| Year |
Citation |
Score |
| 2025 |
Xiao L, Wei Z, Ni C, Dilman AD, Hu J. From -Fluoroalkylation to Fluoroalkylation-Thiolation: Difunctionalization of Alkenes with Fluoroalkyl Phenyl Sulfones and Thiophenols Enabled by Photoredox Copper Catalysis. Organic Letters. PMID 39960021 DOI: 10.1021/acs.orglett.5c00102 |
0.35 |
|
| 2024 |
Liang H, Wang Q, Zhou X, Zhang R, Zhou M, Wei J, Ni C, Hu J. N-Heteroaromatic Fluoroalkylation through Ligand Coupling Reaction of Sulfones. Angewandte Chemie (International Ed. in English). e202401091. PMID 38489249 DOI: 10.1002/anie.202401091 |
0.303 |
|
| 2024 |
Xie Q, Hu J. A Journey of the Development of Privileged Difluorocarbene Reagents TMSCFX (X = Br, F, Cl) for Organic Synthesis. Accounts of Chemical Research. 57: 693-713. PMID 38354302 DOI: 10.1021/acs.accounts.3c00719 |
0.356 |
|
| 2024 |
Liu A, Zhang X, Zhao F, Ni C, Hu J. Controllable Fluorocarbon Chain Elongation: TMSCFBr-Enabled Trifluorovinylation and Pentafluorocyclopropylation of Aldehydes. Journal of the American Chemical Society. PMID 38193677 DOI: 10.1021/jacs.3c12919 |
0.303 |
|
| 2023 |
Wei Z, Zheng W, Wan X, Hu J. Copper-Catalyzed Enantioselective Difluoromethylation-Alkynylation of Olefins by Solving the Dilemma between Acidities and Reduction Potentials of Difluoromethylating Agents. Angewandte Chemie (International Ed. in English). e202308816. PMID 37466977 DOI: 10.1002/anie.202308816 |
0.304 |
|
| 2022 |
Wei Z, Wen L, Zhu K, Wang Q, Zhao Y, Hu J. Regioselective Aromatic Perfluoro--butylation Using Perfluoro--butyl Phenyl Sulfone and Arynes. Journal of the American Chemical Society. 144: 22281-22288. PMID 36475403 DOI: 10.1021/jacs.2c10479 |
0.601 |
|
| 2022 |
Sun G, Liu H, Wang X, Zhang W, Miao W, Luo Q, Gao B, Hu J. Palladium-Catalyzed Defluorinative Coupling of Difluoroalkenes and Aryl Boronic Acids for Ketone Synthesis. Angewandte Chemie (International Ed. in English). PMID 36315428 DOI: 10.1002/anie.202213646 |
0.382 |
|
| 2022 |
Liu Q, Kong T, Ni C, Hu J. Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral α-Difluoromethylamines from Ketimines. Molecules (Basel, Switzerland). 27. PMID 36296670 DOI: 10.3390/molecules27207076 |
0.702 |
|
| 2022 |
Liu Q, Kong T, Ni C, Hu J. Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines. Organic Letters. PMID 35939038 DOI: 10.1021/acs.orglett.2c02250 |
0.672 |
|
| 2022 |
Liu R, Hu J. Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCFBr Reagent. Organic Letters. PMID 35467891 DOI: 10.1021/acs.orglett.2c00958 |
0.426 |
|
| 2022 |
Meng D, Lu Y, Ni C, Zhou M, Li Y, Hu J. S -( T rifluoromethyl) Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 35041768 DOI: 10.1002/chem.202104395 |
0.318 |
|
| 2021 |
Liu A, Ni C, Xie Q, Hu J. TMSCF Br-Enabled Fluorination-Aminocarbonylation of Aldehydes: Modular Access to α-Fluoroamides. Angewandte Chemie (International Ed. in English). e202115467. PMID 34919312 DOI: 10.1002/anie.202115467 |
0.302 |
|
| 2021 |
Wang Q, Tao Q, Dong H, Ni C, Xie X, Hu J. Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro-tert-butylation with DBBF and CsF. Angewandte Chemie (International Ed. in English). PMID 34714973 DOI: 10.1002/anie.202113727 |
0.323 |
|
| 2021 |
Wang Q, Liu A, Wang Y, Ni C, Hu J. Copper-Mediated Cross-Coupling of Diazo Compounds with Sulfinates. Organic Letters. PMID 34410732 DOI: 10.1021/acs.orglett.1c02481 |
0.358 |
|
| 2021 |
Wang X, Zhou M, Liu Q, Ni C, Fei Z, Li W, Hu J. Deoxyfluorination of alcohols with aryl fluorosulfonates. Chemical Communications (Cambridge, England). PMID 34318800 DOI: 10.1039/d1cc02617h |
0.681 |
|
| 2021 |
Wang X, Wang F, Huang F, Ni C, Hu J. Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides. Organic Letters. PMID 33586447 DOI: 10.1021/acs.orglett.1c00190 |
0.326 |
|
| 2021 |
Miao W, Ni C, Xiao P, Jia R, Zhang W, Hu J. Nickel-Catalyzed Reductive 2-Pyridination of Aryl Iodides with Difluoromethyl 2-Pyridyl Sulfone. Organic Letters. PMID 33417469 DOI: 10.1021/acs.orglett.0c03939 |
0.315 |
|
| 2020 |
Kuang C, Zhou X, Xie Q, Ni C, Gu Y, Hu J. Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides. Organic Letters. PMID 33095022 DOI: 10.1021/acs.orglett.0c03258 |
0.353 |
|
| 2020 |
Liang H, Liu R, Zhou M, Fu Y, Ni C, Hu J. Difluorocarbene-Triggered Cyclization: Synthesis of (Hetero)arene-Fused 2,2-Difluoro-2,3-dihydrothiophenes. Organic Letters. PMID 32816493 DOI: 10.1021/Acs.Orglett.0C02688 |
0.476 |
|
| 2020 |
Wei J, Bao K, Wang Y, Sheng R, Hu J. Novel usage of 2-BTSOCFH for metal-free electrophilic difluoroalkanethiolation of indoles. Organic & Biomolecular Chemistry. PMID 32490477 DOI: 10.1039/D0Ob00872A |
0.406 |
|
| 2020 |
Hu J, Wang Q, Ni C, Hu M, Xie Q, Liu Q, Pan S. From C1 to C3: Copper-Catalyzed gem-Bis(trifluoromethyl)olefination of α-Diazo Esters with TMSCF3. Angewandte Chemie (International Ed. in English). PMID 32119159 DOI: 10.1002/Anie.202002409 |
0.785 |
|
| 2020 |
Xie Q, Zhu Z, Li L, Ni C, Hu J. Controllable double CF2-insertion into sp2 C–Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures Chemical Science. 11: 276-280. DOI: 10.1039/C9Sc05018C |
0.358 |
|
| 2020 |
Zubkov MO, Kosobokov MD, Levin VV, Kokorekin VA, Korlyukov AA, Hu J, Dilman AD. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes Chemical Science. 11: 737-741. DOI: 10.1039/C9Sc04643G |
0.428 |
|
| 2020 |
Ye W, Zhu L, Luo Q, Ni C, Hu J. Highly diastereoselective and thermodynamically controlled nucleophilic addition of α-fluoro-α-phenylthio-α-phenylsulfonylmethane (FTSM) to aldehydes Tetrahedron. 76: 130877. DOI: 10.1016/J.Tet.2019.130877 |
0.366 |
|
| 2020 |
Ye W, Ni C, Hu J. Stereoselective nucleophilic monofluoromethylation of tert-butanesulfinimines: Dynamic thermodynamic Resolution of racemic α-fluoro carbanions Journal of Fluorine Chemistry. 231: 109451. DOI: 10.1016/J.Jfluchem.2020.109451 |
0.345 |
|
| 2020 |
Xie Q, Hu J. Chen's Reagent: A Versatile Reagent for Trifluoromethylation, Difluoromethylenation, and Difluoroalkylation in Organic Synthesis Chinese Journal of Chemistry. 38: 202-212. DOI: 10.1002/Cjoc.201900424 |
0.367 |
|
| 2019 |
Zubkov MO, Kosobokov MD, Levin VV, Kokorekin VA, Korlyukov AA, Hu J, Dilman AD. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes. Chemical Science. 11: 737-741. PMID 34123046 DOI: 10.1039/c9sc04643g |
0.323 |
|
| 2019 |
Xie Q, Zhu Z, Ni C, Hu J. Nucleophilic (Phenylsulfonyl/arylthio)difluoromethylation of Aldehydes with TMSCFBr: A Three-Component Strategy. Organic Letters. PMID 31664845 DOI: 10.1021/Acs.Orglett.9B03520 |
0.478 |
|
| 2019 |
Shen X, Zhang W, Ni C, Gu Y, Hu J. Correction to "Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones". Journal of the American Chemical Society. PMID 31244174 DOI: 10.1021/jacs.9b06390 |
0.598 |
|
| 2019 |
Xiao P, Ni C, Miao W, Zhou M, Hu J, Chen D, Hu J. Fluoroalkylation of Various Nucleophiles with Fluoroalkyl Sulfones Through a Single Electron Transfer Process. The Journal of Organic Chemistry. PMID 31083947 DOI: 10.1021/Acs.Joc.9B00419 |
0.398 |
|
| 2019 |
Hu J, Guo J, Kuang C, Rong J, Li L, Ni C. Rapid Deoxyfluorination of Alcohols with 4-Chloro-N-tosylbenzene-1-Sulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30869818 DOI: 10.1002/Chem.201901176 |
0.592 |
|
| 2019 |
Hu J, Xie Q, Zhu Z, Li L, Ni C. A General C-H Difluoromethylation Protocol for Carbon Acids Using TMSCF2Br. Angewandte Chemie (International Ed. in English). PMID 30835963 DOI: 10.1002/Anie.201900763 |
0.367 |
|
| 2019 |
Wei J, Liang H, Ni C, Sheng R, Hu J. Transition-Metal-Free Desulfinative Cross-Coupling of Heteroaryl Sulfinates with Grignard Reagents. Organic Letters. PMID 30676757 DOI: 10.1021/Acs.Orglett.8B03918 |
0.359 |
|
| 2019 |
Wei J, Bao K, Qi C, Liu Y, Ni C, Sheng R, Hu J. Transition‐Metal‐Free Electrophilic Fluoroalkanesulfinylation of Electron‐Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)−S and S=O Bond Cleavage Advanced Synthesis & Catalysis. 361: 5528-5533. DOI: 10.1002/Adsc.201900959 |
0.32 |
|
| 2018 |
Hu J, Xie Q, Li L, Zhu Z, Zhang R, Ni C. From C1 to C2: TMSCF3 as an Efficient Precursor for Pentafluoroethylation. Angewandte Chemie (International Ed. in English). PMID 30138542 DOI: 10.1002/Anie.201807873 |
0.429 |
|
| 2018 |
Supranovich VI, Levin VV, Struchkova MI, Hu J, Dilman AD. Visible light-mediated difluoroalkylation of electron-deficient alkenes. Beilstein Journal of Organic Chemistry. 14: 1637-1641. PMID 30013689 DOI: 10.3762/Bjoc.14.139 |
0.323 |
|
| 2018 |
Hu J, Xing B, Ni C. Hypervalent Iodine(III)-Catalyzed Balz-Schiemann Fluorination under Mild Conditions. Angewandte Chemie (International Ed. in English). PMID 29932480 DOI: 10.1002/Anie.201802466 |
0.464 |
|
| 2018 |
Zhou M, Ni C, Zeng Y, Hu J. Trifluoromethyl Benzoate (TFBz): A Versatile Trifluoromethoxylation Reagent. Journal of the American Chemical Society. PMID 29787259 DOI: 10.1021/Jacs.8B04000 |
0.685 |
|
| 2018 |
Zhang R, Ni C, Zhao Y, Hu J. Synthesis of 2,2-diaryl-1,1-difluoroethenes via Pd-catalyzed dehydrosulfonylative cross-coupling of α-[difluoro(phenylsulfonyl)methyl]benzyl tosylates with arylboronic acids Tetrahedron. 74: 5295-5302. DOI: 10.1016/J.Tet.2018.04.054 |
0.667 |
|
| 2018 |
Zhang R, Ni C, He Z, Hu J. Organocatalyzed Decarboxylative Trifluoromethylation of β-Ketoacids Topics in Catalysis. 61: 664-673. DOI: 10.1007/S11244-018-0973-7 |
0.458 |
|
| 2018 |
Hu J, Yang Y, Lou Z, Ni C, Hu J. Fluoro-Hydroxylation of gem
-Difluoroalkenes: Synthesis of 18
O-labeled α-CF3
Alcohols Chinese Journal of Chemistry. 36: 1202-1208. DOI: 10.1002/Cjoc.201800426 |
0.363 |
|
| 2017 |
Miao W, Zhao Y, Ni C, Gao B, Zhang W, Hu J. Iron-Catalyzed Difluoromethylation of Arylzincs with Difluoromethyl 2-Pyridyl Sulfone. Journal of the American Chemical Society. PMID 29278333 DOI: 10.1021/Jacs.7B11976 |
0.568 |
|
| 2017 |
Hu J, Li L, Ni C, Xie Q, Hu M, Wang F. TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation and Tetrafluoroethylation. Angewandte Chemie (International Ed. in English). PMID 28656676 DOI: 10.1002/Anie.201705734 |
0.619 |
|
| 2017 |
Xie Q, Ni C, Zhang R, Li L, Rong J, Hu J. Efficient Difluoromethylation of Alcohols Using TMSCF2 Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions. Angewandte Chemie (International Ed. in English). PMID 28181719 DOI: 10.1002/Anie.201611823 |
0.579 |
|
| 2017 |
Rong J, Ni C, Wang Y, Kuang C, Gu Y, Hu J. Radical Fluoroalkylation of Aryl Alkenes with Fluorinated Sulfones by Visible-Light Photoredox Catalysis Acta Chimica Sinica. 75: 105. DOI: 10.6023/A16080412 |
0.335 |
|
| 2017 |
Liu Q, Ni C, Hu J. China's flourishing synthetic organofluorine chemistry: innovations in the new millennium National Science Review. 4: 303-325. DOI: 10.1093/Nsr/Nwx058 |
0.664 |
|
| 2017 |
Wang L, Wei J, Wu R, Cheng G, Li X, Hu J, Hu Y, Sheng R. The stability and reactivity of tri-, di-, and monofluoromethyl/methoxy/methylthio groups on arenes under acidic and basic conditions Organic Chemistry Frontiers. 4: 214-223. DOI: 10.1039/C6Qo00674D |
0.309 |
|
| 2017 |
Zhang R, Ni C, He Z, Hu J. Decarboxylative fluorination of β-Ketoacids with N-fluorobenzenesulfonimide (NFSI) for the synthesis of α-fluoroketones: Substrate scope and mechanistic investigation Journal of Fluorine Chemistry. 203: 166-172. DOI: 10.1016/J.Jfluchem.2017.08.010 |
0.405 |
|
| 2017 |
Jiang F, Ni C, Hu J. Efficient nucleophilic difluoromethylation of aldehydes with (phenylsulfonyl)difluoromethylzinc and (phenylsulfonyl)difluoromethylcadmium reagents Journal of Fluorine Chemistry. 198: 67-75. DOI: 10.1016/J.Jfluchem.2016.12.005 |
0.41 |
|
| 2017 |
Rong J, Ni C, Hu J. Cover Picture: Metal-Catalyzed Direct Difluoromethylation Reactions (Asian J. Org. Chem. 2/2017) Asian Journal of Organic Chemistry. 6: 118-118. DOI: 10.1002/Ajoc.201600600 |
0.358 |
|
| 2017 |
Rong J, Ni C, Hu J. Metal-Catalyzed Direct Difluoromethylation Reactions Asian Journal of Organic Chemistry. 6: 139-152. DOI: 10.1002/Ajoc.201600509 |
0.429 |
|
| 2016 |
Xiao P, Rong J, Ni C, Guo J, Li X, Chen D, Hu J. Radical (Phenylsulfonyl)difluoromethylation of Isocyanides with PhSO2CF2H under Transition-Metal-Free Conditions. Organic Letters. 18: 5912-5915. PMID 27934497 DOI: 10.1021/Acs.Orglett.6B03013 |
0.594 |
|
| 2016 |
Liu Q, Shen X, Ni C, Hu J. Stereoselective Carbonyl Olefination with Fluorosulfoximines: Facile Access to Z or E Terminal Monofluoroalkenes. Angewandte Chemie (International Ed. in English). PMID 27879039 DOI: 10.1002/Anie.201610127 |
0.772 |
|
| 2016 |
Li L, Ni C, Wang F, Hu J. Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes. Nature Communications. 7: 13320. PMID 27841256 DOI: 10.1038/Ncomms13320 |
0.318 |
|
| 2016 |
Chen D, Ni C, Zhao Y, Cai X, Li X, Xiao P, Hu J. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3 SiCF2 H. Angewandte Chemie (International Ed. in English). PMID 27552967 DOI: 10.1002/Anie.201605280 |
0.593 |
|
| 2016 |
Ni C, Hu J. The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations. Chemical Society Reviews. PMID 27499359 DOI: 10.1039/c6cs00351f |
0.405 |
|
| 2016 |
Zhou M, Ni C, He Z, Hu J. O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination. Organic Letters. PMID 27440264 DOI: 10.1021/Acs.Orglett.6B01779 |
0.36 |
|
| 2016 |
Miao W, Ni C, Zhao Y, Hu J. Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone. Organic Letters. PMID 27193694 DOI: 10.1021/Acs.Orglett.6B01258 |
0.672 |
|
| 2016 |
Hu J, Zhao J, Wang Y, Rong J, Hu M, Chen D, Xiao P, Ni C, Wang L. Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2CH3). Chemistry, An Asian Journal. PMID 27146599 DOI: 10.1002/Asia.201600577 |
0.719 |
|
| 2016 |
Li X, Zhao J, Hu M, Chen D, Ni C, Wang L, Hu J. Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone. Chemical Communications (Cambridge, England). PMID 26854122 DOI: 10.1039/C5Cc10550A |
0.631 |
|
| 2016 |
Zeng Y, Hu J. Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes. Organic Letters. PMID 26849240 DOI: 10.1021/Acs.Orglett.6B00142 |
0.638 |
|
| 2016 |
Rong J, Deng L, Tan P, Ni C, Gu Y, Hu J. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis. Angewandte Chemie (International Ed. in English). PMID 26797782 DOI: 10.1002/Anie.201510533 |
0.605 |
|
| 2016 |
Hu J, Zeng Y. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation Synthesis. 48: e3-e3. DOI: 10.1055/S-0035-1562547 |
0.67 |
|
| 2016 |
Shen X, Liu Q, Zhang W, Hu J. Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and α,β-Unsaturated Weinreb Amides: Tuning the of Selectivity between C-Cl and C-S Bond Cleavage European Journal of Organic Chemistry. 2016: 906-909. DOI: 10.1002/Ejoc.201501611 |
0.768 |
|
| 2016 |
Hu M, Xie Q, Li X, Ni C, Hu J. Copper-Mediated Deuterotrifluoromethylation of α?Diazo Esters Chinese Journal of Chemistry. 34: 469-472. DOI: 10.1002/Cjoc.201600004 |
0.668 |
|
| 2016 |
Zeng Y, Hu J. ChemInform Abstract: Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation Cheminform. 47. DOI: 10.1002/chin.201640228 |
0.643 |
|
| 2016 |
Shen X, Liu Q, Zhang W, Hu J. ChemInform Abstract: Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and α,β-Unsaturated Weinreb Amides: Tuning the of Selectivity Between C-Cl and C-S Bond Cleavage. Cheminform. 47. DOI: 10.1002/chin.201627075 |
0.662 |
|
| 2015 |
Zeng Y, Ni C, Hu J. Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 26691934 DOI: 10.1002/Chem.201504036 |
0.669 |
|
| 2015 |
He Z, Tan P, Hu J. Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation. Organic Letters. PMID 26651277 DOI: 10.1021/Acs.Orglett.5B03290 |
0.509 |
|
| 2015 |
Hu M, Ni C, Li L, Han Y, Hu J. gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors. Journal of the American Chemical Society. PMID 26501359 DOI: 10.1021/Jacs.5B09888 |
0.639 |
|
| 2015 |
Luo T, Zhang R, Shen X, Zhang W, Ni C, Hu J. Brønsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides. Dalton Transactions (Cambridge, England : 2003). PMID 26239881 DOI: 10.1039/C5Dt02088C |
0.621 |
|
| 2015 |
Zeng Y, Li G, Hu J. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes. Angewandte Chemie (International Ed. in English). PMID 26211756 DOI: 10.1002/Anie.201503308 |
0.686 |
|
| 2015 |
Hu J, Gao B, Li L, Ni C, Hu J. Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide. Organic Letters. 17: 3086-9. PMID 26024050 DOI: 10.1021/Acs.Orglett.5B01361 |
0.46 |
|
| 2015 |
He Z, Tan P, Ni C, Hu J. Fluoroalkylative aryl migration of conjugated N-arylsulfonylated amides using easily accessible sodium di- and monofluoroalkanesulfinates. Organic Letters. 17: 1838-41. PMID 25839912 DOI: 10.1021/Acs.Orglett.5B00308 |
0.434 |
|
| 2015 |
Zhao Y, Jiang F, Hu J. Spontaneous resolution of Julia-Kocienski intermediates facilitates phase separation to produce Z- and E-monofluoroalkenes. Journal of the American Chemical Society. 137: 5199-203. PMID 25831969 DOI: 10.1021/Jacs.5B02112 |
0.607 |
|
| 2015 |
Li X, Zhao J, Zhang L, Hu M, Wang L, Hu J. Copper-mediated trifluoromethylation using phenyl trifluoromethyl sulfoxide. Organic Letters. 17: 298-301. PMID 25541645 DOI: 10.1021/Ol5034018 |
0.645 |
|
| 2015 |
Gao B, Zhao Y, Hu J. AgF-mediated fluorinative cross-coupling of two olefins: facile access to α-CF3 alkenes and β-CF3 ketones. Angewandte Chemie (International Ed. in English). 54: 638-42. PMID 25393744 DOI: 10.1002/Anie.201409705 |
0.652 |
|
| 2015 |
Ni C, Hu M, Hu J. Good partnership between sulfur and fluorine: sulfur-based fluorination and fluoroalkylation reagents for organic synthesis. Chemical Reviews. 115: 765-825. PMID 25144886 DOI: 10.1021/Cr5002386 |
0.65 |
|
| 2015 |
Hu J, Gao B, Li L, Ni C. Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters Synfacts. 11: 974-974. DOI: 10.1055/S-0035-1560073 |
0.477 |
|
| 2015 |
Gao B, Zhao Y, Hu J. Difluoromethyl 2-pyridyl sulfone: A versatile carbonyl gem-difluoroolefination reagent Organic Chemistry Frontiers. 2: 163-168. DOI: 10.1039/C4Qo00291A |
0.591 |
|
| 2015 |
Gao B, Hu J, Zhao Y. Carbonyl olefination of diaryl ketones with heteroaryl sulfoxides Tetrahedron Letters. 56: 4180-4183. DOI: 10.1016/J.Tetlet.2015.05.034 |
0.669 |
|
| 2015 |
Ni C, Jiang F, Zeng Y, Hu J. Chemically oxidative fluorination with fluoride ions Journal of Fluorine Chemistry. 179: 3-13. DOI: 10.1016/J.Jfluchem.2015.06.026 |
0.637 |
|
| 2015 |
Zhu J, Ni C, Gao B, Hu J. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species Journal of Fluorine Chemistry. 171: 139-147. DOI: 10.1016/J.Jfluchem.2014.08.011 |
0.417 |
|
| 2015 |
Gao B, Hu J, Zhao Y, Hu J. ChemInform Abstract: Carbonyl Olefination of Diaryl Ketones with Heteroaryl Sulfoxides. Cheminform. 46: no-no. DOI: 10.1002/chin.201542174 |
0.623 |
|
| 2015 |
Li S, Peng P, Wei J, Hu Y, Hu J, Sheng R. Nucleophilic Difluoroalkylation of Isocyanates with Difluoromethyl 2-Pyridyl Sulfone Advanced Synthesis and Catalysis. 357: 3429-3434. DOI: 10.1002/Adsc.201500150 |
0.424 |
|
| 2014 |
Gao B, Ni C, Hu J. Selective incorporation of difluoromethylene moieties into arenes assisted by transition metals. Chimia. 68: 414-8. PMID 25198751 DOI: 10.2533/Chimia.2014.414 |
0.352 |
|
| 2014 |
Ye W, Zhang L, Ni C, Rong J, Hu J. Stereoselective [3+2] cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO₂CF₂ group: synthesis and transformation of cyclic sulfoximines. Chemical Communications (Cambridge, England). 50: 10596-9. PMID 25077600 DOI: 10.1039/C4Cc05042H |
0.647 |
|
| 2014 |
Gao B, Zhao Y, Hu M, Ni C, Hu J. gem-Difluoroolefination of diaryl ketones and enolizable aldehydes with difluoromethyl 2-pyridyl sulfone: new insights into the Julia-Kocienski reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7803-10. PMID 24807811 DOI: 10.1002/Chem.201402183 |
0.778 |
|
| 2014 |
Zeng Y, Hu J. Silver-catalyzed formal insertion of arynes into Rf-I bonds. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6866-70. PMID 24782445 DOI: 10.1002/Chem.201402846 |
0.653 |
|
| 2014 |
Shen X, Liu Q, Luo T, Hu J. Nucleophilic difluoromethylation of epoxides with PhSO(NTBS)CF₂H by a preorganization strategy. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 6795-800. PMID 24756897 DOI: 10.1002/Chem.201402506 |
0.752 |
|
| 2014 |
Hu M, Rong J, Miao W, Ni C, Han Y, Hu J. Copper-mediated trifluoromethylthiolation of α-diazoesters. Organic Letters. 16: 2030-3. PMID 24660960 DOI: 10.1021/Ol500612N |
0.749 |
|
| 2014 |
Wang F, Li L, Ni C, Hu J. Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine. Beilstein Journal of Organic Chemistry. 10: 344-51. PMID 24605155 DOI: 10.3762/Bjoc.10.32 |
0.479 |
|
| 2014 |
Luo T, Zhang R, Zhang W, Shen X, Umemoto T, Hu J. Divergent rearrangements of cyclopropyl-substituted fluoroepoxides involving C-F bond cleavage and formation. Organic Letters. 16: 888-91. PMID 24422980 DOI: 10.1021/Ol403644N |
0.59 |
|
| 2014 |
Shen X, Miao W, Ni C, Hu J. Stereoselective nucleophilic fluoromethylation of aryl ketones: dynamic kinetic resolution of chiral α-fluoro carbanions. Angewandte Chemie (International Ed. in English). 53: 775-9. PMID 24307659 DOI: 10.1002/Anie.201308484 |
0.563 |
|
| 2014 |
Gao B, Zhao Y, Ni C, Hu J. AgF-mediated fluorinative homocoupling of gem-difluoroalkenes. Organic Letters. 16: 102-5. PMID 24294835 DOI: 10.1021/Ol403083E |
0.656 |
|
| 2014 |
Ni C, Hu J. Recent advances in the synthetic application of difluorocarbene Synthesis (Germany). 46: 842-863. DOI: 10.1055/S-0033-1340856 |
0.382 |
|
| 2014 |
Hu M, Rong J, Miao W, Ni C, Han Y, Hu J. Trifluoromethylthiolation of Diazoesters Synfacts. 10: 741-741. DOI: 10.1055/S-0033-1339154 |
0.362 |
|
| 2014 |
Jiang F, Zhao Y, Hu J. Selective monofluorination of active methylene compounds: The important role of ZnCl2 in inhibiting overfluorination Organic Chemistry Frontiers. 1: 625-629. DOI: 10.1039/C4Qo00090K |
0.56 |
|
| 2014 |
Shen X, Zhou M, Ni C, Zhang W, Hu J. Direct monofluoromethylation of O-, S-, N-, and P-nucleophiles with PhSO(NTs)CH2F: The accelerating effect of α-fluorine substitution Chemical Science. 5: 117-122. DOI: 10.1039/C3Sc51831K |
0.587 |
|
| 2014 |
Miao W, Ni C, Zhao Y, Hu J. Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone Journal of Fluorine Chemistry. DOI: 10.1016/J.Jfluchem.2014.05.012 |
0.635 |
|
| 2014 |
Shen X, Hu J. Fluorinated sulfoximines: Preparation, reactions and applications European Journal of Organic Chemistry. 2014: 4437-4451. DOI: 10.1002/Ejoc.201402086 |
0.636 |
|
| 2014 |
Shen X, Liu Q, Ni C, Hu J. Cover Picture: Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry intogem-Difluoroalkenes (Chin. J. Chem. 8/2014) Chinese Journal of Chemistry. 32: 657-657. DOI: 10.1002/Cjoc.201490017 |
0.729 |
|
| 2014 |
Shen X, Liu Q, Ni C, Hu J. Nucleophilic difluoro(phenylsulfonimidoyl)methylation of unactivated alkyl bromides with PhSO(NTBS)CF2H: Facile entry into gem-difluoroalkenes Chinese Journal of Chemistry. 32: 703-708. DOI: 10.1002/Cjoc.201400403 |
0.77 |
|
| 2014 |
Shen X, Hu J. ChemInform Abstract: Fluorinated Sulfoximines: Preparation, Reactions and Applications Cheminform. 45: no-no. DOI: 10.1002/chin.201448238 |
0.322 |
|
| 2014 |
Shen X, Ni C, Hu J. ChemInform Abstract: Highly Stereoselective and One-Pot Synthesis of Tetra-Substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane. Cheminform. 45: no-no. DOI: 10.1002/chin.201406092 |
0.39 |
|
| 2014 |
He Z, Zhang R, Hu M, Li L, Ni C, Hu J. ChemInform Abstract: Copper-Mediated Trifluoromethylation of Propiolic Acids: Facile Synthesis of α-Trifluoromethyl Ketones. Cheminform. 45: no-no. DOI: 10.1002/chin.201404063 |
0.306 |
|
| 2013 |
Hu M, He Z, Gao B, Li L, Ni C, Hu J. Copper-catalyzed gem-difluoroolefination of diazo compounds with TMSCF3 via C-F bond cleavage. Journal of the American Chemical Society. 135: 17302-5. PMID 24171471 DOI: 10.1021/Ja409941R |
0.632 |
|
| 2013 |
Li L, Wang F, Ni C, Hu J. Synthesis of gem-difluorocyclopropa(e)nes and O-, S-, N-, and P-difluoromethylated compounds with TMSCF(2)Br. Angewandte Chemie (International Ed. in English). 52: 12390-4. PMID 24030756 DOI: 10.1002/Anie.201306703 |
0.397 |
|
| 2013 |
Zeng Y, Zhang L, Zhao Y, Ni C, Zhao J, Hu J. Silver-mediated trifluoromethylation-iodination of arynes. Journal of the American Chemical Society. 135: 2955-8. PMID 23398454 DOI: 10.1021/ja312711c |
0.724 |
|
| 2013 |
Zeng Y, Zhang L, Zhao Y, Ni C, Zhao J, Hu J. Silver-Mediated Trifluoromethylation–Iodination of Arynes Synfacts. 9: 544-544. DOI: 10.1055/S-0033-1338319 |
0.515 |
|
| 2013 |
He Z, Zhang R, Hu M, Li L, Ni C, Hu J. Copper-mediated trifluoromethylation of propiolic acids: Facile synthesis of α-trifluoromethyl ketones Chemical Science. 4: 3478-3483. DOI: 10.1039/C3Sc51613J |
0.691 |
|
| 2013 |
Huang W, Ni C, Zhao Y, Hu J. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and α-fluorinated sulfones New Journal of Chemistry. 37: 1684-1687. DOI: 10.1039/C2Nj40842B |
0.608 |
|
| 2013 |
Zhao Y, Ni C, Jiang F, Gao B, Shen X, Hu J. Copper-catalyzed debenzoylative monofluoromethylation of aryl iodides assisted by the removable (2-Pyridyl)sulfonyl group Acs Catalysis. 3: 631-634. DOI: 10.1021/Cs4000574 |
0.71 |
|
| 2013 |
Hu M, Gao B, Ni C, Zhang L, Hu J. Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base Dedicated to Professor Iwao Ojima on the occasion of his receipt of the ACS Award for Creative Work in Fluorine Chemistry 2013 Journal of Fluorine Chemistry. 155: 52-58. DOI: 10.1016/J.Jfluchem.2013.05.015 |
0.676 |
|
| 2013 |
Shen X, Ni C, Hu J. Highly stereoselective and one-pot synthesis of tetra-substituted monofluoroalkenes with aldehydes and fluorobis(phenylsulfonyl)methane Chinese Journal of Chemistry. 31: 878-884. DOI: 10.1002/Cjoc.201300365 |
0.666 |
|
| 2013 |
Huang W, Ni C, Zhao Y, Hu J. ChemInform Abstract: DIAD-Mediated Metal-Free Cross Dehydrogenative Coupling Between Tertiary Amines and α-Fluorinated Sulfones. Cheminform. 44: no-no. DOI: 10.1002/chin.201344089 |
0.534 |
|
| 2013 |
Zhang W, Zhao Y, Ni C, Mathew T, Hu J. ChemInform Abstract: Palladium-Catalyzed Allylation of 2,2,2-Trifluoroethyl Phenyl Sulfone, a Potential 2,2,2-Trifluoroethyl Pronucleophile. Cheminform. 44: no-no. DOI: 10.1002/chin.201310054 |
0.619 |
|
| 2013 |
Huang W, Ni C, Zhao Y, Gao B, Hu J. ChemInform Abstract: Nucleophilic Difluoromethylation of N,N-Acetals with TMSCF2SO2Ph Reagent Promoted by Trifluoroacetic Acid: A Facile Access to α-Difluoromethylated Tertiary Amines. Cheminform. 44: no-no. DOI: 10.1002/chin.201307067 |
0.542 |
|
| 2012 |
Zhao Y, Gao B, Ni C, Hu J. Copper-mediated fluoroalkylation of aryl iodides enables facile access to diverse fluorinated compounds: the important role of the (2-pyridyl)sulfonyl group. Organic Letters. 14: 6080-3. PMID 23181891 DOI: 10.1021/Ol3029737 |
0.634 |
|
| 2012 |
He Z, Hu M, Luo T, Li L, Hu J. Copper-catalyzed difluoromethylation of β,γ-unsaturated carboxylic acids: an efficient allylic difluoromethylation. Angewandte Chemie (International Ed. in English). 51: 11545-7. PMID 23070804 DOI: 10.1002/Anie.201206556 |
0.634 |
|
| 2012 |
Shen X, Zhang W, Ni C, Gu Y, Hu J. Tuning the reactivity of difluoromethyl sulfoximines from electrophilic to nucleophilic: stereoselective nucleophilic difluoromethylation of aryl ketones. Journal of the American Chemical Society. 134: 16999-7002. PMID 23020196 DOI: 10.1021/Ja308419A |
0.588 |
|
| 2012 |
Hu M, Ni C, Hu J. Copper-mediated trifluoromethylation of α-diazo esters with TMSCF3: the important role of water as a promoter. Journal of the American Chemical Society. 134: 15257-60. PMID 22913648 DOI: 10.1021/Ja307058C |
0.703 |
|
| 2012 |
Shen X, Zhang W, Zhang L, Luo T, Wan X, Gu Y, Hu J. Enantioselective synthesis of cyclopropanes that contain fluorinated tertiary stereogenic carbon centers: a chiral α-fluoro carbanion strategy. Angewandte Chemie (International Ed. in English). 51: 6966-70. PMID 22689532 DOI: 10.1002/Anie.201202451 |
0.589 |
|
| 2012 |
Zhao Y, Gao B, Hu J. From olefination to alkylation: in-situ halogenation of Julia-Kocienski intermediates leading to formal nucleophilic iodo- and bromodifluoromethylation of carbonyl compounds. Journal of the American Chemical Society. 134: 5790-3. PMID 22424273 DOI: 10.1021/Ja301601B |
0.667 |
|
| 2012 |
He Z, Luo T, Hu M, Cao Y, Hu J. Copper-catalyzed di- and trifluoromethylation of α,β-unsaturated carboxylic acids: a protocol for vinylic fluoroalkylations. Angewandte Chemie (International Ed. in English). 51: 3944-7. PMID 22407851 DOI: 10.1002/Anie.201200140 |
0.672 |
|
| 2012 |
Kosobokov MD, Dilman AD, Struchkova MI, Belyakov PA, Hu J. Reactions of sulfur- and phosphorus-substituted fluoroalkylating silicon reagents with imines and enamines under acidic conditions. The Journal of Organic Chemistry. 77: 2080-6. PMID 22283481 DOI: 10.1021/Jo202669W |
0.462 |
|
| 2012 |
Zhao Y, Hu J. Palladium-catalyzed 2,2,2-trifluoroethylation of organoboronic acids and esters. Angewandte Chemie (International Ed. in English). 51: 1033-6. PMID 22170859 DOI: 10.1002/Anie.201106742 |
0.599 |
|
| 2012 |
Zhang W, Ni C, Hu J. Selective fluoroalkylation of organic compounds by tackling the "negative fluorine effect". Topics in Current Chemistry. 308: 25-44. PMID 21898204 DOI: 10.1007/128_2011_246 |
0.427 |
|
| 2012 |
Zhang W, Zhao Y, Ni C, Mathew T, Hu J. Palladium-catalyzed allylation of 2,2,2-trifluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile Tetrahedron Letters. 53: 6565-6568. DOI: 10.1016/J.Tetlet.2012.09.094 |
0.663 |
|
| 2012 |
Huang W, Ni C, Zhao Y, Zhang W, Dilman AD, Hu J. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents Tetrahedron. 68: 5137-5144. DOI: 10.1016/J.Tet.2012.04.039 |
0.619 |
|
| 2012 |
Huang W, Ni C, Zhao Y, Gao B, Hu J. Nucleophilic difluoromethylation of N,N-acetals with TMSCF 2SO 2Ph reagent promoted by trifluoroacetic acid: A facile access to α-difluoromethylated tertiary amines Journal of Fluorine Chemistry. 143: 161-166. DOI: 10.1016/J.Jfluchem.2012.05.018 |
0.613 |
|
| 2012 |
Hu M, Wang F, Zhao Y, He Z, Zhang W, Hu J. Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF 2H (X = S, Se, Te) Journal of Fluorine Chemistry. 135: 45-58. DOI: 10.1016/J.Jfluchem.2011.08.007 |
0.728 |
|
| 2012 |
Shen X, Ni C, Hu J. Nucleophilic fluoroalkylation of α,β-unsaturated carbonyl compounds with α-fluorinated sulfones: Investigation of the reversibility of 1,2-additions and the formation of 1,4-adducts Helvetica Chimica Acta. 95: 2043-2051. DOI: 10.1002/Hlca.201200445 |
0.609 |
|
| 2012 |
Huang W, Ni C, Zhao Y, Zhang W, Dilman AD, Hu J. ChemInform Abstract: Nucleophilic Difluoromethylation of C=N Bonds in Heterocycles with Difluoromethyl Silane Reagents. Cheminform. 43: no-no. DOI: 10.1002/chin.201246166 |
0.533 |
|
| 2012 |
Hu M, Wang F, Zhao Y, He Z, Zhang W, Hu J. ChemInform Abstract: Difluoro(phenylchalcogen)methylation of Aldehydes, Ketones, and Imines with S-, Se-, and Te-Containing Reagents PhXCF2H (X: S, Se, Te). Cheminform. 43: no-no. DOI: 10.1002/chin.201231041 |
0.518 |
|
| 2011 |
Zhao Y, Huang W, Zheng J, Hu J. Efficient and direct nucleophilic difluoromethylation of carbonyl compounds and imines with Me3SiCF2H at ambient or low temperature. Organic Letters. 13: 5342-5. PMID 21910464 DOI: 10.1021/Ol202208B |
0.619 |
|
| 2011 |
Wang F, Luo T, Hu J, Wang Y, Krishnan HS, Jog PV, Ganesh SK, Prakash GK, Olah GA. Synthesis of gem-difluorinated cyclopropanes and cyclopropenes: trifluoromethyltrimethylsilane as a difluorocarbene source. Angewandte Chemie (International Ed. in English). 50: 7153-7. PMID 21681877 DOI: 10.1002/Anie.201101691 |
0.553 |
|
| 2011 |
Shen X, Zhang L, Zhao Y, Zhu L, Li G, Hu J. Nucleophilic fluoromethylation of aldehydes with fluorobis(phenylsulfonyl)methane: the importance of strong Li-O coordination and fluorine substitution for C-C bond formation. Angewandte Chemie (International Ed. in English). 50: 2588-92. PMID 21370343 DOI: 10.1002/Anie.201006931 |
0.667 |
|
| 2011 |
Prakash GK, Ni C, Wang F, Hu J, Olah GA. From difluoromethyl 2-pyridyl sulfone to difluorinated sulfonates: a protocol for nucleophilic difluoro(sulfonato)methylation. Angewandte Chemie (International Ed. in English). 50: 2559-63. PMID 21370337 DOI: 10.1002/Anie.201007594 |
0.522 |
|
| 2011 |
Wang F, Zhang W, Zhu J, Li H, Huang KW, Hu J. Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes. Chemical Communications (Cambridge, England). 47: 2411-3. PMID 21170456 DOI: 10.1039/C0Cc04548A |
0.419 |
|
| 2011 |
Zhao Y, Huang W, Zheng J, Hu J. Difluoromethylation of Carbonyls and Imines with TMSCF2H Synfacts. 2011: 1355-1355. DOI: 10.1055/S-0031-1289357 |
0.665 |
|
| 2011 |
Zhu J, Wang F, Huang W, Zhao Y, Ye W, Hu J. Copper-mediated fluoroalkylation reactions with [(phenylsulfonyl)- difluoromethyl]trimethylsilane: Synthesis of PhSO2CF 2-containing allenes and alkynes Synlett. 899-902. DOI: 10.1055/S-0030-1259676 |
0.633 |
|
| 2011 |
Wang F, Zhang L, Zheng J, Hu J. Chlorodifluoromethyl aryl ketones and sulfones as difluorocarbene reagents: The substituent effect Journal of Fluorine Chemistry. 132: 521-528. DOI: 10.1016/J.Jfluchem.2011.05.009 |
0.401 |
|
| 2011 |
Zhu J, Wang F, Hu J. Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides Science China Chemistry. 54: 95-102. DOI: 10.1007/S11426-010-4139-0 |
0.351 |
|
| 2011 |
Wang F, Huang W, Hu J. Difluoromethylation of O-, S-, N-, C-nucleophiles using difluoromethyltri(n-butyl)ammonium chloride as a new difluorocarbene source Chinese Journal of Chemistry. 29: 2717-2721. DOI: 10.1002/Cjoc.201100325 |
0.322 |
|
| 2011 |
Wang F, Zhang L, Zheng J, Hu J. ChemInform Abstract: Chlorodifluoromethyl Aryl Ketones and Sulfones as Difluorocarbene Reagents: The Substituent Effect. Cheminform. 42: no-no. DOI: 10.1002/chin.201148030 |
0.376 |
|
| 2011 |
Zhu J, Wang F, Huang W, Zhao Y, Ye W, Hu J. ChemInform Abstract: Copper-Mediated Fluoroalkylation Reactions with [(Phenylsulfonyl)difluoromethyl]trimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. Cheminform. 42: no-no. DOI: 10.1002/chin.201133074 |
0.628 |
|
| 2011 |
Zhang W, Hu J. ChemInform Abstract: Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines. Cheminform. 42: no-no. DOI: 10.1002/chin.201111111 |
0.386 |
|
| 2011 |
Zhu L, Li Y, Zhao Y, Hu J. ChemInform Abstract: Nucleophilic (Phenylsulfonyl)difluoromethylation of Alkyl Halides Using PhSO2CF2SiMe3: Preparation of gem-Difluoroalkenes and Trifluoromethyl Compounds. Cheminform. 42: no-no. DOI: 10.1002/chin.201109063 |
0.585 |
|
| 2010 |
Liu J, Hu J. Highly diastereoselective synthesis of α-difluoromethyl amines from N-tert-butylsulfinyl ketimines and difluoromethyl phenyl sulfone. Chemistry (Weinheim An Der Bergstrasse, Germany). 16: 11443-54. PMID 20725920 DOI: 10.1002/Chem.201000893 |
0.443 |
|
| 2010 |
Zhu J, Zhang W, Zhang L, Liu J, Zheng J, Hu J. Copper-mediated fluoroalkylation reactions with iododifluoroacetamides: controlling the selectivity among cross-coupling, intramolecular cyclization, and homocoupling reactions. The Journal of Organic Chemistry. 75: 5505-12. PMID 20704426 DOI: 10.1021/Jo1005262 |
0.427 |
|
| 2010 |
Prakash GK, Wang Y, Mogi R, Hu J, Mathew T, Olah GA. Nucleophilic perfluoroalkylation of imines and carbonyls: perfluoroalkyl sulfones as efficient perfluoroalkyl-transfer motifs. Organic Letters. 12: 2932-5. PMID 20518520 DOI: 10.1021/Ol100918D |
0.561 |
|
| 2010 |
Zhao Y, Huang W, Zhu L, Hu J. Difluoromethyl 2-pyridyl sulfone: a new gem-difluoroolefination reagent for aldehydes and ketones. Organic Letters. 12: 1444-7. PMID 20210302 DOI: 10.1021/Ol100090R |
0.654 |
|
| 2010 |
Zhang W, Huang W, Hu J. Synthesis of Fluoroalkenes from Fluorosulfoximines and Nitrones Synfacts. 2010: 326-326. DOI: 10.1055/S-0029-1219331 |
0.395 |
|
| 2010 |
Zhao Y, Zhu J, Ni C, Hu J. Magnesium metal-mediated reductive trifluoromethylation of aldehydes with phenyl trifluoromethyl sulfone Synthesis. 1899-1904. DOI: 10.1055/S-0029-1218752 |
0.612 |
|
| 2010 |
Zhu L, Li Y, Zhao Y, Hu J. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: Preparation of gem-difluoroalkenes and trifluoromethyl compounds Tetrahedron Letters. 51: 6150-6152. DOI: 10.1016/J.Tetlet.2010.09.068 |
0.653 |
|
| 2010 |
Zemtsov AA, Levin VV, Dilman AD, Struchkova MI, Belyakov PA, Tartakovsky VA, Hu J. Reaction of Baylis-Hillman adducts with fluorinated silanes European Journal of Organic Chemistry. 6779-6785. DOI: 10.1002/Ejoc.201001051 |
0.485 |
|
| 2010 |
Zhu L, Ni C, Zhao Y, Hu J. ChemInform Abstract: 1-tert-Butyl-1H-tetrazol-5-yl Fluoromethyl Sulfone (TBTSO2CH2F): A Versatile Fluoromethylidene Synthon and Its Use in the Synthesis of Monofluorinated Alkenes via Julia-Kocienski Olefination. Cheminform. 41: no-no. DOI: 10.1002/chin.201046043 |
0.578 |
|
| 2010 |
Zhao Y, Zhu J, Ni C, Hu J. ChemInform Abstract: Magnesium Metal Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone. Cheminform. 41: no-no. DOI: 10.1002/chin.201041062 |
0.525 |
|
| 2010 |
Liu J, Hu J. ChemInform Abstract: Synthesis of Fluorinated Chiral Amines Using N-(tert-butyl)sulfinyl Imines Cheminform. 41. DOI: 10.1002/chin.201020237 |
0.307 |
|
| 2010 |
Prakash GKS, Hu J, Olah GA. ChemInform Abstract: Facile Preparation of Di- and Monofluoromethyl Ketones from Trifluoromethyl Ketones via Fluorinated Enol Silyl Ethers. Cheminform. 33: no-no. DOI: 10.1002/chin.200216056 |
0.383 |
|
| 2010 |
Zhang W, Hu J. Efficient synthesis and ring-opening reactions of monofluorinated epoxides derived from α-fluorosulfoximines Advanced Synthesis and Catalysis. 352: 2799-2804. DOI: 10.1002/Adsc.201000499 |
0.481 |
|
| 2009 |
Liu J, Hu J. Synthesis of fluorinated chiral amines using N-tert-butylsulfinyl imines. Future Medicinal Chemistry. 1: 875-88. PMID 21426086 DOI: 10.4155/Fmc.09.62 |
0.453 |
|
| 2009 |
Hu J, Zhang W, Wang F. Selective difluoromethylation and monofluoromethylation reactions. Chemical Communications (Cambridge, England). 7465-78. PMID 20024251 DOI: 10.1039/B916463D |
0.357 |
|
| 2009 |
Zhang W, Huang W, Hu J. Highly stereoselective synthesis of monofluoroalkenes from alpha-fluorosulfoximines and nitrones. Angewandte Chemie (International Ed. in English). 48: 9858-61. PMID 19937885 DOI: 10.1002/Anie.200905077 |
0.303 |
|
| 2009 |
Zhang W, Wang F, Hu J. N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: a new difluoromethylation reagent for S-, N-, and C-nucleophiles. Organic Letters. 11: 2109-12. PMID 19368376 DOI: 10.1021/Ol900567C |
0.419 |
|
| 2009 |
Zhang L, Zhang W, Liu J, Hu J. C-F bond cleavage by intramolecular S(N)2 reaction of alkyl fluorides with O- and N-nucleophiles. The Journal of Organic Chemistry. 74: 2850-3. PMID 19323576 DOI: 10.1021/Jo802819P |
0.462 |
|
| 2009 |
Ni C, Hu J. Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles Tetrahedron Letters. 50: 7252-7255. DOI: 10.1016/J.Tetlet.2009.09.126 |
0.516 |
|
| 2009 |
Li Y, Li H, Hu J. Free radical (phenylsulfonyl)difluoromethylation of alkynes with PhSO2CF2I reagent: stereoselective preparation of PhSO2CF2- and CF2H-substituted alkenes Tetrahedron. 65: 478-483. DOI: 10.1016/J.Tet.2008.11.011 |
0.457 |
|
| 2009 |
Hu J. Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations Journal of Fluorine Chemistry. 130: 1130-1139. DOI: 10.1016/J.Jfluchem.2009.05.016 |
0.339 |
|
| 2009 |
Li Y, Li H, Hu J. ChemInform Abstract: Free Radical (Phenylsulfonyl)difluoromethylation of Alkynes with PhSO2CF2I Reagent: Stereoselective Preparation of PhSO2CF2- and CF2H-Substituted Alkenes. Cheminform. 40. DOI: 10.1002/chin.200922070 |
0.321 |
|
| 2008 |
Ni C, Wang F, Hu J. Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H reagents catalyzed by chiral quaternary ammonium salts. Beilstein Journal of Organic Chemistry. 4: 21. PMID 18941491 DOI: 10.3762/Bjoc.4.21 |
0.496 |
|
| 2008 |
Zhang W, Zhu J, Hu J. Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)–CF2SO2Ph reagent Tetrahedron Letters. 49: 5006-5008. DOI: 10.1016/J.Tetlet.2008.06.064 |
0.451 |
|
| 2008 |
Liu J, Ni C, Wang F, Hu J. Stereoselective synthesis of α-difluoromethyl-β-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph Tetrahedron Letters. 49: 1605-1608. DOI: 10.1016/J.Tetlet.2008.01.034 |
0.393 |
|
| 2008 |
Li Y, Hu J. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds Journal of Fluorine Chemistry. 129: 382-385. DOI: 10.1016/J.Jfluchem.2008.01.010 |
0.498 |
|
| 2007 |
Abid M, Savolainen M, Landge S, Hu J, Surya Prakash GK, Olah GA, Török B. SYNTHESIS OF TRIFLUOROMETHYL-IMINES BY SOLID ACID/SUPERACID CATALYZED MICROWAVE ASSISTED APPROACH. Journal of Fluorine Chemistry. 128: 587-594. PMID 21949445 DOI: 10.1016/J.Jfluchem.2007.01.011 |
0.559 |
|
| 2007 |
Prakash GK, Hu J. Selective fluoroalkylations with fluorinated sulfones, sulfoxides, and sulfides. Accounts of Chemical Research. 40: 921-30. PMID 17708659 DOI: 10.1021/Ar700149S |
0.475 |
|
| 2007 |
Li Y, Liu J, Zhang L, Zhu L, Hu J. Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone. The Journal of Organic Chemistry. 72: 5824-7. PMID 17590048 DOI: 10.1021/jo070618s |
0.326 |
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| 2007 |
Li Y, Hu J. Stereoselective difluoromethylenation using Me3SiCF2SPh: synthesis of chiral 2,4-disubstituted 3,3-difluoropyrrolidines. Angewandte Chemie (International Ed. in English). 46: 2489-92. PMID 17328020 DOI: 10.1002/Anie.200604783 |
0.413 |
|
| 2007 |
Zhang W, Zhu L, Hu J. Electrophilic monofluoromethylation of O-, S-, and N-nucleophiles with chlorofluoromethane Tetrahedron. 63: 10569-10575. DOI: 10.1016/J.Tet.2007.08.043 |
0.379 |
|
| 2007 |
Zhu L, Li Y, Ni C, Hu J, Beier P, Wang Y, Surya Prakash GK, Olah GA. Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide Journal of Fluorine Chemistry. 128: 1241-1247. DOI: 10.1016/J.Jfluchem.2007.05.003 |
0.473 |
|
| 2007 |
Mogi R, Morisaki K, Hu J, Prakash GS, Olah GA. Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group Journal of Fluorine Chemistry. 128: 1098-1103. DOI: 10.1016/J.Jfluchem.2007.03.013 |
0.409 |
|
| 2006 |
Zhang L, Zheng J, Hu J. 2-Chloro-2,2-difluoroacetophenone: a non-ODS-based difluorocarbene precursor and its use in the difluoromethylation of phenol derivatives. The Journal of Organic Chemistry. 71: 9845-8. PMID 17168605 DOI: 10.1021/jo061799l |
0.321 |
|
| 2006 |
Li Y, Ni C, Liu J, Zhang L, Zheng J, Zhu L, Hu J. Stereoselective nucleophilic monofluoromethylation of N-(tert-butanesulfinyl)imines with fluoromethyl phenyl sulfone. Organic Letters. 8: 1693-6. PMID 16597143 DOI: 10.1021/Ol060322T |
0.387 |
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| 2006 |
Hu J, Li Y, Ni C, Liu J, Zhang L, Zheng J, Zhu L. Stereoselective Nucleophilic Monofluoromethylation of Sulfinylimines Synfacts. 2006: 0577-0577. DOI: 10.1055/S-2006-934471 |
0.507 |
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| 2006 |
Liu J, Ni C, Li Y, Zhang L, Wang G, Hu J. Facile preparation of difluoromethyl- and monofluoromethyl-containing amides via Ritter reaction Tetrahedron Letters. 47: 6753-6756. DOI: 10.1016/j.tetlet.2006.07.079 |
0.334 |
|
| 2006 |
Ni C, Hu J. Nucleophilic Difluoromethylation of Carbonyl Compounds Using TMSCF2SO2Ph and Mg0-Mediated Desulfonylation. Cheminform. 37. DOI: 10.1016/J.Tetlet.2005.09.162 |
0.398 |
|
| 2006 |
Prakash GS, Wang Y, Hu J, Olah GA. Erratum to “Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone” [J. Fluorine Chem. 126 (9–10) (2005) 1361–1367] Journal of Fluorine Chemistry. 127: 296. DOI: 10.1016/J.Jfluchem.2005.10.002 |
0.38 |
|
| 2006 |
Liu J, Ni C, Li Y, Zhang L, Wang G, Hu J. Facile Preparation of Difluoromethyl- and Monofluoromethyl-Containing Amides via Ritter Reaction. Cheminform. 37. DOI: 10.1002/chin.200652070 |
0.334 |
|
| 2006 |
Prakash GKS, Wang Y, Hu J, Olah GA. Nucleophilic Difluoromethylation and Difluoromethylenation Using Bromodifluoromethyl Phenyl Sulfone. Cheminform. 37. DOI: 10.1002/chin.200606076 |
0.373 |
|
| 2005 |
Li Y, Hu J. Facile synthesis of chiral alpha-difluoromethyl amines from N-(tert-butylsulfinyl)aldimines. Angewandte Chemie (International Ed. in English). 44: 5882-6. PMID 16149118 DOI: 10.1002/Anie.200501769 |
0.335 |
|
| 2005 |
Reddy VP, Smart MC, Chin KB, Ratnakumar BV, Surampudi S, Hu J, Yan P, Prakash GKS. 13C NMR spectroscopic, CY, and conductivity studies of propylene carbonate-based electrolytes containing various lithium salts Electrochemical and Solid-State Letters. 8: A294-A298. DOI: 10.1149/1.1904466 |
0.428 |
|
| 2005 |
Surya Prakash GK, Wang Y, Hu J, Olah GA. Nucleophilic difluoromethylation and difluoromethylenation using bromodifluoromethyl phenyl sulfone Journal of Fluorine Chemistry. 126: 1361-1367. DOI: 10.1016/J.Jfluchem.2005.07.011 |
0.385 |
|
| 2005 |
Prakash GS, Hu J, Wang Y, Olah GA. Fluoride-induced nucleophilic (phenylthio)difluoromethylation of carbonyl compounds with [difluoro(phenylthio)methyl]trimethylsilane (TMS–CF2SPh) Journal of Fluorine Chemistry. 126: 527-532. DOI: 10.1016/J.Jfluchem.2004.12.005 |
0.464 |
|
| 2005 |
Prakash GKS, Hu J, Wang Y, Olah GA. Convenient Synthesis of Difluoromethyl Alcohols from Both Enolizable and Non-Enolizable Carbonyl Compounds with Difluoromethyl Phenyl Sulfone. Cheminform. 36. DOI: 10.1002/Ejoc.200500101 |
0.331 |
|
| 2005 |
Surya Prakash GK, Hu J, Wang Y, Olah GA. Convenient Synthesis of Difluoromethyl Alcohols from Both Enolizable and Non-Enolizable Carbonyl Compounds with Difluoromethyl Phenyl Sulfone European Journal of Organic Chemistry. 2005: 2218-2223. DOI: 10.1002/ejoc.200500101 |
0.392 |
|
| 2004 |
Prakash GK, Hu J, Wang Y, Olah GA. Nucleophilic difluoromethylation of primary alkyl halides using difluoromethyl phenyl sulfone as a difluoromethyl anion equivalent. Organic Letters. 6: 4315-7. PMID 15524472 DOI: 10.1021/Ol048166I |
0.51 |
|
| 2004 |
Prakash GK, Hu J, Wang Y, Olah GA. Difluoromethyl phenyl sulfone, a difluoromethylidene equivalent: use in the synthesis of 1,1-difluoro-1-alkenes. Angewandte Chemie (International Ed. in English). 43: 5203-6. PMID 15455416 DOI: 10.1002/Anie.200460815 |
0.481 |
|
| 2004 |
Prakash G, Hu J, Simon J, Bellew DR, Olah GA. Preparation of α,α-difluoroalkanesulfonic acids Journal of Fluorine Chemistry. 125: 595-601. DOI: 10.1016/j.jfluchem.2003.11.031 |
0.475 |
|
| 2004 |
Warner WN, Hu J, Prakash GKS, Olah GA, Hogen-Esch TE. Mechanism of the anionic polymerization of methyl methacrylate initiated by tetramethylammonium-triphenylmethide in tetrahydrofuran Journal of Polymer Science, Part a: Polymer Chemistry. 42: 237-244. DOI: 10.1002/Pola.11019 |
0.471 |
|
| 2003 |
Prakash GK, Hu J, Mathew T, Olah GA. Difluoromethyl phenyl sulfone as a selective difluoromethylene dianion equivalent: one-pot stereoselective synthesis of anti-2,2-difluoropropane-1,3-diols. Angewandte Chemie (International Ed. in English). 42: 5216-9. PMID 14601176 DOI: 10.1002/Anie.200352172 |
0.451 |
|
| 2003 |
Prakash GK, Hu J, Olah GA. Alkoxide- and hydroxide-induced nucleophilic trifluoromethylation using trifluoromethyl sulfone or sulfoxide. Organic Letters. 5: 3253-6. PMID 12943400 DOI: 10.1021/Ol035045U |
0.426 |
|
| 2003 |
Prakash GK, Hu J, Olah GA. Preparation of tri- and difluoromethylsilanes via an unusual magnesium metal-mediated reductive tri- and difluoromethylation of chlorosilanes using tri- and difluoromethyl sulfides, sulfoxides, and sulfones. The Journal of Organic Chemistry. 68: 4457-63. PMID 12762751 DOI: 10.1021/Jo030110Z |
0.45 |
|
| 2003 |
Prakash GKS, Hu J, Olah GA. Alkylation of in situ generated fluorinated alkoxides: novel synthesis of partially fluorinated ethers Arkivoc. 2003. DOI: 10.3998/Ark.5550190.0004.311 |
0.486 |
|
| 2003 |
Smart MC, Ratnakumar BV, Ryan-Mowrey VS, Surampudi S, Prakash GKS, Hu J, Cheung I. Improved performance of lithium-ion cells with the use of fluorinated carbonate-based electrolytes Journal of Power Sources. 119: 359-367. DOI: 10.1016/S0378-7753(03)00266-0 |
0.547 |
|
| 2003 |
Prakash GKS, Hu J, Alauddin MM, Conti PS, Olah GA. A General Method of Halogenation for Synthesis of α-Halodifluoromethyl Ketones and [18F]-Labeled Trifluoromethyl Ketones. Cheminform. 34. DOI: 10.1016/S0022-1139(03)00039-3 |
0.328 |
|
| 2003 |
Prakash GKS, Hu J, Alauddin MM, Conti PS, Olah GA. A general method of halogenation for synthesis of α-halodifluoromethyl ketones and [18F]-labeled trifluoromethyl ketones Journal of Fluorine Chemistry. 121: 239-243. DOI: 10.1016/S0022-1139(03)00039-3 |
0.419 |
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| 2003 |
Prakash GKS, Alauddin MM, Hu J, Conti PS, Olah GA. Expedient synthesis of [18F]-labeled α-trifluoromethyl ketones Journal of Labelled Compounds and Radiopharmaceuticals. 46: 1087-1092. DOI: 10.1002/Jlcr.741 |
0.497 |
|
| 2001 |
Surya Prakash G, Hu J, Olah GA. Facile preparation of di- and monofluoromethyl ketones from trifluoromethyl ketones via fluorinated enol silyl ethers Journal of Fluorine Chemistry. 112: 355-360. DOI: 10.1016/S0022-1139(01)00535-8 |
0.521 |
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