| Year |
Citation |
Score |
| 2024 |
Conk RJ, Stahler JF, Shi JX, Yang J, Lefton NG, Brunn JN, Bell AT, Hartwig JF. Polyolefin waste to light olefins with ethylene and base-metal heterogeneous catalysts. Science (New York, N.Y.). eadq7316. PMID 39208080 DOI: 10.1126/science.adq7316 |
0.797 |
|
| 2024 |
Choi K, Brunn JN, Borate K, Kaduskar R, Lizandara Pueyo C, Shinde H, Goetz R, Hartwig JF. Palladium-Catalyzed Amination of Aryl Halides with Aqueous Ammonia and Hydroxide Base Enabled by Ligand Development. Journal of the American Chemical Society. 146: 19414-19424. PMID 38968576 DOI: 10.1021/jacs.4c05768 |
0.85 |
|
| 2024 |
Chen R, Kayrouz CS, McAmis E, Clark DS, Hartwig JF. Carbonic Anhydrase Variants Catalyze the Reduction of Dialkyl Ketones with High Enantioselectivity. Angewandte Chemie (International Ed. in English). e202407111. PMID 38955771 DOI: 10.1002/anie.202407111 |
0.358 |
|
| 2024 |
Nicolai J, Fantoni T, Butcher TW, Arlow S, Ryabukhin SV, Volochnyuk DM, Hartwig JF. Copper-Mediated Cyanodifluoromethylation of (Hetero)aryl Iodides and Activated (Hetero)aryl Bromides with TMSCFCN. Journal of the American Chemical Society. 146: 15464-15472. PMID 38780539 DOI: 10.1021/jacs.4c03618 |
0.318 |
|
| 2024 |
Cheng C, Shi JX, Kang EH, Nelson TF, Sander M, McNeill K, Hartwig JF. Polymers from Plant Oils Linked by Siloxane Bonds for Programmed Depolymerization. Journal of the American Chemical Society. PMID 38651821 DOI: 10.1021/jacs.4c01982 |
0.479 |
|
| 2024 |
Venetos MC, Elkin M, Delaney C, Hartwig JF, Persson KA. Deconvolution and Analysis of the H NMR Spectra of Crude Reaction Mixtures. Journal of Chemical Information and Modeling. PMID 38573053 DOI: 10.1021/acs.jcim.3c01864 |
0.609 |
|
| 2024 |
Yu IF, D'Angelo KA, Hernandez-Mejías ÁD, Cheng N, Hartwig JF. 2-Aminophenanthroline Ligands Enable Mild, Undirected, Iridium-Catalyzed Borylation of Alkyl C-H Bonds. Journal of the American Chemical Society. PMID 38456743 DOI: 10.1021/jacs.3c12981 |
0.861 |
|
| 2024 |
Sterling AJ, Ciccia NR, Guo Y, Hartwig JF, Head-Gordon M. Mechanistic Insights into the Origins of Selectivity in a Cu-Catalyzed C-H Amidation Reaction. Journal of the American Chemical Society. PMID 38381006 DOI: 10.1021/jacs.3c13822 |
0.362 |
|
| 2024 |
Pierson CN, Hartwig JF. Mapping the mechanisms of oxidative addition in cross-coupling reactions catalysed by phosphine-ligated Ni(0). Nature Chemistry. PMID 38355826 DOI: 10.1038/s41557-024-01451-x |
0.319 |
|
| 2024 |
Bloomer BJ, Joyner IA, Garcia-Borràs M, Hu DB, Garçon M, Quest A, Ugarte Montero C, Yu IF, Clark DS, Hartwig JF. Enantio- and Diastereodivergent Cyclopropanation of Allenes by Directed Evolution of an Iridium-Containing Cytochrome. Journal of the American Chemical Society. PMID 38190322 DOI: 10.1021/jacs.3c13011 |
0.805 |
|
| 2023 |
Yu IF, Wilson JW, Hartwig JF. Transition-Metal-Catalyzed Silylation and Borylation of C-H Bonds for the Synthesis and Functionalization of Complex Molecules. Chemical Reviews. 123: 11619-11663. PMID 37751601 DOI: 10.1021/acs.chemrev.3c00207 |
0.826 |
|
| 2023 |
Shi JX, Ciccia NR, Pal S, Kim DD, Brunn JN, Lizandara-Pueyo C, Ernst M, Haydl AM, Messersmith PB, Helms BA, Hartwig JF. Chemical Modification of Oxidized Polyethylene Enables Access to Functional Polyethylenes with Greater Reuse. Journal of the American Chemical Society. PMID 37733607 DOI: 10.1021/jacs.3c07186 |
0.782 |
|
| 2023 |
Delaney CP, Lin E, Huang Q, Yu IF, Rao G, Tao L, Jed A, Fantasia SM, Püntener KA, Britt RD, Hartwig JF. Cross-coupling by a noncanonical mechanism involving the addition of aryl halide to Cu(II). Science (New York, N.Y.). 381: 1079-1085. PMID 37676958 DOI: 10.1126/science.adi9226 |
0.814 |
|
| 2023 |
Luo Y, Li Y, Wu J, Xue XS, Hartwig JF, Shen Q. Oxidative addition of an alkyl halide to form a stable Cu(III) product. Science (New York, N.Y.). 381: 1072-1079. PMID 37676952 DOI: 10.1126/science.adg9232 |
0.601 |
|
| 2023 |
Wilson JW, Su B, Yoritate M, Shi JX, Hartwig JF. Iridium-Catalyzed, Site-Selective Silylation of Secondary C(sp)-H Bonds in Secondary Alcohols and Ketones. Journal of the American Chemical Society. PMID 37638874 DOI: 10.1021/jacs.3c03127 |
0.557 |
|
| 2023 |
Caldeweyher E, Elkin M, Gheibi G, Johansson M, Sköld C, Norrby PO, Hartwig JF. Hybrid Machine Learning Approach to Predict the Site Selectivity of Iridium-Catalyzed Arene Borylation. Journal of the American Chemical Society. 145: 17367-17376. PMID 37523755 DOI: 10.1021/jacs.3c04986 |
0.609 |
|
| 2023 |
Ma S, Hartwig JF. Progression of Hydroamination Catalyzed by Late Transition-Metal Complexes from Activated to Unactivated Alkenes. Accounts of Chemical Research. 56: 1565-1577. PMID 37272995 DOI: 10.1021/acs.accounts.3c00141 |
0.423 |
|
| 2023 |
Huang J, Quest A, Cruz-Morales P, Deng K, Pereira JH, Van Cura D, Kakumanu R, Baidoo EEK, Dan Q, Chen Y, Petzold CJ, Northen TR, Adams PD, Clark DS, Balskus EP, ... Hartwig JF, et al. Complete integration of carbene-transfer chemistry into biosynthesis. Nature. PMID 37138074 DOI: 10.1038/s41586-023-06027-2 |
0.311 |
|
| 2023 |
Yu IF, Manske JL, Diéguez-Vázquez A, Misale A, Pashenko AE, Mykhailiuk PK, Ryabukhin SV, Volochnyuk DM, Hartwig JF. Catalytic undirected borylation of tertiary C-H bonds in bicyclo[1.1.1]pentanes and bicyclo[2.1.1]hexanes. Nature Chemistry. PMID 36973434 DOI: 10.1038/s41557-023-01159-4 |
0.829 |
|
| 2023 |
Ma S, Fan H, Day CS, Xi Y, Hartwig JF. Remote Hydroamination of Disubstituted Alkenes by a Combination of Isomerization and Regioselective N-H Addition. Journal of the American Chemical Society. PMID 36780535 DOI: 10.1021/jacs.2c13054 |
0.68 |
|
| 2022 |
Choi K, Mormino MG, Kalkman ED, Park J, Hartwig JF. Palladium-Catalyzed Aryldifluoromethylation of Aryl Halides with Aryldifluoromethyl Trimethylsilanes. Angewandte Chemie (International Ed. in English). PMID 35960816 DOI: 10.1002/anie.202208204 |
0.445 |
|
| 2022 |
Ma S, Xi Y, Fan H, Roediger S, Hartwig JF. Enantioselective hydroamination of unactivated terminal alkenes. Chem. 8: 532-542. PMID 35647390 DOI: 10.1016/j.chempr.2021.12.005 |
0.393 |
|
| 2021 |
Tlahuext-Aca A, Hartwig JF. Site-Selective Silver-Catalyzed C-H Bond Deuteration of Five-Membered Aromatic Heterocycles and Pharmaceuticals. Acs Catalysis. 11: 1119-1127. PMID 35586574 DOI: 10.1021/acscatal.0c04917 |
0.367 |
|
| 2021 |
Tlahuext-Aca A, Lee SY, Sakamoto S, Hartwig JF. Direct Arylation of Simple Arenes with Aryl Bromides by Synergistic Silver and Palladium Catalysis. Acs Catalysis. 11: 1430-1434. PMID 34790433 DOI: 10.1021/acscatal.0c05254 |
0.577 |
|
| 2021 |
Su B, Hartwig JF. Development of Chiral Ligands for the Transition Metal-catalyzed Enantioselective Silylation and Borylation of C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 34729899 DOI: 10.1002/anie.202113343 |
0.598 |
|
| 2021 |
Butcher TW, Amberg WM, Hartwig JF. Transition-Metal-Catalyzed Monofluoroalkylation: Strategies for the Synthesis of Alkyl Fluorides by C-C Bond Formation. Angewandte Chemie (International Ed. in English). PMID 34658121 DOI: 10.1002/anie.202112251 |
0.368 |
|
| 2021 |
Day CS, Fawcett A, Chatterjee R, Hartwig JF. Mechanistic Investigation of the Iron-Catalyzed Azidation of Alkyl C()-H Bonds with Zhdankin's λ-Azidoiodane. Journal of the American Chemical Society. PMID 34559970 DOI: 10.1021/jacs.1c07330 |
0.68 |
|
| 2021 |
Sakamoto S, Butcher TW, Yang JL, Hartwig JF. gem-Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity. Angewandte Chemie (International Ed. in English). PMID 34555220 DOI: 10.1002/anie.202111476 |
0.425 |
|
| 2021 |
Kalkman ED, Hartwig JF. Direct Observation of Diastereomeric α-C-Bound Enolates during Enantioselective α-Arylations: Synthesis, Characterization, and Reactivity of Arylpalladium Fluorooxindole Complexes. Journal of the American Chemical Society. 143: 11741-11750. PMID 34308646 DOI: 10.1021/jacs.1c05346 |
0.401 |
|
| 2021 |
Fuentes MA, Gava R, Saper NI, Romero E, Caballero A, Hartwig JF, Pérez PJ. Copper-Catalyzed Dehydrogenative Amidation of Light Alkanes. Angewandte Chemie (International Ed. in English). PMID 33979475 DOI: 10.1002/anie.202104737 |
0.37 |
|
| 2021 |
Ji P, Park J, Gu Y, Clark DS, Hartwig JF. Abiotic reduction of ketones with silanes catalysed by carbonic anhydrase through an enzymatic zinc hydride. Nature Chemistry. PMID 33603222 DOI: 10.1038/s41557-020-00633-7 |
0.592 |
|
| 2021 |
Hartwig JF, Fawcett A, Keller MJ, Herrera Z. Site Selective Chlorination of C(sp3)-H Bonds Suitable for Late-Stage Functionalization. Angewandte Chemie (International Ed. in English). PMID 33480134 DOI: 10.1002/anie.202016548 |
0.335 |
|
| 2020 |
Richers CP, Roediger S, Laserna V, Hartwig JF. Effects of ligands on the migratory insertion of alkenes into rhodium-oxygen bonds. Chemical Science. 11: 10449-10456. PMID 34123185 DOI: 10.1039/d0sc04402d |
0.342 |
|
| 2020 |
Ray R, Hartwig JF. Oxalohydrazide Ligands for Copper-Catalyzed C-O Coupling Reactions with High Turnover Numbers. Angewandte Chemie (International Ed. in English). PMID 33377249 DOI: 10.1002/anie.202015654 |
0.69 |
|
| 2020 |
Ma S, Hill CK, Olen CL, Hartwig JF. Ruthenium-Catalyzed Hydroamination of Unactivated Terminal Alkenes with Stoichiometric Amounts of Alkene and an Ammonia Surrogate by Sequential Oxidation and Reduction. Journal of the American Chemical Society. PMID 33356181 DOI: 10.1021/jacs.0c11043 |
0.451 |
|
| 2020 |
Larsen MA, Oeschger RJ, Hartwig JF. Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes. Acs Catalysis. 10: 3415-3424. PMID 33178481 DOI: 10.1021/acscatal.0c00152 |
0.38 |
|
| 2020 |
Xi Y, Ma S, Hartwig JF. Catalytic asymmetric addition of an amine N-H bond across internal alkenes. Nature. PMID 33142305 DOI: 10.1038/s41586-020-2919-z |
0.415 |
|
| 2020 |
Qiu Y, Hartwig JF. Mechanism of Ni-Catalyzed Oxidations of Unactivated C(sp)-H Bonds. Journal of the American Chemical Society. PMID 33111517 DOI: 10.1021/jacs.0c09157 |
0.34 |
|
| 2020 |
Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (Weinheim An Der Bergstrasse, Germany). 132: 6130-6137. PMID 33071367 DOI: 10.1002/ange.201916015 |
0.458 |
|
| 2020 |
Xi Y, Su B, Qi X, Pedram S, Liu P, Hartwig JF. Application of Trimethylgermanyl-Substituted Bisphosphine Ligands with Enhanced Dispersion Interactions to Copper-Catalyzed Hydrobo-ration of Disubstituted Alkenes. Journal of the American Chemical Society. PMID 32962336 DOI: 10.1021/jacs.0c08746 |
0.567 |
|
| 2020 |
Wang JY, Choi K, Zuend SJ, Borate K, Shinde H, Goetz R, Hartwig JF. Cross-Coupling between Hydrazine and Aryl Halides with Hydroxide Base at Low Loadings of Palladium by Rate-Determining Deprotonation of Bound Hydrazine. Angewandte Chemie (International Ed. in English). PMID 32929852 DOI: 10.1002/Anie.202011161 |
0.518 |
|
| 2020 |
Butcher TW, Yang JL, Hartwig JF. Copper-Catalyzed Defluorinative Borylation and Silylation of -Difluoroallyl Groups. Organic Letters. PMID 32841569 DOI: 10.1021/Acs.Orglett.0C02321 |
0.422 |
|
| 2020 |
Butcher TW, Yang JL, Amberg WM, Watkins NB, Wilkinson ND, Hartwig JF. Desymmetrization of difluoromethylene groups by C-F bond activation. Nature. PMID 32480398 DOI: 10.1038/S41586-020-2399-1 |
0.42 |
|
| 2020 |
Oeschger R, Su B, Yu I, Ehinger C, Romero E, He S, Hartwig J. Diverse functionalization of strong alkyl C-H bonds by undirected borylation. Science (New York, N.Y.). 368: 736-741. PMID 32409470 DOI: 10.1126/Science.Aba6146 |
0.813 |
|
| 2020 |
Karmel C, Hartwig JF. Mechanism of the Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Journal of the American Chemical Society. 142: 10494-10505. PMID 32375477 DOI: 10.1021/Jacs.0C03301 |
0.514 |
|
| 2020 |
Su B, Bunescu A, Qiu Y, Zuend SJ, Ernst M, Hartwig JF. Palladium-catalyzed oxidation of β-C(sp3)-H bond of primary alkylamines through a rare four-membered palladacycle intermediate. Journal of the American Chemical Society. PMID 32216373 DOI: 10.1021/Jacs.0C01629 |
0.632 |
|
| 2020 |
Saper NI, Ohgi A, Small DW, Semba K, Nakao Y, Hartwig JF. Nickel-catalysed anti-Markovnikov hydroarylation of unactivated alkenes with unactivated arenes facilitated by non-covalent interactions. Nature Chemistry. PMID 32042137 DOI: 10.1038/S41557-019-0409-4 |
0.494 |
|
| 2020 |
Karmel C, Rubel CZ, Kharitonova EV, Hartwig JF. Iridium-Catalyzed Silylation of Five-Membered Heteroarenes: High Sterically Derived Selectivity from a Pyridyl-Imidazoline Ligand. Angewandte Chemie (International Ed. in English). PMID 31968139 DOI: 10.1002/Anie.201916015 |
0.548 |
|
| 2020 |
Richers CP, Roediger S, Laserna V, Hartwig JF. Effects of Ancillary Ligands on the Insertion of Alkenes into Rhodium-Oxygen Bonds§ Chemical Science. DOI: 10.1039/D0Sc04402D |
0.444 |
|
| 2020 |
Hanna S, Wills T, Butcher TW, Hartwig JF. Palladium-Catalyzed Oxidative Dehydrosilylation forContra-Thermodynamic Olefin Isomerization Acs Catalysis. 10: 8736-8741. DOI: 10.1021/Acscatal.0C02697 |
0.437 |
|
| 2020 |
Larsen MA, Oeschger RJ, Hartwig JF. Effect of Ligand Structure on the Electron Density and Activity of Iridium Catalysts for the Borylation of Alkanes Acs Catalysis. 10: 3415-3424. DOI: 10.1021/Acscatal.0C00152 |
0.455 |
|
| 2019 |
Dorel R, Boehm P, Schwinger DP, Hartwig JF. Copper-mediated Fluorination of Aryl Trisiloxanes with Nucleophilic Fluoride. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 31872488 DOI: 10.1002/Chem.201905040 |
0.478 |
|
| 2019 |
Yoritate M, Londregan AT, Lian Y, Hartwig JF. Sequential Xanthalation and -Trifluoromethylation of Phenols: A Procedure for the Synthesis of Aryl Trifluoromethyl Ethers. The Journal of Organic Chemistry. PMID 31738556 DOI: 10.1021/Acs.Joc.9B02717 |
0.469 |
|
| 2019 |
Hartwig JF, Romero EA. Iridium-Catalyzed Silylation of Unactivated C-H Bonds. Tetrahedron. 75: 4059-4070. PMID 31723309 DOI: 10.1016/J.Tet.2019.05.055 |
0.441 |
|
| 2019 |
Kalkman ED, Mormino MG, Hartwig JF. Unusual Electronic Effects of Ancillary Ligands on the Perfluoroalkylation of Aryl Iodides and Bromides Mediated by Copper(I) Pentafluoro-ethyl Complexes of Substituted Bipyridines. Journal of the American Chemical Society. PMID 31722521 DOI: 10.1021/Jacs.9B10540 |
0.456 |
|
| 2019 |
Oeschger RJ, Larsen MA, Bismuto A, Hartwig JF. Origin of the Difference in Reactivity between Ir Catalysts for the Borylation of C-H Bonds. Journal of the American Chemical Society. PMID 31539230 DOI: 10.1021/Jacs.9B08920 |
0.501 |
|
| 2019 |
He ZT, Hartwig JF. Palladium-catalyzed α-arylation for the addition of small rings to aromatic compounds. Nature Communications. 10: 4083. PMID 31501444 DOI: 10.1038/S41467-019-12090-Z |
0.414 |
|
| 2019 |
Hanna S, Butcher TW, Hartwig JF. Contra-thermodynamic Olefin Isomerization by Chain-Walking Hydrofunctionalization and Formal Retro-hydrofunctionalization. Organic Letters. PMID 31424215 DOI: 10.1021/Acs.Orglett.9B02695 |
0.423 |
|
| 2019 |
Gu Y, Natoli SN, Liu Z, Clark DS, Hartwig JF. Site-Selective Functionalization of (sp3)C-H Bonds Catayzed by Artificial Metalloenzymes Containing an Iridium-Porphyrin Cofactor. Angewandte Chemie (International Ed. in English). PMID 31356719 DOI: 10.1002/Anie.201907460 |
0.452 |
|
| 2019 |
He ZT, Jiang X, Hartwig JF. Stereodivergent Construction of Tertiary Fluorides in Vicinal Stereogenic Pairs by Allylic Substitution with Iridium and Copper Catalysts. Journal of the American Chemical Society. PMID 31343170 DOI: 10.1021/Jacs.9B04440 |
0.484 |
|
| 2019 |
He ZT, Hartwig JF. Palladium-Catalyzed α-Arylation of Carboxylic Acids and Secondary Amides via a Traceless Protecting Strategy. Journal of the American Chemical Society. PMID 31287682 DOI: 10.1021/Jacs.9B03291 |
0.432 |
|
| 2019 |
Karmel C, Chen Z, Hartwig JF. Iridium-Catalyzed Silylation of C-H bonds in Unactivated Arenes: A Sterically-Encumbered Phenanthroline Ligand Accelerates Catalysis Enabling New Reactivity. Journal of the American Chemical Society. PMID 30971087 DOI: 10.1021/Jacs.9B01972 |
0.512 |
|
| 2019 |
Haydl AM, Hartwig JF. Palladium-Catalyzed Methylation of Aryl, Heteroaryl, and Vinyl Boronate Esters. Organic Letters. PMID 30763109 DOI: 10.1021/Acs.Orglett.9B00025 |
0.824 |
|
| 2019 |
Natoli SN, Hartwig JF. Noble-Metal Substitution in Hemoproteins: An Emerging Strategy for Abiological Catalysis. Accounts of Chemical Research. PMID 30693758 DOI: 10.1021/Acs.Accounts.8B00586 |
0.466 |
|
| 2019 |
Hanna S, Holder JC, Hartwig JF. Multicatalytic Approach to the Hydroaminomethylation of α-Olefins. Angewandte Chemie (International Ed. in English). PMID 30635956 DOI: 10.1002/Anie.201811297 |
0.464 |
|
| 2019 |
Jiang Q, Peacock DM, Hartwig JF, Cundari TR. Carbon(sp3)-nitrogen bond-forming reductive elimination from phosphine-ligated alkylpalladium(II) amide complexes: A DFT study Tetrahedron. 75: 137-143. DOI: 10.1016/J.Tet.2018.11.044 |
0.449 |
|
| 2019 |
Hartwig JF, Shaughnessy KH, Shekhar S, Green RA. Palladium‐Catalyzed Amination of Aryl Halides Organic Reactions. 853-958. DOI: 10.1002/0471264180.Or100.14 |
0.79 |
|
| 2018 |
He ZT, Hartwig JF. Enantioselective α-functionalizations of ketones via allylic substitution of silyl enol ethers. Nature Chemistry. PMID 30455430 DOI: 10.1038/S41557-018-0165-X |
0.489 |
|
| 2018 |
He ZT, Li H, Haydl AM, Whiteker GT, Hartwig JF. Trimethylphosphate as a Methylating Agent for Cross Coupling: A Slow-release Mechanism for the Methylation of Arylboronic Esters. Journal of the American Chemical Society. PMID 30419749 DOI: 10.1021/Jacs.8B10076 |
0.828 |
|
| 2018 |
Su B, Lee T, Hartwig JF. Iridium-catalyzed, β-selective C(sp3)-H silylation of aliphatic amines to form silapyrrolidines and 1,2-amino alcohols. Journal of the American Chemical Society. PMID 30354144 DOI: 10.1021/Jacs.8B10428 |
0.655 |
|
| 2018 |
Butcher TW, Hartwig JF. Enantioselective Synthesis of Tertiary Allylic Fluorides by Iridium-Catalyzed Allylic Fluoroalkylation. Angewandte Chemie (International Ed. in English). PMID 30136379 DOI: 10.1002/Anie.201807474 |
0.504 |
|
| 2018 |
Zhang QW, Hartwig JF. Synthesis of heteroaromatic trifluoromethyl ethers with trifluoromethyl triflate as the source of the trifluoromethoxy group. Chemical Communications (Cambridge, England). PMID 30129643 DOI: 10.1039/C8Cc05084H |
0.43 |
|
| 2018 |
Litman ZC, Wang Y, Zhao H, Hartwig JF. Cooperative asymmetric reactions combining photocatalysis and enzymatic catalysis. Nature. 560: 355-359. PMID 30111790 DOI: 10.1038/S41586-018-0413-7 |
0.495 |
|
| 2018 |
Wang JY, Strom AE, Hartwig JF. Mechanistic Studies of Palladium-Catalyzed Aminocarbonylation of Aryl Chlorides with Carbon Monoxide and Ammonia. Journal of the American Chemical Society. PMID 29852736 DOI: 10.1021/Jacs.8B04073 |
0.562 |
|
| 2018 |
Su B, Hartwig JF. Ir-Catalyzed, Silyl-Directed, peri-Borylation of C-H Bonds in Fused Polycyclic Arenes and Heteroarenes. Angewandte Chemie (International Ed. in English). PMID 29779224 DOI: 10.1002/Anie.201805086 |
0.595 |
|
| 2018 |
Peacock DM, Jiang Q, Hanley PS, Cundari TR, Hartwig JF. Reductive Elimination from Phosphine-ligated Alkylpalladium(II) Amido Complexes to Form sp3 Carbon-Nitrogen Bonds. Journal of the American Chemical Society. PMID 29537835 DOI: 10.1021/Jacs.8B00928 |
0.803 |
|
| 2018 |
Jiang X, Boehm P, Hartwig JF. Stereodivergent Allylation of Azaaryl Acetamides and Acetates by Synergistic Iridium and Copper Catalysis. Journal of the American Chemical Society. PMID 29319306 DOI: 10.1021/Jacs.7B12824 |
0.506 |
|
| 2018 |
Karmel C, Li BJ, Hartwig JF. Rhodium-Catalyzed Regioselective Silylation of Alkyl C-H Bonds for the Synthesis of 1,4-Diols. Journal of the American Chemical Society. PMID 29293327 DOI: 10.1021/Jacs.7B11964 |
0.477 |
|
| 2018 |
Peacock DM, Jiang Q, Cundari TR, Hartwig JF. Reductive Elimination to Form C(sp3)–N Bonds from Palladium(II) Primary Alkyl Complexes Organometallics. 37: 3243-3247. DOI: 10.1021/Acs.Organomet.8B00617 |
0.487 |
|
| 2018 |
Karimov RR, Hartwig JF. Übergangsmetall-katalysierte selektive Funktionalisierung von C(sp3
)-H-Bindungen in Naturstoffen Angewandte Chemie. 130: 4309-4317. DOI: 10.1002/Ange.201710330 |
0.3 |
|
| 2017 |
Litman ZC, Sharma A, Hartwig JF. Oxidation of Hindered Allylic C-H Bonds with Applications to the Functionalization of Complex Molecules. Acs Catalysis. 7: 1998-2001. PMID 29910970 DOI: 10.1021/Acscatal.6B03648 |
0.455 |
|
| 2017 |
Bunescu A, Butcher TW, Hartwig JF. Traceless silylation of β-C(sp3)-H bonds of alcohols via perfluorinated acetals. Journal of the American Chemical Society. PMID 29283571 DOI: 10.1021/Jacs.7B12150 |
0.377 |
|
| 2017 |
Karimov RR, Hartwig JF. Transition-Metal-Catalyzed Selective Functionalization of C(sp3)-H Bonds in Natural Products. Angewandte Chemie (International Ed. in English). PMID 29228463 DOI: 10.1002/Anie.201710330 |
0.801 |
|
| 2017 |
Giri R, Brusoe A, Troshin K, Wang JY, Font M, Hartwig JF. Mechanism of the Ullmann Biaryl Ether Synthesis Catalyzed by Complexes of Anionic Ligands. Evidence for the Reaction of Iodoarenes With Ligated Anionic CuI Intermediates. Journal of the American Chemical Society. PMID 29224350 DOI: 10.1021/Jacs.7B11853 |
0.837 |
|
| 2017 |
Hill CK, Hartwig JF. Site-selective oxidation, amination and epimerization reactions of complex polyols enabled by transfer hydrogenation. Nature Chemistry. 9: 1213-1221. PMID 29168493 DOI: 10.1038/Nchem.2835 |
0.393 |
|
| 2017 |
Saper N, Hartwig JF. Mechanistic Investigations of the Hydrogenolysis of Diaryl Ethers Catalyzed by Nickel Complexes of N-Heterocyclic Carbene Ligands. Journal of the American Chemical Society. PMID 29116776 DOI: 10.1021/Jacs.7B10537 |
0.536 |
|
| 2017 |
Arlow SI, Hartwig JF. Synthesis, Characterization, and Reactivity of Palladium Fluoroenolate Complexes. Journal of the American Chemical Society. PMID 29077395 DOI: 10.1021/Jacs.7B09949 |
0.524 |
|
| 2017 |
Hartwig JF. Catalyst-Controlled Site-Selective Bond Activation. Accounts of Chemical Research. 50: 549-555. PMID 28945414 DOI: 10.1021/Acs.Accounts.6B00546 |
0.43 |
|
| 2017 |
Bunescu A, Lee S, Li Q, Hartwig JF. Catalytic Hydroxylation of Polyethylenes. Acs Central Science. 3: 895-903. PMID 28852704 DOI: 10.1021/Acscentsci.7B00255 |
0.393 |
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| 2017 |
Su B, Hartwig JF. Iridium-Catalyzed Enantioselective Silylation of Unactivated C(sp3)-H Bonds. Journal of the American Chemical Society. PMID 28820264 DOI: 10.1021/Jacs.7B06679 |
0.618 |
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| 2017 |
Xi Y, Hartwig JF. Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes. Journal of the American Chemical Society. PMID 28787137 DOI: 10.1021/Jacs.7B07124 |
0.509 |
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| 2017 |
Troshin K, Hartwig JF. Snap deconvolution: An informatics approach to high-throughput discovery of catalytic reactions. Science (New York, N.Y.). 357: 175-181. PMID 28706066 DOI: 10.1126/Science.Aan1568 |
0.436 |
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| 2017 |
Jiang X, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitutions of Aliphatic Esters via Silyl Ketene Acetals. Angewandte Chemie (International Ed. in English). PMID 28597600 DOI: 10.1002/Anie.201704354 |
0.455 |
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| 2017 |
Su B, Zhou TG, Xu PL, Shi ZJ, Hartwig JF. Enantioselective Borylation of Aromatic C-H Bonds with Chiral Dinitrogen Ligands. Angewandte Chemie (International Ed. in English). PMID 28508564 DOI: 10.1002/Anie.201702628 |
0.687 |
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| 2017 |
Key HM, Dydio P, Liu Z, Rha JY, Nazarenko A, Seyedkazemi V, Clark DS, Hartwig JF. Beyond Iron: Iridium-Containing P450 Enzymes for Selective Cyclopropanations of Structurally Diverse Alkenes. Acs Central Science. 3: 302-308. PMID 28470047 DOI: 10.1021/Acscentsci.6B00391 |
0.426 |
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| 2017 |
Xia T, He L, Liu YA, Hartwig JF, Liao X. Palladium-Catalyzed Cross-Coupling of Ethyl Bromodifluoroacetate with Aryl Bromides or Triflates and Cross-Coupling of Ethyl Bromofluoroacetate with Aryl Iodides. Organic Letters. PMID 28467714 DOI: 10.1021/Acs.Orglett.7B00938 |
0.485 |
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| 2017 |
Lee T, Hartwig JF. Mechanistic Studies on Rhodium-Catalyzed Enantioselective Silylation of Aryl C-H Bonds. Journal of the American Chemical Society. PMID 28278372 DOI: 10.1021/Jacs.7B00737 |
0.464 |
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| 2017 |
Jin Y, Chen M, Ge S, Hartwig JF. Palladium-Catalyzed, Enantioselective α-Arylation of α-Fluorooxindoles. Organic Letters. PMID 28263071 DOI: 10.1021/Acs.Orglett.7B00294 |
0.388 |
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| 2017 |
Ge S, Green RA, Hartwig JF. Correction to "Controlling First-Row Catalysts: Amination of Aryl and Heteroaryl Chlorides and Bromides with Primary Aliphatic Amines Catalyzed by a BINAP-Ligated Single-Component Ni(0) Complex". Journal of the American Chemical Society. PMID 28212008 DOI: 10.1021/jacs.7b01463 |
0.328 |
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| 2017 |
Dydio P, Key HM, Hayashi H, Clark DS, Hartwig JF. Chemoselective, Enzymatic C-H Bond Amination Catalyzed by a Cytochrome P450 Containing an Ir(Me)-PIX Cofactor. Journal of the American Chemical Society. PMID 28080030 DOI: 10.1021/Jacs.6B11410 |
0.464 |
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| 2017 |
Wang Y, Bartlett MJ, Denard CA, Hartwig JF, Zhao H. Combining Rh-Catalyzed Diazocoupling and Enzymatic Reduction To Efficiently Synthesize Enantioenriched 2-Substituted Succinate Derivatives Acs Catalysis. 7: 2548-2552. DOI: 10.1021/Acscatal.7B00254 |
0.835 |
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| 2017 |
Fier PS, Hartwig JF. Site‐Selective C‐H Fluorination of Pyridines and Diazines with AgF2 Organic Syntheses. 94: 46-53. DOI: 10.1002/0471264229.Os094.04 |
0.739 |
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| 2016 |
Strom AE, Balcells D, Hartwig JF. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes. Acs Catalysis. 6: 5651-5665. PMID 28713642 DOI: 10.1021/Acscatal.6B01320 |
0.447 |
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| 2016 |
Jiang X, Beiger JJ, Hartwig JF. Stereodivergent Allylic Substitutions with Aryl Acetic Acid Esters by Synergistic Iridium and Lewis Base Catalysis. Journal of the American Chemical Society. PMID 27977923 DOI: 10.1021/Jacs.6B11692 |
0.444 |
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| 2016 |
Su B, Zhou TG, Li XW, Shao XR, Xu PL, Wu WL, Hartwig JF, Shi ZJ. A Chiral Nitrogen Ligand for Enantioselective, Iridium-Catalyzed Silylation of Aromatic C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 27976482 DOI: 10.1002/Anie.201609939 |
0.719 |
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| 2016 |
Jiao Z, Beiger JJ, Jin Y, Ge S, Zhou JS, Hartwig JF. Palladium-Catalyzed Enantioselective α-Arylation of α-Fluoroketones. Journal of the American Chemical Society. 138: 15980-15986. PMID 27960323 DOI: 10.1021/jacs.6b09580 |
0.663 |
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| 2016 |
Morstein J, Kalkman ED, Bold C, Cheng C, Hartwig JF. Correction to "Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles". Organic Letters. 18: 6216. PMID 27934346 DOI: 10.1021/Acs.Orglett.6B03242 |
0.326 |
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| 2016 |
Zhang J, Shrestha R, Hartwig JF, Zhao P. A decarboxylative approach for regioselective hydroarylation of alkynes. Nature Chemistry. 8: 1144-1151. PMID 27874862 DOI: 10.1038/Nchem.2602 |
0.758 |
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| 2016 |
Dydio P, Key HM, Nazarenko A, Rha JY, Seyedkazemi V, Clark DS, Hartwig JF. An artificial metalloenzyme with the kinetics of native enzymes. Science (New York, N.Y.). 354: 102-106. PMID 27846500 DOI: 10.1126/Science.Aah4427 |
0.383 |
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| 2016 |
Karimov RR, Sharma A, Hartwig JF. Late Stage Azidation of Complex Molecules. Acs Central Science. 2: 715-724. PMID 27800554 DOI: 10.1021/Acscentsci.6B00214 |
0.833 |
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| 2016 |
Lee SY, Hartwig JF. Palladium-Catalyzed, Site-Selective Direct Allylation of Aryl C-H Bonds by Silver-Mediated C-H Activation: A Synthetic and Mechanistic Investigation. Journal of the American Chemical Society. PMID 27797512 DOI: 10.1021/Jacs.6B10220 |
0.662 |
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| 2016 |
Peacock DM, Roos CB, Hartwig JF. Palladium-Catalyzed Cross Coupling of Secondary and Tertiary Alkyl Bromides with a Nitrogen Nucleophile. Acs Central Science. 2: 647-652. PMID 27725963 DOI: 10.1021/Acscentsci.6B00187 |
0.532 |
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| 2016 |
Morstein J, Kalkman ED, Cheng C, Hartwig JF. Copper-Mediated C-N Coupling of Arylsilanes with Nitrogen Nucleophiles. Organic Letters. PMID 27689746 DOI: 10.1021/Acs.Orglett.6B02543 |
0.398 |
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| 2016 |
Cheng C, Watts A, Hillmyer MA, Hartwig JF. Polysilylether: A Degradable Polymer from Biorenewable Feedstocks. Angewandte Chemie (International Ed. in English). PMID 27572134 DOI: 10.1002/Anie.201606282 |
0.37 |
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| 2016 |
Chen M, Hartwig JF. Iridium-Catalyzed Regio- and Enantioselective Allylic Substitution of Trisubstituted Allylic Electrophiles. Angewandte Chemie (International Ed. in English). PMID 27531137 DOI: 10.1002/Anie.201607053 |
0.516 |
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| 2016 |
Zhang QW, Brusoe AT, Mascitti V, Hesp KD, Blakemore DC, Kohrt JT, Hartwig JF. Fluorodecarboxylation for the Synthesis of Trifluoromethyl Aryl Ethers. Angewandte Chemie (International Ed. in English). PMID 27384710 DOI: 10.1002/Anie.201604793 |
0.829 |
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| 2016 |
Key HM, Dydio P, Clark DS, Hartwig JF. Abiological catalysis by artificial haem proteins containing noble metals in place of iron. Nature. PMID 27296224 DOI: 10.1038/Nature17968 |
0.339 |
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| 2016 |
Hartwig JF, Larsen MA. Undirected, Homogeneous C-H Bond Functionalization: Challenges and Opportunities. Acs Central Science. 2: 281-92. PMID 27294201 DOI: 10.1021/Acscentsci.6B00032 |
0.419 |
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| 2016 |
Lee T, Hartwig JF. Rhodium-Catalyzed Enantioselective Silylation of Cyclopropyl C-H Bonds. Angewandte Chemie (International Ed. in English). PMID 27253898 DOI: 10.1002/Anie.201603153 |
0.463 |
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| 2016 |
Morstein J, Hou H, Cheng C, Hartwig JF. Trifluoromethylation of Arylsilanes with [(phen)CuCF3 ]. Angewandte Chemie (International Ed. in English). PMID 27214849 DOI: 10.1002/Anie.201601163 |
0.444 |
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| 2016 |
Xi Y, Hartwig JF. Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes Through Catalytic Regioselective Hydroboration. Journal of the American Chemical Society. PMID 27167490 DOI: 10.1021/Jacs.6B02478 |
0.456 |
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| 2016 |
Jiang X, Chen W, Hartwig JF. Iridium-Catalyzed Diastereoselective and Enantioselective Allylic Substitutions with Acyclic α-Alkoxy Ketones. Angewandte Chemie (International Ed. in English). PMID 27038004 DOI: 10.1002/Anie.201600235 |
0.473 |
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| 2016 |
Arlow SI, Hartwig JF. Synthesis of Aryldifluoroamides by Copper-Catalyzed Cross-Coupling. Angewandte Chemie (International Ed. in English). PMID 26929068 DOI: 10.1002/Anie.201600105 |
0.42 |
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| 2016 |
Larsen MA, Cho SH, Hartwig JF. Iridium-Catalyzed, Hydrosilyl-Directed Borylation of Unactivated Alkyl C-H Bonds. Journal of the American Chemical Society. PMID 26745739 DOI: 10.1021/Jacs.5B12153 |
0.608 |
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| 2016 |
Gao F, Webb JD, Sorek H, Wemmer DE, Hartwig JF. Fragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen Acs Catalysis. 6: 7385-7392. DOI: 10.1021/Acscatal.6B02028 |
0.413 |
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| 2016 |
Strom AE, Balcells D, Hartwig JF. Synthetic and Computational Studies on the Rhodium-Catalyzed Hydroamination of Aminoalkenes Acs Catalysis. 6: 5651-5665. DOI: 10.1021/acscatal.6b01320 |
0.336 |
|
| 2015 |
Gao F, Webb JD, Hartwig JF. Chemo- and Regioselective Hydrogenolysis of Diaryl Ether CO Bonds by a Robust Heterogeneous Ni/C Catalyst: Applications to the Cleavage of Complex Lignin-Related Fragments. Angewandte Chemie (International Ed. in English). PMID 26666391 DOI: 10.1002/Anie.201509133 |
0.416 |
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| 2015 |
Wang DY, Choliy Y, Haibach MC, Hartwig JF, Krogh-Jespersen K, Goldman AS. Assessment of the Electronic Factors Determining the Thermodynamics of 'Oxidative Addition' of C-H and N-H Bonds to Ir(I) Complexes. Journal of the American Chemical Society. PMID 26652221 DOI: 10.1021/Jacs.5B09522 |
0.416 |
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| 2015 |
Xi Y, Butcher TW, Zhang J, Hartwig JF. Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes. Angewandte Chemie (International Ed. in English). PMID 26592363 DOI: 10.1002/Anie.201509235 |
0.514 |
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| 2015 |
Hartwig JF. Evolution of C-H Bond Functionalization from Methane to Methodology. Journal of the American Chemical Society. PMID 26566092 DOI: 10.1021/Jacs.5B08707 |
0.474 |
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| 2015 |
Madrahimov ST, Li Q, Sharma A, Hartwig JF. Origins of Regioselectivity in Iridium Catalyzed Allylic Substitution. Journal of the American Chemical Society. PMID 26498382 DOI: 10.1021/Jacs.5B08911 |
0.798 |
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| 2015 |
Chen M, Hartwig JF. Iridium-Catalyzed Enantioselective Allylic Substitution of Enol Silanes from Vinylogous Esters and Amides. Journal of the American Chemical Society. PMID 26441002 DOI: 10.1021/Jacs.5B09980 |
0.512 |
|
| 2015 |
Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Anti-Markovnikov Hydroheteroarylation of Unactivated Alkenes with Indoles, Pyrroles, Benzofurans, and Furans Catalyzed by a Nickel-N-Heterocyclic Carbene System. Journal of the American Chemical Society. 137: 12215-8. PMID 26334367 DOI: 10.1021/Jacs.5B08039 |
0.557 |
|
| 2015 |
Larsen MA, Wilson CV, Hartwig JF. Iridium-Catalyzed Borylation of Primary Benzylic C-H Bonds without a Directing Group: Scope, Mechanism, and Origins of Selectivity. Journal of the American Chemical Society. PMID 26076367 DOI: 10.1021/Jacs.5B04899 |
0.519 |
|
| 2015 |
Brusoe AT, Hartwig JF. Palladium-Catalyzed Arylation of Fluoroalkylamines. Journal of the American Chemical Society. PMID 26065341 DOI: 10.1021/Jacs.5B02512 |
0.858 |
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| 2015 |
Key HM, Clark DS, Hartwig JF. Generation, Characterization, and Tunable Reactivity of Organometallic Fragments Bound to a Protein Ligand. Journal of the American Chemical Society. 137: 8261-8. PMID 26020584 DOI: 10.1021/Jacs.5B04431 |
0.435 |
|
| 2015 |
Lee T, Wilson TW, Berg R, Ryberg P, Hartwig JF. Rhodium-catalyzed enantioselective silylation of arene C-h bonds: desymmetrization of diarylmethanols. Journal of the American Chemical Society. 137: 6742-5. PMID 25948056 DOI: 10.1021/Jacs.5B03091 |
0.451 |
|
| 2015 |
Cheng C, Hartwig JF. Catalytic Silylation of Unactivated C-H Bonds. Chemical Reviews. PMID 25714857 DOI: 10.1021/Cr5006414 |
0.39 |
|
| 2015 |
Green RA, Hartwig JF. Nickel-catalyzed amination of aryl chlorides with ammonia or ammonium salts. Angewandte Chemie (International Ed. in English). 54: 3768-72. PMID 25711163 DOI: 10.1002/Anie.201500404 |
0.487 |
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| 2015 |
Sharma A, Hartwig JF. Metal-catalysed azidation of tertiary C-H bonds suitable for late-stage functionalization. Nature. 517: 600-4. PMID 25631448 DOI: 10.1038/Nature14127 |
0.487 |
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| 2015 |
Cheng C, Hartwig JF. Iridium-catalyzed silylation of aryl C-H bonds. Journal of the American Chemical Society. 137: 592-5. PMID 25514197 DOI: 10.1021/Ja511352U |
0.525 |
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| 2015 |
Snieckus V, Garcia-Irizarry CN, Schramm Y, Takeuchi M, Semba K, Nakao Y, Hartwig JF. Nickel-Catalyzed Anti-Markovnikov Hydroheteroarylation of Nonactivated Alkenes Synfacts. 11: 1251-1251. DOI: 10.1055/S-0035-1560902 |
0.348 |
|
| 2015 |
Denard CA, Bartlett MJ, Wang Y, Lu L, Hartwig JF, Zhao H. Development of a One-Pot tandem reaction combining ruthenium-catalyzed alkene metathesis and enantioselective enzymatic oxidation to produce Aryl epoxides Acs Catalysis. 5: 3817-3822. DOI: 10.1021/Acscatal.5B00533 |
0.837 |
|
| 2014 |
Tran BL, Driess M, Hartwig JF. Copper-catalyzed oxidative dehydrogenative carboxylation of unactivated alkanes to allylic esters via alkenes. Journal of the American Chemical Society. 136: 17292-301. PMID 25389772 DOI: 10.1021/Ja510093X |
0.444 |
|
| 2014 |
Chen W, Chen M, Hartwig JF. Diastereo- and enantioselective iridium-catalyzed allylation of cyclic ketone enolates: synergetic effect of ligands and barium enolates. Journal of the American Chemical Society. 136: 15825-8. PMID 25337972 DOI: 10.1021/Ja506500U |
0.533 |
|
| 2014 |
Ge S, Arlow SI, Mormino MG, Hartwig JF. Pd-catalyzed α-arylation of trimethylsilyl enolates of α,α-difluoroacetamides. Journal of the American Chemical Society. 136: 14401-4. PMID 25254966 DOI: 10.1021/Ja508590K |
0.348 |
|
| 2014 |
Chen M, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylic substitution of silyl dienolates derived from dioxinones. Angewandte Chemie (International Ed. in English). 53: 12172-6. PMID 25223593 DOI: 10.1002/Anie.201406778 |
0.502 |
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| 2014 |
Bair JS, Schramm Y, Sergeev AG, Clot E, Eisenstein O, Hartwig JF. Linear-selective hydroarylation of unactivated terminal and internal olefins with trifluoromethyl-substituted arenes. Journal of the American Chemical Society. 136: 13098-101. PMID 25171744 DOI: 10.1021/Ja505579F |
0.509 |
|
| 2014 |
Green RA, Hartwig JF. Palladium-catalyzed amination of aryl chlorides and bromides with ammonium salts. Organic Letters. 16: 4388-91. PMID 25133675 DOI: 10.1021/Ol501739G |
0.486 |
|
| 2014 |
Cheng C, Hartwig JF. Mechanism of the rhodium-catalyzed silylation of arene C-H bonds. Journal of the American Chemical Society. 136: 12064-72. PMID 25082802 DOI: 10.1021/Ja505844K |
0.469 |
|
| 2014 |
Sevov CS, Hartwig JF. Iridium-catalyzed oxidative olefination of furans with unactivated alkenes. Journal of the American Chemical Society. 136: 10625-31. PMID 25032781 DOI: 10.1021/Ja504414C |
0.805 |
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| 2014 |
Li Q, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of aromatic and benzylic C-H bonds directed by a secondary amine. Angewandte Chemie (International Ed. in English). 53: 8471-4. PMID 24962972 DOI: 10.1002/Anie.201404620 |
0.476 |
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| 2014 |
Fier PS, Hartwig JF. Synthesis and late-stage functionalization of complex molecules through C-H fluorination and nucleophilic aromatic substitution. Journal of the American Chemical Society. 136: 10139-47. PMID 24918484 DOI: 10.1021/Ja5049303 |
0.763 |
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| 2014 |
Chen M, Hartwig JF. Iridium-catalyzed enantioselective allylic substitution of unstabilized enolates derived from α,β-unsaturated ketones. Angewandte Chemie (International Ed. in English). 53: 8691-5. PMID 24917569 DOI: 10.1002/Anie.201403844 |
0.443 |
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| 2014 |
Li Q, Liskey CW, Hartwig JF. Regioselective borylation of the C-H bonds in alkylamines and alkyl ethers. Observation and origin of high reactivity of primary C-H bonds beta to nitrogen and oxygen. Journal of the American Chemical Society. 136: 8755-65. PMID 24836159 DOI: 10.1021/Ja503676D |
0.83 |
|
| 2014 |
Li B, Driess M, Hartwig JF. Iridium-catalyzed regioselective silylation of secondary alkyl C-H bonds for the synthesis of 1,3-diols. Journal of the American Chemical Society. 136: 6586-9. PMID 24734777 DOI: 10.1021/Ja5026479 |
0.432 |
|
| 2014 |
Mormino MG, Fier PS, Hartwig JF. Copper-mediated perfluoroalkylation of heteroaryl bromides with (phen)CuRF. Organic Letters. 16: 1744-7. PMID 24621138 DOI: 10.1021/Ol500422T |
0.771 |
|
| 2014 |
Ge S, Chaładaj W, Hartwig JF. Pd-catalyzed α-arylation of α,α-difluoroketones with aryl bromides and chlorides. A route to difluoromethylarenes. Journal of the American Chemical Society. 136: 4149-52. PMID 24588379 DOI: 10.1021/Ja501117V |
0.508 |
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| 2014 |
Cheng C, Hartwig JF. Rhodium-catalyzed intermolecular C-H silylation of arenes with high steric regiocontrol. Science (New York, N.Y.). 343: 853-7. PMID 24558154 DOI: 10.1126/Science.1248042 |
0.495 |
|
| 2014 |
Denard CA, Huang H, Bartlett MJ, Lu L, Tan Y, Zhao H, Hartwig JF. Cooperative tandem catalysis by an organometallic complex and a metalloenzyme. Angewandte Chemie (International Ed. in English). 53: 465-9. PMID 24536102 DOI: 10.1002/Anie.201305778 |
0.813 |
|
| 2014 |
Larsen MA, Hartwig JF. Iridium-catalyzed C-H borylation of heteroarenes: scope, regioselectivity, application to late-stage functionalization, and mechanism. Journal of the American Chemical Society. 136: 4287-99. PMID 24506058 DOI: 10.1021/Ja412563E |
0.486 |
|
| 2014 |
Sevov CS, Zhou JS, Hartwig JF. Iridium-catalyzed, intermolecular hydroamination of unactivated alkenes with indoles. Journal of the American Chemical Society. 136: 3200-7. PMID 24483848 DOI: 10.1021/Ja412116D |
0.85 |
|
| 2014 |
Tran BL, Li B, Driess M, Hartwig JF. Copper-catalyzed intermolecular amidation and imidation of unactivated alkanes. Journal of the American Chemical Society. 136: 2555-63. PMID 24405209 DOI: 10.1021/Ja411912P |
0.489 |
|
| 2014 |
Ge S, Green RA, Hartwig JF. Controlling first-row catalysts: amination of aryl and heteroaryl chlorides and bromides with primary aliphatic amines catalyzed by a BINAP-ligated single-component Ni(0) complex. Journal of the American Chemical Society. 136: 1617-27. PMID 24397570 DOI: 10.1021/Ja411911S |
0.46 |
|
| 2014 |
Chen W, Hartwig JF. Cation control of diastereoselectivity in iridium-catalyzed allylic substitutions. Formation of enantioenriched tertiary alcohols and thioethers by allylation of 5H-oxazol-4-ones and 5H-thiazol-4-ones. Journal of the American Chemical Society. 136: 377-82. PMID 24295427 DOI: 10.1021/Ja410650E |
0.463 |
|
| 2014 |
Cho SH, Hartwig JF. Iridium-catalyzed diborylation of benzylic C-H bonds directed by a hydrosilyl group: Synthesis of 1,1-benzyldiboronate esters Chemical Science. 5: 694-698. DOI: 10.1039/C3Sc52824C |
0.623 |
|
| 2013 |
Fier PS, Hartwig JF. Selective C-H fluorination of pyridines and diazines inspired by a classic amination reaction. Science (New York, N.Y.). 342: 956-60. PMID 24264986 DOI: 10.1126/Science.1243759 |
0.787 |
|
| 2013 |
Sharma A, Hartwig JF. Enantioselective functionalization of allylic C-H bonds following a strategy of functionalization and diversification. Journal of the American Chemical Society. 135: 17983-9. PMID 24156776 DOI: 10.1021/Ja409995W |
0.478 |
|
| 2013 |
Gallego D, Brück A, Irran E, Meier F, Kaupp M, Driess M, Hartwig JF. From bis(silylene) and bis(germylene) pincer-type nickel(II) complexes to isolable intermediates of the nickel-catalyzed Sonogashira cross-coupling reaction. Journal of the American Chemical Society. 135: 15617-26. PMID 24053603 DOI: 10.1021/Ja408137T |
0.471 |
|
| 2013 |
Hama T, Ge S, Hartwig JF. Palladium-catalyzed α-arylation of zinc enolates of esters: reaction conditions and substrate scope. The Journal of Organic Chemistry. 78: 8250-66. PMID 23931445 DOI: 10.1021/Jo401476F |
0.547 |
|
| 2013 |
Strom AE, Hartwig JF. One-pot anti-Markovnikov hydroamination of unactivated alkenes by hydrozirconation and amination. The Journal of Organic Chemistry. 78: 8909-14. PMID 23899320 DOI: 10.1021/Jo401498W |
0.395 |
|
| 2013 |
Cheng C, Simmons EM, Hartwig JF. Iridium-catalyzed, diastereoselective dehydrogenative silylation of terminal alkenes with (TMSO)2MeSiH. Angewandte Chemie (International Ed. in English). 52: 8984-9. PMID 23857914 DOI: 10.1002/Anie.201304084 |
0.469 |
|
| 2013 |
Hanley PS, Hartwig JF. Migratory insertion of alkenes into metal-oxygen and metal-nitrogen bonds. Angewandte Chemie (International Ed. in English). 52: 8510-25. PMID 23832532 DOI: 10.1002/Anie.201300134 |
0.781 |
|
| 2013 |
Sevov CS, Hartwig JF. Iridium-catalyzed, intermolecular hydroetherification of unactivated aliphatic alkenes with phenols. Journal of the American Chemical Society. 135: 9303-6. PMID 23758128 DOI: 10.1021/Ja4052153 |
0.789 |
|
| 2013 |
Cho SH, Hartwig JF. Iridium-catalyzed borylation of secondary benzylic C-H bonds directed by a hydrosilane. Journal of the American Chemical Society. 135: 8157-60. PMID 23682736 DOI: 10.1021/Ja403462B |
0.628 |
|
| 2013 |
Shrestha R, Mukherjee P, Tan Y, Litman ZC, Hartwig JF. Sterically controlled, palladium-catalyzed intermolecular amination of arenes. Journal of the American Chemical Society. 135: 8480-3. PMID 23678959 DOI: 10.1021/Ja4032677 |
0.771 |
|
| 2013 |
Liskey CW, Hartwig JF. Iridium-catalyzed C-H borylation of cyclopropanes. Journal of the American Chemical Society. 135: 3375-8. PMID 23421575 DOI: 10.1021/Ja400103P |
0.839 |
|
| 2013 |
Fier PS, Luo J, Hartwig JF. Copper-mediated fluorination of arylboronate esters. Identification of a copper(III) fluoride complex. Journal of the American Chemical Society. 135: 2552-9. PMID 23384209 DOI: 10.1021/Ja310909Q |
0.754 |
|
| 2013 |
Sevov CS, Hartwig JF. Iridium-catalyzed intermolecular asymmetric hydroheteroarylation of bicycloalkenes. Journal of the American Chemical Society. 135: 2116-9. PMID 23346874 DOI: 10.1021/Ja312360C |
0.811 |
|
| 2013 |
Fier PS, Hartwig JF. Synthesis of difluoromethyl ethers with difluoromethyltriflate. Angewandte Chemie (International Ed. in English). 52: 2092-5. PMID 23307535 DOI: 10.1002/Anie.201209250 |
0.7 |
|
| 2013 |
Chen W, Hartwig JF. Control of diastereoselectivity for iridium-catalyzed allylation of a prochiral nucleophile with a phosphate counterion. Journal of the American Chemical Society. 135: 2068-71. PMID 23286279 DOI: 10.1021/Ja311363A |
0.488 |
|
| 2013 |
Partridge BM, Hartwig JF. Sterically controlled iodination of arenes via iridium-catalyzed C-H borylation. Organic Letters. 15: 140-3. PMID 23256483 DOI: 10.1021/Ol303164H |
0.43 |
|
| 2013 |
Robbins DW, Hartwig JF. Sterically controlled alkylation of arenes through iridium-catalyzed C-H borylation. Angewandte Chemie (International Ed. in English). 52: 933-7. PMID 23233236 DOI: 10.1002/Anie.201208203 |
0.71 |
|
| 2013 |
Liskey CW, Hartwig JF. Borylation of arenes with bis(hexylene glycolato)diboron Synthesis (Germany). 45: 1837-1842. DOI: 10.1055/S-0033-1338863 |
0.836 |
|
| 2013 |
Denard CA, Hartwig JF, Zhao H. Multistep one-pot reactions combining biocatalysts and chemical catalysts for asymmetric synthesis Acs Catalysis. 3: 2856-2864. DOI: 10.1021/Cs400633A |
0.804 |
|
| 2013 |
Hanley PS, Hartwig JF. Migratorische Insertion von Alkenen in Metall-Sauerstoff- und Metall-Stickstoff-Bindungen Angewandte Chemie. 125: 8668-8684. DOI: 10.1002/Ange.201300134 |
0.726 |
|
| 2012 |
Chen C, Weng Z, Hartwig JF. Synthesis of Copper(I) Thiolate Complexes in the Thioetherification of Aryl Halides. Organometallics. 31: 8031-8037. PMID 23316098 DOI: 10.1021/Om300711C |
0.458 |
|
| 2012 |
Sergeev AG, Webb JD, Hartwig JF. A heterogeneous nickel catalyst for the hydrogenolysis of aryl ethers without arene hydrogenation. Journal of the American Chemical Society. 134: 20226-9. PMID 23163756 DOI: 10.1021/Ja3085912 |
0.413 |
|
| 2012 |
Ge S, Hartwig JF. Highly reactive, single-component nickel catalyst precursor for Suzuki-Miyuara cross-coupling of heteroaryl boronic acids with heteroaryl halides. Angewandte Chemie (International Ed. in English). 51: 12837-41. PMID 23136047 DOI: 10.1002/Anie.201207428 |
0.446 |
|
| 2012 |
Brück A, Gallego D, Wang W, Irran E, Driess M, Hartwig JF. Pushing the σ-donor strength in iridium pincer complexes: bis(silylene) and bis(germylene) ligands are stronger donors than bis(phosphorus(III)) ligands. Angewandte Chemie (International Ed. in English). 51: 11478-82. PMID 23073912 DOI: 10.1002/Anie.201205570 |
0.349 |
|
| 2012 |
Chen W, Hartwig JF. Iridium-catalyzed regioselective and enantioselective allylation of trimethylsiloxyfuran. Journal of the American Chemical Society. 134: 15249-52. PMID 22954355 DOI: 10.1021/Ja306850B |
0.522 |
|
| 2012 |
Hanley PS, Marquard SL, Cundari TR, Hartwig JF. Reductive elimination of alkylamines from low-valent, alkylpalladium(II) amido complexes. Journal of the American Chemical Society. 134: 15281-4. PMID 22934822 DOI: 10.1021/Ja307558X |
0.828 |
|
| 2012 |
Robbins DW, Hartwig JF. A C-H borylation approach to Suzuki-Miyaura coupling of typically unstable 2-heteroaryl and polyfluorophenyl boronates. Organic Letters. 14: 4266-9. PMID 22853624 DOI: 10.1021/Ol301570T |
0.736 |
|
| 2012 |
Liskey CW, Hartwig JF. Iridium-catalyzed borylation of secondary C-H bonds in cyclic ethers. Journal of the American Chemical Society. 134: 12422-5. PMID 22804581 DOI: 10.1021/Ja305596V |
0.816 |
|
| 2012 |
Sevov CS, Zhou J, Hartwig JF. Iridium-catalyzed intermolecular hydroamination of unactivated aliphatic alkenes with amides and sulfonamides. Journal of the American Chemical Society. 134: 11960-3. PMID 22780090 DOI: 10.1021/Ja3052848 |
0.808 |
|
| 2012 |
Fier PS, Hartwig JF. Copper-mediated fluorination of aryl iodides. Journal of the American Chemical Society. 134: 10795-8. PMID 22709145 DOI: 10.1021/Ja304410X |
0.794 |
|
| 2012 |
Madrahimov ST, Hartwig JF. Origins of enantioselectivity during allylic substitution reactions catalyzed by metallacyclic iridium complexes. Journal of the American Chemical Society. 134: 8136-47. PMID 22486270 DOI: 10.1021/Ja212217J |
0.818 |
|
| 2012 |
Fier PS, Hartwig JF. Copper-mediated difluoromethylation of aryl and vinyl iodides. Journal of the American Chemical Society. 134: 5524-7. PMID 22397683 DOI: 10.1021/Ja301013H |
0.785 |
|
| 2012 |
Simmons EM, Hartwig JF. On the interpretation of deuterium kinetic isotope effects in C-H bond functionalizations by transition-metal complexes. Angewandte Chemie (International Ed. in English). 51: 3066-72. PMID 22392731 DOI: 10.1002/Anie.201107334 |
0.381 |
|
| 2012 |
Simmons EM, Hartwig JF. Catalytic functionalization of unactivated primary C-H bonds directed by an alcohol. Nature. 483: 70-3. PMID 22382981 DOI: 10.1038/Nature10785 |
0.449 |
|
| 2012 |
Klinkenberg JL, Hartwig JF. Reductive elimination from arylpalladium cyanide complexes. Journal of the American Chemical Society. 134: 5758-61. PMID 22352451 DOI: 10.1021/Ja300827T |
0.44 |
|
| 2012 |
Tan Y, Barrios-Landeros F, Hartwig JF. Mechanistic studies on direct arylation of pyridine N-oxide: evidence for cooperative catalysis between two distinct palladium centers. Journal of the American Chemical Society. 134: 3683-6. PMID 22313324 DOI: 10.1021/Ja2122156 |
0.83 |
|
| 2012 |
Huang Z, Hartwig JF. Copper(I) enolate complexes in α-arylation reactions: synthesis, reactivity, and mechanism. Angewandte Chemie (International Ed. in English). 51: 1028-32. PMID 22162321 DOI: 10.1002/Anie.201106719 |
0.47 |
|
| 2012 |
Litvinas ND, Fier PS, Hartwig JF. A general strategy for the perfluoroalkylation of arenes and arylbromides by using arylboronate esters and [(phen)CuR(F)]. Angewandte Chemie (International Ed. in English). 51: 536-9. PMID 22083965 DOI: 10.1002/Anie.201106668 |
0.758 |
|
| 2012 |
Hartwig JF. Borylation and silylation of C-H bonds: a platform for diverse C-H bond functionalizations. Accounts of Chemical Research. 45: 864-73. PMID 22075137 DOI: 10.1021/Ar200206A |
0.53 |
|
| 2012 |
Huang DS, DeLuca RJ, Hartwig JF. α‐Arylation of Esters Catalyzed by the Pd(I) Dimer [P(t‐Bu)3Pd(μ‐Br)]2 Organic Syntheses. 4-13. DOI: 10.1002/0471264229.Os088.01 |
0.423 |
|
| 2011 |
Ge S, Hartwig JF. Nickel-catalyzed asymmetric α-arylation and heteroarylation of ketones with chloroarenes: effect of halide on selectivity, oxidation state, and room-temperature reactions. Journal of the American Chemical Society. 133: 16330-3. PMID 21916501 DOI: 10.1021/Ja2082087 |
0.46 |
|
| 2011 |
Robbins DW, Hartwig JF. A simple, multidimensional approach to high-throughput discovery of catalytic reactions. Science (New York, N.Y.). 333: 1423-7. PMID 21903809 DOI: 10.1126/Science.1207922 |
0.746 |
|
| 2011 |
Hanley PS, Hartwig JF. Intermolecular migratory insertion of unactivated olefins into palladium-nitrogen bonds. Steric and electronic effects on the rate of migratory insertion. Journal of the American Chemical Society. 133: 15661-73. PMID 21815675 DOI: 10.1021/Ja205722F |
0.783 |
|
| 2011 |
Marquard SL, Hartwig JF. C(sp3)-O bond-forming reductive elimination of ethers from bisphosphine-ligated benzylpalladium(II) aryloxide complexes. Angewandte Chemie (International Ed. in English). 50: 7119-23. PMID 21688359 DOI: 10.1002/Anie.201101088 |
0.736 |
|
| 2011 |
Sergeev AG, Hartwig JF. Selective, nickel-catalyzed hydrogenolysis of aryl ethers. Science (New York, N.Y.). 332: 439-43. PMID 21512027 DOI: 10.1126/Science.1200437 |
0.444 |
|
| 2011 |
Morimoto H, Tsubogo T, Litvinas ND, Hartwig JF. A broadly applicable copper reagent for trifluoromethylations and perfluoroalkylations of aryl iodides and bromides. Angewandte Chemie (International Ed. in English). 50: 3793-8. PMID 21442711 DOI: 10.1002/Anie.201100633 |
0.422 |
|
| 2011 |
Hartwig JF. Regioselectivity of the borylation of alkanes and arenes. Chemical Society Reviews. 40: 1992-2002. PMID 21336364 DOI: 10.1039/C0Cs00156B |
0.455 |
|
| 2011 |
Tan Y, Hartwig JF. Assessment of the intermediacy of arylpalladium carboxylate complexes in the direct arylation of benzene: evidence for C-H bond cleavage by "ligandless" species. Journal of the American Chemical Society. 133: 3308-11. PMID 21314146 DOI: 10.1021/Ja1113936 |
0.71 |
|
| 2011 |
Liu Z, Yamamichi H, Madrahimov ST, Hartwig JF. Rhodium phosphine-π-arene intermediates in the hydroamination of alkenes. Journal of the American Chemical Society. 133: 2772-82. PMID 21309512 DOI: 10.1021/Ja1057949 |
0.831 |
|
| 2011 |
Carrow BP, Hartwig JF. Distinguishing between pathways for transmetalation in Suzuki-Miyaura reactions. Journal of the American Chemical Society. 133: 2116-9. PMID 21280669 DOI: 10.1021/Ja1108326 |
0.781 |
|
| 2011 |
Liao X, Stanley LM, Hartwig JF. Enantioselective total syntheses of (-)-taiwaniaquinone H and (-)-taiwaniaquinol B by iridium-catalyzed borylation and palladium-catalyzed asymmetric α-arylation. Journal of the American Chemical Society. 133: 2088-91. PMID 21268578 DOI: 10.1021/Ja110215B |
0.488 |
|
| 2011 |
Hartwig JF. Hydrocarbon synthesis: Ringing the chains. Nature Chemistry. 3: 99-101. PMID 21258380 DOI: 10.1038/Nchem.978 |
0.444 |
|
| 2011 |
Klinkenberg JL, Hartwig JF. Catalytic organometallic reactions of ammonia. Angewandte Chemie (International Ed. in English). 50: 86-95. PMID 20857466 DOI: 10.1002/Anie.201002354 |
0.477 |
|
| 2011 |
Hartwig JF, Pouy MJ. Iridium-catalyzed allylic substitution Topics in Organometallic Chemistry. 34: 169-208. DOI: 10.1007/978-3-642-15334-1_7 |
0.842 |
|
| 2011 |
Liao X, Stanley LM, Hartwig JF. ChemInform Abstract: Enantioselective Total Syntheses of (-)-Taiwaniaquinone H (I) and (-)-Taiwaniaquinol B (II) by Iridium-Catalyzed Borylation and Palladium-Catalyzed Asymmetric α-Arylation. Cheminform. 42: no-no. DOI: 10.1002/CHIN.201127191 |
0.316 |
|
| 2010 |
Simmons EM, Hartwig JF. Iridium-catalyzed arene ortho-silylation by formal hydroxyl-directed C-H activation. Journal of the American Chemical Society. 132: 17092-5. PMID 21077625 DOI: 10.1021/Ja1086547 |
0.474 |
|
| 2010 |
Giri R, Hartwig JF. Cu(I)-amido complexes in the Ullmann reaction: reactions of Cu(I)-amido complexes with iodoarenes with and without autocatalysis by CuI. Journal of the American Chemical Society. 132: 15860-3. PMID 20977264 DOI: 10.1021/Ja105695S |
0.655 |
|
| 2010 |
Hartwig JF, Stanley LM. Mechanistically driven development of iridium catalysts for asymmetric allylic substitution. Accounts of Chemical Research. 43: 1461-75. PMID 20873839 DOI: 10.1021/Ar100047X |
0.523 |
|
| 2010 |
Julian LD, Hartwig JF. Intramolecular hydroamination of unbiased and functionalized primary aminoalkenes catalyzed by a rhodium aminophosphine complex. Journal of the American Chemical Society. 132: 13813-22. PMID 20839807 DOI: 10.1021/Ja1052126 |
0.537 |
|
| 2010 |
Klinkenberg JL, Hartwig JF. Slow reductive elimination from arylpalladium parent amido complexes. Journal of the American Chemical Society. 132: 11830-3. PMID 20695642 DOI: 10.1021/Ja1023404 |
0.389 |
|
| 2010 |
Liskey CW, Liao X, Hartwig JF. Cyanation of arenes via iridium-catalyzed borylation. Journal of the American Chemical Society. 132: 11389-91. PMID 20677758 DOI: 10.1021/Ja104442V |
0.831 |
|
| 2010 |
Huang Z, Zhou JS, Hartwig JF. N-H activation of hydrazines by iridium(I). Double N-H activation to form iridium aminonitrene complexes. Journal of the American Chemical Society. 132: 11458-60. PMID 20672808 DOI: 10.1021/Ja1053835 |
0.454 |
|
| 2010 |
Huang DS, Hartwig JF. Palladium-catalyzed gamma-arylation of alpha,beta-unsaturated esters from silyl ketene acetals. Angewandte Chemie (International Ed. in English). 49: 5757-61. PMID 20607784 DOI: 10.1002/Anie.201002328 |
0.428 |
|
| 2010 |
Stanley LM, Bai C, Ueda M, Hartwig JF. Iridium-catalyzed kinetic asymmetric transformations of racemic allylic benzoates. Journal of the American Chemical Society. 132: 8918-20. PMID 20552969 DOI: 10.1021/Ja103779E |
0.521 |
|
| 2010 |
Hanley PS, Markovi? D, Hartwig JF. Intermolecular insertion of ethylene and octene into a palladium-amide bond. Spectroscopic evidence for an ethylene amido intermediate. Journal of the American Chemical Society. 132: 6302-3. PMID 20408534 DOI: 10.1021/Ja102172M |
0.819 |
|
| 2010 |
Robbins DW, Boebel TA, Hartwig JF. Iridium-catalyzed, silyl-directed borylation of nitrogen-containing heterocycles. Journal of the American Chemical Society. 132: 4068-9. PMID 20199022 DOI: 10.1021/Ja1006405 |
0.737 |
|
| 2010 |
Tye JW, Weng Z, Giri R, Hartwig JF. Copper(I) phenoxide complexes in the etherification of aryl halides. Angewandte Chemie (International Ed. in English). 49: 2185-9. PMID 20198667 DOI: 10.1002/Anie.200902245 |
0.828 |
|
| 2010 |
Tan Y, Hartwig JF. Palladium-catalyzed amination of aromatic C-H bonds with oxime esters. Journal of the American Chemical Society. 132: 3676-7. PMID 20187645 DOI: 10.1021/Ja100676R |
0.684 |
|
| 2010 |
Wei CS, Jiménez-Hoyos CA, Videa MF, Hartwig JF, Hall MB. Origins of the selectivity for borylation of primary over secondary C-H bonds catalyzed by Cp*-rhodium complexes. Journal of the American Chemical Society. 132: 3078-91. PMID 20121104 DOI: 10.1021/Ja909453G |
0.411 |
|
| 2010 |
Fernández-Rodríguez MA, Hartwig JF. One-pot synthesis of unsymmetrical diaryl thioethers by palladium-catalyzed coupling of two aryl bromides and a thiol surrogate. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 2355-9. PMID 20112309 DOI: 10.1002/Chem.200902313 |
0.411 |
|
| 2010 |
Sawyer KR, Cahoon JF, Shanoski JE, Glascoe EA, Kling MF, Schlegel JP, Zoerb MC, Hapke M, Hartwig JF, Webster CE, Harris CB. Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin). Journal of the American Chemical Society. 132: 1848-59. PMID 20099849 DOI: 10.1021/Ja906438A |
0.716 |
|
| 2010 |
Mkhalid IA, Barnard JH, Marder TB, Murphy JM, Hartwig JF. C-H activation for the construction of C-B bonds. Chemical Reviews. 110: 890-931. PMID 20028025 DOI: 10.1021/Cr900206P |
0.648 |
|
| 2010 |
Marquard SL, Rosenfeld DC, Hartwig JF. C(sp(3))-N bond-forming reductive elimination of amines: reactions of bisphosphine-ligated benzylpalladium(II) diarylamido complexes. Angewandte Chemie (International Ed. in English). 49: 793-6. PMID 20025002 DOI: 10.1002/Anie.200904032 |
0.773 |
|
| 2010 |
Carrow BP, Hartwig JF. Ligandless, anionic, arylpalladium halide intermediates in the Heck reaction. Journal of the American Chemical Society. 132: 79-81. PMID 20014842 DOI: 10.1021/Ja909306F |
0.798 |
|
| 2010 |
Ueda M, Hartwig JF. Iridium-catalyzed, regio- and enantioselective allylic substitution with aromatic and aliphatic sulfinates. Organic Letters. 12: 92-4. PMID 19954200 DOI: 10.1021/Ol9023248 |
0.503 |
|
| 2010 |
Hartwig J, Stanley L, Bai C, Ueda M. Kinetic Asymmetric Substitution of Racemic Allylic Esters Synfacts. 2010: 1163-1163. DOI: 10.1055/s-0030-1258643 |
0.347 |
|
| 2010 |
Ishiyama T, Takagi J, Hartwig JF, Miyaura N. ChemInform Abstract: A Stoichiometric Aromatic C-H Borylation Catalyzed by Iridium(I)/2,2′-Bipyridine Complexes at Room Temperature. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200251174 |
0.301 |
|
| 2010 |
Takagi J, Sato K, Hartwig JF, Ishiyama T, Miyaura N. ChemInform Abstract: Iridium-Catalyzed C-H Coupling Reaction of Heteroaromatic Compounds with Bis(pinacolato)diboron: Regioselective Synthesis of Heteroarylboronates. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200244181 |
0.362 |
|
| 2010 |
Beare NA, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Arylation of Malonates and Cyanoesters Using Sterically Hindered Trialkyl- and Ferrocenyldialkylphosphine Ligands. Cheminform. 33: no-no. DOI: 10.1002/CHIN.200226065 |
0.36 |
|
| 2010 |
Lee S, Joergensen M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides and Lithium Bis(trimethylsilyl)amide as an Ammonia Equivalent. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200151097 |
0.389 |
|
| 2010 |
Lee S, Hartwig JF. ChemInform Abstract: Improved Catalysts for the Palladium-Catalyzed Synthesis of Oxindoles by Amide α-Arylation. Rate Acceleration, Use of Aryl Chloride Substrates, and a New Carbene Ligand for Asymmetric Transformations. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200140113 |
0.351 |
|
| 2010 |
Loeber O, Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Hydroamination of 1,3-Dienes: A Colorimetric Assay and Enantioselective Additions. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200137094 |
0.359 |
|
| 2010 |
Goodson FE, Hauck SI, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Pure, Regiodefined Polymeric Triarylamines. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199952235 |
0.337 |
|
| 2010 |
Kawatsura M, Hartwig JF. ChemInform Abstract: Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199928079 |
0.313 |
|
| 2010 |
SHAUGHNESSY KH, HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles. Cheminform. 30: no-no. DOI: 10.1002/CHIN.199907067 |
0.34 |
|
| 2010 |
HAMANN BC, HARTWIG JF. ChemInform Abstract: Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl Tosylates. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199847091 |
0.415 |
|
| 2010 |
MANN G, HARTWIG JF, DRIVER MS, FERNANDEZ-RIVAS C. ChemInform Abstract: Palladium-Catalyzed C-N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199825077 |
0.348 |
|
| 2010 |
HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199817100 |
0.324 |
|
| 2010 |
MANN G, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines Enhance Reaction Yields. Cheminform. 29: no-no. DOI: 10.1002/CHIN.199807121 |
0.393 |
|
| 2010 |
MANN G, HARTWIG JF. ChemInform Abstract: Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides. Cheminform. 28: no-no. DOI: 10.1002/CHIN.199752100 |
0.371 |
|
| 2010 |
HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design Cheminform. 28: no-no. DOI: 10.1002/CHIN.199739335 |
0.302 |
|
| 2010 |
LOUIE J, DRIVER MS, HAMANN BC, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate. Cheminform. 28: no-no. DOI: 10.1002/chin.199730084 |
0.599 |
|
| 2010 |
DRIVER MS, HARTWIG JF. ChemInform Abstract: A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by ( dppf)PdCl2 Cheminform. 27: no-no. DOI: 10.1002/CHIN.199645087 |
0.366 |
|
| 2010 |
LOUIE J, HARTWIG JF. ChemInform Abstract: Palladium-Catalyzed Synthesis of Arylamines from Aryl Halides. Mechanistic Studies Lead to Coupling in the Absence of Tin Reagents. Cheminform. 26: no-no. DOI: 10.1002/chin.199541128 |
0.598 |
|
| 2010 |
Huang D, Hartwig J. Corrigendum: Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals Angewandte Chemie International Edition. 49: 7154-7154. DOI: 10.1002/Anie.201090130 |
0.334 |
|
| 2010 |
Huang D, Hartwig J. Berichtigung: Palladium-Catalyzed γ-Arylation of α,β-Unsaturated Esters from Silyl Ketene Acetals Angewandte Chemie. 122: 7310-7310. DOI: 10.1002/Ange.201090130 |
0.334 |
|
| 2010 |
Zhou J, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity Chemtracts. 23: 115-118. |
0.346 |
|
| 2009 |
Tye JW, Hartwig JF. Computational studies of the relative rates for migratory insertions of alkenes into square-planar, methyl, -amido, and -hydroxo complexes of rhodium. Journal of the American Chemical Society. 131: 14703-12. PMID 19778020 DOI: 10.1021/Ja901945B |
0.761 |
|
| 2009 |
Stanley LM, Hartwig JF. Iridium-catalyzed regio- and enantioselective N-allylation of indoles. Angewandte Chemie (International Ed. in English). 48: 7841-4. PMID 19760689 DOI: 10.1002/Anie.200904338 |
0.49 |
|
| 2009 |
Liskey CW, Wei CS, Pahls DR, Hartwig JF. Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds. Chemical Communications (Cambridge, England). 5603-5. PMID 19753371 DOI: 10.1039/B913949D |
0.83 |
|
| 2009 |
Pouy MJ, Stanley LM, Hartwig JF. Enantioselective, iridium-catalyzed monoallylation of ammonia. Journal of the American Chemical Society. 131: 11312-3. PMID 19722644 DOI: 10.1021/Ja905059R |
0.839 |
|
| 2009 |
Vo GD, Hartwig JF. Palladium-catalyzed coupling of ammonia with aryl chlorides, bromides, iodides, and sulfonates: a general method for the preparation of primary arylamines. Journal of the American Chemical Society. 131: 11049-61. PMID 19591470 DOI: 10.1021/Ja903049Z |
0.84 |
|
| 2009 |
Weix DJ, Marković D, Ueda M, Hartwig JF. Direct, intermolecular, enantioselective, iridium-catalyzed allylation of carbamates to form carbamate-protected, branched allylic amines. Organic Letters. 11: 2944-7. PMID 19552468 DOI: 10.1021/Ol901151U |
0.743 |
|
| 2009 |
Stanley LM, Hartwig JF. Regio- and enantioselective N-allylations of imidazole, benzimidazole, and purine heterocycles catalyzed by single-component metallacyclic iridium complexes. Journal of the American Chemical Society. 131: 8971-83. PMID 19480431 DOI: 10.1021/Ja902243S |
0.489 |
|
| 2009 |
Barrios-Landeros F, Carrow BP, Hartwig JF. Effect of ligand steric properties and halide identity on the mechanism for oxidative addition of haloarenes to trialkylphosphine Pd(0) complexes. Journal of the American Chemical Society. 131: 8141-54. PMID 19469511 DOI: 10.1021/Ja900798S |
0.806 |
|
| 2009 |
Alvaro E, Hartwig JF. Resting state and elementary steps of the coupling of aryl halides with thiols catalyzed by alkylbisphosphine complexes of palladium. Journal of the American Chemical Society. 131: 7858-68. PMID 19453106 DOI: 10.1021/Ja901793W |
0.472 |
|
| 2009 |
Madrahimov ST, Markovic D, Hartwig JF. The allyl intermediate in regioselective and enantioselective iridium-catalyzed asymmetric allylic substitution reactions. Journal of the American Chemical Society. 131: 7228-9. PMID 19432473 DOI: 10.1021/Ja902609G |
0.809 |
|
| 2009 |
Fernández-Rodríguez MA, Hartwig JF. A general, efficient, and functional-group-tolerant catalyst system for the palladium-catalyzed thioetherification of aryl bromides and iodides. The Journal of Organic Chemistry. 74: 1663-72. PMID 19154131 DOI: 10.1021/Jo802594D |
0.509 |
|
| 2009 |
Pouy MJ, Stanley LM, Hartwig JF. Enantioselective Monoallylation of Ammonia Synfacts. 2009: 1231-1231. DOI: 10.1055/S-0029-1218131 |
0.381 |
|
| 2009 |
Weix DJ, Marković D, Ueda M, Hartwig JF. Iridium-Catalyzed Allylation of Carbamates Synfacts. 2009: 1113-1113. DOI: 10.1055/S-0029-1217913 |
0.739 |
|
| 2009 |
Liskey CW, Wei CS, Pahls DR, Hartwig JF. Erratum: Pronounced effects of substituents on the iridium-catalyzed borylation of aryl C-H bonds (Chemical Communications (2009) (5603-5605) DOI: 10.1039/b913949d) Chemical Communications. DOI: 10.1039/B924083G |
0.814 |
|
| 2008 |
Alexanian EJ, Hartwig JF. Mechanistic study of beta-hydrogen elimination from organoplatinum(II) enolate complexes. Journal of the American Chemical Society. 130: 15627-35. PMID 18954048 DOI: 10.1021/Ja8056908 |
0.736 |
|
| 2008 |
Herzon SB, Hartwig JF. Hydroaminoalkylation of unactivated olefins with dialkylamines. Journal of the American Chemical Society. 130: 14940-1. PMID 18937477 DOI: 10.1021/Ja806367E |
0.745 |
|
| 2008 |
Ogata T, Hartwig JF. Palladium-catalyzed amination of aryl and heteroaryl tosylates at room temperature. Journal of the American Chemical Society. 130: 13848-9. PMID 18811161 DOI: 10.1021/Ja805810P |
0.531 |
|
| 2008 |
Hartwig JF. Carbon-heteroatom bond formation catalysed by organometallic complexes. Nature. 455: 314-22. PMID 18800130 DOI: 10.1038/Nature07369 |
0.458 |
|
| 2008 |
Shen Q, Hartwig JF. [(CyPF-(t)Bu)PdCl2]: an air-stable, one-component, highly efficient catalyst for amination of heteroaryl and aryl halides. Organic Letters. 10: 4109-12. PMID 18715012 DOI: 10.1021/Ol801615U |
0.642 |
|
| 2008 |
Zhou JS, Hartwig JF. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity. Journal of the American Chemical Society. 130: 12220-1. PMID 18715004 DOI: 10.1021/Ja803523Z |
0.537 |
|
| 2008 |
Hartwig JF. Evolution of a fourth generation catalyst for the amination and thioetherification of aryl halides. Accounts of Chemical Research. 41: 1534-44. PMID 18681463 DOI: 10.1021/Ar800098P |
0.508 |
|
| 2008 |
Tye JW, Weng Z, Johns AM, Incarvito CD, Hartwig JF. Copper complexes of anionic nitrogen ligands in the amidation and imidation of aryl halides. Journal of the American Chemical Society. 130: 9971-83. PMID 18597458 DOI: 10.1021/Ja076668W |
0.841 |
|
| 2008 |
Zhou J, Hartwig JF. Iridium-catalyzed H/D exchange at vinyl groups without olefin isomerization. Angewandte Chemie (International Ed. in English). 47: 5783-7. PMID 18576446 DOI: 10.1002/Anie.200801992 |
0.621 |
|
| 2008 |
Boebel TA, Hartwig JF. Silyl-directed, iridium-catalyzed ortho-borylation of arenes. A one-pot ortho-borylation of phenols, arylamines, and alkylarenes. Journal of the American Chemical Society. 130: 7534-5. PMID 18494474 DOI: 10.1021/Ja8015878 |
0.483 |
|
| 2008 |
Shen Q, Ogata T, Hartwig JF. Highly reactive, general and long-lived catalysts for palladium-catalyzed amination of heteroaryl and aryl chlorides, bromides, and iodides: scope and structure-activity relationships. Journal of the American Chemical Society. 130: 6586-96. PMID 18444639 DOI: 10.1021/Ja077074W |
0.638 |
|
| 2008 |
Barrios-Landeros F, Carrow BP, Hartwig JF. Autocatalytic oxidative addition of PhBr to Pd(PtBu3)2 via Pd(PtBu3)2(H)(Br). Journal of the American Chemical Society. 130: 5842-3. PMID 18402444 DOI: 10.1021/Ja711159Y |
0.791 |
|
| 2008 |
Hama T, Hartwig JF. Palladium-catalyzed alpha-arylation of esters with chloroarenes. Organic Letters. 10: 1549-52. PMID 18358039 DOI: 10.1021/Ol800258U |
0.477 |
|
| 2008 |
Hama T, Hartwig JF. Alpha-arylation of esters catalyzed by the Pd(I) dimer {[P(t-Bu)3]PdBr}2. Organic Letters. 10: 1545-8. PMID 18358038 DOI: 10.1021/Ol8002578 |
0.447 |
|
| 2008 |
Vo GD, Hartwig JF. Palladium-catalyzed alpha-arylation of aldehydes with bromo- and chloroarenes catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Angewandte Chemie (International Ed. in English). 47: 2127-30. PMID 18260078 DOI: 10.1002/Anie.200705357 |
0.814 |
|
| 2008 |
Ueno S, Hartwig JF. Direct, iridium-catalyzed enantioselective and regioselective allylic etherification with aliphatic alcohols. Angewandte Chemie (International Ed. in English). 47: 1928-31. PMID 18236502 DOI: 10.1002/Anie.200705267 |
0.372 |
|
| 2008 |
Liu Z, Hartwig JF. Mild, rhodium-catalyzed intramolecular hydroamination of unactivated terminal and internal alkenes with primary and secondary amines. Journal of the American Chemical Society. 130: 1570-1. PMID 18183986 DOI: 10.1021/Ja710126X |
0.495 |
|
| 2008 |
Liao X, Weng Z, Hartwig JF. Enantioselective alpha-arylation of ketones with aryl triflates catalyzed by difluorphos complexes of palladium and nickel. Journal of the American Chemical Society. 130: 195-200. PMID 18076166 DOI: 10.1021/Ja074453G |
0.518 |
|
| 2008 |
Hartwig J, Hama T. Palladium-Catalyzed α-Arylation of Esters Synfacts. 2008: 0750-0750. DOI: 10.1055/S-2008-1077836 |
0.39 |
|
| 2008 |
Ueno S, Hartwig JF. Iridium-Catalyzed Asymmetric Allylic Etherification Synfacts. 2008: 500-500. DOI: 10.1055/S-2008-1072667 |
0.506 |
|
| 2008 |
Liao X, Weng Z, Hartwig JF. Difluorphos Complexes of Palladium and Nickel-Catalyzed α-Arylation of Ketones Synfacts. 2008: 385-385. DOI: 10.1055/S-2008-1042872 |
0.442 |
|
| 2008 |
Boebel TA, Hartwig JF. Iridium-catalyzed preparation of silylboranes by silane borylation and their use in the catalytic borylation of arenes Organometallics. 27: 6013-6019. DOI: 10.1021/Om800696D |
0.559 |
|
| 2008 |
Zhao P, Hartwig JF. Insertions of ketones and nitriles into organorhodium(i) complexes and β-hydrocarbyl eliminations from rhodium(I) alkoxo and iminyl complexes Organometallics. 27: 4749-4757. DOI: 10.1021/Om800378V |
0.582 |
|
| 2008 |
Boebel TA, Hartwig JF. Conversion of 1,3-disubstituted arenes to chiral α,α-diaryl methylammonium chlorides using arene borylation Tetrahedron. 64: 6824-6830. DOI: 10.1016/J.Tet.2008.04.060 |
0.38 |
|
| 2008 |
Vo GD, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed α-Arylation of Aldehydes with Bromo- and Chloroarenes Catalyzed by [{Pd(allyl)Cl}2] and dppf or Q-phos. Cheminform. 39. DOI: 10.1002/chin.200829078 |
0.819 |
|
| 2008 |
Stavropoulos P, Çelenligil-Çetin R, Kiani S, Tapper A, Pinnapareddy D, Paraskevopoulou P, Adam W, Zhao CG, Bühler B, Schmid A, Bhalla G, Mironov O, Jones CJ, Tenn WJ, Nakamura S, ... ... Hartwig JF, et al. C-H Transformation at Unfunctionalized Alkanes Handbook of C-H Transformations: Applications in Organic Synthesis. 2: 497-651. DOI: 10.1002/9783527619450.ch9 |
0.397 |
|
| 2007 |
Shekhar S, Hartwig JF. Effects of Bases and Halides on the Amination of Chloroarenes Catalyzed by Pd(PBu). Organometallics. 26: 340-351. PMID 29962646 DOI: 10.1021/Om0607548 |
0.614 |
|
| 2007 |
Murphy JM, Liao X, Hartwig JF. Meta halogenation of 1,3-disubstituted arenes via iridium-catalyzed arene borylation. Journal of the American Chemical Society. 129: 15434-5. PMID 18027947 DOI: 10.1021/Ja076498N |
0.712 |
|
| 2007 |
Stambuli JP, Weng Z, Incarvito CD, Hartwig JF. Reductive elimination of ether from T-shaped, monomeric arylpalladium alkoxides. Angewandte Chemie (International Ed. in English). 46: 7674-7. PMID 17786903 DOI: 10.1002/Anie.200702809 |
0.789 |
|
| 2007 |
Pouy MJ, Leitner A, Weix DJ, Ueno S, Hartwig JF. Enantioselective iridium-catalyzed allylic amination of ammonia and convenient ammonia surrogates. Organic Letters. 9: 3949-52. PMID 17725361 DOI: 10.1021/Ol701562P |
0.84 |
|
| 2007 |
Marković D, Hartwig JF. Resting state and kinetic studies on the asymmetric allylic substitutions catalyzed by iridium-phosphoramidite complexes. Journal of the American Chemical Society. 129: 11680-1. PMID 17725356 DOI: 10.1021/Ja074584H |
0.46 |
|
| 2007 |
Johns AM, Liu Z, Hartwig JF. Primary tert- and sec-allylamines via palladium-catalyzed hydroamination and allylic substitution with hydrazine and hydroxylamine derivatives. Angewandte Chemie (International Ed. in English). 46: 7259-61. PMID 17594679 DOI: 10.1002/Anie.200701899 |
0.805 |
|
| 2007 |
Shen Q, Hartwig JF. Lewis acid acceleration of C-N bond-forming reductive elimination from heteroarylpalladium complexes and catalytic amidation of heteroaryl bromides. Journal of the American Chemical Society. 129: 7734-5. PMID 17542591 DOI: 10.1021/Ja0722473 |
0.659 |
|
| 2007 |
Weix DJ, Hartwig JF. Regioselective and enantioselective iridium-catalyzed allylation of enamines. Journal of the American Chemical Society. 129: 7720-1. PMID 17542586 DOI: 10.1021/Ja071455S |
0.714 |
|
| 2007 |
Yamashita Y, Gopalarathnam A, Hartwig JF. Iridium-catalyzed, asymmetric amination of allylic alcohols activated by Lewis acids. Journal of the American Chemical Society. 129: 7508-9. PMID 17523648 DOI: 10.1021/Ja0730718 |
0.391 |
|
| 2007 |
Herzon SB, Hartwig JF. Direct, catalytic hydroaminoalkylation of unactivated olefins with N-alkyl arylamines. Journal of the American Chemical Society. 129: 6690-1. PMID 17474747 DOI: 10.1021/Ja0718366 |
0.732 |
|
| 2007 |
Hartwig JF. Electronic effects on reductive elimination to form carbon-carbon and carbon-heteroatom bonds from palladium(II) complexes. Inorganic Chemistry. 46: 1936-47. PMID 17348724 DOI: 10.1021/Ic061926W |
0.4 |
|
| 2007 |
Murphy JM, Tzschucke CC, Hartwig JF. One-pot synthesis of arylboronic acids and aryl trifluoroborates by Ir-catalyzed borylation of arenes. Organic Letters. 9: 757-60. PMID 17274623 DOI: 10.1021/Ol062903O |
0.808 |
|
| 2007 |
Tzschucke CC, Murphy JM, Hartwig JF. Arenes to anilines and aryl ethers by sequential iridium-catalyzed borylation and copper-catalyzed coupling. Organic Letters. 9: 761-4. PMID 17274622 DOI: 10.1021/Ol062902W |
0.803 |
|
| 2007 |
Zhao P, Incarvito CD, Hartwig JF. Directly observed transmetalation from boron to rhodium. beta-aryl elimination from Rh(I) arylboronates and diarylborinates. Journal of the American Chemical Society. 129: 1876-7. PMID 17256944 DOI: 10.1021/Ja068587Q |
0.549 |
|
| 2007 |
Hartwig J, Tzschucke C, Murphy J. Ir-Catalyzed Borylation and Sequential Functionalization of Arenes Synfacts. 2007: 0534-0534. DOI: 10.1055/S-2007-968425 |
0.375 |
|
| 2007 |
Hartwig J, Takemiya A. Synthesis of Aryl Ketones by Coupling of Aryl Bromides with an Acyl Equivalent Synfacts. 2007: 0193-0193. DOI: 10.1055/s-2006-955803 |
0.313 |
|
| 2007 |
Hartwig J, Murphy J, Lawrence J, Kawamura K, Incarvito C. Ru-Catalyzed Regiospecific Borylation of Methyl C-H Bonds Synfacts. 2007: 0081-0081. DOI: 10.1055/S-2006-955708 |
0.398 |
|
| 2007 |
Shekhar S, Hartwig JF. Effects of bases and halides on the amination of chloroarenes catalyzed by Pd(PtBu3)2 Organometallics. 26: 340-351. DOI: 10.1021/om0607548 |
0.492 |
|
| 2007 |
Hartwig JF, Shekhar S, Shen Q, Barrios-Landeros F. Synthesis of Anilines Cheminform. 38. DOI: 10.1002/9780470682531.Pat0391 |
0.844 |
|
| 2007 |
Pouy MJ, Hartwig JF. Enantioselective iridium-catalyzed allylic amination with ammonia and ammonia surrogates Acs National Meeting Book of Abstracts. |
0.844 |
|
| 2006 |
Johns AM, Tye JW, Hartwig JF. Relative rates for the amination of eta3-allyl and eta3-benzyl complexes of palladium. Journal of the American Chemical Society. 128: 16010-1. PMID 17165734 DOI: 10.1021/Ja067084H |
0.847 |
|
| 2006 |
Takemiya A, Hartwig JF. Palladium-catalyzed synthesis of aryl ketones by coupling of aryl bromides with an acyl anion equivalent. Journal of the American Chemical Society. 128: 14800-1. PMID 17105278 DOI: 10.1021/Ja064782T |
0.498 |
|
| 2006 |
Murphy JM, Lawrence JD, Kawamura K, Incarvito C, Hartwig JF. Ruthenium-catalyzed regiospecific borylation of methyl C-H bonds. Journal of the American Chemical Society. 128: 13684-5. PMID 17044685 DOI: 10.1021/Ja064092P |
0.732 |
|
| 2006 |
Fernández-Rodríguez MA, Shen Q, Hartwig JF. Highly efficient and functional-group-tolerant catalysts for the palladium-catalyzed coupling of aryl chlorides with thiols. Chemistry (Weinheim An Der Bergstrasse, Germany). 12: 7782-96. PMID 17009367 DOI: 10.1002/Chem.200600949 |
0.684 |
|
| 2006 |
Rosenfeld DC, Shekhar S, Takemiya A, Utsunomiya M, Hartwig JF. Hydroamination and hydroalkoxylation catalyzed by triflic acid. Parallels to reactions initiated with metal triflates. Organic Letters. 8: 4179-82. PMID 16956181 DOI: 10.1021/Ol061174+ |
0.61 |
|
| 2006 |
Shekhar S, Trantow B, Leitner A, Hartwig JF. Sequential catalytic isomerization and allylic substitution. Conversion of racemic branched allylic carbonates to enantioenriched allylic substitution products. Journal of the American Chemical Society. 128: 11770-1. PMID 16953612 DOI: 10.1021/Ja0644273 |
0.638 |
|
| 2006 |
Shen Q, Hartwig JF. Palladium-catalyzed coupling of ammonia and lithium amide with aryl halides. Journal of the American Chemical Society. 128: 10028-9. PMID 16881628 DOI: 10.1021/Ja064005T |
0.687 |
|
| 2006 |
Zhao P, Incarvito CD, Hartwig JF. Carbon-oxygen bond formation between a terminal alkoxo ligand and a coordinated olefin. Evidence for olefin insertion into a rhodium alkoxide. Journal of the American Chemical Society. 128: 9642-3. PMID 16866513 DOI: 10.1021/Ja063347W |
0.532 |
|
| 2006 |
Johns AM, Sakai N, Ridder A, Hartwig JF. Direct measurement of the thermodynamics of vinylarene hydroamination. Journal of the American Chemical Society. 128: 9306-7. PMID 16848446 DOI: 10.1021/Ja062773E |
0.725 |
|
| 2006 |
Su W, Raders S, Verkade JG, Liao X, Hartwig JF. Pd-catalyzed alpha-arylation of trimethylsilyl enol ethers with aryl bromides and chlorides: a synergistic effect of two metal fluorides as additives. Angewandte Chemie (International Ed. in English). 45: 5852-5. PMID 16847853 DOI: 10.1002/Anie.200601887 |
0.815 |
|
| 2006 |
Fujita K, Yamashita M, Puschmann F, Alvarez-Falcon MM, Incarvito CD, Hartwig JF. Organometallic chemistry of amidate complexes. accelerating effect of bidentate ligands on the reductive elimination of N-aryl amidates from palladium(II). Journal of the American Chemical Society. 128: 9044-5. PMID 16834372 DOI: 10.1021/Ja062333N |
0.557 |
|
| 2006 |
Sakai N, Ridder A, Hartwig JF. Tropene derivatives by sequential intermolecular and transannular, intramolecular palladium-catalyzed hydroamination of cycloheptatriene. Journal of the American Chemical Society. 128: 8134-5. PMID 16787067 DOI: 10.1021/Ja061349A |
0.501 |
|
| 2006 |
Takemiya A, Hartwig JF. Rhodium-catalyzed intramolecular, anti-Markovnikov hydroamination. Synthesis of 3-arylpiperidines. Journal of the American Chemical Society. 128: 6042-3. PMID 16669666 DOI: 10.1021/Ja058299E |
0.528 |
|
| 2006 |
Hama T, Culkin DA, Hartwig JF. Palladium-catalyzed intermolecular alpha-arylation of zinc amide enolates under mild conditions. Journal of the American Chemical Society. 128: 4976-85. PMID 16608331 DOI: 10.1021/Ja056076I |
0.844 |
|
| 2006 |
Shekhar S, Ryberg P, Hartwig JF, Mathew JS, Blackmond DG, Strieter ER, Buchwald SL. Reevaluation of the mechanism of the amination of aryl halides catalyzed by BINAP-ligated palladium complexes. Journal of the American Chemical Society. 128: 3584-91. PMID 16536531 DOI: 10.1021/Ja045533C |
0.656 |
|
| 2006 |
Zhao P, Incarvito CD, Hartwig JF. Direct observation of beta-aryl eliminations from Rh(I) alkoxides. Journal of the American Chemical Society. 128: 3124-5. PMID 16522075 DOI: 10.1021/Ja058550Q |
0.581 |
|
| 2006 |
Shekhar S, Ryberg P, Hartwig JF. Oxidative addition of phenyl bromide to Pd(BINAP) vs Pd(BINAP)(amine). Evidence for addition to Pd(BINAP). Organic Letters. 8: 851-4. PMID 16494457 DOI: 10.1021/Ol0528890 |
0.553 |
|
| 2006 |
Fernández-Rodríguez MA, Shen Q, Hartwig JF. A general and long-lived catalyst for the palladium-catalyzed coupling of aryl halides with thiols. Journal of the American Chemical Society. 128: 2180-1. PMID 16478149 DOI: 10.1021/Ja0580340 |
0.698 |
|
| 2006 |
Johns AM, Utsunomiya M, Incarvito CD, Hartwig JF. A highly active palladium catalyst for intermolecular hydroamination. Factors that control reactivity and additions of functionalized anilines to dienes and vinylarenes. Journal of the American Chemical Society. 128: 1828-39. PMID 16464081 DOI: 10.1021/Ja056003Z |
0.787 |
|
| 2006 |
Hartwig J, Shekhar S, Tantrow B, Leitner A. Pd(0)/Ir(I)-Catalyzed Sequential Allylic Isomerization and Substitution Synfacts. 2006: 1257-1257. DOI: 10.1055/S-2006-955630 |
0.571 |
|
| 2006 |
Verkade J, Hartwig J, Su W, Raders S, Liao X. Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers Synfacts. 2006: 1164-1164. DOI: 10.1055/S-2006-949478 |
0.805 |
|
| 2006 |
Hartwig J, Hama T, Culkin D. Pd-Catalyzed α-Arylation of Zinc Amide Enolates Synfacts. 2006: 0714-0714. DOI: 10.1055/S-2006-941887 |
0.795 |
|
| 2006 |
Hartwig JF. Discovery and understanding of transition-metal-catalyzed aromatic substitution reactions Synlett. 1283-1294. DOI: 10.1055/S-2006-939728 |
0.462 |
|
| 2006 |
Leitner A, Shekar S, Pouy MJ, Hartwig JF. Ir(I)/Phosphoramidite-Catalyzed Asymmetric Allylic Amination Synfacts. 2006: 137-137. DOI: 10.1055/S-2005-924770 |
0.479 |
|
| 2006 |
Su W, Raders S, Verkade JG, Liao X, Hartwig JF. Cover Picture: Pd-Catalyzed α-Arylation of Trimethylsilyl Enol Ethers with Aryl Bromides and Chlorides: A Synergistic Effect of Two Metal Fluorides as Additives (Angew. Chem. Int. Ed. 35/2006) Angewandte Chemie International Edition. 45: 5717-5717. DOI: 10.1002/Anie.200690118 |
0.819 |
|
| 2005 |
Graening T, Hartwig JF. Iridium-catalyzed regio- and enantioselective allylation of ketone enolates. Journal of the American Chemical Society. 127: 17192-3. PMID 16332060 DOI: 10.1021/JA0566275 |
0.54 |
|
| 2005 |
Wu L, Hartwig JF. Mild palladium-catalyzed selective monoarylation of nitriles. Journal of the American Chemical Society. 127: 15824-32. PMID 16277525 DOI: 10.1021/Ja053027X |
0.476 |
|
| 2005 |
Limmert ME, Roy AH, Hartwig JF. Kumada coupling of aryl and vinyl tosylates under mild conditions. The Journal of Organic Chemistry. 70: 9364-70. PMID 16268609 DOI: 10.1021/JO051394L |
0.754 |
|
| 2005 |
Leitner A, Shekhar S, Pouy MJ, Hartwig JF. A simple iridium catalyst with a single resolved stereocenter for enantioselective allylic amination. Catalyst selection from mechanistic analysis. Journal of the American Chemical Society. 127: 15506-14. PMID 16262414 DOI: 10.1021/Ja054331T |
0.827 |
|
| 2005 |
Boller TM, Murphy JM, Hapke M, Ishiyama T, Miyaura N, Hartwig JF. Mechanism of the mild functionalization of arenes by diboron reagents catalyzed by iridium complexes. Intermediacy and chemistry of bipyridine-ligated iridium trisboryl complexes. Journal of the American Chemical Society. 127: 14263-78. PMID 16218621 DOI: 10.1021/Ja053433G |
0.83 |
|
| 2005 |
Hartwig J. Synthetic chemistry: recipes for excess. Nature. 437: 487-488. PMID 16177775 DOI: 10.1038/437487A |
0.325 |
|
| 2005 |
Bae C, Hartwig JF, Chung H, Harris NK, Switek KA, Hillmyer MA. Regiospecific side-chain functionalization of linear low-density polyethylene with polar groups. Angewandte Chemie (International Ed. in English). 44: 6410-3. PMID 16145705 DOI: 10.1002/Anie.200501837 |
0.473 |
|
| 2005 |
Zhao P, Krug C, Hartwig JF. Transfer of amido groups from isolated rhodium(I) amides to alkenes and vinylarenes. Journal of the American Chemical Society. 127: 12066-73. PMID 16117547 DOI: 10.1021/Ja052473H |
0.793 |
|
| 2005 |
Zhao P, Hartwig JF. Beta-aryl eliminations from Rh(I) iminyl complexes. Journal of the American Chemical Society. 127: 11618-9. PMID 16104735 DOI: 10.1021/Ja054132+ |
0.6 |
|
| 2005 |
Yan XZ, Pawlas J, Goodson T, Hartwig JF. Polaron delocalization in ladder macromolecular systems. Journal of the American Chemical Society. 127: 9105-16. PMID 15969589 DOI: 10.1021/Ja050184N |
0.309 |
|
| 2005 |
Barrios-Landeros F, Hartwig JF. Distinct mechanisms for the oxidative addition of chloro-, bromo-, and iodoarenes to a bisphosphine palladium(0) complex with hindered ligands. Journal of the American Chemical Society. 127: 6944-5. PMID 15884925 DOI: 10.1021/Ja042959I |
0.809 |
|
| 2005 |
Takaya J, Hartwig JF. Mechanistic studies of ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes: Intermediates and evidence for catalysis through π-arene complexes Journal of the American Chemical Society. 127: 5756-5757. PMID 15839651 DOI: 10.1021/Ja0506410 |
0.495 |
|
| 2005 |
Tsukada N, Hartwig JF. Intermolecular and intramolecular, platinum-catalyzed, acceptorless dehydrogenative coupling of hydrosilanes with aryl and aliphatic methyl C-H bonds. Journal of the American Chemical Society. 127: 5022-3. PMID 15810828 DOI: 10.1021/Ja050612P |
0.493 |
|
| 2005 |
Lee DY, Hartwig JF. Zinc trimethylsilylamide as a mild ammonia equivalent and base for the amination of aryl halides and triflates. Organic Letters. 7: 1169-72. PMID 15760166 DOI: 10.1021/Ol050141B |
0.457 |
|
| 2005 |
Leitner A, Shu C, Hartwig JF. Effects of catalyst activation and ligand steric properties on the enantioselective allylation of amines and phenoxides. Organic Letters. 7: 1093-6. PMID 15760147 DOI: 10.1021/Ol050029D |
0.475 |
|
| 2005 |
Hartwig JF, Cook KS, Hapke M, Incarvito CD, Fan Y, Webster CE, Hall MB. Rhodium boryl complexes in the catalytic, terminal functionalization of alkanes. Journal of the American Chemical Society. 127: 2538-52. PMID 15725009 DOI: 10.1021/Ja045090C |
0.746 |
|
| 2005 |
Zhao J, Goldman AS, Hartwig JF. Oxidative addition of ammonia to form a stable monomeric amido hydride complex. Science (New York, N.Y.). 307: 1080-2. PMID 15718464 DOI: 10.1126/Science.1109389 |
0.509 |
|
| 2005 |
Shen Q, Shekhar S, Stambuli JP, Hartwig JF. Highly reactive, general, and long-lived catalysts for coupling heteroaryl and aryl chlorides with primary nitrogen nucleophiles. Angewandte Chemie (International Ed. in English). 44: 1371-5. PMID 15666413 DOI: 10.1002/Anie.200462629 |
0.812 |
|
| 2005 |
Bae C, Hartwig JF, Boaen Harris NK, Long RO, Anderson KS, Hillmyer MA. Catalytic hydroxylation of polypropylenes. Journal of the American Chemical Society. 127: 767-76. PMID 15643903 DOI: 10.1021/ja044440s |
0.508 |
|
| 2005 |
Zhao J, Hartwig JF. Acceptorless, neat, ruthenium-catalyzed dehydrogenative cyclization of diols to lactones Organometallics. 24: 2441-2446. DOI: 10.1021/Om048983M |
0.429 |
|
| 2005 |
Tsukada N, Hartwig JF. Intermolecular and Intramolecular, Platinum-Catalyzed, Acceptorless Dehydrogenative Coupling of Hydrosilanes with Aryl and Aliphatic Methyl C—H Bonds. Cheminform. 36. DOI: 10.1002/CHIN.200534227 |
0.303 |
|
| 2005 |
Lee D, Hartwig JF. Zinc Trimethylsilylamide as a Mild Ammonia Equivalent and Base for the Amination of Aryl Halides and Triflates. Cheminform. 36. DOI: 10.1002/CHIN.200531089 |
0.333 |
|
| 2004 |
Lawrence JD, Takahashi M, Bae C, Hartwig JF. Regiospecific functionalization of methyl C-H bonds of alkyl groups in reagents with heteroatom functionality. Journal of the American Chemical Society. 126: 15334-5. PMID 15563132 DOI: 10.1021/Ja044933X |
0.642 |
|
| 2004 |
Leitner A, Larsen J, Steffens C, Hartwig JF. Palladium-catalyzed addition of mono- and dicarbonyl compounds to conjugated dienes. The Journal of Organic Chemistry. 69: 7552-7. PMID 15497981 DOI: 10.1021/Jo0490999 |
0.547 |
|
| 2004 |
Cook KS, Incarvito CD, Webster CE, Fan Y, Hall MB, Hartwig JF. Rhodium silyl boryl hydride complexes: comparison of bonding and the rates of elimination of borane, silane, and dihydrogen. Angewandte Chemie (International Ed. in English). 43: 5474-7. PMID 15484256 DOI: 10.1002/Anie.200460430 |
0.394 |
|
| 2004 |
Shekhar S, Hartwig JF. Distinct electronic effects on reductive eliminations of symmetrical and unsymmetrical bis-aryl platinum complexes. Journal of the American Chemical Society. 126: 13016-27. PMID 15469300 DOI: 10.1021/Ja0480365 |
0.571 |
|
| 2004 |
Shu C, Leitner A, Hartwig JF. Enantioselective allylation of aromatic amines after in situ generation of an activated cyclometalated iridium catalyst. Angewandte Chemie (International Ed. in English). 43: 4797-800. PMID 15366091 DOI: 10.1002/Anie.200460276 |
0.4 |
|
| 2004 |
Shu C, Hartwig JF. Iridium-catalyzed intermolecular allylic etherification with aliphatic alkoxides: asymmetric synthesis of dihydropyrans and dihydrofurans. Angewandte Chemie (International Ed. in English). 43: 4794-7. PMID 15366090 DOI: 10.1002/Anie.200460214 |
0.475 |
|
| 2004 |
Yamashita M, Hartwig JF. Synthesis, structure, and reductive elimination chemistry of three-coordinate arylpalladium amido complexes. Journal of the American Chemical Society. 126: 5344-5. PMID 15113190 DOI: 10.1021/Ja0315107 |
0.586 |
|
| 2004 |
Liu X, Hartwig JF. Palladium-catalyzed arylation of trimethylsilyl enolates of esters and imides. High functional group tolerance and stereoselective synthesis of alpha-aryl carboxylic acid derivatives. Journal of the American Chemical Society. 126: 5182-91. PMID 15099101 DOI: 10.1021/Ja031544E |
0.465 |
|
| 2004 |
Leitner A, Shu C, Hartwig JF. Editing the stereochemical elements in an iridium catalyst for enantioselective allylic amination. Proceedings of the National Academy of Sciences of the United States of America. 101: 5830-3. PMID 15067140 DOI: 10.1073/Pnas.0307967101 |
0.467 |
|
| 2004 |
Utsunomiya M, Hartwig JF. Ruthenium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society. 126: 2702-3. PMID 14995178 DOI: 10.1021/Ja031542U |
0.522 |
|
| 2004 |
Krug C, Hartwig JF. Imine insertion into a late metal-carbon bond to form a stable amido complex. Journal of the American Chemical Society. 126: 2694-5. PMID 14995174 DOI: 10.1021/Ja038819A |
0.809 |
|
| 2004 |
Stambuli JP, Incarvito CD, Bühl M, Hartwig JF. Synthesis, structure, theoretical studies, and Ligand exchange reactions of monomeric, T-shaped arylpalladium(II) halide complexes with an additional, weak agostic interaction. Journal of the American Chemical Society. 126: 1184-94. PMID 14746489 DOI: 10.1021/Ja037928M |
0.766 |
|
| 2004 |
Ishiyama T, Nobuta Y, Hartwig JF, Miyaura N. Room temperature borylation of arenes and heteroarenes using stoichiometric amounts of pinacolborane catalyzed by iridium complexes in an inert solvent. Chemical Communications (Cambridge, England). 2924-5. PMID 14680243 DOI: 10.1039/B311103B |
0.477 |
|
| 2004 |
Utsunomiya M, Kawatsura M, Hartwig JF. Palladium-catalyzed equilibrium addition of acidic OH groups across dienes. Angewandte Chemie (International Ed. in English). 42: 5865-8. PMID 14673921 DOI: 10.1002/Anie.200352621 |
0.37 |
|
| 2004 |
Utsunomiya M, Hartwig JF. Intermolecular, markovnikov hydroamination of vinylarenes with alkylamines. Journal of the American Chemical Society. 125: 14286-7. PMID 14624571 DOI: 10.1021/Ja0375535 |
0.552 |
|
| 2004 |
Hartwig JF. Development of catalysts for the hydroamination of olefins Pure and Applied Chemistry. 76: 507-516. DOI: 10.1351/Pac200476030507 |
0.408 |
|
| 2004 |
Culkin DA, Hartwig JF. Carbon-carbon bond-forming reductive elimination from arylpalladium complexes containing functionalized alkyl groups. Influence of ligand steric and electronic properties on structure, stability, and reactivity Organometallics. 23: 3398-3416. DOI: 10.1021/Om049726K |
0.818 |
|
| 2004 |
Krug C, Hartwig JF. Reactions of an Arylrhodium Complex with Aldehydes, Imines, Ketones, and Alkynones. New Classes of Insertion Reactions Organometallics. 23: 4594-4607. DOI: 10.1021/Om0496582 |
0.808 |
|
| 2004 |
Roy AH, Hartwig JF. Reductive elimination of aryl halides upon addition of hindered alkylphosphines to dimeric arylpalladium(II) halide complexes Organometallics. 23: 1533-1541. DOI: 10.1021/Om034277U |
0.765 |
|
| 2004 |
Roy AH, Hartwig JF. Oxidative Addition of Aryl Sulfonates to Palladium (0) Complexes of Mono- and Bidentate Phosphines. Mild Addition of Aryl Tosylates and the Effects of Anions on Rate and Mechanism Organometallics. 23: 194-202. DOI: 10.1021/Om034187P |
0.745 |
|
| 2004 |
Shu C, Hartwig JF. Iridium-Catalyzed Intermolecular Allylic Etherification with Aliphatic Alkoxides: Asymmetric Synthesis of Dihydropyrans and Dihydrofurans. Cheminform. 35. DOI: 10.1002/CHIN.200452047 |
0.37 |
|
| 2004 |
Hartwig JF. Metal Complexes as Catalysts for Carbon—Heteroatom Cross-Coupling Reactions Cheminform. 35. DOI: 10.1002/chin.200441257 |
0.32 |
|
| 2004 |
Liu X, Hartwig JF. Palladium-Catalyzed Arylation of Trimethylsilyl Enolates of Esters and Imides. High Functional Group Tolerance and Stereoselective Synthesis of α-Aryl Carboxylic Acid Derivatives. Cheminform. 35. DOI: 10.1002/CHIN.200435044 |
0.315 |
|
| 2004 |
Ishiyama T, Takagi J, Yonekawa Y, Hartwig JF, Miyaura N. Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions. Cheminform. 35. DOI: 10.1002/Adsc.200303058 |
0.472 |
|
| 2003 |
Hama T, Liu X, Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and amides under more neutral conditions. Journal of the American Chemical Society. 125: 11176-7. PMID 16220921 DOI: 10.1021/Ja036792P |
0.839 |
|
| 2003 |
Yamashita M, Cuevas Vicario JV, Hartwig JF. Trans influence on the rate of reductive elimination. Reductive elimination of amines from isomeric arylpalladium amides with unsymmetrical coordination spheres. Journal of the American Chemical Society. 125: 16347-60. PMID 14692777 DOI: 10.1021/Ja037425G |
0.612 |
|
| 2003 |
Kiener CA, Shu C, Incarvito C, Hartwig JF. Identification of an activated catalyst in the iridium-catalyzed allylic amination and etherification. Increased rates, scope, and selectivity. Journal of the American Chemical Society. 125: 14272-3. PMID 14624564 DOI: 10.1021/Ja038319H |
0.511 |
|
| 2003 |
Roy AH, Hartwig JF. Directly observed reductive elimination of aryl halides from monomeric arylpalladium(II) halide complexes. Journal of the American Chemical Society. 125: 13944-5. PMID 14611215 DOI: 10.1021/Ja037959H |
0.75 |
|
| 2003 |
Kanzelberger M, Zhang X, Emge TJ, Goldman AS, Zhao J, Incarvito C, Hartwig JF. Distinct thermodynamics for the formation and cleavage of N-H bonds in aniline and ammonia. Directly-observed reductive elimination of ammonia from an isolated amido hydride complex. Journal of the American Chemical Society. 125: 13644-5. PMID 14599186 DOI: 10.1021/Ja037363U |
0.423 |
|
| 2003 |
Roy AH, Hartwig JF. Oxidative addition of aryl tosylates to palladium(0) and coupling of unactivated aryl tosylates at room temperature. Journal of the American Chemical Society. 125: 8704-5. PMID 12862447 DOI: 10.1021/Ja035835Z |
0.765 |
|
| 2003 |
Stambuli JP, Hartwig JF. Recent advances in the discovery of organometallic catalysts using high-throughput screening assays. Current Opinion in Chemical Biology. 7: 420-6. PMID 12826131 DOI: 10.1016/S1367-5931(03)00056-5 |
0.715 |
|
| 2003 |
Stauffer SR, Hartwig JF. Fluorescence resonance energy transfer (FRET) as a high-throughput assay for coupling reactions. Arylation of amines as a case study. Journal of the American Chemical Society. 125: 6977-85. PMID 12783551 DOI: 10.1021/Ja034161P |
0.448 |
|
| 2003 |
Liu X, Hartwig JF. Palladium-catalyzed alpha-arylation of azlactones to form quaternary amino acid derivatives. Organic Letters. 5: 1915-8. PMID 12762685 DOI: 10.1021/Ol034570Q |
0.454 |
|
| 2003 |
Utsunomiya M, Kuwano R, Kawatsura M, Hartwig JF. Rhodium-catalyzed anti-Markovnikov hydroamination of vinylarenes. Journal of the American Chemical Society. 125: 5608-9. PMID 12733880 DOI: 10.1021/JA0293608 |
0.379 |
|
| 2003 |
Culkin DA, Hartwig JF. Palladium-catalyzed alpha-arylation of carbonyl compounds and nitriles. Accounts of Chemical Research. 36: 234-45. PMID 12693921 DOI: 10.1021/Ar0201106 |
0.845 |
|
| 2003 |
Hooper MW, Utsunomiya M, Hartwig JF. Scope and mechanism of palladium-catalyzed amination of five-membered heterocyclic halides. The Journal of Organic Chemistry. 68: 2861-73. PMID 12662063 DOI: 10.1021/Jo0266339 |
0.486 |
|
| 2003 |
López F, Ohmura T, Hartwig JF. Regio- and enantioselective iridium-catalyzed intermolecular allylic etherification of achiral allylic carbonates with phenoxides. Journal of the American Chemical Society. 125: 3426-7. PMID 12643693 DOI: 10.1021/Ja029790Y |
0.512 |
|
| 2003 |
Webster CE, Fan Y, Hall MB, Kunz D, Hartwig JF. Experimental and computational evidence for a boron-assisted, sigma-bond metathesis pathway for alkane borylation. Journal of the American Chemical Society. 125: 858-9. PMID 12537470 DOI: 10.1021/Ja028394C |
0.428 |
|
| 2003 |
Ohmura T, Hartwig JF. Regio- and enantioselective allylic amination of achiral allylic esters catalyzed by an iridium-phosphoramidite complex. Journal of the American Chemical Society. 124: 15164-5. PMID 12487578 DOI: 10.1021/Ja028614M |
0.499 |
|
| 2003 |
Wolkowski JP, Hartwig JF. Generation of reactivity from typically stable ligands: CbondC bond-forming reductive elimination from aryl palladium(II) complexes of malonate anions. Angewandte Chemie (International Ed. in English). 41: 4289-91. PMID 12434365 DOI: 10.1002/1521-3773(20021115)41:22<4289::Aid-Anie4289>3.0.Co;2-4 |
0.448 |
|
| 2003 |
Kuwano R, Utsunomiya M, Hartwig JF. Aqueous hydroxide as a base for palladium-catalyzed amination of aryl chlorides and bromides. The Journal of Organic Chemistry. 67: 6479-86. PMID 12201770 DOI: 10.1021/Jo0258913 |
0.494 |
|
| 2003 |
Hooper MW, Hartwig JF. Understanding the coupling of heteroaromatic substrates: Synthesis, structures, and reductive eliminations of heteroarylpalladium amido complexes Organometallics. 22: 3394-3403. DOI: 10.1021/Om030257G |
0.458 |
|
| 2003 |
Mann G, Shelby Q, Roy AH, Hartwig JF. Electronic and steric effects on the reductive elimination of diaryl ethers from palladium(II) Organometallics. 22: 2775-2789. DOI: 10.1021/Om030230X |
0.757 |
|
| 2003 |
Anastasi NR, Waltz KM, Weerakoon WL, Hartwig JF. A short synthesis of tetraalkoxydiborane(4) reagents Organometallics. 22: 365-369. DOI: 10.1021/Om0208016 |
0.791 |
|
| 2003 |
Hooper MW, Utsunomiya M, Hartwig JF. Scope and Mechanism of Palladium-Catalyzed Amination of Five-Membered Heterocyclic Halides. Cheminform. 34. DOI: 10.1002/CHIN.200333052 |
0.369 |
|
| 2003 |
Culkin DA, Hartwig JF. Palladium-Catalyzed α-Arylation of Carbonyl Compounds and Nitriles Cheminform. 34. DOI: 10.1002/chin.200326269 |
0.784 |
|
| 2003 |
Ohmura T, Hartwig JF. Regio- and Enantioselective Allylic Amination of Achiral Allylic Esters Catalyzed by an Iridium—Phosphoramidite Complex. Cheminform. 34. DOI: 10.1002/CHIN.200319051 |
0.415 |
|
| 2003 |
Joergensen M, Lee S, Liu X, Wolkowski JP, Hartwig JF. Efficient Synthesis of α-Aryl Esters by Room-Temperature Palladium-Catalyzed Coupling of Aryl Halides with Ester Enolates. Cheminform. 34. DOI: 10.1002/CHIN.200307081 |
0.303 |
|
| 2003 |
Kuwano R, Utsunomiya M, Hartwig JF. Aqueous Hydroxide as a Base for Palladium-Catalyzed Amination of Aryl Chlorides and Bromides. Cheminform. 34. DOI: 10.1002/CHIN.200306053 |
0.414 |
|
| 2003 |
Kataoka N, Shelby Q, Stambuli JP, Hartwig JF. Air-Stable, Sterically Hindered Ferrocenyl Dialkylphosphines for Palladium-Catalyzed C—C, C—N, and C—O Bond-Forming Cross-Couplings. Cheminform. 34. DOI: 10.1002/chin.200303026 |
0.709 |
|
| 2003 |
Ishiyama T, Takagi J, Yonekawa Y, Hartwig J, Miyaura N. Iridium-Catalyzed Direct Borylation of Five-Membered Heteroarenes by Bis(pinacolato)diboron: Regioselective, Stoichiometric, and Room Temperature Reactions Advanced Synthesis & Catalysis. 345: 1103-1106. DOI: 10.1002/ADSC.200303058 |
0.319 |
|
| 2002 |
Stambuli JP, Kuwano R, Hartwig JF. Unparalleled rates for the activation of aryl chlorides and bromides: coupling with amines and boronic acids in minutes at room temperature. Angewandte Chemie (International Ed. in English). 41: 4746-8. PMID 12481346 DOI: 10.1002/Anie.200290036 |
0.71 |
|
| 2002 |
Jørgensen M, Lee S, Liu X, Wolkowski JP, Hartwig JF. Efficient synthesis of alpha-aryl esters by room-temperature palladium-catalyzed coupling of aryl halides with ester enolates. Journal of the American Chemical Society. 124: 12557-65. PMID 12381200 DOI: 10.1021/Ja027643U |
0.471 |
|
| 2002 |
Hartwig JF. Chemical synthesis. Raising the bar for the "perfect reaction". Science (New York, N.Y.). 297: 1653-4. PMID 12215631 DOI: 10.1126/Science.1076371 |
0.417 |
|
| 2002 |
Ishiyama T, Takagi J, Hartwig JF, Miyaura N. A stoichiometric aromatic CbondH borylation catalyzed by iridium(i)/2,2'-bipyridine complexes at room temperature. Angewandte Chemie (International Ed. in English). 41: 3056-8. PMID 12203457 DOI: 10.1002/1521-3773(20020816)41:16<3056::Aid-Anie3056>3.0.Co;2-# |
0.379 |
|
| 2002 |
Stambuli JP, Bühl M, Hartwig JF. Synthesis, characterization, and reactivity of monomeric, arylpalladium halide complexes with a hindered phosphine as the only dative ligand. Journal of the American Chemical Society. 124: 9346-7. PMID 12167009 DOI: 10.1021/Ja0264394 |
0.795 |
|
| 2002 |
Culkin DA, Hartwig JF. Synthesis, characterization, and reactivity of arylpalladium cyanoalkyl complexes: selection of catalysts for the alpha-arylation of nitriles. Journal of the American Chemical Society. 124: 9330-1. PMID 12167001 DOI: 10.1021/Ja026584H |
0.834 |
|
| 2002 |
Kataoka N, Shelby Q, Stambuli JP, Hartwig JF. Air stable, sterically hindered ferrocenyl dialkylphosphines for palladium-catalyzed C[bond]C, C[bond]N, and C[bond]O bond-forming cross-couplings. The Journal of Organic Chemistry. 67: 5553-66. PMID 12153253 DOI: 10.1021/Jo025732J |
0.798 |
|
| 2002 |
Ranasinghe MI, Varnavski OP, Pawlas J, Hauck SI, Louie J, Hartwig JF, Goodson T. Femtosecond excitation energy transport in triarylamine dendrimers. Journal of the American Chemical Society. 124: 6520-1. PMID 12047157 DOI: 10.1021/Ja025505Z |
0.571 |
|
| 2002 |
Schlummer B, Hartwig JF. Brønsted acid-catalyzed intramolecular hydroamination of protected alkenylamines. Synthesis of pyrrolidines and piperidines. Organic Letters. 4: 1471-4. PMID 11975606 DOI: 10.1021/Ol025659J |
0.447 |
|
| 2002 |
Pawlas J, Nakao Y, Kawatsura M, Hartwig JF. A general nickel-catalyzed hydroamination of 1,3-dienes by alkylamines: catalyst selection, scope, and mechanism. Journal of the American Chemical Society. 124: 3669-79. PMID 11929257 DOI: 10.1021/Ja017575W |
0.553 |
|
| 2002 |
Krug C, Hartwig JF. Direct observation of aldehyde insertion into rhodium-aryl and -alkoxide complexes. Journal of the American Chemical Society. 124: 1674-9. PMID 11853443 DOI: 10.1021/Ja017401E |
0.839 |
|
| 2002 |
Nettekoven U, Hartwig JF. A new pathway for hydroamination. Mechanism of palladium-catalyzed addition of anilines to vinylarenes. Journal of the American Chemical Society. 124: 1166-7. PMID 11841274 DOI: 10.1021/Ja017521M |
0.496 |
|
| 2002 |
Kondo Y, García-Cuadrado D, Hartwig JF, Boaen NK, Wagner NL, Hillmyer MA. Rhodium-catalyzed, regiospecific functionalization of polyolefins in the melt. Journal of the American Chemical Society. 124: 1164-5. PMID 11841273 DOI: 10.1021/Ja016763J |
0.312 |
|
| 2002 |
Beare NA, Hartwig JF. Palladium-catalyzed arylation of malonates and cyanoesters using sterically hindered trialkyl- and ferrocenyldialkylphosphine ligands. The Journal of Organic Chemistry. 67: 541-55. PMID 11798329 DOI: 10.1021/Jo016226H |
0.525 |
|
| 2002 |
Ishiyama T, Takagi J, Ishida K, Miyaura N, Anastasi NR, Hartwig JF. Mild iridium-catalyzed borylation of arenes. High turnover numbers, room temperature reactions, and isolation of a potential intermediate. Journal of the American Chemical Society. 124: 390-1. PMID 11792205 DOI: 10.1021/Ja0173019 |
0.846 |
|
| 2002 |
Lee S, Hartwig JF. Improved catalysts for the palladium-catalyzed synthesis of oxindoles by amide alpha-arylation. Rate acceleration, use of aryl chloride substrates, and a new carbene ligand for asymmetric transformations. The Journal of Organic Chemistry. 66: 3402-15. PMID 11348123 DOI: 10.1021/Jo005761Z |
0.505 |
|
| 2002 |
Alcazar-Roman LM, Hartwig JF. Mechanistic studies on oxidative addition of aryl halides and triflates to Pd(BINAP)2 and structural characterization of the product from aryl triflate addition in the presence of amine Organometallics. 21: 491-502. DOI: 10.1021/Om0108088 |
0.823 |
|
| 2002 |
Takagi J, Sato K, Hartwig JF, Ishiyama T, Miyaura N. Iridium-catalyzed C–H coupling reaction of heteroaromatic compounds with bis(pinacolato)diboron: regioselective synthesis of heteroarylboronates Tetrahedron Letters. 43: 5649-5651. DOI: 10.1016/S0040-4039(02)01135-8 |
0.512 |
|
| 2001 |
Alcazar-Roman LM, Hartwig JF. Mechanism of aryl chloride amination: base-induced oxidative addition. Journal of the American Chemical Society. 123: 12905-6. PMID 11749551 DOI: 10.1021/Ja016491K |
0.794 |
|
| 2001 |
Kawamura K, Hartwig JF. Isolated Ir(V) boryl complexes and their reactions with hydrocarbons. Journal of the American Chemical Society. 123: 8422-3. PMID 11516302 DOI: 10.1021/Ja015975D |
0.401 |
|
| 2001 |
Lee S, Beare NA, Hartwig JF. Palladium-catalyzed alpha-arylation of esters and protected amino acids. Journal of the American Chemical Society. 123: 8410-1. PMID 11516296 DOI: 10.1021/Ja016032J |
0.33 |
|
| 2001 |
Lee S, Jørgensen M, Hartwig JF. Palladium-catalyzed synthesis of arylamines from aryl halides and lithium bis(trimethylsilyl)amide as an ammonia equivalent. Organic Letters. 3: 2729-32. PMID 11506620 DOI: 10.1021/Ol016333Y |
0.536 |
|
| 2001 |
Zhao J, Hesslink H, Hartwig JF. Mechanism of beta-hydrogen elimination from square planar iridium(I) alkoxide complexes with labile dative ligands. Journal of the American Chemical Society. 123: 7220-7. PMID 11472149 DOI: 10.1021/Ja010417K |
0.447 |
|
| 2001 |
Stauffer SR, Beare NA, Stambuli JP, Hartwig JF. Palladium-catalyzed arylation of ethyl cyanoacetate. Fluorescence resonance energy transfer as a tool for reaction discovery. Journal of the American Chemical Society. 123: 4641-2. PMID 11457267 DOI: 10.1021/Ja0157402 |
0.723 |
|
| 2001 |
Löber O, Kawatsura M, Hartwig JF. Palladium-catalyzed hydroamination of 1,3-dienes: a colorimetric assay and enantioselective additions. Journal of the American Chemical Society. 123: 4366-7. PMID 11457216 DOI: 10.1021/Ja005881O |
0.472 |
|
| 2001 |
Stambuli JP, Stauffer SR, Shaughnessy KH, Hartwig JF. Screening of homogeneous catalysts by fluorescence resonance energy transfer. Identification of catalysts for room-temperature Heck reactions. Journal of the American Chemical Society. 123: 2677-8. PMID 11456943 DOI: 10.1021/ja0058435 |
0.779 |
|
| 2001 |
Roy AH, Hartwig JF. Reductive elimination of aryl halides from palladium(II). Journal of the American Chemical Society. 123: 1232-3. PMID 11456679 DOI: 10.1021/Ja0034592 |
0.718 |
|
| 2001 |
Culkin DA, Hartwig JF. C-C bond-forming reductive elimination of ketones, esters, and amides from isolated arylpalladium(II) enolates. Journal of the American Chemical Society. 123: 5816-7. PMID 11403622 DOI: 10.1021/Ja015732L |
0.796 |
|
| 2001 |
Kawatsura M, Hartwig JF. Transition Metal-Catalyzed Addition of Amines to Acrylic Acid Derivatives. A High-Throughput Method for Evaluating Hydroamination of Primary and Secondary Alkylamines Organometallics. 20: 1960-1964. DOI: 10.1021/Om0009987 |
0.474 |
|
| 2001 |
Ishiyama T, Hartwig J. ChemInform Abstract: A Heck-Type Reaction Involving Carbon-Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides with N-Pyrazyl Aldimines. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200116114 |
0.35 |
|
| 2001 |
Kawatsura M, Hartwig JF. ChemInform Abstract: Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines. Cheminform. 32: no-no. DOI: 10.1002/CHIN.200104101 |
0.398 |
|
| 2000 |
Stauffer SR, Lee S, Stambuli JP, Hauck SI, Hartwig JF. High turnover number and rapid, room-temperature amination of chloroarenes using saturated carbene ligands. Organic Letters. 2: 1423-6. PMID 10814463 DOI: 10.1021/Ol005751K |
0.769 |
|
| 2000 |
Chen H, Schlecht S, Semple TC, Hartwig JF. Thermal, catalytic, regiospecific functionalization of alkanes Science (New York, N.Y.). 287: 1995-7. PMID 10720320 DOI: 10.1126/Science.287.5460.1995 |
0.474 |
|
| 2000 |
Alcazar-Roman LM, Hartwig JF, Rheingold AL, Liable-Sands LM, Guzei IA. Mechanistic studies of the palladium-catalyzed amination of aryl halides and the oxidative addition of aryl bromides to Pd(BINAP)2 and Pd(DPPF)2: An unusual case of zero-order kinetic behavior and product inhibition Journal of the American Chemical Society. 122: 4618-4630. DOI: 10.1021/Ja9944599 |
0.837 |
|
| 2000 |
Ishiyama T, Hartwig J. A Heck-Type Reaction Involving Carbon−Heteroatom Double Bonds. Rhodium(I)-Catalyzed Coupling of Aryl Halides withN-Pyrazyl Aldimines Journal of the American Chemical Society. 122: 12043-12044. DOI: 10.1021/Ja003306E |
0.475 |
|
| 2000 |
Waltz KM, Hartwig JF. Functionalization of alkanes by isolated transition metal boryl complexes Journal of the American Chemical Society. 122: 11358-11369. DOI: 10.1021/Ja002840J |
0.812 |
|
| 2000 |
Shelby Q, Kataoka N, Mann G, Hartwig J. Unusual in Situ Ligand Modification to Generate a Catalyst for Room Temperature Aromatic C−O Bond Formation Journal of the American Chemical Society. 122: 10718-10719. DOI: 10.1021/Ja002543E |
0.414 |
|
| 2000 |
Kawatsura M, Hartwig JF. Palladium-Catalyzed Intermolecular Hydroamination of Vinylarenes Using Arylamines Journal of the American Chemical Society. 122: 9546-9547. DOI: 10.1021/Ja002284T |
0.537 |
|
| 2000 |
Schlecht S, Hartwig JF. σ-Borane complexes of manganese and rhenium Journal of the American Chemical Society. 122: 9435-9443. DOI: 10.1021/Ja001546O |
0.418 |
|
| 1999 |
Hartwig JF, Kawatsura M, Hauck SI, Shaughnessy KH, Alcazar-Roman LM. Room-Temperature Palladium-Catalyzed Amination of Aryl Bromides and Chlorides and Extended Scope of Aromatic C-N Bond Formation with a Commercial Ligand. The Journal of Organic Chemistry. 64: 5575-5580. PMID 11674624 DOI: 10.1021/Jo990408I |
0.838 |
|
| 1999 |
Chen H, Hartwig JF. Catalytic, Regiospecific End‐Functionalization of Alkanes: Rhenium‐Catalyzed Borylation under Photochemical Conditions Angewandte Chemie. 38: 3391-3393. PMID 10602206 DOI: 10.1002/(Sici)1521-3773(19991115)38:22<3391::Aid-Anie3391>3.0.Co;2-N |
0.472 |
|
| 1999 |
Hartwig JF. Approaches to catalyst discovery. New carbon–heteroatom and carbon–carbon bond formation Pure and Applied Chemistry. 71: 1417-1423. DOI: 10.1351/Pac199971081417 |
0.505 |
|
| 1999 |
Waltz KM, Muhoro CN, Hartwig JF. C−H Activation and Functionalization of Unsaturated Hydrocarbons by Transition-Metal Boryl Complexes Organometallics. 18: 3383-3393. DOI: 10.1021/Om990113V |
0.817 |
|
| 1999 |
Hauck SI, Lakshmi KV, Hartwig JF. Tetraazacyclophanes by Palladium-Catalyzed Aromatic Amination. Geometrically Defined, Stable, High-Spin Diradicals Organic Letters. 1: 2057-2060. DOI: 10.1021/Ol9912276 |
0.345 |
|
| 1999 |
Goodson FE, Hauck SI, Hartwig JF. Palladium-catalyzed synthesis of pure, regiodefined polymeric triarylamines Journal of the American Chemical Society. 121: 7527-7539. DOI: 10.1021/Ja990632P |
0.415 |
|
| 1999 |
Muhoro CN, He X, Hartwig JF. Titanocene Borane σ-Complexes Journal of the American Chemical Society. 121: 5033-5046. DOI: 10.1021/Ja9900757 |
0.447 |
|
| 1999 |
Mann G, Incarvito C, Rheingold AL, Hartwig JF. Palladium-Catalyzed C−O Coupling Involving Unactivated Aryl Halides. Sterically Induced Reductive Elimination To Form the C−O Bond in Diaryl Ethers Journal of the American Chemical Society. 121: 3224-3225. DOI: 10.1021/Ja984321A |
0.54 |
|
| 1999 |
Shaughnessy KH, Kim P, Hartwig JF. A fluorescence-based assay for high-throughput screening of coupling reactions. Application to Heck chemistry Journal of the American Chemical Society. 121: 2123-2132. DOI: 10.1021/Ja983419M |
0.673 |
|
| 1999 |
Kawatsura M, Hartwig JF. Simple, Highly Active Palladium Catalysts for Ketone and Malonate Arylation: Dissecting the Importance of Chelation and Steric Hindrance Journal of the American Chemical Society. 121: 1473-1478. DOI: 10.1021/Ja983378U |
0.531 |
|
| 1998 |
Hartwig JF. Synthesis, Structure, and Reactivity of a Palladium Hydrazonato Complex: A New Type of Reductive Elimination Reaction To Form C-N Bonds and Catalytic Arylation of Benzophenone Hydrazone. Angewandte Chemie (International Ed. in English). 37: 2090-2093. PMID 29711062 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2090::Aid-Anie2090>3.0.Co;2-A |
0.541 |
|
| 1998 |
Hartwig JF. Transition Metal Catalyzed Synthesis of Arylamines and Aryl Ethers from Aryl Halides and Triflates: Scope and Mechanism. Angewandte Chemie (International Ed. in English). 37: 2046-2067. PMID 29711045 DOI: 10.1002/(Sici)1521-3773(19980817)37:15<2046::Aid-Anie2046>3.0.Co;2-L |
0.505 |
|
| 1998 |
Driver MS, Hartwig JF. Oxidative Addition and Reductive Elimination Reactions oftrans-[Ir(PPh3)2(CO)(NC4H4)] andtrans,cis-[Ir(PPh3)2(H)2(CO)(NC4H4)], Including N−H Bond-Forming Reductive Elimination of Pyrrole Organometallics. 17: 1134-1143. DOI: 10.1021/Om971049P |
0.493 |
|
| 1998 |
Louie J, Hartwig JF. The Largest Discrete Oligo(m-aniline). An Exponential Growth Strategy Using Palladium-Catalyzed Amination of Aryl Sulfonates Macromolecules. 31: 6737-6739. DOI: 10.1021/Ma981073U |
0.57 |
|
| 1998 |
Goodson FE, Hartwig JF. Regiodefined Poly(N-arylaniline)s and Donor−Acceptor Copolymers via Palladium-Mediated Amination Chemistry Macromolecules. 31: 1700-1703. DOI: 10.1021/Ma980027R |
0.305 |
|
| 1998 |
Shaughnessy KH, Hamann BC, Hartwig JF. Palladium-Catalyzed Inter- and Intramolecular α-Arylation of Amides. Application of Intramolecular Amide Arylation to the Synthesis of Oxindoles The Journal of Organic Chemistry. 63: 6546-6553. DOI: 10.1021/Jo980611Y |
0.742 |
|
| 1998 |
Hamann BC, Hartwig JF. Sterically Hindered Chelating Alkyl Phosphines Provide Large Rate Accelerations in Palladium-Catalyzed Amination of Aryl Iodides, Bromides, and Chlorides, and the First Amination of Aryl TosylatesJ. Am. Chem. Soc.1998,120, 7369−7370 Journal of the American Chemical Society. 120: 12706-12706. DOI: 10.1021/Ja985527E |
0.482 |
|
| 1998 |
Mann G, Baranano D, Hartwig JF, Rheingold AL, Guzei IA. Carbon−Sulfur Bond-Forming Reductive Elimination Involving sp-, sp2-, and sp3-Hybridized Carbon. Mechanism, Steric Effects, and Electronic Effects on Sulfide Formation Journal of the American Chemical Society. 120: 9205-9219. DOI: 10.1021/Ja981428P |
0.49 |
|
| 1998 |
Hamann BC, Hartwig JF. Sterically hindered chelating alkyl phosphines provide large rate accelerations in palladium-catalyzed amination of aryl iodides, bromides, and chlorides, and the first amination of aryl tosylates [12] Journal of the American Chemical Society. 120: 7369-7370. DOI: 10.1021/Ja981318I |
0.517 |
|
| 1998 |
Mann G, Hartwig JF, Driver MS, Fernández-Rivas C. Palladium-Catalyzed C−N(sp2) Bond Formation: N-Arylation of Aromatic and Unsaturated Nitrogen and the Reductive Elimination Chemistry of Palladium Azolyl and Methyleneamido Complexes Journal of the American Chemical Society. 120: 827-828. DOI: 10.1021/Ja973524G |
0.483 |
|
| 1998 |
Hamann BC, Hartwig JF. Systematic variation of bidentate ligands used in aryl halide amination. Unexpected effects of steric, electronic, and geometric perturbations Journal of the American Chemical Society. 120: 3694-3703. DOI: 10.1021/Ja9721881 |
0.433 |
|
| 1998 |
Hartwig JF. Carbon−Heteroatom Bond-Forming Reductive Eliminations of Amines, Ethers, and Sulfides Accounts of Chemical Research. 31: 852-860. DOI: 10.1021/Ar970282G |
0.397 |
|
| 1998 |
Hartwig JF. Synthese, Struktur und Reaktionen eines Palladium-Hydrazonatokomplexes – neuartige reduktive Eliminierung unter Knüpfung von C-N-Bindungen sowie katalytische Arylierung von Benzophenonhydrazon Angewandte Chemie. 110: 2249-2252. DOI: 10.1002/(Sici)1521-3757(19980803)110:15<2249::Aid-Ange2249>3.0.Co;2-F |
0.324 |
|
| 1998 |
Hartwig JF. Übergangsmetall-katalysierte Synthese von Arylaminen und Arylethern aus Arylhalogeniden und -triflaten: Anwendungen und Reaktionsmechanismus Angewandte Chemie. 110: 2154-2177. DOI: 10.1002/(Sici)1521-3757(19980803)110:15<2154::Aid-Ange2154>3.0.Co;2-C |
0.366 |
|
| 1997 |
Waltz KM, Hartwig JF. Selective functionalization of alkanes by transition-metal boryl complexes Science. 277: 211-213. DOI: 10.1126/Science.277.5323.211 |
0.826 |
|
| 1997 |
Hartwig J. Palladium-Catalyzed Amination of Aryl Halides: Mechanism and Rational Catalyst Design Synlett. 1997: 329-340. DOI: 10.1055/S-1997-789 |
0.554 |
|
| 1997 |
Driver MS, Hartwig JF. Energetics and Mechanism of Alkylamine N−H Bond Cleavage by Palladium Hydroxides: N−H Activation by Unusual Acid−Base Chemistry Organometallics. 16: 5706-5715. DOI: 10.1021/Om970856L |
0.506 |
|
| 1997 |
Mann G, Hartwig JF. Nickel- vs Palladium-Catalyzed Synthesis of Protected Phenols from Aryl Halides The Journal of Organic Chemistry. 62: 5413-5418. DOI: 10.1021/Jo970453V |
0.556 |
|
| 1997 |
Louie J, Driver MS, Hamann BC, Hartwig JF. Palladium-Catalyzed Amination of Aryl Triflates and Importance of Triflate Addition Rate The Journal of Organic Chemistry. 62: 1268-1273. DOI: 10.1021/Jo961930X |
0.68 |
|
| 1997 |
Louie J, Hartwig JF, Fry AF. Discrete high molecular weight triarylamine dendrimers prepared by palladium-catalyzed amination Journal of the American Chemical Society. 119: 11695-11696. DOI: 10.1021/Ja972806D |
0.558 |
|
| 1997 |
Hamann BC, Hartwig JF. Palladium-Catalyzed Direct α-Arylation of Ketones. Rate Acceleration by Sterically Hindered Chelating Ligands and Reductive Elimination from a Transition Metal Enolate Complex Journal of the American Chemical Society. 119: 12382-12383. DOI: 10.1021/Ja9727880 |
0.434 |
|
| 1997 |
Driver MS, Hartwig JF. Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes Journal of the American Chemical Society. 119: 8232-8245. DOI: 10.1021/Ja971057X |
0.453 |
|
| 1997 |
Mann G, Hartwig JF. Palladium-Catalyzed Formation of Diaryl Ethers from Aryl Bromides. Electron Poor Phosphines enhance Reaction Yields Tetrahedron Letters. 38: 8005-8008. DOI: 10.1016/S0040-4039(97)10175-7 |
0.481 |
|
| 1996 |
Hartwig JF, He X. Structural and Reaction Chemistry of Tungstenocene Boryl Complexes Organometallics. 15: 5350-5358. DOI: 10.1021/Om9606303 |
0.444 |
|
| 1996 |
Louie J, Paul F, Hartwig JF. Catalysis with Platinum-Group Alkylamido Complexes. The Active Palladium Amide in Catalytic Aryl Halide Aminations As Deduced from Kinetic Data and Independent Generation Organometallics. 15: 2794-2805. DOI: 10.1021/Om960188O |
0.493 |
|
| 1996 |
He X, Hartwig JF. Boryls Bound to Iron Carbonyl. Structure of a Rare Bis(boryl) Complex, Synthesis of the First Anionic Boryl, and Reaction Chemistry That Includes the Synthetic Equivalent of Boryl Anion Transfer Organometallics. 15: 400-407. DOI: 10.1021/Om950437T |
0.487 |
|
| 1996 |
Mann G, Hartwig JF. Palladium Alkoxides: Potential Intermediacy in Catalytic Amination, Reductive Elimination of Ethers, and Catalytic Etheration. Comments on Alcohol Elimination from Ir(III) Journal of the American Chemical Society. 118: 13109-13110. DOI: 10.1021/Ja963273W |
0.385 |
|
| 1996 |
Hartwig JF, Muhoro CN, He X, Eisenstein O, Bosque R, Maseras F. Catecholborane bound to titanocene. Unusual coordination of ligand σ-bonds Journal of the American Chemical Society. 118: 10936-10937. DOI: 10.1021/Ja962086V |
0.348 |
|
| 1996 |
Hartwig JF. Directly-Observed β-Hydrogen Elimination of a Late Transition Metal Amido Complex and Unusual Fate of Imine Byproducts Journal of the American Chemical Society. 118: 7010-7011. DOI: 10.1021/Ja961439N |
0.328 |
|
| 1996 |
Driver MS, Hartwig JF. A Second-Generation Catalyst for Aryl Halide Amination: Mixed Secondary Amines from Aryl Halides and Primary Amines Catalyzed by (DPPF)PdCl2 Journal of the American Chemical Society. 118: 7217-7218. DOI: 10.1021/Ja960937T |
0.469 |
|
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