Eric Block, Ph.D. - Publications

Affiliations: 
Chemistry State University of New York, Albany, Albany, NY, United States 
Area:
Organosulfur chemistry, olfaction, Allium chemistry, organoselenium chemistry
Website:
http://www.albany.edu/chemistry/eblock.shtml

113 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any innacuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Block E, Dethier B, Bechand B, Cotelesage JJH, George GN, Goto K, Mendoza Rengifo E, Pickering IJ, Sheridan R, Sneeden EY, Vogt L. Ajothiolanes: 3,4-Dimethylthiolane Natural Products from Garlic ( Allium sativum). Journal of Agricultural and Food Chemistry. PMID 30196701 DOI: 10.1021/acs.jafc.8b03638  1
2018 Zhang R, Pan Y, Ahmed L, Block E, Zhang Y, Batista VS, Zhuang H. A Multispecific Investigation of the Metal Effect in Mammalian Odorant Receptors for Sulfur-containing Compounds. Chemical Senses. PMID 29659735 DOI: 10.1093/chemse/bjy022  1
2018 Ahmed L, Zhang Y, Block E, Buehl M, Corr MJ, Cormanich RA, Gundala S, Matsunami H, O'Hagan D, Ozbil M, Pan Y, Sekharan S, Ten N, Wang M, Yang M, et al. Molecular mechanism of activation of human musk receptors OR5AN1 and OR1A1 by ()-muscone and diverse other musk-smelling compounds. Proceedings of the National Academy of Sciences of the United States of America. PMID 29632183 DOI: 10.1073/pnas.1713026115  1
2017 Block E, Bechand B, Gundala S, Vattekkatte A, Wang K, Mousa SS, Godugu K, Yalcin M, Mousa SA. Fluorinated Analog NMR s of Organosulfur Compounds from Garlic (Allium sativum): Synthesis, Chemistry and Anti-Angiogenesis and Antithrombotic Studies. Molecules (Basel, Switzerland). 22. PMID 29182588 DOI: 10.3390/molecules22122081  1
2017 Sneeden EY, Hackett MJ, Cotelesage JJH, Prince RC, Barney M, Goto K, Block E, Pickering IJ, George GN. Photochemically-Generated Thiyl Free Radicals Observed by X-ray Absorption Spectroscopy. Journal of the American Chemical Society. PMID 28750509 DOI: 10.1021/jacs.7b05116  1
2017 Block E, Batista VS, Matsunami H, Zhuang H, Ahmed L. The role of metals in mammalian olfaction of low molecular weight organosulfur compounds. Natural Product Reports. PMID 28471462 DOI: 10.1039/c7np00016b  1
2017 Block E. Fifty Years of Smelling Sulfur: From the Chemistry of Garlic to the Molecular Basis for Olfaction Phosphorus, Sulfur, Silicon, and Related Elements. 192: 141-144. DOI: 10.1080/10426507.2016.1247091.  0.01
2016 Li S, Ahmed L, Zhang R, Pan Y, Matsunami H, Burger JL, Block E, Batista VS, Zhuang H. Smelling Sulfur: Copper and Silver Regulate the Response of Human Odorant Receptor OR2T11 to Low Molecular Weight Thiols. Journal of the American Chemical Society. PMID 27659093 DOI: 10.1021/jacs.6b06983  1
2016 Block E, Booker S, Flores-Penalba S, George G, Gundala S, Landgraf B, Liu J, Lodge S, Pushie J, Rozovsky S, Vattekkatte A, Yaghi R, Zeng H. Trifluoroselenomethionine - a New Non-Natural Amino Acid. Chembiochem : a European Journal of Chemical Biology. PMID 27383291 DOI: 10.1002/cbic.201600266  1
2016 Block E, Booker SJ, Flores-Penalba S, George G, Gundala S, Landgraf BJ, Li F, Lodge SN, Pushie J, Rozovsky S, Vattekkatte A, Yaghi R, Zeng H. Trifluoroselenomethionine -- a New Non-Natural Amino Acid Chembiochem. 17: 1738–1751. PMID 27383291 DOI: 10.1002/cbic.201600266  1
2015 Block E, Jang S, Matsunami H, Batista VS, Zhuang H. Reply to Turin et al.: Vibrational theory of olfaction is implausible. Proceedings of the National Academy of Sciences of the United States of America. 112: E3155. PMID 26045493 DOI: 10.1073/pnas.1508443112  1
2015 Block E, Jang S, Matsunami H, Sekharan S, Dethier B, Ertem MZ, Gundala S, Pan Y, Li S, Li Z, Lodge SN, Ozbil M, Jiang H, Penalba SF, Batista VS, et al. Implausibility of the vibrational theory of olfaction. Proceedings of the National Academy of Sciences of the United States of America. 112: E2766-74. PMID 25901328 DOI: 10.1073/pnas.1503054112  1
2014 Sekharan S, Ertem MZ, Zhuang H, Block E, Matsunami H, Zhang R, Wei JN, Pan Y, Batista VS. QM/MM model of the mouse olfactory receptor MOR244-3 validated by site-directed mutagenesis experiments. Biophysical Journal. 107: L5-8. PMID 25185561 DOI: 10.1016/j.bpj.2014.07.031  1
2014 Garcia M, Greco LF, Favoreto MG, Marsola RS, Wang D, Shin JH, Block E, Thatcher WW, Santos JE, Staples CR. Effect of supplementing essential fatty acids to pregnant nonlactating Holstein cows and their preweaned calves on calf performance, immune response, and health. Journal of Dairy Science. 97: 5045-64. PMID 24931531 DOI: 10.3168/jds.2013-7473  1
2013 Wang K, Groom M, Sheridan R, Zhang S, Block E. Liquid sulfur as a reagent: Synthesis of polysulfanes with 20 or more sulfur atoms with characterization by UPLC-(Ag+)-coordination ion spray-MS Journal of Sulfur Chemistry. 34: 55-66. DOI: 10.1080/17415993.2012.721368  1
2013 Block E. Fifty years of smelling sulfur Journal of Sulfur Chemistry. 34: 158-207. DOI: 10.1080/17415993.2012.717294  1
2013 Block E, Zhuang H. Smelling sulfur: Discovery of a sulfur-sensing olfactory receptor that requires copper Acs Symposium Series. 1152: 1-14. DOI: 10.1021/bk-2013-1152.ch001  1
2013 Wann DA, Bil A, Lane PD, Robertson HE, Rankin DWH, Block E. Gas-phase structures of dithietane derivatives, including an electron diffraction study of 1,3-dithietane 1,1,3,3-tetraoxide Structural Chemistry. 24: 827-835. DOI: 10.1007/s11224-012-0179-8  1
2012 Duan X, Block E, Li Z, Connelly T, Zhang J, Huang Z, Su X, Pan Y, Wu L, Chi Q, Thomas S, Zhang S, Ma M, Matsunami H, Chen GQ, et al. Crucial role of copper in detection of metal-coordinating odorants. Proceedings of the National Academy of Sciences of the United States of America. 109: 3492-7. PMID 22328155 DOI: 10.1073/pnas.1111297109  1
2011 Daly AM, Mitchell EG, Sanchez DA, Block E, Kukolich SG. Microwave spectra and gas phase structural parameters for N-hydroxypyridine-2(1H)-thione. The Journal of Physical Chemistry. A. 115: 14526-30. PMID 22070758 DOI: 10.1021/jp2080385  1
2011 Block E, John Dane A, Cody RB. Crushing garlic and slicing onions: Detection of sulfenic acids and other reactive organosulfur intermediates from garlic and other alliums using direct analysis in real-time mass spectrometry (DART-MS) Phosphorus, Sulfur and Silicon and the Related Elements. 186: 1085-1093. DOI: 10.1080/10426507.2010.507728  1
2011 Block E. Challenges and artifact concerns in analysis of volatile sulfur compounds Acs Symposium Series. 1068: 35-63. DOI: 10.1021/bk-2011-1068.ch002  1
2010 Block E, Dane AJ, Thomas S, Cody RB. Applications of direct analysis in real time mass spectrometry (DART-MS) in Allium chemistry. 2-propenesulfenic and 2-propenesulfinic acids, diallyl trisulfane S-oxide, and other reactive sulfur compounds from crushed garlic and other Alliums. Journal of Agricultural and Food Chemistry. 58: 4617-25. PMID 20225897 DOI: 10.1021/jf1000106  1
2010 Evans DH, Gruhn NE, Jin J, Li B, Lorance E, Okumura N, Macías-Ruvalcaba NA, Zakai UI, Zhang SZ, Block E, Glass RS. Electrochemical and chemical oxidation of dithia-, diselena-, ditellura-, selenathia-, and tellurathiamesocycles and stability of the oxidized species. The Journal of Organic Chemistry. 75: 1997-2009. PMID 20180528 DOI: 10.1021/jo9026484  1
2010 Kubec R, Cody RB, Dane AJ, Musah RA, Schraml J, Vattekkatte A, Block E. Applications of direct analysis in real time-mass spectrometry (DART-MS) in Allium chemistry. (Z)-butanethial S-oxide and 1-butenyl thiosulfinates and their S-(E)-1-butenylcysteine S-oxide precursor from Allium siculum. Journal of Agricultural and Food Chemistry. 58: 1121-8. PMID 20047275 DOI: 10.1021/jf903733e  1
2010 Block E, Cody RB, Dane AJ, Sheridan R, Vattekkatte A, Wang K. Allium chemistry: Use of new instrumental techniques to "see" reactive organosulfur species formed upon crushing garlic and onion Pure and Applied Chemistry. 82: 535-539. DOI: 10.1351/PAC-CON-09-08-12  1
2010 Block E. Oxidation and reduction of sulphides Chemistry of Ethers Crown Ethers Hydroxyl Group and Their Sulphur Analogue. 1: 539-608. DOI: 10.1002/9780470771624.ch13  1
2009 Pickering IJ, Sneeden EY, Prince RC, Block E, Harris HH, Hirsch G, George GN. Localizing the chemical forms of sulfur in vivo using X-ray fluorescence spectroscopic imaging: application to onion (Allium cepa) tissues. Biochemistry. 48: 6846-53. PMID 19463015 DOI: 10.1021/bi900368x  1
2008 Liao C, Zhang SZ, Block E, Clennan EL. Photooxygenation of 1,5-thiaselenocane. The Journal of Organic Chemistry. 73: 8587-90. PMID 18841914 DOI: 10.1021/jo801429b  1
2008 Kruger S, Revuru S, Zhang SZ, Vaughn DD, Block E, Zimmerman P, Brainard RL. Options for high index fluids for third generation 193i lithography Proceedings of Spie - the International Society For Optical Engineering. 6923. DOI: 10.1117/12.772994  1
2008 Glass RS, Berry MJ, Block E, Boakye HT, Carlson BA, Gailer J, George GN, Gladyshev VN, Hatfield DL, Jacobsen NE, Johnson S, Kahakachchi C, Kaminski R, Manley SA, Mix H, et al. Insights into the chemical biology of selenium Phosphorus, Sulfur and Silicon and the Related Elements. 183: 924-930. DOI: 10.1080/10426500801898366  1
2008 Block E, Glass RS, Gruhn N, Jin J, Lorance E, Zakai UI, Zhang SZ. Chemistry of mixed sulfur-, selenium-, or tellurium- and silicon-, or tin-containing heterocycles Phosphorus, Sulfur and Silicon and the Related Elements. 183: 856-862. DOI: 10.1080/10426500801898168  1
2008 Block E, Linderman RJ. Four membered rings with one oxygen, sulfur, or selenium atom Second Supplements to the 2nd Edition of Rodd's Chemistry of Carbon Compounds: a Modern Comprehensive Treatise. 4: 113-145. DOI: 10.1016/B978-044453347-0.50143-9  1
2008 Gardner C, Lawson LD, Block E. In reply [8] Archives of Internal Medicine. 168: 112-113. DOI: 10.1001/archinternmed.2007.14  1
2007 Yang CW, Chen S, Chang CY, Lin MF, Block E, Lorentsen R, Chin JS, Dierenfeld ES. History and dietary husbandry of pangolins in captivity. Zoo Biology. 26: 223-30. PMID 19360575 DOI: 10.1002/zoo.20134  0.36
2007 Glass RS, Block E, Gruhn NE, Jin J, Lorance E, Zakai UI, Zhang SZ. Interaction of C-Si, C-Sn, and Si-Si sigma-bonds with chalcogen lone pairs. The Journal of Organic Chemistry. 72: 8290-7. PMID 17915922 DOI: 10.1021/jo071215v  1
2007 Gardner CD, Lawson LD, Block E, Chatterjee LM, Kiazand A, Balise RR, Kraemer HC. Effect of raw garlic vs commercial garlic supplements on plasma lipid concentrations in adults with moderate hypercholesterolemia: a randomized clinical trial. Archives of Internal Medicine. 167: 346-53. PMID 17325296 DOI: 10.1001/archinte.167.4.346  1
2007 Mousa SA, O'Connor L, Rossman TG, Block E. Pro-angiogenesis action of arsenic and its reversal by selenium-derived compounds. Carcinogenesis. 28: 962-7. PMID 17158527 DOI: 10.1093/carcin/bgl229  1
2007 Brainard RL, Kruger S, Block E. Models for predicting the index of refraction of compounds 193 and 589 nm Proceedings of Spie - the International Society For Optical Engineering. 6519. DOI: 10.1117/12.712431  1
2007 Block E, Glass RS, Dikarev EV, Gruhn NE, Jin J, Li B, Lorance E, Zakai UI, Zhang SZ. Synthesis, structure, reactions, and photoelectron spectra of new mixed sulfur-, selenium- Or tellurium and silicon- Or tin-containing heterocycles Heteroatom Chemistry. 18: 509-515. DOI: 10.1002/hc.20333  1
2007 Garder CD, Lawson LD, Block E. Authors reply Focus On Alternative and Complementary Therapies. 12: 176-177.  1
2007 Gardner CD, Lawson LD, Block E, Chatterjee LM, Kiazand A, Balise RS. Garlic and lipidic profile: Commentary | Ajo y perfil lipídico: Comentario Hipertension. 24: 188-189.  1
2006 Block E, Dikarev EV, Glass RS, Jin J, Li B, Li X, Zhang SZ. Synthesis, structure, and chemistry of new, mixed group 14 and 16 heterocycles: nucleophile-induced ring contraction of mesocyclic dications. Journal of the American Chemical Society. 128: 14949-61. PMID 17105306 DOI: 10.1021/ja065037j  1
2006 Glass RS, Block E, Lorance E, Zakai UI, Gruhn NE, Jin J, Zhang SZ. The Si-Si effect on ionization of beta-disilanyl sulfides and selenides. Journal of the American Chemical Society. 128: 12685-92. PMID 17002362 DOI: 10.1021/ja0573514  1
2005 Filatov AS, Block E, Petrukhina MA. Dimethyl selenoxide. Acta Crystallographica. Section C, Crystal Structure Communications. 61: o596-8. PMID 16210767 DOI: 10.1107/S0108270105027587  1
2005 Lin DY, Zhang SZ, Block E, Katz LC. Encoding social signals in the mouse main olfactory bulb. Nature. 434: 470-7. PMID 15724148 DOI: 10.1038/nature03414  1
2005 Petrukhina MA, Henck C, Li B, Block E, Jin J, Zhang SZ, Clerac R. Spirocyclic sulfur and selenium ligands as molecular rigid rods in coordination of transition metal centers. Inorganic Chemistry. 44: 77-84. PMID 15627363 DOI: 10.1021/ic040102g  1
2005 Block E, Dikarev EV, Jin J, Li B, Petrukhina MA, Zhang SZ. Synthesis, structure, and chemistry of selenium-containing four-membered rings Pure and Applied Chemistry. 77: 2029-2032. DOI: 10.1351/pac200577122029  1
2005 Block E, Hak RJ, Putman D, Zhang SZ. α,β-unsaturated α′-halomethylsulfones: Prepackaged Ramberg-Bäcklund reagents for tandem synthetic processes Phosphorus, Sulfur and Silicon and the Related Elements. 180: 1197-1202. DOI: 10.1080/10426500590910783  1
2005 Block E. Biological activity of allium compounds: Recent results Acta Horticulturae. 688: 41-57.  1
2004 Dikarev EV, Shpanchenko RV, Andreini KW, Block E, Jin J, Petrukhina MA. Powder diffraction study of a coordination polymer comprised of rigid building blocks: [Rh2(O2CCH3)4.mu2-Se2C5H8-Se,Se']infinity. Inorganic Chemistry. 43: 5558-63. PMID 15332807 DOI: 10.1021/ic049497u  1
2004 Block E, Glass RS, Jacobsen NE, Johnson S, Kahakachchi C, Kami?ski R, Skowro?ska A, Boakye HT, Tyson JF, Uden PC. Identification and synthesis of a novel selenium-sulfur amino acid found in selenized yeast: Rapid indirect detection NMR methods for characterizing low-level organoselenium compounds in complex matrices. Journal of Agricultural and Food Chemistry. 52: 3761-71. PMID 15186094 DOI: 10.1021/jf049887z  1
2004 Hile AG, Shan Z, Zhang SZ, Block E. Aversion of European starlings (Sturnus vulgaris) to garlic oil treated granules: garlic oil as an avian repellent. Garlic oil analysis by nuclear magnetic resonance spectroscopy. Journal of Agricultural and Food Chemistry. 52: 2192-6. PMID 15080619 DOI: 10.1021/jf035181d  1
2004 Block E, Jeon HR, Zhang SZ, Dikarev EV. Chloromethanesulfonylethene and dichloromethanesulfonylethene: new reagents for tandem Diels-Alder/Ramberg-Bäcklund reactions. Organic Letters. 6: 437-40. PMID 14748612 DOI: 10.1021/ol0363523  1
2004 Sneeden EY, Harris HH, Pickering IJ, Prince RC, Johnson S, Li X, Block E, George GN. The sulfur chemistry of shiitake mushroom. Journal of the American Chemical Society. 126: 458-9. PMID 14719930 DOI: 10.1021/ja039239g  1
2004 Uden PC, Boakye HT, Kahakachchi C, Hafezi R, Nolibos P, Block E, Johnson S, Tyson JF. Element selective characterization of stability and reactivity of selenium species in selenized yeast Journal of Analytical Atomic Spectrometry. 19: 65-73. DOI: 10.1039/b307508g  1
2004 Block E, Jeon HR, Putman D, Zhang SZ. Prepackaged Ramberg-Bäcklund reagents: Useful tools for organic synthesis Tetrahedron. 60: 7525-7541. DOI: 10.1016/j.tet.2004.06.032  1
2004 Groner P, Gillies CW, Gillies JZ, Zhang Y, Block E. Microwave structural studies of organoselenium compounds 1. Microwave spectra, molecular structure, and methyl barrier to internal rotation of dimethyl diselenide Journal of Molecular Spectroscopy. 226: 169-181. DOI: 10.1016/j.jms.2004.04.001  1
2003 Dikarev EV, Becker RY, Block E, Shan Z, Haltiwanger RC, Petrukhina MA. The first coordination complexes of selenones: a structural comparison with complexes of sulfones. Inorganic Chemistry. 42: 7098-105. PMID 14577777 DOI: 10.1021/ic0302130  1
2003 Lorance ED, Glass RS, Block E, Li X. Synthesis, electrochemistry, and gas-phase photoelectron spectroscopic and theoretical studies of 3,6-bis(perfluoroalkyl)-1,2-dithiins. The Journal of Organic Chemistry. 68: 8110-4. PMID 14535791 DOI: 10.1021/jo034683n  1
2003 Block E, Shan Z, Glass RS, Fabian J. Revised structure of a purported 1,2-dioxin: a combined experimental and theoretical study. The Journal of Organic Chemistry. 68: 4108-11. PMID 12737603 DOI: 10.1021/jo034305i  1
2003 Block E, Tries F, He C, Guo C, Thiruvazhi M, Toscano PJ. Perthio- and perseleno-1,3-butadienes, -but-1-ene-3-ynes, and -[3]-cumulenes: one-step syntheses from 1,4-dilithio-1,3-butadiyne. Organic Letters. 5: 1325-7. PMID 12688750 DOI: 10.1021/ol034258g  1
2003 Dikarev EV, Petrukhina MA, Li X, Block E. Small organoselenium molecules. 1. Dimethyl selenoxide: structure, complexation, and gas-phase transformation. Inorganic Chemistry. 42: 1966-72. PMID 12639131 DOI: 10.1021/ic020556i  1
2001 Dong Y, Lisk D, Block E, Ip C. Characterization of the biological activity of γ-Glutamyl-Se-methylselenocysteine: A novel, naturally occurring anticancer agent from garlic Cancer Research. 61: 2923-2928. PMID 11306469  1
2001 Block E, Birringer M, Jiang W, Nakahodo T, Thompson HJ, Toscano PJ, Uzar H, Zhang X, Zhu Z. Allium chemistry: synthesis, natural occurrence, biological activity, and chemistry of Se-alk(en)ylselenocysteines and their gamma-glutamyl derivatives and oxidation products. Journal of Agricultural and Food Chemistry. 49: 458-70. PMID 11305255 DOI: 10.1021/jf001097b  1
2001 Block E. Chemistry of analogous organoselenium and organosulfur compounds Phosphorus, Sulfur and Silicon and Related Elements. 171: 1-23.  1
2001 Uden PC, Hafezi R, Kotrebai M, Nolibos P, Tyson J, Block E. Anticarcinogenic organoselenium compounds - Chromatographic, atomic and molecular mass spectral speciation Phosphorus, Sulfur and Silicon and Related Elements. 171: 31-56.  1
2000 Ip C, Birringer M, Block E, Kotrebai M, Tyson JF, Uden PC, Lisk DJ. Chemical speciation influences comparative activity of selenium-enriched garlic and yeast in mammary cancer prevention Journal of Agricultural and Food Chemistry. 48: 2062-2070. PMID 10888499 DOI: 10.1021/jf000051f  1
2000 Kotrebai M, Birringer M, Tyson JF, Block E, Uden PC. Selenium speciation in enriched and natural samples by HPLC-ICP-MS and HPLC-ESI-MS with perfluorinated carboxylic acid ion-pairing agents Analyst. 125: 71-78. PMID 10885064 DOI: 10.1039/a906320j  1
2000 Kotrebai M, Tyson JF, Block E, Uden PC. High-performance liquid chromatography of selenium compounds utilizing perfluorinated carboxylic acid ion-pairing agents and inductively coupled plasma and electrospray ionization mass spectrometric detection Journal of Chromatography A. 866: 51-63. PMID 10681009 DOI: 10.1016/S0021-9673(99)01060-2  1
2000 Xie N, Binstead RA, Block E, Chandler WD, Lee DG, Meyer TJ, Thiruvazhi M. Reduction of permanganate by thioanisole: Lewis acid catalysis Journal of Organic Chemistry. 65: 1008-1015. DOI: 10.1021/jo9914162  1
2000 Block E, Birringer M, Deorazio R, Fabian J, Glass RS, Guo C, He C, Lorance E, Qian Q, Schroeder TB, Shan Z, Thiruvazhi M, Wilson GS, Zhang X. Synthesis, properties, oxidation, and electrochemistry of 1,2- dichalcogenins Journal of the American Chemical Society. 122: 5052-5064. DOI: 10.1021/ja994134s  1
2000 Glass RS, Gruhn NE, Lichtenberger DL, Lorance E, Pollard JR, Birringer M, Block E, Deorazio R, He C, Shan Z, Zhang X. Gas-phase photoelectron spectroscopic and theoretical studies of 1,2- dichalcogenins: Ionization energies, orbital assignments, and an explanation of their color Journal of the American Chemical Society. 122: 5065-5074. DOI: 10.1021/ja9941330  1
1999 Block E, Birringer M, He C. 1,2-Dichalcogenins: Simple Syntheses of 1,2-Diselenins, 1,2-Dithiins, and 2-Selenathiin. Angewandte Chemie (International Ed. in English). 38: 1604-1607. PMID 29710998 DOI: 10.1002/(SICI)1521-3773(19990601)38:11<1604::AID-ANIE1604>3.0.CO;2-I  1
1999 Perez-Lourido P, Garcia-Vazquez JA, Romero J, Sousa A, Block E, Maresca KP, Zubieta J. Synthesis and Structural Characterization of Neutral Silver(I) Complexes with Arenephosphinothiols. Crystal Structures of [Ag(4){2-(Ph(2)P)-6-(Me(3)Si)C(6)H(6)S}(4)] and [Ag(4){2-(Ph(2)PO)-6-(Me(3)Si)C(6)H(3)S}(4)]. Inorganic Chemistry. 38: 538-544. PMID 11673959  1
1999 Kotrebai M, Bird SM, Tyson JF, Block E, Uden PC. Characterization of selenium species in biological extracts by enhanced ion-pair liquid chromatography with inductively coupled plasma-mass spectrometry and by referenced electrospray ionization-mass spectrometry Spectrochimica Acta, Part B: Atomic Spectroscopy. 54: 1573-1591. DOI: 10.1016/S0584-8547(99)00086-5  1
1999 Block E, Birringer M, He C. 1,2-Dichalcogenins: Simple syntheses of 1,2-diselenins, 1,2-dithiins, and 2-selenathiin Angewandte Chemie - International Edition. 38: 1604-1607. DOI: 10.1002/(SICI)1521-3773(19990601)38:11<1604::AID-ANIE1604>3.0.CO;2-I  1
1999 Block E. Recent advances in the chemistry of 1,2-dithiins Phosphorus, Sulfur and Silicon and Related Elements. 153: 173-192.  1
1999 Perez-Lourido P, Garcia-Vazquez JA, Romero J, Sousa A, Block E, Maresca KP, Zubieta J. Synthesis and structural characterization of neutral silver(I) complexes with arenephosphinothiols. Crystal structures of [Ag4{2-(Ph2P)-6-(Me3Si)C6H 6S}4] and [Ag4{2-(Ph2PO)-6-(Me3Si)C6H 3S}4] Inorganic Chemistry. 38: 538-544.  1
1999 Gillies JZ, Cotter E, Gillies CW, Warner HE, Block E. Rotational Spectra, Molecular Structure, and Electric Dipole Moment of Propanethial S-Oxide Journal of Physical Chemistry A. 103: 4948-4954.  1
1999 Page JE, Block E, Towers GHN. Visible-light photochemistry and phototoxicity of thiarubrines Photochemistry and Photobiology. 70: 159-165.  1
1999 Kotrebai M, Birringer M, Tyson JF, Block E, Uden PC. Identification of the principal selenium compounds in selenium-enriched natural sample extracts by ion-pair liquid chromatography with inductively coupled plasma- and electrospray ionization-mass spectrometric detection Analytical Communications. 36: 249-252.  1
1998 Calvey EM, White KD, Matusik JE, Sha D, Block E. Allium chemistry: identification of organosulfur compounds in ramp (Allium tricoccum) homogenates. Phytochemistry. 49: 359-64. PMID 9747536 DOI: 10.1016/S0031-9422(98)00191-5  1
1998 Uden PC, Bird SM, Kotrebai M, Nolibos P, Tyson JF, Block E, Denoyer E. Analytical selenoamino acid studies by chromatography with interfaced atomic mass spectrometry and atomic emission spectral detection Fresenius' Journal of Analytical Chemistry. 362: 447-456.  1
1998 Block E. Garlic as a Functional Food: A Status Report Acs Symposium Series. 702: 125-143.  1
1997 Bird SM, Ge H, Uden PC, Tyson JF, Block E, Denoyer E. High-performance liquid chromatography of selenoamino acids and organo selenium compounds. Speciation by inductively coupled plasma mass spectrometry Journal of Chromatography A. 789: 349-359. PMID 9440291 DOI: 10.1016/S0021-9673(97)00657-2  1
1997 Glass RS, Pollard JR, Schroeder TB, Lichtenberger DL, Block E, DeOrazio R, Guo C, Thiruvazhi M. Spectroscopic, theoretical, and electrochemical studies of 1,2-dithiins Phosphorus, Sulfur and Silicon and Related Elements. 120: 439-440.  1
1997 Calvey EM, Block E. Supercritical Fluid Extraction of Allium Species Acs Symposium Series. 660: 113-124.  1
1997 Block E, Bird S, Tyson JF, Uden PC, Zhang X, Denoyer E. The search for anticarcinogenic organoselenium compounds from natural sources Paediatric and Perinatal Drug Therapy. 1: 1-10.  1
1997 Block E, Gulati H, Putman D, Sha D, You N, Zhao SH. Allium Chemistry: Synthesis of 1-[Alk(en)ylsulfinyl]propyl Alk(en)yl Disulfides (Cepaenes), Antithrombotic Flavorants from Homogenates of Onion (Allium cepa) Journal of Agricultural and Food Chemistry. 45: 4414-4422.  1
1997 Schroeder TB, Job C, Brown MF, Glass RS, You N, Block E. 1H-{125Te} indirect detection in nuclear magnetic resonance spectra of organotellurium compounds Magnetic Resonance in Chemistry. 35: 752-756.  1
1997 Calvey EM, Matusik JE, White KD, DeOrazio R, Sha D, Block E. Allium Chemistry: Supercritical Fluid Extraction and LC-APCI-MS of Thiosulfinates and Related Compounds from Homogenates of Garlic, Onion, and Ramp. Identification in Garlic and Ramp and Synthesis of 1-Propanesulfinothioic Acid S-Allyl Ester Journal of Agricultural and Food Chemistry. 45: 4406-4413.  1
1997 Bird SM, Uden PC, Tyson JF, Block E, Denoyer E. Speciation of selenoamino acids and organoselenium compounds in selenium-enriched yeast using high-performance liquid chromatography-inductively coupled plasma mass spectrometry Journal of Analytical Atomic Spectrometry. 12: 785-788.  1
1997 Block E, Glass RS, DeOrazio R, Lichtenberger DL, Pollard JR, Russell EE, Schroeder TB, Thiruvazhi M, Toscano PJ. Significant intramolecular sulfur-sulfur interactions in cis- and trans-2,3-dimethyl-5,6-dithiabicyclo-[2.1.1]hexane Synlett. 525-528.  1
1996 Block E. Recent results in the organosulfur and organoselenium chemistry of genus Allium and Brassica plants: Relevance for cancer prevention Advances in Experimental Medicine and Biology. 401: 155-163. PMID 8886134  1
1996 Block E, Gillies JZ, Gillies CW, Bazzi AA, Putman D, Revelle LK, Wang D, Zhang X. Allium chemistry: Microwave spectroscopic identification, mechanism of formation, synthesis, and reactions of (E,Z)-propanethial S-oxide, the lachrymatory factor of the onion (Allium cepa) Journal of the American Chemical Society. 118: 7492-7501. DOI: 10.1021/ja960722j  1
1996 Block E, Page J, Toscano JP, Wang CX, Zhang X, DeOrazio R, Guo C, Sheridan RS, Neil Towers GH. Photochemistry of thiarubrine A and other 1,2-dithiins: Formation of 2,6-dithiabicyclo[3.1.0]hex-3-enes Journal of the American Chemical Society. 118: 4719-4720. DOI: 10.1021/ja960589v  1
1996 Block E, Bayer T, Naganathan S, Zhao Shu-Hai. Allium chemistry: Synthesis and sigmatropic rearrangements of alk(en)yl 1-propenyl disulfide S-oxides from cut onion and garlic Journal of the American Chemical Society. 118: 2799-2810. DOI: 10.1021/ja953444h  1
1996 Block E, Thiruvazhi M, Toscano PJ, Bayer T, Grisoni S, Zhao Shu-Hai. Allium chemistry: Structure, synthesis, natural occurrence in onion (Allium cepa), and reactions of 2,3-dimethyl-5,6-dithiabicyclo[2.1.1]hexane S-oxides Journal of the American Chemical Society. 118: 2790-2798. DOI: 10.1021/ja951134t  1
1996 Gillies JZ, Gillies CW, Cotter EA, Block E, DeOrazio R. Microwave spectra, molecular structure, and electric dipole moment of 1,2-dithiin Journal of Molecular Spectroscopy. 180: 139-144. DOI: 10.1006/jmsp.1996.0232  1
1996 Ge H, Cai XJ, Tyson JF, Uden PC, Denoyer ER, Block E. Identification of selenium species in selenium-enriched garlic, onion and broccoli using high-performance ion chromatography with inductively coupled plasma mass spectrometry detection Analytical Communications. 33: 279-281.  1
1996 Block E, Cai XJ, Uden PC, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Natural abundance of organoselenium compounds from garlic, onion and related plants and in human garlic breath Pure and Applied Chemistry. 68: 937-944.  1
1995 Cai XJ, Block E, Uden PC, Quimby BD, Sullivan JJ. Allium chemistry: Identification of natural abundance organoselenium compounds in human breath after ingestion of garlic using gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 43: 1751-1753.  1
1995 Cai XJ, Block E, Uden PC, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Identification of selenoamino acids in ordinary and selenium-enriched garlic, onion, and broccoli using gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 43: 1754-1757.  1
1994 Calvey EM, Roach JAG, Block E. Supercritical fluid chromatography of garlic (allium sativum) extracts with mass spectrometric identification of allicin Journal of Chromatographic Science. 32: 93-96. PMID 8200919  1
1994 Block E, Deorazio R. Chemistry in a salad bowl: Comparative organosulfur chemistry of garlic, onion and shiitake mushrooms Pure and Applied Chemistry. 66: 2205-2206. DOI: 10.1351/pac199466102205  1
1994 Cai XJ, Uden PC, Sullivan JJ, Quimby BD, Block E. Headspace-gas chromatography with atomic emission and mass selective detection for the determination of organoselenium compounds in elephant garlic Analytical Proceedings Including Analytical Communications. 31: 325-327. DOI: 10.1039/AI9943100325  1
1994 Block E, De Orazio R, Thiruvazhi M. Simple total syntheses of biologically active pentathiadecane natural products, 2,4,5,7,9-pentathiadecane 2,2,9,9-tetraoxide (dysoxysulfone), from Dysoxylum richii, and 2,3,5,7,9-pentathiadecane 9,9-dioxide, the misidentified lenthionine precursor SE-3 from Shiitake mushroom (Lentinus edodes) Journal of Organic Chemistry. 59: 2273-2275. DOI: 10.1021/jo00088a001  1
1994 Block E, Guo C, Thiruvazhi M, Toscano PJ. Total synthesis of thiarubrine B [3-(3-buten-1-ynyl)-6-(1,3-pentadiynyl)-1,2-dithiin], the antibiotic principle of giant ragweed (Ambrosia trifida) Journal of the American Chemical Society. 116: 9403-9404. DOI: 10.1021/ja00099a097  1
1994 Randle WM, Block E, Littlejohn MH, Putman D, Bussard ML. Onion (Allium cepa L.) thiosulfinates respond to increasing sulfur fertility Journal of Agricultural and Food Chemistry. 42: 2085-2088.  1
1994 Calvey EM, Matusik JE, White KD, Betz JM, Block E, Littlejohn MH, Naganathan S, Putman D. Off-line supercritical fluid extraction of thiosulfinates from garlic and onion Journal of Agricultural and Food Chemistry. 42: 1335-1341.  1
1994 Cai XJ, Uden PC, Block E, Zhang X, Quimby BD, Sullivan JJ. Allium chemistry: Identification of natural abundance organoselenium volatiles from garlic, elephant garlic, onion, and Chinese chive using headspace gas chromatography with atomic emission detection Journal of Agricultural and Food Chemistry. 42: 2081-2084.  1
1993 Block E, Thiruvazhi M. Allium chemistry: Synthesis of alk(en)yl 3,4-dimethyl-2-thienyl disulfides, components of distilled oils and extracts of Allium species Journal of Agricultural and Food Chemistry. 41: 2235-2237.  1
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