Robert G. Bergman - Publications

Affiliations: 
University of California, Berkeley, Berkeley, CA 
Area:
mechanisms of organic reactions
Website:
http://www.cchem.berkeley.edu/rgbgrp/rgbbio.html

326 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Ouellette ET, Carpentier A, Joseph Brackbill I, Lohrey TD, Douair I, Maron L, Bergman RG, Arnold J. σ or π? Bonding interactions in a series of rhenium metallotetrylenes. Dalton Transactions (Cambridge, England : 2003). PMID 33481968 DOI: 10.1039/d1dt00129a  1
2021 Morimoto M, Cao W, Bergman RG, Raymond KN, Toste FD. Chemoselective and Site-Selective Reductions Catalyzed by a Supramolecular Host and a Pyridine-Borane Cofactor. Journal of the American Chemical Society. PMID 33471541 DOI: 10.1021/jacs.0c12479  1
2020 Sebastiani F, Bender TA, Pezzotti S, Li WL, Schwaab G, Bergman RG, Raymond KN, Toste FD, Head-Gordon T, Havenith M. An isolated water droplet in the aqueous solution of a supramolecular tetrahedral cage. Proceedings of the National Academy of Sciences of the United States of America. PMID 33318176 DOI: 10.1073/pnas.2012545117  1
2020 Miyamura H, Bergman RG, Raymond KN, Toste FD. Heterogeneous Supramolecular Catalysis through Immobilization of Anionic ML Assemblies on Cationic Polymers. Journal of the American Chemical Society. 142: 19327-19338. PMID 33136406 DOI: 10.1021/jacs.0c09556  1
2020 Lohrey TD, Rao G, Small DW, Ouellette ET, Bergman RG, Britt RD, Arnold J. Electronic Structures of Rhenium(II) β-Diketiminates Probed by EPR Spectroscopy: Direct Comparison of an Acceptor-Free Complex to Its Dinitrogen, Isocyanide, and Carbon Monoxide Adducts. Journal of the American Chemical Society. 142: 13805-13813. PMID 32786815 DOI: 10.1021/jacs.0c04719  1
2020 Lohrey TD, Cortes EA, Fostvedt JI, Oanta AK, Jain A, Bergman RG, Arnold J. Diverse Reactivity of a Rhenium(V) Oxo Imido Complex: [2 + 2] Cycloadditions, Chalcogen Metathesis, Oxygen Atom Transfer, and Protic and Hydridic 1,2-Additions. Inorganic Chemistry. PMID 32662634 DOI: 10.1021/acs.inorgchem.0c01589  1
2020 Lohrey TD, Cortes EA, Bergman RG, Arnold J. Facile Activation of Triarylboranes by Rhenium(V) Oxo Imido Complexes. Inorganic Chemistry. PMID 32339452 DOI: 10.1021/acs.inorgchem.0c00658  1
2020 Lohrey TD, Fostvedt JI, Bergman RG, Arnold J. Electron acceptors promote proton-hydride tautomerism in low valent rhenium β-diketiminates. Chemical Communications (Cambridge, England). PMID 32125313 DOI: 10.1039/c9cc09475j  1
2020 Bierschenk SM, Bergman RG, Raymond KN, Toste FD. A Nanovessel-Catalyzed Three-Component Aza-Darzens Reaction. Journal of the American Chemical Society. PMID 31909615 DOI: 10.1021/jacs.9b13177  1
2019 Lohrey TD, Bergman RG, Arnold J. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. Dalton Transactions (Cambridge, England : 2003). 48: 17936-17944. PMID 31793591 DOI: 10.1039/c9dt04489b  1
2019 Fostvedt JI, Lohrey TD, Bergman RG, Arnold J. Structural diversity in multinuclear tantalum polyhydrides formed via reductive hydrogenolysis of metal-carbon bonds. Chemical Communications (Cambridge, England). 55: 13263-13266. PMID 31621710 DOI: 10.1039/c9cc07686g  1
2019 Lohrey TD, Rao G, Britt RD, Bergman RG, Arnold J. H Activation and Direct Access to Terminal Nitride and -P Complexes by an Acceptor-Free Rhenium(II) β-Diketiminate. Inorganic Chemistry. PMID 31550147 DOI: 10.1021/acs.inorgchem.9b02556  1
2019 Bender TA, Bergman RG, Raymond KN, Toste FD. A Supramolecular Strategy for Selective Catalytic Hydrogenation Independent of Remote Chain Length. Journal of the American Chemical Society. PMID 31310528 DOI: 10.1021/jacs.9b05604  1
2019 Bender TA, Morimoto M, Bergman RG, Raymond KN, Toste FD. Supramolecular Host-Selective Activation of Iodoarenes by Encapsulated Organometallics. Journal of the American Chemical Society. PMID 30667233 DOI: 10.1021/jacs.8b11842  1
2018 Lohrey TD, Maron L, Bergman RG, Arnold J. A Heterotetrametallic Re-Zn-Zn-Re Complex Generated by an Anionic Rhenium(I) β-Diketiminate. Journal of the American Chemical Society. PMID 30571106 DOI: 10.1021/jacs.8b12494  1
2018 Hong CM, Bergman RG, Raymond KN, Toste FD. Self-Assembled Tetrahedral Hosts as Supramolecular Catalysts. Accounts of Chemical Research. PMID 30272943 DOI: 10.1021/acs.accounts.8b00328  1
2018 Hong CM, Morimoto M, Kapustin EA, Alzakhem N, Bergman RG, Raymond KN, Toste FD. Deconvoluting the Role of Charge in a Supramolecular Catalyst. Journal of the American Chemical Society. PMID 29767972 DOI: 10.1021/jacs.8b01701  1
2018 Ziegler JA, Prange C, Lohrey TD, Bergman RG, Arnold J. Hydroboration Reactivity of Niobium Bis(N-heterocyclic carbene)borate Complexes. Inorganic Chemistry. PMID 29624377 DOI: 10.1021/acs.inorgchem.8b00247  1
2017 Schepartz A, Bergman R, Grubbs RH. Ronald Breslow (1931-2017). Angewandte Chemie (International Ed. in English). PMID 29235715 DOI: 10.1002/anie.201711641  0.48
2017 Lohrey T, Bergman R, Arnold J. Olefin-Supported Rhenium(III) Terminal Oxo Complexes Generated by Nucleophilic Addition to a Cyclopentadienyl Ligand. Angewandte Chemie (International Ed. in English). PMID 28929597 DOI: 10.1002/anie.201707957  1
2017 Garner ME, Parker BF, Hohloch S, Bergman RG, Arnold J. Thorium Metallacycle Facilitates Catalytic Alkyne Hydrophosphination. Journal of the American Chemical Society. PMID 28892619 DOI: 10.1021/jacs.7b08323  1
2017 Hong CM, Kaphan DM, Bergman RG, Raymond KN, Toste FD. Conformational Selection as the Mechanism of Guest Binding in a Flexible Supramolecular Host. Journal of the American Chemical Society. PMID 28581740 DOI: 10.1021/jacs.7b03812  1
2017 Kriegel BM, Naested LC, Nocton G, Lakshmi KV, Lohrey TD, Bergman RG, Arnold J. Redox-Initiated Reactivity of Dinuclear β-Diketiminatoniobium Imido Complexes. Inorganic Chemistry. PMID 28098983 DOI: 10.1021/acs.inorgchem.6b02735  1
2016 Lohrey TD, Bergman RG, Arnold J. Oxygen Atom Transfer and Intramolecular Nitrene Transfer in a Rhenium β-Diketiminate Complex. Inorganic Chemistry. 55: 11993-12000. PMID 27934320 DOI: 10.1021/acs.inorgchem.6b02122  1
2016 Chen S, Bacauanu V, Knecht T, Mercado BQ, Bergman RG, Ellman JA. New Regio- and Stereoselective Cascades via Unstabilized Azomethine Ylide Cycloadditions for the Synthesis of Highly Substituted Tropane and Indolizidine Frameworks. Journal of the American Chemical Society. 138: 12664-70. PMID 27642766 DOI: 10.1021/jacs.6b08355  1
2016 Ziegler JA, Bergman RG, Arnold J. Unusual κ1 coordination of a β-diketiminate ligand in niobium complexes. Dalton Transactions (Cambridge, England : 2003). PMID 27461382 DOI: 10.1039/c6dt02373h  1
2016 Levin MD, Kaphan DM, Hong CM, Bergman RG, Raymond KN, Toste FD. Scope and Mechanism of Cooperativity at the Intersection of Organometallic and Supramolecular Catalysis. Journal of the American Chemical Society. PMID 27458778 DOI: 10.1021/jacs.6b05442  1
2016 Hohloch S, Kriegel BM, Bergman RG, Arnold J. Group 5 chemistry supported by β-diketiminate ligands. Dalton Transactions (Cambridge, England : 2003). PMID 27327510 DOI: 10.1039/c6dt01770c  1
2016 Liberman-Martin AL, Levine DS, Ziegler MS, Bergman RG, Tilley TD. Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. Chemical Communications (Cambridge, England). PMID 27161155 DOI: 10.1039/c6cc02433e  1
2016 Camp C, Grant LN, Bergman RG, Arnold J. Photo-activation of d(0) niobium imido azides: en route to nitrido complexes. Chemical Communications (Cambridge, England). PMID 27033145 DOI: 10.1039/c6cc02081j  1
2016 Wangweerawong A, Hummel JR, Bergman RG, Ellman JA. Preparation of Enantiomerically Pure Perfluorobutanesulfinamide and Its Application to the Asymmetric Synthesis of α-Amino Acids. The Journal of Organic Chemistry. PMID 26844947 DOI: 10.1021/acs.joc.5b02700  1
2016 Brown CJ, Kokai A, Miller GM, Bergman RG, Raymond KN. Improved scope and diastereoselectivity of C-H activation in an expanded supramolecular host Supramolecular Chemistry. 28: 188-191. DOI: 10.1080/10610278.2015.1122196  1
2016 Liberman-Martin AL, Ziegler MS, DiPasquale AG, Bergman RG, Tilley TD. Functionalization of an iridium-diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources Polyhedron. DOI: 10.1016/j.poly.2016.03.044  1
2015 Hart-Cooper WM, Zhao C, Triano RM, Yaghoubi P, Ozores HL, Burford KN, Toste FD, Bergman RG, Raymond KN. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations. Chemical Science. 6: 1383-1393. PMID 29560226 DOI: 10.1039/c4sc02735c  1
2015 Gianetti TL, Nocton G, Minasian SG, Kaltsoyannis N, Kilcoyne ALD, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Electron localization in a mixed-valence diniobium benzene complex. Chemical Science. 6: 993-1003. PMID 29560186 DOI: 10.1039/c4sc02705a  1
2015 Kaphan DM, Levin MD, Bergman RG, Raymond KN, Toste FD. A supramolecular microenvironment strategy for transition metal catalysis. Science (New York, N.Y.). 350: 1235-8. PMID 26785485 DOI: 10.1126/science.aad3087  1
2015 Kriegel BM, Bergman RG, Arnold J. Nitrene Metathesis and Catalytic Nitrene Transfer Promoted by Niobium Bis(imido) Complexes. Journal of the American Chemical Society. PMID 26698833 DOI: 10.1021/jacs.5b11287  1
2015 Hart-Cooper WM, Sgarlata C, Perrin CL, Toste FD, Bergman RG, Raymond KN. Protein-like proton exchange in a synthetic host cavity. Proceedings of the National Academy of Sciences of the United States of America. PMID 26621709 DOI: 10.1073/pnas.1515639112  1
2015 Matsushima Y, Phillips EM, Bergman RG, Ellman JA. Rh(I)-Catalyzed Cycloisomerization of 1,6-Enynes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 26: 1533-1536. PMID 26609195 DOI: 10.1055/s-0034-1380359  1
2015 Dalton DM, Ellis SR, Nichols EM, Mathies RA, Toste FD, Bergman RG, Raymond KN. Supramolecular Ga4L6(12-) Cage Photosensitizes 1,3-Rearrangement of Encapsulated Guest via Photoinduced Electron Transfer. Journal of the American Chemical Society. 137: 10128-31. PMID 26256754 DOI: 10.1021/jacs.5b06317  1
2015 Nechayev M, Gianetti TL, Bergman RG, Arnold J. C-F sp(2) bond functionalization mediated by niobium complexes. Dalton Transactions (Cambridge, England : 2003). 44: 19494-19500. PMID 26216334 DOI: 10.1039/c5dt02082d  1
2015 Kaphan DM, Toste FD, Bergman RG, Raymond KN. Enabling New Modes of Reactivity via Constrictive Binding in a Supramolecular-Assembly-Catalyzed Aza-Prins Cyclization. Journal of the American Chemical Society. 137: 9202-5. PMID 26176416 DOI: 10.1021/jacs.5b01261  1
2015 Chen S, Mercado BQ, Bergman RG, Ellman JA. Regio- and Diastereoselective Synthesis of Highly Substituted, Oxygenated Piperidines from Tetrahydropyridines. The Journal of Organic Chemistry. 80: 6660-8. PMID 26098485 DOI: 10.1021/acs.joc.5b00816  1
2015 Chen S, Bergman RG, Ellman JA. Facile Rh(III)-Catalyzed Synthesis of Fluorinated Pyridines. Organic Letters. 17: 2567-9. PMID 25992591 DOI: 10.1021/acs.orglett.5b00979  1
2015 Brown CJ, Toste FD, Bergman RG, Raymond KN. Supramolecular catalysis in metal-ligand cluster hosts. Chemical Reviews. 115: 3012-35. PMID 25898212 DOI: 10.1021/cr4001226  1
2015 Liberman-Martin AL, Bergman RG, Tilley TD. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Journal of the American Chemical Society. 137: 5328-31. PMID 25879515 DOI: 10.1021/jacs.5b02807  1
2015 Obenhuber AH, Gianetti TL, Bergman RG, Arnold J. Regioselective [2+2] and [4+2] cycloaddition reactivity in an asymmetric niobium(bisimido) moiety towards unsaturated organic molecules. Chemical Communications (Cambridge, England). 51: 1278-81. PMID 25475703 DOI: 10.1039/c4cc07851a  1
2015 Kaphan DM, Levin MD, Bergman RG, Raymond KN, Toste FD. A supramolecular microenvironment strategy for transition metal catalysis Science. 350: 1235-1238. DOI: 10.1126/science.aad3087  1
2015 Matsushima Y, Phillips EM, Bergman RG, Ellman JA. Rhodium(I)-Catalyzed Cycloisomerization of 1,6-Enynes Synlett. 26: 1533-1536. DOI: 10.1055/s-0034-1380359  1
2015 Hart-Cooper WM, Zhao C, Triano RM, Yaghoubi P, Ozores HL, Burford KN, Toste FD, Bergman RG, Raymond KN. The effect of host structure on the selectivity and mechanism of supramolecular catalysis of Prins cyclizations Chemical Science. 6: 1383-1393. DOI: 10.1039/c4sc02735c  1
2015 Gianetti TL, Nocton G, Minasian SG, Kaltsoyannis N, Kilcoyne ALD, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Electron localization in a mixed-valence diniobium benzene complex Chemical Science. 6: 993-1003. DOI: 10.1039/c4sc02705a  1
2015 Zhang Y, Roberts SP, Bergman RG, Ess DH. Mechanism and catalytic impact of Ir-Ta heterobimetallic and Ir-P transition metal/main group interactions on alkene hydrogenation Acs Catalysis. 5: 1840-1849. DOI: 10.1021/cs501884j  1
2014 Camp C, Maron L, Bergman RG, Arnold J. Activation of white phosphorus by low-valent group 5 complexes: formation and reactivity of cyclo-P4 inverted sandwich compounds. Journal of the American Chemical Society. 136: 17652-61. PMID 25469924 DOI: 10.1021/ja5107282  1
2014 Zhao C, Toste FD, Raymond KN, Bergman RG. Nucleophilic substitution catalyzed by a supramolecular cavity proceeds with retention of absolute stereochemistry. Journal of the American Chemical Society. 136: 14409-12. PMID 25265509 DOI: 10.1021/ja508799p  1
2014 Johnson MW, DiPasquale AG, Bergman RG, Toste FD. Synthesis of Stable Gold(III) Pincer Complexes with Anionic Heteroatom Donors. Organometallics. 33: 4169-4172. PMID 25180022 DOI: 10.1021/om500663m  1
2014 Wangweerawong A, Bergman RG, Ellman JA. Asymmetric synthesis of α-branched amines via Rh(III)-catalyzed C-H bond functionalization. Journal of the American Chemical Society. 136: 8520-3. PMID 24901217 DOI: 10.1021/ja5033452  1
2014 Kriegel BM, Bergman RG, Arnold J. Generation of low-valent tantalum species by reversible C-H activation in a cyclometallated tantalum hydride complex. Dalton Transactions (Cambridge, England : 2003). 43: 10046-56. PMID 24870398 DOI: 10.1039/c4dt00923a  1
2014 Johnson MW, Bagley SW, Mankad NP, Bergman RG, Mascitti V, Toste FD. Application of fundamental organometallic chemistry to the development of a gold-catalyzed synthesis of sulfinate derivatives. Angewandte Chemie (International Ed. in English). 53: 4404-7. PMID 24652820 DOI: 10.1002/anie.201400037  1
2014 Hastings CJ, Bergman RG, Raymond KN. Origins of large rate enhancements in the Nazarov cyclization catalyzed by supramolecular encapsulation. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 3966-73. PMID 24615703 DOI: 10.1002/chem.201303885  1
2014 Duttwyler S, Chen S, Lu C, Mercado BQ, Bergman RG, Ellman JA. Regio- and stereoselective 1,2-dihydropyridine alkylation/addition sequence for the synthesis of piperidines with quaternary centers. Angewandte Chemie (International Ed. in English). 53: 3877-80. PMID 24604837 DOI: 10.1002/anie.201310517  1
2014 Obenhuber AH, Gianetti TL, Berrebi X, Bergman RG, Arnold J. Reaction of (bisimido)niobium(V) complexes with organic azides: [3 + 2] cycloaddition and reversible cleavage of β-diketiminato ligands involving nitrene transfer. Journal of the American Chemical Society. 136: 2994-7. PMID 24524190 DOI: 10.1021/ja413194z  1
2014 Zhao C, Crimmin MR, Toste FD, Bergman RG. Ligand-based carbon-nitrogen bond forming reactions of metal dinitrosyl complexes with alkenes and their application to C-H bond functionalization. Accounts of Chemical Research. 47: 517-29. PMID 24359109 DOI: 10.1021/ar400176x  1
2014 Gianetti TL, Bergman RG, Arnold J. Carbon-fluorine bond cleavage in fluoroarenes via a niobium(iii) imido complex: From stoichiometric to catalytic hydrodefluorination Chemical Science. 5: 2517-2524. DOI: 10.1039/c4sc00006d  1
2014 Gianetti TL, Bergman RG, Arnold J. Stoichiometric carbon-carbon bond formation mediated by well defined Nb(III) complexes Dedicated to Professor John E. Bercaw, for his deep and wide-ranging contributions to organometallic chemistry and catalysis. Polyhedron. 84: 19-23. DOI: 10.1016/j.poly.2014.05.031  1
2014 Nechayev M, Kriegel BM, Gianetti TL, Bergman RG, Arnold J. Synthesis and characterization of group 5 imido complexes supported by the 2,6-dichloroaryl β-diketiminato ligand Inorganica Chimica Acta. 422: 114-119. DOI: 10.1016/j.ica.2014.07.006  1
2013 Zhao C, Sun QF, Hart-Cooper WM, DiPasquale AG, Toste FD, Bergman RG, Raymond KN. Chiral amide directed assembly of a diastereo- and enantiopure supramolecular host and its application to enantioselective catalysis of neutral substrates. Journal of the American Chemical Society. 135: 18802-5. PMID 24283463 DOI: 10.1021/ja411631v  1
2013 La Pierre HS, Minasian SG, Abubekerov M, Kozimor SA, Shuh DK, Tyliszczak T, Arnold J, Bergman RG, Toste FD. Vanadium bisimide bonding investigated by X-ray crystallography, 51V and 13C nuclear magnetic resonance spectroscopy, and V L(3,2)-edge X-ray absorption near-edge structure spectroscopy. Inorganic Chemistry. 52: 11650-60. PMID 24024833 DOI: 10.1021/ic4020543  1
2013 Bowring MA, Bergman RG, Tilley TD. Pt-catalyzed C-C activation induced by C-H activation. Journal of the American Chemical Society. 135: 13121-8. PMID 23962182 DOI: 10.1021/ja406260j  1
2013 Lian Y, Hummel JR, Bergman RG, Ellman JA. Facile synthesis of unsymmetrical acridines and phenazines by a Rh(III)-catalyzed amination/cyclization/aromatization cascade. Journal of the American Chemical Society. 135: 12548-51. PMID 23957711 DOI: 10.1021/ja406131a  1
2013 Liberman-Martin AL, Bergman RG, Tilley TD. A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. Journal of the American Chemical Society. 135: 9612-5. PMID 23789917 DOI: 10.1021/ja404339u  1
2013 Gianetti TL, Bergman RG, Arnold J. Dis-assembly of a benzylic CF3 group mediated by a niobium(III) imido complex. Journal of the American Chemical Society. 135: 8145-8. PMID 23663120 DOI: 10.1021/ja4033007  1
2013 Lian Y, Bergman RG, Lavis LD, Ellman JA. Rhodium(III)-catalyzed indazole synthesis by C-H bond functionalization and cyclative capture. Journal of the American Chemical Society. 135: 7122-5. PMID 23642256 DOI: 10.1021/ja402761p  1
2013 Brasse M, Cámpora J, Ellman JA, Bergman RG. Mechanistic study of the oxidative coupling of styrene with 2-phenylpyridine derivatives catalyzed by cationic rhodium(III) via C-H activation. Journal of the American Chemical Society. 135: 6427-30. PMID 23590843 DOI: 10.1021/ja401561q  1
2013 Ischay MA, Takase MK, Bergman RG, Ellman JA. Unstabilized azomethine ylides for the stereoselective synthesis of substituted piperidines, tropanes, and azabicyclo[3.1.0] systems. Journal of the American Chemical Society. 135: 2478-81. PMID 23398467 DOI: 10.1021/ja312311k  1
2013 Duttwyler S, Chen S, Takase MK, Wiberg KB, Bergman RG, Ellman JA. Proton donor acidity controls selectivity in nonaromatic nitrogen heterocycle synthesis. Science (New York, N.Y.). 339: 678-82. PMID 23393259 DOI: 10.1126/science.1230704  1
2013 Mugridge JS, Zahl A, van Eldik R, Bergman RG, Raymond KN. Solvent and pressure effects on the motions of encapsulated guests: tuning the flexibility of a supramolecular host. Journal of the American Chemical Society. 135: 4299-306. PMID 23391095 DOI: 10.1021/ja309949q  1
2013 Wang ZJ, Clary KN, Bergman RG, Raymond KN, Toste FD. A supramolecular approach to combining enzymatic and transition metal catalysis. Nature Chemistry. 5: 100-3. PMID 23344446 DOI: 10.1038/nchem.1531  1
2013 Gianetti TL, Nocton G, Minasian SG, Tomson NC, Kilcoyne AL, Kozimor SA, Shuh DK, Tyliszczak T, Bergman RG, Arnold J. Diniobium inverted sandwich complexes with μ-η6:η6-arene ligands: synthesis, kinetics of formation, and electronic structure. Journal of the American Chemical Society. 135: 3224-36. PMID 23343247 DOI: 10.1021/ja311966h  1
2013 Martin RM, Bergman RG, Ellman JA. Synthesis of isoquinuclidines from highly substituted dihydropyridines via the Diels-Alder reaction. Organic Letters. 15: 444-7. PMID 23320852 DOI: 10.1021/ol303040r  1
2013 Lian Y, Huber T, Hesp KD, Bergman RG, Ellman JA. Rhodium(III)-catalyzed alkenyl C-H bond functionalization: convergent synthesis of furans and pyrroles. Angewandte Chemie (International Ed. in English). 52: 629-33. PMID 23172703 DOI: 10.1002/anie.201207995  1
2013 Johnson MW, Shevick SL, Toste FD, Bergman RG. Preparation and reactivity of terminal gold(i) amides and phosphides Chemical Science. 4: 1023-1027. DOI: 10.1039/c2sc21519e  1
2013 Bowring MA, Bergman RG, Tilley TD. Isolation of a dicationic platinum complex with two accessible coordination sites Organometallics. 32: 5266-5268. DOI: 10.1021/om4008357  1
2012 La Pierre HS, Arnold J, Bergman RG, Toste FD. Carbon monoxide, isocyanide, and nitrile complexes of cationic, d(0) vanadium bisimides: π-back bonding derived from the π symmetry, bonding metal bisimido ligand orbitals. Inorganic Chemistry. 51: 13334-44. PMID 23181489 DOI: 10.1021/ic302044q  1
2012 Hart-Cooper WM, Clary KN, Toste FD, Bergman RG, Raymond KN. Selective monoterpene-like cyclization reactions achieved by water exclusion from reactive intermediates in a supramolecular catalyst. Journal of the American Chemical Society. 134: 17873-6. PMID 23066637 DOI: 10.1021/ja308254k  1
2012 Cobar EA, Horn PR, Bergman RG, Head-Gordon M. Examination of the hydrogen-bonding networks in small water clusters (n = 2-5, 13, 17) using absolutely localized molecular orbital energy decomposition analysis. Physical Chemistry Chemical Physics : Pccp. 14: 15328-39. PMID 23052011 DOI: 10.1039/c2cp42522j  1
2012 Lian Y, Bergman RG, Ellman JA. Rhodium(iii)-catalyzed synthesis of phthalides by cascade addition and cyclization of benzimidates with aldehydes. Chemical Science (Royal Society of Chemistry : 2010). 3: 3088-3092. PMID 23050074 DOI: 10.1039/C2SC20835K  1
2012 Hesp KD, Bergman RG, Ellman JA. Rhodium-catalyzed synthesis of branched amines by direct addition of benzamides to imines. Organic Letters. 14: 2304-7. PMID 22500854 DOI: 10.1021/ol300723x  1
2012 Duttwyler S, Lu C, Rheingold AL, Bergman RG, Ellman JA. Highly diastereoselective synthesis of tetrahydropyridines by a C-H activation-cyclization-reduction cascade. Journal of the American Chemical Society. 134: 4064-7. PMID 22356093 DOI: 10.1021/ja2119833  1
2012 Martin RM, Bergman RG, Ellman JA. Synthesis of pyridines from ketoximes and terminal alkynes via C-H bond functionalization. The Journal of Organic Chemistry. 77: 2501-7. PMID 22332639 DOI: 10.1021/jo202280e  1
2012 Tauchert ME, Incarvito CD, Rheingold AL, Bergman RG, Ellman JA. Mechanism of the rhodium(III)-catalyzed arylation of imines via C-H bond functionalization: inhibition by substrate. Journal of the American Chemical Society. 134: 1482-5. PMID 22257031 DOI: 10.1021/ja211110h  1
2012 Colby DA, Tsai AS, Bergman RG, Ellman JA. Rhodium catalyzed chelation-assisted C-H bond functionalization reactions. Accounts of Chemical Research. 45: 814-25. PMID 22148885 DOI: 10.1021/ar200190g  1
2012 Mugridge JS, Bergman RG, Raymond KN. Equilibrium isotope effects on noncovalent interactions in a supramolecular host-guest system. Journal of the American Chemical Society. 134: 2057-66. PMID 22145944 DOI: 10.1021/ja2067324  1
2012 Curley JJ, Bergman RG, Tilley TD. Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Dalton Transactions (Cambridge, England : 2003). 41: 192-200. PMID 22020701 DOI: 10.1039/c1dt11753j  1
2012 Koller J, Bergman RG. Controlled hydrosilylation of carbonyls and imines catalyzed by a cationic aluminum alkyl complex Organometallics. 31: 2530-2533. DOI: 10.1021/om2008277  1
2011 Tomson NC, Crimmin MR, Petrenko T, Rosebrugh LE, Sproules S, Boyd WC, Bergman RG, DeBeer S, Toste FD, Wieghardt K. A step beyond the Feltham-Enemark notation: spectroscopic and correlated ab initio computational support for an antiferromagnetically coupled M(II)-(NO)- description of Tp*M(NO) (M = Co, Ni). Journal of the American Chemical Society. 133: 18785-801. PMID 22047035 DOI: 10.1021/ja206042k  1
2011 Hastings CJ, Backlund MP, Bergman RG, Raymond KN. Enzyme-like control of carbocation deprotonation regioselectivity in supramolecular catalysis of the Nazarov cyclization. Angewandte Chemie (International Ed. in English). 50: 10570-3. PMID 21932275 DOI: 10.1002/anie.201105325  1
2011 Gianetti TL, Tomson NC, Arnold J, Bergman RG. Z-selective, catalytic internal alkyne semihydrogenation under H2/CO mixtures by a niobium(III) imido complex. Journal of the American Chemical Society. 133: 14904-7. PMID 21854008 DOI: 10.1021/ja206016s  1
2011 Brown CJ, Miller GM, Johnson MW, Bergman RG, Raymond KN. High-turnover supramolecular catalysis by a protected ruthenium(II) complex in aqueous solution. Journal of the American Chemical Society. 133: 11964-6. PMID 21736357 DOI: 10.1021/ja205257x  1
2011 Hesp KD, Bergman RG, Ellman JA. Expedient synthesis of N-acyl anthranilamides and β-enamine amides by the Rh(III)-catalyzed amidation of aryl and vinyl C-H bonds with isocyanates. Journal of the American Chemical Society. 133: 11430-3. PMID 21714533 DOI: 10.1021/ja203495c  1
2011 Mugridge JS, Bergman RG, Raymond KN. 1H NMR chemical shift calculations as a probe of supramolecular host-guest geometry. Journal of the American Chemical Society. 133: 11205-12. PMID 21714506 DOI: 10.1021/ja202254x  1
2011 Zhao C, Toste FD, Bergman RG. Direct Michael addition of alkenes via a cobalt-dinitrosyl mediated vinylic C-H functionalization reaction. Journal of the American Chemical Society. 133: 10787-9. PMID 21699161 DOI: 10.1021/ja204564z  1
2011 Tomson NC, Arnold J, Bergman RG. Synthesis and reactivity of cationic niobium and tantalum methyl complexes supported by imido and β-diketiminato ligands. Dalton Transactions (Cambridge, England : 2003). 40: 7718-29. PMID 21523303 DOI: 10.1039/c1dt10202h  1
2011 Wang ZJ, Brown CJ, Bergman RG, Raymond KN, Toste FD. Hydroalkoxylation catalyzed by a gold(I) complex encapsulated in a supramolecular host. Journal of the American Chemical Society. 133: 7358-60. PMID 21517023 DOI: 10.1021/ja202055v  1
2011 Crimmin MR, Bergman RG, Toste FD. Synthesis of [RuCl2(NO)2(THF)] and its double C-N bond-forming reactions with alkenes. Angewandte Chemie (International Ed. in English). 50: 4484-7. PMID 21480451 DOI: 10.1002/anie.201100816  1
2011 Brasse M, Ellman JA, Bergman RG. A facile, metal- and solvent-free, autoxidative coupling of quinolines with indoles and pyrroles. Chemical Communications (Cambridge, England). 47: 5019-21. PMID 21445416 DOI: 10.1039/c1cc10507h  1
2011 Tsai AS, Tauchert ME, Bergman RG, Ellman JA. Rhodium(III)-catalyzed arylation of Boc-imines via C-H bond functionalization. Journal of the American Chemical Society. 133: 1248-50. PMID 21204527 DOI: 10.1021/ja109562x  1
2011 Tsai AS, Brasse M, Bergman RG, Ellman JA. Rh(III)-catalyzed oxidative coupling of unactivated alkenes via C-H activation. Organic Letters. 13: 540-2. PMID 21175143 DOI: 10.1021/ol102890k  1
2011 Crimmin MR, Colby DA, Ellman JA, Bergman RG. Synthesis and coordination chemistry of tri-substituted benzamidrazones. Dalton Transactions (Cambridge, England : 2003). 40: 514-22. PMID 21109860 DOI: 10.1039/c0dt01267j  1
2011 Koller J, Bergman RG. Highly efficient aluminum-catalyzed ring-opening polymerization of cyclic carbonates, lactones, and lactides, including a unique crystallographic snapshot of an intermediate Organometallics. 30: 3217-3224. DOI: 10.1021/om2003283  1
2011 Bowring MA, Bergman RG, Tilley TD. Disambiguation of metal and Brønsted acid catalyzed pathways for hydroarylation with platinum(II) catalysts Organometallics. 30: 1295-1298. DOI: 10.1021/om2000458  1
2011 Crimmin MR, Rosebrugh LE, Tomson NC, Weyhermüller T, Bergman RG, Toste FD, Wieghardt K. [(TMEDA)Co(NO) 2][BPh 4]: A versatile synthetic entry point to four and five coordinate {Co(NO) 2} 10 complexes Journal of Organometallic Chemistry. 696: 3974-3981. DOI: 10.1016/j.jorganchem.2011.04.038  1
2011 Razgon A, Anstey MR, Yakelis NA, Bergman RG, Sukenik CN. Surface immobilization of an organo-iridium complex through a carbon-metal bond Inorganica Chimica Acta. 375: 305-307. DOI: 10.1016/j.ica.2011.04.042  1
2011 Bergman RG. Toward greener routes to hydrocarbons: Deoxygenation of biomass-related polyols Acs National Meeting Book of Abstracts 1
2010 Tomson NC, Arnold J, Bergman RG. Synthesis, Characterization, and Reactions of Isolable (β-Diketiminato)Nb(III) Imido Complexes. Organometallics. 29: 5010-5025. PMID 21116450 DOI: 10.1021/om1002528  1
2010 Berman AM, Bergman RG, Ellman JA. Rh(I)-catalyzed direct arylation of azines. The Journal of Organic Chemistry. 75: 7863-8. PMID 21033740 DOI: 10.1021/jo101793r  1
2010 Boyd WC, Crimmin MR, Rosebrugh LE, Schomaker JM, Bergman RG, Toste FD. Cobalt-mediated, enantioselective synthesis of C(2) and C(1) dienes. Journal of the American Chemical Society. 132: 16365-7. PMID 21033667 DOI: 10.1021/ja107968c  1
2010 Mugridge JS, Szigethy G, Bergman RG, Raymond KN. Encapsulated guest-host dynamics: guest rotational barriers and tumbling as a probe of host interior cavity space. Journal of the American Chemical Society. 132: 16256-64. PMID 20977233 DOI: 10.1021/ja107656g  1
2010 Nichols JM, Bishop LM, Bergman RG, Ellman JA. Catalytic C-O bond cleavage of 2-aryloxy-1-arylethanols and its application to the depolymerization of lignin-related polymers. Journal of the American Chemical Society. 132: 12554-5. PMID 20731348 DOI: 10.1021/ja106101f  1
2010 Tomson NC, Arnold J, Bergman RG. Halo, Alkyl, Aryl, and Bis(imido) Complexes of Niobium Supported by the beta-Diketiminato Ligand. Organometallics. 29: 2926-2942. PMID 20671985 DOI: 10.1021/om1001827  1
2010 Arceo E, Ellman JA, Bergman RG. Rhenium-catalyzed didehydroxylation of vicinal diols to alkenes using a simple alcohol as a reducing agent. Journal of the American Chemical Society. 132: 11408-9. PMID 20669903 DOI: 10.1021/ja103436v  1
2010 Yotphan S, Bergman RG, Ellman JA. Synthesis of multicyclic pyridine and quinoline derivatives via intramolecular C-H bond functionalization. Organic Letters. 12: 2978-81. PMID 20518526 DOI: 10.1021/ol101002b  1
2010 Arceo E, Ellman JA, Bergman RG. A direct, biomass-based synthesis of benzoic acid: formic acid-mediated deoxygenation of the glucose-derived materials quinic acid and shikimic acid. Chemsuschem. 3: 811-3. PMID 20512802 DOI: 10.1002/cssc.201000111  1
2010 Koller J, Bergman RG. Aluminium-catalyzed intramolecular hydroamination of aminoalkenes. Chemical Communications (Cambridge, England). 46: 4577-9. PMID 20458403 DOI: 10.1039/c002760j  1
2010 Hastings CJ, Pluth MD, Bergman RG, Raymond KN. Enzymelike catalysis of the Nazarov cyclization by supramolecular encapsulation. Journal of the American Chemical Society. 132: 6938-40. PMID 20443566 DOI: 10.1021/ja102633e  1
2010 Mugridge JS, Bergman RG, Raymond KN. Does size really matter? The steric isotope effect in a supramolecular host-guest exchange reaction. Angewandte Chemie (International Ed. in English). 49: 3635-7. PMID 20394089 DOI: 10.1002/anie.200906569  1
2010 Mugridge JS, Bergman RG, Raymond KN. High-precision measurement of isotope effects on noncovalent host-guest interactions. Journal of the American Chemical Society. 132: 1182-3. PMID 20050653 DOI: 10.1021/ja905170x  1
2010 Colby DA, Bergman RG, Ellman JA. Rhodium-catalyzed C-C bond formation via heteroatom-directed C-H bond activation. Chemical Reviews. 110: 624-55. PMID 19438203 DOI: 10.1021/cr900005n  1
2010 Bishop LM, Roberson RE, Bergman RG, Trauner D. On the development of catalytic carba-6π electrocyclizations Synthesis. 2233-2244. DOI: 10.1055/s-0029-1218812  1
2010 Calladine JA, Torres O, Anstey M, Ball GE, Bergman RG, Curley J, Duckett SB, George MW, Gilson AI, Lawes DJ, Perutz RN, Sun XZ, Vollhardt KPC. Photoinduced N2 loss as a route to long-lived organometallic alkane complexes: A time-resolved IR and NMR study Chemical Science. 1: 622-630. DOI: 10.1039/c0sc00311e  1
2010 Koller J, Bergman RG. Highly efficient aluminum-catalyzed hydro-amination/-hydrazination of carbodiimides Organometallics. 29: 5946-5952. DOI: 10.1021/om100735q  1
2010 Koller J, Bergman RG. Synthesis, characterization, and reactivity of aluminum alkyl/amide complexes supported by guanidinate and monoanionic OCO-pincer ligands Organometallics. 29: 3350-3356. DOI: 10.1021/om100278b  1
2010 NICOLAOU KC, SORENSEN EJ, DISCORDIA R, HWANG C, MINTO RE, BHARUCHA KN, BERGMAN RG. ChemInform Abstract: Ten-Membered Ring Enediynes with Remarkable Chemical and Biological Properties. Cheminform. 23: no-no. DOI: 10.1002/chin.199247144  0.4
2009 Brown CJ, Bergman RG, Raymond KN. Enantioselective catalysis of the aza-Cope rearrangement by a chiral supramolecular assembly. Journal of the American Chemical Society. 131: 17530-1. PMID 19950985 DOI: 10.1021/ja906386w  1
2009 Tsai AS, Wilson RM, Harada H, Bergman RG, Ellman JA. Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C-H bond activation. Chemical Communications (Cambridge, England). 3910-2. PMID 19662249 DOI: 10.1039/b902878a  1
2009 Schomaker JM, Toste FD, Bergman RG. Cobalt-mediated [3 + 2]-annulation reaction of alkenes with alpha,beta-unsaturated ketones and imines. Organic Letters. 11: 3698-700. PMID 19639989 DOI: 10.1021/ol901542n  1
2009 Pluth MD, Bergman RG, Raymond KN. Proton-mediated chemistry and catalysis in a self-assembled supramolecular host. Accounts of Chemical Research. 42: 1650-9. PMID 19591461 DOI: 10.1021/ar900118t  1
2009 Arceo E, Marsden P, Bergman RG, Ellman JA. An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation. Chemical Communications (Cambridge, England). 3357-9. PMID 19503869 DOI: 10.1039/b907746d  1
2009 Chan VS, Chiu M, Bergman RG, Toste FD. Development of ruthenium catalysts for the enantioselective synthesis of P-stereogenic phosphines via nucleophilic phosphido intermediates. Journal of the American Chemical Society. 131: 6021-32. PMID 19338305 DOI: 10.1021/ja9014887  1
2009 Yotphan S, Bergman RG, Ellman JA. Application of Daugulis copper-catalyzed direct arylation to the synthesis of 5-aryl benzotriazepines. Organic Letters. 11: 1511-4. PMID 19260648 DOI: 10.1021/ol900103a  1
2009 Pluth MD, Fiedler D, Mugridge JS, Bergman RG, Raymond KN. Molecular recognition and self-assembly special feature: Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host. Proceedings of the National Academy of Sciences of the United States of America. 106: 10438-43. PMID 19181859 DOI: 10.1073/pnas.0809806106  1
2009 Pluth MD, Bergman RG, Raymond KN. The acid hydrolysis mechanism of acetals catalyzed by a supramolecular assembly in basic solution. The Journal of Organic Chemistry. 74: 58-63. PMID 19113901 DOI: 10.1021/jo802131v  1
2009 Pluth MD, Johnson DW, Szigethy G, Davis AV, Teat SJ, Oliver AG, Bergman RG, Raymond KN. Structural consequences of anionic host-cationic guest interactions in a supramolecular assembly. Inorganic Chemistry. 48: 111-20. PMID 19053347 DOI: 10.1021/ic8012848  1
2008 Gribble MW, Ellman JA, Bergman RG. Synthesis of a Benzodiazepine-derived Rhodium NHC Complex by C-H Bond Activation. Organometallics. 27: 2152-2155. PMID 21191469 DOI: 10.1021/om8000839  1
2008 Berman AM, Lewis JC, Bergman RG, Ellman JA. Rh(I)-catalyzed direct arylation of pyridines and quinolines. Journal of the American Chemical Society. 130: 14926-7. PMID 18855360 DOI: 10.1021/ja8059396  1
2008 Bishop LM, Barbarow JE, Bergman RG, Trauner D. Catalysis of 6pi electrocyclizations. Angewandte Chemie (International Ed. in English). 47: 8100-3. PMID 18785197 DOI: 10.1002/anie.200803336  1
2008 Pluth MD, Bergman RG, Raymond KN. Acceleration of amide bond rotation by encapsulation in the hydrophobic interior of a water-soluble supramolecular assembly. The Journal of Organic Chemistry. 73: 7132-6. PMID 18687002 DOI: 10.1021/jo800991g  1
2008 Harada H, Thalji RK, Bergman RG, Ellman JA. Enantioselective intramolecular hydroarylation of alkenes via directed C-H bond activation. The Journal of Organic Chemistry. 73: 6772-9. PMID 18681407 DOI: 10.1021/jo801098z  1
2008 Pluth MD, Bergman RG, Raymond KN. Supramolecular catalysis of orthoformate hydrolysis in basic solution: an enzyme-like mechanism. Journal of the American Chemical Society. 130: 11423-9. PMID 18680290 DOI: 10.1021/ja802839v  1
2008 Tomson NC, Yan A, Arnold J, Bergman RG. An unusally diverse array of products formed upon carbonylation of a dialkylniobium complex. Journal of the American Chemical Society. 130: 11262-3. PMID 18671347 DOI: 10.1021/ja803729k  1
2008 Hastings CJ, Fiedler D, Bergman RG, Raymond KN. Aza Cope rearrangement of propargyl enammonium cations catalyzed by a self-assembled "nanozyme". Journal of the American Chemical Society. 130: 10977-83. PMID 18652468 DOI: 10.1021/ja8013055  1
2008 Lewis JC, Bergman RG, Ellman JA. Direct functionalization of nitrogen heterocycles via Rh-catalyzed C-H bond activation. Accounts of Chemical Research. 41: 1013-25. PMID 18616300 DOI: 10.1021/ar800042p  1
2008 Chiu M, Hoyt HM, Michael FE, Bergman RG, van Halbeek H. Synthesis, structural characterization, and quantitative basicity studies of lithium zirconimidate complexes. Angewandte Chemie (International Ed. in English). 47: 6073-6. PMID 18604799 DOI: 10.1002/anie.200801463  1
2008 Bishop LM, Winkler M, Houk KN, Bergman RG, Trauner D. Mechanistic investigations of the acid-catalyzed cyclization of a vinyl ortho-quinone methide. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 5405-8. PMID 18449871 DOI: 10.1002/chem.200800662  1
2008 Pluth MD, Bergman RG, Raymond KN. Encapsulation of protonated diamines in a water-soluble, chiral, supramolecular assembly allows for measurement of hydrogen-bond breaking followed by nitrogen inversion/rotation. Journal of the American Chemical Society. 130: 6362-6. PMID 18444618 DOI: 10.1021/ja076691h  1
2008 Tsai AS, Bergman RG, Ellman JA. Asymmetric synthesis of (-)-incarvillateine employing an intramolecular alkylation via Rh-catalyzed olefinic C-H bond activation. Journal of the American Chemical Society. 130: 6316-7. PMID 18444613 DOI: 10.1021/ja8012159  1
2008 Lalic G, Krinsky JL, Bergman RG. Scope and mechanism of formal S(N)2' substitution reactions of a monomeric imidozirconium complex with allylic electrophiles. Journal of the American Chemical Society. 130: 4459-65. PMID 18327942 DOI: 10.1021/ja7106096  1
2008 Schomaker JM, Boyd WC, Stewart IC, Toste FD, Bergman RG. Cobalt dinitrosoalkane complexes in the C-H functionalization of olefins. Journal of the American Chemical Society. 130: 3777-9. PMID 18318538 DOI: 10.1021/ja800738d  1
2008 Colby DA, Bergman RG, Ellman JA. Synthesis of dihydropyridines and pyridines from imines and alkynes via C-H activation. Journal of the American Chemical Society. 130: 3645-51. PMID 18302381 DOI: 10.1021/ja7104784  1
2008 Leung DH, Bergman RG, Raymond KN. Enthalpy-entropy compensation reveals solvent reorganization as a driving force for supramolecular encapsulation in water. Journal of the American Chemical Society. 130: 2798-805. PMID 18257565 DOI: 10.1021/ja075975z  1
2008 Razgon A, Bergman RG, Sukenik CN. Ozonolysis-based route to the in situ formation of aldehyde-bearing self-assembled monolayer surfaces. Langmuir : the Acs Journal of Surfaces and Colloids. 24: 2545-52. PMID 18251560 DOI: 10.1021/la703120c  1
2008 Lewis JC, Berman AM, Bergman RG, Ellman JA. Rh(I)-catalyzed arylation of heterocycles via C-H bond activation: expanded scope through mechanistic insight. Journal of the American Chemical Society. 130: 2493-500. PMID 18251465 DOI: 10.1021/ja0748985  1
2008 Yotphan S, Bergman RG, Ellman JA. The stereoselective formation of bicyclic enamines with bridgehead unsaturation via tandem C-H bond activation/alkenylation/electrocyclization. Journal of the American Chemical Society. 130: 2452-3. PMID 18247623 DOI: 10.1021/ja710981b  1
2008 Smith SE, Sasaki JM, Bergman RG, Mondloch JE, Finke RG. Platinum-catalyzed phenyl and methyl group transfer from tin to iridium: evidence for an autocatalytic reaction pathway with an unusual preference for methyl transfer. Journal of the American Chemical Society. 130: 1839-41. PMID 18198879 DOI: 10.1021/ja710365x  1
2008 Krinsky JL, Anderson LL, Arnold J, Bergman RG. Oxygen-centered hexatantalum tetradecaimido cluster complexes. Inorganic Chemistry. 47: 1053-66. PMID 18163614 DOI: 10.1021/ic701920v  1
2008 Hastings CJ, Pluth MD, Biros SM, Bergman RG, Raymond KN. Simultaneously bound guests and chiral recognition: a chiral self-assembled supramolecular host encapsulates hydrophobic guests Tetrahedron. 64: 8362-8367. DOI: 10.1016/j.tet.2008.05.131  1
2008 Pluth MD, Bergman RG, Raymond KN. Selective Stoichiometric and Catalytic Reactivity in the Confines of a Chiral Supramolecular Assembly Supramolecular Catalysis. 165-197. DOI: 10.1002/9783527621781.ch7  1
2008 Rostovtsev VV, Snieckus V, Macklin T, Grushin VV, Ishiyama T, Miyaura N, Kakiuchi F, Dyker G, Kobayashi S, Bandini M, Melloni A, Piccinelli F, Reetz MT, Sommer K, Murai S, ... ... Bergman RG, et al. C-H Transformation at Arenes Handbook of C-H Transformations: Applications in Organic Synthesis. 1: 99-276. DOI: 10.1002/9783527619450.ch5  1
2007 Chan VS, Bergman RG, Toste FD. Pd-catalyzed dynamic kinetic enantioselective arylation of silylphosphines. Journal of the American Chemical Society. 129: 15122-3. PMID 18004858 DOI: 10.1021/ja076457r  1
2007 Nolin KA, Krumper JR, Pluth MD, Bergman RG, Toste FD. Analysis of an unprecedented mechanism for the catalytic hydrosilylation of carbonyl compounds. Journal of the American Chemical Society. 129: 14684-96. PMID 17983224 DOI: 10.1021/ja074477n  1
2007 Fox RJ, Lalic G, Bergman RG. Regio- and stereospecific formation of protected allylic alcohols via zirconium-mediated S(N)2' substitution of allylic chlorides. Journal of the American Chemical Society. 129: 14144-5. PMID 17973391 DOI: 10.1021/ja075967i  1
2007 Pluth MD, Bergman RG, Raymond KN. Catalytic deprotection of acetals in basic solution with a self-assembled supramolecular "nanozyme". Angewandte Chemie (International Ed. in English). 46: 8587-9. PMID 17926313 DOI: 10.1002/anie.200703371  1
2007 Biros SM, Bergman RG, Raymond KN. The hydrophobic effect drives the recognition of hydrocarbons by an anionic metal-ligand cluster. Journal of the American Chemical Society. 129: 12094-5. PMID 17880087 DOI: 10.1021/ja075236i  1
2007 Pluth MD, Bergman RG, Raymond KN. Making amines strong bases: thermodynamic stabilization of protonated guests in a highly-charged supramolecular host1. Journal of the American Chemical Society. 129: 11459-67. PMID 17713905 DOI: 10.1021/ja072654e  1
2007 Hoyt HM, Bergman RG. Kinetic control and multiple mechanisms for C-H bond activation by a Zr=N complex. Angewandte Chemie (International Ed. in English). 46: 5580-2. PMID 17577898 DOI: 10.1002/anie.200701816  1
2007 Cobar EA, Khaliullin RZ, Bergman RG, Head-Gordon M. Theoretical study of the rhenium-alkane interaction in transition metal-alkane sigma-complexes. Proceedings of the National Academy of Sciences of the United States of America. 104: 6963-8. PMID 17442751 DOI: 10.1073/pnas.0610295104  1
2007 Pluth MD, Bergman RG, Raymond KN. Acid catalysis in basic solution: a supramolecular host promotes orthoformate hydrolysis. Science (New York, N.Y.). 316: 85-8. PMID 17412953 DOI: 10.1126/science.1138748  1
2007 Lewis JC, Bergman RG, Ellman JA. Rh(I)-catalyzed alkylation of quinolines and pyridines via C-H bond activation. Journal of the American Chemical Society. 129: 5332-3. PMID 17411050 DOI: 10.1002/chin.200737137  1
2007 Watson MP, Overman LE, Bergman RG. Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. Journal of the American Chemical Society. 129: 5031-44. PMID 17402733 DOI: 10.1021/ja0676962  1
2007 Bergman RG. Organometallic chemistry: C-H activation. Nature. 446: 391-3. PMID 17377575 DOI: 10.1038/446391a  1
2007 Wiedemann SH, Kang DH, Bergman RG, Friend CM. Cyclopropylmethyl/cyclobutyl rearrangements on surfaces: evidence for transient cation formation near O-covered Mo(110). Journal of the American Chemical Society. 129: 4666-77. PMID 17375922 DOI: 10.1021/ja0682428  1
2007 Leung DH, Bergman RG, Raymond KN. Highly selective supramolecular catalyzed allylic alcohol isomerization. Journal of the American Chemical Society. 129: 2746-7. PMID 17302420 DOI: 10.1021/ja068688o  1
2007 Anstey MR, Yung CM, Du J, Bergman RG. Unexpected C-C bond cleavage and C-C bond formation observed in the reaction of a cationic iridium complex with heteroatom-substituted cyclopropanes. Journal of the American Chemical Society. 129: 776-7. PMID 17243810 DOI: 10.1021/ja068312a  1
2007 Rech JC, Yato M, Duckett D, Ember B, LoGrasso PV, Bergman RG, Ellman JA. Synthesis of potent bicyclic bisarylimidazole c-Jun N-terminal kinase inhibitors by catalytic C-H bond activation. Journal of the American Chemical Society. 129: 490-1. PMID 17227002 DOI: 10.1021/ja0676004  1
2007 Krinsky JL, Anderson LL, Arnold J, Bergman RG. Synthesis and properties of oxygen-centered tetradecaimido hexatantalum clusters. Angewandte Chemie (International Ed. in English). 46: 369-72. PMID 17154203 DOI: 10.1002/anie.200603019  1
2007 Watzke A, Wilson RM, O'Malley SJ, Bergman RG, Ellman JA. Asymmetric intramolecular alkylation of chiral aromatic imines via catalytic C-H bond activation Synlett. 2383-2389. DOI: 10.1055/s-2007-985593  1
2007 Krinsky JL, Arnold J, Bergman RG. Platinum group thiophenoxyimine complexes: syntheses and crystallographic/computational studies Organometallics. 26: 897-909. DOI: 10.1021/om0609057  1
2006 Anderson LL, Schmidt JA, Arnold J, Bergman RG. Neutral and Cationic Alkyl Tantalum Imido Complexes: Synthesis and Migratory Insertion Reactions. Organometallics. 25: 3394-3406. PMID 19079787 DOI: 10.1021/om060081t  1
2006 Watson DA, Chiu M, Bergman RG. Zirconium Bis(Amido) Catalysts for Asymmetric Intramolecular Alkene Hydroamination. Organometallics. 25: 4731-4733. PMID 19079735 DOI: 10.1021/om0606791  1
2006 Dong VM, Fiedler D, Carl B, Bergman RG, Raymond KN. Molecular recognition and stabilization of iminium ions in water. Journal of the American Chemical Society. 128: 14464-5. PMID 17090022 DOI: 10.1021/ja0657915  1
2006 Watzke A, O'Malley SJ, Bergman RG, Ellman JA. Reassignment of the configuration of salvianolic acid B and establishment of its identity with lithospermic acid B. Journal of Natural Products. 69: 1231-3. PMID 16933885 DOI: 10.1021/np060136w  1
2006 Fiedler D, van Halbeek H, Bergman RG, Raymond KN. Supramolecular catalysis of unimolecular rearrangements: substrate scope and mechanistic insights. Journal of the American Chemical Society. 128: 10240-52. PMID 16881654 DOI: 10.1021/ja062329b  1
2006 Leung DH, Bergman RG, Raymond KN. Scope and mechanism of the C-H bond activation reactivity within a supramolecular host by an iridium guest: a stepwise ion pair guest dissociation mechanism. Journal of the American Chemical Society. 128: 9781-97. PMID 16866535 DOI: 10.1021/ja061412w  1
2006 Colby DA, Bergman RG, Ellman JA. Stereoselective alkylation of alpha,beta-unsaturated imines via C-H bond activation. Journal of the American Chemical Society. 128: 5604-5. PMID 16637605 DOI: 10.1021/ja0584931  1
2006 Wilson RM, Thalji RK, Bergman RG, Ellman JA. Enantioselective synthesis of a PKC inhibitor via catalytic C-H bond activation. Organic Letters. 8: 1745-7. PMID 16597156 DOI: 10.1021/ol060485h  1
2006 Chan VS, Stewart IC, Bergman RG, Toste FD. Asymmetric catalytic synthesis of P-stereogenic phosphines via a nucleophilic ruthenium phosphido complex. Journal of the American Chemical Society. 128: 2786-7. PMID 16506742 DOI: 10.1002/chin.200628166  1
2006 Wiedemann SH, Ellman JA, Bergman RG. Rhodium-catalyzed direct C-H addition of 3,4-dihydroquinazolines to alkenes and their use in the total synthesis of vasicoline. The Journal of Organic Chemistry. 71: 1969-76. PMID 16496982 DOI: 10.1021/jo052345b  1
2006 Wiedemann SH, Lewis JC, Ellman JA, Bergman RG. Experimental and computational studies on the mechanism of N-heterocycle C-H activation by Rh(I). Journal of the American Chemical Society. 128: 2452-62. PMID 16478202 DOI: 10.1021/ja0576684  1
2006 Lewis JC, Wu JY, Bergman RG, Ellman JA. Microwave-promoted rhodium-catalyzed arylation of heterocycles through C--H bond activation. Angewandte Chemie (International Ed. in English). 45: 1589-91. PMID 16444794 DOI: 10.1002/anie.200504289  1
2006 Fiedler D, Bergman RG, Raymond KN. Stabilization of reactive organometallic intermediates inside a self-assembled nanoscale host. Angewandte Chemie (International Ed. in English). 45: 745-8. PMID 16370008 DOI: 10.1002/anie.200501938  1
2006 Mullins SM, Bergman RG, Arnold J. Olefination and group transfer reactions of an electron deficient tantalum methylidene complex. Dalton Transactions (Cambridge, England : 2003). 203-12. PMID 16357978 DOI: 10.1039/b512741f  1
2006 Zhang Y, Lewis JC, Bergman RG, Ellman JA, Oldfield E. NMR shifts, orbitals, and M⋯H-X bonding in d 8 square planar metal complexes Organometallics. 25: 3515-3519. DOI: 10.1021/om060163h  1
2006 Papaiconomou N, Yakelis N, Salminen J, Bergman R, Prausnitz JM. Synthesis and properties of seven ionic liquids containing 1-methyl-3-octylimidazolium or 1-butyl-4-methylpyridinium cations Journal of Chemical and Engineering Data. 51: 1389-1393. DOI: 10.1021/je060096y  1
2006 Skaddan MB, Bergman RG. The neighboring group effect of fluorine in the tritium labeling of organic substrates with [Cp*(PMe3)IrMe(CH2Cl 2)]+ [BArf]-, a cationic iridium(III) complex Journal of Labelled Compounds and Radiopharmaceuticals. 49: 623-634. DOI: 10.1002/jlcr.1072  1
2005 Yakelis NA, Bergman RG. Sodium Tetrakis[(3,5-trifluoromethyl)phenyl]borate (NaBArF(24)): Safe Preparation, Standardized Purification, and Analysis of Hydration. Organometallics. 24: 3579-3581. PMID 19079785 DOI: 10.1021/om0501428  1
2005 Blum SA, Rivera VA, Ruck RT, Michael FE, Bergman RG. Synthetic and Mechanistic Studies of Strained Heterocycle Opening Reactions Mediated by Zirconium(IV) Imido Complexes. Organometallics. 24: 1647-1659. PMID 16508693 DOI: 10.1021/om049105r  1
2005 Stewart IC, Lee CC, Bergman RG, Toste FD. Living ring-opening polymerization of N-sulfonylaziridines: synthesis of high molecular weight linear polyamines. Journal of the American Chemical Society. 127: 17616-7. PMID 16351086 DOI: 10.1021/ja0554357  1
2005 Lalic G, Blum SA, Bergman RG. Zirconium-mediated SN2' substitution of allylic ethers: regio- and stereospecific formation of protected allylic amines. Journal of the American Chemical Society. 127: 16790-1. PMID 16316217 DOI: 10.1002/chin.200614063  1
2005 Anderson LL, Arnold J, Bergman RG. Proton-catalyzed hydroamination and hydroarylation reactions of anilines and alkenes: a dramatic effect of counteranions on reaction efficiency. Journal of the American Chemical Society. 127: 14542-3. PMID 16231885 DOI: 10.1002/chin.200609076  1
2005 O'Malley SJ, Tan KL, Watzke A, Bergman RG, Ellman JA. Total synthesis of (+)-lithospermic acid by asymmetric intramolecular alkylation via catalytic C-H bond activation. Journal of the American Chemical Society. 127: 13496-7. PMID 16190703 DOI: 10.1021/ja052680h  1
2005 Thalji RK, Ahrendt KA, Bergman RG, Ellman JA. Annulation of aromatic imines via directed C-H bond activation. The Journal of Organic Chemistry. 70: 6775-81. PMID 16095296 DOI: 10.1021/jo050757e  1
2005 Fiedler D, Leung DH, Bergman RG, Raymond KN. Selective molecular recognition, C-H bond activation, and catalysis in nanoscale reaction vessels. Accounts of Chemical Research. 38: 349-58. PMID 15835881 DOI: 10.1021/ar040152p  1
2005 Lin FL, Hoyt HM, van Halbeek H, Bergman RG, Bertozzi CR. Mechanistic investigation of the staudinger ligation. Journal of the American Chemical Society. 127: 2686-95. PMID 15725026 DOI: 10.1021/ja044461m  1
2005 Michael FE, Duncan AP, Sweeney ZK, Bergman RG. Rearrangements and stereomutations of metallacycles derived from allenes and imidozirconium complexes. Journal of the American Chemical Society. 127: 1752-64. PMID 15701010 DOI: 10.1021/ja045607k  1
2005 Lewis JC, Wu J, Bergman RG, Ellman JA. Preagostic Rh-H interactions and C-H bond functionalization: A Combined Experimental and Theoretical Investigation of Rhodium (I) Phosphinite Complexes Organometallics. 24: 5737-5746. DOI: 10.1021/om050700i  1
2004 Blum SA, Bergman RG. Nitro and Nitroso Metathesis Reactions with Monomeric Zirconium Imido Complexes. Organometallics. 23: 4003-4005. PMID 16508695 DOI: 10.1021/om0495776  1
2004 Ruck RT, Bergman RG. Reactions of Imines with Azazirconacyclobutenes and Generation of Electron-Deficient Imidozirconocene Complexes. Organometallics. 23: 2231-2233. PMID 16508694 DOI: 10.1021/om0497994  1
2004 Cordaro JG, Bergman RG. Dissociation of carbanions from acyl iridium compounds: an experimental and computational investigation. Journal of the American Chemical Society. 126: 16912-29. PMID 15612730 DOI: 10.1021/ja045859l  1
2004 Cordaro JG, van Halbeek H, Bergman RG. An iridium difluoroketene complex: synthesis and isolation. Angewandte Chemie (International Ed. in English). 43: 6366-9. PMID 15558693 DOI: 10.1002/anie.200461402  1
2004 Fiedler D, Bergman RG, Raymond KN. Supramolecular catalysis of a unimolecular transformation: aza-Cope rearrangement within a self-assembled host. Angewandte Chemie (International Ed. in English). 43: 6748-51. PMID 15558640 DOI: 10.1002/anie.200461776  1
2004 Krumper JR, Martin RL, Hay PJ, Yung CM, Veltheer J, Bergman RG. Synthesis and reactivity of the hydrido- and alkylrhenium methylidene complexes Cp*(PMe3)2(R)Re=CH2 (R = H, CH3). Journal of the American Chemical Society. 126: 14804-15. PMID 15535706 DOI: 10.1021/ja0468877  1
2004 Tan KL, Park S, Ellman JA, Bergman RG. Intermolecular coupling of alkenes to heterocycles via C-H bond activation. The Journal of Organic Chemistry. 69: 7329-35. PMID 15471487 DOI: 10.1021/jo048666p  1
2004 Yung CM, Skaddan MB, Bergman RG. Stoichiometric and catalytic H/D incorporation by cationic iridium complexes: a common monohydrido-iridium intermediate. Journal of the American Chemical Society. 126: 13033-43. PMID 15469302 DOI: 10.1021/ja046825g  1
2004 Ruck RT, Bergman RG. Zirconium-mediated conversion of amides to nitriles: a surprising additive effect. Angewandte Chemie (International Ed. in English). 43: 5375-7. PMID 15468091 DOI: 10.1002/anie.200461064  1
2004 Ruck RT, Zuckerman RL, Krska SW, Bergman RG. Carboamination: additions of imine C=N bonds across alkynes catalyzed by imidozirconium complexes. Angewandte Chemie (International Ed. in English). 43: 5372-4. PMID 15468090 DOI: 10.1002/anie.200461063  1
2004 Krumper JR, Gerisch M, Magistrato A, Rothlisberger U, Bergman RG, Tilley TD. Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. Journal of the American Chemical Society. 126: 12492-502. PMID 15453783 DOI: 10.1021/ja047665b  1
2004 Rais D, Bergman RG. Synthesis and reactivity of the monomeric late-transition-metal parent amido complex [Ir(Cp*)(PMe3)(Ph)(NH2)]. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 3970-8. PMID 15317061 DOI: 10.1002/chem.200400151  1
2004 Anderson LL, Arnold J, Bergman RG. Catalytic hydroamination of alkynes and norbornene with neutral and cationic tantalum imido complexes. Organic Letters. 6: 2519-22. PMID 15255680 DOI: 10.1021/ol0608810  1
2004 Thalji RK, Ellman JA, Bergman RG. Highly efficient and enantioselective cyclization of aromatic imines via directed C-H bond activation. Journal of the American Chemical Society. 126: 7192-3. PMID 15186153 DOI: 10.1002/chin.200442030  1
2004 Wiedemann SH, Bergman RG, Ellman JA. Rhodium-catalyzed direct C-H addition of 4,4-dimethyl-2-oxazoline to alkenes. Organic Letters. 6: 1685-7. PMID 15128267 DOI: 10.1002/chin.200438130  1
2004 Fiedler D, Leung DH, Bergman RG, Raymond KN. Enantioselective guest binding and dynamic resolution of cationic ruthenium complexes by a chiral metal-ligand assembly. Journal of the American Chemical Society. 126: 3674-5. PMID 15038695 DOI: 10.1021/ja039225a  1
2004 Cordaro JG, Bergman RG. Elimination of R-H from iridium acyl hydrides without loss of CO: evidence for the intervention of metal cation/carbanion pairs. Journal of the American Chemical Society. 126: 3432-3. PMID 15025464 DOI: 10.1021/ja031784u  1
2004 Leung DH, Fiedler D, Bergman RG, Raymond KN. Selective C-H bond activation by a supramolecular host-guest assembly. Angewandte Chemie (International Ed. in English). 43: 963-6. PMID 14966879 DOI: 10.1002/anie.200352772  1
2004 Fiedler D, Pagliero D, Brumaghim JL, Bergman RG, Raymond KN. Encapsulation of cationic ruthenium complexes into a chiral self-assembled cage. Inorganic Chemistry. 43: 846-8. PMID 14753801 DOI: 10.1021/ic035105s  1
2004 Hoyt HM, Michael FE, Bergman RG. C-H bond activation of hydrocarbons by an imidozirconocene complex. Journal of the American Chemical Society. 126: 1018-9. PMID 14746459 DOI: 10.1021/ja0385944  1
2004 Lewis JC, Wiedemann SH, Bergman RG, Ellman JA. Arylation of heterocycles via rhodium-catalyzed C-H bond functionalization. Organic Letters. 6: 35-8. PMID 14703344 DOI: 10.1002/chin.200423062  1
2004 Skaddan MB, Yung CM, Bergman RG. Stoichiometric and catalytic deuterium and tritium labeling of "unactivated" organic substrates with cationic Ir(III) complexes. Organic Letters. 6: 11-3. PMID 14703338 DOI: 10.1021/ol0359923  0.68
2004 Fox DJ, Bergman RG. Synthesis of an Iron Parent Amido Complex and a Comparison of Its Reactivity with the Ruthenium Analog Organometallics. 23: 1656-1670. DOI: 10.1021/om0499660  1
2004 Taw FL, Bergman RG, Brookhart M. Silicon-hydrogen bond activation and formation of silane complexes using a cationic rhodium(III) complex Organometallics. 23: 886-890. DOI: 10.1021/om0341303  1
2004 Corkey BK, Taw FL, Bergman RG, Brookhart M. Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition Polyhedron. 23: 2943-2954. DOI: 10.1016/j.poly.2004.09.005  1
2004 Pluth MD, Bergman RG, Raymond KN. Encapsulation of cationic organometallic guests by a chiral self-assembled supramolecular cage: Enantioselective binding, dynamic resolution, and selective C-H bond activation Chemtracts. 17: 515-522.  1
2003 Fox DJ, Bergman RG. Synthesis of a first-row transition metal parent amido complex and carbon monoxide insertion into the amide N-H bond. Journal of the American Chemical Society. 125: 8984-5. PMID 15369333 DOI: 10.1021/ja035707a  1
2003 Krumper JR, Gerisch M, Suh JM, Bergman RG, Tilley TD. Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. The Journal of Organic Chemistry. 68: 9705-10. PMID 14656097 DOI: 10.1021/jo035120e  1
2003 Blum SA, Walsh PJ, Bergman RG. Epoxide-opening and group-transfer reactions mediated by monomeric zirconium imido complexes. Journal of the American Chemical Society. 125: 14276-7. PMID 14624566 DOI: 10.1021/ja037267t  1
2003 Ackermann L, Bergman RG, Loy RN. Use of group 4 bis(sulfonamido) complexes in the intramolecular hydroamination of alkynes and allenes. Journal of the American Chemical Society. 125: 11956-63. PMID 14505417 DOI: 10.1002/chin.200405113  1
2003 Taw FL, Mueller AH, Bergman RG, Brookhart M. A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. Journal of the American Chemical Society. 125: 9808-13. PMID 12904046 DOI: 10.1021/ja034468o  1
2003 Stewart IC, Bergman RG, Toste FD. Phosphine-catalyzed hydration and hydroalkoxylation of activated olefins: use of a strong nucleophile to generate a strong base. Journal of the American Chemical Society. 125: 8696-7. PMID 12862443 DOI: 10.1021/ja035232n  1
2003 Michael FE, Duncan AP, Sweeney ZK, Bergman RG. Mechanisms of allene stereoinversion by imidozirconium complexes. Journal of the American Chemical Society. 125: 7184-5. PMID 12797785 DOI: 10.1021/ja0348389  1
2003 Tan KL, Vasudevan A, Bergman RG, Ellman JA, Souers AJ. Microwave-assisted C-H bond activation: a rapid entry into functionalized heterocycles. Organic Letters. 5: 2131-4. PMID 12790546 DOI: 10.1002/chin.200340138  1
2003 Blum SA, Tan KL, Bergman RG. Application of physical organic methods to the investigation of organometallic reaction mechanisms. The Journal of Organic Chemistry. 68: 4127-37. PMID 12762711 DOI: 10.1021/jo034198s  1
2003 Ahrendt KA, Bergman RG, Ellman JA. Synthesis of a tricyclic mescaline analogue by catalytic C-H bond activation. Organic Letters. 5: 1301-3. PMID 12688744 DOI: 10.1021/ol034228d  1
2003 Blum SA, Bergman RG, Ellman JA. Enantioselective oxidation of di-tert-butyl disulfide with a vanadium catalyst: progress toward mechanism elucidation. The Journal of Organic Chemistry. 68: 150-5. PMID 12515473 DOI: 10.1021/jo0205560  1
2003 Bergman RG, Cundari TR, Gillespie AM, Gunnoe TB, Harman WD, Klinckman TR, Temple MD, White DP. Computational study of methane activation by TpRe(CO)2 and CpRe(CO)2 with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands Organometallics. 22: 2331-2337. DOI: 10.1021/om021048j  1
2002 Duncan AP, Bergman RG. Selective transformations of organic compounds by imidozirconocene complexes. Chemical Record (New York, N.Y.). 2: 431-45. PMID 12469354 DOI: 10.1002/chin.200330288  1
2002 Holland AW, Bergman RG. Effects of phosphine ligand chelation on the reactivity of monomeric parent amido ruthenium complexes: synthesis and reactivity of such a complex bearing monodentate ligands. Journal of the American Chemical Society. 124: 14684-95. PMID 12465980 DOI: 10.1021/ja027620f  1
2002 Tan KL, Bergman RG, Ellman JA. Intermolecular coupling of isomerizable alkenes to heterocycles via rhodium-catalyzed C-H bond activation. Journal of the American Chemical Society. 124: 13964-5. PMID 12440873 DOI: 10.1021/ja0281129  1
2002 Asplund MC, Snee PT, Yeston JS, Wilkens MJ, Payne CK, Yang H, Kotz KT, Frei H, Bergman RG, Harris CB. Ultrafast UV pump/IR probe studies of C-H activation in linear, cyclic, and aryl hydrocarbons. Journal of the American Chemical Society. 124: 10605-12. PMID 12197763 DOI: 10.1021/ja020418s  1
2002 Cordaro JG, McCusker JK, Bergman RG. Synthesis of mono-substituted 2,2'-bipyridines. Chemical Communications (Cambridge, England). 1496-7. PMID 12189861 DOI: 10.1039/B203595B  1
2002 Holland AW, Bergman RG. Heterocumulene metathesis by iridium guanidinate and ureylene complexes: catalysis involving reversible insertion to form six-membered metallacycles. Journal of the American Chemical Society. 124: 9010-1. PMID 12148979 DOI: 10.1021/ja026178y  1
2002 Taw FL, Mellows H, White PS, Hollander FJ, Bergman RG, Brookhart M, Heinekey DM. Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. Journal of the American Chemical Society. 124: 5100-8. PMID 11982375 DOI: 10.1021/ja0165990  1
2002 Ackermann L, Bergman RG. A highly reactive titanium precatalyst for intramolecular hydroamination reactions. Organic Letters. 4: 1475-8. PMID 11975607 DOI: 10.1021/ol0256724  1
2002 Fulton JR, Sklenak S, Bouwkamp MW, Bergman RG. A comprehensive investigation of the chemistry and basicity of a parent amidoruthenium complex Journal of the American Chemical Society. 124: 4722-4737. PMID 11971722 DOI: 10.1021/ja011876o  1
2002 Taw FL, White PS, Bergman RG, Brookhart M. Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. Journal of the American Chemical Society. 124: 4192-3. PMID 11960431 DOI: 10.1021/ja0255094  0.48
2002 Tan KL, Bergman RG, Ellman JA. Intermediacy of an N-heterocyclic carbene complex in the catalytic C-H activation of a substituted benzimidazole. Journal of the American Chemical Society. 124: 3202-3. PMID 11916392 DOI: 10.1021/ja017351d  1
2002 Klei SR, Golden JT, Tilley TD, Bergman RG. Iridium-catalyzed H/D exchange into organic compounds in water. Journal of the American Chemical Society. 124: 2092-3. PMID 11878944 DOI: 10.1021/ja017219d  1
2002 Tellers DM, Yung CM, Arndtsen BA, Adamson DR, Bergman RG. Electronic and medium effects on the rate of arene C [bond] H activation by cationic Ir(III) complexes. Journal of the American Chemical Society. 124: 1400-10. PMID 11841308 DOI: 10.1021/ja011809u  1
2002 Fulton JR, Holland AW, Fox DJ, Bergman RG. Formation, reactivity, and properties of nondative late transition metal-oxygen and -nitrogen bonds. Accounts of Chemical Research. 35: 44-56. PMID 11790088 DOI: 10.1021/ar000132x  1
2002 Klei SR, Tilley TD, Bergman RG. Iridium (III) and rhodium (III) complexes bearing chelating cyclopentadienyl-phosphine ligands as C-H activation catalysts for the deuteration of hydrocarbons in D2O Organometallics. 21: 4905-4911. DOI: 10.1021/om020375o  1
2002 Klei SR, Tilley TD, Bergman RG. Stoichiometric and catalytic behavior of cationic silyl and silylene complexes Organometallics. 21: 4648-4661. DOI: 10.1021/om0203173  1
2002 Holland AW, Bergman RG. Regiocontrol of cyclometalation in a P4Ru(II) system. Unusual base-induced metalation within a chelate ring versus activation of a methyl group Organometallics. 21: 2149-2152. DOI: 10.1021/om0202470  1
2002 Klei SR, Don Tilley T, Bergman RG. Reactions of Cp*(PMe3)Ir(Me)OTf with silanes: Role of base-free silylene complexes in rearrangements of the resulting silicon-based ligands Organometallics. 21: 3376-3387. DOI: 10.1021/om020191+  1
2002 Klei SR, Golden JT, Burger P, Bergman RG. Cationic Ir(III) alkyl and hydride complexes: Stoichiometric and catalytic C-H activation by Cp*(PMe3 Ir(R)(X) in homogeneous solution Journal of Molecular Catalysis a: Chemical. 189: 79-94. DOI: 10.1016/S1381-1169(02)00192-9  1
2002 Holland AW, Bergman RG. Thermal reactivity of Group 9 transition metal pinacolate complexes: Heterocumulene cleavage and C-O bond formation Inorganica Chimica Acta. 341: 99-106. DOI: 10.1016/S0020-1693(02)01234-3  1
2002 Paisner SN, Lavoie GG, Bergman RG. Formation of planar-chiral alkylphosphine- and aniline-substituted cyclopentadienyl metal complexes and their reactivity toward electrophiles Inorganica Chimica Acta. 334: 253-275. DOI: 10.1016/S0020-1693(02)00742-9  1
2001 Szewczyk JW, Zuckerman RL, Bergman RG, Ellman JA. A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation. Angewandte Chemie (International Ed. in English). 40: 216-219. PMID 29711936 DOI: 10.1002/1521-3773(20010105)40:1<216::AID-ANIE216>3.0.CO;2-K  1
2001 Zuckerman RL, Bergman RG. Mechanistic Investigation of Cycloreversion/Cycloaddition Reactions between Zirconocene Metallacycle Complexes and Unsaturated Organic Substrates. Organometallics. 20: 1792-1807. PMID 16724160 DOI: 10.1021/om010091o  1
2001 Mullins SM, Duncan AP, Bergman RG, Arnold J. Reactivity of a titanium dinitrogen complex supported by guanidinate ligands: investigation of solution behavior and a novel rearrangement of guanidinate ligands. Inorganic Chemistry. 40: 6952-63. PMID 11754277 DOI: 10.1021/ic010631+  1
2001 Tellers DM, Bergman RG. Binding of chlorohydrocarbons to metal centers: quantitative evaluation of relative binding constants and structural characterization of the first isolable transition metal-chloromethane adduct. Journal of the American Chemical Society. 123: 11508-9. PMID 11707141 DOI: 10.1021/ja0164982  0.76
2001 Thalji RK, Ahrendt KA, Bergman RG, Ellman JA. Annulation of aromatic imines via directed C-H activation with Wilkinson's catalyst. Journal of the American Chemical Society. 123: 9692-3. PMID 11572698 DOI: 10.1021/ja016642j  1
2001 Johnson JS, Bergman RG. Imidotitanium complexes as hydroamination catalysts: substantially enhanced reactivity from an unexpected cyclopentadienide/amide ligand exchange. Journal of the American Chemical Society. 123: 2923-4. PMID 11456996 DOI: 10.1021/ja005685h  1
2001 Tan KL, Bergman RG, Ellman JA. Annulation of alkenyl-substituted heterocycles via rhodium-catalyzed intramolecular C-H activated coupling reactions. Journal of the American Chemical Society. 123: 2685-6. PMID 11456947 DOI: 10.1021/ja0058738  1
2001 Golden JT, Andersen RA, Bergman RG. Exceptionally low-temperature carbon--hydrogen/carbon--deuterium exchange reactions of organic and organometallic compounds catalyzed by the Cp*(PMe(3))IrH(ClCH(2)Cl)(+) cation. Journal of the American Chemical Society. 123: 5837-8. PMID 11403632 DOI: 10.1021/ja0155480  1
2001 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. Journal of the American Chemical Society. 123: 5818-9. PMID 11403623 DOI: 10.1021/ja005857a  1
2001 Szewczyk JW, Zuckerman RL, Bergman RG, Ellman JA. A Mass Spectrometric Labeling Strategy for High-Throughput Reaction Evaluation and Optimization: Exploring C-H Activation This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division, U.S. Department of Energy, under contract No. DE-AC03-76SF00098. We are grateful to the National Institutes of Health for support (GM-50353) and for a Postdoctoral Fellowship to J.W.S. Angewandte Chemie (International Ed. in English). 40: 216-219. PMID 11169717 DOI: 10.1002/1521-3773(20010105)40:1<216::AID-ANIE216>3.0.CO;2-K  1
2001 Klei SR, Tilley TD, Bergman RG. An observable silene/silylene rearrangement in a cationic iridium complex Organometallics. 20: 3220-3222. DOI: 10.1021/om010435a  1
2001 Ini S, Oliver AG, Tilley TD, Bergman RG. Synthesis, structure, and hydrosilylation catalysis of a chiral a-frame rhodium(I) dimer with cis diphosphite ligands Organometallics. 20: 3839-3841. DOI: 10.1021/om010428m  1
2001 Holland AW, Glueck DS, Bergman RG. Photochemical reactivity of group 9 metal pinacolate complexes Organometallics. 20: 2250-2261. DOI: 10.1021/om0010870  1
2001 Peterson TH, Golden JT, Bergman RG. Evidence for the intervention of different C-H activating intermediates in the irradiation of (η5-C5Me5)(PMe3) IrH2 and the reaction of (η5-C5Me5)(PMe3)Ir(H)(Cl) with strong base Journal of the American Chemical Society. 123: 455-462. DOI: 10.1021/ja0024993  1
2001 Paisner SN, Bergman RG. High performance liquid chromatography for facile analytical separation of the enantiomers of chiral organometallic complexes Journal of Organometallic Chemistry. 621: 242-245. DOI: 10.1016/S0022-328X(00)00862-7  1
2000 Fulton JR, Bouwkamp MW, Bergman RG. Reactivity of a parent amidoruthenium complex: a transition metal amide of exceptionally high basicity. Journal of the American Chemical Society. 122: 8799-800. PMID 16636699 DOI: 10.1021/ja001622n  1
2000 Zuckerman RL, Krska SW, Bergman RG. Zirconium-mediated metathesis of imines: a study of the scope, longevity, and mechanism of a complicated catalytic system. Journal of the American Chemical Society. 122: 751-61. PMID 16636698 DOI: 10.1021/ja992869r  1
2000 Sweeney ZK, Salsman JL, Andersen RA, Bergman RG. Synthesis of chiral, enantiopure zirconocene imido complexes: highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism. Angewandte Chemie (International Ed. in English). 39: 2339-43. PMID 10941084  1
2000 Sweeney ZK, Salsman JL, Andersen RA, Bergman RG. Cover Picture. Angewandte Chemie (International Ed. in English). 39: 2187. PMID 10941054 DOI: 10.1002/1521-3773(20000703)39:13<2187::AID-ANIE2187>3.0.CO;2-9  1
2000 Tellers DM, Bergman RG. C-H bond activation by a rare cationic iridium dinitrogen complex. An important electronic effect in the chemistry of the hydridotris(pyrazolyl)borate ligand [3] Journal of the American Chemical Society. 122: 954-955. DOI: 10.1021/ja993347e  0.76
2000 Klei SR, Tilley TD, Bergman RG. The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination [8] Journal of the American Chemical Society. 122: 1816-1817. DOI: 10.1021/ja992954z  1
2000 Sweeney ZK, Salsman JL, Andersen RA, Bergman RG. Synthesis of chiral, enantiopure zirconocene imido complexes: Highly selective kinetic resolution and stereoinversion of allenes, and evidence for a stepwise cycloaddition/retrocycloaddition reaction mechanism Angewandte Chemie - International Edition. 39: 2339-2343. DOI: 10.1002/1521-3773(20000703)39:13<2339::AID-ANIE2339>3.0.CO;2-W  1
1999 Sweeney ZK, Polse JL, Bergman RG, Andersen RA. Dihydrogen Activation by Titanium Sulfide Complexes. Organometallics. 18: 5502-5510. PMID 16633550 DOI: 10.1021/om9907876  1
1999 Tellers DM, Ritter JC, Bergman RG. Synthesis of Iridium(III) Carboxamides via the Bimetallic Reaction between Cp(PMe(3))IrPh(OH) and [Cp(PMe(3))Ir(Ph)NCR](+). Inorganic Chemistry. 38: 4810-4818. PMID 11671210 DOI: 10.1021/ic9907157  0.76
1999 McNamara BK, Yeston JS, Bergman RG, Moore CB. The effect of alkane structure on rates of photoinduced C-H bond activation by Cp*Rh(CO)2 in liquid rare gas media: An infrared flash kinetics study Journal of the American Chemical Society. 121: 6437-6443. DOI: 10.1021/ja9904282  0.52
1998 Krska SW, Zuckerman RL, Bergman RG. Use of steric hindrance and a metallacyclobutene resting state to develop robust and kinetically characterizable zirconium-based imine metathesis catalysts [17] Journal of the American Chemical Society. 120: 11828-11829. DOI: 10.1021/ja982569u  1
1998 Poise JL, Andersen RA, Bergman RG. Reactivity of a terminal Ti(IV) imido complex toward alkenes and alkynes: Cycloaddition vs C-H activation Journal of the American Chemical Society. 120: 13405-13414. DOI: 10.1021/ja981489n  1
1998 Kaplan AW, Polse JL, Ball GE, Andersen RA, Bergman RG. Synthesis, structure, and reactivity of η2-N2-aryldiazoalkane titanium complexes: Cleavage of the N-N bond Journal of the American Chemical Society. 120: 11649-11662. DOI: 10.1021/ja981340b  1
1998 Sweeney ZK, Polse JL, Andersen RA, Bergman RG. Cycloaddition and nucleophilic substitution reactions of the monomeric titanocene sulfido complex (η5-C5Me5)2(C5H5N)Ti=S Journal of the American Chemical Society. 120: 7825-7834. DOI: 10.1021/ja980877m  1
1998 Polse JL, Kaplan AW, Andersen RA, Bergman RG. Synthesis of an η2-N2-titanium diazoalkane complex with both imido- metal carbene-like reactivity patterns Journal of the American Chemical Society. 120: 6316-6328. DOI: 10.1021/ja974303d  1
1998 Golden JT, Peterson TH, Holland PL, Bergman RG, Andersen RA. Adduct formation and single and double deprotonation of Cp*(PMe3)Ir(H)2 with main group metal alkyls and aryls: Synthesis and structure of three novel Ir-Al and Ir-Mg heterobimetallics Journal of the American Chemical Society. 120: 223-224. DOI: 10.1021/ja973230v  1
1997 Bromberg SE, Yang H, Asplund MC, Lian T, McNamara BK, Kotz KT, Yeston JS, Wilkens M, Frei H, Bergman RG, Harris CB. The mechanism of a C-H bond activation reaction in room-temperature alkane solution Science. 278: 260-263. DOI: 10.1126/science.278.5336.260  1
1997 McNeill K, Andersen RA, Bergman RG. C-C and C-H bond activation at ruthenium(II): The stepwise degradation of a neopentyl ligand to a trimethylenemethane ligand Journal of the American Chemical Society. 119: 11244-11254. DOI: 10.1021/ja972131e  1
1997 Holland PL, Smith ME, Andersen RA, Bergman RG. X-ray crystal structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p- C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3 +]. Understanding distortions and trans influences in cyclopentadienyl complexes Journal of the American Chemical Society. 119: 12815-12823. DOI: 10.1021/ja971830o  1
1997 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric cyclopentadienylnickel methoxo and amido complexes: Synthesis, characterization, reactivity, and use for exploring the relationship between H-X and M-X bond energies Journal of the American Chemical Society. 119: 12800-12814. DOI: 10.1021/ja971829p  1
1996 Hanna TA, Baranger AM, Bergman RG. Reactivity of Zirconocene Azametallacyclobutenes: Insertion of Aldehydes, Carbon Monoxide, and Formation of alpha,beta-Unsaturated Imines. Formation and Trapping of [Cp(2)Zr=O] in a [4 + 2] Retrocycloaddition(1). The Journal of Organic Chemistry. 61: 4532-4541. PMID 11667377 DOI: 10.1021/jo9521561  0.68
1996 Polse JL, Andersen RA, Bergman RG. Synthesis, structure, and reactivity studies of an η2-N2-titanium diazoalkane complex. Generation and trapping of a carbene complex intermediate Journal of the American Chemical Society. 118: 8737-8738. DOI: 10.1021/ja9614981  1
1996 Lian T, Bromberg SE, Yang H, Proulx G, Bergman RG, Harris CB. Femtosecond IR studies of alkane C-H bond activation by organometallic compounds: Direct observation of reactive intermediates in room temperature solutions Journal of the American Chemical Society. 118: 3769-3770. DOI: 10.1021/ja9541591  1
1996 Luecke HF, Arndtsen BA, Burger P, Bergman RG. Synthesis of Fischer carbene complex of iridium by C-H bond activation of methyl and cyclic ethers: Evidence for reversible α-hydrogen migration Journal of the American Chemical Society. 118: 2517-2518. DOI: 10.1021/ja953437t  1
1996 Bromberg SE, Lian T, Bergman RG, Harris CB. Ultrafast dynamics of Cp*M(CO)2 (M = Ir, Rh) in solution: The origin of the low quantum yields for C-H bond activation Journal of the American Chemical Society. 118: 2069-2072. DOI: 10.1021/ja9531889  1
1996 Holland PL, Andersen RA, Bergman RG. Synthesis, characterization, isomerization, and reactivity of dimeric cyclopentadienylnickel amido complexes Journal of the American Chemical Society. 118: 1092-1104. DOI: 10.1021/ja952882l  1
1996 Tagge CD, Simpson RD, Bergman RG, Hosteller MJ, Girolami GS, Nuzzo RG. Synthesis of a novel volatile platinum complex for use in CVD and a study of the mechanism of its thermal decomposition in solution Journal of the American Chemical Society. 118: 2634-2643. DOI: 10.1021/ja9526527  1
1996 Lian T, Bromberg SE, Yang H, Asplund M, Bergman RG, Harris CB. Femtosecond IR studies of alkane C-H bond activation by organometallic compounds Springer Series in Chemical Physics. 62: 237-238.  1
1992 Wasserman EP, Moore CB, Bergman RG. Gas-Phase Rates of Alkane C-H Oxidative Addition to a Transient CpRh(CO) Complex. Science (New York, N.Y.). 255: 315-8. PMID 17779581 DOI: 10.1126/science.255.5042.315  0.52
1990 Hartwig JF, Bergman RG, Andersen RA. A phosphorus-carbon bond cleavage reaction of coordinated trimethylphosphine in (PMe3)4Ru(OC6H4Me)2 Journal of Organometallic Chemistry. 394: 417-432. DOI: 10.1016/0022-328X(90)87247-B  1
1988 Wasserman EP, Bergman RG, Moore CB. IR flash kinetic spectroscopy of transients generated by irradiation of cyclopentadienylcobalt dicarbonyl in the gas phase and in solution. Journal of the American Chemical Society. 110: 6076-84. PMID 22148784 DOI: 10.1021/ja00226a024  0.52
1988 Stoutland PO, Bergman RG, Nolan SP, Hoff CD. The thermodynamic driving force for CH activation at iridium Polyhedron. 7: 1429-1440. DOI: 10.1016/S0277-5387(00)81772-6  1
1987 Burkhardt ER, Doney JJ, Stack JG, Heathcock CH, Bergman RG. Formation of carbon-carbon bonds using organotransition metal enolate complexes Journal of Molecular Catalysis. 41: 41-57. DOI: 10.1016/0304-5102(87)80018-4  1
1985 Heathcock CH, Doney JJ, Bergman RG. Synthesis and carbon-carbon bond-forming reactions of tungsten, molybdenum, and rhenium enolates Pure and Applied Chemistry. 57: 1789-1798. DOI: 10.1351/pac198557121789  1
1984 Janowicz AH, Periana RA, Buchanan JM, Kovac CA, Stryker JM, Wax MJ, Bergman RG. Oxidative addition of soluble iridium and rhodium complexes to carbon-hydrogen bonds in methane and higher alkanes (1) Pure and Applied Chemistry. 56: 13-23. DOI: 10.1351/pac198456010013  1
1979 White MA, Bergman RG. Identification of binuclear acyl complexes as intermediates in the CO-induced conversion of [(η5-C5H5)Co(CO) (Me)]2 into acetone, and [(η5-C5H 5)Co(CO)(Et)]2 into pentan-3-one Journal of the Chemical Society, Chemical Communications. 1056-1058. DOI: 10.1039/C39790001056  1
1975 Turro NJ, Schuster GB, Bergman RG, Shea KJ, Davis JH. Mechanisms of energy storage and release. Chemiluminescent valence isomerizations. Evidence for a Dewar benzene intermediate in a biscyclopropenyl to benzene rearrangement Journal of the American Chemical Society. 97: 4758-4760. DOI: 10.1021/ja00849a050  0.44
1971 D'Amore MB, Bergman RG. Formation of 6-chlorofulvene from cyclopentadiene and dichlorocarbene Journal of the Chemical Society D: Chemical Communications. 461-462. DOI: 10.1039/C29710000461  1
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