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Ronald J. Gillespie - Publications

Affiliations: 
McMaster University, Hamilton, ON, Canada 
Area:
Valence Shell Electron Pair Repulsion (VSEPR) model of molecular geometry
Website:
http://www.chemistry.mcmaster.ca/extracts/extracts99/ronald_gillespie/

152 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2013 Silvi B, Gillespie RJ, Gatti C. Electron Density Analysis Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 9: 187-226. DOI: 10.1016/B978-0-08-097774-4.00907-4  1
2010 Gillespie RJ, Robinson EA, Pilmé J. Ligand close packing, molecular compactness, the methyl tilt, molecular conformations, and a new model for the anomeric effect. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 3663-75. PMID 20183833 DOI: 10.1002/Chem.200902599  1
2008 Gillespie RJ. Fifty years of the VSEPR model Coordination Chemistry Reviews. 252: 1315-1327. DOI: 10.1016/J.Ccr.2007.07.007  1
2007 Gillespie RJ, Robinson EA. Gilbert N. Lewis and the chemical bond: the electron pair and the octet rule from 1916 to the present day. Journal of Computational Chemistry. 28: 87-97. PMID 17109437 DOI: 10.1002/jcc.20545  1
2007 Silvi B, Gillespie RJ. The ELF Topological Analysis Contribution to Conceptual Chemistry and Phenomenological Models The Quantum Theory of Atoms in Molecules: From Solid State to Dna and Drug Design. 141-162. DOI: 10.1002/9783527610709.ch6  1
2006 Pilmé J, Robinson EA, Gillespie RJ. A topological study of the geometry of AF6E molecules: weak and inactive lone pairs. Inorganic Chemistry. 45: 6198-204. PMID 16878928 DOI: 10.1021/Ic052182+  1
2005 Gillespie RJ, Robinson EA. Models of molecular geometry. Chemical Society Reviews. 34: 396-407. PMID 15852152 DOI: 10.1039/B405359C  1
2005 Gillespie RJ, Robinson EA. The importance of ligand-ligand interactions for molecular geometry and the ligand close-packing model Comptes Rendus Chimie. 8: 1631-1644. DOI: 10.1016/j.crci.2005.03.006  1
2004 Gillespie RJ, Noury S, Pilmé J, Silvi B. An electron localization function study of the geometry of d(0) molecules of the period 4 metals Ca to Mn. Inorganic Chemistry. 43: 3248-56. PMID 15132634 DOI: 10.1021/Ic0354015  1
2004 Robinson EA, Gillespie RJ. The geometry of nonmetal hydrides and the ligand radius of hydrogen. Inorganic Chemistry. 43: 2318-23. PMID 15046507 DOI: 10.1021/ic030290v  1
2004 Gillespie RJ. Teaching molecular geometry with the VSEPR model Journal of Chemical Education. 81: 298+300+302+304. DOI: 10.1021/Ed081P298  1
2003 Robinson EA, Gillespie RJ. Ligand close packing and the geometry of the fluorides of the nonmetals of periods 3, 4, and 5. Inorganic Chemistry. 42: 3865-72. PMID 12793824 DOI: 10.1021/ic030024h  1
2002 Noury S, Silvi B, Gillespie RJ. Chemical bonding in hypervalent molecules: is the octet rule relevant? Inorganic Chemistry. 41: 2164-72. PMID 11952370 DOI: 10.1021/Ic011003V  1
2002 Malcolm NOJ, Gillespie RJ, Popelier PLA. A topological study of homonuclear multiple bonds between the elements of group 14 Journal of the Chemical Society, Dalton Transactions. 3333-3341. DOI: 10.1039/B110610B  1
2002 Matta CF, Gillespie RJ. Understanding and interpreting molecular electron density distributions Journal of Chemical Education. 79: 1141. DOI: 10.1021/Ed079P1141  1
2002 Gillespie RJ, Silvi B. The octet rule and hypervalence: Two misunderstood concepts Coordination Chemistry Reviews. 233: 53-62. DOI: 10.1016/S0010-8545(02)00102-9  1
2002 Brown ID, Gillespie RJ, Morgan KR, Tun Z, Ummat PK. Preparation and crystal structure of mercury hexafluoroniobate (Hg3NbF6) and mercury hexafluorotantalate (Hg3TaF6): mercury layer compounds Cheminform. 16. DOI: 10.1002/Chin.198518037  0.36
2001 Gillespie RJ. Electron densities, atomic charges, and ionic, covalent, and polar bonds Journal of Chemical Education. 78: 1688-1691. DOI: 10.1021/Ed078P1688  1
2001 Gillespie RJ, Popelier PLA. Bond strengths: Chemical bonding and molecular geometry Chemistry in Britain. 37: 45.  1
2000 Heard GL, Gillespie RJ, Rankin DWH. Ligand close packing and the geometries of A(XY)4 and some related molecules Journal of Molecular Structure. 520: 237-248. DOI: 10.1016/S0022-2860(99)00335-X  1
2000 Gillespie RJ. Improving our understanding of molecular geometry and the VSEPR model through the ligand close-packing model and the analysis of electron density distributions Coordination Chemistry Reviews. 197: 51-69. DOI: 10.1016/S0010-8545(99)00199-X  1
1999 Alder RW, Allen PR, Hnyk D, Rankin DWH, Robertson HE, Smart BA, Gillespie RJ, Bytheway I. Molecular structure of 3,3-diethylpentane (tetraethylmethane) in the gas phase as determined by electron diffraction and ab initio calculations Journal of Organic Chemistry. 64: 4226-4232. DOI: 10.1021/Jo981779M  1
1999 Robinson EA, Heard GL, Gillespie RJ. The importance of ligand-ligand interactions in determining molecular geometry: The ligand close packing model Journal of Molecular Structure. 485: 305-319. DOI: 10.1016/S0022-2860(99)00051-4  1
1999 Rowsell BD, Gillespie RJ, Heard GL. Ligand close-packing and the lewis acidity of BF3 and BCl3 Inorganic Chemistry. 38: 4659-4662.  1
1998 Gillespie RJ, Bytheway I, Robinson EA. Bond Lengths and Bond Angles in Oxo, Hydroxo, and Alkoxo Molecules of Be, B, and C: A Close-Packed Nearly Ionic Model. Inorganic Chemistry. 37: 2811-2825. PMID 11670420 DOI: 10.1021/Ic971588M  1
1998 Gillespie RJ. The Physical Basis of the VSEPR Model Structural Chemistry. 9: 73-76. DOI: 10.1023/A:1022491218892  1
1998 Gillespie RJ, Bayles D, Platts J, Heard GL, Bader RFW. The Lennard-Jones function: A quantitative description of the spatial correlation of electrons as determined by the exclusion principle Journal of Physical Chemistry A. 102: 3407-3414. DOI: 10.1021/Jp980592W  1
1998 Gillespie RJ. Covalent and ionic molecules: Why are BeF2 and AlF3 high melting point solids whereas BF3 and SiF4 are gases? Journal of Chemical Education. 75: 923-925. DOI: 10.1021/Ed075P923  1
1998 Bader RFW, Gillespie RJ, Martín F. Core distortions in metal atoms and the use of effective core potentials Chemical Physics Letters. 290: 488-494. DOI: 10.1016/S0009-2614(98)00456-4  1
1998 Gillespie RJ, Robinson EA, Heard GL. Bonding and Geometry of OCF3 -, ONF3, and Related Molecules in Terms of the Ligand Close Packing Model Inorganic Chemistry. 37: 6884-6889.  1
1997 Gillespie RJ, Johnson SA. Study of Bond Angles and Bond Lengths in Disiloxane and Related Molecules in Terms of the Topology of the Electron Density and Its Laplacian. Inorganic Chemistry. 36: 3031-3039. PMID 11669954 DOI: 10.1021/Ic961381D  1
1997 Robinson EA, Johnson SA, Tang TH, Gillespie RJ. Reinterpretation of the Lengths of Bonds to Fluorine in Terms of an Almost Ionic Model. Inorganic Chemistry. 36: 3022-3030. PMID 11669953 DOI: 10.1021/Ic961315B  1
1996 Bytheway I, Popelier PLA, Gillespie RJ. Topological studies of the charge density of some group 2 metallocenes M(η5-C5H5)2 (M = Mg or Ca) Canadian Journal of Chemistry. 74: 1059-1071. DOI: 10.1139/V96-119  1
1996 Gillespie RJ, Robinson EA. Electron Domains and the VSEPR Model of Molecular Geometry Angewandte Chemie (International Edition in English). 35: 495-514. DOI: 10.1002/Anie.199604951  1
1996 Gillespie RJ, Spencer JN, Moog RS. Part 1. Electron configurations from experiment Journal of Chemical Education. 73: 617-622.  1
1996 Gillespie RJ, Spencer JN, Moog RS. Part 2. Bonding and molecular geometry without orbitals - The electron domain model Journal of Chemical Education. 73: 622-627.  1
1996 Spencer JN, Moog RS, Gillespie RJ. Part 3. Ionization energies, electronegativity, polar bonds and partial charges Journal of Chemical Education. 73: 627-631.  1
1996 Spencer JN, Moog RS, Gillespie RJ. Part 4. An approach to reaction thermodynamics through enthalpies, entropies, and free energies of atomization Journal of Chemical Education. 73: 631-636.  1
1995 Bytheway I, Gillespie RJ, Tang TH, Bader RFW. Core distortions and geometries of the difluorides and dihydrides of Ca, Sr, and Ba Inorganic Chemistry. 34: 2407-2414. DOI: 10.1021/Ic00113A023  1
1995 Gillespie RJ, Robinson EA. Hypervalence and the octet rule Inorganic Chemistry. 34: 978-979. DOI: 10.1021/Ic00108A032  1
1995 Bytheway I, Gillespie RJ. Structures of some transition metal fluorides and oxofluorides and the VSEPR model Journal of Fluorine Chemistry. 71: 189. DOI: 10.1016/0022-1139(94)06018-H  1
1994 Gillespie RJ, Bytheway I, DeWitte RS, Bader RFW. Trigonal bipyramidal and related molecules of the main group elements: Investigation of apparent exceptions to the VSEPR model through the analysis of the Laplacian of the electron density Inorganic Chemistry. 33: 2115-2121. DOI: 10.1021/Ic00088A011  1
1994 Gillespie RJ. Provocative opinion: The changing roles of descriptive chemistry: Integrating reactions and properties with theories and principles of inorganic and organic chemistry Journal of Chemical Education. 71: 665-666.  1
1993 Gillespie RJ, Humphreys DA. The forum: Descriptive chemistry in the general chemistry course - A new approach Journal of Chemical Education. 70: 528-530.  1
1992 Gillespie RJ. The VSEPR model revisited Chemical Society Reviews. 21: 59-69. DOI: 10.1039/Cs9922100059  1
1992 Gillespie RJ. Multiple bonds and the VSEPR model Journal of Chemical Education. 69: 116-121. DOI: 10.1021/Ed069P116  1
1992 Stumpo VM, Gillespie RJ. General chemistry: More than a course in chemistry [1] (multiple letters) Journal of Chemical Education. 69: 945-946.  1
1992 Gillespie RJ, Robinson EA. Bond lengths in covalent fluorides. A new value for the covalent radius of fluorine Inorganic Chemistry. 31: 1960-1963.  1
1991 Adams DC, Birchall T, Faggiani R, Gillespie RJ, Vekris JE. The 119Sn Mössbauer and solid-state NMR and the crystal and molecular structure of tin(II) bisfluorosulfate, Sn(OSO2F)2 Canadian Journal of Chemistry. 69: 2122-2126. DOI: 10.1139/V91-306  0.48
1991 Gillespie RJ. What is wrong with the general chemistry course? Journal of Chemical Education. 68: 192. DOI: 10.1021/Ed068P192  1
1990 Birchall T, Denes G, Faggiani R, Frampton CS, Gillespie RJ, Kapoor R, Vekris JE. Crystal and molecular structure and Raman and sup 127 I Moessbauer spectra of iodine(III) bis(fluorosulfate) iodide, I(OSO sub 2 F) sub 2 I Inorganic Chemistry. 29: 1527-1530. DOI: 10.1021/Ic00333A017  0.48
1990 Gillespie RJ, Kent JP, Sawyer JF. Reactions of tetrasulfur tetranitride and trichlorotrithiatriazene with selenium chlorides. The preparations and crystal structures of SeS2N2Cl2, (S5N5)(SeCl5), and the disordered materials (SexS3-xN2Cl)(SbCl6) Inorganic Chemistry. 29: 1251-1259. DOI: 10.1021/Ic00331A028  0.48
1990 Birchall T, Denes G, Faggiani R, Frampton CS, Gillespie RJ, Kapoor R, Vekris JE. Crystal and molecular structure and Raman and 127I Mössbauer spectra of iodine(III) bis(fluorosulfate) iodide, I(OSO2F)2I Inorganic Chemistry. 29: 1527-1530.  1
1990 Gillespie RJ, Kent JP, Sawyer JF. Reactions of S4N4 and S3N3Cl3 with selenium chlorides. The preparations and crystal structures of SeS2N2Cl2, (S5N5)(SeCl5), and the disordered materials (SexS3-xN2Cl)(SbCl6) Inorganic Chemistry. 29: 1251-1259.  1
1989 Faggiani R, Gillespie RJ, Sawyer JF, Vekris JE. Structures of nonadecasulfur(2+) bis[hexafluoroantimonate(1–)] S19(SbF6)2, octasulfur(2+) di-μ-fluoro-dodecafluorotriantimonate(1–) hexafluoroantimonate(1–) S8(Sb3F14)(SbF6), and tetrasulfur(2+) di-μ-fluoro-difluorodiantimony(2+) μ-fluoro-tetrafluorodiantimony(1+) pentakis[hexafluoroantimonate(1–)] S4(Sb2F4)(Sb2F5)(SbF6)5 Acta Crystallographica Section C-Crystal Structure Communications. 45: 1847-1853. DOI: 10.1107/S0108270189003550  0.48
1988 Gillespie RJ, Liang J. Superacid solutions in hydrogen fluoride. Journal of the American Chemical Society. 110: 6053-7. PMID 22148780 DOI: 10.1021/Ja00226A020  1
1988 Collins MJ, Gillespie RJ, Sawyer JF. Hexatellurium octaselenium hexakis(hexafluoroarsenate) sulfur dioxide Acta Crystallographica Section C-Crystal Structure Communications. 44: 405-409. DOI: 10.1107/S0108270187010795  0.48
1988 Faggiani R, Gillespie RJ, Vekris JE. X-ray diffraction study of Te4S4(AsF 6)2·SO2; an electron-rich S 4N4-type cage Journal of the Chemical Society, Chemical Communications. 902-904. DOI: 10.1039/C39880000902  1
1988 Bader RFW, Gillespie RJ, MacDougall PJ. A physical basis for the VSEPR model of molecular geometry Journal of the American Chemical Society. 110: 7329-7336. DOI: 10.1021/Ja00230A009  1
1988 Faggiani R, Gillespie RJ, Kapoor R, Lock CJL, Vekris JE. Preparation and solid-state and solution studies of three compounds of the tetraiodine dication I42+: I42+(AsF6−)2, I42+(SbF6−)2, and I42+(Sb3F14)(SbF6−) Inorganic Chemistry. 27: 4350-4355. DOI: 10.1021/Ic00297A005  0.48
1988 Burns RC, Collins MJ, Eicher SM, Gillespie RJ, Sawyer JF. Preparation and crystal structures of compounds containing the tellurium-sulfur, TexS6-x2+ and tellurium-selenium TexSe6-x2+ cations Inorganic Chemistry. 27: 1807-1813. DOI: 10.1021/Ic00283A026  0.48
1988 Burns RC, Collins MJ, Eicher SM, Gillespie RJ, Sawyer JF. Preparation and crystal structures of compounds containing the TexS6-x 2+ and TexSe6-x 2+ cations Inorganic Chemistry. 27: 1807-1813.  1
1988 Faggiani R, Gillespie RJ, Kapoor R, Lock CJL, Vekris JE. Preparation and solid-state and solution studies of three compounds of the tetraiodine dication I4 2+: I4 2+(AsF6 -)2, I4 2+(SbF6 -)2, and I4 2+(Sb3F14 -)(SbF 6 -) Inorganic Chemistry. 27: 4350-4355.  1
1987 Christian BH, Gillespie RJ, Sawyer JF. Structure of the occupationally disordered crystal of diphosphorus diarsenic trisulfide Acta Crystallographica Section C-Crystal Structure Communications. 43: 187-189. DOI: 10.1107/S0108270187096495  0.48
1987 Faggiani R, Gillespie RJ, Kolis JW. Preparation and structure of diphenyl hexaselenium bis(hexafluoroarsenate) sulphur dioxide [Ph2Se6][AsF6] 2·SO2 Journal of the Chemical Society, Chemical Communications. 592-593. DOI: 10.1039/C39870000592  1
1987 Faggiani R, Gillespie RJ, Kolis JW, Malhotra KC. Preparation and X-ray structure of (Se9Cl)(SbCl6): A seven-membered selenium ring Journal of the Chemical Society, Chemical Communications. 591-592. DOI: 10.1039/C39870000591  1
1987 Faggiani R, Gillespie RJ, Campana C, Kolis JW. The preparation and structure of [W(CO)4(η3- Te3)][SbF6]2 containing the first three-membered chalcogen ring Journal of the Chemical Society, Chemical Communications. 485-486. DOI: 10.1039/C39870000485  1
1987 Collins MJ, Gillespie RJ, Sawyer JF. Preparation and crystal structures of (Te2Se8) (AsF6)2, (Te4.5Se5.5)(AsF6)2, and (Te2Se6)(Te2Se8)(AsF 6)4(SO2)2 Inorganic Chemistry. 26: 1476-1481. DOI: 10.1021/Ic00257A005  1
1987 Brown ID, Gillespie RJ, Morgan KR, Sawyer JF, Schmidt KJ, Tun Z, Ummat PK, Vekris JE. Preparation and crystal structures of Hg3(NbF5)2SO4, Hg3(TaF5)2SO4, and Hg4(Ta2F11)2 Inorganic Chemistry. 26: 689-693. DOI: 10.1021/Ic00252A012  1
1987 Gillespie RJ, Porterfield WW, Wade K. A "vertex electron pair" scheme (VEPS) for describing the skeletal electron distribution in borane-type clusters Polyhedron. 6: 2129-2135. DOI: 10.1016/S0277-5387(00)84275-8  1
1986 Faggiani R, Gillespie RJ, Vekris JE. The cadmium(I) ion, Cd22+; X-ray crystal structure of Cd2(AlCl4)2 Journal of the Chemical Society, Chemical Communications. 517-518. DOI: 10.1039/C39860000517  1
1986 Collins MJ, Gillespie RJ, Sawyer JF, Schrobilgen GJ. Selenium-77 NMR and Raman study of SxSe4-x 2+ cations and crystal structure of (S3.0Se1.0)2(Sb4F 17)(SbF6)3 containing a disordered mixture of SxSe4-x 2+ cations Inorganic Chemistry. 25: 2053-2057. DOI: 10.1021/Ic00232A029  1
1986 Christian BH, Collins MJ, Gillespie RJ, Sawyer JF. Preparations, Raman spectra, and crystal structures of (SCl3)(SbCl6), (SeCl3)(SbCl6), (SBr1.2Cl1.8)(SbCl6), (TeCl3)(AlCl4) (triclinic modification), (TeCl3)(SbF6), (TeCl3)(AsF6), and (TeF3)2(SO4) Inorganic Chemistry. 25: 777-788. DOI: 10.1021/Ic00226A012  1
1986 Collins MJ, Gillespie RJ, Sawyer JF, Schrobilgen GJ. 77Se NMR and Raman Study of SxSe4 -x2+Cations and Crystal Structure of (S3,0Se1,0)2(Sb4F7)(SbF6)3Containing a Disordered Mixture of SxSe4 -x2+Cations. Cheminform. 17. DOI: 10.1002/Chin.198640006  1
1986 Christian BH, Collins MJ, Gillespie RJ, Sawyer JF. Preparations, Raman Spectra, and Crystal Structures of (SCl3)(SbCl6) (I), (SeCl3)(SbCl6) (II), (SBr1.2Cl1.8)(SbCl6) (III), (TeCl3)(AlCl4) (Triclinic Modification) (IV), (TeCl3)(SbF6) (V), (TeCl3)(AsF6) (VI), and (TeF3)2(SO4) (VII). Cheminform. 17. DOI: 10.1002/Chin.198628005  0.48
1986 Boldrini P, Brown ID, Collins MJ, Gillespie RJ, Maharajh E, Slim DR, Sawyer JF. Preparation and Crystal Structures of (Te2Se2)(Sb3F14)(SbF6) (I) Containing the trans-Te2Se22+Cation and (Te3.0Se1.0)(Sb3F14)(SbF6) (II) Containing a Disordered Mixture of the Cations Te3Se2+, Te42+, and Te2Se22+. Cheminform. 17. DOI: 10.1002/Chin.198612025  0.56
1986 Collins MJ, Gillespie RJ, Kolis JW, Sawyer JF. Preparation and structure of [W2(CO)10Se4][AsF6]2 and related compounds Inorganic Chemistry. 25: 2057-2061.  1
1986 Burns RC, Collins MJ, Gillespie RJ, Schrobilgen GJ. 77Se nuclear magnetic resonance study of Se8 2+ and Se10 2+: Examples of rigid and fluxional species. Disproportionation of Se10 2+ at low temperatures Inorganic Chemistry. 25: 4465-4469.  1
1985 Gillespie RJ, Brown ID, Datars WR, Morgan KR, Tun Z, Ummat PK. The preparation and structure of chain and sheet mercury compounds Philosophical Transactions of the Royal Society A. 314: 105-114. DOI: 10.1098/Rsta.1985.0011  0.36
1985 Boldrini P, Brown ID, Collins MJ, Gillespie RJ, Maharajh E, Slim DR, Sawyer JF. Preparation and crystal structures of (Te2Se2)(Sb3F14)(SbF6) containing the trans-Te2Se22+ cation and (Te3.0Se1.0)(Sb3F14)(SbF6) containing a disordered mixture of the cations Te3Se2+, Te42+, and Te2Se22+ Inorganic Chemistry. 24: 4302-4307. DOI: 10.1021/Ic00219A021  0.56
1985 Datars WR, Ummat PK, Gillespie RJ. Transformation between Hg3MF6 and Hg3-δMF6: M = Nb and Ta Materials Research Bulletin. 20: 865-869. DOI: 10.1016/0025-5408(85)90068-6  1
1985 Brown ID, Datars WR, Gillespie RJ, Morgan KR, Tun Z, Ummat PK. Preparation, structure, and properties of mercury layer and chain compounds Journal of Solid State Chemistry. 57: 34-42. DOI: 10.1002/Chin.198535357  1
1985 Collins MJ, Denes G, Gillespie RJ. Iodine(Iii) Bisfluorosulfate Iodide. The X-Ray Crystal Structure Of I(Oso2F)2I Cheminform. 16. DOI: 10.1002/Chin.198505037  0.48
1985 Boldrini P, David Brown I, Collins MJ, Gillespie RJ, Maharajh E, Slim DR, Sawyer JF. Preparation and crystal structures of (Te2Se2)(Sb3F14)(SbF6) containing the trans-Te2Se2 2+ cation and (Te3.0Se1.0) (Sb3F14)(SbF6) containing a disordered mixture of the cations Te3Se2+, Te4 2+, and Te .. Inorganic Chemistry. 24: 4302-4307.  1
1984 Collins MJ, Dénès G, Gillespie RJ. Lodine (III) Bis-fluorosulphate Iodide. The X-Ray crystal structure of l(OSO2F)2l Journal of the Chemical Society - Series Chemical Communications. 1296-1297. DOI: 10.1039/C39840001296  1
1984 Brown ID, Gillespie RJ, Morgan KR, Tun Z, Ummat PK. Preparation and crystal structure of mercury hexafluoroniobate (Hg3NbF6) and mercury hexafluorotantalate (Hg3TaF6): mercury layer compounds Inorganic Chemistry. 23: 4506-4508. DOI: 10.1021/Ic00194A020  0.36
1984 Collins MJ, Gillespie RJ. A selenium-77 and tellurium-125 NMR study of the Te2Se62+ cation: magnetic inequivalence of heavy nuclei Inorganic Chemistry. 23: 1975-1978. DOI: 10.1021/Ic00181A037  0.48
1984 Collins MJ, Gillespie RJ. A Selenium-77 And Tellurium-125 Nmr Study Of The Te2Se62+ Cation: Magnetic Inequivalence Of Heavy Nuclei Cheminform. 15. DOI: 10.1002/Chin.198437004  0.48
1984 Gillespie RJ, Granger P, Morgan KR, Schrobilgen GJ. 199Hg NMR study of the Hg2+, Hg2 2+, Hg3 2+, and Hg4 2+ cations: The first example of Hg-Hg spin-spin coupling Inorganic Chemistry. 23: 887-891.  1
1984 Collins MJ, Gillespie RJ. A 77Se and 125Te NMR study of the Te2Se6 2+ cation: Magnetic inequivalence of heavy nuclei Inorganic Chemistry. 23: 1975-1978.  1
1984 Brown ID, Gillespie RJ, Morgan KR, Tun Z, Ummat PK. Preparation and crystal structure of Hg3NbF6 and Hg3TaF6: Mercury layer compounds Inorganic Chemistry. 23: 4506-4508.  1
1983 Datars WR, Morgan KR, Gillespie RJ. Superconductivity of Hg3NbF6 and Hg3TaF6 Physical Review B. 28: 5049-5052. DOI: 10.1103/PhysRevB.28.5049  1
1983 Gillespie RJ. 51V and 19F N.M.R. study of VO2F43– in solution Journal of the Chemical Society - Series Chemical Communications. 422-423. DOI: 10.1039/C39830000422  1
1983 Gillespie RJ, Kapoor R, Faggiani R, Lock CJL, Murchie M, Passmoreb J. The I42+ cation. X-ray crystal structures of (I42+)(AsF6)2 and (I42-)(Sb3F14)(SbF6) Journal of the Chemical Society - Series Chemical Communications. 8-9. DOI: 10.1039/C39830000008  1
1983 Cutforth BD, Gillespie RJ, Ireland P, Sawyer JF, Ummat PK. Preparation and crystal structure of tetramercury bis(hexafluoroarsenate), Hg4(AsF6)2 Inorganic Chemistry. 22: 1344-1347. DOI: 10.1021/Ic00151A015  1
1983 Burns RC, Gillespie RJ. Vibrational spectra and analysis of Te4+ 6, a trigonal-prismatic cluster cation Spectrochimica Acta Part a: Molecular Spectroscopy. 39: 439-447. DOI: 10.1016/0584-8539(83)80159-7  1
1983 Gillespie RJ, Kapoor R, Faggiani R, Lock CJL, Murchie M, Passmore J. The I4 2+ cation. X-ray crystal structures of (I 4 2+)(AsF6 )2 and (I4 2+)(Sb3F14 -)(SbF6 -) Journal of the Chemical Society, Chemical Communications. 8-9.  1
1983 Chartier D, Datars WR, Gillespie RJ. DIFFERENTIAL THERMAL ANALYSIS OF LINEAR CHAIN MERCURY COMPOUNDS Canadian Journal of Physics. 61: 71-75.  1
1982 Cardinal G, Gillespie RJ, Sawyer JF, Vekris JE. Charge-transfer interactions in the square-planar chalcogen cations, M 42+: Preparation and crystal structures of the compounds (Se42+)- (Sb2F42+).. Journal of the Chemical Society, Dalton Transactions. 765-779. DOI: 10.1039/Dt9820000765  1
1982 Gillespie RJ, Sawyer JF, Slim DR, Tyrer JD. Reactions of trifluorocyclotrithiazene (S3N3F3) and trichlorocyclotrithiazene (S3N3Cl3) with Lewis acids. Preparation and crystal structure of pentathiazyl hexachloroantimonate (S5N5)(SbCl6) Inorganic Chemistry. 13: 1296-1302. DOI: 10.1021/Ic00134A003  0.56
1982 Burns RC, Gillespie RJ, Barnes JA, McGlinchey MJ. Molecular orbital investigation of the structure of some polyatomic cations and anions of the main-group elements Inorganic Chemistry. 21: 799-807. DOI: 10.1021/Ic00132A065  1
1982 Cardinal G, Gillespie RJ, Sawyer JF, Vekris JE. Charge-Transfer Interactions In The Square-Planar Chalcogen Cations, M42+: Preparation And Crystal Structures Of The Compounds (Se42+)(Sb2F42+)(Sb2F5+)(Sbf6-)5, (Se42+)(Alcl4-)2, And (Te42+)(Sbf6-)2 Cheminform. 13. DOI: 10.1002/Chin.198227033  0.48
1982 Gillespie RJ, Kent JP, Sawyer JF, Slim DR, Tyrer JD. Reactions Of Sulfur Nitride (S4N4) With Antimony Pentachloride, Antimony Pentafluoride, Arsenic Pentafluoride, Phosphorus Pentafluoride, And Fluorosulfuric Acid. Preparation And Crystal Structures Of Salts Of The S4N42+ Cation: (S4N4) Cheminform. 13. DOI: 10.1002/Chin.198205032  0.56
1982 Gillespie RJ, Sawyer JF, Slim DR, Tyrer JD. Reactions of S3N3F3 and S3N3Cl3 with Lewis acids. Preparation and crystal structure of pentathiazyl hexachloroantimonate, (S5N5)(SbCl6) Inorganic Chemistry. 21: 1296-1302.  1
1982 Burns RC, Gillespie RJ. Vibrational spectra and analyses of the S4 2+, Se4 2+, Te4 2+, and trans-Te2Se2 2+ polyatomic cations Inorganic Chemistry. 21: 3877-3886.  1
1981 Gillespie RJ, Kent JP, Sawyer JF, Slim DR, Tyrer JD. Reactions of sulfur nitride (S4N4) with antimony pentachloride, antimony pentafluoride, arsenic pentafluoride, phosphorus pentafluoride, and fluorosulfuric acid. Preparation and crystal structures of salts of the S4N42+ cation: (S4N4)(Sb3F14)(SbF6), (S4N4)(SO3F)2, (S4N4)(AsF6)2.cntdot.SO2, (S4N4)(AlCl4)2, and (S4N4)(SbCl6)2 Inorganic Chemistry. 20: 3799-3812. DOI: 10.1021/Ic50225A042  0.56
1981 Christian BH, Gillespie RJ, Sawyer JF. Preparation, x-ray crystal structures and vibrational spectra of some salts of the arsenic-sulfur (As3S4+) and arsenic-selenium (As3Se4+) cations Inorganic Chemistry. 13: 3410-3420. DOI: 10.1021/Ic50224A051  0.48
1981 Batalla E, Datars WR, Chartier D, Gillespie RJ. dHvA effect in Hg3-δSbF6 Solid State Communications. 38: 1203-1205. DOI: 10.1016/0038-1098(81)90988-1  1
1981 Batalla E, Datars WR, Chartier D, Gillespie RJ. Pressure dependence of the Fermi surface of Hg3-δAsF6 Solid State Communications. 40: 711-714. DOI: 10.1016/0038-1098(81)90812-7  1
1981 Gillespie RJ, Kent JP, Sawyer JF. Preparation and crystal structures of the hexafluoroarsenate and hexafluoroantimonate salts of the dimeric thiodiselenazyl cation Se4S2N4 2+ Inorganic Chemistry. 20: 4053-4060.  1
1981 Gillespie RJ, Kent JP, Sawyer JF, Slim DR, David Tyrer J. Reactions of S4N4 with SbCl5, SbF5, AsF5, PF5, and HSO3F. Preparation and crystal structures of salts of the S4N4 2+ cation Inorganic Chemistry. 20: 3799-3812.  1
1981 Gillespie RJ, Kent JP, Sawyer JF. Monomeric and dimeric thiodithiazyl cations, S3N2 + and S6N4 2+. Preparation and crystal structures of (S3N2)(AsF6), (S6N4)(S2O2F)2, and (S6N4)(SO3F)2 Inorganic Chemistry. 20: 3784-3799.  1
1981 Christian BH, Gillespie RJ, Sawyer JF. Preparation, X-ray crystal structures, and vibrational spectra of some salts of the As3S4 + and As3Se4 + cations Inorganic Chemistry. 20: 3410-3420.  1
1980 Faggiani R, Gillespie RJ, Sawyer JF, Tyrer JD. Bis (trichlorophosphine)iminium hexachlorophosphate Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 36: 1014-1017. DOI: 10.1107/S0567740880005195  0.48
1980 Gillespie RJ, Kent JP, Sawyer JF. The molecular adduct cyclotetra(azathiene)–arsenic pentafluoride Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 36: 655-657. DOI: 10.1107/S0567740880004001  0.48
1980 Faggiani R, Gillespie RJ, Lock CJL, Pocé J. The structure of ammonium pertechnetate at 295, 208 and 141 K Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry. 36: 231-233. DOI: 10.1107/S0567740880002993  0.48
1980 Gillespie RJ, Krasznai JP, Slim DR. Crystal structure of (IOF3·IO2F3)2 Journal of the Chemical Society, Dalton Transactions. 481-483. DOI: 10.1039/Dt9800000481  1
1980 Burns RC, Gillespie RJ, Sawyer JF. Preparation and crystal structure of nonadecasulfur bis(hexafluoroarsenate) and an ESR and absorption spectral study of solutions containing the nonadecasulfur(2+) cation and related systems Inorganic Chemistry. 19: 1423-1432. DOI: 10.1021/Ic50208A002  0.48
1980 Gillespie RJ, Humphreys DA. Some conclusions and recommendations from the Mcmaster conference Journal of Chemical Education. 57: 348. DOI: 10.1021/Ed057P348  1
1980 Robinson EA, Gillespie RJ. Bent bonds and multiple bonds Journal of Chemical Education. 57: 329-333. DOI: 10.1021/Ed057P329  1
1980 Gillespie RJ, Martin D, Schrobilgen GJ. A Raman spectroscopic study of noble-gas fluoride adduct formation with bismuth pentafluoride Journal of the Chemical Society, Dalton Transactions. 1898-1903. DOI: 10.1002/Chin.198101033  1
1980 Burns RC, Gillespie RJ, Sawyer JF. Preparation and crystal structure of nonadecasulfur bis(hexafluoroarsenate) and an ESR and absorption spectral study of solutions containing the nonadecasulfur(2+) cation and related systems Cheminform. 11. DOI: 10.1002/Chin.198036027  0.48
1980 Gillespie RJ, Krasznai JP, Slim DR. Crystal Structure Of (Iof3.Cntdot.Io2F3)2 Cheminform. 11. DOI: 10.1002/Chin.198019006  0.56
1980 Burns RC, Gillespie RJ, Sawyer JF. Preparation and crystal structure of S19(AsF6)2 and an ESR and absorption spectral study of solutions containing the S19 2+ cation and related systems Inorganic Chemistry. 19: 1423-1432.  1
1980 Burns RC, Chan WL, Gillespie RJ, Luk WC, Sawyer JF, Slim DR. Preparation and characterization of Se10(AsF6)2, Se10(AsF6)2, and Se10(AlCl4)2 and crystal structure of Se10(SbF6)2 Inorganic Chemistry. 19: 1432-1439.  1
1979 Razavi FS, Datars WR, Chartier D, Gillespie RJ. Fermi surface of incommensurate mercury-chain compounds Physical Review Letters. 42: 1182-1185. DOI: 10.1103/Physrevlett.42.1182  1
1979 Gillespie RJ. Nyholm Memorial Lecture. Ring, cage, and cluster compounds of the main group elements Chemical Society Reviews. 8: 315-352. DOI: 10.1039/CS9790800315  1
1979 Burns RC, Gillespie RJ, Luk W, Slim DR. Preparation, spectroscopic properties, and crystal structures of Te6(AsF6)4.2AsF3 and Te6(AsF6)4.2SO2: a new trigonal-prismatic cluster cation, hexatellurium(4+) Inorganic Chemistry. 11: 3086-3094. DOI: 10.1021/Ic50201A028  0.56
1979 Bougon R, Huy TB, Charpin P, Gillespie RJ, Spekkens PH. Preparation and characterization of some salts of the difluoro-oxobromine(v) cation Journal of the Chemical Society, Dalton Transactions. 6-12. DOI: 10.1002/Chin.197913038  1
1979 Burns RC, Gillespie RJ, Luk WC, Slim DR. Preparation, spectroscopic properties, and crystal structures of Te6(AsF6)4·2AsF3 and Te6(AsF6)4·2SO2: A new trigonal-prismatic cluster cation, Te6 4+ Inorganic Chemistry. 18: 3086-3094.  1
1978 Bruce RB, Gillespie RJ, Slim DR. The crystal structures of S7NSN(CH3)2 and (C6H11)2NSN(C6H11)2 Canadian Journal of Chemistry. 56: 2927-2933. DOI: 10.1139/V78-480  0.56
1978 Burns RC, Gillespie RJ, Luk W. The preparation, spectroscopic properties, and structure of the pentabismuth(3+) cation, Bi53+ Inorganic Chemistry. 10: 3596-3604. DOI: 10.1021/Ic50190A053  0.32
1978 Faggiani R, Gillespie RJ, Lock CJL, Tyrer JD. Preparation, vibrational spectra, and crystal structure of dithionitronium hexachloroantimonate(V), (S2N)(SbCl6) Inorganic Chemistry. 10: 2975-2978. DOI: 10.1021/Ic50189A002  0.48
1978 Gillespie RJ, Martin D, Schrobilgen GJ, Slim DR. The Crystal Structure Of Trifluoroxenon(Iv) Hexafluorobismuthate(V)- The Fluoride-Acceptor Strength Of Bismuth Pentafluoride Cheminform. 9. DOI: 10.1002/Chin.197807002  1
1977 Gillespie RJ, Martin D, Schrobilgen GJ, Slim DR. The crystal structure of trifluoroxenon(IV) hexafluorobismuthate(V): The fluoride-acceptor strength of bismuth pentafluoride Journal of the Chemical Society, Dalton Transactions. 2234-2237. DOI: 10.1039/Dt9770002234  1
1977 Gillespie RJ, Schrobilgen GJ, Slim DR. Crystal structure of μ-fluorosulphato-bis[fluoroxenon(II)] hexafluoroarsenate(V) Journal of the Chemical Society, Dalton Transactions. 1003-1006. DOI: 10.1039/Dt9770001003  1
1977 Gillespie RJ, Slim DR, Vekris JE. The crystal structure of the 1 : 1 adduct of antimony trifluoride and antimony pentafluoride Journal of the Chemical Society-Dalton Transactions. 971-974. DOI: 10.1039/Dt9770000971  0.56
1977 Gillespie RJ, Slim DR, Tyrer JD. A new cationic S–N ring system, S4N42+. The crystal structure of cyclotetrathiazyl bis hexachloroantimonate(V), [S4N4][SbCl6]2, and cyclotetrathiazyl hexafluoroantimonate(V) tetradecafluorotriantimonate, [S4N4][SbF6][Sb3F14] Journal of the Chemical Society, Chemical Communications. 253-255. DOI: 10.1039/C39770000253  0.56
1977 Gillespie RJ, Luk W, Maharajh E, Slim DR. Preparation and crystal structures of tritellurium trisulfur bis(hexafluoroarsenate), ditellurium tetraselenium bis(hexafluoroantimonate), and ditellurium tetraselenium bis(hexafluoroarsenate) Inorganic Chemistry. 16: 892-896. DOI: 10.1021/Ic50170A034  0.56
1977 Gillespie RJ, Schrobilgen GJ, Slim DR. CRYSTAL STRUCTURE OF μ-FLUOROSULFATO-BIS(FLUOROXENON(II)) HEXAFLUOROARSENATE(V) Cheminform. 8. DOI: 10.1002/Chin.197732006  1
1977 Gillespie RJ, Slim DR, Vekris JE. The Crystal Structure Of The 1-1 Adduct Of Antimony Trifluoride And Antimony Pentafluoride Cheminform. 8. DOI: 10.1002/Chin.197732005  0.56
1976 Boldrini P, Brown ID, Gillespie RJ, Ireland PR, Luk W, Slim DR, Vekris JE. Preparation and crystal structures of ditellurium octaselenium bis(hexafluoroarsenate)-sulfur dioxide Te2Se8(AsF6)2 . SO2, and "tetratellurium hexaselenium" bis(hexafluoroarsenate) Te3.7Se6.3(AsF6)2 Inorganic Chemistry. 15: 765-770. DOI: 10.1021/Ic50158A004  0.56
1974 Gillespie RJ, Schrobilgen GJ. Preparation of the KrF+, Kr2F3 +, and BrF6+ ions and their characterisation by 19F nuclear magnetic resonance and Raman spectroscopy Journal of the Chemical Society, Chemical Communications. 90-92. DOI: 10.1039/C39740000090  1
1973 Gillespie RJ, Hulme R. The hydrogen fluoride solvent system. Part VI. Solutions of hydrogen cyanide, silver(I) cyanide, and hexacyanoferric(II) acid: Formation of the difluoromethylammonium cation Journal of the Chemical Society, Dalton Transactions. 1261-1267. DOI: 10.1039/Dt9730001261  1
1972 Gillespie RJ, Landa B, Schrobilgen GJ. Preparation of XeOF3+·Sb2F11– and XeO2F+·Sb2F11–. 19F nuclear magnetic resonance and Raman spectra of XeOF3+ and XeO2F+ Journal of the Chemical Society, Chemical Communications. 607-609. DOI: 10.1039/C39720000607  1
1971 Gillespie RJ, Hulme R, Humphreys DA. The hydrogen fluoride solvent system. Part IV. Solutions of mercury(II) cyanide. Evidence for the Hg2(CN)3 + cation Journal of the Chemical Society a: Inorganic, Physical, and Theoretical Chemistry. 3574-3578. DOI: 10.1039/J19710003574  1
1971 Dean PAW, Gillespie RJ, Hulme R, Humphreys DA. Hydrogen fluoride solvent system. Part III. Solutions of the acids SbF 5, AsF5, and PF5. Evidence for the As 2F11 - ion Journal of the Chemical Society a: Inorganic, Physical, and Theoretical Chemistry. 341-346. DOI: 10.1039/J19710000341  1
1969 Gillespie RJ, Malhotra KC. Cations and oxycations of iodine. VI. Solutions of some iodine compounds in disulfuric acid Inorganic Chemistry. 8: 1751-1756. DOI: 10.1021/Ic50078A038  0.4
1968 Barr J, Gillespie RJ, Kapoor R, Malhotra KC. New polyatomic cations of the group VI B elements: I. Solutions of selenium in highly acidic solvents Canadian Journal of Chemistry. 46: 149-159. DOI: 10.1139/V68-026  0.4
1953 GILLESPIE RJ, MAW GA, VERNON CA. The concept of phosphate bond-energy. Nature. 171: 1147-9. PMID 13072522 DOI: 10.1038/1711147a0  0.52
1949 GILLESPIE RJ, HUGHES ED. Kinetics and mechanism of aromatic nitration. Nature. 163: 599. PMID 18224956  1
1946 GILLESPIE RJ, GRAHAM J. Cryoscopic proof of the formation of nitronium ion. Nature. 158: 480. PMID 20999109 DOI: 10.1038/158480A0  1
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