Robert G. Bergman - Publications

Affiliations: 
University of California, Berkeley, Berkeley, CA 
Area:
mechanisms of organic reactions
Website:
http://www.cchem.berkeley.edu/rgbgrp/rgbbio.html

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Year Citation  Score
2022 Bierschenk SM, Pan JY, Settineri NS, Warzok U, Bergman RG, Raymond KN, Toste FD. Impact of Host Flexibility on Selectivity in a Supramolecular Host-Catalyzed Enantioselective aza-Darzens Reaction. Journal of the American Chemical Society. 144: 11425-11433. PMID 35700232 DOI: 10.1021/jacs.2c04182  0.605
2022 Nguyen QNN, Xia KT, Zhang Y, Chen N, Morimoto M, Pei X, Ha Y, Guo J, Yang W, Wang LP, Bergman RG, Raymond KN, Toste FD, Tantillo DJ. Source of Rate Acceleration for Carbocation Cyclization in Biomimetic Supramolecular Cages. Journal of the American Chemical Society. PMID 35699585 DOI: 10.1021/jacs.2c04179  0.57
2022 Jain A, Fostvedt JI, Kriegel BM, Small DW, Grant LN, Bergman RG, Arnold J. [3 + 2] Cycloadditions and Retrocycloadditions of Niobium Imido Complexes: An Experimental and Computational Mechanistic Study. Inorganic Chemistry. 61: 6574-6583. PMID 35436407 DOI: 10.1021/acs.inorgchem.2c00428  0.516
2022 Ouellette ET, Magdalenski JS, Bergman RG, Arnold J. Applications of Low-Valent Transition Metalates: Development of a Reactive Noncarbonyl Rhenium(I) Anion. Accounts of Chemical Research. PMID 35171568 DOI: 10.1021/acs.accounts.2c00013  0.445
2021 Fostvedt JI, Boreen MA, Bergman RG, Arnold J. A Diverse Array of C-C Bonds Formed at a Tantalum Metal Center. Inorganic Chemistry. PMID 34125521 DOI: 10.1021/acs.inorgchem.1c01159  0.546
2021 Ouellette ET, Carpentier A, Joseph Brackbill I, Lohrey TD, Douair I, Maron L, Bergman RG, Arnold J. σ or π? Bonding interactions in a series of rhenium metallotetrylenes. Dalton Transactions (Cambridge, England : 2003). PMID 33481968 DOI: 10.1039/d1dt00129a  0.481
2021 Morimoto M, Cao W, Bergman RG, Raymond KN, Toste FD. Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine-Borane Cofactor. Journal of the American Chemical Society. PMID 33471541 DOI: 10.1021/jacs.0c12479  0.593
2020 Fostvedt JI, Grant LN, Kriegel BM, Obenhuber AH, Lohrey TD, Bergman RG, Arnold J. 1,2-Addition and cycloaddition reactions of niobium bis(imido) and oxo imido complexes. Chemical Science. 11: 11613-11632. PMID 34094408 DOI: 10.1039/d0sc03489d  0.551
2020 Huang B, He Y, Levin MD, Coelho JAS, Bergman RG, Toste FD. Enantioselective Kinetic Resolution/Desymmetrization of -Quinols: A Case Study in Boronic-Acid-Directed Phosphoric Acid Catalysis. Advanced Synthesis & Catalysis. 362: 295-301. PMID 34093103 DOI: 10.1002/adsc.201900816  0.714
2020 Sebastiani F, Bender TA, Pezzotti S, Li WL, Schwaab G, Bergman RG, Raymond KN, Toste FD, Head-Gordon T, Havenith M. An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage. Proceedings of the National Academy of Sciences of the United States of America. PMID 33318176 DOI: 10.1073/pnas.2012545117  0.503
2020 Miyamura H, Bergman RG, Raymond KN, Toste FD. Heterogeneous Supramolecular Catalysis through Immobilization of Anionic ML Assemblies on Cationic Polymers. Journal of the American Chemical Society. 142: 19327-19338. PMID 33136406 DOI: 10.1021/jacs.0c09556  0.564
2020 Lohrey TD, Rao G, Small DW, Ouellette ET, Bergman RG, Britt RD, Arnold J. Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts. Journal of the American Chemical Society. 142: 13805-13813. PMID 32786815 DOI: 10.1021/Jacs.0C04719  0.51
2020 Lohrey TD, Cortes EA, Fostvedt JI, Oanta AK, Jain A, Bergman RG, Arnold J. Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions. Inorganic Chemistry. PMID 32662634 DOI: 10.1021/Acs.Inorgchem.0C01589  0.6
2020 Lohrey TD, Cortes EA, Bergman RG, Arnold J. Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes. Inorganic Chemistry. PMID 32339452 DOI: 10.1021/Acs.Inorgchem.0C00658  0.59
2020 Lohrey TD, Fostvedt JI, Bergman RG, Arnold J. Electron acceptors promote proton-hydride tautomerism in low valent rhenium β-diketiminates. Chemical Communications (Cambridge, England). PMID 32125313 DOI: 10.1039/C9Cc09475J  0.472
2020 Bierschenk SM, Bergman RG, Raymond KN, Toste FD. A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction. Journal of the American Chemical Society. PMID 31909615 DOI: 10.1021/Jacs.9B13177  0.637
2019 Lohrey TD, Bergman RG, Arnold J. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. Dalton Transactions (Cambridge, England : 2003). 48: 17936-17944. PMID 31793591 DOI: 10.1039/C9Dt04489B  0.481
2019 Fostvedt JI, Lohrey TD, Bergman RG, Arnold J. Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal-carbon bonds. Chemical Communications (Cambridge, England). 55: 13263-13266. PMID 31621710 DOI: 10.1039/C9Cc07686G  0.608
2019 Lohrey TD, Rao G, Britt RD, Bergman RG, Arnold J. H Activation and Direct Access to Terminal Nitride and -P Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate. Inorganic Chemistry. PMID 31550147 DOI: 10.1021/Acs.Inorgchem.9B02556  0.544
2019 Bender TA, Bergman RG, Raymond KN, Toste FD. A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length. Journal of the American Chemical Society. PMID 31310528 DOI: 10.1021/Jacs.9B05604  0.639
2019 Bender TA, Morimoto M, Bergman RG, Raymond KN, Toste FD. Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics. Journal of the American Chemical Society. PMID 30667233 DOI: 10.1021/Jacs.8B11842  0.62
2019 Baumgartner J, Bergman R, Kayser B, Klupinski T, Park Y, Vollhardt K, West M, Zhu B. The Quest for Double Vicinal C–H Bond Activation on the (η 5:η 5-Fulvalene)diiridium Platform: Syntheses and Structures of (η 5:η 5-Fulvalene)Ir2(ortho-μ-C6H4)(CO)2 (Ir–Ir) and Related Complexes Synthesis. 51: 2409-2429. DOI: 10.1055/S-0037-1611736  0.794
2019 Stelson AC, Hong CM, Groenenboom MC, Little CAE, Booth JC, Orloff ND, Bergman RG, Raymond KN, Schwarz KA, Toste FD, Long CJ. Measuring ion-pairing and hydration in variable charge supramolecular cages with microwave microfluidics Communications Chemistry. 2. DOI: 10.1038/s42004-019-0157-9  0.697
2019 Huang B, He Y, Levin MD, Coelho JAS, Bergman RG, Toste FD. Enantioselective Kinetic Resolution/Desymmetrization of Para ‐Quinols: A Case Study in Boronic‐Acid‐Directed Phosphoric Acid Catalysis Advanced Synthesis & Catalysis. 362: 295-301. DOI: 10.1002/Adsc.201900816  0.739
2018 Lohrey TD, Maron L, Bergman RG, Arnold J. A Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate. Journal of the American Chemical Society. PMID 30571106 DOI: 10.1021/Jacs.8B12494  0.565
2018 Hong CM, Bergman RG, Raymond KN, Toste FD. Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts. Accounts of Chemical Research. PMID 30272943 DOI: 10.1021/Acs.Accounts.8B00328  0.788
2018 Hong CM, Morimoto M, Kapustin EA, Alzakhem N, Bergman RG, Raymond KN, Toste FD. Deconvoluting the Role of Charge in a Supramolecular Catalyst. Journal of the American Chemical Society. PMID 29767972 DOI: 10.1021/Jacs.8B01701  0.754
2018 Ziegler JA, Prange C, Lohrey TD, Bergman RG, Arnold J. Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes. Inorganic Chemistry. PMID 29624377 DOI: 10.1021/Acs.Inorgchem.8B00247  0.585
2018 Lohrey TD, Bergman RG, Arnold J. Reductions of a Rhenium(III) Terminal Oxo Complex by Isocyanides and Carbon Monoxide Organometallics. 37: 3552-3557. DOI: 10.1021/Acs.Organomet.8B00238  0.582
2017 Schepartz A, Bergman R, Grubbs RH. Ronald Breslow (1931-2017). Angewandte Chemie (International Ed. in English). PMID 29235715 DOI: 10.1002/Anie.201711641  0.594
2017 Lohrey T, Bergman R, Arnold J. Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. Angewandte Chemie (International Ed. in English). PMID 28929597 DOI: 10.1002/Anie.201707957  0.558
2017 Garner ME, Parker BF, Hohloch S, Bergman RG, Arnold J. Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination. Journal of the American Chemical Society. PMID 28892619 DOI: 10.1021/Jacs.7B08323  0.597
2017 Hong CM, Kaphan DM, Bergman RG, Raymond KN, Toste FD. Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host. Journal of the American Chemical Society. PMID 28581740 DOI: 10.1021/Jacs.7B03812  0.756
2017 Kriegel BM, Naested LC, Nocton G, Lakshmi KV, Lohrey TD, Bergman RG, Arnold J. Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes. Inorganic Chemistry. PMID 28098983 DOI: 10.1021/Acs.Inorgchem.6B02735  0.56
2017 Kriegel BM, Kaltsoyannis N, Chatterjee R, Bergman RG, Arnold J. Synthesis and Redox Chemistry of a Tantalum Alkylidene Complex Bearing a Metallaimidazole Ring Organometallics. 36: 3520-3529. DOI: 10.1021/Acs.Organomet.7B00448  0.548
2016 Lohrey TD, Bergman RG, Arnold J. Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex. Inorganic Chemistry. 55: 11993-12000. PMID 27934320 DOI: 10.1021/Acs.Inorgchem.6B02122  0.495
2016 Chen S, Bacauanu V, Knecht T, Mercado BQ, Bergman RG, Ellman JA. New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks. Journal of the American Chemical Society. 138: 12664-70. PMID 27642766 DOI: 10.1021/Jacs.6B08355  0.579
2016 Ziegler JA, Bergman RG, Arnold J. Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27461382 DOI: 10.1039/C6Dt02373H  0.549
2016 Levin MD, Kaphan DM, Hong CM, Bergman RG, Raymond KN, Toste FD. Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis. Journal of the American Chemical Society. PMID 27458778 DOI: 10.1021/Jacs.6B05442  0.829
2016 Hohloch S, Kriegel BM, Bergman RG, Arnold J. Group 5 chemistry supported by β-diketiminate ligands. Dalton Transactions (Cambridge, England : 2003). PMID 27327510 DOI: 10.1039/C6Dt01770C  0.526
2016 Liberman-Martin AL, Levine DS, Ziegler MS, Bergman RG, Tilley TD. Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. Chemical Communications (Cambridge, England). PMID 27161155 DOI: 10.1039/C6Cc02433E  0.816
2016 Camp C, Grant LN, Bergman RG, Arnold J. Photo-activation of d(0) niobium imido azides: en route to nitrido complexes. Chemical Communications (Cambridge, England). PMID 27033145 DOI: 10.1039/C6Cc02081J  0.536
2016 Wangweerawong A, Hummel JR, Bergman RG, Ellman JA. Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids. The Journal of Organic Chemistry. PMID 26844947 DOI: 10.1021/Acs.Joc.5B02700  0.597
2016 Brown CJ, Kokai A, Miller GM, Bergman RG, Raymond KN. Improved scope and diastereoselectivity of C-H activation in an expanded supramolecular host Supramolecular Chemistry. 28: 188-191. DOI: 10.6084/M9.Figshare.2068773.V1  0.693
2016 Liberman-Martin AL, Levine DS, Liu W, Bergman RG, Tilley TD. Biaryl Reductive Elimination Is Dramatically Accelerated by Remote Lewis Acid Binding to a 2,2′-Bipyrimidyl–Platinum Complex: Evidence for a Bidentate Ligand Dissociation Mechanism Organometallics. 35: 1064-1069. DOI: 10.1021/Acs.Organomet.5B01003  0.795
2016 Liberman-Martin AL, Ziegler MS, DiPasquale AG, Bergman RG, Tilley TD. Functionalization of an iridium-diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources Polyhedron. DOI: 10.1016/J.Poly.2016.03.044  0.82
2016 Hohloch S, Kriegel BM, Bergman RG, Arnold J. ChemInform Abstract: Group 5 Chemistry Supported by β-Diketiminate Ligands Cheminform. 47. DOI: 10.1002/chin.201648229  0.367
2015 Hart-Cooper WM, Zhao C, Triano RM, Yaghoubi P, Ozores HL, Burford KN, Toste FD, Bergman RG, Raymond KN. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations. Chemical Science. 6: 1383-1393. PMID 29560226 DOI: 10.1039/C4Sc02735C  0.653
2015 Gianetti TL, Nocton G, Minasian SG, Kaltsoyannis N, Kilcoyne ALD, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Electron localization in a mixed-valence diniobium benzene complex. Chemical Science. 6: 993-1003. PMID 29560186 DOI: 10.1039/C4Sc02705A  0.814
2015 Kaphan DM, Levin MD, Bergman RG, Raymond KN, Toste FD. A supramolecular microenvironment strategy for transition metal catalysis. Science (New York, N.Y.). 350: 1235-8. PMID 26785485 DOI: 10.1126/Science.Aad3087  0.767
2015 Kriegel BM, Bergman RG, Arnold J. Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. Journal of the American Chemical Society. PMID 26698833 DOI: 10.1021/Jacs.5B11287  0.564
2015 Hart-Cooper WM, Sgarlata C, Perrin CL, Toste FD, Bergman RG, Raymond KN. Protein-like proton exchange in a synthetic host cavity. Proceedings of the National Academy of Sciences of the United States of America. PMID 26621709 DOI: 10.1073/Pnas.1515639112  0.602
2015 Matsushima Y, Phillips EM, Bergman RG, Ellman JA. Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 26: 1533-1536. PMID 26609195 DOI: 10.1055/S-0034-1380359  0.578
2015 Dalton DM, Ellis SR, Nichols EM, Mathies RA, Toste FD, Bergman RG, Raymond KN. Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer. Journal of the American Chemical Society. 137: 10128-31. PMID 26256754 DOI: 10.1021/Jacs.5B06317  0.769
2015 Nechayev M, Gianetti TL, Bergman RG, Arnold J. C-F sp(2) bond functionalization mediated by niobium complexes. Dalton Transactions (Cambridge, England : 2003). 44: 19494-19500. PMID 26216334 DOI: 10.1039/C5Dt02082D  0.79
2015 Kaphan DM, Toste FD, Bergman RG, Raymond KN. Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization. Journal of the American Chemical Society. 137: 9202-5. PMID 26176416 DOI: 10.1021/Jacs.5B01261  0.645
2015 Chen S, Mercado BQ, Bergman RG, Ellman JA. Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines. The Journal of Organic Chemistry. 80: 6660-8. PMID 26098485 DOI: 10.1021/Acs.Joc.5B00816  0.558
2015 Chen S, Bergman RG, Ellman JA. Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines. Organic Letters. 17: 2567-9. PMID 25992591 DOI: 10.1021/Acs.Orglett.5B00979  0.548
2015 Brown CJ, Toste FD, Bergman RG, Raymond KN. Supramolecular catalysis in metal-ligand cluster hosts. Chemical Reviews. 115: 3012-35. PMID 25898212 DOI: 10.1021/Cr4001226  0.705
2015 Liberman-Martin AL, Bergman RG, Tilley TD. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Journal of the American Chemical Society. 137: 5328-31. PMID 25879515 DOI: 10.1021/Jacs.5B02807  0.803
2015 Obenhuber AH, Gianetti TL, Bergman RG, Arnold J. Regioselective [2+2] and [4+2] cycloaddition reactivity in an asymmetric niobium(bisimido) moiety towards unsaturated organic molecules. Chemical Communications (Cambridge, England). 51: 1278-81. PMID 25475703 DOI: 10.1039/C4Cc07851A  0.808
2015 Kaphan DM, Levin MD, Bergman RG, Raymond KN, Toste FD. A supramolecular microenvironment strategy for transition metal catalysis Science. 350: 1235-1238. DOI: 10.1126/science.aad3087  0.704
2015 Matsushima Y, Phillips EM, Bergman RG, Ellman JA. Rhodium(I)-Catalyzed Cycloisomerization of 1,6-Enynes Synlett. 26: 1533-1536. DOI: 10.1055/s-0034-1380359  0.532
2015 Hart-Cooper WM, Zhao C, Triano RM, Yaghoubi P, Ozores HL, Burford KN, Toste FD, Bergman RG, Raymond KN. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations Chemical Science. 6: 1383-1393. DOI: 10.1039/c4sc02735c  0.537
2015 Gianetti TL, Nocton G, Minasian SG, Kaltsoyannis N, Kilcoyne ALD, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Electron localization in a mixed-valence diniobium benzene complex Chemical Science. 6: 993-1003. DOI: 10.1039/c4sc02705a  0.624
2015 Zhang Y, Roberts SP, Bergman RG, Ess DH. Mechanism and catalytic impact of Ir-Ta heterobimetallic and Ir-P transition metal/main group interactions on alkene hydrogenation Acs Catalysis. 5: 1840-1849. DOI: 10.1021/Cs501884J  0.538
2015 Liberman-Martin AL, Bergman RG, Tilley TD. ChemInform Abstract: Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Cheminform. 46: no-no. DOI: 10.1002/chin.201538046  0.782
2015 Brown CJ, Toste FD, Bergman RG, Raymond KN. ChemInform Abstract: Supramolecular Catalysis in Metal-Ligand Cluster Hosts Cheminform. 46: no-no. DOI: 10.1002/chin.201529299  0.688
2014 Camp C, Maron L, Bergman RG, Arnold J. Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds. Journal of the American Chemical Society. 136: 17652-61. PMID 25469924 DOI: 10.1021/Ja5107282  0.516
2014 Zhao C, Toste FD, Raymond KN, Bergman RG. Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry. Journal of the American Chemical Society. 136: 14409-12. PMID 25265509 DOI: 10.1021/Ja508799P  0.691
2014 Johnson MW, DiPasquale AG, Bergman RG, Toste FD. Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors. Organometallics. 33: 4169-4172. PMID 25180022 DOI: 10.1021/Om500663M  0.716
2014 Wangweerawong A, Bergman RG, Ellman JA. Asymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization. Journal of the American Chemical Society. 136: 8520-3. PMID 24901217 DOI: 10.1021/Ja5033452  0.6
2014 Kriegel BM, Bergman RG, Arnold J. Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex. Dalton Transactions (Cambridge, England : 2003). 43: 10046-56. PMID 24870398 DOI: 10.1039/C4Dt00923A  0.557
2014 Johnson MW, Bagley SW, Mankad NP, Bergman RG, Mascitti V, Toste FD. Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives. Angewandte Chemie (International Ed. in English). 53: 4404-7. PMID 24652820 DOI: 10.1002/Anie.201400037  0.706
2014 Hastings CJ, Bergman RG, Raymond KN. Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3966-73. PMID 24615703 DOI: 10.1002/Chem.201303885  0.796
2014 Duttwyler S, Chen S, Lu C, Mercado BQ, Bergman RG, Ellman JA. Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers. Angewandte Chemie (International Ed. in English). 53: 3877-80. PMID 24604837 DOI: 10.1002/Anie.201310517  0.536
2014 Obenhuber AH, Gianetti TL, Berrebi X, Bergman RG, Arnold J. Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer. Journal of the American Chemical Society. 136: 2994-7. PMID 24524190 DOI: 10.1021/Ja413194Z  0.792
2014 Zhao C, Crimmin MR, Toste FD, Bergman RG. Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization. Accounts of Chemical Research. 47: 517-29. PMID 24359109 DOI: 10.1021/Ar400176X  0.798
2014 Gianetti TL, Bergman RG, Arnold J. Carbon-fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: From stoichiometric to catalytic hydrodefluorination Chemical Science. 5: 2517-2524. DOI: 10.1039/C4Sc00006D  0.806
2014 Duttwyler S, Lu C, Rheingold AL, Bergman RG, Ellman JA. Correction to “Highly Diastereoselective Synthesis of Tetrahydropyridines by a C–H Activation–Cyclization–Reduction Cascade” Journal of the American Chemical Society. 136: 11849-11849. DOI: 10.1021/Ja507742P  0.508
2014 Gianetti TL, Bergman RG, Arnold J. Stoichiometric carbon-carbon bond formation mediated by well defined Nb(III) complexes Dedicated to Professor John E. Bercaw, for his deep and wide-ranging contributions to organometallic chemistry and catalysis. Polyhedron. 84: 19-23. DOI: 10.1016/J.Poly.2014.05.031  0.805
2014 Nechayev M, Kriegel BM, Gianetti TL, Bergman RG, Arnold J. Synthesis and characterization of group 5 imido complexes supported by the 2,6-dichloroaryl β-diketiminato ligand Inorganica Chimica Acta. 422: 114-119. DOI: 10.1016/J.Ica.2014.07.006  0.782
2014 Johnson MW, Bagley SW, Mankad NP, Bergman RG, Mascitti V, Toste FD. ChemInform Abstract: Application of Fundamental Organometallic Chemistry to the Development of a Gold-Catalyzed Synthesis of Sulfinate Derivatives. Cheminform. 45: no-no. DOI: 10.1002/chin.201441091  0.658
2014 Zhao C, Sun Q, Hart-Cooper WM, DiPasquale AG, Toste FD, Bergman RG, Raymond KN. ChemInform Abstract: Chiral Amide Directed Assembly of a Diastereo- and Enantiopure Supramolecular Host and Its Application to Enantioselective Catalysis of Neutral Substrates. Cheminform. 45: no-no. DOI: 10.1002/chin.201427059  0.568
2014 Bowring MA, Bergman RG, Tilley TD. ChemInform Abstract: Pt-Catalyzed C-C Activation Induced by C-H Activation. Cheminform. 45: no-no. DOI: 10.1002/chin.201408108  0.785
2013 Zhao C, Sun QF, Hart-Cooper WM, DiPasquale AG, Toste FD, Bergman RG, Raymond KN. Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates. Journal of the American Chemical Society. 135: 18802-5. PMID 24283463 DOI: 10.1021/Ja411631V  0.671
2013 La Pierre HS, Minasian SG, Abubekerov M, Kozimor SA, Shuh DK, Tyliszczak T, Arnold J, Bergman RG, Toste FD. Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy. Inorganic Chemistry. 52: 11650-60. PMID 24024833 DOI: 10.1021/Ic4020543  0.799
2013 Bowring MA, Bergman RG, Tilley TD. Pt-catalyzed C-C activation induced by C-H activation. Journal of the American Chemical Society. 135: 13121-8. PMID 23962182 DOI: 10.1021/Ja406260J  0.811
2013 Lian Y, Hummel JR, Bergman RG, Ellman JA. Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade. Journal of the American Chemical Society. 135: 12548-51. PMID 23957711 DOI: 10.1021/Ja406131A  0.604
2013 Liberman-Martin AL, Bergman RG, Tilley TD. A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. Journal of the American Chemical Society. 135: 9612-5. PMID 23789917 DOI: 10.1021/Ja404339U  0.796
2013 Gianetti TL, Bergman RG, Arnold J. Dis-assembly of a benzylic CF3 group mediated by a niobium(III) imido complex. Journal of the American Chemical Society. 135: 8145-8. PMID 23663120 DOI: 10.1021/Ja4033007  0.786
2013 Lian Y, Bergman RG, Lavis LD, Ellman JA. Rhodium(III)-catalyzed indazole synthesis by C-H bond functionalization and cyclative capture. Journal of the American Chemical Society. 135: 7122-5. PMID 23642256 DOI: 10.1021/Ja402761P  0.606
2013 Brasse M, Cámpora J, Ellman JA, Bergman RG. Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activation. Journal of the American Chemical Society. 135: 6427-30. PMID 23590843 DOI: 10.1021/Ja401561Q  0.612
2013 Ischay MA, Takase MK, Bergman RG, Ellman JA. Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systems. Journal of the American Chemical Society. 135: 2478-81. PMID 23398467 DOI: 10.1021/Ja312311K  0.528
2013 Duttwyler S, Chen S, Takase MK, Wiberg KB, Bergman RG, Ellman JA. Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis. Science (New York, N.Y.). 339: 678-82. PMID 23393259 DOI: 10.1126/Science.1230704  0.585
2013 Mugridge JS, Zahl A, van Eldik R, Bergman RG, Raymond KN. Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host. Journal of the American Chemical Society. 135: 4299-306. PMID 23391095 DOI: 10.1021/Ja309949Q  0.461
2013 Wang ZJ, Clary KN, Bergman RG, Raymond KN, Toste FD. A supramolecular approach to combining enzymatic and transition metal catalysis. Nature Chemistry. 5: 100-3. PMID 23344446 DOI: 10.1038/Nchem.1531  0.664
2013 Gianetti TL, Nocton G, Minasian SG, Tomson NC, Kilcoyne AL, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Diniobium inverted sandwich complexes with μ-η6:η6-arene ligands: synthesis, kinetics of formation, and electronic structure. Journal of the American Chemical Society. 135: 3224-36. PMID 23343247 DOI: 10.1021/Ja311966H  0.825
2013 Martin RM, Bergman RG, Ellman JA. Synthesis of isoquinuclidines from highly substituted dihydropyridines via the Diels-Alder reaction. Organic Letters. 15: 444-7. PMID 23320852 DOI: 10.1021/Ol303040R  0.724
2013 Lian Y, Huber T, Hesp KD, Bergman RG, Ellman JA. Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles. Angewandte Chemie (International Ed. in English). 52: 629-33. PMID 23172703 DOI: 10.1002/Anie.201207995  0.623
2013 Duttwyler S, Chen S, Takase MK, Wiberg KB, Bergman RG, Ellman JA. Nitrogen-Containing Heterocycle Synthesis Initiated by Rh(III)-Catalyzed C−H Activation Synfacts. 9: 521-521. DOI: 10.1055/S-0033-1338387  0.567
2013 Johnson MW, Shevick SL, Toste FD, Bergman RG. Preparation and reactivity of terminal gold(i) amides and phosphides Chemical Science. 4: 1023-1027. DOI: 10.1039/C2Sc21519E  0.726
2013 Bowring MA, Bergman RG, Tilley TD. Isolation of a dicationic platinum complex with two accessible coordination sites Organometallics. 32: 5266-5268. DOI: 10.1021/Om4008357  0.811
2013 Martin RM, Bergman RG, Ellman JA. ChemInform Abstract: Synthesis of Isoquinuclidines from Highly Substituted Dihydropyridines via the Diels-Alder Reaction. Cheminform. 44: no-no. DOI: 10.1002/chin.201324146  0.616
2013 Lian Y, Huber T, Hesp KD, Bergman RG, Ellman JA. ChemInform Abstract: Rhodium(III)-Catalyzed Alkenyl C-H Bond Functionalization: Convergent Synthesis of Furans and Pyrroles. Cheminform. 44: no-no. DOI: 10.1002/chin.201320038  0.301
2012 La Pierre HS, Arnold J, Bergman RG, Toste FD. Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals. Inorganic Chemistry. 51: 13334-44. PMID 23181489 DOI: 10.1021/Ic302044Q  0.796
2012 Hart-Cooper WM, Clary KN, Toste FD, Bergman RG, Raymond KN. Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst. Journal of the American Chemical Society. 134: 17873-6. PMID 23066637 DOI: 10.1021/Ja308254K  0.637
2012 Lian Y, Bergman RG, Ellman JA. Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes. Chemical Science (Royal Society of Chemistry : 2010). 3: 3088-3092. PMID 23050074 DOI: 10.1039/C2Sc20835K  0.622
2012 Hesp KD, Bergman RG, Ellman JA. Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines. Organic Letters. 14: 2304-7. PMID 22500854 DOI: 10.1021/Ol300723X  0.611
2012 Duttwyler S, Lu C, Rheingold AL, Bergman RG, Ellman JA. Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascade. Journal of the American Chemical Society. 134: 4064-7. PMID 22356093 DOI: 10.1021/Ja2119833  0.594
2012 Martin RM, Bergman RG, Ellman JA. Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization. The Journal of Organic Chemistry. 77: 2501-7. PMID 22332639 DOI: 10.1021/Jo202280E  0.74
2012 Tauchert ME, Incarvito CD, Rheingold AL, Bergman RG, Ellman JA. Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate. Journal of the American Chemical Society. 134: 1482-5. PMID 22257031 DOI: 10.1021/Ja211110H  0.634
2012 Colby DA, Tsai AS, Bergman RG, Ellman JA. Rhodium catalyzed chelation-assisted C-H bond functionalization reactions. Accounts of Chemical Research. 45: 814-25. PMID 22148885 DOI: 10.1021/Ar200190G  0.73
2012 Mugridge JS, Bergman RG, Raymond KN. Equilibrium isotope effects on noncovalent interactions in a supramolecular host-guest system. Journal of the American Chemical Society. 134: 2057-66. PMID 22145944 DOI: 10.1021/Ja2067324  0.494
2012 Curley JJ, Bergman RG, Tilley TD. Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Dalton Transactions (Cambridge, England : 2003). 41: 192-200. PMID 22020701 DOI: 10.1039/C1Dt11753J  0.545
2012 Snieckus V, Rantanen T, Martin RM, Bergman RG, Ellman JA. Rh-Catalyzed De Novo Synthesis of Pyridines from Terminal Alkynes and Ketoximes Synfacts. 8: 607-607. DOI: 10.1055/S-0031-1291070  0.57
2012 Koller J, Bergman RG. Controlled hydrosilylation of carbonyls and imines catalyzed by a cationic aluminum alkyl complex Organometallics. 31: 2530-2533. DOI: 10.1021/Om2008277  0.425
2012 Martin RM, Bergman RG, Ellman JA. ChemInform Abstract: Synthesis of Pyridines from Ketoximes and Terminal Alkynes via C-H Bond Functionalization. Cheminform. 43: no-no. DOI: 10.1002/chin.201227149  0.622
2011 Tomson NC, Crimmin MR, Petrenko T, Rosebrugh LE, Sproules S, Boyd WC, Bergman RG, DeBeer S, Toste FD, Wieghardt K. A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni). Journal of the American Chemical Society. 133: 18785-801. PMID 22047035 DOI: 10.1021/Ja206042K  0.785
2011 Hastings CJ, Backlund MP, Bergman RG, Raymond KN. Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization. Angewandte Chemie (International Ed. in English). 50: 10570-3. PMID 21932275 DOI: 10.1002/Anie.201105325  0.757
2011 Gianetti TL, Tomson NC, Arnold J, Bergman RG. Z-selective, catalytic internal alkyne semihydrogenation under H2/CO mixtures by a niobium(III) imido complex. Journal of the American Chemical Society. 133: 14904-7. PMID 21854008 DOI: 10.1021/Ja206016S  0.832
2011 Brown CJ, Miller GM, Johnson MW, Bergman RG, Raymond KN. High-turnover supramolecular catalysis by a protected ruthenium(II) complex in aqueous solution. Journal of the American Chemical Society. 133: 11964-6. PMID 21736357 DOI: 10.1021/Ja205257X  0.76
2011 Hesp KD, Bergman RG, Ellman JA. Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates. Journal of the American Chemical Society. 133: 11430-3. PMID 21714533 DOI: 10.1021/Ja203495C  0.6
2011 Mugridge JS, Bergman RG, Raymond KN. 1H NMR chemical shift calculations as a probe of supramolecular host-guest geometry. Journal of the American Chemical Society. 133: 11205-12. PMID 21714506 DOI: 10.1021/Ja202254X  0.461
2011 Zhao C, Toste FD, Bergman RG. Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction. Journal of the American Chemical Society. 133: 10787-9. PMID 21699161 DOI: 10.1021/Ja204564Z  0.66
2011 Tomson NC, Arnold J, Bergman RG. Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands. Dalton Transactions (Cambridge, England : 2003). 40: 7718-29. PMID 21523303 DOI: 10.1039/C1Dt10202H  0.787
2011 Wang ZJ, Brown CJ, Bergman RG, Raymond KN, Toste FD. Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host. Journal of the American Chemical Society. 133: 7358-60. PMID 21517023 DOI: 10.1021/Ja202055V  0.739
2011 Crimmin MR, Bergman RG, Toste FD. Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes. Angewandte Chemie (International Ed. in English). 50: 4484-7. PMID 21480451 DOI: 10.1002/Anie.201100816  0.74
2011 Brasse M, Ellman JA, Bergman RG. A facile, metal- and solvent-free, autoxidative coupling of quinolines with indoles and pyrroles. Chemical Communications (Cambridge, England). 47: 5019-21. PMID 21445416 DOI: 10.1039/C1Cc10507H  0.553
2011 Tsai AS, Tauchert ME, Bergman RG, Ellman JA. Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization. Journal of the American Chemical Society. 133: 1248-50. PMID 21204527 DOI: 10.1021/Ja109562X  0.718
2011 Tsai AS, Brasse M, Bergman RG, Ellman JA. Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation. Organic Letters. 13: 540-2. PMID 21175143 DOI: 10.1021/Ol102890K  0.676
2011 Crimmin MR, Colby DA, Ellman JA, Bergman RG. Synthesis and coordination chemistry of tri-substituted benzamidrazones. Dalton Transactions (Cambridge, England : 2003). 40: 514-22. PMID 21109860 DOI: 10.1039/C0Dt01267J  0.737
2011 Tsai AS, Brasse M, Bergman RG, Ellman JA. Rh(III)-Catalyzed C-H Activation and Oxidative Couplingwith Alkenes Synfacts. 2011: 423-423. DOI: 10.1055/S-0030-1259604  0.549
2011 Bergman R, Toste F, Boyd W, Crimmin M, Rosebrugh L, Schomaker J. Enantioselective Synthesis ofC2andC1Dienes Synfacts. 2011: 0183-0183. DOI: 10.1055/S-0030-1259337  0.791
2011 Koller J, Bergman RG. Highly efficient aluminum-catalyzed ring-opening polymerization of cyclic carbonates, lactones, and lactides, including a unique crystallographic snapshot of an intermediate Organometallics. 30: 3217-3224. DOI: 10.1021/Om2003283  0.337
2011 Bowring MA, Bergman RG, Tilley TD. Disambiguation of metal and Brønsted acid catalyzed pathways for hydroarylation with platinum(II) catalysts Organometallics. 30: 1295-1298. DOI: 10.1021/Om2000458  0.804
2011 Crimmin MR, Rosebrugh LE, Tomson NC, Weyhermüller T, Bergman RG, Toste FD, Wieghardt K. [(TMEDA)Co(NO) 2][BPh 4]: A versatile synthetic entry point to four and five coordinate {Co(NO) 2} 10 complexes Journal of Organometallic Chemistry. 696: 3974-3981. DOI: 10.1016/J.Jorganchem.2011.04.038  0.834
2011 Razgon A, Anstey MR, Yakelis NA, Bergman RG, Sukenik CN. Surface immobilization of an organo-iridium complex through a carbon-metal bond Inorganica Chimica Acta. 375: 305-307. DOI: 10.1016/J.Ica.2011.04.042  0.802
2011 Zhao C, Toste FD, Bergman RG. ChemInform Abstract: Direct Michael Addition of Alkenes via a Cobalt-Dinitrosyl Mediated Vinylic C-H Functionalization Reaction. Cheminform. 42: no-no. DOI: 10.1002/chin.201151025  0.53
2011 Tsai AS, Tauchert ME, Bergman RG, Ellman JA. ChemInform Abstract: Rhodium(III)-Catalyzed Arylation of Boc-Imines via C-H Bond Functionalization. Cheminform. 42: no-no. DOI: 10.1002/chin.201131069  0.566
2011 Tsai AS, Brasse M, Bergman RG, Ellman JA. ChemInform Abstract: Rh(III)-Catalyzed Oxidative Coupling of Unactivated Alkenes via C-H Activation. Cheminform. 42: no-no. DOI: 10.1002/chin.201117099  0.522
2011 Berman AM, Bergman RG, Ellman JA. ChemInform Abstract: Rh(I)-Catalyzed Direct Arylation of Azines. Cheminform. 42: no-no. DOI: 10.1002/chin.201110151  0.609
2011 Nichols JM, Bishop LM, Bergman RG, Ellman JA. ChemInform Abstract: Catalytic C-O Bond Cleavage of 2-Aryloxy-1-arylethanols and Its Application to the Depolymerization of Lignin-Related Polymers. Cheminform. 42: no-no. DOI: 10.1002/chin.201106032  0.559
2010 Tomson NC, Arnold J, Bergman RG. Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes. Organometallics. 29: 5010-5025. PMID 21116450 DOI: 10.1021/Om1002528  0.774
2010 Berman AM, Bergman RG, Ellman JA. Rh(I)-catalyzed direct arylation of azines. The Journal of Organic Chemistry. 75: 7863-8. PMID 21033740 DOI: 10.1021/Jo101793R  0.716
2010 Boyd WC, Crimmin MR, Rosebrugh LE, Schomaker JM, Bergman RG, Toste FD. Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes. Journal of the American Chemical Society. 132: 16365-7. PMID 21033667 DOI: 10.1021/Ja107968C  0.81
2010 Mugridge JS, Szigethy G, Bergman RG, Raymond KN. Encapsulated guest-host dynamics: guest rotational barriers and tumbling as a probe of host interior cavity space. Journal of the American Chemical Society. 132: 16256-64. PMID 20977233 DOI: 10.1021/Ja107656G  0.459
2010 Nichols JM, Bishop LM, Bergman RG, Ellman JA. Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers. Journal of the American Chemical Society. 132: 12554-5. PMID 20731348 DOI: 10.1021/Ja106101F  0.71
2010 Tomson NC, Arnold J, Bergman RG. Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand. Organometallics. 29: 2926-2942. PMID 20671985 DOI: 10.1021/Om1001827  0.764
2010 Arceo E, Ellman JA, Bergman RG. Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent. Journal of the American Chemical Society. 132: 11408-9. PMID 20669903 DOI: 10.1021/Ja103436V  0.561
2010 Yotphan S, Bergman RG, Ellman JA. Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization. Organic Letters. 12: 2978-81. PMID 20518526 DOI: 10.1021/Ol101002B  0.819
2010 Arceo E, Ellman JA, Bergman RG. A direct, biomass-based synthesis of benzoic acid: formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid. Chemsuschem. 3: 811-3. PMID 20512802 DOI: 10.1002/Cssc.201000111  0.465
2010 Koller J, Bergman RG. Aluminium-catalyzed intramolecular hydroamination of aminoalkenes. Chemical Communications (Cambridge, England). 46: 4577-9. PMID 20458403 DOI: 10.1039/C002760J  0.442
2010 Hastings CJ, Pluth MD, Bergman RG, Raymond KN. Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation. Journal of the American Chemical Society. 132: 6938-40. PMID 20443566 DOI: 10.1021/Ja102633E  0.804
2010 Mugridge JS, Bergman RG, Raymond KN. Does size really matter? The steric isotope effect in a supramolecular host-guest exchange reaction. Angewandte Chemie (International Ed. in English). 49: 3635-7. PMID 20394089 DOI: 10.1002/Anie.200906569  0.536
2010 Mugridge JS, Bergman RG, Raymond KN. High-precision measurement of isotope effects on noncovalent host-guest interactions. Journal of the American Chemical Society. 132: 1182-3. PMID 20050653 DOI: 10.1021/Ja905170X  0.464
2010 Colby DA, Bergman RG, Ellman JA. Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation. Chemical Reviews. 110: 624-55. PMID 19438203 DOI: 10.1021/Cr900005N  0.623
2010 Bishop LM, Roberson RE, Bergman RG, Trauner D. On the development of catalytic carba-6π electrocyclizations Synthesis. 2233-2244. DOI: 10.1055/S-0029-1218812  0.694
2010 Calladine JA, Torres O, Anstey M, Ball GE, Bergman RG, Curley J, Duckett SB, George MW, Gilson AI, Lawes DJ, Perutz RN, Sun XZ, Vollhardt KPC. Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study Chemical Science. 1: 622-630. DOI: 10.1039/C0Sc00311E  0.816
2010 Koller J, Bergman RG. Highly efficient aluminum-catalyzed hydro-amination/-hydrazination of carbodiimides Organometallics. 29: 5946-5952. DOI: 10.1021/Om100735Q  0.412
2010 Koller J, Bergman RG. Synthesis, characterization, and reactivity of aluminum alkyl/amide complexes supported by guanidinate and monoanionic OCO-pincer ligands Organometallics. 29: 3350-3356. DOI: 10.1021/Om100278B  0.474
2010 Cordaro JG, McCusker JK, Bergman RG. ChemInform Abstract: Synthesis of Mono-Substituted 2,2′-Bipyridines. Cheminform. 33: no-no. DOI: 10.1002/chin.200244158  0.8
2010 Fulton JR, Holland AW, Fox DJ, Bergman RG. ChemInform Abstract: Formation, Reactivity, and Properties of Nondative Late Transition Metal-Oxygen and -Nitrogen Bonds Cheminform. 33: no-no. DOI: 10.1002/chin.200217252  0.66
2010 Gerisch M, Krumper JR, Bergman RG, Tilley TD. ChemInform Abstract: Novel Bis(oxazoline) Pincer Ligands: Formation of Mononuclear Rhodium(II) Complexes. Cheminform. 32: no-no. DOI: 10.1002/chin.200140121  0.81
2010 Johnson JS, Bergman RG. ChemInform Abstract: Imidotitanium Complexes as Hydroamination Catalysts: Substantially Enhanced Reactivity from an Unexpected Cyclopentadienide/Amide Ligand Exchange. Cheminform. 32: no-no. DOI: 10.1002/chin.200132053  0.509
2010 Tan KL, Bergman RG, Ellman JA. ChemInform Abstract: Annulation of Alkenyl-Substituted Heterocycles via Rhodium-Catalyzed Intramolecular C-H Activated Coupling Reactions. Cheminform. 32: no-no. DOI: 10.1002/chin.200129130  0.612
2010 BARANGER AM, HANNA TA, BERGMAN RG. ChemInform Abstract: Transfer of Oxygen and Sulfur from Organic Molecules to a Zr-Ir Bond. Evidence for an Unusually Rapid Atom Abstraction Reaction. Cheminform. 27: no-no. DOI: 10.1002/chin.199607211  0.64
2010 BARANGER AM, WALSH PJ, BERGMAN RG. ChemInform Abstract: Variable Regiochemistry in the Stoichiometric and Catalytic Hydroamination of Alkynes by Imidozirconium Complexes Caused by an Unusual Dependence of the Rate Law on Alkyne Structure and Temperature. Cheminform. 24: no-no. DOI: 10.1002/chin.199335131  0.695
2010 PROULX G, BERGMAN RG. ChemInform Abstract: Reaction of a Tantalum Alkylidene Complex with Dinuclear Metal Carbonyls: Formation of C3 Ligands. Cheminform. 24: no-no. DOI: 10.1002/chin.199316141  0.342
2010 WALSH PJ, BARANGER AM, BERGMAN RG. ChemInform Abstract: Stoichiometric and Catalytic Hydroamination of Alkynes and Allene by Zirconium Bisamides Cp2Zr(NHR)2. Cheminform. 23: no-no. DOI: 10.1002/chin.199226089  0.705
2010 WALSH PJ, CARNEY MJ, BERGMAN RG. ChemInform Abstract: Generation, Dative Ligand Trapping, and N-N Bond Cleavage Reactions of the First Monomeric η1-Hydrazido Zirconocene Complex, Cp2Zr=NNPh2. A Zirconium-Mediated Synthesis of Indoles. Cheminform. 22: no-no. DOI: 10.1002/chin.199144161  0.534
2010 TROST MK, BERGMAN RG. ChemInform Abstract: Cp*MoO2Cl-Catalyzed Epoxidation of Olefins by Alkyl Hydroperoxides. Cheminform. 22: no-no. DOI: 10.1002/chin.199131099  0.302
2010 Mugridge J, Bergman R, Raymond K. Inside Cover: Does Size Really Matter? The Steric Isotope Effect in a Supramolecular Host-Guest Exchange Reaction (Angew. Chem. Int. Ed. 21/2010) Angewandte Chemie International Edition. 49: 3546-3546. DOI: 10.1002/Anie.201001707  0.487
2010 Mugridge J, Bergman R, Raymond K. Innentitelbild: Does Size Really Matter? The Steric Isotope Effect in a Supramolecular Host-Guest Exchange Reaction (Angew. Chem. 21/2010) Angewandte Chemie. 122: 3626-3626. DOI: 10.1002/Ange.201001707  0.488
2009 Brown CJ, Bergman RG, Raymond KN. Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly. Journal of the American Chemical Society. 131: 17530-1. PMID 19950985 DOI: 10.1021/Ja906386W  0.686
2009 Tsai AS, Wilson RM, Harada H, Bergman RG, Ellman JA. Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation. Chemical Communications (Cambridge, England). 3910-2. PMID 19662249 DOI: 10.1039/B902878A  0.768
2009 Schomaker JM, Toste FD, Bergman RG. Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines. Organic Letters. 11: 3698-700. PMID 19639989 DOI: 10.1021/Ol901542N  0.745
2009 Pluth MD, Bergman RG, Raymond KN. Proton-mediated chemistry and catalysis in a self-assembled supramolecular host. Accounts of Chemical Research. 42: 1650-9. PMID 19591461 DOI: 10.1021/Ar900118T  0.69
2009 Arceo E, Marsden P, Bergman RG, Ellman JA. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation. Chemical Communications (Cambridge, England). 3357-9. PMID 19503869 DOI: 10.1039/B907746D  0.785
2009 Chan VS, Chiu M, Bergman RG, Toste FD. Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates. Journal of the American Chemical Society. 131: 6021-32. PMID 19338305 DOI: 10.1021/Ja9014887  0.741
2009 Yotphan S, Bergman RG, Ellman JA. Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines. Organic Letters. 11: 1511-4. PMID 19260648 DOI: 10.1021/Ol900103A  0.802
2009 Pluth MD, Fiedler D, Mugridge JS, Bergman RG, Raymond KN. Molecular recognition and self-assembly special feature: Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host. Proceedings of the National Academy of Sciences of the United States of America. 106: 10438-43. PMID 19181859 DOI: 10.1073/Pnas.0809806106  0.748
2009 Pluth MD, Bergman RG, Raymond KN. The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution. The Journal of Organic Chemistry. 74: 58-63. PMID 19113901 DOI: 10.1021/Jo802131V  0.677
2009 Pluth MD, Johnson DW, Szigethy G, Davis AV, Teat SJ, Oliver AG, Bergman RG, Raymond KN. Structural consequences of anionic host-cationic guest interactions in a supramolecular assembly. Inorganic Chemistry. 48: 111-20. PMID 19053347 DOI: 10.1021/Ic8012848  0.656
2009 Berman AM, Lewis JC, Bergman RG, Ellman JA. Direct Arylation of α-Substituted Pyridines andQuinolines Synfacts. 2009: 195-195. DOI: 10.1055/S-0028-1087659  0.505
2009 Tsai AS, Wilson RM, Harada H, Bergman RG, Ellman JA. ChemInform Abstract: Rhodium-Catalyzed Enantioselective Cyclization of Substituted Imidazoles via C-H Bond Activation. Cheminform. 40. DOI: 10.1002/chin.200946127  0.579
2009 Chan VS, Chiu M, Bergman RG, Toste FD. ChemInform Abstract: Development of Ruthenium Catalysts for the Enantioselective Synthesis of P-Stereogenic Phosphines via Nucleophilic Phosphido Intermediates. Cheminform. 40. DOI: 10.1002/chin.200937180  0.696
2009 Yotphan S, Bergman RG, Ellman JA. ChemInform Abstract: Application of Daugulis Copper-Catalyzed Direct Arylation to the Synthesis of 5-Aryl Benzotriazepines. Cheminform. 40. DOI: 10.1002/chin.200933175  0.741
2009 Berman AM, Lewis JC, Bergman RG, Ellman JA. ChemInform Abstract: Rh(I)-Catalyzed Direct Arylation of Pyridines and Quinolines. Cheminform. 40. DOI: 10.1002/chin.200912160  0.721
2008 Gribble MW, Ellman JA, Bergman RG. Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation. Organometallics. 27: 2152-2155. PMID 21191469 DOI: 10.1021/Om8000839  0.633
2008 Berman AM, Lewis JC, Bergman RG, Ellman JA. Rh(I)-catalyzed direct arylation of pyridines and quinolines. Journal of the American Chemical Society. 130: 14926-7. PMID 18855360 DOI: 10.1021/Ja8059396  0.773
2008 Bishop LM, Barbarow JE, Bergman RG, Trauner D. Catalysis of 6pi electrocyclizations. Angewandte Chemie (International Ed. in English). 47: 8100-3. PMID 18785197 DOI: 10.1002/Anie.200803336  0.647
2008 Pluth MD, Bergman RG, Raymond KN. Acceleration of amide bond rotation by encapsulation in the hydrophobic interior of a water-soluble supramolecular assembly. The Journal of Organic Chemistry. 73: 7132-6. PMID 18687002 DOI: 10.1021/Jo800991G  0.671
2008 Harada H, Thalji RK, Bergman RG, Ellman JA. Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation. The Journal of Organic Chemistry. 73: 6772-9. PMID 18681407 DOI: 10.1021/Jo801098Z  0.6
2008 Pluth MD, Bergman RG, Raymond KN. Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism. Journal of the American Chemical Society. 130: 11423-9. PMID 18680290 DOI: 10.1021/Ja802839V  0.687
2008 Tomson NC, Yan A, Arnold J, Bergman RG. An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex. Journal of the American Chemical Society. 130: 11262-3. PMID 18671347 DOI: 10.1021/Ja803729K  0.776
2008 Hastings CJ, Fiedler D, Bergman RG, Raymond KN. Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme". Journal of the American Chemical Society. 130: 10977-83. PMID 18652468 DOI: 10.1021/Ja8013055  0.808
2008 Lewis JC, Bergman RG, Ellman JA. Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation. Accounts of Chemical Research. 41: 1013-25. PMID 18616300 DOI: 10.1021/Ar800042P  0.753
2008 Chiu M, Hoyt HM, Michael FE, Bergman RG, van Halbeek H. Synthesis, structural characterization, and quantitative basicity studies of lithium zirconimidate complexes. Angewandte Chemie (International Ed. in English). 47: 6073-6. PMID 18604799 DOI: 10.1002/Anie.200801463  0.837
2008 Bishop LM, Winkler M, Houk KN, Bergman RG, Trauner D. Mechanistic investigations of the acid-catalyzed cyclization of a vinyl ortho-quinone methide. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 5405-8. PMID 18449871 DOI: 10.1002/Chem.200800662  0.685
2008 Pluth MD, Bergman RG, Raymond KN. Encapsulation of protonated diamines in a water-soluble, chiral, supramolecular assembly allows for measurement of hydrogen-bond breaking followed by nitrogen inversion/rotation. Journal of the American Chemical Society. 130: 6362-6. PMID 18444618 DOI: 10.1021/Ja076691H  0.673
2008 Tsai AS, Bergman RG, Ellman JA. Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation. Journal of the American Chemical Society. 130: 6316-7. PMID 18444613 DOI: 10.1021/Ja8012159  0.714
2008 Lalic G, Krinsky JL, Bergman RG. Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles. Journal of the American Chemical Society. 130: 4459-65. PMID 18327942 DOI: 10.1021/Ja7106096  0.832
2008 Schomaker JM, Boyd WC, Stewart IC, Toste FD, Bergman RG. Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins. Journal of the American Chemical Society. 130: 3777-9. PMID 18318538 DOI: 10.1021/Ja800738D  0.834
2008 Colby DA, Bergman RG, Ellman JA. Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation. Journal of the American Chemical Society. 130: 3645-51. PMID 18302381 DOI: 10.1021/Ja7104784  0.611
2008 Leung DH, Bergman RG, Raymond KN. Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water. Journal of the American Chemical Society. 130: 2798-805. PMID 18257565 DOI: 10.1021/Ja075975Z  0.654
2008 Razgon A, Bergman RG, Sukenik CN. Ozonolysis-based route to the in situ formation of aldehyde-bearing self-assembled monolayer surfaces. Langmuir : the Acs Journal of Surfaces and Colloids. 24: 2545-52. PMID 18251560 DOI: 10.1021/La703120C  0.604
2008 Lewis JC, Berman AM, Bergman RG, Ellman JA. Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight. Journal of the American Chemical Society. 130: 2493-500. PMID 18251465 DOI: 10.1021/Ja0748985  0.796
2008 Yotphan S, Bergman RG, Ellman JA. The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization. Journal of the American Chemical Society. 130: 2452-3. PMID 18247623 DOI: 10.1021/Ja710981B  0.81
2008 Smith SE, Sasaki JM, Bergman RG, Mondloch JE, Finke RG. Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer. Journal of the American Chemical Society. 130: 1839-41. PMID 18198879 DOI: 10.1021/Ja710365X  0.625
2008 Krinsky JL, Anderson LL, Arnold J, Bergman RG. Oxygen-centered hexatantalum tetradecaimido cluster complexes. Inorganic Chemistry. 47: 1053-66. PMID 18163614 DOI: 10.1021/Ic701920V  0.801
2008 Pluth MD, Raymond KN, Bergman RG. Selective Organic and Organometallic Reactions in Water-Soluble Host-Guest Supramolecular Systems Lawrence Berkeley National Laboratory. DOI: 10.2172/952577  0.699
2008 Tsai AS, Bergman RG, Ellman JA. Synthesis of (-)-Incarvillateine Synfacts. 2008: 1254-1254. DOI: 10.1055/S-0028-1087287  0.503
2008 Harada H, Thalji RK, Bergman RG, Ellman JA. Enantioselective Hydroarylation of Alkenes via C-HActivation Synfacts. 2008: 1295-1295. DOI: 10.1055/S-0028-1083619  0.528
2008 Hastings CJ, Pluth MD, Biros SM, Bergman RG, Raymond KN. Simultaneously bound guests and chiral recognition: a chiral self-assembled supramolecular host encapsulates hydrophobic guests Tetrahedron. 64: 8362-8367. DOI: 10.1016/J.Tet.2008.05.131  0.793
2008 Lewis JC, Bergman RG, Ellman JA. ChemInform Abstract: Direct Functionalization of Nitrogen Heterocycles via Rh-Catalyzed C-H Bond Activation Cheminform. 39. DOI: 10.1002/chin.200848273  0.575
2008 Lalic G, Krinsky JL, Bergman RG. ChemInform Abstract: Scope and Mechanism of Formal SN2′Substitution Reactions of a Monomeric Imidozirconium Complex with Allylic Electrophiles. Cheminform. 39. DOI: 10.1002/chin.200835047  0.829
2008 Chan VS, Bergman RG, Toste FD. ChemInform Abstract: Pd-Catalyzed Dynamic Kinetic Enantioselective Arylation of Silylphosphines. Cheminform. 39. DOI: 10.1002/chin.200819174  0.553
2008 Fox RJ, Lalic G, Bergman RG. ChemInform Abstract: Regio- and Stereospecific Formation of Protected Allylic Alcohols via Zirconium-Mediated SN2′ Substitution of Allylic Chlorides. Cheminform. 39. DOI: 10.1002/chin.200814061  0.639
2008 Pluth MD, Bergman RG, Raymond KN. ChemInform Abstract: Catalytic Deprotection of Acetals in Basic Solution with a Self-Assembled Supramolecular “Nanozyme”. Cheminform. 39. DOI: 10.1002/chin.200812055  0.595
2008 Pluth MD, Bergman RG, Raymond KN. Selective Stoichiometric and Catalytic Reactivity in the Confines of a Chiral Supramolecular Assembly Supramolecular Catalysis. 165-197. DOI: 10.1002/9783527621781.Ch7  0.685
2008 Rostovtsev VV, Snieckus V, Macklin T, Grushin VV, Ishiyama T, Miyaura N, Kakiuchi F, Dyker G, Kobayashi S, Bandini M, Melloni A, Piccinelli F, Reetz MT, Sommer K, Murai S, ... ... Bergman RG, et al. C-H Transformation at Arenes Handbook of C-H Transformations: Applications in Organic Synthesis. 1: 99-276. DOI: 10.1002/9783527619450.ch5  0.786
2007 Chan VS, Bergman RG, Toste FD. Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines. Journal of the American Chemical Society. 129: 15122-3. PMID 18004858 DOI: 10.1021/Ja076457R  0.658
2007 Nolin KA, Krumper JR, Pluth MD, Bergman RG, Toste FD. Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds. Journal of the American Chemical Society. 129: 14684-96. PMID 17983224 DOI: 10.1021/Ja074477N  0.821
2007 Fox RJ, Lalic G, Bergman RG. Regio- and stereospecific formation of protected allylic alcohols via zirconium-mediated S(N)2' substitution of allylic chlorides. Journal of the American Chemical Society. 129: 14144-5. PMID 17973391 DOI: 10.1021/Ja075967I  0.709
2007 Pluth MD, Bergman RG, Raymond KN. Catalytic deprotection of acetals in basic solution with a self-assembled supramolecular "nanozyme". Angewandte Chemie (International Ed. in English). 46: 8587-9. PMID 17926313 DOI: 10.1002/Anie.200703371  0.677
2007 Biros SM, Bergman RG, Raymond KN. The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster. Journal of the American Chemical Society. 129: 12094-5. PMID 17880087 DOI: 10.1021/Ja075236I  0.482
2007 Pluth MD, Bergman RG, Raymond KN. Making amines strong bases: thermodynamic stabilization of protonated guests in a highly-charged supramolecular host1. Journal of the American Chemical Society. 129: 11459-67. PMID 17713905 DOI: 10.1021/Ja072654E  0.669
2007 Hoyt HM, Bergman RG. Kinetic control and multiple mechanisms for C-H bond activation by a Zr=N complex. Angewandte Chemie (International Ed. in English). 46: 5580-2. PMID 17577898 DOI: 10.1002/Anie.200701816  0.831
2007 Cobar EA, Khaliullin RZ, Bergman RG, Head-Gordon M. Theoretical study of the rhenium-alkane interaction in transition metal-alkane sigma-complexes. Proceedings of the National Academy of Sciences of the United States of America. 104: 6963-8. PMID 17442751 DOI: 10.1073/Pnas.0610295104  0.334
2007 Pluth MD, Bergman RG, Raymond KN. Acid catalysis in basic solution: a supramolecular host promotes orthoformate hydrolysis. Science (New York, N.Y.). 316: 85-8. PMID 17412953 DOI: 10.1126/Science.1138748  0.678
2007 Lewis JC, Bergman RG, Ellman JA. Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation. Journal of the American Chemical Society. 129: 5332-3. PMID 17411050 DOI: 10.1021/Ja070388Z  0.726
2007 Watson MP, Overman LE, Bergman RG. Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. Journal of the American Chemical Society. 129: 5031-44. PMID 17402733 DOI: 10.1021/Ja0676962  0.753
2007 Bergman RG. Organometallic chemistry: C-H activation. Nature. 446: 391-3. PMID 17377575 DOI: 10.1038/446391A  0.36
2007 Wiedemann SH, Kang DH, Bergman RG, Friend CM. Cyclopropylmethyl/cyclobutyl rearrangements on surfaces: evidence for transient cation formation near O-covered Mo(110). Journal of the American Chemical Society. 129: 4666-77. PMID 17375922 DOI: 10.1021/Ja0682428  0.814
2007 Leung DH, Bergman RG, Raymond KN. Highly selective supramolecular catalyzed allylic alcohol isomerization. Journal of the American Chemical Society. 129: 2746-7. PMID 17302420 DOI: 10.1021/Ja068688O  0.675
2007 Anstey MR, Yung CM, Du J, Bergman RG. Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes. Journal of the American Chemical Society. 129: 776-7. PMID 17243810 DOI: 10.1021/Ja068312A  0.832
2007 Rech JC, Yato M, Duckett D, Ember B, LoGrasso PV, Bergman RG, Ellman JA. Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation. Journal of the American Chemical Society. 129: 490-1. PMID 17227002 DOI: 10.1021/Ja0676004  0.541
2007 Krinsky JL, Anderson LL, Arnold J, Bergman RG. Synthesis and properties of oxygen-centered tetradecaimido hexatantalum clusters. Angewandte Chemie (International Ed. in English). 46: 369-72. PMID 17154203 DOI: 10.1002/Anie.200603019  0.816
2007 Watzke A, Wilson RM, O'Malley SJ, Bergman RG, Ellman JA. Asymmetric intramolecular alkylation of chiral aromatic imines via catalytic C-H bond activation Synlett. 2383-2389. DOI: 10.1055/S-2007-985593  0.725
2007 Lewis JC, Bergman RG, Ellman JA. Rh-Catalyzed C-H Activation Route to 2-Alkylpyridines and 2-Alkylquinolines Synfacts. 2007: 806-806. DOI: 10.1055/S-2007-968795  0.554
2007 Bergman R, Ellman J, Rech J, Yato M, Duckett D, Ember B, LoGrasso P. Rh-Catalyzed C-H Activation Route to Bicyclic Imidazoles Synfacts. 2007: 0472-0472. DOI: 10.1055/S-2007-968478  0.561
2007 Krinsky JL, Arnold J, Bergman RG. Platinum group thiophenoxyimine complexes: syntheses and crystallographic/computational studies Organometallics. 26: 897-909. DOI: 10.1021/Om0609057  0.811
2007 Ruffo F, Renzi AD, Panunzi A, Bergman RG, Howard WH. (N,N‐chelate)(Olefin) Platinum (O) Complexes Inorganic Syntheses. 32: 158-162. DOI: 10.1002/9780470132630.Ch27  0.321
2006 Anderson LL, Schmidt JA, Arnold J, Bergman RG. Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions. Organometallics. 25: 3394-3406. PMID 19079787 DOI: 10.1021/Om060081T  0.715
2006 Watson DA, Chiu M, Bergman RG. Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination. Organometallics. 25: 4731-4733. PMID 19079735 DOI: 10.1021/Om0606791  0.735
2006 Dong VM, Fiedler D, Carl B, Bergman RG, Raymond KN. Molecular recognition and stabilization of iminium ions in water. Journal of the American Chemical Society. 128: 14464-5. PMID 17090022 DOI: 10.1021/Ja0657915  0.721
2006 Watzke A, O'Malley SJ, Bergman RG, Ellman JA. Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B. Journal of Natural Products. 69: 1231-3. PMID 16933885 DOI: 10.1021/Np060136W  0.457
2006 Fiedler D, van Halbeek H, Bergman RG, Raymond KN. Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights. Journal of the American Chemical Society. 128: 10240-52. PMID 16881654 DOI: 10.1021/Ja062329B  0.668
2006 Leung DH, Bergman RG, Raymond KN. Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism. Journal of the American Chemical Society. 128: 9781-97. PMID 16866535 DOI: 10.1021/Ja061412W  0.695
2006 Colby DA, Bergman RG, Ellman JA. Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation. Journal of the American Chemical Society. 128: 5604-5. PMID 16637605 DOI: 10.1021/Ja0584931  0.507
2006 Wilson RM, Thalji RK, Bergman RG, Ellman JA. Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation. Organic Letters. 8: 1745-7. PMID 16597156 DOI: 10.1021/Ol060485H  0.724
2006 Chan VS, Stewart IC, Bergman RG, Toste FD. Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex. Journal of the American Chemical Society. 128: 2786-7. PMID 16506742 DOI: 10.1021/Ja058100Y  0.783
2006 Wiedemann SH, Ellman JA, Bergman RG. Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline. The Journal of Organic Chemistry. 71: 1969-76. PMID 16496982 DOI: 10.1021/Jo052345B  0.823
2006 Wiedemann SH, Lewis JC, Ellman JA, Bergman RG. Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). Journal of the American Chemical Society. 128: 2452-62. PMID 16478202 DOI: 10.1021/Ja0576684  0.833
2006 Lewis JC, Wu JY, Bergman RG, Ellman JA. Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation. Angewandte Chemie (International Ed. in English). 45: 1589-91. PMID 16444794 DOI: 10.1002/Anie.200504289  0.704
2006 Fiedler D, Bergman RG, Raymond KN. Stabilization of reactive organometallic intermediates inside a self-assembled nanoscale host. Angewandte Chemie (International Ed. in English). 45: 745-8. PMID 16370008 DOI: 10.1002/Anie.200501938  0.611
2006 Mullins SM, Bergman RG, Arnold J. Olefination and group transfer reactions of an electron deficient tantalum methylidene complex. Dalton Transactions (Cambridge, England : 2003). 203-12. PMID 16357978 DOI: 10.1039/B512741F  0.726
2006 Bergman R, Ellman J, Colby D. Alkylation of α,β-Unsaturated Imines via C-H Bond Activation Synfacts. 2006: 0814-0814. DOI: 10.1055/S-2006-942012  0.535
2006 Bergman R, Toste F, Chan V, Sterwart I. Synthesis of P-Stereogenic Phosphines Synfacts. 2006: 0700-0700. DOI: 10.1055/S-2006-941821  0.597
2006 Bergman R, Ellman J, Wilson R, Thalji R. Rhodium-Catalyzed Imine-Directed C-H Bond Functionalization Synfacts. 2006: 0586-0586. DOI: 10.1055/S-2006-934472  0.575
2006 Ellman J, Bergman R, Wiedemann S. Rh-Catalyzed C-H Addition of Quinazolines to Alkenes Synfacts. 2006: 0432-0432. DOI: 10.1055/S-2006-934374  0.809
2006 Lalic G, Blum S, Bergman RG. Synthesis of Allylic Amines from Allylic Ethers and Zirconocene Imides Synfacts. 2006: 155-155. DOI: 10.1055/S-2005-924786  0.373
2006 O’Malley SJ, Tan KL, Watzke A, Bergman RG, Ellman JA. Synthesis of (+)-Lithospermic Acid Synfacts. 2006: 98-98. DOI: 10.1055/S-2005-921780  0.642
2006 Zhang Y, Lewis JC, Bergman RG, Ellman JA, Oldfield E. NMR shifts, orbitals, and M⋯H-X bonding in d 8 square planar metal complexes Organometallics. 25: 3515-3519. DOI: 10.1021/Om060163H  0.689
2006 Anderson L, Arnold J, Bergman RG. Erratum: Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes (Organic Letters (2004) 6 (2519)) Organic Letters. 8. DOI: 10.1021/Ol0608810  0.674
2006 Papaiconomou N, Yakelis N, Salminen J, Bergman R, Prausnitz JM. Synthesis and properties of seven ionic liquids containing 1-methyl-3-octylimidazolium or 1-butyl-4-methylpyridinium cations Journal of Chemical and Engineering Data. 51: 1389-1393. DOI: 10.1021/Je060096Y  0.761
2006 Skaddan MB, Bergman RG. The neighboring group effect of fluorine in the tritium labeling of organic substrates with [Cp*(PMe3)IrMe(CH2Cl 2)]+ [BArf]-, a cationic iridium(III) complex Journal of Labelled Compounds and Radiopharmaceuticals. 49: 623-634. DOI: 10.1002/Jlcr.1072  0.421
2005 Yakelis NA, Bergman RG. Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF(24)): Safe Preparation, Standardized Purification, and Analysis of Hydration. Organometallics. 24: 3579-3581. PMID 19079785 DOI: 10.1021/Om0501428  0.784
2005 Blum SA, Rivera VA, Ruck RT, Michael FE, Bergman RG. Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes. Organometallics. 24: 1647-1659. PMID 16508693 DOI: 10.1021/Om049105R  0.825
2005 Stewart IC, Lee CC, Bergman RG, Toste FD. Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines. Journal of the American Chemical Society. 127: 17616-7. PMID 16351086 DOI: 10.1021/Ja0554357  0.633
2005 Lalic G, Blum SA, Bergman RG. Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic amines. Journal of the American Chemical Society. 127: 16790-1. PMID 16316217 DOI: 10.1021/Ja056132F  0.807
2005 Anderson LL, Arnold J, Bergman RG. Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency. Journal of the American Chemical Society. 127: 14542-3. PMID 16231885 DOI: 10.1021/Ja053700I  0.682
2005 O'Malley SJ, Tan KL, Watzke A, Bergman RG, Ellman JA. Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation. Journal of the American Chemical Society. 127: 13496-7. PMID 16190703 DOI: 10.1021/Ja052680H  0.715
2005 Thalji RK, Ahrendt KA, Bergman RG, Ellman JA. Annulation of aromatic imines via directed C-H bond activation. The Journal of Organic Chemistry. 70: 6775-81. PMID 16095296 DOI: 10.1021/Jo050757E  0.592
2005 Fiedler D, Leung DH, Bergman RG, Raymond KN. Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. Accounts of Chemical Research. 38: 349-58. PMID 15835881 DOI: 10.1021/Ar040152P  0.784
2005 Lin FL, Hoyt HM, van Halbeek H, Bergman RG, Bertozzi CR. Mechanistic investigation of the staudinger ligation. Journal of the American Chemical Society. 127: 2686-95. PMID 15725026 DOI: 10.1021/Ja044461M  0.805
2005 Michael FE, Duncan AP, Sweeney ZK, Bergman RG. Rearrangements and stereomutations of metallacycles derived from allenes and imidozirconium complexes. Journal of the American Chemical Society. 127: 1752-64. PMID 15701010 DOI: 10.1021/Ja045607K  0.803
2005 Lewis JC, Wu J, Bergman RG, Ellman JA. Preagostic Rh-H interactions and C-H bond functionalization: A Combined Experimental and Theoretical Investigation of Rhodium (I) Phosphinite Complexes Organometallics. 24: 5737-5746. DOI: 10.1021/Om050700I  0.708
2005 Klei SR, Tan KL, Golden JT, Yung CM, Thalji RK, Ahrendt KA, Ellman JA, Tilley TD, Bergman RG. C—H Bond Activation by Iridium and Rhodium Complexes: Catalytic Hydrogen—Deuterium Exchange and C—C Bond-Forming Reactions Cheminform. 36. DOI: 10.1002/chin.200524251  0.824
2004 Blum SA, Bergman RG. Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes. Organometallics. 23: 4003-4005. PMID 16508695 DOI: 10.1021/Om0495776  0.699
2004 Ruck RT, Bergman RG. Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes. Organometallics. 23: 2231-2233. PMID 16508694 DOI: 10.1021/Om0497994  0.721
2004 Cordaro JG, Bergman RG. Dissociation of carbanions from acyl iridium compounds: an experimental and computational investigation. Journal of the American Chemical Society. 126: 16912-29. PMID 15612730 DOI: 10.1021/Ja045859L  0.802
2004 Cordaro JG, van Halbeek H, Bergman RG. An iridium difluoroketene complex: synthesis and isolation. Angewandte Chemie (International Ed. in English). 43: 6366-9. PMID 15558693 DOI: 10.1002/Anie.200461402  0.805
2004 Fiedler D, Bergman RG, Raymond KN. Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host. Angewandte Chemie (International Ed. in English). 43: 6748-51. PMID 15558640 DOI: 10.1002/Anie.200461776  0.701
2004 Krumper JR, Martin RL, Hay PJ, Yung CM, Veltheer J, Bergman RG. Synthesis and reactivity of the hydrido- and alkylrhenium methylidene complexes Cp*(PMe3)2(R)Re=CH2 (R = H, CH3). Journal of the American Chemical Society. 126: 14804-15. PMID 15535706 DOI: 10.1021/Ja0468877  0.805
2004 Tan KL, Park S, Ellman JA, Bergman RG. Intermolecular coupling of alkenes to heterocycles via C-H bond activation. The Journal of Organic Chemistry. 69: 7329-35. PMID 15471487 DOI: 10.1021/Jo048666P  0.722
2004 Yung CM, Skaddan MB, Bergman RG. Stoichiometric and catalytic H/D incorporation by cationic iridium complexes: a common monohydrido-iridium intermediate. Journal of the American Chemical Society. 126: 13033-43. PMID 15469302 DOI: 10.1021/Ja046825G  0.728
2004 Ruck RT, Bergman RG. Zirconium-mediated conversion of amides to nitriles: a surprising additive effect. Angewandte Chemie (International Ed. in English). 43: 5375-7. PMID 15468091 DOI: 10.1002/Anie.200461064  0.773
2004 Ruck RT, Zuckerman RL, Krska SW, Bergman RG. Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes. Angewandte Chemie (International Ed. in English). 43: 5372-4. PMID 15468090 DOI: 10.1002/Anie.200461063  0.824
2004 Krumper JR, Gerisch M, Magistrato A, Rothlisberger U, Bergman RG, Tilley TD. Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. Journal of the American Chemical Society. 126: 12492-502. PMID 15453783 DOI: 10.1021/Ja047665B  0.815
2004 Rais D, Bergman RG. Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)]. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 3970-8. PMID 15317061 DOI: 10.1002/Chem.200400151  0.432
2004 Anderson LL, Arnold J, Bergman RG. Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes. Organic Letters. 6: 2519-22. PMID 15255680 DOI: 10.1021/Ol0492851  0.715
2004 Thalji RK, Ellman JA, Bergman RG. Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation. Journal of the American Chemical Society. 126: 7192-3. PMID 15186153 DOI: 10.1021/Ja0394986  0.626
2004 Wiedemann SH, Bergman RG, Ellman JA. Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes. Organic Letters. 6: 1685-7. PMID 15128267 DOI: 10.1021/Ol049417Q  0.808
2004 Fiedler D, Leung DH, Bergman RG, Raymond KN. Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly. Journal of the American Chemical Society. 126: 3674-5. PMID 15038695 DOI: 10.1021/Ja039225A  0.755
2004 Cordaro JG, Bergman RG. Elimination of R-H from iridium acyl hydrides without loss of CO: evidence for the intervention of metal cation/carbanion pairs. Journal of the American Chemical Society. 126: 3432-3. PMID 15025464 DOI: 10.1021/Ja031784U  0.815
2004 Leung DH, Fiedler D, Bergman RG, Raymond KN. Selective C-H bond activation by a supramolecular host-guest assembly. Angewandte Chemie (International Ed. in English). 43: 963-6. PMID 14966879 DOI: 10.1002/Anie.200352772  0.75
2004 Fiedler D, Pagliero D, Brumaghim JL, Bergman RG, Raymond KN. Encapsulation of cationic ruthenium complexes into a chiral self-assembled cage. Inorganic Chemistry. 43: 846-8. PMID 14753801 DOI: 10.1021/Ic035105S  0.683
2004 Hoyt HM, Michael FE, Bergman RG. C-H bond activation of hydrocarbons by an imidozirconocene complex. Journal of the American Chemical Society. 126: 1018-9. PMID 14746459 DOI: 10.1021/Ja0385944  0.822
2004 Lewis JC, Wiedemann SH, Bergman RG, Ellman JA. Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization. Organic Letters. 6: 35-8. PMID 14703344 DOI: 10.1021/Ol035985E  0.836
2004 Skaddan MB, Yung CM, Bergman RG. Stoichiometric and catalytic deuterium and tritium labeling of "unactivated" organic substrates with cationic Ir(III) complexes. Organic Letters. 6: 11-3. PMID 14703338 DOI: 10.1021/Ol0359923  0.728
2004 Park Y, Kim J, Yun D, Bergman RG, Vollhardt KPC. Intramolecular Double C-H Activation in FvM2(en)4(Fv=fulvalene; M=Ir, Rh; en=ethylene) Journal of the Korean Chemical Society. 48: 327-330. DOI: 10.5012/Jkcs.2004.48.3.327  0.384
2004 Fox DJ, Bergman RG. Synthesis of an Iron Parent Amido Complex and a Comparison of Its Reactivity with the Ruthenium Analog Organometallics. 23: 1656-1670. DOI: 10.1021/Om0499660  0.415
2004 Taw FL, Bergman RG, Brookhart M. Silicon-hydrogen bond activation and formation of silane complexes using a cationic rhodium(III) complex Organometallics. 23: 886-890. DOI: 10.1021/Om0341303  0.448
2004 Blum SA, Walsh PJ, Bergman RG. Epoxide-Opening and Group-Transfer Reactions Mediated by Monomeric Zirconium Imido Complexes [J. Am. Chem. Soc.2003,125, 14276−14277]. Journal of the American Chemical Society. 126: 9148-9148. DOI: 10.1021/Ja0408146  0.729
2004 Corkey BK, Taw FL, Bergman RG, Brookhart M. Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition Polyhedron. 23: 2943-2954. DOI: 10.1016/J.Poly.2004.09.005  0.421
2004 Fiedler D, Bergman RG, Raymond KN. Cover Picture: Supramolecular Catalysis of a Unimolecular Transformation: Aza-Cope Rearrangement within a Self-Assembled Host (Angew. Chem. Int. Ed. 48/2004) Angewandte Chemie International Edition. 43: 6565-6565. DOI: 10.1002/Anie.200490169  0.613
2004 Fiedler D, Bergman RG, Raymond KN. Titelbild: Supramolecular Catalysis of a Unimolecular Transformation: Aza-Cope Rearrangement within a Self-Assembled Host (Angew. Chem. 48/2004) Angewandte Chemie. 116: 6727-6727. DOI: 10.1002/Ange.200490164  0.612
2004 Pluth MD, Bergman RG, Raymond KN. Encapsulation of cationic organometallic guests by a chiral self-assembled supramolecular cage: Enantioselective binding, dynamic resolution, and selective C-H bond activation Chemtracts. 17: 515-522.  0.649
2003 Fox DJ, Bergman RG. Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond. Journal of the American Chemical Society. 125: 8984-5. PMID 15369333 DOI: 10.1021/Ja035707A  0.651
2003 Krumper JR, Gerisch M, Suh JM, Bergman RG, Tilley TD. Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. The Journal of Organic Chemistry. 68: 9705-10. PMID 14656097 DOI: 10.1021/Jo035120E  0.818
2003 Blum SA, Walsh PJ, Bergman RG. Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes. Journal of the American Chemical Society. 125: 14276-7. PMID 14624566 DOI: 10.1021/Ja037267T  0.747
2003 Ackermann L, Bergman RG, Loy RN. Use of group 4 bis(sulfonamido) complexes in the intramolecular hydroamination of alkynes and allenes. Journal of the American Chemical Society. 125: 11956-63. PMID 14505417 DOI: 10.1021/Ja0361547  0.74
2003 Welch EJ, Crawford NR, Bergman RG, Long JR. New routes to transition metal-carbido species: synthesis and characterization of the carbon-centered trigonal prismatic clusters [W(6)CCl(18)](n)(-) (n = 1, 2, 3). Journal of the American Chemical Society. 125: 11464-5. PMID 13129326 DOI: 10.1021/Ja035962V  0.326
2003 Taw FL, Mueller AH, Bergman RG, Brookhart M. A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. Journal of the American Chemical Society. 125: 9808-13. PMID 12904046 DOI: 10.1021/Ja034468O  0.461
2003 Stewart IC, Bergman RG, Toste FD. Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base. Journal of the American Chemical Society. 125: 8696-7. PMID 12862443 DOI: 10.1021/Ja035232N  0.706
2003 Michael FE, Duncan AP, Sweeney ZK, Bergman RG. Mechanisms of allene stereoinversion by imidozirconium complexes. Journal of the American Chemical Society. 125: 7184-5. PMID 12797785 DOI: 10.1021/Ja0348389  0.805
2003 Tan KL, Vasudevan A, Bergman RG, Ellman JA, Souers AJ. Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles. Organic Letters. 5: 2131-4. PMID 12790546 DOI: 10.1021/Ol030050J  0.729
2003 Blum SA, Tan KL, Bergman RG. Application of physical organic methods to the investigation of organometallic reaction mechanisms. The Journal of Organic Chemistry. 68: 4127-37. PMID 12762711 DOI: 10.1021/Jo034198S  0.757
2003 Ahrendt KA, Bergman RG, Ellman JA. Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation. Organic Letters. 5: 1301-3. PMID 12688744 DOI: 10.1021/Ol034228D  0.615
2003 Blum SA, Bergman RG, Ellman JA. Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation. The Journal of Organic Chemistry. 68: 150-5. PMID 12515473 DOI: 10.1021/Jo0205560  0.746
2003 Bergman RG, Cundari TR, Gillespie AM, Gunnoe TB, Harman WD, Klinckman TR, Temple MD, White DP. Computational study of methane activation by TpRe(CO)2 and CpRe(CO)2 with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands Organometallics. 22: 2331-2337. DOI: 10.1021/Om021048J  0.389
2003 Fox DJ, Bergman RG. Synthesis of a First-Row Transition Metal Parent Amido Complex and Carbon Monoxide Insertion into the Amide N−H Bond  [J. Am. Chem. Soc.2003,125, 8984−8985].  Journal of the American Chemical Society. 125: 11772-11772. DOI: 10.1021/Ja0334513  0.36
2003 Klei SR, Golden JT, Burger P, Bergman RG. Cationic Ir(III) Alkyl and Hydride Complexes: Stoichiometric and Catalytic C—H Activation by Cp*(PMe3)Ir(R)(X) in Homogeneous Solution Cheminform. 34. DOI: 10.1016/S1381-1169(02)00192-9  0.813
2003 Fruchart J, Gras-Masse H, Melnyk O, Fox DJ, Bergman RG. Comments on “Methyl phenylacetate enolate generated with the P4-tBu Schwesinger base: ‘naked’ or not?” Tetrahedron Letters. 44: 2243. DOI: 10.1016/S0040-4039(02)02866-6  0.535
2003 Threlkel RS, Bercaw JE, Seidler PF, Stryker JM, Bergman RG. 1,2,3,4,5-Pentamethylcyclopentadiene Organic Syntheses. DOI: 10.1002/0471264180.Os065.07  0.398
2002 Duncan AP, Bergman RG. Selective transformations of organic compounds by imidozirconocene complexes. Chemical Record (New York, N.Y.). 2: 431-45. PMID 12469354 DOI: 10.1002/Tcr.10039  0.717
2002 Holland AW, Bergman RG. Effects of phosphine ligand chelation on the reactivity of monomeric parent amido ruthenium complexes: synthesis and reactivity of such a complex bearing monodentate ligands. Journal of the American Chemical Society. 124: 14684-95. PMID 12465980 DOI: 10.1021/Ja027620F  0.766
2002 Tan KL, Bergman RG, Ellman JA. Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation. Journal of the American Chemical Society. 124: 13964-5. PMID 12440873 DOI: 10.1021/Ja0281129  0.721
2002 Asplund MC, Snee PT, Yeston JS, Wilkens MJ, Payne CK, Yang H, Kotz KT, Frei H, Bergman RG, Harris CB. Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. Journal of the American Chemical Society. 124: 10605-12. PMID 12197763 DOI: 10.1021/Ja020418S  0.57
2002 Cordaro JG, McCusker JK, Bergman RG. Synthesis of mono-substituted 2,2'-bipyridines. Chemical Communications (Cambridge, England). 1496-7. PMID 12189861 DOI: 10.1039/B203595B  0.798
2002 Holland AW, Bergman RG. Heterocumulene metathesis by iridium guanidinate and ureylene complexes: catalysis involving reversible insertion to form six-membered metallacycles. Journal of the American Chemical Society. 124: 9010-1. PMID 12148979 DOI: 10.1021/Ja026178Y  0.738
2002 Taw FL, Mellows H, White PS, Hollander FJ, Bergman RG, Brookhart M, Heinekey DM. Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. Journal of the American Chemical Society. 124: 5100-8. PMID 11982375 DOI: 10.1021/Ja0165990  0.378
2002 Ackermann L, Bergman RG. A highly reactive titanium precatalyst for intramolecular hydroamination reactions. Organic Letters. 4: 1475-8. PMID 11975607 DOI: 10.1021/Ol0256724  0.606
2002 Fulton JR, Sklenak S, Bouwkamp MW, Bergman RG. A comprehensive investigation of the chemistry and basicity of a parent amidoruthenium complex Journal of the American Chemical Society. 124: 4722-4737. PMID 11971722 DOI: 10.1021/Ja011876O  0.714
2002 Taw FL, White PS, Bergman RG, Brookhart M. Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. Journal of the American Chemical Society. 124: 4192-3. PMID 11960431 DOI: 10.1021/Ja0255094  0.372
2002 Tan KL, Bergman RG, Ellman JA. Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole. Journal of the American Chemical Society. 124: 3202-3. PMID 11916392 DOI: 10.1021/Ja017351D  0.748
2002 Klei SR, Golden JT, Tilley TD, Bergman RG. Iridium-catalyzed H/D exchange into organic compounds in water. Journal of the American Chemical Society. 124: 2092-3. PMID 11878944 DOI: 10.1021/Ja017219D  0.821
2002 Tellers DM, Yung CM, Arndtsen BA, Adamson DR, Bergman RG. Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes. Journal of the American Chemical Society. 124: 1400-10. PMID 11841308 DOI: 10.1021/Ja011809U  0.821
2002 Fulton JR, Holland AW, Fox DJ, Bergman RG. Formation, reactivity, and properties of nondative late transition metal-oxygen and -nitrogen bonds. Accounts of Chemical Research. 35: 44-56. PMID 11790088 DOI: 10.1021/Ar000132X  0.815
2002 Klei SR, Tilley TD, Bergman RG. Iridium (III) and rhodium (III) complexes bearing chelating cyclopentadienyl-phosphine ligands as C-H activation catalysts for the deuteration of hydrocarbons in D2O Organometallics. 21: 4905-4911. DOI: 10.1021/Om020375O  0.843
2002 Klei SR, Tilley TD, Bergman RG. Stoichiometric and catalytic behavior of cationic silyl and silylene complexes Organometallics. 21: 4648-4661. DOI: 10.1021/Om0203173  0.84
2002 Holland AW, Bergman RG. Regiocontrol of cyclometalation in a P4Ru(II) system. Unusual base-induced metalation within a chelate ring versus activation of a methyl group Organometallics. 21: 2149-2152. DOI: 10.1021/Om0202470  0.728
2002 Klei SR, Don Tilley T, Bergman RG. Reactions of Cp*(PMe3)Ir(Me)OTf with silanes: Role of base-free silylene complexes in rearrangements of the resulting silicon-based ligands Organometallics. 21: 3376-3387. DOI: 10.1021/Om020191+  0.83
2002 Klei SR, Golden JT, Burger P, Bergman RG. Cationic Ir(III) alkyl and hydride complexes: Stoichiometric and catalytic C-H activation by Cp*(PMe3 Ir(R)(X) in homogeneous solution Journal of Molecular Catalysis a: Chemical. 189: 79-94. DOI: 10.1016/S1381-1169(02)00192-9  0.818
2002 Holland AW, Bergman RG. Thermal reactivity of Group 9 transition metal pinacolate complexes: Heterocumulene cleavage and C-O bond formation Inorganica Chimica Acta. 341: 99-106. DOI: 10.1016/S0020-1693(02)01234-3  0.752
2002 Paisner SN, Lavoie GG, Bergman RG. Formation of planar-chiral alkylphosphine- and aniline-substituted cyclopentadienyl metal complexes and their reactivity toward electrophiles Inorganica Chimica Acta. 334: 253-275. DOI: 10.1016/S0020-1693(02)00742-9  0.803
2001 Szewczyk JW, Zuckerman RL, Bergman RG, Ellman JA. A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation. Angewandte Chemie (International Ed. in English). 40: 216-219. PMID 29711936 DOI: 10.1002/1521-3773(20010105)40:1<216::Aid-Anie216>3.0.Co;2-K  0.795
2001 Zuckerman RL, Bergman RG. Mechanistic Investigation of Cycloreversion/Cycloaddition Reactions between Zirconocene Metallacycle Complexes and Unsaturated Organic Substrates. Organometallics. 20: 1792-1807. PMID 16724160 DOI: 10.1021/Om010091O  0.783
2001 Straub BF, Bergman RG. The mechanism of hydroamination of allenes, alkynes, and alkenes catalyzed by cyclopentadienyltitanium-imido complexes: a density functional study. Angewandte Chemie (International Ed. in English). 40: 4632-5. PMID 12404369 DOI: 10.1002/1521-3773(20011217)40:24<4632::Aid-Anie4632>3.0.Co;2-V  0.378
2001 Mullins SM, Duncan AP, Bergman RG, Arnold J. Reactivity of a titanium dinitrogen complex supported by guanidinate ligands: investigation of solution behavior and a novel rearrangement of guanidinate ligands. Inorganic Chemistry. 40: 6952-63. PMID 11754277 DOI: 10.1021/Ic010631+  0.8
2001 Kalck P, Wheatley N, Bergman RG. Addendum to structure and reactivity of early-late heterobimetallic complexes. Chemical Reviews. 101: 207-8. PMID 11749366 DOI: 10.1021/Cr000701E  0.323
2001 Tellers DM, Bergman RG. Binding of chlorohydrocarbons to metal centers: quantitative evaluation of relative binding constants and structural characterization of the first isolable transition metal-chloromethane adduct. Journal of the American Chemical Society. 123: 11508-9. PMID 11707141 DOI: 10.1021/Ja0164982  0.669
2001 Thalji RK, Ahrendt KA, Bergman RG, Ellman JA. Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst. Journal of the American Chemical Society. 123: 9692-3. PMID 11572698 DOI: 10.1021/Ja016642J  0.542
2001 Johnson JS, Bergman RG. Imidotitanium complexes as hydroamination catalysts: substantially enhanced reactivity from an unexpected cyclopentadienide/amide ligand exchange. Journal of the American Chemical Society. 123: 2923-4. PMID 11456996 DOI: 10.1021/Ja005685H  0.65
2001 Tan KL, Bergman RG, Ellman JA. Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions. Journal of the American Chemical Society. 123: 2685-6. PMID 11456947 DOI: 10.1021/ja0058738  0.698
2001 Golden JT, Andersen RA, Bergman RG. Exceptionally low-temperature carbon--hydrogen/carbon--deuterium exchange reactions of organic and organometallic compounds catalyzed by the Cp*(PMe(3))IrH(ClCH(2)Cl)(+) cation. Journal of the American Chemical Society. 123: 5837-8. PMID 11403632 DOI: 10.1021/Ja0155480  0.788
2001 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. Journal of the American Chemical Society. 123: 5818-9. PMID 11403623 DOI: 10.1021/Ja005857A  0.808
2001 Szewczyk JW, Zuckerman RL, Bergman RG, Ellman JA. A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, U.S. Department of Energy, under contract No. DE-AC03-76SF00098. We are grateful to the National Institutes of Health for support (GM-50353) and for a Postdoctoral Fellowship to J.W.S. Angewandte Chemie (International Ed. in English). 40: 216-219. PMID 11169717 DOI: 10.1002/1521-3773(20010105)40:1<216::Aid-Anie216>3.3.Co;2-B  0.774
2001 Tellers DM, Bergman RG. Mechanistic study of ligand substitution processes in TpIr(III) complexes Canadian Journal of Chemistry. 79: 525-528. DOI: 10.1139/V00-162  0.706
2001 Klei SR, Tilley TD, Bergman RG. An observable silene/silylene rearrangement in a cationic iridium complex Organometallics. 20: 3220-3222. DOI: 10.1021/Om010435A  0.805
2001 Ini S, Oliver AG, Tilley TD, Bergman RG. Synthesis, structure, and hydrosilylation catalysis of a chiral a-frame rhodium(I) dimer with cis diphosphite ligands Organometallics. 20: 3839-3841. DOI: 10.1021/Om010428M  0.386
2001 Holland AW, Glueck DS, Bergman RG. Photochemical reactivity of group 9 metal pinacolate complexes Organometallics. 20: 2250-2261. DOI: 10.1021/Om0010870  0.811
2001 Duncan AP, Mullins SM, Arnold J, Bergman RG. Synthesis, Structural Investigation, and Reactivity of Neutral and Cationic Bis(guanidinato)zirconium(IV) Complexes Organometallics. 20: 1808-1819. DOI: 10.1021/Om000995U  0.8
2001 Peterson TH, Golden JT, Bergman RG. Evidence for the intervention of different C-H activating intermediates in the irradiation of (η5-C5Me5)(PMe3) IrH2 and the reaction of (η5-C5Me5)(PMe3)Ir(H)(Cl) with strong base Journal of the American Chemical Society. 123: 455-462. DOI: 10.1021/Ja0024993  0.793
2001 Alaimo PJ, Peters DW, Arnold J, Bergman RG. Suggested Modifications to a Distillation-Free Solvent Purification System Journal of Chemical Education. 78: 64. DOI: 10.1021/Ed078P64  0.416
2001 Paisner SN, Bergman RG. High performance liquid chromatography for facile analytical separation of the enantiomers of chiral organometallic complexes Journal of Organometallic Chemistry. 621: 242-245. DOI: 10.1016/S0022-328X(00)00862-7  0.8
2000 Fulton JR, Bouwkamp MW, Bergman RG. Reactivity of a parent amidoruthenium complex: a transition metal amide of exceptionally high basicity. Journal of the American Chemical Society. 122: 8799-800. PMID 16636699 DOI: 10.1021/Ja001622N  0.762
2000 Zuckerman RL, Krska SW, Bergman RG. Zirconium-mediated metathesis of imines: a study of the scope, longevity, and mechanism of a complicated catalytic system. Journal of the American Chemical Society. 122: 751-61. PMID 16636698 DOI: 10.1021/Ja992869R  0.832
2000 Sweeney ZK, Salsman JL, Andersen RA, Bergman RG. Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism. Angewandte Chemie (International Ed. in English). 39: 2339-43. PMID 10941084 DOI: 10.1002/1521-3773(20000703)39:13<2339::Aid-Anie2339>3.0.Co;2-W  0.43
2000 Alaimo PJ, Arndtsen BA, Bergman RG. Alkylation of Iridium via Tandem Carbon−Hydrogen Bond Activation/Decarbonylation of Aldehydes. Access to Complexes with Tertiary and Highly Hindered Metal−Carbon Bonds Organometallics. 19: 2130-2143. DOI: 10.1021/Om9910064  0.497
2000 Fulton JR, Hanna TA, Bergman RG. Insertion of Nitriles into a Zirconium−Iridium Heterobimetallic Complex:  A Mechanistic Study Organometallics. 19: 602-614. DOI: 10.1021/Om990785L  0.356
2000 Zuckerman RL, Bergman RG. Structural Factors that Influence the Course of Overall [2 + 2] Cycloaddition Reactions between Imidozirconocene Complexes and Heterocumulenes Organometallics. 19: 4795-4809. DOI: 10.1021/Om000614C  0.403
2000 Yeston JS, Bergman RG. Intramolecular B−H Bond Activation from a Dihydridobis(dimethylpyrazolyl)borate Ligand:  Formation of a Rhodium(III) Carbene Hydride and a Rare Example of Reverse α-Hydride Migration Organometallics. 19: 2947-2949. DOI: 10.1021/Om000365S  0.452
2000 Tellers DM, Skoog SJ, Bergman RG, Gunnoe TB, Harman WD. Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands:  Different Interactions with Different Transition Metals Organometallics. 19: 2428-2432. DOI: 10.1021/Om000043O  0.696
2000 Paisner SN, Burger P, Bergman RG. Mechanistic Investigation of the Reaction of Iridium Dihydride Complexes with Organic Acid Chlorides Organometallics. 19: 2073-2083. DOI: 10.1021/Om000039C  0.795
2000 Skoog SJ, Mateo C, Lavoie GG, Hollander FJ, Bergman RG. Synthesis of Novel Group 4 Complexes Bearing the Tropidinyl Ligand:  Investigations of Dynamic Behavior, Reactivity, and Catalytic Olefin Polymerization Organometallics. 19: 1406-1421. DOI: 10.1021/Om000038K  0.456
2000 Tellers DM, Bergman RG. C-H bond activation by a rare cationic iridium dinitrogen complex. An important electronic effect in the chemistry of the hydridotris(pyrazolyl)borate ligand [3] Journal of the American Chemical Society. 122: 954-955. DOI: 10.1021/Ja993347E  0.711
2000 Klei SR, Tilley TD, Bergman RG. The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination [8] Journal of the American Chemical Society. 122: 1816-1817. DOI: 10.1021/Ja992954Z  0.806
2000 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric Cyclopentadienylnickel Methoxo and Amido Complexes:  Synthesis, Characterization, Reactivity, and Use for Exploring the Relationship between M−X and H−X Bond Energies [J. Am. Chem. Soc.1997,119, 12800−12814]. Journal of the American Chemical Society. 122: 9352-9352. DOI: 10.1021/Ja004657W  0.68
2000 Zuckerman RL, Krska SW, Bergman RG. Erratum to: “Reversible CH activation of an N-methyl group in a bis-Zr(IV) diazametallacycle: generation of an end-on, side-on coordinated bridging alkylideneamido ligand” [Journal of Organometallic Chemistry 591 (1999) 2–7] Journal of Organometallic Chemistry. 608: 172. DOI: 10.1016/S0022-328X(00)00413-7  0.792
2000 Mullins SM, Hagadorn JR, Bergman* RG, Arnold* J. Synthesis of tantalum fluoride complexes supported by bis(trimethylsilyl)benzamidinate ligands. X-ray structures of [PhC(NSiMe3)2]2TaF3 and [PhC(NSiMe3)2]2TaFPh2 Journal of Organometallic Chemistry. 607: 227-232. DOI: 10.1016/S0022-328X(00)00376-4  0.71
2000 Sweeney ZK, Salsman JL, Andersen RA, Bergman RG. Synthesis of chiral, enantiopure zirconocene imido complexes: Highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism Angewandte Chemie - International Edition. 39: 2339-2343. DOI: 10.1002/1521-3773(20000703)39:13<2339::AID-ANIE2339>3.0.CO;2-W  0.54
1999 Sweeney ZK, Polse JL, Bergman RG, Andersen RA. Dihydrogen Activation by Titanium Sulfide Complexes. Organometallics. 18: 5502-5510. PMID 16633550 DOI: 10.1021/Om9907876  0.595
1999 Tellers DM, Ritter JC, Bergman RG. Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp(PMe(3))IrPh(OH) and [Cp(PMe(3))Ir(Ph)NCR](+). Inorganic Chemistry. 38: 4810-4818. PMID 11671210 DOI: 10.1021/Ic9907157  0.753
1999 Holland PL, Andersen RA, Bergman RG. Application of theE-CApproach to Understanding the Bond Energies Thermodynamics of Late-Metal Amido, Aryloxo and Alkoxo Complexes: An Alternative to pπ/dπ Repulsion Comments On Inorganic Chemistry. 21: 115-129. DOI: 10.1080/02603599908020418  0.698
1999 Mullins SM, Bergman RG, Arnold J. Double Group Transfer Reactions of an Unsaturated Tantalum Methylidene Complex with PyridineN-Oxides Organometallics. 18: 4465-4467. DOI: 10.1021/Om9906870  0.696
1999 Aubart MA, Bergman RG. Tantalum-Mediated Cleavage of an NN Bond in an Organic Diazene (Azoarene) to Produce an Imidometal (MNR) Complex:  An η2-Diazene Complex Is Not an Intermediate Organometallics. 18: 811-813. DOI: 10.1021/Om9809668  0.369
1999 Peterson TH, Golden JT, Bergman RG. Deprotonation of the Transition Metal Hydride (η5-C5Me5)(PMe3)IrH2. Synthesis and Chemistry of the Strongly Basic Lithium Iridate (η5-C5Me5)(PMe3)Ir(H)(Li) Organometallics. 18: 2005-2020. DOI: 10.1021/Om980945D  0.781
1999 McNamara BK, Yeston JS, Bergman RG, Moore CB. The effect of alkane structure on rates of photoinduced C-H bond activation by Cp*Rh(CO)2 in liquid rare gas media: An infrared flash kinetics study Journal of the American Chemical Society. 121: 6437-6443. DOI: 10.1021/Ja9904282  0.534
1999 McNeill K, Bergman RG. Rapid Reduction of Nitric Oxide to Dinitrogen by Zirconium(II):  Kinetic Studies on a Reaction Controlled by Gas−Liquid Transport Journal of the American Chemical Society. 121: 8260-8269. DOI: 10.1021/Ja983011P  0.536
1999 Zuckerman RL, Krska SW, Bergman RG. Reversible CH activation of an N-methyl group in a bis-Zr(IV) diazametallacycle: generation of an end-on, side-on coordinated bridging alkylideneamido ligand Journal of Organometallic Chemistry. 591: 2-7. DOI: 10.1016/S0022-328X(99)00505-7  0.805
1998 Kaplan AW, Bergman RG. Nitrous Oxide Mediated Synthesis of Monomeric Hydroxoruthenium Complexes. Reactivity of (DMPE)2Ru(H)(OH) and the Synthesis of a Silica-Bound Ruthenium Complex Organometallics. 17: 5072-5085. DOI: 10.1021/Om980295D  0.444
1998 Asbury JB, Ghosh HN, Yeston JS, Bergman RG, Lian T. Sub-Picosecond IR Study of the Reactive Intermediate in an Alkane C−H Bond Activation Reaction by CpRh(CO)2 Organometallics. 17: 3417-3419. DOI: 10.1021/Om980194F  0.563
1998 Holland PL, Andersen RA, Bergman RG. Cyclopentadienyl and Imide Ligand Transfer from Zirconium to Iridium:  Can Early Transition Metal Imido Compounds Be Used as Imide Transfer Reagents? Organometallics. 17: 433-437. DOI: 10.1021/Om970827A  0.713
1998 Luecke HF, Bergman RG. Synthesis, Structural Characterization, and Chemistry of a Monomeric Cationic Iridium Carbyne Complex Journal of the American Chemical Society. 120: 11008-11009. DOI: 10.1021/Ja982641O  0.402
1998 Krska SW, Zuckerman RL, Bergman RG. Use of steric hindrance and a metallacyclobutene resting state to develop robust and kinetically characterizable zirconium-based imine metathesis catalysts [17] Journal of the American Chemical Society. 120: 11828-11829. DOI: 10.1021/Ja982569U  0.78
1998 Poise JL, Andersen RA, Bergman RG. Reactivity of a terminal Ti(IV) imido complex toward alkenes and alkynes: Cycloaddition vs C-H activation Journal of the American Chemical Society. 120: 13405-13414. DOI: 10.1021/Ja981489N  0.605
1998 Kaplan AW, Polse JL, Ball GE, Andersen RA, Bergman RG. Synthesis, structure, and reactivity of η2-N2-aryldiazoalkane titanium complexes: Cleavage of the N-N bond Journal of the American Chemical Society. 120: 11649-11662. DOI: 10.1021/Ja981340B  0.626
1998 Aubart MA, Bergman RG. Reaction of Organic Disulfides with Cobalt-Centered Metal Radicals. Use of theE- andC-Based Dual-Parameter Substituent Model and Quantitative Solvent Effect Analyses To Compare Outer-Sphere and Inner-Sphere Electron-Transfer Processes Journal of the American Chemical Society. 120: 8755-8766. DOI: 10.1021/Ja980878E  0.404
1998 Sweeney ZK, Polse JL, Andersen RA, Bergman RG. Cycloaddition and nucleophilic substitution reactions of the monomeric titanocene sulfido complex (η5-C5Me5)2(C5H5N)Ti=S Journal of the American Chemical Society. 120: 7825-7834. DOI: 10.1021/Ja980877M  0.575
1998 Ritter JCM, Bergman RG. A Useful Method for Preparing Iridium Alkoxides and a Study of Their Catalytic Decomposition by Iridium Cations:  A New Mode of β-Hydride Elimination for Coordinatively Saturated Metal Alkoxides Journal of the American Chemical Society. 120: 6826-6827. DOI: 10.1021/Ja980672D  0.312
1998 Kaplan AW, Ritter JCM, Bergman RG. Synthesis and Structural Characterization of Late Transition Metal Parent Amido (LnM-NH2) Complexes: An Acid/Conjugate Base Metathesis Approach Journal of the American Chemical Society. 120: 6828-6829. DOI: 10.1021/Ja980632+  0.332
1998 Mobley TA, Bergman RG. The Use of a Planar Chiral Ligand to Effect C−H Activation with Asymmetric Induction at an Iridium Center. Dramatically Different C−H Activation Stereoselectivities for Benzene and Cyclohexane Journal of the American Chemical Society. 120: 3253-3254. DOI: 10.1021/Ja974323F  0.335
1998 Polse JL, Kaplan AW, Andersen RA, Bergman RG. Synthesis of an η2-N2-titanium diazoalkane complex with both imido- metal carbene-like reactivity patterns Journal of the American Chemical Society. 120: 6316-6328. DOI: 10.1021/Ja974303D  0.566
1998 Golden JT, Peterson TH, Holland PL, Bergman RG, Andersen RA. Adduct formation and single and double deprotonation of Cp*(PMe3)Ir(H)2 with main group metal alkyls and aryls: Synthesis and structure of three novel Ir-Al and Ir-Mg heterobimetallics Journal of the American Chemical Society. 120: 223-224. DOI: 10.1021/Ja973230V  0.806
1998 Howard WA, Bergman RG. The synthesis of olefin, carbonyl and thiolate complexes of platinum(IV) in the [η5-C5Me5)Pt(IV)] system. Crystal and molecular structure of (η2-C5Me5)PtMe2[S(p-CH3(C6H4] Polyhedron. 17: 803-810. DOI: 10.1016/S0277-5387(97)00397-5  0.384
1998 Christoffers J, Bergman RG. Zirconocene-alumoxane (1:1) — a catalyst for the selective dimerization of α-olefins Inorganica Chimica Acta. 270: 20-27. DOI: 10.1016/S0020-1693(97)05819-2  0.368
1997 Bromberg SE, Yang H, Asplund MC, Lian T, McNamara BK, Kotz KT, Yeston JS, Wilkens M, Frei H, Bergman RG, Harris CB. The mechanism of a C-H bond activation reaction in room-temperature alkane solution Science. 278: 260-263. DOI: 10.1126/Science.278.5336.260  0.577
1997 Kaplan AW, Bergman RG. Nitrous Oxide Mediated Oxygen Atom Insertion into a Ruthenium−Hydride Bond. Synthesis and Reactivity of the Monomeric Hydroxoruthenium Complex (DMPE)2Ru(H)(OH) Organometallics. 16: 1106-1108. DOI: 10.1021/Om960991I  0.458
1997 Luecke HF, Bergman RG. Synthesis and C−H Activation Reactions of Cyclometalated Complexes of Ir(III):  Cp*(PMe3)Ir(CH3)+Does Not Undergo Intermolecular C−H Activation in Solution via a Cyclometalated Intermediate Journal of the American Chemical Society. 119: 11538-11539. DOI: 10.1021/Ja972340Z  0.413
1997 McNeill K, Andersen RA, Bergman RG. C-C and C-H bond activation at ruthenium(II): The stepwise degradation of a neopentyl ligand to a trimethylenemethane ligand Journal of the American Chemical Society. 119: 11244-11254. DOI: 10.1021/Ja972131E  0.681
1997 Holland PL, Smith ME, Andersen RA, Bergman RG. X-ray crystal structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p- C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3 +]. Understanding distortions and trans influences in cyclopentadienyl complexes Journal of the American Chemical Society. 119: 12815-12823. DOI: 10.1021/Ja971830O  0.66
1997 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric cyclopentadienylnickel methoxo and amido complexes: Synthesis, characterization, reactivity, and use for exploring the relationship between H-X and M-X bond energies Journal of the American Chemical Society. 119: 12800-12814. DOI: 10.1021/Ja971829P  0.683
1997 Alaimo PJ, Arndtsen BA, Bergman RG. Synthesis of Tertiary and Other Sterically Demanding Alkyl and Aryl Complexes of Iridium by Aldehyde C−H Bond Activation Journal of the American Chemical Society. 119: 5269-5270. DOI: 10.1021/Ja970245K  0.698
1997 Ritter JCM, Bergman RG. The Mechanism of Addition of an Ir−OH bond to Ethylene. Catalytic Tandem Activation by Two [η5-Cp*(Ph)IrPMe3]+Complex Fragments Journal of the American Chemical Society. 119: 2580-2581. DOI: 10.1021/Ja9636653  0.388
1997 Lavoie GG, Bergman RG. Synthesis, Structural Characterization, and Reactivity of Novel Zirconium(IV) Complexes Containing the Tropidinyl Ligand Angewandte Chemie International Edition in English. 36: 2450-2452. DOI: 10.1002/Anie.199724501  0.399
1997 Lavoie GG, Bergman RG. Synthese, Struktur und Reaktivität von Zirconium(IV)-Komplexen mit Tropidinylliganden Angewandte Chemie. 109: 2555-2558. DOI: 10.1002/Ange.19971092208  0.304
1996 Hanna TA, Baranger AM, Bergman RG. Reactivity of Zirconocene Azametallacyclobutenes: Insertion of Aldehydes, Carbon Monoxide, and Formation of alpha,beta-Unsaturated Imines. Formation and Trapping of [Cp(2)Zr=O] in a [4 + 2] Retrocycloaddition(1). The Journal of Organic Chemistry. 61: 4532-4541. PMID 11667377 DOI: 10.1021/Jo9521561  0.708
1996 Proulx G, Bergman RG. Synthesis, Structures, and Kinetics and Mechanism of Decomposition of Terminal Metal Azide Complexes: Isolated Intermediates in the Formation of Imidometal Complexes from Organic Azides Organometallics. 15: 684-692. DOI: 10.1021/Om950796O  0.356
1996 Proulx G, Bergman RG. Synthesis of Alkyltantalocene Oxide, Sulfide, and Imide Derivatives:  Stereospecific Heteroatom and -group Transfers from Oxiranes, Thiiranes, and Aziridines to Methyltantalocene Organometallics. 15: 133-141. DOI: 10.1021/Om950470F  0.32
1996 Polse JL, Andersen RA, Bergman RG. Synthesis, structure, and reactivity studies of an η2-N2-titanium diazoalkane complex. Generation and trapping of a carbene complex intermediate Journal of the American Chemical Society. 118: 8737-8738. DOI: 10.1021/Ja9614981  0.582
1996 Christoffers J, Bergman RG. Catalytic Dimerization Reactions of α-Olefins and α,ω-Dienes with Cp2ZrCl2/Poly(methylalumoxane):  Formation of Dimers, Carbocycles, and Oligomers Journal of the American Chemical Society. 118: 4715-4716. DOI: 10.1021/Ja960227N  0.313
1996 Lian T, Bromberg SE, Yang H, Proulx G, Bergman RG, Harris CB. Femtosecond IR studies of alkane C-H bond activation by organometallic compounds: Direct observation of reactive intermediates in room temperature solutions Journal of the American Chemical Society. 118: 3769-3770. DOI: 10.1021/Ja9541591  0.378
1996 Lee SY, Bergman RG. Generation of Oxozirconocene Complexes from the Reaction of Cp2(THF)ZrN-t-Bu with Organic and Metal Carbonyl Functionalities:  Apparently Divergent Behavior of Transient [Cp2ZrO] Journal of the American Chemical Society. 118: 6396-6406. DOI: 10.1021/Ja954050T  0.365
1996 Tagge CD, Bergman RG. Synthesis, X-ray Structure Determination, and Reactions of (Pentamethylcyclopentadienyl)(nitrosyl)ruthenium η2-Arene Complexes Journal of the American Chemical Society. 118: 6908-6915. DOI: 10.1021/Ja953711J  0.468
1996 Luecke HF, Arndtsen BA, Burger P, Bergman RG. Synthesis of Fischer carbene complex of iridium by C-H bond activation of methyl and cyclic ethers: Evidence for reversible α-hydrogen migration Journal of the American Chemical Society. 118: 2517-2518. DOI: 10.1021/Ja953437T  0.701
1996 Aubart MA, Bergman RG. Activation of Organic Disulfides by a Paramagnetic Heterobimetallic Tantalum/Cobalt Complex and a Comparison of Their Reactions with Cobaltocene. Evidence for a Dependence of Mechanism on the Electronic Properties of the Disulfide Journal of the American Chemical Society. 118: 1793-1794. DOI: 10.1021/Ja953331Y  0.384
1996 Holland PL, Andersen RA, Bergman RG. Synthesis, characterization, isomerization, and reactivity of dimeric cyclopentadienylnickel amido complexes Journal of the American Chemical Society. 118: 1092-1104. DOI: 10.1021/Ja952882L  0.698
1996 Tagge CD, Simpson RD, Bergman RG, Hosteller MJ, Girolami GS, Nuzzo RG. Synthesis of a novel volatile platinum complex for use in CVD and a study of the mechanism of its thermal decomposition in solution Journal of the American Chemical Society. 118: 2634-2643. DOI: 10.1021/Ja9526527  0.363
1996 Proulx G, Bergman RG. Reactions of Cp2Ta(CH2)(CH3) with Substituted and Unsubstituted Metal Carbonyls (Groups 7, 8, and 9). Evidence for Intermediates Involved in the Carbon−Carbon Bond-Forming Steps of the Reduction and Deoxygenation of CO Journal of the American Chemical Society. 118: 1981-1996. DOI: 10.1021/Ja951685J  0.401
1996 Lian T, Bromberg SE, Yang H, Asplund M, Bergman RG, Harris CB. Femtosecond IR studies of alkane C-H bond activation by organometallic compounds Springer Series in Chemical Physics. 62: 237-238. DOI: 10.1007/978-3-642-80314-7_102  0.45
1996 Hanna TA, Baranger AM, Bergman RG. Addition of Organic 1,3-Dipolar Compounds across a Heterobinuclear Bond between Early and Late Transition Metals: Mechanism of Nitrogen Loss from an Organoazido Complex To Form a Bridging Imido Complex Angewandte Chemie International Edition in English. 35: 653-655. DOI: 10.1002/Anie.199606531  0.69
1996 Hanna TA, Baranger AM, Bergman RG. Addition organischer 1,3-dipolarer Verbindungen an eine Bindung zwischen frühem und spätm Übergangsmetall (Zr-Ir): Mechanismus der Stickstoffabspaltung aus einem Organoazido-Komplex unter Bildung eines Komplexes mit verbrückenden Imidoliganden Angewandte Chemie. 108: 693-696. DOI: 10.1002/Ange.19961080617  0.627
1995 Bengali AA, Arndtsen BA, Burger PM, Schultz RH, Weiller BH, Kyle KR, Moore CB, Bergman RG. Activation of carbon-hydrogen bonds in alkanes and other organic molecules by lr(l), Rh(l) and Ir(lll) complexes Pure and Applied Chemistry. 67: 281-288. DOI: 10.1351/Pac199567020281  0.815
1995 Proulx G, Hollander FJ, Bergman RG. Reaction of Cp2(CH3)Ta=CH2 with Ru3(CO)12: deoxygenative coupling of carbon monoxide and methylene units to give a heteronuclear cluster-bound 4-cumulene ligand Canadian Journal of Chemistry. 73: 1111-1115. DOI: 10.1139/V95-137  0.419
1995 Arndtsen BA, Bergman RG. Unusually Mild and Selective Hydrocarbon C-H Bond Activation with Positively Charged Iridium(III) Complexes Science. 270: 1970-1973. DOI: 10.1126/Science.270.5244.1970  0.698
1995 Weydert M, Brennan JG, Andersen RA, Bergman RG. Reactions of a Uranium(IV) Tertiary Alkyl Bond: Facile Ligand-Assisted Reduction and Insertion of Ethylene and Carbon Monoxide Organometallics. 14: 3942-3951. DOI: 10.1021/Om00008A046  0.54
1995 Burn MJ, Fickes MG, Hollander FJ, Bergman RG. Reactions of (PMe3)4Ru(C2H4) and (DMPE)2Ru(C2H4) with Weak Proton-Donating Electrophiles HX (X = OAr, SAr, NHPh, PHPh). Synthesis of Complexes with Metal-Heteroatom Single Bonds Organometallics. 14: 137-150. DOI: 10.1021/Om00001A023  0.397
1995 Hanna TA, Baranger AM, Bergman RG. Reaction of Carbon Dioxide and Heterocumulenes with an Unsymmetrical Metal-Metal Bond. Direct Addition of Carbon Dioxide across a Zirconium-Iridium Bond and Stoichiometric Reduction of Carbon Dioxide to Formate Journal of the American Chemical Society. 117: 11363-11364. DOI: 10.1021/Ja00150A044  0.659
1995 Baranger AM, Hanna TA, Bergman RG. Transfer of Oxygen and Sulfur from Organic Molecules to a Zr-Ir Bond. Evidence for an Unusually Rapid Atom Abstraction Reaction Journal of the American Chemical Society. 117: 10041-10046. DOI: 10.1021/Ja00145A015  0.669
1995 Mobley TA, Schade C, Bergman RG. Diastereomeric and Isotopic Scrambling in (Hydrido)alkyliridium Complexes. Evidence for the Presence of a Common "Alkane Complex" Intermediate Journal of the American Chemical Society. 117: 7822-7823. DOI: 10.1021/Ja00134A034  0.428
1995 Proulx G, Bergman RG. Synthesis and Structure of a Terminal Metal Azide Complex: An Isolated Intermediate in the Formation of Imidometal Complexes from Organic Azides Journal of the American Chemical Society. 117: 6382-6383. DOI: 10.1021/Ja00128A038  0.396
1995 Lee SY, Bergman RG. Reactions of an Imidozirconocene Complex with Cyclopentadienylmetal Carbonyl Complexes: C-H Activation versus Oxygen Atom Abstraction Journal of the American Chemical Society. 117: 5877-5878. DOI: 10.1021/Ja00126A038  0.432
1995 Polse JL, Andersen RA, Bergman RG. Cycloaddition and Cycloreversion Reactions of a Monomeric Ti(IV) Oxo Complex with Terminal and Internal Alkynes. A Reversible Oxametallacyclobutene/Hydroxoacetylide Interconversion Journal of the American Chemical Society. 117: 5393-5394. DOI: 10.1021/Ja00124A036  0.524
1995 Bengali AA, Bergman RG, Moore CB. Evidence for the Formation of Free 16-Electron Species Rather than Solvate Complexes in the Ultraviolet Irradiation of CpCo(CO)2 in Liquefied Noble Gas Solvents Journal of the American Chemical Society. 117: 3879-3880. DOI: 10.1021/Ja00118A029  0.342
1995 McNeill K, Andersen RA, Bergman RG. Interconversion of a 3,3-Dimethylruthenacyclobutane and a Methyl(2-methallyl)ruthenium Complex: The First Direct Observation of Reversible .beta.-Methyl Elimination/Migratory Insertion Journal of the American Chemical Society. 117: 3625-3626. DOI: 10.1021/Ja00117A037  0.625
1995 Hanna TA, Baranger AM, Walsh PJ, Bergman RG. Formation of .alpha.,.beta.-Unsaturated Imines and Successful Trapping of Oxozirconocene in a [4 + 2] Azaoxametallacyclohexene Retrocycloaddition Journal of the American Chemical Society. 117: 3292-3293. DOI: 10.1021/Ja00116A042  0.659
1995 Meyer KE, Walsh PJ, Bergman RG. A Mechanistic Study of the Cycloaddition-Cycloreversion Reactions of Zirconium-Imido Complex Cp2Zr(N-t-Bu)(THF) with Organic Imines and Organic Azides Journal of the American Chemical Society. 117: 974-985. DOI: 10.1021/Ja00108A014  0.531
1995 Arndtsen BA, Bergman RG, Mobley TA, Peterson TH. Selective Intermolecular Carbon-Hydrogen Bond Activation by Synthetic Metal Complexes in Homogeneous Solution Accounts of Chemical Research. 28: 154-162. DOI: 10.1021/Ar00051A009  0.679
1995 Bergman RG. Synthesis and reactions of monomeric late transition metal alkoxo, aryloxo and hydroxo complexes Polyhedron. 14: 3227-3237. DOI: 10.1016/0277-5387(95)85008-2  0.401
1995 Lee SY, Bergman RG. Mechanism and regiochemistry of azametallacyclobutene formation from imidozirconocene complexes and alkynes Tetrahedron. 51: 4255-4276. DOI: 10.1016/0040-4020(94)01117-I  0.439
1995 Arndtsen BA, Bergman RG. CH bond activation in functionalized organic compounds with Cp∗ (PMe3)IrMe(OTf): generation, structural characterization and metal-based rearrangement of the acetone activation product Cp∗ (PMe3)Ir(η3-CH2C(OH)CH2)+OTf− Journal of Organometallic Chemistry. 504: 143-146. DOI: 10.1016/0022-328X(95)05614-U  0.664
1995 Christoffers J, Bergman RG. Stereoselective Synthesis of Chiral Zirconocenes from Doubly Substituted, Donor Functionalized Cyclopentadienes via Helical Chelate Complexes Angewandte Chemie International Edition in English. 34: 2266-2267. DOI: 10.1002/Anie.199522661  0.402
1994 Ma Y, Bergman R. Additions and Corrections - Synthesis and Reactions of Enantiopure (Neomenthylcyclopentadienyl)iridium(III) Halides with Silver Salts. A Dramatic Steric Effect on the Competition between Inter- and Intramolecular C-H Activation Organometallics. 13: 4648-4648. DOI: 10.1021/Om00023A600  0.447
1994 Dobbs DA, Bergman RG. Synthesis and Reactivity of Bridging Imido and Imido-Oxo Complexes of Iridium. Water-Catalyzed and -Uncatalyzed Dimerization of Terminal Iridium Imido Complexes Organometallics. 13: 4594-4605. DOI: 10.1021/Om00023A072  0.412
1994 Butts MD, Bergman RG. Synthesis, Structure, and Reactivity of the Remarkably Stable Early-Late Binuclear Metal Hydride Cp2Ta(.mu.-CH2)2Ir(Cp*)(H). A Warning Concerning Catalyst Identification in Homogeneous Catalytic Reactions Organometallics. 13: 2668-2676. DOI: 10.1021/Om00019A024  0.404
1994 Ma Y, Bergman RG. Synthesis and Reactions of Enantiopure (Neomenthylcyclopentadienyl)iridium(III) Halides with Silver Salts. A Dramatic Steric Effect on the Competition between Inter- and Intramolecular C-H Activation Organometallics. 13: 2548-2550. DOI: 10.1021/Om00019A004  0.376
1994 Butts MD, Bergman RG. Mechanistic Investigations of Cp-Loss Reactions in an Early-Late Heterobimetallic Complex. Isolation of a Cationic Tantalum-Palladium Compound with a Free Cyclopentadienyl Counteranion Organometallics. 13: 1899-1910. DOI: 10.1021/Om00017A054  0.388
1994 Michelman RI, Ball GE, Bergman RG, Andersen RA. Heteroatom Exchange Reactions in Imidoosmium(II) Systems: Cleavage of Os-N Multiple Bonds and Formation of Os-X Bonds (X = O, S, C) Organometallics. 13: 869-881. DOI: 10.1021/Om00015A021  0.544
1994 Meyer TY, Woerpel KA, Novak BM, Bergman RG. Silica as a Ligand: Reactivity of the Iridium-Oxygen Bond of Cp*Ir[silica](Ph)(PMe3) Journal of the American Chemical Society. 116: 10290-10291. DOI: 10.1021/Ja00101A055  0.703
1994 Bengali AA, Schultz RH, Moore CB, Bergman RG. Activation of the C-H Bonds in Neopentane and Neopentane-d12 by (.eta.5-C5(CH3)5)Rh(CO)2: Spectroscopic and Temporal Resolution of Rhodium-Krypton and Rhodium-Alkane Complex Intermediates Journal of the American Chemical Society. 116: 9585-9589. DOI: 10.1021/Ja00100A024  0.402
1994 Schultz RH, Bengali AA, Tauber MJ, Weiller BH, Wasserman EP, Kyle KR, Moore CB, Bergman RG. IR Flash Kinetic Spectroscopy of C-H Bond Activation of Cyclohexane-d0 and -d12 by Cp*Rh(CO)2 in Liquid Rare Gases: Kinetics, Thermodynamics, and Unusual Isotope Effect Journal of the American Chemical Society. 116: 7369-7377. DOI: 10.1021/Ja00095A047  0.72
1994 Baranger AM, Bergman RG. Cooperative Reactivity in the Interactions of X-H Bonds with a Zirconium-Iridium Bridging Imido Complex Journal of the American Chemical Society. 116: 3822-3835. DOI: 10.1021/Ja00088A019  0.689
1994 Meyer KE, Walsh PJ, Bergman RG. Zirconium-Mediated Imine Metathesis. Synthesis of 2,4-Diaza-1-zirconiacyclobutanes and the Mechanism of Their Reactions with Imines and Alkynes Journal of the American Chemical Society. 116: 2669-2670. DOI: 10.1021/Ja00085A077  0.551
1994 Dobbs DA, Bergman RG. Late Transition-Metal Sulfido Complexes: Reactivity Studies and Mechanistic Analysis of Their Conversion into Metal-Sulfur Cubane Complexes Inorganic Chemistry. 33: 5329-5336. DOI: 10.1021/Ic00101A027  0.346
1994 Burn MJ, Bergman RG. A study of the silanolysis of triphenylsilane and p-methoxyphenol catalysed by (PMe3)4RuH2 and the stoichiometric reactions of (PMe3)4Ru(H)(OC6H4-p-X) (X = Me, OMe) with Ph3SiH Journal of Organometallic Chemistry. 472: 43-54. DOI: 10.1016/0022-328X(94)80192-4  0.39
1993 Proulx G, Bergman RG. Reaction of a Tantalum Alkylidene Complex with Dinuclear Metal Carbonyls: Formation of C3 ligands Science. 259: 661-663. DOI: 10.1126/Science.259.5095.661  0.45
1993 Butts MD, Bergman RG. Reactivity of an early-late heterobimetallic complex toward phosphines: synthesis, structure, and reactivity of a cationic tantalum-palladium compound with a free cyclopentadienyl counteranion Organometallics. 12: 4269-4271. DOI: 10.1021/Om00035A005  0.388
1993 Walsh PJ, Hollander FJ, Bergman RG. Monomeric and dimeric zirconocene imido compounds: synthesis, structure, and reactivity Organometallics. 12: 3705-3723. DOI: 10.1021/Om00033A049  0.477
1993 Michelman RI, Bergman RG, Andersen RA. Synthesis, exchange reactions, and metallacycle formation in osmium(II) imido systems: formation and cleavage of osmium-nitrogen bonds Organometallics. 12: 2741-2751. DOI: 10.1021/Om00031A049  0.57
1993 Simpson RD, Bergman RG. Synthesis, structure, and exchange reactions of rhenium alkoxide and aryloxide complexes. Evidence for both proton and hydrogen atom transfer in the exchange transition state Organometallics. 12: 781-796. DOI: 10.1021/Om00027A031  0.389
1993 Hostetler MJ, Butts MD, Bergman RG. Rate and equilibrium study of the reversible oxidative addition of silanes to the iridium center in Cp2Ta(.mu.-CH2)2Ir(CO)2 and of alkene hydrosilylation/isomerization catalyzed by this system Organometallics. 12: 65-75. DOI: 10.1021/Om00025A015  0.786
1993 Burger P, Bergman RG. Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf) Journal of the American Chemical Society. 115: 10462-10463. DOI: 10.1021/Ja00075A113  0.428
1993 Proulx G, Bergman RG. Reaction of Cp2Ta(CH2)CH3 with methyl- and phenylrhenium pentacarbonyl: "Wittig-like" metathesis of bound carbon monoxide to a C:CH2 (vinylidene) group, and NMR evidence for the intervention of a zwitterionic intermediate Journal of the American Chemical Society. 115: 9802-9803. DOI: 10.1021/Ja00074A058  0.308
1993 Weydert M, Andersen RA, Bergman RG. Reactions of uranium complex (MeC5H4)3U(t-Bu): intermolecular fluorine atom abstraction from fluorocarbons including saturated perfluorocarbons Journal of the American Chemical Society. 115: 8837-8838. DOI: 10.1021/Ja00072A046  0.547
1993 Baranger AM, Hollander FJ, Bergman RG. Synthesis of an early-late heterobimetallic imido complex: cooperative reactivity with nitrogen-, oxygen-, and sulfur-hydrogen bonds and formation of a novel aminophosphine complex Journal of the American Chemical Society. 115: 7890-7891. DOI: 10.1021/Ja00070A050  0.698
1993 Woerpel KA, Bergman RG. Synthesis and reactivity of an iridium hydroxo complex. Insertion of ethylene into a metal-oxygen bond Journal of the American Chemical Society. 115: 7888-7889. DOI: 10.1021/Ja00070A049  0.637
1993 Burn MJ, Fickes MG, Hartwig JF, Hollander FJ, Bergman RG. Synthesis of monomeric ruthenium hydroxo complexes (PMe3)4Ru(R)(OH) (R = H, Me) and a unique dimeric ruthenium hydroxo-water complex [trans-Ru(H)(OH)(DMPE)2.cntdot.H2O]2 Journal of the American Chemical Society. 115: 5875-5876. DOI: 10.1021/Ja00066A086  0.541
1993 Weiller BH, Wasserman EP, Moore CB, Bergman RG. Organometallic carbonyl substitution kinetics in liquid xenon by fast time-resolved IR spectroscopy Journal of the American Chemical Society. 115: 4326-4330. DOI: 10.1021/Ja00063A058  0.654
1993 Dobbs DA, Bergman RG. Synthesis of bridging iridium bis(imido) and imido-oxo complexes. Imide and oxygen transfer reactions and hydrogenation of an imido ligand Journal of the American Chemical Society. 115: 3836-3837. DOI: 10.1021/Ja00062A084  0.441
1993 Baranger AM, Walsh PJ, Bergman RG. Variable regiochemistry in the stoichiometric and catalytic hydroamination of alkynes by imidozirconium complexes caused by an unusual dependence of the rate law on alkyne structure and temperature Journal of the American Chemical Society. 115: 2753-2763. DOI: 10.1021/Ja00060A025  0.751
1993 Hostetler MJ, Butts MD, Bergman RG. Scope and mechanism of alkene hydrogenation/isomerization catalyzed by complexes of the type R2E(CH2)2M(CO)(L) (R = Cp, Me, Ph; E = phosphorus, tantalum; M = rhodium, iridium; L = CO, PPh3) Journal of the American Chemical Society. 115: 2743-2752. DOI: 10.1021/Ja00060A024  0.801
1992 Wasserman EP, Moore CB, Bergman RG. Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex. Science (New York, N.Y.). 255: 315-8. PMID 17779581 DOI: 10.1126/science.255.5042.315  0.311
1992 Foo T, Bergman RG. Migratory insertion reactions of indenyliridium dialkyls and alkyl and aryl hydrides Organometallics. 11: 1811-1819. DOI: 10.1021/Om00041A014  0.359
1992 Foo T, Bergman RG. Synthesis and carbon-hydrogen activation reactions of .eta.5-indenyl(trimethylphosphine)iridium alkyl and hydride complexes Organometallics. 11: 1801-1810. DOI: 10.1021/Om00041A013  0.343
1992 Carney MJ, Walsh PJ, Hollander FJ, Bergman RG. Generation of the highly reactive intermediates Cp*2Zr:O and Cp*2Zr:S: trapping reactions with alkynes, nitriles, and dative ligands Organometallics. 11: 761-777. DOI: 10.1021/Om00038A040  0.537
1992 Hostetler MJ, Bergman RG. Secondary .beta.-deuterium isotope effects on the rates and equilibria of organometallic oxidative addition/reductive elimination reactions Journal of the American Chemical Society. 114: 7629-7636. DOI: 10.1021/Ja00046A004  0.794
1992 Dobbs DA, Bergman RG. A rational synthesis of organometallic bridging sulfur dimers and their conversion into homo- and heterometallic cubane complexes. Evidence for a mechanism involving dimerization of doubly unsaturated dinuclear intermediates Journal of the American Chemical Society. 114: 6908-6909. DOI: 10.1021/Ja00043A042  0.431
1992 Hartwig JF, Bergman RG, Andersen RA. Insertion reactions of carbon monoxide and carbon dioxide with ruthenium benzyl, arylamido, and aryloxide complexes: a comparison of the reactivity of ruthenium-carbon, ruthenium-nitrogen, and ruthenium-oxygen bonds. [Erratum to document cited in CA115(11):114728s] Journal of the American Chemical Society. 114: 5907-5907. DOI: 10.1021/Ja00040A090  0.618
1992 Walsh PJ, Baranger AM, Bergman RG. Stoichiometric and catalytic hydroamination of alkynes and allene by zirconium bisamides Cp2Zr(NHR)2 Journal of the American Chemical Society. 114: 1708-1719. DOI: 10.1021/Ja00031A026  0.736
1992 Hostetler MJ, Bergman RG. Observation of .beta.-kinetic and -equilibrium isotope effects in organometallic oxidative addition reactions Journal of the American Chemical Society. 114: 787-788. DOI: 10.1021/Ja00028A071  0.793
1992 Hostetler MJ, Butts MD, Bergman RG. Synthesis and comparative chemistry of the early-late transition metal heterobimetallacycles CpCp′Ta(CH2)2Ir(CO)(L) and their main-group element-late transition metal analogues R2P(CH2)2Ir(CO)(L) Inorganica Chimica Acta. 198: 377-392. DOI: 10.1016/S0020-1693(00)92380-6  0.801
1992 Walsh PJ, Hollander FJ, Bergman RG. Insertion of alkynes into zirconium-nitrogen bonds leading to 2,3-diazametallacyclopentenes. Generation and reactivity of Cp2Zr(N2Ph2) Journal of Organometallic Chemistry. 428: 13-47. DOI: 10.1016/0022-328X(92)83217-6  0.593
1992 Simpson RD, Bergman RG. A Dramatic Difference in the Reactivities of Alkoxido- and Aryloxidorhenium Complexes in Insertion Reactions Angewandte Chemie International Edition in English. 31: 220-223. DOI: 10.1002/Anie.199202201  0.419
1991 Hartwig JF, Bergman RG, Andersen RA. Structure and reactions of oxametallacyclobutanes and oxametallacyclobutenes of ruthenium Organometallics. 10: 3344-3362. DOI: 10.1021/Om00055A061  0.619
1991 Hartwig JF, Bergman RG, Andersen RA. Oxygen- and carbon-bound ruthenium enolates: migratory insertion, reductive elimination, .beta.-hydrogen elimination, and cyclometalation reactions Organometallics. 10: 3326-3344. DOI: 10.1021/Om00055A060  0.614
1991 Hartwig JF, Andersen RA, Bergman RG. Synthesis and chemistry of ruthenium hydrido aryloxides and arylamides. An investigation of structure, nitrogen-hydrogen and oxygen-hydrogen elimination processes, proton-catalyzed exchange reactions, and relative Ru-X bond strengths Organometallics. 10: 1875-1887. DOI: 10.1021/Om00052A037  0.708
1991 Hartwig JF, Andersen RA, Bergman RG. Alkyl, aryl, hydrido, and acetate complexes of (DMPM)2Ru [DMPM = bis(dimethylphosphino)methane]: reductive elimination and oxidative addition of carbon-hydrogen bonds Organometallics. 10: 1710-1719. DOI: 10.1021/Om00052A016  0.694
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