John E. Bercaw - Publications

Affiliations: 
California Institute of Technology, Pasadena, CA 
Area:
organotransition metal chemistry
Website:
http://www.cce.caltech.edu/content/john-e-bercaw

206 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Panchenko VN, Babushkin DE, Bercaw JE, Brintzinger HH. Catalyst Speciation During -Zirconocene-Catalyzed Polymerization of 1-Hexene Studied by UV-vis Spectroscopy-Formation and Partial Re-Activation of Zr-Allyl Intermediates. Polymers. 11. PMID 31146475 DOI: 10.3390/polym11060936  1
2016 Sattler A, Aluthge DC, Winkler JR, Labinger JA, Bercaw JE. Enhanced Productivity of a Supported Olefin Trimerization Catalyst Acs Catalysis. 6: 19-22. DOI: 10.1021/acscatal.5b02604  1
2015 Despagnet-Ayoub E, Takase MK, Labinger JA, Bercaw JE. Reversible 1,2-Alkyl Migration to Carbene and Ammonia Activation in an N-Heterocyclic Carbene-Zirconium Complex. Journal of the American Chemical Society. PMID 26251373 DOI: 10.1021/jacs.5b06695  1
2015 Mindiola DJ, Smith MR, Bercaw JE. Gregory L. Hillhouse: His Life, His Art, His Science, and the Rise of "double Nickel" Organometallics. 34: 4633-4636. DOI: 10.1021/acs.organomet.5b00527  1
2015 Despagnet-Ayoub E, Takase MK, Henling LM, Labinger JA, Bercaw JE. Mechanistic insights on the controlled switch from oligomerization to polymerization of 1-hexene catalyzed by an NHC-zirconium complex Organometallics. 34: 4707-4716. DOI: 10.1021/acs.organomet.5b00472  1
2015 Labinger JA, Leitch DC, Bercaw JE, Deimund MA, Davis ME. Upgrading Light Hydrocarbons: A Tandem Catalytic System for Alkane/Alkene Coupling Topics in Catalysis. 58: 494-501. DOI: 10.1007/s11244-015-0380-2  1
2014 Sattler A, VanderVelde DG, Labinger JA, Bercaw JE. Lewis acid promoted titanium alkylidene formation: off-cycle intermediates relevant to olefin trimerization catalysis. Journal of the American Chemical Society. 136: 10790-800. PMID 25007394 DOI: 10.1021/ja5055687  1
2014 Teets TS, Labinger JA, Bercaw JE. Guanidine-functionalized rhenium cyclopentadienyl carbonyl complexes: Synthesis and cooperative activation of H-H and O-H bonds Organometallics. 33: 4107-4117. DOI: 10.1021/om500650b  1
2014 Leitch DC, Labinger JA, Bercaw JE. Scope and mechanism of homogeneous tantalum/iridium tandem catalytic alkane/alkene upgrading using sacrificial hydrogen acceptors Organometallics. 33: 3353-3365. DOI: 10.1021/om500231t  1
2014 Klet RC, Theriault CN, Klosin J, Labinger JA, Bercaw JE. Investigations into asymmetric post-metallocene group 4 complexes for the synthesis of highly regioirregular polypropylene Macromolecules. 47: 3317-3324. DOI: 10.1021/ma500453t  1
2014 Labinger JA, Bercaw JE. Mechanistic studies on the Shilov system: A retrospective Journal of Organometallic Chemistry. DOI: 10.1016/j.jorganchem.2015.01.027  1
2014 Winston MS, Bercaw JE. Palladium(II) complexes supported by a bidentate bis(secondary)phosphine linked by pyridine Inorganica Chimica Acta. 422: 30-35. DOI: 10.1016/j.ica.2014.08.002  1
2014 Shin JH, Churchill DG, Parkin G, Roggan S, Jankowski C, Limberg C, Tonks I, Bercaw J. Bis(η5-Pentamethylcyclopentadienyl) Complexes of Molybdenum Inorganic Syntheses. 36: 58-62. DOI: 10.1002/9781118744994.ch12  1
2014 Min EYJ, Bercaw JE, Bernskoetter W, Chirik PJ. Bis(η5-Pentamethylcyclopentadienyl) Complexes of Titanium, Zirconium, and Hafnium Inorganic Syntheses. 36: 47-51. DOI: 10.1002/9781118744994.ch10  1
2014 Min EYJ, Bercaw JE, Kenward AL, Piers W. Bis(η5-Pentamethylcyclopentadienyl) Complexes of Scandium Inorganic Syntheses. 36: 42-46. DOI: 10.1002/9781118744994.ch09  1
2013 Do LH, Labinger JA, Bercaw JE. Spectral studies of a Cr(PNP)-MAO system for selective ethylene trimerization catalysis: searching for the active species. Acs Catalysis. 3. PMID 24327931 DOI: 10.1021/cs400778a  1
2013 Despagnet-Ayoub E, Henling LM, Labinger JA, Bercaw JE. Addition of a phosphine ligand switches an N-heterocyclic carbene-zirconium catalyst from oligomerization to polymerization of 1-hexene. Dalton Transactions (Cambridge, England : 2003). 42: 15544-7. PMID 24061616 DOI: 10.1039/c3dt52342j  1
2013 Leitch DC, Lam YC, Labinger JA, Bercaw JE. Upgrading light hydrocarbons via tandem catalysis: a dual homogeneous Ta/Ir system for alkane/alkene coupling. Journal of the American Chemical Society. 135: 10302-5. PMID 23799786 DOI: 10.1021/ja405191a  1
2013 Appel AM, Bercaw JE, Bocarsly AB, Dobbek H, DuBois DL, Dupuis M, Ferry JG, Fujita E, Hille R, Kenis PJ, Kerfeld CA, Morris RH, Peden CH, Portis AR, Ragsdale SW, et al. Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation. Chemical Reviews. 113: 6621-58. PMID 23767781 DOI: 10.1021/cr300463y  1
2013 Lenton TN, Bercaw JE, Panchenko VN, Zakharov VA, Babushkin DE, Soshnikov IE, Talsi EP, Brintzinger HH. Formation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: an EPR- and NMR-spectroscopic study. Journal of the American Chemical Society. 135: 10710-9. PMID 23745750 DOI: 10.1021/ja403170u  1
2013 Despagnet-Ayoub E, Miqueu K, Sotiropoulos JM, Henling LM, Day MW, Labinger JA, Bercaw JE. Unexpected rearrangements in the synthesis of an unsymmetrical tridentate dianionic N-heterocyclic carbene Chemical Science. 4: 2117-2121. DOI: 10.1039/c3sc22171g  1
2013 Sattler A, Labinger JA, Bercaw JE. Highly selective olefin trimerization catalysis by a borane-activated titanium trimethyl complex Organometallics. 32: 6899-6902. DOI: 10.1021/om401098m  1
2013 Teets TS, Labinger JA, Bercaw JE. A thermodynamic analysis of rhenium(I)-Formyl C-H bond formation via base-assisted heterolytic H2 cleavage in the secondary coordination sphere Organometallics. 32: 5530-5545. DOI: 10.1021/om400810v  1
2013 Ahmed TS, Tonks IA, Labinger JA, Bercaw JE. Kinetics and mechanism of indene C-H bond activation by [(COD)Ir(μ2-OH)]2 Organometallics. 32: 3322-3326. DOI: 10.1021/om400230j  1
2013 Despagnet-Ayoub E, Henling LM, Labinger JA, Bercaw JE. Group 4 transition-metal complexes of an aniline-carbene-phenol ligand Organometallics. 32: 2934-2938. DOI: 10.1021/om4001567  1
2013 Tonks IA, Meier JC, Bercaw JE. Alkyne hydroamination and trimerization with titanium bis(phenolate) pyridine complexes: Evidence for low-valent titanium intermediates and synthesis of an ethylene adduct of titanium(II) Organometallics. 32: 3451-3457. DOI: 10.1021/om400080g  1
2013 Kamal MS, Bahuleyan BK, Sohail OB, Emwas AHM, Bercaw JE, Al-Harthi MA. Crystallization analysis fractionation of poly(ethylene-co-styrene) produced by metallocene catalysts Polymer Bulletin. 70: 2645-2656. DOI: 10.1007/s00289-013-0980-6  1
2012 Winston MS, Oblad PF, Labinger JA, Bercaw JE. Activator-free olefin oligomerization and isomerization reactions catalyzed by an air- and water-tolerant Wacker oxidation intermediate. Angewandte Chemie (International Ed. in English). 51: 9822-4. PMID 22945030 DOI: 10.1002/anie.201206215  1
2012 Do LH, Labinger JA, Bercaw JE. Mechanistic Studies of Ethylene and α-Olefin Co-oligomerization Catalyzed by Chromium-PNP Complexes. Organometallics. 31: 5143-5149. PMID 22904593 DOI: 10.1021/om300492r  1
2012 Hazari A, Labinger JA, Bercaw JE. A versatile ligand platform that supports Lewis acid promoted migratory insertion. Angewandte Chemie (International Ed. in English). 51: 8268-71. PMID 22778013 DOI: 10.1002/anie.201203264  1
2012 Klet RC, VanderVelde DG, Labinger JA, Bercaw JE. Highly regioirregular polypropylene from asymmetric group 4 anilide(pyridine)phenoxide complexes. Chemical Communications (Cambridge, England). 48: 6657-9. PMID 22635202 DOI: 10.1039/c2cc32806b  1
2012 Tonks IA, Durrell AC, Gray HB, Bercaw JE. Groups 5 and 6 terminal hydrazido(2-) complexes: N(β) substituent effects on ligand-to-metal charge-transfer energies and oxidation states. Journal of the American Chemical Society. 134: 7301-4. PMID 22506581 DOI: 10.1021/ja302275j  1
2012 Lenton TN, Vandervelde DG, Bercaw JE. Synthesis of a bis(thiophenolate)pyridine ligand and its titanium, zirconium, and tantalum complexes Organometallics. 31: 7492-7499. DOI: 10.1021/om300789h  1
2012 Klet RC, Labinger JA, Bercaw JE. Diverse C-C bond-forming reactions of bis(carbene)platinum(II) complexes Organometallics. 31: 6652-6657. DOI: 10.1021/om300733h  1
2012 Tonks IA, Tofan D, Weintrob EC, Agapie T, Bercaw JE. Zirconium and titanium propylene polymerization precatalysts supported by a fluxional C 2-symmetric bis(anilide)pyridine ligand Organometallics. 31: 1965-1974. DOI: 10.1021/om201262h  1
2012 Atiqullah M, Winston MS, Bercaw JE, Hussain I, Fazal A, Al-Harthi MA, Emwas AHM, Khan MJ, Hossaen A. Effects of a vanadium post-metallocene catalyst-induced polymer backbone inhomogeneity on UV oxidative degradation of the resulting polyethylene film Polymer Degradation and Stability. 97: 1164-1177. DOI: 10.1016/j.polymdegradstab.2012.03.042  1
2011 Miller AJ, Labinger JA, Bercaw JE. Trialkylborane-Assisted CO(2) Reduction by Late Transition Metal Hydrides. Organometallics. 30: 4308-4314. PMID 21909178 DOI: 10.1021/om200364w  1
2011 Baldwin SM, Bercaw JE, Henling LM, Day MW, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides: NMR-spectroscopic identification, crystallographic structure determination, and interconversion with other zirconocene cations. Journal of the American Chemical Society. 133: 1805-13. PMID 21244016 DOI: 10.1021/ja1050428  1
2011 Fu R, Bercaw JE, Labinger JA. Intra- and intermolecular C-H activation by bis(phenolate) pyridineiridium(III) complexes Organometallics. 30: 6751-6765. DOI: 10.1021/om201069k  1
2011 Scott VJ, Labinger JA, Bercaw JE. Large kinetic isotope effects for the protonolysis of metal-methyl complexes are not reliable mechanistic indicators Organometallics. 30: 4374-4378. DOI: 10.1021/om200432b  1
2011 West NM, Labinger JA, Bercaw JE. Heterobimetallic complexes of rhenium and zinc: Potential catalysts for homogeneous syngas conversion Organometallics. 30: 2690-2700. DOI: 10.1021/om200051u  1
2011 West NM, Miller AJM, Labinger JA, Bercaw JE. Homogeneous syngas conversion Coordination Chemistry Reviews. 255: 881-898. DOI: 10.1016/j.ccr.2010.08.019  1
2011 Labinger JA, Bercaw JE. The role of higher oxidation state species in platinum-mediated C-H bond activation and functionalization Topics in Organometallic Chemistry. 503: 29-60. DOI: 10.1007/978-3-642-17429-2_2  1
2011 Bercaw JE. Mechanistic aspects of homogeneously-catalyzed hydrocarbon oxidation with platinum and palladium complexes Acs National Meeting Book of Abstracts 1
2011 West NM, Labinger JA, Bercaw JE. Heterobimetallic complexes of Re and Zn as potential catalysts in a homogeneous syngas conversion scheme Acs National Meeting Book of Abstracts 1
2011 Bercaw J. Homogeneous catalytic approaches to reductive coupling of carbon monoxide Acs National Meeting Book of Abstracts 1
2010 Baldwin SM, Bercaw JE, Brintzinger HH. Cationic alkylaluminum-complexed zirconocene hydrides as participants in olefin polymerization catalysis. Journal of the American Chemical Society. 132: 13969-71. PMID 20860389 DOI: 10.1021/ja105040r  1
2010 Tonks IA, Bercaw JE. (dme)MCl3(NNPh2) (dme = dimethoxyethane; M = Nb, Ta): a versatile synthon for [Ta=NNPh2] hydrazido(2-) complexes. Inorganic Chemistry. 49: 4648-56. PMID 20402474 DOI: 10.1021/ic1004193  1
2010 Wilson AD, Miller AJ, Dubois DL, Labinger JA, Bercaw JE. Thermodynamic studies of [H(2)Rh(diphosphine)(2)](+) and [HRh(diphosphine)(2)(CH(3)CN)](2+) complexes in acetonitrile. Inorganic Chemistry. 49: 3918-26. PMID 20334390 DOI: 10.1021/ic100117y  1
2010 Miller AJ, Labinger JA, Bercaw JE. Homogeneous CO hydrogenation: dihydrogen activation involves a frustrated Lewis pair instead of a platinum complex. Journal of the American Chemical Society. 132: 3301-3. PMID 20178359 DOI: 10.1021/ja100574n  1
2010 Miller AJ, Bercaw JE. Dehydrogenation of amine-boranes with a frustrated Lewis pair. Chemical Communications (Cambridge, England). 46: 1709-11. PMID 20177624 DOI: 10.1039/b925659h  1
2010 Bercaw JE, Durrell AC, Gray HB, Green JC, Hazari N, Labinger JA, Winkler JR. Electronic structures of Pd(II) dimers. Inorganic Chemistry. 49: 1801-10. PMID 20092286 DOI: 10.1021/ic902189g  1
2010 Weinberg DR, Hazari N, Labinger JA, Bercaw JE. Iridium(I) and iridium (III) complexes supported by a diphenolate imidazolyl-carbene ligand Organometallics. 29: 89-100. DOI: 10.1021/om900803r  1
2010 Oblad PF, Bercaw JE, Hazari N, Labinger JA. Oxidation of organometallic Platinum and Palladium complexes obtained from C-H activation Organometallics. 29: 789-794. DOI: 10.1021/om900678z  1
2010 Winston MS, Bercaw JE. A novel bis(phosphido)pyridine [PNP]2- pincer ligand and its potassium and bis(dimethylamido)zirconium(IV) complexes Organometallics. 29: 6408-6416. DOI: 10.1021/om100775g  1
2010 Scott VJ, Labinger JA, Bercaw JE. Mechanism of reductive elimination of methyl iodide from a novel gold(III)-monomethyl complex Organometallics. 29: 4090-4096. DOI: 10.1021/om1006566  1
2010 Bercaw JE, Chen GS, Labinger JA, Lin BL. Protonolysis of platinum(II) and palladium(II) methyl complexes: A combined experimental and theoretical investigation Organometallics. 29: 4354-4359. DOI: 10.1021/om100655w  1
2010 Miller AJM, Labinger JA, Bercaw JE. Homogeneous CO hydrogenation: Ligand effects on the lewis acid-assisted reductive coupling of carbon monoxide Organometallics. 29: 4499-4516. DOI: 10.1021/om100638d  1
2010 Golisz SR, Labinger JA, Bercaw JE. Intramolecular C-H activation of a bisphenolate(benzene)-ligated titanium dibenzyl complex. competing pathways involving α-hydrogen abstraction and σ-bond metathesis Organometallics. 29: 5026-5032. DOI: 10.1021/om100253u  1
2010 Fulmer GR, Miller AJM, Sherden NH, Gottlieb HE, Nudelman A, Stoltz BM, Bercaw JE, Goldberg KI. NMR chemical shifts of trace impurities: Common laboratory solvents, organics, and gases in deuterated solvents relevant to the organometallic chemist Organometallics. 29: 2176-2179. DOI: 10.1021/om100106e  1
2009 Golisz SR, Hazari N, Labinger JA, Bercaw JE. Activation of the C-N bond in nitromethane by palladium alpha-diimine complexes. The Journal of Organic Chemistry. 74: 8441-3. PMID 19799410 DOI: 10.1021/jo901635g  1
2009 Tonks IA, Henling LM, Day MW, Bercaw JE. Amine, amido, and imido complexes of tantalum supported by a pyridine-linked bis(phenolate) pincer ligand: Ta-N pi-bonding influences pincer ligand geometry. Inorganic Chemistry. 48: 5096-105. PMID 19422195 DOI: 10.1021/ic802234x  1
2009 Weintrob EC, Tofan D, Bercaw JE. Synthesis and characterization of iron derivatives having a pyridine-linked bis(anilide) pincer ligand. Inorganic Chemistry. 48: 3808-13. PMID 19301916 DOI: 10.1021/ic900083s  1
2009 Lin BL, Labinger JA, Bercaw JE. Mechanistic investigations of bipyrimidine-promoted palladium-catalyzed allylic acetoxylation of olefins Canadian Journal of Chemistry. 87: 264-271. DOI: 10.1139/V08-133  1
2009 Elowe PR, West NM, Labinger JA, Bercaw JE. Transformations of group 7 carbonyl complexes: Possible intermediates in a homogeneous syngas conversion scheme Organometallics. 28: 6218-6227. DOI: 10.1021/om900804j  1
2009 Bercaw JE, Hazari N, Labinger JA. Activation of a C - H bond in indene by [(COD)Rh(μ 2-OH)] 2 Organometallics. 28: 5489-5492. DOI: 10.1021/om9004498  1
2009 Chen GS, Labinger JA, Bercaw JE. Selective oxidation of sp3 C-H bonds in water catalyzed by a glycinate-platinum(II) complex Organometallics. 28: 4899-4901. DOI: 10.1021/om900267w  1
2009 Scott VJ, Henling LM, Day MW, Bercaw JE, Labinger JA. Competitive activation of a methyl C-H bond of dimethylformamide at an iridium center Organometallics. 28: 4229-4230. DOI: 10.1021/om9002413  1
2009 Bercaw JE, Day MW, Golisz SR, Hazari N, Henling LM, Labinger JA, Schofer SJ, Virgil S. Robotic lepidoptery: Structural characterization of (mostly) unexpected palladium complexes obtained from high-throughput catalyst screening Organometallics. 28: 5017-5024. DOI: 10.1021/om900240a  1
2009 Lin B, Bhattacharyya KX, Labinger JA, Bercaw JE. Competitive benzene c-h bond activation versus olefin insertion in a (monomethyl)palladium(ii) &beta-diketiminate complex Organometallics. 28: 4400-4405. DOI: 10.1021/om900171d  1
2009 Golisz SR, Bercaw JE. Synthesis of early transition metal bisphenolate complexes and their use as olefin polymerization catalysts Macromolecules. 42: 8751-8762. DOI: 10.1021/ma901659q  1
2008 Bercaw JE, Chen GS, Labinger JA, Lin BL. Hydrogen tunneling in protonolysis of platinum(II) and palladium(II) methyl complexes: mechanistic implications. Journal of the American Chemical Society. 130: 17654-5. PMID 19055356 DOI: 10.1021/ja807427d  1
2008 Baldwin SM, Bercaw JE, Brintzinger HH. Alkylaluminum-complexed zirconocene hydrides: identification of hydride-bridged species by NMR spectroscopy. Journal of the American Chemical Society. 130: 17423-33. PMID 19032092 DOI: 10.1021/ja8054723  1
2008 Bercaw JE, Hazari N, Labinger JA, Oblad PF. C-H bond activation by [{(diimine)Pd(mu-OH)}2]2+ dimers: mechanism-guided catalytic improvement. Angewandte Chemie (International Ed. in English). 47: 9941-3. PMID 19006139 DOI: 10.1002/anie.200804455  1
2008 Bercaw JE, Hazari N, Labinger JA. Oxidative aromatization of olefins with dioxygen catalyzed by palladium trifluoroacetate. The Journal of Organic Chemistry. 73: 8654-7. PMID 18821804 DOI: 10.1021/jo8016296  1
2008 Miller AJ, Labinger JA, Bercaw JE. Reductive coupling of carbon monoxide in a rhenium carbonyl complex with pendant Lewis acids. Journal of the American Chemical Society. 130: 11874-5. PMID 18702489 DOI: 10.1021/ja805108z  1
2008 Bercaw JE, Hazari N, Labinger JA, Scott VJ, Sunley GJ. Selective methylative homologation: an alternate route to alkane upgrading. Journal of the American Chemical Society. 130: 11988-95. PMID 18698767 DOI: 10.1021/ja803029s  1
2008 Williams TJ, Caffyn AJ, Hazari N, Oblad PF, Labinger JA, Bercaw JE. C-H bond activation by air-stable [(diimine)M(II)(mu2-OH)]2(2+) dimers (M = Pd, Pt). Journal of the American Chemical Society. 130: 2418-9. PMID 18237167 DOI: 10.1021/ja076740q  1
2008 Agapie T, Day MW, Bercaw JE. Synthesis and reactivity of tantalum complexes supported by bidentate X2 and tridentate LX2 ligands with two phenolates linked to pyridine, thiophene, furan, and benzene connectors: Mechanistic studies of the formation of a tantalum benzylidene and insertion chemistry for tantalum-carbon bonds Organometallics. 27: 6123-6142. DOI: 10.1021/om8002653  1
2008 Agapie T, Henling LM, DiPasquale AG, Rheingold AL, Bercaw JE. Zirconium and titanium complexes supported by tridentate LX2 ligands having two phenolates linked to furan, thiophene, and pyridine donors: Precatalysts for propylene polymerization and oligomerization Organometallics. 27: 6245-6256. DOI: 10.1021/om800136y  1
2008 Min EYJ, Byers JA, Bercaw JE. Catalyst site epimerization during the kinetic resolution of chiral α-olefins by polymerization Organometallics. 27: 2179-2188. DOI: 10.1021/om700778e  1
2008 Moss JR, Ngubane S, Sivaramakrishna A, Makhubela BCE, Bercaw JE, Labinger JA, Day MW, Henling LM, Su H. C-H activation of benzene with Cp*Ru(CO)2CH3 Journal of Organometallic Chemistry. 693: 2700-2702. DOI: 10.1016/j.jorganchem.2008.05.013  1
2008 Miller AJM, Labinger JA, Bercaw JE. Reductive coupling of two CO's from metal carbonyl complexes with pendant Lewis acids Acs National Meeting Book of Abstracts 1
2008 Bercaw JE, Hazari N, Williams TJ, Caffyn AJM, Oblad PF, Labinger JA. Carbon-hydrogen bond activation with platinum and palladium complexes Acs National Meeting Book of Abstracts 1
2007 Williams TJ, Labinger JA, Bercaw JE. Reactions of Indene and Indoles with Platinum Methyl Cations: Indene C-H Activation, Indole π vs. Nitrogen Lone-Pair Coordination. Organometallics. 26: 281-287. PMID 27087735 DOI: 10.1021/om0606643  1
2007 Bercaw JE, Diaconescu PL, Grubbs RH, Hazari N, Kay RD, Labinger JA, Mehrkhodavandi P, Morris GE, Sunley GJ, Vagner P. Conversion of methanol to 2,2,3-trimethylbutane (triptane) over indium(III) iodide. Inorganic Chemistry. 46: 11371-80. PMID 18047325 DOI: 10.1021/ic7014447  1
2007 Agapie T, Labinger JA, Bercaw JE. Mechanistic studies of olefin and alkyne trimerization with chromium catalysts: deuterium labeling and studies of regiochemistry using a model chromacyclopentane complex. Journal of the American Chemical Society. 129: 14281-95. PMID 17973377 DOI: 10.1021/ja073493h  1
2007 Bercaw JE, Grubbs RH, Hazari N, Labinger JA, Li X. Enhanced selectivity in the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide by added phosphorous or hypophosphorous acid. Chemical Communications (Cambridge, England). 2974-6. PMID 17622449 DOI: 10.1039/b705470j  1
2007 Bercaw JE, Labinger JA. The coordination chemistry of saturated molecules. Proceedings of the National Academy of Sciences of the United States of America. 104: 6899-900. PMID 17456607 DOI: 10.1073/pnas.0700902104  1
2007 Chen GS, Labinger JA, Bercaw JE. The role of alkane coordination in C-H bond cleavage at a Pt(II) center. Proceedings of the National Academy of Sciences of the United States of America. 104: 6915-20. PMID 17416678 DOI: 10.1073/pnas.0610981104  1
2007 Agapie T, Bercaw JE. Cyclometalated tantalum diphenolate pincer complexes: Intramolecular C-H/M-CH3 σ-Bond metathesis may be faster than O-H/M-CH 3 protonolysis Organometallics. 26: 2957-2959. DOI: 10.1021/om700284c  1
2007 Marinescu SC, Agapie T, Day MW, Bercaw JE. Group 3 dialkyl complexes with tetradentate (L, L, N, O; L = N, O, S) monoanionic ligands: Synthesis and reactivity Organometallics. 26: 1178-1190. DOI: 10.1021/om0608612  1
2007 Driver TG, Williams TJ, Labinger JA, Bercaw JE. C-H bond activation by dicationic platinum(II) complexes Organometallics. 26: 294-301. DOI: 10.1021/om060792r  1
2007 Weinberg DR, Labinger JA, Bercaw JE. Competitive oxidation and protonation of aqueous monomethylplatinum(II) complexes: A comparison of oxidants Organometallics. 26: 167-172. DOI: 10.1021/om060763g  1
2007 Williams TJ, Labinger JA, Bercaw JE. Reactions of indene and indoles with platinum methyl cations: Indene C-H activation, indole π versus nitrogen lone-pair coordination Organometallics. 26: 281-287. DOI: 10.1021/om0606643  1
2007 Klamo SB, Wendt OF, Henling LM, Day MW, Bercaw JE. Dialkyl and methyl-alkyl zirconocenes: Synthesis and characterization of zirconocene-alkyls that model the polymeryl chain in alkene polymerizations Organometallics. 26: 3018-3030. DOI: 10.1021/om0601302  1
2007 Bercaw JE, Diaconescu PL, Grubbs RH, Hazari N, Labinger JA, Li X, Mehrkhodavandi P, Vagner P. Metal iodide catalyzed conversion of methanol to hydrocarbons Acs National Meeting Book of Abstracts 1
2006 Bercaw JE, Diaconescu PL, Grubbs RH, Kay RD, Kitching S, Labinger JA, Li X, Mehrkhodavandi P, Morris GE, Sunley GJ, Vagner P. On the mechanism of the conversion of methanol to 2,2,3-trimethylbutane (triptane) over zinc iodide. The Journal of Organic Chemistry. 71: 8907-17. PMID 17081022 DOI: 10.1021/jo0617823  1
2006 Byers JA, Bercaw JE. Kinetic resolution of racemic alpha-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control. Proceedings of the National Academy of Sciences of the United States of America. 103: 15303-8. PMID 17032768 DOI: 10.1073/pnas.0603071103  1
2006 Owen JS, Labinger JA, Bercaw JE. Kinetics and mechanism of methane, methanol, and dimethyl ether C-H activation with electrophilic platinum complexes. Journal of the American Chemical Society. 128: 2005-16. PMID 16464102 DOI: 10.1021/ja056387t  1
2006 Elowe PR, McCann C, Pringle PG, Spitzmesser SK, Bercaw JE. Nitrogen-linked diphosphine ligands with ethers attached to nitrogen for chromium-catalyzed ethylene tri- And tetramerizations Organometallics. 25: 5255-5260. DOI: 10.1021/om0601596  1
2006 Lersch M, Dalhus B, Bercaw JE, Labinger J, Tilset M. Improved one-pot synthesis of mixed methyl - aryl platinum(II) diimine complexes Organometallics. 25: 1055-1058. DOI: 10.1021/om050899z  1
2006 Miller SA, Bercaw JE. Mechanism of isotactic polypropylene formation with C 1-symmetric metallocene catalysts Organometallics. 25: 3576-3592. DOI: 10.1021/om050841k  1
2006 Schofer SJ, Day MW, Henling LM, Labinger JA, Bercaw JE. Ethylene trimerization catalysts based on chromium complexes with a nitrogen-bridged diphosphine ligand having ortho-methoxyaryl or ortho-thiomethoxy substituents: Well-defined catalyst precursors and investigations of the mechanism Organometallics. 25: 2743-2749. DOI: 10.1021/om0506062  1
2006 Agapie T, Day MW, Henling LM, Labinger JA, Bercaw JE. A chromium-diphosphine system for catalytic ethylene trimerization: Synthetic and structural studies of chromium complexes with a nitrogen-bridged diphosphine ligand with ortho-methoxyaryl substituents Organometallics. 25: 2733-2742. DOI: 10.1021/om050605+  1
2006 Labinger JA, Bercaw JE, Tilset M. C - H activation by platinum(II): What do gas-phase studies tell us about the solution-phase mechanism? Organometallics. 25: 805-808. DOI: 10.1021/om0502638  1
2005 Chirik PJ, Bercaw JE. Cyclopentadienyl and olefin substituent effects on insertion and β-hydrogen elimination with group 4 metallocenes. kinetics, mechanism, and thermodynamics for zirconocene and hafnocene alkyl hydride derivatives Organometallics. 24: 5407-5423. DOI: 10.1021/om0580351  1
2005 Chirik PJ, Dalleska NF, Henling LM, Bercaw JE. Experimental evidence for γ-agostic assistance in β-methyl elimination, the microscopic reverse of α-agostic assistance in the chain propagation step of olefin polymerization Organometallics. 24: 2789-2794. DOI: 10.1021/om058002l  1
2005 Driver TG, Day MW, Labinger JA, Bercaw JE. Mechanism of C-H bond activation of alkyl-substituted benzenes by cationic platinum(II) complexes Organometallics. 24: 3644-3654. DOI: 10.1021/om050251m  1
2005 Diaconescu PL, Mehrkhodavandi P, Grubbs RH, Labinger JA, Bercaw JE, Sunley GJ, Morris GE, Kay R. Metal-mediated conversion of methanol to hydrocarbons Acs National Meeting Book of Abstracts. 229: INOR-847.  1
2005 Elowe PR, Bercaw JE. Chromium complexes as models for ethylene trimerization catalysts Acs National Meeting Book of Abstracts. 229: INOR-640.  1
2005 Mehrkhodavandi P, Diaconescu PL, Bercaw JE, Labinger JA, Grubbs RH. Investigation of intermediates for zinc-mediated conversion of methanol to hydrocarbons Acs National Meeting Book of Abstracts. 229: INOR-846.  1
2004 Heyduk AF, Driver TG, Labinger JA, Bercaw JE. Kinetic and thermodynamic preferences in aryl vs benzylic C-H bond activation with cationic Pt(II) complexes. Journal of the American Chemical Society. 126: 15034-5. PMID 15547993 DOI: 10.1021/ja045078k  1
2004 Owen JS, Labinger JA, Bercaw JE. Pyridinium-derived N-heterocyclic carbene complexes of platinum: synthesis, structure and ligand substitution kinetics. Journal of the American Chemical Society. 126: 8247-55. PMID 15225067 DOI: 10.1021/ja040075t  1
2004 Baar CR, Levy CJ, Min EY, Henling LM, Day MW, Bercaw JE. Kinetic resolution of chiral alpha-olefins using optically active ansa-zirconocene polymerization catalysts. Journal of the American Chemical Society. 126: 8216-31. PMID 15225063 DOI: 10.1021/ja040021j  1
2004 Agapie T, Schofer SJ, Labinger JA, Bercaw JE. Mechanistic studies of the ethylene trimerization reaction with chromium-diphosphine catalysts: experimental evidence for a mechanism involving metallacyclic intermediates. Journal of the American Chemical Society. 126: 1304-5. PMID 14759164 DOI: 10.1021/ja038968t  1
2004 Miller SA, Bercaw JE. Highly Stereoregular Syndiotactic Polypropylene Formation with Metallocene Catalysts via Influence of Distal Ligand Substituants Organometallics. 23: 1777-1789. DOI: 10.1021/om030333f  1
2004 Piro NA, Owen JS, Bercaw JE. Pyridinium-derived N-heterocyclic carbene ligands: Syntheses, structures and reactivity of N-(2′-pyridyl)pyridin-2-ylidene complexes of nickel(II), palladium(II) and platinum(II) Polyhedron. 23: 2797-2804. DOI: 10.1016/j.poly.2004.06.021  1
2003 Iverson CN, Carter CA, Baker RT, Scollard JD, Labinger JA, Bercaw JE. C-H bond activation by unsymmetrical 2-(N-arylimino)pyrrolide Pt complexes: geometric effects on reactivity. Journal of the American Chemical Society. 125: 12674-5. PMID 14558792 DOI: 10.1021/ja036511d  1
2003 Heyduk AF, Labinger JA, Bercaw JE. Catalytic alcoholysis of tetramethylsilane via Pt-mediated C-H bond activation. Journal of the American Chemical Society. 125: 6366-7. PMID 12785766 DOI: 10.1021/ja029099v  1
2003 Ackerman LJ, Sadighi JP, Kurtz DM, Labinger JA, Bercaw JE. Arene C-H bond activation and arene oxidative coupling by cationic palladium(II) complexes Organometallics. 22: 3884-3890. DOI: 10.1021/om0303294  1
2003 Ackerman LJ, Green MLH, Green JC, Bercaw JE. Experimental and theoretical studies of olefin insertion for ansa-niobocene and ansa-tantalocene ethylene hydride complexes Organometallics. 22: 188-194. DOI: 10.1021/om0206296  1
2003 Chirik PJ, Zubris DL, Ackerman LJ, Henling LM, Day MW, Bercaw JE. Preparation of ansa-niobocene and ansa-tantalocene olefin hydride complexes as transition state analogues in metallocene-catalyzed olefin polymerization Organometallics. 22: 172-187. DOI: 10.1021/om020628d  1
2003 Sadighi JP, Henling LM, Labinger JA, Bercaw JE. Synthesis of a perfluoroalkyl-substituted α-diimine by Sm-mediated reductive coupling Tetrahedron Letters. 44: 8073-8076. DOI: 10.1016/j.tetlet.2003.09.052  1
2002 Zachmanoglou CE, Docrat A, Bridgewater BM, Parkin G, Brandow CG, Bercaw JE, Jardine CN, Lyall M, Green JC, Keister JB. The electronic influence of ring substituents and ansa bridges in zirconocene complexes as probed by infrared spectroscopic, electrochemical, and computational studies. Journal of the American Chemical Society. 124: 9525-46. PMID 12167048 DOI: 10.1021/ja020236y  1
2002 Rostovtsev VV, Henling LM, Labinger JA, Bercaw JE. Structural and mechanistic investigations of the oxidation of dimethylplatinum(II) complexes by dioxygen. Inorganic Chemistry. 41: 3608-19. PMID 12099863 DOI: 10.1021/ic0112903  1
2002 Labinger JA, Bercaw JE. Understanding and exploiting C-H bond activation. Nature. 417: 507-14. PMID 12037558 DOI: 10.1038/417507a  1
2002 Procelewska J, Zahl A, van Eldik R, Zhong HA, Labinger JA, Bercaw JE. Activation volume measurement for C[bond]H activation. Evidence for associative benzene substitution at a platinum(II) center. Inorganic Chemistry. 41: 2808-10. PMID 12033883 DOI: 10.1021/ic0201710  1
2002 Yoder JC, Bercaw JE. Chain epimerization during propylene polymerization with metallocene catalysts: mechanistic studies using a doubly labeled propylene. Journal of the American Chemical Society. 124: 2548-55. PMID 11890805 DOI: 10.1021/ja0123296  1
2002 Zhong HA, Labinger JA, Bercaw JE. C [bond] H activation by cationic platinum(II) complexes: ligand electronic and steric effects. Journal of the American Chemical Society. 124: 1378-99. PMID 11841307  1
2002 Miller SA, Bercaw JE. Isotactic-hemiisotactic polypropylene from C1-symmetric ansa-metallocene catalysts: A new strategy for the synthesis of elastomeric polypropylene Organometallics. 21: 934-945. DOI: 10.1021/om010788+  1
2002 Zhong HA, Labinger JA, Bercaw JE. C-H bond activation by cationic platinum(II) complexes: Ligand electronic and steric effects Journal of the American Chemical Society. 124: 1378-1399. DOI: 10.1021/ja011189x  1
2002 Wong-Foy AG, Henling LM, Day M, Labinger JA, Bercaw JE. Intramolecular C-H activation by dicationic Pt(II) complexes Journal of Molecular Catalysis a: Chemical. 189: 3-16. DOI: 10.1016/S1381-1169(02)00193-0  1
2001 Arakawa H, Aresta M, Armor JN, Barteau MA, Beckman EJ, Bell AT, Bercaw JE, Creutz C, Dinjus E, Dixon DA, Domen K, DuBois DL, Eckert J, Fujita E, Gibson DH, et al. Catalysis research of relevance to carbon management: progress, challenges, and opportunities. Chemical Reviews. 101: 953-96. PMID 11709862 DOI: 10.1021/cr000018s  1
2001 Brandow CG, Mendiratta A, Bercaw JE. Ancillary ligand and olefin substituent effects on olefin dissociation for cationic zirconocene complexes bearing a coordinated pendant olefin Organometallics. 20: 4253-4261. DOI: 10.1021/om010363n  1
2001 Wendt OF, Bercaw JE. Thermally stable dialkylzirconocenes with β-hydrogens. Synthesis and diastereoselectivity Organometallics. 20: 3891-3895. DOI: 10.1021/om0102910  1
2001 Chirik PJ, Henling LM, Bercaw JE. Synthesis of singly and doubly bridged ansa-Zirconocene hydrides. Formation of an unusual mixed valence trimeric hydride by reaction of H2 with {(Me2Si)2(η5- C5H3)2} Zr(CH3)2 and generation of a dinitrogen complex by reaction of N2 with a zirconocene dihydride Organometallics. 20: 534-544. DOI: 10.1021/om000739h  1
2001 Kim YK, Livinghouse T, Bercaw JE. Intramolecular alkene hydroaminations catalyzed by simple amido derivatives of the Group 3 metals Tetrahedron Letters. 42: 2933-2935. DOI: 10.1016/S0040-4039(01)00346-X  1
2001 Scollard JD, Day M, Labinger JA, Bercaw JE. Preparation of dimethyl and chloro/methyl complexes of platinum(II) supported by α-Diimine ligands: Trends in the ease of oxidation to platinum(IV) Helvetica Chimica Acta. 84: 3247-3268. DOI: 10.1002/1522-2675(20011017)84:10<3247::AID-HLCA3247>3.0.CO;2-W  1
2000 Bercaw JE. Aminofluorenyl-pentamethylcyclopentadienyl and bis(aminofluorenyl) derivatives of group 4 metals Organometallics. 19: 5608-5613. DOI: 10.1021/om000723r  1
2000 Johansson L, Tilset M, Labinger JA, Bercaw JE. Mechanistic investigation of benzene C-H activation at a cationic platinum(II) center: Direct observation of a platinum(II) benzene adduct Journal of the American Chemical Society. 122: 10846-10855. DOI: 10.1021/ja0017460  1
2000 Zubris DL, Veghini D, Herzog TA, Bercaw JE. Reactivity and mechanistic studies of stereocontrol for Ziegler-Natta polymerization utilizing Doubly-Silylene bridged group 3 and group 4 metalocenes Acs Symposium Series. 749: 2-14.  1
2000 Muci AR, Bercaw JE. Yttrocene-catalyzed asymmetric cyclization-hydrosilylation of α,ω-dienes Tetrahedron Letters. 41: 7609-7612.  1
2000 Chirik PJ, Bercaw JE. Mechanistic aspects of chain propagation and transfer for metallocene-catalyzed olefin polymerization American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 41: 393-394.  1
1999 Veghini D, Henling LM, Burkhardt TJ, Bercaw JE. Mechanisms of stereocontrol for doubly silylene-bridged C(s)- and C1- symmetric zirconocene catalysts for propylene polymerization. Synthesis and molecular structure of a dilithio double silylene-bridged bis(cyclopentadienyl) complex and the corresponding zirconium dichloride complex Journal of the American Chemical Society. 121: 564-573. DOI: 10.1021/ja982868j  1
1999 Baker RT, Bercaw JE, Whitwell GE, Watkin JG, Labinger JA, Carter CAG. Homogeneous alkane functionalization catalysis Acs National Meeting Book of Abstracts. I&EC-7.  1
1999 Chirik PJ, Day MW, Labinger JA, Bercaw JE. Alkyl rearrangement processes in organozirconium complexes. Observation of internal alkyl complexes during hydrozirconation Journal of the American Chemical Society. 121: 10308-10317.  1
1999 Abrams MB, Yoder JC, Loeber C, Day MW, Bercaw JE. Fluxional η3-allyl derivatives of ansa-scandocenes and an ansa-yttrocene. Measurements of the barriers for the η3 to η1 process as an indicator of olefin binding energy to d0 metallocenes Organometallics. 18: 1389-1401.  1
1998 Stahl SS, Labinger JA, Bercaw JE. Homogeneous Oxidation of Alkanes by Electrophilic Late Transition Metals. Angewandte Chemie (International Ed. in English). 37: 2180-2192. PMID 29711451 DOI: 10.1002/(SICI)1521-3773(19980904)37:16<2180::AID-ANIE2180>3.0.CO;2-A  1
1998 Millar SP, Zubris DL, Bercaw JE, Eisenberg R. On the mechanism of dihydrogen addition to tantalocene complexes [8] Journal of the American Chemical Society. 120: 5329-5330. DOI: 10.1021/ja9739188  1
1998 Miyake S, Bercaw JE. Doubly [SiMe2]-bridged C(s)- and C(2v)-symmetric zirconocene catalysts for propylene polymerization. Synthesis and polymerization characteristics Journal of Molecular Catalysis a: Chemical. 128: 29-39. DOI: 10.1016/S1381-1169(97)00160-X  1
1998 Stahl SS, Labinger JA, Bercaw JE. Homogeneous oxidation of alkanes by electrophilic late transition metals Angewandte Chemie - International Edition. 37: 2180-2192. DOI: 10.1002/(SICI)1521-3773(19980904)37:16<2180::AID-ANIE2180>3.0.CO;2-A  1
1998 Yoder JC, Day MW, Bercaw JE. Racemie-meso interconversion for ansa-scandocene and ansa-yttrocene derivatives Organometallics. 17: 4946-4958.  1
1998 Miyake S, Henling LM, Bercaw JE. Synthesis, molecular structure, and racemate-meso interconversion for rac-(Me2Si)2{η5-C5H-3-(CHMe 2)-5-Me}2MCl2 (M = Ti and Zr) Organometallics. 17: 5528-5533.  1
1998 Veghini D, Day MW, Bercaw JE. Preparation of doubly-silylene-bridged zirconocene alkyl complexes, (Me2Si)2{η5-C5H 2-4-CHMe2}{η5-C5H-3,5-(CHMe 2)2}ZrR2(R = CH3, CH2Ph) and investigations of their activity in 1-pentene polymerization Inorganica Chimica Acta. 280: 226-232.  1
1998 Rostovtsev VV, Labinger JA, Bercaw JE, Lasseter TL, Goldberg KI. Oxidation of dimethylplatinum(II) complexes with dioxygen Organometallics. 17: 4530-4531.  1
1998 Stahl SS, Labinger JA, Bercaw JE. Investigations of the Factors Affecting the Stability of Dihydrogen Adducts of Platinum(II) Inorganic Chemistry. 37: 2422-2431.  1
1998 Holtcamp MW, Henling LM, Day MW, Labinger JA, Bercaw JE. Intramolecular and intermolecular C-H activation at a cationic PtII center Inorganica Chimica Acta. 270: 467-478.  1
1998 Birnbaum ER, Labinger JA, Bercaw JE, Gray HB. Catalysis of aerobic olefin oxidation by a ruthenium perhaloporphyrin complex Inorganica Chimica Acta. 270: 433-439.  1
1998 Kiely AF, Nelson CM, Pastor A, Henling LM, Day MW, Bercaw JE. Heterolysis of H-X bonds by pentamethylcyclopentadienyl - Aminoborole complexes of zirconium and hafnium Organometallics. 17: 1324-1332.  1
1998 Veghini D, Bercaw JE. Mechanisms of stereocontrol for polymerization of α-olefins with doubly-bridged zirconocene catalysts American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 39: 210-211.  1
1998 Blake RE, Antonelli DM, Henling LM, Schaefer WP, Hardcastle KI, Bercaw JE. A cationic imido complex of permethyltantalocene: H2 and carbon-hydrogen bond activation, [2 + 2] cycloaddition reactions, and an unusual reaction with carbon dioxide That affords coordinated isocyanate Organometallics. 17: 718-725.  1
1997 Holtcamp MW, Labinger JA, Bercaw JE. C-H activation at cationic platinum(II) centers Journal of the American Chemical Society. 119: 848-849. DOI: 10.1021/ja9620595  1
1997 Wang L, Stahl SS, Labinger JA, Bercaw JE. (Alkyl) platinum(II) intermediates in C-H activation by platinum complexes in aqueous solution Journal of Molecular Catalysis a: Chemical. 116: 269-275. DOI: 10.1016/S1381-1169(96)00118-5  1
1997 Holtcamp MW, Labinger JA, Bercaw JE. Ligand effects on the rates of protonolysis and isotopic exchange for platinum (II) alkyls Inorganica Chimica Acta. 265: 117-125.  1
1997 Hajela S, Schaefer WP, Bercaw JE. Highly electron deficient Group 3 organometallic complexes based on the 1,4,7-trimethyl-1,4,7-triazacyclononane ligand system Journal of Organometallic Chemistry. 532: 45-53.  1
1997 Pastor A, Kiely AF, Henling LM, Day MW, Bercaw JE. Pentamethylcyclopentadienyl-aminoborole derivatives of zirconium and hafnium with alkyl and allyl ligands Journal of Organometallic Chemistry. 528: 65-75.  1
1996 Gilchrist JH, Bercaw JE. New NMR spectroscopic probe of the absolute stereoselectivity for metal-hydride and metal-alkyl additions to the carbon-carbon double bond. Demonstration with a single-component, isospecific Ziegler-Natta α-olefin polymerization catalyst Journal of the American Chemical Society. 118: 12021-12028. DOI: 10.1021/ja962869g  1
1996 Herzog TA, Zubris DL, Bercaw JE. A new class of zirconocene catalysts for the syndiospecific polymerization of propylene and its modification for varying polypropylene from isotactic to syndiotactic Journal of the American Chemical Society. 118: 11988-11989. DOI: 10.1021/ja962413z  1
1996 Stahl SS, Labinger JA, Bercaw JE. Exploring the mechanism of aqueous C-H activation by Pt(II) through model chemistry: Evidence for the intermediacy of alkylhydridoplatinum(IV) and alkane σ-adducts Journal of the American Chemical Society. 118: 5961-5976. DOI: 10.1021/ja960110z  1
1996 Mitchell JP, Hajela S, Brookhart SK, Hardcastle KI, Henling LM, Bercaw JE. Preparation and structural characterization of an enantiomerically pure, C2-symmetric, single-component Ziegler-Natta α-olefin polymerization catalyst Journal of the American Chemical Society. 118: 1045-1053. DOI: 10.1021/ja953419b  1
1996 Mitchell JP, Hajela S, Brookhart SK, Gilchrist JH, Herzog TA, Miller SA, Bercaw JE. Mechanisms of stereocontrol for isotactic and syndiotactic polymerizations of α-olefins with metallocene catalysts American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 37: 247-248.  1
1996 Coughlin EB, Henling LM, Bercaw JE. Synthesis and structural characterization of {(η5-C5Me4)2SiMe 2}YCH(SiMe3)2. Hydrogenation to [{(η5-C5Me4)2SiMe 2}Y]2(μ2-H)2 and its facile ligand redistribution to Inorganica Chimica Acta. 242: 205-210.  1
1995 Birnbaum ER, Grinstaff MW, Labinger JA, Bercaw JE, Gray HB. On the mechanism of catalytic alkene oxidation by molecular oxygen and halogenated iron porphyrins Journal of Molecular Catalysis. a, Chemical. 104: L119-L122.  1
1995 Birnbaum ER, Schaefer WP, Labinger JA, Bercaw JE, Gray HB. Electronic structures of halogenated ruthenium porphyrins. Crystal structure of RuTFPPCl8(CO)H2O (TFPPCl8 = Octa-β-chlorotetrakis(pentafluorophenyl)porphyrin) Inorganic Chemistry. 34: 1751-1755.  1
1995 Birnbaum ER, Hodge JA, Grinstaff MW, Schaefer WP, Henling L, Labinger JA, Bercaw JE, Gray HB. 19F NMR Spectra and structures of halogenated porphyrins Inorganic Chemistry. 34: 3625-3632.  1
1995 Luinstra GA, Wang L, Stahl SS, Labinger JA, Bercaw JE. CH activation by aqueous platinum complexes: A mechanistic study Journal of Organometallic Chemistry. 504: 75-91.  1
1995 Stahl SS, Labinger JA, Bercaw JE. Formation and reductive elimination of a hydridoalkylplatinum(IV) intermediate upon protonolysis of an alkylplatinum(II) complex Journal of the American Chemical Society. 117: 9371-9372.  1
1995 Chacon ST, Bryan Coughlin E, Henling LM, Bercaw JE. C2-symmetric ansa metallocenes of titanium and zirconium with a ligand system that yields pure rac isomer: preparation and crystal structures of rac-η5-C5H22-SiMe34-CMe3)2SiMe3MCl2(M = Ti or Zr) Journal of Organometallic Chemistry. 497: 171-180.  1
1994 Labinger JA, Bercaw JE, Luinstra GA, Lyon DK, Herring AM. Organometallic methane activation: Functionalization by aqueous platinum complexes Studies in Surface Science and Catalysis. 81: 515-520. DOI: 10.1016/S0167-2991(08)63922-1  1
1994 Freund MS, Labinger JA, Lewis NS, Bercaw JE. Electrocatalytic functionalization of alkanes using aqueous platinum salts Journal of Molecular Catalysis. 87: L11-L15. DOI: 10.1016/0304-5102(93)E0230-E  1
1994 Luinstra GA, Wang L, Stahl SS, Labinger JA, Bercaw JE. Oxidation of Zeise's salt by [PtCl6]2-: A mechanistic model for hydrocarbon oxidation Organometallics. 13: 755-756.  1
1994 Shapiro PJ, Cotter WD, Schaefer WP, Labinger JA, Bercaw JE. Model ziegler-natta α-olefin polymerization catalysts derived from [{(η5-C5Me4)SiMe2(η1 -NCMe3)}(PMe3)Sc(μ2-H)]2and[{(η 5-C5Me4)SiMe2(η1-NCMe 3)}Sc(μ2-CH2CH2CH3) Journal of the American Chemical Society. 116: 4623-4640.  1
1994 Quan RW, Bazan GC, Kiely AF, Schaefer WP, Bercaw JE. Pentamethylcyclopentadienyl aminoborollide derivatives of zirconium and hafnium: A new class of amphoteric molecule having both Lewis acidic and Lewis basic sites Journal of the American Chemical Society. 116: 4489-4490.  1
1994 Hajela S, Bercaw JE. Competitive chain transfer by β-hydrogen and β-methyl elimination for the model Ziegler-Natta olefin polymerization system [Me2Si(η5-C5Me4)2]Sc{CH2CH(CH 3) 2}(PMe3) Organometallics. 13: 1147-1154.  1
1994 Bierwagen EP, Bercaw JE, Goddard WA. Theoretical studies of Ziegler-Natta catalysis: Structural variations and tacticity control Journal of the American Chemical Society. 116: 1481-1489.  1
1993 Antonelli DM, Schaefer WP, Parkin G, Bercaw JE. Synthesis and characterization of (η5-C5Me5) 2TaCl(THF), a useful synthetic precursor for the preparation of oxo, imido and methylidene derivatives of permethyltantalocene Journal of Organometallic Chemistry. 462: 213-220. DOI: 10.1016/0022-328X(93)83360-8  1
1993 Kelson EP, Henling LM, Schaefer WP, Labinger JA, Bercaw JE. Electrocatalytic oxidation by binuclear ruthenium complexes incorporating the anionic tripod ligand [(η5-C5H5)Co{(CH3O) 2P=O}3]- Inorganic Chemistry. 32: 2863-2873.  1
1993 Labinger JA, Herring AM, Lyon DK, Luinstra GA, Bercaw JE, Horváth IT, Eller K. Oxidation of hydrocarbons by aqueous platinum salts: Mechanism and selectivity Organometallics. 12: 895-905.  1
1993 Bazan GC, Schaefer WP, Bercaw JE. Pentamethylcyclopentadienyl-dicarbollide derivatives of scandium Organometallics. 12: 2126-2130.  1
1992 Bercaw JE, Moss JR. Alkanediyl and related derivatives of permethylhafnocene Organometallics. 11: 639-645.  1
1992 Bryan Coughlin E, Bercaw JE. Iso-specific ziegler-natta polymerization of α-olefins with a single-component organoyttrium catalyst Journal of the American Chemical Society. 114: 7606-7607.  1
1992 Nelson JE, Parkin G, Bercaw JE. Synthesis and characterization of thioaldehyde hydride derivatives of permethyltantalocene. Investigations of their equilibration with thiolates and the stereochemistry of alkyl migrations from sulfur to tantalum Organometallics. 11: 2181-2189.  1
1992 Parkin G, Van Asselt A, Leahy DJ, Whinnery L, Hua NG, Quan RW, Henling LM, Schaefer WP, Santarsiero BD, Bercaw JE. Oxo-hydrido and imido-hydrido derivatives of permethyltantalocene. Structures of (η5-C5Me5)2Ta(=O)H and (η5-C5Me5)2Ta(=NC 6H5)H: Doubly or triply bonded tantalum oxo and imido ligands? Inorganic Chemistry. 31: 82-85.  1
1992 Bryan Coughlin E, Bercaw JE. Stereochemistry at carbon for alkyl migration to oxygen in the rearrangement of a tert-butylperoxy alkyl derivative of permethylhafnocene Organometallics. 11: 465-467.  1
1991 Piers WE, Bunel EE, Bercaw JE. Synthesis and characterization of mono-(pentamethylcyclopentadienyl)alkoxyscandium alkyl derivatives, (η5-C5Me5)(OR)ScR′ Journal of Organometallic Chemistry. 407: 51-60. DOI: 10.1016/0022-328X(91)83139-U  1
1991 Cotter WD, Bercaw JE. Investigations of the magnitude of steric and α deuterium kinetic isotope effects in a carboncarbon bond-forming reaction of a permethylscandocene complex Journal of Organometallic Chemistry. 417: C1-C6. DOI: 10.1016/0022-328X(91)80181-I  1
1991 Herring AM, Henling L, Labinger JA, Bercaw JE. Structure of disodium trans-bis(2,6-pyridinedicarboxylato-O,N)platinate(II) hexahydrate Inorganic Chemistry. 30: 851-853.  1
1991 Gibson VC, Parkin G, Bercaw JE. Synthesis and reactivity of permethyltantalocene derivatives possessing η3-allyl, η2-butadiene, η2-methylallene, and η1-alkenylidene ligands. Model studies for the role of surface vinylidenes in the fischer-tropsch hydrocarbon-chain-lengthening process Organometallics. 10: 220-231.  1
1991 St. Clair M, Schaefer WP, Bercaw JE. Reactivity of permethylscandocene derivatives with acetylene. Structure of acetylenediylbis(permethylscandocene), (η5-C5Me5) 2Sc-C≡C-Sc(η5-C5Me5) 2 Organometallics. 10: 525-527.  1
1990 Piers WE, Bercaw JE. α "agostic" assistance in Ziegler-Natta polymerization of olefins. Deuterium isotopic perturbation of stereochemistry indicating coordination of an α C-H bond in chain propagation Journal of the American Chemical Society. 112: 9406-9407.  1
1990 Shapiro PJ, Henling LM, Marsh RE, Bercaw JE. Hydrazido(1-) and 2,2-dimethylhydrazido(1-) derivatives of permethylscandocene. Preparation and structural characterization of their products from reactions with acetonitrile: (η5-C5Me5)2ScN(H)C(CH 3)NNH2 and (η5-C5Me5)2ScN(H)C(CH 3)NNMe2 Inorganic Chemistry. 29: 4560-4565.  1
1990 Power JM, Evertz K, Henling L, Marsh R, Schaefer WP, Labinger JA, Bercaw JE. Synthesis and structural characterization of binuclear ruthenium aquo, hydroxy, and oxo complexes incorporating the anionic tripod ligand [(η5-C5H5)Co{(CH3CH 2O)2P=O}3]- Inorganic Chemistry. 29: 5058-5065.  1
1990 Labinger JA, Herring AM, Bercaw JE. Selective hydroxylation of methyl groups by platinum salts in aqueous medium. Direct conversion of ethanol to ethylene glycol Journal of the American Chemical Society. 112: 5628-5629.  1
1990 Burger BJ, Thompson ME, Cotter WD, Bercaw JE. Ethylene insertion and β-hydrogen elimination for permethylscandocene alkyl complexes. A study of the chain propagation and termination steps in Ziegler-Natta polymerization of ethylene Journal of the American Chemical Society. 112: 1566-1577.  1
1983 Mayer JM, Curtis CJ, Bercaw JE. Hydrogen-transfer reactions which generate new imine, imido, and trimethylenemethane complexes of tantalum. Journal of the American Chemical Society. 105: 2651-60. PMID 19817430 DOI: 10.1021/ja00347a023  0.76
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