Richard Hadley Holm - Publications

Affiliations: 
1962-1965 Harvard University, Cambridge, MA, United States 
 1965-1967 University of Wisconsin, Madison, Madison, WI 
 1967-1975 Massachusetts Institute of Technology, Cambridge, MA, United States 
 1975-1980 Stanford University, Palo Alto, CA 
 1980-2021 Chemistry Harvard University, Cambridge, MA, United States 
Area:
transition element chemistry
Website:
http://faculty.chemistry.harvard.edu/holm

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Year Citation  Score
2019 Xu G, Zhou J, Wang Z, Holm RH, Chen XD. Controlled Incorporation of Nitrides into W-Fe-S Clusters. Angewandte Chemie (International Ed. in English). PMID 31489739 DOI: 10.1002/Anie.201908968  1
2018 Xu G, Wang Z, Ling R, Zhou J, Chen XD, Holm RH. Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron-sulfur clusters relevant to the FeMo cofactor. Proceedings of the National Academy of Sciences of the United States of America. PMID 29654147 DOI: 10.1073/Pnas.1801025115  1
2016 Holm RH, Lo W. Structural Conversions of Synthetic and Protein-Bound Iron-Sulfur Clusters. Chemical Reviews. 116: 13685-13713. PMID 27933770 DOI: 10.1021/Acs.Chemrev.6B00276  1
2014 Ha Y, Tenderholt AL, Holm RH, Hedman B, Hodgson KO, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on monooxo Mo(IV) and bisoxo Mo(VI) bis-dithiolenes: insights into the mechanism of oxo transfer in sulfite oxidase and its relation to the mechanism of DMSO reductase. Journal of the American Chemical Society. 136: 9094-105. PMID 24884723 DOI: 10.1021/Ja503316P  1
2014 Holm RH, Solomon EI. Introduction: Bioinorganic enzymology II. Chemical Reviews. 114: 4039-40. PMID 24758378 DOI: 10.1021/Cr5001332  1
2014 Holm RH, Solomon EI. Introduction: bioinorganic enzymology II. Chemical Reviews. 114: 3367-8. PMID 24712923 DOI: 10.1021/cr500118g  1
2014 Troeppner O, Huang D, Holm RH, Ivanovi?-Burmazovi? I. Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(II) complex. Dalton Transactions (Cambridge, England : 2003). 43: 5274-9. PMID 24572679 DOI: 10.1039/C3Dt53004C  1
2014 Lee SC, Lo W, Holm RH. Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters. Chemical Reviews. 114: 3579-600. PMID 24410527 DOI: 10.1021/Cr4004067  1
2013 Tan LL, Holm RH, Lee SC. Structural Analysis of Cubane-Type Iron Clusters. Polyhedron. 58: 206-217. PMID 24072952 DOI: 10.1016/J.Poly.2013.02.031  1
2012 Zhang X, Huang D, Chen YS, Holm RH. Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features. Inorganic Chemistry. 51: 11017-29. PMID 23030366 DOI: 10.1021/Ic301506X  1
2012 Lo W, Zhang P, Ling CC, Huang S, Holm RH. Formation, spectroscopic characterization, and solution stability of an [Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate. Inorganic Chemistry. 51: 9883-92. PMID 22934734 DOI: 10.1021/Ic301324U  1
2012 Holm RH, Maroney MJ. 50 Years of metals in biology: the Gordon Research Conference. Metallomics : Integrated Biometal Science. 4: 401-2. PMID 22535189 DOI: 10.1039/C2Mt90017C  1
2012 Zheng B, Chen XD, Zheng SL, Holm RH. Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants. Journal of the American Chemical Society. 134: 6479-90. PMID 22424175 DOI: 10.1021/Ja3010539  1
2012 Tenderholt AL, Hodgson KO, Hedman B, Holm RH, Solomon EI. Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites. Inorganic Chemistry. 51: 3436-42. PMID 22372518 DOI: 10.1021/Ic2020397  1
2012 Holm RH. Recent history provides sustainable African water quality project insight. Ground Water. 50: 808-11. PMID 22070428 DOI: 10.1111/j.1745-6584.2011.00888.x  1
2011 Majumdar A, Holm RH. Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters. Inorganic Chemistry. 50: 11242-51. PMID 21985054 DOI: 10.1021/Ic2018117  1
2011 Lo W, Huang S, Zheng SL, Holm RH. Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization. Inorganic Chemistry. 50: 11082-90. PMID 21942299 DOI: 10.1021/Ic2016269  1
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates. Inorganic Chemistry. 50: 10070-81. PMID 21905646 DOI: 10.1021/Ic200942U  1
2011 Xi B, Holm RH. The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state. Inorganic Chemistry. 50: 6280-8. PMID 21648449 DOI: 10.1021/Ic200641K  1
2011 Lo W, Scott TA, Zhang P, Ling CC, Holm RH. Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous media. Journal of Inorganic Biochemistry. 105: 497-508. PMID 21329647 DOI: 10.1016/J.Jinorgbio.2010.12.009  1
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction. Proceedings of the National Academy of Sciences of the United States of America. 108: 1222-7. PMID 21220298 DOI: 10.1073/Pnas.1017430108  1
2011 Holm RH. Topics in African water quality development Proceedings - 2011 Ieee Global Humanitarian Technology Conference, Ghtc 2011. 267-275. DOI: 10.1109/GHTC.2011.103  1
2011 Holm RH, Solomon EI, Majumdar A, Tenderholt A. Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes Coordination Chemistry Reviews. 255: 993-1015. DOI: 10.1016/J.Ccr.2010.10.017  1
2010 Deng L, Majumdar A, Lo W, Holm RH. Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states. Inorganic Chemistry. 49: 11118-26. PMID 21038882 DOI: 10.1021/Ic101702B  1
2010 Tenderholt AL, Wang JJ, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues. Journal of the American Chemical Society. 132: 8359-71. PMID 20499905 DOI: 10.1021/Ja910369C  1
2010 Huang D, Holm RH. Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site. Journal of the American Chemical Society. 132: 4693-701. PMID 20218565 DOI: 10.1021/Ja1003125  1
2010 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. The modular nature of all-ferrous edge-bridged double cubanes. Inorganic Chemistry. 49: 1647-50. PMID 20073485 DOI: 10.1021/Ic902050K  1
2010 Groysman S, Majumdar A, Zheng SL, Holm RH. Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. Inorganic Chemistry. 49: 1082-9. PMID 20030373 DOI: 10.1021/Ic902066M  1
2010 Zhou H, Su W, Achim C, Rao PV, Holm RH. ChemInform Abstract: High-Nuclearity Sulfide-Rich Molybdenum-Iron-Sulfur Clusters: Reevaluation and Extension. Cheminform. 33: no-no. DOI: 10.1002/chin.200237025  0.01
2010 Gray TG, Rudzinski CM, Nocera DG, Holm RH. ChemInform Abstract: Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re6S8]2+ and [Re6Se8]2+. Cheminform. 31: no-no. DOI: 10.1002/chin.200009009  0.01
2010 FRANOLIC JD, LONG JR, HOLM RH. ChemInform Abstract: Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of (W6I14)2-. Cheminform. 26: no-no. DOI: 10.1002/chin.199547044  0.01
2010 LONG JR, WILLIAMSON AS, HOLM RH. ChemInform Abstract: Dimensional Reduction of Re6S8Cl2: Sheets, Chains and Discrete Clusters Composed of Chloride-Terminated (Re6Q8)2+ (Q: S, Se) Cores. Cheminform. 26: no-no. DOI: 10.1002/chin.199517018  0.04
2010 SCHULTZ BE, GHELLER SF, MUETTERTIES MC, SCOTT MJ, HOLM RH. ChemInform Abstract: Molybdenum-Mediated Oxygen Atom Transfer: An Improved Analogue Reaction System of the Molybdenum Oxotransferases. Cheminform. 24: no-no. DOI: 10.1002/chin.199335126  0.04
2010 HOLM RH, DONAHUE JP. ChemInform Abstract: A Thermodynamic Scale for Oxygen Atom Transfer Reactions Cheminform. 24: no-no. DOI: 10.1002/chin.199328330  0.01
2010 YAGHI OM, SCOTT MJ, HOLM RH. ChemInform Abstract: Rhenium-Selenium-Chlorine Solid Phases: Cluster Excision and Core Substitution Reactions of Molecular Species. Cheminform. 24: no-no. DOI: 10.1002/chin.199306034  0.01
2010 HOLM RH, CIURLI S, WEIGEL JA. ChemInform Abstract: Subsite-Specific Structures and Reactions in Native and Synthetic (4Fe - 4S) Cubane-Type Clusters Cheminform. 22: no-no. DOI: 10.1002/CHIN.199139264  0.01
2009 Deng L, Bill E, Wieghardt K, Holm RH. Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states. Journal of the American Chemical Society. 131: 11213-21. PMID 19722678 DOI: 10.1021/Ja903847A  1
2009 Huang D, Deng L, Sun J, Holm RH. Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer complexes and related reactions. Inorganic Chemistry. 48: 6159-66. PMID 19459662 DOI: 10.1021/Ic900494U  1
2009 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site. Inorganic Chemistry. 48: 2735-47. PMID 19326927 DOI: 10.1021/Ic802192W  1
2009 Groysman S, Holm RH. Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites. Biochemistry. 48: 2310-20. PMID 19206188 DOI: 10.1021/Bi900044E  1
2009 Groysman S, Holm RH. A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically demanding thiolate ligand. Inorganic Chemistry. 48: 621-7. PMID 19138143 DOI: 10.1021/Ic801836K  1
2008 Groysman S, Wang JJ, Tagore R, Lee SC, Holm RH. A biomimetic approach to oxidized sites in the xanthine oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes. Journal of the American Chemical Society. 130: 12794-807. PMID 18763763 DOI: 10.1021/Ja804000K  1
2008 Deng L, Holm RH. Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8). Journal of the American Chemical Society. 130: 9878-86. PMID 18593124 DOI: 10.1021/Ja802111W  1
2008 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study. Inorganic Chemistry. 47: 6382-92. PMID 18517189 DOI: 10.1021/Ic800494H  1
2008 Scott TA, Holm RH. VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal. Inorganic Chemistry. 47: 3426-32. PMID 18366157 DOI: 10.1021/Ic702372F  1
2008 McNaughton RL, Lim BS, Knottenbelt SZ, Holm RH, Kirk ML. Spectroscopic and electronic structure studies of symmetrized models for reduced members of the dimethylsulfoxide reductase enzyme family. Journal of the American Chemical Society. 130: 4628-36. PMID 18341333 DOI: 10.1021/Ja074691B  1
2008 Pryadun R, Holm RH. A new class of binuclear and trinuclear iron-sulfur clusters derived from bis[bis(trimethylsilyl)amido]iron(II). Inorganic Chemistry. 47: 3366-70. PMID 18327895 DOI: 10.1021/Ic7023742  1
2008 Lee SC, Holm RH. Toward an expanded oxygen atom transfer reactivity scale: Computational investigation of the energetics of oxo transfer reaction couples Inorganica Chimica Acta. 361: 1166-1176. DOI: 10.1016/J.Ica.2007.10.047  1
2008 Holm RH. Helmut Beinert (1913–2007) Jbic Journal of Biological Inorganic Chemistry. 13: 319-319. DOI: 10.1007/s00775-008-0355-x  0.01
2007 Wang JJ, Holm RH. Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and oxosulfidomolybdates(VI) and -tungstates(VI). Inorganic Chemistry. 46: 11156-64. PMID 18044955 DOI: 10.1021/Ic701294Y  1
2007 Hlavinka ML, Miyaji T, Staples RJ, Holm RH. Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-bridged double cubanes: oxygen-ligated topological PN clusters. Inorganic Chemistry. 46: 9192-200. PMID 17892284 DOI: 10.1021/Ic701070W  1
2007 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. Journal of Inorganic Biochemistry. 101: 1594-600. PMID 17720249 DOI: 10.1016/J.Jinorgbio.2007.07.011  1
2007 Wang JJ, Groysman S, Lee SC, Holm RH. Synthesis of structural analogues of the oxidized sites in the xanthine oxidoreductase enzyme family. Journal of the American Chemical Society. 129: 7512-3. PMID 17530853 DOI: 10.1021/Ja0724442  1
2007 Groysman S, Holm RH. Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases. Inorganic Chemistry. 46: 4090-102. PMID 17432849 DOI: 10.1021/Ic062441A  1
2007 Sun J, Tessier C, Holm RH. Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorganic Chemistry. 46: 2691-9. PMID 17346040 DOI: 10.1021/Ic062362Z  1
2007 Pesavento RP, Berlinguette CP, Holm RH. Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligation. Inorganic Chemistry. 46: 510-6. PMID 17279830 DOI: 10.1021/Ic061704Y  1
2007 Holm R, Söderberg D. Shear influence on fibre orientation Rheologica Acta. 46: 721-729. DOI: 10.1007/S00397-007-0166-Y  0.01
2007 Holm RH, Ciurli S, Weigel JA. Subsite‐Specific Structures and Reactions in Native and Synthetic [4Fe‐4S] Cubane‐Type Clusters Progress in Inorganic Chemistry. 38: 1-74. DOI: 10.1002/9780470166390.Ch1  1
2006 Berlinguette CP, Holm RH. Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophile. Journal of the American Chemical Society. 128: 11993-2000. PMID 16953641 DOI: 10.1021/Ja063604X  1
2006 Bennett MV, Holm RH. Self-assembly of a tetradecanuclear iron nitride cluster. Angewandte Chemie (International Ed. in English). 45: 5613-6. PMID 16858715 DOI: 10.1002/Anie.200601570  1
2006 Wang JJ, Tessier C, Holm RH. Analogue reaction systems of selenate reductase. Inorganic Chemistry. 45: 2979-88. PMID 16562954 DOI: 10.1021/Ic0521630  1
2006 Berlinguette CP, Miyaji T, Zhang Y, Holm RH. Precursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer series. Inorganic Chemistry. 45: 1997-2007. PMID 16499360 DOI: 10.1021/Ic051770K  1
2006 Friedle S, Partyka DV, Bennett MV, Holm RH. Synthesis of metal dithiolene complexes by Si-S bond cleavage of a bis(silanylsulfanyl)alkene Inorganica Chimica Acta. 359: 1427-1434. DOI: 10.1016/J.Ica.2005.09.067  1
2006 Braverman MP, Kunkel DL, Baron JJ, Holm RH. Regulatory considerations for researchers of natural products in the United States Acs Symposium Series. 927: 278-288.  1
2005 Bennett MV, Stoian S, Bominaar EL, Münck E, Holm RH. Initial members of the family of molecular mid-valent high-nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-). Journal of the American Chemical Society. 127: 12378-86. PMID 16131219 DOI: 10.1021/Ja052150L  1
2005 Panda R, Berlinguette CP, Zhang Y, Holm RH. Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 127: 11092-101. PMID 16076217 DOI: 10.1021/Ja052381S  1
2005 Scott TA, Berlinguette CP, Holm RH, Zhou HC. Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein. Proceedings of the National Academy of Sciences of the United States of America. 102: 9741-4. PMID 15985547 DOI: 10.1073/Pnas.0504258102  1
2005 Jiang J, Holm RH. Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes. Inorganic Chemistry. 44: 1068-72. PMID 15859288 DOI: 10.1021/Ic040109Y  1
2005 Rao PV, Bhaduri S, Jiang J, Hong D, Holm RH. On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase. Journal of the American Chemical Society. 127: 1933-45. PMID 15701028 DOI: 10.1021/Ja040222N  1
2005 Holm R, Söderberg D. A theoretical analysis of the flow stability in roll forming of paper Nordic Pulp & Paper Research Journal. 20: 212-216. DOI: 10.3183/npprj-2005-20-02-p212-216  0.01
2005 Holm R, Söderberg D, Norman B. Experimental studies on dewatering during roll forming of paper Nordic Pulp & Paper Research Journal. 20: 205-211. DOI: 10.3183/npprj-2005-20-02-p205-211  0.01
2005 Mastro MA, Eddy CR, Bassim ND, Twigg ME, Edwards A, Henry RL, Holm RH. Theoretical study of the influence of strain and polarization on performance of AlGaN/4H-SiC HBT Solid-State Electronics. 49: 251-256. DOI: 10.1016/j.sse.2004.08.015  1
2005 Hong D, Zhang Y, Holm RH. Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate Inorganica Chimica Acta. 358: 2303-2311. DOI: 10.1016/J.Ica.2004.11.051  1
2004 Dey A, Glaser T, Moura JJ, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment. Journal of the American Chemical Society. 126: 16868-78. PMID 15612726 DOI: 10.1021/Ja0466208  1
2004 Partyka DV, Holm RH. Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon and silicon reagents. Inorganic Chemistry. 43: 8609-16. PMID 15606212 DOI: 10.1021/Ic040097G  1
2004 Wang JJ, Kryatova OP, Rybak-Akimova EV, Holm RH. Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. Inorganic Chemistry. 43: 8092-101. PMID 15578849 DOI: 10.1021/Ic040087F  1
2004 Rao PV, Bhaduri S, Jiang J, Holm RH. Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II rhombs. Inorganic Chemistry. 43: 5833-49. PMID 15360232 DOI: 10.1021/Ic040055S  1
2004 Dey A, Glaser T, Couture MM, Eltis LD, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox. Journal of the American Chemical Society. 126: 8320-8. PMID 15225075 DOI: 10.1021/Ja0484956  1
2004 Panda R, Zhang Y, McLauchlan CC, Venkateswara Rao P, Tiago de Oliveira FA, Münck E, Holm RH. Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 126: 6448-59. PMID 15149242 DOI: 10.1021/Ja030627S  1
2004 Jiang J, Holm RH. An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR). Inorganic Chemistry. 43: 1302-10. PMID 14966965 DOI: 10.1021/ic030301k  1
2004 Enemark JH, Cooney JJ, Wang JJ, Holm RH. Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases. Chemical Reviews. 104: 1175-200. PMID 14871153 DOI: 10.1021/Cr020609D  1
2004 Lee SC, Holm RH. The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters. Chemical Reviews. 104: 1135-58. PMID 14871151 DOI: 10.1021/Cr0206216  1
2004 Venkateswara Rao P, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. Chemical Reviews. 104: 527-59. PMID 14871134 DOI: 10.1021/Cr020615+  1
2004 Holm RH, Solomon EI. Preface: biomimetic inorganic chemistry. Chemical Reviews. 104: 347-8. PMID 14871127 DOI: 10.1021/Cr0206364  1
2004 Zhang Y, Holm RH. Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type clusters topologically related to the nitrogenase P-cluster. Inorganic Chemistry. 43: 674-82. PMID 14731029 DOI: 10.1021/Ic030259T  1
2004 Holm RH. Electron Transfer: Iron-Sulfur Clusters Comprehensive Coordination Chemistry Ii. 8: 61-90. DOI: 10.1016/B0-08-043748-6/08133-0  1
2003 Szilagyi RK, Lim BS, Glaser T, Holm RH, Hedman B, Hodgson KO, Solomon EI. Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy. Journal of the American Chemical Society. 125: 9158-69. PMID 15369373 DOI: 10.1021/Ja029806K  1
2003 Partyka DV, Staples RJ, Holm RH. Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M = Mo, W). Inorganic Chemistry. 42: 7877-86. PMID 14632504 DOI: 10.1021/Ic030185L  1
2003 Daley CJ, Holm RH. Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family. Journal of Inorganic Biochemistry. 97: 287-98. PMID 14511891 DOI: 10.1016/S0162-0134(03)00280-0  1
2003 Jalilehvand F, Lim BS, Holm RH, Hedman B, Hodgson KO. X-ray absorption spectroscopy of a structural analogue of the oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes. Inorganic Chemistry. 42: 5531-6. PMID 12950200 DOI: 10.1021/Ic030039F  1
2003 Zuo JL, Zhou HC, Holm RH. Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase. Inorganic Chemistry. 42: 4624-31. PMID 12870953 DOI: 10.1021/Ic0301369  1
2003 Gray TG, Rudzinski CM, Meyer EE, Holm RH, Nocera DG. Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters. Journal of the American Chemical Society. 125: 4755-70. PMID 12696894 DOI: 10.1021/Ja0286371  1
2003 Zhang Y, Holm RH. Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubane. Journal of the American Chemical Society. 125: 3910-20. PMID 12656626 DOI: 10.1021/Ja0214633  1
2003 Lee SC, Holm RH. Speculative synthetic chemistry and the nitrogenase problem. Proceedings of the National Academy of Sciences of the United States of America. 100: 3595-600. PMID 12642670 DOI: 10.1073/Pnas.0630028100  1
2003 Zhou HC, Holm RH. Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16. Inorganic Chemistry. 42: 11-21. PMID 12513073 DOI: 10.1021/Ic020464T  1
2002 Sanakis Y, Yoo SJ, Osterloh F, Holm RH, Münck E. Determination of antiferromagnetic exchange coupling in the tetrahedral thiolate-bridged diferrous complex [Fe2(SEt)6]2-. Inorganic Chemistry. 41: 7081-5. PMID 12495348 DOI: 10.1021/Ic0204629  1
2002 Zhang Y, Zuo JL, Zhou HC, Holm RH. Rearrangement of symmetrical dicubane clusters into topological analogues of the P cluster of nitrogenase: nature's choice? Journal of the American Chemical Society. 124: 14292-3. PMID 12452688 DOI: 10.1021/Ja0279702  1
2002 Gray TG, Holm RH. Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re(6)Se(8)](2+) Core. Inorganic Chemistry. 41: 4211-6. PMID 12160409 DOI: 10.1021/Ic020214C  1
2002 Zhou HC, Su W, Achim C, Rao PV, Holm RH. High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters: reevaluation and extension. Inorganic Chemistry. 41: 3191-201. PMID 12054998 DOI: 10.1021/Ic0201250  1
2002 Sung KM, Holm RH. Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes. Journal of the American Chemical Society. 124: 4312-20. PMID 11960460 DOI: 10.1021/Ja012735P  1
2002 Laplaza CE, Holm RH. Stability and nickel binding properties of peptides designed as scaffolds for the stabilization of Ni(II)-Fe(4)S(4) bridged assemblies. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 7: 451-60. PMID 11941503 DOI: 10.1007/S00775-001-0320-4  1
2002 Musgrave KB, Laplaza CE, Holm RH, Hedman B, Hodgson KO. Structural characterization of metallopeptides designed as scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy. Journal of the American Chemical Society. 124: 3083-92. PMID 11902899 DOI: 10.1021/Ja011861Q  1
2002 Hauser C, Bill E, Holm RH. Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+). Inorganic Chemistry. 41: 1615-24. PMID 11896732 DOI: 10.1021/Ic011011B  1
2002 Fomitchev DV, McLauchlan CC, Holm RH. Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands. Inorganic Chemistry. 41: 958-66. PMID 11849099 DOI: 10.1021/Ic011106D  1
2001 Laplaza CE, Holm RH. Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase. Journal of the American Chemical Society. 123: 10255-64. PMID 11603975 DOI: 10.1021/Ja010851M  1
2001 Lim BS, Willer MW, Miao M, Holm RH. Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the oxidized active site of the sulfite oxidase enzyme family. Journal of the American Chemical Society. 123: 8343-9. PMID 11516283 DOI: 10.1021/Ja010786G  1
2001 Sung KM, Holm RH. Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites. Inorganic Chemistry. 40: 4518-25. PMID 11511194 DOI: 10.1021/Ic010421X  1
2001 Achim C, Bominaar EL, Staples RJ, Münck E, Holm RH. Influence of extrinsic factors on electron transfer in a mixed-valence Fe(2+)/Fe(3+) complex: experimental results and theoretical considerations. Inorganic Chemistry. 40: 4389-403. PMID 11487347 DOI: 10.1021/Ic010498L  1
2001 Lim BS, Fomitchev DV, Holm RH. Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-. Inorganic Chemistry. 40: 4257-62. PMID 11487330 DOI: 10.1021/Ic010138Y  1
2001 Sung KM, Holm RH. Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum. Journal of the American Chemical Society. 123: 1931-43. PMID 11456814 DOI: 10.1021/Ja0036559  1
2001 Lim BS, Holm RH. Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis, structures, and oxygen atom transfer reactions and kinetics. Journal of the American Chemical Society. 123: 1920-30. PMID 11456813 DOI: 10.1021/Ja003546U  1
2001 Daley CJ, Holm RH. Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for the initial step in biotin synthase catalysis. Inorganic Chemistry. 40: 2785-93. PMID 11375696 DOI: 10.1021/Ic010039K  1
2001 Fomitchev DV, Lim BS, Holm RH. Electron distribution in the nonclassical bis(dithiolene) electron transfer series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results. Inorganic Chemistry. 40: 645-54. PMID 11225106 DOI: 10.1021/Ic001046W  1
2001 Osterloh F, Achim C, Holm RH. Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a topological analogue of the P-cluster of nitrogenase. Inorganic Chemistry. 40: 224-32. PMID 11170527 DOI: 10.1021/Ic000617H  1
2001 Thapper A, Balmes O, Lorber C, Svensson PH, Holm RH, Nordlander E. Synthesis and structural characterization of two tungsten(VI) dioxo complexes with N,O- and N,S-coordinating ligands Inorganica Chimica Acta. 321: 162-166. DOI: 10.1016/S0020-1693(01)00509-6  1
2001 Selby HD, Zheng Z, Gray TG, Holm RH. Bridged multiclusters derived from the face-capped octahedral [Re6/III(μ3-Se)8]2+ cluster core Inorganica Chimica Acta. 312: 205-209. DOI: 10.1016/S0020-1693(00)00324-8  1
2000 Nivorozhkin AL, Segal BM, Musgrave KB, Kates SA, Hedman B, Hodgson KO, Holm RH. Metallocyclopeptide complexes with MII(S.Cys)4 chromophores. Inorganic Chemistry. 39: 2306-13. PMID 12526490 DOI: 10.1021/Ic990421L  1
2000 Sung KM, Holm RH. Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites of tungstoenzymes. Inorganic Chemistry. 39: 1275-81. PMID 12526419 DOI: 10.1021/Ic991153U  1
2000 Osterloh F, Segal BM, Achim C, Holm RH. Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligation. Inorganic Chemistry. 39: 980-9. PMID 12526378 DOI: 10.1021/Ic991016X  1
2000 Lim BS, Donahue JP, Holm RH. Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active sites of the DMSO reductase enzyme family. Inorganic Chemistry. 39: 263-73. PMID 11272534 DOI: 10.1021/Ic9908672  1
2000 Miao M, Willer MW, Holm RH. Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and W(IV)-dithiolene chelate rings. Inorganic Chemistry. 39: 2843-9. PMID 11232822 DOI: 10.1021/Ic000047L  1
2000 Musgrave KB, Lim BS, Sung KM, Holm RH, Hedman B, Hodgson KO. X-ray spectroscopy of enzyme active site analogues and related molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands. Inorganic Chemistry. 39: 5238-47. PMID 11154582 DOI: 10.1021/Ic000601R  1
2000 Lim BS, Sung KM, Holm RH. Structural and functional bis(dithiolene)-molybdenum/tungsten active site analogues of the dimethylsulfoxide reductase enzyme family [13] Journal of the American Chemical Society. 122: 7410-7411. DOI: 10.1021/Ja001197Y  1
2000 Zhou C, Raebiger JW, Segal BM, Holm RH. The influence of net charge on the redox potentials of Fe4S4 cubane-type clusters in aprotic solvents Inorganica Chimica Acta. 300: 892-902. DOI: 10.1016/S0020-1693(99)00593-9  1
1999 Gray TG, Rudzinski CM, Nocera DG, Holm RH. Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re(6)S(8)](2+) and [Re(6)Se(8)](2+). Inorganic Chemistry. 38: 5932-5933. PMID 11671297 DOI: 10.1021/Ic991195I  1
1999 Zheng Z, Gray TG, Holm RH. Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re(6)(&mgr;(3)-Se)(8)](2+). Inorganic Chemistry. 38: 4888-4895. PMID 11671221 DOI: 10.1021/Ic9906050  1
1999 Musgrave KB, Donahue JP, Lorber C, Holm RH, Hedman B, Hodgson KO. An x-ray spectroscopic investigation of bis(dithiolene)molybdenum(IV,V,VI) and -tungsten(IV,V,VI) complexes: Symmetrized structural representations of the active sites of molybdoenzymes in the DMSO reductase family and of tungstoenzymes in the AOR and F(M)DH families Journal of the American Chemical Society. 121: 10297-10307. DOI: 10.1021/Ja990753P  1
1999 Thapper A, Donahue JP, Musgrave KB, Willer MW, Nordlander E, Hedman B, Hodgson KO, Holm RH. The Unperturbed Oxo−Sulfido Functional Groupcis-MoVIOS Related to That in the Xanthine Oxidase Family of Molybdoenzymes:  Synthesis, Structural Characterization, and Reactivity Aspects Inorganic Chemistry. 38: 4104-4114. DOI: 10.1021/Ic990440V  0.01
1999 Goddard CA, Holm RH. Synthesis and reactivity aspects of the bis(dithiolene) chalcogenide series [WIVQ(S2C2R2)2] 2- (Q = O, S, Se) Inorganic Chemistry. 38: 5389-5398. DOI: 10.1021/Ic9903329  1
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A molybdenum-iron-sulfur cluster containing structural elements relevant to the P-cluster of nitrogenase Angewandte Chemie - International Edition. 38: 2066-2070. DOI: 10.1002/(Sici)1521-3773(19990712)38:13/14<2066::Aid-Anie2066>3.0.Co;2-K  1
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A Molybdenum-Iron-Sulfur Cluster Containing Structural Elements Relevant to the P-Cluster of Nitrogenase Angewandte Chemie International Edition. 38: 2066-2070. DOI: 10.1002/(SICI)1521-3773(19990712)38:13/14<2066::AID-ANIE2066>3.0.CO;2-K  0.01
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. Ein Molybdän-Eisen-Schwefel-Cluster mit Strukturelementen des Nitrogenase-P-Clusters Angewandte Chemie. 111: 2199-2203. DOI: 10.1002/(Sici)1521-3757(19990712)111:13/14<2199::Aid-Ange2199>3.0.Co;2-Y  0.01
1999 Zheng Z, Gray TG, Holm RH. Synthesis and structures of solvated monoclusters and bridged Di- and triclusters based on the cubic building block [Re6(μ3-Se)8]2+ Inorganic Chemistry. 38: 4888-4895.  1
1999 Thapper A, Donahue JP, Musgrave KB, Willer MW, Nordlander E, Hedman B, Hodgson KO, Holm RH. The unperturbed oxo-sulfido functional group cis-MoVIOS related to that in the xanthine oxidase family of molybdoenzymes: synthesis, structural characterization, and reactivity aspects Inorganic Chemistry. 38: 4104-4114.  1
1998 Lim BS, Holm RH. Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in nu(CN) Values, and Relation to the Heme-a(3)/Cu(B) Site in Cyanide-Inhibited Heme-Copper Oxidases. Inorganic Chemistry. 37: 4898-4908. PMID 11670655 DOI: 10.1021/Ic9801793  1
1998 Huang J, Holm RH. Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe(3)S(4) Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges. Inorganic Chemistry. 37: 2247-2254. PMID 11670381 DOI: 10.1021/Ic971353A  1
1998 Donahue JP, Holm RH. 3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported by a ring or benzenoid frame. Acta Crystallographica. Section C, Crystal Structure Communications. 54: 1175-8. PMID 9760719  1
1998 Holm RH. [1:3] Site-differentiated and sulfide-bridged cubane clusters in chemistry and biology Pure and Applied Chemistry. 70: 931-938. DOI: 10.1351/Pac199870040931  1
1998 Donahue JP, Goldsmith CR, Nadiminti U, Holm RH. Synthesis, structures, and reactivity of bis(dithiolene)molybdenum(IV,VI) complexes related to the active sites of molybdoenzymes Journal of the American Chemical Society. 120: 12869-12881. DOI: 10.1021/Ja982914F  1
1998 Lorber C, Donahue JP, Goddard CA, Nordlander E, Holm RH. Synthesis, structures, and oxo transfer reactivity of bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes Journal of the American Chemical Society. 120: 8102-8112. DOI: 10.1021/Ja981015O  1
1998 Donahue JP, Lorber C, Nordlander E, Holm RH. Molybdenum and tungsten structural analogues of the active sites of the MoIV + [O] → MoVIO oxygen atom transfer couple of DMSO reductases Journal of the American Chemical Society. 120: 3259-3260. DOI: 10.1021/Ja973917F  1
1998 Segal BM, Hoveyda HR, Holm RH. Terminal Ligand Assignments Based on Trends in Metal - Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters Inorganic Chemistry. 37: 3440-3443. DOI: 10.1021/Ic980092H  1
1998 Goh C, Nivorozhkin A, Yoo SJ, Bominaar EL, Münck E, Holm RH. The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites Inorganic Chemistry. 37: 2926-2932. DOI: 10.1021/Ic980085T  1
1998 Goh C, Nivorozhkin A, Yoo SJ, Bominaar EL, Münck E, Holm RH. The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]:  Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites Inorganic Chemistry. 37: 2926-2932. DOI: 10.1021/ic980085t  0.01
1998 Tucci GC, Donahue JP, Holm RH. Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes Inorganic Chemistry. 37: 1602-1608. DOI: 10.1021/Ic971426Q  1
1998 Willer MW, Long JR, McLauchlan CC, Holm RH. Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies Inorganic Chemistry. 37: 328-333. DOI: 10.1021/Ic970926G  1
1998 Willer MW, Long JR, McLauchlan CC, Holm RH. Ligand Substitution Reactions of [Re6S8Br6]4-:  A Basis Set of Re6S8Clusters for Building Multicluster Assemblies Inorganic Chemistry. 37: 328-333. DOI: 10.1021/ic970926g  0.04
1998 Goh C, Holm RH. Synthesis and structures of the cuboidal iron-sulfur-nitrosyl-phosphine clusters [Fe4S3(NO)4(PR3)3] 0,1+ (R = Et, Pri, C6H11) Inorganica Chimica Acta. 270: 46-54. DOI: 10.1016/S0020-1693(97)05822-2  1
1998 Lim BS, Holm RH. Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in vCN Values, and Relation to the Heme-a3/CuB Site in Cyanide-Inhibited Heme-Copper Oxidases Inorganic Chemistry. 37: 4898-4908.  1
1998 Huang J, Holm RH. Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe3S4 Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges Inorganic Chemistry. 37: 2247-2254.  1
1997 Hoveyda HR, Holm RH. Characterization of the Self-Condensation Equilibrium of [Fe(4)S(4)(SH)(4)](2-): Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster. Inorganic Chemistry. 36: 4571-4578. PMID 11670123  1
1997 Raebiger JW, Crawford CA, Zhou J, Holm RH. Reactivity of Cubane-Type [(OC)(3)MFe(3)S(4)(SR)(3)](3-) Clusters (M = Mo, W): Interconversion with Cuboidal [Fe(3)S(4)](0) Clusters and Electron Transfer. Inorganic Chemistry. 36: 994-1003. PMID 11669661 DOI: 10.1021/Ic961122O  1
1997 Kauffmann KE, Goddard CA, Zang Y, Holm RH, Münck E. Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase. Inorganic Chemistry. 36: 985-993. PMID 11669660 DOI: 10.1021/Ic960826V  1
1997 Beinert H, Holm RH, Münck E. Iron-sulfur clusters: nature's modular, multipurpose structures. Science (New York, N.Y.). 277: 653-9. PMID 9235882 DOI: 10.1126/Science.277.5326.653  1
1997 Huang J, Mukerjee S, Segal BM, Akashi H, Zhou J, Holm RH. Molybdenum - Iron sulfide-bridged double cubanes Journal of the American Chemical Society. 119: 8662-8674. DOI: 10.1021/Ja971401Q  1
1997 Yoo SJ, Hu Z, Goh C, Bominaar EL, Holm RH, Munck E. Determination of the exchange-coupling constant of an Fe3+-Fe3+ pair in a cubane-type iron-sulfur cluster Journal of the American Chemical Society. 119: 8732-8733. DOI: 10.1021/Ja971171F  1
1997 Zhou J, Raebiger JW, Crawford CA, Holm RH. Metal ion incorporation reactions of the cluster [Fe 3S 4(LS 3)] 3-, containing the cuboidal [Fe 3S 4] 0 core Journal of the American Chemical Society. 119: 6242-6250. DOI: 10.1021/Ja9704186  1
1997 Zheng Z, Long JR, Holm RH. A basis set of Re6Se8 cluster building blocks and demonstration of their linking capability: Directed synthesis of an Re12Se16 dicluster Journal of the American Chemical Society. 119: 2163-2171. DOI: 10.1021/Ja9638519  1
1997 Zhang HH, Filipponi A, Di Cicco A, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-edge XAS studies of cyanide-bridged iron-copper molecular assemblies relevant to cyanide-inhibited heme-copper oxidases using four-body multiple-scattering analysis Journal of the American Chemical Society. 119: 2470-2478. DOI: 10.1021/Ja963300I  1
1997 Zheng Z, Holm RH. Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster Inorganic Chemistry. 36: 5173-5178. DOI: 10.1021/Ic970727X  1
1997 Zheng Z, Holm RH. Cluster Condensation by Thermolysis:  Synthesis of a Rhomb-Linked Re12Se16Dicluster and Factors Relevant to the Formation of the Re24Se32Tetracluster Inorganic Chemistry. 36: 5173-5178. DOI: 10.1021/ic970727x  0.01
1997 Zhou C, Holm RH. Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se) Inorganic Chemistry. 36: 4066-4077. DOI: 10.1021/Ic970254U  1
1997 Huang J, Goh C, Holm RH. On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W) Inorganic Chemistry. 36: 356-361. DOI: 10.1021/Ic960844C  1
1997 Holm R, Huang J, Akashi H, Crawford C, Mukerjee S, Raebiger J, Segal B, Zhou C. Recent developments in biologically related metal-sulfur clusters Journal of Inorganic Biochemistry. 67: 246. DOI: 10.1016/S0162-0134(97)80118-3  0.01
1997 Kauffmann KE, Goddard CA, Zang Y, Holm RH, Münck E. Mössbauer and Magnetization Studies of Heme - Copper-Bridged Assemblies Pertinent to Cytochrome c Osidase Inorganic Chemistry. 36: 985-993.  1
1997 Hoveyda HR, Holm RH. Characterization of the Self-Condensation Equilibrium of [Fe4S4(SH)4]2-: Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster Inorganic Chemistry. 36: 4571-4578.  1
1997 Raebiger JW, Crawford CA, Zhou J, Holm RH. Reactivity of Cubane-Type [(OC)3MFe3S4(SR)3]3- Clusters (M = Mo, W): Interconversion with Cuboidal [Fe3S4]0 Clusters and Electron Transfer Inorganic Chemistry. 36: 994-1003.  1
1996 Holm RH, Kennepohl P, Solomon EI. Structural and Functional Aspects of Metal Sites in Biology. Chemical Reviews. 96: 2239-2314. PMID 11848828 DOI: 10.1021/Cr9500390  1
1996 Gardner MT, Deinum G, Kim Y, Babcock GT, Scott MJ, Holm RH. Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase. Inorganic Chemistry. 35: 6878-6884. PMID 11666856 DOI: 10.1021/Ic960575Q  1
1996 Zhang HH, Filipponi A, Di Cicco A, Lee SC, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors. Inorganic Chemistry. 35: 4819-4828. PMID 11666681 DOI: 10.1021/Ic960021N  1
1996 Goddard CA, Long JR, Holm RH. Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe(6)S(8)(PEt(3))(6)](n)()(+) (n = 0-4) Cluster Electron Transfer Series. Inorganic Chemistry. 35: 4347-4354. PMID 11666650 DOI: 10.1021/Ic960052I  1
1996 James TL, Cai L, Muetterties MC, Holm RH. Dihydrogen Evolution by Protonation Reactions of Nickel(I). Inorganic Chemistry. 35: 4148-4161. PMID 11666623 DOI: 10.1021/Ic960216V  1
1996 Scott MJ, Goddard CA, Holm RH. Molecular Assemblies Containing Unsupported [Fe(III)-(&mgr;(2):eta(2)-RCO(2))-Cu(II)] Bridges. Inorganic Chemistry. 35: 2558-2567. PMID 11666470 DOI: 10.1021/Ic9512035  1
1996 Goh C, Segal BM, Huang J, Long JR, Holm RH. Polycubane clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = Bu(t), Cy, Pr(i)) and [Fe4S4]0 core aggregation upon loss of phosphine Journal of the American Chemical Society. 118: 11844-11853. DOI: 10.1021/Ja9620200  1
1996 Long JR, McCarty LS, Holm RH. A solid-state route to molecular clusters: Access to the solution chemistry of [Re6Q8]2+ (Q = S, Se) core-containing clusters via dimensional reduction Journal of the American Chemical Society. 118: 4603-4616. DOI: 10.1021/Ja960216U  1
1996 Long JR, McCarty LS, Holm RH. A Solid-State Route to Molecular Clusters:  Access to the Solution Chemistry of [Re6Q8]2+(Q = S, Se) Core-Containing Clusters via Dimensional Reduction Journal of the American Chemical Society. 118: 4603-4616. DOI: 10.1021/ja960216u  0.01
1996 Zhou J, Hu Z, Miinck E, Holm RH. The cuboidal Fe3S4 cluster: Synthesis, stability, and geometric and electronic structures in a non-protein environment Journal of the American Chemical Society. 118: 1966-1980. DOI: 10.1021/Ja9537843  1
1996 Zhou C, Cai L, Holm RH. Synthesis of a [Fe4S4]-S-Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase Inorganic Chemistry. 35: 2767-2772. DOI: 10.1021/Ic951493P  1
1996 Goddard CA, Long JR, Holm RH. Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe6S8(PEt3)6]n+ (n = 0-4) Cluster Electron Transfer Series Inorganic Chemistry. 35: 4347-4354.  1
1996 Scott MJ, Goddard CA, Holm RH. Molecular Assemblies Containing Unsupported [FeIII-(μ2:η2-RCO2)-Cu II] Bridges Inorganic Chemistry. 35: 2558-2567.  1
1996 Gardner MT, Deinum G, Kim Y, Babcock GT, Scott MJ, Holm RH. Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear FeIII-CN-CuII Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase Inorganic Chemistry. 35: 6878-6884.  1
1995 Holm RH. Chemical approaches to bridged biological metal assemblies Pure and Applied Chemistry. 67: 217-224. DOI: 10.1351/Pac199567020217  1
1995 Zhou J, Holm RH. Synthesis and metal ion incorporation reactions of the cuboidal Fe3S4 cluster Journal of the American Chemical Society. 117: 11353-11354. DOI: 10.1021/Ja00150A039  1
1995 Cai L, Segal BM, Long JR, Scott MJ, Holm RH. Octanuclear iron-sulfur clusters with symmetrically coupled Fe4S4 and Fe4S5 cores Journal of the American Chemical Society. 117: 8863-8864. DOI: 10.1021/Ja00139A025  1
1995 Cai L, Segal BM, Long JR, Scott MJ, Holm RH. Octanuclear Iron-Sulfur Clusters with Symmetrically Coupled Fe4S4 and Fe4S5 Cores Journal of the American Chemical Society. 117: 8863-8864. DOI: 10.1021/ja00139a025  0.12
1995 Franolic JD, Long JR, Holm RH. Comprehensive tungsten - Iodine cluster chemistry: Isolated intermediates in the solid-state nucleation of [W6I14]2- Journal of the American Chemical Society. 117: 8139-8153. DOI: 10.1021/Ja00136A011  1
1995 Franolic JD, Long JR, Holm RH. Comprehensive Tungsten-Iodine Cluster Chemistry: Isolated Intermediates in the Solid-State Nucleation of [W6I14]2- Journal of the American Chemical Society. 117: 8139-8153. DOI: 10.1021/ja00136a011  0.08
1995 Tucci GC, Holm RH. Nickel-mediated formation of thioesters from bound methyl, thiols, and carbon monoxide: A possible reaction pathway of acetyl-coenzyme A synthase activity in nickel-containing carbon monoxide dehydrogenases Journal of the American Chemical Society. 117: 6489-6496. DOI: 10.1021/Ja00129A011  1
1995 Schultz BE, Hille R, Holm RH. Direct oxygen atom transfer in the mechanism of action of Rhodobacter sphaeroides dimethyl sulfoxide reductase Journal of the American Chemical Society. 117: 827-828. DOI: 10.1021/Ja00107A031  1
1995 Schultz BE, Hille R, Holm RH. Direct oxygen atom transfer in the mechanism of action of Rhodobacter sphaeroides dimethyl sulfoxide reductase Journal of the American Chemical Society. 117: 827-828. DOI: 10.1021/ja00107a031  0.01
1995 Scott MJ, Zhang HH, Lee SC, Hedman B, Hodgson KO, Holm RH. Oxygen-Bridged Iron-Copper Assemblies Pertinent to Heme-Copper Oxidases: Synthesis and Structure of an [FeIII-(OH)-CuII] Bridge and Exafs Multiple-Scattering Effects of Linear Oxo and Nonlinear Hydroxo Bridges Journal of the American Chemical Society. 117: 568-569. DOI: 10.1021/Ja00106A080  0.04
1995 Tian ZQ, Donahue JP, Holm RH. Synthesis of new types of dithiolene ligands Inorganic Chemistry. 34: 5567-5572. DOI: 10.1021/Ic00126A029  1
1995 MacDonnell FM, Ruhlandt-Senge K, Ellison JJ, Holm RH, Power PP. Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes Inorganic Chemistry. 34: 1815-1822. DOI: 10.1021/Ic00111A032  1
1995 MacDonnell FM, Ruhlandt-Senge K, Ellison JJ, Holm RH, Power PP. Sterically Encumbered Iron(II) Thiolate Complexes: Synthesis and Structure of Trigonal Planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Moessbauer Spectra of Two- and Three-Coordinate Complexes Inorganic Chemistry. 34: 1815-1822. DOI: 10.1021/ic00111a032  0.01
1995 Long JR, Holm RH. Protein-bound iron-sulfur clusters: application of a structural database Inorganica Chimica Acta. 229: 229-239. DOI: 10.1016/0020-1693(94)04249-U  1
1995 Long JR, Williamson AS, Holm RH. Dimensional reduction of Re6Se8Cl2: sheets, chains, and discrete clusters composed of chloride-terminated [Re6Q8]2+ (Q = S, Se) cores Angewandte Chemie (International Edition in English). 34: 226-229. DOI: 10.1002/Anie.199502261  1
1995 Long JR, Williamson AS, Holm RH. Dimensional Reduction of Re6Se8Cl2: Sheets, Chains, and Discrete Clusters Composed of Chloride-Terminated[Re6Q8]2+(Q S, Se) Cores Angewandte Chemie International Edition in English. 34: 226-229. DOI: 10.1002/anie.199502261  0.04
1995 Long JR, Williamson AS, Holm RH. Verringerung der Dimensionalität von Re6Se8Cl2: Schichten, Ketten und isolierte Cluster von [Re6Q8]2+ (Q = S, Se) mit terminalen Cl-Atomen Angewandte Chemie. 107: 248-251. DOI: 10.1002/Ange.19951070228  0.01
1995 Scott MJ, Zhang HH, Lee SC, Hedman B, Hodgson KO, Holm RH. Oxygen-bridged iron-copper assemblies pertinent to heme-copper oxidases: Synthesis and structure of an [FeIII-(OH)-CuII] bridge and EXAFS multiple-scattering effects of linear oxo and nonlinear hydroxo bridges Journal of the American Chemical Society. 117: 568-569.  1
1994 Black L, Lear E, Wunderlich F, Bence M, Nocker HG, Yahia M, Holm R, Kohn KC, Staatsorchester B, Egk W. Werner Egk: Die Verlobung in San Domingo The Musical Times. 135: 175. DOI: 10.2307/1002920  0.01
1994 Scott MJ, Holm RH. Molecular assemblies containing linear and bent [FeIII-CN-CuII] bridge units: Synthesis, structures, and relevance to cyanide-inhibited heme - Copper oxidases Journal of the American Chemical Society. 116: 11357-11367. DOI: 10.1021/Ja00104A015  1
1994 Long JR, Holm RH. Enumeration and Structural Classification of Clusters Derived from Parent Solids: Metal-Chalcogenide Clusters Composed of Edge-Sharing Tetrahedra Journal of the American Chemical Society. 116: 9987-10002. DOI: 10.1021/Ja00101A020  0.16
1994 Cai L, Holm RH. Synthesis and electron delocalization of [Fe4S4]-S-Fe(III) bridged assemblies related to the exchange-coupled catalytic site of sulfite reductases Journal of the American Chemical Society. 116: 7177-7188. DOI: 10.1021/Ja00095A021  1
1994 Lee SC, Scott MJ, Kauffmann K, Münck E, Holm RH. Cyanide poisoning: An analogue to the binuclear site of oxidized cyanide-inhibited cytochrome c oxidase Journal of the American Chemical Society. 116: 401-402. DOI: 10.1021/Ja00080A058  1
1994 Cen W, MacDonnell FM, Scott MJ, Holm RH. Heterometal clusters containing the cuboidal Fe4S3 fragment: Synthesis, electron distribution, and reactions Inorganic Chemistry. 33: 5809-5818. DOI: 10.1021/Ic00103A031  1
1994 James TL, Smith DM, Holm RH. Stereoelectronic preferences in electron transfer series of nickel with tridentate ligands containing hard - soft donor sets Inorganic Chemistry. 33: 4869-4877. DOI: 10.1021/Ic00100A009  1
1994 Scott MJ, Lee SC, Holm RH. Synthesis and structural characterization of unsupported [FeIII-CN-CuII] bridges related to that in cyanide-inactivated cytochrome c oxidase Inorganic Chemistry. 33: 4651-4662. DOI: 10.1021/Ic00099A015  1
1994 Hendrich MP, Day EP, Wang CP, Synder BS, Holm RH, Münck E. Ground-state electronic structures of binuclear iron(II) sites: Experimental protocol and a consistent description of mössbauer, EPR, and magnetization measurements of the bis(phenolate)-bridged complex [Fe2(salmp)2]2- Inorganic Chemistry. 33: 2848-2856. DOI: 10.1021/Ic00091A028  1
1994 Hendrich MP, Day EP, Wang C, Synder BS, Holm RH, Munck E. Ground-State Electronic Structures of Binuclear Iron(II) Sites: Experimental Protocol and a Consistent Description of Moessbauer, EPR, and Magnetization Measurements of the Bis(phenolate)-Bridged Complex [Fe2(salmp)2]2- Inorganic Chemistry. 33: 2848-2856. DOI: 10.1021/ic00091a028  0.01
1994 Goh C, Weigel JA, Holm RH. The [2:2] site-differentiated clusters [Fe4S4L2(RNC)6] containing two low-spin iron(II) sites Inorganic Chemistry. 33: 4861-4868.  1
1994 Long JR, Holm RH. Enumeration and structural classification of clusters derived from parent solids: Metal-chalcogenide clusters composed of edge-sharing tetrahedra Journal of the American Chemical Society. 116: 9987-10002.  1
1993 Lee SC, Holm RH. Synthesis and characterization of an asymmetric bridged assembly containing the unsupported [FeIII-O-CuII] bridge: An analogue of the binuclear site in oxidized cytochrome c oxidase Journal of the American Chemical Society. 115: 11789-11798. DOI: 10.1021/Ja00078A018  1
1993 Cen W, Lee SC, Li J, MacDonnell FM, Holm RH. Heterometal dependence of electron distributions and redox potentials in clusters with cubane-type [MFe3S4]z cores Journal of the American Chemical Society. 115: 9515-9523. DOI: 10.1021/Ja00074A016  1
1993 Cai L, Weigel JA, Holm RH. Analogs of bridged biological active site assemblies: the Fe4S4-sulfide-heme unit Journal of the American Chemical Society. 115: 9289-9290. DOI: 10.1021/Ja00073A055  0.01
1993 Lee SC, Holm RH. A synthetic analogue of the iron/copper bridged assembly in cytochrome c oxidase Journal of the American Chemical Society. 115: 5833-5834. DOI: 10.1021/Ja00066A065  1
1993 Nordlander E, Lee SC, Cen W, Wu ZY, Natoli CR, Di Cicco A, Filipponi A, Hedman B, Hodgson KO, Holm RH. Heterometal cuboidal clusters MFe4S6(PEt3)4Cl (M = vanadium, molybdenum): synthesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molybdenum cofactor of nitrogenase Journal of the American Chemical Society. 115: 5549-5558. DOI: 10.1021/Ja00066A024  0.01
1993 Schultz BE, Gheller SF, Muetterties MC, Scott MJ, Holm RH. Molybdenum-mediated oxygen atom transfer: An improved analogue reaction system of the molybdenum oxotransferases Journal of the American Chemical Society. 115: 2714-2722. DOI: 10.1021/Ja00060A021  1
1993 Lee SC, Holm RH. Fluoride-bridged dimers: Binuclear copper(II) complexes and iron(III)-copper(II) assemblies Inorganic Chemistry. 32: 4745-4753. DOI: 10.1021/Ic00074A016  1
1993 Schultz BE, Holm RH. Kinetics of oxygen atom transfer in an analogue reaction system of the molybdenum oxotransferases Inorganic Chemistry. 32: 4244-4248. DOI: 10.1021/Ic00072A016  1
1993 Holm R, Donahue JP. A thermodynamic scale for oxygen atom transfer reactions Polyhedron. 12: 571-589. DOI: 10.1016/S0277-5387(00)84972-4  0.01
1993 Yu SB, Holm RH. Tetrahedral and square-pyramidal sulphur-rich complexes of manganese(II) Polyhedron. 12: 263-266. DOI: 10.1016/S0277-5387(00)81637-X  1
1993 Scott MJ, Holm RH. Tetranuclear Cuboidal and Hexanuclear Prismatic Iron–Sulfur–Nitrosyl Clusters Angewandte Chemie International Edition in English. 32: 564-566. DOI: 10.1002/Anie.199305641  0.04
1993 Scott MJ, Holm RH. Vierkernige quaderförmige und sechskernige prismenförmige Nitrosylsulfidoeisen-Cluster Angewandte Chemie. 105: 621-623. DOI: 10.1002/Ange.19931050434  0.01
1993 Nordlander E, Lee SC, Cen W, Wu ZY, Natoli CR, Di Cicco A, Filipponi A, Hedman B, Hodgson KO, Holm RH. Heterometal cuboidal clusters MFE4S6(PEt3)4Cl (M = V, Mo): Syntehesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molydenum cofactor of nitrogenase Journal of the American Chemical Society. 115: 5549-5558.  1
1993 Scott MJ, Holm RH. Tetranuclear cuboidal and hexanuclear prismatic iron - sulfur - nitrosyl clusters Angewandte Chemie (International Edition in English). 32: 564-566.  1
1992 Tan GO, Ensign SA, Ciurli S, Scott MJ, Hedman B, Holm RH, Ludden PW, Korszun ZR, Stephens PJ, Hodgson KO. On the structure of the nickel/iron/sulfur center of the carbon monoxide dehydrogenase from Rhodospirillum rubrum: an x-ray absorption spectroscopy study. Proceedings of the National Academy of Sciences of the United States of America. 89: 4427-31. PMID 1584775 DOI: 10.1073/Pnas.89.10.4427  1
1992 Zhou J, Scott MJ, Hu Z, Peng G, Munck E, Holm RH. Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = iron, cobalt, nickel) Journal of the American Chemical Society. 114: 10843-10854. DOI: 10.1021/Ja00053A021  0.01
1992 Gheller SF, Schultz BE, Scott MJ, Holm RH. A broad-substrate analog reaction system of the molybdenum oxotransferases Journal of the American Chemical Society. 114: 6934-6935. DOI: 10.1021/Ja00043A059  0.01
1992 Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH. Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = sulfur, selenium) Journal of the American Chemical Society. 114: 5415-5423. DOI: 10.1021/Ja00039A063  0.01
1992 You JF, Papaefthymiou GC, Holm RH. [β-Na2Fe18S30]8- and [Na9Fe20Se38]9-: High-nuclearity clusters by mono- or bicyclization of unidimensional polymeric fragments and the existence of isomeric monocyclic clusters Journal of the American Chemical Society. 114: 2697-2710. DOI: 10.1021/Ja00033A050  1
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: Cluster excision and core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784. DOI: 10.1021/Ic00049A013  1
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: cluster excision and core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784. DOI: 10.1021/ic00049a013  0.08
1992 Lee SC, Li J, Mitchell JC, Holm RH. Group 5 tetrathiometalates: Simplified syntheses and structures Inorganic Chemistry. 31: 4333-4338. DOI: 10.1021/Ic00047A021  1
1992 Holm RH. Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology Advances in Inorganic Chemistry. 38: 1-71. DOI: 10.1016/S0898-8838(08)60061-6  1
1992 You JF, Holm RH. A topological method for the enumeration of bridging modes and connectivity patterns of the clusters MmQnLl with four-coordinate metal sites and Qμ2,3,4 bridging atoms Inorganic Chemistry. 31: 2166-2175.  1
1992 Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH. Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = S, Se) Journal of the American Chemical Society. 114: 5415-5423.  1
1992 Zhou J, Scott MJ, Hu Z, Peng G, Münck E, Holm RH. Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = Fe, Co, Ni) Journal of the American Chemical Society. 114: 10843-10854.  1
1991 Liu HY, Scharbert B, Holm RH. An initial approach to biologically related bridged assemblies: PYridinethiolate-Linked Fe4S4-Fe complex systems Journal of the American Chemical Society. 113: 9529-9539. DOI: 10.1021/Ja00025A018  1
1991 Stavropoulos P, Muetterties MC, Carrié M, Holm RH. Structural and reaction chemistry of nickel complexes in relation to carbon monoxide dehydrogenase: A reaction system simulating acetyl-coenzyme A synthase activity Journal of the American Chemical Society. 113: 8485-8492. DOI: 10.1021/Ja00022A041  1
1991 Weigel JA, Holm RH. Intrinsic Binding Properties of a Differentiated Iron Subsite in Analogues of Native [Fe4S4]2+ Clusters Journal of the American Chemical Society. 113: 4184-4191. DOI: 10.1021/Ja00011A020  1
1991 Yu SB, Wang CP, Day EP, Holm RH. A binuclear manganese system with three isolated oxidation states: Synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII Inorganic Chemistry. 30: 4067-4074. DOI: 10.1021/Ic00021A019  1
1991 Yu SB, Papaefthymiou GC, Holm RH. Comprehensive iron-selenium-thiolate cluster chemistry Inorganic Chemistry. 30: 3476-3485. DOI: 10.1021/Ic00018A018  1
1991 You JF, Holm RH. [Na9Fe20Se38]9-: a [sodium-iron-selenium] high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs Inorganic Chemistry. 30: 1431-1433. DOI: 10.1021/IC00007A002  0.01
1991 Ciurli S, Holm RH. Heterometal cubane-type clusters: a rhenium-iron-sulfur (ReFe3S4) single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand Inorganic Chemistry. 30: 743-750. DOI: 10.1021/Ic00004A026  0.01
1991 Snyder BS, Reynolds MS, Holm RH, Papaefthymiou GC, Frankel RB. Electronic properties of monocapped prismane and basket iron-sulphur clusters Polyhedron. 10: 203-213. DOI: 10.1016/S0277-5387(00)81590-9  1
1991 Holm R. Biologically related nickel chemistry Journal of Inorganic Biochemistry. 43: 652. DOI: 10.1016/0162-0134(91)84622-G  0.01
1991 Ciurli S, Holm RH. Heterometal cubane-type clusters: A ReFe3S4 single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand Inorganic Chemistry. 30: 743-750.  1
1991 Krüger HJ, Peng G, Holm RH. Low-potential nickel(III,II) complexes: New systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [niFe]-hydrogenases Inorganic Chemistry. 30: 734-742.  1
1991 Whitener MA, Peng G, Holm RH. Subsite-differentiated analogues of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol Inorganic Chemistry. 30: 2411-2417.  1
1991 You JF, Holm RH. [Na9Fe20Se38]9-: A high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs Inorganic Chemistry. 30: 1431-1433.  1
1990 Lee SC, Holm RH. Entry to the solution chemistry of niobium and tantalum sulfides: Synthesis of soluble forms of the tetrathiometalates [MS4]3- Journal of the American Chemical Society. 112: 9654-9655. DOI: 10.1021/Ja00182A043  1
1990 Ciurli S, Yu SB, Holm RH, Srivastava KKP, Munck E. Synthetic nickel-iron NiFe3Q4 cubane-type clusters (S = 3/2) by reductive rearrangement of linear [Fe3Q4(SEt)4]3- (Q = sulfur, selenium) Journal of the American Chemical Society. 112: 8169-8171. DOI: 10.1021/Ja00178A053  0.04
1990 Weigel JA, Srivastava KKP, Day EP, Münck E, Holm RH. Isonitrile binding to a site-differentiated synthetic analogue of biological [4Fe-4S] clusters: Equilibria, magnetic interactions and the spin-isolated [3Fe-4S] cluster fragment, and the structure of a low-spin iron(II) subsite Journal of the American Chemical Society. 112: 8015-8023. DOI: 10.1021/Ja00178A026  1
1990 Stavropoulos P, Carrie M, Muetterties MC, Holm RH. Reaction sequence related to that of carbon monoxide dehydrogenase (acetyl coenzyme A synthase): thioester formation mediated at structurally defined nickel centers Journal of the American Chemical Society. 112: 5385-5387. DOI: 10.1021/Ja00169A076  0.01
1990 Kruger HJ, Holm RH. Stabilization of trivalent nickel in tetragonal NiS4N2 and NiN6 environments: synthesis, structures, redox potentials and observations related to [NiFe]-hydrogenases Journal of the American Chemical Society. 112: 2955-2963. DOI: 10.1021/Ja00164A018  0.01
1990 Ciurli S, Carrie M, Weigel JA, Carney MJ, Stack TDP, Papaefthymiou GC, Holm RH. Subsite-differentiated analogs of native iron sulfide [4Fe-4S]2+ clusters: preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions Journal of the American Chemical Society. 112: 2654-2664. DOI: 10.1021/Ja00163A028  0.01
1990 You JF, Snyder BS, Papaefthymiou GC, Holm RH. On the molecular solid-state boundary. A cyclic iron-sulfur cluster of nuclearity eighteen: synthesis, structure, and properties Journal of the American Chemical Society. 112: 1067-1076. DOI: 10.1021/Ja00159A028  0.01
1990 Harlan EW, Holm RH. Molybdenum-mediated imido group transfer: Stoichiometric and catalytic reactions and structures Journal of the American Chemical Society. 112: 186-193. DOI: 10.1021/Ja00157A030  1
1990 Stack TDP, Weigel JA, Holm RH. The cavitand concept in the synthesis of subsite-differentiated analogues of biological [4Fe-4S/Se]2+ clusters: Cluster capture reactions, ligand conformational analysis, and the structure of a trigonal [4Fe-4Se]2+ analogue Inorganic Chemistry. 29: 3745-3760. DOI: 10.1021/Ic00344A022  1
1990 Ciurli S, Carrie M, Holm RH. Clusters containing the iron-rhenium-sulfur [ReFe3(.mu.3-S)4] core: an expansion of the heterometal cubane-type cluster series MFe3S4 Inorganic Chemistry. 29: 3493-3501. DOI: 10.1021/Ic00343A042  0.01
1990 Zhang Y, Holm RH. Vanadium-mediated oxygen atom transfer reactions Inorganic Chemistry. 29: 911-917. DOI: 10.1021/Ic00330A005  0.01
1990 Snyder BS, Holm RH. Hexakis(triethylphosphine)hexathioxohexairon(+): extension of stabilization of the basket core topology to the [Fe6S6]+ oxidation level Inorganic Chemistry. 29: 274-279. DOI: 10.1021/Ic00327A025  0.01
1990 Richards AJM, Thomson AJ, Holm RH, Hagen KS. The magnetic circular dichroism spectra of the linear trinuclear clusters [Fe3S4(SR)4]3- in purple aconitase and in a synthetic model Spectrochimica Acta Part a: Molecular Spectroscopy. 46: 987-993. DOI: 10.1016/0584-8539(90)80015-Q  1
1990 Holm R. The biologically relevant oxygen atom transfer chemistry of molybdenum: from synthetic analogue systems to enzymes Coordination Chemistry Reviews. 100: 183-221. DOI: 10.1016/0010-8545(90)85010-P  0.01
1990 CIURLI S, CARRIE M, HOLM RH. ChemInform Abstract: Clusters Containing the (ReFe3(μ3-S)4) Core: An Expansion of the Heterometal Cubane-Type Cluster Series MFe3S4. Cheminform. 21. DOI: 10.1002/CHIN.199051324  0.01
1990 LEE SC, HOLM RH. ChemInform Abstract: Nonmolecular Metal Chalcogenide/Halide Solids and Their Molecular Cluster Analogues Cheminform. 21. DOI: 10.1002/CHIN.199046323  0.04
1990 HOLM RH. ChemInform Abstract: The Biologically Relevant Oxygen Atom Transfer Chemistry of Molybdenum: From Synthetic Analogue Systems to Enzymes Cheminform. 21. DOI: 10.1002/CHIN.199034350  0.01
1990 KRUEGER H, HOLM RH. ChemInform Abstract: Stabilization of Trivalent Nickel in Tetragonal NiS4N2 and NiN6 Environments: Synthesis, Structures, Redox Potentials, and Observations Related to (NiFe)-Hydrogenases. Cheminform. 21. DOI: 10.1002/CHIN.199031048  0.01
1990 YOU J, SNYDER BS, PAPAEFTHYMIOU GC, HOLM RH. ChemInform Abstract: On the Molecular/Solid-State Boundary. A Cyclic Iron-Sulfur Cluster of Nuclearity Eighteen: Synthesis, Structure, and Properties. Cheminform. 21. DOI: 10.1002/CHIN.199020031  0.01
1990 WEIGEL JA, HOLM RH, SURERUS KK, MUENCK E. ChemInform Abstract: Spin Isolation of the (3Fe-4S) Fragment of a (4Fe-4S) Cluster: Electronic Properties of the (3Fe-4S)0 Cluster. Cheminform. 21. DOI: 10.1002/CHIN.199013042  0.01
1990 Lee SC, Holm RH. Nonmolecular metal chalcogenide/halide solids and their molecular cluster analogues Angewandte Chemie (International Edition in English). 29: 840-856. DOI: 10.1002/Anie.199008401  1
1990 Lee SC, Holm RH. „Nichtmolekulare” Metallchalcogenid/-halogenid-Festkörperverbindungen und ihre molekularen Cluster-Analoga Angewandte Chemie. 102: 868-885. DOI: 10.1002/Ange.19901020805  0.04
1990 Ciurli S, Carrié M, Weigel JA, Carney MJ, Stack TDP, Papaefthymiou GC, Holm RH. Subsite-differentiated analogues of native [4Fe-4S]2+ clusters: Preparation of clusters with five- and six-coordinate subsites and modulation of redox potentials and charge distributions Journal of the American Chemical Society. 112: 2654-2664.  1
1989 Conradson SD, Burgess BK, Vaughn SA, Roe AL, Hedman B, Hodgson KO, Holm RH. Cyanide and methylisocyanide binding to the isolated iron-molybdenum cofactor of nitrogenase. The Journal of Biological Chemistry. 264: 15967-74. PMID 2777773  1
1989 Weigel JA, Holm RH, Surerus KK, Munck E. Spin-isolation of the [3Fe-4S] fragment of a [4Fe-4S] cluster: electronic properties of the [3Fe-4S]0 cluster Journal of the American Chemical Society. 111: 9246-9247. DOI: 10.1021/Ja00208A027  0.01
1989 Surerus KK, Munck E, Snyder BS, Holm RH. A binuclear mixed-valence ferromagnetic iron system with an S = 9/2 ground state and valence trapped and detrapped states Journal of the American Chemical Society. 111: 5501-5502. DOI: 10.1021/Ja00196A086  0.01
1989 Snyder BS, Patterson GS, Abrahamson AJ, Holm RH. Binuclear iron system ferromagnetic in three oxidation states: synthesis, structures, and electronic aspects of molecules with a Fe2(OR)2 bridge unit containing Fe(III,III), Fe(III,II), and Fe(II,II) Journal of the American Chemical Society. 111: 5214-5223. DOI: 10.1021/Ja00196A031  0.01
1989 Craig JA, Holm RH. Reduction of nitrate to nitrite by molybdenum-mediated atom transfer: a nitrate reductase analog reaction system Journal of the American Chemical Society. 111: 2111-2115. DOI: 10.1021/Ja00188A026  0.01
1989 Stack TDP, Carney MJ, Holm RH. Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: electron-transfer coupling across sulfur-containing bridges of variable length Journal of the American Chemical Society. 111: 1670-1676. DOI: 10.1021/Ja00187A020  0.01
1989 Yu SB, Holm RH. Aspects of the oxygen atom transfer chemistry of tungsten Inorganic Chemistry. 28: 4385-4391. DOI: 10.1021/Ic00323A021  0.04
1989 Ciurli S, Carney MJ, Holm RH, Papaefthymiou GC. Stability range of heterometal cubane-type clusters MFe3S4: assembly of double-cubane clusters with the rhenium-iron-sulfur [[ReFe3S4]] core Inorganic Chemistry. 28: 2696-2698. DOI: 10.1021/Ic00313A002  0.01
1989 Craig JA, Harlan EW, Snyder BS, Whitener MA, Holm RH. Oxomolybdenum(IV,V,VI) complexes: structures, reactivities, and criteria of detection of binuclear (.mu.-oxo)molybdenum(V) products in oxygen atom transfer systems Inorganic Chemistry. 28: 2082-2091. DOI: 10.1021/Ic00310A015  0.01
1989 Ciurli S, Holm RH. Insertion of vanadium-iron-sulfur, [VFe3S4]2+, and molybdenum-iron-sulfur, [MoFe3S4]3+, cores into a semirigid trithiolate cavitand ligand: regiospecific reactions at a vanadium site similar to that in nitrogenase Inorganic Chemistry. 28: 1685-1690. DOI: 10.1021/Ic00308A018  0.01
1989 Carney MJ, Papaefthymiou GC, Frankel RB, Holm RH. Alternative spin states in synthetic analogs of biological iron-sulfur [4Fe-4S]+ clusters: further cases of variable ground states and the structure of (Et4N)3[Fe4S4(S-o-C6H4S-tert-Bu)4], containing a reduced cluster with a compressed tetragonal distortion Inorganic Chemistry. 28: 1497-1503. DOI: 10.1021/Ic00307A015  0.01
1989 Krueger HJ, Holm RH. Chemical and electrochemical reactivity of nickel(II,I) thiolate complexes: examples of ligand-based oxidation and metal-centered oxidative addition Inorganic Chemistry. 28: 1148-1155. DOI: 10.1021/Ic00305A026  0.01
1989 Reynolds MS, Holm R. Binding of oxysulfur anions to macrocyclic iron(II,III): [(Fe(TPP))2SO4] and Fe(Me6[14]-4,11-dieneN4)(S2O5)] Inorganica Chimica Acta. 155: 113-123. DOI: 10.1016/S0020-1693(00)89291-9  0.01
1989 Harlan E, Zhang Y, Holm R. Oxygen atom and imido group transfer reactions of Mo and V Journal of Inorganic Biochemistry. 36: 307. DOI: 10.1016/0162-0134(89)84468-X  0.01
1989 Scharbert B, Stack T, Weigel J, Whitener M, Holm R. Subsite-specific reactivity of Fe4S4 clusters bound to tridentate, trithiol ligands as models for enzyme active sites Journal of Inorganic Biochemistry. 36: 230. DOI: 10.1016/0162-0134(89)84247-3  0.01
1989 Carney M, Carrié M, Ciurli S, Holm R. Effects of pentacoordination at a single iron atom of site-functionalized Fe4S4 clusters Journal of Inorganic Biochemistry. 36: 230. DOI: 10.1016/0162-0134(89)84246-1  0.01
1989 Krüger H, Holm R. Stabilization of trivalent nickel in an anionic sulfur environment as part of an effort directed towards a functional model for nickel containing hydrogenases Journal of Inorganic Biochemistry. 36: 224. DOI: 10.1016/0162-0134(89)84228-X  0.01
1989 Lautens J, Sherman S, Holm R. Oxygen atom transfer reactions of molybdenum complexes and iron-porphyrin complexes as models for enzyme active sites Journal of Inorganic Biochemistry. 36: 176. DOI: 10.1016/0162-0134(89)84094-2  0.04
1989 You J, Snyder B, Holm R, Papaefthymiou G. [Na2Fe18S30]8−, A high-nuclearity cyclic cluster containing no terminal ligands: Amidate supported formation, structural diversity, novel physical properties Journal of Inorganic Biochemistry. 36: 175. DOI: 10.1016/0162-0134(89)84090-5  0.01
1989 Holm R. Models for metallobiomolecular active sites Journal of Inorganic Biochemistry. 36: 151. DOI: 10.1016/0162-0134(89)84023-1  0.01
1989 SNYDER BS, PATTERSON GS, ABRAHAMSON AJ, HOLM RH. ChemInform Abstract: Binuclear Iron System Ferromagnetic in Three Oxidation States: Synthesis, Structures, and Electronic Aspects of Molecules with a Fe2(OR)2 Bridge Unit Containing Fe(III,III), Fe(III,II), and Fe(II,II). Cheminform. 20. DOI: 10.1002/CHIN.198942288  0.01
1989 CIURLI S, CARNEY MJ, HOLM RH, PAPAEFTHYMIOU GC. ChemInform Abstract: Stability Range of Heterometal Cubane-Type Clusters MFe3S4: Assembly of Double-Cubane Clusters with the ReFe3S4 Core. Cheminform. 20. DOI: 10.1002/CHIN.198942286  0.01
1989 SURERUS KK, MUENCK E, SNYDER BS, HOLM RH. ChemInform Abstract: A Binuclear Mixed-Valence Ferromagnetic Iron System with an S = 9/2 Ground State and Valence Trapped and Detrapped States Cheminform. 20. DOI: 10.1002/CHIN.198941066  0.01
1989 CRAIG JA, HARLAN EW, SNYDER BS, WHITENER MA, HOLM RH. ChemInform Abstract: Oxomolybdenum(IV,V,VI) Complexes: Structures, Reactivities, and Criteria of Detection of Binuclear (μ-Oxo)molybdenum(V) Products in Oxygen Atom Transfer Systems. Cheminform. 20. DOI: 10.1002/CHIN.198939246  0.01
1989 CIURLI S, HOLM RH. ChemInform Abstract: Insertion of (VFe3S4)2+ and (MoFe3S4)3+ Cores into a Semirigid Trithiolate Cavitand Ligand: Regiospecific Reactions at a Vanadium Site Similar to That in Nitrogenase. Cheminform. 20. DOI: 10.1002/CHIN.198931227  0.04
1989 CARNEY MJ, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: Alternative Spin States in Synthetic Analogues of Biological (4Fe-4S)+ Clusters: Further Cases of Variable Ground States and the Structure of (Et4N)3(Fe4S4(S-o-C6H4StBu)4), Containing a Reduced Cluster with a Compressed Tetragonal Dis Cheminform. 20. DOI: 10.1002/CHIN.198931048  0.01
1989 KRUEGER H, HOLM RH. ChemInform Abstract: Chemical and Electrochemical Reactivity of Nickel(II,I) Thiolate Complexes: Examples of Ligand-Based Oxidation and Metal-Centered Oxidative Addition. Cheminform. 20. DOI: 10.1002/CHIN.198926268  0.01
1989 REYNOLDS MS, HOLM RH. ChemInform Abstract: Binding of Oxysulfur Anions to Macrocyclic Iron(II,III): ((Fe(TPP))2SO4) and (Fe(Me6(14)-4,11-dieneN4)(S2O5)). Cheminform. 20. DOI: 10.1002/CHIN.198913261  0.01
1989 ZHANG Y, HOLM RH. ChemInform Abstract: Li3(VS4)·2 DMF: A Solubilized Form of Tetrathiovanadate(V). Cheminform. 20. DOI: 10.1002/CHIN.198903036  0.01
1989 Stack TDP, Carney MJ, Holm RH. Formation of bridged [4Fe-4S]2+ double cubanes by site-specific reactions: Electron-transfer coupling across sulfur-containing bridges of variable length Journal of the American Chemical Society. 111: 1670-1676.  1
1988 Carney MJ, Papaefthymiou GC, Spartalian K, Frankel RB, Holm RH. Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors. Journal of the American Chemical Society. 110: 6084-95. PMID 22148785 DOI: 10.1021/Ja00226A025  1
1988 Conradson SD, Burgess BK, Holm RH. Fluorine-19 chemical shifts as probes of the structure and reactivity of the iron-molybdenum cofactor of nitrogenase. The Journal of Biological Chemistry. 263: 13743-9. PMID 2843534  1
1988 You JF, Snyder BS, Holm RH. [Na2Fe18S30]8-. A high-nuclearity cyclic cluster generated solely by iron-sulfur bridge bonding Journal of the American Chemical Society. 110: 6589-6591. DOI: 10.1021/Ja00227A064  0.01
1988 Caradonna JP, Reddy PR, Holm RH. Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: relevance to molybdoenzymes Journal of the American Chemical Society. 110: 2139-2144. DOI: 10.1021/Ja00215A022  0.01
1988 Mukherjee RN, Stack TDP, Holm RH. Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): structures, antiferromagnetic coupling, and properties in solution Journal of the American Chemical Society. 110: 1850-1861. DOI: 10.1021/Ja00214A030  0.01
1988 Reynolds MS, Holm RH. Iron-sulfur-thiolate basket clusters Inorganic Chemistry. 27: 4494-4499. DOI: 10.1021/Ic00297A031  0.01
1988 Zhang YP, Holm RH. Li3[VS4].cntdot.2DMF: a solubilized form of tetrathiovanadate(V) Inorganic Chemistry. 27: 3875-3876. DOI: 10.1021/Ic00294A043  0.12
1988 Synder BS, Holm RH. Hexanuclear iron-sulfur basket clusters: topological isomers of prismanes. Synthesis, structure, and reactions Inorganic Chemistry. 27: 2339-2347. DOI: 10.1021/Ic00286A024  0.01
1988 Mukherjee RN, Abrahamson AJ, Patterson GS, Stack TDP, Holm RH. A new class of (N,N'-bis(salicylideneamino)ethanato)iron(II) complexes: five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions Inorganic Chemistry. 27: 2137-2144. DOI: 10.1021/Ic00285A026  0.01
1988 Snyder BS, Reynolds MS, Noda I, Holm RH. Core conversion reactions of iron-sulfur clusters: topological isomer of the Fe6S6-prismane core Inorganic Chemistry. 27: 595-597. DOI: 10.1021/Ic00277A004  0.04
1988 Carney MJ, Papaefthymiou GC, Whitener MA, Spartalian K, Frankel RB, Holm RH. Alternative spin states in synthetic analogs of biological clusters: spin-quartet ground states and structures of tetrakis(benzenethiolato)tetrasulfidotetraferrate(3-) and tetrakis(benzenethiolato)tetraselenidotetraferrate(3-) as their tetramethylammonium salts Inorganic Chemistry. 27: 346-352. DOI: 10.1021/Ic00275A023  0.01
1988 YOU J, SNYDER BS, HOLM RH. ChemInform Abstract: (Na2Fe18S30)8-: A High-Nuclearity Cyclic Cluster Generated Solely by Iron-Sulfur Bridge Bonding. Cheminform. 19. DOI: 10.1002/CHIN.198849038  0.01
1988 SNYDER BS, HOLM RH. ChemInform Abstract: Hexanuclear Iron-Sulfur Basket Clusters: Topological Isomers of Prismanes. Synthesis, Structure, and Reactions. Cheminform. 19. DOI: 10.1002/CHIN.198843303  0.01
1988 STACK TDP, HOLM RH. ChemInform Abstract: Subsite-Differentiated Analogues of Biological (4 Fe-4 S)2+ Clusters: Synthesis, Solution and Solid-State Structures, and Subsite-Specific Reactions. Cheminform. 19. DOI: 10.1002/CHIN.198831253  0.01
1988 SNYDER BS, REYNOLDS MS, NODA I, HOLM RH. ChemInform Abstract: Core Conversion Reactions of Iron-Sulfur Clusters: Topological Isomer of the Fe6S6-Prismance Core. Cheminform. 19. DOI: 10.1002/CHIN.198825291  0.01
1988 CARNEY MJ, PAPAEFTHYMIOU GC, WHITENER MA, SPARTALIAN K, FRANKEL RB, HOLM RH. ChemInform Abstract: Alternative Spin States in Synthetic Analogues of Biological Clusters: Spin-Quartet Ground States and Structures of (Fe4S4(SPh)4)3- and (Fe4Se4(SPh)4)3- as Their Tetramethylammonium Salts. Cheminform. 19. DOI: 10.1002/CHIN.198820052  0.01
1988 HOLM RH. ChemInform Abstract: Metal-Centered Oxygen Atom Transfer Reactions Cheminform. 19. DOI: 10.1002/CHIN.198816374  0.01
1988 KRUEGER H, HOLM RH. ChemInform Abstract: Stabilization of Nickel(III) in a Classical N2S2 Coordination Environment Containing Anionic Sulfur. Cheminform. 19. DOI: 10.1002/CHIN.198810337  0.01
1988 Mukherjee RN, Stack TDP, Holm RH. Angle dependence of the properties of the [Fe2X]4+ bridge unit (X = O, S): Structures, antiferromagnetic coupling, and properties in solution Journal of the American Chemical Society. 110: 1850-1861.  1
1988 Mukherjee RN, Abrahamson AJ, Patterson GS, Stack TDP, Holm RH. A new class of (N,N′-bis(salicylideneamino)ethanato)iron(II) complexes: Five-coordinate [FeII(salen)L]-. Preparation, properties, and mechanism of electron-transfer reactions Inorganic Chemistry. 27: 2137-2144.  1
1988 Stack TDP, Holm RH. Subsite-differentiated analogues of biological [4Fe-4S]2+ clusters: Synthesis, solution and solid-state structures, and subsite-specific reactions Journal of the American Chemical Society. 110: 2484-2494.  1
1988 Caradonna JP, Reddy PR, Holm RH. Kinetics, mechanisms, and catalysis of oxygen atom transfer reactions of S-oxide and pyridine N-oxide substrates with molybdenum(IV,VI) complexes: Relevance to molybdoenzymes Journal of the American Chemical Society. 110: 2139-2144.  1
1987 Krueger HJ, Holm RH. Stabilization of nickel(III) in a classical N2S2 coordination environment containing anionic sulfur Inorganic Chemistry. 26: 3645-3647. DOI: 10.1021/Ic00269A002  0.01
1987 Carney MJ, Kovacs JA, Zhang YP, Papaefthymiou GC, Spartalian K, Frankel RB, Holm RH. Comparative electronic properties of vanadium-iron-sulfur and molybdenum-iron-sulfur clusters containing isoelectronic cubane-type [VFe3S4]2+ and [MoFe3S4]3+ cores Inorganic Chemistry. 26: 719-724. DOI: 10.1021/Ic00252A016  0.04
1987 Kovacs JA, Holm RH. Structural chemistry of vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4]2+ core Inorganic Chemistry. 26: 711-718. DOI: 10.1021/Ic00252A015  0.01
1987 Kovacs JA, Holm RH. Heterometallic clusters: synthesis and reactions of vanadium-iron-sulfur single- and double-cubane clusters and the structure of [V2Fe6S8Cl4(C2H4S2)2]4- Inorganic Chemistry. 26: 702-711. DOI: 10.1021/Ic00252A014  0.04
1987 Zhang YP, Bashkin JK, Holm RH. Phosphine cleavage of iron(III)-bridged double cubanes: a new route to MoFe3S4 single cubanes Inorganic Chemistry. 26: 694-702. DOI: 10.1021/Ic00252A013  0.16
1987 Holm RH. Metal-centered oxygen atom transfer reactions Chemical Reviews. 87: 1401-1449. DOI: 10.1021/Cr00082A005  0.01
1987 Kovacs JA, Bashkin JK, Holm RH. [Fe2S2(CO)6]2- as a cluster precursor: synthesis and structure of [MoFe3S6(CO)6]2- and oxidative decarbonylation to a persulfide-bridged MoFe3S4 double cubane Polyhedron. 6: 1445-1456. DOI: 10.1016/S0277-5387(00)80908-0  1
1987 STACK TDP, HOLM RH. ChemInform Abstract: Subsite-Specific Functionalization of the (4 Fe-4 S)2+ Analogue of Iron-Sulfur Protein Clusters. Cheminform. 18. DOI: 10.1002/CHIN.198734287  0.01
1987 CARNEY MJ, KOVACS JA, ZHANG Y, PAPAEFTHYMIOU GC, SPARTALIAN K, FRANKEL RB, HOLM RH. ChemInform Abstract: Comparative Electronic Properties of Vanadium-Iron-Sulfur and Molybdenum-Iron-Sulfur Clusters Containing Isoelectronic Cubane-Type (VFe3S4)2+ and (MoFe3S4)3+ Cores. Cheminform. 18. DOI: 10.1002/chin.198730247  0.01
1987 KOVACS JA, HOLM RH. ChemInform Abstract: Structural Chemistry of Vanadium-Iron-Sulfur Clusters Containing the Cubane-Type (VFe3S4)2+ Core. Cheminform. 18. DOI: 10.1002/chin.198730246  0.01
1987 KOVACS JA, HOLM RH. ChemInform Abstract: Heterometallic Clusters: Synthesis and Reactions of Vanadium-Iron-Sulfur Single- and Double-Cubane Clusters and the Structure of (V2Fe6S8Cl4(C2H4S2)2)4-. Cheminform. 18. DOI: 10.1002/chin.198730245  0.01
1987 HARLAN EW, BERG JM, HOLM RH. ChemInform Abstract: Thermodynamic Fitness of Molybdenum(IV,VI) Complexes for Oxygen Atom Transfer Reactions, Including Those with Enzymatic Substrates. Cheminform. 18. DOI: 10.1002/CHIN.198712079  0.01
1987 NODA I, SNYDER BS, HOLM RH. ChemInform Abstract: Fe7S6(PEt3)4Cl3: A Topological Link Between the Prismatic and Cuboctahedral Structures of Iron-Sulfur Clusters. Cheminform. 18. DOI: 10.1002/CHIN.198709056  0.01
1987 WHITENER MA, BASHKIN JK, HAGEN KS, GIRERD J, GAMP E, EDELSTEIN N, HOLM RH. ChemInform Abstract: A New Inorganic Ring System: Planar Fe3(μ2-SR)3 in (Fe3(SR)3X6)3- - Synthesis, Structures, and Solution Conformation and Equilibrium. Cheminform. 18. DOI: 10.1002/CHIN.198702287  0.01
1987 Zhang YP, Bashkin JK, Holm RH. Phosphine cleavage of iron(III)-bridged double cubanes: A new route to MoFe3S4 single cubanes Inorganic Chemistry. 26: 694-702.  1
1987 Stack TDP, Holm RH. Subsite-specific functionalization of the [4Fe-4S]2+ analogue of iron-sulfur protein clusters Journal of the American Chemical Society. 109: 2546-2547.  1
1986 Caradonna JP, Harlan EW, Holm RH. Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications. Journal of the American Chemical Society. 108: 7856-8. PMID 22283311 DOI: 10.1021/Ja00284A073  1
1986 Harlan EW, Berg JM, Holm RH. Thermodynamic fitness of molybdenum(IV,VI) complexes for oxygen-atom transfer reactions, including those with enzymic substrates Journal of the American Chemical Society. 108: 6992-7000. DOI: 10.1021/Ja00282A025  0.04
1986 Whitener MA, Bashkin JK, Hagen KS, Girerd JJ, Gamp E, Edelstein N, Holm RH. A new inorganic ring system: Planar Fe3(μ2-SR)3 in [Fe3(SR)3X6]3- - Synthesis, structures, and solution conformation and equilibrium Journal of the American Chemical Society. 108: 5607-5620. DOI: 10.1021/Ja00278A040  1
1986 Carney MJ, Holm RH, Papaefthymiou GC, Frankel RB. Demonstration of alternative spin states in clusters containing the biologically relevant [Fe4S4]1+ core Journal of the American Chemical Society. 108: 3519-3521. DOI: 10.1021/Ja00272A064  0.01
1986 Kovacs JA, Holm RH. Assembly of vanadium-iron-sulfur cubane clusters from mononuclear and linear trinuclear reactants Journal of the American Chemical Society. 108: 340-341. DOI: 10.1021/Ja00262A050  0.01
1986 Noda I, Snyder BS, Holm RH. Trichlorotetrakis(triethylphosphine)hexathioheptairon (Fe7S6(PEt3)4Cl3): a topological link between the prismatic and cube-octahedral structures of iron-sulfur clusters Inorganic Chemistry. 25: 3851-3853. DOI: 10.1021/Ic00242A004  0.01
1986 Holm RH, Berg JM. Toward functional models of metalloenzyme active sites: analog reaction systems of the molybdenum oxo transferases Accounts of Chemical Research. 19: 363-370. DOI: 10.1021/Ar00131A006  0.08
1986 Mukherjee RN, Pulla Rao C, Holm RH. Solution chemistry of ethane-1,2-dithiolate complexes: equilibria and electron-transfer reactions Inorganic Chemistry. 25: 2979-2989. DOI: 10.1002/Chin.198652062  0.01
1986 MUKHERJEE RN, RAO CP, HOLM RH. ChemInform Abstract: Solution Chemistry of Ethane-1,2-dithiolate Complexes: Equilibria and Electron-Transfer Reactions. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198652062  0.04
1986 CARNEY MJ, HOLM RH, PAPAEFTHYMIOU GC, FRANKEL RB. ChemInform Abstract: Demonstration of Alternative Spin States in Clusters Containing the Biologically Relevant (Fe4S4)+ Core. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198641062  0.01
1986 RAO CP, DORFMAN JR, HOLM RH. ChemInform Abstract: Synthesis and Structural Systematics of Ethane-1,2-dithiolato Complexes. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198627243  0.01
1986 Rao CP, Dorfman JR, Holm RH. Synthesis and structural systematics of ethane-1,2-dithiolato complexes Inorganic Chemistry. 25: 428-439. DOI: 10.1002/Chin.198627243  0.01
1986 KOVACS JA, HOLM RH. ChemInform Abstract: Assembly of Vanadium - Iron - Sulfur Cubane Clusters from Mononuclear and Linear Trinuclear Reactants. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198618039  0.01
1986 CONRADSON SD, BURGESS BK, NEWTON WE, HODGSON KO, MCDONALD JW, RUBINSON JF, GHELLER SF, MORTENSON LE, ADAMS MWW, MASCHARAK PK, ARMSTRONG WA, HOLM RH. ChemInform Abstract: Structural Insights from the Mo K-Edge X-Ray Absorption Near Edge Structure of the Iron-Molybdenum Protein of Nitrogenase and Its Iron-Molybdenum Cofactor by Comparison with Synthetic Fe Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198616065  0.01
1986 DO Y, SIMHON ED, HOLM RH. ChemInform Abstract: Tetrathiovanadate(V) and Tetrathiorhenate(VII): Structures and Reactions, Including Characterization of the VFe2S4Core Unit. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198616004  0.01
1986 Caradonna JP, Harlan EW, Holm RH. Thiol as an electron donor in molybdenum oxo-transferase analogue reaction systems: Observations by 19F NMR spectroscopy and biological implications Journal of the American Chemical Society. 108: 7856-7858.  1
1985 Do Y, Simhon ED, Holm RH. Tetrathiovanadate(V) and tetrathiorhenate(VII): structures and reactions, including characterization of the VFe2S4 core unit Inorganic Chemistry. 24: 4635-4642. DOI: 10.1021/Ic00220A042  0.01
1985 Watson AD, Rao CP, Dorfman JR, Holm RH. Systematic stereochemistry of metal(II) thiolates: synthesis and structures of [M2(SC2H5)6]2- (M = Mn(II), Ni(II), Zn(II), Cd(II)) Inorganic Chemistry. 24: 2820-2826. DOI: 10.1021/Ic00212A024  0.01
1985 Do Y, Simhon ED, Holm RH. Oxo sulfido ligand substitution in dimolybdate ([Mo2O7]2-): reaction sequence and characterization of the final product, [MoS3(OSiMe3)]- Inorganic Chemistry. 24: 1831-1838. DOI: 10.1021/Ic00206A028  0.01
1985 Do Y, Holm RH. Variability of niobiumsulfur bond lengths: The molecular structures of sulfido-tris(N,N-diethyldithiocarbamato)niobium(V) Inorganica Chimica Acta. 104: 33-40. DOI: 10.1016/S0020-1693(00)83782-2  1
1985 DO Y, HOLM RH. ChemInform Abstract: VARIABILITY OF NIOBIUM:SULFUR MULTIPLE BOND LENGTHS: THE MOLECULAR STRUCTURES OF SULFIDOTRIS(N,N-DIETHYLDITHIOCARBAMATO)NIOBIUM(V) Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198552063  0.01
1985 WATSON AD, RAO CP, DORFMAN JR, HOLM RH. ChemInform Abstract: SYSTEMATIC STEREOCHEMISTRY OF METAL(II) THIOLATES: SYNTHESIS AND STRUCTURES OF (M2(SC2H5)6)2- (M = MN(II), NI(II), ZN(II), CD(II)) Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198550282  0.01
1985 Do Y, Simhon ED, Holm RH. Trinuclear oxothiomolybdates from the reductive cleavage of [Mo8O26]4- with hexamethyldisilthiane Inorganic Chemistry. 24: 2827-2832. DOI: 10.1002/Chin.198550260  0.01
1985 DO Y, SIMHON ED, HOLM RH. ChemInform Abstract: TRINUCLEAR OXOTHIOMOLYBDATES FROM THE REDUCTIVE CLEAVAGE OF (MO8O26)4- WITH HEXAMETHYLDISILTHIANE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198550260  0.01
1985 DO Y, SIMHON ED, HOLM RH. ChemInform Abstract: OXO SULFIDO LIGAND SUBSTITUTION IN DIMOLYBDATE ((MO2O7)2-): REACTION SEQUENCE AND CHARACTERIZATION OF THE FINAL PRODUCT, (MOS3(OSIME3))- Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198541267  0.01
1985 SOLA J, DO Y, BERG JM, HOLM RH. ChemInform Abstract: SOLUBLE SULFIDES OF NIOBIUM(V) AND TANTALUM(V): SYNTHESIS, STRUCTURES, AND PROPERTIES OF THE FIVEFOLD SYMMETRIC CAGES (M6S17)4- Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198539038  0.04
1985 Sola J, Do Y, Berg JM, Holm RH. Soluble sulfides of niobium(V) and tantalum(V): synthesis, structures, and properties of the fivefold symmetric cages [M6S17]4- Inorganic Chemistry. 24: 1706-1713. DOI: 10.1002/Chin.198539038  0.04
1985 CHRISTOU G, HAGEN KS, BASHKIN JK, HOLM RH. ChemInform Abstract: THE CLUSTERS (CO8S6(SPH)8)4-,5-: PREPARATIONS, PROPERTIES, AND STRUCTURAL RELATIONSHIP OF NEAR-CUBIC CO8(μ4-S)6 CORES TO THE CLUSTERS IN SYNTHETIC PENTLANDITE Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198532302  0.01
1985 Christou G, Hagen KS, Bashkin JK, Holm RH. The clusters [Co8S6(SPh)8]4-,5-: Preparations, properties, and structural relationship of near-cubic Co8(μ4-S)6 cores to the clusters in synthetic pentlandite Inorganic Chemistry. 24: 1010-1018. DOI: 10.1002/Chin.198532302  1
1985 Kovacs JA, Bashkin JK, Holm RH. Persulfide-bridged iron-molybdenum-sulfur clusters of biological relevance: two synthetic routes and the structures of intermediate and product clusters Journal of the American Chemical Society. 107: 1784-1786. DOI: 10.1002/Chin.198530341  0.04
1985 KOVACS JA, BASHKIN JK, HOLM RH. ChemInform Abstract: PERSULFIDE-BRIDGED IRON-MOLYBDENUM-SULFUR CLUSTERS OF BIOLOGICAL RELEVANCE: TWO SYNTHETIC ROUTES AND THE STRUCTURES OF INTERMEDIATE AND PRODUCT CLUSTERS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198530341  0.01
1985 DORFMAN JR, RAO CP, HOLM RH. ChemInform Abstract: STRUCTURAL DIVERSITY OF HOMOLEPTIC ETHANE-1,2-DITHIOLATO COMPLEXES OF THE FIRST TRANSITION SERIES Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198529307  0.01
1985 Dorfman JR, Rao CP, Holm RH. Structural diversity of homoleptic ethane-1,2-dithiolato complexes of the first transition series Inorganic Chemistry. 24: 453-454. DOI: 10.1002/Chin.198529307  0.01
1985 BERG JM, HOLM RH. ChemInform Abstract: MODEL FOR THE ACTIVE SITES OF OXO-TRANSFER MOLYBDOENZYMES: REACTIVITY, KINETICS, AND CATALYSIS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198527294  0.12
1985 Berg JM, Holm RH. Model for the active sites of oxo-transfer molybdoenzymes: reactivity, kinetics, and catalysis Journal of the American Chemical Society. 107: 925-932. DOI: 10.1002/Chin.198527294  0.04
1985 Berg JM, Holm RH. Model for the active site of oxo-transfer molybdoenzymes: synthesis, structure, and properties Journal of the American Chemical Society. 107: 917-925. DOI: 10.1002/Chin.198527293  0.04
1985 BERG JM, HOLM RH. ChemInform Abstract: MODEL FOR THE ACTIVE SITE OF OXO-TRANSFER MOLYBDOENZYMES: SYNTHESIS, STRUCTURE, AND PROPERTIES Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198527293  0.01
1985 DORFMAN JR, GIRERD JJ, SIMHON ED, STACK TDP, HOLM RH. ChemInform Abstract: SYNTHESIS, STRUCTURE, AND ELECTRONIC FEATURES OF (μ-SULFIDO)BIS((N,N′-ETHYLENEBIS(SALICYLALDIMINATO))IRON(III)), (FE(SALEN))2S, CONTAINING THE ONLY AUTHENTICATED EXAMPLE OF THE IRON(III)-SULFUR-IRON(III) SINGLE BRIDGE Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198520283  0.01
1985 REYNOLDS MS, BERG JM, HOLM RH. ChemInform Abstract: KINETICS OF OXYGEN ATOM TRANSFER REACTIONS INVOLVING OXOMOLYBDENUM COMPLEXES. GENERAL TREATMENT FOR REACTIONS WITH INTERMEDIATE OXO-BRIDGED MOLYBDENUM(V) DIMER FORMATION Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198503290  0.01
1985 GIRERD JJ, PAPAEFTHYMIOU GC, WATSON AD, GAMP E, HAGEN KS, EDELSTEIN N, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRONIC PROPERTIES OF THE LINEAR ANTIFERROMAGNETICALLY COUPLED CLUSTERS (FE3S4(SR)4)3-, STRUCTURAL ISOMERS OF THE IRON-SULFUR(1+) ((FE3S4)1+) UNIT IN IRON-SULFUR PROTEINS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198503067  0.01
1985 HAGEN KS, WATSON AD, HOLM RH. ChemInform Abstract: ANALOGS OF THE (FE4S4)+ SITES OF REDUCED FERREDOXINS: SINGLE-STEP SYNTHESIS OF THE CLUSTERS (FE4S4(SR)4)3- AND EXAMPLES OF COMPRESSED TETRAGONAL COR STRUCTURES Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198501289  0.01
1984 Holm RH, Berg JM. Mononuclear active sites of molybdoenzymes: chemical approaches to structure and reactivity Pure and Applied Chemistry. 56: 1645-1657. DOI: 10.1351/Pac198456111645  0.08
1984 Palermo RE, Singh R, Bashkin JK, Holm RH. Molybdenum atom ligand substitution reactions of molybdenum-iron-sulfur (MoFe3S4) cubane-type clusters: synthesis and structures of clusters containing molybdenum-bound pseudosubstrates of nitrogenase Journal of the American Chemical Society. 106: 2600-2612. DOI: 10.1021/Ja00321A019  1
1984 Dorfman JR, Girerd JJ, Simhon ED, Stack TDP, Holm RH. Synthesis, structure, and electronic features of (.mu.-sulfido)bis[(N,N'-ethylenebis(salicylaldiminato))iron(III)], [Fe(salen)]2S, containing the only authenticated example of the iron(III)-sulfur-iron(III) single bridge Inorganic Chemistry. 23: 4407-4412. DOI: 10.1021/Ic00194A002  0.01
1984 Hagen KS, Watson AD, Holm RH. Analogs of the [Fe4S4]+ sites of reduced ferredoxins: single-step synthesis of the clusters [Fe4S4(SR)4]3- and examples of compressed tetragonal core structures Inorganic Chemistry. 23: 2984-2990. DOI: 10.1021/Ic00187A017  0.01
1984 Hagen KS, Holm RH. Synthesis and stereochemistry of metal(II) thiolates of the types [M(SR)4]2-, [M2(SR)6]2-, and [M4(SR)10]2- (M = Fe(II), Co(II)) Inorganic Chemistry. 23: 418-427. DOI: 10.1021/Ic00172A009  0.01
1984 Armstrong WH, Youinou MT, Palermo RE, Holm RH. Synthesis of a new class of polydentate ligands: [bis(2-imidazolyl)methyl] amino-thioether-thiols Inorganica Chimica Acta. 88: 21-27. DOI: 10.1016/S0020-1693(00)81865-4  1
1984 Holm RH, Hagen KS, Watson AD. Assembly Of Biologically Relevant Iron-Sulfur Clusters Cheminform. 15: 115-124. DOI: 10.1016/B978-0-08-029249-6.50017-9  1
1984 Reynolds MS, Berg JM, Holm RH. Kinetics of oxygen atom transfer reactions involving oxomolybdenum complexes. General treatment for reactions with intermediate oxo-bridged molybdenum(V) dimer formation Inorganic Chemistry. 23: 3057-3062. DOI: 10.1002/Chin.198503290  0.04
1984 Girerd JJ, Papaefthymiou GC, Watson AD, Gamp E, Hagen KS, Edelstein N, Frankel RB, Holm RH. Electronic properties of the linear antiferromagnetically coupled clusters [Fe3S4(SR)4]3-, structural isomers of the iron-sulfur(1+) ([Fe3S4]1+) unit in iron-sulfur proteins Journal of the American Chemical Society. 106: 5941-5947. DOI: 10.1002/Chin.198503067  0.01
1984 ARMSTRONG WH, YOUINOU M, PALERMO RE, HOLM RH. ChemInform Abstract: SYNTHESIS OF A NEW CLASS OF POLYDENTATE LIGANDS: (BIS(2-IMIDAZOLYL)METHYL)AMINO-THIOETHER-THIOLS Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198450203  0.01
1984 OKUNO Y, HORITA K, YONEMITSU O, SHIBATA K, AMEMIYA T, HOLM RH. ChemInform Abstract: A CONVENIENT METHOD FOR THE SYNTHESIS OF MACROCYCLIC TETRA-AMIDES BY DOUBLE CONDENSATION REACTION Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198435241  0.01
1984 Berg JM, Holm RH. Synthetic approach to the mononuclear active sites of molybdoenzymes: catalytic oxygen atom transfer reactions by oxomolybdenum(IV,VI) complexes with saturation kinetics and without molybdenum(V) dimer formation Journal of the American Chemical Society. 106: 3035-3036. DOI: 10.1002/Chin.198434262  0.16
1984 BERG JM, HOLM RH. ChemInform Abstract: SYNTHETIC APPROACH TO THE MONONUCLEAR ACTIVE SITES OF MOLYBDOENZYMES: CATALYTIC OXYGEN ATOM TRANSFER REACTIONS BY OXOMOLYBDENUM(IV,VI) COMPLEXES WITH SATURATION KINETICS AND WITHOUT MOLYBDENUM(V) DIMER FORMATION Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198434262  0.16
1984 PALERMO RE, SINGH R, BASHKIN JK, HOLM RH. ChemInform Abstract: MOLYBDENUM ATOM LIGAND SUBSTITUTION REACTIONS OF MOLYBDENUM-IRON-SULFUR (MOFE3S4) CUBANE-TYPE CLUSTERS: SYNTHESIS AND STRUCTURES OF CLUSTERS CONTAINING MOLYBDENUM-BOUND PSEUDOSUBSTRATES OF NITROGENASE Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198433252  0.01
1984 HOLM RH, HAGEN KS, WATSON AD. ChemInform Abstract: Assembly of Biologically Relevant Iron-Sulfur Clusters Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198431337  0.01
1984 HAGEN KS, HOLM RH. ChemInform Abstract: SYNTHESIS AND STEREOCHEMISTRY OF METAL(II) THIOLATES OF THE TYPES (M(SR)4)2-, (M2(SR)6)2-, AND (M4(SR)10)2- (M = FE(II), CO(II)) Chemischer Informationsdienst. 15. DOI: 10.1002/Chin.198421287  0.01
1984 COSTA T, DORFMAN JR, HAGEN KS, HOLM RH. ChemInform Abstract: SYNTHESIS AND STEREOCHEMISTRY OF MONO-, BI-, AND TETRANUCLEAR MANGANESE THIOLATES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198413263  0.01
1984 SOLA J, DO Y, BERG JM, HOLM RH. ChemInform Abstract: SOLUBLE METAL SULFIDES. SYNTHESIS AND STRUCTURES OF (M6S17)4- (M = NIOBIUM OR TANTALUM): ICOSAHEDRAL-FRAGMENT CAGES CONTAINING FOUR TYPES OF COORDINATED SULFIDE Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198413038  0.12
1984 JOHNSON RE, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: EFFECTS OF SECONDARY BONDING INTERACTIONS ON THE IRON-SULFUR CUBANE-TYPE (FE4S4)2+ CORE OF FERREDOXIN SITE ANALOGS: (FE4S4(SC6H4-O-OH)4)2-, A DISTORTED CUBANE-TYPE CLUSTER WITH ONE FIVE-COORDINATE IRON ATOM Chemischer Informationsdienst. 15. DOI: 10.1002/CHIN.198412291  0.01
1984 DO Y, SIMHON ED, HOLM RH. ChemInform Abstract: IMPROVED SYNTHESES OF TETRACHLORODI-μ-SULFIDODIFERRATE(2-) ((FE2S2CL4)2-) AND HEXACHLORO-μ-OXODIFERRATE(2-) ((FE2OCL6)2-) AND OXO/SULFIDO LIGAND SUBSTITUTION BY USE OF SILYLSULFIDE REAGENTS Chemischer Informationsdienst. 15. DOI: 10.1002/CHIN.198409037  0.01
1984 DO Y, SIMHON ED, HOLM RH. ChemInform Abstract: DERIVATIVES OF TETRATHIOVANADATE(V): SYNTHESIS OF THE LINEAR HETEROMETALLIC FE(μ2-S)2V(μ2-S)2FE CORE AND THE STRUCTURES OF TETRATHIOVANADATE(3-) ION ((VS4)3-) AND TETRACHLOROTETRATHIODIFERRATEVANADATE(3-) ION ((VFE2S4CL4)3-) Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198406259  0.01
1984 MIZOBE Y, MASCHARAK PK, PALERMO RE, HOLM RH. ChemInform Abstract: SYNTHESIS AND SELECTED PROPERTIES OF A REDUCED SINGLE-CUBANE CLUSTER CONTAINING THE (MOFE3S4)2+ (S = 2) CORE Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198405274  0.01
1984 DORFMAN JR, HOLM RH. ChemInform Abstract: TETRAKIS(ETHANE-1,2-DITHIOLATO)DIVANADATE(III): A BINUCLEAR COMPLEX WITH A QUADRUPLE BRIDGE, A METAL-METAL BOND, AND NONOCTAHEDRAL STEREOCHEMISTRY Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198405262  0.01
1984 YACHANDRA VK, HARE J, GEWIRTH A, CZERNUSZEWICZ RS, KIMURA T, HOLM RH, SPIRO TG. ChemInform Abstract: RESONANCE RAMAN SPECTRA OF SPINACH FERREDOXIN AND ADRENODOXIN AND OF ANALOG COMPLEXES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198404043  1
1984 HAGEN KS, HOLM RH. ChemInform Abstract: THE STEREOCHEMISTRY OF DECAKIS(BENZENETHIOLATO)TETRACADMATE(2-) ION, A CAGE COMPLEX RELATED TO THE CADMIUM-CYSTEINATE AGGREGATES IN METALLOTHIONEINS Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198403292  0.01
1984 MASCHARAK PK, PAPAEFTHYMIOU GC, ARMSTRONG WH, FONER S, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRONIC PROPERTIES OF SINGLE- AND DOUBLE-MOFE3S4 CUBANE-TYPE CLUSTERS Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198401052  0.01
1984 Palermo RE, Singh R, Bashkin JK, Holm RH. Molybdenum atom ligand substitution reactions of MoFe3S4 cubane-type clusters: Synthesis and structures of clusters containing Mo-bound pseudosubstrates of nitrogenase Journal of the American Chemical Society. 106: 2600-2612.  1
1983 Do Y, Simhon ED, Holm RH. Derivatives of tetrathiovanadate(V): synthesis of the linear heterometallic Fe(.mu.2-S)2V(.mu.2-S)2Fe core and the structures of tetrathiovanadate(3-) ion ([VS4]3-) and tetrachlorotetrathiodiferratevanadate(3-) ion ([VFe2S4Cl4]3-) Journal of the American Chemical Society. 105: 6731-6732. DOI: 10.1021/JA00360A041  0.01
1983 Palermo RE, Holm RH. Reactivity properties of single molybdenum iron sulfide (MoFe3S4) cubane-type clusters: synthesis, structure, and ligand substitution reactions of [MoFe3S4Cl3(3,6-(C3H5)2C6H2O2)(THF)]2- Journal of the American Chemical Society. 105: 4310-4318. DOI: 10.1021/ja00351a032  0.01
1983 Hagen KS, Watson AD, Holm RH. Synthetic routes to iron sulfide (Fe2S2, Fe3S4, Fe4S4, and Fe6S9), clusters from the common precursor tetrakis(ethanethiolate)ferrate(2-) ion ([Fe(SC2H5)4]2-): structures and properties of [Fe3S4(SR)4]3- and bis(ethanethiolate)nonathioxohexaferrate(4-) ion ([Fe6S9(SC2H5)2]4-), examples of the newest types of Fe-S-SR clusters Journal of the American Chemical Society. 105: 3905-3913. DOI: 10.1021/Ja00350A028  0.01
1983 Mascharak PK, Armstrong WH, Mizobe Y, Holm RH. Single cubane-type MFe3S4 clusters (M = Mo, W): synthesis and properties of oxidized and reduced forms and the structure of (Et4N)3[MoFe3S4(S-p-C6H4Cl)4(3,6-(C3H5)2C6H2O2)] Journal of the American Chemical Society. 105: 475-483. DOI: 10.1021/Ja00341A029  0.01
1983 Do Y, Simhon ED, Holm RH. Improved syntheses of tetrachlorodi-.mu.-sulfidodiferrate(2-) ([Fe2S2Cl4]2-) and hexachloro-.mu.-oxodiferrate(2-) ([Fe2OCl6]2-) and oxo/sulfido ligand substitution by use of silylsulfide reagents Inorganic Chemistry. 22: 3809-3812. DOI: 10.1021/IC00167A027  0.01
1983 Hagen KS, Holm RH. The stereochemistry of decakis(benzenethiolato)tetracadmate(2-) ion, a cage complex related to the cadmium-cysteinate aggregates in metallothioneins Inorganic Chemistry. 22: 3171-3174. DOI: 10.1021/Ic00163A036  0.01
1983 Mascharak PK, Papaefthymiou GC, Armstrong WH, Foner S, Frankel RB, Holm RH. Electronic properties of single- and double-MoFe3S4 cubane-type clusters Inorganic Chemistry. 22: 2851-2858. DOI: 10.1021/Ic00162A017  0.01
1983 Berg JM, Holm RH. Structure proofs of ligated and polymeric dioxomolybdenum(VI)-tridentate complexes: MoO2(C5H3N-2,6-(CH2S)2)(C4H8SO) and [MoO2(C5H3N-2,6-(CH2O)2)]n Inorganic Chemistry. 22: 1768-1771. DOI: 10.1021/Ic00154A015  0.2
1983 Stephan DW, Papaefthymiou GC, Frankel RB, Holm RH. Analogs of the [4Fe-4S]+ sites of reduced ferredoxins: structural and spectroscopic properties of [(C2H5)4N]3[Fe4S4(S-p-C6H4Br)4] in crystalline and solution phases Inorganic Chemistry. 22: 1550-1557. DOI: 10.1021/Ic00152A026  0.04
1983 Yamamura T, Christou G, Holm RH. The homogeneous hydrogen-evolving systems [Mo2Fe6S8(SPh)9]4-,5-/C6H5SH: reaction characteristics, kinetics, and possible mechanisms Inorganic Chemistry. 22: 939-949. DOI: 10.1021/Ic00148A019  0.01
1983 Hagen KS, Christou G, Holm RH. Trinuclear metal(II)-sulfide-thiolate complexes: synthesis, structures, and properties of [M3S(1,2-(SCH2)2C6H4)3]2- (M = Fe(II), Co(II)) Inorganic Chemistry. 22: 309-314. DOI: 10.1021/Ic00144A021  0.01
1983 Mascharak PK, Hagen KS, Spence JT, Holm RH. Structural distortions of the [Fe4S4]2+ core of [Fe4S4(S-t-C4H9)4]2- in different crystalline environments and detection and instability of oxidized ([Fe4S4]3+) clusters Inorganica Chimica Acta. 80: 157-170. DOI: 10.1016/S0020-1693(00)91277-5  1
1983 Mizobe Y, Mascharak P, Palermo R, Holm R. Synthesis and selected properties of a reduced single-cubane cluster containing the [MoFe3,S4]2+ (S = 2) core Inorganica Chimica Acta. 80: L65-L67. DOI: 10.1016/S0020-1693(00)91249-0  0.01
1983 Costa T, Dorfman JR, Hagen KS, Holm RH. Synthesis and stereochemistry of mono-, bi-, and tetranuclear manganese thiolates Inorganic Chemistry. 22: 4091-4099. DOI: 10.1002/Chin.198413263  0.01
1983 Sola J, Do Y, Berg JM, Holm RH. Soluble metal sulfides. Synthesis and structures of [M6S17]4- (M = niobium or tantalum): icosahedral-fragment cages containing four types of coordinated sulfide Journal of the American Chemical Society. 105: 7784-7786. DOI: 10.1002/Chin.198413038  0.08
1983 Johnson RE, Papaefthymiou GC, Frankel RB, Holm RH. Effects of secondary bonding interactions on the iron-sulfur cubane-type [Fe4S4]2+ core of ferredoxin site analogs: [Fe4S4(SC6H4-o-OH)4]2-, a distorted cubane-type cluster with one five-coordinate iron atom Journal of the American Chemical Society. 105: 7280-7287. DOI: 10.1002/Chin.198412291  0.01
1983 Dorfman JR, Holm RH. Tetrakis(ethane-1,2-dithiolato)divanadate(III): a binuclear complex with a quadruple bridge, a metal-metal bond, and nonoctahedral stereochemistry Inorganic Chemistry. 22: 3179-3181. DOI: 10.1002/Chin.198405262  0.01
1983 Yachandra VK, Hare J, Gewirth A, Czernuszewicz RS, Kimura T, Holm RH, Spiro TG. Resonance Raman spectra of spinach ferredoxin and adrenodoxin and of analog complexes Journal of the American Chemical Society. 105: 6462-6469. DOI: 10.1002/Chin.198404043  1
1983 MASCHARAK PK, HAGEN KS, SPENCE JT, HOLM RH. ChemInform Abstract: STRUCTURAL DISTORTIONS OF THE (FE4S4)2+ CORE OF (FE4S4(S-TERT-C4H9)4)2- IN DIFFERENT CRYSTALLINE ENVIRONMENTS AND DETECTION AND INSTABILITY OF OXIDIZED ((FE4S4)3+) CLUSTERS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198348271  0.01
1983 HAGEN KS, WATSON AD, HOLM RH. ChemInform Abstract: SYNTHETIC ROUTES TO IRON SULFIDE (FE2S2, FE3S4, FE4S4, AND FE6S9), CLUSTERS FROM THE COMMON PRECURSOR TETRAKIS(ETHANETHIOLATE)FERRATE(2-) ION ((FE(SC2H5)4)2-): STRUCTURES AND PROPERTIES OF (FE3S4(SR)4)3- AND BIS(ETHANETHIOLATE)NONATHI Chemischer Informationsdienst. 14. DOI: 10.1002/Chin.198339297  0.01
1983 BERG JM, HOLM RH. ChemInform Abstract: STRUCTURE PROOFS OF LIGATED AND POLYMERIC DIOXOMOLYBDENUM(VI)-TRIDENTATE COMPLEXES: MOO2(C5H3N-2,6-(CH2S)2)(C4H8SO) AND (MOO2(C5H3N-2,6-(CH2O)2))N Chemischer Informationsdienst. 14. DOI: 10.1002/CHIN.198338316  0.16
1983 YAMAMURA T, CHRISTOU G, HOLM RH. ChemInform Abstract: THE HOMOGENEOUS HYDROGEN-EVOLVING SYSTEMS (MO2FE6S8(SPH)9)4-,5-/C6H5SH: REACTION CHARACTERISTICS, KINETICS, AND POSSIBLE MECHANISMS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198326303  0.01
1983 MASCHARAK PK, ARMSTRONG WH, MIZOBE Y, HOLM RH. ChemInform Abstract: SINGLE CUBANE-TYPE MFE3S4 CLUSTERS (M = MO, W): SYNTHESIS AND PROPERTIES OF OXIDIZED AND REDUCED FORMS AND THE STRUCTURE OF (ET4N)3(MOFE3S4(S-P-C6H4CL)4(3,6-(C3H5)2C6H2O2)) Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198321281  0.01
1983 HAGEN KS, STEPHAN DW, HOLM RH. ChemInform Abstract: METAL ION EXCHANGE REACTIONS IN CAGE MOLECULES: THE SYSTEMS (M4-NM′N(SC6H5)10)2- (M, M′ = FE(II), CO(II), ZN(II), CD(II)) WITH ADAMANTANE-LIKE STEREOCHEMISTRY AND THE STRUCTURE OF (FE4(SC6H5)10)2- Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198304317  0.01
1983 HAGEN KS, HOLM RH. ChemInform Abstract: SYSTEMATIC IRON(II)-THIOLATE CHEMISTRY: SYNTHETIC ENTRY TO TRINUCLEAR COMPLEXES Chemischer Informationsdienst. 14. DOI: 10.1002/CHIN.198301307  0.01
1982 Mascharak PK, Smith MC, Armstrong WH, Burgess BK, Holm RH. Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 79: 7056-60. PMID 6960364 DOI: 10.1073/Pnas.79.22.7056  1
1982 Hagen KS, Holm RH. Systematic iron(II)-thiolate chemistry: synthetic entry to trinuclear complexes Journal of the American Chemical Society. 104: 5496-5497. DOI: 10.1021/Ja00384A045  0.01
1982 Armstrong WH, Mascharak PK, Holm RH. Doubly bridged double cubanes containing MFe3S4 clusters (M = Mo, W). Synthesis, structure, and conversion to spin-quartet single clusters in solution Journal of the American Chemical Society. 104: 4373-4383. DOI: 10.1021/Ja00380A011  0.01
1982 Christou G, Mascharak PK, Armstrong WH, Papaefthymiou GC, Frankel RB, Holm RH. Electron-transfer series of MoFe3S4 double-cubane clusters: electronic properties of components and the structure of [(C2H5)4N]5[Mo2Fe6S8(SC6H5)9] Journal of the American Chemical Society. 104: 2820-2831. DOI: 10.1021/Ja00374A021  0.04
1982 Christou G, Hagen KS, Holm RH. Synthesis, structure, and properties of [Co8S6(SC6H5)8]4-, containing an octanuclear Co8S6 rhombic dodecahedron related to that of cobalt pentlandite Journal of the American Chemical Society. 104: 1744-1745. DOI: 10.1021/Ja00370A054  0.01
1982 Hagen KS, Stephan DW, Holm RH. Metal ion exchange reactions in cage molecules: the systems [M4-nM'n(SC6H5)10]2- (M, M' = Fe(II), Co(II), Zn(II), Cd(II)) with adamantane-like stereochemistry and the structure of [Fe4(SC6H5)10]2- Inorganic Chemistry. 21: 3928-3936. DOI: 10.1021/Ic00141A015  0.04
1982 Christou G, Sabat M, Ibers JA, Holm RH. A new structural type in iron-sulfide-thiolate chemistry: preparation, properties, and structure of the hexanuclear cluster [Fe6S9(S-tert-C4H9)2]4- Inorganic Chemistry. 21: 3518-3526. DOI: 10.1021/Ic00139A048  0.01
1982 Papaefthymiou GC, Laskowski EJ, Frota-Pessoa S, Frankel RB, Holm RH. Antiferromagnetic exchange interactions in [Fe4S4(SR)4]2-,3- clusters Inorganic Chemistry. 21: 1723-1728. DOI: 10.1021/Ic00135A005  0.01
1982 Armstrong WH, Mascharak PK, Holm RH. Demonstration of the existence of single cubane-type molybdenum iron sulfide (MoFe3S4) clusters with S = 3/2 ground states: preparation, structure, and properties Inorganic Chemistry. 21: 1699-1701. DOI: 10.1021/Ic00134A095  0.01
1982 Strauss SH, Holm RH. Carbon monoxide affinities of iron(II) octaethylporphyrin, octaethylchlorin, and octaethylisobacteriochlorin Inorganic Chemistry. 21: 863-868. DOI: 10.1021/Ic00133A005  1
1982 Palermo RE, Power PP, Holm RH. Ligand substitution properties of the MFe3S4 double-cubane cluster complexes [Mo2Fe6S8(SR)9]3- and [M2Fe7S8(SR)12]3- (M = molybdenum, tungsten) Inorganic Chemistry. 21: 173-181. DOI: 10.1021/Ic00131A033  0.01
1982 CHRISTOU G, SABAT M, IBERS JA, HOLM RH. ChemInform Abstract: A NEW STRUCTURAL TYPE IN IRON-SULFIDE-THIOLATE CHEMISTRY: PREPARATION, PROPERTIES, AND STRUCTURE OF THE HEXANUCLEAR CLUSTER (FE6S9(S-TERT-C4H9)2)4- Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198249281  0.01
1982 CHRISTOU G, MASCHARAK PK, ARMSTRONG WH, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: ELECTRON-TRANSFER SERIES OF MOFE3S4 DOUBLE-CUBANE CLUSTERS: ELECTRONIC PROPERTIES OF COMPONENTS AND THE STRUCTURE OF ((C2H5)4N)5(MO2FE6S8(SC6H5)9) Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198235269  0.01
1982 PAPAEFTHYMIOU GC, LASKOWSKI EJ, FROTA-PESSOA S, FRANKEL RB, HOLM RH. ChemInform Abstract: ANTIFERROMAGNETIC EXCHANGE INTERACTIONS IN (FE4S4(SR)4)2-,3- CLUSTERS Chemischer Informationsdienst. 13. DOI: 10.1002/CHIN.198233267  0.01
1982 ARMSTRONG WH, MASCHARAK PK, HOLM RH. ChemInform Abstract: DEMONSTRATION OF THE EXISTENCE OF SINGLE CUBANE-TYPE MOLYBDENUM IRON SULFIDE (MOFE3S4) CLUSTERS WITH S = 3/2 GROUND STATES: PREPARATION, STRUCTURE, AND PROPERTIES Chemischer Informationsdienst. 13. DOI: 10.1002/CHIN.198229252  0.01
1982 STRAUSS SH, HOLM RH. ChemInform Abstract: CARBON MONOXIDE AFFINITIES OF IRON(II) OCTAETHYLPORPHYRIN, OCTAETHYLCHLORIN, AND OCTAETHYLISOBACTERIOCHLORIN Chemischer Informationsdienst. 13. DOI: 10.1002/CHIN.198224094  0.01
1982 PALERMO RE, POWER PP, HOLM RH. ChemInform Abstract: LIGAND SUBSTITUTION PROPERTIES OF THE MFE3S4 DOUBLE-CUBANE CLUSTER COMPLEXES (MO2FE6S8(SR)9)3- AND (M2FE7S8(SR)12)3- (M = MOLYBDENUM, TUNGSTEN) Chemischer Informationsdienst. 13. DOI: 10.1002/Chin.198216281  0.01
1982 CHRISTOU G, HOLM RH, SABAT M, IBERS JA. ChemInform Abstract: A HEXANUCLEAR IRON-SULFIDE-THIOLATE CLUSTER: ASSEMBLY AND PROPERTIES OF (FE6S9(S-TERT-C4H9)2)4- CONTAINING THREE TYPES OF BRIDGING SULFUR ATOMS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198203262  0.01
1982 MASCHARAK PK, PAPAEFTHYMIOU GC, FRANKEL RB, HOLM RH. ChemInform Abstract: EVIDENCE FOR THE LOCALIZED IRON(III)/IRON(II) OXIDATION STATE CONFIGURATION AS AN INTRINSIC PROPERTY OF (FE2S2(SR)4)3- CLUSTERS Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198203260  0.01
1981 Paech C, Reynolds JG, Singer TP, Holm RH. Structural identification of iron-sulfur clusters of the respiratory chain-linked NADH dehydrogenase. The Journal of Biological Chemistry. 256: 3167-70. PMID 7204398  1
1981 Holm RH. Centenary Lecture. Metal clusters in biology: quest for a synthetic representation of the catalytic site of nitrogenase Chemical Society Reviews. 10: 455. DOI: 10.1039/Cs9811000455  0.01
1981 Christou G, Holm RH, Sabat M, Ibers JA. A hexanuclear iron-sulfide-thiolate cluster: assembly and properties of [Fe6S9(S-tert-C4H9)2]4- containing three types of bridging sulfur atoms Journal of the American Chemical Society. 103: 6269-6271. DOI: 10.1021/Ja00410A071  0.01
1981 Armstrong WH, Holm RH. Synthesis and structure of a new type of molybdenum-iron-sulfur double-cubane cluster and evidence for formation of magnetically uncoupled S = 3/2 MoFe3S4 subclusters Journal of the American Chemical Society. 103: 6246-6248. DOI: 10.1021/Ja00410A057  0.01
1981 Mascharak PK, Papaefthymiou GC, Frankel RB, Holm RH. Evidence for the localized iron(III)/iron(II) oxidation state configuration as an intrinsic property of [Fe2S2(SR)4]3- clusters Journal of the American Chemical Society. 103: 6110-6116. DOI: 10.1021/Ja00410A021  0.01
1981 Stolzenberg AM, Strauss SH, Holm RH. Iron(II, III)-chlorin and -isobacteriochlorin complexes. Models of the heme prosthetic groups in nitrite and sulfite reductases: Means of formation and spectroscopic and redox properties Journal of the American Chemical Society. 103: 4763-4778. DOI: 10.1021/Ja00406A018  1
1981 Hagen KS, Reynolds JG, Holm RH. Definition of reaction sequences resulting in self-assembly of [Fe4S4(SR)4]2- clusters from simple reactants Journal of the American Chemical Society. 103: 4054-4063. DOI: 10.1021/Ja00404A013  0.01
1981 Reynolds JG, Holm RH. Core chalcogenide atom substitution reactions of [Fe2X2(SR)4]2- and [Fe4X4(SR)4]2-,3- clusters (X = sulfur, selenium) Inorganic Chemistry. 20: 1873-1878. DOI: 10.1021/Ic50220A052  0.01
1981 Wolff TE, Berg JM, Holm RH. Synthesis, structure, and properties of the cluster complex [MoFe4S4(SC2H5)3(C6H4O2)3]3-, containing a single cubane-type molybdenum-iron-sulfur (MoFe3S4) core Inorganic Chemistry. 20: 174-180. DOI: 10.1021/Ic50215A036  0.12
1981 STOLZENBERG AM, STRAUSS SH, HOLM RH. ChemInform Abstract: IRON(II, III)-CHLORIN AND -ISOBACTERIOCHLORIN COMPLEXES. MODELS OF THE HEME PROSTHETIC GROUPS IN NITRITE AND SULFITE REDUCTASES: MEANS OF FORMATION AND SPECTROSCOPIC AND REDOX PROPERTIES Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198146272  0.04
1981 HAGEN KS, REYNOLDS JG, HOLM RH. ChemInform Abstract: DEFINITION OF REACTION SEQUENCES RESULTING IN SELF-ASSEMBLY OF (FE4S4(SR)4)2- CLUSTERS FROM SIMPLE REACTANTS Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198143277  0.01
1981 WOLFF TE, BERG JM, HOLM RH. ChemInform Abstract: SYNTHESIS, STRUCTURE, AND PROPERTIES OF THE CLUSTER COMPLEX (MOFE4S4(SC2H5)3(C6H4O2)3)3-, CONTAINING A SINGLE CUBANE-TYPE MOLYBDENUM-IRON-SULFUR (MOFE3S4) CORE Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198117319  0.08
1981 CHRISTOU G, HAGEMAN RV, HOLM RH. ChemInform Abstract: HYDROGEN EVOLUTION FROM HOMOGENEOUS REACTION SYSTEMS CONTAINING REDUCED MOLYBDENUM-IRON-SULFUR CLUSTERS Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198111298  0.01
1981 REYNOLDS JG, HOLM RH. ChemInform Abstract: IMPROVED SYNTHESES OF THE DIMERIC COMPLEXES (FE2X2(SC6H4Y)4)2- AND (FE2X2((SCH2)2C6H4)2)2- (X = SULFUR, SELENIUM), ANALOGS OF THE 2-FE SITES OF OXIDIZED FERREDOXIN PROTEINS Chemischer Informationsdienst. 12. DOI: 10.1002/CHIN.198105283  0.01
1980 Ibers JA, Holm RH. Modeling coordination sites in metallobiomolecules. Science (New York, N.Y.). 209: 223-35. PMID 7384796 DOI: 10.1126/Science.7384796  1
1980 Frankel RB, Wolff TE, Power PP, Holm RH. ELECTRONIC PROPERTIES OF MOLYBDENUM-IRON-SULFUR-CLUSTERS : APPROACHES TO THE MOLYBDENUM SITE IN NITROGENASE Le Journal De Physique Colloques. 41: C1-495-C1-496. DOI: 10.1051/Jphyscol:19801196  0.01
1980 Papaefthymiou GC, Frankel RB, Foner S, Laskowski EJ, Holm RH. MAGNETIC PROPERTIES OF [Fe4S4(SR)4]3- CLUSTERS Le Journal De Physique Colloques. 41: C1-493-C1-494. DOI: 10.1051/Jphyscol:19801195  0.01
1980 Christou G, Hageman RV, Holm RH. Hydrogen evolution from homogeneous reaction systems containing reduced molybdenum-iron-sulfur clusters Journal of the American Chemical Society. 102: 7600-7601. DOI: 10.1021/ja00545a052  0.01
1980 Wolff TE, Power PP, Frankel RB, Holm RH. Synthesis and electronic and redox properties of "double-cubane" cluster complexes containing molybdenum iron sulfide (MoFe3S4) and tungsten iron sulfide (WFe3S4) cores Journal of the American Chemical Society. 102: 4694-4703. DOI: 10.1021/Ja00534A023  0.01
1980 Reynolds JG, Coyle CL, Holm RH. Electron exchange kinetics of [Fe4S4(SR)4]2-/[Fe4S4(SR)4]3- and [Fe4Se4(SR)4]2-/[Fe4Se4(SR)4]3- systems. Estimates of the intrinsic self-exchange rate constant of 4-Fe sites in oxidized and reduced ferredoxins Journal of the American Chemical Society. 102: 4350-4355. DOI: 10.1021/Ja00533A010  0.01
1980 Stolzenberg AM, Spreer LO, Holm RH. Octaethylisobacteriochlorin, a model of the sirohydrochlorin ring system of siroheme enzymes: preparation and spectroscopic and electrochemical properties of the free base and its zinc(II) complex Journal of the American Chemical Society. 102: 364-370. DOI: 10.1021/Ja00521A059  0.01
1980 Reynolds JG, Holm RH. Improved syntheses of the dimeric complexes [Fe2X2(SC6H4Y)4]2- and [Fe2X2((SCH2)2C6H4)2]2- (X = sulfur, selenium), analogs of the 2-Fe sites of oxidized ferredoxin proteins Inorganic Chemistry. 19: 3257-3260. DOI: 10.1021/Ic50213A011  0.01
1980 Wolff TE, Berg JM, Power PP, Hodgson KO, Holm RH. Structural characterization of the iron-bridged "double-cubane" cluster complexes [Mo2Fe7S8(SC2H5)12]3- and [M2Fe7S8(SCH2C6H5)12]4- (M = molybdenum, tungsten) containing MFe3S4 cores Inorganic Chemistry. 19: 430-437. DOI: 10.1021/Ic50204A029  0.08
1980 Hagen KS, Berg JM, Holm RH. The synthesis and structure of deca(benzenethiolato)tetraferrate(II) dianion, an intermediate in the assembly of [Fe4S4(SC6H5)4]2- from simple reagents Inorganica Chimica Acta. 45. DOI: 10.1016/S0020-1693(00)80078-X  1
1980 HAGEN KS, BERG JM, HOLM RH. ChemInform Abstract: THE SYNTHESIS AND STRUCTURE OF DECA(BENZENETHIOLATO)TETRAFERRATE(II) DIANION, AN INTERMEDIATE IN THE ASSEMBLY OF (FE4S4(SC6H5)4)2- FROM SIMPLE REAGENTS Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198041295  0.12
1980 WOLFF TE, POWER PP, FRANKEL RB, HOLM RH. ChemInform Abstract: SYNTHESIS AND ELECTRONIC AND REDOX PROPERTIES OF “DOUBLE-CUBANE” CLUSTER COMPLEXES CONTAINING MOLYBDENUM IRON SULFIDE (MOFE3S4) AND TUNGSTEN IRON SULFIDE (WFE3S4) CORES Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198040291  0.01
1980 REYNOLDS JG, COYLE CL, HOLM RH. ChemInform Abstract: ELECTRON EXCHANGE KINETICS OF (FE4S4(SR)4)2-/(FE4S4(SR)4)3- AND (FE4SE4(SR)4)2-/(FE4SE4(SR)4)3- SYSTEMS. ESTIMATES OF THE INTRINSIC SELF-EXCHANGE RATE CONSTANT OF 4-FE SITES IN OXIDIZED AND REDUCED FERREDOXINS Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198038281  0.01
1980 STOLZENBERG AM, SPREER LO, HOLM RH. ChemInform Abstract: OCTAETHYLISOBACTERIOCHLORIN, A MODEL OF THE SIROHYDROCHLORIN RING SYSTEM OF SIROHEME ENZYMES: PREPARATION AND SPECTROSCOPIC AND ELECTROCHEMICAL PROPERTIES OF THE FREE BASE AND ITS ZINC(II) COMPLEX Chemischer Informationsdienst. 11. DOI: 10.1002/CHIN.198016283  0.01
1979 McMillan RS, Renaud J, Reynolds JG, Holm RH. Biologically related iron-sulfur clusters as reaction centers. Reduction of acetylene to ethylene in systems based on [Fe4S4(SR)4]3-. Journal of Inorganic Biochemistry. 11: 213-27. PMID 512659 DOI: 10.1016/S0162-0134(00)80019-7  1
1979 Kurtz DM, Holm RH, Ruzicka FJ, Beinert H, Coles CJ, Singer TP. The high potential iron-sulfur cluster of aconitase is a binuclear iron-sulfur cluster. The Journal of Biological Chemistry. 254: 4967-9. PMID 447628  1
1979 Kurtz DM, McMillan RS, Burgess BK, Mortenson LE, Holm RH. Identification of iron-sulfur centers in the iron-molybdenum proteins of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 4986-9. PMID 291915 DOI: 10.1073/Pnas.76.10.4986  1
1979 Coles CJ, Holm RH, Kurtz DM, Orme-Johnson WH, Rawlings J, Singer TP, Wong GB. Characterization of the iron-sulfur centers in succinate dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 3805-8. PMID 226982 DOI: 10.1073/Pnas.76.8.3805  1
1979 Sackett GP, Holm R, Crowley C, Henkins A. A FORTRAN program for lag sequential analysis of contingency and cyclicity in behavioral interaction data Behavior Research Methods & Instrumentation. 11: 366-378. DOI: 10.3758/BF03205679  1
1979 Stolzenberg AM, Spreer LO, Holm RH. Iron octaethylisobacteriochlorin, a model system for the siroheme prosthetic group of nitrite and sulphite reductases Journal of the Chemical Society, Chemical Communications. 1077-1078. DOI: 10.1039/C39790001077  1
1979 Laskowski EJ, Reynolds JG, Frankel RB, Foner S, Papaefthymiou GC, Holm RH. Demonstration of the generality of the [Fe4S4(SR)4]2- (compressed D2d)/[Fe4S4(SR)4]3- (elongated D2d) structural change in electron-transfer reactions of ferredoxin 4-Fe site analogs. A model for unconstrained structural changes in ferredoxin proteins Journal of the American Chemical Society. 101: 6562-6570. DOI: 10.1021/Ja00516A014  0.01
1979 Wolff TE, Berg JM, Power PP, Hodgson KO, Holm RH, Frankel RB. Self-assembly of molybdenum-iron-sulfur clusters as a synthetic approach to the molybdenum site in nitrogenase. Identification of the major products formed by the system FeCl3/MS42-/C2H5SH (M = Molybdenum, tungsten) Journal of the American Chemical Society. 101: 5454-5456. DOI: 10.1021/Ja00512A076  0.01
1979 Berg JM, Hodgson KO, Holm RH. Crystal structure of [(C2H5)4N]3[Fe4S4(SCH2Ph)4], a reduced ferredoxin site analog with a nontetragonal Fe4S4 core structure in the solid state Journal of the American Chemical Society. 101: 4586-4593. DOI: 10.1021/Ja00510A025  0.04
1979 Wolff TE, Berg JM, Hodgson KO, Frankel RB, Holm RH. Synthetic approaches to the molybdenum site in nitrogenase. Preparation and structural properties of the molybdenum-iron-sulfur "double-cubane" cluster complexes [Mo2Fe6S8(SC2H5)9]3- and [Mo2Fe6S9(SC2H5)8]3- Journal of the American Chemical Society. 101: 4140-4150. DOI: 10.1021/Ja00509A021  0.04
1979 Wong GB, Kurtz DM, Holm RH, Mortenson LE, Upchurch RG. A fluorine-19 NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase Journal of the American Chemical Society. 101: 3078-3090. DOI: 10.1021/Ja00505A041  1
1979 WOLFF TE, BERG JM, POWER PP, HODGSON KO, HOLM RH, FRANKEL RB. ChemInform Abstract: SELF-ASSEMBLY OF MOLYBDENUM-IRON-SULFUR CLUSTERS AS A SYNTHETIC APPROACH TO THE MOLYBDENUM SITE IN NITROGENASE. IDENTIFICATION OF THE MAJOR PRODUCTS FORMED BY THE SYSTEM FECL3/MS42-/C2H5SH (M = MOLYBDENUM, TUNGSTEN) Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197951081  0.01
1979 WOLFF TE, BERG JM, HODGSON KO, FRANKEL RB, HOLM RH. ChemInform Abstract: SYNTHETIC APPROACHES TO THE MOLYBDENUM SITE IN NITROGENASE. PREPARATION AND STRUCTURAL PROPERTIES OF THE MOLYBDENUM-IRON-SULFUR “DOUBLE-CUBANE” CLUSTER COMPLEXES (MO2FE6S8(SC2H5)9)3- AND (MO2FE6S9(SC2H5)8)3- Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197944059  0.08
1979 Wong GB, Kurtz DM, Holm RH, Mortenson LE, Upchurch RG. A 19F NMR method for identification of iron-sulfur cores extruded from active centers of proteins, with applications to milk xanthine oxidase and the iron-molybdenum proteins of nitrogenase Journal of the American Chemical Society. 101: 3078-3090.  1
1978 Orme-Johnson WH, Holm RH. Identification of iron--sulfur clusters in proteins. Methods in Enzymology. 53: 268-74. PMID 213682 DOI: 10.1016/S0076-6879(78)53032-2  1
1978 Kurtz DM, Wong GB, Holm RH. Structural identification of the extruded cores of the active centers of iron-sulfur proteins by fluorine-19 nuclear magnetic resonance spectroscopy. Application to milk xanthine oxidase [18] Journal of the American Chemical Society. 100: 6777-6779. DOI: 10.1021/Ja00489A051  1
1978 Johnson RW, Holm RH. Reaction chemistry of the iron-sulfur protein site analogs [Fe4S4(SR)4]2-. Sequential thiolate ligand substitution reactions with electrophiles Journal of the American Chemical Society. 100: 5338-5344. DOI: 10.1021/Ja00485A014  0.01
1978 Laskowski EJ, Frankel RB, Gillum WO, Papaefthymiou GC, Renaud J, Ibers JA, Holm RH. Synthetic analogs of the 4-Fe active sites of reduced ferredoxins. Electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3- and the structure of [(C2H5)3(CH3)N]3[Fe4S4(SC6H5)4] Journal of the American Chemical Society. 100: 5322-5337. DOI: 10.1021/Ja00485A013  0.01
1978 Reynolds JG, Laskowski EJ, Holm RH. Proton magnetic resonance properties of the tetranuclear clusters [Fe4S4(SR)4]3-, analogs of the 4-Fe sites of reduced ferredoxins Journal of the American Chemical Society. 100: 5315-5322. DOI: 10.1021/Ja00485A012  0.01
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