| Year |
Citation |
Score |
| 2017 |
Sanzone JR, Hu CT, Woerpel KA. Uncatalyzed Carboboration of Seven-Membered-Ring trans-Alkenes: Formation of Air-Stable Trialkylboranes. Journal of the American Chemical Society. PMID 28565903 DOI: 10.1021/jacs.7b03986 |
0.48 |
|
| 2016 |
Beaver MG, Buscagan TM, Lavinda O, Woerpel KA. Stereoelectronic Model To Explain Highly Stereoselective Reactions of Seven-Membered-Ring Oxocarbenium-Ion Intermediates. Angewandte Chemie (International Ed. in English). 55: 1816-9. PMID 26791884 DOI: 10.1002/anie.201507806 |
1 |
|
| 2015 |
Sanzone JR, Woerpel KA. High Reactivity of Strained Seven-Membered-Ring trans-Alkenes. Angewandte Chemie (International Ed. in English). PMID 26611657 DOI: 10.1002/anie.201510056 |
1 |
|
| 2015 |
Garcia A, Sanzone JR, Woerpel KA. Participation of Alkoxy Groups in Reactions of Acetals: Violation of the Reactivity/Selectivity Principle in a Curtin-Hammett Kinetic Scenario. Angewandte Chemie (International Ed. in English). 54: 12087-90. PMID 26290402 DOI: 10.1002/anie.201503525 |
1 |
|
| 2015 |
Otte DA, Woerpel KA. Evidence that Additions of Grignard Reagents to Aliphatic Aldehydes Do Not Involve Single-Electron-Transfer Processes. Organic Letters. 17: 3906-9. PMID 26214553 DOI: 10.1021/acs.orglett.5b01893 |
1 |
|
| 2015 |
Hilf JA, Witthoft LW, Woerpel KA. An SN1-type Reaction To Form the 1,2-Dioxepane Ring: Synthesis of 10,12-Peroxycalamenene. The Journal of Organic Chemistry. 80: 8262-7. PMID 26158427 DOI: 10.1021/acs.joc.5b01326 |
1 |
|
| 2015 |
Andia AA, Miner MR, Woerpel KA. Copper(I)-Catalyzed Oxidation of Alkenes Using Molecular Oxygen and Hydroxylamines: Synthesis and Reactivity of α-Oxygenated Ketones. Organic Letters. 17: 2704-7. PMID 25954981 DOI: 10.1021/acs.orglett.5b01120 |
1 |
|
| 2015 |
Garcia A, Otte DA, Salamant WA, Sanzone JR, Woerpel KA. Influence of alkoxy groups on rates of acetal hydrolysis and tosylate solvolysis: electrostatic stabilization of developing oxocarbenium ion intermediates and neighboring-group participation to form oxonium ions. The Journal of Organic Chemistry. 80: 4470-80. PMID 25806832 DOI: 10.1021/acs.joc.5b00338 |
1 |
|
| 2015 |
Hurlocker B, Hu C, Woerpel KA. Structure and reactivity of an isolable seven-membered-ring trans-alkene. Angewandte Chemie (International Ed. in English). 54: 4295-8. PMID 25656271 DOI: 10.1002/anie.201410752 |
1 |
|
| 2015 |
Garcia A, Otte DA, Salamant WA, Sanzone JR, Woerpel KA. Acceleration of acetal hydrolysis by remote alkoxy groups: evidence for electrostatic effects on the formation of oxocarbenium ions. Angewandte Chemie (International Ed. in English). 54: 3061-4. PMID 25614209 DOI: 10.1002/anie.201410043 |
1 |
|
| 2015 |
Chung A, Miner MR, Richert KJ, Rieder CJ, Woerpel KA. Formation of an Endoperoxide upon Chromium-Catalyzed Allylic Oxidation of a Triterpene by Oxygen. The Journal of Organic Chemistry. 80: 266-73. PMID 25393044 DOI: 10.1021/jo502344x |
1 |
|
| 2014 |
Lavinda O, Tran VT, Woerpel KA. Effect of conformational rigidity on the stereoselectivity of nucleophilic additions to five-membered ring bicyclic oxocarbenium ion intermediates. Organic & Biomolecular Chemistry. 12: 7083-91. PMID 25087588 DOI: 10.1039/c4ob01251h |
1 |
|
| 2014 |
Hurlocker B, Miner MR, Woerpel KA. Synthesis of silyl monoperoxyketals by regioselective cobalt-catalyzed peroxidation of silyl enol ethers: application to the synthesis of 1,2-dioxolanes. Organic Letters. 16: 4280-3. PMID 25084342 DOI: 10.1021/ol5020015 |
1 |
|
| 2014 |
Kendale JC, Valentín EM, Woerpel KA. Solvent effects in the nucleophilic substitutions of tetrahydropyran acetals promoted by trimethylsilyl trifluoromethanesulfonate: trichloroethylene as solvent for stereoselective C- and O-glycosylations. Organic Letters. 16: 3684-7. PMID 24991982 DOI: 10.1021/ol501471c |
1 |
|
| 2014 |
Kandur WV, Richert KJ, Rieder CJ, Thomas AM, Hu C, Ziller JW, Woerpel KA. Synthesis and reactivity of 1,2-dioxolanes from β,γ-epoxy ketones. Organic Letters. 16: 2650-3. PMID 24779430 DOI: 10.1021/ol500835f |
1 |
|
| 2014 |
Otte DA, Borchmann DE, Lin C, Weck M, Woerpel KA. 13C NMR spectroscopy for the quantitative determination of compound ratios and polymer end groups. Organic Letters. 16: 1566-9. PMID 24601654 DOI: 10.1021/ol403776k |
1 |
|
| 2013 |
Rotsides CZ, Hu C, Woerpel KA. Diastereoselective synthesis of eight-membered-ring allenes from propargylic epoxides and aldehydes by silylene insertion into carbon-oxygen bonds. Angewandte Chemie (International Ed. in English). 52: 13033-6. PMID 24123797 DOI: 10.1002/anie.201306093 |
1 |
|
| 2013 |
Tran VT, Woerpel KA. Nucleophilic addition to silyl-protected five-membered ring oxocarbenium ions governed by stereoelectronic effects. The Journal of Organic Chemistry. 78: 6609-21. PMID 23738497 DOI: 10.1021/jo400945j |
1 |
|
| 2012 |
Greene MA, Prévost M, Tolopilo J, Woerpel KA. Diastereoselective synthesis of seven-membered-ring trans-alkenes from dienes and aldehydes by silylene transfer. Journal of the American Chemical Society. 134: 12482-4. PMID 22780578 DOI: 10.1021/ja305713v |
1 |
|
| 2012 |
Ventocilla CC, Woerpel KA. Synthesis of silyloxy dienes by silylene transfer to divinyl ketones: application to the asymmetric synthesis of substituted cyclohexanes. The Journal of Organic Chemistry. 77: 3277-83. PMID 22372733 DOI: 10.1021/jo202650k |
1 |
|
| 2011 |
Dibble DJ, Ziller JW, Woerpel KA. Spectroscopic and X-ray crystallographic evidence for electrostatic effects in 4-substituted cyclohexanone-derived hydrazones, imines, and corresponding salts. The Journal of Organic Chemistry. 76: 7706-19. PMID 21806053 DOI: 10.1021/jo200950s |
0.68 |
|
| 2011 |
Ventocilla CC, Woerpel KA. Silylene-mediated polarity reversal of dienoates: additions of dienoates to aldehydes at the δ-position to form trans-dioxasilacyclononenes. Journal of the American Chemical Society. 133: 406-8. PMID 21166421 DOI: 10.1021/ja109631z |
1 |
|
| 2010 |
Ager BJ, Bourque LE, Buchner KM, Woerpel KA. Silylene transfer to allylic sulfides: formation of substituted silacyclobutanes. The Journal of Organic Chemistry. 75: 5729-32. PMID 20704444 DOI: 10.1021/jo1008228 |
1 |
|
| 2010 |
Prévost M, Ziller JW, Woerpel KA. Strained organosilacyclic compounds: synthesis of anti-Bredt olefins and trans-dioxasilacyclooctenes. Dalton Transactions (Cambridge, England : 2003). 39: 9275-81. PMID 20614083 DOI: 10.1039/c003227a |
1 |
|
| 2010 |
Harris JR, Haynes MT, Thomas AM, Woerpel KA. Phosphine-catalyzed reductions of alkyl silyl peroxides by titanium hydride reducing agents: development of the method and mechanistic investigations. The Journal of Organic Chemistry. 75: 5083-91. PMID 20604518 DOI: 10.1021/jo1008367 |
1 |
|
| 2010 |
Buchner KM, Woerpel KA. Palladium- and Nickel-Catalyzed Carbon-Carbon Bond Insertion Reactions with Alkylidenesilacyclopropanes. Organometallics. 29: 1661-1669. PMID 20419110 DOI: 10.1021/om901042j |
1 |
|
| 2010 |
Beaver MG, Woerpel KA. Erosion of stereochemical control with increasing nucleophilicity: O-glycosylation at the diffusion limit. The Journal of Organic Chemistry. 75: 1107-18. PMID 20108907 DOI: 10.1021/jo902222a |
1 |
|
| 2009 |
Bourque LE, Haile PA, Loy JM, Woerpel KA. Silylene oxonium ylides: di-tert-butylsilylene insertion into C-O bonds. Tetrahedron. 65: 5608-5613. PMID 20631913 DOI: 10.1016/j.tet.2009.04.016 |
1 |
|
| 2009 |
Howard BE, Woerpel KA. Silylene transfer to alpha-keto esters and application to the synthesis of gamma-lactones. Tetrahedron. 65: 6447-6453. PMID 20625460 DOI: 10.1016/j.tet.2009.05.066 |
1 |
|
| 2009 |
Krumper JR, Salamant WA, Woerpel KA. Correlations between nucleophilicities and selectivities in the substitutions of tetrahydropyran acetals. The Journal of Organic Chemistry. 74: 8039-50. PMID 19813702 DOI: 10.1021/jo901639b |
1 |
|
| 2009 |
Prévost M, Woerpel KA. Insertions of silylenes into vinyl epoxides: diastereoselective synthesis of functionalized, optically active trans-dioxasilacyclooctenes. Journal of the American Chemical Society. 131: 14182-3. PMID 19769355 DOI: 10.1021/ja906204a |
1 |
|
| 2009 |
Bourque LE, Haile PA, Woerpel KA. Silylene-mediated ring contraction of homoallylic ethers to form allylic silanes. The Journal of Organic Chemistry. 74: 7180-2. PMID 19681592 DOI: 10.1021/jo901111j |
1 |
|
| 2009 |
Leonard NM, Woerpel KA. Formation of medium-sized nitrogen heterocycles from gamma-silyloxy-gamma-lactams. The Journal of Organic Chemistry. 74: 6915-23. PMID 19678646 DOI: 10.1021/jo900869k |
1 |
|
| 2009 |
Harris JR, Waetzig SR, Woerpel KA. Palladium(II)-catalyzed cyclization of unsaturated hydroperoxides for the synthesis of 1,2-dioxanes. Organic Letters. 11: 3290-3. PMID 19555089 DOI: 10.1021/ol901046z |
1 |
|
| 2009 |
Buchner KM, Clark TB, Loy JM, Nguyen TX, Woerpel KA. Alkylidenesilacyclopropanes derived from allenes: applications to the selective synthesis of triols and homoallylic alcohols. Organic Letters. 11: 2173-5. PMID 19382782 DOI: 10.1021/ol900456v |
1 |
|
| 2009 |
Ramirez AP, Thomas AM, Woerpel KA. Preparation of bicyclic 1,2,4-trioxanes from gamma,delta-unsaturated ketones. Organic Letters. 11: 507-10. PMID 19132925 DOI: 10.1021/ol8022853 |
1 |
|
| 2009 |
Yang MT, Woerpel KA. The effect of electrostatic interactions on conformational equilibria of multiply substituted tetrahydropyran oxocarbenium ions. The Journal of Organic Chemistry. 74: 545-53. PMID 19072093 DOI: 10.1021/jo8017846 |
1 |
|
| 2009 |
Anderson LL, Woerpel KA. Formation and utility of azasilacyclopentadienes derived from silacyclopropenes and nitriles. Organic Letters. 11: 425-8. PMID 19072064 DOI: 10.1021/ol802412b |
1 |
|
| 2008 |
Martyn DC, Ramirez AP, Beattie MJ, Cortese JF, Patel V, Rush MA, Woerpel KA, Clardy J. Synthesis of spiro-1,2-dioxolanes and their activity against Plasmodium falciparum. Bioorganic & Medicinal Chemistry Letters. 18: 6521-4. PMID 18993067 DOI: 10.1016/j.bmcl.2008.10.083 |
1 |
|
| 2008 |
Bourque LE, Woerpel KA. Intermolecular silacarbonyl ylide cycloadditions: a direct pathway to oxasilacyclopentenes. Organic Letters. 10: 5257-60. PMID 18922005 DOI: 10.1021/ol8018538 |
1 |
|
| 2008 |
Krumper JR, Salamant WA, Woerpel KA. Continuum of mechanisms for nucleophilic substitutions of cyclic acetals. Organic Letters. 10: 4907-10. PMID 18844363 DOI: 10.1021/ol8019956 |
1 |
|
| 2008 |
Nevárez Z, Woerpel KA. Dearomatization reactions of aryl-substituted silaaziridines. The Journal of Organic Chemistry. 73: 8113-5. PMID 18763839 DOI: 10.1021/jo801502x |
1 |
|
| 2008 |
Beaver MG, Billings SB, Woerpel KA. C-glycosylation reactions of sulfur-substituted glycosyl donors: evidence against the role of neighboring-group participation. Journal of the American Chemical Society. 130: 2082-6. PMID 18215038 DOI: 10.1021/ja0767783 |
1 |
|
| 2008 |
Beaver MG, Billings SB, Woerpel KA. Nucleophilic substitution reactions of 2-phenylthio-substituted carbohydrate acetals and related systems: Episulfonium ions vs. oxocarbenium ions as reactive intermediates European Journal of Organic Chemistry. 771-781. DOI: 10.1002/ejoc.200700911 |
1 |
|
| 2008 |
Evans DA, Woerpel KA, Nosse B, Schall A, Shinde Y, Jezek E, Haque MM, Chhor RB, Reiser O. Synthesis of (-)-(S,S)- bis(4-isopropyloxazoline) (Organic Syntheses) Organic Syntheses. 85: 307. |
1 |
|
| 2008 |
Evans DA, Woerpel KA, Nosse B, Schall A, Shinde Y, Jezek E, Haque MM, Chhor RB, Reiser O. Synthesis of (-)-(S,S)- bis(4-isopropyloxazoline) (Organic Syntheses) Organic Syntheses. 85: 307. |
1 |
|
| 2007 |
Howard BE, Woerpel KA. Synthesis of tertiary alpha-hydroxy acids by silylene transfer to alpha-keto esters. Organic Letters. 9: 4651-3. PMID 17910469 DOI: 10.1021/ol702148x |
1 |
|
| 2007 |
Bourque LE, Cleary PA, Woerpel KA. Metal-catalyzed silylene insertions of allylic ethers: stereoselective formation of chiral allylic silanes. Journal of the American Chemical Society. 129: 12602-3. PMID 17900189 DOI: 10.1021/ja073758s |
1 |
|
| 2007 |
Nevárez Z, Woerpel KA. Metal-catalyzed silylene transfer to imines: synthesis and reactivity of silaaziridines. Organic Letters. 9: 3773-6. PMID 17713917 DOI: 10.1021/ol701424a |
1 |
|
| 2007 |
Kim AI, Kimmel KL, Romero A, Smitrovich JH, Woerpel KA. Mechanistic studies of the allylic rearrangements of alpha-silyloxy allylic silanes to silyloxy vinylic silanes. The Journal of Organic Chemistry. 72: 6595-8. PMID 17645354 DOI: 10.1021/jo070634p |
1 |
|
| 2007 |
Driver TG, Harris JR, Woerpel KA. Kinetic resolution of hydroperoxides with enantiopure phosphines: preparation of enantioenriched tertiary hydroperoxides. Journal of the American Chemical Society. 129: 3836-7. PMID 17358067 DOI: 10.1021/ja070482f |
1 |
|
| 2007 |
Calad SA, Woerpel KA. Formation of chiral quaternary carbon stereocenters using silylene transfer reactions: enantioselective synthesis of (+)-5-epi-acetomycin. Organic Letters. 9: 1037-40. PMID 17305349 DOI: 10.1021/ol063072p |
1 |
|
| 2007 |
Calad SA, Cirakovi? J, Woerpel KA. Synthesis of (+/-)-epi-stegobinone utilizing silacyclopropanes as synthetic intermediates. The Journal of Organic Chemistry. 72: 1027-30. PMID 17253829 DOI: 10.1021/jo0620011 |
1 |
|
| 2006 |
Baghdasarian G, Woerpel KA. Electrostatic effects on the reactions of cyclohexanone oxocarbenium ions. The Journal of Organic Chemistry. 71: 6851-8. PMID 16930037 DOI: 10.1021/jo060968z |
1 |
|
| 2006 |
Clark TB, Woerpel KA. Formation and reactivity of silacyclopropenes derived from siloxyalkynes: stereoselective formation of 1,2,4-triols. Organic Letters. 8: 4109-12. PMID 16928086 DOI: 10.1021/ol061652g |
1 |
|
| 2006 |
Billings SB, Woerpel KA. Nucleophilic substitution reactions of sulfur-substituted cyclohexanone acetals: an analysis of the factors controlling stereoselectivity. The Journal of Organic Chemistry. 71: 5171-8. PMID 16808503 DOI: 10.1021/jo060077r |
1 |
|
| 2006 |
Shenoy SR, Smith DM, Woerpel KA. Nucleophilic additions of trimethylsilyl cyanide to cyclic oxocarbenium ions: evidence for the loss of stereoselectivity at the limits of diffusion control. Journal of the American Chemical Society. 128: 8671-7. PMID 16802834 DOI: 10.1021/ja061110u |
1 |
|
| 2006 |
Romero A, Woerpel KA. Stereoselective synthesis of highly substituted gamma-lactams by the [3+2] annulation of alpha-siloxy allylic silanes with chlorosulfonyl isocyanate. Organic Letters. 8: 2127-30. PMID 16671798 DOI: 10.1021/ol060596g |
1 |
|
| 2006 |
Smith DM, Woerpel KA. Electrostatic interactions in cations and their importance in biology and chemistry. Organic & Biomolecular Chemistry. 4: 1195-201. PMID 16557303 DOI: 10.1039/b600056h |
1 |
|
| 2006 |
Lucero CG, Woerpel KA. Stereoselective C-glycosylation reactions of pyranoses: the conformational preference and reactions of the mannosyl cation. The Journal of Organic Chemistry. 71: 2641-7. PMID 16555815 DOI: 10.1021/jo0522963 |
1 |
|
| 2005 |
Cleary PA, Woerpel KA. Metal-catalyzed rearrangement of homoallylic ethers to silylmethyl allylic silanes in the presence of a Di-tert-butylsilylene source. Organic Letters. 7: 5531-3. PMID 16288549 DOI: 10.1021/ol052456x |
1 |
|
| 2005 |
Ramirez A, Woerpel KA. Synthesis of 1,2-dioxolanes by annulation reactions of peroxycarbenium ions with alkenes. Organic Letters. 7: 4617-20. PMID 16209493 DOI: 10.1021/ol051703u |
1 |
|
| 2005 |
Larsen CH, Ridgway BH, Shaw JT, Smith DM, Woerpel KA. Stereoselective C-glycosylation reactions of ribose derivatives: electronic effects of five-membered ring oxocarbenium ions. Journal of the American Chemical Society. 127: 10879-84. PMID 16076193 DOI: 10.1021/ja0524043 |
1 |
|
| 2005 |
Chamberland S, Ziller JW, Woerpel KA. Structural evidence that alkoxy substituents adopt electronically preferred pseudoaxial orientations in six-membered ring dioxocarbenium ions. Journal of the American Chemical Society. 127: 5322-3. PMID 15826161 DOI: 10.1021/ja050830i |
1 |
|
| 2005 |
Shenoy SR, Woerpel KA. Investigations into the role of ion pairing in reactions of heteroatom-substituted cyclic oxocarbenium ions. Organic Letters. 7: 1157-60. PMID 15760163 DOI: 10.1021/ol0500620 |
1 |
|
| 2005 |
Calad SA, Woerpel KA. Silylene transfer to carbonyl compounds and subsequent Ireland-Claisen rearrangements to control formation of quaternary carbon stereocenters. Journal of the American Chemical Society. 127: 2046-7. PMID 15713073 DOI: 10.1021/ja042893r |
1 |
|
| 2005 |
Clark TB, Woerpel KA. Silver-catalyzed silacyclopropenation of 1-heteroatom-substituted alkynes and subsequent rearrangement reactions Organometallics. 24: 6212-6219. DOI: 10.1021/om050501z |
1 |
|
| 2004 |
Chamberland S, Woerpel KA. Using nucleophilic substitution reactions to understand how a remote alkyl or alkoxy substituent influences the conformation of eight-membered ring oxocarbenium ions. Organic Letters. 6: 4739-41. PMID 15575674 DOI: 10.1021/ol047998d |
1 |
|
| 2004 |
Driver TG, Woerpel KA. Mechanism of silver-mediated di-tert-butylsilylene transfer from a silacyclopropane to an alkene. Journal of the American Chemical Society. 126: 9993-10002. PMID 15303873 DOI: 10.1021/ja0306563 |
1 |
|
| 2004 |
Clark TB, Woerpel KA. Formation and utility of oxasilacyclopentenes derived from functionalized alkynes. Journal of the American Chemical Society. 126: 9522-3. PMID 15291539 DOI: 10.1021/ja047498f |
1 |
|
| 2004 |
Cirakovi? J, Driver TG, Woerpel KA. Metal-catalyzed di-tert-butylsilylene transfer: synthesis and reactivity of silacyclopropanes. The Journal of Organic Chemistry. 69: 4007-12. PMID 15176824 DOI: 10.1021/jo0355505 |
1 |
|
| 2004 |
Smith DM, Woerpel KA. Using stereoelectronic effects to explain selective reactions of 4-substituted five-membered ring oxocarbenium ions. Organic Letters. 6: 2063-6. PMID 15176819 DOI: 10.1021/ol0492647 |
1 |
|
| 2003 |
Ayala L, Lucero CG, Romero JA, Tabacco SA, Woerpel KA. Stereochemistry of nucleophilic substitution reactions depending upon substituent: evidence for electrostatic stabilization of pseudoaxial conformers of oxocarbenium ions by heteroatom substituents. Journal of the American Chemical Society. 125: 15521-8. PMID 14664599 DOI: 10.1021/ja037935a |
1 |
|
| 2003 |
Smith DM, Tran MB, Woerpel KA. Nucleophilic additions to fused bicyclic five-membered ring oxocarbenium ions: evidence for preferential attack on the inside face. Journal of the American Chemical Society. 125: 14149-52. PMID 14611253 DOI: 10.1021/ja0375176 |
1 |
|
| 2003 |
Tenenbaum JM, Woerpel KA. Use of an aminosilyllithium for the diastereoselective synthesis of diphenyl oxasilacyclopentane acetals and polyols. Organic Letters. 5: 4325-7. PMID 14601991 DOI: 10.1021/ol035577a |
1 |
|
| 2003 |
Driver TG, Woerpel KA. Mechanism of di-tert-butylsilylene transfer from a silacyclopropane to an alkene. Journal of the American Chemical Society. 125: 10659-63. PMID 12940750 DOI: 10.1021/ja0301370 |
1 |
|
| 2003 |
Peng ZH, Woerpel KA. [3 + 2] Annulation of allylic silanes in acyclic stereocontrol: total synthesis of (9S)-dihydroerythronolide A. Journal of the American Chemical Society. 125: 6018-9. PMID 12785807 DOI: 10.1021/ja034865z |
1 |
|
| 2002 |
Powell SA, Tenenbaum JM, Woerpel KA. Utilization of 1-oxa-2,2-(dimesityl)silacyclopentane acetals in the stereoselective synthesis of polyols. Journal of the American Chemical Society. 124: 12648-9. PMID 12392397 DOI: 10.1021/ja027335w |
1 |
|
| 2002 |
Roberson CW, Woerpel KA. Development of the [3 + 2] annulations of cyclohexenylsilanes and chlorosulfonyl isocyanate: application to the total synthesis of (+/-)-peduncularine. Journal of the American Chemical Society. 124: 11342-8. PMID 12236749 DOI: 10.1021/ja012152f |
1 |
|
| 2002 |
Peng ZH, Woerpel KA. Synthesis of (+/-)-5-epi-citreoviral and (+/-)-citreoviral and the kinetic resolution of an allylic silane by a [3 + 2] annulation. Organic Letters. 4: 2945-8. PMID 12182595 DOI: 10.1021/ol026343e |
1 |
|
| 2002 |
Cirakovi? J, Driver TG, Woerpel KA. Metal-catalyzed silacyclopropanation of mono- and disubstituted alkenes. Journal of the American Chemical Society. 124: 9370-1. PMID 12167021 DOI: 10.1021/ja020566i |
1 |
|
| 2002 |
Driver TG, Franz AK, Woerpel KA. Diastereoselective silacyclopropanations of functionalized chiral alkenes. Journal of the American Chemical Society. 124: 6524-5. PMID 12047159 DOI: 10.1021/ja020183k |
1 |
|
| 2002 |
Bear TJ, Shaw JT, Woerpel KA. Diastereoselective nucleophilic substitution reactions of oxasilacyclopentane acetals: application of the "inside attack" model for reactions of five-membered ring oxocarbenium ions. The Journal of Organic Chemistry. 67: 2056-64. PMID 11925209 DOI: 10.1021/jo010823m |
1 |
|
| 2002 |
Smitrovich JH, Woerpel KA. Reactions of silylmethyl allylic silanes: Synthesis of tetrahydrofurans Synthesis. 2778-2785. |
1 |
|
| 2001 |
Peng ZH, Woerpel KA. Stereoselective synthesis of substituted gamma-butyrolactones by the [3+2] annulation of allylic silanes with chlorosulfonyl isocyanate: enantioselective total synthesis of (+)-blastmycine. Organic Letters. 3: 675-8. PMID 11259034 DOI: 10.1021/ol0069960 |
1 |
|
| 2001 |
Palmer WS, Woerpel KA. Palladium-catalyzed reactions of Di-tert-butylsiliranes with electron-deficient alkynes and investigations of the catalytic cycle Organometallics. 20: 3691-3697. DOI: 10.1021/om000870p |
1 |
|
| 2000 |
Franz AK, Woerpel KA. Development of reactions of silacyclopropanes as new methods for stereoselective organic synthesis. Accounts of Chemical Research. 33: 813-20. PMID 11087318 DOI: 10.1021/ar9900562 |
1 |
|
| 2000 |
Peng ZH, Woerpel KA. Benzhydryldimethylsilyl allylic silanes: syntheses and applications to Organic Letters. 2: 1379-81. PMID 10814452 |
0.92 |
|
| 2000 |
Roberson CW, Woerpel KA. Formal synthesis of (+/-)-peduncularine: use of the Organic Letters. 2: 621-3. PMID 10814393 |
1 |
|
| 2000 |
Smitrovich JH, Woerpel KA. Stereoselective Synthesis of (Z)- and (E)-Allylic Silanes by Copper-Mediated Substitution Reactions of Allylic Carbamates with Grignard Reagents. The Journal of Organic Chemistry. 65: 1601-1614. PMID 10814135 |
1 |
|
| 2000 |
Smitrovich JH, Woerpel KA. Stereoselective synthesis of (Z)- and (E)-allylic silanes by copper- mediated substitution reactions of allylic carbamates with grignard reagents Journal of Organic Chemistry. 65: 1601-1614. DOI: 10.1021/jo991312r |
1 |
|
| 2000 |
Romero JAC, Tabacco SA, Woerpel KA. Stereochemical reversal of nucleophilic substitution reactions depending upon substituent: Reactions of heteroatom-substituted six-membered-ring oxocarbenium ions through pseudoaxial conformers Journal of the American Chemical Society. 122: 168-169. DOI: 10.1021/ja993366o |
1 |
|
| 2000 |
Franz AK, Woerpel KA. ZnBr2-catalyzed insertions of carbonyl compounds into silacyclopropanes: Regiochemical reversal dependent on metal salt Angewandte Chemie - International Edition. 39: 4295-4299. DOI: 10.1002/1521-3773(20001201)39:23<4295::AID-ANIE4295>3.0.CO;2-A |
1 |
|
| 2000 |
Peng ZH, Woerpel KA. Benzhydryldimethylsilyl allylic silanes: Syntheses and applications to [3 + 2] annulation reactions Organic Letters. 2: 1379-1381. |
1 |
|
| 2000 |
Roberson CW, Woerpel KA. Formal synthesis of (±)-peduncularine: Use of the [3 + 2] annulation of allylic silanes and chlorosulfonyl isocyanate Organic Letters. 2: 621-622. |
1 |
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| 1999 |
Nguyen PT, Palmer WS, Woerpel KA. Stereospecific and Regioselective Isocyanide Insertions into Siliranes and Reactions of the Resulting Iminosilacyclobutanes. The Journal of Organic Chemistry. 64: 1843-1848. PMID 11674272 DOI: 10.1021/jo9816257 |
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| 1999 |
Roberson CW, Woerpel KA. The [3 + 2] Annulation of Allylsilanes and Chlorosulfonyl Isocyanate: Stereoselective Synthesis of 2-Pyrrolidinones. The Journal of Organic Chemistry. 64: 1434-1435. PMID 11674199 DOI: 10.1021/jo982375x |
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| 1999 |
Larsen CH, Ridgway BH, Shaw JT, Woerpel KA. A stereoelectronic model to explain the highly stereoselective reactions of nucleophiles with five-membered-ring oxocarbenium ions [13] Journal of the American Chemical Society. 121: 12208-12209. DOI: 10.1021/ja993349z |
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| 1999 |
Franz AK, Woerpel KA. Stereospecific and regioselective reactions of silacyclopropanes with carbonyl compounds catalyzed by copper salts: Evidence for a transmetalation mechanism Journal of the American Chemical Society. 121: 949-957. DOI: 10.1021/ja982897u |
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| 1999 |
Shaw JT, Woerpel KA. Divergent diastereoselectivity in the addition of nucleophiles to tetrahydrofuran-derived oxonium ions Tetrahedron. 55: 8747-8756. DOI: 10.1016/S0040-4020(99)00441-X |
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| 1998 |
Ridgway BH, Woerpel KA. Transmetalation of Alkylboranes to Palladium in the Suzuki Coupling Reaction Proceeds with Retention of Stereochemistry. The Journal of Organic Chemistry. 63: 458-460. PMID 11672033 |
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| 1998 |
Smitrovich JH, Woerpel KA. Copper-mediated substitution reactions of alkylmagnesium reagents with allylic carbamates: (Z)-selective alkene synthesis [22] Journal of the American Chemical Society. 120: 12998-12999. DOI: 10.1021/ja9820341 |
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| 1998 |
Evans DA, Peterson GS, Johnson JS, Barnes DM, Campos KR, Woerpel KA. An Improved Procedure for the Preparation of 2,2-Bis[2-[4(S)-tert -butyl-1,3-oxazolinyl]] propane [(S,S)-tert-Butylbis(oxazoline)] and Derived Copper(II) Complexes Journal of Organic Chemistry. 63: 4541-4544. |
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| 1997 |
Shaw JT, Woerpel KA. Stereoselective Insertion of Formamides into the C-Si Bond of Siliranes. The Journal of Organic Chemistry. 62: 442-443. PMID 11671427 |
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| 1997 |
Bodnar PM, Shaw JT, Woerpel KA. Tandem aldol-Tishchenko reactions of lithium enolates: A highly stereoselective method for diol and triol synthesis Journal of Organic Chemistry. 62: 5674-5675. DOI: 10.1021/jo971012e |
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| 1997 |
Shaw JT, Woerpel KA. Preparation and synthetic utility of oxasilacyclopentane acetals derived from siliranes Tetrahedron. 53: 16597-16606. DOI: 10.1016/S0040-4020(97)01039-9 |
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| 1997 |
Palmer WS, Woerpel KA. Stereospecific palladium-catalyzed reactions of siliranes with alkynes Organometallics. 16: 1097-1099. |
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| 1997 |
Bodnar PM, Palmer WS, Ridgway BH, Shaw JT, Smitrovich JH, Woerpel KA. Stereo- and Regioselectivity of Reactions of Siliranes with Aldehydes and Related Substrates Journal of Organic Chemistry. 62: 4737-4745. |
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| 1997 |
Shaw JT, Woerpel KA. Divergent Diastereoselectivity in the Addition of Nucleophiles to Five-Membered-Ring Oxonium Ions Journal of Organic Chemistry. 62: 6706-6707. |
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| 1997 |
Palmer WS, Woerpel KA. Synthesis of silirenes by palladium-catalyzed transfer of silylene from siliranes to alkynes Organometallics. 16: 4824-4827. |
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| 1996 |
Smitrovich JH, Woerpel KA. Oxidation of sterically hindered alkoxysilanes and phenylsilanes under basic conditions Journal of Organic Chemistry. 61: 6044-6046. |
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| 1995 |
Bodnar PM, Palmer WS, Shaw JT, Smitrovich JH, Sonnenberg JD, Presley AL, Woerpel KA. Stereo- and regiochemistry of aldehyde insertions into the C-Si bonds of siliranes Journal of the American Chemical Society. 117: 10575-10576. |
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| 1994 |
Meyer TY, Woerpel KA, Novak BM, Bergman RG. Silica as a ligand: Reactivity of the indium-oxygen bond of Cp*Ir[silica](Ph)(PMe3) Journal of the American Chemical Society. 116: 10290-10291. |
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| 1993 |
Woerpel KA, Bergman RG. Synthesis and reactivity of an iridium hydroxo complex. Insertion of ethylene into a metal-oxygen bond Journal of the American Chemical Society. 115: 7888-7889. |
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| 1992 |
Evans DA, Woerpel KA, Scott MJ. 'Bis(oxazolines)' as ligands for self-assembling chiral coordination polymers - structure of a copper(I) catalyst for the enantioselective cyclopropanation of olefins Angewandte Chemie (International Edition in English). 31: 430-432. |
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