John A. Gladysz - Publications

Affiliations: 
1974-1982 University of California, Los Angeles, Los Angeles, CA 
 1982-1998 University of Utah, Salt Lake City, UT 
 1998-2007 Friedrich-Alexander-Universität Erlangen-Nürnberg, Erlangen, Bavaria, Germany 
 2008- Texas A & M University, College Station, TX, United States 
Area:
organometallic chemistry
Website:
http://www.chem.tamu.edu/faculty/faculty_detail.php?ID=1570

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Year Citation  Score
2023 Zarcone SR, Bhuvanesh N, Gladysz JA. Molecules that Turn Themselves Inside-Out: Tuning in/out Equilibria and Homeomorphic Isomerization in Macrobicyclic Dibridgehead Diphosphines P((CH ) ) P Newly Accessible by Earth-Abundant-Metal Templates. Chemistry (Weinheim An Der Bergstrasse, Germany). e202302200. PMID 37738010 DOI: 10.1002/chem.202302200  0.368
2022 Zhu Y, Stollenz M, Zarcone SR, Kharel S, Joshi H, Bhuvanesh N, Reibenspies JH, Gladysz JA. Syntheses, homeomorphic and configurational isomerizations, and structures of macrocyclic aliphatic dibridgehead diphosphines; molecules that turn themselves inside out. Chemical Science. 13: 13368-13386. PMID 36507162 DOI: 10.1039/d2sc04724a  0.66
2022 Estrada AL, Wang L, Hess G, Hampel F, Gladysz JA. Square-Planar and Octahedral Gyroscope-Like Metal Complexes Consisting of Dipolar Rotators Encased in Dibridgehead Di(triaryl)phosphine Stators: Syntheses, Structures, Dynamic Properties, and Reactivity. Inorganic Chemistry. 61: 17012-17025. PMID 36264646 DOI: 10.1021/acs.inorgchem.2c02855  0.451
2022 Wititsuwannakul T, Hall MB, Gladysz JA. Mechanism of Coupling of Methylidene to Ethylene Ligands in Dimetallic Assemblies; Computational Investigation of a Model for a Key Step in Catalytic C Chemistry. Journal of the American Chemical Society. PMID 36174130 DOI: 10.1021/jacs.2c08886  0.59
2022 Zarcone SR, Verardi PJ, Bhuvanesh N, Gladysz JA. A surprise landing on the of macrocyclic dibridgehead diorganoarsines: syntheses, structures, and reactivities. Chemical Communications (Cambridge, England). 58: 8694-8697. PMID 35833414 DOI: 10.1039/d2cc03235j  0.442
2022 Estrada AL, Wititsuwannakul T, Kromm K, Hampel F, Hall MB, Gladysz JA. Syntheses, rearrangements, and structural analyses of unsaturated nitrogen donor ligands derived from diphenyldiazomethane and the chiral rhenium Lewis acid [(η-CH)Re(NO)(PPh)]. Dalton Transactions (Cambridge, England : 2003). PMID 35482287 DOI: 10.1039/d2dt00890d  0.611
2021 Zhu Y, Ehnbom A, Fiedler T, Shu Y, Bhuvanesh N, Hall MB, Gladysz JA. Platinum(II) alkyl complexes of chelating dibridgehead diphosphines P((CH))P ( = 14, 18, 22); facile / isomerizations interconverting gyroscope and parachute like adducts. Dalton Transactions (Cambridge, England : 2003). 50: 12457-12477. PMID 34545894 DOI: 10.1039/d1dt02321g  0.825
2021 Castillo Molina DA, Wititsuwannakul T, Hampel F, Hall MB, Gladysz JA. Syntheses, Structures, Reactivities, and Basicities of Quinolinyl and Isoquinolinyl Complexes of an Electron Rich Chiral Rhenium Fragment and Their Electrophilic Addition Products. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34228842 DOI: 10.1002/chem.202101949  0.61
2021 Collins BK, Clough Mastry M, Ehnbom A, Bhuvanesh N, Hall MB, Gladysz JA. Macrocyclic Complexes Derived from Four cis-L Pt Corners and Four Butadiynediyl Linkers; Syntheses, Electronic Structures, and Square versus Skew Rhombus Geometries. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34114260 DOI: 10.1002/chem.202100305  0.814
2021 Ehnbom A, Gladysz JA. Gyroscopes and the Chemical Literature, 2002-2020: Approaches to a Nascent Family of Molecular Devices. Chemical Reviews. PMID 33635066 DOI: 10.1021/acs.chemrev.0c01001  0.703
2021 Zarcone SR, Chu GM, Ehnbom A, Cardenal A, Fiedler T, Bhuvanesh N, Hall MB, Gladysz JA. Toward Frameworks with Multiple Aligned and Interactive Fe(CO) Rotators: Syntheses and Structures of Diiron Complexes Linked by Two -Diaxial α,ω-Diphosphine Ligands ArP(CH)PAr. Inorganic Chemistry. PMID 33571407 DOI: 10.1021/acs.inorgchem.0c03737  0.793
2020 Wegener AR, Kabes CQ, Gladysz JA. Launching Werner Complexes into the Modern Era of Catalytic Enantioselective Organic Synthesis. Accounts of Chemical Research. PMID 32886471 DOI: 10.1021/Acs.Accounts.0C00410  0.393
2020 Alimohammadi M, Hasaninejad A, Luu QH, Gladysz JA. Λ-[Co((,)-dpen)] 2IB(CF): A Second Generation Air- and Water-Stable Chiral Solvating Agent for Chirality Sensing (dpen = NHCHPhCHPhNH). The Journal of Organic Chemistry. PMID 32663026 DOI: 10.1021/Acs.Joc.0C01332  0.36
2020 Luu QH, Gladysz JA. An Air and Water Stable Hydrogen Bond Donor Catalyst for the Enantioselective Generation of Quarternary Carbon Stereocenters by Additions of Substituted Cyanoacetate Esters to Acetylenic Esters. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32428297 DOI: 10.1002/Chem.202001639  0.367
2020 Maximuck WJ, Ganzmann C, Alvi S, Hooda KR, Gladysz JA. Rendering classical hydrophilic enantiopure Werner salts [M(en)]nX lipophilic (M/n = Cr/3, Co/3, Rh/3, Ir/3, Pt/4); new chiral hydrogen bond donor catalysts and enantioselectivities as a function of metal and charge. Dalton Transactions (Cambridge, England : 2003). PMID 32124905 DOI: 10.1039/D0Dt00523A  0.41
2020 Kabes CQ, Gunn JH, Selbst MA, Lucas RF, Gladysz JA. Syntheses of Enantiopure 1,2-Ethylenediamines with Tethered Secondary Amines of the Formula H2NCH2CH[(CH2) n NHMe]NH2 (n = 1–4) from α-Amino Acids: New Agents for Asymmetric Catalysis Synthesis. DOI: 10.1055/S-0040-1707146  0.447
2020 Kabes CQ, Maximuck WJ, Ghosh SK, Kumar A, Bhuvanesh N, Gladysz JA. Chiral Tricationic Tris(1,2-diphenylethylenediamine) Cobalt(III) Hydrogen Bond Donor Catalysts with Defined Carbon/Metal Configurations; Matched/Mismatched Effects upon Enantioselectivities with Enantiomeric Chiral Counter Anions Acs Catalysis. 10: 3249-3263. DOI: 10.1021/Acscatal.9B05496  0.37
2020 Mukherjee T, Ghosh SK, Wititsuwannakul T, Bhuvanesh N, Gladysz JA. Chiral-at-Metal Ruthenium Complexes with Guanidinobenzimidazole and Pentaphenylcyclopentadienyl Ligands: Synthesis, Resolution, and Preliminary Screening as Enantioselective Second Coordination Sphere Hydrogen Bond Donor Catalysts Organometallics. 39: 1163-1175. DOI: 10.1021/Acs.Organomet.0C00073  0.742
2020 Wititsuwannakul T, Mukherjee T, Hall MB, Gladysz JA. Computational Investigations of Enantioselection in Carbon–Carbon Bond Forming Reactions of Ruthenium Guanidinobenzimidazole Second Coordination Sphere Hydrogen Bond Donor Catalysts Organometallics. 39: 1149-1162. DOI: 10.1021/Acs.Organomet.0C00072  0.814
2020 Wititsuwannakul T, Hall MB, Gladysz JA. A computational study of hydrogen bonding motifs in halide, tetrafluoroborate, hexafluorophosphate, and tetraarylborate salts of chiral cationic ruthenium and cobalt guanidinobenzimidazole hydrogen bond donor catalysts; acceptor properties of the “BArf” anion Polyhedron. 187: 114618. DOI: 10.1016/J.Poly.2020.114618  0.595
2019 Gladysz JA, Amini H, Baranová Z, Weisbach N, Gauthier S, Bhuvanesh N, Reibenspies J. Syntheses, Structures, and Spectroscopic Properties of 1,10-Phenanthroline Based Macrocycles threaded by PtC8Pt, PtC12Pt, and PtC16Pt Axles: Metal-capped Rotaxanes as Insulated Molecular Wires. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31596000 DOI: 10.1002/Chem.201903927  0.434
2019 Bluemel J, Gladysz J, Kharel S, Cluff K, Bhuvanesh N. Structures and Dynamics of Secondary and Tertiary Alkylphosphine Oxides Adsorbed on Silica. Chemistry, An Asian Journal. PMID 31168965 DOI: 10.1002/Asia.201900632  0.495
2019 Zheng Q, Schneider JF, Amini H, Hampel F, Gladysz JA. Wire like diplatinum, triplatinum, and tetraplatinum complexes featuring X[PtC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]CC[triple bond, length as m-dash]C]PtX segments; iterative syntheses and functionalization for measurements of single molecule properties. Dalton Transactions (Cambridge, England : 2003). PMID 30977490 DOI: 10.1039/C9Dt00870E  0.36
2019 Ehnbom A, Hall MB, Gladysz JA. Origin of Shielding and Deshielding Effects in NMR Spectra of Organic Conjugated Polyynes. Organic Letters. PMID 30657692 DOI: 10.1021/Acs.Orglett.8B03990  0.765
2019 Weisbach N, Kuhn H, Amini H, Ehnbom A, Hampel F, Reibenspies JH, Hall MB, Gladysz JA. Triisopropylsilyl (TIPS) Alkynes as Building Blocks for Syntheses of Platinum Triisopropylsilylpolyynyl and Diplatinum Polyynediyl Complexes Organometallics. 38: 3294-3310. DOI: 10.1021/Acs.Organomet.9B00368  0.786
2019 Stollenz M, Joshi H, Ehnbom A, Fiedler T, Kharel S, Reibenspies JH, Bhuvanesh N, Hall MB, Gladysz JA. Platinum complexes containing or derived from olefinic phosphines P(X)((CH2)6CH CH2)2 (X = OH, Ph, (CH2)6CH CH2); ring closing metatheses, structures, and trans/cis isomerizations Polyhedron. 158: 325-333. DOI: 10.1016/J.Poly.2018.09.025  0.84
2019 Maximuck WJ, Gladysz JA. Lipophilic chiral cobalt (III) complexes of hexaamine ligands: Efficacies as enantioselective hydrogen bond donor catalysts Molecular Catalysis. 473: 110360. DOI: 10.1016/J.Mcat.2019.03.018  0.444
2019 Kharel S, Bhuvanesh N, Gladysz JA, Blümel J. New hydrogen bonding motifs of phosphine oxides with a silanediol, a phenol, and chloroform Inorganica Chimica Acta. 490: 215-219. DOI: 10.1016/J.Ica.2019.03.019  0.366
2018 Fiedler T, Barbasiewicz M, Stollenz M, Gladysz JA. Non-metal-templated approaches to bis(borane) derivatives of macrocyclic dibridgehead diphosphines via alkene metathesis. Beilstein Journal of Organic Chemistry. 14: 2354-2365. PMID 30254700 DOI: 10.3762/Bjoc.14.211  0.526
2018 Luu QH, Lewis KG, Banerjee A, Bhuvanesh N, Gladysz JA. The robust, readily available cobalt(iii) trication [Co(NHCHPhCHPhNH)] is a progenitor of broadly applicable chirality and prochirality sensing agents. Chemical Science. 9: 5087-5099. PMID 29938040 DOI: 10.1039/C8Sc01510D  0.374
2018 Gladysz JA, Kharel S, Jia T, Bhuvanesh N, Reibenspies J, Blümel J. A Non-Templated Route to Macrocyclic Dibridgehead Diphosphorus Compounds: Crystallographic Characterization of a "Crossed Chain" Variant of in/out Stereoisomers. Chemistry, An Asian Journal. PMID 29870152 DOI: 10.1002/Asia.201800739  0.492
2018 Joshi H, Kharel S, Ehnbom A, Skopek K, Hess GD, Fiedler T, Hampel F, Bhuvanesh N, Gladysz JA. Three Fold Intramolecular Ring Closing Alkene Metatheses of Square Planar Complexes with cis Phosphorus Donor Ligands P(X(CH) CH=CH) (X/ m = -/5-10, O/3-5); Syntheses, Structures, and Thermal Properties of Macrocyclic Dibridgehead Diphosphorus Complexes. Journal of the American Chemical Society. PMID 29708746 DOI: 10.1021/Jacs.8B02846  0.841
2018 Ghosh SK, Cummins CC, Gladysz JA. A direct route from white phosphorus and fluorous alkyl and aryl iodides to the corresponding trialkyl- and triarylphosphines Organic Chemistry Frontiers. 5: 3421-3429. DOI: 10.1039/C8Qo00943K  0.328
2018 Kharel S, Joshi H, Bhuvanesh N, Gladysz JA. Syntheses, Structures, and Thermal Properties of Gyroscope-like Complexes Consisting of PtCl2 Rotators Encased in Macrocyclic Dibridgehead Diphosphines P((CH2)n)3P with Extended Methylene Chains (n = 20/22/30) and Isomers Thereof Organometallics. 37: 2991-3000. DOI: 10.1021/Acs.Organomet.8B00345  0.467
2018 Joshi H, Kharel S, Bhuvanesh N, Gladysz JA. Synthesis, structure, and reactivity of doubly trans-spanning bis(dialkyl selenide) complexes; a new route to diselenamacrocycles via alkene metathesis in metal coordination spheres Journal of Organometallic Chemistry. 875: 80-87. DOI: 10.1016/J.Jorganchem.2018.08.029  0.558
2018 Gladysz JA. Reaction: Toward Organic-Solvent-free Synthetic Chemistry Chem. 4: 2007-2008. DOI: 10.1016/J.Chempr.2018.08.026  0.305
2017 Mukherjee T, Biswas S, Ehnbom A, Ghosh SK, El-Zoghbi I, Bhuvanesh N, Bazzi HS, Gladysz JA. Syntheses, structures, and stabilities of aliphatic and aromatic fluorous iodine(I) and iodine(III) compounds: the role of iodine Lewis basicity. Beilstein Journal of Organic Chemistry. 13: 2486-2501. PMID 29234476 DOI: 10.3762/Bjoc.13.246  0.823
2017 Hess GD, Fiedler T, Hampel F, Gladysz JA. Octahedral Gyroscope-like Molecules Consisting of Rhenium Rotators within Cage-like Dibridgehead Diphosphine Stators: Syntheses, Substitution Reactions, Structures, and Dynamic Properties. Inorganic Chemistry. PMID 28598610 DOI: 10.1021/Acs.Inorgchem.7B00909  0.454
2017 Ghosh SK, Lewis KG, Kumar A, Gladysz JA. Syntheses of Families of Enantiopure and Diastereopure Cobalt Catalysts Derived from Trications of the Formula [Co(NH2CHArCHArNH2)3](3). Inorganic Chemistry. PMID 28177614 DOI: 10.1021/Acs.Inorgchem.6B03042  0.368
2017 Kharel S, Joshi H, Bierschenk S, Stollenz M, Taher D, Bhuvanesh N, Gladysz JA. Homeomorphic Isomerization as a Design Element in Con-tainer Molecules; Binding, Displacement, and Selective Transport of MCl2 Species (M = Pt, Pd, Ni). Journal of the American Chemical Society. PMID 28075127 DOI: 10.1021/Jacs.6B12788  0.67
2017 Baranová Z, Amini H, Neupane M, Garrett SC, Ehnbom A, Bhuvanesh N, Reibenspies JH, Gladysz JA. Syntheses, Structural Studies, and Copper Iodide Complexes of Macrocycles Derived from Williamson Ether Syntheses Involving 2,9-Bis(4-hydroxyphenyl)-1,10-phenanthroline, α,ω-Dibromides, and Resorcinol or 2,7-Dihydroxynaphthalene Australian Journal of Chemistry. 70: 373. DOI: 10.1071/Ch16587  0.768
2017 Joshi H, Ghosh S, Gladysz J. Enantioselective Additions of Stabilized Carbanions to Imines Generated from α-Amido Sulfones By Using Lipophilic Salts of Chiral Tris(1,2-diphenylethylenediamine) Cobalt(III) Trications as Hydrogen Bond Donor Catalysts Synthesis. 49: 3905-3915. DOI: 10.1055/S-0036-1590502  0.39
2017 Dinh LV, Jurisch M, Fiedler T, Gladysz JA. Recycling and Delivery of Homogeneous Fluorous Rhodium Catalysts Using Poly(tetrafluoroethylene): “Catalyst-on-a-Tape” Acs Sustainable Chemistry & Engineering. 5: 10875-10888. DOI: 10.1021/Acssuschemeng.7B02770  0.766
2017 Steigleder E, Shima T, Lang GM, Ehnbom A, Hampel F, Gladysz JA. Partially Shielded Fe(CO)3 Rotors: Syntheses, Structures, and Dynamic Properties of Complexes with Doubly trans Spanning Diphosphines, trans-Fe(CO)3(PhP((CH2)n)2PPh) Organometallics. 36: 2891-2901. DOI: 10.1021/Acs.Organomet.7B00330  0.812
2017 Dey S, Zhang T, Bhuvanesh N, Gladysz JA. Syntheses and structures of square planar diplatinum butadiynediyl complexes with two different monophosphine ligands on each terminus; probing the feasibility of a new type of inorganic atropisomerism ☆ ☆☆ Journal of Organometallic Chemistry. 849: 237-255. DOI: 10.1016/J.Jorganchem.2017.05.006  0.392
2017 Ghosh SK, Ehnbom A, Lewis KG, Gladysz JA. Hydrogen bonding motifs in structurally characterized salts of the tris(ethylenediamine) cobalt trication, [Co(en)3]3+; An interpretive review, including implications for catalysis Coordination Chemistry Reviews. 350: 30-48. DOI: 10.1016/J.Ccr.2017.04.002  0.747
2017 Zhang T, Bhuvanesh N, Gladysz JA. A Quest for Atropisomerism in Cojoined Square-Planar Metal Complexes: Synthesis and Structures of Sterically Congested Diplatinum Ethynediyl Adducts European Journal of Inorganic Chemistry. 2017: 1017-1025. DOI: 10.1002/Ejic.201601307  0.347
2016 Ehnbom A, Ghosh SK, Lewis KG, Gladysz JA. Octahedral Werner complexes with substituted ethylenediamine ligands: a stereochemical primer for a historic series of compounds now emerging as a modern family of catalysts. Chemical Society Reviews. PMID 27761532 DOI: 10.1039/C6Cs00604C  0.774
2016 Su HL, Balogh J, Al-Hashimi M, Seapy DG, Bazzi HS, Gladysz JA. Convenient protocols for Mizoroki-Heck reactions of aromatic bromides and polybromides with fluorous alkenes of the formula H2C[double bond, length as m-dash]CH(CF2)n-1CF3 (n = 8, 10). Organic & Biomolecular Chemistry. PMID 27722453 DOI: 10.1039/C6Ob01980C  0.415
2016 Lang GM, Skaper D, Hampel F, Gladysz JA. Synthesis, reactivity, structures, and dynamic properties of gyroscope like iron complexes with dibridgehead diphosphine cages: pre- vs. post-metathesis substitutions as routes to adducts with neutral dipolar Fe(CO)(NO)(X) rotors. Dalton Transactions (Cambridge, England : 2003). PMID 27722339 DOI: 10.1039/C6Dt03258C  0.503
2016 Lang GM, Shima T, Wang L, Cluff KJ, Skopek K, Hampel F, Bluemel J, Gladysz JA. Gyroscope Like Complexes based upon Dibridgehead Diphosphine Cages that are Accessed by Three Fold Intramolecular Ring Closing Metatheses and Encase Fe(CO)3, Fe(CO)2(NO)(+) and Fe(CO)3(H)(+) Rotators. Journal of the American Chemical Society. PMID 27203383 DOI: 10.1021/Jacs.6B03178  0.492
2016 Fiedler T, Bhuvanesh N, Hampel F, Reibenspies JH, Gladysz JA. Gyroscope like molecules consisting of trigonal or square planar osmium rotators within three-spoked dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties. Dalton Transactions (Cambridge, England : 2003). PMID 27007878 DOI: 10.1039/C6Dt00692B  0.502
2016 Ghosh SK, Ganzmann C, Bhuvanesh N, Gladysz JA. Werner Complexes with ω-Dimethylaminoalkyl Substituted Ethylenediamine Ligands: Bifunctional Hydrogen-Bond-Donor Catalysts for Highly Enantioselective Michael Additions. Angewandte Chemie (International Ed. in English). PMID 26918320 DOI: 10.1002/Anie.201511314  0.538
2016 Kumar A, Ghosh SK, Gladysz JA. Tris(1,2-diphenylethylenediamine)cobalt(III) Complexes: Chiral Hydrogen Bond Donor Catalysts for Enantioselective α-Aminations of 1,3-Dicarbonyl Compounds. Organic Letters. PMID 26820242 DOI: 10.1021/Acs.Orglett.6B00023  0.36
2016 Lang GM, Bhuvanesh N, Reibenspies JH, Gladysz JA. Syntheses, Reactivity, Structures, and Dynamic Properties of Gyroscope-like Iron Carbonyl Complexes Based on Dibridgehead Diarsine Cages Organometallics. 35: 2873-2889. DOI: 10.1021/Acs.Organomet.6B00447  0.509
2016 Fiedler T, Chen L, Wagner ND, Russell DH, Gladysz JA. Gas and Liquid Phase Diffusivities of Isomeric Metal Complexes Derived from Multifold Ring-Closing Metatheses: Ion Mobility Mass Spectrometry Trumps DOSY NMR Organometallics. 35: 2071-2075. DOI: 10.1021/Acs.Organomet.6B00249  0.451
2016 Taher D, Nawara-Hultzsch AJ, Bhuvanesh N, Hampel F, Gladysz JA. Mono- and disubstitution reactions of gyroscope like complexes derived from Cl Pt Cl rotators within cage like dibridgehead diphosphine ligands Journal of Organometallic Chemistry. 821: 136-141. DOI: 10.1016/J.Jorganchem.2016.03.022  0.493
2016 Balogh J, Hlil AR, Su HL, Xi Z, Bazzi HS, Gladysz JA. An Analogue of Grubbs Third-Generation Catalyst with Fluorophilic Pyridine Ligands: Fluorous/Organic Phase-Transfer Activation of Ring-Closing Alkene Metathesis Chemcatchem. 8: 125-128. DOI: 10.1002/Cctc.201500913  0.305
2015 Lewis KG, Ghosh SK, Bhuvanesh N, Gladysz JA. Cobalt(III) Werner Complexes with 1,2-Diphenylethylenediamine Ligands: Readily Available, Inexpensive, and Modular Chiral Hydrogen Bond Donor Catalysts for Enantioselective Organic Synthesis. Acs Central Science. 1: 50-6. PMID 27162946 DOI: 10.1021/Acscentsci.5B00035  0.43
2015 Stollenz M, Taher D, Bhuvanesh N, Reibenspies JH, Baranová Z, Gladysz JA. Steric control of the in/out sense of bridgehead substituents in macrobicyclic compounds: isolation of new "crossed chain" variants of in/out isomers. Chemical Communications (Cambridge, England). 51: 16053-6. PMID 26345176 DOI: 10.1039/C5Cc05620A  0.503
2015 Tuba R, Xi Z, Bazzi HS, Gladysz JA. Phase-Transfer Activation of Transition Metal Catalysts. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26338471 DOI: 10.1002/Chem.201502403  0.302
2015 Xi Z, Bazzi HS, Gladysz JA. Activation of Single-Component Nickel(II) Polyethylene Catalysts via Phase Transfer of Fluorous Phosphine Ligands. Journal of the American Chemical Society. 137: 10930-3. PMID 26300472 DOI: 10.1021/Jacs.5B06562  0.461
2015 Zhang CP, Xi Z, Mueller KM, Holliday BJ, Bazzi HS, Gladysz JA. Phase and redox shifted four iron/four sulfur clusters: fluorous analogs of metalloenzyme cofactors. Dalton Transactions (Cambridge, England : 2003). PMID 26223369 DOI: 10.1039/C5Dt01959A  0.508
2015 Lang GM, Skaper D, Shima T, Otto M, Wang L, Gladysz JA. Syntheses of Iron(0) Complexes of Symmetrical Trialkylphosphines with Three Terminal Vinyl Groups, P((CH2)mCH=CH2)3 Australian Journal of Chemistry. 68: 1342-1351. DOI: 10.1071/Ch15178  0.522
2015 Ghosh SK, Ganzmann C, Gladysz JA. Synthesis of a series of ω-dimethylaminoalkyl substituted ethylenediamine ligands for use in enantioselective catalysis Tetrahedron Asymmetry. 26: 1273-1280. DOI: 10.1016/J.Tetasy.2015.09.012  0.398
2015 Clough MC, Fiedler T, Bhuvanesh N, Gladysz JA. A phase based approach to insulated molecular wires: Diplatinum octatetraynediyl complexes bearing fluorous trialkylphosphine ligands Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.09.020  0.52
2015 Estrada AL, Jia T, Bhuvanesh N, Blümel J, Gladysz JA. Substitution and Catalytic Chemistry of Gyroscope-Like Complexes Derived from Cl-Rh-CO Rotators and Triply trans Spanning Di(trialkylphosphine) Ligands European Journal of Inorganic Chemistry. 2015: 5318-5321. DOI: 10.1002/Ejic.201500953  0.511
2014 Nawara-Hultzsch AJ, Stollenz M, Barbasiewicz M, Szafert S, Lis T, Hampel F, Bhuvanesh N, Gladysz JA. Gyroscope-like molecules consisting of PdX₂/PtX₂ rotators within three-spoke dibridgehead diphosphine stators: syntheses, substitution reactions, structures, and dynamic properties. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 4617-37. PMID 24604783 DOI: 10.1002/Chem.201304419  0.529
2014 Xi Z, Bazzi HS, Gladysz JA. Liquid/solid phase transfer activation of Grubbs-type alkene metathesis catalysts; Application of silver salts of sulfonated polystyrene Catalysis Science and Technology. 4: 4178-4182. DOI: 10.1039/C4Cy01021C  0.445
2014 Baranová Z, Amini H, Bhuvanesh N, Gladysz JA. Rotaxanes derived from dimetallic polyynediyl complexes: Extended axles and expanded macrocycles Organometallics. 33: 6746-6749. DOI: 10.1021/Om501026U  0.517
2014 Gladysz JA. Award-Winning Organometallic Chemistry:1 The 2013 Robert Robinson Award of the RSC Organometallics. 33: 5911-5911. DOI: 10.1021/Om5009764  0.307
2014 Mukherjee T, Ganzmann C, Bhuvanesh N, Gladysz JA. Syntheses of enantiopure bifunctional 2-guanidinobenzimidazole cyclopentadienyl ruthenium complexes: Highly enantioselective organometallic hydrogen bond donor catalysts for carbon-carbon bond forming reactions Organometallics. 33: 6723-6737. DOI: 10.1021/Om500705S  0.813
2014 Scherer A, Mukherjee T, Hampel F, Gladysz JA. Metal-templated hydrogen bond donors as "organocatalysts" for carbon-carbon bond forming reactions: Syntheses, structures, and reactivities of 2-guanidinobenzimidazole cyclopentadienyl ruthenium complexes Organometallics. 33: 6709-6722. DOI: 10.1021/Om500704U  0.818
2014 Gladysz JA. Award-Winning organometallic chemistry:1 the 2013 RSC Sir Edward Frankland Fellowship Organometallics. 33: 1083. DOI: 10.1021/Om500163V  0.317
2014 Gladysz JA, Liebeskind LS. Editors' Comments on the addition/correction to " Synthesis, structure, and catalytic studies of palladium and platinum bis-sulfoxide complexes " Organometallics. 33: 607. DOI: 10.1021/Om401186Q  0.373
2014 Thomas C, Gladysz JA. Highly active families of catalysts for the ring-opening polymerization of lactide: Metal templated organic hydrogen bond donors derived from 2-Guanidinobenzimidazole Acs Catalysis. 4: 1134-1138. DOI: 10.1021/Cs500134Z  0.417
2014 Sierra D, Bhuvanesh N, Reibenspies JH, Gladysz JA, Klahn AH. Syntheses, structures, and reactions of cyrhetrenylphosphines; Applications in palladium catalyzed Suzuki cross-coupling reactions Journal of Organometallic Chemistry. 749: 416-420. DOI: 10.1016/J.Jorganchem.2013.10.029  0.359
2013 Ghosh SK, Ojeda AS, Guerrero-Leal J, Bhuvanesh N, Gladysz JA. New media for classical coordination chemistry: phase transfer of Werner and related polycations into highly nonpolar fluorous solvents. Inorganic Chemistry. 52: 9369-78. PMID 23895404 DOI: 10.1021/Ic400945U  0.459
2013 Chen LD, Lai CZ, Granda LP, Fierke MA, Mandal D, Stein A, Gladysz JA, Bühlmann P. Fluorous membrane ion-selective electrodes for perfluorinated surfactants: trace-level detection and in situ monitoring of adsorption. Analytical Chemistry. 85: 7471-7. PMID 23789785 DOI: 10.1021/Ac401424J  0.329
2013 Gladysz JA. Correction to Award-Winning Organometallic Chemistry:1 The 2013 Yao Zeng Award in Organometallic Chemistry Organometallics. 33: 437-437. DOI: 10.1021/Om401218W  0.324
2013 Gladysz JA. Award-winning organometallic chemistry:1 the 2013 Yao Zeng Award in organometallic chemistry Organometallics. 32: 6851. DOI: 10.1021/Om401106T  0.334
2013 Gladysz JA. Award-winning organometallic chemistry:1 the 2012 RSC sir geoffrey wilkinson award Organometallics. 32: 5243. DOI: 10.1021/Om400973S  0.31
2013 Gladysz JA. Award-Winning Organometallic Chemistry: The 2011 RSC Organometallic Chemistry Award (and More) Organometallics. 32: 941-941. DOI: 10.1021/Om400058X  0.333
2012 Tuba R, Brothers EN, Reibenspies JH, Bazzi HS, Gladysz JA. Crystal structure and computational investigation of an analogue of Grubbs' second generation catalyst with a fluorous phosphine. Inorganic Chemistry. 51: 9943-9. PMID 22954330 DOI: 10.1021/Ic301434G  0.438
2012 Zeits PD, Fiedler T, Gladysz JA. Ring opening metathesis polymerization of an η4-benzene complex: a direct synthesis of a polyacetylene with a regular pattern of π bound metal fragments. Chemical Communications (Cambridge, England). 48: 7925-7. PMID 22763578 DOI: 10.1039/C2Cc32150E  0.805
2012 Weisbach N, Baranová Z, Gauthier S, Reibenspies JH, Gladysz JA. A new type of insulated molecular wire: a rotaxane derived from a metal-capped conjugated tetrayne. Chemical Communications (Cambridge, England). 48: 7562-4. PMID 22728819 DOI: 10.1039/C2Cc33321J  0.366
2012 Gladysz JA. Award-Winning Organometallic Chemistry: The Centennial Sacconi Medal Organometallics. 31: 7029-7030. DOI: 10.1021/Om3008822  0.326
2012 Clough MC, Zeits PD, Bhuvanesh N, Gladysz JA. Toward permetalated alkyne/azide 3 + 2 or "click" cycloadducts Organometallics. 31: 5231-5234. DOI: 10.1021/Om300542A  0.821
2012 Zeits PD, Rachiero GP, Hampel F, Reibenspies JH, Gladysz JA. Gyroscope-like platinum and palladium complexes with trans-spanning bis(pyridine) ligands Organometallics. 31: 2854-2877. DOI: 10.1021/Om201145X  0.832
2012 Tuba R, Corrêa Da Costa R, Bazzi HS, Gladysz JA. Phase transfer activation of fluorous analogs of Grubbs second-generation catalyst: Ring-opening metathesis polymerization Acs Catalysis. 2: 155-162. DOI: 10.1021/Cs200487J  0.439
2011 Chen LD, Mandal D, Pozzi G, Gladysz JA, Bühlmann P. Potentiometric sensors based on fluorous membranes doped with highly selective ionophores for carbonate. Journal of the American Chemical Society. 133: 20869-77. PMID 22070518 DOI: 10.1021/Ja207680E  0.328
2011 Xi Z, Bazzi HS, Gladysz JA. Analogs of Grubbs' second generation catalyst with hydrophilic phosphine ligands: phase transfer activation of ring closing alkene metathesis. Organic Letters. 13: 6188-91. PMID 22066500 DOI: 10.1021/Ol202548Q  0.521
2011 Stollenz M, Barbasiewicz M, Nawara-Hultzsch AJ, Fiedler T, Laddusaw RM, Bhuvanesh N, Gladysz JA. Dibridgehead diphosphines that turn themselves inside out. Angewandte Chemie (International Ed. in English). 50: 6647-51. PMID 21638522 DOI: 10.1002/Anie.201100893  0.465
2011 Stollenz M, Bhuvanesh N, Reibenspies JH, Gladysz JA. Syntheses and structures of digold complexes of macrobicyclic dibridgehead diphosphines that can turn themselves inside out Organometallics. 30: 6510-6513. DOI: 10.1021/Om200924G  0.364
2011 Gladysz JA. Award-winning organometallic chemistry and the Adolf-von-Baeyer- denkmünze of the GDCh Organometallics. 30: 357. DOI: 10.1021/Om101203C  0.328
2011 Kirillov E, Marquet N, Bader M, Razavi A, Belia V, Hampel F, Roisnel T, Gladysz JA, Carpentier JF. Chiral-at- ansa -bridged group 4 metallocene complexes {(R 1R2C)-(3,6- T Bu2Flu)(3-R3-5-Me- C5H2)}MCl2: Synthesis, structure, stereochemistry, and use in highly isoselective propylene polymerization Organometallics. 30: 263-272. DOI: 10.1021/Om100897J  0.409
2010 Owen GR, Gauthier S, Weisbach N, Hampel F, Bhuvanesh N, Gladysz JA. Towards multistranded molecular wires: syntheses, structures, and reactivities of tetraplatinum bis(polyynediyl) complexes with [upper bond 1 start]Pt-C(x)-Pt-(P(CH2)3P)2-Pt-C(x)-Pt-(P(CH2)3P[upper bond 1 end])2 cores (x = 4, 6, 8). Dalton Transactions (Cambridge, England : 2003). 39: 5260-71. PMID 20454708 DOI: 10.1039/C002041A  0.422
2010 Nawara-Hultzsch AJ, Skopek K, Shima T, Barbasiewicz M, Hess GD, Skaper D, Gladysz JA. Syntheses and palladium, platinum, and borane adducts of symmetrical trialkylphosphines with three terminal vinyl groups, P((CH2) mCH=CH2)3 Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 65: 414-424. DOI: 10.1515/Znb-2010-0327  0.49
2010 Chen LD, Mandal D, Gladysz JA, Bühlmann P. Chemical stability and application of a fluorophilic tetraalkylphosphonium salt in fluorous membrane anion-selective electrodes New Journal of Chemistry. 34: 1867-1874. DOI: 10.1039/B9Nj00696F  0.355
2010 Gladysz JA, Bochmann M, Lichtenberger DL, Liebeskind LS, Marks TJ, Sweigart DA. Another great day for organometallic chemistry Organometallics. 29: 5737. DOI: 10.1021/Om101007R  0.321
2010 Han J, Deng C, Fang R, Zhao D, Wang L, Gladysz JA. Square-planar palladium complexes with trans Di-and tribenzylphosphine ligands bearing O(CH2)4CH=CH2 substituents; Two-and three-fold intramolecular ring-closing metatheses Organometallics. 29: 3231-3234. DOI: 10.1021/Om100536G  0.479
2010 Gladysz JA. Organometallics-quo vadis? Organometallics. 29: 2385. DOI: 10.1021/Om100455F  0.329
2010 Kirillov E, Marquet N, Razavi A, Belia V, Hampel F, Roisnel T, Gladysz JA, Carpentier JF. New C1-symmetric Ph2C-bridged multisubstituted ansa-zirconocenes for highly isospecific propylene polymerization: Synthetic approach via activated fulvenes Organometallics. 29: 5073-5082. DOI: 10.1021/Om100289Y  0.376
2010 Gimbert C, Vallribera A, Gladysz JA, Jurisch M. Thermomorphic fluorous phosphines as organocatalysts for Michael addition reactions Tetrahedron Letters. 51: 4662-4665. DOI: 10.1016/J.Tetlet.2010.06.136  0.41
2010 Mandal D, Gladysz JA. Syntheses of fluorous quaternary ammonium salts and their application as phase transfer catalysts for halide substitution reactions in extremely nonpolar fluorous solvents Tetrahedron. 66: 1070-1077. DOI: 10.1016/J.Tet.2009.11.012  0.486
2010 Seidel SN, Prommesberger M, Eichenseher S, Meyer O, Hampel F, Gladysz JA. Syntheses and structural analyses of chiral rhenium containing amines of the formula (η5-C5H5)Re(NO)(PPh3)((CH2)nNRR′) (n = 0, 1) Inorganica Chimica Acta. 363: 533-548. DOI: 10.1016/J.Ica.2009.03.047  0.537
2010 Dinh LV, Gladysz JA. ChemInform Abstract: Transition Metal Catalysis in Fluorous Media: Extension of a New Immobilization Principle to Biphasic and Monophasic Rhodium-Catalyzed Hydrosilylations of Ketones and Enones. Cheminform. 31: no-no. DOI: 10.1002/chin.200011063  0.721
2010 WANG Y, GLADYSZ JA. ChemInform Abstract: Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+. Enantioselective Syntheses of 3-Substituted Cycloalkanones. Cheminform. 26: no-no. DOI: 10.1002/chin.199532041  0.42
2010 DALTON DM, GARNER CM, FERNANDEZ JM, GLADYSZ JA. ChemInform Abstract: A New Asymmetric Synthesis of Cyanohydrins and Oxygen-Functionalized Derivatives: Stereoselective Addition of Cyanide to Chiral Rhenium Aldehyde and Ketone Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3) (O=CRR′))+BF4-. Cheminform. 23: no-no. DOI: 10.1002/chin.199218059  0.645
2010 PENG T, GLADYSZ JA. ChemInform Abstract: Regiospecific, Diastereospecific, and Enantiospecific Nucleophilic Additions of Chiral Monosubstituted Alkene Complexes of the Formula ((. eta.5-C5H5)-Re-(NO)(PPh3)(H2C=CHR))+ BF4-. Cheminform. 22: no-no. DOI: 10.1002/chin.199140210  0.444
2010 LEE KE, ARIF AM, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(SiMe2X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base- Free Silylene Complexes. Cheminform. 22: no-no. DOI: 10.1002/chin.199117218  0.369
2010 DALTON DM, FERNANDEZ JM, EMERSON K, LARSEN RD, ARIF AM, GLADYSZ JA. ChemInform Abstract: Selective Activation of One Methyl Ketone Enantioface via σ- Binding to a Chiral Transition-Metal Template: Synthesis, Structure, and Reactivity of Rhenium Ketone Complexes ((η5-C5H5)Re(NO)(PPh3)(. eta.1-O=C(CH3)R))+X-. Cheminform. 22: no-no. DOI: 10.1002/chin.199113231  0.428
2010 QUIROS MENDEZ N, MAYNE CL, GLADYSZ JA. ChemInform Abstract: Thermodynamic Aldehyde Enantiofacial Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomeric π-Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η 2-O=CH-Ar))BF4. Cheminform. 22: no-no. DOI: 10.1002/chin.199110252  0.431
2010 QUIROS MENDEZ N, ARIF AM, GLADYSZ JA. ChemInform Abstract: π/σ-Equilibria in Metal Complexes of Organic Carbonyl Compounds: Synthesis and Structure of Chiral Rhenium Complexes ((η 5-C5H5)Re(NO)(PPh3)(O=CH-Ar))X. Cheminform. 22: no-no. DOI: 10.1002/chin.199110251  0.441
2010 PENG T, GLADYSZ JA. ChemInform Abstract: A New Carbon-Hydrogen Bond Activation Reaction: Stereospecific Abstraction of Vinylic Protons from Rhenium Alkene Complexes ((η5- C5H5)Re(NO)(PPh3)(H2C=CHR))+BF- 4 by the Base tBuO-K+. Cheminform. 22: no-no. DOI: 10.1002/chin.199109058  0.356
2009 Podgorsek A, Jurisch M, Stavber S, Zupan M, Iskra J, Gladysz JA. Synthesis and reactivity of fluorous and nonfluorous aryl and alkyl iodine(III) dichlorides: new chlorinating reagents that are easily recycled using biphasic protocols. The Journal of Organic Chemistry. 74: 3133-40. PMID 19320432 DOI: 10.1021/Jo900233H  0.448
2009 Gauthier S, Weisbach N, Bhuvanesh N, Gladysz JA. "Click" chemistry in metal coordination spheres: Copper(I)-catalyzed 3+2 cycloadditions of benzyl azide and platinum polyynyl complexes trans-(C6F5)(p-tol3P) 2Pt(C≡C)nH (n = 2-6) Organometallics. 28: 5597-5599. DOI: 10.1021/Om900680Q  0.405
2009 Kuhn H, Hampel F, Gladysz JA. Syntheses, structures, and dynamic properties of dicobalt π complexes of diplatinum polyynediyl complexes Organometallics. 28: 4979-4987. DOI: 10.1021/Om9005017  0.397
2008 Samoc M, Dalton GT, Gladysz JA, Zheng Q, Velkov Y, Agren H, Norman P, Humphrey MG. Cubic nonlinear optical properties of platinum-terminated polyynediyl chains. Inorganic Chemistry. 47: 9946-57. PMID 18826216 DOI: 10.1021/Ic801145C  0.374
2008 Mandal D, Jurisch M, Consorti CS, Gladysz JA. Ionic transformations in extremely nonpolar fluorous media: easily recoverable phase-transfer catalysts for halide-substitution reactions. Chemistry, An Asian Journal. 3: 1772-82. PMID 18752224 DOI: 10.1002/Asia.200800138  0.499
2008 Skopek K, Barbasiewicz M, Hampel F, Gladysz JA. Three-fold intramolecular ring-closing metatheses involving square-planar platinum complexes with cis-phosphorus donor ligands: syntheses, structures, and properties of parachute-like complexes. Inorganic Chemistry. 47: 3474-6. PMID 18380455 DOI: 10.1021/Ic702391M  0.499
2008 Boswell PG, Szíjjartó C, Jurisch M, Gladysz JA, Rabai J, Bühlmann P. Fluorophilic ionophores for potentiometric pH determinations with fluorous membranes of exceptional selectivity. Analytical Chemistry. 80: 2084-90. PMID 18290670 DOI: 10.1021/Ac702161C  0.41
2008 Owen GR, Stahl J, Hampel F, Gladysz JA. Coordination-driven self-assembly, structures, and dynamic properties of diplatinum hexatriynediyl and butadiynediyl complexes in which the sp carbon chains are shielded by sp3 carbon chains: towards endgroup-endgroup interactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 73-87. PMID 18033704 DOI: 10.1002/Chem.200701268  0.479
2008 Farley RT, Zheng Q, Gladysz JA, Schanze KS. Photophysics of diplatinum polyynediyl oligomers: chain length dependence of the triplet state in sp carbon chains. Inorganic Chemistry. 47: 2955-63. PMID 17902651 DOI: 10.1021/Ic701220T  0.307
2008 Stahl J, Bohling JC, Peters TB, De Quadras L, Gladysz JA. En route to diplatinum polyynediyl complexes trans,trans-(Ar)(R 3P)2Pt(C≡C)nPt(PR3) 2(Ar): Untold tales, including end-group strategies Pure and Applied Chemistry. 80: 459-474. DOI: 10.1351/Pac200880030459  0.383
2008 De Quadras L, Shelton AH, Kuhn H, Hampel F, Schanze KS, Gladysz JA. Syntheses, structures, and electronic and photophysical properties of unsymmetrically substituted butadiynediyl and hexatriynediyl complexes derived from (C6F5)(R3P)2Pt, (p-tol)(R 3P)2Pt, and (Ph3P)Au end-groups Organometallics. 27: 4979-4991. DOI: 10.1021/Om800493X  0.433
2008 Skopek K, Gladysz JA. Syntheses of gyroscope-like molecules via three-fold ring closing metatheses of bis(phosphine) complexes trans-LyM(P((CH2)nCH{double bond, long}CH2)3)2, and extensions to bis(phosphite) complexes trans-Fe(CO)3(P(O(CH2)nCH{double bond, long}CH2)3)2 Journal of Organometallic Chemistry. 693: 857-866. DOI: 10.1016/J.Jorganchem.2007.11.001  0.538
2008 da Costa RC, Jurisch M, Gladysz JA. Synthesis of fluorous sulfur/carbon/sulfur pincer ligands and palladium complexes: New catalyst precursors for the Heck reaction Inorganica Chimica Acta. 361: 3205-3214. DOI: 10.1016/J.Ica.2007.11.016  0.45
2008 Szafert S, Paul F, Meyer WE, Gladysz JA, Lapinte C. Synthesis and reactivity of new heterodinuclear iron/rhenium Cx complexes of the formula (η5-C5Me5)Re(NO)(PPh3)(C{triple bond, long}C)n(η2-dppe)Fe(η5-C5Me5) (n = 3, 4): Redox properties and a dicobalt hexacarbonyl adduct Comptes Rendus Chimie. 11: 693-701. DOI: 10.1016/J.Crci.2007.10.009  0.325
2008 Seidel FO, Gladysz JA. Catalysis of intramolecular Morita-Baylis-Hillman and Rauhut-Currier reactions by fluorous phosphines; facile recovery by liquid/solid organic/fluorous biphase protocols involving precipitation, teflon® tape, and Gore-Rastex® fiber Advanced Synthesis and Catalysis. 350: 2443-2449. DOI: 10.1002/Adsc.200800403  0.515
2007 de Quadras L, Bauer EB, Mohr W, Bohling JC, Peters TB, Martín-Alvarez JM, Hampel F, Gladysz JA. sp carbon chains surrounded by sp(3) carbon double helices: directed syntheses of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages via alkene metathesis. Journal of the American Chemical Society. 129: 8296-309. PMID 17567011 DOI: 10.1021/Ja071612N  0.779
2007 Stahl J, Mohr W, de Quadras L, Peters TB, Bohling JC, Martín-Alvarez JM, Owen GR, Hampel F, Gladysz JA. sp carbon chains surrounded by sp(3) carbon double helices: coordination-driven self-assembly of wirelike Pt(CC)(n)Pt moieties that are spanned by two P(CH(2))(m)P linkages. Journal of the American Chemical Society. 129: 8282-95. PMID 17567010 DOI: 10.1021/Ja0716103  0.47
2007 Consorti CS, Jurisch M, Gladysz JA. Ionic transformations in extremely nonpolar fluorous media: phase transfer catalysis of halide substitution reactions. Organic Letters. 9: 2309-12. PMID 17500561 DOI: 10.1021/Ol0706354  0.446
2007 Seidel F, Gladysz JA. Enantioselective catalysis of intramolecular Morita-Baylis-Hillman and related reactions by chiral rhenium-containing phosphines of the formula (η5-C5H5)Re(NO)(PPh3)(CH 2PAr2) Synlett. 986-988. DOI: 10.1055/S-2007-973859  0.515
2007 de Quadras L, Bauer EB, Stahl J, Zhuravlev F, Hampel F, Gladysz JA. sp Carbon chains surrounded by sp3 carbon double helices: wire-like Pt(CC)nPt moieties that are spanned by two α,ω-diphosphines that bear heteroatoms or alkyl substituents New Journal of Chemistry. 31: 1594. DOI: 10.1039/B708690N  0.781
2007 Hess GD, Hampel F, Gladysz JA. Octahedral gyroscope-like molecules with M(CO) 3(X) rotators encased in three-spoked diphosphine stators: Syntheses by alkene metathesis/hydrogenation sequences, structures, dynamic properties, and reactivities Organometallics. 26: 5129-5131. DOI: 10.1021/Om700625U  0.391
2007 da Costa RC, Hampel F, Gladysz JA. Crystal structure of an unusual bis(fluorous phosphine) ruthenium(III) complex derived from a fluorous Grubbs' catalyst Polyhedron. 26: 581-588. DOI: 10.1016/J.Poly.2006.08.015  0.391
2007 de Quadras L, Stahl J, Zhuravlev F, Gladysz JA. Monophosphine and diphosphine ligands for diplatinum polyynediyl complexes: Efficient syntheses of new functionality-containing systems and model compounds Journal of Organometallic Chemistry. 692: 1859-1870. DOI: 10.1016/J.Jorganchem.2006.12.023  0.524
2007 Skopek K, Hershberger MC, Gladysz JA. Gyroscopes and the chemical literature: 1852-2002 Coordination Chemistry Reviews. 251: 1723-1733. DOI: 10.1016/J.Ccr.2006.12.015  0.373
2007 Da Costa RC, Gladysz JA. Syntheses and reactivity of analogues of Grubbs' second generation metathesis catalyst with fluorous phosphines: A new phase-transfer strategy for catalyst activation Advanced Synthesis and Catalysis. 349: 243-254. DOI: 10.1002/Adsc.200600461  0.514
2006 Wang L, Shima T, Hampel F, Gladysz JA. Gyroscope-like molecules consisting of three-spoke stators that enclose "switchable" neutral dipolar rhodium rotators; reversible cycling between faster and slower rotating Rh(CO)I and Rh(CO)2I species. Chemical Communications (Cambridge, England). 4075-7. PMID 17024253 DOI: 10.1039/B606728J  0.517
2006 Tesevic V, Gladysz JA. Oxidations of secondary alcohols to ketones using easily recyclable bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)(n-1)I(OCOCF3)2. The Journal of Organic Chemistry. 71: 7433-40. PMID 16958539 DOI: 10.1021/Jo0612067  0.31
2006 Zheng Q, Bohling JC, Peters TB, Frisch AC, Hampel F, Gladysz JA. A synthetic breakthrough into an unanticipated stability regime: a series of isolable complexes in which C6, C8, C10, C12, C16, C20, C24, and C28 polyynediyl chains span two platinum atoms. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 6486-505. PMID 16874833 DOI: 10.1002/Chem.200600615  0.36
2006 Corrêa da Costa R, Gladysz JA. Fluorous phase-transfer activation of catalysts: application of a new rate-enhancement strategy to alkene metathesis. Chemical Communications (Cambridge, England). 2619-21. PMID 16779497 DOI: 10.1039/B602428A  0.405
2006 de Quadras L, Hampel F, Gladysz JA. Wire-like PtC[triple bond]CC[triple bond]CC[triple bond]CC[triple bond]CPt moieties surrounded by double-helical "insulation": new motifs featuring P(CH2)20P and P(CH2)4O(CH2)2O(CH2)4P linkages. Dalton Transactions (Cambridge, England : 2003). 2929-33. PMID 16770450 DOI: 10.1039/B604465B  0.509
2006 Friedlein FK, Kromm K, Hampel F, Gladysz JA. Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone: New cyclometalation and catalyst design strategies. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 5267-81. PMID 16628761 DOI: 10.1002/Chem.200501540  0.413
2006 Nawara AJ, Shima T, Hampel F, Gladysz JA. Gyroscope-like molecules consisting of PdX2/PtX2 rotators encased in three-spoke stators: synthesis via alkene metathesis, and facile substitution and demetalation. Journal of the American Chemical Society. 128: 4962-3. PMID 16608324 DOI: 10.1021/Ja061044W  0.453
2006 Dinh LV, Consorti CS, Emnet C, Gladysz JA. π Complexes of fluorous alkynes, cyclobutadienes, and benzenes: Syntheses and phase properties of cobalt and chromium tricarbonyl adducts Organometallics. 25: 1245-1251. DOI: 10.1021/Om050950Z  0.807
2006 Scherer A, Gladysz JA. A promising new catalyst family for enantioselective cycloadditions involving allenes and imines: chiral phosphines with transition metal-CH2-P: linkages Tetrahedron Letters. 47: 6335-6337. DOI: 10.1016/J.Tetlet.2006.07.005  0.467
2006 Lewanzik N, Oeser T, Blümel J, Gladysz JA. Generation of trans-spanning diphosphine ligands via alkene metathesis: Synthesis, structure, and dynamic behavior of a missing link in a series of square-planar platinum complexes Journal of Molecular Catalysis a: Chemical. 254: 20-28. DOI: 10.1016/J.Molcata.2005.12.047  0.546
2006 Consorti CS, Hampel F, Gladysz JA. Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer complexes derived from P(CH2)5P backbones Inorganica Chimica Acta. 359: 4874-4884. DOI: 10.1016/J.Ica.2006.07.092  0.538
2006 Wang L, Hampel F, Gladysz JA. “Gyroskop-Giganten”: dipolare Cl-Rh-CO-Rotatoren, umgeben von Statoren aus drei Speichen 25- bis 27-gliedriger Makrocyclen Angewandte Chemie. 118: 4479-4482. DOI: 10.1002/Ange.200601191  0.368
2006 Emnet C, Weber KM, Vidal JA, Consorti CS, Stuart AM, Gladysz JA. Syntheses and properties of fluorous quaternary phosphonium salts that bear four ponytails; new candidates for phase transfer catalysts and ionic liquids Advanced Synthesis and Catalysis. 348: 1625-1634. DOI: 10.1002/Adsc.200606138  0.468
2005 Dinh LV, Gladysz JA. "Heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails: facile syntheses from polybromocyclopentadienyl complexes, phase properties, and electronic effects. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 7211-22. PMID 16196069 DOI: 10.1002/Chem.200500595  0.814
2005 Tuba R, Tesevic V, Dinh LV, Hampel F, Gladysz JA. Synthesis, structure, and reactivity of fluorous phosphorus/carbon/phosphorus pincer ligands and metal complexes. Dalton Transactions (Cambridge, England : 2003). 2275-83. PMID 15962048 DOI: 10.1039/B502309B  0.804
2005 Dinh LV, Gladysz JA. "Catalyst-on-a-tape"-Teflon: a new delivery and recovery method for homogeneous fluorous catalysts. Angewandte Chemie (International Ed. in English). 44: 4095-7. PMID 15900533 DOI: 10.1002/Anie.200500237  0.728
2005 Giner Planas J, Hampel F, Gladysz JA. Generation and reactions of ruthenium phosphido complexes [(eta5-C5H5)Ru(PR'3)2(PR2)]: remarkably high phosphorus basicities and applications as ligands for palladium-catalyzed Suzuki cross-coupling reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). 11: 1402-16. PMID 15651022 DOI: 10.1002/Chem.200400925  0.536
2005 Emnet C, Gladysz JA. Efficient syntheses of fluorous primary phosphines that do not require PH3 Synthesis. 1012-1018. DOI: 10.1055/S-2005-861815  0.511
2005 Tesevic V, Gladysz JA. An easily accessed class of recyclable hypervalent iodide reagents for functional group oxidations: Bis(trifluoroacetate) adducts of fluorous alkyl iodides, CF3(CF2)n-1I(OCOCF3) 2 Green Chemistry. 7: 833-836. DOI: 10.1039/B511951K  0.306
2005 Dinh LV, Gladysz JA. Monophasic and biphasic hydrosilylations of enones and ketones using a fluorous rhodium catalyst that is easily recycled under fluorous-organic liquid-liquid biphasic conditions New Journal of Chemistry. 29: 173-181. DOI: 10.1039/B415344H  0.754
2005 Friedlein FK, Hampel F, Gladysz JA. A new cyclometalation motif: Synthesis, structure, and reactivity of palladacycles that contain a chiral rhenium fragment in the backbone and are catalyst precursors for heck reactions Organometallics. 24: 4103-4105. DOI: 10.1021/Om0504708  0.417
2005 Eichenseher S, Delacroix O, Kromm K, Hampel F, Gladysz JA. Rhenium-containing phosphorus donor ligands for palladium-catalyzed suzuki cross-coupling reactions: A new strategy for high-activity systems Organometallics. 24: 245-255. DOI: 10.1021/Om0492956  0.474
2005 Dinh LV, Hampel F, Gladysz JA. Syntheses and structures of missing links among polybromocyclopentadienyl rhenium and manganese tricarbonyl complexes Journal of Organometallic Chemistry. 690: 493-503. DOI: 10.1016/J.Jorganchem.2004.09.072  0.767
2005 Kromm K, Eichenseher S, Prommesberger M, Hampel F, Gladysz JA. Synthesis and reactivity of 1,2- and 1,3-diphosphanes that contain four chiral rhenium fragments: Architecturally novel tetrametallo-DMPE and -DMPP species that are unprivileged ligands for enantioselective catalysis European Journal of Inorganic Chemistry. 2983-2998. DOI: 10.1002/Ejic.200500254  0.395
2005 Dinh LV, Gladysz JA. “Katalysatoren am laufenden Band” - Teflon: eine neue Methode zur Applikation und Wiedergewinnung homogener fluoriger Katalysatoren Angewandte Chemie. 117: 4164-4167. DOI: 10.1002/Ange.200500237  0.699
2005 Emnet C, Tuba R, Gladysz JA. Convenient modular syntheses of fluorous secondary phosphines and selected derivatives Advanced Synthesis and Catalysis. 347: 1819-1826. DOI: 10.1002/Adsc.200505145  0.44
2004 Zhuravlev F, Gladysz JA. Electronic structure and chain-length effects in diplatinum polyynediyl complexes trans,trans-[(X)(R3P)2Pt(C triple bond C)(n)Pt(PR3)2(X)]: a computational investigation. Chemistry (Weinheim An Der Bergstrasse, Germany). 10: 6510-22. PMID 15540262 DOI: 10.1002/Chem.200400643  0.355
2004 Shima T, Bauer EB, Hampel F, Gladysz JA. Alkene metatheses in transition metal coordination spheres: dimacrocyclizations that join trans positions of square-planar platinum complexes to give topologically novel diphosphine ligands. Dalton Transactions (Cambridge, England : 2003). 1012-28. PMID 15252680 DOI: 10.1039/B400156G  0.783
2004 Dinh LV, Gladysz JA. Convenient syntheses of "heavy fluorous" cyclopentadienes and cyclopentadienyl complexes with three to five ponytails. Chemical Communications (Cambridge, England). 998-9. PMID 15069513 DOI: 10.1039/B401540A  0.81
2004 Owen GR, Stahl J, Hampel F, Gladysz JA. Syntheses and structures of diplatinum hexatriynediyl complexes, in which the sp carbon chains are shielded by sp3 carbon chains Organometallics. 23: 5889-5892. DOI: 10.1021/Om0493558  0.344
2004 Owen GR, Hampel F, Gladysz JA. Syntheses and structures of tetraplatinum bis(polyynediyl) complexes with laterally arrayed sp carbon chains Organometallics. 23: 5893-5895. DOI: 10.1021/Om049354F  0.445
2004 Zheng Q, Hampel F, Gladysz JA. Longitudinally extended molecular wires based upon PtC≡CC≡CC≡CC≡C repeat units: Iterative syntheses of functionalized linear PtC8Pt, PtC8PtC8Pt, and PtC8PtC8PtC8Pt assemblies Organometallics. 23: 5896-5899. DOI: 10.1021/Om049353N  0.331
2004 Bauer EB, Hampel F, Gladysz JA. Alkyne metatheses in transition metal coordination spheres: Convenient tungsten- and molybdenum-catalyzed syntheses of novel metallamacrocycles Advanced Synthesis and Catalysis. 346: 812-822. DOI: 10.1002/Adsc.200404026  0.789
2003 Jiao H, Costuas K, Gladysz JA, Halet JF, Guillemot M, Toupet L, Paul F, Lapinte C. Bonding and electronic structure in consanguineous and conjugal iron and rhenium sp carbon chain complexes [MC4M'](n)+: computational analyses of the effect of the metal. Journal of the American Chemical Society. 125: 9511-22. PMID 12889982 DOI: 10.1021/Ja034619N  0.351
2003 Mohr W, Stahl J, Hampel F, Gladysz JA. Synthesis, structure, and reactivity of sp carbon chains with bis(phosphine) pentafluorophenylplatinum endgroups: butadiynediyl (C4) through hexadecaoctaynediyl (C16) bridges, and beyond. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 3324-40. PMID 12866077 DOI: 10.1002/Chem.200204741  0.374
2003 Wende M, Gladysz JA. Fluorous catalysis under homogeneous conditions without fluorous solvents: a "greener" catalyst recycling protocol based upon temperature-dependent solubilities and liquid/solid phase separation. Journal of the American Chemical Society. 125: 5861-72. PMID 12733927 DOI: 10.1021/Ja029241S  0.367
2003 Delacroix O, Gladysz JA. Transition-metal-containing chiral bidentate ligands for enantioselective catalysis: non-metallocene architectural units come of age. Chemical Communications (Cambridge, England). 665-75. PMID 12703767 DOI: 10.1039/B207963C  0.327
2003 Rocaboy C, Gladysz JA. Convenient syntheses of fluorous aryl iodides and hypervalent iodine compounds: ArI(L)n reagents that are recoverable by simple liquid/liquid biphase workups, and applications in oxidations of hydroquinones. Chemistry (Weinheim An Der Bergstrasse, Germany). 9: 88-95. PMID 12506367 DOI: 10.1002/Chem.200390034  0.508
2003 Mohr W, Horn CR, Stahl J, Gladysz JA. Convenient and convergent syntheses of long-chain α,ω-dibromides and diphosphines of the formula X(CH2)nX (n = 18-32) Synthesis. 1279-1285. DOI: 10.1055/S-2003-39414  0.494
2003 Rocaboy C, Gladysz JA. Thermomorphic fluorous imine and thioether palladacycles as precursors for highly active Heck and Suzuki catalysts; evidence for palladium nanoparticle pathways New Journal of Chemistry. 27: 39-49. DOI: 10.1039/B208545N  0.503
2003 Bauer EB, Hampel F, Gladysz JA. Alkene Metatheses in Transition Metal Coordination Spheres: Effect of Ring Size and Substitution on the Efficiencies of Macrocyclizations that Join Trans Positions of Square-Planar Platinum Complexes Organometallics. 22: 5567-5580. DOI: 10.1021/Om034121U  0.799
2003 Bauer EB, Szafert S, Hampel F, Gladysz JA. Tungsten-catalyzed alkyne metatheses in transition-metal coordination spheres: Versatile new syntheses of metallamacrocycles Organometallics. 22: 2184-2186. DOI: 10.1021/Om030195U  0.738
2003 Wende M, Seidel F, Gladysz JA. Synthesis and properties of fluorous arenes and triaryl phosphorus compounds with branched fluoroalkyl moieties ("split pony tails") Journal of Fluorine Chemistry. 124: 45-54. DOI: 10.1016/S0022-1139(03)00171-4  0.528
2003 Le Stang S, Meier R, Rocaboy C, Gladysz JA. Convenient syntheses of fluorous phenols of the formula triarylphosphites Journal of Fluorine Chemistry. 119: 141-149. DOI: 10.1016/S0022-1139(02)00242-7  0.44
2003 Horn C, Gladysz J. Cover Picture: Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)] (Eur. J. Inorg. Chem. 12/2003) European Journal of Inorganic Chemistry. 2003: 2189-2189. DOI: 10.1002/Ejic.200390225  0.332
2003 Horn C, Gladysz J. Syntheses of Dimetallamacrocycles by Intramolecular Oxidative Couplings of Dinuclear Bis(1,3-butadiynyl) Complexes: A New Approach to Steric Shielding in (sp-Carbon chain)dirhenium Complexes [(η5-C5Me5)Re(NO)(PR3)(C≡CC≡CC≡CC≡C)(R3P)(ON)Re(η5-C5Me5)] European Journal of Inorganic Chemistry. 2003: 2211-2218. DOI: 10.1002/Ejic.200300043  0.529
2002 Stahl J, Bohling JC, Bauer EB, Peters TB, Mohr W, Martín-Alvarez JM, Hampel F, Gladysz JA. Sp carbon chains surrounded by sp3 carbon double helices: a class of molecules that are accessible by self-assembly and models for "insulated" molecular-scale devices. Angewandte Chemie (International Ed. in English). 41: 1872-6. PMID 19750618 DOI: 10.1002/1521-3773(20020603)41:11<1871::Aid-Anie1871>3.0.Co;2-V  0.607
2002 Planas JG, Gladysz JA. Highly bulky and electron-rich terminal ruthenium phosphido complexes: new donor ligands for palladium-catalyzed suzuki cross-couplings. Inorganic Chemistry. 41: 6947-9. PMID 12495330 DOI: 10.1021/Ic020589Y  0.4
2002 Rocaboy C, Hampel F, Gladysz JA. Syntheses and reactivities of disubstituted and trisubstituted fluorous pyridines with high fluorous phase affinities: solid state, liquid crystal, and ionic liquid-phase properties. The Journal of Organic Chemistry. 67: 6863-70. PMID 12353975 DOI: 10.1021/Jo011173P  0.497
2002 Eichenseher S, Kromm K, Delacroix O, Gladysz JA. New approaches to high-activity transition-metal catalysts for carbon-carbon bond forming reactions. Rhenium-containing phosphorus donor ligands for palladium-catalyzed Suzuki cross-couplings. Chemical Communications (Cambridge, England). 1046-7. PMID 12122657 DOI: 10.1039/B201512A  0.517
2002 Rocaboy C, Gladysz JA. Highly active thermomorphic fluorous palladacycle catalyst precursors for the Heck reaction; evidence for a palladium nanoparticle pathway. Organic Letters. 4: 1993-6. PMID 12049500 DOI: 10.1021/Ol025790R  0.469
2002 Jiao H, Le Stang S, Soós T, Meier R, Kowski K, Rademacher P, Jafarpour L, Hamard JB, Nolan SP, Gladysz JA. How to insulate a reactive site from a perfluoroalkyl group: photoelectron spectroscopy, calorimetric, and computational studies of long-range electronic effects in fluorous phosphines P((CH(2))(m)(CF(2))(7)CF(3))(3). Journal of the American Chemical Society. 124: 1516-23. PMID 11841323 DOI: 10.1021/Ja011877G  0.501
2002 Lichtenberger DL, Gruhn NE, Rai-Chaudhuri A, Renshaw SK, Gladysz JA, Jiao H, Seyler J, Igau A. Vibrational progressions in the valence ionizations of transition metal hydrides: evaluation of metal-hydride bonding and vibrations in (eta(5)-C(5)R(5))Re(NO)(CO)H [R = H, CH(3)]. Journal of the American Chemical Society. 124: 1417-23. PMID 11841310 DOI: 10.1021/Ja0120227  0.34
2002 Lichtenberger DL, Gruhn NE, Rai-Chaudhuri A, Renshaw SK, Gladysz JA, Jiao H, Seyler J, Igau A. How do the electronic structures of low-symmetry metal-hydride and -alkyl complexes compare? Photoelectron spectroscopy and computational studies of (η5-C5R5)Re(NO)(L)R′(L = CO, P(C6H5)3; R, R′ = H, CH3) Organometallics. 21: 5494-5504. DOI: 10.1021/Om020793T  0.478
2002 Horn CR, Martín-Alvarez JM, Gladysz JA. Olefin metatheses in metal coordination spheres: A new approach to steric shielding in dirhenium sp carbon chain complexes of the formula (η5-C5Me5)Re(NO)(PR3)(C≡CC ≡CC≡CC≡C)(R3P)(ON)Re(η5-C5 Me5) Organometallics. 21: 5386-5393. DOI: 10.1021/Om020676Y  0.571
2002 Kromm K, Osburn PL, Gladysz JA. Chelating diphosphines that contain a rhenium stereocenter in the backbone: Applications in rhodium-catalyzed enantioselective ketone hydrosilylations and alkene hydrogenations Organometallics. 21: 4275-4280. DOI: 10.1021/Om020432D  0.388
2002 Kromm K, Hampel F, Gladysz JA. A new family of chelating diphosphines with transition-metal and carbon stereocenters in the backbone: A second-generation rhenium-containing system Organometallics. 21: 4264-4274. DOI: 10.1021/Om020431L  0.51
2002 Kiel WA, Lin G, Gladysz JA. Unprecedented regiospecificity and stereospecificity in reactions of Ph3C+PF6- with rhenium alkyls of the formula (.eta.-C5H5)Re(NO)(PPh3)(CH2R) Cheminform. 11. DOI: 10.1021/Ja00529A092  0.509
2002 Kiel WA, Lin GY, Bodner GS, Gladysz JA. Regiospecific and stereospecific reactions of triphenylmethyl hexafluorophosphate with rhenium alkyls (.eta.-C5H5)Re(NO)(PPh3)(R). .alpha.- vs. .beta.-Hydride abstraction Cheminform. 14. DOI: 10.1021/Ja00353A020  0.413
2002 Mohr W, Peters TB, Bohling JC, Hampel F, Arif AM, Gladysz JA. An unexpected insertion of acetone into the silicon–carbon terminus of an sp carbon chain: syntheses and structures of model monoplatinum hexatriynyl and octatetraynyl complexes Comptes Rendus Chimie. 5: 111-118. DOI: 10.1016/S1631-0748(02)01351-6  0.388
2002 Rocaboy C, Gladysz JA. Syntheses, oxidations, and palladium complexes of fluorous dialkyl sulfides: New precursors to highly active catalysts for the Suzuki coupling Tetrahedron. 58: 4007-4014. DOI: 10.1016/S0040-4020(02)00275-2  0.491
2002 Peters TB, Zheng Q, Stahl J, Bohling JC, Arif AM, Hampel F, Gladysz JA. Syntheses and structures of monoplatinum model complexes for diplatinum polyynediyl adducts LnPt(CC)zPtLn Journal of Organometallic Chemistry. 641: 53-61. DOI: 10.1016/S0022-328X(01)01311-0  0.39
2002 Buhro WE, Gladysz JA. Configurational Processes in Coordinated Ligands. Extremely Facile Phosphorus Inversion in the Pyramidal Terminal Phosphide Complexes (η5-C5H5)Re(NO)(PPh3)(PRR′). Cheminform. 17. DOI: 10.1002/Chin.198606246  0.648
2002 De Rege PJF, Gladysz JA, Horváth IT. Facile and Selective Carbonylation of Methane in Superacids Advanced Synthesis and Catalysis. 344: 1059-1062. DOI: 10.1002/1615-4169(200212)344:10<1059::Aid-Adsc1059>3.0.Co;2-O  0.416
2002 Kromm K, Hampel F, Gladysz JA. Syntheses, structures, and catalytic reactions of palladium adducts of chiral diphosphines that contain a rhenium stereocenter in the backbone Helvetica Chimica Acta. 85: 1778-1789. DOI: 10.1002/1522-2675(200206)85:6<1778::Aid-Hlca1778>3.0.Co;2-9  0.441
2002 Stahl J, Bohling JC, Bauer EB, Peters TB, Mohr W, Martín-Alvarez JM, Hampel F, Gladysz JA. Von sp3-Kohlenstoff-Helices umgebene sp-Kohlenstoffketten: eine Klasse von Molekülen, die durch Selbstorganisation zugänglich und Modellverbindungen für „isolierte“ molekulare Bauelemente sind Wir danken der Deutschen Forschungsgemeinschaft (SFB 583), Johnson Matthey PMC (Platin-Spende), dem Ministerio de Educación y Ciencia und der Fulbright Commission (Stipendien, J.M.M.-A.) für finanzielle Unterstützung und Dr. A. M. Arif für die Mithilfe bei einer Kristallstrukturanalyse. Angewandte Chemie. 114: 1951. DOI: 10.1002/1521-3757(20020603)114:11<1951::Aid-Ange1951>3.0.Co;2-Z  0.607
2001 Ruwwe J, Martín-Alvarez JM, Horn CR, Bauer EB, Szafert S, Lis T, Hampel F, Cagle PC, Gladysz JA. Olefin metatheses in metal coordination spheres: versatile new strategies for the construction of novel monohapto or polyhapto cyclic, macrocyclic, polymacrocyclic, and bridging ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 7: 3931-50. PMID 11596935 DOI: 10.1002/1521-3765(20010917)7:18<3931::Aid-Chem3931>3.0.Co;2-Y  0.781
2001 Kromm K, Zwick BD, Meyer O, Hampel F, Gladysz JA. A new family of chelating diphosphines with a transition metal stereocenter in the backbone: novel applications of "chiral-at-rhenium" complexes in rhodium-catalyzed enantioselective alkene hydrogenations. Chemistry (Weinheim An Der Bergstrasse, Germany). 7: 2015-27. PMID 11405481 DOI: 10.1002/1521-3765(20010504)7:9<2015::Aid-Chem2015>3.0.Co;2-H  0.566
2001 Otto M, Boone BJ, Arif AM, Gladysz JA. Synthesis, structure, and interconversion of chiral rhenium oxygen- and sulfur-bound sulfoxide complexes of formula [(η5-C5H5)-Re(NO)(PPh3) (OS(Me)R)]+ X-; diastereoselective oxidations of coordinated methyl alkyl sulfides Journal of the Chemical Society, Dalton Transactions. 1218-1229. DOI: 10.1039/B009533H  0.504
2001 Jiao H, Gladysz JA. Metal-metal interactions across bridging elemental carbon chains: A computational study of odd-carbon complexes New Journal of Chemistry. 25: 551-562. DOI: 10.1039/B008786F  0.475
2001 Soós T, Bennett BL, Rutherford D, Barthel-Rosa LP, Gladysz JA. Synthesis, reactivity, and metal complexes of fluorous triarylphosphines of the formula P(p-C6H4(CH2)3(CF2)n -1CF3)3 (n = 6, 8, 10) Organometallics. 20: 3079-3086. DOI: 10.1021/Om010193E  0.529
2001 Mohr W, Stark GA, Jiao H, Gladysz JA. New chiral cyclopentadienylrhenium lewis acids featuring fluorinated triarylphosphanes and enhanced acceptor abilities - An unusual carbon-fluorine bond activation in a metal coordination sphere European Journal of Inorganic Chemistry. 925-933. DOI: 10.1002/1099-0682(200104)2001:4<925::Aid-Ejic925>3.0.Co;2-N  0.56
2000 Bauer EB, Ruwwe J, Martin-Alvarez JM, Peters TB, Bohling JC, Hampel FA, Szafert S, Lis T, Gladysz JA. Olefin metatheses in metal coordination spheres: Novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes Chemical Communications. 2261-2262. DOI: 10.1039/B007405P  0.785
2000 Schennach R, Naugle DG, Cocke D, Dembinski R, Gladysz J. Surface reactivity studies of bimetallic complexes, (η5-C5Me5)Re(NO)(PPh3)(CC)n(Ph3P)(ON)Re(η5-C5Me5) (n=2,4,6): candidates for molecular wires Vacuum. 56: 115-121. DOI: 10.1016/S0042-207X(99)00178-5  0.327
2000 Bras JL, Jiao H, Meyer WE, Hampel F, Gladysz JA. Synthesis, crystal structure, and reactions of the 17-valence-electron rhenium methyl complex [(η5-C5Me5)Re(NO)(P(4-C6H4CH3)3)(CH3)]+ B(3,5-C6H3(CF3)2)4−: experimental and computational bonding comparisons with 18-electron methyl and methylidene complexes Journal of Organometallic Chemistry. 616: 54-66. DOI: 10.1016/S0022-328X(00)00531-3  0.473
2000 Meyer WE, Amoroso AJ, Jaeger M, Le Bras J, Wong W, Gladysz J. Synthesis and oxidation of chiral rhenium phosphine methyl complexes of the formula (η5-C5Me5)Re(NO)(PR3)(CH3): in search of radical cations with enhanced kinetic stabilities Journal of Organometallic Chemistry. 616: 44-53. DOI: 10.1016/S0022-328X(00)00528-3  0.545
2000 Szafert S, Haquette P, Falloon SB, Gladysz J. Synthesis and properties of chiral rhenium pentatetraenylidene complexes of the formula [(η5-C5Me5)Re(NO)(PPh3)(CCCCCAr2)]+BF4− (CAr2=9-fluorenylidene) Journal of Organometallic Chemistry. 604: 52-58. DOI: 10.1016/S0022-328X(00)00201-1  0.4
2000 Rocaboy C, Rutherford D, Bennett BL, Gladysz JA. Strategy and design in fluorous phase immobilization:�a systematic study of the effect of ?pony tails? (CH2)3(CF2)n?1CF3 on the partition coefficients of �benzenoid compounds Journal of Physical Organic Chemistry. 13: 596-603. DOI: 10.1002/1099-1395(200010)13:10<596::Aid-Poc284>3.0.Co;2-M  0.422
2000 Rocaboy C, Bauer W, Gladysz J. Convenient Syntheses of a Family of Easily Recoverable Fluorous Primary, Secondary, and Tertiary Aliphatic Amines NH3−x[(CH2)m(CF2)7CF3]x(m = 3−5;x = 1−3) − Fine Tuning of Basicities and Fluorous Phase Affinities European Journal of Organic Chemistry. 2000: 2621-2628. DOI: 10.1002/1099-0690(200007)2000:14<2621::Aid-Ejoc2621>3.0.Co;2-H  0.462
2000 Alvey LJ, Meier R, Soós T, Bernatis P, Gladysz JA. Syntheses and Carbonyliridium Complexes of Unsymmetrically Substituted Fluorous Trialkylphosphanes: Precision Tuning of Electronic Properties, Including Insulation of the Perfluoroalkyl Groups European Journal of Inorganic Chemistry. 2000: 1975-1983. DOI: 10.1002/1099-0682(200009)2000:9<1975::Aid-Ejic1975>3.0.Co;2-M  0.511
1999 Peters TB, Bohling JC, Arif AM, Gladysz JA. C8and C12sp Carbon Chains That Span Two Platinum Atoms:  The First Structurally Characterized 1,3,5,7,9,11-Hexayne Organometallics. 18: 3261-3263. DOI: 10.1021/Om990448C  0.351
1999 Martín-Alvarez JM, Hampel F, Arif AM, Gladysz JA. Olefin Metatheses in Metal Coordination Spheres:  A New Strategy for Cyclic and Macrocyclic Organometallic Compounds Organometallics. 18: 955-957. DOI: 10.1021/Om9808920  0.55
1999 Juliette JJJ, Rutherford D, Horváth IT, Gladysz JA. Transition metal catalysis in fluorous media: Practical application of a new immobilization principle to rhodium-catalyzed hydroborations of alkenes and alkynes Journal of the American Chemical Society. 121: 2696-2704. DOI: 10.1021/Ja982955B  0.347
1999 Klose A, Gladysz JA. Synthesis, properties, and reactions of enantiomerically pure, chiral fluorous phosphines of the formula (menthyl)P(CH2CH2(CF2)(n-1)CF3)2 (n=6, 8) Tetrahedron Asymmetry. 10: 2665-2674. DOI: 10.1016/S0957-4166(99)00272-4  0.44
1999 Dinh LV, Gladysz J. Transition metal catalysis in fluorous media: extension of a new immobilization principle to biphasic and monophasic rhodium-catalyzed hydrosilylations of ketones and enones Tetrahedron Letters. 40: 8995-8998. DOI: 10.1016/S0040-4039(99)01924-3  0.803
1999 Dembinski R, Lis T, Szafert S, Mayne CL, Bartik T, Gladysz J. Appreciably bent sp carbon chains: synthesis, structure, and protonation of organometallic 1,3,5-triynes and 1,3,5,7-tetraynes of the formula (η5-C5Me5)Re(NO)(PPh3)((CC)n-p-C6H4Me) Journal of Organometallic Chemistry. 578: 229-246. DOI: 10.1016/S0022-328X(98)01128-0  0.396
1998 Alvey LJ, Rutherford D, Juliette JJ, Gladysz JA. Additions of PH(3) to Monosubstituted Alkenes of the Formula H(2)C=CH(CH(2))(x)()(CF(2))(y)()CF(3): Convenient, Multigram Syntheses of a Family of Partially Fluorinated Trialkylphosphines with Modulated Electronic Properties and Fluorous Phase Affinities. The Journal of Organic Chemistry. 63: 6302-6308. PMID 11672263 DOI: 10.1021/Jo980692Y  0.432
1998 Guillevic M, Rocaboy C, Arif AM, Horváth IT, Gladysz JA. Organometallic Reactivity Patterns in Fluorocarbons and Implications for Catalysis:  Synthesis, Structure, Solubility, and Oxidative Additions of a Fluorous Analogue of Vaska's Complex,trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2 Organometallics. 17: 707-717. DOI: 10.1021/Om9710834  0.413
1998 Bartik T, Weng W, Ramsden JA, Szafert S, Falloon SB, Arif AM, Gladysz JA. New Forms of Coordinated Carbon:  Wirelike Cumulenic C3and C5sp Carbon Chains that Span Two Different Transition Metals and Mediate Charge Transfer Journal of the American Chemical Society. 120: 11071-11081. DOI: 10.1021/Ja981927Q  0.379
1998 Rutherford D, Juliette JJ, Rocaboy C, Horváth IT, Gladysz J. Transition metal catalysis in fluorous media: application of a new immobilization principle to rhodium-catalyzed hydrogenation of alkenes Catalysis Today. 42: 381-388. DOI: 10.1016/S0920-5861(98)00120-5  0.455
1998 Stark GA, Gladysz JA. Additions of carbon nucleophiles to acyclic imine complexes of the chiral rhenium Lewis acid [(η5-C5H5)Re(NO)(PPh3]+: controlling factors in 1,3-asymmetric induction and syntheses of non-racemic organic amines Inorganica Chimica Acta. 269: 167-180. DOI: 10.1016/S0020-1693(97)05787-3  0.545
1998 Falloon SB, Szafert S, Arif AM, Gladysz JA. Attaching Metal-Capped sp Carbon Chains to Metal Clusters: Synthesis, Structure, and Reactivity of Rhenium/Triosmium Complexes of Formula [(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)y(X)z]m+, Including Carbon Geometries More Distorted than Planar Tetracoordinate Chemistry - a European Journal. 4: 1033-1042. DOI: 10.1002/(Sici)1521-3765(19980615)4:6<1033::Aid-Chem1033>3.0.Co;2-P  0.418
1997 Falloon SB, Arif AM, Gladysz JA. Methods for attaching metal-capped sp carbon chains to metalclusters: synthesis, structure and reactivity of rhenium–triosmiumcarbon complexes[(η5-C5Me5)Re(NO)(PPh3)(CC)nOs3(CO)10H] Chemical Communications. 629-630. DOI: 10.1039/A607884B  0.377
1997 Amoroso AJ, Arif AM, Gladysz JA. Supramolecular Chemistry of Chiral Rhenium Lewis Acids of the Formula [(η5-C5R5)Re(NO)(CO)(PPh3)]+:  Synthesis and Crystal Structure of a 2:1 Adduct of an Ammonia Complex and 18-Crown-6 Organometallics. 16: 6032-6034. DOI: 10.1021/Om970792E  0.419
1997 Stark GA, Arif AM, Gladysz JA. Synthesis, Structure, and Reactivity of Bridging Cyanide Complexes of the Formula [(η5-C5R5)Re(NO)(PPh3)CN(Ph3P)(ON)Re(η5-C5R‘5)]+TfO-(R, R‘ = H, Me) Organometallics. 16: 2909-2918. DOI: 10.1021/Om970167+  0.37
1997 Falloon SB, Weng W, Arif AM, Gladysz JA. Synthesis, Structure, and Reactivity of Polymetallic C3OMe Complexes of the Formula (η5-C5Me5)Re(NO)(PPh3)(C⋮CC(OMe))Mm(CO)n(M/m/n= Re/2/9, Os/3/11):  A New Form of Coordinated Carbon in Which a C3Chain Links Two Metals and Spans a Third Organometallics. 16: 2008-2015. DOI: 10.1021/Om970055I  0.349
1997 Brady M, Weng W, Zhou Y, Seyler JW, Amoroso AJ, Arif AM, Böhme M, Frenking G, Gladysz JA. Consanguineous Families of Coordinated Carbon:  A ReC4Re Assembly That Is Isolable in Three Oxidation States, Including Crystallographically Characterized ReC⋮CC⋮CRe and+ReCCCCRe+Adducts and a Radical Cation in Which Charge Is Delocalized between Rhenium Termini Journal of the American Chemical Society. 119: 775-788. DOI: 10.1021/Ja9631817  0.39
1997 Guillevic M, Arif AM, Gladysz JA, Horváth IT. Synthesis, Structure, and Oxidative Additions of a Fluorous Analogue of Vaska's Complex,trans-[IrCl(CO){P[CH2CH2(CF2)5CF3]3}2]— Altered Reactivity in Fluorocarbons and Implications for Catalysis Angewandte Chemie International Edition in English. 36: 1612-1615. DOI: 10.1002/Anie.199716121  0.352
1997 Gladysz JA, Boone BJ. Chiral Recognition inπ Complexes of Alkenes, Aldehydes, and Ketones with Transition Metal Lewis Acids; Development of a General Model for Enantioface Binding Selectivities Angewandte Chemie International Edition in English. 36: 550-583. DOI: 10.1002/Anie.199705501  0.313
1997 Gladysz JA, Boone BJ. Chirale Erkennung in π‐Komplexen von Alkenen, Aldehyden und Ketonen mit Übergangsmetall‐Lewis‐Säuren; Entwicklung eines allgemeinen Modells für enantiofaciale Komplexierungsselektivitäten Angewandte Chemie. 109: 566-602. DOI: 10.1002/Ange.19971090604  0.381
1996 Stark GA, Gladysz JA. A Search for pi/sigma Equilibria in Chiral Rhenium Imine Complexes of the Formula [(eta(5)-C(5)H(5))Re(NO)(PPh(3))(N(H)=C(CF(3))X)](+)TfO(-): Investigation of Electronic Effects upon the Binding Mode. Inorganic Chemistry. 35: 5509-5513. PMID 11666738 DOI: 10.1021/Ic960302V  0.538
1996 Meyer O, Cagle PC, Weickhardt K, Vichard D, Gladysz JA. Enantioselective syntheses of organosulfur compounds via [2,3] sigmatropic rearrangements of ylides derived from di(allyl), di(propargyl), and di(benzyl) sulfide complexes; Control of carbon configuration by an easily resolved and recycled rhenium auxiliary Pure and Applied Chemistry. 68: 79-88. DOI: 10.1351/Pac199668010079  0.381
1996 Boone BJ, Klein DP, Seyler JW, Quirós Méndez N, Arif AM, Gladysz JA. A Crystallographic Map of Chiral Recognition in π Complexes of Aromatic Aldehydes and a Chiral Transition Metal Lewis Acid:  Enantioface Binding Selectivities in Solution Correlate to Distances between Metal and Carbon Stereocenters in the Solid State Journal of the American Chemical Society. 118: 2411-2421. DOI: 10.1039/C39950000279  0.425
1996 Dewey MA, Stark GA, Gladysz JA. Configurational Equilibria in Amido and Lithioamido Complexes of Formulas (η5-C5H5)Re(NO)(PAr3)(N̈HCHRR‘) and (η5-C5H5)Re(NO)(PAr3)(N̈LiR‘‘):  Epimerization Occurs at Rhenium via Phosphine Dissociation Organometallics. 15: 4798-4807. DOI: 10.1021/Om960662Q  0.306
1996 Bell PT, Cagle PC, Vichard D, Gladysz JA. Diallyl Sulfide Complexes of Chiral Iron and Ruthenium Lewis Acids:  Ylide Generation and Diastereoselective [2,3] Sigmatropic Rearrangements To Give Thiolate Complexes with New Carbon Stereocenters Organometallics. 15: 4695-4701. DOI: 10.1021/Om960541Q  0.533
1996 Cagle PC, Meyer O, Vichard D, Weickhardt K, Arif AM, Gladysz JA. Reactions oft-BuOK and Dibenzyl, Benzyl Allyl, and Allyl β-Keto Sulfide Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+:  Highly Diastereoselective or Chemoselective [2,3]-Sigmatropic Rearrangements Organometallics. 15: 194-204. DOI: 10.1021/Om950701I  0.526
1996 Bartik T, Bartik B, Brady M, Dembinski R, Gladysz JA. A Step-Growth Approach to Metal-Capped One-Dimensional Carbon Allotropes: Syntheses of C12, C16, and C20μ-Polyynediyl Complexes Angewandte Chemie International Edition in English. 35: 414-417. DOI: 10.1002/Anie.199604141  0.311
1995 Peng T, Arif AM, Gladysz JA. Nucleophilic additions to the chiral rhenium alkene complexes [Re(η5-C5H5)(NO)(PPh3)(H2CCHR)]BF4(R = H, Me, CH2CH2Me, Ph or CH2Ph): regio-, diastereo- and enantio-selectivities Journal of the Chemical Society-Dalton Transactions. 1857-1865. DOI: 10.1039/Dt9950001857  0.552
1995 Boone BJ, Klein DP, Méndez NQ, Seyler JW, Arif AM, Gladysz JA. A crystallographic map of chiral recognition in π complexes of aromatic aldehydes and a chiral transition metal Lewis acid: Enantioface binding selectivities in solution correlate to distances between metal and carbon stereocentres in the solid state Journal of the Chemical Society, Chemical Communications. 279-281. DOI: 10.1039/C39950000279  0.306
1995 Meyer O, Arif AM, Gladysz JA. A New Reaction of Coordinated Sulfoxides: Facile and Highly Diastereoselective Deprotonation of a Chiral, Cationic Rhenium DMSO Complex to an Ylide and Subsequent [1,2] Migration of Rhenium from Sulfur to Carbon Organometallics. 14: 1844-1849. DOI: 10.1021/Om00004A043  0.353
1995 Peng T, Gladysz JA. A New Alkene Carbon-Hydrogen Bond Activation Reaction: Facile and Stereospecific Vinylic Deprotonation of the Chiral Cationic Rhenium Alkene Complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4- Organometallics. 14: 898-911. DOI: 10.1021/om00002a042  0.37
1995 Weng W, Bartik T, Johnson MT, Arif AM, Gladysz JA. Electrophile-Induced Cyclizations of Chiral Rhenium Ethynyl and C2Li Complexes of the Formula (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CX): Synthesis, Structure, and Reactivity of Unusual 1,3-Dimetalated Cyclic C4H3 and C4H4 Species Organometallics. 14: 889-897. DOI: 10.1021/Om00002A041  0.534
1995 Wang Y, Gladysz JA. Conjugate Additions of Organocuprates to Cycloalkenone Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+. Enantioselective Syntheses of 3-Substituted Cycloalkanones The Journal of Organic Chemistry. 60: 903-909. DOI: 10.1021/jo00109a022  0.411
1995 Weng W, Bartik T, Brady M, Bartik B, Ramsden JA, Arif AM, Gladysz JA. Synthesis, Structure, and Redox Chemistry of Heteropolymetallic Carbon Complexes with MC2M', MC4M', and MC4M'C4M Linkages. Transmetalations of Lithiocarbon Complexes (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CLi) and (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CC.tplbond.CLi) Journal of the American Chemical Society. 117: 11922-11931. DOI: 10.1021/Ja00153A014  0.435
1995 Cagle PC, Meyer O, Weickhardt K, Arif AM, Gladysz JA. Enantioselective Synthesis of Organosulfur Compounds via [2,3] Rearrangements of Ylides Derived from Di(allyl) and Di(propargyl) Sulfide Complexes. Control of Carbon Configuration by an Easily Resolved and Recycled Chiral Transition Metal Auxiliary Journal of the American Chemical Society. 117: 11730-11744. DOI: 10.1021/Ja00152A014  0.334
1995 Sanaú M, Peng T, Arif AM, Gladysz J. Crystal structures of diastereomeric styrene complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+: effect of ligating enantioface upon bonding and conformation Journal of Organometallic Chemistry. 503: 235-241. DOI: 10.1016/0022-328X(95)05565-7  0.465
1995 Johnson TJ, Alvey LJ, Brady M, Mayne CL, Arif AM, Gladysz JA. Synthesis, Structure, and Reactivity of Chiral RheniumN-Pyrrolyl Complexes Regiochemistry of Electrophilic Addition and Unprecedented Rearrangements to Carbon-Ligated Species Chemistry - a European Journal. 1: 294-303. DOI: 10.1002/Chem.19950010506  0.497
1995 Wang V, Gladysz JA. Reactions of Diazo Compounds and Chiral Rhenium Alkylidene Complexes of the Formula [(η5-C5H5)Re(NO)(PPh3)(CHR)]+ PF−6 A Versatile and Highly Stereoselective Route to Alkene Complexes Chemische Berichte. 128: 213-220. DOI: 10.1002/Cber.19951280303  0.559
1994 Lee KE, Gladysz JA. Synthesis and reactivity of functionalized dimethylgermyl complexes of the formula (n5 -csh5)re(n0)(pph3)(geme2x); equilibria involving the dimethylgermylene complex [(n5 -cshs)re(no)(pph3)(=gemez)]* tfo- Phosphorus, Sulfur, and Silicon and the Related Elements. 87: 113-123. DOI: 10.1080/10426509408037445  0.5
1994 Brady M, Weng W, Gladysz JA. New families of coordinated carbon: Oxidative coupling and cross-coupling of a transition metal butadiynyl complex to bimetallic M- C≡CC≡CC≡CC≡C-M and M-C≡CC≡CC≡C-M adducts Journal of the Chemical Society, Chemical Communications. 2655-2656. DOI: 10.1039/C39940002655  0.348
1994 Stark GA, Arif AM, Gladysz JA. Diastereoselective 1,2 Additions of Nucleophiles to Quinoline Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ Organometallics. 13: 4523-4530. DOI: 10.1021/Om00023A063  0.507
1994 Johnson TJ, Arif AM, Gladysz JA. Synthesis, Structure, and Reactivity of N-Indolyl Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Diastereoselective Electrophilic Additions Organometallics. 13: 3182-3193. DOI: 10.1021/Om00020A035  0.503
1994 Wang Y, Arif AM, Gladysz JA. Anhydrous Monomeric Glyoxal: Pyrolytic Generation and Stabilization by the Chiral Rhenium Fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+ Organometallics. 13: 2164-2169. DOI: 10.1021/Om00018A008  0.482
1994 Peng T, Pu J, Gladysz JA. Syntheses and Structures of Unsymmetrically 1,1- and 1,2-Disubstituted Alkene Complexes of the Chiral Rhenium Lewis Acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: Enantioface Binding Selectivities and Conformational Equilibria Organometallics. 13: 929-940. DOI: 10.1021/Om00015A029  0.477
1994 Peng T, Winter CH, Gladysz JA. Generation and Reactivity of Substitution-Labile Dichloromethane and Chlorobenzene Adducts of the Chiral Pentamethylcyclopentadienyl Rhenium Lewis Acid [(.eta.5-C5Me5)Re(NO)(PPh3)]+ Inorganic Chemistry. 33: 2534-2542. DOI: 10.1021/Ic00090A011  0.669
1994 Cantrell WR, Richter-Addo GB, Gladysz J. Syntheses of cyclic imine complexes of the chiral rhenium Lewis acid [(ν5-C5H5) Re(NO)(PPh3)]+ by hydride ion abstraction from amido complexes Journal of Organometallic Chemistry. 472: 195-204. DOI: 10.1016/0022-328X(94)80206-8  0.488
1993 Johnson TJ, Arif AM, Gladysz JA. Pyrrolyl-N and pyrrolyl-C complexes of the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: synthesis, protonation, and rearrangement chemistry Organometallics. 12: 4728-4730. DOI: 10.1021/Om00036A006  0.529
1993 Peng TS, Wang Y, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of .eta.2-1,3-diene and enyne complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: ozonolysis within a metal coordination sphere Organometallics. 12: 4535-4544. DOI: 10.1021/Om00035A044  0.501
1993 Knight DA, Dewey MA, Stark GA, Bennett BK, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of chiral rhenium imine and methyleneamido complexes of the formulas [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-NR'':CRR')]+ TfO- and (.eta.5-C5H5)Re(NO)(PPh3)(N:CRR') Organometallics. 12: 4523-4534. DOI: 10.1021/Om00035A043  0.538
1993 Dewey MA, Zhou Y, Liu Y, Gladysz JA. Reactions of rhenium cyclopentadienyl and indenyl dichloromethane complexes of the formula [(.eta.5-CxHy)Re(NO)(PPh3)(ClCH2Cl)]+BF4- with ketones: substitution rates and mechanism Organometallics. 12: 3924-3932. DOI: 10.1021/Om00034A027  0.362
1993 Zhou Y, Dewey MA, Gladysz JA. Synthesis and reactivity of chiral rhenium indenyl complexes of the formula [(.eta.5-C9H7)Re(NO)(PPh3)(X)]n+ Organometallics. 12: 3918-3923. DOI: 10.1021/Om00034A026  0.505
1993 Wang Y, Agbossou F, Dalton DM, Liu Y, Arif AM, Gladysz JA. Syntheses and structures of complexes of .alpha.,.beta.-unsaturated carbonyl compounds and the chiral rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+: divergent kinetic and thermodynamic O:C/C:C and O:C/C.tplbond.C binding selectivities Organometallics. 12: 2699-2713. DOI: 10.1021/Om00031A045  0.375
1993 Pu J, Peng TS, Mayne CL, Arif AM, Gladysz JA. Synthesis, structure, and dynamic behavior of symmetrical cis- and trans-alkene complexes of the chiral rhenium Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+: binding selectivities and isomerization processes Organometallics. 12: 2686-2698. DOI: 10.1021/Om00031A044  0.444
1993 Zhou Y, Gladysz JA. Synthesis and reactivity of bimetallic bridging haloalkyl complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)X(CH2)xM(CO)5]+ BF4- (X = iodo, bromo, chloro; M = rhenium, manganese; x = 1, 4) Organometallics. 12: 1073-1078. DOI: 10.1021/om00028a023  0.366
1993 Richter-Addo GB, Knight DA, Dewey MA, Arif AM, Gladysz JA. New strategies for enantioselective syntheses of 1-alkyl- and 1,4-dialkyl-1,2,3,4-tetrahydroisoquinolines: diastereoselective additions of nucleophiles and electrophiles to isoquinoline mediated by an easily resolved and recycled chiral transition metal auxiliary Journal of the American Chemical Society. 115: 11863-11873. DOI: 10.1021/Ja00078A026  0.53
1993 Zhou Y, Seyler JW, Weng W, Arif AM, Gladysz JA. New families of coordinated carbon: oxidative coupling of an ethynyl complex to isolable and crystallographically characterized MC.tplbond.CC.tplbond.CM and +M:C:C:C:C:M+ assemblies Journal of the American Chemical Society. 115: 8509-8510. DOI: 10.1021/Ja00071A095  0.305
1993 Klein DP, Méndez N, Seyler JW, Arif AM, Gladysz J. Structures of propionaldehyde, butyraldehyde, and pivalaldehyde complexes of the chiral rhenium fragment [(η5-C5H5)Re(NO)(PPh3)]+ Journal of Organometallic Chemistry. 450: 157-164. DOI: 10.1016/0022-328X(93)80152-2  0.535
1992 Dewey MA, Knight DA, Arif AM, Gladysz JA. Synthesis and Structure of σr-Complexes of the Chiral Rhenium Lewis Acid [(η5-C5H5)Re(NO)(PPh3)]+ and Aromatic Nitrogen Heterocycles Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 47: 1175-1184. DOI: 10.1515/Znb-1992-0820  0.5
1992 Ramsden JA, Weng W, Gladysz JA. Deprotonation of rhenium terminal acetylide complexes (.eta.5-C5R5)Re(NO)(PPh3)(C.tplbond.CH): generation and reactivity of rhenium/lithium C2 complexes Organometallics. 11: 3635-3645. DOI: 10.1021/Om00059A029  0.471
1992 Zwick BD, Dewey MA, Knight DA, Buhro WE, Arif AM, Gladysz JA. Synthesis, structure, dynamic behavior, and reactivity of chiral rhenium primary phosphine and phosphido complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(PRH2)]+X- and (.eta.5-C5H5)Re(NO)(PPh3) [P(:)RH] Organometallics. 11: 2673-2685. DOI: 10.1021/Om00043A061  0.683
1992 Agbossou F, Ramsden JA, Huang YH, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of (pentamethylcyclopentadienyl)rhenium aldehyde complexes [(.eta.5-C5Me5)Re(NO)(PPh3)(.eta.2-O:CHR)]+ BF4-: highly diastereoselective deuteride additions Organometallics. 11: 693-701. DOI: 10.1021/Om00038A029  0.373
1992 Saura-Llamas I, Dalton DM, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of chiral rhenium carboxylic and carbonic acid ester complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(X)X')]+ X''- Organometallics. 11: 683-693. DOI: 10.1021/Om00038A028  0.425
1992 Klein DP, Gladysz JA. Activation of organic carbonyl compounds by Lewis acids: relative reactivities of .sigma. and .pi. adducts toward nucleophiles and implications for enantioselective addition reactions Journal of the American Chemical Society. 114: 8710-8711. DOI: 10.1021/Ja00048A060  0.301
1992 Ramsden JA, Weng W, Arif AM, Gladysz JA. A versatile new route to carbon complexes of the formula LnMC.tplbond.CM'L'n': deprotonation and metalation of the terminal acetylide complex (.eta.5-C5Me5)Re(NO)(PPh3)(C.tplbond.CH) Journal of the American Chemical Society. 114: 5890-5891. DOI: 10.1021/Ja00040A079  0.479
1992 Peng TS, Gladysz JA. Mechanism of equilibration of diastereomeric chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+BF4-. The metal traverses between alkene enantiofaces without dissociation! Journal of the American Chemical Society. 114: 4174-4181. DOI: 10.1021/ja00037a020  0.413
1992 Saura-Llamas I, Gladysz JA. Epimerization of secondary alcohols by new homogeneous, low oxidation-state metal catalysts: carbon-hydrogen bond activation in rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR') Journal of the American Chemical Society. 114: 2136-2144. DOI: 10.1021/Ja00032A030  0.319
1992 Agbossou SK, Roger C, Igau A, Gladysz JA. Synthesis and reactivity of chiral metal fluoride and water complexes derived from the rhenium fragment [(.eta.5-C5H5)Re(NO)(PPh3)]+ Inorganic Chemistry. 31: 419-424. DOI: 10.1021/Ic00029A014  0.489
1992 Roger C, Peng T, Gladysz J. Synthesis and reactivity of bridging bis(alkyl) and bis(alkylidene) complexes derived from the chiral rhenium fragment [η5-C5H5)Re(NO)(PPh3)]+ Journal of Organometallic Chemistry. 439: 163-175. DOI: 10.1016/0022-328X(92)80227-O  0.49
1992 Peng T, Arif AM, Gladysz JA. Thermodynamic Enantioface-Binding Selectivities of Monosubstituted Alkenes to a Highly Discriminating Chiral Transition -MetalLewis Acid; equilibration of diastereoisomeric (cyclopentadienyl)(alkene)(nitrosyl)(triphenylphosphine)rhenium complexes ([Re(?5-C5H5)(CH2 = CHR)(NO) (PPh3)]+BF4?) Helvetica Chimica Acta. 75: 442-456. DOI: 10.1002/Hlca.19920750204  0.442
1992 Dewey MA, Knight DA, Arif A, Gladysz JA. Synthesis, Structure, and Reactivity of Chiral Rhenium Amido Complexes of the Formula (η5‐C5H5)Re(NO)(PPh3)(NRR') Chemische Berichte. 125: 815-824. DOI: 10.1002/Cber.19921250410  0.538
1991 Dalton DM, Gladysz JA. Synthesis and characterization of chiral rhenium σ-ketone complexes. Binding properties of symmetrical ketones and alkylcyclohexanones Journal of the Chemical Society, Dalton Transactions. 2741-2747. DOI: 10.1039/Dt9910002741  0.494
1991 Ramsden JA, Agbossou F, Senn DR, Gladysz JA. Reactions of the terminal rhenium acetylide complex Re(η5- C5H5)(NO)(PPh3)(C≡CH) and butyllithium; generation, alkylation and stannylation of lithiocarbide complexes of the formula Re(η5-C5H4)(NO)(PPh 3)(C≡CLi) (X = H, Li) Journal of the Chemical Society, Chemical Communications. 1360-1362. DOI: 10.1039/C39910001360  0.544
1991 Dewey MA, Arif AM, Gladysz JA. Synthesis and structure of the rhenium phenylamido complex re(η5-C5H5)(NO)(PPh3)(NHPh); an unprecedented pyramidal amido ligand Journal of the Chemical Society, Chemical Communications. 712-714. DOI: 10.1039/C39910000712  0.469
1991 Roger C, Bodner GS, Hatton WG, Gladysz JA. Mechanism of isomerization of rhenium alkylidene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(:CRCHR'R'')]+X- to alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(RHC:CR'R'')]+X-: an organometallic Wagner-Meerwein-type rearrangement Organometallics. 10: 3266-3274. DOI: 10.1021/Om00055A051  0.476
1991 Saura-Llamas I, Garner CM, Gladysz JA. A new catalyst for the epimerization of secondary alcohols: carbon-hydrogen bond activation in the rhenium alkoxide complexes (.eta.5-C5R5)Re(NO)(PPh3)(OCHRR') Organometallics. 10: 2533-2535. DOI: 10.1021/Om00054A003  0.587
1991 Igau A, Gladysz JA. Reactions of the neohexyl iodide complex [(.eta.5-C5H5)Re(NO)(PPh3)(ICH2CH2C(CH3)3)]+BF4- and nucleophiles: stereochemistry of carbon-iodine bond cleavage in highly accelerated SN2 reactions Organometallics. 10: 2327-2334. DOI: 10.1021/Om00053A040  0.512
1991 Quiros Mendez N, Arif AM, Gladysz JA. Synthesis, structure, and dynamic behavior of rhenium sulfide and sulfoxide complexes of the formula [(.eta.5-C5H5)Re(NO)(L)(XRR')]+X'- (X = S, SO) Organometallics. 10: 2199-2209. DOI: 10.1021/Om00053A024  0.417
1991 Ramsden JA, Garner CM, Gladysz JA. Facile separations of enantiomers of chiral organometallic compounds with a Bakerbond Chiralcel HPLC column Organometallics. 10: 1631-1633. DOI: 10.1021/Om00051A066  0.542
1991 Lichtenberger DL, Rai-Chaudhuri A, Seidel MJ, Gladysz JA, Agbossou SK, Igau A, Winter CH. Delocalized electronic interactions in chiral cyclopentadienylrhenium halide complexes. Valence photoelectron spectra of CpRe(NO)(L)X [Cp = .eta.5-C5H5, .eta.5-C5(CH3)5; L = CO, P(C6H5)3; X = Cl, Br, I] Organometallics. 10: 1355-1364. DOI: 10.1021/Om00051A028  0.673
1991 Kowalczyk JJ, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of chiral rhenium alkyne complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(RC.tplbond.CR')]+BF4- Organometallics. 10: 1079-1088. DOI: 10.1021/Om00050A045  0.527
1991 Lee KE, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of functionalized germyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(GePh2X): equilibria involving the germylene complex [(.eta.5-C5H5)Re(NO)(PPh3)(:GePh2)]+ TfO- Organometallics. 10: 751-760. DOI: 10.1021/Om00049A040  0.477
1991 Dalton DM, Garner CM, Fernandez JM, Gladysz JA. A new asymmetric synthesis of cyanohydrins and oxygen-functionalized derivatives: stereoselective addition of cyanide to chiral rhenium aldehyde and ketone complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(O:CRR')]+BF4- The Journal of Organic Chemistry. 56: 6823-6829. DOI: 10.1021/Jo00024A023  0.673
1991 Dewey MA, Knight DA, Klein DP, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of chiral rhenium amine complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(NRR'R'')]+ TfO- Inorganic Chemistry. 30: 4995-5002. DOI: 10.1021/Ic00026A026  0.502
1991 Igau A, Gladysz J. Synthesis and chemistry of secondary alkyl iodide complexes of the formula[(η5-C5H5)Re(NO)(PPh3)(ICHRR′)]+BF4− Polyhedron. 10: 1903-1909. DOI: 10.1016/S0277-5387(00)86054-4  0.486
1991 Klein DP, Dalton DM, Méndez NQ, Arif AM, Gladysz JA. π/σ Equilibria in rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(OCRR′)]+X-; a marked electronic effect upon the binding mode Journal of Organometallic Chemistry. 412: C7-C10. DOI: 10.1016/0022-328X(91)86066-Y  0.41
1991 Kowalczyk JJ, Arif AM, Gladysz JA. Synthesis, Structure, and Reactivity of Chiral Rhenium Cycloalkene Complexes of the Formula; Facile Vinylic Deprotonation of a Coordinated Alkene Chemische Berichte. 124: 729-742. DOI: 10.1002/Cber.19911240410  0.399
1991 Lee KE, Arif AM, Gladysz JA. Synthesis and Reactivity of Functionalized Dimethylsilyl Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(SiMe2X); New Base-Stabilized Silylene Complexes, Novel Lewis Acid Adducts, and Evidence for Base-Free Silylene Complexes Chemische Berichte. 124: 309-320. DOI: 10.1002/Cber.19911240211  0.548
1990 Peng TS, Gladysz JA. A new carbon-hydrogen bond activation reaction: stereospecific abstraction of vinylic protons from rhenium alkene complexes [(.eta.5-C5H5)Re(NO)(PPh3)(H2C:CHR)]+ BF4- by the base tert-BuO-K+ Organometallics. 9: 2884-2886. DOI: 10.1021/Om00161A016  0.485
1990 Crocco GL, Lee KE, Gladysz JA. Reactions of the rhenium cyanomethyl complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) and ylide complex [(.eta.5-C5H5)Re(NO)(PPh3)(CH2P(p-tol)3))]+PF6- with n-BuLi/TMEDA: generation, stereospecific alkylation, and basicity of transition-metal-substituted carbanions and ylides Organometallics. 9: 2819-2831. DOI: 10.1021/Om00160A034  0.541
1990 Dewey MA, Gladysz JA. Mechanism of equilibration of diastereomeric rhenium amide complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(NHCHRR'): rhenium versus carbon epimerization Organometallics. 9: 1351-1353. DOI: 10.1021/Om00118A084  0.522
1990 Dewey MA, Bakke JM, Gladysz JA. Synthesis and reactivity of chiral rhenium amine and amide complexes of the formulas [(.eta.5-C5H5)Re(NO)PPh3)(NHRR')]+TfO- and (.eta.5C5H5)Re(NO)(PPh3)NRR') Organometallics. 9: 1349-1351. DOI: 10.1021/Om00118A083  0.535
1990 Bodner GS, Peng TS, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of chiral rhenium alkene complexes of the formula [(.eta.5-C5H5)Re(NO)PPh3)(H2C:CHR)]+ X- Organometallics. 9: 1191-1205. DOI: 10.1021/Om00118A047  0.513
1990 Agbossou SK, Bodner GS, Patton AT, Gladysz JA. Synthesis, structure, and reactivity of the chiral rhenium phenyl complex (.eta.5-C5H5)Re(NO)(PPh3)(C6H5) Organometallics. 9: 1184-1191. DOI: 10.1021/Om00118A046  0.521
1990 Dalton DM, Fernandez JM, Emerson K, Larsen RD, Arif AM, Gladysz JA. Selective activation of one methyl ketone enantioface via .sigma.-binding to a chiral transition-metal template: synthesis, structure, and reactivity of rhenium ketone complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.1-O:C(CH3)R)]+X- Journal of the American Chemical Society. 112: 9198-9212. DOI: 10.1021/Ja00181A024  0.457
1990 Garner CM, Quiros Mendez N, Kowalczyk JJ, Fernandez JM, Emerson K, Larsen RD, Gladysz JA. Selective binding and activation of one aldehyde enantioface by a chiral transition-metal Lewis acid: synthesis, structure, and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-O:CHR)]+X- Journal of the American Chemical Society. 112: 5146-5160. DOI: 10.1021/Ja00169A024  0.675
1990 Lee KE, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of the nitrosyl ligand/Lewis acid adduct (.eta.5-C5H5)Re(NO-BCl3)(PPh3)(SiMe2Cl) Inorganic Chemistry. 29: 2885-2887. DOI: 10.1021/Ic00341A005  0.481
1990 Peng T, Gladysz JA. Regiospecific, diastereospecific and enantiospecific nucleophilic additions to chiral monosubstituted alkene complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(H2CCHR)]+ BF4− Tetrahedron Letters. 31: 4417-4420. DOI: 10.1016/S0040-4039(00)97636-6  0.545
1990 Dewey MA, Arif AM, Gladysz JA. Syntheses and structures of σ-pyridine, quinoline, and isoquinoline complexes of the formula [(η5-C5H5)Re(NO)(PPh3)(NCxHy)]+ CF3SO3− Journal of Organometallic Chemistry. 384. DOI: 10.1016/0022-328X(90)87079-S  0.539
1990 Kowalczyk JJ, Agbossou SK, Gladysz JA. Generation and reactivity of the chiral rhenium chlorobenzene complex [(η5-C5H5)Re(NO)(PPh3)(ClC6H5)]+BF−4: an improved functional equivalent of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+BF−4 Journal of Organometallic Chemistry. 397: 333-346. DOI: 10.1016/0022-328X(90)85333-T  0.526
1990 Huang Y, Niedercorn F, Arif AM, Gladysz J. Optical resolution and absolute configuration of the chiral pentamethylcyclopentadienylrhenium carbonyl complex [(η5-C5Me5)Re(NO)(PPh3)(CO)]+ BF4− Journal of Organometallic Chemistry. 383: 213-225. DOI: 10.1016/0022-328X(90)85133-J  0.493
1990 GARNER CM, QUIROS MENDEZ N, KOWALCZYK JJ, FERNANDEZ JM, EMERSON K, LARSEN RD, GLADYSZ JA. ChemInform Abstract: Selective Binding and Activation of One Aldehyde Enantioface by a Chiral Transition-Metal Lewis Acid: Synthesis, Structure, and Reactivity of Rhenium Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η2-O=CHR))+X-. Cheminform. 21. DOI: 10.1002/chin.199041267  0.653
1990 AGBOSSOU SK, SMITH WW, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(ROH))+BF- 4. Cheminform. 21. DOI: 10.1002/chin.199034241  0.376
1990 AGBOSSOU SK, FERNANDEZ JM, GLADYSZ JA. ChemInform Abstract: Synthesis and Properties of Chiral Rhenium Ether Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(OR2))+X-. Cheminform. 21. DOI: 10.1002/chin.199022247  0.416
1990 GARNER CM, FERNANDEZ JM, GLADYSZ JA. ChemInform Abstract: Stereoselective Addition of Cyanide Ion to Chiral Rhenium π-Aldehyde Complexes of the Formulae ((η5-C5H5)Re(NO)(PPh3)(η2-O=CHR))+ BF4-. A New Synthesis of Optically Active Cyanohydrin Derivatives. Cheminform. 21. DOI: 10.1002/chin.199009119  0.644
1990 BUHRO WE, ARIF AM, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Functionalized Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PXX′): An Unusual CCl4 1,3-Addition Leading to an Exo-Substituted η4-Cyclopentadiene Complex. Cheminform. 21. DOI: 10.1002/chin.199003250  0.646
1990 DALTON DM, GLADYSZ JA. ChemInform Abstract: Highly Stereoselective Reduction of Methyl Ketone Complexes of the Chiral Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+ by K((s-C4H9)3BH). Synthesis of Optically Active Secondary Alcohols and Derivatives. Cheminform. 21. DOI: 10.1002/chin.199003109  0.37
1990 Agbossou SK, Smith WW, Gladysz JA. Synthesis and Reactivity of Chiral Rhenium Alcohol Complexes of the Formula [(η5‐C5H5)Re(NO)(PPh3)(ROH)]⊕BF4⊖ Chemische Berichte. 123: 1293-1299. DOI: 10.1002/Cber.19901230612  0.548
1990 Méndez NQ, Mayne CL, Gladysz JA. Thermodynamic Aldehyde Enantioface Binding Selectivities in Complexes of Chiral Metal Fragments; Mechanism of Interconversion of Diastereomericπ-Aldehyde Complexes[(η5-C5H5)Re(NO)(PPh3)(η2-OCHAr)]BF4 Angewandte Chemie International Edition in English. 29: 1475-1476. DOI: 10.1002/Anie.199014751  0.496
1990 Méndez NQ, Arif AM, Gladysz JA. π/σ Equilibria in Metal Complexes of Organic Carbonyl Compounds; Synthesis and Structure of Chiral Rhenium Complexes[(η5-C5H5)Re(NO)(PPh3)(O CHAr)]X Angewandte Chemie International Edition in English. 29: 1473-1474. DOI: 10.1002/Anie.199014731  0.505
1990 Médez NQ, Mayne CL, Gladysz JA. Thermodynamisch kontrollierte enantiofaciale Selektivität bei der Bindung von Aldehyden an chirale Metallkomplex-Fragmente – der Mechanismus der Interkonversion diastereomerer π-Aldehyd-Komplexe [(η5-C5H5) Re(NO)(PPh3)(η2-O = CHAr)]BF4 Angewandte Chemie. 102: 1509-1511. DOI: 10.1002/Ange.19901021246  0.492
1990 Méndez NQ, Arif AM, Gladysz JA. π/σ-Gleichgewichte in Metall-Komplexen organischer Carbonylverbindungen: Synthese und Struktur chiraler Rhenium-Komplexe [(η5-C5H5) Re (NO) (PPh3)(O=CHAr)]X Angewandte Chemie. 102: 1507-1509. DOI: 10.1002/Ange.19901021245  0.47
1989 Bodner GS, Emerson K, Larsen RD, Gladysz JA. Synthesis and structure of chiral rhenium allyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CH2C(R') = CHR) Organometallics. 8: 2399-2404. DOI: 10.1021/Om00112A022  0.5
1989 Czech PT, Gladysz JA, Fenske RF. The role of virtual halogen d orbitals in the stability and reactivity of rhenium alkyl halide complexes of the form [(.eta.5-C5H5)Re(NO)(PPh3)(XR)]+ Organometallics. 8: 1806-1810. DOI: 10.1021/om00109a038  0.373
1989 Winter CH, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of bridging halide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)]2X+ BF4-. Preferential binding of one enantiomer of halide complexes (.eta.5-C5H5)Re(NO)(PPh3)(X) by the chiral Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ Organometallics. 8: 219-225. DOI: 10.1021/Om00103A028  0.695
1989 Fernandez JM, Gladysz JA. Synthetic approaches to the chiral, pyramidal, transition-metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+X-. Generation, characterization, and reactions of a dichloromethane adduct Organometallics. 8: 207-219. DOI: 10.1021/Om00103A027  0.453
1989 Winter CH, Veal WR, Garner CM, Arif AM, Gladysz JA. Synthesis, structure, and reactivity of stable alkyl and aryl iodide complexes of the formula [(.eta.5-C5H5(Re(NO)(PPh3)(IR)]+BF4- Journal of the American Chemical Society. 111: 4766-4776. DOI: 10.1021/Ja00195A033  0.785
1989 Garner CM, Fernández JM, Gladysz JA. Stereoselective addition of cyanide ion to chiral rhenium π-aldehyde complexes of the formulae [(η5-C5H5)Re(NO)(PPh3)(η2-OCHR)]+ BF4-. A new synthesis of optically active cyanohydrin derivatives Tetrahedron Letters. 30: 3931-3934. DOI: 10.1016/S0040-4039(00)99287-6  0.705
1989 Dalton DM, Gladysz JA. Highly stereoselective reduction of methyl ketone complexes of the chiral Lewis acid [(η5-C5H5)Re(NO)(PPh3)]+ by K(s-C4H9)3BH; synthesis of optically active secondary alcohols and derivatives Journal of Organometallic Chemistry. 370: C17-C21. DOI: 10.1016/0022-328X(89)87307-3  0.528
1989 WINTER CH, VEAL WR, GARNER CM, ARIF AM, GLADYSZ JA. ChemInform Abstract: Synthesis, Structure, and Reactivity of Stable Alkyl and Aryl Iodide Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(IR))+BF- 4. Cheminform. 20. DOI: 10.1002/chin.198940283  0.772
1989 FERNANDEZ JM, GLADYSZ JA. ChemInform Abstract: Synthetic Approaches to the Chiral, Pyramidal, Transition-Metal Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+X-. Generation, Characterization, and Reactions of a Dichloromethane Adduct. Cheminform. 20. DOI: 10.1002/chin.198917290  0.361
1989 CROCCO GL, YOUNG CS, LEE KE, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Functionalized Rhenium Silyl Complexes (η5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic Rearrangements Leading to the Disilametallacycle Cyclic (η5-C5H4Si(CH3)2)Re(NO)(PPh3)(Si(CH3)2). Cheminform. 20. DOI: 10.1002/chin.198905244  0.429
1988 Senn DR, Wong A, Patton AT, Marsi M, Strouse CE, Gladysz JA. Synthesis, structure, and reactions of chiral rhenium vinylidene and acetylide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(X)]n+. Vinylidene complexes that are formed by stereospecific C.beta. electrophilic attack, exist as two Re=C=C geometric isomers, and undergo stereospecific C.alpha. nucleophilic attack. Journal of the American Chemical Society. 110: 6096-109. PMID 22148786 DOI: 10.1021/Ja00226A026  0.365
1988 Fernández JM, Emerson K, Larsen RD, Gladysz JA. The selective activation of one methyl ketone enantioface viaσ-binding to a chiral metal template: synthesis and reactivity of rhenium ketone complexes [(η5-C5H5)Re(NO)(PPh3)(η1-Me(R)CO)]+PF6– Journal of the Chemical Society, Chemical Communications. 37-39. DOI: 10.1039/C39880000037  0.435
1988 Crocco GL, Young CS, Lee KE, Gladysz JA. Synthesis and reactivity of functionalized rhenium silyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(SiR2X). Anionic rearrangements leading to the disilametallacycle [cyclic] [.eta.5-C5H4Si(CH3)2]Re(NO)(PPh3)[Si(CH3)2] Organometallics. 7: 2158-2162. DOI: 10.1021/Om00100A012  0.517
1988 Bodner GS, Fernandez JM, Arif AM, Gladysz JA. Selective binding of one enantioface of monosubstituted alkenes to the chiral transition metal Lewis acid [(.eta.5-C5H5)Re(NO)(PPh3)]+ Journal of the American Chemical Society. 110: 4082-4084. DOI: 10.1021/Ja00220A082  0.532
1988 Buhro WE, Zwick BD, Georgiou S, Hutchinson JP, Gladysz JA. Synthesis, structure, dynamic behavior, and reactivity of rhenium phosphido complexes (.eta.5-C5H5)Re(NO)(PPh3)(PR2): the gauche effect in transition-metal chemistry Journal of the American Chemical Society. 110: 2427-2439. DOI: 10.1021/Ja00216A015  0.621
1988 Huang YH, Gladysz JA. Aldehyde and ketone ligands in organometallic complexes and catalysis Journal of Chemical Education. 65: 298. DOI: 10.1021/Ed065P298  0.381
1988 Lee KE, Gladysz JA. Synthesis and reactivity of functionalized rhenium germyl complexes (η5-C5H5)Re(NO)(PPh3)(GePh2X); dynamic equilibria with germylene complex [(η5-C5H5)Re(NO)(PPh3)(GePh2)]+X- Polyhedron. 7: 2209-2211. DOI: 10.1016/S0277-5387(00)81806-9  0.544
1988 Winter CH, Gladysz JA. Generation of the dichloromethane complex [(η5-C5Me5)Re(NO)(PPh3)(ClCH2Cl]+ BF4-, and its conversion to the oxidative addition product [(η5-C5Me5)Re(NO)(PPh3)(Cl)(CH2Cl)]+ BF4- Journal of Organometallic Chemistry. 354. DOI: 10.1016/0022-328X(88)80664-8  0.699
1988 CROCCO GL, GLADYSZ JA. ChemInform Abstract: Divergent Kinetic and Thermodynamic Acidity in Organo-Transition-Metal Hydride Complexes: Synthesis, Structure, and Reactivity of the Rhenium Anion of Li+((η5-C5H5)Re(NO)(PPh3))-. Cheminform. 19. DOI: 10.1002/chin.198851285  0.395
1988 BODNER GS, FERNANDEZ JM, ARIF AM, GLADYSZ JA. ChemInform Abstract: Selective Binding of One Enantioface of Monosubstituted Alkenes to the Chiral Transition Metal Lewis Acid ((η5-C5H5)Re(NO)(PPh3))+. Cheminform. 19. DOI: 10.1002/chin.198840221  0.334
1988 BUHRO WE, ZWICK BD, GEORGIOU S, HUTCHINSON JP, GLADYSZ JA. ChemInform Abstract: Synthesis, Structure, Dynamic Behavior, and Reactivity of Rhenium Phosphido Complexes (η5-C5H5)Re(NO)(PPh3)(PR2). The “Gauche Effect” in Transition-Metal Chemistry. Cheminform. 19. DOI: 10.1002/chin.198831246  0.614
1988 CROCCO GL, GLADYSZ JA. ChemInform Abstract: Reactions of (Cyclopentadienyl)rhenium Halide Complexes (η5-C5H5)Re(NO)(PPh3)(X) with n-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands. Cheminform. 19. DOI: 10.1002/chin.198818282  0.4
1988 BODNER GS, SMITH DE, HATTON WG, HEAH PC, GEORGIOU S, RHEINGOLD AL, GEIB SJ, HUTCHINSON JP, GLADYSZ JA. ChemInform Abstract: Synthesis, Structure, and Alkylation of Chiral Vinylrhenium Complexes (η5-C5H5)Re(NO)(PPh3)(CX=CHR) (X: H, OCH3). A Mechanistic Study of 1,3-Asymmetric Induction from Rhenium to Carbon. Cheminform. 19. DOI: 10.1002/chin.198813288  0.413
1988 WINTER CH, ARIF AM, GLADYSZ JA. ChemInform Abstract: A General Class of Stable Alkyl Halide Complexes: Synthesis, Structure, and Reactivity of Alkyl Iodide Complexes of the Formula ((η5-C5H5)Re(NO)(PPh3)(IR))+BF- 4. Cheminform. 19. DOI: 10.1002/chin.198812273  0.652
1988 Crocco GL, Gladysz JA. Reactions of (cyclopentadienyl)rhenium halide complexes (η5-C5H5)Re(NO)(PPh3)(X) withn-BuLi/TMEDA; Generation and Methylation of Lithio- and Dilithiocyclopentadienyl Ligands Chemische Berichte. 121: 375-377. DOI: 10.1002/Cber.19881210227  0.537
1987 Bodner GS, Patton AT, Smith DE, Georgiou S, Tam W, Wong WK, Strouse CE, Gladysz JA. Crystallographic and theoretical analyses of the structures of rhenium formyl and acyl complexes of the formula (.eta.5-C5H5)Re(NO)(PR3)(COR') Organometallics. 6: 1954-1961. DOI: 10.1021/Om00152A021  0.48
1987 Bodner GS, Gladysz JA, Folmer Nielsen M, Parker VD. Electrochemical oxidation of rhenium alkyl complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(R): evidence for one-electron charge transfer Organometallics. 6: 1628-1633. DOI: 10.1021/Om00151A006  0.412
1987 Buhro WE, Etter MC, Georgiou S, Gladysz JA, McCormick FB. Synthesis, structure, and reactivity of the thioformaldehyde complex [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-H2C:S)]+ PF6- Organometallics. 6: 1150-1156. DOI: 10.1021/Om00149A003  0.681
1987 Bodner GS, Smith DE, Hatton WG, Heah PC, Georgiou S, Rheingold AL, Geib SJ, Hutchinson JP, Gladysz JA. Synthesis, structure, and alkylation of chiral vinylrhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(CX:CHR) (X = H, OCH3). A mechanistic study of 1,3-asymmetric induction from rhenium to carbon Journal of the American Chemical Society. 109: 7688-7705. DOI: 10.1021/Ja00259A018  0.501
1987 Winter CH, Arif AM, Gladysz JA. A general class of stable alkyl halide complexes: synthesis, structure, and reactivity of alkyl iodide complexes of the formula [(.eta.5-C5H5)Re(NO)(PPh3)(IR)]+ BF4- Journal of the American Chemical Society. 109: 7560-7561. DOI: 10.1021/Ja00258A067  0.682
1987 O'Connor EJ, Kobayashi M, Floss HG, Gladysz JA. A versatile new synthesis of organic compounds with chiral methyl groups: stereochemistry of protolytic rhenium-carbon bond cleavage in chiral alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) Journal of the American Chemical Society. 109: 4837-4844. DOI: 10.1021/Ja00250A014  0.452
1987 Bodner GS, Gladysz JA, Nielsen MF, Parker VD. New mechanistic probes of hydride abstraction from rhenium-alkyl complexes (.eta.5-C5H5)Re(NO)(PPh3)(R) by Ph3C+ PF6-. Evidence for initial electron transfer Journal of the American Chemical Society. 109: 1757-1764. DOI: 10.1021/Ja00240A027  0.329
1987 Senn DR, Gladysz JA, Emerson KE, Larsen RD. Synthesis, structure, and reactivity of transition metal/main group metal bridging carboxylate complexes of the formula (.eta.5-C5H5)Re(NO)(PPh3)(CO2MLn) (M = Li, K, Ge, Sn, Pb) Inorganic Chemistry. 26: 2737-2739. DOI: 10.1021/Ic00264A001  0.354
1987 SENN DR, GLADYSZ JA, EMERSON K, LARSEN RD. ChemInform Abstract: Synthesis, Structure, and Reactivity of Transition-Metal/Main-Group-Metal Bridging Carboxylate Complexes of the Formula (η5-C5H5)Re(NO)(PPh3)(CO2MLn) (M: Li, K, Ge, Sn, Pb). Cheminform. 18. DOI: 10.1002/chin.198749291  0.322
1987 O'CONNOR EJ, KOBAYASHI M, FLOSS HG, GLADYSZ JA. ChemInform Abstract: A Versatile New Synthesis of Organic Compounds with Chiral Methyl Groups: Stereochemistry of Protolytic Rhenium-Carbon Bond Cleavage in Chiral Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R). Cheminform. 18. DOI: 10.1002/chin.198747275  0.353
1987 BODNER GS, GLADYSZ JA, NIELSEN MF, PARKER VD. ChemInform Abstract: New Mechanistic Probes of Hydride Abstraction from Rhenium-Alkyl Complexes (η5-C5H5)Re(NO)(PPh3)(R) by Ph3C+PF- 6; Evidence for Initial Electron Transfer. Cheminform. 18. DOI: 10.1002/chin.198731267  0.368
1987 FERNANDEZ JM, EMERSON K, LARSEN RH, GLADYSZ JA. ChemInform Abstract: A General Method for the Selective Binding and Activation of One Aldehyde Enantioface: Synthesis and Reactivity of Rhenium Aldehyde Complexes ((η5-C5H5)Re(NO)(PPh3)(η2-RCH=O))+PF- 6. Cheminform. 18. DOI: 10.1002/chin.198719267  0.383
1987 MCCORMICK FB, GLEASON WB, ZHAO X, HEAH PC, GLADYSZ JA. ChemInform Abstract: Metal Complexes of Sulfur-Containing Ligands. Synthesis and Properties of a Series of Rhenium-Substituted Sulfonium Salts ((η5-C5H5)Re(NO)(PPh3)(CH2-))nS+(CH3)3-n (n = 1-3). Cheminform. 18. DOI: 10.1002/chin.198703278  0.439
1987 CROCCO GL, GLADYSZ JA. ChemInform Abstract: Reaction of the Ylide Complex ((η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3))PF6- with n-Butyl-lithium - Tetramethylethylenediamine. Generation and Stereospecific Alkylation of a Transition Metal-Substituted Wittig Reagent. Cheminform. 18. DOI: 10.1002/chin.198702284  0.401
1986 Crocco GL, Gladysz JA. Reaction of the ylide complex [(η5-C5H5)Re(NO)(PPh3)(CH2P+Ar3)]PF6– with η-butyl-lithium–tetramethylenediamine; generation and stereospecific alkylation of a transition metal-substituted Wittig reagent Journal of the Chemical Society, Chemical Communications. 1154-1156. DOI: 10.1039/C39860001154  0.534
1986 McCormick FB, Gleason WB, Zhao X, Heah PC, Gladysz JA. Metal complexes of sulfur-containing ligands. Synthesis and properties of a series of rhenium-substituted sulfonium salts [(.eta.5-C5H5)Re(NO)(PPh3)(CH2)]nS+(CH3)3-n(n = 1-3) Organometallics. 5: 1778-1785. DOI: 10.1021/Om00140A004  0.528
1986 Vaughn GD, Krein KA, Gladysz JA. Synthesis and reactivity of metallacyclic manganese .alpha.-(silyloxy)alkyl complexes [cyclic] (CO)4MnC(R)(OSi(CH3)3)P(C6H5)2. A new thermodynamic driving force for carbonyl insertion Organometallics. 5: 936-942. DOI: 10.1021/Om00136A016  0.473
1986 Fernandez JM, Emerson K, Larsen RH, Gladysz JA. A general method for the selective binding and activation of one aldehyde enantioface. Synthesis and reactivity of rhenium aldehyde complexes [(.eta.5-C5H5)Re(NO)(PPh3)(.eta.2-RCHO)]+ PF6- Journal of the American Chemical Society. 108: 8268-8270. DOI: 10.1021/Ja00286A030  0.368
1986 Selover JC, Vaughn GD, Strouse CE, Gladysz JA. Synthesis and reactivity of metal .alpha.-hydroxyalkyl complexes; generation of (CO)5MCH(C6H5)OH (M = Mn, Re) Journal of the American Chemical Society. 108: 1455-1462. DOI: 10.1021/Ja00267A015  0.409
1986 Heah PC, Patton AT, Gladysz JA. Deprotonation and anionic rearrangements of organometallic compounds. 5. Kinetic vs. thermodynamic deprotonation in reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases Journal of the American Chemical Society. 108: 1185-1195. DOI: 10.1021/Ja00266A012  0.365
1986 Georgiou S, Gladysz J. Reactions of organorhenium complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+ PF6-; analysis of the energetics of α-hydride abstraction Tetrahedron. 42: 1109-1116. DOI: 10.1016/S0040-4020(01)87514-1  0.532
1986 Crocco GL, Sharp TR, Gladysz JA. Novel electron impact-induced hydrogen rearrangements in the mass spectra of organorhenium hydrides and alkyls International Journal of Mass Spectrometry and Ion Processes. 73: 181-185. DOI: 10.1016/0168-1176(86)80019-2  0.305
1986 VAUGHN GD, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Metallacyclic Manganese α-Hydroxyalkyl Complexes Containing Aliphatic Bridges and Phosphorus and Nitrogen Donor Atoms. First Carbonylation of an Isolable α-Hydroxyalkyl Complex. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198630292  0.309
1986 VAUGHN GD, STROUSE CE, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Stable Metallacyclic Manganese and Rhenium α-Hydroxyalkyl Complexes of the Formula (CO)4MP(C6H5)2(o-C6H4CHOH). Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198630291  0.458
1986 SELOVER JC, VAUGHN GD, STROUSE CE, GLADYSZ JA. ChemInform Abstract: Synthesis and Reactivity of Metal α-Hydroxyalkyl Complexes; Generation of (CO)5MCH(C6H5)OH (M: Mn, Re). Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198630290  0.355
1986 GEORGIOU S, GLADYSZ JA. ChemInform Abstract: Reactions of Organorhenium Complexes (η5-C5H5)Re(NO)(PPh3)(CH2R) with Ph3C+PF6-; Analysis of the Energetics of α-Hydride Abstraction. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198624256  0.4
1986 MARSI M, BRINKMAN KC, LISENSKY CA, VAUGHN GD, GLADYSZ JA. ChemInform Abstract: Reactions of (CO)5MnSi(CH3)3with α-Bromo Carbonyl and Related Organic Compounds. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198602234  0.433
1985 Crocco GL, Gladysz JA. Deprotonation and anionic rearrangements of organometallic compounds. Reactions of the hydride complex (η5-C5H5)Re(NO)(PPh3)(H) with n-butyl-lithium–tetramethylethylenediamine Journal of the Chemical Society, Chemical Communications. 283-284. DOI: 10.1039/C39850000283  0.488
1985 Smith DE, Gladysz JA. Reactions of chiral (.alpha.-methoxyvinyl)rhenium complexes (.eta.5-C5H5)Re(NO)(PPh3)(C(OCH3)=CHR) with alkyl halides. Efficient 1,3-asymmetric induction Organometallics. 4: 1480-1481. DOI: 10.1021/om00127a039  0.391
1985 Asaro MF, Bodner GS, Gladysz JA, Cooper SR, Cooper NJ. Electrochemical oxidation of rhenium alkyl complexes of the type [Re(.eta.-C5H5)(NO)(PPh3)R]: implications for the mechanism of hydride abstraction by Ph3C+PF6- Organometallics. 4: 1020-1024. DOI: 10.1021/Om00125A010  0.513
1985 Marsi M, Brinkman KC, Lisensky CA, Vaughn GD, Gladysz JA. Reactions of (CO)5MnSi(CH3)3 with .alpha.-bromo carbonyl and related organic compounds. Facile reductive silylation The Journal of Organic Chemistry. 50: 3396-3401. DOI: 10.1021/Jo00218A030  0.417
1985 Crocco GL, Gladysz JA. Reaction of the cyanomethyl rhenium complex (.eta.5-C5H5)Re(NO)(PPh3)(CH2CN) with n-BuLi/TMEDA; generation, stereospecific alkylation, and basicity of a transition-metal substituted carbanion Journal of the American Chemical Society. 107: 4103-4104. DOI: 10.1021/Ja00299A071  0.503
1985 Buhro WE, Georgiou S, Hutchinson JP, Gladysz JA. Synthesis, conformation, and reactivity of the rhenium phosphide complex (diphenylphosphido)(triphenylphosphine)nitrosyl(.eta.5-cyclopentadienyl)rhenium. The "Gauche effect" in transition metal chemistry Journal of the American Chemical Society. 107: 3346-3348. DOI: 10.1021/Ja00297A050  0.565
1985 Buhro WE, Gladysz JA. Configurational processes in coordinated ligands. Extremely facile phosphorus inversion in the pyramidal terminal phosphide complexes (.eta.5-C5H5)Re(NO)(PPh3)(PRR') Inorganic Chemistry. 24: 3505-3507. DOI: 10.1021/Ic00216A005  0.66
1985 CROCCO GL, GLADYSZ JA. ChemInform Abstract: REACTION OF THE CYANOMETHYL RHENIUM COMPLEX (η5-C5H5)RE(NO)(PPH3)(CH2CN) WITH N-BULI/TMEDA; GENERATION, STEREOSPECIFIC ALKYLATION, AND BASICITY OF A TRANSITION-METAL SUBSTITUTED CARBANION Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198543317  0.504
1985 BUHRO WE, GEORGIOU S, HUTCHINSON JP, GLADYSZ JA. ChemInform Abstract: SYNTHESIS, CONFORMATION, AND REACTIVITY OF THE RHENIUM PHOSPHIDE COMPLEX (DIPHENYLPHOSPHIDO)(TRIPHENYLPHOSPHINE)NITROSYL(η5-CYCLOPENTADIENYL)RHENIUM# . THE “GAUCHE EFFECT” IN TRANSITION METAL CHEMISTRY Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198538285  0.531
1985 MERRIFIELD JH, FERNANDEZ JM, BUHRO WE, GLADYSZ JA. ChemInform Abstract: CLEAVAGE OF THE RHENIUM-METHYL BOND OF (η-C5H5)RE(NO)(PPH3)(CH3) BY PROTIC AND HALOGEN ELECTROPHILES: STEREOCHEMISTRY AT RHENIUM Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198513259  0.627
1985 NAKAZAWA H, BUHRO WE, BERTRAND G, GLADYSZ JA. ChemInform Abstract: REACTIONS OF PHOSPHORUS ELECTROPHILES WITH ((η5-C5ME5)FE(CO)2)-; SPECTROSCOPIC EVIDENCE FOR A PHOSPHINIDENE COMPLEX Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198507295  0.574
1984 Vaughn GD, Gladysz JA. Hydrogen bonding in organometallic ligands and possible implications for carbon monoxide/hydrogen molecule chemistry, First carbonylation of an isolable metal .alpha.-hydroxyalkyl complex Organometallics. 3: 1596-1598. DOI: 10.1021/Om00088A028  0.438
1984 Brinkman KC, Blakeney AJ, Krone-Schmidt W, Gladysz JA. Alkylation and acylation of the iron carbonyl anion [(CO)4FeSi(CH3)3]-. Evidence for 1,3-silatropic shifts from iron to acyl oxygen Organometallics. 3: 1325-1332. DOI: 10.1021/Om00087A001  0.508
1984 Kiel WA, Buhro WE, Gladysz JA. Reactions of benzylrhenium complexes (.eta.5-C5H5)Re(NO)(L)(CH2Ar) with Ph3C+PF6. Analysis of the Re-C.alpha. rotamers involved in .alpha.-hydride abstraction Organometallics. 3: 879-886. DOI: 10.1021/Om00084A010  0.665
1984 Heah PC, Gladysz JA. Deprotonation and anionic rearrangements of organometallic compounds. 1. Reactions of cyclopentadienylrhenium acyl and alkyl complexes with strong bases Journal of the American Chemical Society. 106: 7636-7637. DOI: 10.1021/Ja00336A062  0.383
1984 Nakazawa H, Buhro WE, Bertrand G, Gladysz JA. Reactions of phosphorus electrophiles with [(.eta.5-C5Me5)Fe(CO)2]-; spectroscopic evidence for a phosphinidene complex Inorganic Chemistry. 23: 3431-3433. DOI: 10.1021/Ic00190A001  0.578
1984 Gladysz JA. New synthetic chemistry of transition metal trialkylsilane complexes Accounts of Chemical Research. 17: 326-332. DOI: 10.1021/Ar00105A005  0.308
1984 Merrifield JH, Fernandez JM, Buhro WE, Gladysz JA. Cleavage of the rhenium-methyl bond of (.eta.-C5H5)Re(NO)(PPh3)(CH3) by protic and halogen electrophiles: stereochemistry at rhenium Inorganic Chemistry. 23: 4022-4029. DOI: 10.1002/Chin.198513259  0.661
1984 VAUGHN GD, KREIN KA, GLADYSZ JA. ChemInform Abstract: REACTIONS OF DIPHENYLPHOSPHINOTRIMETHYLSILANE WITH ALKYLPENTACARBONYLMANGANESE; SYNTHESIS OF YLIDE COMPLEXES AND A NEW THERMODYNAMIC DRIVING FORCE FOR THE INSERTION OF CARBON MONOXIDE Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198430248  0.308
1984 NAKAZAWA H, JOHNSON DL, GLADYSZ JA. ChemInform Abstract: A NEW ROUTE TO METAL ALKYLIDENE COMPLEXES. SYNTHESIS OF YLIDE ADDUCTS (CO)4FE-CH(R)P+AR3 FROM ALDEHYDES, TRIARYLPHOSPHINES, AND (CYCLO) (CO)4FESI(CH3)2CH2CH2SI(CH3)2 Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198411306  0.432
1984 Vaughn GD, Krein KA, Gladysz JA. Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese; Synthesis of the Ylide Complexes and a New Driving Force for CO Insertion Angewandte Chemie International Edition in English. 23: 245-246. DOI: 10.1002/Anie.198402451  0.333
1983 Buhro WE, Wong A, Merrifield JH, Lin GY, Constable AC, Gladysz JA. Synthesis and chemistry of chiral rhenium acyls (.eta.-C5H5)Re(NO)(PPh3)(COR) Organometallics. 2: 1852-1859. DOI: 10.1021/Om50006A026  0.687
1983 Nakazawa H, Johnson DL, Gladysz JA. A new route to metal alkylidene complexes. Synthesis of ylide adducts (CO)4Fe-CH(R)P+Ar3 from aldehydes, triarylphosphines, and [cyclo] (CO)4FeSi(CH3)2CH2CH2Si(CH3)2 Organometallics. 2: 1846-1851. DOI: 10.1021/Om50006A025  0.523
1983 Merrifield JH, Gladysz JA. Synthesis and decarboxylation mechanism of the chiral rhenium formate (.eta.-C5H5)Re(NO)(PPh3)(OCHO) Organometallics. 2: 782-784. DOI: 10.1021/Om00078A022  0.497
1983 Hatton WG, Gladysz JA. Synthesis and chemistry of chiral vinylrhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(CH:CHR'). Stereoselective reactions with electrophiles and a spontaneous alkylidene to olefin rearrangement Journal of the American Chemical Society. 105: 6157-6158. DOI: 10.1021/ja00357a035  0.45
1983 Merrifield JH, Lin GY, Kiel WA, Gladysz JA. Mechanism of coupling of methylidene to ethylene at a homogeneous (triphenylphosphine)nitrosyl(.eta.-cyclopentadienyl)rhenium(+) [(.eta.-C5H5)Re(NO)(PPh3)]+ center. Remarkable enantiomer self-recognition Journal of the American Chemical Society. 105: 5811-5819. DOI: 10.1021/Ja00356A019  0.512
1983 Patton AT, Strouse CE, Knobler CB, Gladysz JA. Syntheses, properties, and x-ray crystal structures of stable methylidene complexes of the formula [(.eta.-C5Me5)Re(NO)(L)(:CH2)]+ PF6- Journal of the American Chemical Society. 105: 5804-5811. DOI: 10.1021/Ja00356A018  0.427
1983 Buhro WE, Patton AT, Strouse CE, Gladysz JA, McCormick FB, Etter MC. Syntheses, chemical properties, and x-ray crystal structures of rhenium formaldehyde and thioformaldehyde complexes Journal of the American Chemical Society. 105: 1056-1058. DOI: 10.1021/Ja00342A070  0.533
1983 Tam W, Marsi M, Gladysz JA. Bimetallic anionic formyl complexes: synthesis and properties Inorganic Chemistry. 22: 1413-1421. DOI: 10.1021/Ic00152A001  0.319
1983 HATTON WG, GLADYSZ JA. ChemInform Abstract: SYNTHESIS AND CHEMISTRY OF CHIRAL VINYLRHENIUM COMPLEXES (η-C5H5)RE(NO)(PPH3)(CH:CHR′). STEREOSELECTIVE REACTIONS WITH ELECTROPHILES AND A SPONTANEOUS ALKYLIDENE TO OLEFIN REARRANGEMENT Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198352284  0.456
1983 MERRIFIELD JH, LIN G, KIEL WA, GLADYSZ JA. ChemInform Abstract: MECHANISM OF COUPLING OF METHYLIDENE TO ETHYLENE AT A HOMOGENEOUS (TRIPHENYLPHOSPHINE)NITROSYL(η-CYCLOPENTADIENYL)RHENIUM(+) ((η-C5H5)RE(NO)(PPH3))+ CENTER. REMARKABLE ENANTIOMER SELF-RECOGNITION Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198350255  0.356
1983 PATTON AT, STROUSE CE, KNOBLER CB, GLADYSZ JA. ChemInform Abstract: SYNTHESES, PROPERTIES, AND X-RAY CRYSTAL STRUCTURES OF STABLE METHYLIDENE COMPLEXES OF THE FORMULA ((η-C5ME5)RE(NO)(L)(:CH2))+ PF6- Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198350254  0.337
1983 BUHRO WE, PATTON AT, STROUSE CE, GLADYSZ JA, MCCORMICK FB, ETTER MC. ChemInform Abstract: SYNTHESES, CHEMICAL PROPERTIES, AND X-RAY CRYSTAL STRUCTURES OF RHENIUM FORMALDEHYDE AND THIOFORMALDEHYDE COMPLEXES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198322296  0.482
1983 MARSI M, GLADYSZ JA. ChemInform Abstract: REACTIONS OF KETALS AND ACETALS WITH (CO)5MNSI(CH3)3. A NEW VINYL ETHER SYNTHESIS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198307143  0.389
1982 Marsi M, Gladysz JA. Reactions of ketals and acetals with (CO)5MnSi(CH3)3. A new vinyl ether synthesis Organometallics. 1: 1467-1473. DOI: 10.1021/Om00071A012  0.488
1982 Merrifield JH, Strouse CE, Gladysz JA. Synthesis, optical resolution, and absolute configuration of pseudotetrahedral organorhenium complexes (.eta.-C5H5)Re(NO)(PPh3)(X) Organometallics. 1: 1204-1211. DOI: 10.1021/Om00069A018  0.468
1982 Brinkman KC, Vaughn GD, Gladysz JA. Substituent effects upon alkyl migration to coordinated CO. Syntheses and carbonylation studies of (CO)5MnCH2I and (CO)5MnCH2OSiMe3 Organometallics. 1: 1056-1060. DOI: 10.1021/Om00068A010  0.342
1982 Tam W, Lin G, Gladysz JA. Syntheses of kinetically unstable neutral formyl complexes via Li(C2H5)3BH and "transformylation" reactions of metal carbonyl cations Organometallics. 1: 525-529. DOI: 10.1021/Om00063A022  0.503
1982 Kiel WA, Lin GY, Constable AG, McCormick FB, Strouse CE, Eisenstein O, Gladysz JA. Synthesis and properties of [(.eta.-C5H5)Re(NO)(PPh3)(:CHC6H5)]+PF6-: a benzylidene complex that is formed by a stereospecific .alpha.-hydride abstraction, exists as two geometric isomers, and undergoes stereospecific nucleophilic attack Journal of the American Chemical Society. 104: 4865-4878. DOI: 10.1021/Ja00382A021  0.477
1982 Tam W, Lin GY, Wong WK, Kiel WA, Wong VK, Gladysz JA. Synthesis and electrophile-induced disproportionation of the neutral formyl triphenylphosphinenitrosyl-.eta.-cyclopentadienylrhenium formyl ((.eta.-C5H5)Re(NO)(PPh3)(CHO)) Journal of the American Chemical Society. 104: 141-152. DOI: 10.1021/Ja00365A027  0.506
1982 Gladysz JA. Transition Metal Formyl Complexes Cheminform. 20: 1-38. DOI: 10.1016/S0065-3055(08)60519-5  0.373
1982 Marsi M, Gladysz J. Organic transformations via metal silane reagents: syntheses of vinyl ethers from dimethyl ketals and (CO)5MnSi(CH3)3 Tetrahedron Letters. 23: 631-634. DOI: 10.1016/S0040-4039(00)86908-7  0.496
1982 KIEL WA, LIN G, CONSTABLE AG, MCCORMICK FB, STROUSE CE, EISENSTEIN O, GLADYSZ JA. ChemInform Abstract: SYNTHESIS AND PROPERTIES OF ((η-C5H5)RE(NO)(PPH3)(:CHC6H5))+PF6-: A BENZYLIDENE COMPLEX THAT IS FORMED BY A STEREOSPECIFIC α-HYDRIDE ABSTRACTION, EXISTS AS TWO GEOMETRIC ISOMERS, AND UNDERGOES STEREOSPECIFIC NUCLEOPHILIC ATTACK Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198250253  0.393
1982 TAM W, LIN G, WONG W, KIEL WA, WONG VK, GLADYSZ JA. ChemInform Abstract: SYNTHESIS AND ELECTROPHILE-INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL TRIPHENYLPHOSPHINENITROSYL-η-CYCLOPENTADIENYLRHENIUM FORMYL ((η-C5H5)RE(NO)(PPH3)(CHO)) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198217289  0.428
1982 Blakeney AJ, Johnson DL, Donovan PW, Gladysz JA. Synthesis Of Iron Carbonyl Trimethylsilanes: Preparations And Interconversions Of Cis-(Co)4Fe(Si(Ch3)3)2, M+((Co)4Fesi(Ch3)3)-, And Trans- (Fe(Co)4Si(Ch3)3)2 Cheminform. 13. DOI: 10.1002/Chin.198213278  0.435
1981 Blakeney AJ, Johnson DL, Donovan PW, Gladysz JA. Synthesis of iron carbonyl trimethylsilanes: preparations and interconversions of cis-(CO)4Fe[Si(CH3)3]2, M+[(CO)4FeSi(CH3)3]-, and trans- [Fe(CO)4Si(CH3)3]2 Inorganic Chemistry. 20: 4415-4419. DOI: 10.1021/Ic50226A076  0.435
1981 Johnson DL, Gladysz JA. Reactions of (CO)5MnSi(CH3)3 with organic carbonyl compounds Inorganic Chemistry. 20: 2508-2515. DOI: 10.1021/Ic50222A028  0.452
1981 Selover J, Marsi M, Parker DW, Gladysz J. Mononuclear anionic formyl complexes; synthesis and properties Journal of Organometallic Chemistry. 206: 317-329. DOI: 10.1016/S0022-328X(00)83029-6  0.368
1981 McCormick FB, Gladysz J. Exploratory organometal-sulfur chemistry; syntheses and unusual properties of rhenium CH2SR, CHSRR′, and CHSR]+ complexes Journal of Organometallic Chemistry. 218: C57-C61. DOI: 10.1016/S0022-328X(00)81018-9  0.517
1981 J. Blakeney A, Gladysz J. New deoxygenative transformations; reactions of (CO)4Fe[Si(CH3)3]2 with acyclic ethers Journal of Organometallic Chemistry. 210: 303-312. DOI: 10.1016/S0022-328X(00)80889-X  0.507
1981 Blakeney AJ, Gladysz J. Preparation and alkylation reactions of K+[(CO)4FeSi(CH3)3]−; Reductive elimination of tetramethylsilane from isolable (CO)4FeRSi(CH3)3 complexes Inorganica Chimica Acta. 53: L25-L27. DOI: 10.1016/S0020-1693(00)84730-1  0.511
1981 JOHNSON DL, GLADYSZ JA. ChemInform Abstract: REACTIONS OF (CO)5MNSI(CH3)3 WITH ORGANIC CARBONYL COMPOUNDS Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198145274  0.349
1981 BLAKENEY AJ, GLADYSZ JA. ChemInform Abstract: PREPARATION AND ALKYLATION REACTIONS OF K+((CO)4FESI(CH3)3)-; REDUCTIVE ELIMINATION OF TETRAMETHYLSILANE FROM ISOLABLE (CO)4FERSI(CH3)3 COMPLEXES Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198119286  0.418
1980 Hanlan AJL, Ugolick RC, Fulcher JG, Togashi S, Bocarsly AB, Gladysz JA. Chemistry via metal atom cocondensation: isomerization and complexation reactions of organocyclopropanes and spirocycles Inorganic Chemistry. 19: 1543-1551. DOI: 10.1021/Ic50208A023  0.332
1980 Blakeney A, Gladysz J. Preparation and properties of (η-C5H5)2ZrCl[Si(CH3)3] and (η-C5H5)2Zr[Si(CH3)3]2; trimethylsilyl group transfer from mercury to zirconium Journal of Organometallic Chemistry. 202: 263-267. DOI: 10.1016/S0022-328X(00)92674-3  0.496
1980 W. Parker D, Marsi M, Gladysz J. Substitution mechanisms at metal carbonyl centers; conversion of Ph3P(CO)4ReBr to Ph3P(CO)4ReCH3 via an anionic acyl intermediate Journal of Organometallic Chemistry. 194: C1-C4. DOI: 10.1016/S0022-328X(00)90345-0  0.476
1980 Constable AG, Gladysz JA. Stereospecific and chemospecific interconversions of the rhenium alkylidene [(η-C5H5)Re(NO)(PPh3)(CHC6H5)]+PF6− and the alkylrhenium (η-C5H5)Re(NO)(PPh3)(CH(OCH3)C6H5) Journal of Organometallic Chemistry. 202. DOI: 10.1016/S0022-328X(00)81394-7  0.49
1980 KIEL WA, LIN G, GLADYSZ JA. ChemInform Abstract: UNPRECEDENTED REGIOSPECIFICITY AND STEREOSPECIFICITY IN REACTIONS OF PH3C+PF6- WITH RHENIUM ALKYLS OF THE FORMULA (η-C5H5)RE(NO)(PPH3)(CH2R) Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198030310  0.425
1979 Wong WK, Tam W, Strouse CE, Gladysz JA. X-Ray crystal structure and chemical transformations of the neutral metal formyl [(η-C5H5)Re(PPh3)(NO)(CHO)] Journal of the Chemical Society, Chemical Communications. 530-532. DOI: 10.1039/C39790000530  0.418
1979 Johnson DL, Gladysz JA. Reactions of benzaldehyde with trialkylsilyl metal carbonyl complexes Journal of the American Chemical Society. 101: 6433-6435. DOI: 10.1021/Ja00515A048  0.443
1979 Wong W, Tam W, Gladysz JA. Electrophile-induced disproportionation of the neutral formyl (.eta.-C5H5)Re(PPh3)(NO)(CHO). Generation of cationic rhenium carbenes of the formula [(.eta.-C5H5)Re(PPh3)(NO)(CHX)]+ (X = hydrogen, methoxy, hydroxy) Journal of the American Chemical Society. 101: 5440-5442. DOI: 10.1021/Ja00512A069  0.506
1979 Tam W, Wong W, Gladysz JA. Neutral metal formyl complexes: generation, reactivity, and models for Fischer-Tropsch catalyst intermediates Journal of the American Chemical Society. 101: 1589-1591. DOI: 10.1021/Ja00500A037  0.333
1979 Gladysz JA, Williams GM, Tam W, Johnson DL, Parker DW, Selover JC. Synthesis of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers: a convenient one-flask preparation of metal alkyls, metal acyls, and mixed-metal compounds Inorganic Chemistry. 18: 553-558. DOI: 10.1021/Ic50193A006  0.47
1979 Gladysz J, Wong VK, Jick BS. New methodology for the introduction of sulfur into organic molecules Tetrahedron. 35: 2329-2335. DOI: 10.1016/S0040-4020(01)93746-9  0.315
1979 Li S, Johnson DL, Gladysz J, Servis KL. 29Si NMR spectra of metal carbonyl silanes by the selective population transfer method Journal of Organometallic Chemistry. 166: 317-321. DOI: 10.1016/S0022-328X(00)82549-8  0.487
1979 Wong W-, Tam W, Gladysz JA. ELECTROPHILE-INDUCED DISPROPORTIONATION OF THE NEUTRAL FORMYL (η-C5H5)RE(PPH3)(NO)(CHO). GENERATION OF CATIONIC RHENIUM CARBENES OF THE FORMULA ((η-C5H5)RE(PPH3)(NO)(CHX))+ (X = HYDROGEN, METHOXY, HYDROXY) Cheminform. 10. DOI: 10.1002/Chin.197951294  0.515
1979 TAM W, WONG W, GLADYSZ JA. ChemInform Abstract: NEUTRAL METAL FORMYL COMPLEXES: GENERATION, REACTIVITY, AND MODELS FOR FISCHER-TROPSCH CATALYST INTERMEDIATES Chemischer Informationsdienst. 10. DOI: 10.1002/Chin.197926318  0.339
1978 Gladysz JA, Tam W. Binuclear and mixed metal formyl complexes: isolation, characterization, and chemistry Journal of the American Chemical Society. 100: 2545-2547. DOI: 10.1021/Ja00476A046  0.316
1978 Gladysz J, H. Merrifield J. Hydride transfer reactions of anionic metal formyl complexes: a mechanistic Test Inorganica Chimica Acta. 30: L317-L318. DOI: 10.1016/S0020-1693(00)88992-6  0.326
1978 Gladysz JA, Fulcher JG, Bocarsly AB. Ligand wrapping around chromium: Reactions of diphenylmethane, 1,4-diphenylbutane, benzyl ether, and benzyl sulfide with chromium atoms Tetrahedron Letters. 19: 1725-1728. DOI: 10.1016/0040-4039(78)80027-6  0.31
1977 Gladysz J, Williams G, Tam W, Johnson DL. A convenient preparation of metal carbonyl monoanions by trialkylborohydride cleavage of metal carbonyl dimers; observation and reactions of a bimetallic manganese-formyl intermediate Journal of Organometallic Chemistry. 140: C1-C6. DOI: 10.1016/S0022-328X(00)84402-2  0.477
1975 Gladysz JA, Avakian RW. Thione Complexes of Group Vib Pentacarbonyls Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry. 5: 247-255. DOI: 10.1080/00945717508057315  0.329
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