Abstract: Construction of Epidithiodioxopiperazines by Directed Oxidation of Hydroxyproline-Derived Dioxopiperazines. Cheminform. 39. DOI: 10.1002/chin.200819159  0.01
2008 Kodanko JJ, Hiebert S, Peterson EA, Sung L, Overman LE, de Moura Linck V, Goerck GC, Amador TA, Leal MB, Elisabetsky E. ChemInform Abstract: Synthesis of All Low-Energy Stereoisomers of the Tris(pyrrolidinoindoline) Alkaloid Hodgkinsine and Preliminary Assessment of Their Antinociceptive Activity. Cheminform. 39. DOI: 10.1002/chin.200807176  0.01
2008 Overman LE, et al. ea. ChemInform Abstract: Total Synthesis of (-)-Sarain A. Cheminform. 39. DOI: 10.1002/chin.200806191  0.01
2007 Overman LE, Sato T. Construction of epidithiodioxopiperazines by directed oxidation of hydroxyproline-derived dioxopiperazines. Organic Letters. 9: 5267-70. PMID 18001051 DOI: 10.1021/Ol702518T  1
2007 Lanman BA, Overman LE, Paulini R, White NS. On the structure of palau'amine: evidence for the revised relative configuration from chemical synthesis. Journal of the American Chemical Society. 129: 12896-900. PMID 17902668 DOI: 10.1021/Ja074939X  1
2007 Kodanko JJ, Hiebert S, Peterson EA, Sung L, Overman LE, de Moura Linck V, Goerck GC, Amador TA, Leal MB, Elisabetsky E. Synthesis of all low-energy stereoisomers of the tris(pyrrolidinoindoline) alkaloid hodgkinsine and preliminary assessment of their antinociceptive activity. The Journal of Organic Chemistry. 72: 7909-14. PMID 17887704 DOI: 10.1021/Jo7013643  1
2007 Becker MH, Chua P, Downham R, Douglas CJ, Garg NK, Hiebert S, Jaroch S, Matsuoka RT, Middleton JA, Ng FW, Overman LE. Total synthesis of (-)-sarain A. Journal of the American Chemical Society. 129: 11987-2002. PMID 17850086 DOI: 10.1021/Ja074300T  1
2007 Steven A, Overman LE. Total synthesis of complex cyclotryptamine alkaloids: stereocontrolled construction of quaternary carbon stereocenters. Angewandte Chemie (International Ed. in English). 46: 5488-508. PMID 17591737 DOI: 10.1002/Anie.200700612  1
2007 Watson MP, Overman LE, Bergman RG. Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. Journal of the American Chemical Society. 129: 5031-44. PMID 17402733 DOI: 10.1021/Ja0676962  1
2007 Kirsch SF, Overman LE, White NS. Catalytic asymmetric synthesis of allylic aryl ethers. Organic Letters. 9: 911-3. PMID 17274626 DOI: 10.1021/Ol070110B  1
2007 Overman LE, Shin Y. Enantioselective total synthesis of (+)-gliocladin C. Organic Letters. 9: 339-41. PMID 17217299 DOI: 10.1021/Ol062801Y  1
2007 Govek SP, Overman LE. Synthesis of (+)-Asperazine Synfacts. 2007: 1115-1115. DOI: 10.1055/S-2007-991212  1
2007 Overman LE, Shin Y. Synthesis of (+)-Gliocladin C Synfacts. 2007: 576-576. DOI: 10.1055/S-2007-968511  1
2007 Overman L, Iimura S, Paulini R, Zakarian A. Synthesis of Guanacastepene N Synfacts. 2007: 0242-0242. DOI: 10.1055/S-2007-968196  0.01
2007 Govek SP, Overman LE. Total synthesis of (+)-asperazine Tetrahedron. 63: 8499-8513. DOI: 10.1016/J.Tet.2007.05.127  1
2007 Steven A, Overman L. Totalsynthese komplexer Cyclotryptaminalkaloide: stereokontrollierter Aufbau quartärer Kohlenstoffstereozentren Angewandte Chemie. 119: 5584-5605. DOI: 10.1002/Ange.200700612  0.01
2007 Anderson CE, Kirsch SF, Overman LE, Richards CJ, Watson MP. Preparation of the cop catalysts: [(S)-COP-OAc]2, [(S)-COP-Cl]2, and (S)-COP-hfacac Organic Syntheses. 84: 148-155. DOI: 10.1002/0471264229.Os084.15  1
2007 Anderson CE, Overman LE, Richards CJ, Watson MP, White N. Preparation of (η5‐(S)‐2‐(4‐Methylethyl)‐Oxazolinylcyclopentadienyl)‐(η4‐Tetraphenylcyclo‐Butadiene)cobalt Organic Syntheses. 139-147. DOI: 10.1002/0471264229.Os084.14  1
2007 Anderson CE, Overman LE, Richards CJ, Watson MP, White N. Preparation of (η5-(S)-2-(4-methylethyl)- oxazolinylcyclopentadienyl)-(η4-tetraphenylcyclo-butadiene) cobalt (cobalt, [1,1′,1″,1‴-(η4-1,3- cyclobutadiene-1,2,3,4-tetrayl)tetrakis [benzene]] [(1,2,3,4,5-η)-1-[(4S)-4, 5-dihydro-4-(1-methylethyl)-2-oxazolyl]-2,4-cyclopentadien-1-yl]) Organic Syntheses. 84: 139-147.  1
2006 Lanman BA, Overman LE. EVALUATION OF STRATEGIES FOR THE SYNTHESIS OF THE GUANIDINE HEMIAMINAL PORTION OF PALAU'AMINE. Heterocycles. 70: 557-570. PMID 19079749 DOI: 10.3987/Com-06-S(W)16  1
2006 Gergely J, Morgan JB, Overman LE. Stereocontrolled synthesis of functionalized cis-cyclopentapyrazolidines by 1,3-dipolar cycloaddition reactions of azomethine imines. The Journal of Organic Chemistry. 71: 9144-52. PMID 17109540 DOI: 10.1021/Jo061537J  1
2006 Iimura S, Overman LE, Paulini R, Zakarian A. Enantioselective total synthesis of guanacastepene N using an uncommon 7-endo Heck cyclization as a pivotal step. Journal of the American Chemical Society. 128: 13095-101. PMID 17017789 DOI: 10.1021/Ja0650504  1
2006 Nilsson BL, Overman LE. Concise synthesis of guanidine-containing heterocycles using the Biginelli reaction. The Journal of Organic Chemistry. 71: 7706-14. PMID 16995677 DOI: 10.1021/Jo061199M  1
2006 Garg NK, Hiebert S, Overman LE. Total synthesis of (-)-sarain A. Angewandte Chemie (International Ed. in English). 45: 2912-5. PMID 16566053 DOI: 10.1002/Anie.200600417  1
2006 Overman LE, Watson DA. Diastereoselection in the formation of contiguous quaternary carbon stereocenters by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2600-8. PMID 16555810 DOI: 10.1021/Jo0523363  1
2006 Overman LE, Watson DA. Diastereoselection in the formation of spirocyclic oxindoles by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2587-99. PMID 16555809 DOI: 10.1021/Jo052335A  1
2006 Cohen F, Overman LE. Enantioselective total synthesis of batzelladine F and definition of its structure. Journal of the American Chemical Society. 128: 2604-8. PMID 16492044 DOI: 10.1021/Ja057433S  1
2006 Cohen F, Overman LE. Evolution of a strategy for the synthesis of structurally complex batzelladine alkaloids. Enantioselective total synthesis of the proposed structure of batzelladine F and structural revision. Journal of the American Chemical Society. 128: 2594-603. PMID 16492043 DOI: 10.1021/Ja0574320  1
2006 Overman LE, Velthuisen EJ. Scope and facial selectivity of the Prins-pinacol synthesis of attached rings. The Journal of Organic Chemistry. 71: 1581-7. PMID 16468809 DOI: 10.1021/Jo0522862  1
2006 Overman LE, Peterson EA. Synthesis of dihydroquinolinones angularly-fused to tetrahydrobenzazepinone rings Heterocycles. 67: 585-588. DOI: 10.3987/Com-05-S(T)76  1
2006 Overman L, Garg N, Hiebert S. Synthesis of (-)-Sarain A Synfacts. 2006: 1089-1089. DOI: 10.1055/S-2006-949386  0.01
2006 Overman L, Cohen F. Synthesis of Batzelladine F Synfacts. 2006: 0646-0646. DOI: 10.1055/S-2006-941835  0.01
2006 Overman L, Earley W, Jacobsen J, Madin A, Meier G, O’Donnell C, Oh T, Old D, Sharp M. Synthesis of (±)-Gelsemine Synfacts. 2006: 0534-0534. DOI: 10.1055/S-2006-934487  0.01
2006 Overman LE, Carpenter NE. The Allylic Trihaloacetimidate Rearrangement Cheminform. 37. DOI: 10.1002/0471264180.Or066.01  0.01
2005 Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Use of the intramolecular Heck reaction for forming congested quaternary carbon stereocenters. Stereocontrolled total synthesis of (+/-)-gelsemine. Journal of the American Chemical Society. 127: 18054-65. PMID 16366557 DOI: 10.1021/Ja055711H  1
2005 Earley WG, Jacobsen JE, Madin A, Meier GP, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Aza-cope rearrangement-mannich cyclizations for the formation of complex tricyclic amines: stereocontrolled total synthesis of (+/-)-gelsemine. Journal of the American Chemical Society. 127: 18046-53. PMID 16366556 DOI: 10.1021/Ja055710P  1
2005 Overman LE, Rhee YH. Total synthesis of (-)-crambidine and definition of the relative configuration of its unique tetracyclic guanidinium core. Journal of the American Chemical Society. 127: 15652-8. PMID 16262433 DOI: 10.1021/Ja055464H  1
2005 Dounay AB, Overman LE, Wrobleski AD. Sequential catalytic asymmetric Heck-iminium ion cyclization: enantioselective total synthesis of the Strychnos alkaloid minfiensine. Journal of the American Chemical Society. 127: 10186-7. PMID 16028927 DOI: 10.1021/Ja0533895  1
2005 Adhikari S, Caille S, Hanbauer M, Ngo VX, Overman LE. Asymmetric construction of quaternary carbon stereocenters: high stereoselection in Mukaiyama aldol reactions of 2-siloxyindoles with chiral aldehydes. Organic Letters. 7: 2795-7. PMID 15957949 DOI: 10.1021/Ol051172+  1
2005 Kirsch SF, Overman LE. Catalytic asymmetric intramolecular aminopalladation: improved palladium(II) catalysts. The Journal of Organic Chemistry. 70: 2859-61. PMID 15787588 DOI: 10.1021/Jo047763F  1
2005 Aron ZD, Overman LE. Total synthesis and properties of the crambescidin core zwitterionic acid and crambescidin 359. Journal of the American Chemical Society. 127: 3380-90. PMID 15755156 DOI: 10.1021/Ja042875+  1
2005 Kirsch SF, Overman LE. Catalytic asymmetric synthesis of chiral allylic esters. Journal of the American Chemical Society. 127: 2866-7. PMID 15740118 DOI: 10.1021/Ja0425583  1
2005 Douglas CJ, Hiebert S, Overman LE. Toward an enantioselective total synthesis of sarain A: construction of an advanced intermediate and rearrangement of the sarain A core under mild conditions. Organic Letters. 7: 933-6. PMID 15727478 DOI: 10.1021/Ol050038M  1
2005 Aron ZD, Overman LE. Stereocontrolled synthesis of angularly substituted 1-azabicyclic rings by cationic 2-aza-cope rearrangements. Organic Letters. 7: 913-6. PMID 15727473 DOI: 10.1021/Ol047330Z  1
2005 Anderson CE, Donde Y, Douglas CJ, Overman LE. Catalytic asymmetric synthesis of chiral allylic amines. Evaluation of ferrocenyloxazoline palladacycle catalysts and imidate motifs. The Journal of Organic Chemistry. 70: 648-57. PMID 15651813 DOI: 10.1021/Jo048490R  1
2005 Prasad RS, Anderson CE, Richards CJ, Overman LE. Synthesis of tert-leucine-derived cobalt oxazoline palladacycles. Reversal of palladation diastereoselectivity and application to the asymmetric rearrangement of N-aryl trifluoroacetimidates Organometallics. 24: 77-81. DOI: 10.1021/Om0493614  1
2005 Anderson CE, Overman LE, Watson MP. Asymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (S)‐2,2,2‐Trichloro‐N‐(1‐propylallyl)acetamide Organic Syntheses. 134-139. DOI: 10.1002/0471264229.Os082.21  1
2005 Anderson CE, Overman LE, Watson MP. Asymmetric rearrangement of allylic trichloroacetimidates: Preparation of (S)-2,2,2-trichloro-N-(1-propylallyl)acetamide Organic Syntheses. 82: 134-139.  1
2004 Burke BJ, Overman LE. Enantioselective synthesis of six-membered palladacycles having metal-bound stereogenic carbons: isolation and reactivity of palladacycles containing readily accessible beta-hydrogens. Journal of the American Chemical Society. 126: 16820-33. PMID 15612721 DOI: 10.1021/Ja045047P  1
2004 Kirsch SF, Overman LE, Watson MP. Monomeric cobalt oxazoline palladacycles (COP). Useful catalysts for catalytic asymmetric rearrangement of allylic trichloroacetimidates. The Journal of Organic Chemistry. 69: 8101-4. PMID 15527296 DOI: 10.1021/Jo0487092  1
2004 Huang A, Kodanko JJ, Overman LE. Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (-)-phenserine. Journal of the American Chemical Society. 126: 14043-53. PMID 15506768 DOI: 10.1021/Ja046690E  1
2004 Overman LE, Velthuisen EJ. Stereocontrolled construction of either stereoisomer of 12-oxatricyclo[6.3.1.0(2,7)]dodecanes using Prins-pinacol reactions. Organic Letters. 6: 3853-6. PMID 15469366 DOI: 10.1021/Ol0482745  1
2004 Olszewski A, Sato K, Aron ZD, Cohen F, Harris A, McDougall BR, Robinson WE, Overman LE, Weiss GA. Guanidine alkaloid analogs as inhibitors of HIV-1 Nef interactions with p53, actin, and p56lck. Proceedings of the National Academy of Sciences of the United States of America. 101: 14079-84. PMID 15371598 DOI: 10.1073/Pnas.0406040101  1
2004 Bewley CA, Ray S, Cohen F, Collins SK, Overman LE. Inhibition of HIV-1 envelope-mediated fusion by synthetic batzelladine analogues. Journal of Natural Products. 67: 1319-24. PMID 15332849 DOI: 10.1021/Np049958O  1
2004 Peterson EA, Overman LE. Contiguous stereogenic quaternary carbons: a daunting challenge in natural products synthesis. Proceedings of the National Academy of Sciences of the United States of America. 101: 11943-8. PMID 15232003 DOI: 10.1073/Pnas.0402416101  1
2004 Aron ZD, Pietraszkiewicz H, Overman LE, Valeriote F, Cuevas C. Synthesis and anticancer activity of side chain analogs of the crambescidin alkaloids. Bioorganic & Medicinal Chemistry Letters. 14: 3445-9. PMID 15177450 DOI: 10.1016/J.Bmcl.2004.04.071  1
2004 Collins SK, McDonald AI, Overman LE, Rhee YH. Enantioselective total synthesis of (-)-dehydrobatzelladine C. [structure: see text]. Organic Letters. 6: 1253-5. PMID 15070310 DOI: 10.1021/Ol0498141  1
2004 Aron ZD, Overman LE. The tethered Biginelli condensation in natural product synthesis. Chemical Communications (Cambridge, England). 253-65. PMID 14740029 DOI: 10.1039/B309910E  1
2004 Douglas CJ, Overman LE. Catalytic asymmetric synthesis of all-carbon quaternary stereocenters. Proceedings of the National Academy of Sciences of the United States of America. 101: 5363-7. PMID 14724294 DOI: 10.1073/Pnas.0307113101  0.88
2004 Burke BJ, Lebsack AD, Overman LE. Scope and limitations of the thionium ion-initiated prins-pinacol synthesis of carbocycles Synlett. 1387-1393. DOI: 10.1055/S-2004-825613  1
2004 Katz JD, Overman LE. Studies towards the total synthesis of palau'amine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene-enamide ring-closing metathesis Tetrahedron. 60: 9559-9568. DOI: 10.1016/J.Tet.2004.06.140  1
2004 Katz JD, Overman LE. Studies towards the total synthesis of palau'amine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene–enamide ring-closing metathesis Tetrahedron. 60: 9559-9568. DOI: 10.1016/j.tet.2004.06.140  0.01
2004 Collins SK, McDonald AI, Overman LE, Rhee YH. Enantioselective Total Synthesis of (-)-Dehydrobatzelladine C. Cheminform. 35. DOI: 10.1002/chin.200435194  0.01
2004 Brueggemann M, McDonald AI, Overman LE, Rosen MD, Schwink L, Scott JP. Total Synthesis of (.+-.)-Didehydrostemofoline (I) (Asparagamine A) and (.+-.)-Isodidehydrostemofoline (II). Cheminform. 35. DOI: 10.1002/chin.200417204  0.01
2003 Brüggemann M, McDonald AI, Overman LE, Rosen MD, Schwink L, Scott JP. Total synthesis of (+/-)-didehydrostemofoline (asparagamine A) and (+/-)-isodidehydrostemofoline. Journal of the American Chemical Society. 125: 15284-5. PMID 14664560 DOI: 10.1021/Ja0388820  1
2003 Cohen F, Collins SK, Overman LE. Assembling polycyclic bisguanidine motifs resembling batzelladine alkaloids by double tethered Biginelli condensations. Organic Letters. 5: 4485-8. PMID 14602031 DOI: 10.1021/Ol0357999  1
2003 Anderson CE, Overman LE. Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity. Journal of the American Chemical Society. 125: 12412-3. PMID 14531676 DOI: 10.1021/Ja037086R  1
2003 Overman LE, Pennington LD. Strategic use of pinacol-terminated Prins cyclizations in target-oriented total synthesis. The Journal of Organic Chemistry. 68: 7143-57. PMID 12968864 DOI: 10.1021/Jo034982C  1
2003 Dounay AB, Overman LE. The asymmetric intramolecular Heck reaction in natural product total synthesis. Chemical Reviews. 103: 2945-64. PMID 12914487 DOI: 10.1021/Cr020039H  1
2003 Kodanko JJ, Overman LE. Enantioselective total syntheses of the cyclotryptamine alkaloids hodgkinsine and hodgkinsine B. Angewandte Chemie (International Ed. in English). 42: 2528-31. PMID 12800178 DOI: 10.1002/Anie.200351261  1
2003 Overman LE, Peterson EA. Enantioselective total synthesis of the cyclotryptamine alkaloid idiospermuline. Angewandte Chemie (International Ed. in English). 42: 2525-8. PMID 12800177 DOI: 10.1002/Anie.200351260  1
2003 Dounay AB, Hatanaka K, Kodanko JJ, Oestreich M, Overman LE, Pfeifer LA, Weiss MM. Catalytic asymmetric synthesis of quaternary carbons bearing two aryl substituents. Enantioselective synthesis of 3-alkyl-3-aryl oxindoles by catalytic asymmetric intramolecular heck reactions. Journal of the American Chemical Society. 125: 6261-71. PMID 12785859 DOI: 10.1021/Ja034525D  1
2003 Corminboeuf O, Overman LE, Pennington LD. Enantioselective total synthesis of briarellins E and F: the first total syntheses of briarellin diterpenes. Journal of the American Chemical Society. 125: 6650-2. PMID 12769572 DOI: 10.1021/Ja035445C  1
2003 Overman LE, Owen CE, Pavan MM, Richards CJ. Catalytic asymmetric rearrangement of allylic N-aryl trifluoroacetimidates. A useful method for transforming prochiral allylic alcohols to chiral allylic amines. Organic Letters. 5: 1809-12. PMID 12762658 DOI: 10.1021/Ol0271786  1
2003 Corminboeuf O, Overman LE, Pennington LD. Total synthesis of the reputed structure of alcyonin and reassignment of its structure. Organic Letters. 5: 1543-6. PMID 12713319 DOI: 10.1021/Ol034384K  1
2003 Overman LE, Peterson EA. Enantioselective synthesis of (-)-idiospermuline Tetrahedron. 59: 6905-6919. DOI: 10.1016/S0040-4020(03)00855-X  1
2003 Overman LE, Rishton GM. Stereocontrolled Preparation of 3‐Acyltetrahydrofurans from Acid‐Promoted Rearrangements of Allylic Ketals: (2S,3S)‐3‐Acetyl‐8‐Carboethoxy‐2,3‐Dimethyl‐1‐Oxa‐8‐Azaspiro[4.5]Decane Organic Syntheses. 63-63. DOI: 10.1002/0471264180.Os071.08  1
2003 Overman LE, Rishton GM. 3‐(S)‐[(tert‐Butyldiphenylsilyl)Oxy]‐2‐Butanone Organic Syntheses. 56-56. DOI: 10.1002/0471264180.Os071.07  1
2003 Arnold H, Overman LE, Sharp MJ, Witschel MC. (E)‐1‐Benzyl‐3‐(1‐Iodoethylidene)Piperidine: Nucleophile‐Promoted Alkyne‐Iminium Ion Cyclizations Organic Syntheses. 111-111. DOI: 10.1002/0471264180.Os070.13  1
2003 Overman LE, Flann CJ, Malone TC. Regioselective Synthesis of Tetrahydropyridines: 1-(4-Methoxyphenyl)-1,2,5,6-tetrahydropyridine Organic Syntheses. 188-188. DOI: 10.1002/0471264180.Os068.23  1
2003 Overman LE, Brown MJ, McCann SF. (Z)‐4‐(Trimethylsilyl)‐3‐Buten‐1‐ol Organic Syntheses. 182-182. DOI: 10.1002/0471264180.Os068.22  0.01
2003 Jessup PJ, Petty CB, Roos J, Overman LE. 1‐N‐Acylamino‐1,3‐dienes from 2,4‐Pentadienoic Acids by the Curtius Rearrangement: Benzyl trans‐1,3‐butadiene‐1‐carbamate Organic Syntheses. 1-1. DOI: 10.1002/0471264180.Os059.01  1
2003 Clizbe LA, Overman LE. Allylically Transposed Amines from Allylic Alcohols: 3,7‐Dimethyl‐1,6‐Octadien‐3‐Amine Organic Syntheses. 4-4. DOI: 10.1002/0471264180.Os058.02  1
2002 Bélanger G, Hong FT, Overman LE, Rogers BN, Tellew JE, Trenkle WC. Stereocontrolled synthesis of triazacyclopenta[cd]pentalenes by intramolecular 1,3-dipolar cycloaddition reactions of azomethine imines. The Journal of Organic Chemistry. 67: 7880-3. PMID 12398520 DOI: 10.1021/Jo026282Y  1
2002 Overman LE, Owen CE, Zipp GG. Diastereoselective lithiation of (eta6-arene)dicarbonyltriphenylphosphane chromium(0) oxazoline complexes--direct preparation of enantiopure complexes having planar chiral fragments of either configuration. Angewandte Chemie (International Ed. in English). 41: 3884-7. PMID 12386879 DOI: 10.1002/1521-3773(20021018)41:20<3884::Aid-Anie3884>3.0.Co;2-0  1
2002 Overman LE, Wolfe JP. New cationic olefin cyclization-pinacol reactions. Ring-expanding cyclopentane annulations that directly install useful functionality in the cyclopentane ring. The Journal of Organic Chemistry. 67: 6421-9. PMID 12201763 DOI: 10.1021/Jo025927R  1
2002 Lebsack AD, Link JT, Overman LE, Stearns BA. Enantioselective total synthesis of quadrigemine C and psycholeine. Journal of the American Chemical Society. 124: 9008-9. PMID 12148978 DOI: 10.1021/Ja0267425  1
2002 Hynes J, Nasser T, Overman LE, Watson DA. Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates. Organic Letters. 4: 929-31. PMID 11893188 DOI: 10.1021/Ol017303Y  1
2002 Kamenecka TM, Overman LE, Ly Sakata SK. Construction of substituted cyclohexanones by reductive cyclization of 7-oxo-2,8-alkadienyl esters. Organic Letters. 4: 79-82. PMID 11772095 DOI: 10.1021/Ol0169325  1
2002 Overman LE, Remarchuk TP. Catalytic asymmetric intramolecular aminopalladation: enantioselective synthesis of vinyl-substituted 2-oxazolidinones, 2-imidazolidinones, and 2-pyrrolidinones. Journal of the American Chemical Society. 124: 12-3. PMID 11772049 DOI: 10.1021/Ja017198N  1
2002 Berger D, Overman L. Preparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal-Alkene Cyclizations Synlett. 1992: 811-813. DOI: 10.1055/S-1992-21501  0.01
2002 Gahman TC, Overman LE. Stereoselective synthesis of carbocyclic ring systems by pinacol-terminated Prins cyclizations Tetrahedron. 58: 6473-6483. DOI: 10.1016/S0040-4020(02)00658-0  1
2001 Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Thwarting β-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction. Angewandte Chemie (International Ed. in English). 40: 1439-1442. PMID 29712379 DOI: 10.1002/1521-3773(20010417)40:8<1439::Aid-Anie1439>3.0.Co;2-F  1
2001 Cohen F, Overman LE. Enantioselective total synthesis of batzelladine F: structural revision and stereochemical definition. Journal of the American Chemical Society. 123: 10782-3. PMID 11674029 DOI: 10.1021/Ja017067M  1
2001 Govek SP, Overman LE. Total synthesis of asperazine. Journal of the American Chemical Society. 123: 9468-9. PMID 11562240 DOI: 10.1021/ja016616l  1
2001 Overman LE, Paone DV. Enantioselective total syntheses of ditryptophenaline and ent-WIN 64821. Journal of the American Chemical Society. 123: 9465-7. PMID 11562239 DOI: 10.1021/Ja0166141  1
2001 MacMillan DW, Overman LE, Pennington LD. A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cladiell-11-ene-3,6,7-triol, sclerophytin A, and the initially purported structure of sclerophytin A. Journal of the American Chemical Society. 123: 9033-44. PMID 11552811 DOI: 10.1021/Ja016351A  1
2001 Lebsack AD, Overman LE, Valentekovich RJ. Enantioselective total synthesis of shahamin K. Journal of the American Chemical Society. 123: 4851-2. PMID 11457302 DOI: 10.1021/Ja015802O  1
2001 Gallou F, MacMillan DW, Overman LE, Paquette LA, Pennington LD, Yang J. Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol. Organic Letters. 3: 135-7. PMID 11429857 DOI: 10.1021/Ol000345M  1
2001 Kamatani A, Overman LE. A new asymmetric synthesis of trans-hydroisoquinolones. Organic Letters. 3: 1229-32. PMID 11348201 DOI: 10.1021/Ol015696V  1
2001 Cohen F, MacMillan DW, Overman LE, Romero A. Stereoselection in the Prins-pinacol synthesis of acyltetrahydrofurans. Organic Letters. 3: 1225-8. PMID 11348200 DOI: 10.1021/Ol0157003  1
2001 Overman LE, Wolfe JP. Synthesis of polycyclic guanidines by cyclocondensation reactions of N-amidinyliminium ions. The Journal of Organic Chemistry. 66: 3167-75. PMID 11325284 DOI: 10.1021/Jo0100998  1
2001 Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Thwarting beta-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction This research was supported by the National Institutes of Health (grant GM-12389). M.O. thanks the Deutsche Forschungsgemeinschaft (DFG) for an Emmy Noether fellowship (Oe 249/1-1). NMR and mass spectra were determined at the University of California, Irvine with instruments purchased with the assistance of the NSF and NIH shared instrumentation programs. We are grateful to Dr. Joseph W. Ziller and Dr. John Greaves for their assistance with X-ray structure and mass spectrometric analyses. Angewandte Chemie (International Ed. in English). 40: 1439-1442. PMID 11317296 DOI: 10.1002/1521-3773(20010417)40:8<1439::AID-ANIE1439>3.0.CO;2-F  1
2001 O'Connor SJ, Overman LE, Rucker PV. Use of sequential intramolecular heck cyclizations for preparing bicyclo[3.2.1]octane fragments of tetracyclic stemodane and stemarane diterpenes Synlett. 1009-1012. DOI: 10.1055/S-2001-14648  1
2001 Gasparski CM, Herrinton PM, Overman LE, Wolfe JP. ChemInform Abstract: Synthesis of 3-Acyltetrahydrofurans from Formaldehyde Acetals of Allylic Diols. Cheminform. 32: no-no. DOI: 10.1002/chin.200110108  0.01
2001 Ashimori A, Overman LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction: Synthetic Developments and Mechanistic Studies Cheminform. 32: no-no. DOI: 10.1002/chin.200105290  0.01
2001 Ponce AM, Overman LE. ChemInform Abstract: A New Method for Stereocontrolled Synthesis of Substituted Tetrahydrothiophenes. Cheminform. 32: no-no. DOI: 10.1002/chin.200101041  0.01
2001 Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion Angewandte Chemie. 113: 1485-1489. DOI: 10.1002/1521-3757(20010417)113:8<1485::Aid-Ange1485>3.0.Co;2-F  0.01
2000 Overman LE, Rosen MD. Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers We thank NIH NIGMS (GM-30859) for financial support, Prof. A. J. Shaka and N. D. Taylor for DPFGSE experiments, Prof. H. Osada for providing spectral data for natural 1, and Prof. R. M. Williams and P. R. Sebahar for providing spectral data and a sample of synthetic ent-21. We are also grateful to Prof. R. M. Williams and Prof. S. J. Danishefsky for open exchange of information prior to publication. NMR and mass spectra were determined at UC Irvine with instruments purchased with the assistance of the NSF and NIH shared instrumentation programs. Angewandte Chemie (International Ed. in English). 39: 4596-4599. PMID 11169682 DOI: 10.1002/1521-3773(20001215)39:24<4596::Aid-Anie4596>3.0.Co;2-F  1
2000 Hoyt SB, Overman LE. Investigation of a dialkylation approach for enantioselective construction of vicinal quaternary stereocenters. Organic Letters. 2: 3241-4. PMID 11009391 DOI: 10.1021/Ol006494M  1
2000 Overman LE, Pennington LD. Total synthesis of the supposed structure of (-)-sclerophytin A and an improved route to (-)-7-deacetoxyalcyonin acetate. Organic Letters. 2: 2683-6. PMID 10990427 DOI: 10.1021/Ol006236P  1
2000 Hanaki N, Link JT, MacMillan DW, Overman LE, Trankle WG, Wurster JA. Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral. Organic Letters. 2: 223-6. PMID 10814287 DOI: 10.1021/Ol991315Q  1
2000 Overman LE, Larrow JF, Stearns BA, Vance JM. Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and meso-Chimonanthine. Angewandte Chemie (International Ed. in English). 39: 213-215. PMID 10649379 DOI: 10.1002/(Sici)1521-3773(20000103)39:1<213::Aid-Anie213>3.0.Co;2-Z  1
2000 Ashimori A, Overman LE. Catalytic asymmetric synthesis of quaternary carbon centers by intramolecular Heck reaction: Synthetic developments and mechanistic studies Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 58: 718-727. DOI: 10.5059/Yukigoseikyokaishi.58.718  1
2000 Overman LE, Rucker PV. Investigations directed at the total synthesis of ouabain. Lessons learned from degradation studies Heterocycles. 52: 1297-1314. DOI: 10.3987/Com-99-S142  1
2000 Overman LE, Pennington LD. A new strategy for synthesis of attached rings Canadian Journal of Chemistry. 78: 732-738. DOI: 10.1139/V00-022  1
2000 Ponce AM, Overman LE. A new method for stereocontrolled synthesis of substituted tetrahydrothiophenes Journal of the American Chemical Society. 122: 8672-8676. DOI: 10.1021/Ja001975M  1
2000 Coffey DS, Overman LE, Stappenbeck F. Enantioselective total syntheses of 13,14,15-isocrambescidin 800 and 13,14,15-isocrambescidin 657 Journal of the American Chemical Society. 122: 4904-4914. DOI: 10.1021/ja000235a  1
2000 Coffey DS, McDonald AI, Overman LE, Rabinowitz MH, Renhowe PA. A practical entry to the crambescidin family of guanidine alkaloids. Enantioselective total syntheses of ptilomycalin A, crambescidin 657 and its methyl ester (neofolitispates 2), and crambescidin 800 Journal of the American Chemical Society. 122: 4893-4903. DOI: 10.1021/Ja000234I  1
2000 Gasparski CM, Herrinton PM, Overman LE, Wolfe JP. Synthesis of 3-acyltetrahydrofurans from formaldehyde acetals of allylic diols Tetrahedron Letters. 41: 9431-9435. DOI: 10.1016/S0040-4039(00)01571-9  1
2000 Overman LE, Pennington LD. ChemInform Abstract: A New Strategy for Synthesis of Attached Rings. Cheminform. 31: no-no. DOI: 10.1002/chin.200049043  0.01
2000 Coffey DS, Overman LE, Stappenbeck F. ChemInform Abstract: Enantioselective Total Syntheses of 13,14,15-Isocrambescidin 800 and 13,14,15-Isocrambescidin 657. Cheminform. 31: no-no. DOI: 10.1002/chin.200037222  0.01
2000 Coffey DS, McDonald AI, Overman LE, Rabinowitz MH, Renhowe PA. ChemInform Abstract: A Practical Entry to the Crambescidin Family of Guanidine Alkaloids. Enantioselective Total Syntheses of Ptilomycalin A, Crambescidin 657 and Its Methyl Ester (Neofolitispates 2), and Crambescidin 800. Cheminform. 31: no-no. DOI: 10.1002/chin.200037221  0.01
2000 Overman LE, Rosen MD. Totalsynthese von (−)-Spirotryprostatin B und drei Stereoisomeren Angewandte Chemie. 112: 4768-4771. DOI: 10.1002/1521-3757(20001215)112:24<4768::Aid-Ange4768>3.0.Co;2-7  0.01
1999 McDonald AI, Overman LE. Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis- or trans-1-Oxo- and 1-Iminohexahydropyrrolo[1,2-c]pyrimidines. The Journal of Organic Chemistry. 64: 1520-1528. PMID 11674214 DOI: 10.1021/Jo981972G  1
1999 Franklin AS, Ly SK, Mackin GH, Overman LE, Shaka AJ. Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B. The Journal of Organic Chemistry. 64: 1512-1519. PMID 11674213 DOI: 10.1021/Jo981971O  1
1999 Cohen F, Overman LE, Sakata SK. Asymmetric total synthesis of batzelladine D. Organic Letters. 1: 2169-72. PMID 10836070 DOI: 10.1021/Ol991269U  1
1999 Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Total Synthesis of (+/-)-Gelsemine. Angewandte Chemie (International Ed. in English). 38: 2934-2936. PMID 10540398 DOI: 10.1002/(Sici)1521-3773(19991004)38:19<2934::Aid-Anie2934>3.0.Co;2-L  1
1999 Kamatani A, Overman LE. A Suzuki coupling method for directly introducing a protected β- aminoethyl group into arenes and alkenes. Convenient synthesis of phenethyl and homoallylic amines Journal of Organic Chemistry. 64: 8743-8744. DOI: 10.1021/Jo991064Z  1
1999 Coffey DS, McDonald AI, Overman LE. Preparation of (3S)-N,N-1,7-bis-tert-butoxycarbonyl-3-hydroxyspermidine in high enantiomeric purity Journal of Organic Chemistry. 64: 8741-8742. DOI: 10.1021/Jo991061M  1
1999 Bogenstätter M, Limberg A, Overman LE, Tomasi AL. Enantioselective total synthesis of the kinesin motor protein inhibitor adociasulfate 1 [12] Journal of the American Chemical Society. 121: 12206-12207. DOI: 10.1021/ja9934091  1
1999 Overman LE, Paone DV, Stearns BA. Direct stereo- and enantiocontrolled synthesis of vicinal stereogenic quaternary carbon centers. Total syntheses of meso- and (-)-chimonanthine and (+)-calycanthine [4] Journal of the American Chemical Society. 121: 7702-7703. DOI: 10.1021/Ja991714G  1
1999 Coffey DS, McDonald AI, Overman LE, Stappenbeck F. Enantioselective total synthesis of 13,14,15-isocrambescidin 800 [5] Journal of the American Chemical Society. 121: 6944-6945. DOI: 10.1021/ja990992c  1
1999 Fox ME, Li C, Marino JP, Overman LE. Enantiodivergent total syntheses of (+)- and (-)-scopadulcic acid A Journal of the American Chemical Society. 121: 5467-5480. DOI: 10.1021/Ja990404V  1
1999 Cloninger MJ, Overman LE. Stereocontrolled synthesis of trisubstituted tetrahydropyrans [3] Journal of the American Chemical Society. 121: 1092-1093. DOI: 10.1021/Ja9838007  1
1999 Donde Y, Overman LE. High enantioselection in the rearrangement of allylic imidates with ferrocenyl oxazoline catalysts Journal of the American Chemical Society. 121: 2933-2934. DOI: 10.1021/Ja983263Q  1
1999 Brosius AD, Overman LE, Schwink L. Total synthesis of (+)-aloperine. Use of a nitrogen-bound silicon tether in an intramolecular Dieis-Alder reaction Journal of the American Chemical Society. 121: 700-709. DOI: 10.1021/ja983013+  1
1999 Jaroch S, Matsuoka RT, Overman LE. Studies towards a total synthesis of Sarains A-C. Stereospecific condensation of α,β-unsaturated esters with the phenyl oxazoline derivative of threonine Tetrahedron Letters. 40: 1273-1276. DOI: 10.1016/S0040-4039(98)02639-2  1
1999 Keith Hollis T, Overman LE. Palladium catalyzed enantioselective rearrangement of allylic imidates to allylic amides Journal of Organometallic Chemistry. 576: 290-299. DOI: 10.1016/S0022-328X(98)01065-1  1
1999 Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Totalsynthese von (±)-Gelsemin Angewandte Chemie. 111: 3110-3112. DOI: 10.1002/(Sici)1521-3757(19991004)111:19<3110::Aid-Ange3110>3.0.Co;2-F  0.01
1999 Iserloh U, Ashimori A, Curran DP, Bachand B, Overman LE, Poon DJ, Calter MA, Govek SP, Matsuura T. Catalytic asymmetric synthesis of quaternary carbon centers: Investigation of intramolecular Heck reactions and the application to calabar alkaloid synthesis Chemtracts. 12: 289-296.  1
1998 Downham R, Ng FW, Overman LE. Asymmetric construction of the diazatricyclic core of the marine alkaloids sarains A-C Journal of Organic Chemistry. 63: 8096-8097. DOI: 10.1021/Jo9817117  1
1998 Ando K, Condroski KR, Houk KN, Wu YD, Ly SK, Overman LE. Stereoselectivities of Nucleophilic Additions to Cycloheptanones. Experimental and Theoretical Studies and General Purpose Force Field for the Prediction of Nucleophilic Addition Stereoselectivities Journal of Organic Chemistry. 63: 3196-3203. DOI: 10.1021/Jo971627B  1
1998 Matsuura T, Overman LE, Poon DJ. Catalytic asymmetric synthesis of either enantiomer of the calabar alkaloids physostigmine and physovenine Journal of the American Chemical Society. 120: 6500-6503. DOI: 10.1021/ja980788+  1
1998 Ashimori A, Bachand B, Calter MA, Govek SP, Overman LE, Poon DJ. Catalytic asymmetric synthesis of quaternary carbon centers. Exploratory studies of intramolecular Heck reactions of (Z)-α,β-unsaturated anilides and mechanistic investigations of asymmetric Heck reactions proceeding via neutral intermediates Journal of the American Chemical Society. 120: 6488-6499. DOI: 10.1021/ja980787h  1
1998 Ashimori A, Bachand B, Overman LE, Poon DJ. Catalytic asymmetric synthesis of quaternary carbon centers. Exploratory investigations of intramolecular heck reactions of (E)-α,β-unsaturated 2-haloanilides and analogues to form enantioenriched spirocyclic products Journal of the American Chemical Society. 120: 6477-6487. DOI: 10.1021/Ja980786P  1
1998 Overman LE, Tomasi AL. Enantioselective total synthesis of hispidospermidin [13] Journal of the American Chemical Society. 120: 4039-4040. DOI: 10.1021/Ja974361Z  1
1998 Cohen F, Overman LE. Planar-chiral cyclopalladated ferrocenyl amines and imines as enantioselective catalysts for allylic imidate rearrangements Tetrahedron Asymmetry. 9: 3213-3222. DOI: 10.1016/S0957-4166(98)00341-3  1
1998 Hynes J, Overman LE, Nasser T, Rucker PV. Intramolecular Heck cyclization of α-sulfenyl enol triflates. Asymmetric synthesis of a pentacyclic cardenolide precursor having functionality at C-11 Tetrahedron Letters. 39: 4647-4650. DOI: 10.1016/S0040-4039(98)00860-0  1
1998 Overman LE, Rucker PV. Enantioselective synthesis of cardenolide precursors using an intramolecular Heck reaction Tetrahedron Letters. 39: 4643-4646. DOI: 10.1016/S0040-4039(98)00859-4  1
1998 Link JT, Overman LE. Forming cyclics with the intramolecular Heck reaction Chemtech. 28: 19-26.  1
1997 Overman LE, Zipp GG. Allylic Transposition of Alcohol and Amine Functionality by Thermal or Palladium(II)-Catalyzed Rearrangements of Allylic N-Benzoylbenzimidates. The Journal of Organic Chemistry. 62: 2288-2291. PMID 11671546 DOI: 10.1021/Jo962129Q  1
1997 Brosius AD, Overman LE. Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration. The Journal of Organic Chemistry. 62: 440-441. PMID 11671426 DOI: 10.1021/Jo9621231  1
1997 Abelman MM, Kado N, Overman LE, Sarkar AK. Synthesis of a phenolic analog of aphidicolin. Diminished stereoselection in intramolecular 6-exo Heck reactions of substrates having a hydrocarbon tether Synlett. 1469-1471. DOI: 10.1055/S-1997-1066  1
1997 Metais E, Overman LE, Rodriguez MI, Stearns BA. Halide-terminated N-acyliminium ion-alkyne cyclizations: A new construction of carbacephem antibiotics Journal of Organic Chemistry. 62: 9210-9216. DOI: 10.1021/Jo971433W  1
1997 Ando S, Minor KP, Overman LE. Ring-Enlarging Cyclohexane Annulations Journal of Organic Chemistry. 62: 6379-6387. DOI: 10.1021/Jo970399I  1
1997 Calter M, Hollis TK, Overman LE, Ziller J, Zipp GG. First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides Journal of Organic Chemistry. 62: 1449-1456. DOI: 10.1021/Jo962090P  1
1997 Overman LE, Ricca DJ, Tran VD. Total synthesis of (±)-scopadulcic acid B Journal of the American Chemical Society. 119: 12031-12040. DOI: 10.1021/Ja972427K  1
1997 Overman LE, Rogers BN, Tellew JE, Trenkle WC. Stereocontrolled synthesis of the tetracyclic core of the bisguanidine alkaloids palau'amine and styloguanidine [4] Journal of the American Chemical Society. 119: 7159-7160. DOI: 10.1021/Ja9712985  1
1997 Berger D, Overman LE, Renhowe PA. Total synthesis of (+)-isolaurepinnacin. Use of acetal-alkene cyclizations to prepare highly functionalized seven-membered cyclic ethers Journal of the American Chemical Society. 119: 2446-2452. DOI: 10.1021/Ja964080B  1
1997 Hollis TK, Overman LE. Cyclopalladated ferrocenyl amines as enantioselective catalysts for the rearrangement of allylic imidates to allylic amides Tetrahedron Letters. 38: 8837-8840. DOI: 10.1016/S0040-4039(97)10385-9  1
1997 Joe D, Overman LE. An unexpected product arising from metal alkylidene mediated ring-closing diene metathesis Tetrahedron Letters. 38: 8635-8638. DOI: 10.1016/S0040-4039(97)10373-2  1
1997 Hong CY, Overman LE, Romero A. Pyridinomorphinans: Asymmetric synthesis of either enantiomer and opioid receptor binding selectivity Tetrahedron Letters. 38: 8439-8442. DOI: 10.1016/S0040-4039(97)10274-X  1
1997 Minor KP, Overman LE. Prins-pinacol spiroannulations Tetrahedron. 53: 8927-8940. DOI: 10.1016/S0040-4020(97)90401-4  1
1997 Overman LE, Trenkle WC. Controlling stereoselection in aza-Cope-Mannich reactions Israel Journal of Chemistry. 37: 23-30. DOI: 10.1002/Ijch.199700005  1
1997 Overman LE, Poon DJ. Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights Angewandte Chemie (International Edition in English). 36: 518-521. DOI: 10.1002/Anie.199705181  1
1997 Overman LE, Poon DJ. Asymmetrische Heck‐Reaktionen über neutrale Intermediate: Verstärkung der Enantioselektion durch Halogenid‐Additive und Einblicke in den Mechanismus Angewandte Chemie. 109: 536-538. DOI: 10.1002/Ange.19971090522  1
1996 Franklin AS, Overman LE. Total Syntheses of Pumiliotoxin A and Allopumiliotoxin Alkaloids. Interplay of Pharmacologically Active Natural Products and New Synthetic Methods and Strategies. Chemical Reviews. 96: 505-522. PMID 11848762 DOI: 10.1021/Cr950021P  1
1996 Overman LE, Tellew JE. Synthesis of 2-Azatricyclo[5.2.1.0(4,10)]decanes and 2,5-Diazatricyclo[5.2.1.0(4,10)]decanes by Intramolecular Azomethine Ylide Cycloadditions. The Journal of Organic Chemistry. 61: 8338-8340. PMID 11667832 DOI: 10.1021/Jo961341R  1
1996 Deng W, Jensen MS, Overman LE, Rucker PV, Vionnet JP. A Strategy for Total Synthesis of Complex Cardenolides. The Journal of Organic Chemistry. 61: 6760-6761. PMID 11667560 DOI: 10.1021/Jo961209R  1
1996 Ragozzino D, Woodward RM, Murata Y, Eusebi F, Overman LE, Miledi R. Design and in vitro pharmacology of a selective gamma-aminobutyric acidC receptor antagonist. Molecular Pharmacology. 50: 1024-30. PMID 8863850  1
1996 Murata Y, Overman LE. Aprotic chloride and bromide-promoted alkyne-iminium ion cyclizations Heterocycles. 42: 549-552. DOI: 10.3987/Com-95-S96  1
1996 Link JT, Overman LE. Stereocontrolled total syntheses of meso-chimonanthine and meso-calycanthine via a novel samarium mediated reductive dialkylation Journal of the American Chemical Society. 118: 8166-8167. DOI: 10.1021/Ja961757M  1
1996 Lin NH, Overman LE, Rabinowitz MH, Robinson LA, Sharp MJ, Zablocki J. Efficient total syntheses of pumiliotoxins A and B. Applications of iodide-promoted iminium ion-alkyne cyclizations in alkaloid construction Journal of the American Chemical Society. 118: 9062-9072. DOI: 10.1021/Ja961641Q  1
1996 Caderas R, Lett R, Overman LE, Rabinowitz MH, Robinson LA, Sharp MJ, Zablocki J. Enantioselective total syntheses of allopumiliotoxins 267A, 323B', and 339A. Application of iodide-promoted iminium ion-alkyne cyclizations for forming allopumiliotoxin A alkaloids Journal of the American Chemical Society. 118: 9073-9082. DOI: 10.1021/Ja961640Y  1
1996 Murata Y, Woodward RM, Miledi R, Overman LE. The first selective antagonist for a GABA(C) receptor Bioorganic and Medicinal Chemistry Letters. 6: 2073-2076. DOI: 10.1016/0960-894X(96)00364-2  1
1996 Overman LE, Tellew JE. Synthesis of 2-azatricyclo[5.2.1.04,10]decanes and 2,5-diazatricyclo[5.2.1.04,10]decanes by intramolecular azomethine ylide cycloadditions Journal of Organic Chemistry. 61: 8338-8340.  1
1995 MacMillan DWC, Overman LE. Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene Journal of the American Chemical Society. 117: 10391-10392. DOI: 10.1021/Ja00146A028  0.01
1995 Lögers M, Overman LE, Welmaker GS. Mannich biscyclizations. Total synthesis of (-)-ajmalicine Journal of the American Chemical Society. 117: 9139-9150. DOI: 10.1021/Ja00141A004  1
1995 Bratz M, Bullock WH, Overman LE, Takemoto T. Total Synthesis of (+)-Laurencin. Use of Acetal-Vinyl Sulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers Journal of the American Chemical Society. 117: 5958-5966. DOI: 10.1021/Ja00127A008  0.01
1995 Knight SD, Overman LE, Pairaudeau G. Asymmetric total syntheses of (-)- and (+)-strychnine and the Wieland-Gumlich aldehyde Journal of the American Chemical Society. 117: 5776-5788. DOI: 10.1021/Ja00126A017  1
1995 Overman LE, Rabinowitz MH, Renhowe PA. Enantioselective Total Synthesis of (-)-Ptilomycalin A Journal of the American Chemical Society. 117: 2657-2658. DOI: 10.1021/Ja00114A034  0.01
1995 Hayashi T, Sugimoto T, Takewaki N, Takeguchi N, Tran VD, O'Connor SJ, Rucker PV, Overman LE. Silyl ethers of cycloheptene, novel proton pump inhibitors obtained during the total synthesis of the scopadulcic acids Bioorganic & Medicinal Chemistry Letters. 5: 2943-2946. DOI: 10.1016/0960-894X(95)00493-8  0.01
1995 Knight SD, Miledi R, Quoc-Thang Nguyen, Overman LE, Pairaudeau G. The enantiomer of strychnine is a weak antagonist of the inhibitory glycine receptor Bioorganic and Medicinal Chemistry Letters. 5: 749-752. DOI: 10.1016/0960-894X(95)00108-6  1
1994 E. Overman L, D. Knight S. Preparation of Spirocyclic Polyethers by Intramolecular Heck Reactions Heterocycles. 39: 497. DOI: 10.3987/Com-94-S(B)76  0.04
1994 Overman LE. Application of intramolecular Heck reactions for forming congested quaternary carbon centers in complex molecule total synthesis Pure and Applied Chemistry. 66: 1423-1430. DOI: 10.1351/Pac199466071423  0.01
1994 Overman LE, Renhowe PA. Regioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl)allyl Organometallic Reagents The Journal of Organic Chemistry. 59: 4138-4142. DOI: 10.1021/Jo00094A026  0.01
1994 Leotta GJ, Overman LE, Welmaker GS. A Convenient Method for the Preparation of 3-Substituted Glutarate Diesters Journal of Organic Chemistry. 59: 1946-1946. DOI: 10.1021/Jo00086A065  1
1994 Deng W, Overman LE. Enantioselective total synthesis of either enantiomer of the antifungal antibiotic preussin (L-657,398) from (S)-phenylalanine Journal of the American Chemical Society. 116: 11241-11250. DOI: 10.1021/Ja00104A005  1
1994 Kamenecka TM, Overman LE. An enantioselective approach to the synthesis of manzamine A Tetrahedron Letters. 35: 4279-4282. DOI: 10.1016/S0040-4039(00)73333-8  1
1994 Hong CY, Overman LE. Preparation of opium alkaloids by palladium catalyzed bis-cyclizations. Formal total synthesis of morphine Tetrahedron Letters. 35: 3453-3456. DOI: 10.1016/S0040-4039(00)73208-4  0.2
1994 Laschat S, Narjes F, Overman LE. Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides. Tetrahedron. 50: 347-358. DOI: 10.1016/S0040-4020(01)80759-6  0.01
1993 E. Overman L, M. Burk R. Total Synrhesis of the Amaryllidaceae Alkaloid (±)-Epielwesine. The Importance of Vinylsilane Stereochemistry in Iminium Ion-Vinylsilane Cyclizations Heterocycles. 35: 205. DOI: 10.3987/Com-92-S7  0.01
1993 Ashimori A, Matsuura T, Overman LE, Poon DJ. Catalytic asymmetric synthesis of either enantiomer of physostigmine. Formation of quaternary carbon centers with high enantioselection by intramolecular Heck reactions of (Z)-2-butenanilides The Journal of Organic Chemistry. 58: 6949-6951. DOI: 10.1021/Jo00077A005  0.01
1993 Heerding DA, Hong CY, Kado N, Look GC, Overman LE. Simple method for controlling stereoselection in Mannich cyclization reactions of aldehydes The Journal of Organic Chemistry. 58: 6947-6948. DOI: 10.1021/Jo00077A004  0.01
1993 Montgomery J, Overman LE. Introduction of the 2-(phenylthio)ethyl, 2-(phenylsulfinyl)ethyl, and 2,2-bis(phenylthio)ethyl substituents into cyclic ketones The Journal of Organic Chemistry. 58: 6476-6479. DOI: 10.1021/Jo00075A054  0.04
1993 Kucera DJ, O'Connor SJ, Overman LE. Total synthesis of (.+-.)-scopadulcic acid A. An illustration of the utility of palladium catalyzed polyene cyclizations The Journal of Organic Chemistry. 58: 5304-5306. DOI: 10.1021/Jo00072A006  0.01
1993 Overman LE, Shim J. Synthesis applications of cationic aza-Cope rearrangements. Part 25. Total synthesis of Amaryllidaceae alkaloids of the 5,11-methanomorphanthridine type. Efficient total syntheses of (-)-pancracine and (.+-.)-pancracine The Journal of Organic Chemistry. 58: 4662-4672. DOI: 10.1021/Jo00069A032  0.01
1993 Overman LE, Rabinowitz MH. Studies toward the total synthesis of (+)-ptilomycalin A. Use of a tethered Biginelli condensation for the preparation of an advanced tricyclic intermediate The Journal of Organic Chemistry. 58: 3235-3237. DOI: 10.1021/Jo00064A007  0.01
1993 Grese TA, Hutchinson KD, Overman LE. General approach to halogenated tetrahydrofuran natural products from red algae of the genus Laurencia. Total synthesis of (±)-kumausallene and (±)-1-epi-kumausallene Journal of Organic Chemistry. 58: 2468-2477. DOI: 10.1021/Jo00061A021  0.08
1993 Hong CY, Kado N, Overman LE. Asymmetric synthesis of either enantiomer of opium alkaloids and morphinans. Total synthesis of (-)- and (+)-dihydrocodeinone and (-)- and (+)-morphine Journal of the American Chemical Society. 115: 11028-11029. DOI: 10.1021/Ja00076A086  0.04
1993 Berger D, Overman LE, Renhowe PA. Enantioselective total synthesis of (+)-isolaurepinnacin Journal of the American Chemical Society. 115: 9305-9306. DOI: 10.1021/Ja00073A063  0.01
1993 Knight SD, Overman LE, Pairaudeau G. Enantioselective total synthesis of (-)-strychnine Journal of the American Chemical Society. 115: 9293-9294. DOI: 10.1021/Ja00073A057  1
1993 Angle SR, Fevig JM, Knight SD, Marquis RW, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. 24. The aza-Cope-Mannich approach to Strychnos alkaloids. Short stereocontrolled total syntheses of (.+-.)-dehydrotubifoline and (.+-.)-akuammicine Journal of the American Chemical Society. 115: 3966-3976. DOI: 10.1021/Ja00063A016  0.01
1993 Hirst GC, Johnson TO, Overman LE. First total synthesis of Lycopodium alkaloids of the magellanane group. Enantioselective total syntheses of (-)-magellanine and (+)-magellaninone Journal of the American Chemical Society. 115: 2992-2993. DOI: 10.1021/Ja00060A064  1
1993 Overman LE, Ricca DJ, Tran VD. First total synthesis of scopadulcic acid B Journal of the American Chemical Society. 115: 2042-2044. DOI: 10.1021/Ja00058A064  0.01
1993 Castro P, Overman LE, Zhang X, Mariano PS. Preparation of enantioenriched tetrahydropyridines by iminium ion-vinylsilane cyclizations Tetrahedron Letters. 34: 5243-5246. DOI: 10.1016/S0040-4039(00)73963-3  0.24
1992 Overman LE, Abelman MM, Kucera DJ, Tran VD, Ricca DJ. Palladium-catalyzed, polyene cyclizations Pure and Applied Chemistry. 64: 1813-1819. DOI: 10.1351/Pac199264121813  1
1992 Overman LE, Rodriguez-Campos IM. Preparation of Unsaturated Seven and Eight Membered Nitrogen Heterocycles by Iodide-Promoted Alkyne-Iminium Ion Cyclizations Synlett. 1992: 995-996. DOI: 10.1055/S-1992-21560  0.01
1992 Ashimori A, Overman LE. Catalytic asymmetric synthesis of quarternary carbon centers. Palladium-catalyzed formation of either enantiomer of spirooxindoles and related spirocyclics using a single enantiomer of a chiral diphosphine ligand The Journal of Organic Chemistry. 57: 4571-4572. DOI: 10.1021/Jo00043A005  0.01
1992 Goldstein SW, Overman LE, Rabinowitz MH. The first enantioselective total syntheses of the allopumiliotoxin A alkaloids 267A and 339B The Journal of Organic Chemistry. 57: 1179-1190. DOI: 10.1021/Jo00030A026  0.01
1992 Overman LE, Sharp MJ. Reaction of Na2Fe(CO)4 with an unsaturated aziridinium ion. Unprecedented rearrangement of an alkyltetracarbonylferrate intermediate The Journal of Organic Chemistry. 57: 1035-1038. DOI: 10.1021/Jo00029A054  0.01
1992 Hopkins MH, Overman LE, Rishton GM. Stereocontrolled preparation of tetrahydrofurans from acid-promoted rearrangements of allylic acetals. [Erratum to document cited in CA115(13):135825m] Journal of the American Chemical Society. 114: 10093-10093. DOI: 10.1021/Ja00051A070  0.01
1992 Overman LE, Robinson LA, Zablocki J. First total synthesis of (+)-allopumiliotoxin 339A. A practical entry to dendrobatid alkaloids of the allopumiliotoxin class Journal of the American Chemical Society. 114: 368-369. DOI: 10.1021/Ja00027A061  0.01
1992 Overman LE. Charge as a key component in reaction design. The invention of cationic cyclization reactions of importance in synthesis Accounts of Chemical Research. 25: 352-359. DOI: 10.1021/Ar00020A005  0.01
1992 Overman LE, Sarkar AK. Iodide-promoted aldiminium ion-alkyne cyclizations. A convenient synthesis of substituted tetrahydropyridines and 3-alkylidenepiperidines. Tetrahedron Letters. 33: 4103-4106. DOI: 10.1016/S0040-4039(00)74663-6  1
1992 Madin A, Overman LE. Controlling stereoselection in intramolecular heck reactions by tailoring the palladium catalyst Tetrahedron Letters. 33: 4859-4862. DOI: 10.1016/S0040-4039(00)61217-0  0.01
1991 Overman LE, Shim J. Synthesis applications of cationic aza-Cope rearrangements. 23. First total synthesis of amaryllidaceae alkaloids of the 5,11-methano morphanthridine type. An efficient total synthesis of (.+-.)-pancracine The Journal of Organic Chemistry. 56: 5005-5007. DOI: 10.1021/Jo00017A002  0.01
1991 Brown MJ, Overman LE. Preparation of 3-amino-4-(hydroxymethyl)azetidin-2-ones from the reaction of glycine enolates with imines of a glycoaldehyde The Journal of Organic Chemistry. 56: 1933-1936. DOI: 10.1021/Jo00005A048  0.01
1991 Brown MJ, Harrison T, Overman LE. General approach to halogenated tetrahydrofuran natural products from red algae of the genus Laurencia. Total synthesis of (.+-.)-trans-kumausyne and demonstration of an asymmetric synthesis strategy Journal of the American Chemical Society. 113: 5378-5384. DOI: 10.1021/Ja00014A032  0.01
1991 Brown MJ, Harrison T, Herrinton PM, Hopkins MH, Hutchinson KD, Overman LE, Mishra P. Acid-promoted reaction of cyclic allylic diols with carbonyl compounds. Stereoselective ring-enlarging tetrahydrofuran annulations Journal of the American Chemical Society. 113: 5365-5378. DOI: 10.1021/Ja00014A031  0.01
1991 Hopkins MH, Overman LE, Rishton GM. Stereocontrolled preparation of tetrahydrofurans from acid-promoted rearrangements of allylic acetals Journal of the American Chemical Society. 113: 5354-5365. DOI: 10.1021/Ja00014A030  0.01
1991 Fevig JM, Marquis RW, Overman LE. New approach to Strychnos alkaloids. Stereocontrolled total synthesis of (.+-.)-dehydrotubifoline Journal of the American Chemical Society. 113: 5085-5086. DOI: 10.1021/Ja00013A068  0.44
1991 Overman LE, Robertson GM, Robichaud AJ. Use of aza-Cope rearrangement-Mannich cyclization reactions to achieve a general entry to Melodinus and Aspidosperma alkaloids. Stereocontrolled total syntheses of (.+-.)-deoxoapodine, (.+-.)-meloscine, and (.+-.)-epimeloscine and a formal synthesis of (.+-.)-1-acetylaspidoalbidine Journal of the American Chemical Society. 113: 2598-2610. DOI: 10.1021/Ja00007A038  1
1991 Flann CJ, Overman LE, Sarkar AK. Synthesis of 3-acyl-3-alkyloxindoles Tetrahedron Letters. 32: 6993-6996. DOI: 10.1016/0040-4039(91)85022-W  1
1991 Johnson TO, Overman LE. Ring-enlarging cyclopentene annulations Tetrahedron Letters. 32: 7361-7364. DOI: 10.1016/0040-4039(91)80107-H  1
1990 Daly JW, Gusovsky F, McNeal ET, Secunda S, Bell M, Creveling CR, Nishizawa Y, Overman LE, Sharp MJ, Rossignol DP. Pumiliotoxin alkaloids: a new class of sodium channel agents. Biochemical Pharmacology. 40: 315-26. PMID 2165404 DOI: 10.1016/0006-2952(90)90694-G  1
1990 Fisher MJ, Overman LE. Intramolecular N-(acyloxy)iminium ion-alkyne cycloadditions. A new route to bicyclic .alpha.-amino ketones The Journal of Organic Chemistry. 55: 1447-1459. DOI: 10.1021/Jo00292A014  0.01
1990 Abelman MM, Overman LE, Tran VD. Construction of quaternary carbon centers by palladium-catalyzed intramolecular alkene insertions. Total synthesis of the Amaryllidaceae alkaloids (.+-.)-tazettine and (.+-.)-6a-epipretazettine Journal of the American Chemical Society. 112: 6959-6964. DOI: 10.1021/Ja00175A033  0.01
1990 Blumenkopf TA, Look GC, Overman LE. Formation of .DELTA.4-oxocenes from Lewis acid promoted cyclizations of 5-hexenyl acetals. Evidence for a concerted ene cyclization mechanism Journal of the American Chemical Society. 112: 4399-4403. DOI: 10.1021/Ja00167A042  0.01
1990 Blumenkopf TA, Bratz M, Castaneda A, Look GC, Overman LE, Rodriguez D, Thompson AS. Preparation of eight-membered cyclic ethers by Lewis acid promoted acetal-alkene cyclizations Journal of the American Chemical Society. 112: 4386-4399. DOI: 10.1021/Ja00167A041  0.01
1990 Overman LE, Renaldo AE. Catalyzed sigmatropic rearrangements. 10. Mechanism of the palladium dichloride catalyzed Cope rearrangement of acyclic dienes. A substituent effect study Journal of the American Chemical Society. 112: 3945-3949. DOI: 10.1021/Ja00166A034  0.01
1990 ABELMAN MM, OVERMAN LE, TRAN VD. ChemInform Abstract: Construction of Quaternary Carbon Centers by Palladium-Catalyzed Intramolecular Alkene Insertions. Total Synthesis of the Amaryllidaceae Alkaloids (.+-.)-Tazettine and (.+-.)-6a-Epipretazettine. Cheminform. 21. DOI: 10.1002/chin.199052339  0.01
1990 BLUMENKOPF TA, LOOK GC, OVERMAN LE. ChemInform Abstract: Formation of δ4-Oxocenes from Lewis Acid Promoted Cyclizations of 5-Hexenyl Acetals. Evidence for a Concerted Ene Cyclization Mechanism. Cheminform. 21. DOI: 10.1002/chin.199038087  0.01
1990 BLUMENKOPF TA, BRATZ M, CASTANEDA A, LOOK GC, OVERMAN LE, RODRIGUEZ D, THOMPSON AS. ChemInform Abstract: Preparation of Eight-Membered Cyclic Ethers by Lewis Acid Promoted Acetal-Alkene Cyclizations. Cheminform. 21. DOI: 10.1002/chin.199037232  0.01
1990 OVERMAN LE, RENALDO AF. ChemInform Abstract: Catalyzed Sigmatropic Rearrangements. Part 10. Mechanism of the Palladium Dichloride Catalyzed Cope Rearrangement of Acyclic Dienes. A Substituent Effect Study. Cheminform. 21. DOI: 10.1002/chin.199035079  0.01
1990 FISHER MJ, OVERMAN LE. ChemInform Abstract: Intramolecular N-(Acyloxy)iminium Ion-Alkyne Cycloadditions. A New Route to Bicyclic α-Amino Ketones. Cheminform. 21. DOI: 10.1002/chin.199033290  0.04
1990 CARPENTER NE, KUCERA DJ, OVERMAN LE. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations of Trienyl Triflates. Cheminform. 21. DOI: 10.1002/chin.199024074  0.01
1990 CASTANEDA A, KUCERA DJ, OVERMAN LE. ChemInform Abstract: Preparation of Seven-Membered Ring Cyclic Ethers and 3-Alkylidenetetrahydropyrans from the Cyclization of Oxonium Cations Derived from Unsubstituted and Silicon-Containing 4-Alken-1-ols. Cheminform. 21. DOI: 10.1002/chin.199019090  0.01
1989 Carpenter NE, Kucera DJ, Overman LE. Palladium-catalyzed polyene cyclizations of trienyl triflates Journal of Organic Chemistry. 54: 5846-5848. DOI: 10.1021/Jo00286A009  1
1989 Castaneda A, Kucera DJ, Overman LE. Preparation of seven-membered ring cyclic ethers and 3-alkylidenetetrahydropyrans from the cyclization of oxonium cations derived from unsubstituted and silicon-containing 4-alken-1-ols Journal of Organic Chemistry. 54: 5695-5707. DOI: 10.1021/Jo00285A016  1
1989 Heitz MP, Overman LE. Complementary use of iminium ion and N-acyl iminium ion cyclization initiators for asymmetric synthesis of both enantiomers of hydroxylated indolizidines The Journal of Organic Chemistry. 54: 2591-2596. DOI: 10.1021/Jo00272A025  0.01
1989 Overman LE, Robertson GM, Robichaud AJ. Synthesis applications of cationic aza-Cope rearrangements. 20. Total synthesis of (.+-.)-meloscine and (.+-.)-epimeloscine Journal of Organic Chemistry. 54: 1236-1238. DOI: 10.1021/Jo00267A003  1
1989 Hirst GC, Howard PN, Overman LE. Stereocontrolled construction of carbocyclic rings by sequential cationic cyclization-pinacol rearrangements Journal of the American Chemical Society. 111: 1514-1515. DOI: 10.1021/Ja00186A065  0.01
1989 Overman LE, Robichaud AJ. Total syntheses of (+)-geissoschizine, (.+-.)-geissoschizine, and (.+-.)-(Z)-isositsirikine. Stereocontrolled synthesis of exocyclic double bonds by stereospecific iminium ion-vinylsilane cyclizations Journal of the American Chemical Society. 111: 300-308. DOI: 10.1021/Ja00183A046  1
1989 Overman LE, Wild H. Preparation of functionalized hydroindol-3-ols via tandem aza-Cope rearrangement-mannich cyclizations. Formal total synthesis of (±)-6a-epipretazettine and related alkaloids Tetrahedron Letters. 30: 647-650. DOI: 10.1016/S0040-4039(01)80272-0  0.01
1989 HEITZ M, OVERMAN LE. ChemInform Abstract: Complementary Use of Iminium Ion and N-Acyliminium Ion Cyclization Initiators for Asymmetric Synthesis of Both Enantiomers of Hydroxylated Indolizidines. Cheminform. 20. DOI: 10.1002/chin.198947084  0.01
1989 OVERMAN LE, WILD H. ChemInform Abstract: Preparation of Functionalized Hydroindol-3-ols via Tandem Aza-Cope Rearrangement-Mannich Cyclizations. Formal Total Synthesis of (.+-.)-6a-Epipretazettine and Related Alkaloids. Cheminform. 20. DOI: 10.1002/chin.198932303  0.01
1989 LETT RM, OVERMAN LE, ZABLOCKI J. ChemInform Abstract: Synthesis of Allopumiliotoxin A Alkaloids (VI) via Iminium Ion-Vinylsilane Cyclizations. Cheminform. 20. DOI: 10.1002/chin.198926300  0.01
1989 OVERMAN LE, ROBICHAUD AJ. ChemInform Abstract: Total Syntheses of (+)-Geissoschizine, (.+-.)-Geissoschizine, and (.+-.)-(Z)-Isositsirikine. Stereocontrolled Synthesis of Exocyclic Double Bonds by Stereospecific Iminium Ion-Vinylsilane Cyclizations. Cheminform. 20. DOI: 10.1002/chin.198915316  0.01
1989 EARLEY WG, JACOBSEN EJ, MEIER GP, OH T, OVERMAN LE. ChemInform Abstract: Synthesis Studies Directed Toward Gelsemine. A New Synthesis of Highly Functionalized cis-Hydroisoquinolines. Cheminform. 20. DOI: 10.1002/chin.198902187  0.01
1988 Daly JW, McNeal E, Gusovsky F, Ito F, Overman LE. Pumiliotoxin alkaloids: relationship of cardiotonic activity to sodium channel activity and phosphatidylinositol turnover. Journal of Medicinal Chemistry. 31: 477-80. PMID 2448459 DOI: 10.1021/Jm00397A036  1
1988 Fisher MJ, Overman LE. Synthesis and Diels-Alder reactions of 5-alkenyl-1,3-oxathiole 3-oxides. A new class of diheterosubstituted 1,3-dienes The Journal of Organic Chemistry. 53: 2630-2634. DOI: 10.1021/Jo00246A047  0.04
1988 Doedens RJ, Meier GP, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. Part 17. Transition-state geometry of [3,3]-sigmatropic rearrangements of iminium ions Journal of Organic Chemistry. 53: 685-690. DOI: 10.1021/Jo00238A039  1
1988 Overman LE, Sharp MJ. Nucleophile-promoted electrophilic cyclization reactions of alkynes [Erratum to document cited in CA108(7):55853J] Journal of the American Chemical Society. 110: 5934-5934. DOI: 10.1021/Ja00225A074  0.01
1988 Fisher MJ, Hehre WJ, Kahn SD, Overman LE. Face selectivity in Diels-Alder reactions of chiral dienes containing allylic substituents Journal of the American Chemical Society. 110: 4625-4633. DOI: 10.1021/Ja00222A022  0.01
1988 Jacobsen EJ, Levin J, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions Journal of the American Chemical Society. 110: 4329-4336. DOI: 10.1021/Ja00221A037  0.01
1988 Abelman MM, Overman LE. Palladium-catalyzed polyene cyclizations of dienyl aryl iodides Journal of the American Chemical Society. 110: 2328-2329. DOI: 10.1021/Ja00215A068  0.01
1988 Overman LE, Thompson AS. Total synthesis of (-)-laurenyne. Use of acetal-initiated cyclizations to prepare functionalized eight-membered cyclic ethers Journal of the American Chemical Society. 110: 2248-2256. DOI: 10.1021/Ja00215A040  0.01
1988 Overman LE, Sharp MJ. Nucleophile-promoted electrophilic cyclization reactions of alkynes Journal of the American Chemical Society. 110: 612-614. DOI: 10.1021/Ja00210A058  0.01
1988 Overman LE, Sharp MJ. Enantioselective total synthesis of the pumiliotoxin a alkaloids via reductive iminium ion-alkyne cyclizations. Total synthesis of (+)-pumiliotoxin a Tetrahedron Letters. 29: 901-904. DOI: 10.1016/S0040-4039(00)82477-6  0.01
1988 Lett RM, Overman LE, Zablocki J. Synthesis of allopumiliotoxin A alkaloids via iminium ion-vinylsilane cyclizations Tetrahedron Letters. 29: 6541-6544. DOI: 10.1016/S0040-4039(00)82392-8  1
1988 Earley WG, Oh T, Overman LE. Synthesis studies directed toward gelsemine. Preparation of an advanced pentacyclic intermediate Tetrahedron Letters. 29: 3785-3788. DOI: 10.1016/S0040-4039(00)82114-0  0.01
1988 Earley WG, Jacobsen E, Patrick Meier G, Oh T, E. Overman L. Synthesis studies directed toward gelsemine. A new synthesis of highly functionalized cis-hydroisoquinolines Tetrahedron Letters. 29: 3781-3784. DOI: 10.1016/S0040-4039(00)82113-9  0.01
1988 Daub GW, Heerding DA, Overman LE. Synthesis of substituted tetrahydropyridines by cyclizations of silicon-containing iminium ions Tetrahedron. 44: 3919-3930. DOI: 10.1016/S0040-4020(01)86645-X  1
1988 Garraffo H, Edwards M, Spande T, Daly J, Overman LE, Severini C, Erspamer V. A naturally occurring erythro diastereomer of pumiliotoxin b Tetrahedron. 44: 6795-6800. DOI: 10.1016/S0040-4020(01)86205-0  0.01
1988 DAUB GW, HEERDING DA, OVERMAN LE. ChemInform Abstract: Synthesis of Substituted Tetrahydropyridines by Cyclizations of Silicon-Containing Iminium Ions. Cheminform. 19. DOI: 10.1002/chin.198845181  0.01
1988 FISHER MJ, HEHRE WJ, KAHN SD, OVERMAN LE. ChemInform Abstract: Face Selectivity in Diels-Alder Reactions of Chiral Dienes Containing Allylic Substituents. Cheminform. 19. DOI: 10.1002/chin.198845084  0.01
1988 FISHER MJ, OVERMAN LE. ChemInform Abstract: Synthesis and Diels-Alder Reactions of 5-Alkenyl-1,3-oxathiole 3-Oxides. A New Class of Diheterosubstituted 1,3-Dienes. Cheminform. 19. DOI: 10.1002/chin.198843198  0.04
1988 OVERMAN LE, THOMPSON AS. ChemInform Abstract: Total Synthesis of (-)-Laurenyne. Use of Acetal-Initiated Cyclizations to Prepare Functionalized Eight-Membered Cyclic Ethers. Cheminform. 19. DOI: 10.1002/chin.198829292  0.01
1988 ABELMAN MM, OVERMAN LE. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations of Dienyl Aryl Iodides. Cheminform. 19. DOI: 10.1002/chin.198829144  0.01
1988 OVERMAN LE, SHARP MJ. ChemInform Abstract: Nucleophile-Promoted Electrophilic Cyclization Reactions of Alkynes. Cheminform. 19. DOI: 10.1002/chin.198818208  0.01
1988 ABELMAN MM, OH T, OVERMAN LE. ChemInform Abstract: Intramolecular Alkene Arylations for Rapid Assembly of Polycyclic Systems Containing Quaternary Centers. A New Synthesis of Spirooxindoles and Other Fused and Bridged Ring Systems. Cheminform. 19. DOI: 10.1002/chin.198809246  0.01
1988 FLANN CJ, OVERMAN LE. ChemInform Abstract: Enantioselective Total Synthesis of Streptazolin. The Tandem Use of Iminium Ion-Vinylsilane Cyclizations and Intramolecular Acylations. Cheminform. 19. DOI: 10.1002/chin.198803348  0.01
1988 FLANN C, MALONE TC, OVERMAN LE. ChemInform Abstract: Iminium Ion and Acyliminium Ion Initiated Cyclization Reactions of Vinylsilanes. Regiocontrolled Synthesis of Tetrahydropyridines and Related Heterocycles. Cheminform. 19. DOI: 10.1002/chin.198803180  0.01
1988 MCCANN SF, OVERMAN LE. ChemInform Abstract: Medium Effects and the Nature of the Rate-Determining Step in Mannich-Type Cyclizations. Cheminform. 19. DOI: 10.1002/chin.198803089  0.01
1988 HERRINTON PM, HOPKINS MH, MISHRA P, BROWN MJ, OVERMAN LE. ChemInform Abstract: Ring-Enlarging Furan Annulations. Cheminform. 19. DOI: 10.1002/chin.198802189  0.01
1987 Herrinton PH, Hopkins MH, Mishra P, Brown MJ, Overman LE. Ring-enlarging furan annulations The Journal of Organic Chemistry. 52: 3711-3712. DOI: 10.1021/Jo00392A048  0.01
1987 Abelman MM, Oh T, Overman LE. Intramolecular alkene arylations for rapid assembly of polycyclic systems containing quaternary centers. A new synthesis of spirooxindoles and other fused and bridged ring systems The Journal of Organic Chemistry. 52: 4130-4133. DOI: 10.1021/Jo00227A038  0.01
1987 Flann CJ, Overman LE. Enantioselective total synthesis of streptazolin. The tandem use of iminium ion vinylsilane cyclizations and intramolecular acylations Journal of the American Chemical Society. 109: 6115-6118. DOI: 10.1021/Ja00254A034  0.01
1987 McCann SF, Overman LE. Medium effects and the nature of the rate-determining step in Mannich-type cyclizations Journal of the American Chemical Society. 109: 6107-6114. DOI: 10.1021/Ja00254A033  0.01
1987 Flann C, Malone TC, Overman LE. Iminium ion and acyliminium ion initiated cyclization reactions of vinylsilanes. Regiocontrolled synthesis of tetrahydropyridines and related heterocycles Journal of the American Chemical Society. 109: 6097-6107. DOI: 10.1021/Ja00254A032  0.01
1987 Hopkins MH, Overman LE. Stereocontrolled preparation of tetrahydrofurans by acid-catalyzed rearrangement of allylic acetals Journal of the American Chemical Society. 109: 4748-4749. DOI: 10.1021/Ja00249A063  0.01
1987 HOPKINS MH, OVERMAN LE. ChemInform Abstract: Stereocontrolled Preparation of Tetrahydrofurans by Acid-Catalyzed Rearrangement of Allylic Acetals. Cheminform. 18. DOI: 10.1002/chin.198747183  0.01
1987 KAHN SD, PAU CF, OVERMAN LE, HEHRE WJ. ChemInform Abstract: Modeling Chemical Reactivity. Part 1. Regioselectivity of Diels-Alder Cycloadditions of Electron-Rich Dienes with Electron-Deficient Dienophiles. Cheminform. 18. DOI: 10.1002/chin.198713094  0.01
1987 BLUMENKOPF TA, OVERMAN LE. ChemInform Abstract: Vinylsilane- and Allylsilane-Terminated Cyclization Reactions Cheminform. 18. DOI: 10.1002/chin.198710363  0.01
1987 OVERMAN LE, OKAZAKI ME, MISHRA P. ChemInform Abstract: tert-Butyldiphenylsilylamines: A Useful Protecting Group for Primary Amines. Cheminform. 18. DOI: 10.1002/chin.198707236  0.01
1986 Kahn SD, Pau CF, Overman LE, Hehre WJ. Modeling chemical reactivity. 1. Regioselectivity of Diels-Alder cycloadditions of electron-rich dienes with electron-deficient dienophiles Journal of the American Chemical Society. 108: 7381-7396. DOI: 10.1021/Ja00283A038  0.01
1986 Overman LE, Castaneda A, Blumenkopf TA. Acetal-initiated cyclizations of vinylsilanes. A general synthesis of allylically unsaturated oxacyclics Journal of the American Chemical Society. 108: 1303-1304. DOI: 10.1021/Ja00266A034  0.01
1986 Blumenkopf TA, Overman LE. Vinylsilane- and alkynylsilane-terminated cyclization reactions Chemical Reviews. 86: 857-873. DOI: 10.1021/Cr00075A009  0.01
1986 Overman LE, Okazaki ME, Mishra P. -Butyldiphenylsilylamines: A useful protecting group for primary amines Tetrahedron Letters. 27: 4391-4394. DOI: 10.1016/S0040-4039(00)84960-6  0.01
1986 OVERMAN LE, BLUMENKOPF TA, CASTANEDA A, THOMPSON AS. ChemInform Abstract: Efficient Preparations of 8- and 9-Membered Cyclic Ethers. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198642226  0.01
1986 Overman LE, Blumenkopf TA, Castaneda A, Thompson AS. Efficient preparations of 8- and 9-membered cyclic ethers Journal of the American Chemical Society. 108: 3516-3517. DOI: 10.1002/Chin.198642226  0.01
1986 OVERMAN LE, LIN N. ChemInform Abstract: Enantioselective Total Synthesis of (+)-Pumiliotoxin A. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198616340  0.04
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