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Daniel A. Singleton - Publications

Affiliations: 
Texas A & M University, College Station, TX, United States 
Area:
organic, organometallic, and bioorganic reaction mechanisms
Website:
http://www.chem.tamu.edu/faculty/faculty_detail.php?ID=45

107 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Kuan KY, Singleton DA. Isotope Effects and the Mechanism of Photoredox-Promoted [2 + 2] Cycloadditions of Enones. The Journal of Organic Chemistry. PMID 33890775 DOI: 10.1021/acs.joc.1c00099  0.36
2020 Roytman VA, Singleton DA. Solvation Dynamics and the Nature of Reaction Barriers and Ion-Pair Intermediates in Carbocation Reactions. Journal of the American Chemical Society. PMID 32578428 DOI: 10.1021/Jacs.0C06295  0.804
2019 Roytman VA, Jin S, Nguyen VT, Nguyen VD, Haug GC, Larionov OV, Singleton DA. Bond Memory in Dynamically-Determined Stereoselectivity. Journal of the American Chemical Society. PMID 31852185 DOI: 10.1021/Jacs.9B12227  0.777
2019 Roytman VA, Singleton DA. Comment on "Activation of methane to CH: A selective industrial route to methanesulfonic acid". Science (New York, N.Y.). 364. PMID 31073043 DOI: 10.1126/Science.Aax7083  0.753
2018 Kurouchi H, Singleton DA. Labelling and determination of the energy in reactive intermediates in solution enabled by energy-dependent reaction selectivity. Nature Chemistry. 10: 237-241. PMID 29359761 DOI: 10.1038/Nchem.2907  0.435
2017 Bailey JO, Singleton DA. Failure and Redemption of Statistical and Nonstatistical Rate Theories in the Hydroboration of Alkenes. Journal of the American Chemical Society. PMID 29029560 DOI: 10.1021/Jacs.7B07175  0.375
2017 Issaian A, Faizi DJ, Bailey JO, Mayer P, Berionni G, Singleton DA, Blum SA. Mechanistic Studies of Formal Thioboration Reactions of Alkynes. The Journal of Organic Chemistry. PMID 28671461 DOI: 10.1021/Acs.Joc.7B01500  0.469
2017 Chattopadhyay B, Dannatt JE, Andújar-de Sanctis IL, Gore KA, Maleczka RE, Singleton DA, Smith MR. Ir-Catalyzed ortho-Borylation of Phenols Directed by Substrate-Ligand Electrostatic Interactions: A Combined Experimental/in Silico Strategy for Optimizing Weak Interactions. Journal of the American Chemical Society. PMID 28453268 DOI: 10.1021/Jacs.7B02232  0.358
2017 Aziz HR, Singleton DA. Concert along the Edge. Dynamics and the Nature of the Border between General and Specific Acid-Base Catalysis. Journal of the American Chemical Society. PMID 28378578 DOI: 10.1021/Jacs.7B02148  0.441
2016 Nieves-Quinones Y, Singleton DA. Dynamics and the Regiochemistry of Nitration of Toluene. Journal of the American Chemical Society. PMID 27794598 DOI: 10.1021/Jacs.6B07328  0.432
2016 Kurouchi H, Andújar-de Sanctis IL, Singleton DA. Controlling Selectivity by Controlling Energy Partitioning in a Thermal Reaction in Solution. Journal of the American Chemical Society. PMID 27764943 DOI: 10.1021/Jacs.6B09052  0.416
2016 Patel A, Chen Z, Yang Z, Gutierrez O, Liu HW, Houk KN, Singleton DA. Dynamically complex [6+4] and [4+2] cycloadditions in the biosynthesis of spinosyn A. Journal of the American Chemical Society. PMID 26909570 DOI: 10.1021/Jacs.6B00017  0.446
2015 Biswas B, Singleton DA. Controlling Selectivity by Controlling the Path of Trajectories. Journal of the American Chemical Society. PMID 26549733 DOI: 10.1021/Jacs.5B08635  0.377
2015 Plata RE, Singleton DA. A case study of the mechanism of alcohol-mediated Morita Baylis-Hillman reactions. The importance of experimental observations. Journal of the American Chemical Society. 137: 3811-26. PMID 25714789 DOI: 10.1021/Ja5111392  0.465
2014 Chen Z, Nieves-Quinones Y, Waas JR, Singleton DA. Isotope effects, dynamic matching, and solvent dynamics in a Wittig reaction. Betaines as bypassed intermediates. Journal of the American Chemical Society. 136: 13122-5. PMID 25208686 DOI: 10.1021/Ja506497B  0.534
2014 Biswas B, Collins SC, Singleton DA. Dynamics and a unified understanding of competitive [2,3]- and [1,2]-sigmatropic rearrangements based on a study of ammonium ylides. Journal of the American Chemical Society. 136: 3740-3. PMID 24579740 DOI: 10.1021/Ja4128289  0.408
2012 Andujar-De Sanctis IL, Singleton DA. Racing carbon atoms. Atomic motion reaction coordinates and structural effects on Newtonian kinetic isotope effects. Organic Letters. 14: 5238-41. PMID 23025278 DOI: 10.1021/Ol302389F  0.454
2012 Roosen PC, Kallepalli VA, Chattopadhyay B, Singleton DA, Maleczka RE, Smith MR. Outer-sphere direction in iridium C-H borylation. Journal of the American Chemical Society. 134: 11350-3. PMID 22703452 DOI: 10.1021/Ja303443M  0.371
2012 Bogle XS, Singleton DA. Dynamic origin of the stereoselectivity of a nucleophilic substitution reaction. Organic Letters. 14: 2528-31. PMID 22540965 DOI: 10.1021/Ol300817A  0.811
2012 Vetticatt MJ, Singleton DA. Isotope effects and heavy-atom tunneling in the Roush allylboration of aldehydes. Organic Letters. 14: 2370-3. PMID 22506639 DOI: 10.1021/Ol300789A  0.796
2012 Gonzalez-James OM, Kwan EE, Singleton DA. Entropic intermediates and hidden rate-limiting steps in seemingly concerted cycloadditions. Observation, prediction, and origin of an isotope effect on recrossing. Journal of the American Chemical Society. 134: 1914-7. PMID 22229840 DOI: 10.1021/Ja208779K  0.521
2011 Bogle XS, Singleton DA. Isotope-induced desymmetrization can mimic isotopic perturbation of equilibria. On the symmetry of bromonium ions and hydrogen bonds. Journal of the American Chemical Society. 133: 17172-5. PMID 21972898 DOI: 10.1021/Ja2084288  0.781
2011 Quijano LM, Singleton DA. Competition between reaction and intramolecular energy redistribution in solution: observation and nature of nonstatistical dynamics in the ozonolysis of vinyl ethers. Journal of the American Chemical Society. 133: 13824-7. PMID 21812422 DOI: 10.1021/Ja2043497  0.798
2010 Vanchura BA, Preshlock SM, Roosen PC, Kallepalli VA, Staples RJ, Maleczka RE, Singleton DA, Smith MR. Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents. Chemical Communications (Cambridge, England). 46: 7724-6. PMID 20852803 DOI: 10.1039/C0Cc02041A  0.389
2010 Gonzalez-James OM, Zhang X, Datta A, Hrovat DA, Borden WT, Singleton DA. Experimental evidence for heavy-atom tunneling in the ring-opening of cyclopropylcarbinyl radical from intramolecular 12C/13C kinetic isotope effects. Journal of the American Chemical Society. 132: 12548-9. PMID 20722415 DOI: 10.1021/Ja1055593  0.493
2010 Gonzalez-James OM, Singleton DA. Isotope effect, mechanism, and origin of catalysis in the decarboxylation of mandelylthiamin. Journal of the American Chemical Society. 132: 6896-7. PMID 20433168 DOI: 10.1021/Ja101775S  0.456
2009 Wang Z, Hirschi JS, Singleton DA. Recrossing and dynamic matching effects on selectivity in a Diels-Alder reaction. Angewandte Chemie (International Ed. in English). 48: 9156-9. PMID 19876990 DOI: 10.1002/Anie.200903293  0.795
2009 Kelly KK, Hirschi JS, Singleton DA. Newtonian kinetic isotope effects. Observation, prediction, and origin of heavy-atom dynamic isotope effects. Journal of the American Chemical Society. 131: 8382-3. PMID 19485324 DOI: 10.1021/Ja9031083  0.821
2009 Oyola Y, Singleton DA. Dynamics and the failure of transition state theory in alkene hydroboration. Journal of the American Chemical Society. 131: 3130-1. PMID 19215077 DOI: 10.1021/Ja807666D  0.759
2009 Hirschi JS, Takeya T, Hang C, Singleton DA. Transition-state geometry measurements from (13)c isotope effects. The experimental transition state for the epoxidation of alkenes with oxaziridines. Journal of the American Chemical Society. 131: 2397-403. PMID 19146405 DOI: 10.1021/Ja8088636  0.81
2008 Thomas JB, Waas JR, Harmata M, Singleton DA. Control elements in dynamically determined selectivity on a bifurcating surface. Journal of the American Chemical Society. 130: 14544-55. PMID 18847260 DOI: 10.1021/Ja802577V  0.669
2007 Soloshonok VA, Ueki H, Yasumoto M, Mekala S, Hirschi JS, Singleton DA. Phenomenon of optical self-purification of chiral non-racemic compounds. Journal of the American Chemical Society. 129: 12112-3. PMID 17850147 DOI: 10.1021/Ja065603A  0.685
2007 Christian CF, Takeya T, Szymanski MJ, Singleton DA. Isotope effects and the mechanism of epoxidation of cyclohexenone with tert-butyl hydroperoxide. The Journal of Organic Chemistry. 72: 6183-9. PMID 17608437 DOI: 10.1021/Jo070777B  0.791
2007 Ralph EC, Hirschi JS, Anderson MA, Cleland WW, Singleton DA, Fitzpatrick PF. Insights into the mechanism of flavoprotein-catalyzed amine oxidation from nitrogen isotope effects on the reaction of N-methyltryptophan oxidase. Biochemistry. 46: 7655-64. PMID 17542620 DOI: 10.1021/Bi700482H  0.766
2006 Ussing BR, Hang C, Singleton DA. Dynamic effects on the periselectivity, rate, isotope effects, and mechanism of cycloadditions of ketenes with cyclopentadiene. Journal of the American Chemical Society. 128: 7594-607. PMID 16756316 DOI: 10.1021/Ja0606024  0.715
2005 Bekele T, Christian CF, Lipton MA, Singleton DA. "Concerted" transition state, stepwise mechanism. Dynamics effects in C2-C6 enyne allene cyclizations. Journal of the American Chemical Society. 127: 9216-23. PMID 15969600 DOI: 10.1021/Ja0508673  0.839
2005 Singleton DA, Wang Z. Isotope effects and the nature of enantioselectivity in the shi epoxidation. The importance of asynchronicity. Journal of the American Chemical Society. 127: 6679-85. PMID 15869289 DOI: 10.1021/Ja0435788  0.627
2005 Nowlan DT, Singleton DA. Mechanism and origin of enantioselectivity in the Rh2(OAc)(DPTI)3-catalyzed cyclopropenation of alkynes. Journal of the American Chemical Society. 127: 6190-1. PMID 15853322 DOI: 10.1021/Ja0504441  0.822
2005 Hirschi J, Singleton DA. The normal range for secondary Swain-Schaad exponents without tunneling or kinetic complexity. Journal of the American Chemical Society. 127: 3294-5. PMID 15755143 DOI: 10.1021/Ja0430752  0.767
2005 Ussing BR, Singleton DA. Isotope effects, dynamics, and the mechanism of solvolysis of aryldiazonium cations in water. Journal of the American Chemical Society. 127: 2888-99. PMID 15740124 DOI: 10.1021/Ja043918P  0.509
2005 Singleton DA, Wang Z. Isotope effects and the mechanism of deoxygenation of epoxides with dichlorocarbene Tetrahedron Letters. 46: 2033-2036. DOI: 10.1016/J.Tetlet.2005.01.153  0.602
2005 Singleton DA, Christian CF. Isotope effects and the mechanism of palladium-catalyzed allylic alkylation Tetrahedron Letters. 46: 1631-1634. DOI: 10.1016/J.Tetlet.2005.01.088  0.826
2005 Singleton DA, Wang Z. Isotope effects and the mechanism of fragmentation of epoxy imino-1,3,4-oxadiazolines Tetrahedron Letters. 46: 819-822. DOI: 10.1016/J.Tetlet.2004.12.008  0.616
2004 Vo LK, Singleton DA. Isotope effects and the nature of stereo- and regioselectivity in hydroaminations of vinylarenes catalyzed by palladium(ii)-diphosphine complexes. Organic Letters. 6: 2469-72. PMID 15228306 DOI: 10.1021/Ol049137A  0.53
2003 Nowlan DT, Gregg TM, Davies HM, Singleton DA. Isotope effects and the nature of selectivity in rhodium-catalyzed cyclopropanations. Journal of the American Chemical Society. 125: 15902-11. PMID 14677982 DOI: 10.1021/Ja036025Q  0.842
2003 Boren B, Hirschi JS, Reibenspies JH, Tallant MD, Singleton DA, Sulikowski GA. Exo-selective Diels-Alder reactions of vinylazepines. Origin of divergent stereoselectivity in Diels-Alder reactions of vinylazepines, vinylpiperideines, and vinylcycloalkenes. The Journal of Organic Chemistry. 68: 8991-5. PMID 14604372 DOI: 10.1021/Jo034462H  0.773
2003 Singleton DA, Vo LK. A few molecules can control the enantiomeric outcome. Evidence supporting absolute asymmetric synthesis using the Soai asymmetric autocatalysis. Organic Letters. 5: 4337-9. PMID 14601994 DOI: 10.1021/Ol035605P  0.403
2003 Singleton DA, Hang C, Szymanski MJ, Meyer MP, Leach AG, Kuwata KT, Chen JS, Greer A, Foote CS, Houk KN. Mechanism of ene reactions of singlet oxygen. A two-step no-intermediate mechanism. Journal of the American Chemical Society. 125: 1319-28. PMID 12553834 DOI: 10.1021/Ja027225P  0.836
2003 Singleton DA, Hang C, Szymanski MJ, Greenwald EE. A new form of kinetic isotope effect. Dynamic effects on isotopic selectivity and regioselectivity. Journal of the American Chemical Society. 125: 1176-7. PMID 12553813 DOI: 10.1021/Ja027221K  0.808
2003 Singleton DA, Nowlan DT, Jahed N, Matyjaszewski K. Isotope effects and the mechanism of atom transfer radical polymerization Macromolecules. 36: 8609-8616. DOI: 10.1021/Ma035310R  0.809
2002 Singleton DA, Wang Y, Yang HW, Romo D. Mechanism and origin of stereoselectivity in Lewis acid catalyzed [2 + 2] cycloadditions of ketenes with aldehydes. Angewandte Chemie (International Ed. in English). 41: 1572-5. PMID 19750669 DOI: 10.1002/1521-3773(20020503)41:9<1572::Aid-Anie1572>3.0.Co;2-B  0.333
2002 Saettel NJ, Wiest O, Singleton DA, Meyer MP. Isotope effects and the mechanism of an electron-transfer-catalyzed Diels-Alder reaction. Journal of the American Chemical Society. 124: 11552-9. PMID 12236770 DOI: 10.1021/Ja026924Z  0.501
2002 Singleton DA, Vo LK. Enantioselective synthesis without discrete optically active additives. Journal of the American Chemical Society. 124: 10010-1. PMID 12188664 DOI: 10.1021/Ja027129O  0.345
2001 Webster CE, Singleton DA, Szymanski MJ, Hall MB, Zhao C, Jia G, Lin Z. Minimum energy structure of hydridotris(pyrazolyl)borato iridium(V) tetrahydride is not a C(3upsilon) capped octahedron. Journal of the American Chemical Society. 123: 9822-9. PMID 11583544 DOI: 10.1021/Ja001233T  0.789
2001 Singleton DA, Schulmeier BE, Hang C, Thomas AA, Leung SW, Merrigan SR. Isotope effects and the distinction between synchronous, asynchronous, and stepwise Diels-Alder reactions Tetrahedron. 57: 5149-5160. DOI: 10.1016/S0040-4020(01)00354-4  0.697
2000 Singleton DA, Hang C. Isotope effects and the mechanism of allylic hydroxylation of alkenes with selenium dioxide Journal of Organic Chemistry. 65: 7554-7560. PMID 11076614 DOI: 10.1021/Jo000922K  0.666
2000 Singleton DA, Hang C. 13C and 2H kinetic isotope effects and the mechanism of Lewis acid- catalyzed ene reactions of formaldehyde Journal of Organic Chemistry. 65: 895-899. PMID 10814025 DOI: 10.1021/Jo9917590  0.673
2000 Singleton DA, Merrigan SR, Kim BJ, Beak P, Phillips LM, Lee JK. 13C kinetic isotope effects and the mechanism of the uncatalyzed decarboxylation of orotic acid Journal of the American Chemical Society. 122: 3296-3300. DOI: 10.1021/Ja993392M  0.426
2000 Frantz DE, Singleton DA. Isotope effects and the mechanism of chlorotrimethylsilane-mediated addition of cuprates to enones Journal of the American Chemical Society. 122: 3288-3295. DOI: 10.1021/Ja993373C  0.729
2000 Singleton DA, Merrigan SR. Resolution of conflicting mechanistic observations in ester aminolysis. A warning on the qualitative prediction of isotope effects for reactive intermediates [16] Journal of the American Chemical Society. 122: 11035-11036. DOI: 10.1021/ja005519+  0.304
1999 Frantz DE, Singleton DA. Carbometalations of simple alkenes with allyldibromoborane Organic Letters. 1: 485-486. PMID 10822588 DOI: 10.1021/Ol990673Q  0.673
1999 Merrigan SR, Singleton DA. 13C and 2H kinetic isotope effects and the mechanism of bromination of 1-pentene under synthetic conditions Organic Letters. 1: 327-329. PMID 10822570 DOI: 10.1021/Ol990659D  0.477
1999 Singleton DA, Hang C. Isotope effects and the mechanism of triazolinedione ene reactions. Aziridinium imides are innocent bystanders Journal of the American Chemical Society. 121: 11885-11893. DOI: 10.1021/ja9933339  0.612
1999 Meyer MP, DelMonte AJ, Singleton DA. Reinvestigation of the isotope effects for the Claisen and aromatic claisen rearrangements: The nature of the Claisen transition states Journal of the American Chemical Society. 121: 10865-10874. DOI: 10.1021/Ja992372H  0.5
1999 Singleton DA, Szymanski MJ. Simultaneous determination of intermolecular and intramolecular 13C and 2H kinetic isotope effects at natural abundance [5] Journal of the American Chemical Society. 121: 9455-9456. DOI: 10.1021/Ja992016Z  0.798
1999 Singleton DA, Schulmeier BE. Evidence for a concerted mechanism in a palladium trimethylenemethane cycloaddition Journal of the American Chemical Society. 121: 9313-9317. DOI: 10.1021/Ja9919229  0.489
1999 Keating AE, Merrigan SR, Singleton DA, Houk KN. Experimental proof of the non-least-motion cycloadditions of dichlorocarbene to alkenes: Kinetic isotope effects and quantum mechanical transition states Journal of the American Chemical Society. 121: 3933-3938. DOI: 10.1021/Ja981427X  0.335
1999 Singleton DA, Hang C. Isotope effects and the experimental transition state for a prototypical thermal ene reaction Tetrahedron Letters. 40: 8939-8943. DOI: 10.1016/S0040-4039(99)01923-1  0.714
1999 Singleton DA, Merrigan SR, Beno BR, Houk KN. Isotope effects for lewis acid catalyzed Diels-Alder reactions. The experimental transition state Tetrahedron Letters. 40: 5817-5821. DOI: 10.1016/S0040-4039(99)01148-X  0.552
1999 Merrigan SR, Le Gloahec VN, Smith JA, Barton DHR, Singleton DA. Separation of the primary and secondary kinetic isotope effects at a reactive center using starting material reactivities. Application to the FeCl3-catalyzed oxidation of C-H bonds with tert-butyl hydroperoxide Tetrahedron Letters. 40: 3847-3850. DOI: 10.1016/S0040-4039(99)00637-1  0.441
1999 Singleton DA, Merrigan SR, Thomas AA. Stereochemical labeling at natural abundance. Stereochemistry, isotope effects, and mechanism of the Diels-Alder reaction of hexachlorocyclopentadiene with ethyl vinyl ether Tetrahedron Letters. 40: 639-642. DOI: 10.1016/S0040-4039(98)02508-8  0.492
1998 Francisco WA, Abu-Soud HM, DelMonte AJ, Singleton DA, Baldwin TO, Raushel FM. Deuterium kinetic isotope effects and the mechanism of the bacterial luciferase reaction Biochemistry. 37: 2596-2606. PMID 9485410 DOI: 10.1021/Bi972266X  0.512
1997 Leung SW, Singleton DA. Reactions of Alkynyldihaloboranes with 1,3-Dienes. 1,4-Alkynylborations and Stepwise Diels-Alder Reactions. The Journal of Organic Chemistry. 62: 1955-1960. PMID 11671495 DOI: 10.1021/Jo961892H  0.461
1997 DelMonte AJ, Haller J, Houk KN, Sharpless KB, Singleton DA, Strassner T, Thomas AA. Experimental and theoretical kinetic isotope effects for asymmetric dihydroxylation. Evidence supporting a rate-limiting '(3+2)' cycloaddition Journal of the American Chemical Society. 119: 9907-9908. DOI: 10.1021/Ja971650E  0.406
1997 Singleton DA, Merrigan SR, Liu J, Houk KN. Experimental geometry of the epoxidation transition state Journal of the American Chemical Society. 119: 3385-3386. DOI: 10.1021/Ja963656U  0.356
1997 Frantz DE, Singleton DA, Snyder JP. 13C kinetic isotope effects for the addition of lithium dibutylcuprate to cyclohexenone. Reductive elimination is rate-determining Journal of the American Chemical Society. 119: 3383-3384. DOI: 10.1021/Ja9636348  0.703
1997 Singleton DA, Leung SW, Martinez JP, Lee YK. Catalysis by temporary covalent activation. A novel catalysis of unactivated Diels-Alder reactions Tetrahedron Letters. 38: 3163-3166. DOI: 10.1016/S0040-4039(97)00584-4  0.437
1997 Singleton DA, Leung SW. In situ formation of alkenyl- and alkynylboranes for Diels-Alder reactions by boron-silicon exchange with alkenyl- and alkynylsilanes Journal of Organometallic Chemistry. 544: 157-161. DOI: 10.1016/S0022-328X(97)00001-6  0.397
1996 Singleton DA, Waller SC, Zhang Z, Frantz DE, Leung SW. Allylboration of alkenes with allyldihaloboranes Journal of the American Chemical Society. 118: 9986-9987. DOI: 10.1021/Ja961616K  0.677
1996 Beno BR, Houk KN, Singleton DA. Synchronous or asynchronous? An 'experimental' transition state from a direct comparison of experimental and theoretical kinetic isotope effects for a Diels-Alder reaction Journal of the American Chemical Society. 118: 9984-9985. DOI: 10.1021/Ja9615278  0.493
1995 Singleton DA, Thomas AA. High-precision simultaneous determination of multiple small kinetic isotope effects at natural abundance Journal of the American Chemical Society. 117: 9357-9358. DOI: 10.1021/Ja00141A030  0.359
1995 Singleton DA, Lee YK. Intramolecular Diels-Alder reactions of vinylboranes. A highly stereoselective two-step decalin synthesis Tetrahedron Letters. 36: 3473-3476. DOI: 10.1016/0040-4039(95)00568-W  0.431
1994 Huval CC, Singleton DA. Versatile [3 + 2] methylenecyclopentane annulations of unactivated and electron-rich olefins with [(trimethylsilyl)methylene]cyclopropanedicarboxylates Journal of Organic Chemistry. 59: 2020-2024. DOI: 10.1021/Jo00087A015  0.308
1994 Singleton DA, Redman AM. Vinylboranes as trans-dihydroxyethylene equivalents for diels-alder reactions Tetrahedron Letters. 35: 509-512. DOI: 10.1016/S0040-4039(00)75824-2  0.422
1994 Huval CC, Singleton DA. A conjunctive diquinane synthesis using a free-radical catalyzed intramolecular [3 + 2] methylenecyclopentane annulation Tetrahedron Letters. 35: 689-690. DOI: 10.1016/S0040-4039(00)75791-1  0.332
1993 Singleton DA, Kim K, Martinez JP. Diels-Alder reactions of 2-Alkenylboranes and cis-1-alkenylboranes. Anomalous selectivity that allows a choice of regiochemistry Tetrahedron Letters. 34: 3071-3074. DOI: 10.1016/S0040-4039(00)93382-3  0.387
1993 Huval CC, Singleton DA. Direct free-radical substitutions on allyl and vinyl halides using alkyl halides/hexabutylditin Tetrahedron Letters. 34: 3041-3042. DOI: 10.1016/S0040-4039(00)93373-2  0.365
1992 Singleton DA, Martinez JP, Ndip GM. In situ formation of vinylboranes for use in Diels-Alder reactions. An easy one-pot Diels-Alder synthesis of cyclohexenols Journal of Organic Chemistry. 57: 5768-5771. DOI: 10.1021/Jo00047A037  0.394
1992 Singleton DA, Leung SW. An unprecedented electronic preference for the "meta" product in Diels-Alder reactions of ethynyldialkylboranes. [(Trimethylsilyl)ethynyl]-9-BBN as a reactive and versatile dienophile Journal of Organic Chemistry. 57: 4796-4797. DOI: 10.1021/Jo00044A008  0.489
1992 Klimko PG, Singleton DA. Silyl group-transfer-mediated serial Michael additions Journal of Organic Chemistry. 57: 1733-1740. DOI: 10.1021/Jo00032A026  0.438
1992 Singleton DA. A [4 + 3] transition state for a [4 + 2] cycloaddition. A new secondary orbital interaction in Diels-Alder reactions Journal of the American Chemical Society. 114: 6563-6564. DOI: 10.1021/Ja00042A049  0.404
1992 Singleton DA, Martinez JP, Watson JV. Vinylboranes are omniphilic dienophiles. Some unusual and useful properties of vinylboranes in diels-alder reactions Tetrahedron Letters. 33: 1017-1020. DOI: 10.1016/S0040-4039(00)91848-3  0.418
1992 Singleton DA, Martinez JP, Watson JV, Ndip GM. Tuning of Vinylborane Dienophilicity. Optimization of Reactivity, Regioselectivity, endo-Stereoselectivity, and Reagent Stability Tetrahedron. 48: 5831-5838. DOI: 10.1016/S0040-4020(01)90174-7  0.398
1991 Gassman PG, Singleton DA, Kagechika H. The unsymmetrical 1,1,3,3-tetramethylallyl cation Journal of the American Chemical Society. 113: 6271-6272. DOI: 10.1021/Ja00016A054  0.456
1991 Singleton DA, Martinez JP. 2-Trimethylsilylvinylboranes: highly reactive and selective diels-alder equivalents of 2-trimethylsilylvinyl alcohol and acetylene Tetrahedron Letters. 32: 7365-7368. DOI: 10.1016/0040-4039(91)80108-I  0.315
1991 Gassman PG, Singleton DA, Kagechika H. An unsymmetrical 1,1,3,3-tetramethylallyl cation Journal of the American Chemical Society. 113: 6271-6272.  0.385
1990 Singleton DA, Church KM. [3 + 2] Methylenecyclopentane annulations of unactivated and electron-rich olefins with 2-(phenylsulfonyl)-1-methylenecyclopropanes Journal of Organic Chemistry. 55: 4780-4782. DOI: 10.1021/Jo00303A002  0.389
1990 Singleton DA, Martinez JP. High reactivity, regioselectivity, and endo-stereoselectivity of vinyl boranes in Diels-Alder reactions Journal of the American Chemical Society. 112: 7423-7424. DOI: 10.1021/Ja00176A069  0.418
1990 Singleton DA, Church KM, Lucero MJ. Catalytic stereocontrol of a radical cyclization Tetrahedron Letters. 31: 5551-5554. DOI: 10.1016/S0040-4039(00)97894-8  0.349
1987 Gassman PG, Singleton DA, Wilwerding JJ, Chavan SP. Acrolein acetals as allyl cation precursors in the ionic diels-alder reaction Journal of the American Chemical Society. 109: 2182-2184. DOI: 10.1021/Ja00241A047  0.697
1987 Gassman PG, Singleton DA. Propargyl cations - powerful ambient temperature dienophiles in the diels-lder reaction Tetrahedron Letters. 28: 5969-5972. DOI: 10.1016/S0040-4039(00)96839-4  0.432
1986 Gassman PG, Singleton DA. Control of regiospecificity in ionic Diels-Alder reactions. The use of allylic alcohols and allylic ethers as precursors of dienophilic allyl cations Journal of Organic Chemistry. 51: 3075-3076. DOI: 10.1021/Jo00365A048  0.531
1985 Brunelle DJ, Singleton DA. Chemical reaction of polychlorinated biphenyls on soils with poly(ethylene glycol)/KOH Chemosphere. 14: 173-181. DOI: 10.1016/0045-6535(85)90096-7  0.321
1984 Brunelle DJ, Singleton DA. N-alkyl-4-(N′,N′-dialkylamino)pyridinium salts: thermally stable phase transfer catalysts for nucleophilic aromatic displacement Tetrahedron Letters. 25: 3383-3386. DOI: 10.1016/S0040-4039(01)91026-3  0.338
1984 Gassman PG, Singleton DA. Distinction between aminium cation radical and protic acid catalyzed "Diels-Alder" reactions Journal of the American Chemical Society. 106: 7993-7994. DOI: 10.1002/Chin.198515124  0.567
1984 Gassman PG, Singleton DA. Acid-catalyzed intramolecular "Diels-Alder" reactions. The cycloaddition of allyl cations to 1,3-dienes Journal of the American Chemical Society. 106: 6085-6086. DOI: 10.1002/Chin.198503188  0.578
1983 Brunelle DJ, Singleton DA. Destruction/removal of polychlorinated biphenyls from non-polar media. Reaction of PCB with poly (ethylene glycol)/KOH Chemosphere. 12: 183-196. DOI: 10.1016/0045-6535(83)90161-3  0.379
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