Tomislav Rovis, Ph.D. - Publications

Affiliations: 
2000-2016 Chemistry Colorado State University, Fort Collins, CO 
 2016- Chemistry Columbia University, New York, NY 
Area:
Organic Chemistry, Catalysis
Website:
https://chem.columbia.edu/people/faculty/tomislav-rovis/

232 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2024 Xie KA, Bednarova E, Joe CL, Sherwood TC, Welin ER, Rovis T. A Unified Method for Oxidative and Reductive Decarboxylative Arylation with Orange Light-Driven Ir/Ni Metallaphotoredox Catalysis. Journal of the American Chemical Society. PMID 39236338 DOI: 10.1021/jacs.4c08375  0.323
2024 Marchese AD, Dorsheimer JR, Rovis T. Photoredox-Catalyzed Generation of Tertiary Anions from Primary Amines via a Radical Polar Crossover. Angewandte Chemie (International Ed. in English). e202317563. PMID 38189622 DOI: 10.1002/anie.202317563  0.366
2023 Wagner-Carlberg N, Rovis T. Rhodium(III)-Catalyzed Remote Hydroamidation of Internal Alkenes via Chain Walking. Acs Catalysis. 13: 16337-16343. PMID 39006066 DOI: 10.1021/acscatal.3c05075  0.442
2023 Treacy SM, Vaz DR, Noman S, Tard C, Rovis T. Coupling of α-bromoamides and unactivated alkenes to form γ-lactams through EDA and photocatalysis. Chemical Science. 14: 1569-1574. PMID 36794189 DOI: 10.1039/d2sc05973h  0.35
2023 Zhang X, Shen Y, Rovis T. Photoinduced Nickel-Catalyzed Selective -Demethylation of Trialkylamines Using C(sp)-Bromides as HAT Reagents. Journal of the American Chemical Society. PMID 36724205 DOI: 10.1021/jacs.2c12767  0.306
2022 Burg F, Rovis T. Rh(III)-catalyzed Intra- and Intermolecular 3,4-Difunctionalization of 1,3-Dienes Rh(III)-π-allyl Amidation with 1,4,2-Dioxazolones. Acs Catalysis. 12: 9690-9697. PMID 37829170 DOI: 10.1021/acscatal.2c02537  0.366
2022 Wagner-Carlberg N, Rovis T. Rhodium(III)-Catalyzed Anti-Markovnikov Hydroamidation of Unactivated Alkenes Using Dioxazolones as Amidating Reagents. Journal of the American Chemical Society. PMID 36453859 DOI: 10.1021/jacs.2c10552  0.513
2021 Kang YC, Treacy SM, Rovis T. Iron-Catalyzed Photoinduced LMCT: a 1° C-H Abstraction Enables Skeletal Rearrangements and C(sp)-H Alkylation. Acs Catalysis. 11: 7442-7449. PMID 35669035 DOI: 10.1021/acscatal.1c02285  0.434
2021 Zhang X, Rovis T. Photocatalyzed Triplet Sensitization of Oximes Using Visible Light Provides a Route to Nonclassical Beckmann Rearrangement Products. Journal of the American Chemical Society. PMID 34905347 DOI: 10.1021/jacs.1c10148  0.502
2021 Dorsheimer JR, Ashley MA, Rovis T. Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines. Journal of the American Chemical Society. 143: 19294-19299. PMID 34767360 DOI: 10.1021/jacs.1c10150  0.521
2021 Lee S, Rovis T. Rh(III)-Catalyzed Three-Component -Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones. Acs Catalysis. 11: 8585-8590. PMID 34745710 DOI: 10.1021/acscatal.1c02406  0.501
2021 Shen Y, Rovis T. Late-Stage -Me Selective Arylation of Trialkylamines Enabled by Ni/Photoredox Dual Catalysis. Journal of the American Chemical Society. PMID 34590864 DOI: 10.1021/jacs.1c08157  0.436
2020 Lee S, Jang YJ, Phipps EJT, Lei H, Rovis T. Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes. Synthesis. 52: 1247-1252. PMID 34290458 DOI: 10.1055/s-0039-1690756  0.543
2020 Ravetz BD, Tay NES, Joe CL, Sezen-Edmonds M, Schmidt MA, Tan Y, Janey JM, Eastgate MD, Rovis T. Development of a Platform for Near-Infrared Photoredox Catalysis. Acs Central Science. 6: 2053-2059. PMID 33274281 DOI: 10.1021/acscentsci.0c00948  0.682
2020 Ashley MA, Rovis T. Photoredox-Catalyzed Deaminative Alkylation via C-N Bond Activation of Primary Amines. Journal of the American Chemical Society. PMID 33058665 DOI: 10.1021/jacs.0c08595  0.424
2020 Lei H, Rovis T. A site-selective amination catalyst discriminates between nearly identical C-H bonds of unsymmetrical disubstituted alkenes. Nature Chemistry. PMID 32541949 DOI: 10.1038/S41557-020-0470-Z  0.453
2020 Lee S, Semakul N, Rovis T. Direct Regio- and Diastereoselective Synthesis of δ-Lactams from Acrylamides and Unactivated Alkenes Initiated by Rh -Catalyzed C-H Activation. Angewandte Chemie (International Ed. in English). PMID 32045098 DOI: 10.1002/Anie.201916332  0.628
2020 Nicastri MC, Lehnherr D, Lam YH, DiRocco DA, Rovis T. Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis. Journal of the American Chemical Society. PMID 31904228 DOI: 10.1021/Jacs.9B10871  0.799
2019 Phipps EJT, Piou T, Rovis T. Rh(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C-H Activation. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 30: 1787-1790. PMID 32801480 DOI: 10.1055/S-0039-1690130  0.519
2019 Lehnherr D, Lam YH, Nicastri MC, Liu J, Newman JA, Regalado EL, DiRocco DA, Rovis T. Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer. Journal of the American Chemical Society. PMID 31849221 DOI: 10.1021/Jacs.9B10870  0.779
2019 Thullen SM, Treacy SM, Rovis T. Regioselective Alkylative Cross-Coupling of Remote Unactivated C()-H Bonds. Journal of the American Chemical Society. 141: 14062-14067. PMID 31478370 DOI: 10.1021/Jacs.9B07014  0.51
2019 Lee S, Lei H, Rovis T. A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources. Journal of the American Chemical Society. PMID 31381308 DOI: 10.1021/Jacs.9B07012  0.601
2019 Lei H, Conway JH, Cook CC, Rovis T. Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes. Journal of the American Chemical Society. PMID 31310537 DOI: 10.1021/Jacs.9B06366  0.541
2019 Theunissen C, Ashley MA, Rovis T. Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis. Journal of the American Chemical Society. PMID 31010292 DOI: 10.1021/Jacs.8B13663  0.746
2019 Phipps EJT, Rovis T. Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols. Journal of the American Chemical Society. PMID 30998324 DOI: 10.1021/Jacs.9B02156  0.492
2019 Hassan IS, Ta AN, Danneman MW, Semakul N, Burns M, Basch CH, Dippon VN, McNaughton BR, Rovis T. Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme. Journal of the American Chemical Society. PMID 30865436 DOI: 10.1021/Jacs.9B01596  0.6
2019 Ashley MA, Yamauchi C, Chu JCK, Otsuka S, Yorimitsu H, Rovis T. Photoredox-Catalyzed Site-Selective α-C(sp )-H Alkylation of Primary Amine Derivatives. Angewandte Chemie (International Ed. in English). PMID 30768740 DOI: 10.1002/Anie.201812227  0.513
2019 Lei H, Rovis T. Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins. Journal of the American Chemical Society. PMID 30715868 DOI: 10.1021/Jacs.9B00237  0.576
2019 Ravetz BD, Pun AB, Churchill EM, Congreve DN, Rovis T, Campos LM. Photoredox catalysis using infrared light via triplet fusion upconversion. Nature. 565: 343-346. PMID 30651612 DOI: 10.1038/S41586-018-0835-2  0.416
2019 Otsuka S, Nogi K, Rovis T, Yorimitsu H. Photoredox-Catalyzed Alkenylation of Benzylsulfoniums. Chemistry, An Asian Journal. PMID 30644178 DOI: 10.1002/Asia.201801732  0.481
2019 Lee S, Jang YJ, Phipps EJT, Lei H, Rovis T. Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes Synthesis. 52: 1247-1252. DOI: 10.1055/S-0039-1690756  0.605
2019 Phipps EJT, Piou T, Rovis T. Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation Synlett. 30: 1787-1790. DOI: 10.1055/s-0039-1690130  0.49
2018 Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 9: 8024. PMID 30542552 DOI: 10.1039/C8Sc90195C  0.808
2018 Ye J, Kalvet I, Schoenebeck F, Rovis T. Direct α-alkylation of primary aliphatic amines enabled by CO and electrostatics. Nature Chemistry. PMID 30061617 DOI: 10.1038/S41557-018-0085-9  0.512
2018 Piou T, Romanov-Michailidis F, Ashley MA, Romanova-Michaelides M, Rovis T. Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization. Journal of the American Chemical Society. PMID 30033723 DOI: 10.1021/Jacs.8B04243  0.545
2018 Romanov-Michailidis F, Ravetz BD, Paley DW, Rovis T. Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles. Journal of the American Chemical Society. PMID 29641190 DOI: 10.1021/Jacs.8B02716  0.486
2018 Rovis T, Oberg K, Cochran B, Cook M. The Catalytic Alkylative Desymmetrization of Anhydrides in a Formal Synthesis of Ionomycin Synthesis. 50: 4343-4350. DOI: 10.1055/S-0037-1610108  0.842
2018 Johnston J, Rovis T. Cluster Preface: Alkene Halofunctionalization Synlett. 29: 399-400. DOI: 10.1055/S-0037-1609319  0.649
2018 Ravetz BD, Wang JY, Ruhl KE, Rovis T. Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II) Acs Catalysis. 9: 200-204. DOI: 10.1021/Acscatal.8B04326  0.42
2018 Ravetz BD, Ruhl KE, Rovis T. External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light Acs Catalysis. 8: 5323-5327. DOI: 10.1021/Acscatal.8B01431  0.413
2017 Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 8: 1666. PMID 30123475 DOI: 10.1039/c6sc90080a  0.806
2017 Thullen SM, Rubush DM, Rovis T. A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation/Ring-Expansion Approach to Substituted Azepanes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 28: 2755-2758. PMID 29861552 DOI: 10.1055/S-0036-1589049  0.83
2017 Conway JH, Rovis T. Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams. Journal of the American Chemical Society. PMID 29278330 DOI: 10.1021/Jacs.7B11455  0.57
2017 Piou T, Rovis T. Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization. Accounts of Chemical Research. PMID 29272106 DOI: 10.1021/Acs.Accounts.7B00444  0.546
2017 Chu JCK, Rovis T. Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer. Angewandte Chemie (International Ed. in English). PMID 29206316 DOI: 10.1002/Anie.201703743  0.451
2017 Thullen SM, Rovis T. A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System. Journal of the American Chemical Society. PMID 29048886 DOI: 10.1021/Jacs.7B09252  0.479
2017 Niu Y, Wang N, Muñoz A, Xu J, Zeng H, Rovis T, Lee JK. Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects. Journal of the American Chemical Society. PMID 29039669 DOI: 10.1021/Jacs.7B05229  0.387
2017 Chen DF, Chu JCK, Rovis T. Directed γ-C(sp(3))-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis. Journal of the American Chemical Society. PMID 29022709 DOI: 10.1021/Jacs.7B09306  0.411
2017 Flanigan DM, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums. Chemical Science. 8: 6566-6569. PMID 28989683 DOI: 10.1039/C7Sc02648J  0.544
2017 Chen DF, Rovis T. N-Heterocyclic Carbene and Chiral Brønsted Acid Cooperative Catalysis for a Highly Enantioselective [4+2] Annulation. Synthesis. 49: 293-298. PMID 28690345 DOI: 10.1055/S-0036-1588349  0.475
2017 Semakul N, Jackson KE, Paton RS, Rovis T. Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation. Chemical Science. 8: 1015-1020. PMID 28451239 DOI: 10.1039/C6Sc02587K  0.463
2017 Stache EE, Rovis T, Doyle AG. Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides. Angewandte Chemie (International Ed. in English). PMID 28230304 DOI: 10.1002/Anie.201700097  0.846
2017 Piou T, Romanov-Michailidis F, Romanova-Michaelides M, Jackson KE, Semakul N, Taggart TD, Newell BS, Rithner CD, Paton RS, Rovis T. Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study. Journal of the American Chemical Society. PMID 28060499 DOI: 10.1021/Jacs.6B11670  0.477
2017 Rovis T, Cochran B, Henderson D, Thullen S. Rhodium-Catalyzed Desymmetrization of meso-Glutaric Anhydrides to Access Enantioenriched anti,anti-Polypropionates Synlett. 29: 306-309. DOI: 10.1055/S-0036-1591488  0.439
2016 Ruhl KE, Rovis T. Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition. Journal of the American Chemical Society. 138: 15527-15530. PMID 27934027 DOI: 10.1021/Jacs.6B08792  0.791
2016 Chu JC, Rovis T. Amide-directed photoredox-catalysed C-C bond formation at unactivated sp(3) C-H bonds. Nature. PMID 27732580 DOI: 10.1038/Nature19810  0.32
2015 Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 26: 1520-1524. PMID 27540274 DOI: 10.1055/S-0034-1381006  0.725
2015 Piou T, Rovis T. Rhodium-catalysed syn-carboamination of alkenes via a transient directing group. Nature. 527: 86-90. PMID 26503048 DOI: 10.1038/Nature15691  0.457
2015 White NA, Rovis T. Correction to "Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals". Journal of the American Chemical Society. 137: 13210. PMID 26439476 DOI: 10.1021/Jacs.5B09675  0.674
2015 Archambeau A, Rovis T. Rhodium(III)-Catalyzed Allylic C(sp(3) )-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles. Angewandte Chemie (International Ed. in English). 54: 13337-40. PMID 26358769 DOI: 10.1002/Anie.201504150  0.465
2015 White NA, Rovis T. Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals. Journal of the American Chemical Society. 137: 10112-5. PMID 26256839 DOI: 10.1021/Jacs.5B06390  0.73
2015 Telitel S, Vallet AL, Flanigan DM, Graff B, Morlet-Savary F, Rovis T, Lalevée J, Lacôte E. Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 13772-7. PMID 26239157 DOI: 10.1002/Chem.201500499  0.38
2015 Romanov-Michailidis F, Rovis T. Organic chemistry: Natural polarity inverted. Nature. 523: 417-8. PMID 26201594 DOI: 10.1038/523417A  0.497
2015 Romanov-Michailidis F, Sedillo KF, Neely JM, Rovis T. Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation. Journal of the American Chemical Society. PMID 26154248 DOI: 10.1021/Jacs.5B04946  0.749
2015 Flanigan DM, Romanov-Michailidis F, White NA, Rovis T. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. Chemical Reviews. PMID 25992594 DOI: 10.1021/Acs.Chemrev.5B00060  0.669
2015 Chu JC, Dalton DM, Rovis T. Zn-catalyzed enantio- and diastereoselective formal [4 + 2] cycloaddition involving two electron-deficient partners: asymmetric synthesis of piperidines from 1-azadienes and nitro-alkenes. Journal of the American Chemical Society. 137: 4445-52. PMID 25821893 DOI: 10.1021/Jacs.5B00033  0.798
2015 Hyster TK, Rovis T. Correction: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 51: 5778. PMID 25749239 DOI: 10.1039/c5cc90120k  0.675
2015 Zhang WZ, Chu JC, Oberg KM, Rovis T. Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon. Journal of the American Chemical Society. 137: 553-5. PMID 25580807 DOI: 10.1021/Ja510348P  0.849
2015 Filloux CM, Rovis T. Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives. Journal of the American Chemical Society. 137: 508-17. PMID 25545834 DOI: 10.1021/Ja511445X  0.576
2015 Hyster TK, Dalton DM, Rovis T. Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones. Chemical Science (Royal Society of Chemistry : 2010). 6: 254-258. PMID 25489470 DOI: 10.1039/C4Sc02590C  0.837
2015 Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate Synlett. 26: 1520-1524. DOI: 10.1055/s-0034-1381006  0.326
2015 Gaunt MJ, Chow HF, Rovis T. Cluster preface: Catalysis using sustainable metals - Part II Synlett. 26: 306. DOI: 10.1055/S-0034-1380054  0.321
2015 White NA, Rovis T. Oxidatively initiated NHC-catalyzed enantioselective synthesis of 3,4-disubstituted cyclopentanones from enals Journal of the American Chemical Society. 137: 10112-10115. DOI: 10.1021/jacs.5b06390  0.643
2014 Rubush DM, Rovis T. Stereoselective Synthesis of Dioxolanes and Oxazolidines via a Desymmetrization Acetalization/Michael Cascade. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 713-717. PMID 25960607 DOI: 10.1055/S-0033-1340669  0.844
2014 Ozboya KE, Rovis T. A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 2665-2668. PMID 25954060 DOI: 10.1055/S-0034-1379167  0.369
2014 White NA, Ozboya KE, Flanigan DM, Rovis T. Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Asian Journal of Organic Chemistry / Managing Editor, Richard Threlfall. 3: 442-444. PMID 25485210 DOI: 10.1002/Ajoc.201402031  0.705
2014 Oberg KM, Martin TJ, Oinen ME, Dalton DM, Friedman RK, Neely JM, Rovis T. Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Pentenyl Isocyanate and 4-Ethynylanisole: Preparation and Use of Taddolpyrrolidine Phosphoramidite. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 91: 150-161. PMID 25346554 DOI: 10.15227/Orgsyn.091.0150  0.797
2014 White NA, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer. Journal of the American Chemical Society. 136: 14674-7. PMID 25302860 DOI: 10.1021/Ja5080739  0.652
2014 Piou T, Rovis T. Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes. Journal of the American Chemical Society. 136: 11292-5. PMID 25093811 DOI: 10.1021/Ja506579T  0.457
2014 Hsieh SY, Wanner B, Wheeler P, Beauchemin AM, Rovis T, Bode JW. Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7228-31. PMID 24839065 DOI: 10.1002/Chem.201402818  0.761
2014 Neely JM, Rovis T. Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activators. Journal of the American Chemical Society. 136: 2735-8. PMID 24512241 DOI: 10.1021/Ja412444D  0.768
2014 Gaunt M, Rovis T, Chow HF. Catalysis using sustainable metals - Part i Synlett. 25: 2715-2716. DOI: 10.1055/S-0034-1379611  0.365
2014 Kohn BL, Rovis T. Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: A direct fluoroacylation of 1,3-dienes Chemical Science. 5: 2889-2892. DOI: 10.1039/C4Sc00743C  0.507
2014 Neely JM, Rovis T. Pyridine synthesis by [4 + 2] cycloadditions of 1-azadienes: Hetero-Diels Alder and transition metal-catalysed approaches Organic Chemistry Frontiers. 1: 1010-1015. DOI: 10.1039/C4Qo00187G  0.767
2014 White NA, Ozboya KE, Flanigan DM, Rovis T. ChemInform Abstract: Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via an N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Cheminform. 45: no-no. DOI: 10.1002/chin.201445160  0.612
2013 Perreault S, Rovis T. Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition. Synthesis. 45: 719-728. PMID 25506094 DOI: 10.1055/S-0032-1316786  0.517
2013 Wheeler P, Vora HU, Rovis T. Asymmetric NHC-catalyzed synthesis of α-fluoroamides from readily accessible α-fluoroenals. Chemical Science (Royal Society of Chemistry : 2010). 4: 1674-1679. PMID 25346841 DOI: 10.1039/C3Sc00089C  0.735
2013 Hyster TK, Rovis T. Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24: 1842-1844. PMID 25346576 DOI: 10.1055/S-0033-1339510  0.731
2013 Zhao X, Glover GS, Oberg KM, Dalton DM, Rovis T. SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24. PMID 24379522 DOI: 10.1055/S-0033-1338842  0.837
2013 Lathrop SP, Rovis T. A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. Chemical Science (Royal Society of Chemistry : 2010). 4. PMID 24224080 DOI: 10.1039/C3Sc22292F  0.743
2013 Davis TA, Hyster TK, Rovis T. Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. Angewandte Chemie (International Ed. in English). 52: 14181-5. PMID 24214733 DOI: 10.1002/Anie.201307631  0.819
2013 White NA, DiRocco DA, Rovis T. Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. Journal of the American Chemical Society. 135: 8504-7. PMID 23713683 DOI: 10.1021/Ja403847E  0.849
2013 Dalton DM, Rappé AK, Rovis T. Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction. Chemical Science (Royal Society of Chemistry : 2010). 4: 2062-2070. PMID 23671790 DOI: 10.1039/C3Sc50271F  0.725
2013 Dalton DM, Rovis T. Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core. Organic Letters. 15: 2346-9. PMID 23631448 DOI: 10.1021/Ol400529K  0.799
2013 Martin TJ, Rovis T. A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether. Angewandte Chemie (International Ed. in English). 52: 5368-71. PMID 23606664 DOI: 10.1002/Anie.201301741  0.607
2013 Hyster TK, Ruhl KE, Rovis T. A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation. Journal of the American Chemical Society. 135: 5364-7. PMID 23548055 DOI: 10.1021/Ja402274G  0.801
2013 Neely JM, Rovis T. Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters. Journal of the American Chemical Society. 135: 66-9. PMID 23244023 DOI: 10.1021/Ja3104389  0.78
2013 Ferreira EM, Rovis T. 17th IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 17), Fort Collins, CO, USA, July 28–August 1, 2013 Green Processing and Synthesis. 2. DOI: 10.1515/gps-2013-0014  0.536
2013 Rovis T, Dalton D. Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition Synfacts. 9: 1030-1030. DOI: 10.1055/s-0033-1339688  0.797
2013 Rovis T, Nolan SP. Stable carbenes: From 'laboratory curiosities' to catalysis mainstays Synlett. 24: 1188-1189. DOI: 10.1055/S-0033-1339192  0.305
2013 DiRocco DA, Rovis T. ChemInform Abstract: Carbene-Catalyzed Stetter Reactions Cheminform. 44: no-no. DOI: 10.1002/chin.201307233  0.408
2013 Oberg KM, Rovis T. Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions Asymmetric Synthesis Ii: More Methods and Applications. 303-308. DOI: 10.1002/9783527652235.ch38  0.828
2012 Vora HU, Wheeler P, Rovis T. Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. Advanced Synthesis & Catalysis. 354: 1617-1639. PMID 23538785 DOI: 10.1002/Adsc.201200031  0.8
2012 Zhao X, Ruhl KE, Rovis T. N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. Angewandte Chemie (International Ed. in English). 51: 12330-3. PMID 23124903 DOI: 10.1002/Anie.201206490  0.851
2012 Hyster TK, Knörr L, Ward TR, Rovis T. Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation. Science (New York, N.Y.). 338: 500-3. PMID 23112327 DOI: 10.1126/Science.1226132  0.702
2012 Rubush DM, Morges MA, Rose BJ, Thamm DH, Rovis T. An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade. Journal of the American Chemical Society. 134: 13554-7. PMID 22871165 DOI: 10.1021/Ja3052427  0.839
2012 DiRocco DA, Rovis T. Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines. Angewandte Chemie (International Ed. in English). 51: 5904-6. PMID 22566184 DOI: 10.1002/Anie.201202442  0.824
2012 DiRocco DA, Rovis T. Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. Journal of the American Chemical Society. 134: 8094-7. PMID 22548244 DOI: 10.1021/Ja3030164  0.765
2012 DiRocco DA, Oberg KM, Rovis T. Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes. Journal of the American Chemical Society. 134: 6143-5. PMID 22455368 DOI: 10.1021/Ja302031V  0.813
2012 DiRocco DA, Noey EL, Houk KN, Rovis T. Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angewandte Chemie (International Ed. in English). 51: 2391-4. PMID 22282312 DOI: 10.1002/Anie.201107597  0.797
2012 Rovis T, Filloux C. 6.12 Benzoin and Stetter Reactions Comprehensive Chirality. 6: 318-344. DOI: 10.1016/B978-0-08-095167-6.00612-1  0.318
2012 Vora HU, Wheeler P, Rovis T. ChemInform Abstract: Exploiting Acyl and Enol Azolium Intermediates via N-Heterocyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes. Cheminform. 43: no-no. DOI: 10.1002/chin.201239239  0.658
2011 Hyster TK, Rovis T. An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis. Chemical Science (Royal Society of Chemistry : 2010). 2: 1606-1610. PMID 25580208 DOI: 10.1039/C1Sc00235J  0.747
2011 Vora HU, Rovis T. Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity. Aldrichimica Acta. 44: 3-11. PMID 25346540  0.618
2011 Du Y, Hyster TK, Rovis T. Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. Chemical Communications (Cambridge, England). 47: 12074-6. PMID 22006288 DOI: 10.1039/C1Cc15843K  0.722
2011 Hyster TK, Rovis T. Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 47: 11846-8. PMID 21986995 DOI: 10.1039/C1Cc15248C  0.733
2011 Ozboya KE, Rovis T. Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones. Chemical Science (Royal Society of Chemistry : 2010). 2: 1835-1838. PMID 21927711 DOI: 10.1039/C1Sc00175B  0.513
2011 Zhao X, DiRocco DA, Rovis T. N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. Journal of the American Chemical Society. 133: 12466-9. PMID 21780842 DOI: 10.1021/Ja205714G  0.81
2011 DiRocco DA, Rovis T. Organocatalytic hydroacylation of unactivated alkenes. Angewandte Chemie (International Ed. in English). 50: 7982-3. PMID 21721090 DOI: 10.1002/Anie.201102920  0.771
2011 DiRocco DA, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives. Journal of the American Chemical Society. 133: 10402-5. PMID 21678918 DOI: 10.1021/Ja203810B  0.805
2011 Um JM, DiRocco DA, Noey EL, Rovis T, Houk KN. Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. Journal of the American Chemical Society. 133: 11249-54. PMID 21675770 DOI: 10.1021/Ja202444G  0.764
2011 Oberg KM, Rovis T. Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates. Journal of the American Chemical Society. 133: 4785-7. PMID 21401131 DOI: 10.1021/Ja200766K  0.821
2011 Moore JL, Silvestri AP, de Alaniz JR, DiRocco DA, Rovis T. Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. Organic Letters. 13: 1742-5. PMID 21355598 DOI: 10.1021/Ol200256A  0.772
2011 DiRocco DA, Rovis T. ChemInform Abstract: Asymmetric Benzoin and Stetter Reactions Cheminform. 42: no-no. DOI: 10.1002/chin.201140200  0.378
2011 DiRocco DA, Rovis T. Organokatalytische Hydroacylierung nichtaktivierter Alkene Angewandte Chemie. 123: 8130-8132. DOI: 10.1002/Ange.201102920  0.791
2011 Du Y, Hyster TK, Rovis T. Rhodium-catalyzed oxidative carbonylation of benzamides with CO under mild conditions Acs National Meeting Book of Abstracts 0.649
2011 Vora HU, Rovis T. Asymmetric N-Heterocyclic carbene (NHC) catalyzed acyl anion reactions Aldrichimica Acta. 44: 3-11.  0.661
2010 Moore JL, Rovis T. Carbene catalysts. Topics in Current Chemistry. 291: 77-144. PMID 21494949 DOI: 10.1007/978-3-642-02815-1_18  0.43
2010 Dalton DM, Rovis T. Organometallic chemistry: C-H carboxylation takes gold. Nature Chemistry. 2: 710-1. PMID 20729887 DOI: 10.1038/Nchem.815  0.751
2010 Hyster TK, Rovis T. Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. Journal of the American Chemical Society. 132: 10565-9. PMID 20662529 DOI: 10.1021/Ja103776U  0.751
2010 Filloux CM, Lathrop SP, Rovis T. Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes. Proceedings of the National Academy of Sciences of the United States of America. 107: 20666-71. PMID 20639467 DOI: 10.1073/Pnas.1002830107  0.747
2010 Vora HU, Rovis T. N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. Journal of the American Chemical Society. 132: 2860-1. PMID 20151675 DOI: 10.1021/Ja910281S  0.557
2010 Miyake GM, DiRocco DA, Liu Q, Oberg KM, Bayram E, Finke RG, Rovis T, Chen EYX. Stereospecific polymerization of chiral oxazolidinone-functionalized alkenes Macromolecules. 43: 7504-7514. DOI: 10.1021/Ma101310N  0.795
2010 Vora HU, Rovis T. ChemInform Abstract: N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Protio and α-Deuterio α-Chloro and α-Fluoro Carboxylic Acids. Cheminform. 41: no-no. DOI: 10.1002/chin.201031028  0.559
2010 Evans DA, Sweeney ZK, Rovis T, Tedrow JS. ChemInform Abstract: Highly Enantioselective Syntheses of Homopropargylic Alcohols and Dihydrofurans Catalyzed by a Bis(oxazolinyl)pyridine-Scandium Triflate Complex. Cheminform. 33: no-no. DOI: 10.1002/chin.200218032  0.744
2010 Lautens M, Fagnou K, Taylor M, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles. Cheminform. 32: no-no. DOI: 10.1002/chin.200134120  0.736
2010 Evans DA, Rovis T, Johnson JS. ChemInform Abstract: Chiral Copper(II) Complexes as Lewis Acids for Catalyzed Cycloaddition, Carbonyl Addition, and Conjugate Addition Reactions Cheminform. 31: no-no. DOI: 10.1002/chin.200031287  0.713
2010 Lautens M, Rovis T. ChemInform Abstract: Hydroalumination of Carbon-Carbon Double Bonds Cheminform. 31: no-no. DOI: 10.1002/chin.200018249  0.377
2010 Lautens M, Rovis T. ChemInform Abstract: Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline. Cheminform. 30: no-no. DOI: 10.1002/chin.199946235  0.514
2010 LAUTENS M, ROVIS T. ChemInform Abstract: Scope of the Nickel Catalyzed Asymmetric Reductive Ring Opening Reaction. Synthesis of Enantiomerically Enriched Cyclohexenols. Cheminform. 29: no-no. DOI: 10.1002/chin.199823035  0.64
2010 LAUTENS M, ROVIS T. ChemInform Abstract: A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes. Cheminform. 29: no-no. DOI: 10.1002/chin.199810093  0.533
2010 LAUTENS M, ROVIS T. ChemInform Abstract: General Strategy Toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline. Cheminform. 28: no-no. DOI: 10.1002/chin.199752115  0.496
2010 LAUTENS M, CHIU P, MA S, ROVIS T. ChemInform Abstract: Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity. Cheminform. 26: no-no. DOI: 10.1002/chin.199527076  0.543
2010 Vora HU, Lathrop SP, Reynolds NT, Kerr MS, De Alaniz JR, Rovis T, Chennamadhavuni S, Davies HML. Preparation of chiral and achiral triazolium salts: Carbene precursors with demonstrated synthetic utility Organic Syntheses. 87: 350-361. DOI: 10.1002/0471264229.Os087.37  0.809
2009 Oberg KM, Lee EE, Rovis T. Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones. Tetrahedron. 65: 5056-5061. PMID 21927511 DOI: 10.1016/J.Tet.2009.02.021  0.844
2009 Friedman RK, Oberg KM, Dalton DM, Rovis T. Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates and Alkynes. Pure and Applied Chemistry. Chimie Pure Et Appliquee. 82: 1353-1364. PMID 20622923 DOI: 10.1351/Pac-Con-09-12-09  0.844
2009 de Alaniz JR, Rovis T. The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 8: 1189-1207. PMID 20585467 DOI: 10.1055/S-0029-1216654  0.502
2009 Perreault S, Rovis T. Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets. Chemical Society Reviews. 38: 3149-59. PMID 19847348 DOI: 10.1039/B816702H  0.512
2009 Dalton DM, Oberg KM, Yu RT, Lee EE, Perreault S, Oinen ME, Pease ML, Malik G, Rovis T. Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. Journal of the American Chemical Society. 131: 15717-28. PMID 19817441 DOI: 10.1021/Ja905065J  0.828
2009 Oinen ME, Yu RT, Rovis T. Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Organic Letters. 11: 4934-7. PMID 19803471 DOI: 10.1021/Ol9020805  0.717
2009 Lathrop SP, Rovis T. Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. Journal of the American Chemical Society. 131: 13628-30. PMID 19731910 DOI: 10.1021/Ja905342E  0.732
2009 DiRocco DA, Oberg KM, Dalton DM, Rovis T. Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. Journal of the American Chemical Society. 131: 10872-4. PMID 19722669 DOI: 10.1021/Ja904375Q  0.843
2009 Yu RT, Friedman RK, Rovis T. Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. Journal of the American Chemical Society. 131: 13250-1. PMID 19711950 DOI: 10.1021/Ja906641D  0.738
2009 Friedman RK, Rovis T. Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates. Journal of the American Chemical Society. 131: 10775-82. PMID 19569692 DOI: 10.1021/Ja903899C  0.528
2009 Liu Q, Rovis T. Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Organic Letters. 11: 2856-9. PMID 19507841 DOI: 10.1021/Ol901081A  0.551
2009 Galan BR, Rovis T. Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes. Angewandte Chemie (International Ed. in English). 48: 2830-4. PMID 19229917 DOI: 10.1002/Anie.200804651  0.41
2009 Yu RT, Lee EE, Malik G, Rovis T. Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. Angewandte Chemie (International Ed. in English). 48: 2379-82. PMID 19229912 DOI: 10.1002/Anie.200805455  0.701
2009 Rovis T, Yu R, Friedman R. Synthesis of Bicyclic Azocine Rings via Rh-Catalyzed [4+2+2] Cycloaddition Synfacts. 2009: 1355-1355. DOI: 10.1055/s-0029-1218313  0.667
2009 Cook MJ, Rovis T. Enantioselective rhodium-catalyzed alkylative desymmetrization of 3,5-dimethylglutaric anhydride Synthesis. 335-338. DOI: 10.1055/S-0028-1083275  0.758
2009 Johnson JB, Cook MJ, Rovis T. Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides Tetrahedron. 65: 3202-3210. DOI: 10.1016/J.Tet.2008.10.075  0.726
2008 Vora HU, Moncecchi JR, Epstein O, Rovis T. Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. The Journal of Organic Chemistry. 73: 9727-31. PMID 18989930 DOI: 10.1021/Jo8020055  0.698
2008 Williams CM, Johnson JB, Rovis T. Nickel-catalyzed reductive carboxylation of styrenes using CO2. Journal of the American Chemical Society. 130: 14936-7. PMID 18928253 DOI: 10.1021/Ja8062925  0.761
2008 Liu Q, Perreault S, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. Journal of the American Chemical Society. 130: 14066-7. PMID 18834123 DOI: 10.1021/Ja805680Z  0.565
2008 Cullen SC, Rovis T. Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Organic Letters. 10: 3141-4. PMID 18549233 DOI: 10.1021/Ol801047K  0.475
2008 Orellana A, Rovis T. Towards the total synthesis of FD-838: modular enantioselective assembly of the core. Chemical Communications (Cambridge, England). 730-2. PMID 18478705 DOI: 10.1039/B716445A  0.738
2008 de Alaniz JR, Kerr MS, Moore JL, Rovis T. Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. The Journal of Organic Chemistry. 73: 2033-40. PMID 18302407 DOI: 10.1021/Jo702313F  0.789
2008 Yu RT, Rovis T. Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides. Journal of the American Chemical Society. 130: 3262-3. PMID 18302377 DOI: 10.1021/Ja710065H  0.744
2008 Lee EE, Rovis T. Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes. Organic Letters. 10: 1231-4. PMID 18284249 DOI: 10.1021/Ol800086S  0.557
2008 Johnson JB, Rovis T. Enantioselective cross-coupling of anhydrides with organozinc reagents: the controlled formation of carbon-carbon bonds through the nucleophilic interception of metalacycles. Accounts of Chemical Research. 41: 327-38. PMID 18232665 DOI: 10.1021/Ar700176T  0.533
2008 Nasveschuk CG, Rovis T. The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis. Organic & Biomolecular Chemistry. 6: 240-54. PMID 18174990 DOI: 10.1039/B714881J  0.732
2008 Nasveschuk CG, Rovis T. A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. The Journal of Organic Chemistry. 73: 612-7. PMID 18088144 DOI: 10.1021/Jo702071V  0.79
2008 Johnson JB, Rovis T. More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. Angewandte Chemie (International Ed. in English). 47: 840-71. PMID 18081111 DOI: 10.1002/Anie.200700278  0.444
2008 Rovis T. Development of chiral bicyclic triazolium salt organic catalysts: The importance of the N-aryl substituent Chemistry Letters. 37: 2-7. DOI: 10.1246/Cl.2008.2  0.439
2008 Nasveschuk CG, Rovis T. A rapid total synthesis of (±)-sylvone Synlett. 0126-0128. DOI: 10.1055/S-2007-990926  0.709
2008 Yu RT, Rovis T. ChemInform Abstract: Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Carbodiimides. Cheminform. 39. DOI: 10.1002/chin.200831169  0.707
2008 Nasveschuk CG, Rovis T. ChemInform Abstract: A Rapid Total Synthesis of (.+-.)-Sylvone. Cheminform. 39. DOI: 10.1002/chin.200822206  0.731
2007 Liu Q, Rovis T. Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Organic Process Research & Development. 11: 598-604. PMID 19603085 DOI: 10.1021/op600278f  0.458
2007 Rogers RL, Moore JL, Rovis T. Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents. Angewandte Chemie (International Ed. in English). 46: 9301-4. PMID 17985335 DOI: 10.1002/Anie.200703124  0.423
2007 Nasveschuk CG, Frein JD, Jui NT, Rovis T. A diastereoselective intermolecular heck reaction of 1,3-dioxepins. Organic Letters. 9: 5099-102. PMID 17958436 DOI: 10.1021/Ol702294U  0.829
2007 Vora HU, Rovis T. Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. Journal of the American Chemical Society. 129: 13796-7. PMID 17929821 DOI: 10.1021/Ja0764052  0.684
2007 Cook MJ, Rovis T. Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. Journal of the American Chemical Society. 129: 9302-3. PMID 17622150 DOI: 10.1021/Ja073269S  0.72
2007 Johnson JB, Bercot EA, Williams CM, Rovis T. A concise synthesis of eupomatilones 4, 6, and 7 by rhodium-catalyzed enantioselective desymmetrization of cyclic meso anhydrides with organozinc reagents generated in situ. Angewandte Chemie (International Ed. in English). 46: 4514-8. PMID 17492814 DOI: 10.1002/Anie.200700816  0.855
2007 Johnson JB, Bercot EA, Rowley JM, Coates GW, Rovis T. Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. Journal of the American Chemical Society. 129: 2718-25. PMID 17295486 DOI: 10.1021/Ja067845G  0.827
2006 Frein JD, Rovis T. Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring. Tetrahedron. 62: 4573-4583. PMID 17710219 DOI: 10.1016/J.Tet.2006.02.042  0.797
2006 Epstein OL, Rovis T. A Sakurai-Prins-Ritter sequence for the three-component diastereoselective synthesis of 4-amino tetrahydropyrans. Journal of the American Chemical Society. 128: 16480-1. PMID 17177379 DOI: 10.1021/Ja066794K  0.42
2006 Yu RT, Rovis T. Enantioselective rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes: application to the total synthesis of (+)-lasubine II. Journal of the American Chemical Society. 128: 12370-1. PMID 16984159 DOI: 10.1021/Ja064868M  0.707
2006 Johnson JB, Yu RT, Fink P, Bercot EA, Rovis T. Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation. Organic Letters. 8: 4307-10. PMID 16956213 DOI: 10.1021/Ol0616337  0.805
2006 Nasveschuk CG, Jui NT, Rovis T. A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans. Chemical Communications (Cambridge, England). 3119-21. PMID 16855705 DOI: 10.1039/B605438B  0.827
2006 Yu RT, Rovis T. Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. Journal of the American Chemical Society. 128: 2782-3. PMID 16506740 DOI: 10.1021/Ja057803C  0.68
2006 Liu Q, Rovis T. Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. Journal of the American Chemical Society. 128: 2552-3. PMID 16492036 DOI: 10.1021/Ja058337U  0.565
2006 Rovis T, Yu R. Indolizinone and Quinolizinone via Asymmetric [2+2+2] Cycloaddition Synfacts. 2006: 1209-1209. DOI: 10.1055/s-2006-955576  0.683
2006 Rovis T, Liu Q. Asymmetric Synthesis of Hydrobenzofuranones via Enantioselective Stetter Reaction Synfacts. 2006: 0508-0508. DOI: 10.1055/s-2006-934454  0.476
2006 Rovis T. Quaternary Stereocenters:  Challenges and Solutions for Organic Synthesis Edited by Jens Christoffers and Angelika Baro (Universität Stuttgart). Wiley-VCH Verlag GmbH & Co. KGA:  Weinheim. 2005. xxiv + 336 pp. $170. ISBN 3-527-31107-6. Journal of the American Chemical Society. 128: 8095-8095. DOI: 10.1021/Ja0598917  0.327
2006 Moore JL, Kerr MS, Rovis T. Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction Tetrahedron. 62: 11477-11482. DOI: 10.1016/J.Tet.2006.06.042  0.786
2006 Rovis T. Recent Advances in Catalytic Asymmetric Desymmetrization Reactions New Frontiers in Asymmetric Catalysis. 275-311. DOI: 10.1002/0470098007.ch10  0.379
2005 Reynolds NT, Rovis T. Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. Journal of the American Chemical Society. 127: 16406-7. PMID 16305222 DOI: 10.1021/Ja055918A  0.812
2005 Kerr MS, Read de Alaniz J, Rovis T. An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. The Journal of Organic Chemistry. 70: 5725-8. PMID 15989360 DOI: 10.1021/Jo050645N  0.834
2005 Nasveschuk CG, Rovis T. Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers. Organic Letters. 7: 2173-6. PMID 15901162 DOI: 10.1021/Ol0505151  0.765
2005 Read de Alaniz J, Rovis T. A highly enantio- and diastereoselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 127: 6284-9. PMID 15853335 DOI: 10.1021/Ja0425132  0.728
2005 Nasveschuk CG, Rovis T. Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes. Angewandte Chemie (International Ed. in English). 44: 3264-7. PMID 15844118 DOI: 10.1002/Anie.200500088  0.733
2005 Bercot EA, Rovis T. Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents. Journal of the American Chemical Society. 127: 247-54. PMID 15631474 DOI: 10.1021/Ja044588B  0.83
2005 Bercot EA, Kindrachuk DE, Rovis T. Complementary diastereoselective reduction of cyclic gamma-keto acids: efficient access to trisubsituted gamma-lactones. Organic Letters. 7: 107-10. PMID 15624989 DOI: 10.1021/Ol047821J  0.786
2005 Rovis T, Reynolds N. Organocatalytic Asymmetric Synthesis of α-Chloroesters Synfacts. 2006: 0078-0078. DOI: 10.1055/s-2005-921718  0.779
2005 Reynolds NT, Rovis T. The effect of pre-existing stereocenters in the intramolecular asymmetric Stetter reaction Tetrahedron. 61: 6368-6378. DOI: 10.1016/J.Tet.2005.03.121  0.843
2005 Bercot EA, Kindrachuk DE, Rovis T. Complementary Diastereoselective Reduction of Cyclic ?-Keto Acids: Efficient Access to Trisubstituted ?-Lactones. Cheminform. 36. DOI: 10.1002/chin.200517114  0.782
2004 Zhang Y, Rovis T. A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters. Journal of the American Chemical Society. 126: 15964-5. PMID 15584721 DOI: 10.1021/Ja044113K  0.458
2004 Bercot EA, Rovis T. A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. Journal of the American Chemical Society. 126: 10248-9. PMID 15315429 DOI: 10.1021/Ja046528B  0.824
2004 Reynolds NT, Read de Alaniz J, Rovis T. Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. Journal of the American Chemical Society. 126: 9518-9. PMID 15291537 DOI: 10.1021/Ja046991O  0.834
2004 Kerr MS, Rovis T. Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. Journal of the American Chemical Society. 126: 8876-7. PMID 15264801 DOI: 10.1021/Ja047644H  0.789
2004 Zhang Y, Rovis T. Use of acid fluorides increases the scope of the reductive acylation of esters. Organic Letters. 6: 1877-9. PMID 15151437 DOI: 10.1021/Ol049333H  0.421
2003 O'Brien EM, Bercot EA, Rovis T. Decarbonylative cross-coupling of cyclic anhydrides: introducing stereochemistry at an sp3 carbon in the cross-coupling event. Journal of the American Chemical Society. 125: 10498-9. PMID 12940714 DOI: 10.1021/Ja036290B  0.766
2003 Kerr MS, Rovis T. Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction Synlett. 1934-1936. DOI: 10.1055/S-2003-41458  0.761
2003 Zhang Y, Rovis T. 1,3-Polyol arrays via the stereoselective rearrangement of vinyl acetals Tetrahedron. 59: 8979-8987. DOI: 10.1016/J.Tet.2003.03.004  0.433
2002 Kerr MS, Read de Alaniz J, Rovis T. A highly enantioselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 124: 10298-9. PMID 12197730 DOI: 10.1021/Ja027411V  0.841
2002 Zhang Y, Reynolds NT, Manju K, Rovis T. Stereoretentive O-to-C rearrangement of vinyl acetals: solvent cage effects as a stereocontrol element. Journal of the American Chemical Society. 124: 9720-1. PMID 12175226 DOI: 10.1021/Ja026972J  0.806
2002 Bercot EA, Rovis T. A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides. Journal of the American Chemical Society. 124: 174-5. PMID 11782160 DOI: 10.1021/Ja017086W  0.849
2001 Evans DA, Sweeney ZK, Rovis T, Tedrow JS. Highly enantioselective syntheses of homopropargylic alcohols and dihydrofurans catalyzed by a bis(oxazolinyl)pyridine-scandium triflate complex. Journal of the American Chemical Society. 123: 12095-6. PMID 11724622 DOI: 10.1021/Ja011983I  0.756
2001 Lautens M, Fagnou K, Taylor M, Rovis T. Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles Journal of Organometallic Chemistry. 624: 259-270. DOI: 10.1016/S0022-328X(00)00904-9  0.766
2001 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. ChemInform Abstract: Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters. Cheminform. 32: no-no. DOI: 10.1002/chin.200103030  0.85
2001 Rovis T, Evans DA. Structural and mechanistic investigations in asymmetric copper(I) and copper(II) catalyzed reactions Progress in Inorganic Chemistry. 50: 1-150.  0.547
2000 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. Enantioselective Lewis acid catalyzed Michael reactions of alkylidene malonates. Catalysis by C2-symmetric bis(oxazoline) copper(II) complexes in the synthesis of chiral, differentiated glutarate esters Journal of the American Chemical Society. 122: 9134-9142. DOI: 10.1021/Ja002246+  0.852
2000 Lautens M, Fagnou K, Rovis T. Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process [8] Journal of the American Chemical Society. 122: 5650-5651. DOI: 10.1021/Ja000134C  0.714
2000 Lautens M, Fagnou K, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon-Heteroatom Bond Forming Process. Cheminform. 31: no-no. DOI: 10.1002/chin.200040088  0.695
1999 Evans DA, Rovis T, Johnson JS. Chiral copper(∥) complexes as Lewis acids for catalyzed cycloaddition, carbonyl addition, and conjugate addition reactions Pure and Applied Chemistry. 71: 1407-1415. DOI: 10.1351/Pac199971081407  0.697
1999 Evans DA, Rovis T, Kozlowski MC, Tedrow JS. C2-symmetric Cu(II) complexes as chiral Lewis acids. Catalytic enantioselective Michael addition of silylketene acetals to alkylidene malonates [21] Journal of the American Chemical Society. 121: 1994-1995. DOI: 10.1021/Ja983864H  0.806
1999 Lautens M, Rovis T. Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline Tetrahedron. 55: 8967-8976. DOI: 10.1016/S0040-4020(99)00456-1  0.561
1998 Lautens M, Rovis T, Smith ND, Ostrovsky D. Metal catalyzed hydrometalations and their applications in synthesis Pure and Applied Chemistry. 70: 1059-1064. DOI: 10.1351/Pac199870051059  0.627
1998 Lautens M, Rovis T. Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols Tetrahedron. 54: 1107-1116. DOI: 10.1016/S0040-4020(97)10211-3  0.61
1997 Lautens M, Rovis T. General strategy toward the tetrahydronaphthalene skeleton. An expedient total synthesis of sertraline Journal of Organic Chemistry. 62: 5246-5247. DOI: 10.1021/Jo971115X  0.547
1997 Lautens M, Rovis T. A new route to the enantioselective synthesis of cycloheptenols. Temperature effects in the asymmetric reductive ring opening [3.2.1] oxabicycloalkenes Journal of the American Chemical Society. 119: 11090-11091. DOI: 10.1021/Ja971770M  0.584
1995 Lautens M, Chiu P, Ma S, Rovis T. Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity Journal of the American Chemical Society. 117: 532-533. DOI: 10.1021/Ja00106A062  0.686
1995 Lautens M, Chiu P, Ma S, Rovis T. Nickel-catalyzed hydroalumination of oxabicyclic alkenes. Ligand effects on the regio- and enantioselectivity Journal of the American Chemical Society. 117: 532-533.  0.325
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