W Dean Harman, Ph.D. - Publications

Affiliations: 
Chemistry University of Virginia, Charlottesville, VA 

169 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilde JH, Smith JA, Dickie DA, Harman WD. Molybdenum-Promoted Synthesis of Isoquinuclidines with Bridgehead CF3 Groups. Journal of the American Chemical Society. PMID 31684729 DOI: 10.1021/jacs.9b10781  0.52
2019 Wilson KB, Smith JA, Nedzbala HS, Pert EK, Dakermanji SJ, Dickie DA, Harman WD. Highly Functionalized Cyclohexenes Derived from Benzene: Sequential Tandem Addition Reactions Promoted by Tungsten. The Journal of Organic Chemistry. PMID 30893999 DOI: 10.1021/acs.joc.9b00279  0.52
2018 Heyer AJ, Shivokevich PJ, Hooe SL, Welch KD, Harman WD, Machan CW. Reversible modulation of the redox characteristics of acid-sensitive molybdenum and tungsten scorpionate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 29623324 DOI: 10.1039/c8dt00598b  0.52
2018 Heyer AJ, Shivokevich PJ, Hooe SL, Welch KD, Harman WD, Machan CW. Reversible modulation of the redox characteristics of acid-sensitive molybdenum and tungsten scorpionate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 29623324 DOI: 10.1039/c8dt00598b  0.52
2018 Heyer AJ, Shivokevich PJ, Hooe SL, Welch KD, Harman WD, Machan CW. Reversible modulation of the redox characteristics of acid-sensitive molybdenum and tungsten scorpionate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 29623324 DOI: 10.1039/c8dt00598b  0.52
2017 Myers JT, Smith JA, Dakermanji SJ, Wilde JH, Wilson KB, Shivokevich PJ, Harman WD. Molybdenum(0) Dihapto-Coordination of Benzene and Trifluorotoluene: The Stabilizing and Chemo-Directing Influence of a CF3 Group. Journal of the American Chemical Society. PMID 28742967 DOI: 10.1021/jacs.7b05009  0.52
2017 Myers JT, Smith JA, Dakermanji SJ, Wilde JH, Wilson KB, Shivokevich PJ, Harman WD. Molybdenum(0) Dihapto-Coordination of Benzene and Trifluorotoluene: The Stabilizing and Chemo-Directing Influence of a CF3 Group. Journal of the American Chemical Society. PMID 28742967 DOI: 10.1021/jacs.7b05009  0.52
2017 Myers JT, Smith JA, Dakermanji SJ, Wilde JH, Wilson KB, Shivokevich PJ, Harman WD. Molybdenum(0) Dihapto-Coordination of Benzene and Trifluorotoluene: The Stabilizing and Chemo-Directing Influence of a CF3 Group. Journal of the American Chemical Society. PMID 28742967 DOI: 10.1021/jacs.7b05009  0.52
2016 MacLeod BL, Pienkos JA, Wilson KB, Sabat M, Myers WH, Harman WD. Synthesis of Novel Hexahydroindoles from the Dearomatization of Indoline Organometallics. 35: 370-387. DOI: 10.1021/acs.organomet.5b00959  0.52
2015 Lankenau AW, Iovan DA, Pienkos JA, Salomon RJ, Wang S, Harrison DP, Myers WH, Harman WD. Enantioenrichment of a tungsten dearomatization agent utilizing chiral acids. Journal of the American Chemical Society. 137: 3649-55. PMID 25710752 DOI: 10.1021/jacs.5b00490  0.52
2015 Myers JT, Shivokevich PJ, Pienkos JA, Sabat M, Myers WH, Harman WD. Synthesis of 2-Substituted 1,2-Dihydronaphthalenes and 1,2-Dihydroanthracenes Using a Recyclable Molybdenum Dearomatization Agent Organometallics. 34: 3648-3657. DOI: 10.1021/acs.organomet.5b00509  0.52
2014 Macleod BL, Pienkos JA, Myers JT, Sabat M, Myers WH, Dean Harman W. Stereoselective synthesis of trans- tetrahydroindolines promoted by A tungsten π base Organometallics. 33: 6286-6289. DOI: 10.1021/om501012q  0.56
2014 Macleod BL, Pienkos JA, Myers JT, Sabat M, Myers WH, Dean Harman W. Stereoselective synthesis of trans- tetrahydroindolines promoted by A tungsten π base Organometallics. 33: 6286-6289. DOI: 10.1021/om501012q  0.56
2014 Macleod BL, Pienkos JA, Myers JT, Sabat M, Myers WH, Dean Harman W. Stereoselective synthesis of trans- tetrahydroindolines promoted by A tungsten π base Organometallics. 33: 6286-6289. DOI: 10.1021/om501012q  0.56
2014 Macleod BL, Pienkos JA, Myers JT, Sabat M, Myers WH, Dean Harman W. Stereoselective synthesis of trans- tetrahydroindolines promoted by A tungsten π base Organometallics. 33: 6286-6289. DOI: 10.1021/om501012q  0.56
2014 Pienkos JA, Knisely AT, Macleod BL, Myers JT, Shivokevich PJ, Teran V, Sabat M, Myers WH, Harman WD. Double protonation of amino-substituted pyridine and pyrimidine tungsten complexes: Friedel-crafts-like coupling to aromatic heterocycles Organometallics. 33: 5464-5469. DOI: 10.1021/om5007402  0.52
2014 Pienkos JA, Knisely AT, Liebov BK, Teran V, Zottig VE, Sabat M, Myers WH, Harman WD. Tungsten-mediated selective ring opening of vinylcyclopropanes Organometallics. 33: 267-277. DOI: 10.1021/om4010115  0.52
2013 Strausberg L, Li M, Harrison DP, Myers WH, Sabat M, Harman WD. Exploiting the o- quinodimethane nature of naphthalene: Cycloaddition reactions with η2-coordinated tungsten-naphthalene complexes Organometallics. 32: 915-925. DOI: 10.1021/om301238q  0.52
2013 Pienkos JA, Zottig VE, Iovan DA, Li M, Harrison DP, Sabat M, Salomon RJ, Strausberg L, Teran VA, Myers WH, Harman WD. Friedel-crafts ring-coupling reactions promoted by tungsten dearomatization agent Organometallics. 32: 691-703. DOI: 10.1021/om3012008  0.52
2011 Harrison DP, Iovan DA, Myers WH, Sabat M, Wang S, Zottig VE, Harman WD. [4 + 2] Cyclocondensation reactions of tungsten-dihydropyridine complexes and the generation of tri- and tetrasubstituted piperidines. Journal of the American Chemical Society. 133: 18378-87. PMID 21961580 DOI: 10.1021/ja2075086  0.52
2011 Harrison DP, Nichols-Nielander AC, Zottig VE, Strausberg L, Salomon RJ, Trindle CO, Sabat M, Gunnoe TB, Iovan DA, Myers WH, Harman WD. Hyperdistorted tungsten allyl complexes and their stereoselective deprotonation to form dihapto-coordinated dienes Organometallics. 30: 2587-2597. DOI: 10.1021/om200183m  0.52
2010 Harrison DP, Sabat M, Myers WH, Harman WD. Polarization of the pyridine ring: highly functionalized piperidines from tungsten-pyridine complex. Journal of the American Chemical Society. 132: 17282-95. PMID 21077610 DOI: 10.1021/ja107536w  0.52
2010 Salomony RJ, Todd MA, Sahat M, Myers WH, Harman WD. Single and double electrophilic addition reactions to the aniline ring promoted by a tungsten π-base Organometallics. 29: 707-709. DOI: 10.1021/om901048x  0.52
2010 Zottig VE, Todd MA, Nichols-Nielander AC, Harrison DP, Sabat M, Myers WH, Harman WD. Epoxidation, cyclopropanation, and electrophilic addition reactions at the meta position of phenol and meta -cresol Organometallics. 29: 4793-4803. DOI: 10.1021/om901017d  0.52
2010 Harrison DP, Kosturko GW, Ramdeen VM, Nichols-Nielander AC, Payne SJ, Sabat M, Myers WH, Harman WD. Tungsten-promoted pyridine ring scission: The selective formation of η2-cyanine and η2-Merocyanine complexes and their derivatives Organometallics. 29: 1909-1915. DOI: 10.1021/om1001777  0.52
2009 Welch KD, Harrison DP, Sabat M, Hejazi EZ, Parr BT, Fanelli MG, Gianfrancesco NA, Nagra DS, Myers WH, Harman WD. Michael-aldol ring closures with dihapto-coordinated pyrrole complexes and the synthesis of tetrahydroindole cores Organometallics. 28: 5960-5967. DOI: 10.1021/om900714r  0.52
2009 Harrison DP, Zottig VE, Kosturko GW, Welch KD, Sabat M, Myers WH, Harman WD. Stereo- and regioselective nucleophilic addition to dihapto-coordinated pyridine complexes Organometallics. 28: 5682-5690. DOI: 10.1021/om900637x  0.52
2009 Salomon RJ, Lis EC, Kasbekar MU, Bassett KC, Myers WH, Trindle CO, Sabat M, Harman WD. Stereoelectronic effects in dihapto-coordinated complexes of TpW (NO)(PMe 3) and their manifestation in diels - Alder cycloaddition of arenes Organometallics. 28: 4724-4734. DOI: 10.1021/om900381c  0.52
2009 Kosturko GW, Harrison DP, Sabat M, Myers WH, Harman WD. Selectfluor-mediated dialkoxylation of tungsten n 2-pyridinium complexes Organometallics. 28: 387-389. DOI: 10.1021/om801068u  0.52
2008 Harrison DP, Welch KD, Nichols-Nielander AC, Sabat M, Myers WH, Harman WD. Efficient synthesis of an eta2-pyridine complex and a preliminary investigation of the bound heterocycle's reactivity. Journal of the American Chemical Society. 130: 16844-5. PMID 19053427 DOI: 10.1021/ja807521d  0.52
2008 Lis EC, Salomon RJ, Sabat M, Myers WH, Harman WD. Synthesis of 1-oxadecalins from anisole promoted by tungsten. Journal of the American Chemical Society. 130: 12472-6. PMID 18722433 DOI: 10.1021/ja803605m  0.52
2008 Todd MA, Sabat M, Myers WH, Smith TM, Harman WD. Stereoselective umpolung tandem addition of heteroatoms to phenol. Journal of the American Chemical Society. 130: 6906-7. PMID 18473458 DOI: 10.1021/ja801076z  0.52
2008 Kosturko GW, Grahams PM, Myers WH, Smith TM, Sabat M, Harman WD. Tungsten-promoted diels-alder cycloaddition of pyridines: Dearomatization of 2,6-dimethoxypyridine generates a potent 2-azadiene synthon Organometallics. 27: 4513-4522. DOI: 10.1021/om800430p  0.52
2007 Todd MA, Sabat M, Myers WH, Harman WD. [2+2] cycloaddition reactions with a tungsten-stabilized 2H-phenol. Journal of the American Chemical Society. 129: 11010-1. PMID 17705493 DOI: 10.1021/ja0739279  0.52
2007 Hoffman PS, Sisson G, Croxen MA, Welch K, Harman WD, Cremades N, Morash MG. Antiparasitic drug nitazoxanide inhibits the pyruvate oxidoreductases of Helicobacter pylori, selected anaerobic bacteria and parasites, and Campylobacter jejuni. Antimicrobial Agents and Chemotherapy. 51: 868-76. PMID 17158936 DOI: 10.1128/AAC.01159-06  0.52
2007 Liu W, Welch K, Trindle CO, Sabat M, Myers WH, Harman WD. Facile intermolecular aryl-F bond cleavage in the presence of aryl C-H bonds: Is the η2-arene intermediate bypassed? Organometallics. 26: 2589-2597. DOI: 10.1021/om070099j  0.52
2007 Welch KD, Harrison DP, Lis EC, Liu W, Salomon RJ, Harman WD, Myers WH. Large-scale syntheses of several synthons to the dearomatization agent {TpW(NO)(PMe3)} and convenient spectroscopic tools for product analysis Organometallics. 26: 2791-2794. DOI: 10.1021/om070034g  0.52
2006 Surendranath Y, Harman WD. The role of electrochemistry in the development of pi-basic dearomatization agents. Dalton Transactions (Cambridge, England : 2003). 3957-65. PMID 17028703 DOI: 10.1039/b607694g  0.52
2006 Liu W, You F, Mocella CJ, Harman WD. A new approach to promoting sluggish Diels-Alder reactions: dihapto-coordination of the diene. Journal of the American Chemical Society. 128: 1426-7. PMID 16448094 DOI: 10.1021/ja0553654  0.52
2006 Ha Y, Dilsky S, Graham PM, Liu W, Reichart TM, Sabat M, Keane JM, Harman WD. Development of group 6 dearomatization agents Organometallics. 25: 5184-5187. DOI: 10.1021/om060597c  0.52
2006 Welch KD, Smith PL, Keller AP, Myers WH, Sabat M, Harman WD. Osmium(II)-, rhenium (i)-, and tungsten(0)-promoted dipolar cycloaddition reactions with pyrroles: Exploiting the azomethine ylide character of this heterocycle Organometallics. 25: 5067-5075. DOI: 10.1021/om060586j  0.52
2006 Lis EC, Delafuente DA, Lin Y, Mocella CJ, Todd MA, Liu W, Sabat M, Myers WH, Harman WD. The uncommon reactivity of dihapto-coordinated nitrile, ketone, and alkene ligands when bound to a powerful π-base Organometallics. 25: 5051-5058. DOI: 10.1021/om060434o  0.52
2006 Todd MA, Grachan ML, Sabat M, Myers WH, Harman WD. Common electrophilic addition reactions at the phenol ring: The chemistry of T pW(NO)(PMe 3)(η 2-phenol) Organometallics. 25: 3948-3954. DOI: 10.1021/om060339f  0.52
2006 Bassett KC, You F, Graham PM, Myers WH, Sabat M, Harman WD. Furan [3 + 2] dipolar cycloadditions promoted by a π-basic tungsten metal fragment Organometallics. 25: 435-439. DOI: 10.1021/om0506926  0.52
2005 Graham PM, Delafuente DA, Liu W, Myers WH, Sabat M, Harman WD. Facile Diels-Alder reactions with pyridines promoted by tungsten. Journal of the American Chemical Society. 127: 10568-72. PMID 16045344 DOI: 10.1021/ja050143r  0.52
2005 Harman WD, Trindle C. Charge donation to and dearomatization of benzene attending complexation: DFT estimates of binding energies of TpMXO(L) with benzene, for Tp = hydridotris(pyrazolyl) borate, MXO = MoNO, ReCO, and WNO, and L = ammonia, N-methylimidazole, pyridine, phosphine, methyl isocyanide, and carbon monoxide. Journal of Computational Chemistry. 26: 194-200. PMID 15593348 DOI: 10.1002/jcc.20155  0.52
2005 Myers WH, Welch KD, Graham PM, Keller A, Sabat M, Trindle CO, Harman WD. Tungsten(0) and rhenium(I) η 2-pyrrole complexes: Dearomatization of pyrroles and their facile isomerizations, protonations, and reductions Organometallics. 24: 5267-5279. DOI: 10.1021/om050393g  0.52
2005 You F, Friedman LA, Bassett KC, Lin Y, Sabat M, Harman WD. Rhenium(I) η 2-coordinated furan complexes: Converting furan into a 1,3-carbon dipole Organometallics. 24: 2903-2912. DOI: 10.1021/om050075h  0.52
2005 Delafuente DA, Myers WH, Sabat M, Harman WD. Tungsten(0) ηn 2-thiophene complexes: Dearomatization of thiophene and its facile oxidation, protonation, and hydrogenation Organometallics. 24: 1876-1885. DOI: 10.1021/om050050i  0.52
2005 Keane JM, Harman WD. A new generation of π-basic dearomatization agents Organometallics. 24: 1786-1798. DOI: 10.1021/om050029h  0.52
2005 Graham PM, Mocella CJ, Sabat M, Harman WD. Dihapto-coordinated amide, ester, and aldehyde complexes and their role in decarbonylation Organometallics. 24: 911-919. DOI: 10.1021/om049016e  0.52
2004 Smith PL, Keane JM, Shankman SE, Chordia MD, Harman WD. Michael addition reactions with eta2-coordinated anisoles: controlling the stereochemistry of the para and benzylic carbons. Journal of the American Chemical Society. 126: 15543-51. PMID 15563183 DOI: 10.1021/ja047054j  0.52
2004 Ding F, Harman WD. Stereoselective tandem 1,4-addition reactions for benzenes: a comparison of Os(II), Re(I), and W(0) systems. Journal of the American Chemical Society. 126: 13752-6. PMID 15493934 DOI: 10.1021/ja047108p  0.52
2004 Keane JM, Chordia MD, Mocella CJ, Sabat M, Trindle CO, Harman WD. Transition metal-stabilized arenium cations: protonation of arenes dihapto-coordinated to pi-basic metal fragments. Journal of the American Chemical Society. 126: 6806-15. PMID 15161309 DOI: 10.1021/ja039824h  0.52
2004 Ding F, Valahovic MT, Keane JM, Anstey MR, Sabat M, Trindle CO, Harman WD. Diastereo- and enantioselective dearomatization of rhenium-bound naphthalenes. The Journal of Organic Chemistry. 69: 2257-67. PMID 15049617 DOI: 10.1021/jo030318k  0.52
2004 Keane JM, Ding F, Sabat M, Harman WD. Solid-state induced control of kinetically unstable stereoisomers. Journal of the American Chemical Society. 126: 785-9. PMID 14733552 DOI: 10.1021/ja0305860  0.52
2004 Mocella CJ, Delafuente DA, Keane JM, Warner GR, Friedman LA, Sabat M, Harman WD. Coordination chemistry and properties of unusually π-basic molybdenum fragments Organometallics. 23: 3772-3779. DOI: 10.1021/om049795z  0.52
2004 Harman WD. Conformational and linkage isomerizations for dihapto-coordinated arenes and aromatic heterocycles: Controlling the stereochemistry of ligand transformations Coordination Chemistry Reviews. 248: 853-866. DOI: 10.1016/j.ccr.2004.03.013  0.52
2003 Friedman LA, You F, Sabat M, Harman WD. Rhenium-promoted diastereo- and enantioselective cyclopentannulation reactions: furans as 1,3-propene dipoles. Journal of the American Chemical Society. 125: 14980-1. PMID 14653720 DOI: 10.1021/ja0304143  0.52
2003 Meiere SH, Keane JM, Gunnoe TB, Sabat M, Harman WD. Binding and activation of aromatic molecules by a molybdenum pi-base. Journal of the American Chemical Society. 125: 2024-5. PMID 12590511 DOI: 10.1021/ja021057j  0.52
2003 Smith KS, Smith PL, Heady TN, Trugman JM, Harman WD, Macdonald TL. In vitro metabolism of tolcapone to reactive intermediates: relevance to tolcapone liver toxicity. Chemical Research in Toxicology. 16: 123-8. PMID 12588182 DOI: 10.1021/tx025569n  0.52
2003 Graham PM, Meiere SH, Sabat M, Harman WD. Dearomatization of benzene, deamidization of N,N-dimethylformamide, and a versatile new tungsten π base Organometallics. 22: 4364-4366. DOI: 10.1021/om030560h  0.52
2003 Schiffler MA, Friedman LA, Brooks BC, Sabat M, Harman WD. Stereoselective Aldehyde Addition to Rhenium-Coordinated Furans Organometallics. 22: 4966-4972. DOI: 10.1021/om030538o  0.52
2003 Stokes SM, Ding F, Smith PL, Keane JM, Kopach ME, Jervis R, Sabat M, Harman WD. Formation of o-quinone methides from η2-coordinated phenols and their controlled release from a transition metal to generate chromans Organometallics. 22: 4170-4171. DOI: 10.1021/om0305317  0.52
2003 Bergman RG, Cundari TR, Gillespie AM, Gunnoe TB, Harman WD, Klinckman TR, Temple MD, White DP. Computational study of methane activation by TpRe(CO)2 and CpRe(CO)2 with a stereoelectronic comparison of cyclopentadienyl and scorpionate ligands Organometallics. 22: 2331-2337. DOI: 10.1021/om021048j  0.52
2003 Trindle C, Sacks G, Harman WD. Computational modeling of complexes of penta-ammine osmium (II) with aromatic ligands International Journal of Quantum Chemistry. 92: 457-469. DOI: 10.1002/qua.10512  0.52
2002 Meiere SH, Valahovic MT, Harman WD. Strategy for the resolution of a chiral dearomatization agent:[TpRe(CO)(1-methylimidazole)] coordination of alpha-pinene (Tp = hydridotris(pyrazolyl)borate). Journal of the American Chemical Society. 124: 15099-103. PMID 12475356 DOI: 10.1021/ja0118845  0.52
2002 Meiere SH, Ding F, Friedman LA, Sabat M, Harman WD. Dihapto coordination of carboxylic acid derivatives with an asymmetric rhenium pi-base: a new mechanism for amide isomerization? Journal of the American Chemical Society. 124: 13506-12. PMID 12418904 DOI: 10.1021/ja011497v  0.52
2002 Ding F, Kopach ME, Sabat M, Harman WD. Tandem 1,4-addition reactions with benzene and alkylated benzenes promoted by pentaammineosmium(II). Journal of the American Chemical Society. 124: 13080-7. PMID 12405835 DOI: 10.1021/ja020279e  0.52
2002 Friedman LA, Sabat M, Harman WD. Cycloaddition reactions of dihapto-coordinated furans. Journal of the American Chemical Society. 124: 7395-404. PMID 12071748 DOI: 10.1021/ja020137k  0.52
2002 Valahovic MT, Gunnoe TB, Sabat M, Harman WD. Ligand-modulated stereo- and regioselective tandem addition reactions of rhenium-bound naphthalene. Journal of the American Chemical Society. 124: 3309-15. PMID 11916415 DOI: 10.1021/ja012066f  0.52
2002 Valahovic MT, Myers WH, Harman WD. Discrimination of enantiofaces and stereoselective electrophilic addition reactions for η2-pyrrole complexes Organometallics. 21: 4581-4589. DOI: 10.1021/om020606r  0.52
2001 Chordia MD, Smith PL, Meiere SH, Sabat M, Harman WD. A facile Diels-Alder reaction with benzene: synthesis of the bicyclo[2.2.2]octene skeleton promoted by rhenium. Journal of the American Chemical Society. 123: 10756-7. PMID 11674016 DOI: 10.1021/ja011689q  0.56
2001 Friedman LA, Harman WD. Methanol addition to dihapto-coordinated rhenium complexes of furan. Journal of the American Chemical Society. 123: 8967-73. PMID 11552803 DOI: 10.1021/ja010513l  0.52
2001 Brooks BC, Meiere SH, Friedman LA, Carrig EH, Gunnoe TB, Harman WD. Interfacial and intrafacial linkage isomerizations of rhenium complexes with aromatic molecules. Journal of the American Chemical Society. 123: 3541-50. PMID 11472125 DOI: 10.1021/ja003195j  0.52
2001 Meiere SH, Harman WD. Binding selectivity of dihapto-coordinated olefins, ketones, and aldehydes utilizing the asymmetric π-basic metal fragment {TpRe(CO)(1-methylimidazole)} (Tp = hydridotris(pyrazolyl)borate) Organometallics. 20: 3876-3883. DOI: 10.1021/om010418l  0.52
2001 Meiere SH, Brooks BC, Gunnoe TB, Carrig EH, Sabat M, Harman WD. Dihapto coordination of aromatic molecules by the asymmetric π-bases {TpRe(CO)(L)} (Tp = hydridotris(pyrazolyl)borate; L = tBuNC, PMe3, pyridine, 1-methylimidazole, or NH3) Organometallics. 20: 3661-3671. DOI: 10.1021/om010227i  0.52
2001 Meiere SH, Brooks BC, Gunnoe TB, Sabat M, Harman WD. A promising new dearomatization agent: Crystal structure, synthesis, and exchange reactions of the versatile complex TpRe(CO)(1-methylimidazole)(η2-benzene) (Tp = hydridotris(pyrazolyl)borate) Organometallics. 20: 1038-1040. DOI: 10.1021/om000900o  0.52
2001 Friedman LA, Meiere SH, Brooks BC, Harman WD. Ethylene rotation in chiral octahedral rhenium(I) complexes Organometallics. 20: 1699-1702. DOI: 10.1021/om000865l  0.52
2000 Gunnoe TB, Meiere SH, Sabat M, Harman WD. [TpRe(bpy)]: a novel pentaaminerhenium system that stabilizes both high and low oxidation states (Tp = hydridotris(pyrazolyl)borate; bpy = 2,2'-bipyridyl). Inorganic Chemistry. 39: 6127-30. PMID 11151513 DOI: 10.1021/ic000707m  0.52
2000 Chordia MD, Harman WD. Asymmetric dearomatization of η2-arene complexes: Synthesis of stereodefined functionalized cyclohexenones and cyclohexenes Journal of the American Chemical Society. 122: 2725-2736. DOI: 10.1021/ja9938433  0.52
2000 Brooks BC, Brent Gunnoe T, Dean Harman W. Dihapto binding of aromatic molecules by π-basic transition metal complexes: Development of alternatives to the {Os(NH3)5}2+ fragment Coordination Chemistry Reviews. 206: 3-61. DOI: 10.1016/S0010-8545(99)00249-0  0.88
2000 Brooks BC, Brent Gunnoe T, Dean Harman W. Dihapto binding of aromatic molecules by π-basic transition metal complexes: Development of alternatives to the {Os(NH3)5}2+ fragment Coordination Chemistry Reviews. 206: 3-61. DOI: 10.1016/S0010-8545(99)00249-0  0.88
2000 Brooks BC, Brent Gunnoe T, Dean Harman W. Dihapto binding of aromatic molecules by π-basic transition metal complexes: Development of alternatives to the {Os(NH3)5}2+ fragment Coordination Chemistry Reviews. 206: 3-61. DOI: 10.1016/S0010-8545(99)00249-0  0.88
2000 Brooks BC, Brent Gunnoe T, Dean Harman W. Dihapto binding of aromatic molecules by π-basic transition metal complexes: Development of alternatives to the {Os(NH3)5}2+ fragment Coordination Chemistry Reviews. 206: 3-61. DOI: 10.1016/S0010-8545(99)00249-0  0.88
2000 Brooks BC, Brent Gunnoe T, Dean Harman W. Dihapto binding of aromatic molecules by π-basic transition metal complexes: Development of alternatives to the {Os(NH3)5}2+ fragment Coordination Chemistry Reviews. 206: 3-61. DOI: 10.1016/S0010-8545(99)00249-0  0.88
2000 Gunnoe TB, Sabat M, Harman WD. Stereoselective Dihapto-Binding of Prochiral Aromatic Compounds by {TpRe(CO)(PMe3)}: Synthesis, Characterization, Stability, and Enantiofacial Discrimination (Tp = Hydrido(tris)pyrazolylborate) Organometallics. 19: 728-737.  0.52
1999 Spera ML, Harman WD. Electrophilic additions to η2-thiophene complexes: Synthesis of novel thiophenium and thiafulvenium species Organometallics. 18: 2988-2998.  0.52
1999 Spera ML, Harman WD. Osmium-mediated electrophilic addition reactions with selenophene and activation of the Se - C bond Organometallics. 18: 1559-1561.  0.52
1999 Helberg LE, Brent Gunnoe T, Brooks BC, Sabat M, Harman WD. Rhenium(I) terpyridine π-bases: Reversible η2-coordination of ketones, aldehydes, and olefins in the terpyridine plane Organometallics. 18: 573-581.  0.52
1998 Gunnoe TB, Sabat M, Harman WD. Reactions of TpRe(CO)2(THF) with aromatic molecules (Tp = hydridotris(pyrazolyl)borate) Journal of the American Chemical Society. 120: 8747-8754. DOI: 10.1021/ja980690v  0.52
1998 Winemiller MD, Harman WD. Dearomatization of naphthalene: Stereoselective cis-1,4 tandem additions promoted by osmium(II) Journal of the American Chemical Society. 120: 7835-7840. DOI: 10.1021/ja980624t  0.52
1998 Kolis SP, Kopach ME, Liu R, Harman WD. Activation of benzylic carbons in η2-Arene complexes: A novel and efficient synthesis of functionalized decalins Journal of the American Chemical Society. 120: 6205-6211. DOI: 10.1021/ja9802652  0.52
1998 Kopach ME, Kolis SP, Liu R, Robertson JW, Chordia MD, Harman WD. Stereodefined tandem addition reactions of η2-Arenes: A versatile route to functionalized cyclohexenes Journal of the American Chemical Society. 120: 6199-6204. DOI: 10.1021/ja980264+  0.52
1998 Chordia MD, Harman WD. Asymmetric induction in η2-arene complexes of pentaammineosmium(II) Journal of the American Chemical Society. 120: 5637-5642. DOI: 10.1021/ja980082f  0.52
1998 Kolis SP, Chordia MD, Liu R, Kopach ME, Harman WD. Activation of styrenes toward Diels-Alder cycloadditions by osmium(II): Synthesis of stereodefined decalin ring systems Journal of the American Chemical Society. 120: 2218-2226. DOI: 10.1021/ja973700l  0.52
1998 Brooks BC, Chin RM, Harman WD. The asymmetric π-Bases fac-{Re(dien)(PPh3)(PF3)}+ and fac-{Re(dien)(PPh3)(CO)}+: Evidence for formation of an η2-Furan complex Organometallics. 17: 4716-4723.  0.52
1998 Orth SD, Barrera J, Rowe SM, Helberg LE, Harman WD. Reversible β-hydride elimination of amine ligands forming stable cis-η2-iminium hydride OsII complexes Inorganica Chimica Acta. 270: 337-344.  0.52
1997 Harman WD. The Activation of Aromatic Molecules with Pentaammineosmium(II). Chemical Reviews. 97: 1953-1978. PMID 11848895  0.52
1997 Kolis SP, Kopach ME, Liu R, Harman WD. Osmium-Promoted Electrophilic Substitution of Anisoles: A Versatile New Method for the Incorporation of Carbon Substituents. The Journal of Organic Chemistry. 62: 130-136. PMID 11671374  0.52
1997 Chin RM, Barrera J, Dubois RH, Helberg LE, Sabat M, Bartucz TY, Lough AJ, Morris RH, Harman WD. Preparation of Rhenium(I) and Rhenium(II) Amine Dinitrogen Complexes and the Characterization of an Elongated Dihydrogen Species. Inorganic Chemistry. 36: 3553-3558. PMID 11670037  0.52
1997 Thompson CD, Vachaspati PR, Kolis SP, Gulden PH, Garst ME, Wiese A, Munk SA, Harman WD, Macdonald TL. A proposed mechanism for p-aminoclonidine allergenicity based on its relative oxidative lability. Chemical Research in Toxicology. 10: 1032-6. PMID 9305586 DOI: 10.1021/tx9700735  0.52
1997 Spera ML, Chen H, Moody MW, Hill MM, Harman WD. Electrophilic addition to η2-aldehyde complexes of pentaammineosmium(II): The formation of Fischer carbyne complexes via η2- aldehydium intermediates Journal of the American Chemical Society. 119: 12772-12778. DOI: 10.1021/ja972766d  0.52
1997 Spera ML, Harman WD. Electrophile-promoted carbon - Sulfur bond cleavage in η2-thiophene complexes of pentaammineosmium(II) Journal of the American Chemical Society. 119: 8843-8851. DOI: 10.1021/ja970941k  0.52
1997 Winemiller MD, Kelsch BA, Sabat M, Harman WD. Characterization and isomerization of nη2-naphthalene and η2-phenanthrene complexes of pentaammineosmium(II) Organometallics. 16: 3672-3678.  0.52
1996 Helberg LE, Orth SD, Sabat M, Harman WD. Coordination Chemistry of Low-Valent Rhenium Polypyridyl Complexes: Synthesis, Reactivity, and Electrochemistry. Inorganic Chemistry. 35: 5584-5594. PMID 11666750  0.52
1996 Hodges LM, Spera ML, Moody MW, Harman WD. The synthesis of η2-β-vinylpyrrole complexes and their conversion to highly substituted indoles Journal of the American Chemical Society. 118: 7117-7127. DOI: 10.1021/ja961072m  0.52
1996 Chen H, Harman WD. Dissociative nucleophilic substitution of η2-olefin complexes via a novel η2-vinyl cation inTermediate Journal of the American Chemical Society. 118: 5672-5683. DOI: 10.1021/ja960389j  0.52
1996 Spera ML, Martin Chin R, Winemiller MD, Lopez KW, Sabat M, Harman WD. Sequential electrophile/nucleophile additions for η2-cyclopentadiene complexes of osmium(II), ruthenium(II), and rhenium(I) Organometallics. 15: 5447-5449.  0.52
1996 Kolis SP, Gonzalez J, Bright LM, Harman WD. Dearomatization of anilines by coordination to pentaammineosmium (II) Organometallics. 15: 245-259.  0.52
1995 Gonzalez J, Koontz JI, Hodges LM, Nilsson KR, Neely LK, Myers WH, Sabat M, Harman WD. Osmium-promoted dipolar cycloadditions with pyrroles: An efficient, stereoselective synthesis of 7-azanorbornanes Journal of the American Chemical Society. 117: 3405-3421. DOI: 10.1021/ja00117a010  0.52
1995 Liu R, Chen H, Harman WD. The aldol reaction for 2,3-η2-furan complexes of osmium(II): Cyclization across C(2) and C(4) to form a new heterocycle Organometallics. 14: 2861-2867.  0.52
1995 Helberg LE, Barrera J, Sabat M, Harman WD. Rhenium(I) coordination chemistry: Synthesis, reactivity, and electrochemistry of terpyridyl complexes Inorganic Chemistry. 34: 2033-2041.  0.52
1995 Spera ML, Harman WD. η2-Thiophene complexes of pentaammineosmium(II) and their reversible protonation to form novel η2-2H-thiophenium species Organometallics. 14: 1559-1561.  0.52
1995 Hodges LM, Gonzalez J, Koontz JI, Myers WH, Harman WD. β-Electrophilic additions of pentaammineosmium(II) η2-pyrrole complexes Journal of Organic Chemistry. 60: 2125-2146.  0.52
1994 Li ZW, Harman WD, Lay PA, Taube H. Extension of the preparation of new osmium species to the cis-tetraammine moiety Inorganic Chemistry. 33: 3635-3638. DOI: 10.1021/ic00095a004  0.52
1994 Kopach ME, Harman WD. The osmium(II)-promoted [4 + 2] cycloaddition reaction of anisole and N-methylmaleimide and characterization of the η2-4H-anisolium intermediate Journal of Organic Chemistry. 59: 6506-6507.  0.52
1994 Kopach ME, Harman WD. Novel Michael additions to phenols promoted by osmium(II): Convenient stereoselective syntheses of 2,4- and 2,5-cyclohexadienones Journal of the American Chemical Society. 116: 6581-6592.  0.52
1994 Chen H, Hodges LM, Liu R, Stevens WC, Sabat M, Harman WD. Dearomatization of furan: Structure of an η2-furan complex and a survey of its reactivity Journal of the American Chemical Society. 116: 5499-5500.  0.52
1993 Orth SD, Barrera J, Sabat M, Harman WD. Coordination compounds of pentaaminerhenium(III/II) Inorganic Chemistry. 32: 594-601. DOI: 10.1021/ic00057a018  0.52
1993 Kopach ME, Kelsh LP, Stork KC, Harman WD. Direct 10β-alkylation of β-estradiol: Osmium(II) as a dearomatization agent Journal of the American Chemical Society. 115: 5322-5323.  0.52
1993 Call JT, Hughes KA, Harman WD, Finn MG. Stability of pentaammineosmium(II) in aqueous solution Inorganic Chemistry. 32: 2123-2127.  0.52
1993 Hodges LM, Sabat M, Harman WD. Carbynes and carbenes in coordination chemistry: A new class of pentaammine and tetraammine complexes of osmium(II) Inorganic Chemistry. 32: 371-372.  0.52
1992 Myers WH, Koontz JI, Harman WD. Tautomerizations, protonations, and electrophilic additions of η2-coordinated pyrroles Journal of the American Chemical Society. 114: 5684-5692.  0.52
1992 Barrera J, Orth SD, Harman WD. β-hydride elimination for an amine ligand the microscopic reverse: The first of a cis-iminium hydride in equilibrium with its amine precursor Journal of the American Chemical Society. 114: 7316-7318.  0.52
1991 Lay PA, Harman WD. Recent Advances in Osmium Chemistry Advances in Inorganic Chemistry. 37: 219-379. DOI: 10.1016/S0898-8838(08)60008-2  0.52
1991 Myers WH, Sabat M, Harman WD. Enamine character of a 2,3-η2-coordinated pyrrole Journal of the American Chemical Society. 113: 6682-6683.  0.52
1991 Harman WD, Hasegawa T, Taube H. Allyl complexes of pentaammineosmium Inorganic Chemistry. 30: 453-456.  0.52
1990 Harman WD, Schaefer WP, Taube H. The regio- and stereospecific selective hydrogenation of η2-coordinated arenes Journal of the American Chemical Society. 112: 2682-2685. DOI: 10.1021/ja00163a031  0.52
1990 Harman WD, Taube H. Isostructural η2-dihydrogen complexes [Os(NH3)5(H2)]n+ (n = 2, 3) and the hydrogenation of acetone Journal of the American Chemical Society. 112: 2261-2263. DOI: 10.1021/ja00162a028  0.52
1990 Harman WD, Gebhard M, Taube H. Crystal structure and pyrolysis of decaammine (.eta.2:.eta.2-.mu.-benzene)diosmium(4+): evidence for the formation of a stable .eta.2:.eta.6-.mu.-arene complex Inorganic Chemistry. 29: 567-569. DOI: 10.1021/ic00328a050  1
1990 HARMAN WD, GEBHARD M, TAUBE H. ChemInform Abstract: Crystal Structure and Pyrolysis of ((Os(NH3)5)2(η2:η2-μ-C6H6))4+: Evidence for the Formation of a Stable η2:η6-μ-Arene Complex. Cheminform. 21. DOI: 10.1002/chin.199020267  1
1990 HARMAN WD, GEBHARD M, TAUBE H. ChemInform Abstract: Crystal Structure and Pyrolysis of ((Os(NH3)5)2(η2:η2-μ-C6H6))4+: Evidence for the Formation of a Stable η2:η6-μ-Arene Complex. Cheminform. 21. DOI: 10.1002/chin.199020267  1
1990 Harman WD, Gebhard M, Taube H. Crystal structure and pyrolysis of [(Os(NH3)5)2(η2:η 2-μ-C6H6)]4+: Evidence for the formation of a stable η2:η6-μ-arene complex Inorganic Chemistry. 29: 567-569.  0.52
1989 Cordone R, Harman WD, Taube H. π-Heterocyclic complexes of pentaammineosmium(II) and the metal-induced cycloaddition of pyrrole and maleic anhydride Journal of the American Chemical Society. 111: 5969-5970. DOI: 10.1021/ja00197a083  0.52
1989 Harman WD, Dobson JC, Taube H. Alkyne addition reactions on pentaammineosmium(II): the formation of .pi.-enol and .pi.-vinyl ether complexes Journal of the American Chemical Society. 111: 3061-3062. DOI: 10.1021/ja00190a048  1
1989 Harman WD, Dobson JC, Taube H. Alkyne addition reactions on pentaammineosmium(II): the formation of .pi.-enol and .pi.-vinyl ether complexes Journal of the American Chemical Society. 111: 3061-3062. DOI: 10.1021/ja00190a048  1
1989 Harman WD, Dobson JC, Taube H. Alkyne addition reactions on pentaammineosmium(II): the formation of .pi.-enol and .pi.-vinyl ether complexes Journal of the American Chemical Society. 111: 3061-3062. DOI: 10.1021/ja00190a048  1
1989 Harman WD, Dobson JC, Taube H. Alkyne addition reactions on pentaammineosmium(II): the formation of .pi.-enol and .pi.-vinyl ether complexes Journal of the American Chemical Society. 111: 3061-3062. DOI: 10.1021/ja00190a048  1
1989 Cordone R, Harman WD, Taube H. Carbon-hydrogen bond activation in novel η2-bound cationic heterocycle complexes of pentaammineosmium(II) Journal of the American Chemical Society. 111: 2896-2900. DOI: 10.1021/ja00190a025  0.52
1989 Harman WD, Wishart JF, Taube H. Arene-to-alkyne linkage isomerizations of diphenylacetylene on pentaammineosmium Inorganic Chemistry. 28: 2411-2413. DOI: 10.1021/ic00311a031  0.52
1989 Harman WD, Dobson JC, Taube H. Alkyne addition reactions on pentaammineosmium(II): The formation of π-enol and π-vinyl ether complexes Journal of the American Chemical Society. 111: 3061-3062.  0.52
1988 Harman WD, Taube H. The selective hydrogenation of benzene to cyclohexene on pentaammineosmium(II) Journal of the American Chemical Society. 110: 7906-7907. DOI: 10.1021/ja00231a068  0.52
1988 Harman WD, Taube H. .pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines Journal of the American Chemical Society. 110: 7555-7557. DOI: 10.1021/ja00230a056  1
1988 Harman WD, Taube H. .pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines Journal of the American Chemical Society. 110: 7555-7557. DOI: 10.1021/ja00230a056  1
1988 Harman WD, Taube H. .pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines Journal of the American Chemical Society. 110: 7555-7557. DOI: 10.1021/ja00230a056  1
1988 Harman WD, Taube H. .pi.-Localization in aromatic ligands: formation of mixed-metal .eta.2:.eta.2-.mu.-arene complexes of ruthenium(II) and osmium(II) ammines Journal of the American Chemical Society. 110: 7555-7557. DOI: 10.1021/ja00230a056  1
1988 Dean Harman W, Sekine M, Taube H. Substituent effects on η2-coordinated arene complexes of pentaammineosmium(II) Journal of the American Chemical Society. 110: 5725-5731. DOI: 10.1021/ja00225a024  0.68
1988 Dean Harman W, Sekine M, Taube H. Substituent effects on η2-coordinated arene complexes of pentaammineosmium(II) Journal of the American Chemical Society. 110: 5725-5731. DOI: 10.1021/ja00225a024  0.68
1988 Harman WD, Taube H. Redox-coupled linkage isomerizations with η2-coordinated anilines Journal of the American Chemical Society. 110: 5403-5407. DOI: 10.1021/ja00224a027  0.52
1988 Harman WD, Sekine M, Taube H. Redox-promoted linkage isomerizations of aldehydes and ketones on pentaammineosmium Journal of the American Chemical Society. 110: 2439-2445. DOI: 10.1021/ja00216a016  0.52
1988 Sekine M, Harman WD, Taube H. Nitrile complexes of pentaammineosmium(II) and -(III) Inorganic Chemistry. 27: 3604-3608. DOI: 10.1021/ic00293a033  0.52
1988 Dean Harman W, Taube H. Redox-catalyzed condensation of hexaammineosmium(II) with acetone Inorganic Chemistry. 27: 3261-3262. DOI: 10.1021/ic00291a051  0.92
1988 Dean Harman W, Taube H. Redox-catalyzed condensation of hexaammineosmium(II) with acetone Inorganic Chemistry. 27: 3261-3262. DOI: 10.1021/ic00291a051  0.92
1988 Dean Harman W, Taube H. Redox-catalyzed condensation of hexaammineosmium(II) with acetone Inorganic Chemistry. 27: 3261-3262. DOI: 10.1021/ic00291a051  0.92
1988 Dean Harman W, Taube H. Redox-catalyzed condensation of hexaammineosmium(II) with acetone Inorganic Chemistry. 27: 3261-3262. DOI: 10.1021/ic00291a051  0.92
1988 Harman WD, Taube H. π-Localization in aromatic ligands: Formation of mixed-metal η2:η2-μ-arene complexes of ruthenium(II) and osmium(II) ammines Journal of the American Chemical Society. 110: 7555-7557.  0.52
1987 Harman WD, Taube H. Reactivity of pentaammineosmium(II) with benzene Journal of the American Chemical Society. 109: 1883-1885. DOI: 10.1021/ja00240a061  0.52
1987 Harman WD, Taube H. Synthesis of [Os(NH3)5(η2-TMB)]2+: A valuable precursor for pentaammineosmium(II) chemistry Inorganic Chemistry. 26: 2917-2918. DOI: 10.1021/ic00264a042  0.52
1987 Droege MW, Harman WD, Taube H. Higher oxidation state chemistry of osmocene: Dimeric nature of the osmocenium ion Inorganic Chemistry. 26: 1309-1315. DOI: 10.1021/ic00255a023  0.52
1987 HARMAN WD, FAIRLIE DP, TAUBE H. ChemInform Abstract: Synthesis, Characterization, and Reactivity of the (η2-Acetone)pentaammineosmium(II) Complex. Cheminform. 18. DOI: 10.1002/chin.198719304  1
1987 HARMAN WD, FAIRLIE DP, TAUBE H. ChemInform Abstract: Synthesis, Characterization, and Reactivity of the (η2-Acetone)pentaammineosmium(II) Complex. Cheminform. 18. DOI: 10.1002/chin.198719304  1
1987 HARMAN WD, FAIRLIE DP, TAUBE H. ChemInform Abstract: Synthesis, Characterization, and Reactivity of the (η2-Acetone)pentaammineosmium(II) Complex. Cheminform. 18. DOI: 10.1002/chin.198719304  1
1986 Harman WD, Fairlie DP, Taube H. Synthesis, characterization, and reactivity of the (η2-acetone)pentaammineosmium(II) complex Journal of the American Chemical Society. 108: 8223-8227. DOI: 10.1021/ja00286a018  0.52
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