Richard Hadley Holm - Publications

Affiliations: 
1962-1965 Harvard University, Cambridge, MA, United States 
 1965-1967 University of Wisconsin, Madison, Madison, WI 
 1967-1975 Massachusetts Institute of Technology, Cambridge, MA, United States 
 1975-1980 Stanford University, Palo Alto, CA 
 1980- Chemistry Harvard University, Cambridge, MA, United States 
Area:
transition element chemistry
Website:
http://faculty.chemistry.harvard.edu/holm

240 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Xu G, Wang Z, Ling R, Zhou J, Chen XD, Holm RH. Ligand metathesis as rational strategy for the synthesis of cubane-type heteroleptic iron-sulfur clusters relevant to the FeMo cofactor. Proceedings of the National Academy of Sciences of the United States of America. PMID 29654147 DOI: 10.1073/pnas.1801025115  1
2014 Ha Y, Tenderholt AL, Holm RH, Hedman B, Hodgson KO, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional theory calculations on monooxo Mo(IV) and bisoxo Mo(VI) bis-dithiolenes: insights into the mechanism of oxo transfer in sulfite oxidase and its relation to the mechanism of DMSO reductase. Journal of the American Chemical Society. 136: 9094-105. PMID 24884723 DOI: 10.1021/ja503316p  1
2014 Holm RH, Solomon EI. Introduction: Bioinorganic enzymology II. Chemical Reviews. 114: 4039-40. PMID 24758378 DOI: 10.1021/cr5001332  1
2014 Holm RH, Solomon EI. Introduction: bioinorganic enzymology II. Chemical Reviews. 114: 3367-8. PMID 24712923 DOI: 10.1021/cr500118g  1
2014 Troeppner O, Huang D, Holm RH, Ivanovi?-Burmazovi? I. Thermodynamics and high-pressure kinetics of a fast carbon dioxide fixation reaction by a (2,6-pyridinedicarboxamidato-hydroxo)nickel(II) complex. Dalton Transactions (Cambridge, England : 2003). 43: 5274-9. PMID 24572679 DOI: 10.1039/c3dt53004c  1
2014 Lee SC, Lo W, Holm RH. Developments in the biomimetic chemistry of cubane-type and higher nuclearity iron-sulfur clusters. Chemical Reviews. 114: 3579-600. PMID 24410527 DOI: 10.1021/cr4004067  1
2013 Tan LL, Holm RH, Lee SC. Structural Analysis of Cubane-Type Iron Clusters. Polyhedron. 58: 206-217. PMID 24072952 DOI: 10.1016/j.poly.2013.02.031  1
2012 Zhang X, Huang D, Chen YS, Holm RH. Synthesis of binucleating macrocycles and their nickel(II) hydroxo- and cyano-bridged complexes with divalent ions: anatomical variation of ligand features. Inorganic Chemistry. 51: 11017-29. PMID 23030366 DOI: 10.1021/ic301506x  1
2012 Lo W, Zhang P, Ling CC, Huang S, Holm RH. Formation, spectroscopic characterization, and solution stability of an [Fe4S4]2+ cluster derived from β-cyclodextrin dithiolate. Inorganic Chemistry. 51: 9883-92. PMID 22934734 DOI: 10.1021/ic301324u  1
2012 Holm RH, Maroney MJ. 50 Years of metals in biology: the Gordon Research Conference. Metallomics : Integrated Biometal Science. 4: 401-2. PMID 22535189 DOI: 10.1039/c2mt90017c  0.92
2012 Zheng B, Chen XD, Zheng SL, Holm RH. Selenium as a structural surrogate of sulfur: template-assisted assembly of five types of tungsten-iron-sulfur/selenium clusters and the structural fate of chalcogenide reactants. Journal of the American Chemical Society. 134: 6479-90. PMID 22424175 DOI: 10.1021/ja3010539  1
2012 Tenderholt AL, Hodgson KO, Hedman B, Holm RH, Solomon EI. Substrate and metal control of barrier heights for oxo transfer to Mo and W bis-dithiolene sites. Inorganic Chemistry. 51: 3436-42. PMID 22372518 DOI: 10.1021/ic2020397  1
2011 Majumdar A, Holm RH. Specific incorporation of chalcogenide bridge atoms in molybdenum/tungsten-iron-sulfur single cubane clusters. Inorganic Chemistry. 50: 11242-51. PMID 21985054 DOI: 10.1021/ic2018117  1
2011 Lo W, Huang S, Zheng SL, Holm RH. Cubane-type Fe4S4 clusters with chiral thiolate ligation: formation by ligand substitution, detection of intermediates by 1H NMR, and solid state structures including spontaneous resolution upon crystallization. Inorganic Chemistry. 50: 11082-90. PMID 21942299 DOI: 10.1021/ic2016269  1
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Fast carbon dioxide fixation by 2,6-pyridinedicarboxamidato-nickel(II)-hydroxide complexes: influence of changes in reactive site environment on reaction rates. Inorganic Chemistry. 50: 10070-81. PMID 21905646 DOI: 10.1021/ic200942u  1
2011 Xi B, Holm RH. The [MoFe3S4]2+ oxidation state: synthesis, substitution reactions, and structures of phosphine-ligated cubane-type clusters with the S=2 ground state. Inorganic Chemistry. 50: 6280-8. PMID 21648449 DOI: 10.1021/ic200641k  1
2011 Lo W, Scott TA, Zhang P, Ling CC, Holm RH. Stabilities of cubane type [Fe₄S₄(SR)₄](2-) clusters in partially aqueous media. Journal of Inorganic Biochemistry. 105: 497-508. PMID 21329647 DOI: 10.1016/j.jinorgbio.2010.12.009  1
2011 Huang D, Makhlynets OV, Tan LL, Lee SC, Rybak-Akimova EV, Holm RH. Kinetics and mechanistic analysis of an extremely rapid carbon dioxide fixation reaction. Proceedings of the National Academy of Sciences of the United States of America. 108: 1222-7. PMID 21220298 DOI: 10.1073/pnas.1017430108  1
2011 Holm RH, Solomon EI, Majumdar A, Tenderholt A. Comparative molecular chemistry of molybdenum and tungsten and its relation to hydroxylase and oxotransferase enzymes Coordination Chemistry Reviews. 255: 993-1015. DOI: 10.1016/j.ccr.2010.10.017  1
2010 Deng L, Majumdar A, Lo W, Holm RH. Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states. Inorganic Chemistry. 49: 11118-26. PMID 21038882 DOI: 10.1021/ic101702b  1
2010 Tenderholt AL, Wang JJ, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge X-ray absorption spectroscopy and density functional calculations on Mo(IV) and Mo(VI)=O bis-dithiolenes: insights into the mechanism of oxo transfer in DMSO reductase and related functional analogues. Journal of the American Chemical Society. 132: 8359-71. PMID 20499905 DOI: 10.1021/ja910369c  1
2010 Huang D, Holm RH. Reactions of the terminal Ni(II)-OH group in substitution and electrophilic reactions with carbon dioxide and other substrates: structural definition of binding modes in an intramolecular Ni(II)...Fe(II) bridged site. Journal of the American Chemical Society. 132: 4693-701. PMID 20218565 DOI: 10.1021/ja1003125  1
2010 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. The modular nature of all-ferrous edge-bridged double cubanes. Inorganic Chemistry. 49: 1647-50. PMID 20073485 DOI: 10.1021/ic902050k  1
2010 Groysman S, Majumdar A, Zheng SL, Holm RH. Reactions of monodithiolene tungsten(VI) sulfido complexes with copper(I) in relation to the structure of the active site of carbon monoxide dehydrogenase. Inorganic Chemistry. 49: 1082-9. PMID 20030373 DOI: 10.1021/ic902066m  1
2009 Deng L, Bill E, Wieghardt K, Holm RH. Cubane-type Co4S4 clusters: synthesis, redox series, and magnetic ground states. Journal of the American Chemical Society. 131: 11213-21. PMID 19722678 DOI: 10.1021/ja903847a  1
2009 Huang D, Deng L, Sun J, Holm RH. Cleavage of Ni-(mu(2)-S)-Ni bridges in dinuclear nickel(II) dithiolate pincer complexes and related reactions. Inorganic Chemistry. 48: 6159-66. PMID 19459662 DOI: 10.1021/ic900494u  1
2009 Chakrabarti M, Deng L, Holm RH, Münck E, Bominaar EL. Mössbauer, electron paramagnetic resonance, and theoretical studies of a carbene-based all-ferrous Fe4S4 cluster: electronic origin and structural identification of the unique spectroscopic site. Inorganic Chemistry. 48: 2735-47. PMID 19326927 DOI: 10.1021/ic802192w  1
2009 Groysman S, Holm RH. Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites. Biochemistry. 48: 2310-20. PMID 19206188 DOI: 10.1021/bi900044e  1
2009 Groysman S, Holm RH. A series of mononuclear quasi-two-coordinate copper(I) complexes employing a sterically demanding thiolate ligand. Inorganic Chemistry. 48: 621-7. PMID 19138143 DOI: 10.1021/ic801836k  1
2008 Groysman S, Wang JJ, Tagore R, Lee SC, Holm RH. A biomimetic approach to oxidized sites in the xanthine oxidoreductase family: synthesis and stereochemistry of tungsten(VI) analogue complexes. Journal of the American Chemical Society. 130: 12794-807. PMID 18763763 DOI: 10.1021/ja804000k  1
2008 Deng L, Holm RH. Stabilization of fully reduced iron-sulfur clusters by carbene ligation: the [FenSn]0 oxidation levels (n = 4, 8). Journal of the American Chemical Society. 130: 9878-86. PMID 18593124 DOI: 10.1021/ja802111w  1
2008 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Electronic control of the "Bailar twist" in formally d0-d2 molybdenum tris(dithiolene) complexes: a sulfur K-edge X-ray absorption spectroscopy and density functional theory study. Inorganic Chemistry. 47: 6382-92. PMID 18517189 DOI: 10.1021/ic800494h  1
2008 Scott TA, Holm RH. VFe3S4 single and double cubane clusters: synthesis, structures, and dependence of redox potentials and electron distribution on ligation and heterometal. Inorganic Chemistry. 47: 3426-32. PMID 18366157 DOI: 10.1021/ic702372f  1
2008 McNaughton RL, Lim BS, Knottenbelt SZ, Holm RH, Kirk ML. Spectroscopic and electronic structure studies of symmetrized models for reduced members of the dimethylsulfoxide reductase enzyme family. Journal of the American Chemical Society. 130: 4628-36. PMID 18341333 DOI: 10.1021/ja074691b  1
2008 Pryadun R, Holm RH. A new class of binuclear and trinuclear iron-sulfur clusters derived from bis[bis(trimethylsilyl)amido]iron(II). Inorganic Chemistry. 47: 3366-70. PMID 18327895 DOI: 10.1021/ic7023742  1
2008 Lee SC, Holm RH. Toward an expanded oxygen atom transfer reactivity scale: Computational investigation of the energetics of oxo transfer reaction couples Inorganica Chimica Acta. 361: 1166-1176. DOI: 10.1016/j.ica.2007.10.047  1
2007 Wang JJ, Holm RH. Silylation, sulfidation, and benzene-1,2-dithiolate complexation reactions of oxo- and oxosulfidomolybdates(VI) and -tungstates(VI). Inorganic Chemistry. 46: 11156-64. PMID 18044955 DOI: 10.1021/ic701294y  1
2007 Hlavinka ML, Miyaji T, Staples RJ, Holm RH. Hydroxide-promoted core conversions of molybdenum-iron-sulfur edge-bridged double cubanes: oxygen-ligated topological PN clusters. Inorganic Chemistry. 46: 9192-200. PMID 17892284 DOI: 10.1021/ic701070w  1
2007 Tenderholt AL, Szilagyi RK, Holm RH, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge XAS of WVO vs. MoVO bis(dithiolene) complexes: contributions of relativistic effects to electronic structure and reactivity of tungsten enzymes. Journal of Inorganic Biochemistry. 101: 1594-600. PMID 17720249 DOI: 10.1016/j.jinorgbio.2007.07.011  1
2007 Wang JJ, Groysman S, Lee SC, Holm RH. Synthesis of structural analogues of the oxidized sites in the xanthine oxidoreductase enzyme family. Journal of the American Chemical Society. 129: 7512-3. PMID 17530853 DOI: 10.1021/ja0724442  1
2007 Groysman S, Holm RH. Synthesis and structures of bis(dithiolene)tungsten(IV,VI) thiolate and selenolate complexes: approaches to the active sites of molybdenum and tungsten formate dehydrogenases. Inorganic Chemistry. 46: 4090-102. PMID 17432849 DOI: 10.1021/ic062441a  1
2007 Sun J, Tessier C, Holm RH. Sulfur ligand substitution at the nickel(II) sites of cubane-type and cubanoid NiFe3S4 clusters relevant to the C-clusters of carbon monoxide dehydrogenase. Inorganic Chemistry. 46: 2691-9. PMID 17346040 DOI: 10.1021/ic062362z  1
2007 Pesavento RP, Berlinguette CP, Holm RH. Stabilization of reduced molybdenum-iron-sulfur single- and double-cubane clusters by cyanide ligation. Inorganic Chemistry. 46: 510-6. PMID 17279830 DOI: 10.1021/ic061704y  1
2006 Berlinguette CP, Holm RH. Edge-bridged Mo2Fe6S8 to pN-type Mo2Fe6S9 cluster conversion: structural fate of the attacking sulfide/selenide nucleophile. Journal of the American Chemical Society. 128: 11993-2000. PMID 16953641 DOI: 10.1021/ja063604x  1
2006 Bennett MV, Holm RH. Self-assembly of a tetradecanuclear iron nitride cluster. Angewandte Chemie (International Ed. in English). 45: 5613-6. PMID 16858715 DOI: 10.1002/anie.200601570  1
2006 Wang JJ, Tessier C, Holm RH. Analogue reaction systems of selenate reductase. Inorganic Chemistry. 45: 2979-88. PMID 16562954 DOI: 10.1021/ic0521630  1
2006 Berlinguette CP, Miyaji T, Zhang Y, Holm RH. Precursors to clusters with the topology of the P(N) cluster of nitrogenase: edge-bridged double cubane clusters [(Tp)2Mo2Fe6S8L4]z: synthesis, structures, and electron transfer series. Inorganic Chemistry. 45: 1997-2007. PMID 16499360 DOI: 10.1021/ic051770k  1
2006 Friedle S, Partyka DV, Bennett MV, Holm RH. Synthesis of metal dithiolene complexes by Si-S bond cleavage of a bis(silanylsulfanyl)alkene Inorganica Chimica Acta. 359: 1427-1434. DOI: 10.1016/j.ica.2005.09.067  1
2005 Bennett MV, Stoian S, Bominaar EL, Münck E, Holm RH. Initial members of the family of molecular mid-valent high-nuclearity iron nitrides: [Fe4N2X10]4- and [Fe10N8X12]5- (X = Cl-, Br-). Journal of the American Chemical Society. 127: 12378-86. PMID 16131219 DOI: 10.1021/ja052150l  1
2005 Panda R, Berlinguette CP, Zhang Y, Holm RH. Synthesis of MFe3S4 clusters containing a planar M(II) site (M = Ni, Pd, Pt), a structural element in the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 127: 11092-101. PMID 16076217 DOI: 10.1021/ja052381s  1
2005 Scott TA, Berlinguette CP, Holm RH, Zhou HC. Initial synthesis and structure of an all-ferrous analogue of the fully reduced [Fe4S4]0 cluster of the nitrogenase iron protein. Proceedings of the National Academy of Sciences of the United States of America. 102: 9741-4. PMID 15985547 DOI: 10.1073/pnas.0504258102  1
2005 Jiang J, Holm RH. Reaction systems related to dissimilatory nitrate reductase: nitrate reduction mediated by bis(dithiolene)tungsten complexes. Inorganic Chemistry. 44: 1068-72. PMID 15859288 DOI: 10.1021/ic040109y  1
2005 Rao PV, Bhaduri S, Jiang J, Hong D, Holm RH. On [Fe4S4]2+ -(mu2-SR)-M II bridge formation in the synthesis of an A-cluster analogue of carbon monoxide dehydrogenase/acetylcoenzyme A synthase. Journal of the American Chemical Society. 127: 1933-45. PMID 15701028 DOI: 10.1021/ja040222n  1
2005 Hong D, Zhang Y, Holm RH. Heterometal cubane-type WFe3S4 and related clusters trigonally symmetrized with hydrotris(3,5-dimethylpyrazolyl)borate Inorganica Chimica Acta. 358: 2303-2311. DOI: 10.1016/j.ica.2004.11.051  1
2004 Dey A, Glaser T, Moura JJ, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy and DFT calculations on [Fe3S4]0,+ clusters: delocalization, redox, and effect of the protein environment. Journal of the American Chemical Society. 126: 16868-78. PMID 15612726 DOI: 10.1021/ja0466208  1
2004 Partyka DV, Holm RH. Oxygen/sulfur substitution reactions of tetraoxometalates effected by electrophilic carbon and silicon reagents. Inorganic Chemistry. 43: 8609-16. PMID 15606212 DOI: 10.1021/ic040097g  1
2004 Wang JJ, Kryatova OP, Rybak-Akimova EV, Holm RH. Comparative kinetics and mechanism of oxygen and sulfur atom transfer reactions mediated by bis(dithiolene) complexes of molybdenum and tungsten. Inorganic Chemistry. 43: 8092-101. PMID 15578849 DOI: 10.1021/ic040087f  1
2004 Rao PV, Bhaduri S, Jiang J, Holm RH. Sulfur bridging interactions of cis-planar NiII-S2N2 coordination units with nickel(II), copper(I,II), zinc(II), and mercury(II): a library of bridging modes, including NiII(micro2-SR)2MI,II rhombs. Inorganic Chemistry. 43: 5833-49. PMID 15360232 DOI: 10.1021/ic040055s  1
2004 Dey A, Glaser T, Couture MM, Eltis LD, Holm RH, Hedman B, Hodgson KO, Solomon EI. Ligand K-edge X-ray absorption spectroscopy of [Fe4S4]1+,2+,3+ clusters: changes in bonding and electronic relaxation upon redox. Journal of the American Chemical Society. 126: 8320-8. PMID 15225075 DOI: 10.1021/ja0484956  1
2004 Panda R, Zhang Y, McLauchlan CC, Venkateswara Rao P, Tiago de Oliveira FA, Münck E, Holm RH. Initial structure modification of tetrahedral to planar nickel(II) in a nickel-iron-sulfur cluster related to the C-cluster of carbon monoxide dehydrogenase. Journal of the American Chemical Society. 126: 6448-59. PMID 15149242 DOI: 10.1021/ja030627s  1
2004 Jiang J, Holm RH. An expanded set of functional groups in bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes, Including WIV-SR and WVI-O(SR). Inorganic Chemistry. 43: 1302-10. PMID 14966965 DOI: 10.1021/ic030301k  1
2004 Enemark JH, Cooney JJ, Wang JJ, Holm RH. Synthetic analogues and reaction systems relevant to the molybdenum and tungsten oxotransferases. Chemical Reviews. 104: 1175-200. PMID 14871153 DOI: 10.1021/cr020609d  1
2004 Lee SC, Holm RH. The clusters of nitrogenase: synthetic methodology in the construction of weak-field clusters. Chemical Reviews. 104: 1135-58. PMID 14871151 DOI: 10.1021/cr0206216  1
2004 Venkateswara Rao P, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. Chemical Reviews. 104: 527-59. PMID 14871134 DOI: 10.1021/cr020615+  1
2004 Holm RH, Solomon EI. Preface: biomimetic inorganic chemistry. Chemical Reviews. 104: 347-8. PMID 14871127 DOI: 10.1021/cr0206364  1
2004 Zhang Y, Holm RH. Structural conversions of molybdenum-iron-sulfur edge-bridged double cubanes and P(n)-type clusters topologically related to the nitrogenase P-cluster. Inorganic Chemistry. 43: 674-82. PMID 14731029 DOI: 10.1021/ic030259t  1
2004 Holm RH. Electron Transfer: Iron-Sulfur Clusters Comprehensive Coordination Chemistry Ii. 8: 61-90. DOI: 10.1016/B0-08-043748-6/08133-0  1
2003 Szilagyi RK, Lim BS, Glaser T, Holm RH, Hedman B, Hodgson KO, Solomon EI. Description of the ground state wave functions of Ni dithiolenes using sulfur K-edge X-ray absorption spectroscopy. Journal of the American Chemical Society. 125: 9158-69. PMID 15369373 DOI: 10.1021/ja029806k  1
2003 Partyka DV, Staples RJ, Holm RH. Nucleophilic reactivity and oxo/sulfido substitution reactions of MVIO3 Groups (M = Mo, W). Inorganic Chemistry. 42: 7877-86. PMID 14632504 DOI: 10.1021/ic030185l  1
2003 Daley CJ, Holm RH. Reactions of site-differentiated [Fe4S4]2+, 1+ clusters with sulfonium cations: reactivity analogues of biotin synthase and other members of the S-adenosylmethionine enzyme family. Journal of Inorganic Biochemistry. 97: 287-98. PMID 14511891 DOI: 10.1016/S0162-0134(03)00280-0  1
2003 Jalilehvand F, Lim BS, Holm RH, Hedman B, Hodgson KO. X-ray absorption spectroscopy of a structural analogue of the oxidized active sites in the sulfite oxidase enzyme family and related molybdenum(V) complexes. Inorganic Chemistry. 42: 5531-6. PMID 12950200 DOI: 10.1021/ic030039f  1
2003 Zuo JL, Zhou HC, Holm RH. Vanadium-iron-sulfur clusters containing the cubane-type [VFe3S4] core unit: synthesis of a cluster with the topology of the PN cluster of nitrogenase. Inorganic Chemistry. 42: 4624-31. PMID 12870953 DOI: 10.1021/ic0301369  1
2003 Gray TG, Rudzinski CM, Meyer EE, Holm RH, Nocera DG. Spectroscopic and photophysical properties of hexanuclear rhenium(III) chalcogenide clusters. Journal of the American Chemical Society. 125: 4755-70. PMID 12696894 DOI: 10.1021/ja0286371  1
2003 Zhang Y, Holm RH. Synthesis of a molecular Mo2Fe6S9 cluster with the topology of the PN cluster of nitrogenase by rearrangement of an edge-bridged Mo2Fe6S8 double cubane. Journal of the American Chemical Society. 125: 3910-20. PMID 12656626 DOI: 10.1021/ja0214633  1
2003 Lee SC, Holm RH. Speculative synthetic chemistry and the nitrogenase problem. Proceedings of the National Academy of Sciences of the United States of America. 100: 3595-600. PMID 12642670 DOI: 10.1073/pnas.0630028100  1
2003 Zhou HC, Holm RH. Synthesis and reactions of cubane-type iron-sulfur-phosphine clusters, including soluble clusters of nuclearities 8 and 16. Inorganic Chemistry. 42: 11-21. PMID 12513073 DOI: 10.1021/ic020464t  1
2002 Sanakis Y, Yoo SJ, Osterloh F, Holm RH, Münck E. Determination of antiferromagnetic exchange coupling in the tetrahedral thiolate-bridged diferrous complex [Fe2(SEt)6]2-. Inorganic Chemistry. 41: 7081-5. PMID 12495348 DOI: 10.1021/ic0204629  1
2002 Zhang Y, Zuo JL, Zhou HC, Holm RH. Rearrangement of symmetrical dicubane clusters into topological analogues of the P cluster of nitrogenase: nature's choice? Journal of the American Chemical Society. 124: 14292-3. PMID 12452688  1
2002 Gray TG, Holm RH. Site-differentiated hexanuclear rhenium(III) cyanide clusters [Re(6)Se(8)(PEt(3))(n)()(CN)(6)(-)(n)()](n)()(-)(4) (n = 4, 5) and kinetics of solvate ligand exchange on the cubic [Re(6)Se(8)](2+) Core. Inorganic Chemistry. 41: 4211-6. PMID 12160409 DOI: 10.1021/ic020214c  1
2002 Zhou HC, Su W, Achim C, Rao PV, Holm RH. High-nuclearity sulfide-rich molybdenum[bond]iron[bond]sulfur clusters: reevaluation and extension. Inorganic Chemistry. 41: 3191-201. PMID 12054998  1
2002 Sung KM, Holm RH. Functional analogue reaction systems of the DMSO reductase isoenzyme family: probable mechanism of S-oxide reduction in oxo transfer reactions mediated by bis(dithiolene)-tungsten(IV,VI) complexes. Journal of the American Chemical Society. 124: 4312-20. PMID 11960460 DOI: 10.1021/ja012735p  1
2002 Laplaza CE, Holm RH. Stability and nickel binding properties of peptides designed as scaffolds for the stabilization of Ni(II)-Fe(4)S(4) bridged assemblies. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 7: 451-60. PMID 11941503 DOI: 10.1007/s00775-001-0320-4  1
2002 Musgrave KB, Laplaza CE, Holm RH, Hedman B, Hodgson KO. Structural characterization of metallopeptides designed as scaffolds for the stabilization of nickel(II)-Fe(4)S(4) bridged assemblies by X-ray absorption spectroscopy. Journal of the American Chemical Society. 124: 3083-92. PMID 11902899 DOI: 10.1021/ja011861q  1
2002 Hauser C, Bill E, Holm RH. Single- and double-cubane clusters in the multiple oxidation states [VFe(3)S(4)](3+,2+,1+). Inorganic Chemistry. 41: 1615-24. PMID 11896732 DOI: 10.1021/ic011011b  1
2002 Fomitchev DV, McLauchlan CC, Holm RH. Heterometal cubane-type MFe(3)S(4) clusters (M = Mo, V) trigonally symmetrized with hydrotris(pyrazolyl)borate(1-) and tris(pyrazolyl)methanesulfonate(1-) capping ligands. Inorganic Chemistry. 41: 958-66. PMID 11849099 DOI: 10.1021/ic011106d  1
2001 Laplaza CE, Holm RH. Helix-loop-helix peptides as scaffolds for the construction of bridged metal assemblies in proteins: the spectroscopic A-cluster structure in carbon monoxide dehydrogenase. Journal of the American Chemical Society. 123: 10255-64. PMID 11603975 DOI: 10.1021/ja010851m  1
2001 Lim BS, Willer MW, Miao M, Holm RH. Monodithiolene molybdenum(V, VI) complexes: a structural analogue of the oxidized active site of the sulfite oxidase enzyme family. Journal of the American Chemical Society. 123: 8343-9. PMID 11516283 DOI: 10.1021/ja010786g  1
2001 Sung KM, Holm RH. Substitution and oxidation reactions of bis(dithiolene)tungsten complexes of potential relevance to enzyme sites. Inorganic Chemistry. 40: 4518-25. PMID 11511194 DOI: 10.1021/ic010421x  1
2001 Achim C, Bominaar EL, Staples RJ, Münck E, Holm RH. Influence of extrinsic factors on electron transfer in a mixed-valence Fe(2+)/Fe(3+) complex: experimental results and theoretical considerations. Inorganic Chemistry. 40: 4389-403. PMID 11487347 DOI: 10.1021/ic010498l  1
2001 Lim BS, Fomitchev DV, Holm RH. Nickel dithiolenes revisited: structures and electron distribution from density functional theory for the three-member electron-transfer series [Ni(S2C2Me2)2]0,1-,2-. Inorganic Chemistry. 40: 4257-62. PMID 11487330 DOI: 10.1021/ic010138y  1
2001 Sung KM, Holm RH. Oxo transfer reactions mediated by bis(dithiolene)tungsten analogues of the active sites of molybdoenzymes in the DMSO reductase family: comparative reactivity of tungsten and molybdenum. Journal of the American Chemical Society. 123: 1931-43. PMID 11456814 DOI: 10.1021/ja0036559  1
2001 Lim BS, Holm RH. Bis(dithiolene)molybdenum analogues relevant to the DMSO reductase enzyme family: synthesis, structures, and oxygen atom transfer reactions and kinetics. Journal of the American Chemical Society. 123: 1920-30. PMID 11456813 DOI: 10.1021/ja003546u  1
2001 Daley CJ, Holm RH. Reactivity of [Fe4S4(SR)4]2-,3- clusters with sulfonium cations: analogue reaction systems for the initial step in biotin synthase catalysis. Inorganic Chemistry. 40: 2785-93. PMID 11375696 DOI: 10.1021/ic010039k  1
2001 Fomitchev DV, Lim BS, Holm RH. Electron distribution in the nonclassical bis(dithiolene) electron transfer series [M(CO)2(S2C2Me2)2]0/1-/2- (M = Mo, W): assessment by structural, spectroscopic, and density functional theory results. Inorganic Chemistry. 40: 645-54. PMID 11225106 DOI: 10.1021/ic001046w  1
2001 Osterloh F, Achim C, Holm RH. Molybdenum-iron-sulfur clusters of nuclearities eight and sixteen, including a topological analogue of the P-cluster of nitrogenase. Inorganic Chemistry. 40: 224-32. PMID 11170527 DOI: 10.1021/ic000617h  1
2001 Thapper A, Balmes O, Lorber C, Svensson PH, Holm RH, Nordlander E. Synthesis and structural characterization of two tungsten(VI) dioxo complexes with N,O- and N,S-coordinating ligands Inorganica Chimica Acta. 321: 162-166. DOI: 10.1016/S0020-1693(01)00509-6  1
2001 Selby HD, Zheng Z, Gray TG, Holm RH. Bridged multiclusters derived from the face-capped octahedral [Re6/III(μ3-Se)8]2+ cluster core Inorganica Chimica Acta. 312: 205-209. DOI: 10.1016/S0020-1693(00)00324-8  1
2000 Nivorozhkin AL, Segal BM, Musgrave KB, Kates SA, Hedman B, Hodgson KO, Holm RH. Metallocyclopeptide complexes with MII(S.Cys)4 chromophores. Inorganic Chemistry. 39: 2306-13. PMID 12526490 DOI: 10.1021/ic990421l  1
2000 Sung KM, Holm RH. Synthesis and structures of bis(dithiolene)-tungsten(IV) complexes related to the active sites of tungstoenzymes. Inorganic Chemistry. 39: 1275-81. PMID 12526419 DOI: 10.1021/ic991153u  1
2000 Osterloh F, Segal BM, Achim C, Holm RH. Reduced mono-, di-, and tetracubane-type clusters containing the [MoFe3S4]2+ core stabilized by tertiary phosphine ligation. Inorganic Chemistry. 39: 980-9. PMID 12526378 DOI: 10.1021/ic991016x  1
2000 Lim BS, Donahue JP, Holm RH. Synthesis and structures of bis(dithiolene)molybdenum complexes related to the active sites of the DMSO reductase enzyme family. Inorganic Chemistry. 39: 263-73. PMID 11272534 DOI: 10.1021/ic9908672  1
2000 Miao M, Willer MW, Holm RH. Oxo/sulfidotungstate(VI) as precursors to W(VI)O2, W(VI)OS, and W(VI)S2 complexes and W(IV)-dithiolene chelate rings. Inorganic Chemistry. 39: 2843-9. PMID 11232822 DOI: 10.1021/ic000047l  1
2000 Musgrave KB, Lim BS, Sung KM, Holm RH, Hedman B, Hodgson KO. X-ray spectroscopy of enzyme active site analogues and related molecules: bis(dithiolene)molybdenum(IV) and -tungsten(IV,VI) complexes with variant terminal ligands. Inorganic Chemistry. 39: 5238-47. PMID 11154582 DOI: 10.1021/ic000601r  1
2000 Lim BS, Sung KM, Holm RH. Structural and functional bis(dithiolene)-molybdenum/tungsten active site analogues of the dimethylsulfoxide reductase enzyme family [13] Journal of the American Chemical Society. 122: 7410-7411. DOI: 10.1021/ja001197y  1
2000 Zhou C, Raebiger JW, Segal BM, Holm RH. The influence of net charge on the redox potentials of Fe4S4 cubane-type clusters in aprotic solvents Inorganica Chimica Acta. 300: 892-902. DOI: 10.1016/S0020-1693(99)00593-9  1
1999 Gray TG, Rudzinski CM, Nocera DG, Holm RH. Highly Emissive Hexanuclear Rhenium(III) Clusters Containing the Cubic Cores [Re(6)S(8)](2+) and [Re(6)Se(8)](2+). Inorganic Chemistry. 38: 5932-5933. PMID 11671297  0.96
1999 Zheng Z, Gray TG, Holm RH. Synthesis and Structures of Solvated Monoclusters and Bridged Di- and Triclusters Based on the Cubic Building Block [Re(6)(&mgr;(3)-Se)(8)](2+). Inorganic Chemistry. 38: 4888-4895. PMID 11671221  0.96
1999 Musgrave KB, Donahue JP, Lorber C, Holm RH, Hedman B, Hodgson KO. An x-ray spectroscopic investigation of bis(dithiolene)molybdenum(IV,V,VI) and -tungsten(IV,V,VI) complexes: Symmetrized structural representations of the active sites of molybdoenzymes in the DMSO reductase family and of tungstoenzymes in the AOR and F(M)DH families Journal of the American Chemical Society. 121: 10297-10307. DOI: 10.1021/ja990753p  1
1999 Zheng Z, Gray TG, Holm RH. Synthesis and structures of solvated monoclusters and bridged Di- and triclusters based on the cubic building block [Re6(μ3-Se)8]2+ Inorganic Chemistry. 38: 4888-4895.  1
1999 Goddard CA, Holm RH. Synthesis and reactivity aspects of the bis(dithiolene) chalcogenide series [WIVQ(S2C2R2)2] 2- (Q = O, S, Se) Inorganic Chemistry. 38: 5389-5398.  1
1999 Thapper A, Donahue JP, Musgrave KB, Willer MW, Nordlander E, Hedman B, Hodgson KO, Holm RH. The unperturbed oxo-sulfido functional group cis-MoVIOS related to that in the xanthine oxidase family of molybdoenzymes: synthesis, structural characterization, and reactivity aspects Inorganic Chemistry. 38: 4104-4114.  1
1999 Osterloh F, Sanakis Y, Staples RJ, Münck E, Holm RH. A molybdenum-iron-sulfur cluster containing structural elements relevant to the P-cluster of nitrogenase Angewandte Chemie - International Edition. 38: 2066-2070.  1
1998 Lim BS, Holm RH. Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in nu(CN) Values, and Relation to the Heme-a(3)/Cu(B) Site in Cyanide-Inhibited Heme-Copper Oxidases. Inorganic Chemistry. 37: 4898-4908. PMID 11670655  0.96
1998 Huang J, Holm RH. Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe(3)S(4) Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges. Inorganic Chemistry. 37: 2247-2254. PMID 11670381  0.64
1998 Donahue JP, Holm RH. 3,4-Bis(1-adamantyl)-1,2-dithiete: the first structurally characterized dithiete unsupported by a ring or benzenoid frame. Acta Crystallographica. Section C, Crystal Structure Communications. 54: 1175-8. PMID 9760719  1
1998 Donahue JP, Goldsmith CR, Nadiminti U, Holm RH. Synthesis, structures, and reactivity of bis(dithiolene)molybdenum(IV,VI) complexes related to the active sites of molybdoenzymes Journal of the American Chemical Society. 120: 12869-12881. DOI: 10.1021/ja982914f  1
1998 Lorber C, Donahue JP, Goddard CA, Nordlander E, Holm RH. Synthesis, structures, and oxo transfer reactivity of bis(dithiolene)tungsten(IV,VI) complexes related to the active sites of tungstoenzymes Journal of the American Chemical Society. 120: 8102-8112. DOI: 10.1021/ja981015o  1
1998 Donahue JP, Lorber C, Nordlander E, Holm RH. Molybdenum and tungsten structural analogues of the active sites of the MoIV + [O] → MoVIO oxygen atom transfer couple of DMSO reductases Journal of the American Chemical Society. 120: 3259-3260. DOI: 10.1021/ja973917f  1
1998 Goh C, Nivorozhkin A, Yoo SJ, Bominaar EL, Münck E, Holm RH. The Mixed-Valence Double-Cubanoid Cluster [Fe8S12(ButNC)12]: Synthesis, Structure, and Exchange Coupling of a New Structural Array of Four Fe(III) Sites Inorganic Chemistry. 37: 2926-2932.  1
1998 Tucci GC, Donahue JP, Holm RH. Comparative Kinetics of Oxo Transfer to Substrate Mediated by Bis(dithiolene)dioxomolybdenum and -tungsten Complexes Inorganic Chemistry. 37: 1602-1608.  1
1998 Willer MW, Long JR, McLauchlan CC, Holm RH. Ligand Substitution Reactions of [Re6S8Br6]4-: A Basis Set of Re6S8 Clusters for Building Multicluster Assemblies Inorganic Chemistry. 37: 328-333.  1
1998 Lim BS, Holm RH. Molecular Heme-Cyanide-Copper Bridged Assemblies: Linkage Isomerism, Trends in vCN Values, and Relation to the Heme-a3/CuB Site in Cyanide-Inhibited Heme-Copper Oxidases Inorganic Chemistry. 37: 4898-4908.  1
1998 Segal BM, Hoveyda HR, Holm RH. Terminal Ligand Assignments Based on Trends in Metal - Ligand Bond Lengths of Cubane-Type [Fe4S4]2+,+ Clusters Inorganic Chemistry. 37: 3440-3443.  1
1998 Huang J, Holm RH. Synthesis, Identification, and Reactivity Properties of Symmetrical MoFe3S4 Double Cubanes with Fe-S-Fe and Fe-O-Fe Bridges Inorganic Chemistry. 37: 2247-2254.  1
1998 Goh C, Holm RH. Synthesis and structures of the cuboidal iron-sulfur-nitrosyl-phosphine clusters [Fe4S3(NO)4(PR3)3] 0,1+ (R = Et, Pri, C6H11) Inorganica Chimica Acta. 270: 46-54.  1
1998 Holm RH. [1:3] Site-differentiated and sulfide-bridged cubane clusters in chemistry and biology Pure and Applied Chemistry. 70: 931-938.  1
1997 Hoveyda HR, Holm RH. Characterization of the Self-Condensation Equilibrium of [Fe(4)S(4)(SH)(4)](2-): Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster. Inorganic Chemistry. 36: 4571-4578. PMID 11670123  0.48
1997 Raebiger JW, Crawford CA, Zhou J, Holm RH. Reactivity of Cubane-Type [(OC)(3)MFe(3)S(4)(SR)(3)](3-) Clusters (M = Mo, W): Interconversion with Cuboidal [Fe(3)S(4)](0) Clusters and Electron Transfer. Inorganic Chemistry. 36: 994-1003. PMID 11669661  1
1997 Kauffmann KE, Goddard CA, Zang Y, Holm RH, Münck E. Mössbauer and Magnetization Studies of Heme-Copper-Bridged Assemblies Pertinent to Cytochrome c Oxidase. Inorganic Chemistry. 36: 985-993. PMID 11669660  0.6
1997 Beinert H, Holm RH, Münck E. Iron-sulfur clusters: nature's modular, multipurpose structures. Science (New York, N.Y.). 277: 653-9. PMID 9235882 DOI: 10.1126/science.277.5326.653  1
1997 Huang J, Mukerjee S, Segal BM, Akashi H, Zhou J, Holm RH. Molybdenum - Iron sulfide-bridged double cubanes Journal of the American Chemical Society. 119: 8662-8674. DOI: 10.1021/ja971401q  1
1997 Yoo SJ, Hu Z, Goh C, Bominaar EL, Holm RH, Munck E. Determination of the exchange-coupling constant of an Fe3+-Fe3+ pair in a cubane-type iron-sulfur cluster Journal of the American Chemical Society. 119: 8732-8733. DOI: 10.1021/ja971171f  1
1997 Zhou J, Raebiger JW, Crawford CA, Holm RH. Metal ion incorporation reactions of the cluster [Fe 3S 4(LS 3)] 3-, containing the cuboidal [Fe 3S 4] 0 core Journal of the American Chemical Society. 119: 6242-6250. DOI: 10.1021/ja9704186  1
1997 Zheng Z, Long JR, Holm RH. A basis set of Re6Se8 cluster building blocks and demonstration of their linking capability: Directed synthesis of an Re12Se16 dicluster Journal of the American Chemical Society. 119: 2163-2171. DOI: 10.1021/ja9638519  1
1997 Zhang HH, Filipponi A, Di Cicco A, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-edge XAS studies of cyanide-bridged iron-copper molecular assemblies relevant to cyanide-inhibited heme-copper oxidases using four-body multiple-scattering analysis Journal of the American Chemical Society. 119: 2470-2478. DOI: 10.1021/ja963300i  1
1997 Kauffmann KE, Goddard CA, Zang Y, Holm RH, Münck E. Mössbauer and Magnetization Studies of Heme - Copper-Bridged Assemblies Pertinent to Cytochrome c Osidase Inorganic Chemistry. 36: 985-993.  1
1997 Hoveyda HR, Holm RH. Characterization of the Self-Condensation Equilibrium of [Fe4S4(SH)4]2-: Spectroscopic Identification of a Unique Sulfido-Bridged Acyclic Tricubane Cluster Inorganic Chemistry. 36: 4571-4578.  1
1997 Huang J, Goh C, Holm RH. On the Existence in Solution of Doubly Thiolate-Bridged Double Cubanes Containing the Heterometal [MFe3S4] Core (M = Mo, W) Inorganic Chemistry. 36: 356-361.  1
1997 Raebiger JW, Crawford CA, Zhou J, Holm RH. Reactivity of Cubane-Type [(OC)3MFe3S4(SR)3]3- Clusters (M = Mo, W): Interconversion with Cuboidal [Fe3S4]0 Clusters and Electron Transfer Inorganic Chemistry. 36: 994-1003.  1
1997 Zhou C, Holm RH. Comparative Isotropic Shifts, Redox Potentials, and Ligand Binding Propensities of [1:3] Site-Differentiated Cubane-Type [Fe4Q4]2+ Clusters (Q = S, Se) Inorganic Chemistry. 36: 4066-4077.  1
1997 Zheng Z, Holm RH. Cluster Condensation by Thermolysis: Synthesis of a Rhomb-Linked Re12Se16 Dicluster and Factors Relevant to the Formation of the Re24Se32 Tetracluster Inorganic Chemistry. 36: 5173-5178.  1
1996 Holm RH, Kennepohl P, Solomon EI. Structural and Functional Aspects of Metal Sites in Biology. Chemical Reviews. 96: 2239-2314. PMID 11848828  1
1996 Gardner MT, Deinum G, Kim Y, Babcock GT, Scott MJ, Holm RH. Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear Fe(III)-CN-Cu(II) Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase. Inorganic Chemistry. 35: 6878-6884. PMID 11666856  1
1996 Zhang HH, Filipponi A, Di Cicco A, Lee SC, Scott MJ, Holm RH, Hedman B, Hodgson KO. Multiple-Edge XAS Studies of Synthetic Iron-Copper Bridged Molecular Assemblies Relevant to Cytochrome c Oxidase. Structure Determination Using Multiple-Scattering Analysis with Statistical Evaluation of Errors. Inorganic Chemistry. 35: 4819-4828. PMID 11666681  1
1996 Goddard CA, Long JR, Holm RH. Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe(6)S(8)(PEt(3))(6)](n)()(+) (n = 0-4) Cluster Electron Transfer Series. Inorganic Chemistry. 35: 4347-4354. PMID 11666650  1
1996 James TL, Cai L, Muetterties MC, Holm RH. Dihydrogen Evolution by Protonation Reactions of Nickel(I). Inorganic Chemistry. 35: 4148-4161. PMID 11666623  1
1996 Scott MJ, Goddard CA, Holm RH. Molecular Assemblies Containing Unsupported [Fe(III)-(&mgr;(2):eta(2)-RCO(2))-Cu(II)] Bridges. Inorganic Chemistry. 35: 2558-2567. PMID 11666470  1
1996 Goh C, Segal BM, Huang J, Long JR, Holm RH. Polycubane clusters: Synthesis of [Fe4S4(PR3)4]1+,0 (R = Bu(t), Cy, Pr(i)) and [Fe4S4]0 core aggregation upon loss of phosphine Journal of the American Chemical Society. 118: 11844-11853. DOI: 10.1021/ja9620200  1
1996 Zhou J, Hu Z, Miinck E, Holm RH. The cuboidal Fe3S4 cluster: Synthesis, stability, and geometric and electronic structures in a non-protein environment Journal of the American Chemical Society. 118: 1966-1980. DOI: 10.1021/ja9537843  1
1996 Zhou C, Cai L, Holm RH. Synthesis of a [Fe4S4]-S-Ferriheme Bridged Assembly Containing an Isobacteriochlorin Component: A Further Analogue of the Active Site of Sulfite Reductase Inorganic Chemistry. 35: 2767-2772.  1
1996 Goddard CA, Long JR, Holm RH. Synthesis and Characterization of Four Consecutive Members of the Five-Member [Fe6S8(PEt3)6]n+ (n = 0-4) Cluster Electron Transfer Series Inorganic Chemistry. 35: 4347-4354.  1
1996 Scott MJ, Goddard CA, Holm RH. Molecular Assemblies Containing Unsupported [FeIII-(μ2:η2-RCO2)-Cu II] Bridges Inorganic Chemistry. 35: 2558-2567.  1
1996 Gardner MT, Deinum G, Kim Y, Babcock GT, Scott MJ, Holm RH. Vibrational Analysis of a Molecular Heme-Copper Assembly with a Nearly Linear FeIII-CN-CuII Bridge: Insight into Cyanide Binding to Fully Oxidized Cytochrome c Oxidase Inorganic Chemistry. 35: 6878-6884.  1
1996 Long JR, McCarty LS, Holm RH. A solid-state route to molecular clusters: Access to the solution chemistry of [Re6Q8]2+ (Q = S, Se) core-containing clusters via dimensional reduction Journal of the American Chemical Society. 118: 4603-4616.  1
1995 Holm RH. Chemical approaches to bridged biological metal assemblies Pure and Applied Chemistry. 67: 217-224. DOI: 10.1351/pac199567020217  1
1995 Long JR, Holm RH. Protein-bound iron-sulfur clusters: application of a structural database Inorganica Chimica Acta. 229: 229-239. DOI: 10.1016/0020-1693(94)04249-U  1
1995 Tian ZQ, Donahue JP, Holm RH. Synthesis of new types of dithiolene ligands Inorganic Chemistry. 34: 5567-5572.  1
1995 MacDonnell FM, Ruhlandt-Senge K, Ellison JJ, Holm RH, Power PP. Sterically encumbered iron(II) thiolate complexes: Synthesis and structure of trigonal planar [Fe(SR)3]- (R = 2,4,6-t-Bu3C6H2) and Mössbauer spectra of two- and three-coordinate complexes Inorganic Chemistry. 34: 1815-1822.  1
1995 Long JR, Williamson AS, Holm RH. Dimensional reduction of Re6Se8Cl2: sheets, chains, and discrete clusters composed of chloride-terminated [Re6Q8]2+ (Q = S, Se) cores Angewandte Chemie (International Edition in English). 34: 226-229.  1
1995 Zhou J, Holm RH. Synthesis and metal ion incorporation reactions of the cuboidal Fe3S4 cluster Journal of the American Chemical Society. 117: 11353-11354.  1
1995 Cai L, Segal BM, Long JR, Scott MJ, Holm RH. Octanuclear iron-sulfur clusters with symmetrically coupled Fe4S4 and Fe4S5 cores Journal of the American Chemical Society. 117: 8863-8864.  1
1995 Franolic JD, Long JR, Holm RH. Comprehensive tungsten - Iodine cluster chemistry: Isolated intermediates in the solid-state nucleation of [W6I14]2- Journal of the American Chemical Society. 117: 8139-8153.  1
1995 Tucci GC, Holm RH. Nickel-mediated formation of thioesters from bound methyl, thiols, and carbon monoxide: A possible reaction pathway of acetyl-coenzyme A synthase activity in nickel-containing carbon monoxide dehydrogenases Journal of the American Chemical Society. 117: 6489-6496.  1
1995 Schultz BE, Hille R, Holm RH. Direct oxygen atom transfer in the mechanism of action of Rhodobacter sphaeroides dimethyl sulfoxide reductase Journal of the American Chemical Society. 117: 827-828.  1
1995 Scott MJ, Zhang HH, Lee SC, Hedman B, Hodgson KO, Holm RH. Oxygen-bridged iron-copper assemblies pertinent to heme-copper oxidases: Synthesis and structure of an [FeIII-(OH)-CuII] bridge and EXAFS multiple-scattering effects of linear oxo and nonlinear hydroxo bridges Journal of the American Chemical Society. 117: 568-569.  1
1994 Scott MJ, Holm RH. Molecular assemblies containing linear and bent [FeIII-CN-CuII] bridge units: Synthesis, structures, and relevance to cyanide-inhibited heme - Copper oxidases Journal of the American Chemical Society. 116: 11357-11367.  1
1994 Cen W, MacDonnell FM, Scott MJ, Holm RH. Heterometal clusters containing the cuboidal Fe4S3 fragment: Synthesis, electron distribution, and reactions Inorganic Chemistry. 33: 5809-5818.  1
1994 Hendrich MP, Day EP, Wang CP, Synder BS, Holm RH, Münck E. Ground-state electronic structures of binuclear iron(II) sites: Experimental protocol and a consistent description of mössbauer, EPR, and magnetization measurements of the bis(phenolate)-bridged complex [Fe2(salmp)2]2- Inorganic Chemistry. 33: 2848-2856.  1
1994 Goh C, Weigel JA, Holm RH. The [2:2] site-differentiated clusters [Fe4S4L2(RNC)6] containing two low-spin iron(II) sites Inorganic Chemistry. 33: 4861-4868.  1
1994 Scott MJ, Lee SC, Holm RH. Synthesis and structural characterization of unsupported [FeIII-CN-CuII] bridges related to that in cyanide-inactivated cytochrome c oxidase Inorganic Chemistry. 33: 4651-4662.  1
1994 James TL, Smith DM, Holm RH. Stereoelectronic preferences in electron transfer series of nickel with tridentate ligands containing hard - soft donor sets Inorganic Chemistry. 33: 4869-4877.  1
1994 Long JR, Holm RH. Enumeration and structural classification of clusters derived from parent solids: Metal-chalcogenide clusters composed of edge-sharing tetrahedra Journal of the American Chemical Society. 116: 9987-10002.  1
1994 Cai L, Holm RH. Synthesis and electron delocalization of [Fe4S4]-S-Fe(III) bridged assemblies related to the exchange-coupled catalytic site of sulfite reductases Journal of the American Chemical Society. 116: 7177-7188.  1
1994 Lee SC, Scott MJ, Kauffmann K, Münck E, Holm RH. Cyanide poisoning: An analogue to the binuclear site of oxidized cyanide-inhibited cytochrome c oxidase Journal of the American Chemical Society. 116: 401-402.  1
1993 Yu SB, Holm RH. Tetrahedral and square-pyramidal sulphur-rich complexes of manganese(II) Polyhedron. 12: 263-266. DOI: 10.1016/S0277-5387(00)81637-X  1
1993 Lee SC, Holm RH. A synthetic analogue of the iron/copper bridged assembly in cytochrome c oxidase Journal of the American Chemical Society. 115: 5833-5834.  1
1993 Lee SC, Holm RH. Fluoride-bridged dimers: Binuclear copper(II) complexes and iron(III)-copper(II) assemblies Inorganic Chemistry. 32: 4745-4753.  1
1993 Schultz BE, Holm RH. Kinetics of oxygen atom transfer in an analogue reaction system of the molybdenum oxotransferases Inorganic Chemistry. 32: 4244-4248.  1
1993 Lee SC, Holm RH. Synthesis and characterization of an asymmetric bridged assembly containing the unsupported [FeIII-O-CuII] bridge: An analogue of the binuclear site in oxidized cytochrome c oxidase Journal of the American Chemical Society. 115: 11789-11798.  1
1993 Nordlander E, Lee SC, Cen W, Wu ZY, Natoli CR, Di Cicco A, Filipponi A, Hedman B, Hodgson KO, Holm RH. Heterometal cuboidal clusters MFE4S6(PEt3)4Cl (M = V, Mo): Syntehesis, structural analysis by crystallography and EXAFS, and relevance to the core structure of the iron-molydenum cofactor of nitrogenase Journal of the American Chemical Society. 115: 5549-5558.  1
1993 Cen W, Lee SC, Li J, MacDonnell FM, Holm RH. Heterometal dependence of electron distributions and redox potentials in clusters with cubane-type [MFe3S4]z cores Journal of the American Chemical Society. 115: 9515-9523.  1
1993 Schultz BE, Gheller SF, Muetterties MC, Scott MJ, Holm RH. Molybdenum-mediated oxygen atom transfer: An improved analogue reaction system of the molybdenum oxotransferases Journal of the American Chemical Society. 115: 2714-2722.  1
1993 Scott MJ, Holm RH. Tetranuclear cuboidal and hexanuclear prismatic iron - sulfur - nitrosyl clusters Angewandte Chemie (International Edition in English). 32: 564-566.  1
1992 Tan GO, Ensign SA, Ciurli S, Scott MJ, Hedman B, Holm RH, Ludden PW, Korszun ZR, Stephens PJ, Hodgson KO. On the structure of the nickel/iron/sulfur center of the carbon monoxide dehydrogenase from Rhodospirillum rubrum: an x-ray absorption spectroscopy study. Proceedings of the National Academy of Sciences of the United States of America. 89: 4427-31. PMID 1584775  1
1992 Holm RH. Trinuclear Cuboidal and Heterometallic Cubane-Type Iron-Sulfur Clusters: New Structural and Reactivity Themes in Chemistry and Biology Advances in Inorganic Chemistry. 38: 1-71. DOI: 10.1016/S0898-8838(08)60061-6  1
1992 You JF, Holm RH. A topological method for the enumeration of bridging modes and connectivity patterns of the clusters MmQnLl with four-coordinate metal sites and Qμ2,3,4 bridging atoms Inorganic Chemistry. 31: 2166-2175.  1
1992 Ciurli S, Ross PK, Scott MJ, Yu SB, Holm RH. Synthetic nickel-containing heterometal cubane-type clusters with NiFe3Q4 cores (Q = S, Se) Journal of the American Chemical Society. 114: 5415-5423.  1
1992 Yaghi OM, Scott MJ, Holm RH. Rhenium-selenium-chlorine solid phases: Cluster excision and core substitution reactions of molecular species Inorganic Chemistry. 31: 4778-4784.  1
1992 Zhou J, Scott MJ, Hu Z, Peng G, Münck E, Holm RH. Synthesis and comparative reactivity and electronic structural features of [MFe3S4]z+ cubane-type clusters (M = Fe, Co, Ni) Journal of the American Chemical Society. 114: 10843-10854.  1
1992 Lee SC, Li J, Mitchell JC, Holm RH. Group 5 tetrathiometalates: Simplified syntheses and structures Inorganic Chemistry. 31: 4333-4338.  1
1992 You JF, Papaefthymiou GC, Holm RH. [β-Na2Fe18S30]8- and [Na9Fe20Se38]9-: High-nuclearity clusters by mono- or bicyclization of unidimensional polymeric fragments and the existence of isomeric monocyclic clusters Journal of the American Chemical Society. 114: 2697-2710.  1
1991 Snyder BS, Reynolds MS, Holm RH, Papaefthymiou GC, Frankel RB. Electronic properties of monocapped prismane and basket iron-sulphur clusters Polyhedron. 10: 203-213. DOI: 10.1016/S0277-5387(00)81590-9  1
1991 Ciurli S, Holm RH. Heterometal cubane-type clusters: A ReFe3S4 single-cubane cluster by cleavage of an iron-bridged double cubane and the site-voided cubane [Fe3S4] as a cluster ligand Inorganic Chemistry. 30: 743-750.  1
1991 Krüger HJ, Peng G, Holm RH. Low-potential nickel(III,II) complexes: New systems based on tetradentate amidate-thiolate ligands and the influence of ligand structure on potentials in relation to the nickel site in [niFe]-hydrogenases Inorganic Chemistry. 30: 734-742.  1
1991 Whitener MA, Peng G, Holm RH. Subsite-differentiated analogues of biological [4Fe-4S] clusters effected by binding of a macrocyclic polyether trithiol Inorganic Chemistry. 30: 2411-2417.  1
1991 Liu HY, Scharbert B, Holm RH. An initial approach to biologically related bridged assemblies: PYridinethiolate-Linked Fe4S4-Fe complex systems Journal of the American Chemical Society. 113: 9529-9539.  1
1991 Yu SB, Wang CP, Day EP, Holm RH. A binuclear manganese system with three isolated oxidation states: Synthesis, structures, and properties of molecules with a Mn2(OR)2 bridge unit containing MnIIIMnIII, MnIIIMnII, and MnIIMnII Inorganic Chemistry. 30: 4067-4074.  1
1991 Yu SB, Papaefthymiou GC, Holm RH. Comprehensive iron-selenium-thiolate cluster chemistry Inorganic Chemistry. 30: 3476-3485.  1
1991 Weigel JA, Holm RH. Intrinsic Binding Properties of a Differentiated Iron Subsite in Analogues of Native [Fe4S4]2+ Clusters Journal of the American Chemical Society. 113: 4184-4191.  1
1991 You JF, Holm RH. [Na9Fe20Se38]9-: A high-nuclearity bicyclic cluster constructed by the fusion of Fe2Se2 rhombs Inorganic Chemistry. 30: 1431-1433.  1
1991 Stavropoulos P, Muetterties MC, Carrié M, Holm RH. Structural and reaction chemistry of nickel complexes in relation to carbon monoxide dehydrogenase: A reaction system simulating acetyl-coenzyme A synthase activity Journal of the American Chemical Society. 113: 8485-8492.  1
1990 Lee SC, Holm RH. Entry to the solution chemistry of niobium and tantalum sulfides: Synthesis of soluble forms of the tetrathiometalates [MS4]3- Journal of the American Chemical Society. 112: 9654-9655.  1
1990 Harlan EW, Holm RH. Molybdenum-mediated imido group transfer: Stoichiometric and catalytic reactions and structures Journal of the American Chemical Society. 112: 186-193.  1
1990 Weigel JA, Srivastava KKP, Day EP, Münck E, Holm RH. Isonitrile binding to a site-differentiated synthetic analogue of biological [4Fe-4S] clusters: Equilibria, magnetic interactions and the spin-isolated [3Fe-4S] cluster fragment, and the structure of a low-spin iron(II) subsite Journal of the American Chemical Society. 112: 8015-8023.  1
1989 Conradson SD, Burgess BK, Vaughn SA, Roe AL, Hedman B, Hodgson KO, Holm RH. Cyanide and methylisocyanide binding to the isolated iron-molybdenum cofactor of nitrogenase. The Journal of Biological Chemistry. 264: 15967-74. PMID 2777773  0.72
1988 Carney MJ, Papaefthymiou GC, Spartalian K, Frankel RB, Holm RH. Ground spin state variability in [Fe4S4(SR)4]3-. Synthetic analogs of the reduced clusters in ferredoxins and other iron-sulfur proteins: cases of extreme sensitivity of electronic state and structure to extrinsic factors. Journal of the American Chemical Society. 110: 6084-95. PMID 22148785 DOI: 10.1021/ja00226a025  0.56
1988 Conradson SD, Burgess BK, Holm RH. Fluorine-19 chemical shifts as probes of the structure and reactivity of the iron-molybdenum cofactor of nitrogenase. The Journal of Biological Chemistry. 263: 13743-9. PMID 2843534  0.52
1986 Caradonna JP, Harlan EW, Holm RH. Thiol as an electron donor in molybdenum oxo-transferase analog reaction systems: observations by fluorine-19 NMR spectroscopy and biological implications. Journal of the American Chemical Society. 108: 7856-8. PMID 22283311 DOI: 10.1021/ja00284a073  0.68
1982 Mascharak PK, Smith MC, Armstrong WH, Burgess BK, Holm RH. Fluorine-19 chemical shifts as structural probes of metal-sulfur clusters and the cofactor of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 79: 7056-60. PMID 6960364 DOI: 10.1073/pnas.79.22.7056  1
1981 Paech C, Reynolds JG, Singer TP, Holm RH. Structural identification of iron-sulfur clusters of the respiratory chain-linked NADH dehydrogenase. The Journal of Biological Chemistry. 256: 3167-70. PMID 7204398  1
1980 Ibers JA, Holm RH. Modeling coordination sites in metallobiomolecules. Science (New York, N.Y.). 209: 223-35. PMID 7384796  1
1979 McMillan RS, Renaud J, Reynolds JG, Holm RH. Biologically related iron-sulfur clusters as reaction centers. Reduction of acetylene to ethylene in systems based on [Fe4S4(SR)4]3-. Journal of Inorganic Biochemistry. 11: 213-27. PMID 512659  0.48
1979 Kurtz DM, Holm RH, Ruzicka FJ, Beinert H, Coles CJ, Singer TP. The high potential iron-sulfur cluster of aconitase is a binuclear iron-sulfur cluster. The Journal of Biological Chemistry. 254: 4967-9. PMID 447628  1
1979 Kurtz DM, McMillan RS, Burgess BK, Mortenson LE, Holm RH. Identification of iron-sulfur centers in the iron-molybdenum proteins of nitrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 4986-9. PMID 291915 DOI: 10.1073/pnas.76.10.4986  1
1979 Coles CJ, Holm RH, Kurtz DM, Orme-Johnson WH, Rawlings J, Singer TP, Wong GB. Characterization of the iron-sulfur centers in succinate dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. 76: 3805-8. PMID 226982  1
1978 Orme-Johnson WH, Holm RH. Identification of iron--sulfur clusters in proteins. Methods in Enzymology. 53: 268-74. PMID 213682 DOI: 10.1016/S0076-6879(78)53032-2  1
1977 Lane RW, Gillum WO, Laskowski EJ, Holm RH, Frankel RB, Papaefthymiou GC. Synthesis and electronic properties of the tetranuclear trianions [Fe4S4(SR)4]3-, analogues of the 4-Fe active sites of reduced ferredoxins. Journal of the American Chemical Society. 99: 2350-2. PMID 864137  1
1977 Hill CI, Renaud J, Holm RH, Mortenson IE. Synthetic analogues of the active sites of iron-sulfur proteins. 15. Comparative polarographic potentials of the [Fe4S4(SR)4]2 -- ,3 -- and clostridium pasteurianum ferredoxin redox couples. Journal of the American Chemical Society. 99: 2549-57. PMID 850027  1
1977 Gillum WO, Mortenson LE, Chen JS, Holm RH. Quantitative extrusions of the Fe4S4 cores of the active sites of ferredoxins and the hydrogenase of Clostridium pasteurianum. Journal of the American Chemical Society. 99: 584-95. PMID 830694  0.48
1977 Lane RW, Ibers JA, Frankel RB, Papaefthymiou GC, Holm RH. Synthetic analogues of the active sites of iron-sulfur proteins. 14. Synthesis, properties, and structures of bis(o-xylyl-alpha,alpha'-dithiolato)ferrate(II, III) anions, analogues of oxidized and reduced rubredoxin sites. Journal of the American Chemical Society. 99: 84-98. PMID 830690  1
1977 Hill CL, Steenkamp DJ, Holm RH, Singer TP. Identification of the iron-sulfur center in trimethylamine dehydrogenase. Proceedings of the National Academy of Sciences of the United States of America. 74: 547-51. PMID 265519  1
1976 Dawson JH, Holm RH, Trudell JR, Barth G, Linder RE, Bunnenberg E, Djerassi C, Tang SC. Letter: Oxidized cytochrome P-450. Magnetic circular dichroism evidence for thiolate ligation in the substrate-bound form. Implications for the catalytic mechanism. Journal of the American Chemical Society. 98: 3707-8. PMID 1270706  0.4
1976 Holm RH, Tang SC, Koch S, Papaefthymiou GC, Foner S, Frankel RB, Ibers JA. Model system studies of axial ligation in the oxidized reaction states of cytochrome P-450 enzymes. Advances in Experimental Medicine and Biology. 74: 321-34. PMID 183472  1
1976 Tang SC, Koch S, Papaefthymiou GC, Foner S, Frankel RB, Ibers JA, Holm RH. Axial ligation modes in iron(III) Porphyrins. Models for the oxidized reaction states of cytochrome P-450 enzymes and the molecular structure of iron(III) protoporphyrin IX dimethyl ester p-nitrobenzenethiolate. Journal of the American Chemical Society. 98: 2414-34. PMID 177476  1
1975 Yang CY, Johnson KH, Holm RH, Norman JG. Letter: Theoretical model for the 4-Fe active sites in oxidized ferredoxin and reduced "high-potential" proteins. Electronic structure of the analogue [Fe4S4(SCH3)4]2-. Journal of the American Chemical Society. 97: 6596-8. PMID 1184875  1
1975 Koch S, Tang SC, Holm RH, Frankel RH, Ibers JA. Letter: Ferric porphyrin thiolates. Possible relationship to cytochrome P-450 enzymes and the structure of (p-nitrobenzenethiolato)iron(III) protoporphyrin IX dimethyl ester. Journal of the American Chemical Society. 97: 916-8. PMID 1133375  1
1975 Que L, Holm RH, Mortenson LE. Letter: Extrusion of Fe2S2 and Fe4S4 cores from the active sites of ferredoxin proteins. Journal of the American Chemical Society. 97: 463-4. PMID 1133364  0.64
1975 Tang SP, Spiro TG, Antanaitis C, Moss TH, Holm RH, Herskovitz T, Mortensen LE. Resonance Raman spectroscopic evidence for structural variation among bacterial ferredoxin, HiPIP, and Fe4S4(SCH2Ph)42. Biochemical and Biophysical Research Communications. 62: 1-6. PMID 1111508  0.92
1975 Lane RW, Ibers JA, Frankel RB, Holm RH. Synthetic analogs of active sites of iron-sulfur proteins: bis (o-xylyldithiolato) ferrate (III) monoanion, a structurally unconstrained model for the rubredoxin Fe-S4 unit. Proceedings of the National Academy of Sciences of the United States of America. 72: 2868-72. PMID 1059080  1
1974 Que L, Bobrik MA, Ibers JA, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VII. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2- and the structure of ((CH3)4N)2(Fe4S4(SC6H5)4). Journal of the American Chemical Society. 96: 4168-78. PMID 4854592  1
1974 DePamphilis BV, Averill BA, Herskovitz T, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. VI. Spectral and redox characteristics of the tetranuclear clusters (Fe4S4(SR)4).2-. Journal of the American Chemical Society. 96: 4159-67. PMID 4854591  1
1974 Holm RH, Averill BA, Herskovitz T, Frankel RB, Gray HB, Siiman O, Grunthaner FJ. Equivalence of metal centers in the iron-sulfur protein active site analogs (Fe4S4(SR)4)2-. Journal of the American Chemical Society. 96: 2644-6. PMID 4833717  1
1974 Holm RH, Phillips WD, Averill BA, Mayerle JJ, Herskovitz T. Synthetic analogs of the active sites of iron-sulfur proteins. V. Proton resonance properties of the tetranuclear clusters (Fe4S4(SR)4). Evidence for dominant contact interactions. Journal of the American Chemical Society. 96: 2109-17. PMID 4833642  1
1974 Bobrik MA, Que L, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IV. Ligand substitution reactions of the tetranuclear clusters (Fe4S4(SR)4)2-. Journal of the American Chemical Society. 96: 285-7. PMID 4810571  0.64
1974 Que L, Anglin JR, Bobrik MA, Davison A, Holm RH. Synthetic analogs of the active sites of iron-sulfur proteins. IX. Formation and some electronic and reactivity properties of Fe4S4 Glycyl-L-cysteinylglycyl oligopeptide complexes obtained by ligand substitution reactions. Journal of the American Chemical Society. 96: 6042-8. PMID 4416035  0.64
1974 Frankel RB, Herskovitz T, Averill BA, Holm RH, Krusic PJ, Phillips WD. Synthetic analogs of the active sites of iron-sulfur proteins. 8. Some electronic properties of (Fe4S4(SR)4)3-, analogs of reduced bacterial ferredoxins. Biochemical and Biophysical Research Communications. 58: 974-82. PMID 4365892 DOI: 10.1016/S0006-291X(74)80239-1  1
1973 Averill BA, Herskovitz T, Holm RH, Ibers JA. Synthetic analogs of the active sites of iron-sulfur proteins. II. Synthesis and structure of the tetra(mercapto-m 3 -sulfido-iron) clusters, (Fe 4 S 4 (SR) 4 ) 2- . Journal of the American Chemical Society. 95: 3523-34. PMID 4708377  1
1973 Mayerle JJ, Frankel RB, Holm RH, Ibers JA, Phillips WD, Weiher JF. Synthetic analogs of the active sites of iron-sulfur proteins. Structure and properties of bis(o-xylyldithiolato-m2-sulfidoferrate (3)), an analog of the 2Fe-2S proteins. Proceedings of the National Academy of Sciences of the United States of America. 70: 2429-33. PMID 4525429 DOI: 10.1073/pnas.70.8.2429  1
1973 McDonald CC, Phillips WD, Lovenberg W, Holm RH. PMR studies on Clostridium pasteurianum ferredoxin: origins of contact-shifted resonances and denaturation by dimethyl sulfoxide. Annals of the New York Academy of Sciences. 222: 789-99. PMID 4522445  1
1972 Herskovitz T, Averill BA, Holm RH, Ibers JA, Phillips WD, Weiher JF. Structure and properties of a synthetic analogue of bacterial iron--sulfur proteins. Proceedings of the National Academy of Sciences of the United States of America. 69: 2437-41. PMID 4506765  1
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