Raphaël Robiette - Publications

Université catholique de Louvain, Ottignies-Louvain-la-Neuve, Wallonie, Belgium 

66 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Bensaida A, Mahaut D, Tumanov N, Wouters J, Champagne B, Vanthuyne N, Robiette R, Berionni G. Reactivity and Steric Parameters from 2D to 3D Bulky Pyridines : Increasing Steric Demand at Nitrogen with Chiral Azatriptycenes. Angewandte Chemie (International Ed. in English). e202407503. PMID 38781114 DOI: 10.1002/anie.202407503  0.666
2024 Janssens J, De Roose M, Jacquemin A, Vanhosmael T, Delbrassinne A, Collard L, Robiette R. One-Carbon Homologation of Knoevenagel Adducts: Enantioselective Access to Benzhydryl Derivatives. The Journal of Organic Chemistry. 89: 7270-7274. PMID 38695495 DOI: 10.1021/acs.joc.4c00057  0.302
2023 Vogl LS, Mayer P, Robiette R, Waser M. Chiral Isochalcogenourea-Catalysed Enantioselective (4+2) Cycloadditions of Allenoates. Angewandte Chemie (Weinheim An Der Bergstrasse, Germany). 136: e202315345. PMID 38549953 DOI: 10.1002/ange.202315345  0.411
2023 Vogl LS, Mayer P, Robiette R, Waser M. Chiral Isochalcogenourea-Catalysed Enantioselective (4+2) Cycloadditions of Allenoates. Angewandte Chemie (International Ed. in English). 63: e202315345. PMID 38010747 DOI: 10.1002/anie.202315345  0.411
2021 Caillé J, Robiette R. Cycloaddition of cyclopropanes for the elaboration of medium-sized carbocycles. Organic & Biomolecular Chemistry. PMID 34114583 DOI: 10.1039/d1ob00838b  0.303
2021 Hu L, Mahaut D, Tumanov N, Wouters J, Collard L, Robiette R, Berionni G. Sterically hindered -substituted phosphatriptycenes as configurationally stable -chirogenic triarylphosphines. Dalton Transactions (Cambridge, England : 2003). PMID 33729265 DOI: 10.1039/d1dt00816a  0.713
2019 Scheinok S, Driesschaert B, d'Hose D, Sonveaux P, Robiette R, Gallez B. Synthesis and characterization of a 5-membered ring cyclic hydroxylamine coupled to triphenylphosphonium to detect mitochondrial superoxide by EPR spectrometry. Free Radical Research. 1-9. PMID 31744337 DOI: 10.1080/10715762.2019.1692137  0.306
2019 Hu L, Mahaut D, Tumanov N, Wouters J, Robiette R, Berionni G. Complementary Synthetic Approaches Toward 9-Phosphatriptycene and Structure-Reactivity Investigations of its Association with Sterically Hindered Lewis Acids. The Journal of Organic Chemistry. PMID 31385508 DOI: 10.1021/Acs.Joc.9B01570  0.707
2019 Richald M, Delbrassinne A, Robiette R. Unexpected Vinylcyclopropane Rearrangement: New Strategies toward Skipped Dienes Using Sulfonium Ylides European Journal of Organic Chemistry. 2019: 3779-3782. DOI: 10.1002/Ejoc.201900720  0.698
2018 Frédéric CJ, Cornil J, Vandamme M, Dumitrescu L, Tikad A, Robiette R, Vincent SP. Highly ( Z)-Diastereoselective Synthesis of Trifluoromethylated exo-Glycals via Photoredox and Copper Catalysis. Organic Letters. PMID 30350649 DOI: 10.1021/Acs.Orglett.8B02891  0.472
2018 Eitzinger A, Zielke K, Widhalm M, Robiette R, Waser M. Syntheses of Highly Functionalized Spirocyclohexenes by Formal [4+2] Annulation of Arylidene Azlactones with Allenoates. Asian Journal of Organic Chemistry. 7: 1620-1625. PMID 30175031 DOI: 10.1002/Ajoc.201800275  0.366
2018 Fan Y, Tiffner M, Schörgenhumer J, Robiette R, Waser M, Kass SR. Synthesis of Cyclic Organic Carbonates Using Atmospheric Pressure CO2 and Charge-Containing Thiourea Catalysts. The Journal of Organic Chemistry. PMID 30020780 DOI: 10.1021/Acs.Joc.8B01374  0.349
2018 Clergue S, Olivier R, Thierry D, Geoffroy D, Trieu-Van T, Soumia EA, Gabriella BC, Robiette R. Asymmetric Sulfur Ylide-Mediated Formal (4+1) Annulation Reaction: Scope and Mechanism. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29770508 DOI: 10.1002/Chem.201801874  0.774
2017 Depré D, Vermeulen WA, Lang Y, Dubois J, Vandevivere J, Vandermeersch J, Huang L, Robiette R. Origin of the E/Z Selectivity in the Synthesis of Tetrasubstituted Olefins by Wittig Reaction of α-Fluorophosphonium Ylides: An Explanation for the Low Stereoselectivity Observed in Reactions of α-Alkoxy Aldehydes. Organic Letters. PMID 28267343 DOI: 10.1021/Acs.Orglett.7B00344  0.444
2017 Waser M, Roiser L, Meisinger N, Monkowius U, Himmelsbach M, Robiette R. Asymmetric synthesis of 2,3-dihydrobenzofurans via a (4+1) annulation between ammonium ylides and in situ generated ortho-quinone methides. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28165173 DOI: 10.1002/Chem.201700171  0.477
2017 Novacek J, Robiette R, Waser M. On the origin of the stereoselectivity in chiral amide-based ammonium ylide-mediated epoxidations. Monatshefte Fur Chemie. 148: 77-81. PMID 28127093 DOI: 10.1007/S00706-016-1866-8  0.478
2016 Roiser L, Robiette R, Waser M. Benzylic Ammonium Ylide Mediated Epoxidations. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 27: 1963-1968. PMID 27766017 DOI: 10.1055/S-0035-1562344  0.44
2016 Caruano J, Muccioli G, Robiette R. Biologically active γ-lactams: synthesis and natural sources. Organic and Biomolecular Chemistry. 14: 10134-10156. PMID 27748489 DOI: 10.1039/C6Ob01349J  0.312
2016 Novacek J, Roiser L, Zielke K, Robiette R, Waser M. Towards a General Understanding of Carbonyl-Stabilised Ammonium Ylide-Mediated Epoxidation Reactions. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27381752 DOI: 10.1002/Chem.201602052  0.498
2016 Robiette R, Trieu-Van T, Aggarwal VK, Harvey JN. Activation of the SN2 Reaction by Adjacent π Systems: The Critical Role of Electrostatic Interactions and of Dissociative Character. Journal of the American Chemical Society. PMID 26725828 DOI: 10.1021/Jacs.5B11402  0.646
2016 Rousseau O, Delaunay T, Dequirez G, Trieu-Van T, Robeyns K, Robiette R. ChemInform Abstract: Formal Asymmetric [4 + 1] Annulation Reaction Between Sulfur Ylides and 1,3-Dienes. Cheminform. 47. DOI: 10.1002/CHIN.201603061  0.809
2015 Rousseau O, Delaunay T, Dequirez G, Trieu-Van T, Robeyns K, Robiette R. Formal Asymmetric (4+1) Annulation Reaction between Sulfur Ylides and 1,3-Dienes. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 12899-902. PMID 26235566 DOI: 10.1002/Chem.201502579  0.821
2015 Pichler M, Novacek J, Robiette R, Poscher V, Himmelsbach M, Monkowius U, Müller N, Waser M. Asymmetric syntheses of three-membered heterocycles using chiral amide-based ammonium ylides. Organic & Biomolecular Chemistry. 13: 2092-9. PMID 25521410 DOI: 10.1039/C4Ob02318H  0.469
2015 Rousseau O, Delaunay T, Dequirez G, Trieu-Van T, Robeyns K, Robiette R. Magnesium(II)-Catalyzed Asymmetric (4+1)-Annulation Reaction Synfacts. 11: 1179-1179. DOI: 10.1055/S-0035-1560683  0.407
2014 Caruano J, Feledziak M, Labar G, Michaux C, Perpète EA, Muccioli GG, Robiette R, Marchand-Brynaert J. (S)-1-(Pent-4'-enoyl)-4-(hydroxymethyl)-azetidin-2-one derivatives as inhibitors of human fatty acid amide hydrolase (hFAAH): synthesis, biological evaluation and molecular modelling. Journal of Enzyme Inhibition and Medicinal Chemistry. 29: 654-62. PMID 24102523 DOI: 10.3109/14756366.2013.837900  0.523
2013 Van Den Berge E, Robiette R. Development of a regioselective N-methylation of (benz)imidazoles providing the more sterically hindered isomer. The Journal of Organic Chemistry. 78: 12220-3. PMID 24180460 DOI: 10.1021/Jo401978B  0.751
2013 Mathieu V, Van Den Berge E, Ceusters J, Konopka T, Cops A, Bruyère C, Pirker C, Berger W, Trieu-Van T, Serteyn D, Kiss R, Robiette R. New 5-Aryl-1H-imidazoles display in vitro antitumor activity against apoptosis-resistant cancer models, including melanomas, through mitochondrial targeting. Journal of Medicinal Chemistry. 56: 6626-37. PMID 23845202 DOI: 10.1021/Jm400287V  0.703
2013 Robiette R, Rousseau O, Delaunay T. Synthesis of Monosubstituted 1,1-Dicarbonyl Ester 1,3-Dienes Synlett. 25: 519-522. DOI: 10.1055/S-0033-1340468  0.791
2013 Villemin E, Robeyns K, Robiette R, Herent M, Marchand-Brynaert J. Polycyclic phosphonic acid derivatives obtained by a [4+2] cycloaddition strategy using phosphonodienes Tetrahedron. 69: 1138-1147. DOI: 10.1016/J.Tet.2012.11.059  0.638
2013 Robiette R, Pospíšil J. On the Origin of E/Z Selectivity in the Modified Julia Olefination – Importance of the Elimination Step European Journal of Organic Chemistry. 2013: 836-840. DOI: 10.1002/Ejoc.201201634  0.339
2012 Billard F, Robiette R, Pospíšil J. Julia-Kocienski reaction-based 1,3-diene synthesis: aldehyde-dependent (E,E/E,Z)-selectivity. The Journal of Organic Chemistry. 77: 6358-64. PMID 22764737 DOI: 10.1021/Jo300929A  0.414
2012 Pospíšil J, Robiette R, Sato H, Debrus K. Practical synthesis of β-oxo benzo[d]thiazolyl sulfones: scope and limitations. Organic & Biomolecular Chemistry. 10: 1225-34. PMID 22183419 DOI: 10.1039/C1Ob06510F  0.378
2012 Dive G, Robiette R, Chenel A, Ndong M, Meier C, Desouter-Lecomte M. Laser control in open quantum systems: preliminary analysis toward the Cope rearrangement control in methyl-cyclopentadienylcarboxylate dimer Theoretical Chemistry Accounts. 131: 1236. DOI: 10.1007/S00214-012-1236-5  0.33
2012 Driesschaert B, Robiette R, Duff CSL, Collard L, Robeyns K, Gallez B, Marchand-Brynaert J. Configurationally Stable Tris(tetrathioaryl)methyl Molecular Propellers (Eur. J. Org. Chem. 33/2012) European Journal of Organic Chemistry. 2012. DOI: 10.1002/Ejoc.201290090  0.486
2012 Driesschaert B, Robiette R, Duff CSL, Collard L, Robeyns K, Gallez B, Marchand-Brynaert J. Configurationally stable tris(tetrathioaryl)methyl molecular propellers European Journal of Organic Chemistry. 2012: 6517-6525. DOI: 10.1002/Ejoc.201200801  0.551
2011 Driesschaert B, Robiette R, Lucaccioni F, Gallez B, Marchand-Brynaert J. Chiral properties of tetrathiatriarylmethyl spin probes. Chemical Communications (Cambridge, England). 47: 4793-5. PMID 21409216 DOI: 10.1039/C1Cc10988J  0.494
2011 Villemin E, Elias B, Robiette R, Robeyns K, Herent MF, Habib-Jiwan JL, Marchand-Brynaert J. Novel phosphonated bicyclic frameworks from Diels-Alder reaction as chelating agents of di- and trivalent metal cations Tetrahedron Letters. 52: 5140-5144. DOI: 10.1016/J.Tetlet.2011.07.116  0.519
2011 Berge EVD, Pospíšil J, Trieu‐Van T, Collard L, Robiette R. Planar Chirality of Imidazole-Containing Macrocycles - Understanding and Tuning Atropisomerism European Journal of Organic Chemistry. 2011: 6649-6655. DOI: 10.1002/Ejoc.201100805  0.389
2010 Robiette R, Tran T, Cordi A, Tinant B, Marchand-Brynaert J. A Practical Synthesis of 1,2-Nitroamines by Michael Addition of N-Nucleophiles to Nitroalkenes Synthesis. 2010: 3138-3142. DOI: 10.1055/S-0030-1258176  0.631
2010 Nshimyumukiza P, Berge EVD, Delest B, Mijatovic T, Kiss R, Marchand-Brynaert J, Robiette R. Synthesis and biological evaluation of novel imidazole-containing macrocycles Tetrahedron. 66: 4515-4520. DOI: 10.1016/J.Tet.2010.04.070  0.555
2010 Robert F, Naik AD, Hidara F, Tinant B, Robiette R, Wouters J, Garcia Y. Engineering Solid-State Molecular Switches:N-Salicylidene N-Heterocycle Derivatives European Journal of Organic Chemistry. 2010: 621-637. DOI: 10.1002/Ejoc.200901175  0.306
2009 Monbaliu J, Robiette R, Peeters D, Marchand-Brynaert J. (R)-4-phenyloxazolidin-2-thione: an efficient chiral auxiliary for [4+2] cycloaddition of 1-aminodiene and activated phosphonodienophiles Tetrahedron Letters. 50: 1314-1317. DOI: 10.1016/J.Tetlet.2009.01.036  0.798
2008 Delest B, Nshimyumukiza P, Fasbender O, Tinant B, Marchand-Brynaert J, Darro F, Robiette R. Divergent and regioselective synthesis of 1,2,4- and 1,2,5-trisubstituted imidazoles. The Journal of Organic Chemistry. 73: 6816-23. PMID 18681408 DOI: 10.1021/Jo801256B  0.624
2008 Howells D, Robiette R, Fang GY, Knowles LS, Woodrow MD, Harvey JN, Aggarwal VK. Reactions of silyl-stabilised sulfur ylides with organoboranes: enantioselectivity, mechanism, and understanding. Organic & Biomolecular Chemistry. 6: 1185-9. PMID 18362956 DOI: 10.1039/B718496D  0.672
2008 Robiette R, Marchand-Brynaert J. Diastereoselective Synthesis of Vinylcyclopropanes from Dienes and Sulfur Ylides Synlett. 2008: 517-520. DOI: 10.1055/S-2008-1032080  0.669
2007 Robiette R, Aggarwal VK, Harvey JN. Mechanism of the Morita-Baylis-Hillman reaction: a computational investigation. Journal of the American Chemical Society. 129: 15513-25. PMID 18041831 DOI: 10.1021/Ja0717865  0.673
2007 Broustal G, Ariza X, Campagne JM, Garcia J, Georges Y, Marinetti A, Robiette R. A stereoselective approach to 1,3-amino alcohols protected as cyclic carbamates: Kinetic vs. thermodynamic control European Journal of Organic Chemistry. 4293-4297. DOI: 10.1002/Ejoc.200700503  0.386
2006 Robiette R. Mechanism and diastereoselectivity of aziridine formation from sulfur ylides and imines: a computational study. The Journal of Organic Chemistry. 71: 2726-34. PMID 16555826 DOI: 10.1021/Jo052559T  0.395
2006 Robiette R, Richardson J, Aggarwal VK, Harvey JN. Reactivity and selectivity in the Wittig reaction: a computational study. Journal of the American Chemical Society. 128: 2394-409. PMID 16478195 DOI: 10.1021/Ja056650Q  0.645
2006 Robiette R, Conza M, Aggarwal VK. Delineation of the factors governing reactivity and selectivity in epoxide formation from ammonium ylides and aldehydes. Organic & Biomolecular Chemistry. 4: 621-3. PMID 16467935 DOI: 10.1039/B516926G  0.595
2006 Robiette R, Fang GY, Harvey JN, Aggarwal VK. Is phenyl a good migrating group in the rearrangement of organoborates generated from sulfur ylides? Chemical Communications (Cambridge, England). 741-3. PMID 16465325 DOI: 10.1039/B514987H  0.658
2006 Aggarwal VK, Charmant JP, Fuentes D, Harvey JN, Hynd G, Ohara D, Picoul W, Robiette R, Smith C, Vasse JL, Winn CL. Highly enantioselective synthesis of glycidic amides using camphor-derived sulfonium salts. Mechanism and applications in synthesis. Journal of the American Chemical Society. 128: 2105-14. PMID 16464113 DOI: 10.1021/Ja0568345  0.716
2006 Aggarwal V, Charmant J, Fuentes D, Harvey J, Hynd G, Ohara D, Picoul W, Robiette R, Smith C, Vasse J, Winn C. Synthesis of SK&F 104353 Synfacts. 2006: 0633-0633. DOI: 10.1055/S-2006-941825  0.577
2006 Harvey JN, Aggarwal VK, Bathelt CM, Carreón-Macedo JL, Gallagher T, Holzmann N, Mulholland AJ, Robiette R. QM and QM/MM studies of selectivity in organic and bioorganic chemistry Journal of Physical Organic Chemistry. 19: 608-615. DOI: 10.1002/Poc.1030  0.652
2005 Robiette R, Richardson J, Aggarwal VK, Harvey JN. On the origin of high E selectivity in the Wittig reaction of stabilized ylides: importance of dipole-dipole interactions. Journal of the American Chemical Society. 127: 13468-9. PMID 16190689 DOI: 10.1021/Ja0539589  0.653
2005 Aggarwal VK, Harvey JN, Robiette R. On the importance of leaving group ability in reactions of ammonium, oxonium, phosphonium, and sulfonium ylides. Angewandte Chemie (International Ed. in English). 44: 5468-71. PMID 16059960 DOI: 10.1002/Anie.200501526  0.66
2005 Robiette R, Defacqz N, Peeters D, Marchand-Brynaert J. A Novel Strategy Towards Aminophosphonic Derivatives Based on the Diels-Alder Cycloaddition: Experimental and Theoretical Approaches Current Organic Synthesis. 2: 453-477. DOI: 10.2174/157017905774322668  0.737
2005 Boulanger M, Leyssens T, Robiette R, Peeters D. Theoretical approach of steric effects in the Diels-Alder reaction Journal of Molecular Structure-Theochem. 731: 101-106. DOI: 10.1016/J.Theochem.2005.07.005  0.665
2004 Tinant B, Defacqz N, Robiette R, Touillaux R, Marchand-Brynaert J. Stereochemistry and conformation of amido-phosphonocyclohexene derivatives, assigned by NMR and X-ray diffraction analyses Phosphorus Sulfur and Silicon and the Related Elements. 179: 389-402. DOI: 10.1080/10426500490262522  0.504
2003 Robiette R, Cheboub-Benchaba K, Peeters D, Marchand-Brynaert J. Design of a new and highly effective chiral auxiliary for Diels-Alder reaction of 1-aminodiene. The Journal of Organic Chemistry. 68: 9809-12. PMID 14656111 DOI: 10.1021/Jo0302049  0.731
2003 Robiette R, Dekoker-Malengreau A, Marchand-Brynaert J. A study of the alkylation and rearrangement products of chiral 1,3-oxazolidine- and thiazolidine-2-thiones Heterocycles. 60: 523-536. DOI: 10.3987/Com-02-9653  0.646
2003 Tinant B, Robiette R, Marchand-Brynaert J. Crystal structure of (S)-3-(Z-1 ',3 '-butadienyl)-4-phenylthiazoline-2-one, C13H13NOS, a chiral 1-amino-diene useful in Diels-Alder cycloaddition reactions Zeitschrift Fur Kristallographie-New Crystal Structures. 218: 475-476. DOI: 10.1524/Ncrs.2003.218.Jg.507  0.526
2003 Robiette R, Defacqz N, Stofferis J, Marchand-Brynaert J. [4+2] Cycloaddition of 1-aminodienes and 2-substituted vinylphosphonates: application to asymmetric synthesis of 3-amino-5-phosphono-1-cyclohexene derivatives Tetrahedron. 59: 4167-4175. DOI: 10.1016/S0040-4020(03)00580-5  0.605
2002 Robiette R, Marchand-Brynaert J, Peeters D. Influence of diene substitution on transition state stabilization in Diels-Alder reaction. The Journal of Organic Chemistry. 67: 6823-6. PMID 12227818 DOI: 10.1021/Jo025796U  0.717
2002 Robiette R, Marchand-Brynaert J, Peeters D. Theoretical study of the influence of phosphonate substituents on Diels-Alder reactions Journal of Molecular Structure-Theochem. 587: 159-169. DOI: 10.1016/S0166-1280(02)00113-6  0.725
2001 Robiette R, Marchand-Brynaert J. Asymmetric synthesis of β- and γ-amidophosphonates by Diels–Alder reaction using chiral aminodiene: theoretical and experimental study of the facial selectivity of chiral N-dienyl lactam Journal of the Chemical Society-Perkin Transactions 1. 2155-2158. DOI: 10.1039/B105070M  0.593
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