Christopher Colin Cummins - Publications

Affiliations: 
Chemistry Massachusetts Institute of Technology, Cambridge, MA, United States 
Area:
synthetic chemistry
Website:
http://chemistry.mit.edu/people/cummins-christopher

153 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Geeson MB, Transue WJ, Cummins CC. Organoiron- and Fluoride-Catalyzed Phosphinidene Transfer to Styrenic Olefins in a Stereoselective Synthesis of Unprotected Phosphiranes. Journal of the American Chemical Society. PMID 31408599 DOI: 10.1021/jacs.9b07069  0.52
2019 Geeson MB, Ríos P, Transue WJ, Cummins CC. Orthophosphate and Sulfate Utilization for C-E (E = P, S) Bond Formation via Trichlorosilyl Phosphide and Sulfide Anions. Journal of the American Chemical Society. PMID 30901207 DOI: 10.1021/jacs.9b01475  0.52
2018 Transue WJ, Nava M, Terban MW, Yang J, Greenberg MW, Wu G, Foreman ES, Mustoe CL, Kennepohl P, Owen JS, Billinge SJL, Kulik HJ, Cummins CC. Anthracene as a Launchpad for a Phosphinidene Sulfide and for Generation of a Phosphorus-Sulfur Material having the Composition PS, a Vulcanized Red Phosphorus that is Yellow. Journal of the American Chemical Society. PMID 30512942 DOI: 10.1021/jacs.8b10775  0.52
2018 Transue WJ, Yang J, Nava M, Sergeyev IV, Barnum TJ, McCarthy MC, Cummins CC. Synthetic and Spectroscopic Investigations Enabled by Modular Synthesis of Molecular Phosphaalkyne Precursors. Journal of the American Chemical Society. PMID 30485736 DOI: 10.1021/jacs.8b09845  0.52
2018 Paparo A, Silvia JS, Spaniol TP, Okuda J, Cummins CC. Countercation Effect on CO Binding to Oxo Titanate with Bulky Anilide Ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30350897 DOI: 10.1002/chem.201803265  0.76
2018 Joost M, Nava M, Transue WJ, Martin-Drumel MA, McCarthy MC, Patterson D, Cummins CC. Sulfur monoxide thermal release from an anthracene-based precursor, spectroscopic identification, and transfer reactivity. Proceedings of the National Academy of Sciences of the United States of America. PMID 29773708 DOI: 10.1073/pnas.1804035115  0.52
2018 Joost M, Transue WJ, Cummins CC. Diazomethane umpolung atop anthracene: an electrophilic methylene transfer reagent. Chemical Science. 9: 1540-1543. PMID 29675198 DOI: 10.1039/c7sc04506a  0.52
2017 Stauber JM, Zhang S, Gvozdik N, Jiang Y, Avena L, Stevenson KJ, Cummins CC. Cobalt and Vanadium Trimetaphosphate Polyanions: Synthesis, Characterization and Electrochemical Evaluation for Non-Aqueous Redox-Flow Battery Applications. Journal of the American Chemical Society. PMID 29232132 DOI: 10.1021/jacs.7b08751  0.84
2017 Joost M, Nava M, Transue WJ, Cummins CC. An exploding N-isocyanide reagent formally composed of anthracene, dinitrogen and a carbon atom. Chemical Communications (Cambridge, England). PMID 28990025 DOI: 10.1039/c7cc06516g  0.52
2017 Zhang S, Nava MJ, Chow GK, Lopez N, Wu G, Britt DR, Nocera DG, Cummins CC. On the incompatibility of lithium-O2 battery technology with CO2. Chemical Science. 8: 6117-6122. PMID 28989641 DOI: 10.1039/c7sc01230f  0.84
2017 Joost M, Transue WJ, Cummins CC. Terminal tungsten pnictide complex formation through pnictaethynolate decarbonylation. Chemical Communications (Cambridge, England). PMID 28920594 DOI: 10.1039/c7cc06841g  0.52
2017 Transue WJ, Velian A, Nava M, García-Iriepa C, Temprado M, Cummins CC. On the Mechanism and Scope of Phosphinidene Transfer from Dibenzo-7-Phosphanorbornadiene Compounds. Journal of the American Chemical Society. PMID 28703579 DOI: 10.1021/jacs.7b05464  0.52
2017 Stauber JM, Alliger GE, Nocera DG, Cummins CC. Second-Coordination-Sphere Assisted Selective Colorimetric Turn-on Fluoride Sensing by a Mono-Metallic Co(II) Hexacarboxamide Cryptand Complex. Inorganic Chemistry. PMID 28665117 DOI: 10.1021/acs.inorgchem.7b01335  0.84
2017 Knopf I, Tofan D, Beetstra D, Al-Nezari A, Al-Bahily K, Cummins CC. A family of cis-macrocyclic diphosphines: modular, stereoselective synthesis and application in catalytic CO2/ethylene coupling. Chemical Science. 8: 1463-1468. PMID 28616145 DOI: 10.1039/c6sc03614g  0.76
2017 Hou GL, Chen B, Transue WJ, Yang Z, Grützmacher H, Driess M, Cummins CC, Borden WT, Wang XB. Spectroscopic Characterization, Computational Investigation, and Comparisons of ECX- (E = As, P, and N; X = S and O) Anions. Journal of the American Chemical Society. PMID 28589728 DOI: 10.1021/jacs.7b02984  0.52
2017 Stauber JM, Cummins CC. Terminal Titanyl Complexes of Tri- and Tetrametaphosphate: Synthesis, Structures, and Reactivity with Hydrogen Peroxide. Inorganic Chemistry. PMID 28207244 DOI: 10.1021/acs.inorgchem.6b03149  0.84
2016 Hou GL, Chen B, Transue WJ, Hrovat DA, Cummins CC, Borden WT, Wang XB. Negative ion photoelectron spectroscopy of PN: electron affinity and electronic structures of PN˙. Chemical Science. 7: 4667-4675. PMID 30155115 DOI: 10.1039/c5sc04667j  0.52
2016 Stauber JM, Müller P, Dai Y, Wu G, Nocera DG, Cummins CC. Multi-electron reactivity of a cofacial di-tin(ii) cryptand: partial reduction of sulfur and selenium and reversible generation of S3˙(). Chemical Science. 7: 6928-6933. PMID 28567264 DOI: 10.1039/c6sc01754a  0.84
2016 Courtemanche MA, Transue WJ, Cummins CC. Phosphinidene Reactivity of a Transient Vanadium P≡N Complex. Journal of the American Chemical Society. PMID 27958729 DOI: 10.1021/jacs.6b10545  0.52
2016 Nava M, Martin-Drumel MA, Lopez CA, Crabtree KN, Womack CC, Nguyen TL, Thorwirth S, Cummins CC, Stanton JF, McCarthy MC. Spontaneous and Selective Formation of HSNO, a Crucial Intermediate Linking H2S and Nitroso Chemistries. Journal of the American Chemical Society. PMID 27540860 DOI: 10.1021/jacs.6b05886  1
2016 Hou GL, Chen B, Transue WJ, Hrovat DA, Cummins CC, Borden WT, Wang XB. A Joint Experimental and Computational Study of the Negative Ion Photoelectron Spectroscopy of the 1-Phospha-2,3,4-triazolate Anion, HCPN3(.) The Journal of Physical Chemistry. A. PMID 27434547 DOI: 10.1021/acs.jpca.6b06343  1
2016 Chakarawet K, Knopf I, Nava M, Jiang Y, Stauber JM, Cummins CC. Crystalline Metaphosphate Acid Salts: Synthesis in Organic Media, Structures, Hydrogen-Bonding Capability, and Implication of Superacidity. Inorganic Chemistry. PMID 27267865 DOI: 10.1021/acs.inorgchem.6b00749  1
2016 Transue WJ, Velian A, Nava M, Martin-Drumel MA, Womack C, Jiang J, Hou GL, Wang XB, McCarthy M, Field RW, Cummins CC. A Molecular Precursor to Phosphaethyne and its Application in Synthesis of the Aromatic 1,2,3,4-Phosphatriazolate Anion. Journal of the American Chemical Society. PMID 27171847 DOI: 10.1021/jacs.6b03910  1
2015 Stauber JM, Bloch ED, Vogiatzis KD, Zheng SL, Hadt RG, Hayes D, Chen LX, Gagliardi L, Nocera DG, Cummins CC. Pushing MOM to the Right: A Cryptand-Encapsulated Co-O-Co Unit. Journal of the American Chemical Society. PMID 26559923 DOI: 10.1021/jacs.5b09827  1
2015 Velian A, Cossairt BM, Cummins CC. Assembly and stabilization of {E(cyclo-P3)2} (E = Sn, Pb) as a bridging ligand spanning two triaryloxyniobium units. Dalton Transactions (Cambridge, England : 2003). PMID 26505867 DOI: 10.1039/c5dt03383g  1
2015 Nava M, Lopez N, Müller P, Wu G, Nocera DG, Cummins CC. Anion-Receptor Mediated Oxidation of Carbon Monoxide to Carbonate by Peroxide Dianion. Journal of the American Chemical Society. PMID 26465825 DOI: 10.1021/jacs.5b08495  1
2015 Paparo A, Silvia JS, Kefalidis CE, Spaniol TP, Maron L, Okuda J, Cummins CC. A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO2. Angewandte Chemie (International Ed. in English). 54: 9115-9. PMID 26110967 DOI: 10.1002/anie.201502532  0.76
2015 Velian A, Cummins CC. Inorganic chemistry. Synthesis and characterization of P₂N₃⁻: an aromatic ion composed of phosphorus and nitrogen. Science (New York, N.Y.). 348: 1001-4. PMID 26023134 DOI: 10.1126/science.aab0204  0.48
2015 Spinney HA, Clough CR, Cummins CC. The titanium tris-anilide cation [Ti(N[(t)Bu]Ar)3](+) stabilized as its perfluoro-tetra-phenylborate salt: structural characterization and synthesis in connection with redox activity of 4,4'-bipyridine dititanium complexes. Dalton Transactions (Cambridge, England : 2003). 44: 6784-96. PMID 25739447 DOI: 10.1039/c5dt00105f  0.64
2015 Anderson BL, Maher AG, Nava M, Lopez N, Cummins CC, Nocera DG. Ultrafast Photoinduced Electron Transfer from Peroxide Dianion. The Journal of Physical Chemistry. B. 119: 7422-9. PMID 25635708 DOI: 10.1021/jp5110505  1
2015 Diaconescu PL, Cummins CC. Radical anionic versus neutral 2,2'-bipyridyl coordination in uranium complexes supported by amide and ketimide ligands. Dalton Transactions (Cambridge, England : 2003). 44: 2676-83. PMID 25510329 DOI: 10.1039/c4dt02422b  1
2015 Velian A, Cummins CC. Synthesis and characterization of P2N3-: An aromatic ion composed of phosphorus and nitrogen Science. 348: 1001-1004. DOI: 10.1126/science.aab0204  1
2015 Spinney HA, Clough CR, Cummins CC. The titanium tris-anilide cation [Ti(N[tBu]Ar)3]+ stabilized as its perfluoro-tetra-phenylborate salt: Structural characterization and synthesis in connection with redox activity of 4,4′-bipyridine dititanium complexes Dalton Transactions. 44: 6784-6796. DOI: 10.1039/c5dt00105f  1
2015 Velian A, Transue WJ, Cummins CC. Synthesis, Characterization, and Thermolysis of Dibenzo-7-dimethylgermanorbornadiene Organometallics. 34: 4644-4646. DOI: 10.1021/acs.organomet.5b00529  1
2015 Knopf I, Cummins CC. Revisiting CO2 reduction with NaBH4 under aprotic conditions: Synthesis and characterization of sodium triformatoborohydride Organometallics. 34: 1601-1603. DOI: 10.1021/acs.organomet.5b00190  1
2015 Paparo A, Silvia JS, Kefalidis CE, Spaniol TP, Maron L, Okuda J, Cummins CC. A Dimetalloxycarbene Bonding Mode and Reductive Coupling Mechanism for Oxalate Formation from CO2 Angewandte Chemie - International Edition. DOI: 10.1002/anie.201502532  1
2014 Majumdar S, Stauber JM, Palluccio TD, Cai X, Velian A, Rybak-Akimova EV, Temprado M, Captain B, Cummins CC, Hoff CD. Role of axial base coordination in isonitrile binding and chalcogen atom transfer to vanadium(III) complexes. Inorganic Chemistry. 53: 11185-96. PMID 25280113 DOI: 10.1021/ic5017005  1
2014 Velian A, Nava M, Temprado M, Zhou Y, Field RW, Cummins CC. A retro Diels-Alder route to diphosphorus chemistry: molecular precursor synthesis, kinetics of P2 transfer to 1,3-dienes, and detection of P2 by molecular beam mass spectrometry. Journal of the American Chemical Society. 136: 13586-9. PMID 25198657 DOI: 10.1021/ja507922x  1
2014 Jiang Y, Chakarawet K, Kohout AL, Nava M, Marino N, Cummins CC. Dihydrogen tetrametaphosphate, [P4O12H2]2-: synthesis, solubilization in organic media, preparation of its anhydride [P4O11]2- and acidic methyl ester, and conversion to tetrametaphosphate metal complexes via protonolysis. Journal of the American Chemical Society. 136: 11894-7. PMID 25102033 DOI: 10.1021/ja5058339  0.48
2014 Ullman AM, Sun X, Graham DJ, Lopez N, Nava M, De Las Cuevas R, Müller P, Rybak-Akimova EV, Cummins CC, Nocera DG. Electron-transfer studies of a peroxide dianion. Inorganic Chemistry. 53: 5384-91. PMID 24773522 DOI: 10.1021/ic500759g  1
2014 Cummins CC, Huang C, Miller TJ, Reintinger MW, Stauber JM, Tannou I, Tofan D, Toubaei A, Velian A, Wu G. The stannylphosphide anion reagent sodium bis(triphenylstannyl) phosphide: synthesis, structural characterization, and reactions with indium, tin, and gold electrophiles. Inorganic Chemistry. 53: 3678-87. PMID 24621383 DOI: 10.1021/ic403178j  1
2014 Cozzolino AF, Silvia JS, Lopez N, Cummins CC. Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide. Dalton Transactions (Cambridge, England : 2003). 43: 4639-52. PMID 24492850 DOI: 10.1039/c3dt52738g  0.76
2014 Manna CM, Nassar MY, Tofan D, Chakarawet K, Cummins CC. Facile synthesis of mononuclear early transition-metal complexes of κ3cyclo-tetrametaphosphate ([P4O12]4-) and cyclo-trimetaphosphate ([P3O9]3-. Dalton Transactions (Cambridge, England : 2003). 43: 1509-18. PMID 24285119 DOI: 10.1039/c3dt52526k  1
2014 Cummins CC. Phosphorus: From the Stars to Land & Sea Daedalus. 143: 9-20. DOI: 10.1162/DAED_a_00301  1
2014 Knopf I, Ono T, Temprado M, Tofan D, Cummins CC. Uptake of one and two molecules of CO2 by the molybdate dianion: A soluble, molecular oxide model system for carbon dioxide fixation Chemical Science. 5: 1772-1776. DOI: 10.1039/c4sc00132j  1
2014 Cozzolino AF, Silvia JS, Lopez N, Cummins CC. Experimental and computational studies on the formation of cyanate from early metal terminal nitrido ligands and carbon monoxide Dalton Transactions. 43: 4639-4652. DOI: 10.1039/c3dt52738g  1
2014 Jiang Y, Chakarawet K, Kohout AL, Nava M, Marino N, Cummins CC. Dihydrogen tetrametaphosphate, [P4O12H 2]2-: Synthesis, solubilization in organic media, preparation of its anhydride [P4O11]2- and acidic methyl ester, and conversion to tetrametaphosphate metal complexes via protonolysis Journal of the American Chemical Society. 136: 11894-11897. DOI: 10.1021/ja5058339  1
2014 Breunig JM, Tofan D, Cummins CC. Contrasting cyclo-P3 ligand transfer reactivity of valence-isoelectronic aryloxide complexes [(P3)Nb(ODipp) 3]- and [(P3)W(ODipp)3] European Journal of Inorganic Chemistry. 1605-1609. DOI: 10.1002/ejic.201301140  1
2013 Tofan D, Temprado M, Majumdar S, Hoff CD, Cummins CC. Functionalization reactions characteristic of a robust bicyclic diphosphane framework. Inorganic Chemistry. 52: 8851-64. PMID 23841641 DOI: 10.1021/ic401052a  1
2013 Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Chui M, Temprado M, Silvia JS, Cozzolino AF, Tofan D, Velian A, Cummins CC, Captain B, Hoff CD. Thermodynamic and kinetic study of cleavage of the N-O bond of N-oxides by a vanadium(III) complex: enhanced oxygen atom transfer reaction rates for adducts of nitrous oxide and mesityl nitrile oxide. Journal of the American Chemical Society. 135: 11357-72. PMID 23805977 DOI: 10.1021/ja405395z  1
2013 Huss AS, Curley JJ, Cummins CC, Blank DA. Relaxation and dissociation following photoexcitation of the (μ-N2)[Mo(N[t-Bu]Ar)3]2 dinitrogen cleavage intermediate. The Journal of Physical Chemistry. B. 117: 1429-36. PMID 23249096 DOI: 10.1021/jp310122x  1
2013 Wang LP, Tofan D, Chen J, Van Voorhis T, Cummins CC. A pathway to diphosphorus from the dissociation of photoexcited tetraphosphorus Rsc Advances. 3: 23166-23171. DOI: 10.1039/c3ra43940b  1
2013 Vlaisavljevich B, Diaconescu PL, Lukens WL, Gagliardi L, Cummins CC. Investigations of the electronic structure of arene-bridged diuranium complexes Organometallics. 32: 1341-1352. DOI: 10.1021/om3010367  1
2012 Cozzolino AF, Tofan D, Cummins CC, Temprado M, Palluccio TD, Rybak-Akimova EV, Majumdar S, Cai X, Captain B, Hoff CD. Two-step binding of O2 to a vanadium(III) trisanilide complex to form a non-vanadyl vanadium(V) peroxo complex. Journal of the American Chemical Society. 134: 18249-52. PMID 23082724 DOI: 10.1021/ja309621h  1
2012 Velian A, Cummins CC. Facile synthesis of dibenzo-7λ3-phosphanorbornadiene derivatives using magnesium anthracene. Journal of the American Chemical Society. 134: 13978-81. PMID 22894133 DOI: 10.1021/ja306902j  0.48
2012 Fox AR, Cummins CC. A highly reduced cyanogen ligand derived from cyanide reductive coupling. Chemical Communications (Cambridge, England). 48: 3061-3. PMID 22343665 DOI: 10.1039/c2cc17212g  0.64
2012 Diaconescu PL, Cummins CC. μ-η6,η6-Arene-bridged diuranium hexakisketimide complexes isolable in two states of charge. Inorganic Chemistry. 51: 2902-16. PMID 22339231 DOI: 10.1021/ic202163m  1
2012 Lopez N, Graham DJ, McGuire R, Alliger GE, Shao-Horn Y, Cummins CC, Nocera DG. Reversible reduction of oxygen to peroxide facilitated by molecular recognition. Science (New York, N.Y.). 335: 450-3. PMID 22282808 DOI: 10.1126/science.1212678  0.84
2012 Lopez N, Graham DJ, McGuire R, Alliger GE, Shao-Horn Y, Cummins CC, Nocera DG. Reversible reduction of oxygen to peroxide facilitated by molecular recognition Science. 335: 450-453. DOI: 10.1126/science.1212678  1
2012 Tofan D, Cummins CC. Bicyclic dinuclear tris-(ditopic diphosphane) complexes of zerovalent group 10 metals Chemical Science. 3: 2474-2478. DOI: 10.1039/c2sc20559a  1
2012 Velian A, Cummins CC. Synthesis of a diniobium tetraphosphorus complex by a 2(3-1) process Chemical Science. 3: 1003-1006. DOI: 10.1039/c2sc00931e  1
2012 Rankin MA, Cummins CC. Terminal phosphinidene formation via tantalaziridine complexes Dalton Transactions. 41: 9615-9618. DOI: 10.1039/c2dt31082a  1
2012 Fox AR, Cummins CC. A highly reduced cyanogen ligand derived from cyanide reductive coupling Chemical Communications. 48: 3061-3063. DOI: 10.1039/c2cc17212g  1
2012 Velian A, Cummins CC. Facile synthesis of dibenzo-7λ 3-phosphanorbornadiene derivatives using magnesium anthracene Journal of the American Chemical Society. 134: 13978-13981. DOI: 10.1021/ja306902j  1
2012 Krummenacher I, Cummins CC. Carbon-phosphorus triple bond formation through multiple bond metathesis of an anionic niobium phosphide with carbon dioxide Polyhedron. 32: 10-13. DOI: 10.1016/j.poly.2011.07.016  1
2012 Daly AM, Cossairt BM, Southwood G, Carey SJ, Cummins CC, Kukolich SG. Microwave spectrum of arsenic triphosphide Journal of Molecular Spectroscopy. 278: 68-71. DOI: 10.1016/j.jms.2012.03.007  1
2012 Clough CR, Silvia JS, Müller P, Cummins CC. Synthesis and characterization of the trimetaphosphate molybdenum tricarbonyl anion [ (P 3O 9) Mo(CO) 3] 3- as its tris(bis(triphenylphosphine)iminium) salt Inorganica Chimica Acta. 382: 195-198. DOI: 10.1016/j.ica.2011.11.060  1
2011 Moroz YS, Cozzolino AF, Rybak-Akimova EV, Cummins CC. Bis(μ(2)-η:η-2,4,6-trimethyl-benzonitrile)-bis-[(N-isopropyl-3,5-dimethyl-anilido)molybdenum(III)](Mo-Mo). Acta Crystallographica. Section E, Structure Reports Online. 67: m1643-4. PMID 22199474 DOI: 10.1107/S1600536811044680  1
2011 Solis-Ibarra D, Silvia JS, Jancik V, Cummins CC. Facile synthesis of zero-, one-, and two-dimensional vanadyl pyrophosphates. Inorganic Chemistry. 50: 9980-4. PMID 21936494 DOI: 10.1021/ic200510y  1
2011 Tofan D, Cossairt BM, Cummins CC. White phosphorus activation at a metal-phosphorus triple bond: a new route to cyclo-triphosphorus or cyclo-pentaphosphorus complexes of niobium. Inorganic Chemistry. 50: 12349-58. PMID 21894967 DOI: 10.1021/ic2014607  1
2011 Cai X, Majumdar S, Fortman GC, Frutos LM, Temprado M, Clough CR, Cummins CC, Germain ME, Palluccio T, Rybak-Akimova EV, Captain B, Hoff CD. Thermodynamic, kinetic, and mechanistic study of oxygen atom transfer from mesityl nitrile oxide to phosphines and to a terminal metal phosphido complex. Inorganic Chemistry. 50: 9620-30. PMID 21875050 DOI: 10.1021/ic2013599  1
2011 Schwarzmaier C, Noor A, Glatz G, Zabel M, Timoshkin AY, Cossairt BM, Cummins CC, Kempe R, Scheer M. Formation of cyclo-E4(2-) units (E4 =P4, As4, AsP3) by a complex with a Cr-Cr quintuple bond. Angewandte Chemie (International Ed. in English). 50: 7283-6. PMID 21698734 DOI: 10.1002/anie.201102361  1
2011 Alliger GE, Müller P, Do LH, Cummins CC, Nocera DG. Family of cofacial bimetallic complexes of a hexaanionic carboxamide cryptand. Inorganic Chemistry. 50: 4107-15. PMID 21446665 DOI: 10.1021/ic200143b  1
2011 Curley JJ, Cozzolino AF, Cummins CC. Nitrogen fixation to cyanide at a molybdenum center. Dalton Transactions (Cambridge, England : 2003). 40: 2429-32. PMID 21293816 DOI: 10.1039/c0dt01326a  0.64
2011 Montag M, Clough CR, Müller P, Cummins CC. Cyclophosphates as ligands for cobalt(III) in water. Chemical Communications (Cambridge, England). 47: 662-4. PMID 21116534 DOI: 10.1039/c0cc04342g  1
2011 Creutz SE, Krummenacher I, Clough CR, Cummins CC. A trigonal and hindered tertiary phosphine ligand rendered anionic by a niobate anchor: Formation of zwitterionic M(i) (M = Cu, Ag, Au, Rh) complexes Chemical Science. 2: 2166-2172. DOI: 10.1039/c1sc00375e  1
2011 Silvia JS, Cummins CC. Binding, release, and functionalization of CO2 at a nucleophilic oxo anion complex of titanium Chemical Science. 2: 1474-1479. DOI: 10.1039/c1sc00215e  1
2011 Curley JJ, Cozzolino AF, Cummins CC. Nitrogen fixation to cyanide at a molybdenum center Dalton Transactions. 40: 2429-2432. DOI: 10.1039/c0dt01326a  1
2010 Cossairt BM, Cummins CC. Molecular gallium arsenide phosphide clusters prepared from AsP(3), P(4), and [{GaC(SiMe(3))(3)}(4)]. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 12603-8. PMID 20859969 DOI: 10.1002/chem.201001819  1
2010 Tofan D, Cummins CC. Photochemical incorporation of diphosphorus units into organic molecules. Angewandte Chemie (International Ed. in English). 49: 7516-8. PMID 20799313 DOI: 10.1002/anie.201004385  1
2010 Rankin MA, Cummins CC. Carbon dioxide reduction by terminal tantalum hydrides: formation and isolation of bridging methylene diolate complexes. Journal of the American Chemical Society. 132: 10021-3. PMID 20593902 DOI: 10.1021/ja104761n  1
2010 Fox AR, Creutz SE, Cummins CC. A bimetallic uranium mu-dicarbide complex: synthesis, X-ray crystal structure, and bonding. Dalton Transactions (Cambridge, England : 2003). 39: 6632-4. PMID 20582336 DOI: 10.1039/c0dt00419g  1
2010 Cossairt BM, Cummins CC, Head AR, Lichtenberger DL, Berger RJ, Hayes SA, Mitzel NW, Wu G. On the molecular and electronic structures of AsP3 and P4. Journal of the American Chemical Society. 132: 8459-65. PMID 20515032 DOI: 10.1021/ja102580d  1
2010 Alliger GE, Müller P, Cummins CC, Nocera DG. Cofacial dicobalt complex of a binucleating hexacarboxamide cryptand ligand. Inorganic Chemistry. 49: 3697-9. PMID 20337489 DOI: 10.1021/ic100395a  1
2010 Fox AR, Arnold PL, Cummins CC. Uranium-nitrogen multiple bonding: isostructural anionic, neutral, and cationic uranium nitride complexes featuring a linear U=N=U core. Journal of the American Chemical Society. 132: 3250-1. PMID 20178384 DOI: 10.1021/ja910364u  1
2010 Cossairt BM, Piro NA, Cummins CC. Early-transition-metal-mediated activation and transformation of white phosphorus. Chemical Reviews. 110: 4164-77. PMID 20175534 DOI: 10.1021/cr9003709  1
2010 Silvia JS, Cummins CC. Ligand-based reduction of CO(2) to CO mediated by an anionic niobium nitride complex. Journal of the American Chemical Society. 132: 2169-71. PMID 20121151 DOI: 10.1021/ja910445r  1
2010 Cossairt BM, Cummins CC. Shuttling P3 from niobium to rhodium: the synthesis and use of Ph3SnP3(C6H8) as a P3- synthon. Angewandte Chemie (International Ed. in English). 49: 1595-8. PMID 20112318 DOI: 10.1002/anie.200906633  1
2010 Cossairt BM, Cummins CC. Radical synthesis of trialkyl, triaryl, trisilyl and tristannyl phosphines from P4 New Journal of Chemistry. 34: 1533-1536. DOI: 10.1039/c0nj00124d  1
2010 Figueroa JS, Piro NA, Mindiola DJ, Fickes MG, Cummins CC. Niobaziridine hydrides Organometallics. 29: 5215-5229. DOI: 10.1021/om100522p  1
2010 Fox AR, Silvia JS, Townsend EM, Cummins CC. Six-coordinate uranium complexes featuring a bidentate anilide ligand Comptes Rendus Chimie. 13: 781-789. DOI: 10.1016/j.crci.2010.05.001  1
2009 Germain ME, Temprado M, Castonguay A, Kryatova OP, Rybak-Akimova EV, Curley JJ, Mendiratta A, Tsai YC, Cummins CC, Prabhakar R, McDonough JE, Hoff CD. Coordination-mode control of bound nitrile radical complex reactivity: intercepting end-on nitrile-Mo(III) radicals at low temperature. Journal of the American Chemical Society. 131: 15412-23. PMID 19919164 DOI: 10.1021/ja905849a  1
2009 Spinney HA, Piro NA, Cummins CC. Triple-bond reactivity of an AsP complex intermediate: synthesis stemming from molecular arsenic, As(4). Journal of the American Chemical Society. 131: 16233-43. PMID 19842699 DOI: 10.1021/ja906550h  1
2009 Cossairt BM, Cummins CC. Properties and reactivity patterns of AsP(3): an experimental and computational study of group 15 elemental molecules. Journal of the American Chemical Society. 131: 15501-11. PMID 19799430 DOI: 10.1021/ja906294m  1
2009 Curley JJ, Piro NA, Cummins CC. A terminal molybdenum arsenide complex synthesized from yellow arsenic. Inorganic Chemistry. 48: 9599-601. PMID 19764796 DOI: 10.1021/ic9016068  1
2009 Curley JJ, Murahashi T, Cummins CC. Synthesis and reversible reductive coupling of cationic, dinitrogen-derived diazoalkane complexes. Inorganic Chemistry. 48: 7181-93. PMID 19580311 DOI: 10.1021/ic900495s  1
2009 Piro NA, Cummins CC. An unusual P-P double bond formed via phospha-Wittig transformation of a terminal PO complex. Journal of the American Chemical Society. 131: 8764-5. PMID 19505095 DOI: 10.1021/ja903860k  1
2009 Fox AR, Cummins CC. Uranium-nitrogen multiple bonding: the case of a four-coordinate uranium(VI) nitridoborate complex. Journal of the American Chemical Society. 131: 5716-7. PMID 19341243 DOI: 10.1021/ja8095812  1
2009 Cossairt BM, Diawara MC, Cummins CC. Facile synthesis of AsP3. Science (New York, N.Y.). 323: 602. PMID 19179522 DOI: 10.1126/science.1168260  1
2009 Piro NA, Cummins CC. Tetraphosphabenzenes obtained via a triphosphacyclobutadiene intermediate. Angewandte Chemie (International Ed. in English). 48: 934-8. PMID 19101967 DOI: 10.1002/anie.200804432  1
2009 Silvia JS, Cummins CC. Two-electron reduction of a vanadium(V) nitride by CO to release cyanate and open a coordination site. Journal of the American Chemical Society. 131: 446-7. PMID 19099473 DOI: 10.1021/ja807767w  1
2009 Silvia JS, Cummins CC. Reduction of CO2 to CO mediated by anionic terminal nitrido complexes Acs National Meeting Book of Abstracts 1
2008 Cossairt BM, Cummins CC. A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions. Angewandte Chemie (International Ed. in English). 47: 8863-6. PMID 18855962 DOI: 10.1002/anie.200803971  1
2008 Cossairt BM, Cummins CC. Phosphaalkenes as long-lived phosphorus cluster surface functional groups: intramolecular P=C addition to a niobium-supported P7 cage. Inorganic Chemistry. 47: 9363-71. PMID 18800834 DOI: 10.1021/ic8009282  1
2008 Fox AR, Bart SC, Meyer K, Cummins CC. Towards uranium catalysts. Nature. 455: 341-9. PMID 18800133 DOI: 10.1038/nature07372  1
2008 Temprado M, McDonough JE, Mendiratta A, Tsai YC, Fortman GC, Cummins CC, Rybak-Akimova EV, Hoff CD. Thermodynamic and kinetic studies of H atom transfer from HMo(CO)3(eta(5)-C5H5) to Mo(N[t-Bu]Ar)3 and (PhCN)Mo(N[t-Bu]Ar)3: direct insertion of benzonitrile into the Mo-H bond of HMo(N[t-Bu]Ar)3 forming (Ph(H)C=N)Mo(N[t-Bu]Ar)3. Inorganic Chemistry. 47: 9380-9. PMID 18788794 DOI: 10.1021/ic800945m  1
2008 Clough CR, Müller P, Cummins CC. 6-Coordinate tungsten(VI) tris-n-isopropylanilide complexes: products of terminal oxo and nitrido transformations effected by main group electrophiles. Dalton Transactions (Cambridge, England : 2003). 4458-63. PMID 18698449 DOI: 10.1039/b801037d  1
2008 Piro NA, Cummins CC. P2 addition to terminal phosphide M[triple bond]P triple bonds: a rational synthesis of cyclo-P3 complexes. Journal of the American Chemical Society. 130: 9524-35. PMID 18588294 DOI: 10.1021/ja802080m  1
2008 Curley JJ, Cook TR, Reece SY, Müller P, Cummins CC. Shining light on dinitrogen cleavage: structural features, redox chemistry, and photochemistry of the key intermediate bridging dinitrogen complex. Journal of the American Chemical Society. 130: 9394-405. PMID 18576632 DOI: 10.1021/ja8002638  1
2008 Christian G, Stranger R, Yates BF, Cummins CC. Investigating CN- cleavage by three-coordinate M[N(R)Ar]3 complexes. Dalton Transactions (Cambridge, England : 2003). 338-44. PMID 18411843 DOI: 10.1039/b713757e  1
2008 McDonough JE, Mendiratta A, Curley JJ, Fortman GC, Fantasia S, Cummins CC, Rybak-Akimova EV, Nolan SP, Hoff CD. Thermodynamic, kinetic, and computational study of heavier chalcogen (S, Se, and Te) terminal multiple bonds to molybdenum, carbon, and phosphorus. Inorganic Chemistry. 47: 2133-41. PMID 18260626 DOI: 10.1021/ic701611p  1
2008 Tonzetich ZJ, Schrock RR, Wampler KM, Bailey BC, Cummins CC, Müller P. A tungstenVI nitride having a W2(mu-N)2 core. Inorganic Chemistry. 47: 1560-7. PMID 18257522 DOI: 10.1021/ic701913q  1
2008 Cossairt BM, Cummins CC. A reactive niobium phosphinidene P8 cluster obtained by reductive coupling of white phosphorus. Angewandte Chemie (International Ed. in English). 47: 169-72. PMID 18022991 DOI: 10.1002/anie.200704354  1
2008 Betley TA, Surendranath Y, Childress MV, Alliger GE, Fu R, Cummins CC, Nocera DG. A ligand field chemistry of oxygen generation by the oxygen-evolving complex and synthetic active sites. Philosophical Transactions of the Royal Society of London. Series B, Biological Sciences. 363: 1293-303; discussion. PMID 17971328 DOI: 10.1098/rstb.2007.2226  1
2007 Christian G, Stranger R, Yates BF, Cummins CC. Rationalizing the different products in the reaction of N2 with three-coordinate MoL3 complexes. Dalton Transactions (Cambridge, England : 2003). 1939-47. PMID 17702174 DOI: 10.1039/b701050h  1
2007 Piro NA, Cummins CC. Ethylenebis(triphenylphosphine)platinum as a probe for niobium-mediated diphosphorus chemistry. Inorganic Chemistry. 46: 7387-93. PMID 17676729 DOI: 10.1021/ic700514u  1
2007 Christian G, Stranger R, Petrie S, Yates BF, Cummins CC. Breaking chemistry's strongest bond: can three-coordinate [M{N(R)Ar}3] complexes cleave carbon monoxide? Chemistry (Weinheim An Der Bergstrasse, Germany). 13: 4264-72. PMID 17385762 DOI: 10.1002/chem.200601643  1
2007 Agarwal P, Piro NA, Meyer K, Müller P, Cummins CC. An isolable and monomeric phosphorus radical that is resonance-stabilized by the vanadium(IV/V) redox couple. Angewandte Chemie (International Ed. in English). 46: 3111-4. PMID 17351998 DOI: 10.1002/anie.200700059  1
2007 Fox AR, Clough CR, Piro NA, Cummins CC. A terminal nitride-to-phosphide conversion sequence followed by tungsten phosphide functionalization using a diphenylphosphenium synthon. Angewandte Chemie (International Ed. in English). 46: 973-6. PMID 17211909 DOI: 10.1002/anie.200604736  1
2007 Christian G, Stranger R, Yates BF, Cummins CC. Cleavage of CO by Mo[N(R)Ar]3 complexes European Journal of Inorganic Chemistry. 3736-3741. DOI: 10.1002/ejic.200700304  1
2006 Curley JJ, Sceats EL, Cummins CC. A cycle for organic nitrile synthesis via dinitrogen cleavage. Journal of the American Chemical Society. 128: 14036-7. PMID 17061880 DOI: 10.1021/ja066090a  1
2006 Piro NA, Figueroa JS, McKellar JT, Cummins CC. Triple-bond reactivity of diphosphorus molecules. Science (New York, N.Y.). 313: 1276-9. PMID 16946068 DOI: 10.1126/science.1129630  1
2006 McDonough JE, Weir JJ, Sukcharoenphon K, Hoff CD, Kryatova OP, Rybak-Akimova EV, Scott BL, Kubas GJ, Mendiratta A, Cummins CC. Comparison of thermodynamic and kinetic aspects of oxidative addition of PhE-EPh (E = S, Se, Te) to Mo(CO)3(PR3)2, W(CO)3(PR3)2, and Mo(N[tBu]Ar)3 complexes. The role of oxidation state and ancillary ligands in metal complex induced chalcogenyl radical generation. Journal of the American Chemical Society. 128: 10295-303. PMID 16881661 DOI: 10.1021/ja063250+  1
2006 Mendiratta A, Cummins CC, Cotton FA, Ibragimov SA, Murillo CA, Villagrán D. A diamagnetic dititanium(III) paddlewheel complex with no direct metal-metal bond. Inorganic Chemistry. 45: 4328-30. PMID 16711677 DOI: 10.1021/ic0602650  1
2006 Figueroa JS, Cummins CC. A niobaziridine hydride system for white phosphorus or dinitrogen activation and N- or P-atom transfer. Dalton Transactions (Cambridge, England : 2003). 2161-8. PMID 16673028 DOI: 10.1039/b602530g  1
2006 Mendiratta A, Cummins CC, Kryatova OP, Rybak-Akimova EV, McDonough JE, Hoff CD. Benzonitrile extrusion from molybdenum(IV) ketimide complexes obtained via radical C-E (E = O, S, Se) bond formation: toward a new nitrogen atom transfer reaction. Journal of the American Chemical Society. 128: 4881-91. PMID 16594725 DOI: 10.1021/ja0587796  1
2006 Figueroa JS, Piro NA, Clough CR, Cummins CC. A nitridoniobium(V) reagent that effects acid chloride to organic nitrile conversion: synthesis via heterodinuclear (Nb/Mo) dinitrogen cleavage, mechanistic insights, and recycling. Journal of the American Chemical Society. 128: 940-50. PMID 16417385 DOI: 10.1021/ja056408j  1
2006 Cummins CC. Terminal, anionic carbide, nitride, and phosphide transition-metal complexes as synthetic entries to low-coordinate phosphorus derivatives. Angewandte Chemie (International Ed. in English). 45: 862-70. PMID 16385612 DOI: 10.1002/anie.200503327  1
2005 Stephens FH, Johnson MJ, Cummins CC, Kryatova OP, Kryatov SV, Rybak-Akimova EV, McDonough JE, Hoff CD. Mechanism of white phosphorus activation by three-coordinate molybdenum(III) complexes: a thermochemical, kinetic, and quantum chemical investigation. Journal of the American Chemical Society. 127: 15191-200. PMID 16248661 DOI: 10.1021/ja054253+  1
2005 Mendiratta A, Cummins CC. Heterobimetallic reductive cross-coupling of benzonitrile with carbon dioxide, pyridine, and benzophenone. Inorganic Chemistry. 44: 7319-21. PMID 16212356 DOI: 10.1021/ic051320s  1
2005 Mendiratta A, Figueroa JS, Cummins CC. Synthesis of a four-coordinate titanium(IV) oxoanion via deprotonation and decarbonylation of complexed formate. Chemical Communications (Cambridge, England). 3403-5. PMID 15997278 DOI: 10.1039/b504492h  1
2005 Figueroa JS, Cummins CC. Triatomic EP2 triangles (E=Ge, Sn, Pb) as mu2:eta3,eta3-bridging ligands. Angewandte Chemie (International Ed. in English). 44: 4592-6. PMID 15991199 DOI: 10.1002/anie.200500707  1
2005 McDonough JE, Weir JJ, Carlson MJ, Hoff CD, Kryatova OP, Rybak-Akimova EV, Clough CR, Cummins CC. Solution calorimetric and stopped-flow kinetic studies of the reaction of *Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and theoretical estimates of the Se-Se, Te-Te, H-Se, and H-Te bond strengths. Inorganic Chemistry. 44: 3127-36. PMID 15847418 DOI: 10.1021/ic048321p  1
2005 Murahashi T, Clough CR, Figueroa JS, Cummins CC. A ligand composed of dinitrogen and methyldiphenylphosphane in a cationic molybdenum complex. Angewandte Chemie (International Ed. in English). 44: 2560-3. PMID 15782376 DOI: 10.1002/anie.200463057  1
2004 Figueroa JS, Cummins CC. Phosphaalkynes from acid chlorides via P for O(Cl) metathesis: a recyclable niobium phosphide (P(3-)) reagent that effects C-P triple-bond formation. Journal of the American Chemical Society. 126: 13916-7. PMID 15506740 DOI: 10.1021/ja0461522  1
2004 Soo HS, Figueroa JS, Cummins CC. A homoleptic molybdenum(IV) enolate complex: synthesis, molecular and electronic structure, and NCN group transfer to form a terminal cyanoimide of molybdenum(VI). Journal of the American Chemical Society. 126: 11370-6. PMID 15355120 DOI: 10.1021/ja0472533  1
2004 Clough CR, Greco JB, Figueroa JS, Diaconescu PL, Davis WM, Cummins CC. Organic nitriles from acid chlorides: an isovalent N for (O)CL exchange reaction mediated by a tungsten nitride complex. Journal of the American Chemical Society. 126: 7742-3. PMID 15212498 DOI: 10.1021/ja0492438  1
2004 Figueroa JS, Cummins CC. Diorganophosphanylphosphinidenes as complexed ligands: synthesis via an anionic terminal phosphide of niobium. Angewandte Chemie (International Ed. in English). 43: 984-8. PMID 14966886 DOI: 10.1002/anie.200352779  1
2003 Mendiratta A, Cummins CC, Kryatova OP, Rybak-Akimova EV, McDonough JE, Hoff CD. Molybdenum chalcogenobenzimidato complexes: radical synthesis and nitrile extrusion via beta-EPh (E = S, Se, and Te) elimination. Inorganic Chemistry. 42: 8621-3. PMID 14686837 DOI: 10.1021/ic035077d  1
2003 Stephens FH, Figueroa JS, Diaconescu PL, Cummins CC. Molybdenum-phosphorus triple bond stabilization by ancillary alkoxide ligation: synthesis and structure of a terminal phosphide tris-1-methylcyclohexanoxide complex. Journal of the American Chemical Society. 125: 9264-5. PMID 12889934 DOI: 10.1021/ja0354317  1
2003 Figueroa JS, Cummins CC. The niobaziridine-hydride functional group: synthesis and divergent reactivity. Journal of the American Chemical Society. 125: 4020-1. PMID 12670202 DOI: 10.1021/ja028446y  1
2002 Brask JK, Durà-Vilà V, Diaconescu PL, Cummins CC. Vanadium nitride functionalization and denitrogenation by carbon disulfide and dioxide. Chemical Communications (Cambridge, England). 902-3. PMID 12123036  1
2002 Diaconescu PL, Cummins CC. Diuranium inverted sandwiches involving naphthalene and cyclooctatetraene. Journal of the American Chemical Society. 124: 7660-1. PMID 12083911 DOI: 10.1021/ja026200n  1
2002 Agapie T, Diaconescu PL, Cummins CC. Methine (CH) transfer via a chlorine atom abstraction/benzene-elimination strategy: molybdenum methylidyne synthesis and elaboration to a phosphaisocyanide complex. Journal of the American Chemical Society. 124: 2412-3. PMID 11890770 DOI: 10.1021/ja017278r  1
2001 Brask JK, Fickes MG, Sangtrirutnugul P, Durà-Villà V, Odom AL, Cummins CC. Niobium and vanadium iminophosphinimide complexes Chemical Communications. 1676-1677. PMID 12240439  1
2001 Cherry JP, Stephens FH, Johnson MJ, Diaconescu PL, Cummins CC. Terminal phosphide and dinitrogen molybdenum compounds obtained from pnictide-bridged precursors. Inorganic Chemistry. 40: 6860-2. PMID 11754262 DOI: 10.1021/ic015592g  1
2001 Cherry JP, Johnson AR, Baraldo LM, Tsai YC, Cummins CC, Kryatov SV, Rybak-Akimova EV, Capps KB, Hoff CD, Haar CM, Nolan SP. On the origin of selective nitrous oxide N-N bond cleavage by three-coordinate molybdenum(III) complexes. Journal of the American Chemical Society. 123: 7271-86. PMID 11472154 DOI: 10.1021/ja0031063  1
2001 Greco JB, Peters JC, Baker TA, Davis WM, Cummins CC, Wu G. Atomic carbon as a terminal ligand: studies of a carbidomolybdenum anion featuring solid-state (13)C NMR data and proton-transfer self-exchange kinetics. Journal of the American Chemical Society. 123: 5003-13. PMID 11457328 DOI: 10.1021/ja003548e  1
2001 Barybin MV, Diaconescu PL, Cummins CC. Coordination chemistry of a chelating amidoximato ligand. Inorganic Chemistry. 40: 2892-7. PMID 11375709 DOI: 10.1021/ic0100370  1
2000 Agapie T, Odom AL, Cummins CC. In pursuit of the molybdenum(III) tris(thiolate) fragment: unusual structure of a dimolybdenum mu-nitrido complex. Inorganic Chemistry. 39: 174-9. PMID 11272522 DOI: 10.1021/ic9904891  1
2000 Meyer K, Mindiola DJ, Baker TA, Davis WM, Cummins CC. Uranium Hexakisamido Complexes This work was supported by the National Science Foundation (CAREER Award CHE-9501992), the Alfred P. Sloan Foundation, the National Science Board (1998 Alan T. Waterman award to C.C.C.), and the Packard Foundation. K.M. thanks the Deutsche Forschungsgemeinschaft for a postdoctoral fellowship. Angewandte Chemie (International Ed. in English). 39: 3063-3066. PMID 11028031 DOI: 10.1002/1521-3773(20000901)39:17<3063::AID-ANIE3063>3.0.CO;2-0  1
1999 Odom AL, Mindiola DJ, Cummins CC. A Nucleophilic Chromium(V) Dioxo Radical Anion. Inorganic Chemistry. 38: 3290-3295. PMID 11671062  1
1998 Mindiola DJ, Cummins CC. Deprotonated 2,3:5,6-Dibenzo-7- aza bicyclo[2.2.1]hepta-2,5-diene as a Nitrido Nitrogen Source by Anthracene Elimination: Synthesis of an Iodide(nitride)chromium(VI) Complex. Angewandte Chemie (International Ed. in English). 37: 945-947. PMID 29711483 DOI: 10.1002/(SICI)1521-3773(19980420)37:7<945::AID-ANIE945>3.0.CO;2-X  1
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