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John T. Groves - Publications

Affiliations: 
1969-1985 Chemistry University of Michigan, Ann Arbor, Ann Arbor, MI 
 1985- Chemistry Princeton University, Princeton, NJ 
Area:
Bioorganic and Bioinorganic Chemistry
Website:
https://chemistry.princeton.edu/faculty/john-t-groves

150 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Groves JT, Feng L, Austin RN. Structure and Function of Alkane Monooxygenase (AlkB). Accounts of Chemical Research. PMID 38032826 DOI: 10.1021/acs.accounts.3c00590  0.606
2022 McQueen CF, Groves JT. Toxicity of the iron siderophore mycobactin J in mouse macrophages: Evidence for a hypoxia response. Journal of Inorganic Biochemistry. 227: 111669. PMID 34864292 DOI: 10.1016/j.jinorgbio.2021.111669  0.761
2021 Coutard N, Goldberg JM, Valle HU, Cao Y, Jia X, Jeffrey PD, Gunnoe TB, Groves JT. Aerobic Partial Oxidation of Alkanes Using Photodriven Iron Catalysis. Inorganic Chemistry. PMID 34962799 DOI: 10.1021/acs.inorgchem.1c03086  0.805
2021 Chan KH, Groves JT. Concise Modular Synthesis and NMR Structural Determination of Gallium Mycobactin T. The Journal of Organic Chemistry. 86: 15453-15468. PMID 34699221 DOI: 10.1021/acs.joc.1c01966  0.486
2019 Nelp MT, Zheng V, Davis KM, Stiefel K, Groves JT. Potent Activation of Indoleamine 2,3-Dioxygenase by Polysulfides. Journal of the American Chemical Society. PMID 31436417 DOI: 10.1021/Jacs.9B07338  0.654
2019 Li G, Kates PA, Dilger AK, Cheng PT, Ewing WR, Groves JT. Manganese-Catalyzed Desaturation of N-Acyl Amines and Ethers Acs Catalysis. 9: 9513-9517. DOI: 10.1021/Acscatal.9B03457  0.334
2019 Fu R, Nielsen RJ, Liebov NS, Goddard WA, Gunnoe TB, Groves JT. DFT Mechanistic Study of Methane Mono-Esterification by Hypervalent Iodine Alkane Oxidation Process The Journal of Physical Chemistry C. 123: 15674-15684. DOI: 10.1021/Acs.Jpcc.9B04239  0.383
2019 Liebov NS, Goldberg JM, Boaz NC, Coutard N, Kalman SE, Zhuang T, Groves JT, Gunnoe TB. Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride Chemcatchem. 11: 5045-5054. DOI: 10.1002/Cctc.201901175  0.774
2018 McQueen CF, Groves JT. A reevaluation of iron binding by Mycobactin J. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 30014257 DOI: 10.1007/S00775-018-1592-2  0.766
2018 Liu W, Huang X, Placzek MS, Krska SW, McQuade P, Hooker JM, Groves JT. Site-selective F fluorination of unactivated C-H bonds mediated by a manganese porphyrin. Chemical Science. 9: 1168-1172. PMID 29675161 DOI: 10.1039/C7Sc04545J  0.598
2018 Schwartz NA, Boaz NC, Kalman SE, Zhuang T, Goldberg JM, Fu R, Nielsen RJ, Goddard WA, Groves JT, Gunnoe TB. Mechanism of Hydrocarbon Functionalization by an Iodate/Chloride System: The Role of Ester Protection Acs Catalysis. 8: 3138-3149. DOI: 10.1021/Acscatal.7B04397  0.802
2017 Huang X, Groves JT. Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins. Chemical Reviews. PMID 29286645 DOI: 10.1021/Acs.Chemrev.7B00373  0.365
2017 Li G, Dilger A, Cheng P, Ewing W, Groves JT. Selective C-H Halogenations with a Highly Fluorinated Manganese Porphyrin. Angewandte Chemie (International Ed. in English). PMID 29235203 DOI: 10.1002/Anie.201710676  0.412
2017 Huang X, Zhuang T, Kates PA, Gao H, Chen X, Groves JT. Alkyl Isocyanates via Manganese-Catalyzed C-H Activation for the Preparation of Substituted Ureas. Journal of the American Chemical Society. PMID 28976738 DOI: 10.1021/Jacs.7B07658  0.378
2017 Hsieh CH, Huang X, Amaya JA, Rutland CD, Keys CL, Groves JT, Austin RN, Makris TM. The Enigmatic P450 Decarboxylase OleT is Capable of, but Evolved to Frustrate, Oxygen Rebound Chemistry. Biochemistry. PMID 28603981 DOI: 10.1021/Acs.Biochem.7B00338  0.671
2017 Gao H, Groves JT. Fast Hydrogen Atom Abstraction by a Hydroxo Iron(III) Porphyrazine. Journal of the American Chemical Society. PMID 28245648 DOI: 10.1021/Jacs.6B13091  0.348
2017 Liu W, Cheng M, Nielsen RJ, Goddard WA, Groves JT. Probing the C–O Bond-Formation Step in Metalloporphyrin-Catalyzed C–H Oxygenation Reactions Acs Catalysis. 7: 4182-4188. DOI: 10.1021/Acscatal.7B00655  0.377
2016 Huang X, Groves JT. Beyond ferryl-mediated hydroxylation: 40 years of the rebound mechanism and C-H activation. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27909920 DOI: 10.1007/S00775-016-1414-3  0.407
2016 Huang X, Groves JT. Taming Azide Radicals for Catalytic C-H Azidation Acs Catalysis. 6: 751-759. DOI: 10.1021/Acscatal.5B02474  0.336
2015 Liu W, Groves JT. Manganese Catalyzed C-H Halogenation. Accounts of Chemical Research. 48: 1727-35. PMID 26042637 DOI: 10.1021/Acs.Accounts.5B00062  0.396
2015 Huang X, Bergsten TM, Groves JT. Manganese-catalyzed late-stage aliphatic C-H azidation. Journal of the American Chemical Society. 137: 5300-3. PMID 25871027 DOI: 10.1021/Jacs.5B01983  0.321
2015 Wang X, Ullrich R, Hofrichter M, Groves JT. Heme-thiolate ferryl of aromatic peroxygenase is basic and reactive. Proceedings of the National Academy of Sciences of the United States of America. 112: 3686-91. PMID 25759437 DOI: 10.1073/Pnas.1503340112  0.735
2015 Kalman SE, Munz D, Fortman GC, Boaz NC, Groves JT, Gunnoe TB. Partial oxidation of light alkanes by periodate and chloride salts. Dalton Transactions (Cambridge, England : 2003). 44: 5294-8. PMID 25708552 DOI: 10.1039/C5Dt00558B  0.77
2015 Boaz NC, Bell SR, Groves JT. Ferryl protonation in oxoiron(IV) porphyrins and its role in oxygen transfer. Journal of the American Chemical Society. 137: 2875-85. PMID 25651467 DOI: 10.1021/Ja508759T  0.806
2015 Groves JT. Cytochrome P450 enzymes: Understanding the biochemical hieroglyphs F1000research. 4. DOI: 10.12688/F1000Research.6314.1  0.322
2014 Konnick MM, Hashiguchi BG, Devarajan D, Boaz NC, Gunnoe TB, Groves JT, Gunsalus N, Ess DH, Periana RA. Selective CH functionalization of methane, ethane, and propane by a perfluoroarene iodine(III) complex. Angewandte Chemie (International Ed. in English). 53: 10490-4. PMID 25131994 DOI: 10.1002/Anie.201406185  0.774
2014 Groves JT, Boaz NC. Biochemistry. Fishing for peroxidase protons. Science (New York, N.Y.). 345: 142-3. PMID 25013049 DOI: 10.1126/Science.1256754  0.79
2014 Fortman GC, Boaz NC, Munz D, Konnick MM, Periana RA, Groves JT, Gunnoe TB. Selective monooxidation of light alkanes using chloride and iodate. Journal of the American Chemical Society. 136: 8393-401. PMID 24866148 DOI: 10.1021/Ja502657G  0.774
2014 O'Reilly ME, Pahls DR, Webb JR, Boaz NC, Majumdar S, Hoff CD, Groves JT, Cundari TR, Gunnoe TB. Reductive functionalization of a rhodium(III)-methyl bond by electronic modification of the supporting ligand. Dalton Transactions (Cambridge, England : 2003). 43: 8273-81. PMID 24715057 DOI: 10.1039/C4Dt00234B  0.773
2014 Stavniichuk R, Shevalye H, Lupachyk S, Obrosov A, Groves JT, Obrosova IG, Yorek MA. Peroxynitrite and protein nitration in the pathogenesis of diabetic peripheral neuropathy. Diabetes/Metabolism Research and Reviews. 30: 669-78. PMID 24687457 DOI: 10.1002/Dmrr.2549  0.316
2014 Groves JT. Enzymatic C-H bond activation: Using push to get pull. Nature Chemistry. 6: 89-91. PMID 24451580 DOI: 10.1038/Nchem.1855  0.333
2014 Pahls DR, Groves JT, Gunnoe TB, Cundari TR. Theoretical study of reductive functionalization of methyl ligands of group 9 complexes supported by two bipyridyl ligands: A key step in catalytic hydrocarbon functionalization Organometallics. 33: 1936-1944. DOI: 10.1021/Om4010093  0.306
2013 Liu W, Huang X, Groves JT. Oxidative aliphatic C-H fluorination with manganese catalysts and fluoride ion. Nature Protocols. 8: 2348-54. PMID 24177292 DOI: 10.1038/Nprot.2013.144  0.337
2013 Wang D, Groves JT. Efficient water oxidation catalyzed by homogeneous cationic cobalt porphyrins with critical roles for the buffer base. Proceedings of the National Academy of Sciences of the United States of America. 110: 15579-84. PMID 24019473 DOI: 10.1073/Pnas.1315383110  0.394
2013 Bertrand EM, Keddis R, Groves JT, Vetriani C, Austin RN. Identity and mechanisms of alkane-oxidizing metalloenzymes from deep-sea hydrothermal vents. Frontiers in Microbiology. 4: 109. PMID 23825470 DOI: 10.3389/Fmicb.2013.00109  0.653
2013 Wang X, Peter S, Ullrich R, Hofrichter M, Groves JT. Driving force for oxygen-atom transfer by heme-thiolate enzymes. Angewandte Chemie (International Ed. in English). 52: 9238-41. PMID 23825007 DOI: 10.1002/Anie.201302137  0.73
2013 Liu W, Groves JT. Manganese-catalyzed oxidative benzylic C-H fluorination by fluoride ions. Angewandte Chemie (International Ed. in English). 52: 6024-7. PMID 23616443 DOI: 10.1002/Anie.201301097  0.333
2013 Bergstrom CL, Beales PA, Lv Y, Vanderlick TK, Groves JT. Cytochrome c causes pore formation in cardiolipin-containing membranes. Proceedings of the National Academy of Sciences of the United States of America. 110: 6269-74. PMID 23576757 DOI: 10.1073/pnas.1303819110  0.766
2013 Naing SH, Parvez S, Pender-Cudlip M, Groves JT, Austin RN. Substrate specificity and reaction mechanism of purified alkane hydroxylase from the hydrocarbonoclastic bacterium Alcanivorax borkumensis (AbAlkB). Journal of Inorganic Biochemistry. 121: 46-52. PMID 23337786 DOI: 10.1016/J.Jinorgbio.2012.12.012  0.668
2012 Cooper HL, Mishra G, Huang X, Pender-Cudlip M, Austin RN, Shanklin J, Groves JT. Parallel and competitive pathways for substrate desaturation, hydroxylation, and radical rearrangement by the non-heme diiron hydroxylase AlkB. Journal of the American Chemical Society. 134: 20365-75. PMID 23157204 DOI: 10.1021/Ja3059149  0.739
2012 Liu W, Huang X, Cheng MJ, Nielsen RJ, Goddard WA, Groves JT. Oxidative aliphatic C-H fluorination with fluoride ion catalyzed by a manganese porphyrin. Science (New York, N.Y.). 337: 1322-5. PMID 22984066 DOI: 10.1126/Science.1222327  0.359
2012 Pouy MJ, Milczek EM, Figg TM, Otten BM, Prince BM, Gunnoe TB, Cundari TR, Groves JT. Flavin-catalyzed insertion of oxygen into rhenium-methyl bonds. Journal of the American Chemical Society. 134: 12920-3. PMID 22827584 DOI: 10.1021/Ja3054139  0.315
2012 Wang X, Peter S, Kinne M, Hofrichter M, Groves JT. Detection and kinetic characterization of a highly reactive heme-thiolate peroxygenase compound I. Journal of the American Chemical Society. 134: 12897-900. PMID 22827262 DOI: 10.1021/Ja3049223  0.747
2012 Groves JT, Watanabe Y. Preparation and characterization of an iron(III) porphyrin N-oxide. Journal of the American Chemical Society. 108: 7836-7. PMID 22283297 DOI: 10.1021/Ja00284A059  0.345
2012 Groves JT, Watanabe Y. The mechanism of olefin epoxidation by oxo-iron porphyrins. Direct observation of an intermediate. Journal of the American Chemical Society. 108: 507-8. PMID 22175471 DOI: 10.1021/Ja00263A026  0.324
2012 Callaghan AV, Morris BE, Pereira IA, McInerney MJ, Austin RN, Groves JT, Kukor JJ, Suflita JM, Young LY, Zylstra GJ, Wawrik B. The genome sequence of Desulfatibacillum alkenivorans AK-01: a blueprint for anaerobic alkane oxidation. Environmental Microbiology. 14: 101-13. PMID 21651686 DOI: 10.1111/J.1462-2920.2011.02516.X  0.626
2011 Umile TP, Wang D, Groves JT. Dissection of the mechanism of manganese porphyrin-catalyzed chlorine dioxide generation. Inorganic Chemistry. 50: 10353-62. PMID 21936530 DOI: 10.1021/Ic201430V  0.78
2011 Peter S, Kinne M, Wang X, Ullrich R, Kayser G, Groves JT, Hofrichter M. Selective hydroxylation of alkanes by an extracellular fungal peroxygenase. The Febs Journal. 278: 3667-75. PMID 21812933 DOI: 10.1111/J.1742-4658.2011.08285.X  0.744
2011 Austin RN, Groves JT. Alkane-oxidizing metalloenzymes in the carbon cycle. Metallomics : Integrated Biometal Science. 3: 775-87. PMID 21743926 DOI: 10.1039/C1Mt00048A  0.649
2011 Beales PA, Bergstrom CL, Geerts N, Groves JT, Vanderlick TK. Single vesicle observations of the cardiolipin-cytochrome C interaction: induction of membrane morphology changes. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 6107-15. PMID 21504165 DOI: 10.1021/La104924C  0.762
2011 Umile TP, Groves JT. Catalytic generation of chlorine dioxide from chlorite using a water-soluble manganese porphyrin. Angewandte Chemie (International Ed. in English). 50: 695-8. PMID 21226156 DOI: 10.1002/Anie.201004482  0.746
2011 Cooper HL, Groves JT. Molecular probes of the mechanism of cytochrome P450. Oxygen traps a substrate radical intermediate. Archives of Biochemistry and Biophysics. 507: 111-8. PMID 21075070 DOI: 10.1016/J.Abb.2010.11.001  0.638
2010 Jin N, Lahaye DE, Groves JT. A "push-pull" mechanism for heterolytic o-o bond cleavage in hydroperoxo manganese porphyrins. Inorganic Chemistry. 49: 11516-24. PMID 21080695 DOI: 10.1021/Ic1015274  0.778
2010 Surmeli NB, Litterman NK, Miller AF, Groves JT. Peroxynitrite mediates active site tyrosine nitration in manganese superoxide dismutase. Evidence of a role for the carbonate radical anion. Journal of the American Chemical Society. 132: 17174-85. PMID 21080654 DOI: 10.1021/Ja105684W  0.797
2010 Liu W, Groves JT. Manganese porphyrins catalyze selective C-H bond halogenations. Journal of the American Chemical Society. 132: 12847-9. PMID 20806921 DOI: 10.1021/Ja105548X  0.404
2010 Su J, Groves JT. Mechanisms of peroxynitrite interactions with heme proteins. Inorganic Chemistry. 49: 6317-29. PMID 20666389 DOI: 10.1021/Ic902157Z  0.574
2009 Su J, Groves JT. Direct detection of the oxygen rebound intermediates, ferryl Mb and NO2, in the reaction of metmyoglobin with peroxynitrite. Journal of the American Chemical Society. 131: 12979-88. PMID 19705829 DOI: 10.1021/Ja902473R  0.573
2009 Bell SR, Groves JT. A highly reactive p450 model compound I. Journal of the American Chemical Society. 131: 9640-1. PMID 19552441 DOI: 10.1021/Ja903394S  0.746
2008 Austin RN, Luddy K, Erickson K, Pender-Cudlip M, Bertrand E, Deng D, Buzdygon RS, van Beilen JB, Groves JT. Cage escape competes with geminate recombination during alkane hydroxylation by the diiron oxygenase AlkB. Angewandte Chemie (International Ed. in English). 47: 5232-4. PMID 18512839 DOI: 10.1002/Anie.200801184  0.751
2007 Drel VR, Pacher P, Vareniuk I, Pavlov IA, Ilnytska O, Lyzogubov VV, Bell SR, Groves JT, Obrosova IG. Evaluation of the peroxynitrite decomposition catalyst Fe(III) tetra-mesitylporphyrin octasulfonate on peripheral neuropathy in a mouse model of type 1 diabetes. International Journal of Molecular Medicine. 20: 783-92. PMID 17982684 DOI: 10.3892/Ijmm.20.6.783  0.711
2007 Obrosova IG, Drel VR, Oltman CL, Mashtalir N, Tibrewala J, Groves JT, Yorek MA. Role of nitrosative stress in early neuropathy and vascular dysfunction in streptozotocin-diabetic rats. American Journal of Physiology. Endocrinology and Metabolism. 293: E1645-55. PMID 17911342 DOI: 10.1152/Ajpendo.00479.2007  0.76
2007 Jin N, Ibrahim M, Spiro TG, Groves JT. Trans-dioxo manganese(V) porphyrins. Journal of the American Chemical Society. 129: 12416-7. PMID 17887684 DOI: 10.1021/Ja0761737  0.53
2007 Lahaye D, Groves JT. Modeling the haloperoxidases: reversible oxygen atom transfer between bromide ion and an oxo-Mn(V) porphyrin. Journal of Inorganic Biochemistry. 101: 1786-97. PMID 17825916 DOI: 10.1016/J.Jinorgbio.2007.07.017  0.785
2007 Drel VR, Pacher P, Vareniuk I, Pavlov I, Ilnytska O, Lyzogubov VV, Tibrewala J, Groves JT, Obrosova IG. A peroxynitrite decomposition catalyst counteracts sensory neuropathy in streptozotocin-diabetic mice. European Journal of Pharmacology. 569: 48-58. PMID 17644085 DOI: 10.1016/J.Ejphar.2007.05.055  0.764
2007 Vareniuk I, Pavlov IA, Drel VR, Lyzogubov VV, Ilnytska O, Bell SR, Tibrewala J, Groves JT, Obrosova IG. Nitrosative stress and peripheral diabetic neuropathy in leptin-deficient (ob/ob) mice. Experimental Neurology. 205: 425-36. PMID 17475250 DOI: 10.1016/J.Expneurol.2007.03.019  0.751
2007 Chakrabarty S, Austin RN, Deng D, Groves JT, Lipscomb JD. Radical intermediates in monooxygenase reactions of rieske dioxygenases. Journal of the American Chemical Society. 129: 3514-5. PMID 17341076 DOI: 10.1021/Ja068188V  0.737
2007 Rozhkova-Novosad EA, Chae JC, Zylstra GJ, Bertrand EM, Alexander-Ozinskas M, Deng D, Moe LA, van Beilen JB, Danahy M, Groves JT, Austin RN. Profiling mechanisms of alkane hydroxylase activity in vivo using the diagnostic substrate norcarane. Chemistry & Biology. 14: 165-72. PMID 17317570 DOI: 10.1016/J.Chembiol.2006.12.007  0.738
2007 Datta A, Quintavalla SM, Groves JT. Kinetic selectivity in the N-alkylation of 2-pyridyl porphyrins: a facile approach to the alphaalphabetabeta scaffold. The Journal of Organic Chemistry. 72: 1818-21. PMID 17263579 DOI: 10.1021/Jo062017R  0.527
2007 Balakrishnan G, Hu Y, Oyerinde OF, Su J, Groves JT, Spiro TG. A conformational switch to β-sheet structure in cytochrome c leads to heme exposure. Implications for cardiolipin peroxidation and apoptosis Journal of the American Chemical Society. 129: 504-505. PMID 17227009 DOI: 10.1021/Ja0678727  0.496
2006 Luo M, Lin H, Fischbach MA, Liu DR, Walsh CT, Groves JT. Enzymatic tailoring of enterobactin alters membrane partitioning and iron acquisition. Acs Chemical Biology. 1: 29-32. PMID 17163637 DOI: 10.1021/Cb0500034  0.523
2006 Austin RN, Deng D, Jiang Y, Luddy K, van Beilen JB, Ortiz de Montellano PR, Groves JT. The diagnostic substrate bicyclohexane reveals a radical mechanism for bacterial cytochrome P450 in whole cells. Angewandte Chemie (International Ed. in English). 45: 8192-4. PMID 17103473 DOI: 10.1002/Anie.200603282  0.708
2006 Wang C, Shalyaev KV, Bonchio M, Carofiglio T, Groves JT. Fast catalytic hydroxylation of hydrocarbons with ruthenium porphyrins. Inorganic Chemistry. 45: 4769-82. PMID 16749842 DOI: 10.1021/Ic0520566  0.651
2006 De Angelis F, Jin N, Car R, Groves JT. Electronic structure and reactivity of isomeric oxo-Mn(V) porphyrins: effects of spin-state crossing and pKa modulation. Inorganic Chemistry. 45: 4268-76. PMID 16676990 DOI: 10.1021/Ic060306S  0.521
2006 Groves JT. High-valent iron in chemical and biological oxidations. Journal of Inorganic Biochemistry. 100: 434-47. PMID 16516297 DOI: 10.1016/J.Jinorgbio.2006.01.012  0.411
2006 Puranik M, Weeks CL, Lahaye D, Kabil O, Taoka S, Nielsen SB, Groves JT, Banerjee R, Spiro TG. Dynamics of carbon monoxide binding to cystathionine βsynthase Journal of Biological Chemistry. 281: 13433-13438. PMID 16505479 DOI: 10.1074/Jbc.M600246200  0.786
2006 Han YZ, Sanford MS, England MD, Groves JT. Mechanistic studies of an unusual epoxide-forming elimination of a beta-hydroxyalkyl rhodium porphyrin. Chemical Communications (Cambridge, England). 549-51. PMID 16432579 DOI: 10.1039/B511974J  0.76
2005 Luo M, Fadeev EA, Groves JT. Mycobactin-mediated iron acquisition within macrophages. Nature Chemical Biology. 1: 149-53. PMID 16408019 DOI: 10.1038/Nchembio717  0.513
2005 Bertrand E, Sakai R, Rozhkova-Novosad E, Moe L, Fox BG, Groves JT, Austin RN. Reaction mechanisms of non-heme diiron hydroxylases characterized in whole cells. Journal of Inorganic Biochemistry. 99: 1998-2006. PMID 16084596 DOI: 10.1016/J.Jinorgbio.2005.06.020  0.661
2005 Fadeev EA, Luo M, Groves JT. Synthesis and structural modeling of the amphiphilic siderophore rhizobactin-1021 and its analogs. Bioorganic & Medicinal Chemistry Letters. 15: 3771-4. PMID 15990296 DOI: 10.1016/J.Bmcl.2005.05.114  0.521
2005 Luo M, Fadeev EA, Groves JT. Membrane dynamics of the amphiphilic siderophore, acinetoferrin. Journal of the American Chemical Society. 127: 1726-36. PMID 15701007 DOI: 10.1021/Ja044230F  0.517
2004 Moe LA, Hu Z, Deng D, Austin RN, Groves JT, Fox BG. Remarkable aliphatic hydroxylation by the diiron enzyme toluene 4-monooxygenase in reactions with radical or cation diagnostic probes norcarane, 1,1-dimethylcyclopropane, and 1,1-diethylcyclopropane. Biochemistry. 43: 15688-701. PMID 15595825 DOI: 10.1021/Bi040033H  0.799
2004 Fadeev EA, Luo M, Groves JT. Synthesis, structure, and molecular dynamics of gallium complexes of schizokinen and the amphiphilic siderophore acinetoferrin. Journal of the American Chemical Society. 126: 12065-75. PMID 15382941 DOI: 10.1021/Ja048145J  0.538
2004 Sanford MS, Groves JT. Anti-Markovnikov hydrofunctionalization of olefins mediated by rhodium-porphyrin complexes. Angewandte Chemie (International Ed. in English). 43: 588-90. PMID 14743411 DOI: 10.1002/Anie.200351941  0.49
2004 Zhou H, Groves JT. Host-guest interactions of cyclodextrins and metalloporphyrins: Supramolecular building blocks toward artificial heme proteins Journal of Porphyrins and Phthalocyanines. 8: 125-140. DOI: 10.1142/S108842460400012X  0.502
2003 Zhou H, Groves JT. Hemodextrin: a self-assembled cyclodextrin-porphyrin construct that binds dioxygen. Biophysical Chemistry. 105: 639-48. PMID 14499924 DOI: 10.1016/S0301-4622(03)00094-2  0.519
2003 Austin RN, Buzzi K, Kim E, Zylstra GJ, Groves JT. Xylene monooxygenase, a membrane-spanning non-heme diiron enzyme that hydroxylates hydrocarbons via a substrate radical intermediate. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 8: 733-40. PMID 12811621 DOI: 10.1007/S00775-003-0466-3  0.654
2003 Groves JT. The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies. Proceedings of the National Academy of Sciences of the United States of America. 100: 3569-74. PMID 12655056 DOI: 10.1073/Pnas.0830019100  0.316
2003 Pacher P, Liaudet L, Bai P, Mabley JG, Kaminski PM, Virág L, Deb A, Szabó E, Ungvári Z, Wolin MS, Groves JT, Szabó C. Potent metalloporphyrin peroxynitrite decomposition catalyst protects against the development of doxorubicin-induced cardiac dysfunction. Circulation. 107: 896-904. PMID 12591762 DOI: 10.1161/01.Cir.0000048192.52098.Dd  0.309
2002 Szabó C, Mabley JG, Moeller SM, Shimanovich R, Pacher P, Virag L, Soriano FG, Van Duzer JH, Williams W, Salzman AL, Groves JT. Part I: pathogenetic role of peroxynitrite in the development of diabetes and diabetic vascular complications: studies with FP15, a novel potent peroxynitrite decomposition catalyst. Molecular Medicine (Cambridge, Mass.). 8: 571-80. PMID 12477967 DOI: 10.1007/Bf03402167  0.736
2002 Auclair K, Hu Z, Little DM, Ortiz De Montellano PR, Groves JT. Revisiting the mechanism of P450 enzymes with the radical clocks norcarane and spiro[2,5]octane. Journal of the American Chemical Society. 124: 6020-7. PMID 12022835 DOI: 10.1021/Ja025608H  0.759
2002 Sauve AA, Groves JT. Synthesis of trithiolanes and tetrathianes from thiiranes catalyzed by ruthenium salen nitrosyl complexes. Journal of the American Chemical Society. 124: 4770-8. PMID 11971726 DOI: 10.1021/Ja017462C  0.629
2001 Brazeau BJ, Austin RN, Tarr C, Groves JT, Lipscomb JD. Intermediate Q from soluble methane monooxygenase hydroxylates the mechanistic substrate probe norcarane: evidence for a stepwise reaction. Journal of the American Chemical Society. 123: 11831-7. PMID 11724588 DOI: 10.1021/Ja016376+  0.695
2001 Shimanovich R, Hannah S, Lynch V, Gerasimchuk N, Mody TD, Magda D, Sessler J, Groves JT. Mn(II)-texaphyrin as a catalyst for the decomposition of peroxynitrite. Journal of the American Chemical Society. 123: 3613-4. PMID 11472141 DOI: 10.1021/Ja005856I  0.73
2001 Bourassa JL, Ives EP, Marqueling AL, Shimanovich R, Groves JT. Myoglobin catalyzes its own nitration. Journal of the American Chemical Society. 123: 5142-3. PMID 11457363 DOI: 10.1021/Ja015621M  0.758
2001 Shimanovich R, Groves JT. Mechanisms of peroxynitrite decomposition catalyzed by FeTMPS, a bioactive sulfonated iron porphyrin. Archives of Biochemistry and Biophysics. 387: 307-17. PMID 11370855 DOI: 10.1006/Abbi.2000.2247  0.771
2000 Jin N, Bourassa JL, Tizio SC, Groves JT. Rapid, Reversible Oxygen Atom Transfer between an Oxomanganese(V) Porphyrin and Bromide: A Haloperoxidase Mimic with Enzymatic Rates. Angewandte Chemie (International Ed. in English). 39: 3849-3851. PMID 29711713 DOI: 10.1002/1521-3773(20001103)39:21<3849::Aid-Anie3849>3.0.Co;2-0  0.498
2000 Groves JT, Wang CC. Nitric oxide synthase: models and mechanisms. Current Opinion in Chemical Biology. 4: 687-95. PMID 11102875 DOI: 10.1016/S1367-5931(00)00146-0  0.346
2000 Austin RN, Chang HK, Zylstra GJ, Groves JT. The non-heme diiron alkane monooxygenase of Pseudomonas oleovorans (AlkB) hydroxylates via a substrate radical intermediate [12] Journal of the American Chemical Society. 122: 11747-11748. DOI: 10.1021/Ja001500V  0.652
2000 Jin N, Bourassa JL, Tizio SC, Groves JT. Rapid, reversible oxygen atom transfer between an oxomanganese(v) porphyrin and bromide: A haloperoxidase mimic with enzymatic rates Angewandte Chemie - International Edition. 39: 3849-3851. DOI: 10.1002/1521-3773(20001103)39:21<3849::AID-ANIE3849>3.0.CO;2-0  0.449
2000 GROVES JT. Reactivity and mechanisms of metalloporphyrin-catalyzed oxidations Journal of Porphyrins and Phthalocyanines. 4: 350-352. DOI: 10.1002/(Sici)1099-1409(200006/07)4:4<350::Aid-Jpp249>3.0.Co;2-G  0.385
1999 Groves JT. Peroxynitrite: reactive, invasive and enigmatic. Current Opinion in Chemical Biology. 3: 226-35. PMID 10226050 DOI: 10.1016/S1367-5931(99)80036-2  0.302
1999 Wang CC, Ho DM, Groves JT. Models of Nitric Oxide Synthase:  Iron(III) Porphyrin-Catalyzed Oxidation of Fluorenone Oxime to Nitric Oxide and Fluorenone Journal of the American Chemical Society. 121: 12094-12103. DOI: 10.1021/Ja992373+  0.397
1999 Jin N, Groves JT. Unusual Kinetic Stability of a Ground-State Singlet Oxomanganese(V) Porphyrin. Evidence for a Spin State Crossing Effect Journal of the American Chemical Society. 121: 2923-2924. DOI: 10.1021/Ja984429Q  0.462
1998 Lee J, Hunt JA, Groves JT. Mechanisms of Iron Porphyrin Reactions with Peroxynitrite Journal of the American Chemical Society. 120: 7493-7501. DOI: 10.1021/Ja980507Y  0.365
1998 Lee J, Hunt JA, Groves JT. Manganese Porphyrins as Redox-Coupled Peroxynitrite Reductases Journal of the American Chemical Society. 120: 6053-6061. DOI: 10.1021/Ja9801036  0.364
1998 Groves JT, Crowley SJ, Shalyaev KV. Paramagnetic1H-NMR relaxation probes of stereoselectivity in metalloporphyrin catalyzed olefin epoxidation Chirality. 10: 106-119. DOI: 10.1002/Chir.18  0.338
1997 Hunt JA, Lee J, Groves JT. Amphiphilic peroxynitrite decomposition catalysts in liposomal assemblies. Chemistry & Biology. 4: 845-58. PMID 9384531 DOI: 10.1016/S1074-5521(97)90117-4  0.566
1997 Groves JT. Artificial enzymes. The importance of being selective. Nature. 389: 329-30. PMID 9311771 DOI: 10.1038/38602  0.327
1997 Groves JT, Lee J, Marla SS. Detection and Characterization of an Oxomanganese(V) Porphyrin Complex by Rapid-Mixing Stopped-Flow Spectrophotometry Journal of the American Chemical Society. 119: 6269-6273. DOI: 10.1021/Ja962605U  0.316
1997 Lee J, Hunt JA, Groves JT. Rapid decomposition of peroxynitrite by manganese porphyrin-antioxidant redox couples Bioorganic & Medicinal Chemistry Letters. 7: 2913-2918. DOI: 10.1016/S0960-894X(97)10109-3  0.344
1997 Groves JT, Shalyaev KV, Bonchio M, Carofiglio T. Rapid catalytic oxygenation of hydrocarbons with perhalogenated ruthenium porphyrin complexes Studies in Surface Science and Catalysis. 110: 865-872. DOI: 10.1016/S0167-2991(97)81049-X  0.364
1996 Baum EZ, Ding WD, Siegel MM, Hulmes J, Bebernitz GA, Sridharan L, Tabei K, Krishnamurthy G, Carofiglio T, Groves JT, Bloom JD, DiGrandi M, Bradley M, Ellestad G, Seddon AP, et al. Flavins inhibit human cytomegalovirus UL80 protease via disulfide bond formation. Biochemistry. 35: 5847-55. PMID 8639546 DOI: 10.1021/Bi9529972  0.301
1996 Groves JT, Bonchio M, Carofiglio T, Shalyaev K. Rapid Catalytic Oxygenation of Hydrocarbons by Ruthenium Pentafluorophenylporphyrin Complexes:  Evidence for the Involvement of a Ru(III) Intermediate Journal of the American Chemical Society. 118: 8961-8962. DOI: 10.1021/Ja9542092  0.332
1996 Lahiri J, Fate GD, Ungashe SB, Groves JT. Multi-heme self-assembly in phospholipid vesicles Journal of the American Chemical Society. 118: 2347-2358. DOI: 10.1021/Ja953092E  0.314
1995 Groves JT, Roman JS. Nitrous Oxide Activation by a Ruthenium Porphyrin Journal of the American Chemical Society. 117: 5594-5595. DOI: 10.1021/Ja00125A025  0.322
1994 Groves JT, Gross Z, Stern MK. Preparation and Reactivity of Oxoiron(IV) Porphyrins Inorganic Chemistry. 33: 5065-5072. DOI: 10.1021/Ic00100A035  0.526
1992 Watanabe Y, Groves JT. 9 Molecular Mechanism of Oxygen Activation by P-450 The Enzymes. 20: 405-452. DOI: 10.1016/S1874-6047(08)60027-X  0.354
1991 Nick RJ, Ray GB, Fish KM, Spiro TG, Groves JT. Evidence for a weak Mn:O bond and a non-porphyrin radical in manganese-substituted horseradish peroxidase compound I Journal of the American Chemical Society. 113: 1838-1840. DOI: 10.1021/Ja00005A062  0.311
1990 Groves JT, Han Y, Engen DV. Co-ordination of styrene oxide to a sterically hindered ruthenium(II) porphyrin Journal of the Chemical Society, Chemical Communications. 436-437. DOI: 10.1039/C39900000436  0.343
1990 Groves JT, Viski P. Asymmetric hydroxylation, epoxidation, and sulfoxidation catalyzed by vaulted binaphthyl metalloporphyrins The Journal of Organic Chemistry. 55: 3628-3634. DOI: 10.1021/Jo00298A046  0.344
1989 Groves JT, Neumann R. Regioselective oxidation catalysis in synthetic phospholipid vesicles. Membrane-spanning steroidal metalloporphyrins Journal of the American Chemical Society. 111: 2900-2909. DOI: 10.1021/Ja00190A026  0.512
1988 Groves JT, Neumann R. Enzymic regioselectivity in the hydroxylation of cholesterol catalyzed by a membrane-spanning metalloporphyrin The Journal of Organic Chemistry. 53: 3891-3893. DOI: 10.1021/Jo00251A054  0.504
1988 Groves JT, Watanabe Y. Reactive iron porphyrin derivatives related to the catalytic cycles of cytochrome P-450 and peroxidase. Studies of the mechanism of oxygen activation Journal of the American Chemical Society. 110: 8443-8452. DOI: 10.1021/Ja00233A021  0.331
1988 Groves JT, Ahn KH, Quinn R. Cis-trans isomerization of epoxides catalyzed by ruthenium(II) porphyrins Journal of the American Chemical Society. 110: 4217-4220. DOI: 10.1021/Ja00221A021  0.319
1987 Groves JT, Neumann R. Membrane-spanning steroidal metalloporphyrins as site-selective catalysts in synthetic vesicles Journal of the American Chemical Society. 109: 5045-5047. DOI: 10.1021/Ja00250A059  0.493
1987 Groves JT, Stern MK. Olefin epoxidation by manganese (IV) porphyrins: evidence for two reaction pathways Journal of the American Chemical Society. 109: 3812-3814. DOI: 10.1021/Ja00246A067  0.31
1987 Groves JT, Watanabe Y. Preparation and characterization of an (acylperoxo)iron(III) porphyrin Inorganic Chemistry. 26: 785-786. DOI: 10.1021/Ic00253A002  0.309
1987 GROVES JT, NEUMANN R. ChemInform Abstract: Membrane-Spanning Steroidal Metalloporphyrins as Site-Selective Catalysts in Synthetic Vesicles. Cheminform. 18. DOI: 10.1002/chin.198748123  0.434
1986 Groves JT, Avaria-Neisser GE, Fish KM, Imachi M, Kuczkowski RL. Hydrogen-deuterium exchange during propylene epoxidation by cytochrome P-450 Journal of the American Chemical Society. 108: 3837-3838. DOI: 10.1021/Ja00273A053  0.343
1986 Groves JT, Watanabe Y. Heterolytic and homolytic oxygen-oxygen bond cleavage reactions of acylperoxomanganese(III) porphyrins Inorganic Chemistry. 25: 4808-4810. DOI: 10.1021/Ic00247A006  0.305
1984 Groves JT, Quinn R. Models of oxidized heme proteins. Preparation and characterization of a trans-dioxoruthenium(VI) porphyrin complex Inorganic Chemistry. 23: 3844-3846. DOI: 10.1021/Ic00192A004  0.33
1983 Boso B, Lang G, McMurry TJ, Groves JT. Mössbauer effect study of tight spin coupling in oxidized chloro‐5,10,15,20‐tetra(mesityl)porphyrinatoiron(III) The Journal of Chemical Physics. 79: 1122-1126. DOI: 10.1063/1.445913  0.332
1983 Groves JT, Nemo TE. Aliphatic hydroxylation catalyzed by iron porphyrin complexes Journal of the American Chemical Society. 105: 6243-6248. DOI: 10.1002/Chin.198402114  0.318
1982 Groves JT, Kruper WJ, Haushalter RC, Butler WM. Synthesis, characterization, and molecular structure of oxo(porphyrinato)chromium(IV) complexes Inorganic Chemistry. 21: 1363-1368. DOI: 10.1021/ic00134a018  0.45
1982 GROVES JT, KRUPER WJJ, HAUSHALTER RC, BUTLER WM. ChemInform Abstract: SYNTHESIS, CHARACTERIZATION, AND MOLECULAR STRUCTURE OF OXO(PORPHYRINATO)CHROMIUM(IV) COMPLEXES Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198229237  0.455
1981 Groves JT, Haushalter RC, Nakamura M, Nemo TE, Evans BJ. High-valent iron-porphyrin complexes related to peroxidase and cytochrome P-450 Journal of the American Chemical Society. 103: 2884-2886. DOI: 10.1021/Ja00400A075  0.533
1981 GROVES JT, KRUPER WJJ, HAUSHALTER RC. ChemInform Abstract: HYDROCARBON OXIDATIONS WITH OXOMETALLOPORPHINATES. ISOLATION AND REACTIONS OF A (PORPHINATO)MANGANESE(V) COMPLEX Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198101285  0.513
1981 Groves JT, Haushalter RC. E.S.R. evidence for chromium(V) porphyrinates Journal of the Chemical Society, Chemical Communications. 1165-1166.  0.41
1980 Groves JT, Kruper WJ, Haushalter RC. Hydrocarbon oxidations with oxometalloporphinates. Isolation and reactions of a (porphinato)manganese(V) complex Journal of the American Chemical Society. 102: 6375-6377. DOI: 10.1021/ja00540a050  0.508
1976 Groves JT, Van der Puy M. Stereospecific aliphatic hydroxylation by iron-hydrogen peroxide. Evidence for a stepwise process Journal of the American Chemical Society. 98: 5290-5297. DOI: 10.1021/Ja00433A039  0.302
1976 Groves JT, McClusky GA. Aliphatic hydroxylation via oxygen rebound. Oxygen transfer catalyzed by iron Journal of the American Chemical Society. 98: 859-861. DOI: 10.1021/Ja00419A049  0.308
1975 Groves JT, Van der Puy M. Directive effects in free radical oxidation by iron(III). Reductive decarboxylation of peracids Journal of the American Chemical Society. 97: 7118-7122. DOI: 10.1002/Chin.197607144  0.374
1974 Groves JT, Van der Puy M. Stereospecific aliphatic hydroxylation by an iron-based oxidant Journal of the American Chemical Society. 96: 5274-5275. DOI: 10.1021/Ja00823A055  0.341
1974 Groves JT, Ma KW. Dehalogenations with sodium borohydride. Evidence for a free radical reaction Journal of the American Chemical Society. 96: 6527-6529. DOI: 10.1002/Chin.197450143  0.314
1970 Breslow R, Ryan G, Groves JT. Chlorocyclopropenes, chlorocyclopropenyl cations, and cyclopropenone Journal of the American Chemical Society. 92: 988-993. DOI: 10.1021/Ja00707A041  0.459
1970 Breslow R, Groves JT. Cyclopropenyl cation. Synthesis and characterization Journal of the American Chemical Society. 92: 984-987. DOI: 10.1021/Ja00707A040  0.463
1970 BRESLOW R, RYAN G, GROVES JT. ChemInform Abstract: CHLORCYCLOPROPENE, CHLORPROPENYL-KATIONEN UND CYCLOPROPENON Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197020175  0.428
1970 BRESLOW R, GROVES JT. ChemInform Abstract: CYCLOPROPENYL-KATION, SYNTH. UND CHARAKTERISIERUNG Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197019050  0.428
1968 Breslow R, Olin SS, Groves JT. Oxidative cyclization of farnesyl acetate by a free radical path Tetrahedron Letters. 9: 1837-1840. DOI: 10.1016/S0040-4039(00)76376-3  0.457
1966 Breslow R, Groves J, Olin S. A novel oxidative terpene cyclization Tetrahedron Letters. 7: 4717-4719. DOI: 10.1016/S0040-4039(00)72930-3  0.445
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