Year |
Citation |
Score |
2023 |
Blackburn MAS, Wagen CC, Bodrogean MR, Tadross PM, Bendelsmith AJ, Kutateladze DA, Jacobsen EN. Dual-Hydrogen-Bond Donor and Brønsted Acid Cocatalysis Enables Highly Enantioselective Protio-Semipinacol Rearrangement Reactions. Journal of the American Chemical Society. PMID 37428959 DOI: 10.1021/jacs.3c02960 |
0.839 |
|
2023 |
Ovian JM, Vojáčková P, Jacobsen EN. Enantioselective Transition-Metal Catalysis via an Anion-Binding Approach. Nature. PMID 36787801 DOI: 10.1038/s41586-023-05804-3 |
0.824 |
|
2022 |
Samha MH, Wahlman JLH, Read JA, Werth J, Jacobsen EN, Sigman MS. Exploring Structure-Function Relationships of Aryl Pyrrolidine-Based Hydrogen-Bond Donors in Asymmetric Catalysis Using Data-Driven Techniques. Acs Catalysis. 12: 14836-14845. PMID 36816226 DOI: 10.1021/acscatal.2c04824 |
0.614 |
|
2022 |
Wagen CC, Jacobsen EN. Evidence for Oxonium Ions in Ethereal "Hydrogen Chloride". Organic Letters. PMID 36450043 DOI: 10.1021/acs.orglett.2c03622 |
0.799 |
|
2022 |
Wagen CC, McMinn SE, Kwan EE, Jacobsen EN. Screening for Generality in Asymmetric Catalysis. Nature. PMID 36049504 DOI: 10.1038/s41586-022-05263-2 |
0.838 |
|
2022 |
Kutateladze DA, Wagen CC, Jacobsen EN. Chloride-Mediated Alkene Activation Drives Enantioselective Thiourea and Hydrogen Chloride Co-Catalyzed Prins Cyclizations. Journal of the American Chemical Society. PMID 35994741 DOI: 10.1021/jacs.2c06688 |
0.843 |
|
2022 |
Li Q, Levi SM, Wagen C, Wendlandt AE, Jacobsen EN. Site-selective, stereocontrolled glycosylation of minimally protected sugars. Nature. PMID 35709829 DOI: 10.1038/s41586-022-04958-w |
0.816 |
|
2021 |
Kutateladze DA, Jacobsen EN. Cooperative Hydrogen-Bond-Donor Catalysis with Hydrogen Chloride Enables Highly Enantioselective Prins Cyclization Reactions. Journal of the American Chemical Society. PMID 34812618 DOI: 10.1021/jacs.1c10890 |
0.434 |
|
2021 |
Sharma HA, Essman JZ, Jacobsen EN. Enantioselective catalytic 1,2-boronate rearrangements. Science (New York, N.Y.). 374: 752-757. PMID 34735250 DOI: 10.1126/science.abm0386 |
0.843 |
|
2021 |
Strassfeld DA, Algera RF, Wickens ZK, Jacobsen EN. A Case Study in Catalyst Generality: Simultaneous, Highly-Enantioselective Brønsted- and Lewis-Acid Mechanisms in Hydrogen-Bond-Donor Catalyzed Oxetane Openings. Journal of the American Chemical Society. PMID 34152759 DOI: 10.1021/jacs.1c03992 |
0.463 |
|
2021 |
Ronchi E, Paradine SM, Jacobsen EN. Enantioselective, Catalytic Multicomponent Synthesis of Homoallylic Amines Enabled by Hydrogen-Bonding and Dispersive Interactions. Journal of the American Chemical Society. PMID 33949857 DOI: 10.1021/jacs.1c03024 |
0.848 |
|
2020 |
Metternich JB, Reiterer M, Jacobsen EN. Asymmetric Nazarov Cyclizations of Unactivated Dienones by Hydrogen-Bond-Donor/Lewis Acid Co-Catalyzed, Enantioselective Proton-Transfer. Advanced Synthesis & Catalysis. 362: 4092-4097. PMID 33162875 DOI: 10.1002/Adsc.202000831 |
0.434 |
|
2020 |
Kennedy CR, Choi BY, Reeves MR, Jacobsen EN. Enantioselective Catalysis of an Anionic Oxy-Cope Rearrangement Enabled by Synergistic Ion Binding. Israel Journal of Chemistry. 60: 461-474. PMID 33132416 DOI: 10.1002/Ijch.201900168 |
0.44 |
|
2020 |
Sharma H, Mennie KM, Kwan EE, Jacobsen EN. Enantioselective Aryl-Iodide-Catalyzed Wagner-Meerwein Rearrangements. Journal of the American Chemical Society. PMID 32845619 DOI: 10.1021/Jacs.0C08150 |
0.763 |
|
2020 |
Levin MD, Ovian JM, Read JA, Sigman MS, Jacobsen EN. Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides. Journal of the American Chemical Society. PMID 32799536 DOI: 10.1021/Jacs.0C07043 |
0.852 |
|
2020 |
Li Q, Levi SM, Jacobsen EN. Highly Selective β-Mannosylations and β-Rhamnosylations Catalyzed by Bis-thiourea. Journal of the American Chemical Society. PMID 32527078 DOI: 10.1021/Jacs.0C04255 |
0.328 |
|
2020 |
Strassfeld DA, Wickens ZK, Picazo E, Jacobsen EN. Highly Enantioselective, Hydrogen-Bond-Donor Catalyzed Additions to Oxetanes. Journal of the American Chemical Society. PMID 32364378 DOI: 10.1021/Jacs.0C03991 |
0.857 |
|
2020 |
Kutateladze DA, Strassfeld DA, Jacobsen EN. Enantioselective Tail-to-Head Cyclizations Catalyzed by Dual-Hydrogen-Bond Donors. Journal of the American Chemical Society. PMID 32223127 DOI: 10.1021/Jacs.0C02665 |
0.543 |
|
2020 |
Mayfield AB, Metternich JB, Trotta AH, Jacobsen EN. Stereospecific Furanosylations Catalyzed by Bis-Thiourea Hydrogen-Bond Donors. Journal of the American Chemical Society. PMID 32013410 DOI: 10.1021/Jacs.0C00335 |
0.504 |
|
2019 |
Ovian JM, Jacobsen EN. A catalytic one-two punch. Science (New York, N.Y.). 366: 948-949. PMID 31753983 DOI: 10.1126/Science.Aaz6166 |
0.835 |
|
2019 |
Bendelsmith AJ, Kim SC, Wasa M, Roche SP, Jacobsen EN. Enantioselective Synthesis of α-Allyl Amino Esters via Hydrogen-Bond Donor Catalysis. Journal of the American Chemical Society. PMID 31280564 DOI: 10.1021/Jacs.9B05556 |
0.707 |
|
2019 |
Haj MK, Banik SM, Jacobsen EN. Catalytic, Enantioselective 1,2-Difluorination of Cinnamamides. Organic Letters. PMID 30963766 DOI: 10.1021/Acs.Orglett.9B00938 |
0.826 |
|
2019 |
Levi SM, Li Q, Rötheli AR, Jacobsen EN. Catalytic activation of glycosyl phosphates for stereoselective coupling reactions. Proceedings of the National Academy of Sciences of the United States of America. 116: 35-39. PMID 30559190 DOI: 10.1073/Pnas.1811186116 |
0.483 |
|
2018 |
Zhou B, Haj MK, Jacobsen EN, Houk KN, Xue XS. Mechanism and Origins of Chemo- and Stereoselectivities of Aryl Iodide-Catalyzed Asymmetric Difluorinations of β-Substituted Styrenes. Journal of the American Chemical Society. PMID 30350956 DOI: 10.1021/Jacs.8B05935 |
0.461 |
|
2018 |
Kwan EE, Zeng Y, Besser HA, Jacobsen EN. Concerted nucleophilic aromatic substitutions. Nature Chemistry. PMID 30013193 DOI: 10.1038/S41557-018-0079-7 |
0.66 |
|
2018 |
Wendlandt AE, Vangal P, Jacobsen EN. Quaternary stereocentres via an enantioconvergent catalytic S1 reaction. Nature. 556: 447-451. PMID 29695848 DOI: 10.1038/S41586-018-0042-1 |
0.823 |
|
2018 |
Mennie KM, Banik SM, Reichert EC, Jacobsen EN. Catalytic Diastereo- and Enantioselective Fluoroamination of Alkenes. Journal of the American Chemical Society. PMID 29583001 DOI: 10.1021/Jacs.8B02143 |
0.836 |
|
2017 |
Banik SM, Levina A, Hyde AM, Jacobsen EN. Lewis acid enhancement by hydrogen-bond donors for asymmetric catalysis. Science (New York, N.Y.). 358: 761-764. PMID 29123063 DOI: 10.1126/Science.Aao5894 |
0.825 |
|
2017 |
Klausen RS, Kennedy CR, Hyde AM, Jacobsen EN. Chiral Thioureas Promote Enantioselective Pictet-Spengler Cyclization by Stabilizing Every Intermediate and Transition State in the Carboxylic Acid-Catalyzed Reaction. Journal of the American Chemical Society. PMID 28787140 DOI: 10.1021/Jacs.7B06811 |
0.777 |
|
2017 |
Banik SM, Mennie K, Jacobsen EN. Catalytic 1,3-Difunctionalization via Oxidative C-C Bond Activation. Journal of the American Chemical Society. PMID 28622723 DOI: 10.1021/Jacs.7B05160 |
0.785 |
|
2017 |
Park Y, Harper KC, Kuhl N, Kwan EE, Liu RY, Jacobsen EN. Macrocyclic bis-thioureas catalyze stereospecific glycosylation reactions. Science (New York, N.Y.). 355: 162-166. PMID 28082586 DOI: 10.1126/Science.Aal1875 |
0.824 |
|
2017 |
List B, Shevchenko GA, Park Y, Harper KC, Kuhl N, Kwan EE, Liu RY, Jacobsen EN. Stereospecific Glycosylation through Catalytic Stereoinversion Synfacts. 13: 420. DOI: 10.1055/S-0036-1590092 |
0.482 |
|
2016 |
Ford DD, Lehnherr D, Kennedy CR, Jacobsen EN. Anion-Abstraction Catalysis: The Cooperative Mechanism of α-Chloroether Activation by Dual Hydrogen-Bond Donors. Acs Catalysis. 6: 4616-4620. PMID 31754547 DOI: 10.1021/Acscatal.6B01384 |
0.849 |
|
2016 |
Kwan EE, Park Y, Besser HA, Anderson TL, Jacobsen EN. Sensitive and Accurate 13C Kinetic Isotope Effect Measurements Enabled by Polarization Transfer. Journal of the American Chemical Society. PMID 28005341 DOI: 10.1021/Jacs.6B10621 |
0.301 |
|
2016 |
Park Y, Schindler CS, Jacobsen EN. Enantioselective Aza-Sakurai Cyclizations: Dual Role of Thiourea as H-bond Donor and Lewis Base. Journal of the American Chemical Society. PMID 27787993 DOI: 10.1021/Jacs.6B09736 |
0.703 |
|
2016 |
Woerly E, Banik SM, Jacobsen EN. Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source. Journal of the American Chemical Society. PMID 27709922 DOI: 10.1021/Jacs.6B09499 |
0.856 |
|
2016 |
Kennedy CR, Lehnherr D, Rajapaksa NS, Ford DD, Park Y, Jacobsen EN. Mechanism-Guided Development of a Highly Active Bis-Thiourea Catalyst for Anion-Abstraction Catalysis. Journal of the American Chemical Society. 138: 13525–8. PMID 27704810 DOI: 10.1021/Jacs.6B09205 |
0.84 |
|
2016 |
Hennessy ET, Jacobsen EN. Organometallic chemistry: A new metathesis. Nature Chemistry. 8: 741-742. PMID 27442278 DOI: 10.1038/Nchem.2581 |
0.457 |
|
2016 |
Kennedy CR, Guidera JA, Jacobsen EN. Synergistic Ion-Binding Catalysis Demonstrated via an Enantioselective, Catalytic [2,3]-Wittig Rearrangement. Acs Central Science. 2: 416-23. PMID 27413786 DOI: 10.1021/Acscentsci.6B00125 |
0.531 |
|
2016 |
Banik SM, Medley JW, Jacobsen EN. Catalytic, asymmetric difluorination of alkenes to generate difluoromethylated stereocenters. Science (New York, N.Y.). 353: 51-4. PMID 27365443 DOI: 10.1126/Science.Aaf8078 |
0.828 |
|
2016 |
Kennedy CR, Lin S, Jacobsen EN. The Cation-π Interaction in Small-Molecule Catalysis. Angewandte Chemie (International Ed. in English). PMID 27329991 DOI: 10.1002/Anie.201600547 |
0.55 |
|
2016 |
Lehnherr D, Ford DD, Bendelsmith AJ, Kennedy CR, Jacobsen EN. Conformational Control of Chiral Amido-Thiourea Catalysts Enables Improved Activity and Enantioselectivity. Organic Letters. 18: 3214-7. PMID 27294369 DOI: 10.1021/Acs.Orglett.6B01435 |
0.855 |
|
2016 |
Ford DD, Lehnherr D, Kennedy CR, Jacobsen EN. On- and Off-Cycle Catalyst Cooperativity in Anion-Binding Catalysis. Journal of the American Chemical Society. 138: 7860-3. PMID 27276389 DOI: 10.1021/Jacs.6B04686 |
0.855 |
|
2016 |
Banik SM, Medley JW, Jacobsen EN. Catalytic, Diastereoselective 1,2-Difluorination of Alkenes. Journal of the American Chemical Society. PMID 27046019 DOI: 10.1021/Jacs.6B02391 |
0.828 |
|
2016 |
Ford DD, Lehnherr D, Kennedy CR, Jacobsen EN. Anion-Abstraction Catalysis: The Cooperative Mechanism of α-Chloroether Activation by Dual H-Bond Donors Acs Catalysis. 6: 4616–4620. DOI: 10.1021/acscatal.6b01384 |
0.761 |
|
2016 |
Kennedy CR, Lin S, Jacobsen EN. Die Kation-π-Wechselwirkung in der Katalyse mit niedermolekularen Verbindungen Angewandte Chemie. 128: 12784-12814. DOI: 10.1002/Ange.201600547 |
0.45 |
|
2016 |
Jacobsen EN. Advanced Synthesis & Catalysis after 15 Years: Challenges and New Opportunities for Synthetic Science Advanced Synthesis and Catalysis. 358: 2. DOI: 10.1002/Adsc.201600013 |
0.323 |
|
2015 |
Turek AK, Hardee DJ, Ullman AM, Nocera DG, Jacobsen EN. Activation of Electron-Deficient Quinones through Hydrogen-Bond-Donor-Coupled Electron Transfer. Angewandte Chemie (International Ed. in English). PMID 26612607 DOI: 10.1002/Anie.201508060 |
0.312 |
|
2015 |
Liu RY, Wasa M, Jacobsen EN. Enantioselective synthesis of tertiary α-chloro esters by non-covalent catalysis. Tetrahedron Letters. 56: 3428-3430. PMID 26085694 DOI: 10.1016/J.Tetlet.2015.01.124 |
0.751 |
|
2015 |
Witten MR, Jacobsen EN. A Simple Primary Amine Catalyst for Enantioselective α-Hydroxylations and α-Fluorinations of Branched Aldehydes. Organic Letters. 17: 2772-5. PMID 25952578 DOI: 10.1021/Acs.Orglett.5B01193 |
0.689 |
|
2014 |
Fang YQ, Tadross PM, Jacobsen EN. Highly enantioselective, intermolecular hydroamination of allenyl esters catalyzed by bifunctional phosphinothioureas. Journal of the American Chemical Society. 136: 17966-8. PMID 25496451 DOI: 10.1021/Ja5117638 |
0.483 |
|
2014 |
Zhang H, Lin S, Jacobsen EN. Enantioselective selenocyclization via dynamic kinetic resolution of seleniranium ions by hydrogen-bond donor catalysts. Journal of the American Chemical Society. 136: 16485-8. PMID 25380129 DOI: 10.1021/Ja510113S |
0.66 |
|
2014 |
Yeung CS, Ziegler RE, Porco JA, Jacobsen EN. Thiourea-catalyzed enantioselective addition of indoles to pyrones: alkaloid cores with quaternary carbons. Journal of the American Chemical Society. 136: 13614-7. PMID 25213353 DOI: 10.1021/Ja508523G |
0.522 |
|
2014 |
Wasa M, Liu RY, Roche SP, Jacobsen EN. Asymmetric Mannich synthesis of α-amino esters by anion-binding catalysis. Journal of the American Chemical Society. 136: 12872-5. PMID 25178040 DOI: 10.1021/Ja5075163 |
0.728 |
|
2014 |
White DE, Tadross PM, Lu Z, Jacobsen EN. A broadly applicable and practical oligomeric (salen) Co catalyst for enantioselective epoxide ring-opening reactions. Tetrahedron. 70: 4165-4180. PMID 25045188 DOI: 10.1016/J.Tet.2014.03.043 |
0.767 |
|
2014 |
Xu H, Zhang H, Jacobsen EN. Chiral sulfinamidourea and strong Brønsted acid-cocatalyzed enantioselective Povarov reaction to access tetrahydroquinolines. Nature Protocols. 9: 1860-6. PMID 25010906 DOI: 10.1038/Nprot.2014.125 |
0.637 |
|
2014 |
Witten MR, Jacobsen EN. Catalytic asymmetric synthesis of 8-oxabicyclooctanes by intermolecular [5+2] pyrylium cycloadditions. Angewandte Chemie (International Ed. in English). 53: 5912-6. PMID 24782332 DOI: 10.1002/Anie.201402834 |
0.726 |
|
2014 |
Bergonzini G, Schindler CS, Wallentin CJ, Jacobsen EN, Stephenson CR. Photoredox Activation and Anion Binding Catalysis in the Dual Catalytic Enantioselective Synthesis of β-Amino Esters. Chemical Science (Royal Society of Chemistry : 2010). 5. PMID 24294480 DOI: 10.1039/C3Sc52265B |
0.632 |
|
2014 |
Witten MR, Jacobsen EN. Catalytic Asymmetric Synthesis of 8-Oxabicyclooctanes Synfacts. 10: 753-753. DOI: 10.1055/S-0034-1378223 |
0.537 |
|
2013 |
Brindle CS, Yeung CS, Jacobsen EN. Chiral β-Iodoamines by Urea-Catalyzed Iodocyclization of Trichloroacetimidates. Chemical Sciences Journal. 4. PMID 24416631 DOI: 10.1039/C3Sc50410G |
0.823 |
|
2013 |
Ford DD, Nielsen LP, Zuend SJ, Musgrave CB, Jacobsen EN. Mechanistic basis for high stereoselectivity and broad substrate scope in the (salen)Co(III)-catalyzed hydrolytic kinetic resolution. Journal of the American Chemical Society. 135: 15595-608. PMID 24041239 DOI: 10.1021/Ja408027P |
0.817 |
|
2013 |
Rajapaksa NS, Jacobsen EN. Enantioselective catalytic transannular ketone-ene reactions. Organic Letters. 15: 4238-41. PMID 23923982 DOI: 10.1021/Ol401968M |
0.851 |
|
2013 |
Birrell JA, Jacobsen EN. A practical method for the synthesis of highly enantioenriched trans-1,2-amino alcohols. Organic Letters. 15: 2895-7. PMID 23742206 DOI: 10.1021/Ol401013S |
0.65 |
|
2013 |
Schindler CS, Jacobsen EN. Chemistry. A new twist on cooperative catalysis. Science (New York, N.Y.). 340: 1052-3. PMID 23723222 DOI: 10.1126/Science.1238769 |
0.705 |
|
2013 |
Brown AR, Uyeda C, Brotherton CA, Jacobsen EN. Enantioselective thiourea-catalyzed intramolecular cope-type hydroamination. Journal of the American Chemical Society. 135: 6747-9. PMID 23597402 DOI: 10.1021/Ja402893Z |
0.801 |
|
2013 |
Rajapaksa NS, McGowan MA, Rienzo M, Jacobsen EN. Enantioselective total synthesis of (+)-reserpine. Organic Letters. 15: 706-9. PMID 23331099 DOI: 10.1021/Ol400046N |
0.866 |
|
2013 |
Lalonde MP, McGowan MA, Rajapaksa NS, Jacobsen EN. Enantioselective formal aza-Diels-Alder reactions of enones with cyclic imines catalyzed by primary aminothioureas. Journal of the American Chemical Society. 135: 1891-4. PMID 23321009 DOI: 10.1021/Ja310718F |
0.834 |
|
2013 |
Brak K, Jacobsen EN. Asymmetric ion-pairing catalysis. Angewandte Chemie (International Ed. in English). 52: 534-61. PMID 23192886 DOI: 10.1002/Anie.201205449 |
0.813 |
|
2013 |
Gerard B, O’Shea MW, Donckele E, Kesavan S, Akella LB, Xu H, Jacobsen EN, Marcaurelle LA. Correction to Application of a Catalytic Asymmetric Povarov Reaction using Chiral Ureas to the Synthesis of a Tetrahydroquinoline Library Acs Combinatorial Science. 16: 46-46. DOI: 10.1021/Co400123X |
0.619 |
|
2012 |
Tadross PM, Jacobsen EN. Site-selective reactions: Remodelling by diversity and design. Nature Chemistry. 4: 963-5. PMID 23174971 DOI: 10.1038/Nchem.1509 |
0.341 |
|
2012 |
Gerard B, O'Shea MW, Donckele E, Kesavan S, Akella LB, Xu H, Jacobsen EN, Marcaurelle LA. Application of a catalytic asymmetric Povarov reaction using chiral ureas to the synthesis of a tetrahydroquinoline library. Acs Combinatorial Science. 14: 621-30. PMID 23088641 DOI: 10.1021/Co300098V |
0.547 |
|
2012 |
Lin S, Jacobsen EN. Thiourea-catalysed ring opening of episulfonium ions with indole derivatives by means of stabilizing non-covalent interactions. Nature Chemistry. 4: 817-24. PMID 23000995 DOI: 10.1038/Nchem.1450 |
0.659 |
|
2012 |
Burns NZ, Jacobsen EN. Organic chemistry: catalysis in tight spaces. Nature. 483: 278-9. PMID 22422255 DOI: 10.1038/483278A |
0.745 |
|
2012 |
Nielsen LP, Zuend SJ, Ford DD, Jacobsen EN. Mechanistic basis for high reactivity of (salen)Co-OTs in the hydrolytic kinetic resolution of terminal epoxides. The Journal of Organic Chemistry. 77: 2486-95. PMID 22292515 DOI: 10.1021/Jo300181F |
0.854 |
|
2011 |
Lee Y, Klausen RS, Jacobsen EN. Thiourea-catalyzed enantioselective iso-Pictet-Spengler reactions. Organic Letters. 13: 5564-7. PMID 21919478 DOI: 10.1021/Ol202300T |
0.855 |
|
2011 |
Burns NZ, Witten MR, Jacobsen EN. Dual catalysis in enantioselective oxidopyrylium-based [5 + 2] cycloadditions. Journal of the American Chemical Society. 133: 14578-81. PMID 21848300 DOI: 10.1021/Ja206997E |
0.83 |
|
2011 |
Birrell JA, Desrosiers JN, Jacobsen EN. Enantioselective acylation of silyl ketene acetals through fluoride anion-binding catalysis. Journal of the American Chemical Society. 133: 13872-5. PMID 21800916 DOI: 10.1021/Ja205602J |
0.766 |
|
2011 |
Beck EM, Hyde AM, Jacobsen EN. Chiral sulfinamide/achiral sulfonic acid cocatalyzed enantioselective protonation of enol silanes. Organic Letters. 13: 4260-3. PMID 21786775 DOI: 10.1021/Ol201608A |
0.697 |
|
2011 |
Uyeda C, Jacobsen EN. Transition-state charge stabilization through multiple non-covalent interactions in the guanidinium-catalyzed enantioselective Claisen rearrangement. Journal of the American Chemical Society. 133: 5062-75. PMID 21391614 DOI: 10.1021/Ja110842S |
0.774 |
|
2011 |
Burns NZ, Witten MR, Jacobsen EN. Thiourea-Catalyzed Intramolecular [5+2] Cycloadditions Synfacts. 2011: 1241-1241. DOI: 10.1055/S-0031-1289260 |
0.783 |
|
2011 |
Beck EM, Hyde AM, Jacobsen EN. Enantioselective Protonation of Enol Silanes by ProtonatedChiral Sulfinamides Synfacts. 2011: 1131-1131. DOI: 10.1055/S-0030-1261120 |
0.395 |
|
2011 |
Jacobsen E, Uyeda C, Rötheli A. Chiral Guanidinium-Catalyzed Enantioselective Claisen Rearrangement Synfacts. 2011: 0215-0215. DOI: 10.1055/S-0030-1259348 |
0.518 |
|
2010 |
Jacobsen EN, MacMillan DW. Organocatalysis. Proceedings of the National Academy of Sciences of the United States of America. 107: 20618-9. PMID 21119011 DOI: 10.1073/Pnas.1016087107 |
0.667 |
|
2010 |
Uyeda C, Rötheli AR, Jacobsen EN. Catalytic enantioselective claisen rearrangements of O-allyl β-ketoesters. Angewandte Chemie (International Ed. in English). 49: 9753-6. PMID 21080393 DOI: 10.1002/Anie.201005183 |
0.743 |
|
2010 |
Knowles RR, Jacobsen EN. Attractive noncovalent interactions in asymmetric catalysis: links between enzymes and small molecule catalysts. Proceedings of the National Academy of Sciences of the United States of America. 107: 20678-85. PMID 20956302 DOI: 10.1073/Pnas.1006402107 |
0.692 |
|
2010 |
Veitch GE, Jacobsen EN. Tertiary aminourea-catalyzed enantioselective iodolactonization. Angewandte Chemie (International Ed. in English). 49: 7332-5. PMID 20803601 DOI: 10.1002/Anie.201003681 |
0.509 |
|
2010 |
McGowan MA, Stevenson CP, Schiffler MA, Jacobsen EN. An enantioselective total synthesis of (+)-peloruside A. Angewandte Chemie (International Ed. in English). 49: 6147-50. PMID 20586089 DOI: 10.1002/Anie.201002177 |
0.846 |
|
2010 |
Brown AR, Kuo WH, Jacobsen EN. Enantioselective catalytic alpha-alkylation of aldehydes via an SN1 pathway. Journal of the American Chemical Society. 132: 9286-8. PMID 20568761 DOI: 10.1021/Ja103618R |
0.625 |
|
2010 |
Knowles RR, Lin S, Jacobsen EN. Enantioselective thiourea-catalyzed cationic polycyclizations. Journal of the American Chemical Society. 132: 5030-2. PMID 20369901 DOI: 10.1021/Ja101256V |
0.781 |
|
2010 |
Xu H, Zuend SJ, Woll MG, Tao Y, Jacobsen EN. Asymmetric cooperative catalysis of strong Brønsted acid-promoted reactions using chiral ureas. Science (New York, N.Y.). 327: 986-90. PMID 20167783 DOI: 10.1126/Science.1182826 |
0.854 |
|
2010 |
Jacobsen E, McGowan M, Stevenson C, Schiffler M. Synthesis of (+)-Peloruside A Synfacts. 2010: 1330-1330. DOI: 10.1055/S-0030-1258875 |
0.799 |
|
2010 |
Jacobsen E, Veitch G. Highly Enantioselective Iodolactonization Synfacts. 2010: 1310-1310. DOI: 10.1055/S-0030-1258783 |
0.433 |
|
2010 |
Jacobsen E, Brown A, Kuo W. Catalytic Asymmetric α-Alkylation of Aldehydes with Benzhydryl Cations Synfacts. 2010: 1069-1069. DOI: 10.1055/s-0030-1257965 |
0.515 |
|
2010 |
Xu H, Zuend SJ, Woll MG, Tao Y, Jacobsen EN. Asymmetric Povarov Reactions Cobalt-Catalyzed by Chiral Ureas/AchiralAcids Synfacts. 2010: 601-601. DOI: 10.1055/S-0029-1219750 |
0.848 |
|
2010 |
Zuend SJ, Coughlin MP, Lalonde MP, Jacobsen EN. Gram-Scale Strecker Synthesis of Unnatural α-AminoAcids Synfacts. 2010: 108-108. DOI: 10.1055/S-0029-1218492 |
0.779 |
|
2010 |
SCHAUS SE, BRAANALT J, JACOBSEN EN. ChemInform Abstract: Asymmetric Hetero-Diels-Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes. Cheminform. 29: no-no. DOI: 10.1002/chin.199825159 |
0.705 |
|
2010 |
LEIGHTON JL, JACOBSEN EN. ChemInform Abstract: Efficient Synthesis of (R)-4-((Trimethylsilyl)oxy)-2-cyclopentenone by Enantioselective Catalytic Epoxide Ring Opening. Cheminform. 27: no-no. DOI: 10.1002/CHIN.199620079 |
0.328 |
|
2010 |
LARROW JF, JACOBSEN EN, GAO Y, HONG Y, NIE X, ZEPP CM. ChemInform Abstract: A Practical Method for the Large-Scale Preparation of (N,N′-Bis(3,5-di- tert-butylsalicylidene)-1,2-cyclohexanediaminato(2-))manganese(III) Chloride, a Highly Enantioselective Epoxidation Catalyst. Cheminform. 25: no-no. DOI: 10.1002/chin.199436210 |
0.353 |
|
2010 |
JACOBSEN EN. ChemInform Abstract: Asymmetric Catalytic Epoxidation of Unfunctionalized Olefins Cheminform. 25: no-no. DOI: 10.1002/CHIN.199431302 |
0.463 |
|
2009 |
Mita T, Jacobsen EN. Bifunctional Asymmetric Catalysis with Hydrogen Chloride: Enantioselective Ring-Opening of Aziridines Catalyzed by a Phosphinothiourea. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 2009: 1680-1684. PMID 20161432 DOI: 10.1055/S-0029-1217344 |
0.532 |
|
2009 |
Zuend SJ, Coughlin MP, Lalonde MP, Jacobsen EN. Scaleable catalytic asymmetric Strecker syntheses of unnatural alpha-amino acids. Nature. 461: 968-70. PMID 19829379 DOI: 10.1038/Nature08484 |
0.834 |
|
2009 |
Zuend SJ, Jacobsen EN. Mechanism of amido-thiourea catalyzed enantioselective imine hydrocyanation: transition state stabilization via multiple non-covalent interactions. Journal of the American Chemical Society. 131: 15358-74. PMID 19778044 DOI: 10.1021/Ja9058958 |
0.825 |
|
2009 |
Peterson EA, Jacobsen EN. Enantioselective, thiourea-catalyzed intermolecular addition of indoles to cyclic N-acyl iminium ions. Angewandte Chemie (International Ed. in English). 48: 6328-31. PMID 19610008 DOI: 10.1002/Anie.200902420 |
0.601 |
|
2009 |
Loy RN, Jacobsen EN. Enantioselective intramolecular openings of oxetanes catalyzed by (salen)Co(III) complexes: access to enantioenriched tetrahydrofurans. Journal of the American Chemical Society. 131: 2786-7. PMID 19199427 DOI: 10.1021/Ja809176M |
0.746 |
|
2009 |
Klausen RS, Jacobsen EN. Weak Brønsted acid-thiourea co-catalysis: enantioselective, catalytic protio-Pictet-Spengler reactions. Organic Letters. 11: 887-90. PMID 19178157 DOI: 10.1021/Ol802887H |
0.846 |
|
2009 |
Mita T, Jacobsen EN. Bifunctional asymmetric catalysis with hydrogen chloride: Enantioselective ring opening of aziridines catalyzed by a phosphinothiourea Synlett. 1680-1684. DOI: 10.1055/s-0029-1217344 |
0.348 |
|
2009 |
Klausen RS, Jacobsen EN. Brønsted Acid-Thiourea Co-Catalysis Synfacts. 2009: 443-443. DOI: 10.1055/S-0028-1088101 |
0.678 |
|
2008 |
Groll M, Balskus EP, Jacobsen EN. Structural analysis of spiro beta-lactone proteasome inhibitors. Journal of the American Chemical Society. 130: 14981-3. PMID 18928262 DOI: 10.1021/Ja806059T |
0.726 |
|
2008 |
Watson MP, Jacobsen EN. Asymmetric intramolecular arylcyanation of unactivated olefins via C-CN bond activation. Journal of the American Chemical Society. 130: 12594-5. PMID 18761453 DOI: 10.1021/Ja805094J |
0.724 |
|
2008 |
Uyeda C, Jacobsen EN. Enantioselective Claisen rearrangements with a hydrogen-bond donor catalyst. Journal of the American Chemical Society. 130: 9228-9. PMID 18576616 DOI: 10.1021/Ja803370X |
0.773 |
|
2008 |
Reisman SE, Doyle AG, Jacobsen EN. Enantioselective thiourea-catalyzed additions to oxocarbenium ions. Journal of the American Chemical Society. 130: 7198-9. PMID 18479086 DOI: 10.1021/Ja801514M |
0.794 |
|
2008 |
Fang YQ, Jacobsen EN. Cooperative, highly enantioselective phosphinothiourea catalysis of imine-allene [3 + 2] cycloadditions. Journal of the American Chemical Society. 130: 5660-1. PMID 18393504 DOI: 10.1021/Ja801344W |
0.548 |
|
2008 |
Raheem IT, Thiara PS, Jacobsen EN. Regio- and enantioselective catalytic cyclization of pyrroles onto N-acyliminium ions. Organic Letters. 10: 1577-80. PMID 18341346 DOI: 10.1021/Ol800256J |
0.816 |
|
2008 |
Mergott DJ, Zuend SJ, Jacobsen EN. Catalytic asymmetric total synthesis of (+)-yohimbine. Organic Letters. 10: 745-8. PMID 18257582 DOI: 10.1021/Ol702781Q |
0.848 |
|
2008 |
Mazet C, Jacobsen EN. Dinuclear {(salen)Al} complexes display expanded scope in the conjugate cyanation of alpha,beta-unsaturated imides. Angewandte Chemie (International Ed. in English). 47: 1762-5. PMID 18219639 DOI: 10.1002/Anie.200704461 |
0.696 |
|
2008 |
Grachan ML, Tudge MT, Jacobsen EN. Enantioselective catalytic carbonyl-ene cyclization reactions. Angewandte Chemie (International Ed. in English). 47: 1469-72. PMID 18188857 DOI: 10.1002/Anie.200704439 |
0.851 |
|
2008 |
Mergott DJ, Zuend SJ, Jacobsen EN. Synthesis of (+)-Yohimbine Synfacts. 2008: 793-793. DOI: 10.1055/S-2008-1078537 |
0.798 |
|
2008 |
Reisman SE, Doyle AG, Jacobsen EN. Enantioselective Additions to Oxocarbenium Ions via AnionBinding Synfacts. 2008: 1106-1106. DOI: 10.1055/S-2008-1078145 |
0.575 |
|
2008 |
Jacobsen E, Fang Y. A New Phosphinothiourea Catalyst Synfacts. 2008: 0755-0755. DOI: 10.1055/S-2008-1077815 |
0.324 |
|
2008 |
Grachan ML, Tudge MT, Jacobsen EN. Enantioselective Intramolecular Carbonyl-Ene Cyclization Synfacts. 2008: 383-383. DOI: 10.1055/S-2008-1042790 |
0.537 |
|
2008 |
Yoon TP, Jacobsen EN. ChemInform Abstract: Arenecarboxylic Acid Esters Cheminform. 39. DOI: 10.1002/chin.200849252 |
0.565 |
|
2008 |
Vanderwal CD, Jacobsen EN. ChemInform Abstract: Alk-2-enoic Acid Esters Cheminform. 39. DOI: 10.1002/chin.200849251 |
0.568 |
|
2008 |
Vanderwal CD, Jacobsen EN. ChemInform Abstract: Alk-2-enoic Acids Cheminform. 39. DOI: 10.1002/chin.200843262 |
0.547 |
|
2008 |
Belser T, Jacobsen E. Cooperative Catalysis in the Hydrolytic Kinetic Resolution of Epoxides by Chiral [(salen)Co(III)] Complexes Immobilized on Gold Colloids Advanced Synthesis & Catalysis. 350: 967-971. DOI: 10.1002/Adsc.200800028 |
0.498 |
|
2007 |
Doyle AG, Jacobsen EN. Small-molecule H-bond donors in asymmetric catalysis. Chemical Reviews. 107: 5713-43. PMID 18072808 DOI: 10.1021/Cr068373R |
0.532 |
|
2007 |
Zuend SJ, Jacobsen EN. Cooperative catalysis by tertiary amino-thioureas: mechanism and basis for enantioselectivity of ketone cyanosilylation. Journal of the American Chemical Society. 129: 15872-83. PMID 18052247 DOI: 10.1021/Ja0735352 |
0.841 |
|
2007 |
Raheem IT, Thiara PS, Peterson EA, Jacobsen EN. Enantioselective Pictet-Spengler-type cyclizations of hydroxylactams: H-bond donor catalysis by anion binding. Journal of the American Chemical Society. 129: 13404-5. PMID 17941641 DOI: 10.1021/Ja076179W |
0.776 |
|
2007 |
Balskus EP, Jacobsen EN. Asymmetric catalysis of the transannular Diels-Alder reaction. Science (New York, N.Y.). 317: 1736-40. PMID 17885133 DOI: 10.1126/Science.1146939 |
0.828 |
|
2007 |
Doyle AG, Jacobsen EN. Enantioselective alkylation of acyclic alpha,alpha-disubstituted tributyltin enolates catalyzed by a {Cr(salen)} complex. Angewandte Chemie (International Ed. in English). 46: 3701-5. PMID 17407117 DOI: 10.1002/Anie.200604901 |
0.551 |
|
2007 |
Tan KL, Jacobsen EN. Indium-mediated asymmetric allylation of acylhydrazones using a chiral urea catalyst. Angewandte Chemie (International Ed. in English). 46: 1315-7. PMID 17211916 DOI: 10.1002/Anie.200603354 |
0.708 |
|
2007 |
Jacobsen E, Doyle A. Asymmetric α-Alkylation of Acyclic Tin Enolates Synfacts. 2007: 0732-0732. DOI: 10.1055/s-2007-968614 |
0.533 |
|
2007 |
Jacobsen E, Tan K. Asymmetric Allylation of Acylhydrazones Synfacts. 2007: 0435-0435. DOI: 10.1055/S-2007-968345 |
0.691 |
|
2006 |
Lalonde MP, Chen Y, Jacobsen EN. A chiral primary amine thiourea catalyst for the highly enantioselective direct conjugate addition of alpha,alpha-disubstituted aldehydes to nitroalkenes. Angewandte Chemie (International Ed. in English). 45: 6366-70. PMID 16937417 DOI: 10.1002/Anie.200602221 |
0.819 |
|
2006 |
Huang H, Jacobsen EN. Highly enantioselective direct conjugate addition of ketones to nitroalkenes promoted by a chiral primary amine-thiourea catalyst. Journal of the American Chemical Society. 128: 7170-1. PMID 16734464 DOI: 10.1021/Ja0620890 |
0.568 |
|
2006 |
Balskus EP, Jacobsen EN. Alpha,beta-unsaturated beta-silyl imide substrates for catalytic, enantioselective conjugate additions: a total synthesis of (+)-lactacystin and the discovery of a new proteasome inhibitor. Journal of the American Chemical Society. 128: 6810-2. PMID 16719460 DOI: 10.1021/Ja061970A |
0.759 |
|
2006 |
Taylor MS, Jacobsen EN. Asymmetric catalysis by chiral hydrogen-bond donors. Angewandte Chemie (International Ed. in English). 45: 1520-43. PMID 16491487 DOI: 10.1002/Anie.200503132 |
0.537 |
|
2006 |
Jacobsen E, Balskus E. Synthesis of (+)-Lactacystin Synfacts. 2006: 1202-1202. DOI: 10.1055/S-2006-955595 |
0.748 |
|
2006 |
Jacobsen E, Lalonde M, Chen Y. Conjugate Addition of α,α-Disubstituted Aldehydes to Nitroalkenes Synfacts. 2006: 1170-1170. DOI: 10.1055/S-2006-949458 |
0.766 |
|
2006 |
Jacobsen E, Huang H. Chiral Amine-Thiourea Catalyst for the Asymmetric Michael Addition Synfacts. 2006: 0727-0727. DOI: 10.1055/S-2006-941907 |
0.441 |
|
2006 |
Boezio A, Jarvo ER, Lawrence BM, Jacobsen EN. Synthesis of (-)-Colombiasin A and(-)-Elisapterosin B Synfacts. 2006: 196-196. DOI: 10.1055/S-2006-931920 |
0.624 |
|
2006 |
Taylor MS, Jacobsen EN. Asymmetrische Katalyse durch chirale Wasserstoffbrückendonoren Angewandte Chemie. 118: 1550-1573. DOI: 10.1002/Ange.200503132 |
0.443 |
|
2006 |
Nielsen LPC, Jacobsen EN. Catalytic Asymmetric Epoxide Ring-opening Chemistry Aziridines and Epoxides in Organic Synthesis. 229-269. DOI: 10.1002/3527607862.ch7 |
0.339 |
|
2006 |
Stevenson CP, Nielsen LPC, Jacobsen EN. Preparation of (S)-methyl glycidate via hydrolytic kinetic resolution Organic Syntheses. 83: 162-169. DOI: 10.1002/0471264229.Os083.21 |
0.786 |
|
2005 |
Taylor MS, Tokunaga N, Jacobsen EN. Enantioselective thiourea-catalyzed acyl-mannich reactions of isoquinolines. Angewandte Chemie (International Ed. in English). 44: 6700-4. PMID 16175644 DOI: 10.1002/Anie.200502277 |
0.62 |
|
2005 |
Jarvo ER, Lawrence BM, Jacobsen EN. Highly enantio- and regioselective quinone Diels-Alder reactions catalyzed by a tridentate [(Schiff Base)Cr(III)] complex. Angewandte Chemie (International Ed. in English). 44: 6043-6. PMID 16134190 DOI: 10.1002/Anie.200502176 |
0.786 |
|
2005 |
Boezio AA, Jarvo ER, Lawrence BM, Jacobsen EN. Efficient total syntheses of (-)-colombiasin A and (-)-elisapterosin B: application of the Cr-catalyzed asymmetric quinone Diels-Alder reaction. Angewandte Chemie (International Ed. in English). 44: 6046-50. PMID 16108082 DOI: 10.1002/Anie.200502178 |
0.816 |
|
2005 |
Fuerst DE, Jacobsen EN. Thiourea-catalyzed enantioselective cyanosilylation of ketones. Journal of the American Chemical Society. 127: 8964-5. PMID 15969569 DOI: 10.1021/Ja052511X |
0.547 |
|
2005 |
Gandelman M, Jacobsen EN. Highly enantioselective catalytic conjugate addition of N-heterocycles to alpha,beta-unsaturated ketones and imides. Angewandte Chemie (International Ed. in English). 44: 2393-7. PMID 15761885 DOI: 10.1002/Anie.200463058 |
0.624 |
|
2005 |
Taylor MS, Zalatan DN, Lerchner AM, Jacobsen EN. Highly enantioselective conjugate additions to alpha,beta-unsaturated ketones catalyzed by a (salen)Al complex. Journal of the American Chemical Society. 127: 1313-7. PMID 15669872 DOI: 10.1021/Ja044999S |
0.553 |
|
2005 |
Doyle AG, Jacobsen EN. Enantioselective alkylations of tributyltin enolates catalyzed by Cr(salen)Cl: access to enantiomerically enriched all-carbon quaternary centers. Journal of the American Chemical Society. 127: 62-3. PMID 15631449 DOI: 10.1021/Ja043601P |
0.662 |
|
2005 |
Yoon TP, Jacobsen EN. Highly enantioselective thiourea-catalyzed nitro-Mannich reactions. Angewandte Chemie (International Ed. in English). 44: 466-8. PMID 15624148 DOI: 10.1002/Anie.200461814 |
0.729 |
|
2005 |
Jacobsen E, Raheem I. Thiourea Derivative Catalyzed Asymmetric Aza-Baylis-Hillman Reaction Synfacts. 2006: 0075-0075. DOI: 10.1055/s-2005-921710 |
0.802 |
|
2005 |
Jarvo ER, Lawrence BM, Jacobsen EN. Quinone Diels-Alder Reactions Catalyzed by a [(Schiff Base)CrIII] Complex Synfacts. 2005: 305-305. DOI: 10.1055/S-2005-921640 |
0.7 |
|
2005 |
Jacobsen EN, Pfaltz A, Shibasaki M. Catalytic C-C bond formation Advanced Synthesis and Catalysis. 347: 1471. DOI: 10.1002/Adsc.200505313 |
0.502 |
|
2005 |
Raheem IT, Jacobsen EN. Highly enantioselective aza-Baylis-Hillman reactions catalyzed by chiral thiourea derivatives Advanced Synthesis and Catalysis. 347: 1701-1708. DOI: 10.1002/Adsc.200505230 |
0.824 |
|
2005 |
Wenzel AG, Jacobsen EN. Asymmetric Catalysis in Enantioselective Synthesis of β-Amino Acids Enantioselective Synthesis of β-Amino Acids: Second Edition. 107-115. DOI: 10.1002/0471698482.ch4 |
0.768 |
|
2005 |
Chavez DE, Jacobsen EN. An efficient, highly diastereo- and enantioselective hetero-Diels-Alder catalyst. Preparation of (2S,6R)-6-(tert-butyldimethyl-silyloxymethyl)-2- methoxy-2,5-dihydropyran Organic Syntheses. 82: 34-42. DOI: 10.1002/0471264229.Os082.06 |
0.685 |
|
2004 |
Vanderwal CD, Jacobsen EN. Enantioselective formal hydration of alpha,beta-unsaturated imides by Al-catalyzed conjugate addition of oxime nucleophiles. Journal of the American Chemical Society. 126: 14724-5. PMID 15535689 DOI: 10.1021/Ja045563F |
0.701 |
|
2004 |
Taylor MS, Jacobsen EN. Highly enantioselective catalytic acyl-pictet-spengler reactions. Journal of the American Chemical Society. 126: 10558-9. PMID 15327311 DOI: 10.1021/Ja046259P |
0.674 |
|
2004 |
Sammis GM, Danjo H, Jacobsen EN. Cooperative dual catalysis: application to the highly enantioselective conjugate cyanation of unsaturated imides. Journal of the American Chemical Society. 126: 9928-9. PMID 15303860 DOI: 10.1021/Ja046653N |
0.763 |
|
2004 |
Kim SK, Jacobsen EN. General catalytic synthesis of highly enantiomerically enriched terminal aziridines from racemic epoxides. Angewandte Chemie (International Ed. in English). 43: 3952-4. PMID 15274223 DOI: 10.1002/Anie.200460369 |
0.622 |
|
2004 |
Joly GD, Jacobsen EN. Thiourea-catalyzed enantioselective hydrophosphonylation of imines: practical access to enantiomerically enriched alpha-amino phosphonic acids. Journal of the American Chemical Society. 126: 4102-3. PMID 15053588 DOI: 10.1021/Ja0494398 |
0.774 |
|
2004 |
Taylor MS, Jacobsen EN. Asymmetric catalysis in complex target synthesis. Proceedings of the National Academy of Sciences of the United States of America. 101: 5368-73. PMID 15020767 DOI: 10.1073/Pnas.0307893101 |
0.658 |
|
2004 |
Nielsen LP, Stevenson CP, Blackmond DG, Jacobsen EN. Mechanistic investigation leads to a synthetic improvement in the hydrolytic kinetic resolution of terminal epoxides. Journal of the American Chemical Society. 126: 1360-2. PMID 14759192 DOI: 10.1021/Ja038590Z |
0.838 |
|
2004 |
Raheem IT, Goodman SN, Jacobsen EN. Catalytic asymmetric total syntheses of quinine and quinidine. Journal of the American Chemical Society. 126: 706-7. PMID 14733531 DOI: 10.1021/Ja039550Y |
0.808 |
|
2004 |
Keith JM, Jacobsen EN. Asymmetric hydrocyanation of hydrazones catalyzed by lanthanide--PYBOX complexes. Organic Letters. 6: 153-5. PMID 14723516 DOI: 10.1021/Ol035844C |
0.551 |
|
2003 |
Taylor MS, Jacobsen EN. Enantioselective Michael additions to alpha,beta-unsaturated imides catalyzed by a Salen-Al complex. Journal of the American Chemical Society. 125: 11204-5. PMID 16220935 DOI: 10.1021/Ja037177O |
0.589 |
|
2003 |
Ruck RT, Jacobsen EN. Asymmetric hetero-ene reactions of trimethylsilyl enol ethers catalyzed by tridentate Schiff base chromium(III) complexes. Angewandte Chemie (International Ed. in English). 42: 4771-4. PMID 14562344 DOI: 10.1002/Anie.200351591 |
0.753 |
|
2003 |
Chavez DE, Jacobsen EN. Catalyst-controlled inverse-electron-demand hetero-Diels-Alder reactions in the enantio- and diastereoselective synthesis of iridoid natural products. Organic Letters. 5: 2563-5. PMID 12841781 DOI: 10.1021/Ol034883L |
0.751 |
|
2003 |
Sammis GM, Jacobsen EN. Highly enantioselective, catalytic conjugate addition of cyanide to alpha,beta-unsaturated imides. Journal of the American Chemical Society. 125: 4442-3. PMID 12683813 DOI: 10.1021/Ja034635K |
0.72 |
|
2003 |
Yoon TP, Jacobsen EN. Privileged chiral catalysts. Science (New York, N.Y.). 299: 1691-3. PMID 12637734 DOI: 10.1126/Science.1083622 |
0.734 |
|
2003 |
Wenzel AG, Lalonde MP, Jacobsen EN. Divergent Stereoinduction Mechanisms in Urea-Catalyzed Additions to Imines Synlett. 1919-1922. DOI: 10.1055/S-2003-41503 |
0.856 |
|
2003 |
White DE, Jacobsen EN. New oligomeric catalyst for the hydrolytic kinetic resolution of terminal epoxides under solvent-free conditions Tetrahedron Asymmetry. 14: 3633-3638. DOI: 10.1016/J.Tetasy.2003.09.024 |
0.661 |
|
2003 |
Larrow JF, Roberts E, Verhoeven TR, Ryan KM, Senanayake CH, Reider PJ, Jacobsen EN. (1S,2R)‐1‐Aminoindan‐2‐ol Organic Syntheses. 76: 46-46. DOI: 10.1002/0471264180.Os076.06 |
0.477 |
|
2003 |
Larrow JF, Jacobsen EN. (R,R)‐N,N′‐Bis(3,5‐di‐tert‐Butylsalicylidene)‐1,2‐Cyclohexanediamino Manganese(III) Chloride, A Highly Enantioselective Epoxidation Catalyst Organic Syntheses. 1-1. DOI: 10.1002/0471264180.Os075.01 |
0.331 |
|
2002 |
Ready JM, Jacobsen EN. A practical oligomeric [(salen)Co] catalyst for asymmetric epoxide ring-opening reactions. Angewandte Chemie (International Ed. in English). 41: 1374-7. PMID 19750769 DOI: 10.1002/1521-3773(20020415)41:8<1374::Aid-Anie1374>3.0.Co;2-8 |
0.701 |
|
2002 |
Goodman SN, Jacobsen EN. Enantiopure beta-hydroxy morpholine amides from terminal epoxides by carbonylation at 1 atm. Angewandte Chemie (International Ed. in English). 41: 4703-5. PMID 12481332 DOI: 10.1002/Anie.200290022 |
0.486 |
|
2002 |
Movassaghi M, Jacobsen EN. Chemistry. The simplest "enzyme". Science (New York, N.Y.). 298: 1904-5. PMID 12471240 DOI: 10.1126/Science.1076547 |
0.526 |
|
2002 |
Wenzel AG, Jacobsen EN. Asymmetric catalytic Mannich reactions catalyzed by urea derivatives: enantioselective synthesis of beta-aryl-beta-amino acids. Journal of the American Chemical Society. 124: 12964-5. PMID 12405820 DOI: 10.1021/Ja028353G |
0.827 |
|
2002 |
Gademann K, Chavez DE, Jacobsen EN. Highly enantioselective inverse-electron-demand hetero-diels-alder reactions of alpha,beta-unsaturated aldehydes. Angewandte Chemie (International Ed. in English). 41: 3059-61. PMID 12203458 DOI: 10.1002/1521-3773(20020816)41:16<3059::Aid-Anie3059>3.0.Co;2-I |
0.781 |
|
2002 |
Vachal P, Jacobsen EN. Structure-based analysis and optimization of a highly enantioselective catalyst for the strecker reaction. Journal of the American Chemical Society. 124: 10012-4. PMID 12188665 DOI: 10.1021/Ja027246J |
0.797 |
|
2002 |
Joly GD, Jacobsen EN. Catalyst-controlled diastereoselective hetero-Diels-Alder reactions. Organic Letters. 4: 1795-8. PMID 12000301 DOI: 10.1021/Ol0258785 |
0.837 |
|
2002 |
Ruck RT, Jacobsen EN. Asymmetric catalysis of hetero-ene reactions with tridentate Schiff base chromium(III) complexes. Journal of the American Chemical Society. 124: 2882-3. PMID 11902873 DOI: 10.1021/Ja025588J |
0.738 |
|
2002 |
Movassaghi M, Jacobsen EN. A direct method for the conversion of terminal epoxides into gamma-butanolides. Journal of the American Chemical Society. 124: 2456-7. PMID 11890792 DOI: 10.1021/Ja025604C |
0.679 |
|
2002 |
Schaus SE, Brandes BD, Larrow JF, Tokunaga M, Hansen KB, Gould AE, Furrow ME, Jacobsen EN. Highly selective hydrolytic kinetic resolution of terminal epoxides catalyzed by chiral (salen)Co(III) complexes. Practical synthesis of enantioenriched terminal epoxides and 1,2-diols. Journal of the American Chemical Society. 124: 1307-15. PMID 11841300 DOI: 10.1021/Ja016737L |
0.79 |
|
2002 |
Movassaghi M, Jacobsen EN. A direct method for the conversion of terminal epoxides into γ-butanolides Journal of the American Chemical Society. 124: 2456-2457. DOI: 10.1021/ja025604c |
0.527 |
|
2002 |
Goodman SN, Jacobsen EN. A Practical Synthesis of α,β-Unsaturated Imides, Useful Substrates for Asymmetric Conjugate Addition Reactions Advanced Synthesis and Catalysis. 344: 953-956. DOI: 10.1002/1615-4169(200210)344:9<953::Aid-Adsc953>3.0.Co;2-A |
0.47 |
|
2002 |
Jacobsen E. Advanced Synthesis & Catalysis Enters Its Second Year Advanced Synthesis & Catalysis. 344: 1. DOI: 10.1002/1615-4169(200201)344:1<1::Aid-Adsc1>3.0.Co;2-A |
0.352 |
|
2002 |
Gademann K, Chavez DE, Jacobsen EN. Highly Enantioselective Inverse-Electron-Demand Hetero-DielsâAlder Reactions of α,β-Unsaturated Aldehydes This work was supported by the NIH (GM-59316), with additional support from the Schweizerischer Nationalfonds zur Förderung der wissenschaftlichen Forschung (postdoctoral fellowship to K.G.), and the National Science Foundation (predoctoral fellowship to D.E.C.). We are grateful to Dr. R. Staples for carrying out the X-ray crystal structure analysis of 1. Angewandte Chemie. 114: 3059. DOI: 10.1002/1521-3757(20020816)114:16<3185::Aid-Ange3185>3.0.Co;2-S |
0.573 |
|
2002 |
Ready JM, Jacobsen EN. A Practical Oligomeric [(salen)Co] Catalyst for Asymmetric Epoxide Ring-Opening Reactions This work was supported by the NIH (GM 43214). H2salen=bis(salicylidene)ethylenediamine. Angewandte Chemie. 114: 1432. DOI: 10.1002/1521-3757(20020415)114:8<1432::Aid-Ange1432>3.0.Co;2-6 |
0.517 |
|
2001 |
Thompson CF, Jamison TF, Jacobsen EN. FR901464: total synthesis, proof of structure, and evaluation of synthetic analogues. Journal of the American Chemical Society. 123: 9974-83. PMID 11592876 DOI: 10.1021/Ja016615T |
0.663 |
|
2001 |
Chavez DE, Jacobsen EN. Total Synthesis of Fostriecin (CI-920) We thank Professor Andrew G. Myers and Scott E. Schaus for helpful discussions, and Dr. Alexandra E. Gould and Isabel K. Reichardt for important preliminary experimental work. We also thank Dr. Robert J. Schultz of the Drug Synthesis and Chemistry Branch, Developmental Therapeutics Program, Division of Cancer Treatment and Diagnosis, National Cancer institute, for a sample of natural fostriecin. This work was supported by the NIH (GM-59316), and by Beinecke Memorial and NSF predoctoral fellowships to D.E.C. Angewandte Chemie (International Ed. in English). 40: 3667-3670. PMID 11592216 DOI: 10.1002/1521-3773(20011001)40:19<3667::Aid-Anie3667>3.0.Co;2-6 |
0.672 |
|
2001 |
White MC, Doyle AG, Jacobsen EN. A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2. Journal of the American Chemical Society. 123: 7194-5. PMID 11459514 DOI: 10.1021/Ja015884G |
0.725 |
|
2001 |
Ready JM, Jacobsen EN. Highly active oligomeric (salen)co catalysts for asymmetric epoxide ring-opening reactions. Journal of the American Chemical Society. 123: 2687-8. PMID 11456948 DOI: 10.1021/Ja005867B |
0.711 |
|
2001 |
Brandes BD, Jacobsen EN. Regioselective ring opening of enantiomerically enriched epoxides via catalysis with chiral (salen)Cr(III) complexes Synlett. 1013-1015. DOI: 10.1055/S-2001-14649 |
0.387 |
|
2001 |
Buchwald S, Burk M, Jacobsen E, Kobayashi S, Pfaltz A, Wong C. Nobel Prizes in Chemistry 2001; Congratulations from the Editors Advanced Synthesis & Catalysis. 343: 753-753. DOI: 10.1002/1615-4169(20011231)343:8<753::Aid-Adsc753>3.0.Co;2-9 |
0.507 |
|
2001 |
Su JT, Vachal P, Jacobsen EN. Practical Synthesis of a Soluble Schiff Base Catalyst for the Asymmetric Strecker Reaction Advanced Synthesis and Catalysis. 343: 197-200. DOI: 10.1002/1615-4169(20010226)343:2<197::Aid-Adsc197>3.0.Co;2-8 |
0.807 |
|
2001 |
Keith JM, Larrow JF, Jacobsen EN. Practical Considerations in Kinetic Resolution Reactions Advanced Synthesis and Catalysis. 343: 5-26. DOI: 10.1002/1615-4169(20010129)343:1<5::Aid-Adsc5>3.0.Co;2-I |
0.499 |
|
2000 |
Breinbauer R, Jacobsen EN. Cooperative Asymmetric Catalysis with Dendrimeric Angewandte Chemie (International Ed. in English). 39: 3604-3607. PMID 11091412 DOI: 10.1002/1521-3773(20001016)39:20<3604::Aid-Anie3604>3.0.Co;2-9 |
0.67 |
|
2000 |
Jacobsen EN. Asymmetric catalysis of epoxide ring-opening reactions. Accounts of Chemical Research. 33: 421-31. PMID 10891060 DOI: 10.1021/Ar960061V |
0.56 |
|
2000 |
Denmark SE, Jacobsen EN. Catalytic asymmetric synthesis. Accounts of Chemical Research. 33: 324. PMID 10891049 DOI: 10.1021/Ar000046X |
0.537 |
|
2000 |
Schaus SE, Jacobsen EN. Asymmetric ring opening of meso epoxides with TMSCN catalyzed by (pybox)lanthanide complexes. Organic Letters. 2: 1001-4. PMID 10768207 DOI: 10.1021/Ol005721H |
0.73 |
|
2000 |
Sigman MS, Vachal P, Jacobsen EN. A General Catalyst for the Asymmetric Strecker Reaction This work was supported by the NIH (GM-43214). A postdoctoral fellowship to M.S.S. (NIH), and a predoctoral fellowship to P.V. sponsored by Alfred Bader are gratefully acknowledged. Angewandte Chemie (International Ed. in English). 39: 1279-1281. PMID 10767031 DOI: 10.1002/(Sici)1521-3773(20000403)39:7<1279::Aid-Anie1279>3.0.Co;2-U |
0.792 |
|
2000 |
Vachal P, Jacobsen EN. Enantioselective catalytic addition of HCN to ketoimines. Catalytic synthesis of quaternary amino acids. Organic Letters. 2: 867-70. PMID 10754690 DOI: 10.1021/Ol005636+ |
0.774 |
|
2000 |
Jacobsen EN, Breinbauer R. Nickel comes full cycle Science. 287: 437-438. DOI: 10.1126/Science.287.5452.437 |
0.608 |
|
2000 |
Thompson CF, Jamison TF, Jacobsen EN. Total synthesis of FR901464. Convergent assembly of chiral components prepared by asymmetric catalysis [17] Journal of the American Chemical Society. 122: 10482-10483. DOI: 10.1021/Ja0055357 |
0.636 |
|
2000 |
Foote CS, Jacobsen EN. Catalytic asymmetric synthesis special issue: Editorial Accounts of Chemical Research. 33: 323. DOI: 10.1021/ar0000455 |
0.397 |
|
2000 |
Breinbauer R, Jacobsen EN. Cooperative asymmetric catalysis with dendrimer bound [Co(salen)] catalysts Angewandte Chemie. 39: 3604-3607. DOI: 10.1002/1521-3773(20001016)39:20<3604::Aid-Anie3604>3.0.Co;2 |
0.672 |
|
1999 |
Wu MH, Hansen KB, Jacobsen EN. Regio- and Enantioselective Cyclization of Epoxy Alcohols Catalyzed by a [Co(salen)] Complex. Angewandte Chemie (International Ed. in English). 38: 2012-2014. PMID 34182660 DOI: 10.1002/(SICI)1521-3773(19990712)38:13/14<2012::AID-ANIE2012>3.0.CO;2-H |
0.547 |
|
1999 |
Francis MB, Jacobsen EN. Discovery of Novel Catalysts for Alkene Epoxidation from Metal-Binding Combinatorial Libraries. Angewandte Chemie (International Ed. in English). 38: 937-941. PMID 29711875 DOI: 10.1002/(Sici)1521-3773(19990401)38:7<937::Aid-Anie937>3.0.Co;2-O |
0.646 |
|
1999 |
Li Z, Fernández M, Jacobsen EN. Enantioselective ring opening of meso aziridines catalyzed by Tridentate Schiff base chromium(III) complexes. Organic Letters. 1: 1611-3. PMID 10836024 DOI: 10.1021/Ol990992H |
0.483 |
|
1999 |
Peukert S, Jacobsen EN. Enantioselective parallel synthesis using polymer-supported chiral Co(salen) complexes. Organic Letters. 1: 1245-8. PMID 10825975 DOI: 10.1021/Ol990920Q |
0.463 |
|
1999 |
Dossetter AG, Jamison TF, Jacobsen EN. Highly Enantio- and Diastereoselective Hetero-Diels-Alder Reactions Catalyzed by New Chiral Tridentate Chromium(III) Catalysts. Angewandte Chemie (International Ed. in English). 38: 2398-2400. PMID 10458800 DOI: 10.1002/(Sici)1521-3773(19990816)38:16<2398::Aid-Anie2398>3.0.Co;2-E |
0.726 |
|
1999 |
Hinterding K, Jacobsen EN. Regioselective carbomethoxylation of chiral epoxides: A new route to enantiomerically pure β-hydroxy esters Journal of Organic Chemistry. 64: 2164-2165. DOI: 10.1021/Jo982336L |
0.395 |
|
1999 |
Myers JK, Jacobsen EN. Asymmetric synthesis of β-amino acid derivatives via catalytic conjugate addition of hydrazoic acid to unsaturated imides [10] Journal of the American Chemical Society. 121: 8959-8960. DOI: 10.1021/Ja991621Z |
0.386 |
|
1999 |
Ready JM, Jacobsen EN. Asymmetric catalytic synthesis of α-aryloxy alcohols: Kinetic resolution of terminal epoxides via highly enantioselective ring-opening with phenols Journal of the American Chemical Society. 121: 6086-6087. DOI: 10.1021/Ja9910917 |
0.67 |
|
1999 |
Annis DA, Jacobsen EN. Polymer-supported chiral Co(salen) complexes: Synthetic applications and mechanistic investigations in the hydrolytic kinetic resolution of terminal epoxides Journal of the American Chemical Society. 121: 4147-4154. DOI: 10.1021/Ja984410N |
0.84 |
|
1999 |
Lebel H, Jacobsen EN. Chromium catalyzed kinetic resolution of 2,2-disubstituted epoxides Tetrahedron Letters. 40: 7303-7306. DOI: 10.1016/S0040-4039(99)01502-6 |
0.511 |
|
1999 |
Wu MH, Hansen KB, Jacobsen EN. Regio- and enantioselective cyclization of epoxy alcohols catalyzed by a [Co(III)(salen)] complex Angewandte Chemie - International Edition. 38: 2012-2014. DOI: 10.1002/(Sici)1521-3773(19990712)38:13/14<2012::Aid-Anie2012>3.0.Co;2-H |
0.599 |
|
1999 |
Francis MB, Jacobsen EN. Discovery of novel catalysts for alkene epoxidation from metal-binding combinatorial libraries Angewandte Chemie - International Edition. 38: 937-941. DOI: 10.1002/(SICI)1521-3773(19990401)38:7<937::AID-ANIE937>3.0.CO;2-O |
0.575 |
|
1999 |
Dossetter A, Jamison T, Jacobsen E. Hochenantio- und -diastereoselektive Hetero-Diels-Alder-Reaktionen, katalyisert durch neue chirale Chrom(III)-Komplexe Angewandte Chemie. 111: 2549-2552. DOI: 10.1002/(Sici)1521-3757(19990816)111:16<2549::Aid-Ange2549>3.0.Co;2-H |
0.625 |
|
1999 |
Francis MB, Jacobsen EN. Entdeckung neuer Katalysatoren für die Alkenepoxidierung durch metallbindende kombinatorische Bibliotheken Angewandte Chemie. 111: 987-991. DOI: 10.1002/(Sici)1521-3757(19990401)111:7<987::Aid-Ange987>3.0.Co;2-9 |
0.478 |
|
1998 |
Furrow ME, Schaus SE, Jacobsen EN. Practical Access to Highly Enantioenriched C-3 Building Blocks via Hydrolytic Kinetic Resolution. The Journal of Organic Chemistry. 63: 6776-6777. PMID 11672291 DOI: 10.1021/Jo981332D |
0.607 |
|
1998 |
Francis MB, Jamison TF, Jacobsen EN. Combinatorial libraries of transition-metal complexes, catalysts and materials. Current Opinion in Chemical Biology. 2: 422-8. PMID 9691076 DOI: 10.1016/S1367-5931(98)80019-7 |
0.706 |
|
1998 |
Lebel H, Jacobsen EN. Enantioselective total synthesis of taurospongin A Journal of Organic Chemistry. 63: 9624-9625. DOI: 10.1021/Jo9819741 |
0.462 |
|
1998 |
Schaus SE, Brånalt J, Jacobsen EN. Total synthesis of muconin by efficient assembly of chiral building blocks Journal of Organic Chemistry. 63: 4876-4877. DOI: 10.1021/Jo9810765 |
0.653 |
|
1998 |
Wu MH, Jacobsen EN. Asymmetric Ring Opening of Meso Epoxides with Thiols: Enantiomeric Enrichment Using a Bifunctional Nucleophile Journal of Organic Chemistry. 63: 5252-5254. DOI: 10.1021/Jo980155D |
0.398 |
|
1998 |
Schaus SE, Brånalt J, Jacobsen EN. Asymmetric Hetero-Diels−Alder Reactions Catalyzed by Chiral (Salen)Chromium(III) Complexes The Journal of Organic Chemistry. 63: 403-405. DOI: 10.1021/Jo971758C |
0.727 |
|
1998 |
Konsler RG, Karl J, Jacobsen EN. Cooperative asymmetric catalysis with dimeric salen complexes [11] Journal of the American Chemical Society. 120: 10780-10781. DOI: 10.1021/Ja982683C |
0.535 |
|
1998 |
Sigman MS, Jacobsen EN. Enantioselective addition of hydrogen cyanide to imines catalyzed by a chiral (salen)Al(III) complex [1] Journal of the American Chemical Society. 120: 5315-5316. DOI: 10.1021/Ja980299+ |
0.619 |
|
1998 |
Sigman MS, Jacobsen EN. Schiff base catalysts for the asymmetric strecker reaction identified and optimized from parallel synthetic libraries Journal of the American Chemical Society. 120: 4901-4902. DOI: 10.1021/Ja980139Y |
0.658 |
|
1998 |
Palucki M, Finney NS, Pospisil PJ, Güler ML, Ishida T, Jacobsen EN. The mechanistic basis for electronic effects on enantioselectivity in the (salen)Mn(III)-catalyzed epoxidation reaction Journal of the American Chemical Society. 120: 948-954. DOI: 10.1021/Ja973468J |
0.499 |
|
1998 |
Dakin LA, Schaus SE, Jacobsen EN, Panek JS. Carbenoid insertions into the silicon-hydrogen bond catalyzed by chiral copper (I) Schiff base complexes Tetrahedron Letters. 39: 8947-8950. DOI: 10.1016/S0040-4039(98)02013-9 |
0.714 |
|
1998 |
Zamojski A, Jacobsen EN, Kakiuchi F, Konsler RG, Larrow JF, Tokunaga M. Enantioselective catalytic ring opening of epoxides with carboxylic acids Chemtracts. 11: 287-290. DOI: 10.1016/S0040-4039(96)02414-8 |
0.709 |
|
1998 |
Annis DA, Helluin O, Jacobsen EN. Stereochemistry as a diversity element: Solid-phase synthesis of cyclic RGD peptide derivatives by asymmetric catalysis Angewandte Chemie - International Edition. 37: 1907-1909. DOI: 10.1002/(Sici)1521-3773(19980803)37:13/14<1907::Aid-Anie1907>3.0.Co;2-A |
0.774 |
|
1997 |
Tokunaga M, Larrow JF, Kakiuchi F, Jacobsen EN. Asymmetric catalysis with water: efficient kinetic resolution of terminal epoxides by means of catalytic hydrolysis. Science (New York, N.Y.). 277: 936-8. PMID 9252321 DOI: 10.1126/Science.277.5328.936 |
0.711 |
|
1997 |
Schaus SE, Larrow JF, Jacobsen EN. Practical Synthesis of Enantiopure Cyclic 1,2-Amino Alcohols via Catalytic Asymmetric Ring Opening of Meso Epoxides The Journal of Organic Chemistry. 62: 4197-4199. DOI: 10.1021/Jo970146P |
0.671 |
|
1997 |
Brandes BD, Jacobsen EN. Synthesis of enantiopure 3-chlorostyrene oxide via an asymmetric epoxidation-hydrolytic kinetic resolution sequence Tetrahedron Asymmetry. 8: 3927-3933. DOI: 10.1016/S0957-4166(97)00568-5 |
0.494 |
|
1997 |
Wu MH, Jacobsen EN. An efficient formal synthesis of balanol via the asymmetric epoxide ring opening reaction Tetrahedron Letters. 38: 1693-1696. DOI: 10.1016/S0040-4039(97)00192-5 |
0.5 |
|
1997 |
Finney NS, Pospisil PJ, Chang S, Palucki M, Konsler RG, Hansen KB, Jacobsen EN. On the Viability of Oxametallacyclic Intermediates in the(salen)Mn-Catalyzed Asymmetric Epoxidation Angewandte Chemie International Edition in English. 36: 1720-1723. DOI: 10.1002/Anie.199717201 |
0.594 |
|
1997 |
Finney NS, Pospisil PJ, Chang S, Palucki M, Konsler RG, Hansen KB, Jacobsen EN. Zum Auftreten von oxametallacyclischen Intermediaten in der [Mn(salen)]-katalysierten asymmetrischen Epoxidierung Angewandte Chemie. 109: 1798-1801. DOI: 10.1002/Ange.19971091614 |
0.378 |
|
1996 |
Martínez LE, Nugent WA, Jacobsen EN. Highly Efficient and Enantioselective Synthesis of Carbocyclic Nucleoside Analogs Using Selective Early Transition Metal Catalysis. The Journal of Organic Chemistry. 61: 7963-7966. PMID 11667763 DOI: 10.1021/Jo961241L |
0.371 |
|
1996 |
Leighton JL, Jacobsen EN. Efficient synthesis of (R)-4-(trimethylsilyl)oxy)-2-cyclopentenone by enantioselective catalytic epoxide ring opening Journal of Organic Chemistry. 61: 389-390. DOI: 10.1021/Jo951557D |
0.671 |
|
1996 |
Hansen KB, Leighton JL, Jacobsen EN. On the mechanism of asymmetric nucleophilic ring-opening of epoxides catalyzed by (salen)Cr(III) complexes Journal of the American Chemical Society. 118: 10924-10925. DOI: 10.1021/Ja962600X |
0.705 |
|
1996 |
Francis MB, Finney NS, Jacobsen EN. Combinatorial approach to the discovery of novel coordination complexes Journal of the American Chemical Society. 118: 8983-8984. DOI: 10.1021/Ja961842U |
0.52 |
|
1996 |
Quan RW, Li Z, Jacobsen EN. Enantiofacially Selective Binding of Prochiral Olefins to a Chiral Catalyst via Simultaneous Face−Face and Edge−Face Aromatic Interactions Journal of the American Chemical Society. 118: 8156-8157. DOI: 10.1021/Ja9618098 |
0.459 |
|
1996 |
Larrow JF, Schaus SE, Jacobsen EN. Kinetic resolution of terminal epoxides via highly regioselective and enantioselective ring opening with TMSN3. An efficient, catalytic route to 1,2-amino alcohols Journal of the American Chemical Society. 118: 7420-7421. DOI: 10.1021/Ja961708+ |
0.679 |
|
1996 |
Schaus SE, Jacobsen EN. Dynamic kinetic resolution of epichlorohydrin via enantioselective catalytic ring opening with TMSN3. Practical synthesis of aryl oxazolidinone antibacterial agents Tetrahedron Letters. 37: 7937-7940. DOI: 10.1016/0040-4039(96)01835-7 |
0.706 |
|
1996 |
Pospisil PJ, Carsten DH, Jacobsen EN. X-Ray Structural Studies of Highly Enantioselective Mn(salen) Epoxidation Catalysts Chemistry - a European Journal. 2: 974-980. DOI: 10.1002/Chem.19960020812 |
0.466 |
|
1995 |
Velde SLV, Jacobsen EN. Kinetic Resolution Of Racemic Chromenes Via Asymmetric Epoxidation : Synthesis Of (+)-Teretifolione B Journal of Organic Chemistry. 60: 5380-5381. DOI: 10.1021/Jo00122A008 |
0.396 |
|
1995 |
Martínez LE, Leighton JL, Carsten DH, Jacobsen EN. Highly enantioselective ring opening of epoxides catalyzed by (salen)Cr(III) complexes Journal of the American Chemical Society. 117: 5897-5898. DOI: 10.1021/Ja00126A048 |
0.637 |
|
1995 |
Li Z, Quan RW, Jacobsen EN. Mechanism of the (Diimine)copper-Catalyzed Asymmetric Aziridination of Alkenes. Nitrene Transfer via Ligand-Accelerated Catalysis Journal of the American Chemical Society. 117: 5889-5890. DOI: 10.1021/Ja00126A044 |
0.365 |
|
1995 |
Palucki M, McCormick GJ, Jacobsen EN. Low temperature asymmetric epoxidation of unfunctionalized olefins catalyzed by (salen)Mn(III) complexes Tetrahedron Letters. 36: 5457-5460. DOI: 10.1016/0040-4039(95)01088-Y |
0.451 |
|
1995 |
Brandes BD, Jacobsen EN. Enantioselective catalytic epoxidation of tetrasubstituted olefins Tetrahedron Letters. 36: 5123-5126. DOI: 10.1016/0040-4039(95)00965-F |
0.555 |
|
1995 |
Hansen KB, Finney NS, Jacobsen EN. Carbenoid Transfer to Imines: A New Asymmetric Catalytic Synthesis of Aziridines Angewandte Chemie International Edition in English. 34: 676-678. DOI: 10.1002/Anie.199506761 |
0.462 |
|
1995 |
Hansen KB, Finney NS, Jacobsen EN. Carbenoidübertragung auf Imine: eine neue asymmetrische katalytische Synthese von Aziridinen Angewandte Chemie. 107: 750-752. DOI: 10.1002/Ange.19951070626 |
0.377 |
|
1994 |
Jacobsen EN, Finney NS. Synthetic and biological catalysts in chemical synthesis: how to assess practical utility. Chemistry & Biology. 1: 85-90. PMID 9383375 DOI: 10.1016/1074-5521(94)90045-0 |
0.528 |
|
1994 |
Brandes BD, Jacobsen EN. Highly Enantioselective, Catalytic Epoxidation of Trisubstituted Olefins Journal of Organic Chemistry. 59: 4378-4380. DOI: 10.1021/Jo00095A009 |
0.526 |
|
1994 |
Larrow JF, Jacobsen EN, Gao Y, Hong Y, Nie X, Zepp CM. A Practical Method for the Large-Scale Preparation of [N,N'-Bis(3,5-di-tertbutylsalicylidene)-1,2-cyclohexanediaminato(2-)]manganese(III) chloride, a Highly Enantioselective Epoxidation Catalyst The Journal of Organic Chemistry. 59: 1939-1942. DOI: 10.1021/Jo00086A062 |
0.41 |
|
1994 |
Palucki M, Pospisil PJ, Zhang W, Jacobsen EN. Highly Enantioselective, Low-Temperature Epoxidation of Styrene Journal of the American Chemical Society. 116: 9333-9334. DOI: 10.1021/Ja00099A062 |
0.316 |
|
1994 |
Chang S, Galvin JM, Jacobsen EN. Effect of Chiral Quaternary Ammonium Salts on (salen)Mn-Catalyzed Epoxidation of cis-Olefins. A Highly Enantioselective, Catalytic Route to Trans-Epoxides Journal of the American Chemical Society. 116: 6937-6938. DOI: 10.1021/Ja00094A059 |
0.605 |
|
1994 |
Zhang W, Lee NH, Jacobsen EN. Nonstereospecific Mechanisms in Asymmetric Addition to Alkenes Result in Enantiodifferentiation after the First Irreversible Step Journal of the American Chemical Society. 116: 425-426. DOI: 10.1021/Ja00080A070 |
0.422 |
|
1994 |
Chang S, Heid RM, Jacobsen EN. Enantioselective epoxidation of cyclic 1,3-dienes catalyzed by a sterically and electronically optimized (salen)Mn complex Tetrahedron Letters. 35: 669-672. DOI: 10.1016/S0040-4039(00)75786-8 |
0.611 |
|
1994 |
Jacobsen EN, Deng L, Furukawa Y, Martínez LE. Enantioselective catalytic epoxidation of cinnamate esters Tetrahedron. 50: 4323-4334. DOI: 10.1016/S0040-4020(01)89369-8 |
0.637 |
|
1993 |
Chang S, Lee NH, Jacobsen EN. Regio- and enantioselective catalytic epoxidation of conjugated polyenes. Formal synthesis of LTA4 methyl ester Journal of Organic Chemistry. 58: 6939-6941. DOI: 10.1021/Jo00077A001 |
0.631 |
|
1993 |
Li Z, Conser KR, Jacobsen EN. Asymmetric alkene aziridination with readily available chiral diimine-based catalysts Journal of the American Chemical Society. 115: 5326-5327. DOI: 10.1021/Ja00065A067 |
0.524 |
|
1993 |
Allain EJ, Hager LP, Deng L, Jacobsen EN. Highly enantioselective epoxidation of disubstituted alkenes with hydrogen peroxide catalyzed by chloroperoxidase Journal of the American Chemical Society. 115: 4415-4416. DOI: 10.1021/Ja00063A091 |
0.568 |
|
1993 |
Fields LB, Jacobsen EN. Synthesis and characterization of chiral bimetallic complexes bearing hard and soft Lewis acidic sites Tetrahedron: Asymmetry. 4: 2229-2240. DOI: 10.1016/S0957-4166(00)80073-7 |
0.39 |
|
1992 |
Deng L, Jacobsen EN. A practical, highly enantioselective synthesis of the taxol side chain via asymmetric catalysis. Journal of Organic Chemistry. 57: 4320-4323. DOI: 10.1021/Jo00041A054 |
0.538 |
|
1992 |
Pospisil PJ, Wilson SR, Jacobsen EN. A substoichiometric pyridine-lithium enolate complex: solution and x-ray data and implications for catalysis in the aldol reaction Journal of the American Chemical Society. 114: 7585-7587. DOI: 10.1021/Ja00045A054 |
0.342 |
|
1992 |
Palucki M, Hanson P, Jacobsen EN. Asymmetric oxidation of sulfides with H2O2 catalyzed by (salen)Mn(III) complexes Tetrahedron Letters. 33: 7111-7114. DOI: 10.1016/S0040-4039(00)60849-3 |
0.441 |
|
1991 |
Zhang W, Jacobsen EN. Asymmetric olefin epoxidation with sodium hypochlorite catalyzed by easily prepared chiral manganese(III) salen complexes The Journal of Organic Chemistry. 56: 2296-2298. DOI: 10.1021/Jo00007A012 |
0.446 |
|
1991 |
Jacobsen EN, Zhang W, Muci AR, Ecker JR, Deng L. Highly enantioselective epoxidation catalysts derived from 1,2-diaminocyclohexane Journal of the American Chemical Society. 113: 7063-7064. DOI: 10.1021/Ja00018A068 |
0.609 |
|
1991 |
Jacobsen EN, Zhang W, Guler ML. Electronic tuning of asymmetric catalysts Journal of the American Chemical Society. 113: 6703-6704. DOI: 10.1021/Ja00017A069 |
0.418 |
|
1991 |
Lee NH, Muci AR, Jacobsen EN. Enantiomerically Pure Epoxychromans via Asymmetric Catalysis Tetrahedron Letters. 32: 5055-5058. DOI: 10.1016/S0040-4039(00)93426-9 |
0.443 |
|
1991 |
Zhang W, Jacobsen EN. Preparation of trans-1,2-diamino-1,2-dimethylcyclohexane via highly stereoselective olefin oxidation by dinitrogen tetroxide Tetrahedron Letters. 32: 1711-1714. DOI: 10.1016/S0040-4039(00)74310-3 |
0.465 |
|
1991 |
Lee NH, Jacobsen EN. Enantioselective epoxidation of conjugated dienes and enynes. Trans-epoxides from cis-olefins Tetrahedron Letters. 32: 6533-6536. DOI: 10.1016/0040-4039(91)80212-O |
0.459 |
|
1990 |
Zhang W, Loebach JL, Wilson SR, Jacobsen EN. Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes Journal of the American Chemical Society. 112: 2801-2803. DOI: 10.1021/Ja00163A052 |
0.467 |
|
1989 |
Svendsen JS, Marko I, Jacobsen EN, Rao CP, Bott S, Sharpless KB. The structure of osmium tetraoxide-cinchona alkaloid complexes The Journal of Organic Chemistry. 54: 2263-2264. DOI: 10.1021/Jo00271A002 |
0.601 |
|
1989 |
Wai JSM, Marko I, Svendsen JS, Finn MG, Jacobsen EN, Sharpless KB. A mechanistic insight leads to a greatly improved osmium-catalyzed asymmetric dihydroxylation process Journal of the American Chemical Society. 111: 1123-1125. DOI: 10.1021/Ja00185A050 |
0.714 |
|
1989 |
Jacobsen EN, Marko I, France MB, Svendsen JS, Sharpless KB. Kinetic role of the alkaloid ligands in asymmetric catalytic dihydroxylation Journal of the American Chemical Society. 111: 737-739. DOI: 10.1021/Ja00184A055 |
0.68 |
|
1988 |
Jacobsen EN, Goldberg KI, Bergman RG. Rapid, reversible intramolecular carbon-hydrogen oxidative addition and hydrogen exchange in a heterodinuclear "early-late" transition metal complex Journal of the American Chemical Society. 110: 3706-3707. DOI: 10.1021/Ja00219A081 |
0.63 |
|
1988 |
Jacobsen EN, Marko I, Mungall WS, Schroeder G, Sharpless KB. Asymmetric dihydroxylation via ligand-accelerated catalysis Journal of the American Chemical Society. 110: 1968-1970. DOI: 10.1021/Ja00214A053 |
0.634 |
|
1986 |
Jacobsen EN, Trost MK, Bergman RG. Synthesis of organometallic heterodinuclear .mu.-oxo complexes by extrusion of alkenes from zirconium/tungsten oxaalkyl complexes Journal of the American Chemical Society. 108: 8092-8094. DOI: 10.1021/Ja00285A038 |
0.479 |
|
1985 |
Jacobsen EN, Bergman RG. Synthesis and chemistry of a bridging vinylidenedicobalt complex. Evidence for a nonchain radical mechanism in its reaction with metal hydrides to give heteronuclear clusters Journal of the American Chemical Society. 107: 2023-2032. DOI: 10.1021/Ja00293A037 |
0.471 |
|
1985 |
Jacobsen EN, Totten GE, Wenke G, Karydas AC, Rhodes YE. Steric effects on the titanium tetrachloride promoted dimerization of silyl ketene acetals Synthetic Communications. 15: 301-306. DOI: 10.1002/Chin.198543102 |
0.753 |
|
1985 |
JACOBSEN EN, BERGMAN RG. ChemInform Abstract: SYNTHESIS AND CHEMISTRY OF A BRIDGING VINYLIDENEDICOBALT COMPLEX. EVIDENCE FOR A NONCHAIN RADICAL MECHANISM IN ITS REACTION WITH METAL HYDRIDES TO GIV HETERONUCLEAR CLUSTERS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198533307 |
0.434 |
|
1984 |
Jacobsen EN, Bergman RG. Synthesis, crystal and molecular structure, and reactions of the bridging vinylidenedicobalt complex (.mu.-CCH2)(CpCoCO)2. Reaction with molybdenum hydrides to give a heteronuclear cluster complex Organometallics. 3: 329-331. DOI: 10.1021/Om00080A031 |
0.441 |
|
1983 |
Wenke WG, Jacobsen EN, Totten GE, Karydas AC, Rhodes YE. Silyl ketene acetal chemistry: Steric limitations in lewis acid-promoted addition of ketones Synthetic Communications. 13: 449-458. DOI: 10.1080/00397918308081822 |
0.822 |
|
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