Kenneth D. Karlin, Ph.D. - Publications

Affiliations: 
1978-1989 Chemistry State University of New York, Albany, Albany, NY, United States 
 1990- Chemistry Johns Hopkins University, Baltimore, MD 
Area:
Inorganic/Bioinorganic Chemistry
Website:
http://www.jhu.edu/~chem/karlin/

280 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any innacuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Ehudin MA, Schaefer AW, Adam SM, Quist DA, Diaz DE, Tang JA, Solomon EI, Karlin KD. Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome oxidase inspired low-spin heme-peroxo-copper complexes. Chemical Science. 10: 2893-2905. PMID 30996867 DOI: 10.1039/c8sc05165h  1
2019 Quist DA, Ehudin MA, Karlin KD. Unprecedented direct cupric-superoxo conversion to a bis--oxo dicopper(III) complex and resulting oxidative activity. Inorganica Chimica Acta. 485: 155-161. PMID 30988551 DOI: 10.1016/j.ica.2018.10.015  0.52
2019 Ehudin MA, Gee LB, Sabuncu S, Braun A, Moënne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD. Tuning the Geometric and Electronic Structure of Synthetic High-Valent Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands. Journal of the American Chemical Society. PMID 30860832 DOI: 10.1021/jacs.9b00795  1
2019 Schaefer AW, Ehudin MA, Quist DA, Tang JA, Karlin KD, Solomon EI. Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions. Journal of the American Chemical Society. PMID 30836005 DOI: 10.1021/jacs.9b00118  1
2018 Adam SM, Wijeratne GB, Rogler PJ, Diaz DE, Quist DA, Liu JJ, Karlin KD. Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function. Chemical Reviews. PMID 30372042 DOI: 10.1021/acs.chemrev.8b00074  1
2018 Hong S, Yan JJ, Karmalkar DG, Sutherlin KD, Kim J, Lee YM, Goo Y, Mascharak PK, Hedman B, Hodgson KO, Karlin KD, Solomon EI, Nam W. A mononuclear nonheme {FeNO} complex: synthesis and structural and spectroscopic characterization. Chemical Science. 9: 6952-6960. PMID 30210769 DOI: 10.1039/c8sc01962b  1
2018 Bhadra M, Lee JYC, Cowley RE, Kim S, Siegler MA, Solomon EI, Karlin KD. Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. Journal of the American Chemical Society. PMID 29957998 DOI: 10.1021/jacs.8b04671  1
2017 Sharma SK, Schaefer AW, Lim H, Matsumura H, Moënne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD. A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex - The Product of the Reaction of Nitrogen Monoxide (•NO(g)) with a Ferric-Superoxide Species. Journal of the American Chemical Society. PMID 29091732 DOI: 10.1021/jacs.7b08468  1
2017 López I, Cao R, Quist DA, Karlin KD, Le Poul N. Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29073346 DOI: 10.1002/chem.201705066  0.84
2017 Wijeratne GB, Hematian S, Siegler MA, Karlin KD. Copper(I) / NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex - Redox Reversal Giving Copper(I) / NO(g) Disproportionation. Journal of the American Chemical Society. PMID 28820592 DOI: 10.1021/jacs.7b07808  1
2017 Schaefer AW, Kieber-Emmons MT, Adam SM, Karlin KD, Solomon EI. Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. Journal of the American Chemical Society. PMID 28521498 DOI: 10.1021/jacs.7b03292  1
2017 Garcia-Bosch I, Cowley RE, Díaz DE, Peterson RL, Solomon EI, Karlin KD. Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2Cu(II)2(O2(2-)) Species to Form L2Cu(III)2(O)2 Cores with Enhanced Oxidative Reactivity. Journal of the American Chemical Society. PMID 28195739 DOI: 10.1021/jacs.6b12990  1
2016 Adam SM, Garcia-Bosch I, Schaefer AW, Sharma SK, Siegler MA, Solomon EI, Karlin KD. Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-Operoxo Breakage versus Reductive O-O Cleavage Chemistry. Journal of the American Chemical Society. PMID 28029788 DOI: 10.1021/jacs.6b11322  1
2016 Cao R, Elrod LT, Lehane RL, Kim E, Karlin KD. A Peroxynitrite Dicopper Complex: Formation via Cu-NO and Cu-O2 Intermediates and Reactivity via O-O Cleavage Chemistry. Journal of the American Chemical Society. 138: 16148-16158. PMID 27960334 DOI: 10.1021/jacs.6b10689  0.96
2016 Quist DA, Diaz DE, Liu JJ, Karlin KD. Activation of dioxygen by copper metalloproteins and insights from model complexes. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27921179 DOI: 10.1007/s00775-016-1415-2  0.6
2016 Liu JJ, Diaz DE, Quist DA, Karlin KD. Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms. Israel Journal of Chemistry. 56: 9-10. PMID 27909346 DOI: 10.1002/ijch.201600025  0.6
2016 Hong S, Kumar P, Cho KB, Lee YM, Karlin KD, Nam W. Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes. Angewandte Chemie (International Ed. in English). PMID 27593390 DOI: 10.1002/anie.201605705  1
2016 Yamada M, Karlin KD, Fukuzumi S. One-Step Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide Catalysed by Copper Complexes Incorporated into Mesoporous Silica-Alumina. Chemical Science (Royal Society of Chemistry : 2010). 7: 2856-2863. PMID 27453774 DOI: 10.1039/C5SC04312C  0.56
2016 Sharma SK, Kim H, Rogler PJ, A Siegler M, Karlin KD. Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27350154 DOI: 10.1007/s00775-016-1369-4  1
2016 Cao R, Saracini C, Ginsbach JW, Kieber-Emmons MT, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. Journal of the American Chemical Society. PMID 27228314 DOI: 10.1021/jacs.6b02404  1
2016 Kumar P, Lee YM, Hu L, Chen JW, Park YJ, Yao J, Chen H, Karlin KD, Nam W. Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation. Journal of the American Chemical Society. PMID 27221953 DOI: 10.1021/jacs.6b04040  1
2016 Garcia-Bosch I, Cowley RE, Díaz DE, Siegler MA, Nam W, Solomon EI, Karlin KD. Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2 O2 Core with Unexpected Structure and Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26919169 DOI: 10.1002/chem.201600551  1
2015 Saracini C, Ohkubo K, Suenobu T, Meyer GJ, Karlin KD, Fukuzumi S. Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates. Journal of the American Chemical Society. PMID 26651492 DOI: 10.1021/jacs.5b10177  1
2015 Karlin KD, Lippard SJ, Valentine JS, Burrows CJ. Solving 21st Century Problems in Biological Inorganic Chemistry Using Synthetic Models. Accounts of Chemical Research. 48: 2659-60. PMID 26481328 DOI: 10.1021/acs.accounts.5b00447  1
2015 Chatterjee S, Sengupta K, Hematian S, Karlin KD, Dey A. Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction. Journal of the American Chemical Society. PMID 26419806 DOI: 10.1021/jacs.5b06513  1
2015 Hematian S, Garcia-Bosch I, Karlin KD. Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides. Accounts of Chemical Research. 48: 2462-74. PMID 26244814 DOI: 10.1021/acs.accounts.5b00265  1
2015 Sharma SK, Rogler PJ, Karlin KD. Reactions of a heme-superoxo complex toward a cuprous chelate and •NO(g): CcO and NOD chemistry. Journal of Porphyrins and Phthalocyanines. 19: 352-360. PMID 26056423 DOI: 10.1142/S108842461550025X  1
2015 Hematian S, Kenkel I, Shubina TE, Dürr M, Liu JJ, Siegler MA, Ivanovic-Burmazovic I, Karlin KD. Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs. Journal of the American Chemical Society. 137: 6602-15. PMID 25974136 DOI: 10.1021/jacs.5b02174  1
2015 Hematian S, Kenkel I, Shubina TE, Dürr M, Liu JJ, Siegler MA, Ivanovic-Burmazovic I, Karlin KD. Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs. Journal of the American Chemical Society. 137: 6602-15. PMID 25974136 DOI: 10.1021/jacs.5b02174  1
2015 Kumar P, Lee YM, Park YJ, Siegler MA, Karlin KD, Nam W. Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. Journal of the American Chemical Society. 137: 4284-7. PMID 25793706 DOI: 10.1021/ja513234b  1
2015 Kumar P, Lee YM, Park YJ, Siegler MA, Karlin KD, Nam W. Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. Journal of the American Chemical Society. 137: 4284-7. PMID 25793706 DOI: 10.1021/ja513234b  1
2015 Lee JY, Karlin KD. Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation. Current Opinion in Chemical Biology. 25: 184-93. PMID 25756327 DOI: 10.1016/j.cbpa.2015.02.014  1
2015 Lee JY, Karlin KD. Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation. Current Opinion in Chemical Biology. 25: 184-93. PMID 25756327 DOI: 10.1016/j.cbpa.2015.02.014  1
2015 Kim S, Ginsbach JW, Lee JY, Peterson RL, Liu JJ, Siegler MA, Sarjeant AA, Solomon EI, Karlin KD. Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. Journal of the American Chemical Society. 137: 2867-74. PMID 25706825 DOI: 10.1021/ja508371q  1
2015 Kim S, Ginsbach JW, Lee JY, Peterson RL, Liu JJ, Siegler MA, Sarjeant AA, Solomon EI, Karlin KD. Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. Journal of the American Chemical Society. 137: 2867-74. PMID 25706825 DOI: 10.1021/ja508371q  1
2015 Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society. 137: 2796-9. PMID 25697226 DOI: 10.1021/ja511504n  1
2015 Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society. 137: 2796-9. PMID 25697226 DOI: 10.1021/ja511504n  1
2015 Kakuda S, Rolle CJ, Ohkubo K, Siegler MA, Karlin KD, Fukuzumi S. Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. Journal of the American Chemical Society. 137: 3330-7. PMID 25659416 DOI: 10.1021/ja512584r  1
2015 Kakuda S, Rolle CJ, Ohkubo K, Siegler MA, Karlin KD, Fukuzumi S. Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. Journal of the American Chemical Society. 137: 3330-7. PMID 25659416 DOI: 10.1021/ja512584r  1
2015 Garcia-Bosch I, Adam SM, Schaefer AW, Sharma SK, Peterson RL, Solomon EI, Karlin KD. A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes. Journal of the American Chemical Society. 137: 1032-5. PMID 25594533 DOI: 10.1021/ja5115198  1
2015 Garcia-Bosch I, Adam SM, Schaefer AW, Sharma SK, Peterson RL, Solomon EI, Karlin KD. A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes. Journal of the American Chemical Society. 137: 1032-5. PMID 25594533 DOI: 10.1021/ja5115198  1
2014 Park GY, Lee JY, Himes RA, Thomas GS, Blackburn NJ, Karlin KD. Copper-peptide complex structure and reactivity when found in conserved His-X(aa)-His sequences. Journal of the American Chemical Society. 136: 12532-5. PMID 25171435 DOI: 10.1021/ja505098v  1
2014 Park GY, Lee JY, Himes RA, Thomas GS, Blackburn NJ, Karlin KD. Copper-peptide complex structure and reactivity when found in conserved His-X(aa)-His sequences. Journal of the American Chemical Society. 136: 12532-5. PMID 25171435 DOI: 10.1021/ja505098v  1
2014 Lee JY, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD. Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. Journal of the American Chemical Society. 136: 9925-37. PMID 24953129 DOI: 10.1021/ja503105b  1
2014 Lee JY, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD. Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. Journal of the American Chemical Society. 136: 9925-37. PMID 24953129 DOI: 10.1021/ja503105b  1
2014 Kim S, Ginsbach JW, Billah AI, Siegler MA, Moore CD, Solomon EI, Karlin KD. Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. Journal of the American Chemical Society. 136: 8063-71. PMID 24854766 DOI: 10.1021/ja502974c  1
2014 Kim S, Ginsbach JW, Billah AI, Siegler MA, Moore CD, Solomon EI, Karlin KD. Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. Journal of the American Chemical Society. 136: 8063-71. PMID 24854766 DOI: 10.1021/ja502974c  1
2014 Kieber-Emmons MT, Ginsbach JW, Wick PK, Lucas HR, Helton ME, Lucchese B, Suzuki M, Zuberbühler AD, Karlin KD, Solomon EI. Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angewandte Chemie (International Ed. in English). 53: 4935-9. PMID 24700427 DOI: 10.1002/anie.201402166  1
2014 Kieber-Emmons MT, Ginsbach JW, Wick PK, Lucas HR, Helton ME, Lucchese B, Suzuki M, Zuberbühler AD, Karlin KD, Solomon EI. Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angewandte Chemie (International Ed. in English). 53: 4935-9. PMID 24700427 DOI: 10.1002/anie.201402166  1
2014 Hematian S, Siegler MA, Karlin KD. Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 19: 515-28. PMID 24430198 DOI: 10.1007/s00775-013-1081-6  1
2014 Hematian S, Siegler MA, Karlin KD. Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 19: 515-28. PMID 24430198 DOI: 10.1007/s00775-013-1081-6  1
2014 Saracini C, Liakos DG, Zapata Rivera JE, Neese F, Meyer GJ, Karlin KD. Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studies. Journal of the American Chemical Society. 136: 1260-3. PMID 24428309 DOI: 10.1021/ja4115314  1
2014 Saracini C, Liakos DG, Zapata Rivera JE, Neese F, Meyer GJ, Karlin KD. Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studies. Journal of the American Chemical Society. 136: 1260-3. PMID 24428309 DOI: 10.1021/ja4115314  1
2014 Yokoyama A, Han JE, Karlin KD, Nam W. An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion. Chemical Communications (Cambridge, England). 50: 1742-4. PMID 24394960 DOI: 10.1039/c3cc48782b  1
2014 Kim S, Siegler MA, Karlin KD. Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. Chemical Communications (Cambridge, England). 50: 2844-6. PMID 24322625 DOI: 10.1039/c3cc47942k  1
2014 Karlin KD. Progress in Inorganic Chemistry Progress in Inorganic Chemistry. 59: 1-583. DOI: 10.1002/9781118869994  1
2013 Li Y, Sharma SK, Karlin KD. New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins. Polyhedron. 58. PMID 24223452 DOI: 10.1016/j.poly.2012.11.011  1
2013 Li Y, Sharma SK, Karlin KD. New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins. Polyhedron. 58. PMID 24223452 DOI: 10.1016/j.poly.2012.11.011  1
2013 Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society. 135: 16454-67. PMID 24164682 DOI: 10.1021/ja4065377  1
2013 Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society. 135: 16454-67. PMID 24164682 DOI: 10.1021/ja4065377  1
2013 Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorganic Chemistry. 52: 12872-4. PMID 24164429 DOI: 10.1021/ic402357u  1
2013 Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorganic Chemistry. 52: 12872-4. PMID 24164429 DOI: 10.1021/ic402357u  1
2013 Garcia-Bosch I, Sharma SK, Karlin KD. A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate. Journal of the American Chemical Society. 135: 16248-51. PMID 24147457 DOI: 10.1021/ja405739m  1
2013 Qayyum MF, Sarangi R, Fujisawa K, Stack TD, Karlin KD, Hodgson KO, Hedman B, Solomon EI. L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes. Journal of the American Chemical Society. 135: 17417-31. PMID 24102191 DOI: 10.1021/ja4078717  1
2013 Sharma V, Karlin KD, Wikström M. Computational study of the activated O(H) state in the catalytic mechanism of cytochrome c oxidase. Proceedings of the National Academy of Sciences of the United States of America. 110: 16844-9. PMID 24082138 DOI: 10.1073/pnas.1220379110  1
2013 Yokoyama A, Cho KB, Karlin KD, Nam W. Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. Journal of the American Chemical Society. 135: 14900-3. PMID 24066924 DOI: 10.1021/ja405891n  1
2013 Yokoyama A, Cho KB, Karlin KD, Nam W. Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. Journal of the American Chemical Society. 135: 14900-3. PMID 24066924 DOI: 10.1021/ja405891n  1
2013 Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S. Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group. Journal of the American Chemical Society. 135: 6513-22. PMID 23509853 DOI: 10.1021/ja3125977  1
2013 Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S. Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group. Journal of the American Chemical Society. 135: 6513-22. PMID 23509853 DOI: 10.1021/ja3125977  1
2013 Fukuzumi S, Karlin KD. Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. Coordination Chemistry Reviews. 257: 187-195. PMID 23470920 DOI: 10.1016/j.ccr.2012.05.031  1
2013 Fukuzumi S, Karlin KD. Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. Coordination Chemistry Reviews. 257: 187-195. PMID 23470920 DOI: 10.1016/j.ccr.2012.05.031  1
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex. Journal of the American Chemical Society. 135: 4018-26. PMID 23442145 DOI: 10.1021/ja312256u  1
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex. Journal of the American Chemical Society. 135: 4018-26. PMID 23442145 DOI: 10.1021/ja312256u  1
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. Journal of the American Chemical Society. 135: 2825-34. PMID 23394287 DOI: 10.1021/ja312523u  1
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. Journal of the American Chemical Society. 135: 2825-34. PMID 23394287 DOI: 10.1021/ja312523u  1
2013 Peterson RL, Kim S, Karlin KD. Copper Enzymes Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 3: 149-177. DOI: 10.1016/B978-0-08-097774-4.00309-0  1
2012 Fukuzumi S, Yamada Y, Karlin KD. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. Electrochimica Acta. 82: 493-511. PMID 23457415 DOI: 10.1016/j.electacta.2012.03.132  1
2012 Fukuzumi S, Yamada Y, Karlin KD. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. Electrochimica Acta. 82: 493-511. PMID 23457415 DOI: 10.1016/j.electacta.2012.03.132  1
2012 Karlin KD, Zhang CX, Rheingold AL, Galliker B, Kaderli S, Zuberbühler AD. Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations. Inorganica Chimica Acta. 389: 138-150. PMID 23420124 DOI: 10.1016/j.ica.2012.01.042  1
2012 Karlin KD, Zhang CX, Rheingold AL, Galliker B, Kaderli S, Zuberbühler AD. Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations. Inorganica Chimica Acta. 389: 138-150. PMID 23420124 DOI: 10.1016/j.ica.2012.01.042  1
2012 Kim S, Saracini C, Siegler MA, Drichko N, Karlin KD. Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorganic Chemistry. 51: 12603-5. PMID 23153187 DOI: 10.1021/ic302071e  1
2012 Kim S, Saracini C, Siegler MA, Drichko N, Karlin KD. Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorganic Chemistry. 51: 12603-5. PMID 23153187 DOI: 10.1021/ic302071e  1
2012 Hematian S, Siegler MA, Karlin KD. Heme/copper assembly mediated nitrite and nitric oxide interconversion. Journal of the American Chemical Society. 134: 18912-5. PMID 23130610 DOI: 10.1021/ja3083818  1
2012 Hematian S, Siegler MA, Karlin KD. Heme/copper assembly mediated nitrite and nitric oxide interconversion. Journal of the American Chemical Society. 134: 18912-5. PMID 23130610 DOI: 10.1021/ja3083818  1
2012 Yokoyama A, Han JE, Cho J, Kubo M, Ogura T, Siegler MA, Karlin KD, Nam W. Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. Journal of the American Chemical Society. 134: 15269-72. PMID 22950528 DOI: 10.1021/ja307384e  1
2012 Yokoyama A, Han JE, Cho J, Kubo M, Ogura T, Siegler MA, Karlin KD, Nam W. Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. Journal of the American Chemical Society. 134: 15269-72. PMID 22950528 DOI: 10.1021/ja307384e  1
2012 Ghiladi RA, Rheingold AL, Siegler MA, Karlin KD. Synthesis and Characterization of New Trinuclear Copper Complexes. Inorganica Chimica Acta. 389: 131-137. PMID 22773847 DOI: 10.1016/j.ica.2012.02.020  1
2012 Ghiladi RA, Rheingold AL, Siegler MA, Karlin KD. Synthesis and Characterization of New Trinuclear Copper Complexes. Inorganica Chimica Acta. 389: 131-137. PMID 22773847 DOI: 10.1016/j.ica.2012.02.020  1
2012 Yamada Y, Maeda K, Ohkubo K, Karlin KD, Fukuzumi S. Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex. Physical Chemistry Chemical Physics : Pccp. 14: 9654-9. PMID 22692585 DOI: 10.1039/c2cp41207a  1
2012 Park GY, Qayyum MF, Woertink J, Hodgson KO, Hedman B, Narducci Sarjeant AA, Solomon EI, Karlin KD. Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage. Journal of the American Chemical Society. 134: 8513-24. PMID 22571744 DOI: 10.1021/ja300674m  1
2012 Fukuzumi S, Doi K, Itoh A, Suenobu T, Ohkubo K, Yamada Y, Karlin KD. Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity. Proceedings of the National Academy of Sciences of the United States of America. 109: 15572-7. PMID 22543164 DOI: 10.1073/pnas.1119994109  1
2012 Fukuzumi S, Tahsini L, Lee YM, Ohkubo K, Nam W, Karlin KD. Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes. Journal of the American Chemical Society. 134: 7025-35. PMID 22462521 DOI: 10.1021/ja211656g  1
2012 Comba P, Haaf C, Helmle S, Karlin KD, Pandian S, Waleska A. Dioxygen reactivity of new bispidine-copper complexes. Inorganic Chemistry. 51: 2841-51. PMID 22332786 DOI: 10.1021/ic2019296  1
2012 Tahsini L, Kotani H, Lee YM, Cho J, Nam W, Karlin KD, Fukuzumi S. Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 1084-93. PMID 22237962 DOI: 10.1002/chem.201103215  1
2012 Tahsini L, Kotani H, Lee YM, Cho J, Nam W, Karlin KD, Fukuzumi S. Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 1084-93. PMID 22237962 DOI: 10.1002/chem.201103215  1
2012 Kieber-Emmons MT, Qayyum MF, Li Y, Halime Z, Hodgson KO, Hedman B, Karlin KD, Solomon EI. Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase. Angewandte Chemie (International Ed. in English). 51: 168-72. PMID 22095556 DOI: 10.1002/anie.201104080  1
2011 Kieber-Emmons MT, Li Y, Halime Z, Karlin KD, Solomon EI. Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorganic Chemistry. 50: 11777-86. PMID 22007669 DOI: 10.1021/ic2018727  1
2011 Kieber-Emmons MT, Li Y, Halime Z, Karlin KD, Solomon EI. Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorganic Chemistry. 50: 11777-86. PMID 22007669 DOI: 10.1021/ic2018727  1
2011 Halime Z, Kotani H, Li Y, Fukuzumi S, Karlin KD. Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights. Proceedings of the National Academy of Sciences of the United States of America. 108: 13990-4. PMID 21808032 DOI: 10.1073/pnas.1104698108  1
2011 Halime Z, Kotani H, Li Y, Fukuzumi S, Karlin KD. Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights. Proceedings of the National Academy of Sciences of the United States of America. 108: 13990-4. PMID 21808032 DOI: 10.1073/pnas.1104698108  1
2011 Peterson RL, Himes RA, Kotani H, Suenobu T, Tian L, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Cupric superoxo-mediated intermolecular C-H activation chemistry. Journal of the American Chemical Society. 133: 1702-5. PMID 21265534 DOI: 10.1021/ja110466q  1
2011 Peterson RL, Himes RA, Kotani H, Suenobu T, Tian L, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Cupric superoxo-mediated intermolecular C-H activation chemistry. Journal of the American Chemical Society. 133: 1702-5. PMID 21265534 DOI: 10.1021/ja110466q  1
2011 Choi YJ, Cho KB, Kubo M, Ogura T, Karlin KD, Cho J, Nam W. Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Transactions (Cambridge, England : 2003). 40: 2234-41. PMID 21258722 DOI: 10.1039/c0dt01036g  1
2011 Choi YJ, Cho KB, Kubo M, Ogura T, Karlin KD, Cho J, Nam W. Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Transactions (Cambridge, England : 2003). 40: 2234-41. PMID 21258722 DOI: 10.1039/c0dt01036g  1
2011 Halime Z, Karlin KD. Cytochrome c Oxidase and Models Copper-Oxygen Chemistry. 283-319. DOI: 10.1002/9781118094365.ch9  1
2011 Karlin KD, Itoh S. Copper-Oxygen Chemistry Copper-Oxygen Chemistry. DOI: 10.1002/9781118094365  1
2010 Woertink JS, Tian L, Maiti D, Lucas HR, Himes RA, Karlin KD, Neese F, Würtele C, Holthausen MC, Bill E, Sundermeyer J, Schindler S, Solomon EI. Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state. Inorganic Chemistry. 49: 9450-9. PMID 20857998 DOI: 10.1021/ic101138u  1
2010 Lee Y, Lee DH, Park GY, Lucas HR, Narducci Sarjeant AA, Kieber-Emmons MT, Vance MA, Milligan AE, Solomon EI, Karlin KD. Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species. Inorganic Chemistry. 49: 8873-85. PMID 20822156 DOI: 10.1021/ic101041m  1
2010 Karlin KD. Bioinorganic chemistry: Redox control of oxoiron(IV). Nature Chemistry. 2: 711-2. PMID 20729888 DOI: 10.1038/nchem.813  1
2010 Karlin KD. Bioinorganic chemistry: Redox control of oxoiron(IV). Nature Chemistry. 2: 711-2. PMID 20729888 DOI: 10.1038/nchem.813  1
2010 Lucas HR, Meyer GJ, Karlin KD. CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism. Journal of the American Chemical Society. 132: 12927-40. PMID 20726586 DOI: 10.1021/ja104107q  1
2010 Himes RA, Barnese K, Karlin KD. One is lonely and three is a crowd: two coppers are for methane oxidation. Angewandte Chemie (International Ed. in English). 49: 6714-6. PMID 20672276 DOI: 10.1002/anie.201003403  1
2010 Himes RA, Barnese K, Karlin KD. One is lonely and three is a crowd: two coppers are for methane oxidation. Angewandte Chemie (International Ed. in English). 49: 6714-6. PMID 20672276 DOI: 10.1002/anie.201003403  1
2010 Schopfer MP, Wang J, Karlin KD. Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling. Inorganic Chemistry. 49: 6267-82. PMID 20666386 DOI: 10.1021/ic100033y  1
2010 Fukuzumi S, Kotani H, Lucas HR, Doi K, Suenobu T, Peterson RL, Karlin KD. Mononuclear copper complex-catalyzed four-electron reduction of oxygen. Journal of the American Chemical Society. 132: 6874-5. PMID 20443560 DOI: 10.1021/ja100538x  1
2010 Halime Z, Kieber-Emmons MT, Qayyum MF, Mondal B, Gandhi T, Puiu SC, Chufán EE, Sarjeant AA, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorganic Chemistry. 49: 3629-45. PMID 20380465 DOI: 10.1021/ic9020993  1
2010 Halime Z, Kieber-Emmons MT, Qayyum MF, Mondal B, Gandhi T, Puiu SC, Chufán EE, Sarjeant AA, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorganic Chemistry. 49: 3629-45. PMID 20380465 DOI: 10.1021/ic9020993  1
2010 Karlin KD. Bioinorganic chemistry: Model offers intermediate insight. Nature. 463: 168-9. PMID 20075910 DOI: 10.1038/463168a  1
2010 Karlin KD. Bioinorganic chemistry: Model offers intermediate insight. Nature. 463: 168-9. PMID 20075910 DOI: 10.1038/463168a  1
2010 Wang J, Schopfer MP, Puiu SC, Sarjeant AA, Karlin KD. Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. Inorganic Chemistry. 49: 1404-19. PMID 20030370 DOI: 10.1021/ic901431r  1
2010 Wang J, Schopfer MP, Puiu SC, Sarjeant AA, Karlin KD. Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. Inorganic Chemistry. 49: 1404-19. PMID 20030370 DOI: 10.1021/ic901431r  1
2010 Park GY, Lee Y, Lee DH, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex. Chemical Communications (Cambridge, England). 46: 91-3. PMID 20024303 DOI: 10.1039/b918616f  1
2009 Lucas HR, Karlin KD. Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. Metal Ions in Life Sciences. 6: 295-361. PMID 20877799 DOI: 10.1039/BK9781847559159-00295  1
2009 Lucas HR, Karlin KD. Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. Metal Ions in Life Sciences. 6: 295-361. PMID 20877799 DOI: 10.1039/BK9781847559159-00295  1
2009 Himes RA, Karlin KD. A new copper-oxo player in methane oxidation. Proceedings of the National Academy of Sciences of the United States of America. 106: 18877-8. PMID 19889982 DOI: 10.1073/pnas.0911413106  1
2009 Lee Y, Park GY, Lucas HR, Vajda PL, Kamaraj K, Vance MA, Milligan AE, Woertink JS, Siegler MA, Narducci Sarjeant AA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. Inorganic Chemistry. 48: 11297-309. PMID 19886646 DOI: 10.1021/ic9017695  1
2009 Lucas HR, Meyer GJ, Karlin KD. Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems. Journal of the American Chemical Society. 131: 13924-5. PMID 19736941 DOI: 10.1021/ja906172c  1
2009 Lucas HR, Meyer GJ, Karlin KD. Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems. Journal of the American Chemical Society. 131: 13924-5. PMID 19736941 DOI: 10.1021/ja906172c  1
2009 Maiti D, Woertink JS, Ghiladi RA, Solomon EI, Karlin KD. Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex. Inorganic Chemistry. 48: 8342-56. PMID 19663454 DOI: 10.1021/ic900975y  1
2009 Park GY, Deepalatha S, Puiu SC, Lee DH, Mondal B, Narducci Sarjeant AA, del Rio D, Pau MY, Solomon EI, Karlin KD. A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 14: 1301-11. PMID 19662443 DOI: 10.1007/s00775-009-0575-8  1
2009 Schopfer MP, Mondal B, Lee DH, Sarjeant AA, Karlin KD. Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate. Journal of the American Chemical Society. 131: 11304-5. PMID 19627146 DOI: 10.1021/ja904832j  1
2009 Himes RA, Karlin KD. Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). Current Opinion in Chemical Biology. 13: 119-31. PMID 19286415 DOI: 10.1016/j.cbpa.2009.02.025  1
2009 Himes RA, Karlin KD. Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). Current Opinion in Chemical Biology. 13: 119-31. PMID 19286415 DOI: 10.1016/j.cbpa.2009.02.025  1
2009 Lucas HR, Li L, Sarjeant AA, Vance MA, Solomon EI, Karlin KD. Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex. Journal of the American Chemical Society. 131: 3230-45. PMID 19216527 DOI: 10.1021/ja807081d  1
2009 Wang J, Schopfer MP, Sarjeant AA, Karlin KD. Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). Journal of the American Chemical Society. 131: 450-1. PMID 19099478 DOI: 10.1021/ja8084324  1
2009 Wang J, Schopfer MP, Sarjeant AA, Karlin KD. Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). Journal of the American Chemical Society. 131: 450-1. PMID 19099478 DOI: 10.1021/ja8084324  1
2008 Himes RA, Park GY, Siluvai GS, Blackburn NJ, Karlin KD. Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. Angewandte Chemie (International Ed. in English). 47: 9084-7. PMID 18932185 DOI: 10.1002/anie.200803908  1
2008 Himes RA, Park GY, Siluvai GS, Blackburn NJ, Karlin KD. Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. Angewandte Chemie (International Ed. in English). 47: 9084-7. PMID 18932185 DOI: 10.1002/anie.200803908  1
2008 Maiti D, Narducci Sarjeant AA, Karlin KD. Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. Inorganic Chemistry. 47: 8736-47. PMID 18783212 DOI: 10.1021/ic800617m  1
2008 Maiti D, Narducci Sarjeant AA, Karlin KD. Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. Inorganic Chemistry. 47: 8736-47. PMID 18783212 DOI: 10.1021/ic800617m  1
2008 Maiti D, Lee DH, Narducci Sarjeant AA, Pau MY, Solomon EI, Gaoutchenova K, Sundermeyer J, Karlin KD. Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species. Journal of the American Chemical Society. 130: 6700-1. PMID 18457392 DOI: 10.1021/ja801540e  1
2008 Zhu Q, Lian Y, Thyagarajan S, Rokita SE, Karlin KD, Blough NV. Hydrogen peroxide and dioxygen activation by dinuclear copper complexes in aqueous solution: hydroxyl radical production initiated by internal electron transfer. Journal of the American Chemical Society. 130: 6304-5. PMID 18433125 DOI: 10.1021/ja800080z  1
2008 Maiti D, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. Inorganic Chemistry. 47: 3787-800. PMID 18396862 DOI: 10.1021/ic702437c  1
2008 Maiti D, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. Inorganic Chemistry. 47: 3787-800. PMID 18396862 DOI: 10.1021/ic702437c  1
2008 Maiti D, Narducci Sarjeant AA, Itoh S, Karlin KD. Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety. Journal of the American Chemical Society. 130: 5644-5. PMID 18393421 DOI: 10.1021/ja800795b  1
2008 Maiti D, Narducci Sarjeant AA, Itoh S, Karlin KD. Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety. Journal of the American Chemical Society. 130: 5644-5. PMID 18393421 DOI: 10.1021/ja800795b  1
2008 Sarangi R, York JT, Helton ME, Fujisawa K, Karlin KD, Tolman WB, Hodgson KO, Hedman B, Solomon EI. X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding. Journal of the American Chemical Society. 130: 676-86. PMID 18076173 DOI: 10.1021/ja0762745  1
2008 Fry HC, Lucas HR, Sarjeant AA, Karlin KD, Meyer GJ. Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorganic Chemistry. 47: 241-56. PMID 18052158 DOI: 10.1021/ic701903h  1
2008 Fry HC, Lucas HR, Sarjeant AA, Karlin KD, Meyer GJ. Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorganic Chemistry. 47: 241-56. PMID 18052158 DOI: 10.1021/ic701903h  1
2008 Maiti D, Lee DH, Gaoutchenova K, Würtele C, Holthausen MC, Sarjeant AA, Sundermeyer J, Schindler S, Karlin KD. Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie (International Ed. in English). 47: 82-5. PMID 18022887 DOI: 10.1002/anie.200704389  1
2008 Maiti D, Lee DH, Gaoutchenova K, Würtele C, Holthausen MC, Sarjeant AA, Sundermeyer J, Schindler S, Karlin KD. Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie (International Ed. in English). 47: 82-5. PMID 18022887 DOI: 10.1002/anie.200704389  1
2008 George SD, Karlin KD. Protagonists in Chemistry Inorganica Chimica Acta. 361: 807-808. DOI: 10.1016/j.ica.2007.09.001  1
2008 Fry HC, Lucas HR, Zakharov LN, Rheingold AL, Meyer GJ, Karlin KD. Intermolecular versus intramolecular electron-/atom- (Cl{radical dot}) transfer in heme-iron and copper pyridylalkylamine complexes Inorganica Chimica Acta. 361: 1100-1115. DOI: 10.1016/j.ica.2007.08.016  1
2008 Lucas HR, Meyer GJ, Karlin KD. The rate of dioxygen and carbon monoxide binding to copper(I) complexes of various ligands: Extension of the "flash-and-trap" technique Acs National Meeting Book of Abstracts 1
2007 Lee Y, Lee DH, Sarjeant AA, Karlin KD. Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition. Journal of Inorganic Biochemistry. 101: 1845-58. PMID 17651805 DOI: 10.1016/j.jinorgbio.2007.06.016  1
2007 Chufán EE, Mondal B, Gandhi T, Kim E, Rubie ND, Moënne-Loccoz P, Karlin KD. Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity. Inorganic Chemistry. 46: 6382-94. PMID 17616124 DOI: 10.1021/ic700363k  1
2007 Maiti D, Woertink JS, Vance MA, Milligan AE, Sarjeant AA, Solomon EI, Karlin KD. Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry. Journal of the American Chemical Society. 129: 8882-92. PMID 17592845 DOI: 10.1021/ja071968z  1
2007 Lee DH, Hatcher LQ, Vance MA, Sarangi R, Milligan AE, Sarjeant AA, Incarvito CD, Rheingold AL, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues. Inorganic Chemistry. 46: 6056-68. PMID 17580938 DOI: 10.1021/ic700541k  1
2007 Chufán EE, Puiu SC, Karlin KD. Heme-copper/dioxygen adduct formation, properties, and reactivity. Accounts of Chemical Research. 40: 563-72. PMID 17550225 DOI: 10.1021/ar700031t  1
2007 Maiti D, Lucas HR, Sarjeant AA, Karlin KD. Aryl hydroxylation from a mononuclear copper-hydroperoxo species. Journal of the American Chemical Society. 129: 6998-9. PMID 17497785 DOI: 10.1021/ja071704c  1
2007 Maiti D, Sarjeant AA, Karlin KD. Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry. Journal of the American Chemical Society. 129: 6720-1. PMID 17474748 DOI: 10.1021/ja0719024  1
2007 Ghiladi RA, Chufan EE, del Río D, Solomon EI, Krebs C, Huynh BH, Huang HW, Moënne-Loccoz P, Kaderli S, Honecker M, Zuberbühler AD, Marzilli L, Cotter RJ, Karlin KD. Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+. Inorganic Chemistry. 46: 3889-902. PMID 17444630 DOI: 10.1021/ic061726k  1
2007 Himes RA, Park GY, Barry AN, Blackburn NJ, Karlin KD. Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry. Journal of the American Chemical Society. 129: 5352-3. PMID 17411054 DOI: 10.1021/ja0708013  1
2007 Chufan EE, Verani CN, Puiu SC, Rentschler E, Schatzschneider U, Incarvito C, Rheingold AL, Karlin KD. Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine. Inorganic Chemistry. 46: 3017-26. PMID 17371009 DOI: 10.1021/ic061686k  1
2007 Maiti D, Fry HC, Woertink JS, Vance MA, Solomon EI, Karlin KD. A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols. Journal of the American Chemical Society. 129: 264-5. PMID 17212392 DOI: 10.1021/ja067411l  1
2007 Lee DH, Murthy NN, Karlin KD. Copper-dioxygen reactivity using dinucleating ligands with activated methylene or ketone function Bulletin of the Chemical Society of Japan. 80: 732-742. DOI: 10.1246/bcsj.80.732  1
2007 Wang J, Puiu SC, Karlin KD. Modeling NO reduction activity of nitric oxide reductase and cytochrome c oxidase Acs National Meeting Book of Abstracts 1
2006 Lee Y, Lee DH, Sarjeant AA, Zakharov LN, Rheingold AL, Karlin KD. Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands. Inorganic Chemistry. 45: 10098-107. PMID 17140215 DOI: 10.1021/ic060730t  1
2006 Hatcher LQ, Lee DH, Vance MA, Milligan AE, Sarangi R, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation. Inorganic Chemistry. 45: 10055-7. PMID 17140210 DOI: 10.1021/ic061813c  1
2006 Li L, Sarjeant AA, Karlin KD. Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions. Inorganic Chemistry. 45: 7160-72. PMID 16933916 DOI: 10.1021/ic060598x  1
2006 Li L, Murthy NN, Telser J, Zakharov LN, Yap GP, Rheingold AL, Karlin KD, Rokita SE. Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions. Inorganic Chemistry. 45: 7144-59. PMID 16933915 DOI: 10.1021/ic0605930  1
2006 Thyagarajan S, Murthy NN, Narducci Sarjeant AA, Karlin KD, Rokita SE. Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species. Journal of the American Chemical Society. 128: 7003-8. PMID 16719480 DOI: 10.1021/ja061014t  1
2006 Hatcher LQ, Vance MA, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects. Inorganic Chemistry. 45: 3004-13. PMID 16562956 DOI: 10.1021/ic052185m  1
2006 Lee Y, Sarjeant AA, Karlin KD. A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands. Chemical Communications (Cambridge, England). 621-3. PMID 16446829 DOI: 10.1039/b513768c  1
2006 Helton ME, Maiti D, Zakharov LN, Rheingold AL, Porco JA, Karlin KD. A mu-eta2:eta2-disulfide dicopper(II) complex from reaction of S8 with a copper(I) precursor: reactivity of the bound disulfur moiety. Angewandte Chemie (International Ed. in English). 45: 1138-41. PMID 16385608 DOI: 10.1002/anie.200503216  1
2006 Smirnov VV, Brinkley DW, Lanci MP, Karlin KD, Roth JP. Probing metal-mediated O2 activation in chemical and biological systems Journal of Molecular Catalysis a: Chemical. 251: 100-107. DOI: 10.1002/jrs.1406  1
2006 Sprakel VSI, Elemans JAAW, Feiters MC, Lucchese B, Karlin KD, Nolte RJM. Synthesis and characterization of PY2- and TPA-appended diphenylglycoluril receptors and their bis-CuI complexes European Journal of Organic Chemistry. 2281-2295. DOI: 10.1002/ejoc.200500865  1
2006 Lee DH, Mondal B, Karlin KD. Nitrogen Monoxide and Nitrous Oxide Binding and Reduction Activation of Small Molecules: Organometallic and Bioinorganic Perspectives. 43-79. DOI: 10.1002/9783527609352.ch2  1
2005 Li L, Narducci Sarjeant AA, Vance MA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Journal of the American Chemical Society. 127: 15360-1. PMID 16262386 DOI: 10.1021/ja054948a  1
2005 Li L, Narducci Sarjeant AA, Vance MA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Journal of the American Chemical Society. 127: 15360-1. PMID 16262386 DOI: 10.1021/ja054948a  1
2005 Sprakel VS, Feiters MC, Meyer-Klaucke W, Klopstra M, Brinksma J, Feringa BL, Karlin KD, Nolte RJ. Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals. Dalton Transactions (Cambridge, England : 2003). 3522-34. PMID 16234934 DOI: 10.1039/b506288h  1
2005 Ito T, Thyagarajan S, Karlin KD, Rokita SE. Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex. Chemical Communications (Cambridge, England). 4812-4. PMID 16193123 DOI: 10.1039/b509690a  1
2005 Kim E, Helton ME, Lu S, Moënne-Loccoz P, Incarvito CD, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes. Inorganic Chemistry. 44: 7014-29. PMID 16180864 DOI: 10.1021/ic050446m  1
2005 Kim E, Helton ME, Lu S, Moënne-Loccoz P, Incarvito CD, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes. Inorganic Chemistry. 44: 7014-29. PMID 16180864 DOI: 10.1021/ic050446m  1
2005 Del Río D, Sarangi R, Chufán EE, Karlin KD, Hedman B, Hodgson KO, Solomon EI. Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4). Journal of the American Chemical Society. 127: 11969-78. PMID 16117536 DOI: 10.1021/ja043374r  1
2005 Fry HC, Cohen AD, Toscano JP, Meyer GJ, Karlin KD. Photoinduced carbon monoxide migration in a synthetic heme-copper complex. Journal of the American Chemical Society. 127: 6225-30. PMID 15853327 DOI: 10.1021/ja043199e  1
2005 Shearer J, Zhang CX, Zakharov LN, Rheingold AL, Karlin KD. Substrate oxidation by copper-dioxygen adducts: mechanistic considerations. Journal of the American Chemical Society. 127: 5469-83. PMID 15826184 DOI: 10.1021/ja045191a  1
2005 Wasser IM, Huang HW, Moënne-Loccoz P, Karlin KD. Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase. Journal of the American Chemical Society. 127: 3310-20. PMID 15755147 DOI: 10.1021/ja0458773  1
2005 Kim E, Kamaraj K, Galliker B, Rubie ND, Moënne-Loccoz P, Kaderli S, Zuberbühler AD, Karlin KD. Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link. Inorganic Chemistry. 44: 1238-47. PMID 15732964 DOI: 10.1021/ic048907b  1
2005 Osako T, Karlin KD, Itoh S. Carbon-halogen bond activation mechanism by copper(I) complexes of (2-pyridyl)alkylamine ligands. Inorganic Chemistry. 44: 410-5. PMID 15651888 DOI: 10.1021/ic048902e  1
2005 Li L, Karlin KD, Rokita SE. Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. Journal of the American Chemical Society. 127: 520-1. PMID 15643865 DOI: 10.1021/ja044209e  1
2005 Li L, Karlin KD, Rokita SE. Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. Journal of the American Chemical Society. 127: 520-1. PMID 15643865 DOI: 10.1021/ja044209e  1
2005 Ghiladi RA, Huang HW, Moënne-Loccoz P, Stasser J, Blackburn NJ, Woods AS, Cotter RJ, Incarvito CD, Rheingold AL, Karlin KD. Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O2(2-))-CuII]+. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 10: 63-77. PMID 15583964 DOI: 10.1007/s00775-004-0609-1  1
2004 Fry HC, Hoertz PG, Wasser IM, Karlin KD, Meyer GJ. Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes. Journal of the American Chemical Society. 126: 16712-3. PMID 15612695 DOI: 10.1021/ja045195f  1
2004 Wasser IM, Fry HC, Hoertz PG, Meyer GJ, Karlin KD. Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex. Inorganic Chemistry. 43: 8272-81. PMID 15606173 DOI: 10.1021/ic0490932  1
2004 Wasser IM, Fry HC, Hoertz PG, Meyer GJ, Karlin KD. Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex. Inorganic Chemistry. 43: 8272-81. PMID 15606173 DOI: 10.1021/ic0490932  1
2004 Kim E, Shearer J, Lu S, Moënne-Loccoz P, Helton ME, Kaderli S, Zuberbühler AD, Karlin KD. Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. Journal of the American Chemical Society. 126: 12716-7. PMID 15469233 DOI: 10.1021/ja045941g  1
2004 Kim E, Shearer J, Lu S, Moënne-Loccoz P, Helton ME, Kaderli S, Zuberbühler AD, Karlin KD. Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. Journal of the American Chemical Society. 126: 12716-7. PMID 15469233 DOI: 10.1021/ja045941g  1
2004 Lucchese B, Humphreys KJ, Lee DH, Incarvito CD, Sommer RD, Rheingold AL, Karlin KD. Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. Inorganic Chemistry. 43: 5987-98. PMID 15360248 DOI: 10.1021/ic0497477  1
2004 Lucchese B, Humphreys KJ, Lee DH, Incarvito CD, Sommer RD, Rheingold AL, Karlin KD. Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. Inorganic Chemistry. 43: 5987-98. PMID 15360248 DOI: 10.1021/ic0497477  1
2004 Hatcher LQ, Karlin KD. Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 669-83. PMID 15311336 DOI: 10.1007/s00775-004-0578-4  1
2004 Hatcher LQ, Karlin KD. Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 669-83. PMID 15311336 DOI: 10.1007/s00775-004-0578-4  1
2004 Liang HC, Henson MJ, Hatcher LQ, Vance MA, Zhang CX, Lahti D, Kaderli S, Sommer RD, Rheingold AL, Zuberbühler AD, Solomon EI, Karlin KD. Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. Inorganic Chemistry. 43: 4115-7. PMID 15236520 DOI: 10.1021/ic0498283  1
2004 Liang HC, Henson MJ, Hatcher LQ, Vance MA, Zhang CX, Lahti D, Kaderli S, Sommer RD, Rheingold AL, Zuberbühler AD, Solomon EI, Karlin KD. Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. Inorganic Chemistry. 43: 4115-7. PMID 15236520 DOI: 10.1021/ic0498283  1
2004 Wick PK, Karlin KD, Suzuki M, Zuberbühler AD. Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+. Micron (Oxford, England : 1993). 35: 137-9. PMID 15036318 DOI: 10.1016/j.micron.2003.10.044  1
2004 Wick PK, Karlin KD, Suzuki M, Zuberbühler AD. Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+. Micron (Oxford, England : 1993). 35: 137-9. PMID 15036318 DOI: 10.1016/j.micron.2003.10.044  1
2004 Kim E, Chufán EE, Kamaraj K, Karlin KD. Synthetic models for heme-copper oxidases. Chemical Reviews. 104: 1077-133. PMID 14871150 DOI: 10.1021/cr0206162  1
2004 Kim E, Chufán EE, Kamaraj K, Karlin KD. Synthetic models for heme-copper oxidases. Chemical Reviews. 104: 1077-133. PMID 14871150 DOI: 10.1021/cr0206162  1
2004 Wasser IM, Martens CF, Verani CN, Rentschler E, Huang HW, Moënne-Loccoz P, Zakharov LN, Rheingold AL, Karlin KD. Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorganic Chemistry. 43: 651-62. PMID 14731027 DOI: 10.1021/ic0348143  1
2004 Wasser IM, Martens CF, Verani CN, Rentschler E, Huang HW, Moënne-Loccoz P, Zakharov LN, Rheingold AL, Karlin KD. Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorganic Chemistry. 43: 651-62. PMID 14731027 DOI: 10.1021/ic0348143  1
2004 Karlin KD, Kim E. Ligand influences in heme-copper O2-chemistry as synthetic models for cytochrome c oxidase Chemistry Letters. 33: 1226-1231. DOI: 10.1246/cl.2004.1226  1
2004 Lee DH, Lucchese B, Karlin KD. Multimetal Oxidases Comprehensive Coordination Chemistry Ii. 8: 437-457. DOI: 10.1016/B0-08-043748-6/08143-3  1
2003 Shearer J, Zhang CX, Hatcher LQ, Karlin KD. Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. Journal of the American Chemical Society. 125: 12670-1. PMID 14558790 DOI: 10.1021/ja0359409  1
2003 Shearer J, Zhang CX, Hatcher LQ, Karlin KD. Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. Journal of the American Chemical Society. 125: 12670-1. PMID 14558790 DOI: 10.1021/ja0359409  1
2003 Fry HC, Scaltrito DV, Karlin KD, Meyer GJ. The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes. Journal of the American Chemical Society. 125: 11866-71. PMID 14505408 DOI: 10.1021/ja034911v  1
2003 Thompson DW, Kretzer RM, Lebeau EL, Scaltrito DV, Ghiladi RA, Lam KC, Rheingold AL, Karlin KD, Meyer GJ. Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex. Inorganic Chemistry. 42: 5211-8. PMID 12924892 DOI: 10.1021/ic026307b  1
2003 Kamaraj K, Kim E, Galliker B, Zakharov LN, Rheingold AL, Zuberbühler AD, Karlin KD. Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity. Journal of the American Chemical Society. 125: 6028-9. PMID 12785812 DOI: 10.1021/ja034263f  1
2003 Kamaraj K, Kim E, Galliker B, Zakharov LN, Rheingold AL, Zuberbühler AD, Karlin KD. Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity. Journal of the American Chemical Society. 125: 6028-9. PMID 12785812 DOI: 10.1021/ja034263f  1
2003 Chen P, Fujisawa K, Helton ME, Karlin KD, Solomon EI. Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues. Journal of the American Chemical Society. 125: 6394-408. PMID 12785779 DOI: 10.1021/ja0214678  1
2003 Kretzer RM, Ghiladi RA, Lebeau EL, Liang HC, Karlin KD. Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species. Inorganic Chemistry. 42: 3016-25. PMID 12716196 DOI: 10.1021/ic020521i  1
2003 Henson MJ, Vance MA, Zhang CX, Liang HC, Karlin KD, Solomon EI. Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes. Journal of the American Chemical Society. 125: 5186-92. PMID 12708870 DOI: 10.1021/ja0276366  1
2003 Kim E, Helton ME, Wasser IM, Karlin KD, Lu S, Huang HW, Moenne-Loccoz P, Incarvito CD, Rheingold AL, Honecker M, Kaderli S, Zuberbuhler AD. Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models. Proceedings of the National Academy of Sciences of the United States of America. 100: 3623-8. PMID 12655050 DOI: 10.1073/pnas.0737180100  1
2003 Kim E, Helton ME, Wasser IM, Karlin KD, Lu S, Huang HW, Moenne-Loccoz P, Incarvito CD, Rheingold AL, Honecker M, Kaderli S, Zuberbuhler AD. Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models. Proceedings of the National Academy of Sciences of the United States of America. 100: 3623-8. PMID 12655050 DOI: 10.1073/pnas.0737180100  1
2003 Zhang CX, Kaderli S, Costas M, Kim EI, Neuhold YM, Karlin KD, Zuberbühler AD. Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. Inorganic Chemistry. 42: 1807-24. PMID 12639113 DOI: 10.1021/ic0205684  1
2003 Zhang CX, Kaderli S, Costas M, Kim EI, Neuhold YM, Karlin KD, Zuberbühler AD. Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. Inorganic Chemistry. 42: 1807-24. PMID 12639113 DOI: 10.1021/ic0205684  1
2003 Helton ME, Chen P, Paul PP, Tyeklár Z, Sommer RD, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry. Journal of the American Chemical Society. 125: 1160-1. PMID 12553805 DOI: 10.1021/ja027574j  1
2003 Zhang CX, Liang HC, Kim EI, Shearer J, Helton ME, Kim E, Kaderli S, Incarvito CD, Zuberbühler AD, Rheingold AL, Karlin KD. Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics. Journal of the American Chemical Society. 125: 634-5. PMID 12526654 DOI: 10.1021/ja028779v  1
2003 Shin H, Lee DH, Kang C, Karlin KD. Electrocatalytic four-electron reductions of O2 to H 2O with cytochrome c oxidase model compounds Electrochimica Acta. 48: 4077-4082. DOI: 10.1016/S0013-4686(03)00565-6  1
2002 Humphreys KJ, Johnson AE, Karlin KD, Rokita SE. Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 7: 835-42. PMID 12203020 DOI: 10.1007/s00775-002-0369-8  1
2002 Humphreys KJ, Karlin KD, Rokita SE. Targeted strand scission of DNA substrates by a tricopper(II) coordination complex. Journal of the American Chemical Society. 124: 8055-66. PMID 12095349 DOI: 10.1021/ja012539i  1
2002 Humphreys KJ, Karlin KD, Rokita SE. Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties. Journal of the American Chemical Society. 124: 6009-19. PMID 12022834 DOI: 10.1021/ja020039z  1
2002 Ghiladi RA, Karlin KD. Low-temperature UV-visible and NMR spectroscopic investigations of O(2) binding to ((6)L)Fe(II), a ferrous heme bearing covalently tethered axial pyridine ligands. Inorganic Chemistry. 41: 2400-7. PMID 11978105 DOI: 10.1021/ic0103547  1
2002 Liang HC, Zhang CX, Henson MJ, Sommer RD, Hatwell KR, Kaderli S, Zuberbühler AD, Rheingold AL, Solomon EI, Karlin KD. Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes. Journal of the American Chemical Society. 124: 4170-1. PMID 11960420 DOI: 10.1021/ja0125265  1
2002 Liang HC, Kim E, Incarvito CD, Rheingold AL, Karlin KD. A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+). Inorganic Chemistry. 41: 2209-12. PMID 11952376 DOI: 10.1021/ic010816g  1
2002 Wasser IM, de Vries S, Moënne-Loccoz P, Schröder I, Karlin KD. Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry. Chemical Reviews. 102: 1201-34. PMID 11942794 DOI: 10.1021/cr0006627  1
2001 Itoh S, Bandoh H, Nakagawa M, Nagatomo S, Kitagawa T, Karlin KD, Fukuzumi S. Formation, characterization, and reactivity of bis(mu-oxo)dinickel(III) complexes supported by a series of bis[2-(2-pyridyl)ethyl]amine ligands. Journal of the American Chemical Society. 123: 11168-78. PMID 11697960 DOI: 10.1021/ja0104094  1
2001 Ghiladi RA, Kretzer RM, Guzei I, Rheingold AL, Neuhold YM, Hatwell KR, Zuberbühler AD, Karlin KD. (F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation. Inorganic Chemistry. 40: 5754-67. PMID 11681882 DOI: 10.1021/ic0105866  1
2001 Scaltrito DV, Fry HC, Showalter BM, Thompson DW, Liang HC, Zhang CX, Kretzer RM, Kim E, Toscano JP, Karlin KD, Meyer GJ. Reversible carbon monoxide photodissociation from Cu(I) coordination compounds. Inorganic Chemistry. 40: 4514-5. PMID 11511192 DOI: 10.1021/ic010684r  1
2001 Rhames FC, Murthy NN, Karlin KD, Blackburn NJ. Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc). Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 6: 567-77. PMID 11472020 DOI: 10.1007/s007750100233  1
2001 Ghiladi RA, Hatwell KR, Karlin KD, Huang HW, Moënne-Loccoz P, Krebs C, Huynh BH, Marzilli LA, Cotter RJ, Kaderli S, Zuberbühler AD. Dioxygen reactivity of mononuclear heme and copper components yielding a high-spin heme-peroxo-cu complex. Journal of the American Chemical Society. 123: 6183-4. PMID 11414855 DOI: 10.1021/ja010602y  1
2001 Humphreys KJ, Karlin KD, Rokita SE. Recognition and strand scission at junctions between single- and double-stranded DNA by a trinuclear copper complex. Journal of the American Chemical Society. 123: 5588-9. PMID 11389647 DOI: 10.1021/ja010403e  1
2001 Schatz M, Becker M, Thaler F, Hampel F, Schindler S, Jacobson RR, Tyeklár Z, Murthy NN, Ghosh P, Chen Q, Zubieta J, Karlin KD. Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands. Inorganic Chemistry. 40: 2312-22. PMID 11327908 DOI: 10.1021/ic000924n  1
2001 Murthy NN, Mahroof-Tahir M, Karlin KD. Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities. Inorganic Chemistry. 40: 628-35. PMID 11225103 DOI: 10.1021/ic000792y  1
2001 Barton JK, Karlin KD. Bio-inorganic chemistry new advances, new directions and new investigators Current Opinion in Chemical Biology. 5: 165-167. DOI: 10.1016/S1367-5931(00)00186-1  1
2001 Zhang CX, Liang HC, Kim EI, Gan QF, Tyeklár Z, Lam KC, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex Chemical Communications. 631-632.  1
2000 Liang HC, Karlin KD, Dyson R, Kaderli S, Jung B, Zuberbühler AD. Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts. Inorganic Chemistry. 39: 5884-94. PMID 11188519 DOI: 10.1021/ic0007916  1
2000 Moënne-Loccoz P, Richter OMH, Huang HW, Wasser IM, Ghiladi RA, Karlin KD, De Vries S. Nitric oxide reductase from Paracoccus denitrificans contains an oxo-bridged heme/non-heme diiron center [25] Journal of the American Chemical Society. 122: 9344-9345. DOI: 10.1021/ja0016295  1
2000 Karlin KD. Inorganica Chimica Acta: Preface Inorganica Chimica Acta. 297: xvii-xx. DOI: 10.1016/S0020-1693(99)00414-4  1
2000 Ju TD, Woods AS, Cotter RJ, Moënne-Loccoz P, Karlin KD. Dioxygen and nitric oxide reactivity of a reduced heme/non-heme diiron(II) complex [(5L)Fe(II)···Fe(II)-Cl]+. Using a tethered tetraarylporphyrin for the development of an active site reactivity model for bacterial nitric oxide reductase Inorganica Chimica Acta. 297: 362-372. DOI: 10.1016/S0020-1693(99)00404-1  1
1999 Feiters MC, Gebbink RJ, Solé VA, Nolting HF, Karlin KD, Nolte RJ. X-ray Absorption Spectroscopic Studies of the Copper(I) Complexes of Crown Ether Appended Bis{(2-pyridyl)ethyl}amines and Their Dioxygen Adducts. Inorganic Chemistry. 38: 6171-6180. PMID 11671329  1
1999 Kopf MA, Karlin KD. Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate. Inorganic Chemistry. 38: 4922-4923. PMID 11671230  1
1999 Becker M, Schindler S, Karlin KD, Kaden TA, Kaderli S, Palanché T, Zuberbühler AD. Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen. Inorganic Chemistry. 38: 1989-1995. PMID 11670976  1
1999 Liang HC, Dahan M, Karlin KD. Dioxygen-activating bio-inorganic model complexes. Current Opinion in Chemical Biology. 3: 168-75. PMID 10226046 DOI: 10.1016/S1367-5931(99)80029-5  1
1999 Ghiladi RA, Ju TD, Lee DH, Moënne-Loccoz P, Kaderli S, Neuhold YM, Zuberbühler AD, Woods AS, Cotter RJ, Karlin KD. Formation and characterization of a high-spin heme-copper dioxygen (peroxo) complex [8] Journal of the American Chemical Society. 121: 9885-9886. DOI: 10.1021/ja992296i  1
1999 Pidcock E, DeBeer S, Obias HV, Hedman B, Hodgson KO, Karlin KD, Solomon EI. A study of solid [{Cu(MePY2)}2O2]2+ using resonance Raman and X- ray absorption spectroscopies: An intermediate Cu2O2 core structure or a solid solution? Journal of the American Chemical Society. 121: 1870-1878. DOI: 10.1021/ja983444s  1
1999 Pidcock E, Obias HV, Abe M, Liang HC, Karlin KD, Solomon EL. Spectroscopic and theoretical studies of oxygenated dicopper(I) complexes containing hydrocarbon-linked Bis[2-(2-pyridyl)ethyl]amine units: Investigation of a butterfly [Cu2(μ-η2:η2)(O2)]2+ core Journal of the American Chemical Society. 121: 1299-1308. DOI: 10.1021/ja983310e  1
1999 Klein Gebbink RJM, Martens CF, Kenis PJA, Jansen RJ, Nolting HF, Armando Solé V, Feiters MC, Karlin KD, Nolte RJM. Synthesis, Structure, and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands Inorganic Chemistry. 38: 5755-5768.  1
1999 Kopf MA, Neuhold YM, Zuberbühler AD, Karlin KD. Oxo- and hydroxo-bridged heme-copper assemblies formed from acid-base or metal-dioxygen chemistry Inorganic Chemistry. 38: 3093-3102.  1
1999 Corsi DM, Murthy NN, Young VG, Karlin KD. Synthesis, structure, and solution NMR studies of cyanide-copper(II) and cyanide-bridged iron(III)-copper(II) complexes Inorganic Chemistry. 38: 848-858.  1
1999 Ju TD, Ghiladi RA, Lee DH, Van Strijdonck GPF, Woods AS, Cotter RJ, Young VG, Karlin KD. Dioxygen reactivity of fully reduced [LFeII⋯CuI]+ complexes utilizing tethered tetraarylporphyrinates: Active site models for heme-copper oxidases Inorganic Chemistry. 38: 2244-2245.  1
1999 Karlin KD, Gan QF, Tyeklár Z. Dioxygen-copper reactivity at trinuclear centers: Formation of hexanuclear and mixed-valent adducts Chemical Communications. 2295-2296.  1
1998 Root DE, Mahroof-Tahir M, Karlin KD, Solomon EI. Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu(2)((UN-O-)(OOH)](2+). Inorganic Chemistry. 37: 4838-4848. PMID 11670647  1
1998 Karlin S, Zhu ZY, Karlin KD. Extended metal environments of cytochrome c oxidase structures. Biochemistry. 37: 17726-34. PMID 9922138 DOI: 10.1021/bi981390t  1
1998 Obias HV, Lin Y, Murthy NN, Pidcock E, Solomon EI, Ralle M, Blackburn NJ, Neuhold YM, Zuberbuhler AD, Karlin KD. Peroxo-, oxo-, and hydroxo-bridged dicopper complexes: Observation of exogenous hydrocarbon substrate oxidation [3] Journal of the American Chemical Society. 120: 12960-12961. DOI: 10.1021/ja981878h  1
1998 Obias HV, Van Strijdonck GPF, Lee DH, Ralle M, Blackburn NJ, Karlin KD. Heterobinucleating ligand-induced structural and chemical variations in [(L)Fe(III)-O-Cu(II)]+ μ-oxo complexes [9] Journal of the American Chemical Society. 120: 9696-9697. DOI: 10.1021/ja9810989  1
1998 Pidcock E, Obias HV, Zhang CX, Karlin KD, Solomon EI. Investigation of the reactive oxygen intermediate in an arene hydroxylation reaction performed by xylyl-bridged binuclear copper complexes Journal of the American Chemical Society. 120: 7841-7847. DOI: 10.1021/ja980687b  1
1998 Karlin KD, Zhu ZY, Karlin S. The environment of multinuclear copper metal linkages in protein structures Journal of Biological Inorganic Chemistry. 3: 172-187. DOI: 10.1007/s007750050218  1
1998 Root DE, Mahroof-Tahir M, Karlin KD, Solomon EI. Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu2(UN-0-)(OOH)]2+ Inorganic Chemistry. 37: 4838-4848.  1
1998 Karlin KD, Lee DH, Obias HV, Humphreys KJ. Copper-dioxygen complexes: Functional models for proteins Pure and Applied Chemistry. 70: 855-862.  1
1997 Lee DH, Murthy NN, Karlin KD. Binuclear Copper Complexes Based on the 6,6'-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine Ligand. Inorganic Chemistry. 36: 5785-5792. PMID 11670200  1
1997 Frey ST, Murthy NN, Weintraub ST, Thompson LK, Karlin KD. Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex. Inorganic Chemistry. 36: 956-957. PMID 11669653  0.72
1997 Karlin S, Zhu ZY, Karlin KD. The extended environment of mononuclear metal centers in protein structures. Proceedings of the National Academy of Sciences of the United States of America. 94: 14225-30. PMID 9405594 DOI: 10.1073/pnas.94.26.14225  1
1997 Nanthakumar A, Fox S, Murthy NN, Karlin KD. Inferences from the 1H-NMR spectroscopic study of an antiferromagnetically coupled heterobinuclear Fe(III)-(X)-Cu(II) S = 2 spin system (X = O2-, OH-) Journal of the American Chemical Society. 119: 3898-3906. DOI: 10.1021/ja962404q  1
1997 Karlin KD, Lee DH, Kaderli S, Zuberbühler AD. Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent Chemical Communications. 475-476.  1
1997 Klein Gebbink RJM, Martens CF, Feiters MC, Karlin KD, Nolte RJM. Novel molecular receptors capable of forming Cu2-O2 complexes. Effect of preorganization on O2 binding Chemical Communications. 389-390.  1
1997 Lee DH, Murthy NN, Lin Y, Sarwar Nasir N, Karlin KD. Copper ion complexes with derivatized chelating pterin ligands Inorganic Chemistry. 36: 6328-6334.  1
1997 Comba P, Hilfenhaus P, Karlin KD. Modeling of End-On (μ-Peroxo)dicopper(II) Complexes Inorganic Chemistry. 36: 2309-2313.  1
1997 Lee DH, Murthy NN, Karlin KD. Binuclear Copper Complexes Based on the 6,6′-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2′-bipyridine Ligand Inorganic Chemistry. 36: 5785-5792.  1
1996 Lee DH, Murthy NN, Karlin KD. Copper(I)/Dioxygen Reactivity with Dinuclear Compounds: Catalytic Oxygenation and Oxo-Transfer to a Ketone. Inorganic Chemistry. 35: 804-805. PMID 11666248  1
1994 Karlin KD, Tyeklár Z. Functional biomimics for copper proteins involved in reversible O2-binding, substrate oxidation/oxygenation and nitrite reduction. Advances in Inorganic Biochemistry. 9: 123-72. PMID 8140947  0.72
Show low-probability matches.