| Year |
Citation |
Score |
| 2023 |
Chambers RK, Weaver JD, Kim J, Hoar JL, Krska SW, White MC. A preparative small-molecule mimic of liver CYP450 enzymes in the aliphatic C-H oxidation of carbocyclic -heterocycles. Proceedings of the National Academy of Sciences of the United States of America. 120: e2300315120. PMID 37428920 DOI: 10.1073/pnas.2300315120 |
0.344 |
|
| 2022 |
Ali SZ, Budaitis BG, Fontaine DFA, Pace AL, Garwin JA, White MC. Allylic C-H amination cross-coupling furnishes tertiary amines by electrophilic metal catalysis. Science (New York, N.Y.). 376: 276-283. PMID 35420962 DOI: 10.1126/science.abn8382 |
0.341 |
|
| 2021 |
Ide T, Feng K, Dixon CF, Teng D, Clark JR, Han W, Wendell CI, Koch V, White MC. Late-Stage Intermolecular Allylic C-H Amination. Journal of the American Chemical Society. PMID 34514799 DOI: 10.1021/jacs.1c06335 |
0.444 |
|
| 2020 |
Feng K, Quevedo RE, Kohrt JT, Oderinde MS, Reilly U, White MC. Late-stage oxidative C(sp)-H methylation. Nature. PMID 32179876 DOI: 10.1038/S41586-020-2137-8 |
0.452 |
|
| 2020 |
Chambers RK, Zhao J, Delaney CP, White MC. Chemoselective Tertiary C-H Hydroxylation for Late-Stage Functionalization with Mn(PDP)/Chloroacetic Acid Catalysis. Advanced Synthesis & Catalysis. 362: 417-423. PMID 32165875 DOI: 10.1002/Adsc.201901472 |
0.551 |
|
| 2019 |
Ma R, Young J, Promontorio R, Dannheim FM, Pattillo CC, White MC. Synthesis of anti-1,3-Amino Alcohol Motifs via Pd(II)/SOX catalysis with the Capacity for Stereodivergence. Journal of the American Chemical Society. PMID 31140795 DOI: 10.1021/Jacs.9B02690 |
0.418 |
|
| 2018 |
Zhao J, Nanjo T, de Lucca EC, White MC. Chemoselective methylene oxidation in aromatic molecules. Nature Chemistry. PMID 30559371 DOI: 10.1038/S41557-018-0175-8 |
0.549 |
|
| 2018 |
White MC, Zhao J. Aliphatic C-H Oxidations for Late-Stage Functionalization. Journal of the American Chemical Society. PMID 30185033 DOI: 10.1021/Jacs.8B05195 |
0.582 |
|
| 2018 |
Liu W, Ali S, Ammann S, White MC. Asymmetric Allylic C-H Alkylation via Palladium(II)/cis-ArSOX Catalysis. Journal of the American Chemical Society. PMID 30091907 DOI: 10.1021/Jacs.8B05668 |
0.518 |
|
| 2018 |
Clark JR, Feng K, Sookezian A, White MC. Manganese-catalysed benzylic C(sp)-H amination for late-stage functionalization. Nature Chemistry. PMID 29713037 DOI: 10.1038/S41557-018-0020-0 |
0.591 |
|
| 2018 |
Ma R, White MC. C-H to C-N Cross-Coupling of Sulfonamides with Olefins. Journal of the American Chemical Society. PMID 29432000 DOI: 10.1021/Jacs.7B13492 |
0.508 |
|
| 2017 |
Nanjo T, de Lucca EC, White MC. Remote, Late-Stage Oxidation of Aliphatic C-H Bonds in Amide-Containing Molecules. Journal of the American Chemical Society. PMID 28921954 DOI: 10.1021/Jacs.7B07665 |
0.557 |
|
| 2017 |
Griffin JR, Wendell CI, Garwin JA, White MC. Catalytic C(sp3)-H Alkylation via an Iron Carbene Intermediate. Journal of the American Chemical Society. PMID 28898063 DOI: 10.1021/Jacs.7B07602 |
0.496 |
|
| 2016 |
Osberger TJ, Rogness DC, Kohrt JT, Stepan AF, White MC. Oxidative diversification of amino acids and peptides by small-molecule iron catalysis. Nature. PMID 27479323 DOI: 10.1038/Nature18941 |
0.477 |
|
| 2016 |
Ammann SE, Liu W, White MC. Enantioselective Allylic C-H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis. Angewandte Chemie (International Ed. in English). PMID 27376625 DOI: 10.1002/Anie.201603576 |
0.626 |
|
| 2016 |
Pattillo CC, Strambeanu II, Calleja P, Vermeulen NA, Mizuno T, White MC. Aerobic Linear Allylic C-H Amination: Overcoming Benzoquinone Inhibition. Journal of the American Chemical Society. PMID 26730458 DOI: 10.1021/Jacs.5B11294 |
0.695 |
|
| 2016 |
Paradine SM, Griffin JR, Zhao J, Petronico AL, Miller SM, White MC. ChemInform Abstract: A Manganese Catalyst for Highly Reactive Yet Chemoselective Intramolecular C(sp3)-H Amination. Cheminform. 47. DOI: 10.1002/chin.201621205 |
0.789 |
|
| 2015 |
Howell JM, Feng K, Clark JR, Trzepkowski LJ, White MC. Remote Oxidation of Aliphatic C-H Bonds in Nitrogen Containing Molecules. Journal of the American Chemical Society. PMID 26536374 DOI: 10.1021/Jacs.5B10299 |
0.565 |
|
| 2014 |
Osberger TJ, White MC. N-Boc amines to oxazolidinones via Pd(II)/bis-sulfoxide/Brønsted acid co-catalyzed allylic C-H oxidation. Journal of the American Chemical Society. 136: 11176-81. PMID 24999765 DOI: 10.1021/Ja506036Q |
0.536 |
|
| 2014 |
Ammann SE, Rice GT, White MC. Terminal olefins to chromans, isochromans, and pyrans via allylic C-H oxidation. Journal of the American Chemical Society. 136: 10834-7. PMID 24983326 DOI: 10.1021/Ja503322E |
0.6 |
|
| 2014 |
Howell JM, Liu W, Young AJ, White MC. General allylic C-H alkylation with tertiary nucleophiles. Journal of the American Chemical Society. 136: 5750-4. PMID 24641574 DOI: 10.1021/Ja500726E |
0.587 |
|
| 2013 |
Covell DJ, White MC. A C-H oxidation approach for streamlining synthesis of chiral polyoxygenated motifs. Tetrahedron. 69: 7771-7778. PMID 25013239 DOI: 10.1016/J.Tet.2013.05.012 |
0.827 |
|
| 2013 |
Gormisky PE, White MC. Catalyst-controlled aliphatic C-H oxidations with a predictive model for site-selectivity. Journal of the American Chemical Society. 135: 14052-5. PMID 24020940 DOI: 10.1021/Ja407388Y |
0.796 |
|
| 2013 |
Strambeanu II, White MC. Catalyst-controlled C-O versus C-N allylic functionalization of terminal olefins. Journal of the American Chemical Society. 135: 12032-7. PMID 23855956 DOI: 10.1021/Ja405394V |
0.539 |
|
| 2013 |
Delcamp JH, Gormisky PE, White MC. Oxidative Heck vinylation for the synthesis of complex dienes and polyenes. Journal of the American Chemical Society. 135: 8460-3. PMID 23701421 DOI: 10.1021/Ja402891M |
0.8 |
|
| 2013 |
Bigi MA, White MC. Terminal olefins to linear α,β-unsaturated ketones: Pd(II)/hypervalent iodine co-catalyzed Wacker oxidation-dehydrogenation. Journal of the American Chemical Society. 135: 7831-4. PMID 23672479 DOI: 10.1021/Ja402651Q |
0.519 |
|
| 2012 |
Bigi MA, Liu P, Zou L, Houk KN, White MC. Cafestol to Tricalysiolide B and Oxidized Analogues: Biosynthetic and Derivatization Studies Using Non-heme Iron Catalyst Fe(PDP). Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 23: 2768-2772. PMID 23585710 DOI: 10.1055/S-0032-1317708 |
0.432 |
|
| 2012 |
Bigi MA, Reed SA, White MC. Directed metal (oxo) aliphatic C-H hydroxylations: overriding substrate bias. Journal of the American Chemical Society. 134: 9721-6. PMID 22607637 DOI: 10.1021/Ja301685R |
0.55 |
|
| 2012 |
Jiang C, Covell DJ, Stepan AF, Plummer MS, White MC. Sequential allylic C-H amination/vinylic C-H arylation: a strategy for unnatural amino acid synthesis from α-olefins. Organic Letters. 14: 1386-9. PMID 22360547 DOI: 10.1021/Ol300063T |
0.834 |
|
| 2012 |
White MC. Chemistry. Adding aliphatic C-H bond oxidations to synthesis. Science (New York, N.Y.). 335: 807-9. PMID 22344434 DOI: 10.1126/Science.1207661 |
0.495 |
|
| 2012 |
Paradine SM, White MC. Iron-catalyzed intramolecular allylic C-H amination. Journal of the American Chemical Society. 134: 2036-9. PMID 22260649 DOI: 10.1021/Ja211600G |
0.797 |
|
| 2012 |
White MC. C-H bond functionalization & synthesis in the 21st century: A brief history and prospectus Synlett. 23: 2746-2748. DOI: 10.1055/S-0032-1317701 |
0.489 |
|
| 2011 |
Stang EM, White MC. Molecular complexity via C-H activation: a dehydrogenative Diels-Alder reaction. Journal of the American Chemical Society. 133: 14892-5. PMID 21842902 DOI: 10.1021/Ja2059704 |
0.828 |
|
| 2011 |
Gormisky PE, White MC. Synthetic versatility in C-H oxidation: a rapid approach to differentiated diols and pyrans from simple olefins. Journal of the American Chemical Society. 133: 12584-9. PMID 21744821 DOI: 10.1021/Ja206013J |
0.836 |
|
| 2011 |
Young AJ, White MC. Allylic C-H alkylation of unactivated α-olefins: serial ligand catalysis resumed. Angewandte Chemie (International Ed. in English). 50: 6824-7. PMID 21656620 DOI: 10.1002/Anie.201101654 |
0.473 |
|
| 2011 |
Stang EM, White MC. On the macrocyclization of the erythromycin core: preorganization is not required. Angewandte Chemie (International Ed. in English). 50: 2094-7. PMID 21344559 DOI: 10.1002/Anie.201007309 |
0.782 |
|
| 2011 |
Bigi MA, Reed SA, White MC. Diverting non-haem iron catalysed aliphatic C-H hydroxylations towards desaturations. Nature Chemistry. 3: 216-22. PMID 21336327 DOI: 10.1038/Nchem.967 |
0.493 |
|
| 2010 |
Qi XB, Rice GT, Lall MS, Plummer MS, White MC. Diversification of a β-Lactam Pharmacophore via Allylic C-H Amination: Accelerating Effect of Lewis Acid Co-Catalyst. Tetrahedron. 66: 4816-4826. PMID 21379377 DOI: 10.1016/J.Tet.2010.04.064 |
0.769 |
|
| 2010 |
Vermeulen NA, Delcamp JH, White MC. Synthesis of complex allylic esters via C-H oxidation vs C-C bond formation. Journal of the American Chemical Society. 132: 11323-8. PMID 20662536 DOI: 10.1021/Ja104826G |
0.825 |
|
| 2010 |
Chen MS, White MC. Combined effects on selectivity in Fe-catalyzed methylene oxidation. Science (New York, N.Y.). 327: 566-71. PMID 20110502 DOI: 10.1126/Science.1183602 |
0.687 |
|
| 2010 |
White M, Qi X, Rice G, Lall M, Plummer M. Accelerating Effect of Lewis Acid Co-Catalyst on C-H Amination Synfacts. 2010: 1050-1050. DOI: 10.1055/s-0030-1257893 |
0.387 |
|
| 2010 |
Qi X, Rice GT, Lall MS, Plummer MS, White MC. Diversification of a β-lactam pharmacophore via allylic C-H amination: Accelerating effect of Lewis acid co-catalyst Tetrahedron. 66: 4816-4826. DOI: 10.1016/j.tet.2010.04.064 |
0.707 |
|
| 2009 |
Stang EM, White MC. Total synthesis and study of 6-deoxyerythronolide B by late-stage C-H oxidation. Nature Chemistry. 1: 547-51. PMID 21378935 DOI: 10.1038/Nchem.351 |
0.83 |
|
| 2009 |
Reed SA, Mazzotti AR, White MC. A catalytic, Brønsted base strategy for intermolecular allylic C-H amination. Journal of the American Chemical Society. 131: 11701-6. PMID 19645492 DOI: 10.1021/Ja903939K |
0.588 |
|
| 2009 |
Rice GT, White MC. Allylic C-H amination for the preparation of syn-1,3-amino alcohol motifs. Journal of the American Chemical Society. 131: 11707-11. PMID 19645489 DOI: 10.1021/Ja9054959 |
0.565 |
|
| 2008 |
Young AJ, White MC. Catalytic intermolecular allylic C-H alkylation. Journal of the American Chemical Society. 130: 14090-1. PMID 18831588 DOI: 10.1021/Ja806867P |
0.554 |
|
| 2008 |
Delcamp JH, Brucks AP, White MC. A general and highly selective chelate-controlled intermolecular oxidative Heck reaction. Journal of the American Chemical Society. 130: 11270-1. PMID 18671350 DOI: 10.1021/Ja804120R |
0.733 |
|
| 2008 |
Covell DJ, White MC. A chiral Lewis acid strategy for enantioselective allylic C-H oxidation. Angewandte Chemie (International Ed. in English). 47: 6448-51. PMID 18624317 DOI: 10.1002/Anie.200802106 |
0.831 |
|
| 2008 |
Reed SA, White MC. Catalytic intermolecular linear allylic C-H amination via heterobimetallic catalysis. Journal of the American Chemical Society. 130: 3316-8. PMID 18302379 DOI: 10.1021/Ja710206U |
0.506 |
|
| 2008 |
White M, Delcamp J, Brucks A. Highly Selective Chelate-Controlled Heck-Miyaura Coupling Reaction Synfacts. 2008: 1208-1208. DOI: 10.1055/s-0028-1083466 |
0.609 |
|
| 2007 |
Chen MS, White MC. A predictably selective aliphatic C-H oxidation reaction for complex molecule synthesis. Science (New York, N.Y.). 318: 783-7. PMID 17975062 DOI: 10.1126/Science.1148597 |
0.729 |
|
| 2007 |
Fraunhoffer KJ, White MC. syn-1,2-Amino alcohols via diastereoselective allylic C-H amination. Journal of the American Chemical Society. 129: 7274-6. PMID 17516648 DOI: 10.1021/Ja071905G |
0.799 |
|
| 2007 |
White M, Covell D, Vermeulen N, Labenz N. Total Synthesis of Protected l-Galactose by Hydrocarbon Oxidation Synfacts. 2007: 0167-0167. DOI: 10.1055/s-2006-955854 |
0.782 |
|
| 2006 |
Delcamp JH, White MC. Sequential hydrocarbon functionalization: allylic C-H oxidation/vinylic C-H arylation. Journal of the American Chemical Society. 128: 15076-7. PMID 17117844 DOI: 10.1021/Ja066563D |
0.768 |
|
| 2006 |
Covell DJ, Vermeulen NA, Labenz NA, White MC. Polyol synthesis through hydrocarbon oxidation: de novo synthesis of L-galactose. Angewandte Chemie (International Ed. in English). 45: 8217-20. PMID 17109456 DOI: 10.1002/Anie.200603321 |
0.828 |
|
| 2006 |
Fraunhoffer KJ, Prabagaran N, Sirois LE, White MC. Macrolactonization via hydrocarbon oxidation. Journal of the American Chemical Society. 128: 9032-3. PMID 16834366 DOI: 10.1021/Ja063096R |
0.825 |
|
| 2005 |
Chen MS, Prabagaran N, Labenz NA, White MC. Serial ligand catalysis: a highly selective allylic C-H oxidation. Journal of the American Chemical Society. 127: 6970-1. PMID 15884938 DOI: 10.1021/Ja0500198 |
0.699 |
|
| 2005 |
Fraunhoffer KJ, Bachovchin DA, White MC. Hydrocarbon oxidation vs C-C bond-forming approaches for efficient syntheses of oxygenated molecules. Organic Letters. 7: 223-6. PMID 15646963 DOI: 10.1021/Ol047800P |
0.814 |
|
| 2004 |
Chen MS, White MC. A sulfoxide-promoted, catalytic method for the regioselective synthesis of allylic acetates from monosubstituted olefins via C-H oxidation. Journal of the American Chemical Society. 126: 1346-7. PMID 14759185 DOI: 10.1021/Ja039107N |
0.732 |
|
| 2001 |
White MC, Doyle AG, Jacobsen EN. A synthetically useful, self-assembling MMO mimic system for catalytic alkene epoxidation with aqueous H2O2. Journal of the American Chemical Society. 123: 7194-5. PMID 11459514 DOI: 10.1021/Ja015884G |
0.739 |
|
| 2001 |
White MC, Burke MD, Peleg S, Brem H, Posner GH. Conformationally restricted hybrid analogues of the hormone 1 alpha,25-dihydroxyvitamin D(3): design, synthesis, and biological evaluation. Bioorganic & Medicinal Chemistry. 9: 1691-9. PMID 11425569 DOI: 10.1016/S0968-0896(01)00087-6 |
0.506 |
|
| 2001 |
Weiskopf AS, Vouros P, Cunniff J, Binderup E, Björkling F, Binderup L, White MC, Posner GH. Examination of structurally selective derivatization of vitamin D(3) analogues by electrospray mass spectrometry. Journal of Mass Spectrometry : Jms. 36: 71-8. PMID 11180648 DOI: 10.1002/Jms.105 |
0.369 |
|
| 1999 |
Hofer H, Ho Gm, Peterlik M, Uskokovic MR, Lee JK, White MC, Posner GH, Cross HS. Biological effects of 1alpha-hydroxy- and 1beta-(hydroxymethyl)-vitamin D compounds relevant for potential colorectal cancer therapy. The Journal of Pharmacology and Experimental Therapeutics. 291: 450-5. PMID 10525058 |
0.363 |
|
| 1997 |
Posner GH, Lee JK, White MC, Hutchings RH, Dai H, Kachinski JL, Dolan P, Kensler TW. Antiproliferative Hybrid Analogs of the Hormone 1alpha,25-Dihydroxyvitamin D(3): Design, Synthesis, and Preliminary Biological Evaluation. The Journal of Organic Chemistry. 62: 3299-3314. PMID 11671717 DOI: 10.1021/Jo970049W |
0.538 |
|
| 1997 |
Boyan BD, Posner GH, Greising DM, White MC, Sylvia VL, Dean DD, Schwartz Z. Hybrid structural analogues of 1,25-(OH)2D3 regulate chondrocyte proliferation and proteoglycan production as well as protein kinase C through a nongenomic pathway. Journal of Cellular Biochemistry. 66: 457-70. PMID 9282324 DOI: 10.1002/(Sici)1097-4644(19970915)66:4<457::Aid-Jcb5>3.0.Co;2-K |
0.385 |
|
| 1997 |
Posner GH, Lee JK, White MC, Hutchings RH, Dai H, Kachinski JL, Dolan P, Kensler TW. Antiproliferative Hybrid Analogs of the Hormone 1α,25-Dihydroxyvitamin D3: Design, Synthesis, and Preliminary Biological Evaluation Journal of Organic Chemistry. 62: 3291-3298. DOI: 10.1021/jo970049w |
0.389 |
|
| 1996 |
Peleg S, Liu YY, Reddy S, Horst RL, White MC, Posner GH. A 20-epi side chain restores growth-regulatory and transcriptional activities of an A ring-modified hybrid analog of 1 alpha, 25-dihydroxyvitamin D3 without increasing its affinity to the vitamin D receptor. Journal of Cellular Biochemistry. 63: 149-61. PMID 8913867 DOI: 10.1002/(Sici)1097-4644(19961101)63:2<149::Aid-Jcb3>3.0.Co;2-Y |
0.361 |
|
| 1995 |
Posner GH, Li Z, White MC, Vinader V, Takeuchi K, Guggino SE, Dolan P, Kensler TW. 1 alpha,25-dihydroxyvitamin D3 analogs featuring aromatic and heteroaromatic rings: design, synthesis, and preliminary biological testing. Journal of Medicinal Chemistry. 38: 4529-37. PMID 7473581 DOI: 10.1021/Jm00022A019 |
0.456 |
|
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