cached image

Michel R. Gagné, Ph.D. - Publications

Affiliations: 
1987-1991 Chemistry Northwestern University, Evanston, IL 
 1991-1992 Chemistry California Institute of Technology, Pasadena, CA 
 1992-1995 Chemistry Harvard University, Cambridge, MA, United States 
 1995- Chemistry University of North Carolina, Chapel Hill, Chapel Hill, NC 
Area:
Organic Chemistry, Catalysis, Asymmetric Catalysis, Synthetic Methods, Synthetic Receptors, Biofuels, Renewable Feedstocks
Website:
http://www.chem.unc.edu/people/faculty/gagne/

144 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Wierschen AL, Romano N, Lee SJ, Gagné MR. Silylpalladium Cations Enable the Oxidative Addition of C(sp3)-O Bonds. Journal of the American Chemical Society. PMID 31532990 DOI: 10.1021/jacs.9b08178  1
2019 Peruzzi MT, Gallou F, Lee SJ, Gagné MR. Site Selective Amide Reduction of Cyclosporine A Enables Diverse Derivation of an Important Cyclic Peptide. Organic Letters. PMID 30993986 DOI: 10.1021/acs.orglett.9b01245  1
2018 Peruzzi MT, Mei QQ, Lee SJ, Gagné MR. Chemoselective amide reductions by heteroleptic fluoroaryl boron Lewis acids. Chemical Communications (Cambridge, England). PMID 29780984 DOI: 10.1039/c8cc01863d  1
2018 Roselli CA, Gagné MR. Computed thermodynamic stabilities of silylium Lewis base adducts. Organic & Biomolecular Chemistry. PMID 29542789 DOI: 10.1039/c8ob00354h  1
2018 Bender TA, Payne PR, Gagné MR. Late-stage chemoselective functional-group manipulation of bioactive natural products with super-electrophilic silylium ions. Nature Chemistry. 10: 85-90. PMID 29256501 DOI: 10.1038/nchem.2863  1
2017 Peruzzi MT, Lee SJ, Gagné MR. Gold(I) Catalyzed Dearomative Claisen Rearrangement of Allyl, Allenyl Methyl, and Propargyl Aryl Ethers. Organic Letters. PMID 29111766 DOI: 10.1021/acs.orglett.7b03306  1
2017 McCulley C, Geier MJ, Hudson BM, Gagné MR, Tantillo DJ. Biomimetic Platinum-Promoted Polyene Polycyclizations - Influence of Alkene Substitution and Pre-Cyclization Conformations. Journal of the American Chemical Society. PMID 28719198 DOI: 10.1021/jacs.7b05381  1
2016 Roselli CA, Gagné MR. Gold(i)-catalyzed addition of aldehydes to cyclopropylidene bearing 6-aryl-1,5-enynes. Organic & Biomolecular Chemistry. PMID 27853802 DOI: 10.1039/c6ob02128j  1
2016 Chung MK, White PS, Lee SJ, Gagné MR, Waters ML. Investigation of a Catenane with a Responsive Noncovalent Network: Mimicking Long Range Responses in Proteins. Journal of the American Chemical Society. PMID 27631725 DOI: 10.1021/jacs.6b07833  1
2016 Bender TA, Dabrowski JA, Zhong H, Gagné MR. Diastereoselective B(C6F5)3-Catalyzed Reductive Carbocyclization of Unsaturated Carbohydrates. Organic Letters. PMID 27508492 DOI: 10.1021/acs.orglett.6b02050  1
2016 Chung MK, Lee SJ, Waters ML, Gagné MR. Tetrameric psuedo-peptide receptors with allosteric properties. Chemical Communications (Cambridge, England). PMID 27265568 DOI: 10.1039/c6cc03296f  1
2015 Adduci LL, Bender TA, Dabrowski JA, Gagné MR. Erratum: Chemoselective conversion of biologically sourced polyols into chiral synthons. Nature Chemistry. 7: 759. PMID 26291950 DOI: 10.1038/nchem.2331  1
2015 Aseman MD, Roselli CA, Gagné MR. Promoting C-C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt-CH3 (+) Complexes. Organometallics. 34: 2707-2709. PMID 26146438 DOI: 10.1021/acs.organomet.5b00121  1
2015 Adduci LL, Bender TA, Dabrowski JA, Gagné MR. Chemoselective conversion of biologically sourced polyols into chiral synthons. Nature Chemistry. 7: 576-81. PMID 26100806 DOI: 10.1038/nchem.2277  1
2015 Weber D, Gagné MR. Aurophilicity in gold(I) catalysis: for better or worse? Topics in Current Chemistry. 357: 167-211. PMID 25518972 DOI: 10.1007/128_2014_585  1
2015 Nguyen QNN, Lodewyk MW, Bezer S, Gagné MR, Waters ML, Tantillo DJ. Effects of helix macrodipole and local interactions on catalysis of acyl transfer by α-helical peptides Acs Catalysis. 5: 1617-1622. DOI: 10.1021/cs5019277  1
2015 Aseman MD, Roselli CA, Gagné MR. Promoting C-C Bond Coupling of Benzyne and Methyl Ligands in Electron-Deficient (triphos)Pt-CH3+ Complexes Organometallics. 34: 2707-2709. DOI: 10.1021/acs.organomet.5b00121  1
2014 Bezer S, Matsumoto M, Lodewyk MW, Lee SJ, Tantillo DJ, Gagné MR, Waters ML. Correction: Identification and optimization of short helical peptides with novel reactive functionality as catalysts for acyl transfer by reactive tagging. Organic & Biomolecular Chemistry. 12: 7410. PMID 26036650 DOI: 10.1039/c4ob90119c  1
2014 Nguyen H, Gagné MR. Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt(2+) Catalysts. Acs Catalysis. 4: 855-859. PMID 25838970 DOI: 10.1021/cs401190c  1
2014 Matsumoto M, Lee SJ, Waters ML, Gagné MR. A catalyst selection protocol that identifies biomimetic motifs from β-hairpin libraries. Journal of the American Chemical Society. 136: 15817-20. PMID 25347708 DOI: 10.1021/ja503012g  1
2014 Matsumoto M, Lee SJ, Gagné MR, Waters ML. Cross-strand histidine-aromatic interactions enhance acyl-transfer rates in beta-hairpin peptide catalysts. Organic & Biomolecular Chemistry. 12: 8711-8. PMID 25254932 DOI: 10.1039/c4ob01754d  1
2014 Geier MJ, Dadkhah Aseman M, Gagné MR. Anion-Dependent Switch in C-X Reductive Elimination Diastereoselectivity. Organometallics. 33: 4353-4356. PMID 25221379 DOI: 10.1021/om5006929  1
2014 Bertucci MA, Lee SJ, Gagné MR. Selective transamidation of 3-oxo-N-acyl homoserine lactones by hydrazine derivatives. Organic & Biomolecular Chemistry. 12: 7197-200. PMID 25139543 DOI: 10.1039/c4ob01156b  1
2014 Zheng H, Adduci LL, Felix RJ, Gagné MR. Gold-catalyzed diastereoselective cycloisomerization of alkylidene-cyclopropane-bearing 1,6-diynes. Angewandte Chemie (International Ed. in English). 53: 7904-7. PMID 24920312 DOI: 10.1002/anie.201405147  1
2014 Felix RJ, Munro-Leighton C, Gagné MR. Electrophilic Pt(II) complexes: precision instruments for the initiation of transformations mediated by the cation-olefin reaction. Accounts of Chemical Research. 47: 2319-31. PMID 24845777 DOI: 10.1021/ar500047j  1
2014 Zheng H, Felix RJ, Gagné MR. Gold-catalyzed enantioselective ring-expanding cycloisomerization of cyclopropylidene bearing 1,5-enynes. Organic Letters. 16: 2272-5. PMID 24684491 DOI: 10.1021/ol5007955  1
2014 Geier MJ, Gagné MR. Diastereoselective Pt catalyzed cycloisomerization of polyenes to polycycles. Journal of the American Chemical Society. 136: 3032-5. PMID 24517454 DOI: 10.1021/ja500656k  1
2014 Adduci LL, McLaughlin MP, Bender TA, Becker JJ, Gagné MR. Metal-free deoxygenation of carbohydrates. Angewandte Chemie (International Ed. in English). 53: 1646-9. PMID 24492972 DOI: 10.1002/anie.201306864  1
2014 Bezer S, Matsumoto M, Lodewyk MW, Lee SJ, Tantillo DJ, Gagné MR, Waters ML. Identification and optimization of short helical peptides with novel reactive functionality as catalysts for acyl transfer by reactive tagging. Organic & Biomolecular Chemistry. 12: 1488-94. PMID 24448664 DOI: 10.1039/c3ob41421c  1
2013 Gutierrez O, Harrison JG, Felix RJ, Guzman FC, Gagné MR, Tantillo DJ. Carbonium vs. carbenium ion-like transition state geometries for carbocation cyclization - how strain associated with bridging affects 5-exo vs. 6-endo selectivity. Chemical Science (Royal Society of Chemistry : 2010). 4. PMID 24404374 DOI: 10.1039/C3SC51657A  1
2013 Weber D, Gagné MR. σ-π-Diauration as an alternative binding mode for digold intermediates in gold(i) catalysis. Chemical Science (Royal Society of Chemistry : 2010). 47: 335-338. PMID 23914295 DOI: 10.1039/C2SC21281A  1
2013 Felix RJ, Gutierrez O, Tantillo DJ, Gagné MR. Gold(I)-catalyzed formation of bicyclo[4.2.0]oct-1-enes. The Journal of Organic Chemistry. 78: 5685-90. PMID 23663099 DOI: 10.1021/jo400139g  1
2013 Sokol JG, Cochrane NA, Becker JJ, Gagné MR. Catalytic platinum-initiated cation-olefin reactions with alkene terminating groups. Chemical Communications (Cambridge, England). 49: 5046-8. PMID 23619982 DOI: 10.1039/c3cc41699b  1
2013 Geier MJ, Gagné MR. A Cyclization/Oxygenation Scheme for the Conversion of Polyenes into C3-Oxygenated Polycycles. Organometallics. 32: 380-383. PMID 23526863 DOI: 10.1021/om400003c  1
2013 Bertucci MA, Lee SJ, Gagné MR. Thiourea-catalyzed aminolysis of N-acyl homoserine lactones. Chemical Communications (Cambridge, England). 49: 2055-7. PMID 23376901 DOI: 10.1039/c3cc00268c  1
2013 McLaughlin MP, Adduci LL, Becker JJ, Gagné MR. Iridium-catalyzed hydrosilylative reduction of glucose to hexane(s). Journal of the American Chemical Society. 135: 1225-7. PMID 23305415 DOI: 10.1021/ja3110494  1
2013 Cochrane NA, Nguyen H, Gagne MR. Catalytic enantioselective cyclization and C3-fluorination of polyenes. Journal of the American Chemical Society. 135: 628-31. PMID 23282101 DOI: 10.1021/ja3116795  1
2012 Chung MK, Lee SJ, Waters ML, Gagné MR. Self-assembled multi-component catenanes: the effect of multivalency and cooperativity on structure and stability. Journal of the American Chemical Society. 134: 11430-43. PMID 22686511 DOI: 10.1021/ja302347q  1
2012 Chung MK, White PS, Lee SJ, Waters ML, Gagné MR. Self-assembled multi-component catenanes: structural insights into an adaptable class of molecular receptors and [2]-catenanes. Journal of the American Chemical Society. 134: 11415-29. PMID 22686480 DOI: 10.1021/ja302345n  1
2012 Brown TJ, Weber D, Gagné MR, Widenhoefer RA. Mechanistic analysis of gold(I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis(gold) vinyl species and reversible C-O bond formation. Journal of the American Chemical Society. 134: 9134-7. PMID 22621418 DOI: 10.1021/ja303844h  1
2012 Felix RJ, Weber D, Gutierrez O, Tantillo DJ, Gagné MR. A gold-catalysed enantioselective Cope rearrangement of achiral 1,5-dienes. Nature Chemistry. 4: 405-9. PMID 22522261 DOI: 10.1038/nchem.1327  1
2012 Andrews RS, Becker JJ, Gagné MR. A photoflow reactor for the continuous photoredox-mediated synthesis of C-glycoamino acids and C-glycolipids. Angewandte Chemie (International Ed. in English). 51: 4140-3. PMID 22441991 DOI: 10.1002/anie.201200593  1
2012 Weber D, Jones TD, Adduci LL, Gagné MR. Strong electronic and counterion effects on geminal digold formation and reactivity as revealed by gold(I)-aryl model complexes. Angewandte Chemie (International Ed. in English). 51: 2452-6. PMID 22278847 DOI: 10.1002/anie.201107659  1
2012 Zhao SB, Wang RY, Nguyen H, Becker JJ, Gagné MR. Electrophilic fluorination of cationic Pt-aryl complexes. Chemical Communications (Cambridge, England). 48: 443-5. PMID 22080210 DOI: 10.1039/c1cc15006e  1
2011 Zhao SB, Becker JJ, Gagné MR. Steric Crowding Makes Challenging C(sp3)-F Reductive Eliminations Feasible. Organometallics. 30: 3926-3929. PMID 21869853 DOI: 10.1021/om200515f  1
2011 Zhao SB, Wang RY, Gagné MR. {Bis[2-(diphenyl-phosphan-yl)eth-yl]phenyl-phosphane-κP,P',P''}[(Z)-8-mesityl-cyclo-oct-4-en-1-yl]platinum(II) tetra-fluorido-borate dichloro-methane disolvate. Acta Crystallographica. Section E, Structure Reports Online. 67: m972. PMID 21836947 DOI: 10.1107/S1600536811023853  1
2011 Sokol JG, Korapala CS, White PS, Becker JJ, Gagné MR. Terminating platinum-initiated cation-olefin reactions with simple alkenes. Angewandte Chemie (International Ed. in English). 50: 5658-61. PMID 21574222 DOI: 10.1002/anie.201100463  1
2011 Cochrane NA, Brookhart MS, Gagné MR. Driving Catalyst Reoxidation in Wacker Cyclizations with Acetal-Based Metal-Hydride Abstractors. Organometallics. 30: 2457-2460. PMID 21572581 DOI: 10.1021/om2001958  0.8
2011 Andrews RS, Becker JJ, Gagné MR. Investigating the rate of photoreductive glucosyl radical generation. Organic Letters. 13: 2406-9. PMID 21473567 DOI: 10.1021/ol200644w  1
2011 Weber D, Gagné MR. Pd(0)/Au(I) redox incompatibilities as revealed by Pd-catalyzed homo-coupling of arylgold(I)-complexes. Chemical Communications (Cambridge, England). 47: 5172-4. PMID 21451856 DOI: 10.1039/c1cc11055a  1
2011 Chung MK, Severin K, Lee SJ, Waters ML, Gagné MR. Constitutionally selective amplification of multicomponent 84-membered macrocyclic hosts for (-)-cytidine•H+ Chemical Science. 2: 744-747. DOI: 10.1039/c0sc00548g  1
2011 Munro-Leighton C, Adduci LL, Becker JJ, Gagné MR. Oxidative addition of secondary C-X bonds to palladium(0): A beneficial anomeric acceleration Organometallics. 30: 2646-2649. DOI: 10.1021/om200221r  1
2011 Yu X, Dai Y, Yang T, Gagné MR, Gong H. Facile synthesis of salmochelin S1, S2, MGE, DGE, and TGE Tetrahedron. 67: 144-151. DOI: 10.1016/j.tet.2010.11.007  1
2010 Andrews RS, Becker JJ, Gagné MR. Intermolecular addition of glycosyl halides to alkenes mediated by visible light. Angewandte Chemie (International Ed. in English). 49: 7274-6. PMID 20740519 DOI: 10.1002/anie.201004311  1
2010 Ghosh S, Ingerman LA, Frye AG, Lee SJ, Gagné MR, Waters ML. Dynamic cyclic thiodepsipeptide libraries from thiol-thioester exchange. Organic Letters. 12: 1860-3. PMID 20329734 DOI: 10.1021/ol1004752  1
2009 Tarselli MA, Liu A, Gagné MR. Gold(I)-catalyzed intermolecular hydroarylation of allenes with nucleophilic arenes: scope and limitations. Tetrahedron. 65: 1785-1789. PMID 21512612 DOI: 10.1016/j.tet.2008.10.110  1
2009 Bell F, Holland J, Green JC, Gagné MR. Computational Studies on the Pt(II)-Catalyzed Cycloisomerization of 1,6-dienes into Bicyclopropanes: A Mechanistic Quandary Evaluated by DFT. Organometallics. 28: 2038-2045. PMID 20161262 DOI: 10.1021/om800760x  1
2009 Nelsen DL, Gagné MR. Platinum(II) Enyne Cycloisomerization Catalysis: Intermediates and Resting States. Organometallics. 28: 950-952. PMID 20160853 DOI: 10.1021/om801069s  1
2009 Hutchby M, Houlden CE, Ford JG, Tyler SN, Gagné MR, Lloyd-Jones GC, Booker-Milburn KI. Hindered ureas as masked isocyanates: facile carbamoylation of nucleophiles under neutral conditions. Angewandte Chemie (International Ed. in English). 48: 8721-4. PMID 19816899 DOI: 10.1002/anie.200904435  1
2009 Chung MK, White PS, Lee SJ, Gagné MR. Synthesis of interlocked 56-membered rings by dynamic self-templating. Angewandte Chemie (International Ed. in English). 48: 8683-6. PMID 19816896 DOI: 10.1002/anie.200903478  1
2009 Weber D, Gagné MR. Dinuclear gold-silver resting states may explain silver effects in gold(I)-catalysis. Organic Letters. 11: 4962-5. PMID 19807117 DOI: 10.1021/ol902116b  1
2009 Tarselli MA, Zuccarello JL, Lee SJ, Gagné MR. Gold(I)-catalyzed cascade cyclization of allenyl epoxides. Organic Letters. 11: 3490-2. PMID 19588972 DOI: 10.1021/ol901391s  1
2009 Weber D, Tarselli MA, Gagné MR. Mechanistic surprises in the gold(I)-catalyzed intramolecular hydroarylation of allenes. Angewandte Chemie (International Ed. in English). 48: 5733-6. PMID 19562821 DOI: 10.1002/anie.200902049  1
2009 Gong H, Andrews RS, Zuccarello JL, Lee SJ, Gagné MR. Sn-free Ni-catalyzed reductive coupling of glycosyl bromides with activated alkenes. Organic Letters. 11: 879-82. PMID 19170565 DOI: 10.1021/ol8028737  1
2009 Houlden CE, Hutchby M, Bailey CD, Ford JG, Tyler SN, Gagné MR, Lloyd-Jones GC, Booker-Milburn KI. Room-temperature palladium-catalyzed C-H activation: ortho-carbonylation of aniline derivatives. Angewandte Chemie (International Ed. in English). 48: 1830-3. PMID 19170153 DOI: 10.1002/anie.200805842  1
2009 Pelczar EM, Munro-Leighton C, Gagné MR. Oxidative addition of glycosylbromides to trans-Ir(PMe 3) 2(CO)Cl Organometallics. 28: 663-665. DOI: 10.1021/om8011135  1
2009 Becker JJ, Gagné MR. Chiral Selection in DCC Dynamic Combinatorial Chemistry: in Drug Discovery, Bioorganic Chemistry, and Materials Science. 155-168. DOI: 10.1002/9780470551554.ch5  1
2008 Schiltz H, Chung MK, Lee SJ, Gagné MR. The effect of gas-phase reactions on the quantitation of cyclic hydrazone libraries by electrospray ionization (ESI) mass spectrometry. Organic & Biomolecular Chemistry. 6: 3597-600. PMID 19082161 DOI: 10.1039/b808490d  1
2008 Gong H, Gagné MR. Diastereoselective Ni-catalyzed Negishi cross-coupling approach to saturated, fully oxygenated C-alkyl and C-aryl glycosides. Journal of the American Chemical Society. 130: 12177-83. PMID 18698769 DOI: 10.1021/ja8041564  1
2008 Chung MK, Hebling CM, Jorgenson JW, Severin K, Lee SJ, Gagné MR. Deracemization of a dynamic combinatorial library induced by (-)-cytidine and (-)-2-thiocytidine. Journal of the American Chemical Society. 130: 11819-27. PMID 18693687 DOI: 10.1021/ja803658n  1
2008 Mullen CA, Campbell AN, Gagné MR. Asymmetric oxidative cation/olefin cyclization of polyenes: evidence for reversible cascade cyclization. Angewandte Chemie (International Ed. in English). 47: 6011-4. PMID 18649296 DOI: 10.1002/anie.200801423  1
2008 Houlden CE, Bailey CD, Ford JG, Gagné MR, Lloyd-Jones GC, Booker-Milburn KI. Distinct reactivity of Pd(OTs)2: the intermolecular Pd(II)-catalyzed 1,2-carboamination of dienes. Journal of the American Chemical Society. 130: 10066-7. PMID 18613664 DOI: 10.1021/ja803397y  1
2008 Korotchenko VN, Severin K, Gagné MR. The aerobic oxidation of alcohols with a ruthenium porphyrin catalyst in organic and fluorinated solvents. Organic & Biomolecular Chemistry. 6: 1961-5. PMID 18480911 DOI: 10.1039/b800583d  1
2008 Tarselli MA, Gagné MR. Gold(I)-catalyzed intramolecular hydroarylation of allenes. The Journal of Organic Chemistry. 73: 2439-41. PMID 18278940 DOI: 10.1021/jo7024948  1
2008 Feducia JA, Gagné MR. Reversibility effects on the stereoselectivity of Pt(II)-mediated cascade poly-ene cyclizations. Journal of the American Chemical Society. 130: 592-9. PMID 18095679 DOI: 10.1021/ja075518i  1
2007 Mullen CA, Gagné MR. Regioselective oxidative cation-olefin cyclization of poly-enes: catalyst turnover via hydride abstraction. Journal of the American Chemical Society. 129: 11880-1. PMID 17850150 DOI: 10.1021/ja073573l  1
2007 Tarselli MA, Chianese AR, Lee SJ, Gagné MR. Gold(I)-catalyzed asymmetric cycloisomerization of eneallenes into vinylcyclohexenes. Angewandte Chemie (International Ed. in English). 46: 6670-3. PMID 17661298 DOI: 10.1002/anie.200701959  1
2007 Korotchenko VN, Gagné MR. Palladium-catalyzed cyclization of 1,omega-dienols: multiple ways to intramolecularly trap a carbocation. The Journal of Organic Chemistry. 72: 4877-81. PMID 17530903 DOI: 10.1021/jo0705871  1
2007 Chianese AR, Lee SJ, Gagné MR. Electrophilic activation of alkenes by platinum(II): so much more than a slow version of palladium(II). Angewandte Chemie (International Ed. in English). 46: 4042-59. PMID 17487902 DOI: 10.1002/anie.200603954  1
2007 Gong H, Sinisi R, Gagné MR. A room temperature negishi cross-coupling approach to C-alkyl glycosides. Journal of the American Chemical Society. 129: 1908-9. PMID 17261000 DOI: 10.1021/ja068950t  1
2007 Campbell AN, Gagné MR. Room-temperature β-H elimination in (P2P)Pt(OR) cations: Convenient synthesis of a platinum hydride Organometallics. 26: 2788-2790. DOI: 10.1021/om061105z  1
2007 Nowroozi-Isfahani T, Musaev DG, Morokuma K, Gagné MR. Density functional study of platinum(II)-mediated bicyclization of 1,6-dienylphenols Organometallics. 26: 2540-2549. DOI: 10.1021/om060632f  1
2007 Korotchenko VN, Gagné MR. Fluorophobic enhanced decontamination of a mustard simulant by porous monolithic flow-through columns Reactive and Functional Polymers. 67: 422-431. DOI: 10.1016/j.reactfunctpolym.2007.02.010  1
2006 Feducia JA, Campbell AN, Doherty MQ, Gagné MR. Modular catalysts for diene cycloisomerization: rapid and enantioselective variants for bicyclopropane synthesis. Journal of the American Chemical Society. 128: 13290-7. PMID 17017811 DOI: 10.1021/ja064335d  1
2006 Voshell SM, Lee SJ, Gagné MR. The discovery of an enantioselective receptor for (-)-adenosine from a racemic dynamic combinatorial library. Journal of the American Chemical Society. 128: 12422-3. PMID 16984185 DOI: 10.1021/ja0647699  1
2006 Mullen CA, Gagné MR. Catalytic asymmetric prins cyclizations: cation generation and trapping with (BINAP)Pt dications. Organic Letters. 8: 665-8. PMID 16468737 DOI: 10.1021/ol052845r  1
2006 Feducia JA, Campbell AN, Anthis JW, Gagné MR. Protonolysis of cationic Pt-C bonds with mild acids: Can ligand torsional effects speed associative processes? Organometallics. 25: 3114-3117. DOI: 10.1021/om051066b  1
2006 Burri E, Leeder SM, Severin K, Gagné MR. Modulating the activity and selectivity of an immobilized ruthenium-porphyrin catalyst using a fluorous solvent Advanced Synthesis and Catalysis. 348: 1640-1644. DOI: 10.1002/adsc.200505456  1
2005 Kerber WD, Gagné MR. Cycloisomerization of dienes with carbophilic lewis acids: mimicking terpene biosynthesis with Pt(II) catalysts. Organic Letters. 7: 3379-81. PMID 16018665 DOI: 10.1021/ol051277c  1
2005 Kerber WD, Nelsen DL, White PS, Gagné MR. Synthesis and ligand exchange reactions of P2Pd(II) and P2Pt(II) salicylaldimates. Dalton Transactions (Cambridge, England : 2003). 1948-51. PMID 15909041 DOI: 10.1039/b501827g  1
2005 Voshell SM, Gagné MR. Rigidified dendritic structures for imprinting chiral information Organometallics. 24: 6338-6350. DOI: 10.1021/om050647y  1
2005 Nelsen DL, White PS, Gagné MR. Synthesis and characterization of bifunctional compounds: Templates for metal crown ether assemblies Organometallics. 24: 5479-5483. DOI: 10.1021/om050639h  1
2004 Becker JJ, Gagné MR. Exploiting the synergy between coordination chemistry and molecular imprinting in the quest for new catalysts. Accounts of Chemical Research. 37: 798-804. PMID 15491126 DOI: 10.1021/ar000102u  1
2004 Kerber WD, Koh JH, Gagné MR. Platinum(II)-catalyzed 1,6-diene cycloisomerizations: turnover in the absence of beta-hydride elimination. Organic Letters. 6: 3013-5. PMID 15330671 DOI: 10.1021/ol048780u  1
2004 Koh JH, Gagné MR. Pd(II)- and Pt(II)-mediated polycyclization reactions of 1,5- and 1,6-dienes: evidence in support of carbocation intermediates. Angewandte Chemie (International Ed. in English). 43: 3459-61. PMID 15221839 DOI: 10.1002/anie.200453913  1
2004 Pelz KA, White PS, Gagné MR. Persistent N-chirality as the only Source of asymmetry in nonracemic N 2PdCl 2 complexes Organometallics. 23: 3210-3217. DOI: 10.1021/om0498495  1
2004 Koh JH, Mascarenhas C, Gagné MR. Pd(II)-Catalyzed cyclogeneration of carbocations: Subsequent rearrangement and trapping under oxidative conditions Tetrahedron. 60: 7405-7410. DOI: 10.1016/j.tet.2004.06.023  1
2004 Aït-Haddou H, Leeder SM, Gagné MR. Amino-acid containing metallomonomers copolymerized into porous organic polymers: Applicability to allylic alkylation catalysis Inorganica Chimica Acta. 357: 3854-3864. DOI: 10.1016/j.ica.2004.04.017  1
2003 Leeder SM, Gagné MR. Fluorophobic effect promotes partitioning of organics into macroporous organic polymers: a method for achieving high local concentrations. Journal of the American Chemical Society. 125: 9048-54. PMID 15369360 DOI: 10.1021/ja0353558  1
2003 Viton F, White PS, Gagné MR. Crown-ether functionalised second coordination sphere palladium catalysts by molecular imprinting. Chemical Communications (Cambridge, England). 3040-1. PMID 14703847  1
2003 Becker JJ, White PS, Gagné MR. Synthesis and characterization of chiral diphosphine platinum(II) VANOL and VAPOL complexes Organometallics. 22: 3245-3249. DOI: 10.1021/om7006419  1
2003 Becker JJ, Gagné MR. Imprinting Chiral Information into Rigidified Dendrimers Organometallics. 22: 4984-4998. DOI: 10.1021/om0340387  1
2003 Anthis JW, Larsen AO, White PS, Gagné MR. Ethylene-linked bis(phenol) ligands: Efficient synthesis, Ti(IV) coordination chemistry, and Lewis acid catalysis Journal of Organometallic Chemistry. 688: 121-124. DOI: 10.1016/j.jorganchem.2003.08.046  1
2002 Becker JJ, Van Orden LJ, White PS, Gagné MR. Electron-poor benzonitriles as labile, stabilizing ligands in asymmetric catalysis. Organic Letters. 4: 727-30. PMID 11869112  1
2002 Brunkan NM, Gagné MR. NMR structure of an unusual Pt2(μ-BINOL) dimer: More surprises from a seemingly simple chiral ligand Organometallics. 21: 4711-4717. DOI: 10.1021/om0204888  1
2002 Brunkan NM, Gagné MR. (dppe)Pt(OTf)2 and (R-BINAP)Pt(OTf)2 Lewis acids catalyze the Diels-Alder reaction by different mechanisms Organometallics. 21: 1576-1582. DOI: 10.1021/om010987t  1
2002 Brunkan NM, White PS, Gagné MR. Thermodynamic and kinetic relationships between Lewis acid-Lewis base complexes relevant to the P2Pt(OTf)2-catalyzed Diels-Alder reaction Organometallics. 21: 1565-1575. DOI: 10.1021/om0109861  1
2002 Koh JH, Larsen AO, White PS, Gagné MR. Disparate roles of chiral ligands and molecularly imprinted cavities in asymmetric catalysis and chiral poisoning Organometallics. 21: 7-9. DOI: 10.1021/om010944c  1
2001 Kissling RM, Gagné MR. Structure and reactivity of mixed alkali metal alkoxide/aryloxide catalysts. The Journal of Organic Chemistry. 66: 9005-10. PMID 11749634 DOI: 10.1021/jo016105h  1
2001 Becker JJ, White PS, Gagné MR. Asymmetric catalysis with the normally unresolvable, conformationally dynamic 2,2'-bis(diphenylphosphino)-1,1'-biphenyl (biphep). Journal of the American Chemical Society. 123: 9478-9. PMID 11562245 DOI: 10.1021/ja016167p  1
2001 Koh JH, Larsen AO, Gagné MR. Asymmetric Pt(II)-catalyzed ene reactions: counterion-dependent additive and diphosphine electronic effects. Organic Letters. 3: 1233-6. PMID 11348202 DOI: 10.1021/ol015702n  1
2001 Vinson SL, Gagné MR. Can a fluorous biphase solvent system improve a polymer immobilized heterogeneous hydrogenation catalyst? Chemical Communications. 1130-1131.  1
2001 Santora BP, Gagné MR, Moloyt KG, Radu NS. Porogen and cross-linking effects on the surface area, pore volume distribution, and morphology of macroporous polymers obtained by bulk polymerization 3 Macromolecules. 34: 658-661.  1
2000 Kissling RM, Gagne MR. Improved ester interchange catalysts Organic Letters. 2: 4209-12. PMID 11150201 DOI: 10.1021/ol0067585  1
2000 Taylor RA, Santora BP, Gagne MR. A polymer-supported rhodium catalyst that functions in polar protic solvents Organic Letters. 2: 1781-3. PMID 10880225 DOI: 10.1021/ol005999+  1
2000 Evans DA, Campos KR, Tedrow JS, Michael FE, Gagné MR. Application of chiral mixed phosphorus/sulfur ligands to palladium-catalyzed allylic substitutions Journal of the American Chemical Society. 122: 7905-7920. DOI: 10.1021/ja992543i  1
2000 Brunkan NM, Gagné MR. Effect of correl cavities associated with molecularly imprinted platinum centers on the selectivity of ligand-exchange reactions at platinum Journal of the American Chemical Society. 122: 6217-6225. DOI: 10.1021/ja000462c  1
2000 Santora BP, Gagné MR. A wolf in sheep's clothing Chemical Innovation. 30: 22-29.  1
2000 Gagné MR, Becker JJ, Brunkan NM. Molecular imprinting approach to controlling catalyst selectivities American Chemical Society, Polymer Preprints, Division of Polymer Chemistry. 41: 404.  1
1999 Evans DA, Campos KR, Tedrow JS, Michael FE, Gagné MR. Chiral Mixed Phosphorus/Sulfur Ligands for Palladium-Catalyzed Allylic Alkylations and Aminations. The Journal of Organic Chemistry. 64: 2994-2995. PMID 11674390 DOI: 10.1021/jo990344b  1
1999 Kissling RM, Gagné MR. Alkali Metal Alkoxide Clusters: Convenient Catalysts for the Synthesis of Methylphosphonates. The Journal of Organic Chemistry. 64: 1585-1590. PMID 11674222 DOI: 10.1021/jo9820521  1
1999 Larsen AO, White PS, Gagné MR. Acid-Base Adducts of Catalytically Active Titanium(IV) Lewis Acids. Inorganic Chemistry. 38: 4824-4828. PMID 11671212  1
1999 Becker JJ, White PS, Gagné MR. Synthesis and Characterization of Chiral Platinum(II) Sulfonamides: (dppe)Pt(NN) and (dppe)Pt(NO) Complexes. Inorganic Chemistry. 38: 798-801. PMID 11670846  1
1999 Korn MR, Lennon JD, Glish GL, Gagné MR. α,ω-heterotelechelic poly(ε-caprolactone)s via ring-opening/chain-transfer polymerization and their utility as precursors to AB and ABC block copolymers Macromolecules. 32: 5149-5153. DOI: 10.1021/ma981400y  1
1999 Larsen AO, Taylor RA, White PS, Gagné MR. Asymmetric Synthesis of Rigid C2-Symmetric Bis(ferrocenyl) Diol and Diamine Ligands Organometallics. 18: 5157-5162.  1
1999 Mills WY, Kissling RM, Gagné MR. A novel catalytic approach to the chemical detoxification of P-ester nerve agents Chemical Communications. 1713-1714.  1
1999 Santora BP, White PS, Gagné MR. Methods for the synthesis of the diels-alder catalysts (ArO)2TiX2 (X = Cl, Br, I; Ar = 2-tert-butyl-6-methylphenyl) Organometallics. 18: 2557-2560.  1
1998 Brunkan NM, White PS, Gagne MR. Unorthodox C,O binding mode of Me2BINOL in Pt(II) complexes [14] Journal of the American Chemical Society. 120: 11002-11003. DOI: 10.1021/ja982143f  1
1998 Brunkan NM, White PS, Gagné MR. Platinum(II) complexes with constructive and destructive interaction of diphosphane and binaphthol ligands Angewandte Chemie - International Edition. 37: 1579-1582. DOI: 10.1002/(SICI)1521-3773(19980619)37:11<1579::AID-ANIE1579>3.0.CO;2-A  1
1998 Chen H, White PS, Gagné MR. Synthesis and reactivity of titanium(IV)-salen complexes containing oxygen and chloride ligands Organometallics. 17: 5358-5366.  1
1998 Armistead LT, White PS, Gagné MR. Synthesis and structure of chiral titanium(IV) complexes containing N-substituted amino alcohols Organometallics. 17: 4232-4239.  1
1998 Santora BP, Larsen AO, Gagné MR. Toward the molecular imprinting of titanium Lewis acids: Demonstration of Diels-Alder catalysis Organometallics. 17: 3138-3140.  1
1998 Korn MR, Gagné MR. Convenient depolymerization route to telechelic polycarbonate oligomers Macromolecules. 31: 4023-4026.  1
1998 Armistead LT, White PS, Gagné MR. Synthesis and structure of titanium(IV) amido complexes containing C2-symmetric bis(sulfonamide) ligands Organometallics. 17: 216-220.  1
1997 Stanton MG, Gagné MR. A Mild Protocol for the Conversion of Simple Esters to tert-Butyl Esters. The Journal of Organic Chemistry. 62: 8240-8242. PMID 11671944  0.48
1994 Giardello MA, Conticello VP, Brard L, Gagné MR, Marks TJ. Chiral organolanthanides designed for asymmetric catalysis. A kinetic and mechanistic study of enantioselective olefin hydroamination/cyclization and hydrogenation by C1-Symmetric Me2Si(Me4C5)(C5H 3R*)Ln complexes where R* = chiral auxiliary Journal of the American Chemical Society. 116: 10241-10254.  1
1992 Gagne MR, Grubbs RH, Feldman J, Ziller JW. Catalytic activity of a well-defined binuclear ruthenium alkylidene complex Organometallics. 11: 3933-3935. DOI: 10.1021/om00060a003  0.4
1992 Gagné MR, Stern CL, Marks TJ. Organolanthanide-catalyzed hydroamination. A kinetic, mechanistic, and diastereoselectivity study of the cyclization of N-unprotected amino olefins Journal of the American Chemical Society. 114: 275-294.  1
1992 Gagné MR, Grubbs RH, Feldman J, Ziller JW. Catalytic activity of a well-defined binuclear ruthenium alkylidene complex Organometallics. 11: 3933-3935.  1
1992 Gagné MR, Brard L, Conticello VP, Giardello MA, Stern CL, Marks TJ. Stereoselection effects in the catalytic hydroamination/cyclization of aminoolefins at chiral organolanthanide centers Organometallics. 11: 2003-2005.  1
1990 Marinelli G, Streib WE, Huffman JC, Caulton KG, Gagné MR, Takats J, Dartiguenave M, Chardon C, Jackson SA, Eisenstein O. The origin of structural variety of alkyne complexes of d8 metals. An example of structural isomerism Polyhedron. 9: 1867-1881. DOI: 10.1016/S0277-5387(00)83999-6  1
1990 Gagné MR, Nolan SP, Marks TJ. Organolanthanide-centered hydroamination/cyclization of aminoolefins. Expedient oxidative access to catalytic cycles Organometallics. 9: 1716-1718.  1
1989 Gagné MR, Marks TJ. Organolanthanide-catalyzed hydroamination. Facile, regiospecific cyclization of unprotected amino olefins Journal of the American Chemical Society. 111: 4108-4109.  1
1988 Gagné MR, Takats J. Directed synthesis of dimetallacyclobutenes: Reaction of M(CO)4(η2-CF3C≡CCF3) (M = Ru, Os) with other 18-electron species Organometallics. 7: 561-563.  1
Show low-probability matches.