William B. Tolman - Publications

Affiliations: 
Chemistry University of Minnesota, Twin Cities, Minneapolis, MN 
Area:
Inorganic Chemistry; Organic Chemistry; Chemical Biology; Polymer Chemistry
Website:
http://www.chem.umn.edu/directory/faculty.lasso?serial=425

209 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Krishnan VM, Shopov DY, Bouchey CJ, Bailey WD, Parveen R, Vlaisavljevich B, Tolman WB. Structural Characterization of the [CuOR] Core. Journal of the American Chemical Society. PMID 33621089 DOI: 10.1021/jacs.0c13470  0.44
2020 Popowski Y, Moreno JJ, Nichols AW, Hooe SL, Bouchey CJ, Rath NP, Machan CW, Tolman WB. Mechanistic insight into initiation and regioselectivity in the copolymerization of epoxides and anhydrides by Al complexes. Chemical Communications (Cambridge, England). PMID 33099587 DOI: 10.1039/d0cc05652a  0.44
2019 Elwell CE, Mandal M, Bouchey CJ, Que L, Cramer CJ, Tolman WB. Carboxylate Structural Effects on the Properties and Proton-Coupled Electron Transfer Reactivity of [CuOCR] Cores. Inorganic Chemistry. PMID 31710477 DOI: 10.1021/acs.inorgchem.9b02293  1
2019 Mandal M, Elwell CE, Bouchey CJ, Zerk TJ, Tolman WB, Cramer CJ. Mechanisms for Hydrogen-Atom Abstraction by Mononuclear Copper(III) Cores: Hydrogen-Atom Transfer or Concerted Proton-Coupled Electron Transfer? Journal of the American Chemical Society. PMID 31617707 DOI: 10.1021/jacs.9b08109  1
2019 Zerk TJ, Saouma CT, Mayer JM, Tolman WB. Low Reorganization Energy for Electron Self-Exchange by a Formally Copper(III,II) Redox Couple. Inorganic Chemistry. PMID 31577145 DOI: 10.1021/acs.inorgchem.9b02185  0.44
2019 Elwell CE, Neisen BD, Tolman WB. Copper Complexes of Multidentate Carboxamide Ligands. Inorganica Chimica Acta. 485: 131-139. PMID 31105329 DOI: 10.1016/j.ica.2018.10.011  0.56
2019 Bailey WD, Dhar D, Cramblitt AC, Tolman WB. Mechanistic Dichotomy in Proton-Coupled Electron-Transfer Reactions of Phenols with a Copper Superoxide Complex. Journal of the American Chemical Society. PMID 30907590 DOI: 10.1021/jacs.9b00466  0.56
2019 Bailey WD, Gagnon NL, Elwell CE, Cramblitt AC, Bouchey CJ, Tolman WB. Revisiting the Synthesis and Nucleophilic Reactivity of an Anionic Copper Superoxide Complex. Inorganic Chemistry. PMID 30901201 DOI: 10.1021/acs.inorgchem.9b00090  0.44
2018 Dhar D, Yee GM, Tolman WB. Effects of Charged Ligand Substituents on the Properties of the Formally Copper(III)-Hydroxide ([CuOH]) Unit. Inorganic Chemistry. PMID 30070473 DOI: 10.1021/acs.inorgchem.8b01529  0.56
2018 Fieser ME, Schimler SD, Mitchell LA, Wilborn EG, John A, Hogan LT, Benson B, LaPointe AM, Tolman WB. Dual-catalytic decarbonylation of fatty acid methyl esters to form olefins. Chemical Communications (Cambridge, England). PMID 29938264 DOI: 10.1039/c8cc03823f  0.68
2018 Macaranas JA, Luke AM, Mandal M, Neisen BD, Marell DJ, Cramer CJ, Tolman WB. Sterically Induced Ligand Framework Distortion Effects on Catalytic Cyclic Ester Polymerizations. Inorganic Chemistry. PMID 29485872 DOI: 10.1021/acs.inorgchem.8b00250  1
2017 Stasiw DE, Luke AM, Rosen T, League AB, Mandal M, Neisen BD, Cramer CJ, Kol M, Tolman WB. Mechanism of the Polymerization of rac-Lactide by Fast Zinc Alkoxide Catalysts. Inorganic Chemistry. PMID 29116765 DOI: 10.1021/acs.inorgchem.7b02544  1
2017 Fieser ME, Sanford MJ, Mitchell LA, Dunbar CR, Mandal M, Van Zee NJ, Urness DM, Cramer CJ, Coates GW, Tolman WB. Mechanistic Insights into the Alternating Copolymerization of Epoxides and Cyclic Anhydrides Using a (Salph)AlCl and Iminium Salt Catalytic System. Journal of the American Chemical Society. PMID 28984455 DOI: 10.1021/jacs.7b09079  1
2017 Neisen BD, Gagnon NL, Dhar D, Spaeth AD, Tolman WB. Formally Copper(III)-Alkylperoxo Complexes as Models of Possible Intermediates in Monooxygenase Enzymes. Journal of the American Chemical Society. PMID 28722408 DOI: 10.1021/jacs.7b05754  0.56
2017 Dhar D, Yee GM, Markle TF, Mayer JM, Tolman WB. Reactivity of the copper(iii)-hydroxide unit with phenols. Chemical Science. 8: 1075-1085. PMID 28572905 DOI: 10.1039/c6sc03039d  0.56
2017 Spaeth AD, Gagnon NL, Dhar D, Yee GM, Tolman WB. Determination of the Cu(III)-OH Bond Distance by Resonance Raman Spectroscopy Using a Normalized Version of Badger's Rule. Journal of the American Chemical Society. PMID 28319386 DOI: 10.1021/jacs.7b00210  0.56
2017 Elwell CE, Gagnon NL, Neisen BD, Dhar D, Spaeth AD, Yee GM, Tolman WB. Copper-Oxygen Complexes Revisited: Structures, Spectroscopy, and Reactivity. Chemical Reviews. PMID 28103018 DOI: 10.1021/acs.chemrev.6b00636  0.56
2016 Macaranas JA, Fieser ME, Luke AM, Mandal M, Cramer CJ, Tolman WB. Correction to Understanding the Mechanism of Polymerization of ε-Caprolactone Catalyzed by Aluminum Salen Complexes. Inorganic Chemistry. PMID 28029242 DOI: 10.1021/acs.inorgchem.6b03059  1
2016 Stasiw DE, Mandal M, Neisen BD, Mitchell LA, Cramer CJ, Tolman WB. Why So Slow? Mechanistic Insights from Studies of a Poor Catalyst for Polymerization of ε-Caprolactone. Inorganic Chemistry. PMID 28005338 DOI: 10.1021/acs.inorgchem.6b02849  1
2016 Marlier EE, Macaranas JA, Marell DJ, Dunbar CR, Johnson MA, DePorre Y, Miranda MO, Neisen BD, Cramer CJ, Hillmyer MA, Tolman WB. Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations. Acs Catalysis. 6: 1215-1224. PMID 26900488 DOI: 10.1021/acscatal.5b02607  1
2016 Marlier EE, MacAranas JA, Marell DJ, Dunbar CR, Johnson MA, DePorre Y, Miranda MO, Neisen BD, Cramer CJ, Hillmyer MA, Tolman WB. Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations Acs Catalysis. 6: 1215-1224. DOI: 10.1021/acscatal.5b02607  1
2015 Neisen BD, Solntsev P, Halvagar MR, Tolman WB. Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating Bis(carboxamide) Ligands. European Journal of Inorganic Chemistry. 2015: 5856-5863. PMID 27840589 DOI: 10.1002/ejic.201501060  0.56
2015 Dhar D, Yee GM, Spaeth AD, Boyce DW, Zhang H, Dereli B, Cramer CJ, Tolman WB. Perturbing the Copper(III)-Hydroxide Unit through Ligand Structural Variation. Journal of the American Chemical Society. PMID 26693733 DOI: 10.1021/jacs.5b10985  1
2015 Ding K, John A, Shin J, Lee Y, Quinn T, Tolman WB, Hillmyer MA. High-Performance Pressure-Sensitive Adhesives from Renewable Triblock Copolymers. Biomacromolecules. 16: 2537-9. PMID 26214728 DOI: 10.1021/acs.biomac.5b00754  1
2015 Eisenhart RJ, Rudd PA, Planas N, Boyce DW, Carlson RK, Tolman WB, Bill E, Gagliardi L, Lu CC. Pushing the Limits of Delta Bonding in Metal-Chromium Complexes with Redox Changes and Metal Swapping. Inorganic Chemistry. PMID 26168331 DOI: 10.1021/acs.inorgchem.5b01163  1
2015 Gagnon N, Tolman WB. [CuO](+) and [CuOH](2+) Complexes: Intermediates in Oxidation Catalysis? Accounts of Chemical Research. PMID 26075312 DOI: 10.1021/acs.accounts.5b00169  1
2015 Meyer F, Tolman WB. Forums on small-molecule activation: from biological principles to energy applications. Inorganic Chemistry. 54: 5039. PMID 26027479 DOI: 10.1021/acs.inorgchem.5b00768  1
2015 Yee GM, Tolman WB. Transition metal complexes and the activation of dioxygen. Metal Ions in Life Sciences. 15: 131-204. PMID 25707468 DOI: 10.1007/978-3-319-12415-5_5  1
2015 Dhar D, Tolman WB. Hydrogen atom abstraction from hydrocarbons by a copper(III)-hydroxide complex. Journal of the American Chemical Society. 137: 1322-9. PMID 25581555 DOI: 10.1021/ja512014z  1
2015 John A, Hogan LT, Hillmyer MA, Tolman WB. Olefins from biomass feedstocks: catalytic ester decarbonylation and tandem Heck-type coupling. Chemical Communications (Cambridge, England). 51: 2731-3. PMID 25579879 DOI: 10.1039/c4cc09003a  1
2015 Tolman WB. @InorgChem. Inorganic Chemistry. 54: 1-3. PMID 25556955 DOI: 10.1021/ic502893j  1
2015 Shearouse WC, Lillie LM, Reineke TM, Tolman WB. Sustainable Polyesters Derived from Glucose and Castor Oil: Building Block Structure Impacts Properties Acs Macro Letters. 4: 284-288. DOI: 10.1021/acsmacrolett.5b00099  1
2015 Neisen BD, Solntsev PV, Halvagar MR, Tolman WB. Secondary Sphere Hydrogen Bonding in Monocopper Complexes of Potentially Dinucleating Bis(carboxamide) Ligands European Journal of Inorganic Chemistry. DOI: 10.1002/ejic.201501060  1
2014 Börjesson K, ?oso D, Gray V, Grossman JC, Guan J, Harris CB, Hertkorn N, Hou Z, Kanai Y, Lee D, Lomont JP, Majumdar A, Meier SK, Moth-Poulsen K, Myrabo RL, ... ... Tolman WB, et al. Exploring the potential of fulvalene dimetals as platforms for molecular solar thermal energy storage: computations, syntheses, structures, kinetics, and catalysis. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 15587-604. PMID 25284044 DOI: 10.1002/chem.201404170  1
2014 Hillmyer MA, Tolman WB. Aliphatic polyester block polymers: renewable, degradable, and sustainable. Accounts of Chemical Research. 47: 2390-6. PMID 24852135 DOI: 10.1021/ar500121d  1
2014 Halvagar MR, Solntsev PV, Lim H, Hedman B, Hodgson KO, Solomon EI, Cramer CJ, Tolman WB. Hydroxo-bridged dicopper(II,III) and -(III,III) complexes: models for putative intermediates in oxidation catalysis. Journal of the American Chemical Society. 136: 7269-72. PMID 24821432 DOI: 10.1021/ja503629r  1
2014 Boyce DW, Salmon DJ, Tolman WB. Linkage isomerism in transition-metal complexes of mixed (arylcarboxamido)(arylimino)pyridine ligands. Inorganic Chemistry. 53: 5788-96. PMID 24819403 DOI: 10.1021/ic500638z  1
2014 Scheuermann ML, Boyce DW, Grice KA, Kaminsky W, Stoll S, Tolman WB, Swang O, Goldberg KI. Oxygen-promoted C-H bond activation at palladium. Angewandte Chemie (International Ed. in English). 53: 6492-5. PMID 24817523 DOI: 10.1002/anie.201402484  1
2014 Tolman WB. Reflections on year one Inorganic Chemistry. 53: 1-2. DOI: 10.1021/ic403065b  1
2013 Tehranchi J, Donoghue PJ, Cramer CJ, Tolman WB. Reactivity of (Dicarboxamide)M(II)-OH (M = Cu, Ni) Complexes: Reaction with Acetonitrile to Yield M(II)-Cyanomethides. European Journal of Inorganic Chemistry. 2013. PMID 24415908 DOI: 10.1002/ejic.201300328  1
2013 Miranda MO, DePorre Y, Vazquez-Lima H, Johnson MA, Marell DJ, Cramer CJ, Tolman WB. Understanding the mechanism of polymerization of ε-caprolactone catalyzed by aluminum salen complexes. Inorganic Chemistry. 52: 13692-701. PMID 24219558 DOI: 10.1021/ic402255m  1
2013 Halvagar MR, Tolman WB. Isolation of a 2-hydroxytetrahydrofuran complex from copper-promoted hydroxylation of THF. Inorganic Chemistry. 52: 8306-8. PMID 23886308 DOI: 10.1021/ic401446s  1
2013 Tolman WB. Editorial for the virtual issue on models of metalloenzymes. Inorganic Chemistry. 52: 7307-10. PMID 23819601 DOI: 10.1021/ic4013813  1
2013 Halvagar MR, Neisen B, Tolman WB. Copper-, palladium-, and platinum-containing complexes of an asymmetric dinucleating ligand. Inorganic Chemistry. 52: 793-9. PMID 23268657 DOI: 10.1021/ic301914u  1
2013 Knight SC, Schaller CP, Tolman WB, Hillmyer MA. Renewable carvone-based polyols for use in polyurethane thermosets Rsc Advances. 3: 20399-20404. DOI: 10.1039/c3ra44084b  1
2013 Tolman WB. Editorial: A change of the guard Inorganic Chemistry. 52: 1-2. DOI: 10.1021/ic3026073  1
2013 McGarry KA, Hurley KR, Volp KA, Hill IM, Merritt BA, Peterson KL, Rudd PA, Erickson NC, Seiler LA, Gupta P, Bates FS, Tolman WB. Student involvement in improving the culture of safety in academic laboratories Journal of Chemical Education. 90: 1414-1417. DOI: 10.1021/ed400305e  1
2013 Halvagar MR, Salmon DJ, Tolman WB. Small Molecule Models: Cu, Ni, Co Comprehensive Inorganic Chemistry Ii (Second Edition): From Elements to Applications. 3: 455-486. DOI: 10.1016/B978-0-08-097774-4.00321-1  1
2013 Salmon DJ, Tolman WB. Synthetic models of copper-nitrosyl species proposed as intermediates in biological denitrification Structure and Bonding. 154: 137-154. DOI: 10.1007/430-2013-93  1
2012 Shin J, Lee Y, Tolman WB, Hillmyer MA. Thermoplastic elastomers derived from menthide and tulipalin A. Biomacromolecules. 13: 3833-40. PMID 23062206 DOI: 10.1021/bm3012852  1
2012 Gupta AK, Tolman WB. Cu(I)/O2 chemistry using a β-diketiminate supporting ligand derived from N,N-dimethylhydrazine: a [Cu3O2]3+ complex with novel reactivity. Inorganic Chemistry. 51: 1881-8. PMID 22268598 DOI: 10.1021/ic202214c  1
2012 Taguchi T, Gupta R, Lassalle-Kaiser B, Boyce DW, Yachandra VK, Tolman WB, Yano J, Hendrich MP, Borovik AS. Preparation and properties of a monomeric high-spin Mn(V)-oxo complex. Journal of the American Chemical Society. 134: 1996-9. PMID 22233169 DOI: 10.1021/ja210957u  1
2012 Yang L, Tolman WB. Type 1 copper site synthetic model complexes with increased redox potentials. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 17: 285-91. PMID 21960257 DOI: 10.1007/s00775-011-0849-9  1
2012 Gurusamy-Thangavelu SA, Emond SJ, Kulshrestha A, Hillmyer MA, MacOsko CW, Tolman WB, Hoye TR. Polyurethanes based on renewable polyols from bioderived lactones Polymer Chemistry. 3: 2941-2948. DOI: 10.1039/c2py20454a  1
2012 Miranda MO, Pietrangelo A, Hillmyer MA, Tolman WB. Catalytic decarbonylation of biomass-derived carboxylic acids as efficient route to commodity monomers Green Chemistry. 14: 490-494. DOI: 10.1039/C2GC16115J  1
2012 Ding K, Miranda MO, Moscato-Goodpaster B, Ajellal N, Breyfogle LE, Hermes ED, Schaller CP, Roe SE, Cramer CJ, Hillmyer MA, Tolman WB. Roles of monomer binding and alkoxide nucleophilicity in aluminum-catalyzed polymerization of ε - Caprolactone Macromolecules. 45: 5387-5396. DOI: 10.1021/ma301130b  1
2011 Donoghue PJ, Tehranchi J, Cramer CJ, Sarangi R, Solomon EI, Tolman WB. Rapid C-H bond activation by a monocopper(III)-hydroxide complex. Journal of the American Chemical Society. 133: 17602-5. PMID 22004091 DOI: 10.1021/ja207882h  1
2011 Sarangi R, Yang L, Winikoff SG, Gagliardi L, Cramer CJ, Tolman WB, Solomon EI. X-ray absorption spectroscopic and computational investigation of a possible S···S interaction in the [Cu3S2]3+ core. Journal of the American Chemical Society. 133: 17180-91. PMID 21923178 DOI: 10.1021/ja111323m  1
2011 Yang L, Tehranchi J, Tolman WB. Reactions of Ph3Sb═S with copper(I) complexes supported by N-donor ligands: formation of stable adducts and S-transfer reactivity. Inorganic Chemistry. 50: 2606-12. PMID 21338053 DOI: 10.1021/ic102449m  1
2011 Lowe JR, Martello MT, Tolman WB, Hillmyer MA. Functional biorenewable polyesters from carvone-derived lactones Polymer Chemistry. 2: 702-708. DOI: 10.1039/c0py00283f  1
2011 Shin J, Martello MT, Shrestha M, Wissinger JE, Tolman WB, Hillmyer MA. Pressure-sensitive adhesives from renewable triblock copolymers Macromolecules. 44: 87-94. DOI: 10.1021/ma102216d  1
2010 Donoghue PJ, Gupta AK, Boyce DW, Cramer CJ, Tolman WB. An anionic, tetragonal copper(II) superoxide complex. Journal of the American Chemical Society. 132: 15869-71. PMID 20977226 DOI: 10.1021/ja106244k  1
2010 Pietrangelo A, Knight SC, Gupta AK, Yao LJ, Hillmyer MA, Tolman WB. Mechanistic study of the stereoselective polymerization of D,L-lactide using indium(III) halides. Journal of the American Chemical Society. 132: 11649-57. PMID 20672812 DOI: 10.1021/ja103841h  1
2010 Tolman WB, Solomon EI. Preface: Forum on dioxygen activation and reduction. Inorganic Chemistry. 49: 3555-6. PMID 20380456 DOI: 10.1021/ic100161a  1
2010 Gupta AK, Tolman WB. Copper/alpha-ketocarboxylate chemistry with supporting peralkylated diamines: reactivity of copper(I) complexes and dicopper-oxygen intermediates. Inorganic Chemistry. 49: 3531-9. PMID 20218646 DOI: 10.1021/ic100032n  1
2010 Tolman WB. Binding and activation of N2O at transition-metal centers: recent mechanistic insights. Angewandte Chemie (International Ed. in English). 49: 1018-24. PMID 20058284 DOI: 10.1002/anie.200905364  1
2009 Wanamaker CL, Bluemle MJ, Pitet LM, O'Leary LE, Tolman WB, Hillmyer MA. Consequences of polylactide stereochemistry on the properties of polylactide-polymenthide-polylactide thermoplastic elastomers. Biomacromolecules. 10: 2904-11. PMID 19775147 DOI: 10.1021/bm900721p  1
2009 Pietrangelo A, Hillmyer MA, Tolman WB. Stereoselective and controlled polymerization of D,L-lactide using indium(III) trichloride. Chemical Communications (Cambridge, England). 2736-7. PMID 19532938 DOI: 10.1039/b902968k  1
2009 Lowe JR, Tolman WB, Hillmyer MA. Oxidized dihydrocarvone as a renewable multifunctional monomer for the synthesis of shape memory polyesters. Biomacromolecules. 10: 2003-8. PMID 19505135 DOI: 10.1021/bm900471a  1
2009 Hong S, Hill LM, Gupta AK, Naab BD, Gilroy JB, Hicks RG, Cramer CJ, Tolman WB. Effects of electron-deficient beta-diketiminate and formazan supporting ligands on copper(I)-mediated dioxygen activation. Inorganic Chemistry. 48: 4514-23. PMID 19425614 DOI: 10.1021/ic9002466  1
2009 Hong S, Gupta AK, Tolman WB. Intermediates in reactions of copper(I) complexes with N-oxides: from the formation of stable adducts to oxo transfer. Inorganic Chemistry. 48: 6323-5. PMID 19425587 DOI: 10.1021/ic900435p  1
2009 Huber SM, Ertem MZ, Aquilante F, Gagliardi L, Tolman WB, Cramer CJ. Generating Cu(II)-oxyl/Cu(III)-oxo species from Cu(I)-alpha-ketocarboxylate complexes and O2: in silico studies on ligand effects and C-H-activation reactivity. Chemistry (Weinheim An Der Bergstrasse, Germany). 15: 4886-95. PMID 19322769 DOI: 10.1002/chem.200802338  1
2009 Bar-Nahum I, Gupta AK, Huber SM, Ertem MZ, Cramer CJ, Tolman WB. Reduction of nitrous oxide to dinitrogen by a mixed valent tricopper-disulfido cluster. Journal of the American Chemical Society. 131: 2812-4. PMID 19206272 DOI: 10.1021/ja808917k  1
2009 Wanamaker CL, Tolman WB, Hillmyer MA. Hydrolytic degradation behavior of a renewable thermoplastic elastomer. Biomacromolecules. 10: 443-8. PMID 19159199 DOI: 10.1021/bm801292v  1
2009 Wanamaker CL, Tolman WB, Hillmyer MA. 2-Biopolymers: Poly(D-lactide)-poly(menthide)-poly(D-lactide) triblock copolymers as crystal nucleating agents for poly(L-lactide) Macromolecular Symposia. 283: 130-138. DOI: 10.1002/masy.200950917  1
2008 York JT, Bar-Nahum I, Tolman WB. Copper-Sulfur Complexes Supported by N-Donor Ligands: Towards Models of the Cu(Z) Site in Nitrous Oxide Reductase. Inorganica Chimica Acta. 361: 885-893. PMID 19262681 DOI: 10.1016/j.ica.2007.06.047  1
2008 Que L, Tolman WB. Biologically inspired oxidation catalysis. Nature. 455: 333-40. PMID 18800132 DOI: 10.1038/nature07371  1
2008 Petrovic D, Hill LM, Jones PG, Tolman WB, Tamm M. Synthesis and reactivity of copper(I) complexes with an ethylene-bridged bis(imidazolin-2-imine) ligand. Dalton Transactions (Cambridge, England : 2003). 887-94. PMID 18259621 DOI: 10.1039/b715590e  1
2008 Friese SJ, Kucera BE, Young VG, Que L, Tolman WB. Iron(II) complexes of sterically bulky alpha-ketocarboxylates. structural models for alpha-ketoacid-dependent nonheme iron halogenases. Inorganic Chemistry. 47: 1324-31. PMID 18217706 DOI: 10.1021/ic701823y  1
2008 Sarangi R, York JT, Helton ME, Fujisawa K, Karlin KD, Tolman WB, Hodgson KO, Hedman B, Solomon EI. X-ray absorption spectroscopic and theoretical studies on (L)2[Cu2(S2)n]2+ complexes: disulfide versus disulfide(*1-) bonding. Journal of the American Chemical Society. 130: 676-86. PMID 18076173 DOI: 10.1021/ja0762745  1
2008 Bar-Nahum I, York JT, Young VG, Tolman WB. Novel reactivity of side-on (disulfido)dicopper complexes supported by bi- and tridentate nitrogen donors: impact of axial coordination. Angewandte Chemie (International Ed. in English). 47: 533-6. PMID 18058868 DOI: 10.1002/anie.200704690  1
2007 Wanamaker CL, O'Leary LE, Lynd NA, Hillmyer MA, Tolman WB. Renewable-resource thermoplastic elastomers based on polylactide and polymenthide. Biomacromolecules. 8: 3634-40. PMID 17960909 DOI: 10.1021/bm700699g  1
2007 Hong S, Huber SM, Gagliardi L, Cramer CC, Tolman WB. Copper(I)-alpha-ketocarboxylate complexes: characterization and O2 reactions that yield copper-oxygen intermediates capable of hydroxylating arenes. Journal of the American Chemical Society. 129: 14190-2. PMID 17958429 DOI: 10.1021/ja0760426  1
2007 York JT, Bar-Nahum I, Tolman WB. Structural diversity in copper-sulfur chemistry: synthesis of novel Cu/S clusters through metathesis reactions. Inorganic Chemistry. 46: 8105-7. PMID 17824695 DOI: 10.1021/ic700760p  1
2007 Silvernail CM, Yao LJ, Hill LM, Hillmyer MA, Tolman WB. Structural and mechanistic studies of bis(phenolato)amine zinc(II) catalysts for the polymerization of epsilon-caprolactone. Inorganic Chemistry. 46: 6565-74. PMID 17630684 DOI: 10.1021/ic700581s  1
2007 Brown EC, Johnson B, Palavicini S, Kucera BE, Casella L, Tolman WB. Modular syntheses of multidentate ligands with variable N-donors: applications to tri- and tetracopper(I) complexes. Dalton Transactions (Cambridge, England : 2003). 3035-42. PMID 17622421 DOI: 10.1039/b705806c  1
2007 York JT, Llobet A, Cramer CJ, Tolman WB. Heterobimetallic dioxygen activation: synthesis and reactivity of mixed Cu-Pd and Cu-Pt bis(mu-oxo) complexes. Journal of the American Chemical Society. 129: 7990-9. PMID 17550254 DOI: 10.1021/ja071744g  1
2007 Cramer CJ, Tolman WB. Mononuclear Cu-O2 complexes: geometries, spectroscopic properties, electronic structures, and reactivity. Accounts of Chemical Research. 40: 601-8. PMID 17458929 DOI: 10.1021/ar700008c  1
2007 Brown EC, Bar-Nahum I, York JT, Aboelella NW, Tolman WB. Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes. Inorganic Chemistry. 46: 486-96. PMID 17279827 DOI: 10.1021/ic061589r  1
2007 Drennan CL, Tolman WB. Bioinorganic chemistry. New vistas in bioinorganic chemistry Current Opinion in Chemical Biology. 11: 113-114. DOI: 10.1016/j.cbpa.2007.02.040  1
2006 Hill LM, Gherman BF, Aboelella NW, Cramer CJ, Tolman WB. Electronic tuning of beta-diketiminate ligands with fluorinated substituents: effects on the O2-reactivity of mononuclear Cu(I) complexes. Dalton Transactions (Cambridge, England : 2003). 4944-53. PMID 17047744 DOI: 10.1039/b609939d  1
2006 Heppner DE, Gherman BF, Tolman WB, Cramer CJ. Can an ancillary ligand lead to a thermodynamically stable end-on 1 : 1 Cu-O2 adduct supported by a beta-diketiminate ligand? Dalton Transactions (Cambridge, England : 2003). 4773-82. PMID 17033702 DOI: 10.1039/b608980a  1
2006 Gherman BF, Tolman WB, Cramer CJ. Characterization of the structure and reactivity of monocopper-oxygen complexes supported by beta-diketiminate and anilido-imine ligands. Journal of Computational Chemistry. 27: 1950-61. PMID 17019721 DOI: 10.1002/jcc.20502  1
2006 Klein DP, Young VG, Tolman WB, Que L. Mononitrosyl iron complexes supported by sterically hindered carboxylate ligands. Inorganic Chemistry. 45: 8006-8. PMID 16999396 DOI: 10.1021/ic0610740  1
2006 Friese SJ, Kucera BE, Que L, Tolman WB. Self-assembly of the 2-His-1-carboxylate facial triad in mononuclear iron(II) and zinc(II) models of metalloenzyme active sites. Inorganic Chemistry. 45: 8003-5. PMID 16999395 DOI: 10.1021/ic061564s  1
2006 Sarangi R, Aboelella N, Fujisawa K, Tolman WB, Hedman B, Hodgson KO, Solomon EI. X-ray absorption edge spectroscopy and computational studies on LCuO2 species: Superoxide-Cu(II) versus peroxide-Cu(III) bonding. Journal of the American Chemical Society. 128: 8286-96. PMID 16787093 DOI: 10.1021/ja0615223  1
2006 York JT, Young VG, Tolman WB. Heterobimetallic activation of dioxygen: characterization and reactivity of novel Cu(I)-Ge(II) complexes. Inorganic Chemistry. 45: 4191-8. PMID 16676981 DOI: 10.1021/ic060050q  1
2006 Aboelella NW, Gherman BF, Hill LM, York JT, Holm N, Young VG, Cramer CJ, Tolman WB. Effects of thioether substituents on the O2 reactivity of beta-diketiminate-Cu(I) complexes: probing the role of the methionine ligand in copper monooxygenases. Journal of the American Chemical Society. 128: 3445-58. PMID 16522125 DOI: 10.1021/ja057745v  1
2006 Breyfogle LE, Williams CK, Young VG, Hillmyer MA, Tolman WB. Comparison of structurally analogous Zn2, Co2, and Mg2 catalysts for the polymerization of cyclic esters. Dalton Transactions (Cambridge, England : 2003). 928-36. PMID 16462953 DOI: 10.1039/b507014g  1
2006 Tolman WB. Using synthetic chemistry to understand copper protein active sites: a personal perspective. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 11: 261-71. PMID 16447049 DOI: 10.1007/s00775-006-0078-9  1
2006 Gherman BF, Heppner DE, Tolman WB, Cramer CJ. Models for dioxygen activation by the CuB site of dopamine beta-monooxygenase and peptidylglycine alpha-hydroxylating monooxygenase. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 11: 197-205. PMID 16344970 DOI: 10.1007/s00775-005-0066-5  1
2006 Tolman WB. Activation of Small Molecules: Organometallic and Bioinorganic Perspectives Activation of Small Molecules: Organometallic and Bioinorganic Perspectives. 1-363. DOI: 10.1002/9783527609352  1
2005 York JT, Brown EC, Tolman WB. Characterization of a complex comprising a [Cu2(S2)2]2+ core: bis(mu-S2 2-)dicopperIII or bis(mu-S2).-)dicopperII? Angewandte Chemie (International Ed. in English). 44: 7745-8. PMID 16267877 DOI: 10.1002/anie.200503134  1
2005 Brown EC, York JT, Antholine WE, Ruiz E, Alvarez S, Tolman WB. [Cu3(mu-S)2]3+ clusters supported by N-donor ligands: progress toward a synthetic model of the catalytic site of nitrous oxide reductase. Journal of the American Chemical Society. 127: 13752-3. PMID 16201771 DOI: 10.1021/ja053971t  1
2005 Reynolds AM, Gherman BF, Cramer CJ, Tolman WB. Characterization of a 1:1 Cu-O2 adduct supported by an anilido imine ligand. Inorganic Chemistry. 44: 6989-97. PMID 16180861 DOI: 10.1021/ic050280p  1
2005 Zhang D, Hillmyer MA, Tolman WB. Catalytic polymerization of a cyclic ester derived from a "cool" natural precursor. Biomacromolecules. 6: 2091-5. PMID 16004449 DOI: 10.1021/bm050076t  1
2005 Reynolds AM, Lewis EA, Aboelella NW, Tolman WB. Reactivity of a 1:1 copper-oxygen complex: isolation of a Cu(II)-o-iminosemiquinonato species. Chemical Communications (Cambridge, England). 2014-6. PMID 15834490 DOI: 10.1039/b418939f  1
2005 Jensen TR, Schaller CP, Hillmyer MA, Tolman WB. Zinc N-heterocyclic carbene complexes and their polymerization of d,l-lactide Journal of Organometallic Chemistry. 690: 5881-5891. DOI: 10.1016/j.jorganchem.2005.07.070  1
2004 Aboelella NW, Kryatov SV, Gherman BF, Brennessel WW, Young VG, Sarangi R, Rybak-Akimova EV, Hodgson KO, Hedman B, Solomon EI, Cramer CJ, Tolman WB. Dioxygen activation at a single copper site: structure, bonding, and mechanism of formation of 1:1 Cu-O2 adducts. Journal of the American Chemical Society. 126: 16896-911. PMID 15612729 DOI: 10.1021/ja045678j  1
2004 Jensen TR, Breyfogle LE, Hillmyer MA, Tolman WB. Stereoelective polymerization of D,L-lactide using N-heterocyclic carbene based compounds. Chemical Communications (Cambridge, England). 2504-5. PMID 15514837 DOI: 10.1039/b405362a  1
2004 Aboelella NW, York JT, Reynolds AM, Fujita K, Kinsinger CR, Cramer CJ, Riordan CG, Tolman WB. Mixed metal bis(mu-oxo) complexes with [CuM(mu-O)2]n+(M = Ni(III) or Pd(II)) cores. Chemical Communications (Cambridge, England). 1716-7. PMID 15278152 DOI: 10.1039/b404640d  1
2004 Brown EC, Aboelella NW, Reynolds AM, Aullón G, Alvarez S, Tolman WB. A new class of (mu-eta2:eta2-disulfido)dicopper complexes: synthesis, characterization, and disulfido exchange. Inorganic Chemistry. 43: 3335-7. PMID 15154793 DOI: 10.1021/ic049811k  1
2004 Aboelella NW, Reynolds AM, Tolman WB. Biophysics. Catching copper in the act. Science (New York, N.Y.). 304: 836-7. PMID 15131298 DOI: 10.1126/science.1098301  1
2004 Kryatov SV, Chavez FA, Reynolds AM, Rybak-Akimova EV, Que L, Tolman WB. Mechanistic studies on the formation and reactivity of dioxygen adducts of diiron complexes supported by sterically hindered carboxylates. Inorganic Chemistry. 43: 2141-50. PMID 15018538 DOI: 10.1021/ic049976t  1
2004 Lewis EA, Tolman WB. Reactivity of dioxygen-copper systems. Chemical Reviews. 104: 1047-76. PMID 14871149 DOI: 10.1021/cr020633r  1
2004 Zhang D, Xu J, Alcazar-Roman L, Greenman L, Cramer CJ, Hillmver MA, Tolman WB. Isotactic polymers with alternating lactic acid and oxetane subunits from the endoentropic polymerization of a 14-membered ring Macromolecules. 37: 5274-5281. DOI: 10.1021/ma049571s  1
2004 Zhang D, Hillmyer MA, Tolman WB. A new synthetic route to poly[3-hydroxypropionic acid] (P[3-HP]): Ring-opening polymerization of 3-HP macrocyclic esters Macromolecules. 37: 8198-8200. DOI: 10.1021/ma048092q  1
2004 Que J, Tolman WB. Introduction to Volume 8 Comprehensive Coordination Chemistry Ii. 8: xv. DOI: 10.1016/B0-08-043748-6/90012-0  1
2004 Tolman WB. Metal-Radical Arrays Comprehensive Coordination Chemistry Ii. 8: 715-737. DOI: 10.1016/B0-08-043748-6/08196-2  1
2004 Que J, Tolman WB. Recurring Structural Motifs in Bioinorganic Chemistry Comprehensive Coordination Chemistry Ii. 8: 1-15. DOI: 10.1016/B0-08-043748-6/08164-0  1
2003 Williams CK, Breyfogle LE, Choi SK, Nam W, Young VG, Hillmyer MA, Tolman WB. A highly active zinc catalyst for the controlled polymerization of lactide. Journal of the American Chemical Society. 125: 11350-9. PMID 16220958 DOI: 10.1021/ja0359512  1
2003 Jazdzewski BA, Reynolds AM, Holland PL, Young VG, Kaderli S, Zuberbühler AD, Tolman WB. Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 8: 381-93. PMID 12761659 DOI: 10.1007/s00775-002-0420-9  1
2003 Cramer CJ, Tolman WB, Theopold KH, Rheingold AL. Variable character of O-O and M-O bonding in side-on (eta(2)) 1:1 metal complexes of O2. Proceedings of the National Academy of Sciences of the United States of America. 100: 3635-40. PMID 12634422 DOI: 10.1073/pnas.0535926100  1
2003 Alcazar-Roman LM, O'Keefe BJ, Hillmyer MA, Tolman WB. Electronic influence of ligand substituents on the rate of polymerization of ε-caprolactone by single-site aluminium alkoxide catalysts Dalton Transactions. 3082-3087. DOI: 10.1039/b303760f  1
2003 Hagadorn JR, Zahn TI, Que L, Tolman WB. Dicopper(I,I) and delocalized mixed-valent dicopper(I,II) complexes of a sterically hindered carboxylate ligand Dalton Transactions. 1790-1794. DOI: 10.1039/b301154b  1
2002 Chavez FA, Ho RY, Pink M, Young VG, Kryatov SV, Rybak-Akimova EV, Andres H, Münck E, Que L, Tolman WB. Unusual peroxo intermediates in the reaction of dioxygen with carboxylate-bridged diiron(II,II) paddlewheel complexes. Angewandte Chemie (International Ed. in English). 41: 149-52. PMID 12491468 DOI: 10.1002/1521-3773(20020104)41:1<149::AID-ANIE149>3.0.CO;2-#  1
2002 Que L, Tolman WB. Bis(mu-oxo)dimetal "diamond" cores in copper and iron complexes relevant to biocatalysis. Angewandte Chemie (International Ed. in English). 41: 1114-37. PMID 12491240 DOI: 10.1002/1521-3773(20020402)41:7<1114::AID-ANIE1114>3.0.CO;2-6  1
2002 Spencer DJ, Reynolds AM, Holland PL, Jazdzewski BA, Duboc-Toia C, Le Pape L, Yokota S, Tachi Y, Itoh S, Tolman WB. Copper chemistry of beta-diketiminate ligands: monomer/dimer equilibria and a new class of bis(mu-oxo)dicopper compounds. Inorganic Chemistry. 41: 6307-21. PMID 12444774 DOI: 10.1021/ic020369k  1
2002 Lee WZ, Tolman WB. Toward synthetic analogues of linked redox and catalytic multimetal sites in proteins: a model of the histidine-cysteine bridged dicopper array. Inorganic Chemistry. 41: 5656-8. PMID 12401068 DOI: 10.1021/ic025937a  1
2002 Williams CK, Brooks NR, Hillmyer MA, Tolman WB. Metalloenzyme inspired dizinc catalyst for the polymerization of lactide. Chemical Communications (Cambridge, England). 2132-3. PMID 12357810  1
2002 Aboelella NW, Lewis EA, Reynolds AM, Brennessel WW, Cramer CJ, Tolman WB. Snapshots of dioxygen activation by copper: the structure of a 1:1 Cu/O(2) adduct and its use in syntheses of asymmetric Bis(mu-oxo) complexes. Journal of the American Chemical Society. 124: 10660-1. PMID 12207513 DOI: 10.1021/ja027164v  1
2002 O'Keefe BJ, Breyfogle LE, Hillmyer MA, Tolman WB. Mechanistic comparison of cyclic ester polymerizations by novel iron(III)-alkoxide complexes: single vs multiple site catalysis. Journal of the American Chemical Society. 124: 4384-93. PMID 11960467 DOI: 10.1021/ja012689t  1
2002 Spencer DJ, Johnson BJ, Johnson BJ, Tolman WB. Calix[4]arenes linked to multiple bidentate N-donors: potential ligands for synthetic modeling of multinuclear metalloenzymes. Organic Letters. 4: 1391-3. PMID 11950370 DOI: 10.1021/ol025715g  1
2002 Spencer DJ, Aboelella NW, Reynolds AM, Holland PL, Tolman WB. beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes. Journal of the American Chemical Society. 124: 2108-9. PMID 11878952 DOI: 10.1021/ja017820b  1
2002 Tolman WB, Que L. Sterically hindered benzoates: A synthetic strategy for modeling dioxygen activation at diiron active sites in proteins Dalton Transactions. 653-660. DOI: 10.1039/b108262k  1
2002 Aubrecht KB, Hillmyer MA, Tolman WB. Polymerization of lactide by monomeric Sn(II) alkoxide complexes Macromolecules. 35: 644-650. DOI: 10.1021/ma011873w  1
2002 Chowdhury A, Peteanu LA, Holland PL, Tolman WB. The electronic properties of a model active site for blue copper proteins as probed by Stark spectroscopy Journal of Physical Chemistry B. 106: 3007-3012. DOI: 10.1021/jp0115751  1
2001 Jazdzewski BA, Holland PL, Pink M, Young VG, Spencer DJ, Tolman WB. Three-coordinate copper(II)-phenolate complexes. Inorganic Chemistry. 40: 6097-107. PMID 11703106 DOI: 10.1021/ic010615c  1
2001 O'Keefe BJ, Monnier SM, Hillmyer MA, Tolman WB. Rapid and controlled polymerization of lactide by structurally characterized ferric alkoxides. Journal of the American Chemical Society. 123: 339-40. PMID 11456524 DOI: 10.1021/ja003537l  1
2001 DeBeer George S, Metz M, Szilagyi RK, Wang H, Cramer SP, Lu Y, Tolman WB, Hedman B, Hodgson KO, Solomon EI. A quantitative description of the ground-state wave function of Cu(A) by X-ray absorption spectroscopy: comparison to plastocyanin and relevance to electron transfer. Journal of the American Chemical Society. 123: 5757-67. PMID 11403610 DOI: 10.1021/ja004109i  1
2001 Tolman WB, Spencer DJ. New advances in ligand design for synthetic modeling of metalloprotein active sites. Current Opinion in Chemical Biology. 5: 188-95. PMID 11282346 DOI: 10.1016/S1367-5931(00)00189-7  1
2001 Schneider JL, Young VG, Tolman WB. Copper(I) chemistry of bis(pyrazolyl)diphenylborate ligands: formation of a heterocycle by Cu-mediated acetonitrile addition. Inorganic Chemistry. 40: 165-8. PMID 11195375 DOI: 10.1021/ic000637j  1
2001 Bechtold K, Hillmyer MA, Tolman WB. Perfectly alternating copolymer of lactic acid and ethylene oxide as a plasticizing agent for polylactide Macromolecules. 34: 8641-8648. DOI: 10.1021/ma0114887  1
2001 Aubrecht KB, Chang K, Hillmyer MA, Tolman WB. Lactide polymerization activity of alkoxide, phenoxide, and amide derivatives of yttrium(III) arylamidinates Journal of Polymer Science, Part a: Polymer Chemistry. 39: 284-293. DOI: 10.1002/1099-0518(20010115)39:2<284::AID-POLA40>3.0.CO;2-C  1
2001 O'Keefe BJ, Hillmyer MA, Tolman WB. Polymerization of lactide and related cyclic esters by discrete metal complexes Journal of the Chemical Society, Dalton Transactions. 2215-2224.  1
2001 Chavez FA, Que L. J, Tolman WB. Metal ion complexation by a new, highly sterically hindered, bowl-shaped carboxylate ligand Chemical Communications. 111-112.  1
2000 Lam BM, Halfen JA, Young VG, Hagadorn JR, Holland PL, Lledós A, Cucurull-Sánchez L, Novoa JJ, Alvarez S, Tolman WB. Ligand macrocycle structural effects on copper-dioxygen reactivity. Inorganic Chemistry. 39: 4059-72. PMID 11198861 DOI: 10.1021/ic000248p  1
2000 Hagadorn JR, Que L, Tolman WB. N-donor effects on carboxylate binding in mononuclear iron(II) complexes of a sterically hindered benzoate ligand. Inorganic Chemistry. 39: 6086-90. PMID 11188526 DOI: 10.1021/ic000531o  1
2000 Itoh S, Taki M, Nakao H, Holland PL, Tolman WB, Que Jr, Fukuzumi S. Aliphatic Hydroxylation by a Bis(µ-oxo)dicopper(III) Complex. Angewandte Chemie (International Ed. in English). 39: 398-400. PMID 10649424 DOI: 10.1002/(SICI)1521-3773(20000117)39:2<398::AID-ANIE398>3.0.CO;2-2  1
2000 Chamberlain BM, Jazdzewski BA, Pink M, Hillmyer MA, Tolman WB. Controlled polymerization of DL-lactide and ε-caprolactone by structurally well-defined alkoxo-bridged Di- and triyttrium(III) complexes Macromolecules. 33: 3970-3977. DOI: 10.1021/ma0000834  1
2000 Holland PL, Cramer CJ, Wilkinson EC, Mahapatra S, Rodgers KR, Itoh S, Taki M, Fukuzumi S, Que L, Tolman WB. Resonance Raman spectroscopy as a probe of the bis(μ-oxo)dicopper core Journal of the American Chemical Society. 122: 792-802. DOI: 10.1021/ja992003l  1
2000 Meggers E, Holland PL, Tolman WB, Romesberg FE, Schultz PG. A novel copper-mediated DNA base pair [6] Journal of the American Chemical Society. 122: 10714-10715. DOI: 10.1021/ja0025806  1
2000 Randall DW, George SD, Holland PL, Hedman B, Hodgson KO, Tolman WB, Solomon EI. Spectroscopic and electronic structural studies of blue copper model complexes. 2. Comparison of three-and four-coordinate Cu(II)-thiolate complexes and fungal laccase Journal of the American Chemical Society. 122: 11632-11648. DOI: 10.1021/ja001592o  1
2000 Holland PL, Tolman WB. A structural model of the type 1 copper protein active site: N2S(thiolate)s(thioether) ligation in a Cu(II) complex [23] Journal of the American Chemical Society. 122: 6331-6332. DOI: 10.1021/ja001328v  1
2000 Berreau LM, Halfen JA, Young VG, Tolman WB. Heterocyclic donor influences on the binding and activation of CO, NO, and O2 by copper complexes of hybrid triazacyclononane-pyridyl ligands Inorganica Chimica Acta. 297: 115-128. DOI: 10.1016/S0020-1693(99)00292-3  1
2000 Jazdzewski BA, Tolman WB. Understanding the copper-phenoxyl radical array in galactose oxidase: Contributions from synthetic modeling studies Coordination Chemistry Reviews. 200: 633-685. DOI: 10.1016/S0010-8545(00)00342-8  1
2000 Hillmyer MA, Tolman WB, Chamberlain BM, Aubrecht KB. Discrete yttrium catalysts for the controlled polymerization of cyclic esters American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 41: 426.  1
1999 Holland PL, Rodgers KR, Tolman WB. Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene? Angewandte Chemie (International Ed. in English). 38: 1139-42. PMID 25138522 DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1139::AID-ANIE1139>3.0.CO;2-0  1
1999 Cahoy J, Holland PL, Tolman WB. Experimental Studies of the Interconversion of &mgr;-eta(2):eta(2)-Peroxo- and Bis(&mgr;-oxo)dicopper Complexes. Inorganic Chemistry. 38: 2161-2168. PMID 11671001  1
1999 Chamberlain BM, Sun Y, Hagadorn JR, Hemmesch EW, Young VG, Pink M, Hillmyer MA, Tolman WB. Discrete yttrium(III) complexes as lactide polymerization catalysts Macromolecules. 32: 2400-2402. DOI: 10.1021/ma990005k  1
1999 Hagadorn JR, Que L, Tolman WB, Prisecaru I, Münck E. Conformational tuning of valence delocalization in carboxylate-rich diiron complexes [20] Journal of the American Chemical Society. 121: 9760-9761. DOI: 10.1021/ja992038l  1
1999 Holland PL, Tolman WB. Three-coordinate Cu(II) complexes: Structural models of trigonal-planar type 1 copper protein active sites [5] Journal of the American Chemical Society. 121: 7270-7271. DOI: 10.1021/ja991533e  1
1999 Holland PL, Tolman WB. Dioxygen activation by copper sites: Relative stability and reactivity of (μ-η2:η2-peroxo)- and bis(μ-oxo)dicopper cores Coordination Chemistry Reviews. 190: 855-869. DOI: 10.1016/S0010-8545(99)00125-3  1
1999 Cahoy J, Holland PL, Tolman WB. Experimental studies of the interconversion of μ-η2:η2-peroxo- and bis(μ-oxo)dicopper complexes Inorganic Chemistry. 38: 2161-2168.  1
1999 Berreau LM, Mahapatra S, Halfen JA, Houser RP, Young VG, Tolman WB. Reactivity of peroxo- and Bis(μ-oxo)dicopper complexes with catechols Angewandte Chemie - International Edition. 38: 207-210.  1
1998 Hagadorn JR, Que L, Tolman WB. A Bulky Benzoate Ligand for Modeling the Carboxylate-Rich Active Sites of Non-Heme Diiron Enzymes. Journal of the American Chemical Society. 120: 13531-13532. PMID 28926239 DOI: 10.1021/ja983333t  0.56
1998 Halfen JA, Young VG, Tolman WB. An Unusual Ligand Oxidation by a (&mgr;-eta(2):eta(2)-Peroxo)dicopper Compound: 1 degrees > 3 degrees C-H Bond Selectivity and a Novel Bis(&mgr;-alkylperoxo)dicopper Intermediate. Inorganic Chemistry. 37: 2102-2103. PMID 11670360  0.76
1998 Hagadorn JR, Que L. J, Tolman WB. A bulky benzoate ligand for modeling the carboxylate-rich active sites of non-heme diiron enzymes [10] Journal of the American Chemical Society. 120: 13531-13532. DOI: 10.1021/ja983333t  1
1998 Schneider JL, Carrier SM, Ruggiero CE, Young VG, Tolman WB. Influences of ligand environment on the spectroscopic properties and disproportionation reactivity of copper-nitrosyl complexes Journal of the American Chemical Society. 120: 11408-11418. DOI: 10.1021/ja982172q  1
1998 Gamelin DR, Randall DW, Hay MT, Houser RP, Mulder TC, Canters GW, De Vries S, Tolman WB, Lu Y, Solomon EI. Spectroscopy of mixed-valence Cu(A)-type centers: Ligand-field control of ground-state properties related to electron transfer Journal of the American Chemical Society. 120: 5246-5263. DOI: 10.1021/ja973161k  1
1998 Tolman WB, Caudle MT, Pecoraro VL. Thermodynamic viability of hydrogen atom transfer from water coordinated to the oxygen-evolving complex of photosystem II Chemtracts. 11: 339-345. DOI: 10.1021/ja9641158  1
1998 Jameson DL, Castellano RK, Reger DL, Collins JE, Tolman WB, Tokar CJ. Poly(1-pyrazolyl)alkane ligands Inorganic Syntheses. 32: 51-63.  1
1998 Berreau LM, Halfen JA, Young VG, Tolman WB. Synthesis and Copper Coordination Chemistry of Hindered 1,4,7-Triazacyclononane Ligands with Amide Appendages Inorganic Chemistry. 37: 1091-1098.  1
1998 Blackburn NJ, Ralle M, Sanders D, Fee JA, De Vries S, Houser RP, Tolman WB, Hay MT, Lu Y. XAS Studies on the CuA Centers of Heme-Copper Oxidases and Loop-Directed Mutants of Azurin: Implications for Redox Reactivity Acs Symposium Series. 692: 241-259.  1
1998 Halfen JA, Tolman WB, Weighardt K. C2-symmetric 1,4-diisopropyl-7-R-1,4,7-triazacyclononanes Inorganic Syntheses. 32: 75-81.  1
1998 Jazdzewski BA, Young V.G. J, Tolman WB. A three coordinate copper(I)-phenoxide complex that models the reduced form of galactose oxidase Chemical Communications. 2521-2522.  1
1998 Keyes MC, Chamberlain BM, Caltagirone SA, Halfen JA, Tolman WB. A new set of structurally related enantiopure polypyrazolyl ligands of varying rotational symmetry: Synthesis, metal complexation, and comparison of asymmetric induction Organometallics. 17: 1984-1992.  1
1998 Halfen JA, Young VG, Tolman WB. An Unusual Ligand Oxidation by a (μ-η2:η2-Peroxo)dicopper Compound: 1° > 3° C-H Bond Selectivity and a Novel Bis(μ-alkylperoxo)dicopper Intermediate Inorganic Chemistry. 37: 2102-2103.  1
1998 Schneider JL, Halfen JA, Young VG, Tolman WB. Mono- versus bidentate coordination of the NONOate [Et2N(N2O2)]- to copper(II) complexes of tetradentate ligands New Journal of Chemistry. 22: 459-466.  1
1997 Boese R, Cammack JK, Matzger AJ, Pflug K, Tolman WB, Vollhardt KPC, Weidman TW. Photochemistry of (fulvalene)tetracarbonyldiruthenium and its derivatives: Efficient light energy storage devices Journal of the American Chemical Society. 119: 6757-6773. DOI: 10.1021/ja9707062  1
1997 Blackburn NJ, De Vries S, Barr ME, Houser RP, Tolman WB, Sanders D, Fee JA. X-ray absorption studies on the mixed-valence and fully reduced forms of the soluble Cu(A) domains of cytochrome c oxidase Journal of the American Chemical Society. 119: 6135-6143. DOI: 10.1021/ja970513e  1
1997 Halfen JA, Jazdzewski BA, Mahapatra S, Berreau LM, Wilkinson EC, Que L, Tolman WB. Synthetic models of the inactive Copper(II)-tyrosinate and active Copper(II)-tyrosyl radical forms of galactose and glyoxal oxidases Journal of the American Chemical Society. 119: 8217-8227. DOI: 10.1021/ja9700663  1
1997 Williams KR, Gamelin DR, LaCroix LB, Houser RP, Tolman WB, Mulder TC, De Vries S, Hedman B, Hodgson KO, Solomon EI. Influence of copper-sulfur covalency and copper-copper bonding on valence delocalization and electron transfer in the Cu(A) site of cytochrome c oxidase Journal of the American Chemical Society. 119: 613-614. DOI: 10.1021/ja963225b  1
1997 Karlin KD, Tolman WB, Kaderli S, Zuberbühler AD. Kinetic and thermodynamic parameters of copper-dioxygen interaction with different oxygen binding modes Journal of Molecular Catalysis a: Chemical. 117: 215-222. DOI: 10.1016/S1381-1169(96)00250-6  1
1997 Mahapatra S, Kaderli S, Llobet A, Neuhold YM, Palanché T, Halfen JA, Young VG, Kaden TA, Que L, Zuberbühler AD, Tolman WB. Binucleating ligand structural effects on (μ-peroxo)- and bis(μ-oxo)dicopper complex formation and decay: Competition between arene hydroxylation and aliphatic C-H bond activation Inorganic Chemistry. 36: 6343-6356.  1
1997 Tolman WB. Making and Breaking the Dioxygen 0-0 Bond: New Insights from Studies of Synthetic Copper Complexes Accounts of Chemical Research. 30: 227-237.  1
1997 Mahapatra S, Young V.G. J, Kaderli S, Zuberbuhler AD, Tolman WB. Tuning the structure and reactivity of the [Cu2(μ-O)2]2+ core: Characterization of a new bis(μ-oxo)dicopper complex stabilized by a sterically hindered dinucleating bis(triazacyclononane) ligand Angewandte Chemie - International Edition in English. 36: 130-133.  1
1996 Schneider JL, Young VG, Tolman WB. Synthesis and Characterization of a Copper Complex of [Et(2)N(N(2)O(2))](-) Stabilized with Respect to NO Release in Aqueous Solution. Inorganic Chemistry. 35: 5410-5411. PMID 11666724  0.76
1996 Halfen JA, Mahapatra S, Wilkinson EC, Kaderli S, Young VG, Que L, Zuberbühler AD, Tolman WB. Reversible cleavage and formation of the dioxygen O-O bond within a dicopper complex. Science (New York, N.Y.). 271: 1397-400. PMID 8596910  1
1996 Cramer CJ, Smith BA, Tolman WB. Ab initio characterization of the isomerism between the μ-η2:η2-peroxo- and bis(μ-oxo)dicopper cores Journal of the American Chemical Society. 118: 11283-11287. DOI: 10.1021/ja962455n  1
1996 Halfen JA, Young VG, Tolman WB. Dioxygen activation by a Copper(I) complex of a new tetradentate tripodal ligand: Mechanistic insights into peroxodicopper core reactivity Journal of the American Chemical Society. 118: 10920-10921. DOI: 10.1021/ja962344o  1
1996 Mahapatra S, Halfen JA, Wilkinson EC, Pan G, Wang X, Young VG, Cramer CJ, Que L, Tolman WB. Structural, spectroscopic, and theoretical characterization of bis(μ-oxo)dicopper complexes, novel intermediates in copper-mediated dioxygen activation Journal of the American Chemical Society. 118: 11555-11574. DOI: 10.1021/ja962305c  1
1996 Mahapatra S, Halfen JA, Tolman WB. Mechanistic study of the oxidative N-dealkylation reactions of bis(μ-oxo)dicopper complexes Journal of the American Chemical Society. 118: 11575-11586. DOI: 10.1021/ja962304k  1
1996 Halfen JA, Mahapatra S, Wilkinson EC, Gengenbach AJ, Young VG, Que Jnr L, Tolman WB. Synthetic modeling of nitrite binding and activation by reduced copper proteins. Characterization of copper(I)-nitrite complexes that evolve nitric oxide Journal of the American Chemical Society. 118: 763-776. DOI: 10.1021/ja952691i  1
1996 Schneider JL, Young VG, Tolman WB. Synthesis and Characterization of a Copper Complex of [Et2N(N2O2)] Stabilized with Respect to NO Release in Aqueous Solution Inorganic Chemistry. 35: 5410-5411.  1
1996 Halfen JA, Young VG, Tolman WB. Modeling of the Chemistry of the Active Site of Galactose Oxidase Angewandte Chemie (International Edition in English). 35: 1687-1690.  1
1996 Berreau LM, Mahapatra S, Halfen JA, Young VG, Tolman WB. Independent Synthesis and Structural Characterization of a Mononuclear Copper-Hydroxide Complex Previously Assigned as a Copper-Superoxide Species Inorganic Chemistry. 35: 6339-6342.  1
1996 Houser RP, Young VG, Tolman WB. A thiolate-bridged, fully delocalized mixed-valence dicopper(I,II) complex that models the CuA biological electron-transfer site Journal of the American Chemical Society. 118: 2101-2102.  1
1995 Halfen JA, Tolman WB. (Nitrito-O,O')bis(triphenylphosphine)-copper(I), (PPh3)2Cu(NO2-O,O'). Acta Crystallographica. Section C, Crystal Structure Communications. 51: 215-7. PMID 7734085  1
1995 Houser RP, Tolman WB. Mixed valence, tricopper(I,II,I) complexes with thiolate bridges. Progress toward synthetic models of the putative {Cu2}3+ sites in nitrous oxide reductase and cytochrome c oxidase Inorganic Chemistry. 34: 1632-1633.  1
1995 Christenson DL, Tokar CJ, Tolman WB. New copper and rhodium cyclopropanation catalysts supported by chiral bis(pyrazolyl)pyridines. A metal-dependent enantioselectivity switch Organometallics. 14: 2148-2150.  1
1995 Houser RP, Halfen JA, Young VG, Blackburn NJ, Tolman WB. Structural characterization of the first example of a bis(μ-thiolato)dicopper(II) complex. Relevance to proposals for the electron transfer sites in cytochrome c oxidase and nitrous oxide reductase Journal of the American Chemical Society. 117: 10745-10746.  1
1995 Mahapatra S, Halfen JA, Wilkinson EC, Pan G, Cramer CJ, Que L, Tolman WB. A new intermediate in copper dioxygen chemistry: Breaking the O-O bond to form a {Cu2(μ-O)2}2+ core Journal of the American Chemical Society. 117: 8865-8866.  1
1994 Mahapatra S, Halfen JA, Tolman WB. Catalytic reduction of nitric oxide to nitrous oxide by alcohols mediated by copper(I) complexes Journal of the Chemical Society, Chemical Communications. 1625-1626. DOI: 10.1039/C39940001625  1
1994 LeCloux DD, Tokar CJ, Osawa M, Houser RP, Keyes MC, Tolman WB. Optically active and C3-symmetric tris(pyrazolyl)hydroborate and tris(pyrazolyl)phosphine oxide ligands: Synthesis and structural characterization Organometallics. 13: 2855-2866.  1
1994 LeCloux DD, Keyes MC, Osawa M, Reynolds V, Tolman WB. Transition metal complexes of optically active tris(pyrazolyl)hydroborates Inorganic Chemistry. 33: 6361-6368.  1
1994 Mahapatra S, Halfen JA, Wilkinson EC, Que L, Tolman WB. Modeling copper-dioxygen reactivity in proteins: Aliphatic C-H bond activation by a new dicopper(II)-peroxo complex Journal of the American Chemical Society. 116: 9785-9786.  1
1994 Halfen JA, Tolman WB. Synthetic model of the substrate adduct to the reduced active site of copper nitrite reductase Journal of the American Chemical Society. 116: 5475-5476.  1
1994 Ruggiero CE, Carrier SM, Tolman WB. Reductive disproportionation of NO mediated by copper complexes: Modeling N2O generation by copper proteins and heterogeneous catalysts Angewandte Chemie (International Edition in English). 33: 895-897.  1
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