T. Don Tilley - Publications

Affiliations: 
1983-1994 Chemistry University of California, San Diego, La Jolla, CA 
 1994- University of California, Berkeley, Berkeley, CA 
Area:
Synthetic, structural, and reactivity studies on transition metal compounds
Website:
http://chemistry.berkeley.edu/faculty/chem/tilley

307 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2020 Bergman HM, Kiel GR, Witzke RJ, Nenon DP, Schwartzberg AM, Liu Y, Tilley TD. Shape-Selective Synthesis of Pentacene Macrocycles and the Effect of Geometry on Singlet Fission. Journal of the American Chemical Society. PMID 33169994 DOI: 10.1021/jacs.0c09941  0.52
2020 Samkian A, Kiel GR, Jones CG, Bergman HM, Oktawiec J, Nelson HM, Tilley TD. MicroED Elucidation of Diverse Solid-State Packing in a Family of Electron-Deficient Expanded Helicenes. Angewandte Chemie (International Ed. in English). PMID 33090649 DOI: 10.1002/anie.202012213  0.4
2020 Amtawong J, Skjelstad BB, Balcells D, Tilley TD. Concerted Proton-Electron Transfer Reactivity at a Multimetallic CoO Cubane Cluster. Inorganic Chemistry. PMID 32997494 DOI: 10.1021/acs.inorgchem.0c02625  0.56
2020 Phillips NA, Smith PW, Tilley TD, Minasian SG. Gauging aromatic conjugation and charge delocalization in the aryl silanes PhSiH ( = 0-4), with silicon K-edge XAS and TDDFT. Dalton Transactions (Cambridge, England : 2003). PMID 32936166 DOI: 10.1039/d0dt03153d  0.36
2020 Dombrowski JP, Ziegler MS, Phadke NM, Mansoor E, Levine DS, Witzke RJ, Head-Gordon M, Bell AT, Tilley TD. Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially-Hydrolyzed Framework Sites in Zeolites and Zeotypes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32926472 DOI: 10.1002/chem.202002926  1
2020 Desnoyer AN, Nicolay A, Rios P, Ziegler MS, Tilley TD. Bimetallics in a Nutshell: Complexes Supported by Chelating Naphthyridine-Based Ligands. Accounts of Chemical Research. PMID 32878429 DOI: 10.1021/acs.accounts.0c00382  0.76
2020 Kiel GR, Bay KL, Samkian AE, Schuster NJ, Lin JB, Handford RC, Nuckolls C, Houk KN, Tilley TD. Expanded Helicenes as Synthons for Chiral Macrocyclic Nanocarbons. Journal of the American Chemical Society. PMID 32450694 DOI: 10.1021/jacs.0c03177  0.4
2020 Desnoyer AN, Nicolay A, Ziegler MS, Torquato NA, Tilley TD. A Dicopper Platform that Stabilizes the Formation of Pentanuclear Coinage Metal Hydride Complexes. Angewandte Chemie (International Ed. in English). PMID 32372506 DOI: 10.1002/anie.202004346  0.76
2020 Handford RC, Wheeler TA, Tilley TD. Structure and Bonding in a Diamond-Shaped Tin Cluster Possessing a cyclo-Sn4 Core. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32219897 DOI: 10.1002/chem.202000969  0.4
2020 Nicolay A, Ziegler MS, Small DW, Grünbauer R, Scheer M, Tilley TD. Isomerism and dynamic behavior of bridging phosphaalkynes bound to a dicopper complex. Chemical Science. 11: 1607-1616. PMID 32206279 DOI: 10.1039/c9sc05835d  0.76
2019 Amtawong J, Balcells D, Wilcoxen J, Handford RC, Biggins N, Nguyen AI, Britt RD, Tilley TD. Isolation and Study of Ruthenium-Cobalt Oxo Cubanes Bearing a High-Valent, Terminal Ru-Oxo with Significant Oxyl Radical Character. Journal of the American Chemical Society. PMID 31697896 DOI: 10.1021/jacs.9b10320  0.56
2019 Nguyen AI, Van Allsburg KM, Terban MW, Bajdich M, Oktawiec J, Amtawong J, Ziegler MS, Dombrowski JP, Lakshmi KV, Drisdell WS, Yano J, Billinge SJL, Tilley TD. Stabilization of reactive CoO cubane oxygen-evolution catalysts within porous frameworks. Proceedings of the National Academy of Sciences of the United States of America. PMID 31142656 DOI: 10.1073/pnas.1815013116  0.76
2019 Handford RC, Smith PW, Tilley TD. Activations of all Bonds to Silicon (Si-H, Si-C) in a Silane with Extrusion of [CoSiCo] Silicide Cores. Journal of the American Chemical Society. PMID 31117667 DOI: 10.1021/jacs.9b04265  0.4
2019 Witzke RJ, Tilley TD. A two-coordinate Ni(i) silyl complex: CO insertion and oxidatively-induced silyl migrations. Chemical Communications (Cambridge, England). PMID 31111837 DOI: 10.1039/c9cc03128f  0.52
2018 Arnold J, Tilley TD. An enigmatic trailblazer on the frontier of discovery: Richard A. Andersen. Chemical Communications (Cambridge, England). PMID 30324202 DOI: 10.1039/c8cc90464b  0.96
2018 Liu HJ, Ziegler MS, Tilley TD. Synthesis, structures, and reactivity studies of cyclometalated N-heterocyclic carbene complexes of ruthenium. Dalton Transactions (Cambridge, England : 2003). PMID 30083678 DOI: 10.1039/c8dt01925h  0.76
2018 Nguyen AI, Darago LE, Balcells D, Tilley TD. Influence of a "Dangling" Co(II) Ion Bound to a [MnCo3O4] Oxo Cubane. Journal of the American Chemical Society. PMID 30001620 DOI: 10.1021/jacs.8b04065  0.56
2018 Nicolay A, Tilley TD. Selective synthesis of a series of isostructural MIICuI heterobimetallic complexes spontaneously assembled by an unsymmetrical naphthyridine-based ligand. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29852541 DOI: 10.1002/chem.201802623  0.56
2018 Smith PW, Tilley TD. Base-Free Iron Hydrosilylene Complexes via an α-Hydride Migration that Induces Spin Pairing. Journal of the American Chemical Society. PMID 29528225 DOI: 10.1021/jacs.8b01185  0.36
2018 Olshansky L, Huerta-Lavorie R, Nguyen AI, Vallapurackal J, Furst A, Tilley TD, Borovik AS. Artificial Metalloproteins Containing Co4O4 Cubane Active Sites. Journal of the American Chemical Society. PMID 29401385 DOI: 10.1021/jacs.7b13052  0.56
2018 Kiel GR, Samkian AE, Nicolay A, Witzke RJ, Tilley TD. Titanocene-Mediated Dinitrile Coupling: A Divergent Route to Nitrogen-Containing Polycyclic Aromatic Hydrocarbons. Journal of the American Chemical Society. PMID 29383934 DOI: 10.1021/jacs.7b13823  0.56
2017 Kiel GR, Patel SC, Smith PW, Levine DS, Tilley TD. Expanded Helicenes: A General Synthetic Strategy and Remarkable Supramolecular and Solid-State Behavior. Journal of the American Chemical Society. PMID 29215272 DOI: 10.1021/jacs.7b10902  0.68
2017 Nguyen AI, Wang J, Levine DS, Ziegler MS, Tilley TD. Synthetic control and empirical prediction of redox potentials for Co4O4 cubanes over a 1.4 V range: implications for catalyst design and evaluation of high-valent intermediates in water oxidation. Chemical Science. 8: 4274-4284. PMID 29081963 DOI: 10.1039/c7sc00627f  0.76
2017 Levine DS, Tilley TD, Andersen RA. Efficient and selective catalysis for hydrogenation and hydrosilation of alkenes and alkynes with PNP complexes of scandium and yttrium. Chemical Communications (Cambridge, England). PMID 29043320 DOI: 10.1039/c7cc06417a  0.96
2017 Ziegler MS, Lakshmi KV, Tilley TD. Dicopper Cu(I)Cu(I) and Cu(I)Cu(II) Complexes in Copper-Catalyzed Azide-Alkyne Cycloaddition. Journal of the American Chemical Society. PMID 28394586 DOI: 10.1021/jacs.6b13261  0.76
2017 Nguyen AI, Suess DL, Darago LE, Oyala PH, Levine DS, Ziegler MS, Britt RD, Tilley TD. Manganese-Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts. Journal of the American Chemical Society. PMID 28347135 DOI: 10.1021/jacs.7b01792  0.76
2017 Kiel GR, Ziegler MS, Tilley TD. Zirconacyclopentadiene-Annulated Polycyclic Aromatic Hydrocarbons. Angewandte Chemie (International Ed. in English). PMID 28334480 DOI: 10.1002/anie.201700818  0.76
2016 Spanjers CS, Guillo P, Tilley TD, Janik MJ, Rioux RM. Identification of Second Shell Coordination in Transition Metal Species using Theoretical XANES: Example of Ti-O-(C,Si,Ge) Complexes. The Journal of Physical Chemistry. A. PMID 27951643 DOI: 10.1021/acs.jpca.6b12197  0.32
2016 Dombrowski JP, Johnson GR, Bell AT, Tilley TD. Correction: Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Transactions (Cambridge, England : 2003). PMID 27834429 DOI: 10.1039/c6dt90202b  1
2016 Lipke MC, Liberman-Martin AL, Tilley TD. Electrophilic Activation of Silicon-Hydrogen Bonds in Catalytic Hydrosilations. Angewandte Chemie (International Ed. in English). PMID 27641142 DOI: 10.1002/anie.201605198  0.96
2016 Lipke MC, Liberman-Martin AL, Tilley TD. Significant Cooperativity Between Ruthenium and Silicon in Catalytic Transformations of an Isocyanide. Journal of the American Chemical Society. PMID 27384746 DOI: 10.1021/jacs.6b05736  0.96
2016 Dombrowski JP, Johnson GR, Bell AT, Tilley TD. Ga[OSi(O(t)Bu)3]3·THF, a thermolytic molecular precursor for high surface area gallium-containing silica materials of controlled dispersion and stoichiometry. Dalton Transactions (Cambridge, England : 2003). PMID 27312519 DOI: 10.1039/c6dt01676f  1
2016 Ziegler MS, Levine DS, Lakshmi KV, Tilley TD. Aryl Group Transfer from Tetraarylborato Anions to an Electrophilic Dicopper(I) Center and Mixed-Valence μ-Aryl Dicopper(I,II) Complexes. Journal of the American Chemical Society. PMID 27176131 DOI: 10.1021/jacs.6b00802  0.76
2016 Liberman-Martin AL, Levine DS, Ziegler MS, Bergman RG, Tilley TD. Lewis acid-base interactions between platinum(ii) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand. Chemical Communications (Cambridge, England). PMID 27161155 DOI: 10.1039/c6cc02433e  1
2016 Dong Y, Lipschutz MI, Tilley TD. Regioselective, Transition Metal-Free C-O Coupling Reactions Involving Aryne Intermediates. Organic Letters. PMID 27010921 DOI: 10.1021/acs.orglett.6b00183  1
2016 Liberman-Martin AL, Ziegler MS, DiPasquale AG, Bergman RG, Tilley TD. Functionalization of an iridium-diamidocarbene complex by ligand-based reactions with titanocene and zirconocene sources Polyhedron. DOI: 10.1016/j.poly.2016.03.044  1
2016 Liu HJ, Cai IC, Fedorov A, Ziegler MS, Copéret C, Tilley TD. Tricoordinate Organochromium(III) Complexes Supported by a Bulky Silylamido Ligand Produce Ultra-High-Molecular Weight Polyethylene in the Absence of Activators Helvetica Chimica Acta. DOI: 10.1002/hlca.201600199  1
2015 Panetier JA, Letko CS, Tilley TD, Head-Gordon M. Computational Characterization of Redox Non-Innocence in Cobalt-Bis(Diaryldithiolene) Catalyzed Proton Reduction. Journal of Chemical Theory and Computation. PMID 26598074 DOI: 10.1021/acs.jctc.5b00968  1
2015 Nguyen AI, Ziegler MS, Oña-Burgos P, Sturzbecher-Hoehne M, Kim W, Bellone DE, Tilley TD. Mechanistic Investigations of Water Oxidation by a Molecular Cobalt Oxide Analogue: Evidence for a Highly Oxidized Intermediate and Exclusive Terminal Oxo Participation. Journal of the American Chemical Society. PMID 26390993 DOI: 10.1021/jacs.5b08396  1
2015 Liu HJ, Landis C, Raynaud C, Eisenstein O, Tilley TD. Donor-Promoted 1,2-Hydrogen Migration from Silicon to a Saturated Ruthenium Center and Access to Silaoxiranyl and Silaiminyl Complexes. Journal of the American Chemical Society. 137: 9186-94. PMID 26135519 DOI: 10.1021/jacs.5b05571  1
2015 Lipschutz MI, Chantarojsiri T, Dong Y, Tilley TD. Synthesis, characterization, and alkyne trimerization catalysis of a heteroleptic two-coordinate fe(i) complex. Journal of the American Chemical Society. 137: 6366-72. PMID 25928273 DOI: 10.1021/jacs.5b02504  1
2015 Liberman-Martin AL, Bergman RG, Tilley TD. Lewis Acidity of Bis(perfluorocatecholato)silane: Aldehyde Hydrosilylation Catalyzed by a Neutral Silicon Compound. Journal of the American Chemical Society. 137: 5328-31. PMID 25879515 DOI: 10.1021/jacs.5b02807  1
2015 Liu HJ, Ziegler MS, Tilley TD. The Ruthenostannylene Complex [Cp*(IXy)H2 Ru-Sn-Trip]: Providing Access to Unusual Ru-Sn Bonded Stanna-imine, Stannene, and Ketenylstannyl Complexes. Angewandte Chemie (International Ed. in English). 54: 6622-6. PMID 25845838 DOI: 10.1002/anie.201502156  1
2015 Van Allsburg KM, Anzenberg E, Drisdell WS, Yano J, Tilley TD. Oxygen-atom transfer chemistry and thermolytic properties of a di-tert-butylphosphate-ligated Mn4O4 cubane. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 4646-54. PMID 25676196 DOI: 10.1002/chem.201406114  1
2015 Liu W, Tilley TD. Sterically controlled functionalization of carbon surfaces with -C6H4CH2X (X = OSO2Me or N3) groups for surface attachment of redox-active molecules. Langmuir : the Acs Journal of Surfaces and Colloids. 31: 1189-95. PMID 25549529 DOI: 10.1021/la503796z  1
2015 Davenport TC, Tilley TD. Dinuclear first-row transition metal complexes with a naphthyridine-based dinucleating ligand. Dalton Transactions (Cambridge, England : 2003). 44: 12244-55. PMID 25420206 DOI: 10.1039/c4dt02727b  1
2015 Ahn HS, Yano J, Tilley TD. Water Oxidation by Cobalt Centers on Various Oxide Surfaces: The Effects of Oxide Surface Acidity and Oxygen Atom Affinity on Catalysis Acs Catalysis. 5: 2573-2576. DOI: 10.1021/cs502120f  1
2015 Levine DS, Tilley TD, Andersen RA. C-H Bond Activations by Monoanionic, PNP-Supported Scandium Dialkyl Complexes Organometallics. 34: 4647-4655. DOI: 10.1021/acs.organomet.5b00213  1
2015 Smith PW, Tilley TD. Silane-Allyl Coupling Reactions of Cp∗(iPr2MeP)Fe(η3-C3H5) and Synthetic Access to the Hydrido-Dinitrogen Complex Cp∗(iPr2MeP)FeH(N2) Organometallics. 34: 2134-2138. DOI: 10.1021/acs.organomet.5b00184  1
2015 Swierk JR, Klaus S, Trotochaud L, Bell AT, Tilley TD. Electrochemical Study of the Energetics of the Oxygen Evolution Reaction at Nickel Iron (Oxy)Hydroxide Catalysts Journal of Physical Chemistry C. 119: 19022-19029. DOI: 10.1021/acs.jpcc.5b05861  1
2014 Lipke MC, Tilley TD. Hypercoordinate ketone adducts of electrophilic η3-H2SiRR' ligands on ruthenium as key intermediates for efficient and robust catalytic hydrosilation. Journal of the American Chemical Society. 136: 16387-98. PMID 25347044 DOI: 10.1021/ja509073c  1
2014 Arnold J, Brothers PJ, Mountford P, Piers WE, Thomas CM, Tilley TD. The influence of Michael Lappert on the chemistry landscape. Dalton Transactions (Cambridge, England : 2003). 43: 16553-6. PMID 25331627 DOI: 10.1039/c4dt90167c  0.64
2014 Lipschutz MI, Tilley TD. Useful Method for the Preparation of Low-Coordinate Nickel(I) Complexes via Transformations of the Ni(I) Bis(amido) Complex K{Ni[N(SiMe3)(2,6- (i) Pr2-C6H3)]2} Organometallics. 33: 5566-5570. PMID 25328273 DOI: 10.1021/om500849u  1
2014 Liu HJ, Guihaumé J, Davin T, Raynaud C, Eisenstein O, Tilley TD. 1,2-hydrogen migration to a saturated ruthenium complex via reversal of electronic properties for tin in a stannylene-to-metallostannylene conversion. Journal of the American Chemical Society. 136: 13991-4. PMID 25247392 DOI: 10.1021/ja507799e  1
2014 Cai IC, Lipschutz MI, Tilley TD. A bis(amido) ligand set that supports two-coordinate chromium in the +1, +2, and +3 oxidation states. Chemical Communications (Cambridge, England). 50: 13062-5. PMID 25222516 DOI: 10.1039/c4cc06615d  1
2014 Nguyen AI, Hadt RG, Solomon EI, Tilley TD. Efficient C-H Bond Activations via O2 Cleavage by a Dianionic Cobalt(II) Complex. Chemical Science (Royal Society of Chemistry : 2010). 5: 2874-2878. PMID 25071930 DOI: 10.1039/C4SC00108G  1
2014 Liu HJ, Raynaud C, Eisenstein O, Tilley TD. Cyclometalated N-heterocyclic carbene complexes of ruthenium for access to electron-rich silylene complexes that bind the Lewis acids CuOTf and AgOTf. Journal of the American Chemical Society. 136: 11473-82. PMID 25050912 DOI: 10.1021/ja5054237  1
2014 Letko CS, Panetier JA, Head-Gordon M, Tilley TD. Mechanism of the electrocatalytic reduction of protons with diaryldithiolene cobalt complexes. Journal of the American Chemical Society. 136: 9364-76. PMID 24950387 DOI: 10.1021/ja5019755  1
2014 Lipschutz MI, Tilley TD. Carbon-carbon cross-coupling reactions catalyzed by a two-coordinate nickel(II)-bis(amido) complex via observable Ni(I) , Ni(II) , and Ni(III) intermediates. Angewandte Chemie (International Ed. in English). 53: 7290-4. PMID 24889777 DOI: 10.1002/anie.201404577  1
2014 Davenport TC, Ahn HS, Ziegler MS, Tilley TD. A molecular structural analog of proposed dinuclear active sites in cobalt-based water oxidation catalysts. Chemical Communications (Cambridge, England). 50: 6326-9. PMID 24797957 DOI: 10.1039/c3cc46865h  1
2014 Lipke MC, Neumeyer F, Tilley TD. Interconversion of η3-H2SiRR' σ-complexes and 16-electron silylene complexes via reversible H-H or C-H elimination. Journal of the American Chemical Society. 136: 6092-102. PMID 24666100 DOI: 10.1021/ja501803w  1
2014 Ahn HS, Davenport TC, Tilley TD. Molecular cobalt electrocatalyst for proton reduction at low overpotential. Chemical Communications (Cambridge, England). 50: 3834-7. PMID 24589710 DOI: 10.1039/c3cc49682a  1
2014 Liu W, Sharp ID, Tilley TD. Multifunctional silicon surfaces: reaction of dichlorocarbene generated from Seyferth reagent with hydrogen-terminated silicon (111) surfaces. Langmuir : the Acs Journal of Surfaces and Colloids. 30: 172-8. PMID 24328351 DOI: 10.1021/la403789a  1
2014 Gladysz JA, Bedford RB, Fujita M, Gabbaï FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, Norton JR, Petrukhina MA, Ren T, Stahl SS, Tilley TD, et al. Organometallics roundtable 2013-2014 Organometallics. 33: 1505-1527. DOI: 10.1021/om500253z  1
2014 Liu HJ, Ziegler MS, Tilley TD. Ring-opening and double-metallation reactions of the N-Heterocyclic carbene ligand in Cp∗(IXy)Ru (IXy = 1,3-bis(2,6-dimethylphenyl)imidazol-2-ylidene) complexes. Access to an anionic fischer-type carbene complex of ruthenium This paper is dedicated to John Bercaw on the occasion of his 70th birthday Polyhedron. 84: 203-208. DOI: 10.1016/j.poly.2014.08.052  1
2014 Gross CL, Brumaghim JL, Jefferis JM, Dickinson PW, Girolami GS, Gribble CW, Tilley TD. Mono(η5-Pentamethylcyclopentadienyl) Complexes of Osmium Inorganic Syntheses. 36: 74-78. DOI: 10.1002/9781118744994.ch15  1
2013 Lipschutz MI, Yang X, Chatterjee R, Tilley TD. A structurally rigid bis(amido) ligand framework in low-coordinate Ni(I), Ni(II), and Ni(III) analogues provides access to a Ni(III) methyl complex via oxidative addition. Journal of the American Chemical Society. 135: 15298-301. PMID 24079707 DOI: 10.1021/ja408151h  1
2013 Bowring MA, Bergman RG, Tilley TD. Pt-catalyzed C-C activation induced by C-H activation. Journal of the American Chemical Society. 135: 13121-8. PMID 23962182 DOI: 10.1021/ja406260j  1
2013 Hayes PG, Xu Z, Beddie C, Keith JM, Hall MB, Tilley TD. The osmium-silicon triple bond: synthesis, characterization, and reactivity of an osmium silylyne complex. Journal of the American Chemical Society. 135: 11780-3. PMID 23906040 DOI: 10.1021/ja406799y  1
2013 Rumberger EM, Ahn HS, Bell AT, Tilley TD. Water oxidation catalysis via immobilization of the dimanganese complex [Mn2(μ-O)2Cl(μ-O2CCH3)(bpy)2(H2O)](NO3)2 onto silica. Dalton Transactions (Cambridge, England : 2003). 42: 12238-47. PMID 23861177 DOI: 10.1039/c3dt51472b  1
2013 Lipke MC, Tilley TD. Silane-isocyanide coupling involving 1,1-insertion of XylNC into the Si-H bond of a σ-silane ligand. Journal of the American Chemical Society. 135: 10298-301. PMID 23834657 DOI: 10.1021/ja404910h  1
2013 Liberman-Martin AL, Bergman RG, Tilley TD. A remote Lewis acid trigger dramatically accelerates biaryl reductive elimination from a platinum complex. Journal of the American Chemical Society. 135: 9612-5. PMID 23789917 DOI: 10.1021/ja404339u  1
2013 Guillo P, Fasulo ME, Lipschutz MI, Tilley TD. Synthesis and characterization of tantalum silsesquioxane complexes. Dalton Transactions (Cambridge, England : 2003). 42: 1991-5. PMID 23283146 DOI: 10.1039/c2dt32601a  1
2013 Zaks J, Sun J, Kirmayer S, Urban JJ, Tilley TD, Segalman RA, Fleming GR. Effect of bridge on energy transfer and photoinduced charge separation in perylene-diimide-naphthalene-bisimide-hexathiophene based donor-bridge-acceptor triads Epj Web of Conferences. 41. DOI: 10.1051/epjconf/20134105011  1
2013 Fasulo ME, Lipke MC, Tilley TD. Structural and mechanistic investigation of a cationic hydrogen-substituted ruthenium silylene catalyst for alkene hydrosilation Chemical Science. 4: 3882-3887. DOI: 10.1039/c3sc51585k  1
2013 Ahn HS, Yano J, Tilley TD. Photocatalytic water oxidation by very small cobalt domains on a silica surface Energy and Environmental Science. 6: 3080-3087. DOI: 10.1039/c3ee42067a  1
2013 Bowring MA, Bergman RG, Tilley TD. Isolation of a dicationic platinum complex with two accessible coordination sites Organometallics. 32: 5266-5268. DOI: 10.1021/om4008357  1
2013 Fasulo ME, Calimano E, Buchanan JM, Tilley TD. Multiple Si-H bond activations by tBu2PCH 2CH2PtBu2 and tBu 2PCH2PtBu2 Di(phosphine) complexes of rhodium and iridium Organometallics. 32: 1016-1028. DOI: 10.1021/om300943e  1
2013 Ugeda MM, Yu M, Bradley AJ, Doak P, Liu W, Moore GF, Sharp ID, Tilley TD, Neaton JB, Crommie MF. Adsorption and stability of π-bonded ethylene on GaP(110) Journal of Physical Chemistry C. 117: 26091-26096. DOI: 10.1021/jp408539x  1
2013 Cordeiro PJ, Guillo P, Spanjers CS, Chang JW, Lipschutz MI, Fasulo ME, Rioux RM, Tilley TD. Titanium-germoxy precursor route to germanium-modified epoxidation catalysts with enhanced activity Acs Catalysis. 3: 2269-2279. DOI: 10.1021/cs400529x  1
2013 Stockton AM, Mora MF, Cable ML, Davenport TC, Tilley TD, Willis PA. Hydrolysis of 3-carboxy-6,8-difluoro-7-hydroxycoumarin (Pacific Blue™) succinimidyl ester under acidic and basic conditions Dyes and Pigments. 96: 148-151. DOI: 10.1016/j.dyepig.2012.08.005  1
2013 Neumeyer F, Lipschutz MI, Tilley TD. Group 8 transition metal complexes of the tripodal triphosphino ligands PhSi(CH2PR2)3 (R = Ph, iPr) European Journal of Inorganic Chemistry. 6075-6078. DOI: 10.1002/ejic.201301074  1
2013 Ahn HS, Tilley TD. Electrocatalytic water oxidation at neutral pH by a nanostructured Co(PO3)2 Anode Advanced Functional Materials. 23: 227-233. DOI: 10.1002/adfm.201200920  1
2012 Lipke MC, Tilley TD. Stabilization of ArSiH4(-) and SiH6(2-) anions in diruthenium Si-H σ-complexes. Angewandte Chemie (International Ed. in English). 51: 11115-21. PMID 23037588 DOI: 10.1002/anie.201202328  1
2012 Fasulo ME, Tilley TD. Synthesis and reactivity of cationic ruthenium germylene complexes [Cp*(PiPr3)RuH2(=GeRR')]+. Chemical Communications (Cambridge, England). 48: 7690-2. PMID 22740052 DOI: 10.1039/c2cc32840b  1
2012 Lipschutz MI, Tilley TD. Synthesis and reactivity of a conveniently prepared two-coordinate bis(amido) nickel(II) complex. Chemical Communications (Cambridge, England). 48: 7146-8. PMID 22692366 DOI: 10.1039/c2cc32974c  1
2012 Wright RJ, Zhang W, Yang X, Fasulo M, Tilley TD. Isolation, observation, and computational modeling of proposed intermediates in catalytic proton reductions with the hydrogenase mimic Fe2(CO)6S2C6H4. Dalton Transactions (Cambridge, England : 2003). 41: 73-82. PMID 22031098 DOI: 10.1039/c1dt11428j  1
2012 Curley JJ, Bergman RG, Tilley TD. Preparation and physical properties of early-late heterobimetallic compounds featuring Ir-M bonds (M = Ti, Zr, Hf). Dalton Transactions (Cambridge, England : 2003). 41: 192-200. PMID 22020701 DOI: 10.1039/c1dt11753j  1
2012 Fasulo ME, Tilley TD. Stoichiometric reaction chemistry of cationic ruthenium silylene complexes toward polar and nonpolar organic substrates Organometallics. 31: 5049-5057. DOI: 10.1021/om300390n  1
2012 Raboin L, Yano J, Tilley TD. Epoxidation catalysts derived from introduction of titanium centers onto the surface of mesoporous aluminophosphate: Comparisons with analogous catalysts based on mesoporous silica Journal of Catalysis. 285: 168-176. DOI: 10.1016/j.jcat.2011.09.023  1
2011 Davenport TC, Tilley TD. Dinucleating naphthyridine-based ligand for assembly of bridged dicopper(I) centers: three-center two-electron bonding involving an acetonitrile donor. Angewandte Chemie (International Ed. in English). 50: 12205-8. PMID 22038762 DOI: 10.1002/anie.201106081  1
2011 Yee SK, Sun J, Darancet P, Tilley TD, Majumdar A, Neaton JB, Segalman RA. Inverse rectification in donor-acceptor molecular heterojunctions. Acs Nano. 5: 9256-63. PMID 22010940 DOI: 10.1021/nn203520v  1
2011 Chou NH, Ross PN, Bell AT, Tilley TD. Comparison of cobalt-based nanoparticles as electrocatalysts for water oxidation. Chemsuschem. 4: 1566-9. PMID 21997965 DOI: 10.1002/cssc.201100075  1
2011 Lipke MC, Tilley TD. High electrophilicity at silicon in η3-silane σ-complexes: Lewis base adducts of a silane ligand, featuring octahedral silicon and three Ru-H-Si interactions. Journal of the American Chemical Society. 133: 16374-7. PMID 21936540 DOI: 10.1021/ja207169e  1
2011 Cordeiro PJ, Tilley TD. Enhancement of epoxidation efficiencies for Ta-SBA15 catalysts. The influence of modification with -EMe3 (E = Si, Ge, Sn) groups. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 6295-304. PMID 21517024 DOI: 10.1021/la200090u  1
2011 Gessner VH, Tannaci JF, Miller AD, Tilley TD. Assembly of macrocycles by zirconocene-mediated, reversible carbon-carbon bond formation. Accounts of Chemical Research. 44: 435-46. PMID 21473633 DOI: 10.1021/ar100148g  1
2011 Roggan S, Limberg C, Knispel C, Tilley TD. Transition metal complexes of the novel hexadentate ligand 1,4-bis(di(N-methylimidazol-2-yl)methyl)phthalazine. Dalton Transactions (Cambridge, England : 2003). 40: 4315-23. PMID 21409278 DOI: 10.1039/c0dt01406k  1
2011 Gessner VH, Tilley TD. Diphenylanthracene macrocylces from reductive zirconocene coupling: on the edge of steric overload. Organic Letters. 13: 1154-7. PMID 21288005 DOI: 10.1021/ol2000099  1
2011 Kachian JS, Tannaci J, Wright RJ, Tilley TD, Bent SF. Disulfide passivation of the Ge(100)-2 × 1 surface. Langmuir : the Acs Journal of Surfaces and Colloids. 27: 179-86. PMID 21141841 DOI: 10.1021/la103614f  1
2011 Fasulo ME, Glaser PB, Tilley TD. Cp*(PiPr 3)RuOTf: A reagent for access to ruthenium silylene complexes Organometallics. 30: 5524-5531. DOI: 10.1021/om200795x  1
2011 Bowring MA, Bergman RG, Tilley TD. Disambiguation of metal and Brønsted acid catalyzed pathways for hydroarylation with platinum(II) catalysts Organometallics. 30: 1295-1298. DOI: 10.1021/om2000458  1
2011 Yoon CW, Hirsekorn KF, Neidig ML, Yang X, Tilley TD. Mechanism of the decomposition of aqueous hydrogen peroxide over heterogeneous TiSBA15 and TS-1 selective oxidation catalysts: Insights from spectroscopic and density functional theory studies Acs Catalysis. 1: 1665-1678. DOI: 10.1021/cs2003774  1
2011 Choi YS, Moschetta EG, Miller JT, Fasulo M, McMurdo MJ, Rioux RM, Tilley TD. Highly dispersed Pd-SBA15 materials from tris(tert-butoxy)siloxy complexes of Pd(II) Acs Catalysis. 1: 1166-1177. DOI: 10.1021/cs2002719  1
2011 Cordeiro PJ, Tilley TD. Enhancement of the catalytic activity of titanium-based terminal olefin epoxidation catalysts via surface modification with functionalized protic molecules Acs Catalysis. 1: 455-467. DOI: 10.1021/cs200017s  1
2011 Fasulo ME, Tilley TD. Interligand H⋯Si interactions in tungsten silyl trihydride complexes Journal of Organometallic Chemistry. 696: 1325-1330. DOI: 10.1016/j.jorganchem.2010.11.046  1
2010 Yang J, Tilley TD. Efficient hydrosilylation of carbonyl compounds with the simple amide catalyst [Fe{N(SiMe3)2}2]. Angewandte Chemie (International Ed. in English). 49: 10186-8. PMID 20949580 DOI: 10.1002/anie.201005055  1
2010 Levi ZU, Tilley TD. Synthesis and electronic properties of extended, fused-ring aromatic systems containing multiple pentalene units. Journal of the American Chemical Society. 132: 11012-4. PMID 20698660 DOI: 10.1021/ja1043159  1
2010 Calimano E, Tilley TD. Synthesis and reactivity of rhodium and iridium alkene, alkyl and silyl complexes supported by a phenyl-substituted PNP pincer ligand. Dalton Transactions (Cambridge, England : 2003). 39: 9250-63. PMID 20401366 DOI: 10.1039/b925856f  1
2010 Geramita K, Tao Y, Segalman RA, Tilley TD. Synthesis and characterization of fluorinated heterofluorene-containing donor-acceptor systems. The Journal of Organic Chemistry. 75: 1871-87. PMID 20196535 DOI: 10.1021/jo902488w  0.4
2010 Guihaumé J, Raynaud C, Eisenstein O, Perrin L, Maron L, Tilley TD. Facile interconversion of [Cp2(Cl)Hf(SnH3)] and [Cp2(Cl)Hf(mu-H)SnH2]: DFT investigations of hafnocene stannyl complexes as masked stannylenes. Angewandte Chemie (International Ed. in English). 49: 1816-9. PMID 20135660 DOI: 10.1002/anie.200906476  1
2010 Yang J, Fasulo M, Tilley TD. (MeQn2SiH)Fe[N(SiMe3)2]2 (Qn = 8-quinolyl): An unusual δ-agostic iron complex containing an η1-SiH interaction New Journal of Chemistry. 34: 2528-2529. DOI: 10.1039/c0nj00554a  1
2010 Calimano E, Tilley TD. Reactions of cationic PNP-supported iridium silylene complexes with polar organic substrates Organometallics. 29: 1680-1692. DOI: 10.1021/om901078d  1
2010 McBee JL, Tilley TD. Nucleophilic attack of amides onto coordinated ethylene in platinum complexes supported by a chelating pyridyl-pyrrolide ligand: Azaplatinacyclobutane and vinylamine complexes Organometallics. 29: 184-192. DOI: 10.1021/om900569b  1
2010 Yang J, Del Rosal I, Fasulo M, Sangtrirutnugul P, Maron L, Tilley TD. Nickel complexes with bis(8-quinolyl)silyl ligands. An unusual Ni 3Si2 cluster containing six-coordinate silicon Organometallics. 29: 5544-5550. DOI: 10.1021/om1004622  1
2010 Tilley TD. Transition-metal silyl derivatives Silicon-Heteroatom Bond: Updates From the Chemistry of Functional Groups. 245-308. DOI: 10.1002/9780470772447.ch9  1
2010 Tilley TD. Appendix to 'Transition-metal silyl derivatives' Silicon-Heteroatom Bond: Updates From the Chemistry of Functional Groups. 309-364. DOI: 10.1002/9780470772447.ch10  1
2010 Patai S, Rappoport Z, Fred Armitage DA, Corriu RJP, Kendrick TC, Parbhoo B, Tilley TD, White JW, Young JC. Silicon-Heteroatom Bond: Updates from the Chemistry of Functional Groups Silicon-Heteroatom Bond: Updates From the Chemistry of Functional Groups. 1-529. DOI: 10.1002/9780470772447  1
2009 Vignolle J, Tilley TD. N-heterocyclic carbene-stabilized gold nanoparticles and their assembly into 3D superlattices. Chemical Communications (Cambridge, England). 7230-2. PMID 19921039 DOI: 10.1039/b913884f  1
2009 Tao C, Sun J, Zhang X, Yamachika R, Wegner D, Bahri Y, Samsonidze G, Cohen ML, Louie SG, Tilley TD, Segalman RA, Crommie MF. Spatial resolution of a type II heterojunction in a single bipolar molecule. Nano Letters. 9: 3963-7. PMID 19904920 DOI: 10.1021/nl901860n  1
2009 Malen JA, Doak P, Baheti K, Tilley TD, Majumdar A, Segalman RA. The nature of transport variations in molecular heterojunction electronics. Nano Letters. 9: 3406-12. PMID 19711966 DOI: 10.1021/nl9013875  1
2009 McBee JL, Escalada J, Tilley TD. High oxidation state rhodium and iridium bis(silyl)dihydride complexes supported by a chelating pyridyl-pyrrolide ligand. Journal of the American Chemical Society. 131: 12703-13. PMID 19681602 DOI: 10.1021/ja9035169  1
2009 Shinohara A, McBee J, Tilley TD. Germylene and silylene complexes of molybdenum via E-H (E = Ge, Si) bond activations: steric influences on intramolecular MoH...E interactions. Inorganic Chemistry. 48: 8081-3. PMID 19630379 DOI: 10.1021/ic901168s  0.52
2009 Calimano E, Tilley TD. Synthesis and structure of PNP-supported iridium silyl and silylene complexes: catalytic hydrosilation of alkenes. Journal of the American Chemical Society. 131: 11161-73. PMID 19603748 DOI: 10.1021/ja903737j  1
2009 Wright RJ, Lim C, Tilley TD. Diiron proton reduction catalysts possessing electron-rich and electron-poor naphthalene-1,8-dithiolate ligands. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 8518-25. PMID 19575350 DOI: 10.1002/chem.200900989  0.36
2009 Miller AD, McBee JL, Tilley TD. Zirconocene-mediated macrocyclizations of diynes containing di-o-methylphenylene spacers. The Journal of Organic Chemistry. 74: 2880-3. PMID 19323577 DOI: 10.1021/jo802715m  1
2009 Huynh K, Vignolle J, Tilley TD. Perfluoropentaphenylborole: a new approach to Lewis acidic, electron-deficient compounds. Angewandte Chemie (International Ed. in English). 48: 2835-7. PMID 19301345 DOI: 10.1002/anie.200900695  1
2009 Miller AD, Tannaci JF, Johnson SA, Lee H, McBee JL, Tilley TD. Mesityl alkyne substituents for control of regiochemistry and reversibility in zirconocene couplings: new synthetic strategies for unsymmetrical zirconacyclopentadienes and conjugated polymers. Journal of the American Chemical Society. 131: 4917-27. PMID 19296582 DOI: 10.1021/ja809896t  1
2009 Hayes PG, Gribble CW, Waterman R, Tilley TD. A hydrogen-substituted osmium stannylene complex: isomerization to a metallostannylene complex via an unusual alpha-hydrogen migration from tin to osmium. Journal of the American Chemical Society. 131: 4606-7. PMID 19290659 DOI: 10.1021/ja901050m  1
2009 Levi ZU, Tilley TD. Versatile synthesis of pentalene derivatives via the Pd-catalyzed homocoupling of haloenynes. Journal of the American Chemical Society. 131: 2796-7. PMID 19199434 DOI: 10.1021/ja809930f  1
2009 Tannaci JF, Kratter IH, Rider EA, McBee JL, Miller AD, Tilley TD. Stereoselective macrocyclization through zirconocene-mediated coupling of achiral dialkynes. Chemical Communications (Cambridge, England). 233-4. PMID 19099079 DOI: 10.1039/b815750b  1
2009 Geramita K, McBee J, Tilley TD. 2,7-Substituted hexafluoroheterofluorenes as potential building blocks for electron transporting materials. The Journal of Organic Chemistry. 74: 820-9. PMID 19067545 DOI: 10.1021/jo802171t  1
2009 McBee JL, Tilley TD. Synthesis and reactivity of iridium and rhodium silyl complexes supported by a bipyridine ligand Organometallics. 28: 5072-5081. DOI: 10.1021/om900385a  1
2009 Hayes PG, Waterman R, Glaser PB, Tilley TD. Synthesis, structure, and reactivity of neutral hydrogen-substituted ruthenium silylene and germylene complexes Organometallics. 28: 5082-5089. DOI: 10.1021/om900348m  1
2009 Tilley TD, McBee JL. Five-coordinate dihydridosilyl platinum(IV) complexes supported by a chelating monoanionic nitrogen-based ligand Organometallics. 28: 3947-3952. DOI: 10.1021/om9002686  1
2009 Perrin L, Maron L, Eisenstein O, Tilley TD. Bond activations of PhSiH 3 by Cp 2SmH: A mechanistic investigation by the DFT method Organometallics. 28: 3767-3775. DOI: 10.1021/om900106n  1
2009 Bazinet P, Tilley TD. Octa- and nonamethylfluorenyl complexes of zirconium(IV) reactive hydride derivatives and reversible hydrogen migrationbetween the metal and the fluorenyl ligand Organometallics. 28: 2285-2293. DOI: 10.1021/om900047x  1
2009 Miller AD, Johnson SA, Tupper KA, McBee JL, Don Tilley T. Unsymmetrical Zirconacyclopentadienes from Isolated Zirconacyclopropenes with 1-Alkynylphosphine Ligands Organometallics. 28: 1252-1262. DOI: 10.1021/om801040t  0.76
2009 Esswein AJ, Mcmurdo MJ, Ross PN, Bell AT, Tilley TD. Size-dependent activity of Co3O4 nanoparticle anodes for alkaline water electrolysis Journal of Physical Chemistry C. 113: 15068-15072. DOI: 10.1021/jp904022e  1
2009 Bradley CA, Yuhas BD, McMurdo MJ, Tilley TD. Functionalized sìlìcone nanospheres: Synthesis, transition metal immobilization, and catalytic applications Chemistry of Materials. 21: 174-185. DOI: 10.1021/cm8018154  1
2009 Doak P, Tamblyn I, Darancet PT, Prendergast D, Segalman RA, Tilley TD, Neaton JB. First-principles studies of single-molecule photovoltaics Acs National Meeting Book of Abstracts 1
2009 Tilley TD, Wright RJ, Lim C. Diiron hexacarbonyl proton reduction catalysts based on rigid naphthalene-1,8-dithiolate ligands Acs National Meeting Book of Abstracts 1
2008 McBee JL, Bell AT, Tilley TD. Mechanistic studies of the hydroamination of norbornene with electrophilic platinum complexes: the role of proton transfer. Journal of the American Chemical Society. 130: 16562-71. PMID 19554728 DOI: 10.1021/ja8030104  1
2008 Geramita K, McBee J, Tao Y, Segalman RA, Tilley TD. Synthesis and characterization of 2,7-bis(pentafluorophenylethynyl)hexafluoroheterofluorenes: new materials with high electron affinities. Chemical Communications (Cambridge, England). 5107-9. PMID 18956037 DOI: 10.1039/b813440e  0.56
2008 Tannaci JF, Noji M, McBee JL, Tilley TD. 9,10-Disubstituted octafluoroanthracene derivatives via palladium-catalyzed cross-coupling. The Journal of Organic Chemistry. 73: 7895-900. PMID 18788782 DOI: 10.1021/jo8017268  1
2008 Ruddy DA, Tilley TD. Kinetics and mechanism of olefin epoxidation with aqueous H2O2 and a highly selective surface-modified TaSBA15 heterogeneous catalyst. Journal of the American Chemical Society. 130: 11088-96. PMID 18662001 DOI: 10.1021/ja8027313  1
2008 Calimano E, Tilley TD. Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex. Journal of the American Chemical Society. 130: 9226-7. PMID 18582049 DOI: 10.1021/ja803332h  1
2008 Miller AD, McBee JL, Tilley TD. Mechanism of reversible alkyne coupling at zirconocene: ancillary ligand effects. Journal of the American Chemical Society. 130: 4992-9. PMID 18336028 DOI: 10.1021/ja800025u  1
2008 Baheti K, Malen JA, Doak P, Reddy P, Jang SY, Tilley TD, Majumdar A, Segalman RA. Probing the chemistry of molecular heterojunctions using thermoelectricity. Nano Letters. 8: 715-9. PMID 18269258 DOI: 10.1021/nl072738l  1
2008 Barros N, Eisenstein O, Maron L, Tilley TD. DFT investigation of the catalytic hydromethylation of olefins by scandocenes. 2. Influence of the ansa ligand on propene and isobutene hydromethylation Organometallics. 27: 2252-2257. DOI: 10.1021/om701270w  1
2008 Sangtrirutnugul P, Tilley TD. Alkyl and hydrido complexes of platinum(IV) supported by the bis(8-quinolyl)methylsilyl ligand Organometallics. 27: 2223-2230. DOI: 10.1021/om701162h  1
2008 Bazinet P, Tilley TD. Octa- and nonamethylfluorenyl complexes of Zr(II), Zr(IV), and Hf(IV). Investigation of steric and electronic effects Organometallics. 27: 1267-1274. DOI: 10.1021/om701133e  1
2008 Fischbach A, Bazinet PR, Waterman R, Tilley TD. β-phosphinoethylboranes as ambiphilic ligands in nickel-methyl complexes Organometallics. 27: 1135-1139. DOI: 10.1021/om7010886  1
2008 Ruddy DA, Jarupatrakorn J, Rioux RM, Miller JT, McMurdo MJ, McBee JL, Tupper KA, Don Tilley T. Site-isolated Pt-SBA15 materials from tris(tert-butoxy)siloxy complexes of Pt(II) and Pt(IV) Chemistry of Materials. 20: 6517-6527. DOI: 10.1021/cm801598k  0.6
2008 Fujdala KL, Tilley DD. Tailoring Properties of Silicon-Containing Oxide Catalysts Via the Thermolytic Molecular Precursor Route Organosilicon Chemistry I: From Molecules to Materials. 379-388. DOI: 10.1002/9783527620777.ch65d  1
2008 Tilley TD. New Chemistry for Reactive Transition-Metal Silicon Bonds Organosilicon Chemistry I: From Molecules to Materials. 225-230. DOI: 10.1002/9783527620777.ch49  1
2008 Sun J, Tilley TD, Segalman RA. Perylene-thiophene based donor-acceptor oligomers for molecular scale photovoltaics Aiche Annual Meeting, Conference Proceedings 1
2007 Ruddy DA, Tilley TD. Highly selective olefin epoxidation with aqueous H2O2 over surface-modified TaSBA15 prepared via the TMP method. Chemical Communications (Cambridge, England). 3350-2. PMID 18019495 DOI: 10.1039/b706443h  1
2007 Tannaci JF, Noji M, McBee J, Tilley TD. 9,10-Dichlorooctafluoroanthracene as a building block for n-type organic semiconductors. The Journal of Organic Chemistry. 72: 5567-73. PMID 17590045 DOI: 10.1021/jo070404a  1
2007 Waterman R, Hayes PG, Tilley TD. Synthetic development and chemical reactivity of transition-metal silylene complexes. Accounts of Chemical Research. 40: 712-9. PMID 17477497 DOI: 10.1002/chin.200744223  1
2007 Hoefelmeyer JD, Liu H, Somorjai GA, Tilley TD. Reverse micelle synthesis of rhodium nanoparticles. Journal of Colloid and Interface Science. 309: 86-93. PMID 17229435 DOI: 10.1016/j.jcis.2006.12.060  1
2007 Sangtrirutnugul P, Tilley TD. Silyl derivatives of [Bis(8-quinolyl)methylsilyl]iridium(III) complexes: Catalytic redistribution of arylsilanes and dehydrogenative arene silylation Organometallics. 26: 5557-5568. DOI: 10.1021/om700494q  1
2007 Bradley CA, McMurdo MJ, Tilley TD. Selective catalytic cyclohexene oxidation using titanium-functionalized silicone nanospheres? Journal of Physical Chemistry C. 111: 17570-17579. DOI: 10.1021/jp074512c  1
2007 Borodko Y, Humphrey SM, Tilley TD, Frei H, Somorjai GA. Charge-transfer interaction of poly(vinylpyrrolidone) with platinum and rhodium nanoparticles Journal of Physical Chemistry C. 111: 6288-6295. DOI: 10.1021/jp068742n  1
2006 Waterman R, Tilley TD. Antimony-antimony bond formation by reductive elimination from a hafnium bis(stibido) complex. Inorganic Chemistry. 45: 9625-7. PMID 17112252 DOI: 10.1021/ic061826q  1
2006 Han LB, Tilley TD. Selective homo- and heterodehydrocouplings of phosphines catalyzed by rhodium phosphido complexes. Journal of the American Chemical Society. 128: 13698-9. PMID 17044692 DOI: 10.1021/ja065346+  1
2006 Waterman R, Tilley TD. Terminal stibinidene ligands. Generation of CpCp*Hf=Sb(dmp) and trapping reactions with PMe3 and 2-butyne. Chemical Communications (Cambridge, England). 4030-2. PMID 17003889 DOI: 10.1039/b609773a  1
2006 Waterman R, Tilley TD. Catalytic antimony-antimony bond formation through stibinidene elimination from zirconocene and hafnocene complexes. Angewandte Chemie (International Ed. in English). 45: 2926-9. PMID 16555350 DOI: 10.1002/anie.200600318  1
2006 Hayes PG, Beddie C, Hall MB, Waterman R, Tilley TD. Hydrogen-substituted osmium silylene complexes: effect of charge localization on catalytic hydrosilation. Journal of the American Chemical Society. 128: 428-9. PMID 16402827 DOI: 10.1021/ja057494q  1
2006 Barros N, Eisenstein O, Maron L, Tilley TD. DFT investigation of the catalytic hydromethylation of α-olefins by metallocenes. 1. Differences between scandium and lutetium in propene hydromethylation Organometallics. 25: 5699-5708. DOI: 10.1021/om060498z  1
2006 Karshtedt D, Bell AT, Don Tilley T. Stoichiometric and catalytic reactions involving Si-H bond activations by Rh and Ir complexes containing a pyridylindolide ligand Organometallics. 25: 4471-4482. DOI: 10.1021/om060492+  0.92
2006 Bazinet P, Tupper KA, Tilley TD. Octa- and nonamethylfluorene and an electron-rich permethylfluorenyl ruthenocene derivative Organometallics. 25: 4286-4291. DOI: 10.1021/om0603464  1
2006 Gaderbauer W, Zirngast M, Baumgartner J, Marschner C, Tilley TD. Synthesis of polysilanylmagnesium compounds Organometallics. 25: 2599-2606. DOI: 10.1021/om060147k  1
2006 Karshtedt D, McBee JL, Bell AT, Don Tilley T. Stoichiometric and catalytic arene activations by platinum complexes containing bidentate monoanionic nitrogen-based ligands Organometallics. 25: 1801-1811. DOI: 10.1021/om0600902  0.96
2006 Sangtrirutnugul P, Stradiotto M, Don Tilley T. Rhodium complexes containing a tridentate bis(8-quinolyl)methylsilyl ligand: Synthesis and reactivity Organometallics. 25: 1607-1617. DOI: 10.1021/om050859v  0.88
2006 Geramita K, McBee J, Shen Y, Radu N, Tilley TD. Synthesis and characterization of perfluoroaryl-substituted siloles and thiophenes: A series of electron-deficient blue light emitting materials Chemistry of Materials. 18: 3261-3269. DOI: 10.1021/cm060346u  1
2006 Fontaine FG, Tupper KA, Tilley TD. Synthesis, characterization and reactivity of tetramethylphospholyl complexes of scandium Journal of Organometallic Chemistry. 691: 4595-4600. DOI: 10.1016/j.jorganchem.2006.06.042  1
2006 Ruddy DA, Ohler NL, Bell AT, Tilley TD. Thermolytic molecular precursor route to site-isolated vanadia-silica materials and their catalytic performance in methane selective oxidation Journal of Catalysis. 238: 277-285. DOI: 10.1016/j.jcat.2005.11.032  1
2005 Neale NR, Tilley TD. Synthesis, structure, and alpha-elimination chemistry of hafnocene triarylstannyl complexes. Journal of the American Chemical Society. 127: 14745-55. PMID 16231929 DOI: 10.1021/ja0529586  1
2005 Brutchey RL, Ruddy DA, Andersen LK, Tilley TD. Influence of surface modification of Ti-SBA15 catalysts on the epoxidation mechanism for cyclohexene with aqueous hydrogen peroxide. Langmuir : the Acs Journal of Surfaces and Colloids. 21: 9576-83. PMID 16207038 DOI: 10.1021/la051182j  0.84
2005 Karshtedt D, Bell AT, Tilley TD. Platinum-based catalysts for the hydroamination of olefins with sulfonamides and weakly basic anilines. Journal of the American Chemical Society. 127: 12640-6. PMID 16144412 DOI: 10.1021/ja052836d  1
2005 Brutchey RL, Drake IJ, Bell AT, Tilley TD. Liquid-phase oxidation of alkylaromatics by a H-atom transfer mechanism with a new heterogeneous CoSBA-15 catalyst. Chemical Communications (Cambridge, England). 3736-8. PMID 16027928 DOI: 10.1039/b506426k  1
2005 Hoefelmeyer JD, Niesz K, Somorjai GA, Tilley TD. Radial anisotropic growth of rhodium nanoparticles. Nano Letters. 5: 435-8. PMID 15755090 DOI: 10.1021/nl048100g  1
2005 Sadow AD, Tilley TD. Synthesis and characterization of scandium silyl complexes of the type Cp*2ScSiHRR'. sigma-Bond metathesis reactions and catalytic dehydrogenative silation of hydrocarbons. Journal of the American Chemical Society. 127: 643-56. PMID 15643889 DOI: 10.1021/ja040141r  1
2005 Fontaine FG, Tilley TD. Control of selectivity in the hydromethylation of olefins via ligand modification in scandocene catalysts Organometallics. 24: 4340-4342. DOI: 10.1021/om0505460  1
2005 Jarupatrakorn J, Coles MP, Tilley TD. Synthesis and characterization of MO[OSi(OtBu)3] 4 and MO2[OSt(O≤Bu)3]2 (M = Mo, W): Models for isolated oxo-molybdenum and -tungsten sites on silica and precursors to molybdena- And tungsta-silica materials Chemistry of Materials. 17: 1818-1828. DOI: 10.1021/cm040344e  1
2005 Brutchey RL, Mork BV, Sirbuly DJ, Yang P, Tilley TD. A dimeric molecular precursor [(tBuO)2Ti{μ-O 2Si[OSi(OtBu)3]2}]2 to Ti(IV)/SiO2 catalysts for selective cyclohexene epoxidation Journal of Molecular Catalysis a: Chemical. 238: 1-12. DOI: 10.1016/j.molcata.2005.04.032  1
2005 Tupper KA, Tilley TD. Synthesis and characterization of scandium complexes with reduced ligands: Crystal structures of Cp*ScI2, [C*ScI(bpy)]2, and [Cp*ScCl(bpy)]2 Journal of Organometallic Chemistry. 690: 1689-1698. DOI: 10.1016/j.jorganchem.2005.01.017  1
2005 Holland AW, Li G, Shahin AM, Long GJ, Bell AT, Tilley TD. New Fe/SiO2 materials prepared using diiron molecular precursors: Synthesis, characterization and catalysis Journal of Catalysis. 235: 150-163. DOI: 10.1016/j.jcat.2005.07.003  1
2005 Brutchey RL, Lugmair CG, Schebaum LO, Tilley TD. Thermolytic conversion of a bis(alkoxy)tris(siloxy)tantalum(V) single-source molecular precursor to catalytic tantala-silica materials Journal of Catalysis. 229: 72-81. DOI: 10.1016/j.jcat.2004.10.015  1
2005 Drake IJ, Fujdala KL, Bell AT, Tilley TD. Dimethyl carbonate production via the oxidative carbonylation of methanol over Cu/SiO2 catalysts prepared via molecular precursor grafting and chemical vapor deposition approaches Journal of Catalysis. 230: 14-27. DOI: 10.1016/j.jcat.2004.10.001  1
2005 Hess C, Drake IJ, Hoefelmeyer JD, Tilley TD, Bell AT. Partial oxidation of methanol over highly dispersed vanadia supported on silica SBA-15 Catalysis Letters. 105: 1-8. DOI: 10.1007/s10562-005-7997-x  1
2005 Fujdala KL, Tilley TD. Synthesis and characterization of Et2NM{OB[OSi(O tBu)3]2}3 (M = Zr, Hf) molecular precursors to Zr/B/Si/O and Hf/B/Si/O materials Zeitschrift Fur Anorganische Und Allgemeine Chemie. 631: 2619-2622. DOI: 10.1002/zaac.200500128  1
2005 Hoefelmeyer JD, Rioux RM, Tilley TD, Somorjai GA. CO Hydrogenation on Rh/SBA-15 materials: A study of particle size effects Acs National Meeting Book of Abstracts. 229: INOR-824.  1
2005 Ruddy DA, Ohler NL, Bell AT, Tilley TD. Thermolytic molecular precursor route to site-isolated vanadia-silica catalyts for methane partial oxidation Acs National Meeting Book of Abstracts. 229: INOR-841.  1
2004 Jarupatrakorn J, Tilley TD. Synthesis and characterization of [(diene)Rh[mu-OSi(OtBu)3]]2, a precursor to silica-bound rhodium. Dalton Transactions (Cambridge, England : 2003). 2808-13. PMID 15514769 DOI: 10.1039/B407398C  1
2004 Krumper JR, Gerisch M, Magistrato A, Rothlisberger U, Bergman RG, Tilley TD. Unusual Ar-H/Rh-H J(HH) NMR coupling in complexes of rhodium(III): experimental evidence and theoretical support for an eta1-arene structure. Journal of the American Chemical Society. 126: 12492-502. PMID 15453783 DOI: 10.1021/ja047665b  1
2004 Fujdala KL, Drake IJ, Bell AT, Tilley TD. Atomic level control over surface species via a molecular precursor approach: isolated Cu(I) sites and Cu nanoparticles supported on mesoporous silica. Journal of the American Chemical Society. 126: 10864-6. PMID 15339170 DOI: 10.1021/ja048701+  1
2004 Mork BV, Tilley TD, Schultz AJ, Cowan JA. Silylene hydride complexes of molybdenum with silicon-hydrogen interactions: neutron structure of (eta(5)-C(5)Me(5))(Me(2)PCH(2)CH(2)PMe(2))Mo(H)(SiEt(2)). Journal of the American Chemical Society. 126: 10428-40. PMID 15315459 DOI: 10.1021/ja040026g  1
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. silicon-carbon bond activations of PhSiH(3) by silyl complexes. Inorganic Chemistry. 43: 4353-62. PMID 15236548 DOI: 10.1021/ic030282e  1
2004 Mork BV, Tilley TD. Synthons for coordinatively unsaturated complexes of tungsten, and their use for the synthesis of high oxidation-state silylene complexes. Journal of the American Chemical Society. 126: 4375-85. PMID 15053627 DOI: 10.1021/ja030548g  1
2004 Leites LA, Bukalov SS, Garbuzova IA, Feldman JD, Don Tilley T. Probing the structure of the silylene complex (Cy3P)2Pt=SiMes2.; UV-Vis and pre-resonance Raman investigations. Spectrochimica Acta. Part a, Molecular and Biomolecular Spectroscopy. 60: 801-4. PMID 15036090 DOI: 10.1016/S1386-1425(03)00303-2  0.48
2004 Karshtedt D, Bell AT, Tilley TD. Pt-Ag catalyst system for hydroarylations with unactivated arenes and olefins Acs National Meeting Book of Abstracts. 228: INOR-45. DOI: 10.1021/om0495325  1
2004 Glaser PB, Don Tilley T. Synthesis and reactivity of silyl and silylene ligands in the coordination sphere of the 14-electron fragment Cp*( iPr 3P)Os + Organometallics. 23: 5799-5812. DOI: 10.1021/om040062o  0.92
2004 Glaser PB, Wanandi PW, Don Tilley T. Synthesis, structure, and reactivity of osmium silyl and silylene complexes Cp*(Me3P)2OsSiR2X and [Cp*(Me3P)2OsSiR2][B(C6F5 )4] (R = Me, iPr; X = Cl, OTf) Organometallics. 23: 693-704. DOI: 10.1021/om0341808  0.92
2004 Mork BV, McMillan A, Yuen H, Tilley TD. The [(η 5-C 5Me 5)(2,2′-bipyridine) ru] - anion and its use in the synthesis of alkyl, gallyl, and stannyl complexes of ruthenium Organometallics. 23: 2855-2859. DOI: 10.1021/om030695n  1
2004 Turculet L, Feldman JD, Tilley TD. Coordination chemistry and reactivity of new zwitterionic rhodium and iridium complexes featuring the tripodal phosphine ligand [PhB(CH 2P iPr 2) 3] -. Activation of H-H, Si-H, and ligand B-C bonds Organometallics. 23: 2488-2502. DOI: 10.1021/om030686e  1
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of alkyl, hydride, and silyl derivatives of the (terphenyl)imido fragments Cp*(ArMesN=)Ta (Cp* = η5-C5Me5 (see abstract) Organometallics. 23: 31-43. DOI: 10.1021/om030567z  1
2004 Han WQ, Brutchey R, Tilley TD, Zettl A. Activated Boron Nitride Derived from Activated Carbon Nano Letters. 4: 173-176. DOI: 10.1021/nl034843a  1
2004 Drake IJ, Fujdala KL, Baxamusa S, Bell AT, Tilley TD. Effects of precursor composition on the local structure of Cu dispersed on mesoporous silica: A detailed X-ray absorption spectroscopy study Journal of Physical Chemistry B. 108: 18421-18434. DOI: 10.1021/jp040255p  1
2004 Fujdala KL, Don Tilley T. Dimolybdenum(III) Complexes of -OSi(OtBu)3, -O 2P(OtBu)2, and -OB[OSi(OtBu) 3]2 as Single-Source Molecular Precursors to Molybdenum-Containing, Multi-Component Oxide Materials Chemistry of Materials. 16: 1035-1047. DOI: 10.1021/cm030563k  0.96
2004 Neale NR, Tilley TD. Reactions of hafnocene stannyl complexes with stannanes: Implications for the mechanism of the metal-catalyzed dehydropolymerization of secondary stannanes Tetrahedron. 60: 7247-7260. DOI: 10.1016/j.tet.2004.06.064  1
2004 Gavenonis J, Don Tilley T. Synthesis and reactivity of bis(heptamethylindenyl) yttrium (Ind*2Y) complexes containing alkyl and hydride ligands: Crystal structure of Ind*2YCl(THF) Journal of Organometallic Chemistry. 689: 870-878. DOI: 10.1016/j.jorganchem.2003.11.033  0.96
2004 Evans OR, Bell AT, Tilley TD. Oxidative dehydrogenation of propane over vanadia-based catalysts supported on high-surface-area mesoporous MgAl2O4 Journal of Catalysis. 226: 292-300. DOI: 10.1016/j.jcat.2004.06.002  1
2004 Dai H, Chen L, Tilley TD, Iglesia E, Bell AT. Effects of additives on the activity and selectivity of supported vanadia catalysts for the oxidative dehydrogenation of propane Studies in Surface Science and Catalysis. 147: 679-684.  1
2004 Lugmair CG, Tilley TD. Synthesis and reactivity of Ti(III) Tris(tert-butoxy)siloxy complexes Zeitschrift Fur Naturforschung - Section B Journal of Chemical Sciences. 59: 1540-1547.  1
2004 Bell AT, Drake IJ, Fujdala KL, Tilley TD. Effects of Cu dispersion and oxidation state on the activity and selectivity of silica-supported Cu for the synthesis of dimethyl carbonate Acs National Meeting Book of Abstracts. 228: CATL-1.  1
2004 Karshtedt D, Bell AT, Tilley TD. Pt-Ag catalyst system for hydroarylations with unactivated arenes and olefins Acs National Meeting Book of Abstracts. 228: INOR-45.  1
2004 Gavenonis J, Tilley TD. Synthesis and reactivity of tris(imido)rhenium complexes containing rhenium-main group element bonds. Silicon-carbon bond activations of PhSiH 3 by silyl complexes Inorganic Chemistry. 43: 4353-4362.  1
2004 Turculet L, Tilley TD. Synthesis and reactivity of d0 alkyl, silyl, and hydride complexes of titanium and zirconium featuring an aryl-substituted tripodal triamido ligand derived from cis, cis-1,3,5-triaminocyclohexane Organometallics. 23: 1542-1553.  1
2003 Krumper JR, Gerisch M, Suh JM, Bergman RG, Tilley TD. Monomeric rhodium(II) catalysts for the preparation of aziridines and enantioselective formation of cyclopropanes from ethyl diazoacetate at room temperature. The Journal of Organic Chemistry. 68: 9705-10. PMID 14656097 DOI: 10.1021/jo035120e  1
2003 Glaser PB, Tilley TD. Catalytic hydrosilylation of alkenes by a ruthenium silylene complex. Evidence for a new hydrosilylation mechanism. Journal of the American Chemical Society. 125: 13640-1. PMID 14599184 DOI: 10.1021/ja037620v  1
2003 Sadow AD, Tilley TD. Cationic hafnium silyl complexes and their enhanced reactivity in sigma-bond metathesis processes with Si-H and C-H bonds. Journal of the American Chemical Society. 125: 9462-75. PMID 12889977 DOI: 10.1021/ja030024g  1
2003 Sadow AD, Tilley TD. Homogeneous catalysis with methane. A strategy for the hydromethylation of olefins based on the nondegenerate exchange of alkyl groups and sigma-bond metathesis at scandium. Journal of the American Chemical Society. 125: 7971-7. PMID 12823019 DOI: 10.1021/ja021341a  1
2003 Johnson SA, Liu FQ, Suh MC, Zürcher S, Haufe M, Mao SS, Tilley TD. Regioselective coupling of pentafluorophenyl substituted alkynes: mechanistic insight into the zirconocene coupling of alkynes and a facile route to conjugated polymers bearing electron-withdrawing pentafluorophenyl substituents. Journal of the American Chemical Society. 125: 4199-211. PMID 12670242 DOI: 10.1021/ja0209161  1
2003 Sadow AD, Tilley TD. Catalytic functionalization of hydrocarbons by sigma-bond-metathesis chemistry: dehydrosilylation of methane with a scandium catalyst. Angewandte Chemie (International Ed. in English). 42: 803-5. PMID 12596205 DOI: 10.1002/anie.200390213  1
2003 Fujdala KL, Oliver AG, Hollander FJ, Tilley TD. Tris(tert-butoxy)siloxy derivatives of boron, including the boronous acid HOB[OSi(O(t)Bu)(3)](2) and the metal (siloxy)boryloxide complex Cp(2)Zr(Me)OB[OSi(O(t)Bu)(3)](2): a remarkable crystal structure with 18 independent molecules in its asymmetric unit. Inorganic Chemistry. 42: 1140-50. PMID 12588150 DOI: 10.1021/ic0205482  1
2003 Mork BV, Tilley TD. Multiple bonding between silicon and molybdenum: a transition-metal complex with considerable silylyne character. Angewandte Chemie (International Ed. in English). 42: 357-60. PMID 12548699 DOI: 10.1002/anie.200390116  1
2003 Feldman JD, Mitchell GP, Nolte JO, Tilley TD. Synthesis and study of platinum silylene complexes of the type (R 3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl) Canadian Journal of Chemistry. 81: 1127-1136. DOI: 10.1139/v03-018  1
2003 Turculet L, Feldman JD, Tilley TD. Coordinatively and electronically unsaturated zwitterionic iron silyl complexes featuring the tripodal phosphine ligand [PhB(CH2PiPr2)3]- Organometallics. 22: 4627-4629. DOI: 10.1021/om030568r  1
2003 Karshtedt D, Bell AT, Tilley TD. Synthesis and study of heterobimetallic complexes supported by a ferrocene-based bisphosphine-diamine ligand Organometallics. 22: 2855-2861. DOI: 10.1021/om0300631  1
2003 Sadow AD, Tilley TD. Enhanced reactivity of cationic hafnocene complexes toward σ-bond metathesis reactions. Si-H and Si-C bond activations in stoichiometric and catalytic organosilane conversions Organometallics. 22: 3577-3585. DOI: 10.1021/om0210107  1
2003 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Rhodium(III) and rhodium(II) complexes of novel bis(oxazoline) pincer ligands Organometallics. 22: 47-58. DOI: 10.1021/om0207562  1
2003 Brutchey RL, Goldberger JE, Koffas TS, Tilley TD. Nonaqueous, molecular precursor route to hybrid inorganic/organic zirconia-silica materials containing covalently linked organic bridges Chemistry of Materials. 15: 1040-1046. DOI: 10.1021/cm020653+  1
2003 Nitschke JR, Don Tilley T. Convenient, zirconocene-coupling routes to germole- and thiophene-containing macrocycles with triangular geometries Journal of Organometallic Chemistry. 666: 15-22. DOI: 10.1016/S0022-328X(02)02028-4  0.88
2003 Fujdala KL, Tilley TD. Thermolytic molecular precursor routes to Cr/Si/Al/O and Cr/Si/Zr/O catalysts for the oxidative dehydrogenation and dehydrogenation of propane Journal of Catalysis. 218: 123-134. DOI: 10.1016/S0021-9517(03)00141-6  1
2003 Fujdala KL, Tilley TD. Design and synthesis of heterogeneous catalysts: The thermolytic molecular precursor approach Journal of Catalysis. 216: 265-275. DOI: 10.1016/S0021-9517(02)00106-9  1
2002 Nozaki C, Lugmair CG, Bell AT, Tilley TD. Synthesis, characterization, and catalytic performance of single-site iron(III) centers on the surface of SBA-15 silica. Journal of the American Chemical Society. 124: 13194-203. PMID 12405848  1
2002 Gavenonis J, Tilley TD. Reversible intramolecular hydride transfer between tantalum and an aromatic ring: an eta(5)-cyclohexadienyl complex as a masked hydride. Journal of the American Chemical Society. 124: 8536-7. PMID 12121088 DOI: 10.1021/ja025684k  1
2002 Sadow AD, Tilley TD. Activation of arene C[bond]H bonds by a cationic hafnium silyl complex possessing an alpha-agostic Si[bond]H interaction. Journal of the American Chemical Society. 124: 6814-5. PMID 12059188 DOI: 10.1021/ja025940t  1
2002 Neale NR, Tilley TD. A new mechanism for metal-catalyzed stannane dehydrocoupling based on alpha-H-elimination in a hafnium hydrostannyl complex. Journal of the American Chemical Society. 124: 3802-3. PMID 11942796 DOI: 10.1021/ja017495s  1
2002 Klei SR, Golden JT, Tilley TD, Bergman RG. Iridium-catalyzed H/D exchange into organic compounds in water. Journal of the American Chemical Society. 124: 2092-3. PMID 11878944 DOI: 10.1021/ja017219d  1
2002 Schafer LL, Nitschke JR, Mao SS, Liu FQ, Harder G, Haufe M, Tilley TD. Zirconocene-mediated, high-yielding macrocyclizations of silyl-terminated diynes. Chemistry (Weinheim An Der Bergstrasse, Germany). 8: 74-83. PMID 11826866 DOI: 10.1002/1521-3765(20020104)8:1<74::AID-CHEM74>3.0.CO;2-P  1
2002 Gavenonis J, Tilley TD. Tantalum alkyl and silyl complexes of the bulky (terphenyl)imido ligand Organometallics. 21: 5549-5563. DOI: 10.1021/om020509y  1
2002 Feldman JD, Peters JC, Tilley TD. Structural and chemical properties of zwitterionic iridium complexes featuring the tripodal phosphine ligand [PhB(CH2PPh2)3]- Organometallics. 21: 4050-4064. DOI: 10.1021/om0205086  1
2002 Turculet L, Tilley TD. Zirconium amide, halide, and alkyl complexes supported by tripodal amido ligands derived from cis,cis-1,3,5-triaminocyclohexane Organometallics. 21: 3961-3972. DOI: 10.1021/om020414w  1
2002 Feldman JD, Peters JC, Don Tilley T. Activations of silanes with [PhB(CH2PPh2)3]Ir(H)(η3-C8 H13). Formation of iridium silylene complexes via the extrusion of silylenes from secondary silanes R2SiH2 Organometallics. 21: 4065-4075. DOI: 10.1021/om020389u  0.96
2002 Klei SR, Tilley TD, Bergman RG. Iridium (III) and rhodium (III) complexes bearing chelating cyclopentadienyl-phosphine ligands as C-H activation catalysts for the deuteration of hydrocarbons in D2O Organometallics. 21: 4905-4911. DOI: 10.1021/om020375o  1
2002 Burckhardt U, Casty GL, Gavenonis J, Tilley TD. Neutral and anionic silyl hydride derivatives of the tantalum imido fragment Cp*(DippN=)Ta (Cp* = η5-C5Me5; Dipp = 2,6-iPr2C6H3). Reactive σ-bonds and intramolecular C-H bond activations involving the silyl ligands Organometallics. 21: 3108-3122. DOI: 10.1021/om0203227  1
2002 Klei SR, Don Tilley T, Bergman RG. Reactions of Cp*(PMe3)Ir(Me)OTf with silanes: Role of base-free silylene complexes in rearrangements of the resulting silicon-based ligands Organometallics. 21: 3376-3387. DOI: 10.1021/om020191+  0.92
2002 Freeman WP, Dysard JM, Tilley TD, Rheingold AL. Synthesis and reactivity of η5-germacyclopentadienyl complexes of iron Organometallics. 21: 1734-1738. DOI: 10.1021/om0110991  1
2002 Schultz M, Boncella JM, Berg DJ, Don Tilley T, Andersen RA. Coordination of 2,2′-bipyridyl and 1,10-phenanthroline to substituted ytterbocenes: An experimental investigation of spin coupling in lanthanide complexes Organometallics. 21: 460-472. DOI: 10.1021/om010661k  0.88
2002 Fujdala KL, Tilley TD. New vanadium tris(tert-butoxy)siloxy complexes and their thermolytic conversions to vanadia-silica materials Chemistry of Materials. 14: 1376-1384. DOI: 10.1021/cm011524g  1
2002 Lugmair CG, Fujdala KL, Tilley TD. New tris(tert-butoxy)siloxy complexes of aluminum and their transformation to homogeneous aluminosilicate materials via low-temperature thermolytic pathways Chemistry of Materials. 14: 888-898. DOI: 10.1021/cm010846h  1
2002 Tilley TD. Molecular design and synthesis of heterogeneous and single-site, supported catalysts Journal of Molecular Catalysis a: Chemical. 182: 17-24. DOI: 10.1016/S1381-1169(01)00461-7  1
2002 Heyn RH, Tilley TD. Coordinatively and electronically unsaturated tris(trimethylsilyl)silyl complexes of manganese and iron Inorganica Chimica Acta. 341: 91-98. DOI: 10.1016/S0020-1693(02)01182-9  1
2002 Pak C, Bell AT, Tilley TD. Oxidative dehydrogenation of propane over vanadia-magnesia catalysts prepared by thermolysis of OV(OtBu)3 in the presence of nanocrystalline MgO Journal of Catalysis. 206: 49-59. DOI: 10.1006/jcat.2001.3473  1
2001 Nitschke JR, Tilley TD. Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling. Angewandte Chemie (International Ed. in English). 40: 2142-2145. PMID 29712218 DOI: 10.1002/1521-3773(20010601)40:11<2142::AID-ANIE2142>3.0.CO;2-3  1
2001 Castillo I, Tilley TD. Mechanistic aspects of samarium-mediated sigma-bond activations of arene C-H and arylsilane Si-C bonds. Journal of the American Chemical Society. 123: 10526-34. PMID 11673984 DOI: 10.1021/ja011472w  1
2001 Nitschke JR, Tilley TD. Efficient, high-yield route to long, functionalized p-phenylene oligomers containing perfluorinated segments, and their cyclodimerizations by zirconocene coupling. Journal of the American Chemical Society. 123: 10183-90. PMID 11603967 DOI: 10.1021/ja011018s  1
2001 Fujdala KL, Tilley TD. An efficient, single-source molecular precursor to silicoaluminophosphates. Journal of the American Chemical Society. 123: 10133-4. PMID 11592907 DOI: 10.1021/ja0167295  1
2001 Mork BV, Tilley TD. High oxidation-state (formally d(0)) tungsten silylene complexes via double Si-H bond activation. Journal of the American Chemical Society. 123: 9702-3. PMID 11572703 DOI: 10.1021/ja0165436  1
2001 Payne CK, Snee PT, Yang H, Kotz KT, Schafer LL, Tilley TD, Harris CB. Intramolecular rearrangements on ultrafast timescales: femtosecond infrared studies of ring slip in (eta(1)-C(5)Cl(5))Mn(CO)(5). Journal of the American Chemical Society. 123: 7425-6. PMID 11472175 DOI: 10.1021/ja003905l  1
2001 Schafer LL, Tilley TD. Efficient diastereoselective syntheses of chiral macrocycles via zirconocene coupling. Synthetic control of size and geometry. Journal of the American Chemical Society. 123: 2683-4. PMID 11456946 DOI: 10.1021/ja015509o  1
2001 Nitschke JR, Tilley TD. Novel Templating Effect in the Macrocyclization of Functionalized Diynes by Zirconocene Coupling This work was supported by the Director, Office of Basic Energy Sciences, Chemical Sciences Division, of the U.S. Department of Energy under Contract No. DE-AC03-76SF00098. The Center for New Directions in Organic Synthesis is supported by Bristol-Myers Squibb as Sponsoring Member. We also thank Dr. F. J. Hollander of the U.C. Berkeley X-ray diffraction facility (CHEXRAY) for help with determination of the X-ray structures. Angewandte Chemie (International Ed. in English). 40: 2142-2145. PMID 11433471 DOI: 10.1002/1521-3773(20010601)40:11<2142::AID-ANIE2142>3.0.CO;2-3  1
2001 Gerisch M, Krumper JR, Bergman RG, Tilley TD. Novel bis(oxazoline) pincer ligands: formation of mononuclear rhodium(II) complexes. Journal of the American Chemical Society. 123: 5818-9. PMID 11403623 DOI: 10.1021/ja005857a  1
2001 Kriesel JW, Tilley TD. A new molecular precursor for magnesia-silica materials Journal of Materials Chemistry. 11: 1081-1085. DOI: 10.1039/b007742i  1
2001 Nakamoto M, Tilley TD. Reactions of zirconacyclopentadienes with nitrosobenzene. Characterization of zirconacycle intermediates and formation of N-phenylpyrroles Organometallics. 20: 5515-5517. DOI: 10.1021/om010873h  1
2001 Sadow AD, Tilley TD. Enhanced reactivity of cationic vs neutral hafnocene complexes in stoichiometric and catalytic σ-bond metathesis reactions involving Si-H and Si-C bonds Organometallics. 20: 4457-4459. DOI: 10.1021/om010737c  1
2001 Castillo I, Tilley TD. Organolutetium complexes in σ-bond metathesis reactions involving silicon. Catalysts for the hydrogenolysis of Si-C bonds Organometallics. 20: 5598-5605. DOI: 10.1021/om010709u  1
2001 Dysard JM, Tilley TD, Woo TK. Silabenzene and disilabenzene complexes of ruthenium Organometallics. 20: 1195-1203. DOI: 10.1021/om000829m  1
2001 Kriesel JW, Sander MS, Tilley TD. Block copolymer-assisted synthesis of mesoporous, multicomponent oxides by nonhydrolytic, thermolytic decomposition of molecular precursors in nonpolar media Chemistry of Materials. 13: 3554-3563. DOI: 10.1021/cm010068t  1
2001 Fujdala KL, Tilley TD. Thermolytic transformation of tris(alkoxy)siloxychromium(IV) single-source molecular precursors to catalytic chromia-silica materials Chemistry of Materials. 13: 1817-1827. DOI: 10.1021/cm010027x  1
2001 Stradiotto M, Fujdala KL, Don Tilley T. Generation and reactivity of {(ethane-1,2-diyl)-bis[diisopropylphosphine-κP]}-{[2,4,6-tri (tert-butyl)phenyl]phosphino-κP}rhodium ([Rh{PH(1Bu3C6H2)} (iPr2PCH2CH2PiPr 2)]): Catalytic C-P bond formation via intramolecular C-H/P-H dehydrogenative cross-coupling Helvetica Chimica Acta. 84: 2958-2970. DOI: 10.1002/1522-2675(20011017)84:10<2958::AID-HLCA2958>3.0.CO;2-L  0.96
2001 Kriesel JW, Tilley TD. Carbosilane dendrimers as nanoscopic building blocks for hybrid organic-inorganic materials and catalyst supports Advanced Materials. 13: 1645-1648. DOI: 10.1002/1521-4095(200111)13:21<1645::AID-ADMA1645>3.0.CO;2-1  1
2001 Kriesel JW, Sander MS, Tilley TD. General route to homogeneous, mesoporous, multicomponent oxides based on the thermolytic transformation of molecular precursors in non-polar media Advanced Materials. 13: 331-335. DOI: 10.1002/1521-4095(200103)13:5<331::AID-ADMA331>3.0.CO;2-0  1
2000 Dysard JM. Tantalum-mediated substitution at germanium: A germolyl-to-germole transformation leading to η4-C4Me4GeMeCl complexes Organometallics. 19: 4720-4725. DOI: 10.1021/om000518b  1
2000 Lucht BL, Buretea MA, Don Tilley T. Poly(2,5-diphenylgermole): incorporation of a germole ring into a conjugated polymer Organometallics. 19: 3469-3475. DOI: 10.1021/om000191e  0.6
2000 Lu VY, Tilley TD. Poly(diaryl)stannanes: Influence of substituents on the σ-σ* transition energy Macromolecules. 33: 2403-2412. DOI: 10.1021/ma991556d  1
2000 Dysard JM, Tilley TD. Synthesis and reactivity of η5-silolyl, η5-germolyl, and η5- germole dianion complexes of zirconium and hafnium Journal of the American Chemical Society. 122: 3097-3105. DOI: 10.1021/ja993563n  1
2000 Wanandi PW, Glaser PB, Tilley TD. Reactivity of an osmium silylene complex toward chlorocarbons: Promotion of metal redox chemistry by a silylene ligand and relevance to the mechanism of the direct process [12] Journal of the American Chemical Society. 122: 972-973. DOI: 10.1021/ja993089l  1
2000 Klei SR, Tilley TD, Bergman RG. The mechanism of silicon-hydrogen and carbon-hydrogen bond activation by iridium(III): Production of a silylene complex and the first direct observation of Ir(III)/Ir(V) C-H bond oxidative addition and reductive elimination [8] Journal of the American Chemical Society. 122: 1816-1817. DOI: 10.1021/ja992954z  1
2000 Nitschke JR, Zurcher S, Tilley TD. New zirconocene-coupling route to large, functionalized macrocycles Journal of the American Chemical Society. 122: 10345-10352. DOI: 10.1021/ja0020310  1
2000 Kriesel JW, Don Tilley T. Synthesis and chemical functionalization of high surface area dendrimer-based xerogels and their use as new catalyst supports Chemistry of Materials. 12: 1171-1179. DOI: 10.1021/cm000098g  0.96
2000 Male JL, Niessen HG, Bell AT, Don Tilley T. Thermolytic molecular precursor route to active and selective vanadia-zirconia catalysts for the oxidative dehydrogenation of propane Journal of Catalysis. 194: 431-444. DOI: 10.1006/jcat.2000.2938  0.4
1999 Peters JC, Feldman JD, Tilley TD. Silylene extrusion from a silane: Direct conversion of Mes2SiH2 to an iridium silylene dihydride [1] Journal of the American Chemical Society. 121: 9871-9872. DOI: 10.1021/ja992367d  1
1999 Jiang B, Tilley TD. General, efficient route to thiophene-1-oxides and well-defined, mixed thiophene-thiophene-1-oxide oligomers [12] Journal of the American Chemical Society. 121: 9744-9745. DOI: 10.1021/ja992365t  1
1999 Burckhardt U, Tilley TD. Carbonylation chemistry of the tantalum silyl hydride Cp*(2,6- (i)Pr2C6H3N=)Ta[Si(SiMe3)3]H: The unexpected formation of a Ta(V) carbonyl complex and the complete reduction of CO [12] Journal of the American Chemical Society. 121: 6328-6329. DOI: 10.1021/ja9905849  1
1998 Mitchell GP, Tilley TD. Generation of a Silylene Complex by the 1,2-Migration of Hydrogen from Silicon to Platinum. Angewandte Chemie (International Ed. in English). 37: 2524-2526. PMID 29711339 DOI: 10.1002/(SICI)1521-3773(19981002)37:18<2524::AID-ANIE2524>3.0.CO;2-H  0.48
1998 Feldman JD, Mitchell GP, Nolte JO, Tilley TD. Isolation and characterization of neutral platinum silylene complexes of the type (R3P)2Pt=SiMes2 (Mes = 2,4,6-trimethylphenyl) [2] Journal of the American Chemical Society. 120: 11184-11185. DOI: 10.1021/ja981882t  1
1998 Rulkens R, Tilley TD. A molecular precursor route to active and selective vanadia-silica- zirconia heterogeneous catalysts for the oxidative dehydrogenation of propane [10] Journal of the American Chemical Society. 120: 9959-9960. DOI: 10.1021/ja981798d  1
1998 Kriesel JW, König S, Freitas MA, Marshall AG, Leary JA, Tilley TD. Synthesis of highly charged organometallic dendrimers and their characterization by electrospray mass spectrometry and single-crystal x-ray diffraction Journal of the American Chemical Society. 120: 12207-12215. DOI: 10.1021/ja981610q  1
1998 Dysard JM, Tilley TD. η5-silolyl and η5-germolyl complexes of d0 hafnium. Structural characterization of an ν5-silolyl complex [1] Journal of the American Chemical Society. 120: 8245-8246. DOI: 10.1021/ja9812857  1
1998 Mitchell GP, Tilley TD. Reversible 1,2-migration of hydrogen between platinum and silicon via intermediate silylene complexes Journal of the American Chemical Society. 120: 7635-7636. DOI: 10.1021/ja9808346  1
1998 Lucht BL, Mao SSH, Tilley TD. A zirconocene-coupling route to substituted poly(p- phenylenedienylene)s: Band Gap tuning via conformational control Journal of the American Chemical Society. 120: 4354-4365. DOI: 10.1021/ja9743811  1
1997 Mao SSH, Tilley TD. Versatile, transition-metal mediated route to blue-light-emitting polymers with chemically tunable luminescent properties Macromolecules. 30: 5566-5569. DOI: 10.1021/ma9701402  1
1997 Gountchev TI, Tilley TD. Structure and reactivity of chelating imido-amido complexes of tantalum. Mechanistic studies on the addition of silanes to Ta-N multiple bonds Journal of the American Chemical Society. 119: 12831-12841. DOI: 10.1021/ja9721982  1
1997 Mitchell GP, Tilley TD. Reversible cycloaddition of isocyanates to ruthenium silylene complexes Journal of the American Chemical Society. 119: 11236-11243. DOI: 10.1021/ja972020f  1
1996 Freeman WP, Tilley TD, Liable-Sands LM, Rheingold AL. Synthesis and study of cyclic π-systems containing silicon ang germanium. The question of aromaticity in cyclopentadienyl analogues Journal of the American Chemical Society. 118: 10457-10468. DOI: 10.1021/ja962103g  1
1996 Su K, Tilley TD, Sailor MJ. Molecular and polymer precursor routes to manganese-doped zinc orthosilicate phosphors Journal of the American Chemical Society. 118: 3459-3468. DOI: 10.1021/ja9537639  1
1994 Radu NS, Tilley TD. Sigma-Bond metathesis reactions involving lanthanide-silicon and lanthanide-hydrogen bonds Phosphorus, Sulfur, and Silicon and the Related Elements. 87: 209-218. DOI: 10.1080/10426509408037454  1
1993 Imori T, Tilley TD. High molecular mass polystannanes via dehydropolymerization of di(n-butyl)stannane Journal of the Chemical Society, Chemical Communications. 1607-1609. DOI: 10.1039/C39930001607  1
1992 Blake RE, Heyn RH, Tilley TD. Synthesis and structure of [(η5-C5Me5Ru(μ-NHPh)]2 ,an electron-deficient ruthenium amide complex Polyhedron. 11: 709-710. DOI: 10.1016/S0277-5387(00)83329-X  1
1990 Tilley TD. Mechanistic Aspects of Transition-Metal Catalyzed Dehydrogenative Silane Coupling Reactions Comments On Inorganic Chemistry. 10: 37-51. DOI: 10.1080/02603599008048649  1
1984 Boncella JM, Tilley TD, Andersen RA. Reaction of M(C5Me5)2(OEt2), M = Eu or Yb, with phenylacetylene; formation of mixed-valence Yb3(C5Me5)4(μ-C≡CPh)4 and Eu2(C5Me5)2(µ-C≡CPh)2(tetrahydrofuran)4 Journal of the Chemical Society - Series Chemical Communications. 710-712. DOI: 10.1039/C39840000710  1
1984 Tilley TD, Grubbs RH, Bercaw JE. Halide, hydride, and alkyl derivatives of (pentamethylcyclopentadienyl)bis(trimethylphosphine)ruthenium Organometallics. 3: 274-278. DOI: 10.1021/om00080a019  1
1981 Tilley TD, Andersen RA. Preparation and crystal structure of μ-carbonyl-OC-bis(Pentamethyl-cyclopentadienyl)(tetrahydrofuran)ytterbium(III)tricarbonylcobalt(I); A Yb-OC-Co linkage Journal of the Chemical Society - Series Chemical Communications. 985-986. DOI: 10.1039/C39810000985  1
0 Suslick BA. . DOI: 10.1021/acscatal.7b01560  1
Show low-probability matches.