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Maurice S. Brookhart - Publications

Affiliations: 
University of North Carolina, Chapel Hill, Chapel Hill, NC 
Area:
Synthetic Organometallic Chemistry, Catalysis
Website:
http://www.chem.unc.edu/people/faculty/brookhart/

299 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Kocen AL, Brookhart M, Daugulis O. A highly active Ni(II)-triadamantylphosphine catalyst for ultrahigh-molecular-weight polyethylene synthesis. Nature Communications. 10: 438. PMID 30683873 DOI: 10.1038/S41467-019-08309-8  0.84
2018 Chen Z, Brookhart M. Exploring Ethylene/Polar Vinyl Monomer Copolymerizations Using Ni and Pd α-Diimine Catalysts. Accounts of Chemical Research. PMID 30028122 DOI: 10.1021/acs.accounts.8b00225  0.48
2016 Bézier D, Guan C, Krogh-Jespersen K, Goldman AS, Brookhart M. Experimental and computational study of alkane dehydrogenation catalyzed by a carbazolide-based rhodium PNP pincer complex. Chemical Science. 7: 2579-2586. PMID 28660029 DOI: 10.1039/C5Sc04794C  1
2016 Bolig AD, Lyons TW, DiSalvo DT, Brookhart M. Intramolecular Hydrogen Transfer Reactions Catalyzed by Pentamethylcyclopentadienyl Rhodium and Cobalt Olefin Complexes: Mechanistic Studies. Polyhedron. 103: 51-57. PMID 26858471 DOI: 10.1016/J.Poly.2015.07.076  0.72
2016 Chen Z, Allen KE, White PS, Daugulis O, Brookhart M. Synthesis of Branched Polyethylene with "half-Sandwich" Pyridine-Imine Nickel Complexes Organometallics. 35: 1756-1760. DOI: 10.1021/Acs.Organomet.6B00165  1
2016 Yao W, Jia X, Leng X, Goldman AS, Brookhart M, Huang Z. Catalytic alkane transfer-dehydrogenation by PSCOP iridium pincer complexes Polyhedron. 116: 12-19. DOI: 10.1016/J.Poly.2016.02.044  1
2016 Bolig AD, Lyons TW, DiSalvo DT, Brookhart M. Intramolecular hydrogen transfer reactions catalyzed by pentamethylcyclopentadienyl rhodium and cobalt olefin complexes: Mechanistic studies Polyhedron. 103: 51-57. DOI: 10.1016/j.poly.2015.07.076  1
2015 Chen Z, Mesgar M, White PS, Daugulis O, Brookhart M. Synthesis of branched ultrahigh-molecular-weight polyethylene using highly active neutral, single-component Ni(II) catalysts Acs Catalysis. 5: 631-636. DOI: 10.1021/Cs501948D  1
2015 Allen KE, Campos J, Daugulis O, Brookhart M. Living Polymerization of Ethylene and Copolymerization of Ethylene/Methyl Acrylate Using "Sandwich" Diimine Palladium Catalysts Acs Catalysis. 5: 456-464. DOI: 10.1021/Cs5016029  1
2015 Turlington CR, White PS, Brookhart M, Templeton JL. Sequential Nitrene Transfers to an Organometallic Half-Sandwich Iridium Complex Organometallics. 34: 4810-4812. DOI: 10.1021/Acs.Organomet.5B00717  1
2015 Lyons TW, Bézier D, Brookhart M. Iridium Pincer-Catalyzed Dehydrogenation of Ethers Featuring Ethylene as the Hydrogen Acceptor Organometallics. 34: 4058-4062. DOI: 10.1021/Acs.Organomet.5B00501  1
2015 Kang P, Chen Z, Brookhart M, Meyer TJ. Electrocatalytic Reduction of Carbon Dioxide: Let the Molecules Do the Work Topics in Catalysis. 58: 30-45. DOI: 10.1007/S11244-014-0344-Y  1
2014 Kang P, Zhang S, Meyer TJ, Brookhart M. Rapid selective electrocatalytic reduction of carbon dioxide to formate by an iridium pincer catalyst immobilized on carbon nanotube electrodes. Angewandte Chemie (International Ed. in English). 53: 8709-13. PMID 24899071 DOI: 10.1002/Anie.201310722  0.48
2014 Cheng C, Kim BG, Guironnet D, Brookhart M, Guan C, Wang DY, Krogh-Jespersen K, Goldman AS. Synthesis and characterization of carbazolide-based iridium PNP pincer complexes. Mechanistic and computational investigation of alkene hydrogenation: evidence for an Ir(III)/Ir(V)/Ir(III) catalytic cycle. Journal of the American Chemical Society. 136: 6672-83. PMID 24746026 DOI: 10.1021/Ja501572G  1
2014 Turlington CR, White PS, Brookhart M, Templeton JL. Oxygen atom transfer to a half-sandwich iridium complex: clean oxidation yielding a molecular product. Journal of the American Chemical Society. 136: 3981-94. PMID 24571611 DOI: 10.1021/Ja413023F  1
2014 Turlington CR, Morris J, White PS, Brennessel WW, Jones WD, Brookhart M, Templeton JL. Exploring oxidation of half-sandwich rhodium complexes: Oxygen atom insertion into the rhodium-carbon bond of κ2-coordinated 2-phenylpyridine Organometallics. 33: 4442-4448. DOI: 10.1021/Om500660N  1
2014 Bézier D, Brookhart M. Applications of PC(sp3)P iridium complexes in transfer dehydrogenation of alkanes Acs Catalysis. 4: 3411-3420. DOI: 10.1021/Cs500892P  1
2014 Gruhn NE, Goldberg KI, Brookhart M. Virtual issue on research in the center for enabling new technologies through catalysis (CENTC) Acs Catalysis. 4: 1318-1319. DOI: 10.1021/Cs500312Z  1
2014 Turlington CR, White PS, Brookhart M, Templeton JL. Half-sandwich Rh(Cp*) and Ir(Cp*) complexes with oxygen atom transfer reagents as ligands Journal of Organometallic Chemistry. DOI: 10.1016/J.Jorganchem.2015.02.007  1
2013 Turlington CR, Harrison DP, White PS, Brookhart M, Templeton JL. Probing the oxidation chemistry of half-sandwich iridium complexes with oxygen atom transfer reagents. Inorganic Chemistry. 52: 11351-60. PMID 24063760 DOI: 10.1021/Ic4016405  1
2013 Walter MD, White PS, Schauer CK, Brookhart M. Stability and dynamic processes in 16VE iridium(III) ethyl hydride and rhodium(I) σ-ethane complexes: experimental and computational studies. Journal of the American Chemical Society. 135: 15933-47. PMID 24053635 DOI: 10.1021/Ja4079539  1
2013 Lyons TW, Brookhart M. Cobalt-catalyzed hydrosilation/hydrogen-transfer cascade reaction: a new route to silyl enol ethers. Chemistry (Weinheim An Der Bergstrasse, Germany). 19: 10124-7. PMID 23780615 DOI: 10.1002/Chem.201301502  0.72
2013 Bézier D, Park S, Brookhart M. Selective reduction of carboxylic acids to aldehydes catalyzed by B(C6F5)3. Organic Letters. 15: 496-9. PMID 23317512 DOI: 10.1021/Ol303296A  0.56
2013 Campos J, Kundu S, Pahls DR, Brookhart M, Carmona E, Cundari TR. Mechanism of hydrogenolysis of an iridium-methyl bond: evidence for a methane complex intermediate. Journal of the American Chemical Society. 135: 1217-20. PMID 23311932 DOI: 10.1021/Ja310982V  1
2013 Wingard LA, Finniss MC, Norris M, White PS, Brookhart M, Templeton JL. Synthesis, structure, and reactivity of iridium(III) complexes containing a 4,6-dimethyl-1,3-benzenediphenylimine pincer ligand. Inorganic Chemistry. 52: 515-26. PMID 23265184 DOI: 10.1021/Ic302589B  1
2013 Kang P, Meyer TJ, Brookhart M. Selective electrocatalytic reduction of carbon dioxide to formate by a water-soluble iridium pincer catalyst Chemical Science. 4: 3497-3502. DOI: 10.1039/C3Sc51339D  1
2013 Walter MD, White PS, Brookhart M. Synthesis, structure and computational studies of a cationic T-shaped Pd-complex New Journal of Chemistry. 37: 1128-1133. DOI: 10.1039/C3Nj41145A  1
2013 Zhang D, Nadres ET, Brookhart M, Daugulis O. Synthesis of highly branched polyethylene using "sandwich" (8-p-tolyl naphthyl α-diimine)nickel(II) catalysts Organometallics. 32: 5136-5143. DOI: 10.1021/Om400704H  1
2013 Campos J, Peloso R, Brookhart M, Carmona E. A cationic terminal methylene complex of Ir(I) supported by a pincer ligand Organometallics. 32: 3423-3426. DOI: 10.1021/Om400383S  1
2013 Bézier D, Park S, Brookhart M. Selective reduction of carboxylic acids to aldehydes catalyzed by B(C 6F5)3 Organic Letters. 15: 496-499. DOI: 10.1021/ol303296a  1
2013 Nawara-Hultzsch AJ, Hackenberg JD, Punji B, Supplee C, Emge TJ, Bailey BC, Schrock RR, Brookhart M, Goldman AS. Rational design of highly active "hybrid" phosphine-phosphinite pincer iridium catalysts for alkane metathesis Acs Catalysis. 3: 2505-2514. DOI: 10.1021/Cs400624C  1
2013 Kundu S, Lyons TW, Brookhart M. Synthesis of piperylene and toluene via transfer dehydrogenation of pentane and pentene Acs Catalysis. 3: 1768-1773. DOI: 10.1021/Cs400398W  1
2013 Lyons TW, Brookhart M. Cobalt-catalyzed hydrosilation/hydrogen-transfer cascade reaction: A new route to silyl enol ethers Chemistry - a European Journal. 19: 10124-10127. DOI: 10.1002/chem.201301502  1
2012 Lyons TW, Guironnet D, Findlater M, Brookhart M. Synthesis of p-xylene from ethylene. Journal of the American Chemical Society. 134: 15708-11. PMID 22934909 DOI: 10.1021/Ja307612B  1
2012 Park S, Bézier D, Brookhart M. An efficient iridium catalyst for reduction of carbon dioxide to methane with trialkylsilanes. Journal of the American Chemical Society. 134: 11404-7. PMID 22765847 DOI: 10.1021/Ja305318C  0.56
2012 Biswas S, Huang Z, Choliy Y, Wang DY, Brookhart M, Krogh-Jespersen K, Goldman AS. Olefin isomerization by iridium pincer catalysts. Experimental evidence for an η3-allyl pathway and an unconventional mechanism predicted by DFT calculations. Journal of the American Chemical Society. 134: 13276-95. PMID 22765770 DOI: 10.1021/Ja301464C  1
2012 Haibach MC, Kundu S, Brookhart M, Goldman AS. Alkane metathesis by tandem alkane-dehydrogenation-olefin-metathesis catalysis and related chemistry. Accounts of Chemical Research. 45: 947-58. PMID 22584036 DOI: 10.1021/Ar3000713  1
2012 Kang P, Cheng C, Chen Z, Schauer CK, Meyer TJ, Brookhart M. Selective electrocatalytic reduction of CO2 to formate by water-stable iridium dihydride pincer complexes. Journal of the American Chemical Society. 134: 5500-3. PMID 22390391 DOI: 10.1021/Ja300543S  1
2012 Findlater M, Schultz KM, Bernskoetter WH, Cartwright-Sykes A, Heinekey DM, Brookhart M. Dihydrogen complexes of iridium and rhodium. Inorganic Chemistry. 51: 4672-8. PMID 22364621 DOI: 10.1021/Ic202630X  1
2012 Park S, Brookhart M. Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines. Journal of the American Chemical Society. 134: 640-53. PMID 22091749 DOI: 10.1021/Ja209567M  0.56
2012 Park S, Bézier D, Brookhart M. An efficient iridium catalyst for reduction of carbon dioxide to methane with trialkylsilanes Journal of the American Chemical Society. 134: 11404-11407. DOI: 10.1021/ja305318c  1
2012 Cheng C, Brookhart M. Iridium-catalyzed reduction of secondary amides to secondary amines and imines by diethylsilane Journal of the American Chemical Society. 134: 11304-11307. DOI: 10.1021/Ja304547S  1
2012 Park S, Brookhart M. Development and mechanistic investigation of a highly efficient iridium(V) silyl complex for the reduction of tertiary amides to amines Journal of the American Chemical Society. 134: 640-653. DOI: 10.1021/ja209567m  1
2012 Park S, Kim BG, Göttker-Schnetmann I, Brookhart M. Redistribution of trialkyl silanes catalyzed by iridium silyl complexes Acs Catalysis. 2: 307-316. DOI: 10.1021/Cs200629T  1
2012 Anderson-Wile AM, Edson JB, Coates GW. Living Transition Metal-Catalyzed Alkene Polymerization: Polyolefin Synthesis and New Polymer Architectures Polymer Science: a Comprehensive Reference, 10 Volume Set. 3: 739-778. DOI: 10.1016/B978-0-444-53349-4.00084-4  1
2012 Cheng C, Brookhart M. Efficient reduction of esters to aldehydes through iridium-catalyzed hydrosilylation Angewandte Chemie - International Edition. 51: 9422-9424. DOI: 10.1002/Anie.201205154  1
2011 Chen Z, Chen C, Weinberg DR, Kang P, Concepcion JJ, Harrison DP, Brookhart MS, Meyer TJ. Electrocatalytic reduction of CO2 to CO by polypyridyl ruthenium complexes. Chemical Communications (Cambridge, England). 47: 12607-9. PMID 21998823 DOI: 10.1039/C1Cc15071E  1
2011 Findlater M, Cartwright-Sykes A, White PS, Schauer CK, Brookhart M. Role of coordination geometry in dictating the barrier to hydride migration in d6 square-pyramidal iridium and rhodium pincer complexes. Journal of the American Chemical Society. 133: 12274-84. PMID 21702471 DOI: 10.1021/Ja204851X  1
2011 Cheng C, Guironnet D, Barborak J, Brookhart M. Preparation and characterization of conjugated polymers made by postpolymerization reactions of alternating polyketones. Journal of the American Chemical Society. 133: 9658-61. PMID 21615113 DOI: 10.1021/Ja202361K  0.84
2011 Cochrane NA, Brookhart MS, Gagné MR. Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors. Organometallics. 30: 2457-2460. PMID 21572581 DOI: 10.1021/Om2001958  1
2011 Choi J, MacArthur AH, Brookhart M, Goldman AS. Dehydrogenation and related reactions catalyzed by iridium pincer complexes. Chemical Reviews. 111: 1761-79. PMID 21391566 DOI: 10.1021/Cr1003503  1
2011 Vicente BC, Huang Z, Brookhart M, Goldman AS, Scott SL. Reactions of phosphinites with oxide surfaces: a new method for anchoring organic and organometallic complexes. Dalton Transactions (Cambridge, England : 2003). 40: 4268-74. PMID 21384048 DOI: 10.1039/C0Dt01369B  1
2011 Park S, Brookhart M. Hydrosilylation of epoxides catalyzed by a cationic η1- silane iridium(iii) complex Chemical Communications. 47: 3643-3645. PMID 21321708 DOI: 10.1039/C0Cc05714B  1
2011 Ahuja R, Punji B, Findlater M, Supplee C, Schinski W, Brookhart M, Goldman AS. Catalytic dehydroaromatization of n-alkanes by pincer-ligated iridium complexes. Nature Chemistry. 3: 167-71. PMID 21258391 DOI: 10.1038/Nchem.946  1
2011 Walter MD, White PS, Schauer CK, Brookhart M. The quest for stable σ-methane complexes: Computational and experimental studies New Journal of Chemistry. 35: 2884-2893. DOI: 10.1039/C1Nj20602H  1
2011 Cheng C, Guironnet D, Barborak J, Brookhart M. Preparation and characterization of conjugated polymers made by postpolymerization reactions of alternating polyketones Journal of the American Chemical Society. 133: 9658-9661. DOI: 10.1021/ja202361k  1
2011 Urbin SA, Pintauer T, White P, Brookhart M. Synthesis, characterization, and reactivity of (π-allyl)palladium(II) wrap-around complexes with 1,3-dienes Inorganica Chimica Acta. 369: 150-158. DOI: 10.1016/J.Ica.2010.12.046  1
2011 Goldman AS, Krogh-Jespersen K, Brookhart M. Dehydrogenation and related reactions of alkanes catalyzed by pincerâ-iridium complexes Acs National Meeting Book of Abstracts 1
2010 Park S, Brookhart M. Hydrosilation of Carbonyl-Containing Substrates Catalyzed by an Electrophilic η-Silane Iridium(III) Complex. Organometallics. 29: 6057-6064. PMID 21572562 DOI: 10.1021/Om100818Y  0.56
2010 Huang Z, White PS, Brookhart M. Ligand exchanges and selective catalytic hydrogenation in molecular single crystals. Nature. 465: 598-601. PMID 20520710 DOI: 10.1038/Nature09085  1
2010 Findlater M, Bernskoetter WH, Brookhart M. Proton-catalyzed hydrogenation of a d(8) Ir(I) complex yields a trans Ir(III) dihydride. Journal of the American Chemical Society. 132: 4534-5. PMID 20232913 DOI: 10.1021/Ja100168W  1
2010 Bochmann M, Brookhart M, Gladysz JA, Lichtenberger DL, Liebeskind LS, Marks TJ, Schrock RR, Sweigart DA, Whitmire KH. Dedication to the special volume for Dietmar Seyferth Organometallics. 29: 4647. DOI: 10.1021/Om100975M  1
2010 Park S, Brookhart M. Hydrosilylation of carbonyl-containing substrates catalyzed by an electrophilic η1-silane iridium(III) complex Organometallics. 29: 6057-6064. DOI: 10.1021/om100818y  1
2010 O'Connor AR, White PS, Brookhart M. Synthesis, characterization, and reactivity studies of (cyclohexenyl) nickel(ii) complexes Organometallics. 29: 5382-5389. DOI: 10.1021/Om100391V  1
2010 O'Connor AR, Brookhart M. Polymerization of 1,3-dienes and styrene catalyzed by cationic allyl ni(II) complexes Journal of Polymer Science, Part a: Polymer Chemistry. 48: 1901-1912. DOI: 10.1002/Pola.23955  1
2010 Huang Z, Rolfe E, Carson EC, Brookhart M, Goldman AS, El-Khalafy SH, Roy MacArthur AH. Efficient heterogeneous dual catalyst systems for alkane metathesis Advanced Synthesis and Catalysis. 352: 125-135. DOI: 10.1002/Adsc.200900539  1
2009 Bernskoetter WH, Schauer CK, Goldberg KI, Brookhart M. Characterization of a rhodium(I) sigma-methane complex in solution. Science (New York, N.Y.). 326: 553-6. PMID 19900892 DOI: 10.1126/Science.1177485  1
2009 Walter MD, White PS, Brookhart M. Gamma-agostic interactions stabilize the propagating species in the vinyl addition polymerization of norbornene. Chemical Communications (Cambridge, England). 6361-3. PMID 19841777 DOI: 10.1039/B916457J  1
2009 Bernskoetter WH, Hanson SK, Buzak SK, Davis Z, White PS, Swartz R, Goldberg KI, Brookhart M. Investigations of iridium-mediated reversible C-H bond cleavage: characterization of a 16-electron iridium(III) methyl hydride complex. Journal of the American Chemical Society. 131: 8603-13. PMID 19489584 DOI: 10.1021/Ja901706B  1
2009 Walter MD, Moorhouse RA, Urbin SA, White PS, Brookhart M. Gamma-agostic species as key intermediates in the vinyl addition polymerization of norbornene with cationic (allyl)Pd catalysts: synthesis and mechanistic insights. Journal of the American Chemical Society. 131: 9055-69. PMID 19473005 DOI: 10.1021/Ja9025598  1
2009 Rix FC, Rachita MJ, Wagner MI, Brookhart M, Milani B, Barborak JC. Palladium(ii)-catalyzed copolymerization of styrenes with carbon monoxide: Mechanism of chain propagation and chain transfer Dalton Transactions. 8977-8992. DOI: 10.1039/B911392D  1
2009 Kundu S, Choliy Y, Zhuo G, Ahuja R, Emge TJ, Warmuth R, Brookhart M, Krogh-Jespersen K, Goldman AS. Rational design and synthesis of highly active pincer-iridium catalysts for alkane dehydrogenation Organometallics. 28: 5432-5444. DOI: 10.1021/Om900568F  1
2009 O'Connor AR, Urbin SA, Moorhouse RA, While PS, Brookhart M. Synthesis and reactivity of cationic (Allyl)(arene)nickel(II) and (Allyl)(arene)palladium(II) complexes Organometallics. 28: 2372-2384. DOI: 10.1021/Om801103P  1
2009 Bailey BC, Schrock RR, Kundu S, Goldman AS, Huang Z, Brookhart M. Evaluation of molybdenum and tungsten metathesis catalysts for homogeneous tandem alkane metathesis Organometallics. 28: 355-360. DOI: 10.1021/Om800877Q  1
2009 Walter MD, Moorhouse RA, White PS, Brookhart M. Vinyl addition polymerization of norbornene with cationic (allyl)Ni catalysts: Mechanistic insights and characterization of first insertion products Journal of Polymer Science, Part a: Polymer Chemistry. 47: 2560-2573. DOI: 10.1002/Pola.23340  1
2009 Huang Z, Brookhart M, Goldman AS, Kundu S, Ray A, Scott SL, Vicente BC. Highly active and recyclable heterogeneous iridium pincer catalysts for transfer dehydrogenation of alkanes Advanced Synthesis and Catalysis. 351: 188-206. DOI: 10.1002/Adsc.200800615  1
2009 Yang J, Brookhart M. Reduction of alkyl halides by triethylsilane based on a cationic iridium bis(phosphinite) pincer catalyst: Scope, selectivity and mechanism Advanced Synthesis and Catalysis. 351: 175-187. DOI: 10.1002/Adsc.200800528  1
2009 Goldman AS, Brookhart M, Huang Z, Krogh-Jespersen K, Kundu S, Scott SL. Transition-metal-based catalytic systems for the dehydrogenation and metathesis of alkanes: Solution-phase and solid-supported iridium-based pincer catalysts Acs National Meeting Book of Abstracts 1
2009 Biswas S, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. Regioselectivity in the transfer-dehydrogenation of alkanes by two pincer-iridium-based catalysts Acs National Meeting Book of Abstracts 1
2008 Yang J, White PS, Brookhart M. Scope and mechanism of the iridium-catalyzed cleavage of alkyl ethers with triethylsilane. Journal of the American Chemical Society. 130: 17509-18. PMID 19053420 DOI: 10.1021/Ja806419H  1
2008 Yang J, White PS, Schauer CK, Brookhart M. Structural and spectroscopic characterization of an unprecedented cationic transition-metal eta1-silane complex. Angewandte Chemie (International Ed. in English). 47: 4141-3. PMID 18435435 DOI: 10.1002/Anie.200705359  1
2008 Ahuja R, Kundu S, Goldman AS, Brookhart M, Vicente BC, Scott SL. Catalytic ring expansion, contraction, and metathesis-polymerization of cycloalkanes. Chemical Communications (Cambridge, England). 253-5. PMID 18092104 DOI: 10.1039/B712197K  1
2008 Bernskoetter WH, Brookhart M. Kinetics and mechanism of iridium-catalyzed dehydrogenation of primary amines to nitriles Organometallics. 27: 2036-2045. DOI: 10.1021/Om701148T  1
2008 Biswas S, Ahuja R, Ray A, Choliy Y, Krogh-Jespersen K, Brookhart M, Goldman AS. A tale of two ligands. Subtle differences in sterics exert major differences in the energetics of alkane dehydrogenation catalyzed by pincer complexes (tBuPCP)Ir vs. (tBuPOCOP)Ir Acs National Meeting Book of Abstracts 1
2007 Bolig AD, Brookhart M. Activation of sp3 C-H bonds with cobalt(I): Catalytic synthesis of enamines Journal of the American Chemical Society. 129: 14544-14545. PMID 17985901 DOI: 10.1021/Ja075694R  1
2007 Brookhart M, Green ML, Parkin G. Agostic interactions in transition metal compounds. Proceedings of the National Academy of Sciences of the United States of America. 104: 6908-14. PMID 17442749 DOI: 10.1073/Pnas.0610747104  1
2007 O'Connor AR, White PS, Brookhart M. The mechanism of polymerization of butadiene by "ligand-free" nickel(II) complexes. Journal of the American Chemical Society. 129: 4142-3. PMID 17371029 DOI: 10.1021/Ja070364S  1
2007 Shiotsuki M, White PS, Brookhart M, Templeton JL. Mechanistic studies of platinum(II)-catalyzed ethylene dimerization: determination of barriers to migratory insertion in diimine Pt(II) hydrido ethylene and ethyl ethylene intermediates. Journal of the American Chemical Society. 129: 4058-67. PMID 17346046 DOI: 10.1021/Ja068118O  1
2007 Roy AH, Lenges CP, Brookhart M. Scope and mechanism of the intermolecular addition of aromatic aldehydes to olefins catalyzed by Rh(I) olefin complexes. Journal of the American Chemical Society. 129: 2082-93. PMID 17263531 DOI: 10.1021/Ja066509X  1
2007 Doherty MD, Grant B, White PS, Brookhart M. Reactions of H 2 and R 3SiH with electrophilic cobalt(III) alkyl complexes: Spectroscopic characterization, dynamics, and chemistry of [Cp*Co(L)(H)(η 2-H 2)][B(Ar F) 4] and [Cp*Co(L)(H)η 2-HSiR 3][B(Ar F) 4] Organometallics. 26: 5950-5960. DOI: 10.1021/Om700620W  1
2007 Doherty MD, Trudeau S, White PS, Morken JP, Brookhart M. Ethylene oligomerization catalyzed by a unique phosphine - Oxazoline palladium(II) complex. Propagation and chain transfer mechanisms Organometallics. 26: 1261-1269. DOI: 10.1021/Om061025V  1
2007 McCord EF, McLain SJ, Nelson LTJ, Ittel SD, Tempel D, Killian CM, Johnson LK, Brookhart M. 13C NMR analysis of α-olefin enchainment in poly(α-olefins) produced with nickel and palladium α-diimine catalysts Macromolecules. 40: 410-420. DOI: 10.1021/Ma061547M  1
2007 Yang J, Brookhart M. Iridium-catalyzed reduction of alkyl halides by triethylsilane Journal of the American Chemical Society. 129: 12656-12657. DOI: 10.1021/Ja075725I  1
2007 Domski GJ, Rose JM, Coates GW, Bolig AD, Brookhart M. Living alkene polymerization: New methods for the precision synthesis of polyolefins Progress in Polymer Science (Oxford). 32: 30-92. DOI: 10.1016/J.Progpolymsci.2006.11.001  1
2006 Sykes AC, White P, Brookhart M. Reactions of Anilines and Benzamides with a Fourteen-Electron Iridium(I) Bis(Phosphinite) Complex: N-H Oxidative Addition versus Lewis Base Coordination. Organometallics. 25: 1664-1675. PMID 19079781 DOI: 10.1021/Om051070N  1
2006 Göttker-Schnetmann I, Heinekey DM, Brookhart M. Temperature- and solvent-dependent binding of dihydrogen in iridium pincer complexes. Journal of the American Chemical Society. 128: 17114-9. PMID 17177464 DOI: 10.1021/Ja065854J  1
2006 Goldman AS, Roy AH, Huang Z, Ahuja R, Schinski W, Brookhart M. Catalytic alkane metathesis by tandem alkane dehydrogenation-olefin metathesis. Science (New York, N.Y.). 312: 257-61. PMID 16614220 DOI: 10.1126/Science.1123787  1
2006 Sykes AC, White P, Brookhart M. Reactions of anilines and benzamides with a 14-electron iridium(I) bis(phosphinite) complex: N-H oxidative addition versus lewis base coordination Organometallics. 25: 1664-1675. DOI: 10.1021/om051070n  1
2006 Zhang L, Brookhart M, White PS. Synthesis, characterization, and ethylene polymerization activities of neutral nickel(II) complexes derived from anilino-substituted enone ligands bearing trifluoromethyl and trifluoroacetyl substituents Organometallics. 25: 1868-1874. DOI: 10.1021/Om050931P  1
2006 Schrekker HS, Kotov V, Preishuber-Pflugl P, White P, Brookhart M. Efficient slurry-phase homopolymerization of ethylene to branched polyethylenes using α-diimine nickel(II) catalysts covalently linked to silica supports Macromolecules. 39: 6341-6354. DOI: 10.1021/Ma061032V  1
2005 Broene RD, Brookhart M, Lamanna WM, Volpe AF. Cobalt-catalyzed dimerization of alpha-olefins to give linear alpha-olefin products. Journal of the American Chemical Society. 127: 17194-5. PMID 16332061 DOI: 10.1021/Ja056655N  1
2005 Williams BS, Leatherman MD, White PS, Brookhart M. Reactions of vinyl acetate and vinyl trifluoroacetate with cationic diimine Pd(II) and Ni(II) alkyl complexes: identification of problems connected with copolymerizations of these monomers with ethylene. Journal of the American Chemical Society. 127: 5132-46. PMID 15810848 DOI: 10.1021/Ja045969S  1
2005 Díaz-Requejo MM, Wehrmann P, Leatherman MD, Trofimenko S, Mecking S, Brookhart M, Pérez PJ. Controlled, copper-catalyzed functionalization of polyolefins Macromolecules. 38: 4966-4969. DOI: 10.1021/Ma050626F  1
2004 Göttker-Schnetmann I, Brookhart M. Mechanistic studies of the transfer dehydrogenation of cyclooctane catalyzed by iridium bis(phosphinite) p-XPCP pincer complexes Journal of the American Chemical Society. 126: 9330-9338. PMID 15281824 DOI: 10.1021/Ja048393F  1
2004 Jenkins JC, Brookhart M. A mechanistic investigation of the polymerization of ethylene catalyzed by neutral Ni(II) complexes derived from bulky anilinotropone ligands. Journal of the American Chemical Society. 126: 5827-42. PMID 15125675 DOI: 10.1021/Ja030634G  1
2004 Karafilidis C, Hermann H, Rufiñska A, Gabor B, Mynott RJ, Breitenbruch G, Weidenthaler C, Rust J, Joppek W, Brookhart MS, Thiel W, Fink G. Metallocene-catalyzed C7-linkage in the hydrooligomerization of norbornene by sigma-bond metathesis: insight into the microstructure of polynorbornene. Angewandte Chemie (International Ed. in English). 43: 2444-6. PMID 15114586 DOI: 10.1002/Anie.200353454  1
2004 Göttker-Schnetmann I, White P, Brookhart M. Iridium Bis(phosphinite) p-XPCP Pincer Complexes: Highly Active Catalysts for the Transfer Dehydrogenation of Alkanes Journal of the American Chemical Society. 126: 1804-1811. PMID 14871112 DOI: 10.1021/Ja0385235  1
2004 Liu W, Brookhart M. Mechanistic studies of palladium(II)-a-diimine-catalyzed polymerizations of cis- and trans-2-butenes Organometallics. 23: 6099-6107. DOI: 10.1021/Om040077M  1
2004 Taw FL, Bergman RG, Brookhart M. Silicon-hydrogen bond activation and formation of silane complexes using a cationic rhodium(III) complex Organometallics. 23: 886-890. DOI: 10.1021/Om0341303  1
2004 Göttker-Schnetmann I, White PS, Brookhart M. Synthesis and Properties of Iridium Bis(phosphinite) Pincer Complexes (p-XPCP)IrH 2, (p-XPCP)Ir(CO), (p-XPCP)Ir(H)(aryl), and {(p-XPCP)Ir}H 2{μ-N 2} and Their Relevance in Alkane Transfer Dehydrogenation Organometallics. 23: 1766-1776. DOI: 10.1021/Om030670O  1
2004 Daugulis O, Brookhart M. Decarbonylation of aryl ketones mediated by bulky cyclopentadienylrhodium Bis(ethylene) complexes Organometallics. 23: 527-534. DOI: 10.1021/Om030563U  1
2004 Corkey BK, Taw FL, Bergman RG, Brookhart M. Aromatic and aldehyde carbon-hydrogen bond activation at cationic Rh(III) centers. Evaluation of electronic substituent effects on aldehyde binding and C-H oxidative addition Polyhedron. 23: 2943-2954. DOI: 10.1016/J.Poly.2004.09.005  1
2003 Taw FL, Mueller AH, Bergman RG, Brookhart M. A mechanistic investigation of the carbon-carbon bond cleavage of aryl and alkyl cyanides using a cationic RhIII silyl complex. Journal of the American Chemical Society. 125: 9808-13. PMID 12904046 DOI: 10.1021/Ja034468O  1
2003 Leatherman MD, Svejda SA, Johnson LK, Brookhart M. Mechanistic studies of nickel(II) alkyl agostic cations and alkyl ethylene complexes: investigations of chain propagation and isomerization in (alpha-diimine)Ni(II)-catalyzed ethylene polymerization. Journal of the American Chemical Society. 125: 3068-81. PMID 12617674 DOI: 10.1021/Ja021071W  1
2003 Diaz-Requejo MM, DiSalvo D, Brookhart M. Synthesis of 1,2-diheteroatom-substituted alkenes via rhodium-catalyzed intramolecular hydrogen transfer. Journal of the American Chemical Society. 125: 2038-9. PMID 12590518 DOI: 10.1021/Ja029393N  0.52
2003 Daugulis O, Brookhart M, White PS. Ethylene polymerization using tetramethyl(2-methylthioethyl)cyclopentadienyl complexes of cobalt Organometallics. 22: 4699-4704. DOI: 10.1021/Om030414B  1
2003 Malinoski JM, Brookhart M. Polymerization and Oligomerization of Ethylene by Cationic Nickel (II) and Palladium(II) Complexes Containing Bidentate Phenacyldiarylphosphine Ligands Organometallics. 22: 5324-5335. DOI: 10.1021/Om030388H  1
2003 Hicks FA, Jenkins JC, Brookhart M. Synthesis and ethylene polymerization activity of a series of 2-anilinotropone-based neutral nickel(II) catalysts Organometallics. 22: 3533-3545. DOI: 10.1021/Om030142C  1
2003 Malinoski JM, White PS, Brookhart M. Structural characterization of [κ2-(t-Bu)2PCH2C(O)C6 H5]PdMe(η2-C2H4)+ BAr′4-: A model for the catalyst resting state for ethylene polymerization Organometallics. 22: 621-623. DOI: 10.1021/Om020951G  1
2003 Jenkins JC, Brookhart M. A highly active anilinoperinaphthenone-based neutral nickel(II) catalyst for ethylene polymerization Organometallics. 22: 250-256. DOI: 10.1021/Om020648F  1
2003 Gottfried AC, Brookhart M. Living and block copolymerization of ethylene and α-olefins using palladium(II)-α-diimine catalysts Macromolecules. 36: 3085-3100. DOI: 10.1021/Ma025902U  0.88
2002 Taw FL, Mellows H, White PS, Hollander FJ, Bergman RG, Brookhart M, Heinekey DM. Synthesis and investigation of [Cp(PMe(3))Rh(H)(H(2))](+) and its partially deuterated and tritiated isotopomers: evidence for a hydride/dihydrogen structure. Journal of the American Chemical Society. 124: 5100-8. PMID 11982375 DOI: 10.1021/Ja0165990  1
2002 Taw FL, White PS, Bergman RG, Brookhart M. Carbon-carbon bond activation of R-CN (R = Me, Ar, iPr, tBu) using a cationic Rh(III) complex. Journal of the American Chemical Society. 124: 4192-3. PMID 11960431 DOI: 10.1021/Ja0255094  1
2002 Daugulis O, Brookhart M, White PS. Phosphinidine-palladium complexes for the polymerization and oligomerization of ethylene Organometallics. 21: 5935-5943. DOI: 10.1021/Om020631X  1
2002 Daugulis O, Brookhart M. Polymerization of ethylene with cationic palladium and nickel catalysts containing bulky nonenolizable imine-phosphine ligands Organometallics. 21: 5926-5934. DOI: 10.1021/Om0206305  1
2002 Liu W, Malinoski JM, Brookhart M. Ethylene polymerization and ethylene/methyl 10-undecenoate copolymerization using nickel(II) and palladium(II) complexes derived from a bulky P,O chelating ligand Organometallics. 21: 2836-2838. DOI: 10.1021/Om0201516  0.88
2002 Reinartz S, Brookhart M, Templeton JL. Platinum(II) and platinum(IV) acyl and formyl complexes Organometallics. 21: 247-249. DOI: 10.1021/Om010772J  1
2002 Preishuber-Pflugl P, Brookhart M. Highly Active Supported Nickel Diimine Catalysts for Polymerization of Ethylene Macromolecules. 35: 6074-6076. DOI: 10.1021/Ma020230T  0.88
2002 Hong SC, Jia S, Teodorescu M, Kowalewski T, Matyjaszewski K, Gottfried AC, Brookhart M. Polyolefin graft copolymers via living polymerization techniques: Preparation of poly(n-butyl acrylate)-graft-polyethylene through the combination of Pd-mediated living olefin polymerization and atom transfer radical polymerization Journal of Polymer Science, Part a: Polymer Chemistry. 40: 2736-2749. DOI: 10.1002/Pola.10348  0.88
2001 Reinartz S, White PS, Brookhart M, Templeton JL. Structural characterization of an intermediate in arene C-H bond activation and measurement of the barrier to C-H oxidative addition: a platinum(II) eta(2)-benzene adduct. Journal of the American Chemical Society. 123: 12724-5. PMID 11741456 DOI: 10.1021/Ja011765P  1
2001 Shultz LH, Tempel DJ, Brookhart M. Palladium(II) beta-agostic alkyl cations and alkyl ethylene complexes: investigation of polymer chain isomerization mechanisms. Journal of the American Chemical Society. 123: 11539-55. PMID 11716707 DOI: 10.1021/Ja011055J  1
2001 Shultz CS, DeSimone JM, Brookhart M. Four- and five-coordinate CO insertion mechanisms in d(8)-nickel(II) complexes. Journal of the American Chemical Society. 123: 9172-3. PMID 11552830 DOI: 10.1021/Ja0160896  0.76
2001 Reinartz S, Baik MH, White PS, Brookhart M, Templeton JL. Synthesis, structure, and electronic properties of monomeric and dimeric trispyrazolylborate platinum(II) hydride complexes. Inorganic Chemistry. 40: 4726-32. PMID 11511222 DOI: 10.1021/Ic010099Q  1
2001 Reinartz S, White PS, Brookhart M, Templeton JL. Five-coordinate trispyrazolylborate dihydridosilyl platinum(IV) complexes. Journal of the American Chemical Society. 123: 6425-6. PMID 11427073 DOI: 10.1021/Ja0104047  1
2001 Dias EL, Brookhart M, White PS. Synthesis and properties of a stable, cationic, rhodium Lewis-acid catalyst for hydrosilation, Mukaiyama aldol and cyclopropanation reactions Chemical Communications. 423-424. DOI: 10.1039/B007815H  1
2001 Ledford J, Shultz CS, Gates DP, White PS, DeSimone JM, Brookhart M. Bond angle effects on the migratory insertion of ethylene and carbon monoxide into palladium(II)-methyl bonds in complexes bearing bidentate phosphine ligands Organometallics. 20: 5266-5276. DOI: 10.1021/Om010489K  1
2001 Hicks FA, Brookhart M. A highly active anilinotropone-based neutral nickel(II) catalyst for ethylene polymerization Organometallics. 20: 3217-3219. DOI: 10.1021/Om010211S  1
2001 and LHS, Brookhart M. Measurement of the Barrier to β-Hydride Elimination in a β-Agostic Palladium−Ethyl Complex: A Model for the Energetics of Chain-Walking in (α-Diimine)PdR+ Olefin Polymerization Catalysts Organometallics. 20: 3975-3982. DOI: 10.1021/Om010197J  0.88
2001 Reinartz S, White PS, Brookhart M, Templeton JL. Syntheses of platinum(IV) aryl dihydride complexes via arene C-H bond activation Organometallics. 20: 1709-1712. DOI: 10.1021/Om001029E  1
2001 Leatherman MD, Brookhart M. Ni(II)-catalyzed polymerization of trans-2-butene [4] Macromolecules. 34: 2748-2750. DOI: 10.1021/Ma002142J  0.92
2001 Gottfried AC, Brookhart M. Living polymerization of ethylene using Pd(II) α-diimine catalysts Macromolecules. 34: 1140-1142. DOI: 10.1021/Ma001595L  0.88
2001 Mccord EF, Mclain SJ, Nelson LTJ, Arthur SD, Coughlin EB, Ittel SD, Johnson LK, Tempel D, Killian CM, Brookhart M. 13C and 2D NMR Analysis of Propylene Polymers Made with α-Diimine Late Metal Catalysts† Macromolecules. 34: 362-371. DOI: 10.1021/Ma0012898  0.88
2001 Muellers BT, Park JW, Brookhart MS, Green MM. Glassy state and secondary structures of chiral macromolecules: Polyisocyanates and polyketones Macromolecules. 34: 572-581. DOI: 10.1021/Ma001102C  1
2001 Brookhart M, Johnnson LK, Killian CM, Svejda SA, Gates D, Tempel DJ, Huff RL, Leatherman MD. Olefin polymerizations using cationic Ni(II) and Pd(II) diimine complexes Macromolecular Symposia. 174: 29-30. DOI: 10.1002/1521-3900(200109)174:1<29::Aid-Masy29>3.0.Co;2-Y  1
2001 Böhm VPW, Brookhart M. Rhodium(I)‐katalysierte Dehydrokupplung von Phosphanen Angewandte Chemie. 113: 4832-4834. DOI: 10.1002/1521-3757(20011217)113:24<4832::Aid-Ange4832>3.0.Co;2-V  0.88
2000 Ittel SD, Johnson LK, Brookhart M. Late-metal catalysts for ethylene homo- and copolymerization. Chemical Reviews. 100: 1169-204. PMID 11749263 DOI: 10.1021/Cr9804644  1
2000 Bosch M, Brookhart MS, Ilg K, Werner H. The Rhodium-Catalyzed Cyclotetramerization of Butadiene: Isolation and Structural Characterization of an Intermediate This work was supported by the Deutsche Forschungsgemeinschaft (SFB 347). K.I. thanks the Fonds der Chemischen Industrie for a Ph.D. scholarship. Angewandte Chemie (International Ed. in English). 39: 2304-2307. PMID 10941072 DOI: 10.1002/1521-3773(20000703)39:13<2304::Aid-Anie2304>3.0.Co;2-V  1
2000 Brookhart M, Grant BE, Lenges CP, Prosenc MH, White PS. High Oxidation State Organocobalt Complexes: Synthesis and Characterization of Dihydridodisilyl Cobalt(V) Species Angewandte Chemie. 39: 1676-1679. PMID 10820474 DOI: 10.1002/(Sici)1521-3773(20000502)39:9<1676::Aid-Anie1676>3.0.Co;2-M  1
2000 Hicks FA, Brookhart M. Synthesis of 2-anilinotropones via palladium-catalyzed amination of 2-triflatotropone Organic Letters. 2: 219-21. PMID 10814286 DOI: 10.1021/Ol991310T  1
2000 Gates DP, White PS, Brookhart M. The insertion of sulfur dioxide into palladium–methyl bonds: the synthesis and X-ray crystal structure of an unusual [(dppp)PdOS(Me)O]2[BAr′4]2 dimer Chemical Communications. 47-48. DOI: 10.1039/A905993H  1
2000 Lenges CP, White PS, Marshall aWJ, Brookhart M. Synthesis, Structure, and Reactivity of [C5Me5CoLL‘] Complexes with L = Pyridine and L‘ = Olefin or L−L‘ = Bipyridine Organometallics. 19: 1247-1254. DOI: 10.1021/Om990860S  1
2000 Reinartz S, White PS, Brookhart M, Templeton JL. Acid-assisted reductive elimination as a route to platinum(II) products from platinum(IV) tris(pyrazolyl)borate reagents Organometallics. 19: 3854-3866. DOI: 10.1021/Om000440Z  1
2000 Reinartz S, White PS, Brookhart M, Templeton JL. Tp′PtH3: a stable platinum(IV) trihydride Organometallics. 19: 3748-3750. DOI: 10.1021/Om000406K  1
2000 Yagyu T, Osakada K, Brookhart M. Single and Multiple Insertion of Carbon−Carbon Triple Bonds into the Palladium−Aryl Bond of Cationic and Neutral Arylpalladium Complexes with a 2,2‘-Bipyridine Ligand Organometallics. 19: 2125-2129. DOI: 10.1021/Om0000360  0.88
2000 Shultz CS, Ledford J, DeSimone JM, Brookhart M. Kinetic studies of migratory insertion reactions at the (1,3- bis(diphenylphosphino)propane)Pd(II) center and their relationship to the alternating copolymerization of ethylene and carbon monoxide Journal of the American Chemical Society. 122: 6351-6356. DOI: 10.1021/Ja994251N  1
2000 Tempel DJ, Johnson LK, Huff RL, White PS, Brookhart M. Mechanistic studies of Pd(II)-α-diimine-catalyzed olefin polymerizations Journal of the American Chemical Society. 122: 6686-6700. DOI: 10.1021/Ja000893V  1
2000 Rachita MJ, Huff RL, Bennett JL, Brookhart M. Oligomerization of ethylene to branched alkenes using neutral phosphinosulfonamide nickel(II) complexes Journal of Polymer Science Part A. 38: 4627-4640. DOI: 10.1002/1099-0518(200012)38:1+<4627::Aid-Pola20>3.0.Co;2-9  0.88
1999 Lenges CP, Brookhart M, White PS. Structure and Reactivity of a Cobalt(I) Phthalaldehyde Complex with Both σ- and π-Bonded Aldehyde Groups. Angewandte Chemie (International Ed. in English). 38: 552-555. PMID 29711779 DOI: 10.1002/(Sici)1521-3773(19990215)38:4<552::Aid-Anie552>3.0.Co;2-B  1
1999 Lenges CP, Brookhart M. Isomerization of Aldehydes Catalyzed by Rhodium(I) Olefin Complexes. Angewandte Chemie. 38: 3533-3537. PMID 10602233 DOI: 10.1002/(Sici)1521-3773(19991203)38:23<3533::Aid-Anie3533>3.0.Co;2-E  0.52
1999 Svejda SA, Brookhart M. Ethylene Oligomerization and Propylene Dimerization Using Cationic (α-Diimine)nickel(II) Catalysts Organometallics. 18: 65-74. DOI: 10.1021/Om980736T  0.88
1999 Small BL, Brookhart M. Polymerization of Propylene by a New Generation of Iron Catalysts: Mechanisms of Chain Initiation, Propagation, and Termination Macromolecules. 32: 2120-2130. DOI: 10.1021/Ma981698S  0.88
1999 Svejda SA, Johnson LK, Brookhart M. Low-temperature spectroscopic observation of chain growth and migratory insertion barriers in (α-diimine)Ni(II) olefin polymerization catalysts [5] Journal of the American Chemical Society. 121: 10634-10635. DOI: 10.1021/Ja991931H  1
1999 Lenges CP, Brookhart M. Addition of Olefins to Aromatic Ketones Catalyzed by Rh(I) Olefin Complexes Journal of the American Chemical Society. 121: 6616-6623. DOI: 10.1021/Ja990702S  0.88
1999 Lenges CP, White PS, Brookhart M. Hydrogen/Deuterium Exchange Reactions and Transfer Hydrogenations Catalyzed by [C5Me5Rh(olefin)2] Complexes: Conversion of Alkoxysilanes to Silyl Enolates† Journal of the American Chemical Society. 121: 4385-4396. DOI: 10.1021/Ja984409O  1
1999 Çetinkaya B, Çetinkaya E, Brookhart M, White PS. Ruthenium(II) complexes with 2,6-pyridyl-diimine ligands: synthesis, characterization and catalytic activity in epoxidation reactions Journal of Molecular Catalysis a-Chemical. 142: 101-112. DOI: 10.1016/S1381-1169(98)00285-4  1
1999 Lenges CP, Brookhart M. Durch Rhodium(I)‐Olefinkomplexe katalysierte Isomerisierung von Aldehyden Angewandte Chemie. 111: 3746-3750. DOI: 10.1002/(Sici)1521-3757(19991203)111:23<3746::Aid-Ange3746>3.0.Co;2-B  0.88
1999 Lenges CP, Brookhart M, White PS. Struktur und Reaktivität eines Phthalaldehyd‐Cobalt(I)‐Komplexes mit einer σ‐ und einer π‐gebundenen Carbonylgruppe Angewandte Chemie. 111: 535-538. DOI: 10.1002/(Sici)1521-3757(19990215)111:4<535::Aid-Ange535>3.0.Co;2-E  1
1998 Tempel DJ, Brookhart M. The Dynamics of the β-Agostic Isopropyl Complex (ArNC(R)−C(R)NAr)Pd(CH(CH2-μ-H)(CH3))+BAr4‘- (Ar = 2,6-C6H3(i-Pr)2): Evidence for In-Place Rotation versus Dissociation of the Agostic Methyl Group Organometallics. 17: 2290-2296. DOI: 10.1021/Om971137+  0.88
1998 and AML, Brookhart M. Reactions of Cationic Palladium(II) Methyl and Vinyl Complexes with Alkynes Organometallics. 17: 1530-1537. DOI: 10.1021/Om9710125  0.88
1998 McLain SJ, Feldman J, McCord EF, Gardner KH, Teasley MF, Coughlin EB, Sweetman KJ, Johnson LK, Brookhart M. Addition Polymerization of Cyclopentene with Nickel and Palladium Catalysts Macromolecules. 31: 6705-6707. DOI: 10.1021/Ma971639Z  0.88
1998 Small BL, Brookhart M. Iron-Based Catalysts with Exceptionally High Activities and Selectivities for Oligomerization of Ethylene to Linear α-Olefins Journal of the American Chemical Society. 120: 7143-7144. DOI: 10.1021/Ja981317Q  0.88
1998 Lenges CP, White aPS, Brookhart M. Mechanistic and Synthetic Studies of the Addition of Alkyl Aldehydes to Vinylsilanes Catalyzed by Co(I) Complexes Journal of the American Chemical Society. 120: 6965-6979. DOI: 10.1021/Ja980610N  0.88
1998 Small BL, Brookhart M, Bennett AMA. Highly Active Iron and Cobalt Catalysts for the Polymerization of Ethylene Journal of the American Chemical Society. 120: 4049-4050. DOI: 10.1021/Ja9802100  0.88
1998 Chang S, Scharrer E, Brookhart M. Catalytic silane alcoholysis based on the C5H5(CO)(PPh3)Fe+ moiety. NMR spectroscopic identification of key intermediates Journal of Molecular Catalysis a-Chemical. 130: 107-119. DOI: 10.1016/S1381-1169(97)00205-7  0.88
1997 Díaz-Requejo MM, Pérez PJ, Brookhart M, Templeton JL. Substituent Effects on the Reaction Rates of Copper-Catalyzed Cyclopropanation and Aziridination of para-Substituted Styrenes† Organometallics. 16: 4399-4402. DOI: 10.1021/Om970382Q  0.88
1997 Killian CM, Johnson aLK, Brookhart M. Preparation of Linear α-Olefins Using Cationic Nickel(II) α-Diimine Catalysts Organometallics. 16: 2005-2007. DOI: 10.1021/Om961057Q  0.88
1997 and CPL, Brookhart M. Co(I)-Catalyzed Inter- and Intramolecular Hydroacylation of Olefins with Aromatic Aldehydes Journal of the American Chemical Society. 119: 3165-3166. DOI: 10.1021/Ja9639776  0.88
1997 LaPointe AM, Rix FC, Brookhart M. Mechanistic studies of palladium(II)-catalyzed hydrosilation and dehydrogenative silation reactions Journal of the American Chemical Society. 119: 906-917. DOI: 10.1021/Ja962979N  1
1997 Lenges CP, Brookhart M, Grant BE. H/D exchange reactions between C6D6 and C5Me5Co(CH2=CHR)2 (R = H, SiMe3): Evidence for oxidative addition of Csp2−H bonds to the [C5Me5(L)Co] moiety Journal of Organometallic Chemistry. 528: 199-203. DOI: 10.1016/S0022-328X(96)06592-8  0.88
1997 McLain SJ, McCord EF, Johnson LK, Ittel SD, Nelson LTJ, Arthur SD, Halfhill MJ, Teasley MF, Tempel DJ, Killian C, Brookhart MS. 13C and 2D NMR of novel ethylene and olefin polymers made with new late metal catalysts American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 38: 772-773.  1
1996 Casarrubios L, Pérez JA, Brookhart M, Templeton JL. Lewis acid-catalyzed synthesis of aziridines Journal of Organic Chemistry. 61: 8358-8359. DOI: 10.1021/Jo961391W  1
1996 Killian CM, Tempel DJ, Johnson LK, Brookhart M. Living polymerization of α-olefins using Ni(II)-α-diimine catalysts. Synthesis of new block polymers based on α-olefins Journal of the American Chemical Society. 118: 11664-11665. DOI: 10.1021/Ja962516H  1
1996 Brookhart M, Wagner MI. Synthesis of a Stereoblock Polyketone through Ancillary Ligand Exchange Journal of the American Chemical Society. 118: 7219-7220. DOI: 10.1021/Ja9610141  0.88
1996 DiRenzo GM, White PS, Brookhart M. Mechanistic studies of catalytic olefin dimerization reactions using electrophilic η3-allyl-palladium(II) complexes Journal of the American Chemical Society. 118: 6225-6234. DOI: 10.1021/Ja9602354  1
1996 Rix FC, Brookhart M, White PS. Mechanistic Studies of the Palladium(II)-Catalyzed Copolymerization of Ethylene with Carbon Monoxide Journal of the American Chemical Society. 118: 4746-4764. DOI: 10.1021/Ja953276T  1
1996 Johnson LK, Mecking S, Brookhart M. Copolymerization of Ethylene and Propylene with Functionalized Vinyl Monomers by Palladium(II) Catalysts Journal of the American Chemical Society. 118: 267-268. DOI: 10.1021/Ja953247I  0.88
1996 Rix FC, Brookhart M, White PS. Electronic effects on the {Beta}-alkyl migratory insertion reaction of para-substituted styrene methyl palladium complexes Journal of the American Chemical Society. 118: 2436-2448. DOI: 10.1021/Ja9527434  1
1995 Scharrer E, Chang S, Brookhart M. Spectroscopic Characterization And Dynamic Properties Of Cationic Eta 2-Silane And Eta 2-H2 Complexes Of General Structure Cp(Co)(L)Fe(Hsir3)+ And Cp( Co)(L)Fe(H2)+ (L=Pet3, Pph3) Organometallics. 14: 5686-5694. DOI: 10.1021/Om00012A039  0.88
1995 Johnson LK, Killian CM, Brookhart M. New Pd(II)- and Ni(II)-Based Catalysts for Polymerization of Ethylene and .alpha.-Olefins Journal of the American Chemical Society. 117: 6414-6415. DOI: 10.1021/Ja00128A054  0.88
1995 Rix FC, Brookhart M. Energetics of Migratory Insertion Reactions in Pd(II) Acyl Ethylene, Alkyl Ethylene, and Alkyl Carbonyl Complexes Journal of the American Chemical Society. 117: 1137-1138. DOI: 10.1021/Ja00108A034  0.88
1995 Scharrer E, Brookhart M. Insertion Reactions Of Electrophilic Iron Carbene Complexes With Organosilanes : A Synthetic And Mechanistic Study Journal of Organometallic Chemistry. 497: 61-71. DOI: 10.1016/0022-328X(95)00117-9  0.88
1995 Brookhart MS, DeSimone JM, Johnson RE, Tahiliani S. t-Boc protected poly(p-hydroxystyrene-alt-carbon monoxide): a new class of deep-UV resists Proceedings of Spie - the International Society For Optical Engineering. 2438: 787-794.  1
1994 Powell KR, Perez PJ, Luan L, Feng SG, White PS, Brookhart M, Templeton JL. Synthesis and Reactivity of Low-Valent Amido, Imido, Azavinylidene, and Nitrido Complexes of Tungsten Organometallics. 13: 1851-1864. DOI: 10.1021/Om00017A048  1
1994 Hauptman E, Brookhart M, Fagan PJ, Calabrese JC. Generation of [C5(CH3)5Ru(NO)(CH3)(H2O)]+ [BAr'4]- (Ar' = 3,5-C6H3(CF3)2) and its reaction with methyl acrylate to produce chelate complexes of the type C5(CH3)5Ru(NO)(CH(R)CH2COOCH3)+ (R = H, CH3) Organometallics. 13: 774-780. DOI: 10.1021/Om00015A010  0.88
1994 Hauptman E, Sabo-Etienne S, White PS, Brookhart M, Garner JM, Fagan PJ, Calabrese JC. Design and Study of Rh(III) Catalysts for the Selective Tail-to-Tail Dimerization of Methyl Acrylate Journal of the American Chemical Society. 116: 8038-8060. DOI: 10.1021/Ja00097A011  1
1994 Brookhart M, Wagner MI, Balavoine GGA, Haddou HA. Polymers with Main-Chain Chirality. Synthesis of Highly Isotactic, Optically Active Poly(4-tert-butylstyrene-alt-CO) Using Pd(II) Catalysts Based on C2-Symmetric Bisoxazoline Ligands Journal of the American Chemical Society. 116: 3641-3642. DOI: 10.1021/Ja00087A077  0.88
1994 Chang S, Yoon J, Brookhart M. Carbon-Carbon Bond-Forming Reactions of Eta(3)-Allyl Iron Tricarbonyl Anions with Carbon Electrophiles Journal of the American Chemical Society. 116: 1869-1879. DOI: 10.1021/Ja00084A030  0.88
1994 Perez PJ, White PS, Brookhart M, Templeton JL. Nitrene Transfer to Trimethylphosphine from Cationic Tungsten Tosylnitrene Complexes [Tp'(CO)2W(NTs)][X] Inorganic Chemistry. 33: 6050-6056. DOI: 10.1021/Ic00104A013  1
1993 Chang S, White PS, Brookhart M. Hydride reduction of (diene)iron tricarbonyl complexes as a route to substituted (allyl)iron tricarbonyl anions. Detection of a formyl intermediate in the hydride reduction of (1,3-butadiene)iron tricarbonyl by Et3BH- Organometallics. 12: 3636-3644. DOI: 10.1021/Om00033A041  1
1993 Pérez PJ, Brookhart M, Templeton JL. A copper(I) catalyst for carbene and nitrene transfer to form cyclopropanes, cyclopropenes, and aziridines Organometallics. 12: 261-262. DOI: 10.1021/Om00026A007  0.88
1992 Brookhart M, Grant B, Volpe AF. [(3,5-(CF3)2C6H3)4B]-[H(OEt2)2]+: a convenient reagent for generation and stabilization of cationic, highly electrophilic organometallic complexes Organometallics. 11: 3920-3922. DOI: 10.1021/Om00059A071  0.88
1992 Luan L, Brookhart M, Templeton JL. Intramolecular hydride migration from formyl to carbonyl and nitrene ligands Organometallics. 11: 1433-1435. DOI: 10.1021/Om00040A003  0.88
1992 Brookhart M, Chandler WA, Pfister AC, Santini CC, White PS. Synthesis and reactivity of bidentate phosphine iron complex [(C2F5)2PCH2CH2P(C2F5)2]Fe(CO)3 Organometallics. 11: 1263-1274. DOI: 10.1021/Om00039A036  1
1992 Bennett MA, McMahon IJ, Pelling S, Brookhart M, Lincoln DM. Protonation of diene complexes of rhodium, iridium, ruthenium, and osmium: a fine balance between terminal and agostic hydrides Organometallics. 11: 127-138. DOI: 10.1021/Om00037A028  0.88
1992 Brookhart M, Hauptman E, Lincoln DM. .beta.-Migratory insertion reactions of (.eta.5-C5R'5)Rh(L)(C2H4)R+BF4- (R' = hydrogen, methyl; R = hydrogen, ethyl; L = P(OMe)3, PMe3). Comparison of the energetics of hydride versus alkyl migration Journal of the American Chemical Society. 114: 10394-10401. DOI: 10.1021/Ja00052A040  0.88
1992 Brookhart M, Hauptman E. Mechanism of rhodium(III)-catalyzed methyl acrylate dimerization Journal of the American Chemical Society. 114: 4437-4439. DOI: 10.1021/Ja00037A081  0.88
1992 Brookhart M, Chandler W, Kessler RJ, Liu Y, Pienta NJ, Santini CC, Hall C, Perutz RN, Timney JA. Matrix isolation and transient absorption studies of [bis[bis(pentafluoroethyl)phosphino]ethane]tetracarbonylchromium: intermolecular alkane complexes and intramolecular F-coordination Journal of the American Chemical Society. 114: 3802-3815. DOI: 10.1021/Ja00036A032  0.88
1991 Brookhart M, Sabo-Etienne S. Catalytic tail-to-tail dimerization of methyl acrylate using rhodium(III) catalysts Journal of the American Chemical Society. 113: 2777-2779. DOI: 10.1021/Ja00007A076  0.88
1991 Brookhart M, Liu Y. Investigation of the stereochemistry of iron-carbon.alpha. bond cleavage when phenylcyclopropane is generated by .gamma.-ionization of stereospecifically deuterated C5H5(CO)2FeCHDCHDCH(OCH3)C6H5 complexes. A transition-state model for transfer of the carbene ligand from C5H5(CO)2Fe:CHR+ to alkenes Journal of the American Chemical Society. 113: 939-944. DOI: 10.1021/Ja00003A029  0.88
1991 Brookhart M, Liu Y, Goldman EW, Timmers DA, Williams GD. Enantioselective cyclopropane syntheses using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+. A mechanistic analysis of the carbene transfer reaction Journal of the American Chemical Society. 113: 927-939. DOI: 10.1021/Ja00003A028  0.88
1991 Feng SG, Luan L, White P, Brookhart MS, Templeton JL, Young CG. Mononuclear cis-carbonyloxotungsten(IV) complexes of hydrotris(3,5-dimethyl-1-pyrazolyl)borate Inorganic Chemistry. 30: 2582-2584. DOI: 10.1021/Ic00012A003  1
1990 Brookhart M, Volpe AF, Lincoln DM, Horvath IT, Millar JM. Detection of an alkyl ethylene complex during ethylene polymerization by a cobalt(III) catalyst. Energetics of the .beta.-migratory insertion reaction Journal of the American Chemical Society. 112: 5634-5636. DOI: 10.1021/Ja00170A035  0.88
1990 Brookhart M, Lincoln DM, Bennett MA, Pelling S. Dynamics of agostic complexes of the type C5R5(C2H4)M(CH2CH2-.mu.-H)+. Energy differences between and ancillary ligand control of agostic and terminal hydride structures Journal of the American Chemical Society. 112: 2691-2694. DOI: 10.1021/Ja00163A033  0.88
1989 Brookhart M, Liu Y. Resolution of the chiral-at-iron acetyl complexes C5H5(CO)(PR3)FeC(O)CH3 (R = CH3, CH2CH3). Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFe)- and (RFe)-C5H5(CO)(PR3)Fe:CHCH3+ (R = CH3, CH2CH3) Organometallics. 8: 1572-1573. DOI: 10.1021/Om00108A037  0.88
1989 Brookhart M, Liu Y. When phenylcyclopropanes are generated by .gamma.-ionization of erythro- and threo-d2-C5H5(CO)2FeCHDCHDCH(OCH3)C6H5, cleavage of the Fe-C.alpha. bond occurs with inversion of configuration of C.alpha. Organometallics. 8: 1569-1572. DOI: 10.1021/Om00108A036  0.88
1989 Brookhart M, Lincoln DM, Volpe AF, Schmidt GF. Ligand and substituent effects on the dynamics and structure of agostic ethylenecobalt complexes of the type C5R5(L)Co(CH2CHR'-.mu.-H)+ BF4- [L = P(OMe)3, PMe3; R = H, Me; R' = H, Me] Organometallics. 8: 1212-1218. DOI: 10.1021/Om00107A014  0.88
1989 Brookhart M, Studabaker WB, Humphrey MB, Husk GR. Synthesis and spectral characterization of a series of iron and ruthenium benzylidene complexes, Cp(CO)(L)M:CH(C6H4R)+ (M = Fe, Ru; L = CO, PPh3; R = p-H, p-F, p-CH3, p-OCH3). Barriers to aryl rotation and benzylidene transfer reactions Organometallics. 8: 132-140. DOI: 10.1021/Om00103A016  0.88
1989 Brookhart M, Yoon J, Noh SK. Reactions of the (.eta.3-allyl)iron tricarbonyl anion with carbon electrophiles Journal of the American Chemical Society. 111: 4117-4118. DOI: 10.1021/Ja00193A063  0.88
1989 Brookhart M, Buck RC, Danielson E. Synthesis, spectroscopic characterization, dynamics, and phosphine trapping of Cp(CO)Fe[.eta.3-CH(R)C6H5] complexes (R = H, OCH3) Journal of the American Chemical Society. 111: 567-574. DOI: 10.1021/Ja00184A026  0.88
1989 Brookhart M, Buck RC. Formation of Cp(CO)(PR3)FeCH(OCH3)C6H5 complexes via PR3 substitution reactions, hydride addition to Cp(CO)(PR3)Fe:C(OCH3)C6H5+, and methoxide addition to Cp(CO)(PR3)Fe:CHC6H5+. Kinetic and thermodynamic diastereoselectivities. Relative reactivities of synclinal and anticlinal iron carbene isomers Journal of the American Chemical Society. 111: 559-567. DOI: 10.1021/Ja00184A025  0.88
1989 Brookhart M, Buck RC. Enantioselective benzylidene transfer reactions using the chiral-at-iron benzylidene complexes (SFeSc)- and (RFeSc)-Cp(CO)(Ph2R★P_Fe=CH6H5+ (R★ = (S-2-methylbutyl) and SFe- and (RFe)-Cp(CO)PEt3Fe=CHC6H5+ Journal of Organometallic Chemistry. 370: 111-127. DOI: 10.1016/0022-328X(89)87279-1  0.88
1988 Brookhart M, Noh SK, Timmers FJ, Hong YH. Anionic manganese tricarbonyl complexes of C7 and C8 cyclic dienes and polyenes: synthesis and reactions with electrophiles Organometallics. 7: 2458-2465. DOI: 10.1021/Om00102A005  0.88
1988 Brookhart M, Liu Y, Buck RC. Diastereoselective reactions of chiral-at-iron carbene complexes C5H5(CO)(PR3)Fe:CHR+. Synclinal isomers are more reactive than anticlinal isomers Journal of the American Chemical Society. 110: 2337-2339. DOI: 10.1021/Ja00215A074  0.88
1987 Brookhart M, Noh SK, Timmers FJ. General route to anionic (.eta.4-diene)manganese tricarbonyl complexes. Reactions with electrophiles Organometallics. 6: 1829-1831. DOI: 10.1021/Om00151A043  0.88
1987 Brookhart M, Studabaker WB, Husk GR. Iron and ruthenium cyclopropylcarbene complexes C5H5(CO)2M:CH(c-C3H5)+ CF3SO3-. Cyclopropylcarbene transfer reactions Organometallics. 6: 1141-1145. DOI: 10.1021/Om00149A001  0.88
1987 Brookhart M, Studabaker WB. Cyclopropanes from reactions of transition metal carbene complexes with olefins Chemical Reviews. 87: 411-432. DOI: 10.1021/Cr00078A008  0.88
1986 Rush PK, Noh SK, Brookhart M. A general route to C6H6(CO)2Mn-R complexes via C6H6(CO)2Mn−Na+: alkyl group migrations from manganese to the coordinated arene ring Organometallics. 5: 1745-1747. DOI: 10.1021/Om00139A038  0.88
1986 Studabaker WB, Brookhart M. (η5-C5H5)(Ph2PCH2CH2PPH2)RuCH2+ AsF6−. Spectral Characterization and measurement of the barrier to methylene rotation Journal of Organometallic Chemistry. 310. DOI: 10.1016/S0022-328X(00)99564-0  0.88
1985 Brookhart M, Cox K, Cloke FGN, Green JC, Green MLH, Hare PM, Bashkin J, Derome AE, Grebenik PD. Hexakis(trimethylphosphine)molybdenum chemistry: Dinitrogen, ethylene, butadiene, η-cyclopentadienyl, and related derivatives Journal of the Chemical Society, Dalton Transactions. 423-433. DOI: 10.1039/Dt9850000423  1
1985 Timmers F, Brookhart M. Synthesis and reactivity of methyl-substituted butenylmanganese tricarbonyl complexes containing a two-electron, three-center Mn.cntdot..cntdot..cntdot.H.cntdot..cntdot..cntdot.C interaction Organometallics. 4: 1365-1371. DOI: 10.1021/Om00127A011  0.88
1985 Brookhart M, Studabaker WB, Husk GR. Synthesis, spectral characterization, and carbene-transfer reactions of CpFe(CO)2=CH(c-C3H5)+ CF3SO3-. Stabilization of cyclopropylmethylidene by an organometallic fragment Organometallics. 4: 943-944. DOI: 10.1021/Om00124A028  0.88
1985 Schmidt GF, Brookhart M. Implications of three-center, two-electron M--H--C bonding for related alkyl migration reactions: design and study of an ethylene polymerization catalyst Journal of the American Chemical Society. 107: 1443-1444. DOI: 10.1021/Ja00291A073  0.88
1984 Brookhart M, Kegley SE, Husk GR. Transfer of ethylidene from .eta.5-C5H5(CO)2Fe:CHMe+ to para-substituted styrenes. Loss of stereochemistry about the C.alpha.-C.beta. double bond of cis-.beta.-deuterio-p-methoxystyrene Organometallics. 3: 650-652. DOI: 10.1021/Om00082A033  0.88
1984 Brookhart M, Timmers D, Tucker JR, Williams GD, Husk GR, Brunner H, Hammer B. Enantioselective Cyclopropane Synthesis Using The Chiral Carbene Complexes (Sfesc)- And (Rfesc)-(C5H5)(Co)(Ph2R*P)Fe:Chch3+ (R* = (S)-2-Methylbutyl). Role Of Metal Vs. Ligand Chirality In The Optical Induction Cheminform. 15. DOI: 10.1002/Chin.198406258  0.88
1984 Humphrey MB, Lamanna WM, Brookhart M, Husk GR. CRYSTAL AND MOLECULAR STRUCTURE OF (η5-PENTAMETHYLCYCLOPENTADIENYL)(TRIFLUOROMETHANESULFONATO)IRON(II) DICARBONYL: A STRONG ELECTROSTATIC IRON-TRIFLATE INTERACTION Cheminform. 15. DOI: 10.1002/Chin.198405067  0.88
1983 Schultz AJ, Teller RG, Beno MA, Williams JM, Brookhart M, Lamanna W, Humphrey MB. Argonne intense pulsed neutron source used to solve the molecular structure of a novel organometallic complex. Science (New York, N.Y.). 220: 197-9. PMID 17795829 DOI: 10.1126/Science.220.4593.197  1
1983 Brookhart M, Green MLH, Pardy RBA. Two-electron, three-centre carbon–hydrogen–cobalt bonds in the compounds [Co(η-C5Me4R)(η-C2H4)(η-C2H4-µ-H)] BF4, R = Me and Et Journal of the Chemical Society, Chemical Communications. 691-693. DOI: 10.1039/C39830000691  0.88
1983 Brookhart M, Timmers D, Tucker JR, Williams GD, Husk GR, Brunner H, Hammer B. Enantioselective cyclopropane synthesis using the chiral carbene complexes (SFeSC)- and (RFeSC)-(C5H5)(CO)(Ph2R*P)Fe=CHCH3+ (R*=(S)-2-methylbutyl). Role of metal vs. ligand chirality in the optical induction Journal of the American Chemical Society. 105: 6721-6723. DOI: 10.1021/Ja00360A034  0.88
1983 Brookhart M, Tucker JR, Husk GR. Synthesis, spectral characterization and alkylidene-transfer reactions of electrophilic iron carbene complexes Cp(CO)(L)Fe:CHR+ (L = CO, PPh3; R = Me, Et, CHMe2) Journal of the American Chemical Society. 105: 258-264. DOI: 10.1021/Ja00340A020  0.88
1983 Humphrey MB, Lamanna WM, Brookhart M, Husk GR. Crystal and molecular structure of (.eta.5-pentamethylcyclopentadienyl)(trifluoromethanesulfonato)iron(II) dicarbonyl: a strong electrostatic iron-triflate interaction Inorganic Chemistry. 22: 3355-3358. DOI: 10.1021/Ic00164A035  0.88
1983 Brookhart M, Green MLH. Carbonhydrogen-transition metal bonds Journal of Organometallic Chemistry. 250: 395-408. DOI: 10.1016/0022-328X(83)85065-7  0.88
1982 Kegley SE, Brookhart M, Husk GR. Spectroscopic characterization of electrophilic d4 methylene and benzylidene complexes of the type Cp(CO)2(L)M(:CHR)+ (L = PPh3, PEt3; M = Mo, W; R = H, Ph). Experimental determination of barriers to rotation about the tungsten-methylene multiple bond Organometallics. 1: 760-762. DOI: 10.1021/Om00065A019  0.88
1982 Karel KJ, Albright TA, Brookhart M. Fluxionality in (cycloheptatriene)iron tricarbonyl complexes Organometallics. 1: 419-430. DOI: 10.1021/Om00063A001  0.88
1982 Brookhart M, Lamanna W, Humphrey MB. Structural characterization and fluxional behavior of cyclohexenylmanganese tricarbonyl. Intramolecular carbon-hydrogen bond activation via a 2-electron, 3-center manganese...hydrogen...carbon interaction Journal of the American Chemical Society. 104: 2117-2126. DOI: 10.1021/Ja00372A006  0.88
1982 Lau CP, Singh P, Cline SJ, Seiders R, Brookhart M, Marsh WE, Hodgson DJ, Hatfield WE. Synthesis of 1,1'-bicobaltocene salts of tetracyano-p-quinodimethanide and the structure of 1,1'-bicobaltocene[CoIIICoIII] tris(tetracyano-p-quinodimethanide) Inorganic Chemistry. 13: 208-212. DOI: 10.1021/Ic00131A038  0.88
1982 Brookhart M, Lamanna W, Humphrey MB. Structural characterization and fluxional behavior of cyclohexenylmanganese tricarbonyl. Intramolecular carbon-hydrogen bond activation via a 2-electron, 3-center manganese...hydrogen...carbon interaction Cheminform. 13. DOI: 10.1002/Chin.198232283  0.88
1981 Karel KJ, Brookhart M, Aumann R. Detailed mechanism of thermal hydrogen migration in cyclohexadieneiron tricarbonyl Journal of the American Chemical Society. 103: 2695-2698. DOI: 10.1021/Ja00400A034  0.88
1981 Brookhart M, Tucker JR, Husk GR. Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+ Journal of the American Chemical Society. 103: 979-981. DOI: 10.1021/Ja00394A063  0.88
1981 Henis NBH, Lamanna W, Humphrey MB, Bursey MM, Brookhart MS. A pivotal application of field desorption mass spectrometry to distinguish between molecular and ionic organometallic complexes Inorganica Chimica Acta. 54: L11-L12. DOI: 10.1016/S0020-1693(00)95368-4  1
1981 Brookhart M, Humphrey MB, Kratzer HJ, Nelson GO. Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions Cheminform. 12. DOI: 10.1002/Chin.198112326  0.88
1980 Brookhart M, Humphrey MB, Kratzer HJ, Nelson GO. Reactions of .eta.5-C5H5(CO)2FeCHC6H5+ with alkenes and alkynes. Observation of efficient benzylidene-transfer reactions Journal of the American Chemical Society. 102: 7802-7803. DOI: 10.1021/Ja00546A039  0.88
1980 Brookhart M, Tucker JR, Flood TC, Jensen J. Spectroscopic characterization of an electrophilic transition-metal-methylene complex, .eta.5-C5H5[(C6H5)2PCH2CH2P(C6H5)2]Fe:CH2+ Journal of the American Chemical Society. 102: 1203-1205. DOI: 10.1021/Ja00523A068  0.88
1980 Brookhart M, Tucker JR, Husk GR. Measurement of barriers to aryl rotation in Cp(CO)2FeCHC6H5+ and Cp(CO)2FeCH(p-CH3C6H4)+ Journal of Organometallic Chemistry. 193. DOI: 10.1016/S0022-328X(00)86090-8  0.88
1980 Brookhart M, Tucker JR, Husk GR. Facile synthesis, spectral characterization, and ethylidene transfer reactions of complexes of the type Cp(CO)(L)Fe:CHCH3+ Cheminform. 12. DOI: 10.1002/Chin.198122291  0.88
1979 Lewis CP, Brookhart M, Hitching W, Eisenstadt A. Fluxional Behavior and Substituent Site Preferences in Cationic Monosubstituted Tropyliumiron Tricarbonyl Complexes Journal of the American Chemical Society. 101: 4896-4906. DOI: 10.1021/Ja00511A019  0.88
1979 Brookhart M, Nelson GO. The reaction of benzylideneacetoneiron tricarbonyl with dienes; measurement of relative reactivities using competition experiments Journal of Organometallic Chemistry. 164: 193-202. DOI: 10.1016/S0022-328X(00)86704-2  0.88
1979 Lewis CP, Kitching W, Eisenstadt A, Brookhart M. Fluxional Behavior And Substituent Site Preferences In Cationic Monosubstituted Tropyliumiron Tricarbonyl Complexes Cheminform. 10. DOI: 10.1002/Chin.197947298  0.88
1978 Karel KJ, Brookhart M. Detection and measurement of the rate of 1,3-iron shift in cycloheptatrieneiron tricarbonyl Journal of the American Chemical Society. 100: 1619-1621. DOI: 10.1021/Ja00473A058  0.88
1978 Karel KJ, Brookhart M. Detection And Measurement Of The Rate Of 1,3-Iron Shift In Cycloheptatrieneiron Tricarbonyl Cheminform. 9. DOI: 10.1002/Chin.197825260  0.88
1977 Brookhart M, Graham CR, Nelson GO, Scholes G. Chemistry Of Diene And Enone Iron Tricarbonyl Complexes Annals of the New York Academy of Sciences. 295: 254-270. DOI: 10.1111/J.1749-6632.1977.Tb41840.X  0.88
1977 Brookhart M, Nelson GO. Isolation of stable secondary cationic iron carbene complexes dicarbonyl(.eta.5-cyclopentadienyl)phenylcarbeneiron hexafluorophosphate and carbonyl(.eta.5-cyclopentadienyl)triphenylphosphine(phenylcarbene)iron hexafluorophosphate Journal of the American Chemical Society. 99: 6099-6101. DOI: 10.1021/Ja00460A045  0.88
1977 Graham CR, Scholes G, Brookhart M. Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthetic and mechanistic studies of the reactions of 1,3,5-cyclooctatriene and its derivatives with benzylideneacetoneiron tricarbonyl Journal of the American Chemical Society. 99: 1180-1188. DOI: 10.1021/Ja00446A033  0.88
1977 Brookhart M, Karel KJ, Nance LE. The stereospecificity of proton addition to cycloheptatrieneiron tricarbonyl Journal of Organometallic Chemistry. 140: 203-210. DOI: 10.1016/S0022-328X(00)93196-6  0.88
1977 Brookhart MS, Lewis CP, Eisenstadt A. Low temperature spectroscopic observation of oxygen-protonated troponeiron tricarbonyl complexes Journal of Organometallic Chemistry. 127: C14-C18. DOI: 10.1016/S0022-328X(00)84206-0  1
1977 Brookhart M, Nelson GO. Isolation of stable secondary cationic iron carbene complexes dicarbonyl(.eta.5-cyclopentadienyl)phenylcarbeneiron hexafluorophosphate and carbonyl(.eta.5-cyclopentadienyl)triphenylphosphine(phenylcarbene)iron hexafluorophosphate Cheminform. 8. DOI: 10.1002/Chin.197749315  0.88
1977 Graham CR, Scholes G, Brookhart M. Selective Trapping Of Dienes By Benzylideneacetoneiron Tricarbonyl. Synthetic And Mechanistic Studies Of The Reactions Of 1,3,5-Cyclooctatriene And Its Derivatives With Benzylideneacetoneiron Tricarbonyl Cheminform. 8. DOI: 10.1002/Chin.197719301  0.88
1976 Brookhart M, Nelson GO, Scholes G, Watson RA. Preparation of bicyclo[4.2.0]octa-2,4-dien-7-one via trapping with benzylideneacetoneiron tricarbonyl Journal of the Chemical Society, Chemical Communications. 195-196. DOI: 10.1039/C39760000195  1
1976 Brookhart MS, Koszalka GW, Nelson GO, Scholes G, Watson RA. Synthesis and reactions of the tautomeric complexes η-2,3,4,5-cyclooctatrienoneiron tricarbonyl and bicyclo[4.2.0]octa-2,4-dien-7-oneiron tricarbonyl. Generation of bicyclo[4.2.0]octa-2,4-dien-7-one Journal of the American Chemical Society. 98: 8155-8161. DOI: 10.1021/Ja00441A045  1
1976 Brookhart M, Whitesides TH, Crockett JM. Spectroscopic studies of the structures of protonated dieneiron tricarbonyl complexes Inorganic Chemistry. 15: 1550-1554. DOI: 10.1021/Ic50161A017  0.88
1976 Brookhart M, Nelson GO, Scholes G, Watson RA. Preparation Of Bicyclo(4.2.0)Octa-2,4-Dien-7-One By Trapping With Benzylideneacetoneiron Tricarbonyl Cheminform. 7. DOI: 10.1002/Chin.197630203  0.88
1975 Lewis CP, Brookhart M. Epimerization of bicyclo[6.1.0.]nonatriene Journal of the American Chemical Society. 97: 651-653. DOI: 10.1021/Ja00836A035  0.88
1974 Brookhart M, Young GJ. Low temperature protonation of cyclo-octa-1,5-diene-(duroquinone)nickel(0) Journal of the Chemical Society, Chemical Communications. 205-205. DOI: 10.1039/C39740000205  0.88
1974 Scholes G, Graham CR, Brookhart M. Selective trapping of dienes by benzylideneacetoneiron tricarbonyl. Synthesis and thermal rearrangement of tricyclo[4.4.0.02,5]deca-7,9-diene and tricyclo[4.3.0.07,9]nona-2,4-diene Journal of the American Chemical Society. 96: 5665-5667. DOI: 10.1021/Ja00824A106  0.88
1974 Brookhart M, Harris DL. .pi. to .sigma. Rearrangements upon metal protonation of polyolefin-transition metal complexes Inorganic Chemistry. 13: 1540-1541. DOI: 10.1021/Ic50136A064  0.88
1974 Brookhart M, Dedmond RE, Lewis BF. Isomerization of bicyclo[5.1.0]-2,4-octadieneiron tricarbonyl to bicyclo[4.2.0]-2,4-octadieneiron tricarbonyl Journal of Organometallic Chemistry. 72: 239-245. DOI: 10.1016/S0022-328X(00)81497-7  1
1974 Humphries BA, Rohrbach MS, Brookhart MS, Harrison JH. Kinetics of formation of the 4,4′-bis-dimethylaminodiphenyl carbonium ion (BDC+) and its reaction with sulfhydryl residues Bioorganic Chemistry. 3: 163-175. DOI: 10.1016/0045-2068(74)90040-6  1
1974 Brookhart M, Harris DL. .pi. to .sigma. Rearrangements upon metal protonation of polyolefin-transition metal complexes Cheminform. 5. DOI: 10.1002/Chin.197433348  0.88
1973 Brookhart M, Harris DL, Dammann RC. Observation of a π- to σ-rearrangement upon proton addition to bicyclo[6,1,0]nonatrienetricarbonylmolybdenum Journal of the Chemical Society, Chemical Communications. 187. DOI: 10.1039/C39730000187  1
1973 Reardon EJ, Brookhart M. cis4-Cyclononatetraeneiron tricarbonyl. Its synthesis, thermal rearrangement, and low-temperature protonation Journal of the American Chemical Society. 95: 4311-4316. DOI: 10.1021/Ja00794A028  0.88
1973 Brookhart M, Lippman NM, Reardon EJ. Isomerization of 1,3,5-cyclooctatrieneiron tricarbonyl to bicyclo[4.2.0]octa-2,4,-dieneiron tricarbonyl Journal of Organometallic Chemistry. 54: 247-253. DOI: 10.1016/S0022-328X(00)85015-9  1
1973 Reardon EJJ, Brookhart M. Cis(4)-Cyclononatetraeneiron Tricarbonyl, Its Synthesis, Thermal Rearrangement, And Low-Temperature Protonation Cheminform. 4. DOI: 10.1002/Chin.197336365  0.88
1973 Brookhart M, Harris DL, Dammann RC. Beobachtung Einer Pi‐Sigma‐Umlagerung Nach Addition Von Protonen An Bicyclo(6,1,0)Nonatrientricarbonylmolybdaen Cheminform. 4. DOI: 10.1002/Chin.197326410  0.88
1973 Brookhart M, Davis ER, Harris DL. Protonierung Von Cyclooctatetraeneisentricarbonyl Und Methylcyclooctatetraeneisentricarbonyl Bei Niedriger Temperatur, Erzeugung Und Beobachtung Von Cyclooctatrienyleisentricarbonyl-Kationen Cheminform. 4. DOI: 10.1002/Chin.197302380  0.88
1973 Isidor JL, Brookhart MS, McKee RL. A novel furan dimer Journal of Organic Chemistry. 38: 612-613.  1
1972 Brookhart M, Davis ER, Harris DL. Low-temperature protonation of cyclooctatetraeneiron tricarbonyl and methylcyclooctatetraeneiron tricarbonyl. Generation and observation of cyclooctatrienyliron tricarbonyl cations Journal of the American Chemical Society. 94: 7853-7858. DOI: 10.1021/Ja00777A030  0.88
1972 Lustgarten RK, Brookhart M, Winstein S. Degenerate and nondegenerate isomerizations of 7-norbornadienyl cations Journal of the American Chemical Society. 94: 2347-2363. DOI: 10.1021/Ja00762A028  1
1972 Brookhart M, Harris DL. Generation of trans-π-pentadienyliron tricarbonyl cations from protonation of (trans,trans-2,4-hexadienal)iron tricarbonyl Journal of Organometallic Chemistry. 42: 441-446. DOI: 10.1016/S0022-328X(00)90094-9  1
1972 Lustgarten RK, Brookhart M, Winstein S. Entartete Und Nichtentartete Isomerisierungen Von Norbornadienyl-(7)-Kationen Cheminform. 3. DOI: 10.1002/Chin.197226165  0.88
1971 Brookhart M, Davis ER. Low temperature protonation of methylcyclooctatetraeneiron tricarbonyl Tetrahedron Letters. 12: 4349-4352. DOI: 10.1016/S0040-4039(01)97438-6  0.88
1971 Brookhart M, Lustgarten RK, Harris DL, Winstein S. Direkte Beobachtungen An Substituierten Quadricyclyl-Kationen Und Ihre Umlagerungen Cheminform. 2. DOI: 10.1002/Chin.197128152  0.88
1970 Brookhart M, Davis ER. Direct observation of the cyclooctatrienyliron tricarbonyl cation and its electrocyclic ring closure to the bicyclo[5.1.0]octadienyliron tricarbonyl cation Journal of the American Chemical Society. 92: 7622-7623. DOI: 10.1021/Ja00729A038  0.88
1970 Richey, Jr. HG, Nichols JD, Gassman PG, Fentiman, Jr. AF, Winstein S, Brookhart M, Lustgarten RK. Additions and Corrections - A Classical 7-Norbornenyl Cation. Competition between Aryl and Alkenyl Functions in Stabilizing 7-Aryl-7-norborenyl Cations Journal of the American Chemical Society. 92: 7240-7240. DOI: 10.1021/Ja00727A605  0.88
1970 Richey HG, Nichols JD, Gassman PG, Fentiman AF, Winstein S, Brookhart M, Lustgarten RK. A classical 7-norbornenyl cation. Competition between aryl and alkenyl functions in stabilizing 7-aryl-7-norbornenyl cations [1] Journal of the American Chemical Society. 92: 3783-3784. DOI: 10.1021/Ja00715A041  1
1970 Richey HGJ, Nichols JD, Gassman PG, Fentiman AFJ, Winstein S, Brookhart M, Lustgarten RK. Ein Klassisches Norbornenyl-(7)-Kation, Konkurrenz Zwischen Aryl- Und Alkenylfunktionen In Stabilisierten 7-Aryl-Norbornenyl-(7)-Kationen Cheminform. 1. DOI: 10.1002/Chin.197037140  0.88
1968 Lustgarten RK, Brookhart M, Winstein S. Direct observation of methyl-substituted 7-norbornadienyl and bicyclo[3.2.0]heptadienyl cations [18] Journal of the American Chemical Society. 90: 7364-7366. DOI: 10.1021/Ja01028A045  1
1967 Brookhart M, Lustgarten RK, Winstein S. 7-Phenyl- and 7-methoxynorbornadienyl cations Journal of the American Chemical Society. 89: 6354-6355. DOI: 10.1021/Ja01000A067  0.88
1967 Brookhart M, Lustgarten RK, Winstein S. Bridge flipping and rearrangement of norbornadienyl and 7-methylnorbornadienyl cations [3] Journal of the American Chemical Society. 89: 6352-6354. DOI: 10.1021/Ja01000A066  1
1967 Lustgarten RK, Brookhart M, Winstein S. Degenerate five-carbon scrambling in the 7-norbornadienyl cation. Journal of the American Chemical Society. 89: 6350-6352. DOI: 10.1021/Ja01000A065  0.88
1964 Baker EW, Brookhart MS, Corwin AH. Piperidinate complexes of nickel and copper mesoporphyrin IX Journal of the American Chemical Society. 86: 4587-4590. DOI: 10.1021/Ja01075A014  1
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