☰

Kenneth D. Karlin, Ph.D. - Publications

Affiliations: 
1978-1989 Chemistry State University of New York, Albany, Albany, NY, United States 
 1990- Chemistry Johns Hopkins University, Baltimore, MD 
Area:
Inorganic/Bioinorganic Chemistry
Website:
http://www.jhu.edu/~chem/karlin/
Tree Info Similar researchers PubMed Report error

402/422 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Panda S, Phan H, Karlin KD. Heme-copper and Heme O-derived synthetic (bioinorganic) chemistry toward an understanding of cytochrome c oxidase dioxygen chemistry. Journal of Inorganic Biochemistry. 249: 112367. PMID 37742491 DOI: 10.1016/j.jinorgbio.2023.112367  0.457
2023 Kim B, Karlin KD. Ligand-Copper(I) Primary O-Adducts: Design, Characterization, and Biological Significance of Cupric-Superoxides. Accounts of Chemical Research. PMID 37527056 DOI: 10.1021/acs.accounts.3c00297  0.538
2023 Kim B, Brueggemeyer MT, Transue WJ, Park Y, Cho J, Siegler MA, Solomon EI, Karlin KD. Fenton-like Chemistry by a Copper(I) Complex and HO Relevant to Enzyme Peroxygenase C-H Hydroxylation. Journal of the American Chemical Society. PMID 37195014 DOI: 10.1021/jacs.3c02273  0.512
2023 Bhadra M, Albert T, Franke A, Josef V, Ivanović-Burmazović I, Swart M, Moënne-Loccoz P, Karlin KD. Reductive Coupling of Nitric Oxide by Cu(I): Stepwise Formation of Mono- and Dinitrosyl Species to a Cupric Hyponitrite Intermediate. Journal of the American Chemical Society. 145: 2230-2242. PMID 36652374 DOI: 10.1021/jacs.2c09874  0.855
2022 Aldous L, Comba P, DeBeer S, Dey A, Draksharapu A, Duboc C, Itoh S, Karlin K, Kundu S, López Domene R, Maréchal JD, Mazumdar S, Mukherjee R, Parker D, Pordea A, et al. Small molecule activation and synthetic analogues: general discussion. Faraday Discussions. PMID 35531924 DOI: 10.1039/d2fd90012b  0.336
2022 Ash P, Chakravarty AR, Comba P, Dey A, Goswami D, Jäger CM, Karlin K, Kundu S, La Gatta S, López Domene R, Maréchal JD, Mazumdar S, Mugesh G, Pantazis D, Pordea A, et al. Natural and artificial enzymes and medicinal aspects: general discussion. Faraday Discussions. PMID 35510879 DOI: 10.1039/d2fd90014a  0.33
2022 Anilkumar A, Ash P, Chakravarty AR, Comba P, DeBeer S, Dey A, Draksharapu A, Goswami D, Itoh S, Karlin K, Lakshmi KV, Mazumdar S, Pantazis D, Parker D, Que L, et al. Electron transfer, spectroscopy and theory: general discussion. Faraday Discussions. PMID 35510729 DOI: 10.1039/d2fd90013k  0.344
2022 Dey A, Goswami D, Karlin K, Solomon EI, P Stack TD. Introductory lecture: general discussion. Faraday Discussions. PMID 35510421 DOI: 10.1039/d2fd90011d  0.328
2022 Davydov R, Herzog AE, Jodts RJ, Karlin KD, Hoffman BM. End-On Copper(I) Superoxo and Cu(II) Peroxo and Hydroperoxo Complexes Generated by Cryoreduction/Annealing and Characterized by EPR/ENDOR Spectroscopy. Journal of the American Chemical Society. 144: 377-389. PMID 34981938 DOI: 10.1021/jacs.1c10252  0.516
2021 Bhunia S, Rana A, Hematian S, Karlin KD, Dey A. Proton Relay in Iron Porphyrins for Hydrogen Evolution Reaction. Inorganic Chemistry. PMID 34097396 DOI: 10.1021/acs.inorgchem.1c01079  0.789
2021 Bhadra M, Transue WJ, Lim H, Cowley RE, Lee JYC, Siegler MA, Josephs P, Henkel G, Lerch M, Schindler S, Neuba A, Hodgson KO, Hedman B, Solomon EI, Karlin KD. A Thioether-Ligated Cupric Superoxide Model with Hydrogen Atom Abstraction Reactivity. Journal of the American Chemical Society. PMID 33684290 DOI: 10.1021/jacs.1c00260  0.86
2020 Karlin KD, Kim H, Rogler PJ, Sharma SK, Schaefer AW, Solomon EI. Ferric Heme Superoxide Reductive Transformations to Ferric Heme (Hydro)Peroxide Species: Spectroscopic Characterization and Thermodynamic Implications for H-atom Transfer (HAT). Angewandte Chemie (International Ed. in English). PMID 33348450 DOI: 10.1002/anie.202013791  0.668
2020 Lim H, Baker ML, Cowley RE, Kim S, Bhadra M, Siegler MA, Kroll T, Sokaras D, Weng TC, Biswas DR, Dooley DM, Karlin KD, Hedman B, Hodgson KO, Solomon EI. Kβ X-ray Emission Spectroscopy as a Probe of Cu(I) Sites: Application to the Cu(I) Site in Preprocessed Galactose Oxidase. Inorganic Chemistry. PMID 33136386 DOI: 10.1021/acs.inorgchem.0c02495  0.843
2020 Kim H, Rogler PJ, Sharma SK, Schaefer AW, Solomon EI, Karlin KD. Heme-FeIII Superoxide, Peroxide and Hydroperoxide Thermodynamic Relationships: FeIII-O2•- Complex H-Atom Abstraction Reactivity. Journal of the American Chemical Society. PMID 31913628 DOI: 10.1021/Jacs.9B12571  0.722
2019 Kim H, Sharma SK, Schaefer AW, Solomon EI, Karlin KD. Heme-Cu Binucleating Ligand Supports Heme/O and Fe-Cu/O Reactivity Providing High- and Low-Spin Fe-Peroxo-Cu Complexes. Inorganic Chemistry. PMID 31657921 DOI: 10.1021/Acs.Inorgchem.9B02521  0.788
2019 Wijeratne GB, Bhadra M, Siegler MA, Karlin KD. Copper(I) Complex Mediated Nitric Oxide Reductive Coupling: Ligand Hydrogen Bonding Derived Proton Transfer Promotes N2O(g) Release. Journal of the American Chemical Society. PMID 31621325 DOI: 10.1021/Jacs.9B07286  0.805
2019 Diaz DE, Bhadra M, Karlin KD. Dimethylanilinic -Oxides and Their Oxygen Surrogacy Role in the Formation of a Putative High-Valent Copper-Oxygen Species. Inorganic Chemistry. PMID 31580063 DOI: 10.1021/Acs.Inorgchem.9B02066  0.855
2019 Diaz DE, Quist DA, Herzog AE, Schaefer AW, Kipouros I, Bhadra M, Solomon EI, Karlin KD. Impact of Intramolecular Hydrogen Bonding on the Reactivity of Cupric Superoxide Complexes with O-H and C-H Substrates. Angewandte Chemie (International Ed. in English). PMID 31469942 DOI: 10.1002/Anie.201908471  0.841
2019 Ehudin MA, Quist DA, Karlin KD. Enhanced Rates of C-H Bond Cleavage by a Hydrogen Bonded Synthetic Heme High-Valent Iron(IV) Oxo Complex. Journal of the American Chemical Society. PMID 31318198 DOI: 10.1021/jacs.9b01253  0.346
2019 Quist DA, Ehudin MA, Schaefer AW, Schneider GL, Solomon EI, Karlin KD. Ligand Identity Induced Generation of Enhanced Oxidative HAT Reactivity for a CuII2(O2•¬-) Complex Driven by Formation of a CuII2(-OOH) Compound with a Strong O-H Bond. Journal of the American Chemical Society. PMID 31299154 DOI: 10.1021/Jacs.9B05277  0.526
2019 Moenne-Loccoz P, Karlin KD, Liu JJ, Siegler MA. Direct Resonance Raman Characterization of a Peroxynitrito Copper Complex Generated from O2 and NO and Mechanistic Insights into Metal Mediated Peroxynitrite Decomposition. Angewandte Chemie (International Ed. in English). PMID 31158311 DOI: 10.1002/Anie.201904672  0.571
2019 Ehudin MA, Senft L, Franke A, Ivanović-Burmazović I, Karlin KD. Formation and Reactivity of New Isoporphyrins: Implications for Understanding the Tyr-His Cross-Link Cofactor Biogenesis in Cytochrome c Oxidase. Journal of the American Chemical Society. PMID 31150209 DOI: 10.1021/jacs.9b01791  0.32
2019 Ehudin MA, Schaefer AW, Adam SM, Quist DA, Diaz DE, Tang JA, Solomon EI, Karlin KD. Influence of intramolecular secondary sphere hydrogen-bonding interactions on cytochrome oxidase inspired low-spin heme-peroxo-copper complexes. Chemical Science. 10: 2893-2905. PMID 30996867 DOI: 10.1039/C8Sc05165H  0.543
2019 Quist DA, Ehudin MA, Karlin KD. Unprecedented direct cupric-superoxo conversion to a bis--oxo dicopper(III) complex and resulting oxidative activity. Inorganica Chimica Acta. 485: 155-161. PMID 30988551 DOI: 10.1016/j.ica.2018.10.015  0.554
2019 Ehudin MA, Gee LB, Sabuncu S, Braun A, Moënne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD. Tuning the Geometric and Electronic Structure of Synthetic High-Valent Iron(IV)-Oxo Models in the Presence of a Lewis Acid and Various Axial Ligands. Journal of the American Chemical Society. PMID 30860832 DOI: 10.1021/Jacs.9B00795  0.466
2019 Schaefer AW, Ehudin MA, Quist DA, Tang JA, Karlin KD, Solomon EI. Spin Interconversion of Heme-Peroxo-Copper Complexes Facilitated by Intramolecular Hydrogen-Bonding Interactions. Journal of the American Chemical Society. PMID 30836005 DOI: 10.1021/Jacs.9B00118  0.383
2018 Adam SM, Wijeratne GB, Rogler PJ, Diaz DE, Quist DA, Liu JJ, Karlin KD. Synthetic Fe/Cu Complexes: Toward Understanding Heme-Copper Oxidase Structure and Function. Chemical Reviews. PMID 30372042 DOI: 10.1021/Acs.Chemrev.8B00074  0.814
2018 Hong S, Yan JJ, Karmalkar DG, Sutherlin KD, Kim J, Lee YM, Goo Y, Mascharak PK, Hedman B, Hodgson KO, Karlin KD, Solomon EI, Nam W. A mononuclear nonheme {FeNO} complex: synthesis and structural and spectroscopic characterization. Chemical Science. 9: 6952-6960. PMID 30210769 DOI: 10.1039/C8Sc01962B  0.679
2018 Bhadra M, Lee JYC, Cowley RE, Kim S, Siegler MA, Solomon EI, Karlin KD. Intramolecular Hydrogen Bonding Enhances Stability and Reactivity of Mononuclear Cupric Superoxide Complexes. Journal of the American Chemical Society. PMID 29957998 DOI: 10.1021/Jacs.8B04671  0.823
2017 Sharma SK, Schaefer AW, Lim H, Matsumura H, Moënne-Loccoz P, Hedman B, Hodgson KO, Solomon EI, Karlin KD. A Six-Coordinate Peroxynitrite Low-Spin Iron(III) Porphyrinate Complex - The Product of the Reaction of Nitrogen Monoxide (•NO(g)) with a Ferric-Superoxide Species. Journal of the American Chemical Society. PMID 29091732 DOI: 10.1021/Jacs.7B08468  0.744
2017 López I, Cao R, Quist DA, Karlin KD, Le Poul N. Direct Determination of Electron-Transfer Properties of Dicopper-Bound Reduced Dioxygen Species by a Cryo-Spectroelectrochemical Approach. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29073346 DOI: 10.1002/Chem.201705066  0.653
2017 Wijeratne GB, Hematian S, Siegler MA, Karlin KD. Copper(I) / NO(g) Reductive Coupling Producing a trans-Hyponitrite Bridged Dicopper(II) Complex - Redox Reversal Giving Copper(I) / NO(g) Disproportionation. Journal of the American Chemical Society. PMID 28820592 DOI: 10.1021/Jacs.7B07808  0.839
2017 Schaefer AW, Kieber-Emmons MT, Adam SM, Karlin KD, Solomon EI. Phenol-Induced O-O Bond Cleavage in a Low-Spin Heme-Peroxo-Copper Complex: Implications for O2 Reduction in Heme-Copper Oxidases. Journal of the American Chemical Society. PMID 28521498 DOI: 10.1021/Jacs.7B03292  0.492
2017 Garcia-Bosch I, Cowley RE, Díaz DE, Peterson RL, Solomon EI, Karlin KD. Substrate and Lewis Acid Coordination Promote O-O Bond Cleavage of an Unreactive L2Cu(II)2(O2(2-)) Species to Form L2Cu(III)2(O)2 Cores with Enhanced Oxidative Reactivity. Journal of the American Chemical Society. PMID 28195739 DOI: 10.1021/Jacs.6B12990  0.829
2016 Adam SM, Garcia-Bosch I, Schaefer AW, Sharma SK, Siegler MA, Solomon EI, Karlin KD. Critical Aspects of Heme-Peroxo-Cu Complex Structure and Nature of Proton Source Dictate Metal-Operoxo Breakage versus Reductive O-O Cleavage Chemistry. Journal of the American Chemical Society. PMID 28029788 DOI: 10.1021/Jacs.6B11322  0.859
2016 Cao R, Elrod LT, Lehane RL, Kim E, Karlin KD. A Peroxynitrite Dicopper Complex: Formation via Cu-NO and Cu-O2 Intermediates and Reactivity via O-O Cleavage Chemistry. Journal of the American Chemical Society. 138: 16148-16158. PMID 27960334 DOI: 10.1021/Jacs.6B10689  0.866
2016 Quist DA, Diaz DE, Liu JJ, Karlin KD. Activation of dioxygen by copper metalloproteins and insights from model complexes. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27921179 DOI: 10.1007/S00775-016-1415-2  0.469
2016 Liu JJ, Diaz DE, Quist DA, Karlin KD. Copper(I)-Dioxygen Adducts and Copper Enzyme Mechanisms. Israel Journal of Chemistry. 56: 9-10. PMID 27909346 DOI: 10.1002/ijch.201600025  0.427
2016 Hong S, Kumar P, Cho KB, Lee YM, Karlin KD, Nam W. Mechanistic Insight into the Nitric Oxide Dioxygenation Reaction of Nonheme Iron(III)-Superoxo and Manganese(IV)-Peroxo Complexes. Angewandte Chemie (International Ed. in English). PMID 27593390 DOI: 10.1002/Anie.201605705  0.721
2016 Yamada M, Karlin KD, Fukuzumi S. One-Step Selective Hydroxylation of Benzene to Phenol with Hydrogen Peroxide Catalysed by Copper Complexes Incorporated into Mesoporous Silica-Alumina. Chemical Science (Royal Society of Chemistry : 2010). 7: 2856-2863. PMID 27453774 DOI: 10.1039/C5Sc04312C  0.431
2016 Sharma SK, Kim H, Rogler PJ, A Siegler M, Karlin KD. Isocyanide or nitrosyl complexation to hemes with varying tethered axial base ligand donors: synthesis and characterization. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. PMID 27350154 DOI: 10.1007/S00775-016-1369-4  0.682
2016 Cao R, Saracini C, Ginsbach JW, Kieber-Emmons MT, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Peroxo and Superoxo Moieties Bound to Copper Ion: Electron-Transfer Equilibrium with a Small Reorganization Energy. Journal of the American Chemical Society. PMID 27228314 DOI: 10.1021/Jacs.6B02404  0.648
2016 Kumar P, Lee YM, Hu L, Chen JW, Park YJ, Yao J, Chen H, Karlin KD, Nam W. Factors That Control the Reactivity of Cobalt(III)-Nitrosyl Complexes in Nitric Oxide Transfer and Dioxygenation Reactions: A Combined Experimental and Theoretical Investigation. Journal of the American Chemical Society. PMID 27221953 DOI: 10.1021/Jacs.6B04040  0.746
2016 Garcia-Bosch I, Cowley RE, Díaz DE, Siegler MA, Nam W, Solomon EI, Karlin KD. Dioxygen Activation by a Macrocyclic Copper Complex Leads to a Cu2 O2 Core with Unexpected Structure and Reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26919169 DOI: 10.1002/Chem.201600551  0.846
2015 Saracini C, Ohkubo K, Suenobu T, Meyer GJ, Karlin KD, Fukuzumi S. Laser-Induced Dynamics of Peroxodicopper(II) Complexes Vary with the Ligand Architecture. One-Photon Two-Electron O2 Ejection and Formation of Mixed-Valent Cu(I)Cu(II)-Superoxide Intermediates. Journal of the American Chemical Society. PMID 26651492 DOI: 10.1021/Jacs.5B10177  0.597
2015 Karlin KD, Lippard SJ, Valentine JS, Burrows CJ. Solving 21st Century Problems in Biological Inorganic Chemistry Using Synthetic Models. Accounts of Chemical Research. 48: 2659-60. PMID 26481328 DOI: 10.1021/Acs.Accounts.5B00447  0.467
2015 Chatterjee S, Sengupta K, Hematian S, Karlin KD, Dey A. Electrocatalytic O2-Reduction by Synthetic Cytochrome c Oxidase Mimics: Identification of a "Bridging Peroxo" Intermediate Involved in Facile 4e(-)/4H(+) O2-Reduction. Journal of the American Chemical Society. PMID 26419806 DOI: 10.1021/Jacs.5B06513  0.863
2015 Hematian S, Garcia-Bosch I, Karlin KD. Synthetic Heme/Copper Assemblies: Toward an Understanding of Cytochrome c Oxidase Interactions with Dioxygen and Nitrogen Oxides. Accounts of Chemical Research. 48: 2462-74. PMID 26244814 DOI: 10.1021/Acs.Accounts.5B00265  0.877
2015 Sharma SK, Rogler PJ, Karlin KD. Reactions of a heme-superoxo complex toward a cuprous chelate and •NO(g): CcO and NOD chemistry. Journal of Porphyrins and Phthalocyanines. 19: 352-360. PMID 26056423 DOI: 10.1142/S108842461550025X  0.758
2015 Hematian S, Kenkel I, Shubina TE, Dürr M, Liu JJ, Siegler MA, Ivanovic-Burmazovic I, Karlin KD. Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs. Journal of the American Chemical Society. 137: 6602-15. PMID 25974136 DOI: 10.1021/Jacs.5B02174  0.851
2015 Hematian S, Kenkel I, Shubina TE, Dürr M, Liu JJ, Siegler MA, Ivanovic-Burmazovic I, Karlin KD. Nitrogen Oxide Atom-Transfer Redox Chemistry; Mechanism of NO(g) to Nitrite Conversion Utilizing μ-oxo Heme-Fe(III)-O-Cu(II)(L) Constructs. Journal of the American Chemical Society. 137: 6602-15. PMID 25974136 DOI: 10.1021/Jacs.5B02174  0.851
2015 Kumar P, Lee YM, Park YJ, Siegler MA, Karlin KD, Nam W. Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. Journal of the American Chemical Society. 137: 4284-7. PMID 25793706 DOI: 10.1021/Ja513234B  0.751
2015 Kumar P, Lee YM, Park YJ, Siegler MA, Karlin KD, Nam W. Reactions of Co(III)-nitrosyl complexes with superoxide and their mechanistic insights. Journal of the American Chemical Society. 137: 4284-7. PMID 25793706 DOI: 10.1021/Ja513234B  0.751
2015 Lee JY, Karlin KD. Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation. Current Opinion in Chemical Biology. 25: 184-93. PMID 25756327 DOI: 10.1016/j.cbpa.2015.02.014  0.317
2015 Lee JY, Karlin KD. Elaboration of copper-oxygen mediated C-H activation chemistry in consideration of future fuel and feedstock generation. Current Opinion in Chemical Biology. 25: 184-93. PMID 25756327 DOI: 10.1016/j.cbpa.2015.02.014  0.317
2015 Kim S, Ginsbach JW, Lee JY, Peterson RL, Liu JJ, Siegler MA, Sarjeant AA, Solomon EI, Karlin KD. Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. Journal of the American Chemical Society. 137: 2867-74. PMID 25706825 DOI: 10.1021/Ja508371Q  0.718
2015 Kim S, Ginsbach JW, Lee JY, Peterson RL, Liu JJ, Siegler MA, Sarjeant AA, Solomon EI, Karlin KD. Amine oxidative N-dealkylation via cupric hydroperoxide Cu-OOH homolytic cleavage followed by site-specific fenton chemistry. Journal of the American Chemical Society. 137: 2867-74. PMID 25706825 DOI: 10.1021/Ja508371Q  0.718
2015 Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society. 137: 2796-9. PMID 25697226 DOI: 10.1021/Ja511504N  0.521
2015 Kim S, Lee JY, Cowley RE, Ginsbach JW, Siegler MA, Solomon EI, Karlin KD. A N3S(thioether)-ligated Cu(II)-superoxo with enhanced reactivity. Journal of the American Chemical Society. 137: 2796-9. PMID 25697226 DOI: 10.1021/Ja511504N  0.521
2015 Kakuda S, Rolle CJ, Ohkubo K, Siegler MA, Karlin KD, Fukuzumi S. Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. Journal of the American Chemical Society. 137: 3330-7. PMID 25659416 DOI: 10.1021/Ja512584R  0.487
2015 Kakuda S, Rolle CJ, Ohkubo K, Siegler MA, Karlin KD, Fukuzumi S. Lewis acid-induced change from four- to two-electron reduction of dioxygen catalyzed by copper complexes using scandium triflate. Journal of the American Chemical Society. 137: 3330-7. PMID 25659416 DOI: 10.1021/Ja512584R  0.487
2015 Garcia-Bosch I, Adam SM, Schaefer AW, Sharma SK, Peterson RL, Solomon EI, Karlin KD. A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes. Journal of the American Chemical Society. 137: 1032-5. PMID 25594533 DOI: 10.1021/Ja5115198  0.874
2015 Garcia-Bosch I, Adam SM, Schaefer AW, Sharma SK, Peterson RL, Solomon EI, Karlin KD. A "naked" Fe(III)-(O₂²⁻)-Cu(II) species allows for structural and spectroscopic tuning of low-spin heme-peroxo-Cu complexes. Journal of the American Chemical Society. 137: 1032-5. PMID 25594533 DOI: 10.1021/Ja5115198  0.874
2014 Park GY, Lee JY, Himes RA, Thomas GS, Blackburn NJ, Karlin KD. Copper-peptide complex structure and reactivity when found in conserved His-X(aa)-His sequences. Journal of the American Chemical Society. 136: 12532-5. PMID 25171435 DOI: 10.1021/Ja505098V  0.716
2014 Park GY, Lee JY, Himes RA, Thomas GS, Blackburn NJ, Karlin KD. Copper-peptide complex structure and reactivity when found in conserved His-X(aa)-His sequences. Journal of the American Chemical Society. 136: 12532-5. PMID 25171435 DOI: 10.1021/Ja505098V  0.716
2014 Lee JY, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD. Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. Journal of the American Chemical Society. 136: 9925-37. PMID 24953129 DOI: 10.1021/Ja503105B  0.816
2014 Lee JY, Peterson RL, Ohkubo K, Garcia-Bosch I, Himes RA, Woertink J, Moore CD, Solomon EI, Fukuzumi S, Karlin KD. Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric-superoxo complex. Journal of the American Chemical Society. 136: 9925-37. PMID 24953129 DOI: 10.1021/Ja503105B  0.816
2014 Kim S, Ginsbach JW, Billah AI, Siegler MA, Moore CD, Solomon EI, Karlin KD. Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. Journal of the American Chemical Society. 136: 8063-71. PMID 24854766 DOI: 10.1021/Ja502974C  0.554
2014 Kim S, Ginsbach JW, Billah AI, Siegler MA, Moore CD, Solomon EI, Karlin KD. Tuning of the copper-thioether bond in tetradentate N₃S(thioether) ligands; O-O bond reductive cleavage via a [Cu(II)₂(μ-1,2-peroxo)]²⁺/[Cu(III)₂(μ-oxo)₂]²⁺ equilibrium. Journal of the American Chemical Society. 136: 8063-71. PMID 24854766 DOI: 10.1021/Ja502974C  0.554
2014 Kieber-Emmons MT, Ginsbach JW, Wick PK, Lucas HR, Helton ME, Lucchese B, Suzuki M, Zuberbühler AD, Karlin KD, Solomon EI. Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angewandte Chemie (International Ed. in English). 53: 4935-9. PMID 24700427 DOI: 10.1002/Anie.201402166  0.781
2014 Kieber-Emmons MT, Ginsbach JW, Wick PK, Lucas HR, Helton ME, Lucchese B, Suzuki M, Zuberbühler AD, Karlin KD, Solomon EI. Observation of a Cu(II)(2) (μ-1,2-peroxo)/Cu(III)(2) (μ-oxo)(2) equilibrium and its implications for copper-dioxygen reactivity. Angewandte Chemie (International Ed. in English). 53: 4935-9. PMID 24700427 DOI: 10.1002/Anie.201402166  0.781
2014 Hematian S, Siegler MA, Karlin KD. Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 19: 515-28. PMID 24430198 DOI: 10.1007/S00775-013-1081-6  0.837
2014 Hematian S, Siegler MA, Karlin KD. Nitric oxide generation from heme/copper assembly mediated nitrite reductase activity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 19: 515-28. PMID 24430198 DOI: 10.1007/S00775-013-1081-6  0.837
2014 Saracini C, Liakos DG, Zapata Rivera JE, Neese F, Meyer GJ, Karlin KD. Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studies. Journal of the American Chemical Society. 136: 1260-3. PMID 24428309 DOI: 10.1021/Ja4115314  0.456
2014 Saracini C, Liakos DG, Zapata Rivera JE, Neese F, Meyer GJ, Karlin KD. Excitation wavelength dependent O2 release from copper(II)-superoxide compounds: laser flash-photolysis experiments and theoretical studies. Journal of the American Chemical Society. 136: 1260-3. PMID 24428309 DOI: 10.1021/Ja4115314  0.456
2014 Yokoyama A, Han JE, Karlin KD, Nam W. An isoelectronic NO dioxygenase reaction using a nonheme iron(III)-peroxo complex and nitrosonium ion. Chemical Communications (Cambridge, England). 50: 1742-4. PMID 24394960 DOI: 10.1039/C3Cc48782B  0.616
2014 Kim S, Siegler MA, Karlin KD. Peroxynitrite chemistry derived from nitric oxide reaction with a Cu(II)-OOH species and a copper mediated NO reductive coupling reaction. Chemical Communications (Cambridge, England). 50: 2844-6. PMID 24322625 DOI: 10.1039/C3Cc47942K  0.537
2014 Garcia‐Bosch I, Karlin KD. Copper Peroxide Bioinorganic Chemistry: From Metalloenzymes to Bioinspired Synthetic Systems Patai's Chemistry of Functional Groups. 1-52. DOI: 10.1002/9780470682531.Pat0863  0.489
2013 Li Y, Sharma SK, Karlin KD. New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins. Polyhedron. 58. PMID 24223452 DOI: 10.1016/J.Poly.2012.11.011  0.699
2013 Li Y, Sharma SK, Karlin KD. New heme-dioxygen and carbon monoxide adducts using pyridyl or imidazolyl tailed porphyrins. Polyhedron. 58. PMID 24223452 DOI: 10.1016/J.Poly.2012.11.011  0.699
2013 Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society. 135: 16454-67. PMID 24164682 DOI: 10.1021/Ja4065377  0.638
2013 Peterson RL, Ginsbach JW, Cowley RE, Qayyum MF, Himes RA, Siegler MA, Moore CD, Hedman B, Hodgson KO, Fukuzumi S, Solomon EI, Karlin KD. Stepwise protonation and electron-transfer reduction of a primary copper-dioxygen adduct. Journal of the American Chemical Society. 135: 16454-67. PMID 24164682 DOI: 10.1021/Ja4065377  0.638
2013 Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorganic Chemistry. 52: 12872-4. PMID 24164429 DOI: 10.1021/Ic402357U  0.651
2013 Ginsbach JW, Peterson RL, Cowley RE, Karlin KD, Solomon EI. Correlation of the electronic and geometric structures in mononuclear copper(II) superoxide complexes. Inorganic Chemistry. 52: 12872-4. PMID 24164429 DOI: 10.1021/Ic402357U  0.651
2013 Garcia-Bosch I, Sharma SK, Karlin KD. A selective stepwise heme oxygenase model system: an iron(IV)-oxo porphyrin π-cation radical leads to a verdoheme-type compound via an isoporphyrin intermediate. Journal of the American Chemical Society. 135: 16248-51. PMID 24147457 DOI: 10.1021/Ja405739M  0.818
2013 Qayyum MF, Sarangi R, Fujisawa K, Stack TD, Karlin KD, Hodgson KO, Hedman B, Solomon EI. L-edge X-ray absorption spectroscopy and DFT calculations on Cu2O2 species: direct electrophilic aromatic attack by side-on peroxo bridged dicopper(II) complexes. Journal of the American Chemical Society. 135: 17417-31. PMID 24102191 DOI: 10.1021/Ja4078717  0.572
2013 Sharma V, Karlin KD, Wikström M. Computational study of the activated O(H) state in the catalytic mechanism of cytochrome c oxidase. Proceedings of the National Academy of Sciences of the United States of America. 110: 16844-9. PMID 24082138 DOI: 10.1073/Pnas.1220379110  0.441
2013 Yokoyama A, Cho KB, Karlin KD, Nam W. Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. Journal of the American Chemical Society. 135: 14900-3. PMID 24066924 DOI: 10.1021/Ja405891N  0.561
2013 Yokoyama A, Cho KB, Karlin KD, Nam W. Reactions of a chromium(III)-superoxo complex and nitric oxide that lead to the formation of chromium(IV)-oxo and chromium(III)-nitrito complexes. Journal of the American Chemical Society. 135: 14900-3. PMID 24066924 DOI: 10.1021/Ja405891N  0.561
2013 Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S. Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group. Journal of the American Chemical Society. 135: 6513-22. PMID 23509853 DOI: 10.1021/Ja3125977  0.661
2013 Kakuda S, Peterson RL, Ohkubo K, Karlin KD, Fukuzumi S. Enhanced catalytic four-electron dioxygen (O2) and two-electron hydrogen peroxide (H2O2) reduction with a copper(II) complex possessing a pendant ligand pivalamido group. Journal of the American Chemical Society. 135: 6513-22. PMID 23509853 DOI: 10.1021/Ja3125977  0.661
2013 Fukuzumi S, Karlin KD. Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. Coordination Chemistry Reviews. 257: 187-195. PMID 23470920 DOI: 10.1016/J.Ccr.2012.05.031  0.499
2013 Fukuzumi S, Karlin KD. Kinetics and thermodynamics of formation and electron-transfer reactions of Cu-O2 and Cu2-O2 complexes. Coordination Chemistry Reviews. 257: 187-195. PMID 23470920 DOI: 10.1016/J.Ccr.2012.05.031  0.499
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex. Journal of the American Chemical Society. 135: 4018-26. PMID 23442145 DOI: 10.1021/Ja312256U  0.788
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Acid-induced mechanism change and overpotential decrease in dioxygen reduction catalysis with a dinuclear copper complex. Journal of the American Chemical Society. 135: 4018-26. PMID 23442145 DOI: 10.1021/Ja312256U  0.788
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. Journal of the American Chemical Society. 135: 2825-34. PMID 23394287 DOI: 10.1021/Ja312523U  0.77
2013 Das D, Lee YM, Ohkubo K, Nam W, Karlin KD, Fukuzumi S. Temperature-independent catalytic two-electron reduction of dioxygen by ferrocenes with a copper(II) tris[2-(2-pyridyl)ethyl]amine catalyst in the presence of perchloric acid. Journal of the American Chemical Society. 135: 2825-34. PMID 23394287 DOI: 10.1021/Ja312523U  0.77
2013 Peterson RL, Kim S, Karlin KD. Copper Enzymes Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 3: 149-177. DOI: 10.1016/B978-0-08-097774-4.00309-0  0.527
2012 Karlin KD, Zhang CX, Rheingold AL, Galliker B, Kaderli S, Zuberbühler AD. Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations. Inorganica Chimica Acta. 389: 138-150. PMID 23420124 DOI: 10.1016/J.Ica.2012.01.042  0.539
2012 Karlin KD, Zhang CX, Rheingold AL, Galliker B, Kaderli S, Zuberbühler AD. Reversible dioxygen binding and arene hydroxylation reactions: Kinetic and thermodynamic studies involving ligand electronic and structural variations. Inorganica Chimica Acta. 389: 138-150. PMID 23420124 DOI: 10.1016/J.Ica.2012.01.042  0.539
2012 Kim S, Saracini C, Siegler MA, Drichko N, Karlin KD. Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorganic Chemistry. 51: 12603-5. PMID 23153187 DOI: 10.1021/Ic302071E  0.433
2012 Kim S, Saracini C, Siegler MA, Drichko N, Karlin KD. Coordination chemistry and reactivity of a cupric hydroperoxide species featuring a proximal H-bonding substituent. Inorganic Chemistry. 51: 12603-5. PMID 23153187 DOI: 10.1021/Ic302071E  0.433
2012 Hematian S, Siegler MA, Karlin KD. Heme/copper assembly mediated nitrite and nitric oxide interconversion. Journal of the American Chemical Society. 134: 18912-5. PMID 23130610 DOI: 10.1021/Ja3083818  0.842
2012 Hematian S, Siegler MA, Karlin KD. Heme/copper assembly mediated nitrite and nitric oxide interconversion. Journal of the American Chemical Society. 134: 18912-5. PMID 23130610 DOI: 10.1021/Ja3083818  0.842
2012 Yokoyama A, Han JE, Cho J, Kubo M, Ogura T, Siegler MA, Karlin KD, Nam W. Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. Journal of the American Chemical Society. 134: 15269-72. PMID 22950528 DOI: 10.1021/Ja307384E  0.558
2012 Yokoyama A, Han JE, Cho J, Kubo M, Ogura T, Siegler MA, Karlin KD, Nam W. Chromium(IV)-peroxo complex formation and its nitric oxide dioxygenase reactivity. Journal of the American Chemical Society. 134: 15269-72. PMID 22950528 DOI: 10.1021/Ja307384E  0.558
2012 Ghiladi RA, Rheingold AL, Siegler MA, Karlin KD. Synthesis and Characterization of New Trinuclear Copper Complexes. Inorganica Chimica Acta. 389: 131-137. PMID 22773847 DOI: 10.1016/J.Ica.2012.02.020  0.755
2012 Ghiladi RA, Rheingold AL, Siegler MA, Karlin KD. Synthesis and Characterization of New Trinuclear Copper Complexes. Inorganica Chimica Acta. 389: 131-137. PMID 22773847 DOI: 10.1016/J.Ica.2012.02.020  0.755
2012 Yamada Y, Maeda K, Ohkubo K, Karlin KD, Fukuzumi S. Improvement of durability of an organic photocatalyst in p-xylene oxygenation by addition of a Cu(II) complex. Physical Chemistry Chemical Physics : Pccp. 14: 9654-9. PMID 22692585 DOI: 10.1039/C2Cp41207A  0.574
2012 Park GY, Qayyum MF, Woertink J, Hodgson KO, Hedman B, Narducci Sarjeant AA, Solomon EI, Karlin KD. Geometric and electronic structure of [{Cu(MeAN)}2(μ-η2:η2(O2(2-)))]2+ with an unusually long O-O bond: O-O bond weakening vs activation for reductive cleavage. Journal of the American Chemical Society. 134: 8513-24. PMID 22571744 DOI: 10.1021/Ja300674M  0.709
2012 Fukuzumi S, Doi K, Itoh A, Suenobu T, Ohkubo K, Yamada Y, Karlin KD. Formation of a long-lived electron-transfer state in mesoporous silica-alumina composites enhances photocatalytic oxygenation reactivity. Proceedings of the National Academy of Sciences of the United States of America. 109: 15572-7. PMID 22543164 DOI: 10.1073/Pnas.1119994109  0.46
2012 Fukuzumi S, Tahsini L, Lee YM, Ohkubo K, Nam W, Karlin KD. Factors that control catalytic two- versus four-electron reduction of dioxygen by copper complexes. Journal of the American Chemical Society. 134: 7025-35. PMID 22462521 DOI: 10.1021/Ja211656G  0.774
2012 Comba P, Haaf C, Helmle S, Karlin KD, Pandian S, Waleska A. Dioxygen reactivity of new bispidine-copper complexes. Inorganic Chemistry. 51: 2841-51. PMID 22332786 DOI: 10.1021/Ic2019296  0.515
2012 Tahsini L, Kotani H, Lee YM, Cho J, Nam W, Karlin KD, Fukuzumi S. Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 1084-93. PMID 22237962 DOI: 10.1002/Chem.201103215  0.678
2012 Tahsini L, Kotani H, Lee YM, Cho J, Nam W, Karlin KD, Fukuzumi S. Electron-transfer reduction of dinuclear copper peroxo and bis-μ-oxo complexes leading to the catalytic four-electron reduction of dioxygen to water. Chemistry (Weinheim An Der Bergstrasse, Germany). 18: 1084-93. PMID 22237962 DOI: 10.1002/Chem.201103215  0.678
2012 Kieber-Emmons MT, Qayyum MF, Li Y, Halime Z, Hodgson KO, Hedman B, Karlin KD, Solomon EI. Spectroscopic elucidation of a new heme/copper dioxygen structure type: implications for O···O bond rupture in cytochrome c oxidase. Angewandte Chemie (International Ed. in English). 51: 168-72. PMID 22095556 DOI: 10.1002/Anie.201104080  0.547
2011 Kieber-Emmons MT, Li Y, Halime Z, Karlin KD, Solomon EI. Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorganic Chemistry. 50: 11777-86. PMID 22007669 DOI: 10.1021/Ic2018727  0.333
2011 Kieber-Emmons MT, Li Y, Halime Z, Karlin KD, Solomon EI. Electronic structure of a low-spin heme/Cu peroxide complex: spin-state and spin-topology contributions to reactivity. Inorganic Chemistry. 50: 11777-86. PMID 22007669 DOI: 10.1021/Ic2018727  0.333
2011 Halime Z, Kotani H, Li Y, Fukuzumi S, Karlin KD. Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights. Proceedings of the National Academy of Sciences of the United States of America. 108: 13990-4. PMID 21808032 DOI: 10.1073/Pnas.1104698108  0.424
2011 Halime Z, Kotani H, Li Y, Fukuzumi S, Karlin KD. Homogeneous catalytic O2 reduction to water by a cytochrome c oxidase model with trapping of intermediates and mechanistic insights. Proceedings of the National Academy of Sciences of the United States of America. 108: 13990-4. PMID 21808032 DOI: 10.1073/Pnas.1104698108  0.424
2011 Peterson RL, Himes RA, Kotani H, Suenobu T, Tian L, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Cupric superoxo-mediated intermolecular C-H activation chemistry. Journal of the American Chemical Society. 133: 1702-5. PMID 21265534 DOI: 10.1021/Ja110466Q  0.69
2011 Peterson RL, Himes RA, Kotani H, Suenobu T, Tian L, Siegler MA, Solomon EI, Fukuzumi S, Karlin KD. Cupric superoxo-mediated intermolecular C-H activation chemistry. Journal of the American Chemical Society. 133: 1702-5. PMID 21265534 DOI: 10.1021/Ja110466Q  0.69
2011 Choi YJ, Cho KB, Kubo M, Ogura T, Karlin KD, Cho J, Nam W. Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Transactions (Cambridge, England : 2003). 40: 2234-41. PMID 21258722 DOI: 10.1039/C0Dt01036G  0.671
2011 Choi YJ, Cho KB, Kubo M, Ogura T, Karlin KD, Cho J, Nam W. Spectroscopic and computational characterization of CuII-OOR (R = H or cumyl) complexes bearing a Me6-tren ligand. Dalton Transactions (Cambridge, England : 2003). 40: 2234-41. PMID 21258722 DOI: 10.1039/C0Dt01036G  0.671
2010 Woertink JS, Tian L, Maiti D, Lucas HR, Himes RA, Karlin KD, Neese F, Würtele C, Holthausen MC, Bill E, Sundermeyer J, Schindler S, Solomon EI. Spectroscopic and computational studies of an end-on bound superoxo-Cu(II) complex: geometric and electronic factors that determine the ground state. Inorganic Chemistry. 49: 9450-9. PMID 20857998 DOI: 10.1021/Ic101138U  0.806
2010 Lee Y, Lee DH, Park GY, Lucas HR, Narducci Sarjeant AA, Kieber-Emmons MT, Vance MA, Milligan AE, Solomon EI, Karlin KD. Sulfur donor atom effects on copper(I)/O(2) chemistry with thioanisole containing tetradentate N(3)S ligand leading to μ-1,2-peroxo-dicopper(II) species. Inorganic Chemistry. 49: 8873-85. PMID 20822156 DOI: 10.1021/Ic101041M  0.865
2010 Lucas HR, Meyer GJ, Karlin KD. CO and O2 binding to pseudo-tetradentate ligand-copper(I) complexes with a variable N-donor moiety: kinetic/thermodynamic investigation reveals ligand-induced changes in reaction mechanism. Journal of the American Chemical Society. 132: 12927-40. PMID 20726586 DOI: 10.1021/Ja104107Q  0.765
2010 Schopfer MP, Wang J, Karlin KD. Bioinspired heme, heme/nonheme diiron, heme/copper, and inorganic NOx chemistry: *NO((g)) oxidation, peroxynitrite-metal chemistry, and *NO((g)) reductive coupling. Inorganic Chemistry. 49: 6267-82. PMID 20666386 DOI: 10.1021/Ic100033Y  0.814
2010 Fukuzumi S, Kotani H, Lucas HR, Doi K, Suenobu T, Peterson RL, Karlin KD. Mononuclear copper complex-catalyzed four-electron reduction of oxygen. Journal of the American Chemical Society. 132: 6874-5. PMID 20443560 DOI: 10.1021/Ja100538X  0.853
2010 Halime Z, Kieber-Emmons MT, Qayyum MF, Mondal B, Gandhi T, Puiu SC, Chufán EE, Sarjeant AA, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorganic Chemistry. 49: 3629-45. PMID 20380465 DOI: 10.1021/Ic9020993  0.858
2010 Halime Z, Kieber-Emmons MT, Qayyum MF, Mondal B, Gandhi T, Puiu SC, Chufán EE, Sarjeant AA, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Heme-copper-dioxygen complexes: toward understanding ligand-environmental effects on the coordination geometry, electronic structure, and reactivity. Inorganic Chemistry. 49: 3629-45. PMID 20380465 DOI: 10.1021/Ic9020993  0.858
2010 Wang J, Schopfer MP, Puiu SC, Sarjeant AA, Karlin KD. Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. Inorganic Chemistry. 49: 1404-19. PMID 20030370 DOI: 10.1021/Ic901431R  0.859
2010 Wang J, Schopfer MP, Puiu SC, Sarjeant AA, Karlin KD. Reductive coupling of nitrogen monoxide (*NO) facilitated by heme/copper complexes. Inorganic Chemistry. 49: 1404-19. PMID 20030370 DOI: 10.1021/Ic901431R  0.859
2010 Park GY, Lee Y, Lee DH, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Thioether S-ligation in a side-on micro-eta2:eta2-peroxodicopperii complex. Chemical Communications (Cambridge, England). 46: 91-3. PMID 20024303 DOI: 10.1039/B918616F  0.787
2009 Lucas HR, Karlin KD. Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. Metal Ions in Life Sciences. 6: 295-361. PMID 20877799 DOI: 10.1039/9781847559333-00295  0.747
2009 Lucas HR, Karlin KD. Copper-Carbon Bonds in Mechanistic and Structural Probing of Proteins as well as in Situations where Copper is a Catalytic or Receptor Site. Metal Ions in Life Sciences. 6: 295-361. PMID 20877799 DOI: 10.1039/9781847559333-00295  0.747
2009 Himes RA, Karlin KD. A new copper-oxo player in methane oxidation. Proceedings of the National Academy of Sciences of the United States of America. 106: 18877-8. PMID 19889982 DOI: 10.1073/Pnas.0911413106  0.431
2009 Lee Y, Park GY, Lucas HR, Vajda PL, Kamaraj K, Vance MA, Milligan AE, Woertink JS, Siegler MA, Narducci Sarjeant AA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Copper(I)/O2 chemistry with imidazole containing tripodal tetradentate ligands leading to mu-1,2-peroxo-dicopper(II) species. Inorganic Chemistry. 48: 11297-309. PMID 19886646 DOI: 10.1021/Ic9017695  0.879
2009 Lucas HR, Meyer GJ, Karlin KD. Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems. Journal of the American Chemical Society. 131: 13924-5. PMID 19736941 DOI: 10.1021/Ja906172C  0.76
2009 Lucas HR, Meyer GJ, Karlin KD. Carbon monoxide and nitrogen monoxide ligand dynamics in synthetic heme and heme-copper complex systems. Journal of the American Chemical Society. 131: 13924-5. PMID 19736941 DOI: 10.1021/Ja906172C  0.76
2009 Maiti D, Woertink JS, Ghiladi RA, Solomon EI, Karlin KD. Molecular oxygen and sulfur reactivity of a cyclotriveratrylene derived trinuclear copper(I) complex. Inorganic Chemistry. 48: 8342-56. PMID 19663454 DOI: 10.1021/Ic900975Y  0.827
2009 Park GY, Deepalatha S, Puiu SC, Lee DH, Mondal B, Narducci Sarjeant AA, del Rio D, Pau MY, Solomon EI, Karlin KD. A peroxynitrite complex of copper: formation from a copper-nitrosyl complex, transformation to nitrite and exogenous phenol oxidative coupling or nitration. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 14: 1301-11. PMID 19662443 DOI: 10.1007/S00775-009-0575-8  0.879
2009 Schopfer MP, Mondal B, Lee DH, Sarjeant AA, Karlin KD. Heme/O2/*NO nitric oxide dioxygenase (NOD) reactivity: phenolic nitration via a putative heme-peroxynitrite intermediate. Journal of the American Chemical Society. 131: 11304-5. PMID 19627146 DOI: 10.1021/Ja904832J  0.833
2009 Himes RA, Karlin KD. Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). Current Opinion in Chemical Biology. 13: 119-31. PMID 19286415 DOI: 10.1016/J.Cbpa.2009.02.025  0.367
2009 Himes RA, Karlin KD. Copper-dioxygen complex mediated C-H bond oxygenation: relevance for particulate methane monooxygenase (pMMO). Current Opinion in Chemical Biology. 13: 119-31. PMID 19286415 DOI: 10.1016/J.Cbpa.2009.02.025  0.367
2009 Lucas HR, Li L, Sarjeant AA, Vance MA, Solomon EI, Karlin KD. Toluene and ethylbenzene aliphatic C-H bond oxidations initiated by a dicopper(II)-mu-1,2-peroxo complex. Journal of the American Chemical Society. 131: 3230-45. PMID 19216527 DOI: 10.1021/Ja807081D  0.803
2009 Wang J, Schopfer MP, Sarjeant AA, Karlin KD. Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). Journal of the American Chemical Society. 131: 450-1. PMID 19099478 DOI: 10.1021/Ja8084324  0.863
2009 Wang J, Schopfer MP, Sarjeant AA, Karlin KD. Heme-copper assembly mediated reductive coupling of nitrogen monoxide (*NO). Journal of the American Chemical Society. 131: 450-1. PMID 19099478 DOI: 10.1021/Ja8084324  0.863
2008 Himes RA, Park GY, Siluvai GS, Blackburn NJ, Karlin KD. Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. Angewandte Chemie (International Ed. in English). 47: 9084-7. PMID 18932185 DOI: 10.1002/Anie.200803908  0.617
2008 Himes RA, Park GY, Siluvai GS, Blackburn NJ, Karlin KD. Structural studies of copper(I) complexes of amyloid-beta peptide fragments: formation of two-coordinate bis(histidine) complexes. Angewandte Chemie (International Ed. in English). 47: 9084-7. PMID 18932185 DOI: 10.1002/Anie.200803908  0.617
2008 Maiti D, Narducci Sarjeant AA, Karlin KD. Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. Inorganic Chemistry. 47: 8736-47. PMID 18783212 DOI: 10.1021/Ic800617M  0.635
2008 Maiti D, Narducci Sarjeant AA, Karlin KD. Copper-hydroperoxo-mediated N-debenzylation chemistry mimicking aspects of copper monooxygenases. Inorganic Chemistry. 47: 8736-47. PMID 18783212 DOI: 10.1021/Ic800617M  0.635
2008 Maiti D, Lee DH, Narducci Sarjeant AA, Pau MY, Solomon EI, Gaoutchenova K, Sundermeyer J, Karlin KD. Reaction of a copper-dioxygen complex with nitrogen monoxide (*NO) leads to a copper(II)-peroxynitrite species. Journal of the American Chemical Society. 130: 6700-1. PMID 18457392 DOI: 10.1021/Ja801540E  0.676
2008 Zhu Q, Lian Y, Thyagarajan S, Rokita SE, Karlin KD, Blough NV. Hydrogen peroxide and dioxygen activation by dinuclear copper complexes in aqueous solution: hydroxyl radical production initiated by internal electron transfer. Journal of the American Chemical Society. 130: 6304-5. PMID 18433125 DOI: 10.1021/Ja800080Z  0.71
2008 Maiti D, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. Inorganic Chemistry. 47: 3787-800. PMID 18396862 DOI: 10.1021/Ic702437C  0.672
2008 Maiti D, Woertink JS, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper dioxygen adducts: formation of bis(mu-oxo)dicopper(III) versus (mu-1,2)Peroxodicopper(II) complexes with small changes in one pyridyl-ligand substituent. Inorganic Chemistry. 47: 3787-800. PMID 18396862 DOI: 10.1021/Ic702437C  0.672
2008 Maiti D, Narducci Sarjeant AA, Itoh S, Karlin KD. Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety. Journal of the American Chemical Society. 130: 5644-5. PMID 18393421 DOI: 10.1021/Ja800795B  0.558
2008 Maiti D, Narducci Sarjeant AA, Itoh S, Karlin KD. Suggestion of an organometallic intermediate in an intramolecular dechlorination reaction involving copper(I) and a ArCH2Cl moiety. Journal of the American Chemical Society. 130: 5644-5. PMID 18393421 DOI: 10.1021/Ja800795B  0.558
2008 Sarangi R, York JT, Helton ME, Fujisawa K, Karlin KD, Tolman WB, Hodgson KO, Hedman B, Solomon EI. X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding. Journal of the American Chemical Society. 130: 676-86. PMID 18076173 DOI: 10.1021/Ja0762745  0.632
2008 Fry HC, Lucas HR, Sarjeant AA, Karlin KD, Meyer GJ. Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorganic Chemistry. 47: 241-56. PMID 18052158 DOI: 10.1021/Ic701903H  0.825
2008 Fry HC, Lucas HR, Sarjeant AA, Karlin KD, Meyer GJ. Carbon monoxide coordination and reversible photodissociation in copper(I) pyridylalkylamine compounds. Inorganic Chemistry. 47: 241-56. PMID 18052158 DOI: 10.1021/Ic701903H  0.825
2008 Maiti D, Lee DH, Gaoutchenova K, Würtele C, Holthausen MC, Sarjeant AA, Sundermeyer J, Schindler S, Karlin KD. Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie (International Ed. in English). 47: 82-5. PMID 18022887 DOI: 10.1002/Anie.200704389  0.581
2008 Maiti D, Lee DH, Gaoutchenova K, Würtele C, Holthausen MC, Sarjeant AA, Sundermeyer J, Schindler S, Karlin KD. Reactions of a copper(II) superoxo complex lead to C-H and O-H substrate oxygenation: modeling copper-monooxygenase C-H hydroxylation. Angewandte Chemie (International Ed. in English). 47: 82-5. PMID 18022887 DOI: 10.1002/Anie.200704389  0.581
2008 Fry HC, Lucas HR, Zakharov LN, Rheingold AL, Meyer GJ, Karlin KD. Intermolecular versus intramolecular electron-/atom- (Cl{radical dot}) transfer in heme-iron and copper pyridylalkylamine complexes Inorganica Chimica Acta. 361: 1100-1115. DOI: 10.1016/J.Ica.2007.08.016  0.8
2008 Lucas HR, Meyer GJ, Karlin KD. The rate of dioxygen and carbon monoxide binding to copper(I) complexes of various ligands: Extension of the "flash-and-trap" technique Acs National Meeting Book of Abstracts.  0.704
2007 Lee Y, Lee DH, Sarjeant AA, Karlin KD. Thiol-copper(I) and disulfide-dicopper(I) complex O2-reactivity leading to sulfonate-copper(II) complex or the formation of a cross-linked thioether-phenol product with phenol addition. Journal of Inorganic Biochemistry. 101: 1845-58. PMID 17651805 DOI: 10.1016/J.Jinorgbio.2007.06.016  0.73
2007 Chufán EE, Mondal B, Gandhi T, Kim E, Rubie ND, Moënne-Loccoz P, Karlin KD. Reactivity studies on Fe(III)-(O2(2-))-Cu(II) compounds: influence of the ligand architecture and copper ligand denticity. Inorganic Chemistry. 46: 6382-94. PMID 17616124 DOI: 10.1021/Ic700363K  0.879
2007 Maiti D, Woertink JS, Vance MA, Milligan AE, Sarjeant AA, Solomon EI, Karlin KD. Copper(I)/S(8) reversible reactions leading to an end-on bound dicopper(II) disulfide complex: nucleophilic reactivity and analogies to copper-dioxygen chemistry. Journal of the American Chemical Society. 129: 8882-92. PMID 17592845 DOI: 10.1021/Ja071968Z  0.702
2007 Lee DH, Hatcher LQ, Vance MA, Sarangi R, Milligan AE, Sarjeant AA, Incarvito CD, Rheingold AL, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Copper(I) complex O(2)-reactivity with a N(3)S thioether ligand: a copper-dioxygen adduct including sulfur ligation, ligand oxygenation, and comparisons with all nitrogen ligand analogues. Inorganic Chemistry. 46: 6056-68. PMID 17580938 DOI: 10.1021/Ic700541K  0.878
2007 Chufán EE, Puiu SC, Karlin KD. Heme-copper/dioxygen adduct formation, properties, and reactivity. Accounts of Chemical Research. 40: 563-72. PMID 17550225 DOI: 10.1021/Ar700031T  0.64
2007 Maiti D, Lucas HR, Sarjeant AA, Karlin KD. Aryl hydroxylation from a mononuclear copper-hydroperoxo species. Journal of the American Chemical Society. 129: 6998-9. PMID 17497785 DOI: 10.1021/Ja071704C  0.831
2007 Maiti D, Sarjeant AA, Karlin KD. Copper(II)-hydroperoxo complex induced oxidative N-dealkylation chemistry. Journal of the American Chemical Society. 129: 6720-1. PMID 17474748 DOI: 10.1021/Ja0719024  0.629
2007 Ghiladi RA, Chufan EE, del Río D, Solomon EI, Krebs C, Huynh BH, Huang HW, Moënne-Loccoz P, Kaderli S, Honecker M, Zuberbühler AD, Marzilli L, Cotter RJ, Karlin KD. Further insights into the spectroscopic properties, electronic structure, and kinetics of formation of the heme-peroxo-copper complex [(F8TPP)FeIII-(O2(2-)-CuII(TMPA)]+. Inorganic Chemistry. 46: 3889-902. PMID 17444630 DOI: 10.1021/Ic061726K  0.76
2007 Himes RA, Park GY, Barry AN, Blackburn NJ, Karlin KD. Synthesis and X-ray absorption spectroscopy structural studies of Cu(I) complexes of histidylhistidine peptides: the predominance of linear 2-coordinate geometry. Journal of the American Chemical Society. 129: 5352-3. PMID 17411054 DOI: 10.1021/Ja0708013  0.722
2007 Chufan EE, Verani CN, Puiu SC, Rentschler E, Schatzschneider U, Incarvito C, Rheingold AL, Karlin KD. Generation and characterization of [(P)M-(X)-Co(TMPA)]n+ assemblies; P = Porphyrinate, M = FeIII and CoIII, X = O2-, OH-, O2(2-), and TMPA = tris(2-pyridylmethyl)amine. Inorganic Chemistry. 46: 3017-26. PMID 17371009 DOI: 10.1021/Ic061686K  0.737
2007 Maiti D, Fry HC, Woertink JS, Vance MA, Solomon EI, Karlin KD. A 1:1 copper-dioxygen adduct is an end-on bound superoxo copper(II) complex which undergoes oxygenation reactions with phenols. Journal of the American Chemical Society. 129: 264-5. PMID 17212392 DOI: 10.1021/Ja067411L  0.783
2007 Lee DH, Murthy NN, Karlin KD. Copper-dioxygen reactivity using dinucleating ligands with activated methylene or ketone function Bulletin of the Chemical Society of Japan. 80: 732-742. DOI: 10.1246/Bcsj.80.732  0.612
2007 Karlin KD, Gultneh Y. Binding and Activation of Molecular Oxygen by Copper Complexes Progress in Inorganic Chemistry. 35: 219-327. DOI: 10.1002/9780470166369.Ch3  0.416
2006 Lee Y, Lee DH, Sarjeant AA, Zakharov LN, Rheingold AL, Karlin KD. Thioether sulfur oxygenation from O2 or H2O2 reactivity of copper complexes with tridentate N2Sthioether ligands. Inorganic Chemistry. 45: 10098-107. PMID 17140215 DOI: 10.1021/Ic060730T  0.742
2006 Hatcher LQ, Lee DH, Vance MA, Milligan AE, Sarangi R, Hodgson KO, Hedman B, Solomon EI, Karlin KD. Dioxygen reactivity of a copper(I) complex with a N3S thioether chelate; peroxo-dicopper(II) formation including sulfur-ligation. Inorganic Chemistry. 45: 10055-7. PMID 17140210 DOI: 10.1021/Ic061813C  0.869
2006 Li L, Sarjeant AA, Karlin KD. Reactivity study of a hydroperoxodicopper(II) complex: hydroxylation, dehydrogenation, and ligand cross-link reactions. Inorganic Chemistry. 45: 7160-72. PMID 16933916 DOI: 10.1021/Ic060598X  0.628
2006 Li L, Murthy NN, Telser J, Zakharov LN, Yap GP, Rheingold AL, Karlin KD, Rokita SE. Targeted guanine oxidation by a dinuclear copper(II) complex at single stranded/double stranded DNA junctions. Inorganic Chemistry. 45: 7144-59. PMID 16933915 DOI: 10.1021/Ic0605930  0.626
2006 Thyagarajan S, Murthy NN, Narducci Sarjeant AA, Karlin KD, Rokita SE. Selective DNA strand scission with binuclear copper complexes: implications for an active Cu2-O2 species. Journal of the American Chemical Society. 128: 7003-8. PMID 16719480 DOI: 10.1021/Ja061014T  0.577
2006 Hatcher LQ, Vance MA, Narducci Sarjeant AA, Solomon EI, Karlin KD. Copper-dioxygen adducts and the side-on peroxo dicopper(II)/bis(mu-oxo) dicopper(III) equilibrium: Significant ligand electronic effects. Inorganic Chemistry. 45: 3004-13. PMID 16562956 DOI: 10.1021/Ic052185M  0.865
2006 Lee Y, Sarjeant AA, Karlin KD. A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands. Chemical Communications (Cambridge, England). 621-3. PMID 16446829 DOI: 10.1039/B513768C  0.659
2006 Helton ME, Maiti D, Zakharov LN, Rheingold AL, Porco JA, Karlin KD. A mu-eta2:eta2-disulfide dicopper(II) complex from reaction of S8 with a copper(I) precursor: reactivity of the bound disulfur moiety. Angewandte Chemie (International Ed. in English). 45: 1138-41. PMID 16385608 DOI: 10.1002/Anie.200503216  0.643
2006 Hatcher LQ, Karlin KD. Ligand Influences in Copper-Dioxygen Complex-Formation and Substrate Oxidations Advances in Inorganic Chemistry. 58: 131-184. DOI: 10.1016/S0898-8838(05)58004-8  0.861
2006 Smirnov VV, Brinkley DW, Lanci MP, Karlin KD, Roth JP. Probing metal-mediated O2 activation in chemical and biological systems Journal of Molecular Catalysis a: Chemical. 251: 100-107. DOI: 10.1016/J.Molcata.2006.02.026  0.428
2006 Sprakel VSI, Elemans JAAW, Feiters MC, Lucchese B, Karlin KD, Nolte RJM. Cover Picture: Synthesis and Characterization of PY2- and TPA-Appended Diphenylglycoluril Receptors and Their Bis-CuI Complexes (Eur. J. Org. Chem. 10/2006) European Journal of Organic Chemistry. 2006: 2241-2241. DOI: 10.1002/Ejoc.200690020  0.429
2006 Sprakel VSI, Elemans JAAW, Feiters MC, Lucchese B, Karlin KD, Nolte RJM. Synthesis and characterization of PY2- and TPA-appended diphenylglycoluril receptors and their bis-CuI complexes European Journal of Organic Chemistry. 2281-2295. DOI: 10.1002/Ejoc.200500865  0.478
2006 Lee DH, Mondal B, Karlin KD. Nitrogen Monoxide and Nitrous Oxide Binding and Reduction Activation of Small Molecules: Organometallic and Bioinorganic Perspectives. 43-79. DOI: 10.1002/9783527609352.ch2  0.729
2005 Li L, Narducci Sarjeant AA, Vance MA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Journal of the American Chemical Society. 127: 15360-1. PMID 16262386 DOI: 10.1021/Ja054948A  0.496
2005 Li L, Narducci Sarjeant AA, Vance MA, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Exogenous nitrile substrate hydroxylation by a new dicopper-hydroperoxide complex. Journal of the American Chemical Society. 127: 15360-1. PMID 16262386 DOI: 10.1021/Ja054948A  0.496
2005 Sprakel VS, Feiters MC, Meyer-Klaucke W, Klopstra M, Brinksma J, Feringa BL, Karlin KD, Nolte RJ. Oxygen binding and activation by the complexes of PY2- and TPA-appended diphenylglycoluril receptors with copper and other metals. Dalton Transactions (Cambridge, England : 2003). 3522-34. PMID 16234934 DOI: 10.1039/B506288H  0.586
2005 Ito T, Thyagarajan S, Karlin KD, Rokita SE. Recognition of guanines at a double helix-coil junction in DNA by a trinuclear copper complex. Chemical Communications (Cambridge, England). 4812-4. PMID 16193123 DOI: 10.1039/B509690A  0.34
2005 Kim E, Helton ME, Lu S, Moënne-Loccoz P, Incarvito CD, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes. Inorganic Chemistry. 44: 7014-29. PMID 16180864 DOI: 10.1021/Ic050446M  0.681
2005 Kim E, Helton ME, Lu S, Moënne-Loccoz P, Incarvito CD, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Tridentate copper ligand influences on heme-peroxo-copper formation and properties: reduced, superoxo, and mu-peroxo iron/copper complexes. Inorganic Chemistry. 44: 7014-29. PMID 16180864 DOI: 10.1021/Ic050446M  0.681
2005 Del Río D, Sarangi R, Chufán EE, Karlin KD, Hedman B, Hodgson KO, Solomon EI. Geometric and electronic structure of the heme-peroxo-copper complex [(F8TPP)FeIII-(O22-)-CuII(TMPA)](ClO4). Journal of the American Chemical Society. 127: 11969-78. PMID 16117536 DOI: 10.1021/Ja043374R  0.537
2005 Fry HC, Cohen AD, Toscano JP, Meyer GJ, Karlin KD. Photoinduced carbon monoxide migration in a synthetic heme-copper complex. Journal of the American Chemical Society. 127: 6225-30. PMID 15853327 DOI: 10.1021/Ja043199E  0.742
2005 Shearer J, Zhang CX, Zakharov LN, Rheingold AL, Karlin KD. Substrate oxidation by copper-dioxygen adducts: mechanistic considerations. Journal of the American Chemical Society. 127: 5469-83. PMID 15826184 DOI: 10.1021/Ja045191A  0.684
2005 Wasser IM, Huang HW, Moënne-Loccoz P, Karlin KD. Heme/non-heme diiron(II) complexes and O2, CO, and NO adducts as reduced and substrate-bound models for the active site of bacterial nitric oxide reductase. Journal of the American Chemical Society. 127: 3310-20. PMID 15755147 DOI: 10.1021/Ja0458773  0.838
2005 Kim E, Kamaraj K, Galliker B, Rubie ND, Moënne-Loccoz P, Kaderli S, Zuberbühler AD, Karlin KD. Dioxygen reactivity of copper and heme-copper complexes possessing an imidazole-phenol cross-link. Inorganic Chemistry. 44: 1238-47. PMID 15732964 DOI: 10.1021/Ic048907B  0.722
2005 Osako T, Karlin KD, Itoh S. Carbon-halogen bond activation mechanism by copper(I) complexes of (2-pyridyl)alkylamine ligands. Inorganic Chemistry. 44: 410-5. PMID 15651888 DOI: 10.1021/Ic048902E  0.55
2005 Li L, Karlin KD, Rokita SE. Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. Journal of the American Chemical Society. 127: 520-1. PMID 15643865 DOI: 10.1021/Ja044209E  0.427
2005 Li L, Karlin KD, Rokita SE. Changing selectivity of DNA oxidation from deoxyribose to Guanine by ligand design and a new binuclear copper complex. Journal of the American Chemical Society. 127: 520-1. PMID 15643865 DOI: 10.1021/Ja044209E  0.427
2005 Ghiladi RA, Huang HW, Moënne-Loccoz P, Stasser J, Blackburn NJ, Woods AS, Cotter RJ, Incarvito CD, Rheingold AL, Karlin KD. Heme-copper/dioxygen adduct formation relevant to cytochrome c oxidase: spectroscopic characterization of [(6L)FeIII-(O2(2-))-CuII]+. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 10: 63-77. PMID 15583964 DOI: 10.1007/S00775-004-0609-1  0.786
2004 Fry HC, Hoertz PG, Wasser IM, Karlin KD, Meyer GJ. Efficient photodissociation of O2 from synthetic heme and heme/M (M = Fe, Cu) complexes. Journal of the American Chemical Society. 126: 16712-3. PMID 15612695 DOI: 10.1021/Ja045195F  0.845
2004 Wasser IM, Fry HC, Hoertz PG, Meyer GJ, Karlin KD. Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex. Inorganic Chemistry. 43: 8272-81. PMID 15606173 DOI: 10.1021/Ic0490932  0.837
2004 Wasser IM, Fry HC, Hoertz PG, Meyer GJ, Karlin KD. Photochemical organic oxidations and dechlorinations with a mu-oxo bridged heme/non-heme diiron complex. Inorganic Chemistry. 43: 8272-81. PMID 15606173 DOI: 10.1021/Ic0490932  0.837
2004 Kim E, Shearer J, Lu S, Moënne-Loccoz P, Helton ME, Kaderli S, Zuberbühler AD, Karlin KD. Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. Journal of the American Chemical Society. 126: 12716-7. PMID 15469233 DOI: 10.1021/Ja045941G  0.79
2004 Kim E, Shearer J, Lu S, Moënne-Loccoz P, Helton ME, Kaderli S, Zuberbühler AD, Karlin KD. Heme/Cu/O2 reactivity: change in FeIII-(O2 2-)-CuII unit peroxo binding geometry effected by tridentate copper chelation. Journal of the American Chemical Society. 126: 12716-7. PMID 15469233 DOI: 10.1021/Ja045941G  0.79
2004 Lucchese B, Humphreys KJ, Lee DH, Incarvito CD, Sommer RD, Rheingold AL, Karlin KD. Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. Inorganic Chemistry. 43: 5987-98. PMID 15360248 DOI: 10.1021/Ic0497477  0.827
2004 Lucchese B, Humphreys KJ, Lee DH, Incarvito CD, Sommer RD, Rheingold AL, Karlin KD. Mono-, bi-, and trinuclear CuII-Cl containing products based on the tris(2-pyridylmethyl)amine chelate derived from copper(I) complex dechlorination reactions of chloroform. Inorganic Chemistry. 43: 5987-98. PMID 15360248 DOI: 10.1021/Ic0497477  0.827
2004 Hatcher LQ, Karlin KD. Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 669-83. PMID 15311336 DOI: 10.1007/S00775-004-0578-4  0.879
2004 Hatcher LQ, Karlin KD. Oxidant types in copper-dioxygen chemistry: the ligand coordination defines the Cu(n)-O2 structure and subsequent reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 9: 669-83. PMID 15311336 DOI: 10.1007/S00775-004-0578-4  0.879
2004 Liang HC, Henson MJ, Hatcher LQ, Vance MA, Zhang CX, Lahti D, Kaderli S, Sommer RD, Rheingold AL, Zuberbühler AD, Solomon EI, Karlin KD. Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. Inorganic Chemistry. 43: 4115-7. PMID 15236520 DOI: 10.1021/Ic0498283  0.846
2004 Liang HC, Henson MJ, Hatcher LQ, Vance MA, Zhang CX, Lahti D, Kaderli S, Sommer RD, Rheingold AL, Zuberbühler AD, Solomon EI, Karlin KD. Solvent effects on the conversion of dicopper(II) micro-eta(2):eta(2)-peroxo to bis-micro-oxo dicopper(III) complexes: direct probing of the solvent interaction. Inorganic Chemistry. 43: 4115-7. PMID 15236520 DOI: 10.1021/Ic0498283  0.846
2004 Kim E, Chufán EE, Kamaraj K, Karlin KD. Synthetic models for heme-copper oxidases. Chemical Reviews. 104: 1077-133. PMID 14871150 DOI: 10.1021/Cr0206162  0.51
2004 Kim E, Chufán EE, Kamaraj K, Karlin KD. Synthetic models for heme-copper oxidases. Chemical Reviews. 104: 1077-133. PMID 14871150 DOI: 10.1021/Cr0206162  0.51
2004 Wasser IM, Martens CF, Verani CN, Rentschler E, Huang HW, Moënne-Loccoz P, Zakharov LN, Rheingold AL, Karlin KD. Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorganic Chemistry. 43: 651-62. PMID 14731027 DOI: 10.1021/Ic0348143  0.833
2004 Wasser IM, Martens CF, Verani CN, Rentschler E, Huang HW, Moënne-Loccoz P, Zakharov LN, Rheingold AL, Karlin KD. Synthesis and spectroscopy of micro-oxo (O(2)(-))-bridged heme/non-heme diiron complexes: models for the active site of nitric oxide reductase. Inorganic Chemistry. 43: 651-62. PMID 14731027 DOI: 10.1021/Ic0348143  0.833
2004 Karlin KD, Kim E. Ligand influences in heme-copper O2-chemistry as synthetic models for cytochrome c oxidase Chemistry Letters. 33: 1226-1231. DOI: 10.1246/Cl.2004.1226  0.604
2003 Chufán EE, Karlin KD. An iron-peroxo porphyrin complex: new synthesis and reactivity toward a Cu(II) complex giving a heme-peroxo-copper adduct. Journal of the American Chemical Society. 125: 16160-1. PMID 14692736 DOI: 10.1021/Ja036632D  0.628
2003 Shearer J, Zhang CX, Hatcher LQ, Karlin KD. Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. Journal of the American Chemical Society. 125: 12670-1. PMID 14558790 DOI: 10.1021/Ja0359409  0.796
2003 Shearer J, Zhang CX, Hatcher LQ, Karlin KD. Distinguishing rate-limiting electron versus H-atom transfers in Cu2O2-mediated oxidative N-dealkylations: application of inter- versus intramolecular kinetic isotope effects. Journal of the American Chemical Society. 125: 12670-1. PMID 14558790 DOI: 10.1021/Ja0359409  0.796
2003 Fry HC, Scaltrito DV, Karlin KD, Meyer GJ. The rate of O2 and CO binding to a copper complex, determined by a "flash-and-trap" technique, exceeds that for hemes. Journal of the American Chemical Society. 125: 11866-71. PMID 14505408 DOI: 10.1021/Ja034911V  0.73
2003 Thompson DW, Kretzer RM, Lebeau EL, Scaltrito DV, Ghiladi RA, Lam KC, Rheingold AL, Karlin KD, Meyer GJ. Synthesis, characterization, and laser flash photolysis reactivity of a carbonmonoxy heme complex. Inorganic Chemistry. 42: 5211-8. PMID 12924892 DOI: 10.1021/Ic026307B  0.682
2003 Kamaraj K, Kim E, Galliker B, Zakharov LN, Rheingold AL, Zuberbühler AD, Karlin KD. Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity. Journal of the American Chemical Society. 125: 6028-9. PMID 12785812 DOI: 10.1021/Ja034263F  0.599
2003 Kamaraj K, Kim E, Galliker B, Zakharov LN, Rheingold AL, Zuberbühler AD, Karlin KD. Copper(I) and copper(II) complexes possessing cross-linked imidazole-phenol ligands: structures and dioxygen reactivity. Journal of the American Chemical Society. 125: 6028-9. PMID 12785812 DOI: 10.1021/Ja034263F  0.599
2003 Chen P, Fujisawa K, Helton ME, Karlin KD, Solomon EI. Spectroscopy and bonding in side-on and end-on Cu2(S2) cores: comparison to peroxide analogues. Journal of the American Chemical Society. 125: 6394-408. PMID 12785779 DOI: 10.1021/Ja0214678  0.55
2003 Kretzer RM, Ghiladi RA, Lebeau EL, Liang HC, Karlin KD. Synthesis and characterization of reduced heme and heme/copper carbonmonoxy species. Inorganic Chemistry. 42: 3016-25. PMID 12716196 DOI: 10.1021/Ic020521I  0.722
2003 Henson MJ, Vance MA, Zhang CX, Liang HC, Karlin KD, Solomon EI. Resonance raman investigation of equatorial ligand donor effects on the Cu(2)O(2)(2+) core in end-on and side-on mu-peroxo-dicopper(II) and bis-mu-oxo-dicopper(III) complexes. Journal of the American Chemical Society. 125: 5186-92. PMID 12708870 DOI: 10.1021/Ja0276366  0.579
2003 Kim E, Helton ME, Wasser IM, Karlin KD, Lu S, Huang HW, Moenne-Loccoz P, Incarvito CD, Rheingold AL, Honecker M, Kaderli S, Zuberbuhler AD. Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models. Proceedings of the National Academy of Sciences of the United States of America. 100: 3623-8. PMID 12655050 DOI: 10.1073/Pnas.0737180100  0.866
2003 Kim E, Helton ME, Wasser IM, Karlin KD, Lu S, Huang HW, Moenne-Loccoz P, Incarvito CD, Rheingold AL, Honecker M, Kaderli S, Zuberbuhler AD. Superoxo, mu-peroxo, and mu-oxo complexes from heme/O2 and heme-Cu/O2 reactivity: copper ligand influences in cytochrome c oxidase models. Proceedings of the National Academy of Sciences of the United States of America. 100: 3623-8. PMID 12655050 DOI: 10.1073/Pnas.0737180100  0.866
2003 Zhang CX, Kaderli S, Costas M, Kim EI, Neuhold YM, Karlin KD, Zuberbühler AD. Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. Inorganic Chemistry. 42: 1807-24. PMID 12639113 DOI: 10.1021/Ic0205684  0.608
2003 Zhang CX, Kaderli S, Costas M, Kim EI, Neuhold YM, Karlin KD, Zuberbühler AD. Copper(I)-dioxygen reactivity of [(L)Cu(I)](+) (L = tris(2-pyridylmethyl)amine): kinetic/thermodynamic and spectroscopic studies concerning the formation of Cu-O2 and Cu2-O2 adducts as a function of solvent medium and 4-pyridyl ligand substituent variations. Inorganic Chemistry. 42: 1807-24. PMID 12639113 DOI: 10.1021/Ic0205684  0.608
2003 Helton ME, Chen P, Paul PP, Tyeklár Z, Sommer RD, Zakharov LN, Rheingold AL, Solomon EI, Karlin KD. Reaction of elemental sulfur with a copper(I) complex forming a trans-mu-1,2 end-on disulfide complex: new directions in copper-sulfur chemistry. Journal of the American Chemical Society. 125: 1160-1. PMID 12553805 DOI: 10.1021/Ja027574J  0.489
2003 Zhang CX, Liang HC, Kim EI, Shearer J, Helton ME, Kim E, Kaderli S, Incarvito CD, Zuberbühler AD, Rheingold AL, Karlin KD. Tuning copper-dioxygen reactivity and exogenous substrate oxidations via alterations in ligand electronics. Journal of the American Chemical Society. 125: 634-5. PMID 12526654 DOI: 10.1021/Ja028779V  0.718
2003 Ouant LD, Shearer J, Liang HC, Zhang CX, Karlin KD, Vance M, Henson MJ, Solomon EI. Dioxygen activation by copper(I) complexes: Electronic effects on the formation and substrate reactivity of the Cu202 core Journal of Inorganic Biochemistry. 96: 214. DOI: 10.1016/S0162-0134(03)80744-4  0.725
2003 Lee Y, Lee DH, Karlin KD, Mah YJ. Thioether ligand containing copper complexes; Modeling PHM and DβH proteins Journal of Inorganic Biochemistry. 96: 177. DOI: 10.1016/S0162-0134(03)80688-8  0.456
2003 Karlin KD, Kim E, Ghiladi RA, Helton ME, Shearer J, Lu S, Huang H, Moenne-Loccoz P. Copper ligand influences in synthetic model reactivity studies of the cytochrome c oxidase binuclear active site Journal of Inorganic Biochemistry. 96: 163. DOI: 10.1016/S0162-0134(03)80666-9  0.797
2003 Fry H, Scaltrito DV, Karlin KD, Meyer GJ. Time resolved spectroscopic determination of a sub-microsecond, 1:1 copper dioxygen interaction in which the rate exceeds that for hemes Journal of Inorganic Biochemistry. 96: 133. DOI: 10.1016/S0162-0134(03)80617-7  0.63
2003 Helton ME, Kim E, Karlin KD, Honecker M, Kaderli S, Neuhold Y, Lahti D, Zuberbuehler AD. Oxygenation kinetics of iron and copper protein active site model complexes Journal of Inorganic Biochemistry. 96: 65. DOI: 10.1016/S0162-0134(03)80513-5  0.56
2003 Shin H, Lee DH, Kang C, Karlin KD. Electrocatalytic four-electron reductions of O2 to H 2O with cytochrome c oxidase model compounds Electrochimica Acta. 48: 4077-4082. DOI: 10.1016/S0013-4686(03)00565-6  0.528
2002 Humphreys KJ, Johnson AE, Karlin KD, Rokita SE. Oxidative strand scission of nucleic acids by a multinuclear copper(II) complex. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 7: 835-42. PMID 12203020 DOI: 10.1007/S00775-002-0369-8  0.842
2002 Humphreys KJ, Karlin KD, Rokita SE. Targeted strand scission of DNA substrates by a tricopper(II) coordination complex. Journal of the American Chemical Society. 124: 8055-66. PMID 12095349 DOI: 10.1021/Ja012539I  0.823
2002 Humphreys KJ, Karlin KD, Rokita SE. Efficient and specific strand scission of DNA by a dinuclear copper complex: comparative reactivity of complexes with linked tris(2-pyridylmethyl)amine moieties. Journal of the American Chemical Society. 124: 6009-19. PMID 12022834 DOI: 10.1021/Ja020039Z  0.839
2002 Ghiladi RA, Karlin KD. Low-temperature UV-visible and NMR spectroscopic investigations of O(2) binding to ((6)L)Fe(II), a ferrous heme bearing covalently tethered axial pyridine ligands. Inorganic Chemistry. 41: 2400-7. PMID 11978105 DOI: 10.1021/Ic0103547  0.731
2002 Liang HC, Zhang CX, Henson MJ, Sommer RD, Hatwell KR, Kaderli S, Zuberbühler AD, Rheingold AL, Solomon EI, Karlin KD. Contrasting copper-dioxygen chemistry arising from alike tridentate alkyltriamine copper(I) complexes. Journal of the American Chemical Society. 124: 4170-1. PMID 11960420 DOI: 10.1021/Ja0125265  0.598
2002 Liang HC, Kim E, Incarvito CD, Rheingold AL, Karlin KD. A bis-acetonitrile two-coordinate copper(I) complex: synthesis and characterization of highly soluble B(C(6)F(5))(4)(-) salts of [Cu(MeCN)(2)](+) and [Cu(MeCN)(4)](+). Inorganic Chemistry. 41: 2209-12. PMID 11952376 DOI: 10.1021/Ic010816G  0.656
2002 Wasser IM, de Vries S, Moënne-Loccoz P, Schröder I, Karlin KD. Nitric oxide in biological denitrification: Fe/Cu metalloenzyme and metal complex NO(x) redox chemistry. Chemical Reviews. 102: 1201-34. PMID 11942794 DOI: 10.1021/Cr0006627  0.838
2001 Itoh S, Bandoh H, Nakagawa M, Nagatomo S, Kitagawa T, Karlin KD, Fukuzumi S. Formation, characterization, and reactivity of bis(mu-oxo)dinickel(III) complexes supported by a series of bis[2-(2-pyridyl)ethyl]amine ligands. Journal of the American Chemical Society. 123: 11168-78. PMID 11697960 DOI: 10.1021/Ja0104094  0.532
2001 Ghiladi RA, Kretzer RM, Guzei I, Rheingold AL, Neuhold YM, Hatwell KR, Zuberbühler AD, Karlin KD. (F(8)TPP)Fe(II)/O(2) reactivity studies [F(8)TPP = tetrakis(2,6-difluorophenyl)porphyrinate(2-)]: spectroscopic (UV-Visible and NMR) and kinetic study of solvent-dependent (Fe/O(2) = 1:1 or 2:1) reversible O(2)-reduction and ferryl formation. Inorganic Chemistry. 40: 5754-67. PMID 11681882 DOI: 10.1021/Ic0105866  0.726
2001 Scaltrito DV, Fry HC, Showalter BM, Thompson DW, Liang HC, Zhang CX, Kretzer RM, Kim E, Toscano JP, Karlin KD, Meyer GJ. Reversible carbon monoxide photodissociation from Cu(I) coordination compounds. Inorganic Chemistry. 40: 4514-5. PMID 11511192 DOI: 10.1021/Ic010684R  0.698
2001 Rhames FC, Murthy NN, Karlin KD, Blackburn NJ. Isocyanide binding to the copper(I) centers of the catalytic core of peptidylglycine monooxygenase (PHMcc). Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 6: 567-77. PMID 11472020 DOI: 10.1007/S007750100233  0.334
2001 Ghiladi RA, Hatwell KR, Karlin KD, Huang HW, Moënne-Loccoz P, Krebs C, Huynh BH, Marzilli LA, Cotter RJ, Kaderli S, Zuberbühler AD. Dioxygen reactivity of mononuclear heme and copper components yielding a high-spin heme-peroxo-cu complex. Journal of the American Chemical Society. 123: 6183-4. PMID 11414855 DOI: 10.1021/Ja010602Y  0.722
2001 Humphreys KJ, Karlin KD, Rokita SE. Recognition and strand scission at junctions between single- and double-stranded DNA by a trinuclear copper complex. Journal of the American Chemical Society. 123: 5588-9. PMID 11389647 DOI: 10.1021/Ja010403E  0.745
2001 Schatz M, Becker M, Thaler F, Hampel F, Schindler S, Jacobson RR, Tyeklár Z, Murthy NN, Ghosh P, Chen Q, Zubieta J, Karlin KD. Copper(I) complexes, copper(I)/O(2) reactivity, and copper(II) complex adducts, with a series of tetradentate tripyridylalkylamine tripodal ligands. Inorganic Chemistry. 40: 2312-22. PMID 11327908 DOI: 10.1021/Ic000924N  0.764
2001 Murthy NN, Mahroof-Tahir M, Karlin KD. Dicopper(I) complexes of unsymmetrical binucleating ligands and their dioxygen reactivities. Inorganic Chemistry. 40: 628-35. PMID 11225103 DOI: 10.1021/Ic000792Y  0.621
2001 Barton JK, Karlin KD. Bio-inorganic chemistry new advances, new directions and new investigators Current Opinion in Chemical Biology. 5: 165-167. DOI: 10.1016/S1367-5931(00)00186-1  0.329
2001 Zhang CX, Liang HC, Kim EI, Gan QF, Tyeklár Z, Lam KC, Rheingold AL, Kaderli S, Zuberbühler AD, Karlin KD. Dioxygen mediated oxo-transfer to an amine and oxidative N-dealkylation chemistry with a dinuclear copper complex Chemical Communications. 631-632.  0.364
2000 Liang HC, Karlin KD, Dyson R, Kaderli S, Jung B, Zuberbühler AD. Dioxygen-binding kinetics and thermodynamics of a series of dicopper(I) complexes with bis[2-(2-pyridyl)ethyl]amine tridendate chelators forming side-on peroxo-bridged dicopper(II) adducts. Inorganic Chemistry. 39: 5884-94. PMID 11188519 DOI: 10.1021/Ic0007916  0.504
2000 Moënne-Loccoz P, Richter OMH, Huang HW, Wasser IM, Ghiladi RA, Karlin KD, De Vries S. Nitric oxide reductase from Paracoccus denitrificans contains an oxo-bridged heme/non-heme diiron center [25] Journal of the American Chemical Society. 122: 9344-9345. DOI: 10.1021/Ja0016295  0.797
2000 Ju TD, Woods AS, Cotter RJ, Moënne-Loccoz P, Karlin KD. Dioxygen and nitric oxide reactivity of a reduced heme/non-heme diiron(II) complex [(5L)Fe(II)···Fe(II)-Cl]+. Using a tethered tetraarylporphyrin for the development of an active site reactivity model for bacterial nitric oxide reductase Inorganica Chimica Acta. 297: 362-372. DOI: 10.1016/S0020-1693(99)00404-1  0.521
1999 Feiters MC, Gebbink RJ, Solé VA, Nolting HF, Karlin KD, Nolte RJ. X-ray Absorption Spectroscopic Studies of the Copper(I) Complexes of Crown Ether Appended Bis{(2-pyridyl)ethyl}amines and Their Dioxygen Adducts. Inorganic Chemistry. 38: 6171-6180. PMID 11671329 DOI: 10.1021/Ic990056Y  0.552
1999 Kopf MA, Karlin KD. Dioxygen Reactivity of Reduced Heme and Heme-Copper Complexes Utilizing Tetraarylporphyrinates Tethered with Both a Pyridyl Axial Ligand and N,N-Bis[2-(2-pyridyl)ethyl]amine Chelate. Inorganic Chemistry. 38: 4922-4923. PMID 11671230 DOI: 10.1021/Ic990546Q  0.54
1999 Becker M, Schindler S, Karlin KD, Kaden TA, Kaderli S, Palanché T, Zuberbühler AD. Intramolecular Ligand Hydroxylation: Mechanistic High-Pressure Studies on the Reaction of a Dinuclear Copper(I) Complex with Dioxygen. Inorganic Chemistry. 38: 1989-1995. PMID 11670976 DOI: 10.1021/Ic981066M  0.421
1999 Liang HC, Dahan M, Karlin KD. Dioxygen-activating bio-inorganic model complexes. Current Opinion in Chemical Biology. 3: 168-75. PMID 10226046 DOI: 10.1016/S1367-5931(99)80029-5  0.403
1999 Karlin KD, Gan QF, Tyeklár Z. Dioxygen-copper reactivity at trinuclear centers: Formation of hexanuclear and mixed-valent adducts Chemical Communications. 2295-2296. DOI: 10.1039/A906830I  0.552
1999 Ghiladi RA, Ju TD, Lee DH, Moënne-Loccoz P, Kaderli S, Neuhold YM, Zuberbühler AD, Woods AS, Cotter RJ, Karlin KD. Formation and characterization of a high-spin heme-copper dioxygen (peroxo) complex [8] Journal of the American Chemical Society. 121: 9885-9886. DOI: 10.1021/Ja992296I  0.678
1999 Pidcock E, DeBeer S, Obias HV, Hedman B, Hodgson KO, Karlin KD, Solomon EI. A study of solid [{Cu(MePY2)}2O2]2+ using resonance Raman and X- ray absorption spectroscopies: An intermediate Cu2O2 core structure or a solid solution? Journal of the American Chemical Society. 121: 1870-1878. DOI: 10.1021/Ja983444S  0.826
1999 Pidcock E, Obias HV, Abe M, Liang HC, Karlin KD, Solomon EL. Spectroscopic and theoretical studies of oxygenated dicopper(I) complexes containing hydrocarbon-linked Bis[2-(2-pyridyl)ethyl]amine units: Investigation of a butterfly [Cu2(μ-η2:η2)(O2)]2+ core Journal of the American Chemical Society. 121: 1299-1308. DOI: 10.1021/Ja983310E  0.842
1999 Klein Gebbink RJM, Martens CF, Kenis PJA, Jansen RJ, Nolting HF, Armando Solé V, Feiters MC, Karlin KD, Nolte RJM. Synthesis, Structure, and Reactivity of Copper Dioxygen Complexes Derived from Molecular Receptor Ligands Inorganic Chemistry. 38: 5755-5768. DOI: 10.1021/Ic990108J  0.57
1999 Ju TD, Ghiladi RA, Lee DH, Van Strijdonck GPF, Woods AS, Cotter RJ, Young VG, Karlin KD. Dioxygen reactivity of fully reduced [LFeII⋯CuI]+ complexes utilizing tethered tetraarylporphyrinates: Active site models for heme-copper oxidases Inorganic Chemistry. 38: 2244-2245. DOI: 10.1021/Ic9900511  0.697
1999 Kopf MA, Neuhold YM, Zuberbühler AD, Karlin KD. Oxo- and hydroxo-bridged heme-copper assemblies formed from acid-base or metal-dioxygen chemistry Inorganic Chemistry. 38: 3093-3102. DOI: 10.1021/Ic981431+  0.473
1999 Corsi DM, Murthy NN, Young VG, Karlin KD. Synthesis, structure, and solution NMR studies of cyanide-copper(II) and cyanide-bridged iron(III)-copper(II) complexes Inorganic Chemistry. 38: 848-858. DOI: 10.1021/Ic981091S  0.449
1998 Root DE, Mahroof-Tahir M, Karlin KD, Solomon EI. Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu(2)((UN-O-)(OOH)](2+). Inorganic Chemistry. 37: 4838-4848. PMID 11670647 DOI: 10.1021/Ic980606C  0.559
1998 Karlin S, Zhu ZY, Karlin KD. Extended metal environments of cytochrome c oxidase structures. Biochemistry. 37: 17726-34. PMID 9922138 DOI: 10.1021/Bi981390T  0.325
1998 Karlin KD, Lee DH, Obias HV, Humphreys KJ. Copper-dioxygen complexes: Functional models for proteins Pure and Applied Chemistry. 70: 855-862. DOI: 10.1351/Pac199870040855  0.845
1998 Obias HV, Lin Y, Murthy NN, Pidcock E, Solomon EI, Ralle M, Blackburn NJ, Neuhold YM, Zuberbuhler AD, Karlin KD. Peroxo-, oxo-, and hydroxo-bridged dicopper complexes: Observation of exogenous hydrocarbon substrate oxidation [3] Journal of the American Chemical Society. 120: 12960-12961. DOI: 10.1021/Ja981878H  0.816
1998 Obias HV, Van Strijdonck GPF, Lee DH, Ralle M, Blackburn NJ, Karlin KD. Heterobinucleating ligand-induced structural and chemical variations in [(L)Fe(III)-O-Cu(II)]+ μ-oxo complexes [9] Journal of the American Chemical Society. 120: 9696-9697. DOI: 10.1021/Ja9810989  0.867
1998 Pidcock E, Obias HV, Zhang CX, Karlin KD, Solomon EI. Investigation of the reactive oxygen intermediate in an arene hydroxylation reaction performed by xylyl-bridged binuclear copper complexes Journal of the American Chemical Society. 120: 7841-7847. DOI: 10.1021/Ja980687B  0.84
1998 Karlin KD, Zhu ZY, Karlin S. The environment of multinuclear copper metal linkages in protein structures Journal of Biological Inorganic Chemistry. 3: 172-187. DOI: 10.1007/S007750050218  0.457
1998 Root DE, Mahroof-Tahir M, Karlin KD, Solomon EI. Effect of Protonation on Peroxo-Copper Bonding: Spectroscopic and Electronic Structure Study of [Cu2(UN-0-)(OOH)]2+ Inorganic Chemistry. 37: 4838-4848.  0.342
1997 Lee DH, Murthy NN, Karlin KD. Binuclear Copper Complexes Based on the 6,6'-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2'-bipyridine Ligand. Inorganic Chemistry. 36: 5785-5792. PMID 11670200 DOI: 10.1021/Ic970639C  0.53
1997 Comba P, Hilfenhaus P, Karlin KD. Modeling of End-On (&mgr;-Peroxo)dicopper(II) Complexes. Inorganic Chemistry. 36: 2309-2313. PMID 11669865 DOI: 10.1021/Ic961317W  0.445
1997 Frey ST, Murthy NN, Weintraub ST, Thompson LK, Karlin KD. Hydrolysis of Unactivated Esters and Acetonitrile Hydration by a Hydroxo-Dicopper(II) Complex. Inorganic Chemistry. 36: 956-957. PMID 11669653 DOI: 10.1021/Ic961439O  0.838
1997 Karlin S, Zhu ZY, Karlin KD. The extended environment of mononuclear metal centers in protein structures. Proceedings of the National Academy of Sciences of the United States of America. 94: 14225-30. PMID 9405594 DOI: 10.1073/Pnas.94.26.14225  0.444
1997 Karlin KD, Lee DH, Kaderli S, Zuberbühler AD. Copper dioxygen complexes stable at ambient temperature: Optimization of ligand design and solvent Chemical Communications. 475-476. DOI: 10.1039/A607862A  0.411
1997 Gebbink RJMK, Martens CF, Feiters MC, Karlin KD, Nolte RJM. Novel molecular receptors capable of formingCu2–O2 complexes. Effect of preorganization onO2 binding Chemical Communications. 389-390. DOI: 10.1039/A607284D  0.495
1997 Nanthakumar A, Fox S, Murthy NN, Karlin KD. Inferences from the 1H-NMR spectroscopic study of an antiferromagnetically coupled heterobinuclear Fe(III)-(X)-Cu(II) S = 2 spin system (X = O2-, OH-) Journal of the American Chemical Society. 119: 3898-3906. DOI: 10.1021/Ja962404Q  0.492
1997 Murthy NN, Karlin KD, Bertini I, Luchinat C. NMR and Electronic Relaxation in Paramagnetic Dicopper(II) Compounds Journal of the American Chemical Society. 119: 2156-2162. DOI: 10.1021/Ja961555Q  0.409
1997 Lee DH, Murthy NN, Lin Y, Sarwar Nasir N, Karlin KD. Copper ion complexes with derivatized chelating pterin ligands Inorganic Chemistry. 36: 6328-6334. DOI: 10.1021/Ic970810K  0.5
1997 Karlin KD, Kaderli S, Zuberbühler AD. Kinetics and Thermodynamics of Copper(I)/Dioxygen Interaction Accounts of Chemical Research. 30: 139-147. DOI: 10.1021/Ar950257F  0.379
1997 Karlin KD, Tolman WB, Kaderli S, Zuberbühler AD. Kinetic and thermodynamic parameters of copper-dioxygen interaction with different oxygen binding modes Journal of Molecular Catalysis a: Chemical. 117: 215-222. DOI: 10.1016/S1381-1169(96)00250-6  0.637
1997 Klein Gebbink RJM, Martens CF, Feiters MC, Karlin KD, Nolte RJM. Novel molecular receptors capable of forming Cu2-O2 complexes. Effect of preorganization on O2 binding Chemical Communications. 389-390.  0.423
1997 Comba P, Hilfenhaus P, Karlin KD. Modeling of End-On (μ-Peroxo)dicopper(II) Complexes Inorganic Chemistry. 36: 2309-2313.  0.302
1997 Lee DH, Murthy NN, Karlin KD. Binuclear Copper Complexes Based on the 6,6′-Bis[[bis(2-pyridylmethyl)amino]methyl]-2,2′-bipyridine Ligand Inorganic Chemistry. 36: 5785-5792.  0.343
1996 Lee DH, Murthy NN, Karlin KD. Copper(I)/Dioxygen Reactivity with Dinuclear Compounds: Catalytic Oxygenation and Oxo-Transfer to a Ketone. Inorganic Chemistry. 35: 804-805. PMID 11666248 DOI: 10.1021/Ic951490C  0.611
1996 Martens CF, Murthy NN, Obias HV, Karlin KD. Oxo-bridged haem/non-haem iron complexes Chemical Communications. 629-630. DOI: 10.1039/Cc9960000629  0.813
1996 Jung B, Karlin KD, Zuberbühler AD. Formation and Interconversion of End-on and Side-on μ-Peroxo−Dicopper(II) Complexes Journal of the American Chemical Society. 118: 3763-3764. DOI: 10.1021/Ja954157G  0.431
1996 Fox S, Nanthakumar A, Wikström M, Karlin KD, Blackburn NJ. XAS Structural Comparisons of Reversibly Interconvertible Oxo- and Hydroxo-Bridged Heme-Copper Oxidase Model Compounds Journal of the American Chemical Society. 118: 24-34. DOI: 10.1021/Ja951686B  0.482
1996 Frey ST, Sun HHJ, Murthy NN, Karlin KD. A new trinuclear copper complex and its reactions with plasmid DNA Inorganica Chimica Acta. 242: 329-338. DOI: 10.1016/0020-1693(96)04883-9  0.842
1995 Karlin KD, Fox S, Nanthakumar A, Murthy NN, Wei N, Obias HV, Martens CF. Copper-dioxygen chemistry and modeling the Fe-Cu center in cytochrome c oxidase Pure and Applied Chemistry. 67: 289-296. DOI: 10.1351/Pac199567020289  0.872
1995 Nanthakumar A, Fox S, Karlin KD. Copper–dioxygen reactivity involved in the formation of µ-oxo [(por)FeIII–O–CuIIL]+ heterodinuclear complexes (por = porphyrinate, L = tetradentate ligand), and novel synthesis of square-planar FeII(por) species Journal of the Chemical Society, Chemical Communications. 499-501. DOI: 10.1039/C39950000499  0.442
1995 Lee D, Wei N, Murthy NN, Tyeklar Z, Karlin KD, Kaderli S, Jung B, Zuberbuehler AD. Reversible O2 Binding to a Dinuclear Copper(I) Complex with Linked Tris(2-pyridylmethyl)amine Units: Kinetic-Thermodynamic Comparisons with Mononuclear Analogs Journal of the American Chemical Society. 117: 12498-12513. DOI: 10.1021/Ja00155A014  0.538
1995 Reedy BJ, Murthy NN, Karlin KD, Blackburn NJ. Isocyanides as Ligand-Directed Indicators of Cu(I) Coordination in Copper Proteins. Probing the Inequivalence of the Cu(I) Centers in Reduced Dopamine-.beta.-monooxygenase Journal of the American Chemical Society. 117: 9826-9831. DOI: 10.1021/Ja00144A007  0.55
1995 Sanyal I, Ghosh P, Karlin KD. Mononuclear Copper(II)-Acylperoxo Complexes Inorganic Chemistry. 34: 3050-3056. DOI: 10.1021/Ic00115A035  0.508
1995 Martens CF, van Strijdonck aP, Obias HV, Murthy NN, Karlin KD. Oxo-bridged FeCu and heme/non-heme iron complexes as heme-copper oxidase models Journal of Inorganic Biochemistry. 59: 712. DOI: 10.1016/0162-0134(95)97800-6  0.824
1995 Root DE, Murthy NN, Karlin KD, Kitajima N, Fujisawa K, Moro-oka Y, Solomon EI. Peroxo and superoxo copper complexes: Electronic structure contributions to reactivity Journal of Inorganic Biochemistry. 59: 701. DOI: 10.1016/0162-0134(95)97789-S  0.44
1995 Klein Gebbink R, Feiters M, Karlin K, Nolte R. Supramolecular Cu2:O2 complexes; Towards biomimetic and selective oxygenation of exogeneous substrates Journal of Inorganic Biochemistry. 59: 682. DOI: 10.1016/0162-0134(95)97770-Q  0.537
1994 Karlin KD, Tyeklár Z. Functional biomimics for copper proteins involved in reversible O2-binding, substrate oxidation/oxygenation and nitrite reduction. Advances in Inorganic Biochemistry. 9: 123-72. PMID 8140947  0.332
1994 Karlin KD, Nanthakumar A, Fox S, Murthy NN, Ravi N, Huynh BH, Orosz RD, Day EP. X-ray Structure and Physical Properties of the Oxo-Bridged Complex [(F8-TPP)Fe-O-Cu(TMPA)]+, F8-TPP = Tetrakis(2,6-difluorophenyl)porphyrinate(2-), TMPA = Tris(2-pyridylmethyl)amine: Modeling the Cytochrome c Oxidase Fe-Cu Heterodinuclear Active Site Journal of the American Chemical Society. 116: 4753-4763. DOI: 10.1021/Ja00090A023  0.509
1994 Karlin KD, Nasir MS, Cohen BI, Cruse RW, Kaderli S, Zuberbuehler AD. Reversible Dioxygen Binding and Aromatic Hydroxylation in O2-Reactions with Substituted Xylyl Dinuclear Copper(I) Complexes: Syntheses and Low-Temperature Kinetic/Thermodynamic and Spectroscopic Investigations of a Copper Monooxygenase Model System Journal of the American Chemical Society. 116: 1324-1336. DOI: 10.1021/Ja00083A018  0.841
1994 Wei N, Murthy NN, Karlin KD. Chemistry of Pentacoordinate [LCuII-Cl]+ Complexes with Quinolyl Containing Tripodal Tetradentate Ligands L Inorganic Chemistry. 33: 6093-6100. DOI: 10.1021/Ic00104A018  0.406
1994 Wei N, Lee D, Murthy NN, Tyeklar Z, Karlin KD, Kaderli S, Jung B, Zuberbuehler AD. Kinetic Preference without Thermodynamic Stabilization in the Intra- vs Intermolecular Formation of Copper-Dioxygen Complexes Inorganic Chemistry. 33: 4625-4626. DOI: 10.1021/Ic00099A010  0.422
1994 Wei N, Murthy NN, Chen Q, Zubieta J, Karlin KD. Copper(I)/Dioxygen Reactivity of Mononuclear Complexes with Pyridyl and Quinolyl Tripodal Tetradentate Ligands: Reversible Formation of Cu:O2 = 1:1 and 2:1 Adducts Inorganic Chemistry. 33: 1953-1965. DOI: 10.1021/Ic00087A036  0.7
1994 Wei N, Murthy NN, Tyeklar Z, Karlin KD. Copper(I) Complexes with Pyridyl- and Imidazoyl-Containing Tripodal Tetradentate Ligands and Their Reactions with Dioxygen Inorganic Chemistry. 33: 1177-1183. DOI: 10.1021/Ic00084A034  0.471
1993 Fox S, Nanthakumar A, Wei N, Murthy NN, Karlin KD. Investigations of dioxygen reactivity with synthetic models of the metalloproteins hemocyanin and cytochrome c oxidase Pure and Applied Chemistry. 65: 2335-2342. DOI: 10.1351/Pac199365112335  0.585
1993 Murthy NN, Karlin KD. A dinuclear zinc hydroxide complex which traps atmospheric carbon dioxide: formation of a tri-zinc complex with a triply bridging carbonate group Journal of the Chemical Society, Chemical Communications. 1236-1238. DOI: 10.1039/C39930001236  0.406
1993 Sanyal I, Karlin KD, Strange RW, Blackburn NJ. Chemistry and structural studies on the dioxygen-binding copper-1,2-dimethylimidazole system Journal of the American Chemical Society. 115: 11259-11270. DOI: 10.1021/Ja00077A027  0.509
1993 Murthy NN, Mahroof-Tahir M, Karlin KD. Facile amide hydrolysis effected by dinuclear copper complexes Journal of the American Chemical Society. 115: 10404-10405. DOI: 10.1021/Ja00075A084  0.5
1993 Karlin KD, Wei N, Jung B, Kaderli S, Niklaus P, Zuberbuehler AD. Kinetics and thermodynamics of formation of copper-dioxygen adducts: oxygenation of mononuclear copper(I) complexes containing tripodal tetradentate ligands Journal of the American Chemical Society. 115: 9506-9514. DOI: 10.1021/Ja00074A015  0.56
1993 Nanthakumar A, Fox S, Murthy NN, Karlin KD, Ravi N, Huynh BH, Orosz RD, Day EP, Hagen KS, Blackburn NJ. Oxo- and hydroxo-bridged (porphyrin)iron(III)-copper(II) species as cytochrome c oxidase models: acid-base interconversions and x-ray structure of the Fe(III)-(O2-)-Cu(II) complex Journal of the American Chemical Society. 115: 8513-8514. DOI: 10.1021/Ja00071A097  0.559
1993 Tyeklár Z, Jacobson RR, Wei N, Murthy NN, Zubieta JA, Karlin KD. Reversible reaction of O2 (and CO) with a copper(I) complex. X-ray structures of relevant mononuclear Cu(I) precursor adducts and the trans-(μ-1,2-peroxo)dicopper(II) product Journal of the American Chemical Society. 115: 2677-2689. DOI: 10.1021/Ja00060A017  0.699
1993 Jiang F, Conry RR, Bubacco L, Tyeklar Z, Jacobson RR, Karlin KD, Peisach J. Crystal structure and electron spin echo envelope modulation study of [Cu(II)(TEPA)(NO2)]PF6 (TEPA = tris[2-(2-pyridyl)ethyl]amine): a model for the purported structure of the nitrite derivative of hemocyanin Journal of the American Chemical Society. 115: 2093-2102. DOI: 10.1021/Ja00059A001  0.718
1993 Sanyal I, Murthy NN, Karlin KD. A dicopper(I) complex and its oxygenation chemistry using a dinucleating ligand with a pendant alkene group Inorganic Chemistry. 32: 5330-5337. DOI: 10.1021/Ic00075A061  0.468
1993 Jiang F, Karlin KD, Peisach J. An electron spin echo envelope modulation (ESEEM) study of electron-nuclear hyperfine and nuclear quadrupole interactions of dz2 ground state copper(II) complexes with substituted imidazoles Inorganic Chemistry. 32: 2576-2582. DOI: 10.1021/Ic00063A060  0.386
1993 Mahroof-Tahir M, Karlin KD, Chen Q, Zubieta JA. Phosphate ester coordination to dicopper(II) compounds; X-ray structure of a bis(4-nitrophenyl)phosphato bridged dicopper(II) complex Inorganica Chimica Acta. 207: 135-138. DOI: 10.1016/S0020-1693(00)91467-1  0.55
1993 Sarwar Nasir M, Jacobson RR, Zubieta J, Karlin KD. Pyridine ligand donor substituent effects upon structure, redox properties and O2 reactivity of xylyl dinuclear copper(I) complexes Inorganica Chimica Acta. 203: 5-7. DOI: 10.1016/S0020-1693(00)82896-0  0.548
1993 Murthy NN, Mahroof-Tahir M, Karlin KD. Amide hydrolysis mediated by a dinuclear copper complex with terminal CuOH ligation Journal of Inorganic Biochemistry. 51: 506. DOI: 10.1016/0162-0134(93)85534-F  0.492
1993 Karlin KD, Gan Q, Nanthakumar A, Fox S, Ravi N, Huynh BH, Orosz RD, Day EP, Hagen KS, Blackburn NJ. Copper-O22 reactivity. Involvement of oxodicopper(II) in amine oxidations and reduction of O2 using porphyrin-iron(II) and copper(I) Journal of Inorganic Biochemistry. 51: 278. DOI: 10.1016/0162-0134(93)85310-5  0.554
1993 Nanthakumar A, Fox S, Hagen KS, Karlin KD. Modelling the binuclear site of cytochrome oxidase: Examples of μ-oxo and μ-hydroxo bridged ferric-cupric complexes Journal of Inorganic Biochemistry. 51: 270. DOI: 10.1016/0162-0134(93)85302-O  0.412
1992 Mahroof-Tahir M, Karlin KD. A dinuclear mixed-valence Cu(I)/Cu(II) complex and its reversible reactions with dioxygen: generation of a superoxodicopper(II) species Journal of the American Chemical Society. 114: 7599-7601. DOI: 10.1021/Ja00045A064  0.529
1992 Nanthakumar A, Nasir MS, Karlin KD, Ravi N, Hanh HB. A cytochrome c oxidase reactivity model: generation of a peroxo-bridged iron/copper dinuclear complex Journal of the American Chemical Society. 114: 6564-6566. DOI: 10.1021/Ja00042A050  0.448
1992 Nasir MS, Cohen BI, Karlin KD. Mechanism of aromatic hydroxylation in a copper monooxygenase model system. 1,2-methyl migrations and the NIH shift in copper chemistry Journal of the American Chemical Society. 114: 2482-2494. DOI: 10.1021/Ja00033A024  0.654
1992 Nasir MS, Karlin KD, Chen Q, Zubieta J. Copper(I) and copper(II) complexes of new chelating pterins Journal of the American Chemical Society. 114: 2264-2265. DOI: 10.1021/Ja00032A054  0.629
1992 Sanyal I, Mahroof-Tahir M, Nasir MS, Ghosh P, Cohen BI, Gultneh Y, Cruse RW, Farooq A, Karlin KD. Reactions of dioxygen (O2) with mononuclear copper(I) complexes: temperature-dependent formation of peroxo- or oxo- (and dihydroxo-) bridged dicopper(II) complexes Inorganic Chemistry. 31: 4322-4332. DOI: 10.1021/Ic00047A020  0.868
1992 Gultneh Y, Farooq A, Liu S, Karlin KD, Zubieta J. Synthesis, structure, and characterization of a phenolate-bridged dimanganese(II) complex of a dinucleating phenol ligand Inorganic Chemistry. 31: 3607-3611. DOI: 10.1021/Ic00043A022  0.737
1992 Mahroof-Tahir M, Murthy NN, Karlin KD, Blackburn NJ, Shaikh SN, Zubieta J. New thermally stable hydroperoxo- and peroxo-copper complexes Inorganic Chemistry. 31: 3001-3003. DOI: 10.1021/Ic00040A003  0.555
1992 Ling J, Farooq A, Karlin KD, Loehr TM, Sanders-Loehr J. Vibrational spectroscopic studies of a hydroxo-bridged dinuclear copper complex, a potential model for multicopper proteins Inorganic Chemistry. 31: 2552-2556. DOI: 10.1021/Ic00038A045  0.681
1992 Karlin KD, Tyeklar Z, Farooq A, Haka MS, Ghosh P, Cruse RW, Gultneh Y, Hayes JC, Toscano PJ, Zubieta J. Dioxygen-copper reactivity and functional modeling of hemocyanins. Reversible binding of O2 and carbon monoxide to dicopper(I) complexes [CuI2(L)]2+ (L = dinucleating ligand) and the structure of a bis(carbonyl) adduct, [CuI2(L)(CO)2]2+ Inorganic Chemistry. 31: 1436-1451. DOI: 10.1021/Ic00034A026  0.84
1992 Wei N, Tyeklár Z, Karlin KD. Dinuclear Cu(I) complexes containing two connected tripodal tetradentate subunits. Journal of Inorganic Biochemistry. 47: 61. DOI: 10.1016/0162-0134(92)84162-G  0.5
1992 Tyeklár Z, Wei N, Jacobson RR, Karlin KD. Structure, electrochemistry and reactivity of copper(I) complexes containing tripodal tetradentate ligands. Journal of Inorganic Biochemistry. 47: 60. DOI: 10.1016/0162-0134(92)84160-O  0.719
1992 Shin PK, Crans DC, Karlin KD, Tyeklar Z. Intramolecular exchange within tripodal pyridyl copper(I) complexes Journal of Inorganic Biochemistry. 47: 59. DOI: 10.1016/0162-0134(92)84155-G  0.501
1992 Nasir MS, Lee D, Karlin KD. Investigation of copper(I) and copper(II) complexes of new pterin chelates. Journal of Inorganic Biochemistry. 47: 55. DOI: 10.1016/0162-0134(92)84143-B  0.517
1992 Martens C, Gebbink R, Kenis P, Schenning A, Feiters M, Karlin K, Nolte R. Design and synthesis of model systems for oxygen binding and activation in dinuclear copper proteins. Journal of Inorganic Biochemistry. 47: 53. DOI: 10.1016/0162-0134(92)84138-D  0.452
1992 Mahroof-Tahir M, Karlin KD. Reaction of dioxygen with a mixed-valence copper(I)-copper(II) dinuclear complex Journal of Inorganic Biochemistry. 47: 52. DOI: 10.1016/0162-0134(92)84136-B  0.528
1992 Gan Q, Karlin KD. Dioxygen reactivity with new di- and trinuclear copper(I) complexes Journal of Inorganic Biochemistry. 47: 50. DOI: 10.1016/0162-0134(92)84128-A  0.493
1992 Conry RR, Paul PP, Karlin KD. Reactions of dinuclear copper complexes with nitrogen oxides Journal of Inorganic Biochemistry. 47: 48. DOI: 10.1016/0162-0134(92)84123-5  0.475
1992 Karlin KD, Nanthakumar A, Nasir MS. Reactivity models for cytochrome C oxidase: Synthesis and characterization of peroxo-bridged iron-copper bimetallic complexes Journal of Inorganic Biochemistry. 47: 16. DOI: 10.1016/0162-0134(92)84087-4  0.446
1991 Baldwin MJ, Ross PK, Pate JE, Tyeklar Z, Karlin KD, Solomon EI. Spectroscopic and theoretical studies of an end-on peroxide-bridged coupled binuclear copper(II) model complex of relevance to the active sites in hemocyanin and tyrosinase Journal of the American Chemical Society. 113: 8671-8679. DOI: 10.1021/Ja00023A014  0.468
1991 Paul PP, Karlin KD. Functional modeling of copper nitrite reductases: reactions of NO2- or nitric oxide with copper(I) complexes Journal of the American Chemical Society. 113: 6331-6332. DOI: 10.1021/Ja00016A093  0.475
1991 Karlin KD, Wei N, Jung B, Kaderli S, Zuberbuehler AD. Kinetic, thermodynamic, and spectral characterization of the primary copper-oxygen (Cu-O2) adduct in a reversibly formed and structurally characterized peroxo-dicopper(II) complex Journal of the American Chemical Society. 113: 5868-5870. DOI: 10.1021/Ja00015A054  0.6
1991 Paul PP, Tyeklar Z, Jacobson RR, Karlin KD. Reactivity patterns and comparisons in three classes of synthetic copper-dioxygen {Cu2-O2} complexes: implication for structure and biological relevance Journal of the American Chemical Society. 113: 5322-5332. DOI: 10.1021/Ja00014A027  0.782
1991 Sanyal I, Strange RW, Blackburn NJ, Karlin KD. Formation of a Copper-Dioxygen Complex (cu2-o2) Using Simple Imidazole Ligands Journal of the American Chemical Society. 113: 4692-4693. DOI: 10.1021/Ja00012A054  0.601
1991 Nasir MS, Karlin KD, McGowty D, Zubieta J. Unsymmetrical dicopper complexes. Direct observation of reversible O2 binding in a copper monooxygenase model system Journal of the American Chemical Society. 113: 698-700. DOI: 10.1021/Ja00002A062  0.523
1991 Jacobson RR, Tyeklar Z, Karlin KD, Zubieta J. Fluoride as a terminal and bridging ligand for copper: isolation and x-ray crystallographic characterization of copper monomeric and dimeric complexes [CuII(TMPA)F]nn+ (n = 1 or 2; TMPA = tris[(2-pyridyl)methyl]amine) Inorganic Chemistry. 30: 2035-2040. DOI: 10.1021/Ic00009A017  0.79
1991 Tyeklár Z, Karlin KD. Biomimetic Binding and Activation of Dioxygen with Copper Complexes Studies in Surface Science and Catalysis. 66: 237-248. DOI: 10.1016/S0167-2991(08)62839-6  0.616
1991 Jacobson RR, Tyeklár Z, Karlin KD. Reaction of organic halides with [CuI(TMPA)CH3CN]PF6 Inorganica Chimica Acta. 181: 111-118. DOI: 10.1016/S0020-1693(00)85268-8  0.539
1991 Karlin KD, Tyeklár Z, Farooq A, Jacobson RR, Sinn E, Lee DW, Bradshaw JE, Wilson LJ. Peroxide (O22-) as a bridging ligand for copper(II): strong exchange coupling in complexes derived from copper(I) and dioxygen Inorganica Chimica Acta. 182: 1-3. DOI: 10.1016/S0020-1693(00)85178-6  0.723
1991 Karlin KD. Copper-dioxygen (Cu2O2) complexes: Synthesis, structure and biological relevance Journal of Inorganic Biochemistry. 43: 169. DOI: 10.1016/0162-0134(91)84161-2  0.456
1990 Paul PP, Tyeklar Z, Farooq A, Karlin KD, Liu S, Zubieta J. Isolation and x-ray structure of a dinuclear copper-nitrosyl complex Journal of the American Chemical Society. 112: 2430-2432. DOI: 10.1021/Ja00162A060  0.66
1990 Karlin KD, Gan QF, Farooq A, Liu S, Zubieta J. A trinuclear copper(I) complex: reaction with dioxygen and the formation of a hexanuclear copper(II) cluster Inorganic Chemistry. 29: 2549-2551. DOI: 10.1021/Ic00339A001  0.707
1990 Nasir MS, Cohen BI, Karlin KD. Oxidative dehalogenation during a copper complex mediated hydroxylation reaction Inorganica Chimica Acta. 176: 185-187. DOI: 10.1016/S0020-1693(00)84843-4  0.82
1990 Karlin KD, Sanyal I, Farooq A, Jacobson RR, Shaikh SN, Zubieta J. Model for the possible 'endogenous' bridge in oxy-hemocyanin: a di-μ-(OR)2-bridged dicopper(II) complex (R = H, alkyl) with low-energy charge-transfer absorption Inorganica Chimica Acta. 174: 13-15. DOI: 10.1016/S0020-1693(00)80271-6  0.656
1989 Pate JE, Ross PK, Thamann TJ, Reed CA, Karlin KD, Sorrell TN, Solomon EI. Spectroscopic studies of the charge transfer and vibrational features of binuclear copper(II) azide complexes: comparison to the coupled binuclear copper active site in met azide hemocyanin and tyrosinase Journal of the American Chemical Society. 111: 5198-5209. DOI: 10.1021/Ja00196A029  0.448
1989 Blackburn NJ, Strange RW, Reedijk J, Volbeda A, Farooq A, Karlin KD, Zubieta J. X-ray absorption edge spectroscopy of copper(I) complexes. Coordination geometry of copper(I) in the reduced forms of copper proteins and their derivatives with carbon monoxide Inorganic Chemistry. 28: 1349-1357. DOI: 10.1021/Ic00306A027  0.691
1989 Tyeklar Z, Karlin KD. Copper-dioxygen chemistry: a bioinorganic challenge Accounts of Chemical Research. 22: 241-248. DOI: 10.1021/Ar00163A003  0.444
1989 Karlin KD, Qingfen G, Farooq A, Shuncheng L, Zubieta J. Synthesis and X-ray crystal structure of a trinuclear copper(I) cluster Inorganica Chimica Acta. 165: 37-39. DOI: 10.1016/S0020-1693(00)83397-6  0.65
1988 Cruse RW, Kaderli S, Karlin KD, Zuberbuehler AD. Kinetic and thermodynamic studies on the reaction of oxygen with two dinuclear copper(I) complexes Journal of the American Chemical Society. 110: 6882-6883. DOI: 10.1021/Ja00228A046  0.76
1988 Karlin KD, Ghosh P, Cruse RW, Farooq A, Gultneh Y, Jacobson RR, Blackburn NJ, Strange RW, Zubieta J. Dioxygen-copper reactivity: generation, characterization, and reactivity of a hydroperoxodicopper(II) complex Journal of the American Chemical Society. 110: 6769-6780. DOI: 10.1021/Ja00228A027  0.873
1988 Cruse RW, Kaderli S, Meyer CJ, Zuberbuehler AD, Karlin KD. Copper-mediated hydroxylation of an arene: kinetics and mechanism of the reaction of a dicopper(II) m-xylyl-containing complex with H2O2 to yield a phenoxodicopper(II) complex Journal of the American Chemical Society. 110: 5020-5024. DOI: 10.1021/Ja00223A020  0.809
1988 Blackburn NJ, Strange RW, Farooq A, Haka MS, Karlin KD. X-ray absorption studies of three-coordinate dicopper(I) complexes and their dioxygen adducts Journal of the American Chemical Society. 110: 4263-4272. DOI: 10.1021/Ja00221A027  0.78
1988 Karlin KD, I. Cohen B, Farooq A, Liu S, Zubieta J. Copper mediated hydroxylation of a modified monooxygenase model system Inorganica Chimica Acta. 153: 9-11. DOI: 10.1016/S0020-1693(00)83349-6  0.665
1987 Karlin KD, Cruse RW, Gultneh Y. Dioxygen-copper reactivity: A hydroperoxo-dicopper(II) complex Journal of the Chemical Society, Chemical Communications. 599-600. DOI: 10.1039/C39870000599  0.781
1987 Ghosh P, Tyeklar Z, Karlin KD, Jacobson RR, Zubieta J. Dioxygen-copper reactivity: x-ray structure and characterization of an (acylperoxo)dicopper complex Journal of the American Chemical Society. 109: 6889-6891. DOI: 10.1021/Ja00256A073  0.723
1987 Karlin KD, Cohen BI, Jacobson RR, Zubieta J. Dioxygen—Copper Reactivity: Hydroxylation-induced Methyl Migration in a Copper Monooxygenase Model System Journal of the American Chemical Society. 109: 6194-6196. DOI: 10.1021/Ja00254A055  0.698
1987 Pate JE, Cruse RW, Karlin KD, Solomon EI. Vibrational, electronic, and resonance Raman spectral studies of [Cu2(YXL-O-)O2]+, a copper(II) peroxide model complex of oxyhemocyanin Journal of the American Chemical Society. 109: 2624-2630. DOI: 10.1021/Ja00243A013  0.809
1987 Blackburn NJ, Strange RW, Cruse RW, Karlin KD. Dioxygen-copper reactivity: EXAFS studies of a peroxo-dicopper(II) complex Journal of the American Chemical Society. 109: 1235-1237. DOI: 10.1021/Ja00238A037  0.795
1987 Karlin KD, Farooq A, Hayes JC, Cohen BI, Rowe TM, Sinn E, Zubieta J. Models for met-hemocyanin derivatives: structural and spectroscopic comparisons of analogous phenolate and X (X = OH-, OMe-, N3-, Cl-, OAc-, OBz-) doubly bridged dinuclear copper(II) complexes Inorganic Chemistry. 26: 1271-1280. DOI: 10.1021/Ic00255A017  0.819
1987 Karlin KD, Cohen BI, Hayes JC, Farooq A, Zubieta J. Models for methemocyanin derivatives: Structural and spectroscopic comparisons of related azido-coordinated (N3 -) mono- and dinuclear copper(II) complexes Inorganic Chemistry. 26: 147-153. DOI: 10.1021/Ic00248A029  0.782
1987 Garcia MC, Karlin KD, Holwerda RA. Oxidation of (hydroxyethyl)ferrocene by [2-pyridylmethylbis(2-ethylthioethyl)/amine]copper(II) Journal of Inorganic Biochemistry. 30: 167-175. DOI: 10.1016/0162-0134(87)80061-2  0.516
1986 Baek HK, Karlin KD, Holwerda RA. Kinetic stability of the cysteine adduct with [tris(2-(2-pyridyl)ethyl)amine]copper(II) Inorganic Chemistry. 25: 2347-2349. DOI: 10.1021/Ic00234A014  0.525
1986 Baek HK, Karlin KD, Holwerda RA. Kinetic Stability of the Cysteine Adduct with [Tris(2-(2-pyridyl)ethyl)amine]copper(II). Cheminform. 17. DOI: 10.1002/Chin.198647327  0.47
1985 Karlin KD, Haka MS, Cruse RW, Gultneh Y. Dioxygen-copper reactivity. Reversible oxygen and carbon monoxide binding by a new series of binuclear copper(I) complexes Journal of the American Chemical Society. 107: 5828-5829. DOI: 10.1021/Ja00306A055  0.854
1985 Karlin KD, Cohen BI. Synthesis and characterization of copper(II) complexes of a tetradentate N3O ligand: Mononuclear analogs for phenolate-bridged dinuclear complexes Inorganica Chimica Acta. 107: L17-L20. DOI: 10.1016/S0020-1693(00)82277-X  0.694
1984 Blackburn NJ, Karlin KD, Concannon M, Hayes JC, Gultneh Y, Zubieta J. Studies on a model copper mono-oxygenase system: Peroxo-Cuii binuclear intermediates in the hydroxylation of an aromatic ring Journal of the Chemical Society - Series Chemical Communications. 939-940. DOI: 10.1039/C39840000939  0.722
1984 Karlin KD, Hayes JC, Gultneh Y, Cruse RW, McKown JW, Hutchinson JP, Zubieta J. Copper-mediated hydroxylation of an arene ― model system for the action of copper monooxygenases: structures of a binuclear Cu(I) complex and its oxygenated product Journal of the American Chemical Society. 106: 2121-2128. DOI: 10.1021/Ja00319A036  0.845
1984 Karlin KD, McKown JW, Hayes JC, Hutchinson JP, Zubieta J. Synthesis and structure of a mono-chloro bridged copper(II) dimer containing a linear CuII-Cl-CuII bridge Transition Metal Chemistry. 9: 405-406. DOI: 10.1007/Bf00637031  0.72
1984 Karlin KD, Cruse RW, McKown JW, Hayes JC, Dahlstrom PL, Zubieta J. Structure and properties of a monomeric copper(II) complex with a N3 tridentate unit containing 2-thio-1-methylimidazole Transition Metal Chemistry. 9: 404-405. DOI: 10.1007/Bf00637030  0.842
1983 Karlin KD, Hayes JC, Hutchinson JP, Zubieta J. Synthesis and characterization of a novel dicopper(I) complex of a thiaether containing meta-xylyl binucleating ligand Inorganica Chimica Acta. 78. DOI: 10.1016/S0020-1693(00)86473-7  0.689
1982 Karlin KD, Hayes JC, Juen S, Hutchinson JP, Zubieta J. Tetragonal vs. trigonal coordination in copper(II) complexes with tripod ligands: structures and properties of [Cu(C21H24N4)Cl]PF6 and [Cu(C18H18N4)Cl]PF6 Inorganic Chemistry. 21: 4106-4108. DOI: 10.1021/Ic00141A049  0.769
1982 Karlin KD, Hayes JC, Hutchinson JP, Hyde JR, Zubieta J. Synthesis and x-ray structural characterization of Cu(I) and Cu(II) derivatives of a new symmetric tripodal ligand N(CH2CH2-py)3, (py = 2-pyridyl) Inorganica Chimica Acta. 64: L219-L220. DOI: 10.1016/S0020-1693(00)90334-7  0.743
1982 Karlin KD, Cruse RM, Kokoska GF, Orsini JJ. ESR spectra of new dicopper(II) complexes of novel binucleating ligands Inorganica Chimica Acta. 66. DOI: 10.1016/S0020-1693(00)85774-6  0.442
1981 Karlin KD, Dahlstrom PL, Dipierro LT, Simon RA, Zubieta J. X-ray Structure Analysis of a Dicopper Complex of a New Binucleating Ligand Containing a para-Xylyl Connecting Group; Large Cu…Cu Separation in [(CuCl2C18H20N3)2]·2H2O Journal of Coordination Chemistry. 11: 61-63. DOI: 10.1080/00958978108080668  0.597
1981 Karlin KD, Dahlstrom PL, Cozzette SN, Scensny PM, Zubieta JA. Activation of O2 by a binuclear copper(I) compound. Hydroxylation of a new xylyl-binucleating ligand to produce a phenoxy-bridged binuclear copper(II) complex; X-ray crystal structure of [Cu2{OC6H3[CH2N(CH2CH2py)2]2-2,6}(OMe)](py = 2-pyridyl) Journal of the Chemical Society, Chemical Communications. 881-882. DOI: 10.1039/C39810000881  0.641
1980 Karlin KD, Dahlstrom PL, Hyde JR, Zubieta J. Structural comparison of CuI and CuII complexes displaying analogous N2S2 co-ordination; x-ray analyses of tetraco-ordinate [Cu(pma)]BPh4 and pentaco-ordinate [Cu(pma)SO 4] [pma = 2-pyridylmethylbis-(2-ethylthioethyl)amine] Journal of the Chemical Society, Chemical Communications. 906-908. DOI: 10.1039/C39800000906  0.623
1980 Baltusis LM, Karlin KD, Rabinowitz HN, Dewan JC, Lippard SJ. Synthesis and structure of Fe(L'H)(NO)2, a tetracoordinate complex having a twelve-membered chelate ring, and its conversion to pentacoordinate FeL'(NO) through formal loss of "HNO" (L' = SCH2CH2NMeCH2CH2CH2NMeCH2CH2S-) Inorganic Chemistry. 19: 2627-2632. DOI: 10.1021/Ic50211A030  0.57
1979 Karlin KD, Dahlstrom PL, Stanford ML, Zubieta J. Distorted tetrahedral complexes of copper(I) and copper(II) displaying N2S2 co-ordination. X-Ray crystal structure of [2-(2-pyridyl)ethyl]bis[2-(ethylthio)ethyl]aminecopper(I) tetraphenylborate Journal of the Chemical Society, Chemical Communications. 465-467. DOI: 10.1039/C39790000465  0.631
1977 Ginsberg A, Lines M, Karlin K, Lippard S, DiSalvo F. Additions and Corrections - Orbitally Dependent Exchange in Two Sulfur-Bridged Binuclear Iron(II) Complexes. Magnetic Exchange in Transition Metal Complexes. Journal of the American Chemical Society. 99: 1289-1289. DOI: 10.1021/Ja00446A605  0.602
1977 Karlin KD, Rabinowitz HN, Lewis DL, Lippard SJ. Synthesis and characterization of the pentacoordinate mononitrosyliron complexes Fe(NO)[SCH2CH2N(CH3)(CH2)nN(CH3)CH2CH2S], n = 2,3 Inorganic Chemistry. 16: 3262-3267. DOI: 10.1021/Ic50178A055  0.514
Low-probability matches (unlikely to be authored by this person)
2010 Himes RA, Barnese K, Karlin KD. One is lonely and three is a crowd: two coppers are for methane oxidation. Angewandte Chemie (International Ed. in English). 49: 6714-6. PMID 20672276 DOI: 10.1002/Anie.201003403  0.285
2010 Himes RA, Barnese K, Karlin KD. One is lonely and three is a crowd: two coppers are for methane oxidation. Angewandte Chemie (International Ed. in English). 49: 6714-6. PMID 20672276 DOI: 10.1002/Anie.201003403  0.285
2010 Himes R, Barnese K, Karlin K. Eins ist zu wenig, drei sind zuviel: Oxidation von Methan an Dikupferzentren Angewandte Chemie. 122: 6864-6866. DOI: 10.1002/Ange.201003403  0.278
1993 Karlin KD. Metalloenzymes, structural motifs, and inorganic models. Science (New York, N.Y.). 261: 701-8. PMID 7688141 DOI: 10.1126/Science.7688141  0.266
2008 George SD, Karlin KD. Protagonists in Chemistry Inorganica Chimica Acta. 361: 807-808. DOI: 10.1016/J.Ica.2007.09.001  0.259
2011 Karlin KD, Itoh S. Copper-Oxygen Chemistry Copper-Oxygen Chemistry. DOI: 10.1002/9781118094365  0.256
2010 Karlin KD. Bioinorganic chemistry: Redox control of oxoiron(IV). Nature Chemistry. 2: 711-2. PMID 20729888 DOI: 10.1038/Nchem.813  0.231
2010 Karlin KD. Bioinorganic chemistry: Redox control of oxoiron(IV). Nature Chemistry. 2: 711-2. PMID 20729888 DOI: 10.1038/Nchem.813  0.231
2004 Wick PK, Karlin KD, Suzuki M, Zuberbühler AD. Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+. Micron (Oxford, England : 1993). 35: 137-9. PMID 15036318 DOI: 10.1016/J.Micron.2003.10.044  0.211
2004 Wick PK, Karlin KD, Suzuki M, Zuberbühler AD. Dicopper peroxo complexes: low temperature stopped-flow reaction kinetics of [(BQPA)CuI]+ and [(Me2-TMPA)CuI]+. Micron (Oxford, England : 1993). 35: 137-9. PMID 15036318 DOI: 10.1016/J.Micron.2003.10.044  0.211
2022 Karlin KD, Hota PK, Kim B. Concluding remarks: discussion on natural and artificial enzymes including synthetic models. Faraday Discussions. PMID 35507381 DOI: 10.1039/d2fd00073c  0.195
2007 Wang J, Puiu SC, Karlin KD. Modeling NO reduction activity of nitric oxide reductase and cytochrome c oxidase Acs National Meeting Book of Abstracts.  0.158
2012 Fukuzumi S, Yamada Y, Karlin KD. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. Electrochimica Acta. 82: 493-511. PMID 23457415 DOI: 10.1016/J.Electacta.2012.03.132  0.152
2012 Fukuzumi S, Yamada Y, Karlin KD. Hydrogen Peroxide as a Sustainable Energy Carrier: Electrocatalytic Production of Hydrogen Peroxide and the Fuel Cell. Electrochimica Acta. 82: 493-511. PMID 23457415 DOI: 10.1016/J.Electacta.2012.03.132  0.152
2010 Karlin KD. Bioinorganic chemistry: Model offers intermediate insight. Nature. 463: 168-9. PMID 20075910 DOI: 10.1038/463168A  0.139
2010 Karlin KD. Bioinorganic chemistry: Model offers intermediate insight. Nature. 463: 168-9. PMID 20075910 DOI: 10.1038/463168A  0.139
2004 Lee DH, Lucchese B, Karlin KD. Multimetal Oxidases Comprehensive Coordination Chemistry Ii. 8: 437-457. DOI: 10.1016/B0-08-043748-6/08143-3  0.129
2011 Halime Z, Karlin KD. Cytochrome c Oxidase and Models Copper-Oxygen Chemistry. 283-319. DOI: 10.1002/9781118094365.ch9  0.089
2000 Karlin KD. Inorganica Chimica Acta: Preface Inorganica Chimica Acta. 297: xvii-xx. DOI: 10.1016/S0020-1693(99)00414-4  0.066
2014 Karlin KD. Progress in Inorganic Chemistry Progress in Inorganic Chemistry. 59: 1-583. DOI: 10.1002/9781118869994  0.062
Hide low-probability matches.