Marcetta Y. Darensbourg - Publications

Affiliations: 
Texas A & M University, College Station, TX, United States 
Area:
organometallic chemistry
Website:
http://www.chem.tamu.edu/faculty/faculty_detail.php?ID=38

233 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Yang X, Elrod LC, Le T, Vega VS, Naumann H, Rezenom Y, Reibenspies JH, Hall MB, Darensbourg MY. Controlling O Reactivity in Synthetic Analogues of [NiFeS]- and [NiFeSe]-Hydrogenase Active Sites. Journal of the American Chemical Society. PMID 31465212 DOI: 10.1021/jacs.9b07448  1
2019 Pectol DC, Khan S, Chupik RB, Elsabahy M, Wooley KL, Darensbourg MY, Lim SM. Toward the Optimization of Dinitrosyl Iron Complexes as Therapeutics for Smooth Muscle Cells. Molecular Pharmaceutics. PMID 31244220 DOI: 10.1021/acs.molpharmaceut.9b00389  0.68
2019 Arnet NA, Bhuvanesh N, Darensbourg MY. Proton affinity studies of nickel NS complexes and control of aggregation. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 31175446 DOI: 10.1007/s00775-019-01671-4  0.64
2019 Yang X, Elrod LC, Reibenspies JH, Hall MB, Darensbourg MY. Oxygen uptake in complexes related to [NiFeS]- and [NiFeSe]-hydrogenase active sites. Chemical Science. 10: 1368-1373. PMID 30809352 DOI: 10.1039/c8sc04436h  1
2018 Ghosh P, Ding S, Quiroz MY, Bhuvanesh NY, Hsieh CH, Palacios PM, Pierce BS, Darensbourg MY, Hall MB. Structural and Electronic Responses to the Three Redox Levels of Fe(NO)N₂S₂-Fe(NO)₂. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30216575 DOI: 10.1002/chem.201804168  1
2018 Ahmed ME, Dey S, Darensbourg MY, Dey A. Oxygen-Tolerant H Production by [FeFe]-Hase Active Site Mimics Aided by 2 Sphere Proton Shuttle. Journal of the American Chemical Society. PMID 30180564 DOI: 10.1021/jacs.8b05983  0.96
2018 Sil D, Martinez Z, Ding S, Bhuvanesh N, Darensbourg DJ, Hall MB, Darensbourg MY. Cyanide Docking and Linkage Isomerism in Models for the Artificial [FeFe]-Hydrogenase Maturation Process. Journal of the American Chemical Society. PMID 30001628 DOI: 10.1021/jacs.8b04189  1
2018 Ghosh P, Quiroz M, Pulukkody R, Bhuvanesh N, Darensbourg MY. Bridging cyanides from cyanoiron metalloligands to redox-active dinitrosyl iron units. Dalton Transactions (Cambridge, England : 2003). PMID 29927453 DOI: 10.1039/c8dt01761a  0.68
2017 Ghosh P, Ding S, Chupik RB, Quiroz M, Hsieh CH, Bhuvanesh N, Hall MB, Darensbourg MY. A matrix of heterobimetallic complexes for interrogation of hydrogen evolution reaction electrocatalysts. Chemical Science. 8: 8291-8300. PMID 29619175 DOI: 10.1039/c7sc03378h  1
2017 Ding S, Ghosh P, Darensbourg MY, Hall MB. Interplay of hemilability and redox activity in models of hydrogenase active sites. Proceedings of the National Academy of Sciences of the United States of America. PMID 29087322 DOI: 10.1073/pnas.1710475114  1
2017 Lunsford AM, Goldstein KF, Cohan MA, Denny JA, Bhuvanesh N, Ding S, Hall MB, Darensbourg MY. Comparisons of MN2S2vs. bipyridine as redox-active ligands to manganese and rhenium in (L-L)M'(CO)3Cl complexes. Dalton Transactions (Cambridge, England : 2003). PMID 28322401 DOI: 10.1039/c7dt00600d  1
2017 Ghosh P, Quiroz M, Wang N, Bhuvanesh N, Darensbourg MY. Complexes of MN2S2·Fe(η(5)-C5R5)(CO) as platform for exploring cooperative heterobimetallic effects in HER electrocatalysis. Dalton Transactions (Cambridge, England : 2003). PMID 28174781 DOI: 10.1039/c6dt04666e  0.64
2017 Pulukkody R, Chupik RB, Montalvo SK, Khan S, Bhuvanesh N, Lim SM, Darensbourg MY. Toward biocompatible dinitrosyl iron complexes: sugar-appended thiolates. Chemical Communications (Cambridge, England). PMID 28058431 DOI: 10.1039/c6cc08659d  0.68
2016 Lunsford AM, Beto CC, Ding S, Erdem ÖF, Wang N, Bhuvanesh N, Hall MB, Darensbourg MY. Cyanide-bridged iron complexes as biomimetics of tri-iron arrangements in maturases of the H cluster of the di-iron hydrogenase. Chemical Science. 7: 3710-3719. PMID 30009000 DOI: 10.1039/c6sc00213g  1
2016 Ding S, Ghosh P, Lunsford AM, Wang N, Bhuvanesh N, Hall MB, Darensbourg MY. Hemi-labile Bridging Thiolates as Proton Shuttles in Bio-inspired H2 Production Electrocatalysts. Journal of the American Chemical Society. PMID 27540751 DOI: 10.1021/jacs.6b06461  1
2016 Blank JH, Moncho S, Lunsford AM, Brothers EN, Darensbourg MY, Bengali AA. Ligand Displacement Reaction Paths in a Diiron Hydrogenase Active Site Model Complex. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27482938 DOI: 10.1002/chem.201601677  1
2016 Blank JH, Raju RK, Yan T, Brothers EN, Darensbourg MY, Bengali AA. Iron(0) mediated C-H activation of 1-hexyne: a mechanistic study using time-resolved infrared spectroscopy. Dalton Transactions (Cambridge, England : 2003). PMID 27436484 DOI: 10.1039/c6dt02501c  1
2016 Darensbourg MY, Llobet A. Preface for Small Molecule Activation: From Biological Principles to Energy Applications. Part 3: Small Molecules Related to (Artificial) Photosynthesis. Inorganic Chemistry. 55: 371-7. PMID 26782691 DOI: 10.1021/acs.inorgchem.5b02925  1
2015 Lunsford AM, Blank JH, Moncho S, Haas SC, Muhammad S, Brothers EN, Darensbourg MY, Bengali AA. Catalysis and Mechanism of H2 Release from Amine-Boranes by Diiron Complexes. Inorganic Chemistry. PMID 26716767 DOI: 10.1021/acs.inorgchem.5b02601  1
2015 Crouthers DJ, Ding S, Denny JA, Bethel RD, Hsieh CH, Hall MB, Darensbourg MY. A Reduced 2Fe2S Cluster Probe of Sulfur-Hydrogen versus Sulfur-Gold Interactions. Angewandte Chemie (International Ed. in English). 54: 11102-6. PMID 26352022 DOI: 10.1002/anie.201504574  1
2015 Pulukkody R, Darensbourg MY. Synthetic Advances Inspired by the Bioactive Dinitrosyl Iron Unit. Accounts of Chemical Research. 48: 2049-58. PMID 26090911 DOI: 10.1021/acs.accounts.5b00215  1
2015 Denny JA, Darensbourg MY. Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry. Chemical Reviews. 115: 5248-73. PMID 25948147 DOI: 10.1021/cr500659u  0.64
2015 Bethel RD, Crouthers DJ, Hsieh CH, Denny JA, Hall MB, Darensbourg MY. Regioselectivity in ligand substitution reactions on diiron complexes governed by nucleophilic and electrophilic ligand properties. Inorganic Chemistry. 54: 3523-35. PMID 25767959 DOI: 10.1021/acs.inorgchem.5b00072  1
2015 Denny JA, Foley WS, Todd AD, Darensbourg MY. The ligand unwrapping/rewrapping pathway that exchanges metals in S-acetylated, hexacoordinate N2S2O2 complexes Chemical Science. 6: 7079-7088. DOI: 10.1039/c5sc02269j  1
2015 Denny JA, Darensbourg MY. Metallodithiolates as Ligands in Coordination, Bioinorganic, and Organometallic Chemistry Chemical Reviews. 115: 5248-5273. DOI: 10.1021/cr500659u  1
2015 Bethel RD, Darensbourg MY. The Bioorganometallic Chemistry of Hydrogenase Bioorganometallic Chemistry: Applications in Drug Discovery, Biocatalysis, and Imaging. 239-272. DOI: 10.1002/9783527673438.ch08  1
2014 Zheng D, Wang N, Wang M, Ding S, Ma C, Darensbourg MY, Hall MB, Sun L. Intramolecular iron-mediated C-H bond heterolysis with an assist of pendant base in a [FeFe]-hydrogenase model. Journal of the American Chemical Society. 136: 16817-23. PMID 25244613 DOI: 10.1021/ja5078014  1
2014 Pinder TA, Montalvo SK, Hsieh CH, Lunsford AM, Bethel RD, Pierce BS, Darensbourg MY. Metallodithiolates as ligands to dinitrosyl iron complexes: toward the understanding of structures, equilibria, and spin coupling. Inorganic Chemistry. 53: 9095-105. PMID 25144614 DOI: 10.1021/ic501117f  0.68
2014 Dey S, Rana A, Crouthers D, Mondal B, Das PK, Darensbourg MY, Dey A. Electrocatalytic O₂ reduction by [Fe-Fe]-hydrogenase active site models. Journal of the American Chemical Society. 136: 8847-50. PMID 24846692 DOI: 10.1021/ja5021684  1
2014 Hsieh CH, Ding S, Erdem ÖF, Crouthers DJ, Liu T, McCrory CC, Lubitz W, Popescu CV, Reibenspies JH, Hall MB, Darensbourg MY. Redox active iron nitrosyl units in proton reduction electrocatalysis. Nature Communications. 5: 3684. PMID 24785411 DOI: 10.1038/ncomms4684  1
2014 Pinder TA, Montalvo SK, Lunsford AM, Hsieh CH, Reibenspies JH, Darensbourg MY. Versatile N2S2 nickel-dithiolates as mono- and bridging bidentate, S-donor ligands to gold(i) Dalton Transactions. 43: 138-144. PMID 24108061 DOI: 10.1039/c3dt52295d  1
2014 Pulukkody R, Kyran SJ, Drummond MJ, Hsieh CH, Darensbourg DJ, Darensbourg MY. Hammett correlations as test of mechanism of CO-induced disulfide elimination from dinitrosyl iron complexes Chemical Science. 5: 3795-3802. DOI: 10.1039/c4sc01523a  1
2014 Crouthers DJ, Denny JA, Bethel RD, Munoz DG, Darensbourg MY. Conformational mobility and pendent base effects on electrochemistry of synthetic analogues of the [FeFe]-hydrogenase active site Organometallics. 33: 4747-4755. DOI: 10.1021/om500023j  1
2014 Pinder TA, Montalvo SK, Hsieh CH, Lunsford AM, Bethel RD, Pierce BS, Darensbourg MY. Metallodithiolates as ligands to dinitrosyl iron complexes: Toward the understanding of structures, equilibria, and spin coupling Inorganic Chemistry. 53: 9095-9105. DOI: 10.1021/ic501117f  1
2014 Chmielowiec B, Saadi FH, Baricuatro JH, Javier A, Kim YG, Sun G, Darensbourg MY, Soriaga MP. Molecular catalysis that transpires only when the complex is heterogenized: Studies of a hydrogenase complex surface-tethered on polycrystalline and (1 1 1)-faceted gold by EC, PM-FT-IRRAS, HREELS, XPS and STM Journal of Electroanalytical Chemistry. 716: 63-70. DOI: 10.1016/j.jelechem.2013.12.025  1
2014 Baricuatro JH, Kim YG, Saadi FH, McCrory CCL, Sanabria-Chinchilla J, Crouthers D, Darensbourg MY, Soriaga MP. Heterogenization of a Water-Insoluble Molecular Complex for Catalysis of the Proton-Reduction Reaction in Highly Acidic Aqueous Solutions Electrocatalysis. 5: 226-228. DOI: 10.1007/s12678-014-0200-7  1
2014 Sanabria-Chinchilla J, Javier A, Crouthers D, Baricuatro JH, Darensbourg MY, Soriaga MP. Addendum to Immobilization-Enabled Proton-Reduction Catalysis by a Di-iron Hydrogenase Mimic Electrocatalysis. 5: 113. DOI: 10.1007/s12678-014-0188-z  1
2014 Sanabria-Chinchilla J, Javier A, Crouthers D, Baricuatro JH, Darensbourg MY, Soriaga MP. Immobilization-Enabled Proton Reduction Catalysis by a Di-iron Hydrogenase Mimic Electrocatalysis. 5: 5-7. DOI: 10.1007/s12678-013-0157-y  1
2014 Golden M, Darensbourg M, Irwin J, Frost B. N,N'-Bis(Mercaptoethyl)-1,4-Diazacycloheptane (H2BME-DACH) and its Nickel Complex: A Model for Bioinorganic Chemistry Inorganic Syntheses. 36: 238-247. DOI: 10.1002/9781118744994.ch43  1
2013 Hsieh CH, Pulukkody R, Darensbourg MY. A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion. Chemical Communications (Cambridge, England). 49: 9326-8. PMID 23999554 DOI: 10.1039/c3cc45091k  0.68
2013 Bethel RD, Darensbourg MY. Bioinorganic chemistry: Enzymes activated by synthetic components Nature. 499: 40-41. PMID 23803763 DOI: 10.1038/nature12260  1
2013 Stoian SA, Hsieh CH, Singleton ML, Casuras AF, Darensbourg MY, McNeely K, Sweely K, Popescu CV. Hyperfine interactions and electron distribution in FeIIFe I and FeIFeI models for the active site of the [FeFe] hydrogenases: Mössbauer spectroscopy studies of low-spin Fe I Journal of Biological Inorganic Chemistry. 18: 609-622. PMID 23700296 DOI: 10.1007/s00775-013-1005-5  1
2013 Pulukkody R, Kyran SJ, Bethel RD, Hsieh CH, Hall MB, Darensbourg DJ, Darensbourg MY. Carbon monoxide induced reductive elimination of disulfide in an N-heterocyclic carbene (NHC)/thiolate dinitrosyl iron complex (DNIC). Journal of the American Chemical Society. 135: 8423-30. PMID 23668326 DOI: 10.1021/ja403916v  1
2013 Leidel N, Hsieh CH, Chernev P, Sigfridsson KGV, Darensbourg MY, Haumann M. Bridging-hydride influence on the electronic structure of an [FeFe] hydrogenase active-site model complex revealed by XAES-DFT Dalton Transactions. 42: 7539-7554. PMID 23446996 DOI: 10.1039/c3dt33042g  1
2013 Hsieh CH, Brothers SM, Reibenspies JH, Hall MB, Popescu CV, Darensbourg MY. Ambidentate thiocyanate and cyanate ligands in dinitrosyl iron complexes. Inorganic Chemistry. 52: 2119-24. PMID 23373599 DOI: 10.1021/ic3025149  1
2013 Hsieh CH, Pulukkody R, Darensbourg MY. A dinitrosyl iron complex as a platform for metal-bound imidazole to N-heterocyclic carbene conversion Chemical Communications. 49: 9326-9328. DOI: 10.1039/c3cc45091k  1
2013 Hsieh CH, Chupik RB, Pinder TA, Darensbourg MY. Dinitrosyl iron adducts of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligands Polyhedron. 58: 151-155. DOI: 10.1016/j.poly.2012.09.047  1
2012 Hsieh CH, Erdem OF, Harman SD, Singleton ML, Reijerse E, Lubitz W, Popescu CV, Reibenspies JH, Brothers SM, Hall MB, Darensbourg MY. Structural and spectroscopic features of mixed valent Fe(II)Fe(I) complexes and factors related to the rotated configuration of diiron hydrogenase. Journal of the American Chemical Society. 134: 13089-102. PMID 22774845 DOI: 10.1021/ja304866r  1
2012 Muhammad S, Moncho S, Brothers EN, Darensbourg MY, Darensbourg DJ, Bengali AA. Time resolved infrared spectroscopy: kinetic studies of weakly binding ligands in an iron-iron hydrogenase model compound. Inorganic Chemistry. 51: 7362-9. PMID 22680284 DOI: 10.1021/ic300785z  1
2012 Darensbourg MY, Bethel RD. Biomimetic chemistry: Merging the old with the new Nature Chemistry. 4: 11-13. PMID 22169864 DOI: 10.1038/nchem.1228  1
2012 Denny JA, Foley WS, Almaraz E, Reibenspies JH, Bhuvanesh N, Darensbourg MY. Comparisons of zinc with cadmium in N 2S 2 coordination and as S-bonded adducts to tungsten carbonyls Dalton Transactions. 41: 143-148. PMID 22083144 DOI: 10.1039/c1dt11336d  1
2011 Hess JL, Hsieh CH, Brothers SM, Hall MB, Darensbourg MY. Self-assembly of dinitrosyl iron units into imidazolate-edge-bridged molecular squares: characterization including Mössbauer spectroscopy. Journal of the American Chemical Society. 133: 20426-34. PMID 22074010 DOI: 10.1021/ja208384d  1
2011 Hess JL, Hsieh CH, Reibenspies JH, Darensbourg MY. N-heterocyclic carbene ligands as mimics of imidazoles/histidine for the stabilization of Di-and trinitrosyl iron complexes Inorganic Chemistry. 50: 8541-8552. PMID 21823576 DOI: 10.1021/ic201138f  1
2011 Brothers SM, Darensbourg MY, Hall MB. Modeling structures and vibrational frequencies for dinitrosyl iron complexes (DNICs) with density functional theory. Inorganic Chemistry. 50: 8532-40. PMID 21819054 DOI: 10.1021/ic201137t  1
2011 Hsieh CH, Chupik RB, Brothers SM, Hall MB, Darensbourg MY. cis-Dithiolatonickel as metalloligand to dinitrosyl iron units: the di-metallic structure of Ni(μ-SR)[Fe(NO)2] and an unexpected, abbreviated metalloadamantyl cluster, Ni2(μ-SR)4[Fe(NO)2]3. Dalton Transactions (Cambridge, England : 2003). 40: 6047-53. PMID 21552576 DOI: 10.1039/c1dt10438a  1
2011 Singleton ML, Crouthers DJ, Duttweiler RP, Reibenspies JH, Darensbourg MY. Sulfonated diiron complexes as water-soluble models of the [Fe-Fe]-hydrogenase enzyme active site. Inorganic Chemistry. 50: 5015-26. PMID 21524099 DOI: 10.1021/ic200272x  1
2011 Jenkins RM, Pinder TA, Hatley ML, Reibenspies JH, Darensbourg MY. Tetradentate N2S2 vanadyl(IV) coordination complexes: Synthesis, characterization, and reactivity studies Inorganic Chemistry. 50: 1849-1855. PMID 21299197 DOI: 10.1021/ic1022533  1
2011 Sun N, Liu LV, Dey A, Villar-Acevedo G, Kovacs JA, Darensbourg MY, Hodgson KO, Hedman B, Solomon EI. S K-edge X-ray absorption spectroscopy and density functional theory studies of high and low spin {FeNO}7 thiolate complexes: exchange stabilization of electron delocalization in {FeNO}7 and {FeO2}8. Inorganic Chemistry. 50: 427-36. PMID 21158471 DOI: 10.1021/ic1006378  0.96
2011 Darensbourg MY, Weigand W. Hydrogenases European Journal of Inorganic Chemistry. 917-918. DOI: 10.1002/ejic.201190017  1
2011 Darensbourg MY, Weigand W. Sulfoxygenation of active site models of [NiFe] and [FeFe] hydrogenases - A commentary on possible chemical models of hydrogenase enzyme oxygen sensitivity European Journal of Inorganic Chemistry. 994-1004. DOI: 10.1002/ejic.201001148  1
2010 Hsieh CH, Darensbourg MY. A {Fe(NO)3}10 trinitrosyliron complex stabilized by an n-heterocyclic carbene and the cationic and neutral {Fe(NO)2}(9/10) products of its NO release. Journal of the American Chemical Society. 132: 14118-25. PMID 20857969 DOI: 10.1021/ja104135x  0.68
2010 Bethel RD, Singleton ML, Darensbourg MY. The modular assembly of clusters is the natural synthetic strategy for the active site of [FeFe] hydrogenase Angewandte Chemie - International Edition. 49: 8567-8569. PMID 20845347 DOI: 10.1002/anie.201003747  1
2010 Singleton ML, Reibenspies JH, Darensbourg MY. A cyclodextrin host/guest approach to a hydrogenase active site biomimetic cavity Journal of the American Chemical Society. 132: 8870-8871. PMID 20536241 DOI: 10.1021/ja103774j  1
2010 Jenkins RM, Singleton ML, Leamer LA, Reibenspies JH, Darensbourg MY. Orientation and stereodynamic paths of planar monodentate ligands in square planar nickel N2S complexes Inorganic Chemistry. 49: 5503-5514. PMID 20507173 DOI: 10.1021/ic1002012  1
2010 Surawatanawong P, Tye JW, Darensbourg MY, Hall MB. Mechanism of electrocatalytic hydrogen production by a di-iron model of iron-iron hydrogenase: a density functional theory study of proton dissociation constants and electrode reduction potentials. Dalton Transactions (Cambridge, England : 2003). 39: 3093-104. PMID 20221544 DOI: 10.1039/b925262b  1
2010 Liu T, Li B, Popescu CV, Bilko A, Pérez LM, Hall MB, Darensbourg MY. Analysis of a pentacoordinate iron dicarbonyl as synthetic analogue of the Hmd or mono-iron hydrogenase active site. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 3083-9. PMID 20119989 DOI: 10.1002/chem.200902684  1
2010 Darensbourg MY. Hydrogenase active sites: A new paradigm for natural product-inspired synthesis based on organometallic chemistry Comments On Inorganic Chemistry. 31: 144-152. DOI: 10.1080/02603594.2010.517463  1
2010 Hsieh CH, Darensbourg MY. A {Fe(NO)3}10 trinitrosyliron complex stabilized by an N-heterocyclic carbene and the cationic and neutral {Fe(NO)2} 9/10 products of its NO release Journal of the American Chemical Society. 132: 14118-14125. DOI: 10.1021/ja104135x  1
2009 De Paula QA, Liu Q, Almaraz E, Denny JA, Mangrum JB, Bhuvanesh N, Darensbourg MY, Farrell NP. Reactions of palladium and gold complexes with zinc-thiolate chelates using electrospray mass spectrometry and X-ray diffraction: Molecular identification of [Pd(bme-dach)], [Au(bme-dach]+ and [ZnCl(bme-dach)]2Pd Dalton Transactions. 10896-10903. PMID 20023920 DOI: 10.1039/b917748p  1
2009 Li B, Liu T, Popescu CV, Bilko A, Darensbourg MY. Synthesis and mössbauer characterization of octahedral iron(II) carbonyl complexes Fel2(CO)3L and Fel2(CO) 2L2: Developing models of the [Fe]-H2ase active site Inorganic Chemistry. 48: 11283-11289. PMID 19860458 DOI: 10.1021/ic9017882  1
2009 Almaraz E, Denny JA, Foley WS, Reibenspies JH, Bhuvanesh N, Darensbourg MY. Zinc/Nickel exchange and ligand cannibalism in N2S 2O1,2 donor ligand sets Dalton Transactions. 9496-9502. PMID 19859605 DOI: 10.1039/b914422f  1
2009 Li B, Liu T, Singleton ML, Darensbourg MY. Influence of sulf-oxygenation on CO/L substitution and Fe(CO)3 rotation in thiolate-bridged diiron complexes. Inorganic Chemistry. 48: 8393-403. PMID 19663420 DOI: 10.1021/ic901093c  0.84
2009 Green KN, Hess JL, Thomas CM, Darensbourg MY. Resin-bound models of the [FeFe]-hydrogenase enzyme active site and studies of their reactivity Dalton Transactions. 4344-4350. PMID 19662312 DOI: 10.1039/b823152d  1
2009 Jenkins RM, Singleton ML, Almaraz E, Reibenspies JH, Darensbourg MY. Imidazole-containing (N 3S)-Ni II complexes relating to nickel containing biomolecules Inorganic Chemistry. 48: 7280-7293. PMID 19572492 DOI: 10.1021/ic900778k  1
2009 Liu T, Li B, Singleton ML, Hall MB, Darensbourg MY. Sulfur oxygenates of biomimetics of the diiron subsite of the [FeFe]-hydrogenase active site: properties and oxygen damage repair possibilities. Journal of the American Chemical Society. 131: 8296-307. PMID 19507910 DOI: 10.1021/ja9016528  1
2009 Almaraz E, Foley WS, Denny JA, Reibenspies JH, Golden ML, Darensbourg MY. Development of five-coordinate zinc Mono- and dithiolates as S-donor metalloligands: Formation of a Zn-W coordination polymer Inorganic Chemistry. 48: 5288-5295. PMID 19413331 DOI: 10.1021/ic900261s  1
2009 Green KN, Brothers SM, Lee B, Darensbourg MY, Rockcliffe DA. Chemical issues addressing the construction of the distal Ni[cysteine-glycine-cysteine] 2- site of acetyl CoA synthase: Why not copper? Inorganic Chemistry. 48: 2780-2792. PMID 19253985 DOI: 10.1021/ic801628r  1
2009 Li B, Liu T, Singleton ML, Darensbourg MY. Influence of sulf-oxygenation on CO/L substitution and Fe(CO)3 rotation in thiolate-bridged diiron complexes Inorganic Chemistry. 48: 8393-8403. DOI: 10.1021/ic901093c  1
2008 Singleton ML, Bhuvanesh N, Reibenspies JH, Darensbourg MY. Synthetic support of de novo design: Sterically bulky [FeFe]-hydrogenase models Angewandte Chemie - International Edition. 47: 9492-9495. PMID 18956391 DOI: 10.1002/anie.200803939  1
2008 Wang N, Wang M, Liu T, Li P, Zhang T, Darensbourg MY, Sun L. CO-migration in the ligand substitution process of the chelating diphosphite diiron complex (μ-pdt)[Fe(CO)3][Fe(CO){(EtO) 2PN(Me)P(OEt)2}] Inorganic Chemistry. 47: 6948-6955. PMID 18610970 DOI: 10.1021/ic800525n  1
2008 Thomas CM, Liu T, Hall MB, Darensbourg MY. Series of mixed valent Fe(II)Fe(I) complexes that model the Hox state of [FeFe]hydrogenase: redox properties, density-functional theory investigation, and reactivities with extrinsic CO. Inorganic Chemistry. 47: 7009-24. PMID 18597449 DOI: 10.1021/ic800654a  1
2008 Almaraz E, De Paula QA, Liu Q, Reibenspies JH, Darensbourg MY, Farrell NP. Thiolate bridging and metal exchange in adducts of a zinc finger model and PtII complexes: Biomimetic studies of protein/Pt/DNA interactions Journal of the American Chemical Society. 130: 6272-6280. PMID 18422317 DOI: 10.1021/ja711254q  1
2008 Thomas CM, Liu T, Hall MB, Darensbourg MY. Regioselective (12)CO/(13)CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase. Chemical Communications (Cambridge, England). 1563-5. PMID 18354800 DOI: 10.1039/b719559a  1
2008 Tye JW, Darensbourg MY, Hall MB. Refining the active site structure of iron-iron hydrogenase using computational infrared spectroscopy. Inorganic Chemistry. 47: 2380-8. PMID 18307282 DOI: 10.1021/ic7013732  1
2008 Hess JL, Conder HL, Green KN, Darensbourg MY. Electronic effects of (N2S2)M(NO) complexes (M = Fe, Co) as metallodithiolate ligands Inorganic Chemistry. 47: 2056-2063. PMID 18260623 DOI: 10.1021/ic7017874  1
2008 Hess JL, Young MD, Murillo CA, Darensbourg MY. A paramagnetic trigonal paddlewheel complex with iron-dithiolato ligand paddles: {[(C9H18N2S2)Fe(NO)]3Ag2}(BF4)2 Journal of Molecular Structure. 890: 70-74. DOI: 10.1016/j.molstruc.2008.04.016  1
2008 Singleton ML, Jenkins RM, Klemashevich CL, Darensbourg MY. The effect of bridgehead steric bulk on the ground state and intramolecular exchange processes of (μ-SCH2CR2CH2S)[Fe(CO)3][Fe(CO)2L] complexes Comptes Rendus Chimie. 11: 861-874. DOI: 10.1016/j.crci.2008.01.018  1
2007 Dey A, Green KN, Jenkins RM, Jeffrey SP, Darensbourg M, Hodgson KO, Hedman B, Solomon EI. S K-edge XAS and DFT calculations on square-planar NiII-thiolate complexes: effects of active and passive H-bonding. Inorganic Chemistry. 46: 9655-60. PMID 17949080 DOI: 10.1021/ic7006292  1
2007 Thomas CM, Darensbourg MY, Hall MB. Computational definition of a mixed valent Fe(II)Fe(I) model of the [FeFe]hydrogenase active site resting state. Journal of Inorganic Biochemistry. 101: 1752-7. PMID 17698202 DOI: 10.1016/j.jinorgbio.2007.06.037  1
2007 Green KN, Brothers SM, Jenkins RM, Carson CE, Grapperhaus CA, Darensbourg MY. An experimental and computational study of sulfur-modified nucleophilicity in a dianionic NiN2S2 complex Inorganic Chemistry. 46: 7536-7544. PMID 17685511 DOI: 10.1021/ic700878y  1
2007 Dey A, Jeffrey SP, Darensbourg M, Hodgson KO, Hedman B, Solomon EI. Sulfur K-edge XAS and DFT studies on NiII complexes with oxidized thiolate ligands: implications for the roles of oxidized thiolates in the active sites of Fe and Co nitrile hydratase. Inorganic Chemistry. 46: 4989-96. PMID 17500514 DOI: 10.1021/ic070244l  1
2007 Liu T, Darensbourg MY. A mixed-valent, Fe(II)Fe(I), diiron complex reproduces the unique rotated state of the [FeFe]hydrogenase active site Journal of the American Chemical Society. 129: 7008-7009. PMID 17497786 DOI: 10.1021/ja071851a  1
2007 Jeffery SP, Singleton ML, Reibenspies JH, Darensbourg MY. Control of S-based aggregation: designed synthesis of NiM2 and Ni2M trinuclear complexes. Inorganic Chemistry. 46: 179-85. PMID 17198426 DOI: 10.1021/ic061475f  0.92
2007 Thomas CM, Rüdiger O, Liu T, Carson CE, Hall MB, Darensbourg MY. Synthesis of carboxylic acid-modified [FeFe]-hydrogenase model complexes amenable to surface immobilization Organometallics. 26: 3976-3984. DOI: 10.1021/om7003354  1
2007 Rampersad MV, Zuidema E, Ernsting JM, Van Leeuwen PWNM, Darensbourg MY. CO and ethylene migratory insertion reactions and copolymerization involving palladium complexes of a NiN2S2 metallodithiolate ligand Organometallics. 26: 783-792. DOI: 10.1021/om0605783  1
2007 Jeffery SP, Singleton ML, Reibenspies JH, Darensbourg MY. Control of S-based aggregation: Designed synthesis of NiM2 and Ni2M trinuclear complexes Inorganic Chemistry. 46: 179-185. DOI: 10.1021/ic061475f  1
2007 Green KN, James WD, Cantillo AV, Darensbourg MY. The acetyl CoA synthase paradigm for hybrid bio-organometallics: Quantitative measures for resin-bound Ni-Rh complexes Journal of Organometallic Chemistry. 692: 1392-1397. DOI: 10.1016/j.jorganchem.2006.10.051  1
2006 Jeffery SP, Green KN, Rampersad MV, Reibenspies JH, Darensbourg MY. NiN2S2 complexes as metallodithiolate ligands to RhI, RhII and RhIII Dalton Transactions. 4244-4252. PMID 16932817 DOI: 10.1039/b605768c  1
2006 Tye JW, Darensbourg MY, Hall MB. Correlation between computed gas-phase and experimentally determined solution-phase infrared spectra: models of the iron-iron hydrogenase enzyme active site. Journal of Computational Chemistry. 27: 1454-62. PMID 16807976 DOI: 10.1002/jcc.20456  1
2006 Green KN, Jeffery SP, Reibenspies JH, Darensbourg MY. A nickel tripeptide as a metallodithiolate ligand anchor for resin-bound organometallics Journal of the American Chemical Society. 128: 6493-6498. PMID 16683815 DOI: 10.1021/ja060876r  1
2006 Chiang CY, Darensbourg MY. Iron nitrosyl complexes as models for biological nitric oxide transfer reagents. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 11: 359-70. PMID 16520978 DOI: 10.1007/s00775-006-0084-y  1
2006 Tye JW, Darensbourg MY, Hall MB. De novo design of synthetic di-iron(I) complexes as structural models of the reduced form of iron-iron hydrogenase. Inorganic Chemistry. 45: 1552-9. PMID 16471966 DOI: 10.1021/ic051231f  1
2006 Phelps AL, Rampersad MV, Fitch SB, Darensbourg MY, Darensbourg DJ. A kinetic study of the ring-opening process in tungsten carbonyl complexes containing hemilabile metallodithiolate ligands. Inorganic Chemistry. 45: 119-26. PMID 16390047 DOI: 10.1021/ic051367d  1
2006 Tye JW, Darensbourg MY, Hall MB. The reaction of electrophiles with models of iron-iron hydrogenase: A switch in regioselectivity Journal of Molecular Structure: Theochem. 771: 123-128. DOI: 10.1016/j.theochem.2006.03.022  1
2006 Tye JW, Darensbourg MY, Hall MB. The Activation of Dihydrogen Activation of Small Molecules: Organometallic and Bioinorganic Perspectives. 121-158. DOI: 10.1002/9783527609352.ch4  1
2005 Rampersad MV, Jeffery SP, Golden ML, Lee J, Reibenspies JH, Darensbourg DJ, Darensbourg MY. Characterization of steric and electronic properties of NiN2S2 complexes as S-donor metallodithiolate ligands. Journal of the American Chemical Society. 127: 17323-34. PMID 16332082 DOI: 10.1021/ja055051g  1
2005 Chiang CY, Lee J, Dalrymple C, Sarahan MC, Reibenspies JH, Darensbourg MY. Synthesis and molecular structures of mononitrosyl (N2S2)M(NO) complexes (M = Fe, Co). Inorganic Chemistry. 44: 9007-16. PMID 16296856 DOI: 10.1021/ic051027s  1
2005 Tye JW, Hall MB, Darensbourg MY. Better than platinum? Fuel cells energized by enzymes. Proceedings of the National Academy of Sciences of the United States of America. 102: 16911-2. PMID 16286638 DOI: 10.1073/pnas.0508740102  1
2005 Liu Q, Golden M, Darensbourg MY, Farrell N. Thiolate-bridged heterodinuclear platinum-zinc chelates as models for ternary platinum-DNA-protein complexes and zinc ejection from zinc fingers. Evidence from studies using ESI-mass spectrometry Chemical Communications. 4360-4362. PMID 16113748 DOI: 10.1039/b507751f  1
2005 Tye JW, Lee J, Wang HW, Mejia-Rodriguez R, Reibenspies JH, Hall MB, Darensbourg MY. Dual electron uptake by simultaneous iron and ligand reduction in an N-heterocyclic carbene substituted [FeFe] hydrogenase model compound. Inorganic Chemistry. 44: 5550-2. PMID 16060601 DOI: 10.1021/ic050402d  1
2005 Golden ML, Whaley CM, Rampersad MV, Reibenspies JH, Hancock RD, Darensbourg MY. N2S2Ni metallodithiolate complexes as ligands: structural and aqueous solution quantitative studies of the ability of metal ions to form M-S-Ni bridges to mercapto groups coordinated to nickel(II). implications for acetyl coenzyme A synthase. Inorganic Chemistry. 44: 875-83. PMID 15859264 DOI: 10.1021/ic0489701  1
2005 Jeffery SP, Lee J, Darensbourg MY. Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes. Chemical Communications (Cambridge, England). 1122-4. PMID 15726165 DOI: 10.1039/b416898d  0.92
2005 Darensbourg MY. Synthetic chemistry: Making a natural fuel cell Nature. 433: 589+591. PMID 15703733  1
2005 Rampersad MV, Jeffery SP, Reibenspies JH, Ortiz CG, Darensbourg DJ, Darensbourg MY. N2S2Ni metallothiolates as a class of ligands that support organometallic and bioorganometallic reactivity. Angewandte Chemie (International Ed. in English). 44: 1217-20. PMID 15696588 DOI: 10.1002/anie.200461747  1
2005 Bhuvanesh NSP, Reibenspies JH, Golden ML, Darensbourg MY, Zhang Y, Lee PL. The vapochromic behavior, desulfoxidation and structural characterization of the SO2 adducts of Ni(BME-DACH) from powder data Synthesis and Reactivity in Inorganic, Metal-Organic and Nano-Metal Chemistry. 35: 11-17. DOI: 10.1081/SIM-200047506  1
2005 Jeffery SP, Lee J, Darensbourg MY. Metallodithiolato ligands as bridges in multiply bonded dimolybdenum complexes Chemical Communications. 1122-1124. DOI: 10.1039/b416898d  1
2004 Mejia-Rodriguez R, Chong D, Reibenspies JH, Soriaga MP, Darensbourg MY. The hydrophilic phosphatriazaadamantane ligand in the development of H 2 production electrocatalysts: Iron hydrogenase model complexes Journal of the American Chemical Society. 126: 12004-12014. PMID 15382935 DOI: 10.1021/ja039394v  1
2004 Golden ML, Reibenspies JH, Darensbourg MY. Accommodation of the irregular coordination geometry of lead(II) by a square planar N2S2 ligand and its preference for zinc(II). Inorganic Chemistry. 43: 5798-800. PMID 15360227 DOI: 10.1021/ic049489d  0.92
2004 Chiang CY, Miller ML, Reibenspies JH, Darensbourg MY. Bismercaptoethanediazacyclooctane as a N2S2 chelating agent and Cys-X-Cys mimic for Fe(NO) and Fe(NO)2. Journal of the American Chemical Society. 126: 10867-74. PMID 15339171 DOI: 10.1021/ja049627y  1
2004 Golden ML, Yarbrough JC, Reibenspies JH, Darensbourg MY. Sensing of sulfur dioxide by base metal thiolates: structures and properties of molecular NiN2S2/SO2 adducts. Inorganic Chemistry. 43: 4702-7. PMID 15257599 DOI: 10.1021/ic049387n  1
2004 Webster CE, Darensbourg MY, Lindahl PA, Hall MB. Structures and Energetics of Models for the Active Site of Acetyl-Coenzyme A Synthase: Role of Distal and Proximal Metals in Catalysis Journal of the American Chemical Society. 126: 3410-3411. PMID 15025453 DOI: 10.1021/ja038083h  1
2004 Golden ML, Reibenspies JH, Darensbourg MY. Accommodation of the irregular coordination geometry of lead(II) by a square planar N2S2 ligand and its preference for Zinc(II) Inorganic Chemistry. 43: 5798-5800. DOI: 10.1021/ic049489d  1
2004 TYE JW, HALL MB, GEORGAKAKI IP, DARENSBOURG MY. SYNERGY BETWEEN THEORY AND EXPERIMENT AS APPLIED TO H/D EXCHANGE ACTIVITY ASSAYS IN [Fe]H2ase ACTIVE SITE MODELS Advances in Inorganic Chemistry. 56: 1-26. DOI: 10.1016/S0898-8838(04)56001-4  1
2004 Georgakaki IP, Darensbourg MY. Hydrogen Activation Comprehensive Coordination Chemistry Ii. 8: 549-568. DOI: 10.1016/B0-08-043748-6/08138-X  1
2004 Golden ML, Jeffery SP, Miller ML, Reibenspies JH, Darensbourg MY. The Construction of (N2S2)Ni-Pd Clusters: A Slant-Chair, a Basket and a C4-Paddlewheel Structure European Journal of Inorganic Chemistry. 231-236.  1
2003 Golden ML, Rampersad MV, Reibenspies JH, Darensbourg MY. Capture of Ni(II), Cu(I) and Z(II) by thiolate sulfurs of an N2S2Ni complex: a role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site. Chemical Communications (Cambridge, England). 1824-5. PMID 12931985  1
2003 Miller ML, Ibrahim SA, Golden ML, Darensbourg MY. Adamantane-like cluster complexes of mixed-valent copper-copper and nickel-copper thiolates. Inorganic Chemistry. 42: 2999-3007. PMID 12716194 DOI: 10.1021/ic0262684  1
2003 Georgakaki IP, Miller ML, Darensbourg MY. Requirements for functional models of the iron hydrogenase active site: D2/H2O exchange activity in ((mu-SMe)(mu-pdt)[Fe(CO)2(PMe3)]2+)[BF4-]. Inorganic Chemistry. 42: 2489-94. PMID 12691553 DOI: 10.1021/ic026005+  1
2003 Darensbourg MY, Lyon EJ, Zhao X, Georgakaki IP. The organometallic active site of [Fe]hydrogenase: Models and entatic states Proceedings of the National Academy of Sciences of the United States of America. 100: 3683-3688. PMID 12642671 DOI: 10.1073/pnas.0536955100  1
2003 Zhao X, Chiang CY, Miller ML, Rampersad MV, Darensbourg MY. Activation of alkenes and H2 by [Fe]-H2ase model complexes. Journal of the American Chemical Society. 125: 518-24. PMID 12517165 DOI: 10.1021/ja0280168  1
2003 Georgakaki IP, Thomson LM, Lyon EJ, Hall MB, Darensbourg MY. Fundamental properties of small molecule models of Fe-only hydrogenase: Computations relative to the definition of an entatic state in the active site Coordination Chemistry Reviews. 238: 255-266. DOI: 10.1016/S0010-8545(02)00326-0  1
2003 Chong D, Georgakaki IP, Mejia-Rodriguez R, Sanabria-Chinchilla J, Soriaga MP, Darensbourg MY. Electrocatalysis of hydrogen production by active site analogues of the iron hydrogenase enzyme: Structure/function relationships Journal of the Chemical Society. Dalton Transactions. 4158-4163.  1
2003 Golden ML, Rampersad MV, Reibenspies JH, Darensbourg MY. Capture of NiII, CuI and ZnII by thiolate sulfurs of an N2S2Ni complex: A role for a metallothiolate ligand in the acetyl-coenzyme A synthase active site Chemical Communications. 9: 1824-1825.  1
2002 Zhao X, Georgakaki IP, Miller ML, Mejia-Rodriguez R, Chiang CY, Darensbourg MY. Catalysis of H(2)/D(2) scrambling and other H/D exchange processes by [Fe]-hydrogenase model complexes. Inorganic Chemistry. 41: 3917-28. PMID 12132916 DOI: 10.1021/ic020237r  1
2002 Kaasjager VE, Bouwman E, Gorter S, Reedijk J, Grapperhaus CA, Reibenspies JH, Smee JJ, Darensbourg MY, Derecskei-Kovacs A, Thomson LM. Unique reactivity of a tetradentate N(2)S(2) complex of nickel: intermediates in the production of sulfur oxygenates. Inorganic Chemistry. 41: 1837-44. PMID 11925177 DOI: 10.1021/ic010784x  1
2002 Zhao X, Hsiao YM, Lai CH, Reibenspies JH, Darensbourg MY. Oxidative addition of phosphine-tethered thiols to iron carbonyl: binuclear phosphinothiolate complexes, (mu-SCH(2)CH(2)PPh(2))(2)Fe(2)(CO)(4), and hydride derivatives. Inorganic Chemistry. 41: 699-708. PMID 11849069 DOI: 10.1021/ic010741g  1
2002 De Moura CVR, Silva RM, Cesar A, Darensbourg MY, Reibenspies J. X-ray structure of [Nb(η5-C5H5)2 (SCH2CH2CH2S]. ECP quantum chemistry of niobium five and six metallacycle complexes Polyhedron. 21: 2227-2235. DOI: 10.1016/S0277-5387(02)01179-8  1
2001 Zhao X, Georgakaki IP, Miller ML, Yarbrough JC, Darensbourg MY. H/D exchange reactions in dinuclear iron thiolates as activity assay models of Fe-H2ase. Journal of the American Chemical Society. 123: 9710-1. PMID 11572707 DOI: 10.1021/ja0167046  1
2001 Lyon EJ, Georgakaki IP, Reibenspies JH, Darensbourg MY. Coordination sphere flexibility of active-site models for Fe-only hydrogenase: studies in intra- and intermolecular diatomic ligand exchange. Journal of the American Chemical Society. 123: 3268-78. PMID 11457062 DOI: 10.1021/ja003147z  1
2001 Smee JJ, Miller ML, Grapperhaus CA, Reibenspies JH, Darensbourg MY. Subtle bite-angle influences on N(2)S(2)Ni complexes. Inorganic Chemistry. 40: 3601-5. PMID 11421712 DOI: 10.1021/ic0008619  1
2000 Liaw WF, Chiang CY, Lee GH, Peng SM, Lai CH, Darensbourg MY. Heterobimetallics of nickel-iron dinitrosyl: electronic control by chelate and diatomic ligands. Inorganic Chemistry. 39: 480-4. PMID 11229566 DOI: 10.1021/ic990631y  1
2000 Bellefeuille JA, Grapperhaus CA, Derecskei-Kovacs A, Reibenspies JH, Darensbourg MY. Correlation of electrochemistry, nucleophilicity and density functional calculations of the cis-dithiolate (bme*-daco)Ni Inorganica Chimica Acta. 300: 73-81. DOI: 10.1016/S0020-1693(99)00575-7  1
2000 Darensbourg MY, Lyon EJ, Smee JJ. The bio-organometallic chemistry of active site iron in hydrogenases Coordination Chemistry Reviews. 206: 533-561. DOI: 10.1016/S0010-8545(00)00268-X  1
1999 Grapperhaus CA, Bellefeuille JA, Reibenspies JH, Darensbourg MY. Synthesis and Dimer Cleavage Reactions of the N(2)S Thiolate Bridged Dimer [(mmp-dach)(2)Ni(2)]Cl(2). Inorganic Chemistry. 38: 3698-3703. PMID 11671129  0.92
1999 Lyon EJ, Georgakaki IP, Reibenspies JH, Darensbourg MY. Carbon Monoxide and Cyanide Ligands in a Classical Organometallic Complex Model for Fe-Only Hydrogenase. Angewandte Chemie (International Ed. in English). 38: 3178-3180. PMID 10556894 DOI: 10.1002/(SICI)1521-3773(19991102)38:21<3178::AID-ANIE3178>3.0.CO;2-4  1
1999 Lai CH, Reibenspies JH, Darensbourg MY. Nickel mediated sulfur-selenium and sulfur-sulfur bond formation Chemical Communications. 2473-2474.  1
1999 Grapperhaus CA, Bellefeuille JA, Reibenspies JH, Darensbourg MY. Synthesis and dimer cleavage reactions of the N2S thiolate bridged dimer [(mmp-dach)2Ni2]Cl2 Inorganic Chemistry. 38: 3698-3703.  1
1999 Smee JJ, Goodman DC, Reibenspies JH, Darensbourg MY. Models for terminal Ni(S-cysteine) modification in [NiFe]hydrogenases by iodoacetamide and iodoacetate European Journal of Inorganic Chemistry. 539-546.  1
1998 Lyon EJ, Musie G, Reibenspies JH, Darensbourg MY. Sulfur Site Iodine Adduct of a Nickel Thiolate Complex. Inorganic Chemistry. 37: 6942-6946. PMID 11670834  1
1998 Musie G, Lai CH, Reibenspies JH, Sumner LW, Darensbourg MY. Pentacoordinate (&mgr;-Oxo)diiron(III) Thiolate Complexes and Dimeric Iron(II) Precursors. Inorganic Chemistry. 37: 4086-4093. PMID 11670528  0.96
1998 Grapperhaus CA, Tuntulani T, Reibenspies JH, Darensbourg MY. Methylation of Tethered Thiolates in [(bme-daco)Zn](2) and [(bme-daco)Cd](2) as a Model of Zinc Sulfur-Methylation Proteins. Inorganic Chemistry. 37: 4052-4058. PMID 11670523  0.92
1998 Lai CH, Lee WZ, Miller ML, Reibenspies JH, Darensbourg DJ, Darensbourg MY. Responses of the Fe(CN)2(CO) unit to electronic changes as related to its role in [NiFe]hydrogenase Journal of the American Chemical Society. 120: 10103-10114. DOI: 10.1021/ja982053a  1
1998 Bouwman E, Driessen WL, Kang J, Darensbourg MY. N-(2-hydroxyethyl)-3,5-dimethylpyrazole, a dinuclear copper complex, and N-(2-p-toluenesulfonylethyl)-3,5-dimethylpyrazole Inorganic Syntheses. 32: 82-87.  1
1998 Music G, Reibenspies JH, Darensbourg MY. Synthesis, Structures, and Electrochemical Properties of Nickel Complexes of Macrocyclic N2S2 Aminothioethers Inorganic Chemistry. 37: 302-310.  1
1998 Mills DK, Font I, Farmer PJ, Hsiao YM, Tuntulani T, Buonomo RM, Goodman DC, Musie G, Grapperhaus CA, Maguire MJ, Lai CH, Hatley ML, Smee JJ, Bellefeuille JA, Darensbourg MY, et al. 1,5-diazacyclooctane, pendant arm thiolato derivatives and [N,N′-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II) Inorganic Syntheses. 32: 89-98.  1
1998 Bouwman E, Reedijk J, Kang J, Darensbourg MY. N-(2-mercaptoethyl)-3,5-dimethylpyrazole (Formula Presented) Inorganic Syntheses. 32: 87-89.  1
1998 Musie G, Lai CH, Reibenspies JH, Sumner LW, Darensbourg MY. Pentacoordinate (μ-Oxo)diiron (III) Thiolate Complexes and Dimeric Iron(II) Precursors Inorganic Chemistry. 37: 4086-4093.  1
1998 Grapperhaus CA, Tuntulani T, Reibenspies JH, Darensbourg MY. Methylation of Tethered Thiolates in [(bme-daco)Zn]2 and [(bme-daco)Cd]2 as a Model of Zinc Sulfur-Methylation Proteins Inorganic Chemistry. 37: 4052-4058.  1
1998 Bellefeuille JA, Grapperhaus CA, Buonomo RM, Reibenspies JH, Darensbourg MY. Alkylation-induced O-atom rearrangement in nickel S-oxygenates Organometallics. 17: 4813-4821.  1
1998 Grapperhaus CA, Darensbourg MY. Oxygen Capture by Sulfur in Nickel Thiolates Accounts of Chemical Research. 31: 451-459.  1
1997 Grapperhaus CA, Maguire MJ, Tuntulani T, Darensbourg MY. Singlet Oxygen and the Production of Sulfur Oxygenates of Nickel(II) and Palladium(II) Thiolates. Inorganic Chemistry. 36: 1860-1866. PMID 11669791  1
1997 Darensbourg DJ, Reibenspies JH, Lai CH, Lee WZ, Darensbourg MY. Analysis of an organometallic iron site model for the heterodimetallic unit of [NiFe]hydrogenase Journal of the American Chemical Society. 119: 7903-7904. DOI: 10.1021/ja971559a  1
1997 Goodman DC, Reibenspies JH, Goswami N, Jurisson S, Darensbourg MY. A new macrocyclic N3S2 ligand and its nickel(II), cobalt(II), rhodium(III)-103, and rhodium(III)-105 complexes Journal of the American Chemical Society. 119: 4955-4963. DOI: 10.1021/ja964187z  1
1997 Al-Arfaj AR, Reibenspies JH, Hussain MS, Darensbourg MY, Akhtar N, Isab AA. Cyano[tri(cyclohexyl)phosphino]gold(I), [Au(CN){(C6H11)3P}] Acta Crystallographica Section C: Crystal Structure Communications. 53: 1553-1555.  1
1996 Goodman DC, Farmer PJ, Darensbourg MY, Reibenspies JH. A Coordination Polymer of Nickel(II) Based on a Pentadentate N, S, and O Donor Ligand. Inorganic Chemistry. 35: 4989-4994. PMID 11666704  1
1996 Goodman DC, Buonomo RM, Farmer PJ, Reibenspies JH, Darensbourg MY. Polydentate N(2)S(2)O and N(2)S(2)O(2) Ligands as Alcoholic Derivatives of (N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctane)nickel(II) and (N,N'-Bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II). Inorganic Chemistry. 35: 4029-4037. PMID 11666601  0.96
1996 Musie G, Farmer PJ, Tuntulani T, Reibenspies JH, Darensbourg MY. Influence of Sulfur Metalation on the Accessibility of the Ni(II/I) Couple in [N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase. Inorganic Chemistry. 35: 2176-2183. PMID 11666411  0.96
1996 Grapperhaus CA, Darensbourg MY, Sumner LW, Russell DH. Template effect for O 2 addition across cis-sulfur sites in nickel dithiolates Journal of the American Chemical Society. 118: 1791-1792. DOI: 10.1021/ja953489i  1
1996 Musie G, Farmer PJ, Tuntulani T, Reibenspies JH, Darensbourg MY. Influence of Sulfur Metalation on the Accessibility of the NiII/I Couple in [N,N'-Bis(2-mercaptoethyl)-1,5-diazacyclooctanato]nickel(II): Insight into the Redox Properties of [NiFe]-Hydrogenase Inorganic Chemistry. 35: 2176-2183.  1
1996 Buonomo RM, Reibenspies JH, Darensbourg MY. Structural and electrochemical comparison of NIII in an N2S2 with two, and no axial and of a five coordinate nickel(II) complex Chemische Berichte. 129: 779-784.  1
1996 Goodman DC, Buonomo RM, Farmer PJ, Reibenspies JH, Darensbourg MY. Polydentate N2S2O and N2S2O2 ligands as alcoholic derivatives of (N,N'-bis(2-mercaptoethyl)-1,5-diazacyclooctane)mckel(II) and (N,N'-bis(2-mercapto-2-methylpropane)-1,5-diazacyclooctane)nickel(II) Inorganic Chemistry. 35: 4029-4037.  1
1996 Lai CH, Reibenspies JH, Darensbourg MY. Thiolate bridged nickel-iron complexes containing both iron(0) and iron(II) carbonyls Angewandte Chemie (International Edition in English). 35: 2390-2393.  1
1996 Kim JS, Reibenspies JH, Darensbourg MY. Characteristics of nickel(O), nickel(I), and nickel(II) in phosphino thioether complexes: Molecular structure and S-dealkylation of (Ph2P(o-C6H4)SCH3) 2Ni0 Journal of the American Chemical Society. 118: 4115-4123.  1
1996 Kim JS, Reibenspies JH, Darensbourg MY. Light induced sulfur-dealkylation of phosphino-thioether nickel(0) complexes Inorganica Chimica Acta. 250: 283-294.  1
1995 Tuntulani T, Musie G, Reibenspies JH, Darensbourg MY. Metallosulfoxides and -sulfones: Sulfur oxygenates of [1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctanato]palladium(II) Inorganic Chemistry. 34: 6279-6286.  1
1995 Darensbourg MY, Tuntulani T, Reibenspies JH. Structure/function relationships in ligand-based SO2/O2 conversion to sulfate as promoted by nickel and palladium thiolates Inorganic Chemistry. 34: 6287-6294.  1
1995 Buonomo RM, Font I, Maguire MJ, Reibenspies JH, Tuntulani T, Darensbourg MY. Study of sulfinate and sulfenate complexes derived from the oxygenation of thiolate sulfur in [1,5-bis(2-mercapto-2-methylpropyl)-1,5-diazacyclooctanato(2-)]nickel(II) Journal of the American Chemical Society. 117: 963-973.  1
1994 Darensbourg MY, Font I, Pala M, Reibenspies JH. Synthetic strategies for N2S20-pentacoordinate nickel(II) based on the highly sterically encumbered ligand N,N’-BIS(2-mercapto-2-methylpropane)-1, 5-diazacyclooctane Journal of Coordination Chemistry. 32: 39-49. DOI: 10.1080/00958979408024236  1
1994 Darensbourg MY, Tuntulani T, Reibenspies JH. Sulfur site adducts of sulfur dioxide in nickel-bound thiolates and their conversion to sulfate Inorganic Chemistry. 33: 611-613.  1
1994 Wander SA, Reibenspies JH, Kim JS, Darensbourg MY. Synthesis and characterization of a stable iron(II) hydride-thiolate complex: (PhS)Fe(H)(CO)2(P(OPh)3)2 Inorganic Chemistry. 33: 1421-1426.  1
1994 Farmer PJ, Verpeaux JN, Amatore C, Darensbourg MY, Musie G. Reduction-promoted sulfur-oxygen bond cleavage in a nickel sulfenate as a model for the activation of [NiFe] hydrogenase Journal of the American Chemical Society. 116: 9355-9356.  1
1993 Hsiao YM, Chojnacki SS, Hinton P, Reibenspies JH, Darensbourg MY. Organometallic chemistry of sulfur/phosphorus donor ligand complexes of nickel(II) and nickel(0) Organometallics. 12: 870-875.  1
1993 Font I, Buonomo R, Reibenspies JH, Darensbourg MY. Variable oxygenation levels of sulfur in sterically hindered thiolates: Molecular structure of [N-(2-mercapto-2-methylpropyl)-N′-(2-sulfeno-2-methylpropyl)-1,5- diazacyclooctanato]nickel(II) Inorganic Chemistry. 32: 5897-5898.  1
1993 Farmer PJ, Solouki T, Soma T, Russell DH, Darensbourg MY. Divergent pathways for the addition of dioxygen to sulfur in nickel cis-dithiolates: An isotopomeric analysis Inorganic Chemistry. 32: 4171-4172.  1
1993 Chojnacki SS, Hsiao YM, Darensbourg MY, Reibenspies JH. X-ray structure and solution characterization of Ni(μ-SCH2CH2PPh2)2Mo(CO) 4 Inorganic Chemistry. 32: 3573-3576.  1
1993 Farmer PJ, Reibenspies JH, Lindahl PA, Darensbourg MY. Effects of sulfur site modification on the redox potentials of derivatives of [N,N′- Bis(2-mercaptoethyl)-1,5 -diazacyclooctanato] nickel(II) Journal of the American Chemical Society. 115: 4665-4674.  1
1993 Goodman DC, Tuntulani T, Farmer PJ, Darensbourg MY, Reibenspies JH. Axial ligation of diazacyclooctanenickel and -zinc complexes Angewandte Chemie (International Edition in English). 32: 116-119.  1
1992 Farmer PJ, Solouki T, Mills DK, Soma T, Russell DH, Reibenspies JH, Darensbourg MY. Isotopic labeling investigation of the oxygenation of nickel-bound thiolates by molecular oxygen Journal of the American Chemical Society. 114: 4601-4605.  1
1992 Darensbourg MY, Wander SA, Reibenspies JH. Synthesis and characterization of the electron-rich iron hydride HFe(CO)2(P(OPh)3)2 - and its ligand-based redox substitution with thiolates Organometallics. 11: 3185-3190.  1
1992 Darensbourg MY, Pala M, Houliston SA, Kidwell KP, Spencer D, Chojnacki SS, Reibenspies JH. Stereochemical nonrigidity in heterobimetallic complexes containing the bent metallocene-thiolate fragment Inorganic Chemistry. 31: 1487-1493.  1
1992 Tuntulani T, Reibenspies JH, Farmer PJ, Darensbourg MY. Preparations and structures of a zinc(II) dimer and zinc(II)/nickel(II) pentanuclear derivatives of N,N′-bis(mercaptoethyl)-1,5-diazacyclooctane: [(BME-DACO)Zn]2 and {[(BME-DACO)Ni]3[ZnCl]2}{BF4}2 Inorganic Chemistry. 31: 3497-3499.  1
1992 Darensbourg MY, Font I, Mills DK, Pala M, Reibenspies JH. Variable modes of nickel(II) coordination with macrocyclic ligands based on 1,5-bis(2-mercaptoethyl)-1,5-diazacyclooctane (BME-DACO) Inorganic Chemistry. 31: 4965-4971.  1
1992 De Sousa GF, Filgueiras CAL, Darensbourg MY, Reibenspies JH. Complexation of organotin halides with ambidentate, S, N, and O donor ligands Inorganic Chemistry. 31: 3044-3049.  1
1991 Luchsinger MM, Bozkurt B, Akgerman A, Janzen CP, Addiego WP, Darensbourg MY. Direct synthesis of mixed metal sulfide catalysts and their hydrodenitrogenation activity Applied Catalysis. 68: 229-247. DOI: 10.1016/S0166-9834(00)84105-6  1
1990 Arndt LW, Ash CE, Darensbourg MY, May Hsiao Y, Kim CM, Reibenspies J, Youngdahl KA. The synthesis and molecular structure of (Ph3PAu)2Fe(CO)3P(OEt)3: a triangular Au2Fe cluster Journal of Organometallic Chemistry. 394: 733-741. DOI: 10.1016/0022-328X(90)87264-E  1
1990 Darensbourg MY, Ash CE, Arndt LW, Janzen CP, Youngdahl KA, Park YK. Reactions of anionic transition metal carbonyl hydrides with electrophilic metal carbonyls: Nucleophilic addition (hydride transfer) vs. electron transfer mechanisms Journal of Organometallic Chemistry. 383: 191-199. DOI: 10.1016/0022-328X(90)85131-H  1
1990 Mills DK, Reibenspies JH, Darensbourg MY. Sterically protected nickel(II) in a N2S2 donor environment: 1,5-Bis(mercaptoethyl)-1,5-diazacyclooctane and its methylated derivative Inorganic Chemistry. 29: 4364-4366.  1
1990 Darensbourg MY, Longridge EM, Payne V, Reibenspies J, Riordan CG, Springs JJ, Calabrese JC. Isolation of chromium(0) thiols: Molecular structure of (ButSH)Cr(CO)5 Inorganic Chemistry. 29: 2721-2726.  1
1990 Darensbourg MY, Bischoff CJ, Houliston SA, Pala M, Reibenspies J. Conformations of (π5-C5H5)2Nb(S-p-C 66H4X)2 n (n=0,1): Responsiveness to para substituants on aryl groups and to d-electron count Journal of the American Chemical Society. 112: 6905-6912.  1
1990 Springs J, Janzen CP, Darensbourg MY, Calabrese JC, Krusic PJ, Verpeaux JN, Amatore C. Electron paramagnetic resonance and electrochemical study of the oxidation chemistry of mononuclear and binuclear chromium carbonyl thiolates Journal of the American Chemical Society. 112: 5789-5797.  1
1989 Darensbourg MY, Floris B, Youngdahl KA. Addition of acrylonitrile to anionic transition metal hydrides. An ionic model for homogeneous olefin processes Tetrahedron Letters. 30: 1781-1784. DOI: 10.1016/S0040-4039(00)99578-9  1
1989 Liaw WF, Kim C, Darensbourg MY, Rheingold AL. Thiolate, thioether, and thiol derivatives of iron(0) carbonyls Journal of the American Chemical Society. 111: 3591-3597.  1
1989 Darensbourg MY, Silva R, Reibenspies J, Prout CK. Structural studies of (η5-C5H5)2Nb(SC 6H5)2, [(η5-C5H5)2Nb(SC 6H5)2 +], and [(η5-C5H5)2Nb(μ-SC 6H5)2Mo(CO)4 +] Organometallics. 8: 1315-1323.  1
1989 Darensbourg MY, Liaw WF, Riordan CG. Protonation sites in thiolato iron carbonylates: Evidence for an arrested Fe(RS-H) oxidative addition Journal of the American Chemical Society. 111: 8051-8052.  1
1989 Darensbourg MY, Ludwig M, Riordan CG. Spectroscopic and chemical studies of nickel(II) hydrides Inorganic Chemistry. 28: 1630-1634.  1
1988 Darensbourg MY, Liaw WF, Reibenspies J. Binuclear reductive elimination of water: New route to the (triphenylstannyl)pentacarbonyltungsten anion, Ph3SnW(CO)5 - Inorganic Chemistry. 27: 2555-2558.  1
1988 Arndt LW, Bancroft BT, Darensbourg MY, Janzen CP, Kim CM, Reibenspies J, Varner KE, Youngdahl KA. Promotion of Me/CO migratory insertion by transition-metal Lewis acids. Synthesis and reactivity of a transition-metal heterobimetallic carbonyl alkyl anion, MeFeW(CO)9 - Organometallics. 7: 1302-1309.  1
1987 Darensbourg MY, Ash CE. Anionic Transition Metal Hydrides Advances in Organometallic Chemistry. 27: 1-50. DOI: 10.1016/S0065-3055(08)60025-8  1
1987 Ash CE, Darensbourg MY, Hall MB. Temperature and solvent dependence of scalar coupling constants in salts of trans-HFe(CO)3PR3 - Journal of the American Chemical Society. 109: 4173-4180.  1
1987 Ash CE, Hurd PW, Darensbourg MY, Newcomb M. Competing nucleophilic displacement and radical chain reduction in reactions of transition-metal hydride anions with alkyl bromides Journal of the American Chemical Society. 109: 3313-3317.  1
1987 Ash CE, Kim CM, Darensbourg MY, Rheingold AL. Properties and x-ray structure of PPN+[cis-HFe(CO)3P(OPh)3]-: An unexpected structural isomer Inorganic Chemistry. 26: 1357-1361.  1
1987 Darensbourg DJ, Darensbourg MY, Goh LY, Ludvig M, Wiegreffe P. The reaction of (Cy3P)2Ni(H)(CH3) with carbon dioxide. Formation of a hydridonickel formate complex, HNi(O2CH)(Cy3P)2 Journal of the American Chemical Society. 109: 7539-7540.  1
1986 Darensbourg MY, Ludvig MM. Deprotonation of [HMo(CO)2(P P)2]BF4 complexes: Hard anions as proton carriers Inorganic Chemistry. 25: 2894-2898.  1
1986 Arndt LW, Darensbourg MY, Delord T, Bancroft BT. Metal donor → metal acceptor complexes: Fe(CO)4 2-, HFe(CO)4 -, and trans-HFe(CO)3P(OMe)3 - as anionic ligands to M(CO)5 0, M = Cr, W 1 Journal of the American Chemical Society®. 108: 2617-2627.  1
1986 Ash CE, Delord T, Simmons D, Darensbourg MY. Solution and solid-state structures of salts of trans-HFe(CO)3PR3 - including a study of alkali cation contact ion pairing Organometallics. 5: 17-25.  1
1986 Tooley PA, Ovalles C, Kao SC, Darensbourg DJ, Darensbourg MY. Anionic group 6 hydrides and carboxylates as homogeneous catalysts for reduction of aldehydes and ketones Journal of the American Chemical Society. 108: 5465-5470.  1
1986 Darensbourg DJ, Darensbourg MY, Gray RL, Simmons D, Arndt LW. Intramolecular ligand rearrangements in anionic group 6 metal pentacarbonyl hydride derivatives Inorganic Chemistry. 25: 880-882.  1
1985 Tooley PA, Arndt LW, Darensbourg MY. Olefin isomerization catalysis by heterobimetallic hydrides, HFeM(CO)8L- (M = Cr, Mo, W; L = CO, PR3) Journal of the American Chemical Society. 107: 2422-2427.  1
1985 Gaus PL, Kao SC, Youngdahl K, Darensbourg MY. Anionic group 6 transition-metal carbonyl hydrides as reducing agents. Ketones, aldehydes, and epoxides Journal of the American Chemical Society. 107: 2428-2434.  1
1985 Kao SC, Spillett CT, Ash C, Lusk R, Park YK, Darensbourg MY. Relative reactivity and mechanistic studies of the hydride-transfer reagents HM(CO)4L- (M = Cr, W; L = CO, PR3) Organometallics. 4: 83-91.  1
1985 Arndt LW, Darensbourg MY, Fackler JP, Lusk RJ, Marier DO, Youngdahl KA. Comparisons of the heterobimetallic and heterotrimetallic anions HFeW(CO)9 - and Ph3PAuFeW(CO)9 - Journal of the American Chemical Society. 107: 7218-7219.  1
1984 Kao SC, Darensbourg MY, Schenk W. The nature of alkali cation contact ion pairs with anionic transition-metal hydrides HM(CO)4L- (M = Cr, W; L = CO, PR3) Organometallics. 3: 871-876.  1
1984 Kao SC, Gaus PL, Youngdahl K, Darensbourg MY. Selective reduction of acyl chlorides to aldehydes by anionic 6B transition-metal hydrides Organometallics. 3: 1601-1603.  1
1984 Kao SC, Darensbourg MY. Relative reactivities of anionic transition-metal hydrides. Reduction of alkyl halides Organometallics. 3: 646-647.  1
1984 Arndt L, Delord T, Darensbourg MY. Chemistry of new heteronuclear bridging hydrides: (μ-H)[Fe(CO)4M(CO)5]- (M = Cr, Mo, W) Journal of the American Chemical Society. 106: 456-457.  1
1984 Darensbourg MY, El Mehdawi R, Delord TJ, Fronczek FR, Watkins SF. Binuclear molybdenum carbonyls bridged both by hydride and by bidentate phosphine ligands. Crystal and molecular structures of salts of (μ-H)(μ-Ph2P(CH2)nPPh2)Mo 2(CO)8 - (n = 1-4) and their reactions with acids Journal of the American Chemical Society. 106: 2583-2591.  1
1983 Hanckel JM, Darensbourg MY. Anion-assisted transfer of a sterically constrained proton: Molecular structure of HMo(CO)2(Ph2PCH2CH2PPh 2)2 + AlCl4 - Journal of the American Chemical Society. 105: 6979-6980.  1
1982 Darensbourg MY, Jimenez P, Sackett JR, Hanckel JM, Kump RL. Interactions of CpM′(CO)3 - (M′ = Cr, Mo, W) with cations: Effects on CO exchange and RX addition reactions Journal of the American Chemical Society. 104: 1521-1530.  1
1982 Darensbourg MY, Bau R, Marks MW, Burch RR, Deaton JC, Slater S. Structural characterizations of salts of HCr(CO)5 - and (μ-H)2BH2Cr(CO)4 - and studies of their interconversions Journal of the American Chemical Society. 104: 6961-6969.  1
1982 Darensbourg MY, Hanckel JM. Site-specific ion fairing of monosubstifuted vanadium carbonylaies, LV(CO)5 - Organometallics. 1: 82-87.  1
1981 Atwood JD, Atwood ML, Darensbourg MY, Darensbourg DJ. Chromium, molybdenum, and tungsten. Annual survey covering the year 1976 Journal of Organometallic Chemistry. 223: 49-116. DOI: 10.1016/S0022-328X(00)89672-2  1
1981 Darensbourg MY, Deaton JC. The HCr(CO)5 - anion Inorganic Chemistry. 20: 1644-1646.  1
1981 Darensbourg DJ, Darensbourg MY, Walker N. Studies using (n-Bu)3P=O as a carbon monoxide labilizing ligand in the synthesis of metal carbonyl complexes highly enriched in 13CO Inorganic Chemistry. 20: 1918-1921.  1
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