Tomislav Rovis, Ph.D. - Publications

Affiliations: 
2000-2016 Chemistry Colorado State University, Fort Collins, CO 
 2016- Chemistry Columbia University, New York, NY 
Area:
Organic Chemistry, Catalysis
Website:
https://chem.columbia.edu/people/faculty/tomislav-rovis/

246 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Dorsheimer JR, Ashley MA, Rovis T. Dual Nickel/Photoredox-Catalyzed Deaminative Cross-Coupling of Sterically Hindered Primary Amines. Journal of the American Chemical Society. 143: 19294-19299. PMID 34767360 DOI: 10.1021/jacs.1c10150  1
2021 Tay NES, Lehnherr D, Rovis T. Photons or Electrons? A Critical Comparison of Electrochemistry and Photoredox Catalysis for Organic Synthesis. Chemical Reviews. PMID 34751568 DOI: 10.1021/acs.chemrev.1c00384  1
2021 Lee S, Rovis T. Rh(III)-Catalyzed Three-Component -Carboamination of Alkenes Using Arylboronic Acids and Dioxazolones. Acs Catalysis. 11: 8585-8590. PMID 34745710 DOI: 10.1021/acscatal.1c02406  1
2021 Burg F, Rovis T. Diastereoselective Three-Component 3,4-Amino Oxygenation of 1,3-Dienes Catalyzed by a Cationic Heptamethylindenyl Rhodium(III) Complex. Journal of the American Chemical Society. PMID 34668705 DOI: 10.1021/jacs.1c09276  0.2
2021 Shen Y, Rovis T. Late-Stage -Me Selective Arylation of Trialkylamines Enabled by Ni/Photoredox Dual Catalysis. Journal of the American Chemical Society. PMID 34590864 DOI: 10.1021/jacs.1c08157  0.12
2021 Resnick SJ, Iketani S, Hong SJ, Zask A, Liu H, Kim S, Melore S, Lin FY, Nair MS, Huang Y, Lee S, Tay NES, Rovis T, Yang HW, Xing L, et al. Inhibitors of coronavirus 3CL proteases protect cells from protease-mediated cytotoxicity. Journal of Virology. PMID 33910954 DOI: 10.1128/JVI.02374-20  1
2021 Treacy SM, Rovis T. Copper Catalyzed C(sp)-H Bond Alkylation via Photoinduced Ligand-to-Metal Charge Transfer. Journal of the American Chemical Society. PMID 33576606 DOI: 10.1021/jacs.1c00687  1
2020 Ravetz BD, Tay NES, Joe CL, Sezen-Edmonds M, Schmidt MA, Tan Y, Janey JM, Eastgate MD, Rovis T. Development of a Platform for Near-Infrared Photoredox Catalysis. Acs Central Science. 6: 2053-2059. PMID 33274281 DOI: 10.1021/acscentsci.0c00948  1
2020 Ashley MA, Rovis T. Photoredox-Catalyzed Deaminative Alkylation via C-N Bond Activation of Primary Amines. Journal of the American Chemical Society. PMID 33058665 DOI: 10.1021/jacs.0c08595  1
2020 Resnick SJ, Iketani S, Hong SJ, Zask A, Liu H, Kim S, Melore S, Nair MS, Huang Y, Tay NES, Rovis T, Yang HW, Stockwell BR, Ho DD, Chavez A. A simplified cell-based assay to identify coronavirus 3CL protease inhibitors. Biorxiv : the Preprint Server For Biology. PMID 32869020 DOI: 10.1101/2020.08.29.272864  1
2020 Lei H, Rovis T. A site-selective amination catalyst discriminates between nearly identical C-H bonds of unsymmetrical disubstituted alkenes. Nature Chemistry. PMID 32541949 DOI: 10.1038/S41557-020-0470-Z  1
2020 Piou T, Romanov-Michailidis F, Romanova-Michaelides M, Jackson KE, Semakul N, Taggart TD, Newell BS, Rithner CD, Paton RS, Rovis T. Correction to "Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study". Journal of the American Chemical Society. PMID 32271011 DOI: 10.1021/jacs.0c00951  1
2020 Lee S, Semakul N, Rovis T. Direct Regio- and Diastereoselective Synthesis of δ-Lactams from Acrylamides and Unactivated Alkenes Initiated by Rh -Catalyzed C-H Activation. Angewandte Chemie (International Ed. in English). PMID 32045098 DOI: 10.1002/Anie.201916332  1
2020 Nicastri MC, Lehnherr D, Lam YH, DiRocco DA, Rovis T. Synthesis of Sterically Hindered Primary Amines by Concurrent Tandem Photoredox Catalysis. Journal of the American Chemical Society. PMID 31904228 DOI: 10.1021/Jacs.9B10871  1
2019 Phipps EJT, Piou T, Rovis T. Rh(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C-H Activation. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 30: 1787-1790. PMID 32801480 DOI: 10.1055/S-0039-1690130  1
2019 Lehnherr D, Lam YH, Nicastri MC, Liu J, Newman JA, Regalado EL, DiRocco DA, Rovis T. Electrochemical Synthesis of Hindered Primary and Secondary Amines via Proton-Coupled Electron Transfer. Journal of the American Chemical Society. PMID 31849221 DOI: 10.1021/Jacs.9B10870  1
2019 Thullen SM, Treacy SM, Rovis T. Regioselective Alkylative Cross-Coupling of Remote Unactivated C()-H Bonds. Journal of the American Chemical Society. 141: 14062-14067. PMID 31478370 DOI: 10.1021/Jacs.9B07014  1
2019 Lee S, Lei H, Rovis T. A Rh(III)-Catalyzed Formal [4+1] Approach to Pyrrolidines from Unactivated Terminal Alkenes and Nitrene Sources. Journal of the American Chemical Society. PMID 31381308 DOI: 10.1021/Jacs.9B07012  1
2019 Lei H, Conway JH, Cook CC, Rovis T. Ligand Controlled Ir-Catalyzed Regiodivergent Oxyamination of Unactivated Alkenes. Journal of the American Chemical Society. PMID 31310537 DOI: 10.1021/Jacs.9B06366  1
2019 Ravetz BD, Pun AB, Churchill EM, Congreve DN, Rovis T, Campos LM. Author Correction: Photoredox catalysis using infrared light via triplet fusion upconversion. Nature. PMID 31089213 DOI: 10.1038/S41586-019-1122-6  1
2019 Theunissen C, Ashley MA, Rovis T. Visible-Light-Controlled Ruthenium-Catalyzed Olefin Metathesis. Journal of the American Chemical Society. PMID 31010292 DOI: 10.1021/Jacs.8B13663  1
2019 Phipps EJT, Rovis T. Rh(III)-Catalyzed C-H Activation-Initiated Directed Cyclopropanation of Allylic Alcohols. Journal of the American Chemical Society. PMID 30998324 DOI: 10.1021/Jacs.9B02156  1
2019 Hassan IS, Ta AN, Danneman MW, Semakul N, Burns M, Basch CH, Dippon VN, McNaughton BR, Rovis T. Asymmetric δ-Lactam Synthesis with a Monomeric Streptavidin Artificial Metalloenzyme. Journal of the American Chemical Society. PMID 30865436 DOI: 10.1021/Jacs.9B01596  1
2019 Ashley MA, Yamauchi C, Chu JCK, Otsuka S, Yorimitsu H, Rovis T. Photoredox-Catalyzed Site-Selective α-C(sp )-H Alkylation of Primary Amine Derivatives. Angewandte Chemie (International Ed. in English). PMID 30768740 DOI: 10.1002/Anie.201812227  1
2019 Lei H, Rovis T. Ir-Catalyzed Intermolecular Branch-Selective Allylic C-H Amidation of Unactivated Terminal Olefins. Journal of the American Chemical Society. PMID 30715868 DOI: 10.1021/Jacs.9B00237  1
2019 Ravetz BD, Pun AB, Churchill EM, Congreve DN, Rovis T, Campos LM. Photoredox catalysis using infrared light via triplet fusion upconversion. Nature. 565: 343-346. PMID 30651612 DOI: 10.1038/S41586-018-0835-2  1
2019 Otsuka S, Nogi K, Rovis T, Yorimitsu H. Photoredox-Catalyzed Alkenylation of Benzylsulfoniums. Chemistry, An Asian Journal. PMID 30644178 DOI: 10.1002/Asia.201801732  1
2019 Lee S, Jang YJ, Phipps EJT, Lei H, Rovis T. Rhodium(III)-Catalyzed Three-Component 1,2-Diamination of Unactivated Terminal Alkenes Synthesis. 52: 1247-1252. DOI: 10.1055/S-0039-1690756  0.01
2019 Phipps EJT, Piou T, Rovis T. Rhodium(III)-Catalyzed Cyclopropanation of Unactivated Olefins Initiated by C–H Activation Synlett. 30: 1787-1790. DOI: 10.1055/s-0039-1690130  0.01
2018 Stache EE, Ertel AB, Tomislav R, Doyle AG. Generation of Phosphoranyl Radicals via Photoredox Catalysis Enables Voltage-Independent Activation of Strong C-O Bonds. Acs Catalysis. 8: 11134-11139. PMID 31367474 DOI: 10.1021/Acscatal.8B03592  0.01
2018 Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 9: 8024. PMID 30542552 DOI: 10.1039/C8Sc90195C  1
2018 Ye J, Kalvet I, Schoenebeck F, Rovis T. Direct α-alkylation of primary aliphatic amines enabled by CO and electrostatics. Nature Chemistry. PMID 30061617 DOI: 10.1038/S41557-018-0085-9  0.2
2018 Piou T, Romanov-Michailidis F, Ashley MA, Romanova-Michaelides M, Rovis T. Stereodivergent Rhodium(III)-Catalyzed cis-Cyclopropanation Enabled by Multivariate Optimization. Journal of the American Chemical Society. PMID 30033723 DOI: 10.1021/Jacs.8B04243  1
2018 Romanov-Michailidis F, Ravetz BD, Paley DW, Rovis T. Ir(III)-Catalyzed Carbocarbation of Alkynes through Undirected Double C-H Bond Activation of Anisoles. Journal of the American Chemical Society. PMID 29641190 DOI: 10.1021/Jacs.8B02716  1
2018 Rovis T, Oberg K, Cochran B, Cook M. The Catalytic Alkylative Desymmetrization of Anhydrides in a Formal Synthesis of Ionomycin Synthesis. 50: 4343-4350. DOI: 10.1055/S-0037-1610108  0.01
2018 Johnston J, Rovis T. Cluster Preface: Alkene Halofunctionalization Synlett. 29: 399-400. DOI: 10.1055/S-0037-1609319  0.01
2018 Ravetz BD, Wang JY, Ruhl KE, Rovis T. Photoinduced Ligand-to-Metal Charge Transfer Enables Photocatalyst-Independent Light-Gated Activation of Co(II) Acs Catalysis. 9: 200-204. DOI: 10.1021/Acscatal.8B04326  0.01
2018 Ravetz BD, Ruhl KE, Rovis T. External Regulation of Cobalt-Catalyzed Cycloaddition Polymerization with Visible Light Acs Catalysis. 8: 5323-5327. DOI: 10.1021/Acscatal.8B01431  0.01
2017 Hyster TK, Dalton DM, Rovis T. Correction: Ligand design for Rh(iii)-catalyzed C-H activation: an unsymmetrical cyclopentadienyl group enables a regioselective synthesis of dihydroisoquinolones. Chemical Science. 8: 1666. PMID 30123475 DOI: 10.1039/c6sc90080a  1
2017 Thullen SM, Rubush DM, Rovis T. A Photochemical Two-Step Formal [5+2] Cycloaddition: A Condensation/Ring-Expansion Approach to Substituted Azepanes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 28: 2755-2758. PMID 29861552 DOI: 10.1055/S-0036-1589049  1
2017 Conway JH, Rovis T. Regiodivergent Iridium(III)-Catalyzed Diamination of Alkenyl Amides with Secondary Amines: Complementary Access to γ- or δ-Lactams. Journal of the American Chemical Society. PMID 29278330 DOI: 10.1021/Jacs.7B11455  1
2017 Piou T, Rovis T. Electronic and Steric Tuning of a Prototypical Piano Stool Complex: Rh(III) Catalysis for C-H Functionalization. Accounts of Chemical Research. PMID 29272106 DOI: 10.1021/Acs.Accounts.7B00444  1
2017 Chu JCK, Rovis T. Complementary Strategies for Directed C(sp3 )-H Functionalization: A Comparison of Transition-Metal-Catalyzed Activation, Hydrogen Atom Transfer, and Carbene/Nitrene Transfer. Angewandte Chemie (International Ed. in English). PMID 29206316 DOI: 10.1002/Anie.201703743  1
2017 Thullen SM, Rovis T. A Mild Hydroaminoalkylation of Conjugated Dienes Using a Unified Cobalt and Photoredox Catalytic System. Journal of the American Chemical Society. PMID 29048886 DOI: 10.1021/Jacs.7B09252  1
2017 Niu Y, Wang N, Muñoz A, Xu J, Zeng H, Rovis T, Lee JK. Experimental and Computational Gas Phase Acidities of Conjugate Acids of Triazolylidene Carbenes: Rationalizing Subtle Electronic Effects. Journal of the American Chemical Society. PMID 29039669 DOI: 10.1021/Jacs.7B05229  1
2017 Chen DF, Chu JCK, Rovis T. Directed γ-C(sp(3))-H Alkylation of Carboxylic Acid Derivatives through Visible Light Photoredox Catalysis. Journal of the American Chemical Society. PMID 29022709 DOI: 10.1021/Jacs.7B09306  1
2017 Flanigan DM, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed nucleophilic dearomatization of alkyl pyridiniums. Chemical Science. 8: 6566-6569. PMID 28989683 DOI: 10.1039/C7Sc02648J  1
2017 Chen DF, Rovis T. N-Heterocyclic Carbene and Chiral Brønsted Acid Cooperative Catalysis for a Highly Enantioselective [4+2] Annulation. Synthesis. 49: 293-298. PMID 28690345 DOI: 10.1055/S-0036-1588349  1
2017 Semakul N, Jackson KE, Paton RS, Rovis T. Heptamethylindenyl (Ind*) enables diastereoselective benzamidation of cyclopropenes via Rh(iii)-catalyzed C-H activation. Chemical Science. 8: 1015-1020. PMID 28451239 DOI: 10.1039/C6Sc02587K  1
2017 Stache EE, Rovis T, Doyle AG. Dual Nickel- and Photoredox-Catalyzed Enantioselective Desymmetrization of Cyclic meso-Anhydrides. Angewandte Chemie (International Ed. in English). PMID 28230304 DOI: 10.1002/Anie.201700097  0.04
2017 Piou T, Romanov-Michailidis F, Romanova-Michaelides M, Jackson KE, Semakul N, Taggart TD, Newell BS, Rithner CD, Paton RS, Rovis T. Correlating Reactivity and Selectivity to Cyclopentadienyl Ligand Properties in Rh(III)-Catalyzed C-H Activation Reactions: An Experimental and Computational Study. Journal of the American Chemical Society. PMID 28060499 DOI: 10.1021/Jacs.6B11670  1
2017 Rovis T, Cochran B, Henderson D, Thullen S. Rhodium-Catalyzed Desymmetrization of meso-Glutaric Anhydrides to Access Enantioenriched anti,anti-Polypropionates Synlett. 29: 306-309. DOI: 10.1055/S-0036-1591488  0.01
2017 Stahl S, Rovis T. Cluster Preface: Catalytic Aerobic Oxidations Synlett. 28: 1546-1547. DOI: 10.1055/S-0036-1590547  0.01
2017 Chu JCK, Rovis T. Komplementäre Strategien für die dirigierte C(sp3)-H-Funktionalisierung: ein Vergleich von übergangsmetallkatalysierter Aktivierung, Wasserstoffatomtransfer und Carben- oder Nitrentransfer Angewandte Chemie. 130: 64-105. DOI: 10.1002/Ange.201703743  0.01
2016 Ruhl KE, Rovis T. Visible Light-Gated Cobalt Catalysis for a Spatially and Temporally Resolved [2+2+2] Cycloaddition. Journal of the American Chemical Society. 138: 15527-15530. PMID 27934027 DOI: 10.1021/Jacs.6B08792  1
2016 Chu JC, Rovis T. Amide-directed photoredox-catalysed C-C bond formation at unactivated sp(3) C-H bonds. Nature. PMID 27732580 DOI: 10.1038/Nature19810  0.01
2015 Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylic Acid. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 26: 1520-1524. PMID 27540274 DOI: 10.1055/S-0034-1381006  1
2015 Piou T, Rovis T. Rhodium-catalysed syn-carboamination of alkenes via a transient directing group. Nature. 527: 86-90. PMID 26503048 DOI: 10.1038/Nature15691  1
2015 White NA, Rovis T. Correction to "Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals". Journal of the American Chemical Society. 137: 13210. PMID 26439476 DOI: 10.1021/Jacs.5B09675  1
2015 Archambeau A, Rovis T. Rhodium(III)-Catalyzed Allylic C(sp(3) )-H Activation of Alkenyl Sulfonamides: Unexpected Formation of Azabicycles. Angewandte Chemie (International Ed. in English). 54: 13337-40. PMID 26358769 DOI: 10.1002/Anie.201504150  1
2015 White NA, Rovis T. Oxidatively Initiated NHC-Catalyzed Enantioselective Synthesis of 3,4-Disubstituted Cyclopentanones from Enals. Journal of the American Chemical Society. 137: 10112-5. PMID 26256839 DOI: 10.1021/Jacs.5B06390  1
2015 Telitel S, Vallet AL, Flanigan DM, Graff B, Morlet-Savary F, Rovis T, Lalevée J, Lacôte E. Influence of Electronic Effects on the Reactivity of Triazolylidene-Boryl Radicals: Consequences for the use of N-Heterocyclic Carbene Boranes in Organic and Polymer Synthesis. Chemistry (Weinheim An Der Bergstrasse, Germany). 21: 13772-7. PMID 26239157 DOI: 10.1002/Chem.201500499  1
2015 Romanov-Michailidis F, Rovis T. Organic chemistry: Natural polarity inverted. Nature. 523: 417-8. PMID 26201594 DOI: 10.1038/523417A  1
2015 Romanov-Michailidis F, Sedillo KF, Neely JM, Rovis T. Expedient Access to 2,3-Dihydropyridines from Unsaturated Oximes by Rh(III)-Catalyzed C-H Activation. Journal of the American Chemical Society. PMID 26154248 DOI: 10.1021/Jacs.5B04946  1
2015 Flanigan DM, Romanov-Michailidis F, White NA, Rovis T. Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes. Chemical Reviews. PMID 25992594 DOI: 10.1021/Acs.Chemrev.5B00060  1
2015 Chu JC, Dalton DM, Rovis T. Zn-catalyzed enantio- and diastereoselective formal [4 + 2] cycloaddition involving two electron-deficient partners: asymmetric synthesis of piperidines from 1-azadienes and nitro-alkenes. Journal of the American Chemical Society. 137: 4445-52. PMID 25821893 DOI: 10.1021/Jacs.5B00033  1
2015 Hyster TK, Rovis T. Correction: Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 51: 5778. PMID 25749239 DOI: 10.1039/c5cc90120k  1
2015 Deng W, Gowen BG, Zhang L, Wang L, Lau S, Iannello A, Xu J, Rovis TL, Xiong N, Raulet DH. Antitumor immunity. A shed NKG2D ligand that promotes natural killer cell activation and tumor rejection. Science (New York, N.Y.). 348: 136-9. PMID 25745066 DOI: 10.1126/Science.1258867  1
2015 Zhang WZ, Chu JC, Oberg KM, Rovis T. Enantioselective rhodium-catalyzed isomerization of 4-iminocrotonates: asymmetric synthesis of a unique chiral synthon. Journal of the American Chemical Society. 137: 553-5. PMID 25580807 DOI: 10.1021/Ja510348P  1
2015 Filloux CM, Rovis T. Rh(I)-bisphosphine-catalyzed asymmetric, intermolecular hydroheteroarylation of α-substituted acrylate derivatives. Journal of the American Chemical Society. 137: 508-17. PMID 25545834 DOI: 10.1021/Ja511445X  1
2015 Hyster TK, Dalton DM, Rovis T. Ligand Design for Rh(III)-Catalyzed C-H Activation: An Unsymmetrical Cyclopentadienyl Enables a Regioselective Synthesis of Dihydroisoquinolones. Chemical Science (Royal Society of Chemistry : 2010). 6: 254-258. PMID 25489470 DOI: 10.1039/C4Sc02590C  1
2015 Davis TA, Wang C, Rovis T. Rhodium(III)-Catalyzed C-H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate Synlett. 26: 1520-1524. DOI: 10.1055/s-0034-1381006  1
2015 Gaunt MJ, Chow HF, Rovis T. Cluster preface: Catalysis using sustainable metals - Part II Synlett. 26: 306. DOI: 10.1055/S-0034-1380054  1
2015 White NA, Rovis T. Oxidatively initiated NHC-catalyzed enantioselective synthesis of 3,4-disubstituted cyclopentanones from enals Journal of the American Chemical Society. 137: 10112-10115. DOI: 10.1021/jacs.5b06390  1
2014 Rubush DM, Rovis T. Stereoselective Synthesis of Dioxolanes and Oxazolidines via a Desymmetrization Acetalization/Michael Cascade. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 713-717. PMID 25960607 DOI: 10.1055/S-0033-1340669  1
2014 Ozboya KE, Rovis T. A Late Stage Strategy for the Functionalization of Triazolium-based NHC catalysts. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 25: 2665-2668. PMID 25954060 DOI: 10.1055/S-0034-1379167  1
2014 White NA, Ozboya KE, Flanigan DM, Rovis T. Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Asian Journal of Organic Chemistry / Managing Editor, Richard Threlfall. 3: 442-444. PMID 25485210 DOI: 10.1002/Ajoc.201402031  1
2014 Oberg KM, Martin TJ, Oinen ME, Dalton DM, Friedman RK, Neely JM, Rovis T. Enantioselective Rhodium-Catalyzed [2+2+2] Cycloaddition of Pentenyl Isocyanate and 4-Ethynylanisole: Preparation and Use of Taddolpyrrolidine Phosphoramidite. Organic Syntheses; An Annual Publication of Satisfactory Methods For the Preparation of Organic Chemicals. 91: 150-161. PMID 25346554 DOI: 10.15227/Orgsyn.091.0150  1
2014 White NA, Rovis T. Enantioselective N-heterocyclic carbene-catalyzed β-hydroxylation of enals using nitroarenes: an atom transfer reaction that proceeds via single electron transfer. Journal of the American Chemical Society. 136: 14674-7. PMID 25302860 DOI: 10.1021/Ja5080739  1
2014 Rovis TL, Legname G. Prion protein-specific antibodies-development, modes of action and therapeutics application. Viruses. 6: 3719-37. PMID 25275428 DOI: 10.3390/v6103719  1
2014 Piou T, Rovis T. Rh(III)-catalyzed cyclopropanation initiated by C-H activation: ligand development enables a diastereoselective [2 + 1] annulation of N-enoxyphthalimides and alkenes. Journal of the American Chemical Society. 136: 11292-5. PMID 25093811 DOI: 10.1021/Ja506579T  1
2014 Hsieh SY, Wanner B, Wheeler P, Beauchemin AM, Rovis T, Bode JW. Stereoelectronic basis for the kinetic resolution of N-heterocycles with chiral acylating reagents. Chemistry (Weinheim An Der Bergstrasse, Germany). 20: 7228-31. PMID 24839065 DOI: 10.1002/Chem.201402818  1
2014 Neely JM, Rovis T. Rh(III)-catalyzed decarboxylative coupling of acrylic acids with unsaturated oxime esters: carboxylic acids serve as traceless activators. Journal of the American Chemical Society. 136: 2735-8. PMID 24512241 DOI: 10.1021/Ja412444D  1
2014 Gabaev I, Elbasani E, Ameres S, Steinbrück L, Stanton R, Döring M, Rovis TL, Kalinke U, Jonjic S, Moosmann A, Messerle M. Expression of the human cytomegalovirus UL11 glycoprotein in viral infection and evaluation of its effect on virus-specific CD8 T cells Journal of Virology. 88: 14326-14339. DOI: 10.1128/JVI.01691-14  1
2014 Gaunt M, Rovis T, Chow HF. Catalysis using sustainable metals - Part i Synlett. 25: 2715-2716. DOI: 10.1055/S-0034-1379611  1
2014 Kohn BL, Rovis T. Cobaltate anion couples terminal dienes with trifluoroacetic anhydride: A direct fluoroacylation of 1,3-dienes Chemical Science. 5: 2889-2892. DOI: 10.1039/C4Sc00743C  1
2014 Neely JM, Rovis T. Pyridine synthesis by [4 + 2] cycloadditions of 1-azadienes: Hetero-Diels Alder and transition metal-catalysed approaches Organic Chemistry Frontiers. 1: 1010-1015. DOI: 10.1039/C4Qo00187G  1
2014 White NA, Ozboya KE, Flanigan DM, Rovis T. ChemInform Abstract: Rapid Construction of (-)-Paroxetine and (-)-Femoxetine via an N-Heterocyclic Carbene Catalyzed Homoenolate Addition to Nitroalkenes. Cheminform. 45: no-no. DOI: 10.1002/chin.201445160  0.01
2013 Perreault S, Rovis T. Enantioselective Synthesis of the Tricyclic Core of FR901483 Featuring a Rh-Catalyzed [2+2+2] Cycloaddition. Synthesis. 45: 719-728. PMID 25506094 DOI: 10.1055/S-0032-1316786  1
2013 Wheeler P, Vora HU, Rovis T. Asymmetric NHC-catalyzed synthesis of α-fluoroamides from readily accessible α-fluoroenals. Chemical Science (Royal Society of Chemistry : 2010). 4: 1674-1679. PMID 25346841 DOI: 10.1039/C3Sc00089C  1
2013 Hyster TK, Rovis T. Rhodium(III)-Catalyzed C-H Activation Mediated Synthesis of Isoquinolones from Amides and Cyclopropenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24: 1842-1844. PMID 25346576 DOI: 10.1055/S-0033-1339510  1
2013 Zhao X, Glover GS, Oberg KM, Dalton DM, Rovis T. SNAr-Derived Decomposition By-products Involving Pentafluorophenyl Triazolium Carbenes. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 24. PMID 24379522 DOI: 10.1055/S-0033-1338842  1
2013 Lathrop SP, Rovis T. A photoisomerization-coupled asymmetric Stetter reaction: application to the total synthesis of three diastereomers of (-)-cephalimysin A. Chemical Science (Royal Society of Chemistry : 2010). 4. PMID 24224080 DOI: 10.1039/C3Sc22292F  1
2013 Davis TA, Hyster TK, Rovis T. Rhodium(III)-catalyzed intramolecular hydroarylation, amidoarylation, and Heck-type reaction: three distinct pathways determined by an amide directing group. Angewandte Chemie (International Ed. in English). 52: 14181-5. PMID 24214733 DOI: 10.1002/Anie.201307631  1
2013 White NA, DiRocco DA, Rovis T. Asymmetric N-heterocyclic carbene catalyzed addition of enals to nitroalkenes: controlling stereochemistry via the homoenolate reactivity pathway to access δ-lactams. Journal of the American Chemical Society. 135: 8504-7. PMID 23713683 DOI: 10.1021/Ja403847E  1
2013 Stanietsky N, Rovis TL, Glasner A, Seidel E, Tsukerman P, Yamin R, Enk J, Jonjic S, Mandelboim O. Mouse TIGIT inhibits NK-cell cytotoxicity upon interaction with PVR. European Journal of Immunology. 43: 2138-50. PMID 23677581 DOI: 10.1002/eji.201243072  1
2013 Dalton DM, Rappé AK, Rovis T. Perfluorinated Taddol Phosphoramidite as an L,Z-Ligand on Rh(I) and Co(-I): Evidence for Bidentate Coordination via Metal-C6F5 Interaction. Chemical Science (Royal Society of Chemistry : 2010). 4: 2062-2070. PMID 23671790 DOI: 10.1039/C3Sc50271F  1
2013 Lankry D, Rovis TL, Jonjic S, Mandelboim O. The interaction between CD300a and phosphatidylserine inhibits tumor cell killing by NK cells. European Journal of Immunology. 43: 2151-61. PMID 23640773 DOI: 10.1002/eji.201343433  1
2013 Dalton DM, Rovis T. Catalytic, asymmetric indolizidinone aza-quaternary stereocenter synthesis: expedient synthesis of the cylindricine alkaloid core. Organic Letters. 15: 2346-9. PMID 23631448 DOI: 10.1021/Ol400529K  1
2013 Martin TJ, Rovis T. A catalytic asymmetric synthesis of polysubstituted piperidines using a rhodium(I)-catalyzed [2+2+2] cycloaddition employing a cleavable tether. Angewandte Chemie (International Ed. in English). 52: 5368-71. PMID 23606664 DOI: 10.1002/Anie.201301741  1
2013 Hyster TK, Ruhl KE, Rovis T. A coupling of benzamides and donor/acceptor diazo compounds to form γ-lactams via Rh(III)-catalyzed C-H activation. Journal of the American Chemical Society. 135: 5364-7. PMID 23548055 DOI: 10.1021/Ja402274G  1
2013 Che X, Oliver SL, Reichelt M, Sommer MH, Haas J, Roviš TL, Arvin AM. ORF11 protein interacts with the ORF9 essential tegument protein in varicella-zoster virus infection. Journal of Virology. 87: 5106-17. PMID 23427162 DOI: 10.1128/JVI.00102-13  1
2013 Neely JM, Rovis T. Rh(III)-catalyzed regioselective synthesis of pyridines from alkenes and α,β-unsaturated oxime esters. Journal of the American Chemical Society. 135: 66-9. PMID 23244023 DOI: 10.1021/Ja3104389  1
2013 Ferreira EM, Rovis T. 17th IUPAC Conference on Organometallic Chemistry Directed Towards Organic Synthesis (OMCOS 17), Fort Collins, CO, USA, July 28–August 1, 2013 Green Processing and Synthesis. 2. DOI: 10.1515/gps-2013-0014  0.01
2013 Rovis T. SYNTHESIS/SYNLETT Editorial Board Focus: Professor Tomislav Rovis (Colorado State University, Fort Collins, USA) Synthesis (Germany). 45: A155. DOI: 10.1055/s-0033-1340224  1
2013 Rovis T, Dalton D. Rhodium-Catalyzed Enantioselective [2+2+2] Cycloaddition Synfacts. 9: 1030-1030. DOI: 10.1055/s-0033-1339688  0.01
2013 Rovis T, Nolan SP. Stable carbenes: From 'laboratory curiosities' to catalysis mainstays Synlett. 24: 1188-1189. DOI: 10.1055/S-0033-1339192  1
2013 DiRocco DA, Rovis T. ChemInform Abstract: Carbene-Catalyzed Stetter Reactions Cheminform. 44: no-no. DOI: 10.1002/chin.201307233  0.01
2013 Oberg KM, Rovis T. Heterocycle Construction via Asymmetric Rhodium-Catalyzed Cycloadditions Asymmetric Synthesis Ii: More Methods and Applications. 303-308. DOI: 10.1002/9783527652235.ch38  1
2012 Vora HU, Wheeler P, Rovis T. Exploiting Acyl and Enol Azolium Intermediates via NHeterocyclic Carbene Catalyzed Reactions of Alpha-Reducible Aldehydes. Advanced Synthesis & Catalysis. 354: 1617-1639. PMID 23538785 DOI: 10.1002/Adsc.201200031  1
2012 Zhao X, Ruhl KE, Rovis T. N-heterocyclic-carbene-catalyzed asymmetric oxidative hetero-Diels-Alder reactions with simple aliphatic aldehydes. Angewandte Chemie (International Ed. in English). 51: 12330-3. PMID 23124903 DOI: 10.1002/Anie.201206490  1
2012 Hyster TK, Knörr L, Ward TR, Rovis T. Biotinylated Rh(III) complexes in engineered streptavidin for accelerated asymmetric C-H activation. Science (New York, N.Y.). 338: 500-3. PMID 23112327 DOI: 10.1126/Science.1226132  1
2012 Rubush DM, Morges MA, Rose BJ, Thamm DH, Rovis T. An asymmetric synthesis of 1,2,4-trioxane anticancer agents via desymmetrization of peroxyquinols through a Brønsted acid catalysis cascade. Journal of the American Chemical Society. 134: 13554-7. PMID 22871165 DOI: 10.1021/Ja3052427  1
2012 DiRocco DA, Rovis T. Catalytic asymmetric cross-aza-benzoin reactions of aliphatic aldehydes with N-Boc-protected imines. Angewandte Chemie (International Ed. in English). 51: 5904-6. PMID 22566184 DOI: 10.1002/Anie.201202442  1
2012 DiRocco DA, Rovis T. Catalytic asymmetric α-acylation of tertiary amines mediated by a dual catalysis mode: N-heterocyclic carbene and photoredox catalysis. Journal of the American Chemical Society. 134: 8094-7. PMID 22548244 DOI: 10.1021/Ja3030164  1
2012 DiRocco DA, Oberg KM, Rovis T. Isolable analogues of the Breslow intermediate derived from chiral triazolylidene carbenes. Journal of the American Chemical Society. 134: 6143-5. PMID 22455368 DOI: 10.1021/Ja302031V  1
2012 DiRocco DA, Noey EL, Houk KN, Rovis T. Catalytic asymmetric intermolecular Stetter reactions of enolizable aldehydes with nitrostyrenes: computational study provides insight into the success of the catalyst. Angewandte Chemie (International Ed. in English). 51: 2391-4. PMID 22282312 DOI: 10.1002/Anie.201107597  1
2012 Rovis T, Filloux C. 6.12 Benzoin and Stetter Reactions Comprehensive Chirality. 6: 318-344. DOI: 10.1016/B978-0-08-095167-6.00612-1  1
2012 Vora HU, Wheeler P, Rovis T. ChemInform Abstract: Exploiting Acyl and Enol Azolium Intermediates via N-Heterocyclic Carbene-Catalyzed Reactions of α-Reducible Aldehydes. Cheminform. 43: no-no. DOI: 10.1002/chin.201239239  0.04
2011 Hyster TK, Rovis T. An Improved Catalyst Architecture for Rhodium (III) Catalyzed C-H Activation and its Application to Pyridone Synthesis. Chemical Science (Royal Society of Chemistry : 2010). 2: 1606-1610. PMID 25580208 DOI: 10.1039/C1Sc00235J  1
2011 Vora HU, Rovis T. Asymmetric N-Heterocyclic Carbene (NHC) Catalyzed Acyl Anion Reactivity. Aldrichimica Acta. 44: 3-11. PMID 25346540  1
2011 Du Y, Hyster TK, Rovis T. Rhodium(III)-catalyzed oxidative carbonylation of benzamides with carbon monoxide. Chemical Communications (Cambridge, England). 47: 12074-6. PMID 22006288 DOI: 10.1039/C1Cc15843K  1
2011 Hyster TK, Rovis T. Pyridine synthesis from oximes and alkynes via rhodium(III) catalysis: Cp* and Cp(t) provide complementary selectivity. Chemical Communications (Cambridge, England). 47: 11846-8. PMID 21986995 DOI: 10.1039/C1Cc15248C  1
2011 Ozboya KE, Rovis T. Enamine/Carbene Cascade Catalysis in the Diastereo- and Enantioselective Synthesis of Functionalized Cyclopentanones. Chemical Science (Royal Society of Chemistry : 2010). 2: 1835-1838. PMID 21927711 DOI: 10.1039/C1Sc00175B  1
2011 Zhao X, DiRocco DA, Rovis T. N-heterocyclic carbene and Brønsted acid cooperative catalysis: asymmetric synthesis of trans-γ-lactams. Journal of the American Chemical Society. 133: 12466-9. PMID 21780842 DOI: 10.1021/Ja205714G  1
2011 DiRocco DA, Rovis T. Organocatalytic hydroacylation of unactivated alkenes. Angewandte Chemie (International Ed. in English). 50: 7982-3. PMID 21721090 DOI: 10.1002/Anie.201102920  1
2011 DiRocco DA, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of enals with nitroalkenes: enhancement of catalytic efficiency through bifunctional additives. Journal of the American Chemical Society. 133: 10402-5. PMID 21678918 DOI: 10.1021/Ja203810B  1
2011 Um JM, DiRocco DA, Noey EL, Rovis T, Houk KN. Quantum mechanical investigation of the effect of catalyst fluorination in the intermolecular asymmetric Stetter reaction. Journal of the American Chemical Society. 133: 11249-54. PMID 21675770 DOI: 10.1021/Ja202444G  1
2011 Oberg KM, Rovis T. Enantioselective rhodium-catalyzed [4+2] cycloaddition of α,β-unsaturated imines and isocyanates. Journal of the American Chemical Society. 133: 4785-7. PMID 21401131 DOI: 10.1021/Ja200766K  1
2011 Moore JL, Silvestri AP, de Alaniz JR, DiRocco DA, Rovis T. Mechanistic investigation of the enantioselective intramolecular stetter reaction: proton transfer is the first irreversible step. Organic Letters. 13: 1742-5. PMID 21355598 DOI: 10.1021/Ol200256A  1
2011 DiRocco DA, Rovis T. ChemInform Abstract: Asymmetric Benzoin and Stetter Reactions Cheminform. 42: no-no. DOI: 10.1002/chin.201140200  0.01
2011 DiRocco DA, Rovis T. Organokatalytische Hydroacylierung nichtaktivierter Alkene Angewandte Chemie. 123: 8130-8132. DOI: 10.1002/Ange.201102920  0.01
2011 Du Y, Hyster TK, Rovis T. Rhodium-catalyzed oxidative carbonylation of benzamides with CO under mild conditions Acs National Meeting Book of Abstracts 1
2011 Vora HU, Rovis T. Asymmetric N-Heterocyclic carbene (NHC) catalyzed acyl anion reactions Aldrichimica Acta. 44: 3-11.  1
2010 Moore JL, Rovis T. Carbene catalysts. Topics in Current Chemistry. 291: 77-144. PMID 21494949 DOI: 10.1007/978-3-642-02815-1_18  1
2010 Dalton DM, Rovis T. Organometallic chemistry: C-H carboxylation takes gold. Nature Chemistry. 2: 710-1. PMID 20729887 DOI: 10.1038/Nchem.815  1
2010 Hyster TK, Rovis T. Rhodium-catalyzed oxidative cycloaddition of benzamides and alkynes via C-H/N-H activation. Journal of the American Chemical Society. 132: 10565-9. PMID 20662529 DOI: 10.1021/Ja103776U  1
2010 Filloux CM, Lathrop SP, Rovis T. Multicatalytic, asymmetric Michael/Stetter reaction of salicylaldehydes and activated alkynes. Proceedings of the National Academy of Sciences of the United States of America. 107: 20666-71. PMID 20639467 DOI: 10.1073/Pnas.1002830107  1
2010 Vora HU, Rovis T. N-Heterocyclic carbene catalyzed asymmetric hydration: direct synthesis of alpha-protio and alpha-deuterio alpha-chloro and alpha-fluoro carboxylic acids. Journal of the American Chemical Society. 132: 2860-1. PMID 20151675 DOI: 10.1021/Ja910281S  1
2010 Miyake GM, DiRocco DA, Liu Q, Oberg KM, Bayram E, Finke RG, Rovis T, Chen EYX. Stereospecific polymerization of chiral oxazolidinone-functionalized alkenes Macromolecules. 43: 7504-7514. DOI: 10.1021/Ma101310N  1
2010 Vora HU, Rovis T. ChemInform Abstract: N-Heterocyclic Carbene Catalyzed Asymmetric Hydration: Direct Synthesis of α-Protio and α-Deuterio α-Chloro and α-Fluoro Carboxylic Acids. Cheminform. 41: no-no. DOI: 10.1002/chin.201031028  0.01
2010 Evans DA, Sweeney ZK, Rovis T, Tedrow JS. ChemInform Abstract: Highly Enantioselective Syntheses of Homopropargylic Alcohols and Dihydrofurans Catalyzed by a Bis(oxazolinyl)pyridine-Scandium Triflate Complex. Cheminform. 33: no-no. DOI: 10.1002/chin.200218032  0.01
2010 Lautens M, Fagnou K, Taylor M, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Ring Opening of Oxabicyclic Alkenes with Heteroatom Nucleophiles. Cheminform. 32: no-no. DOI: 10.1002/chin.200134120  0.01
2010 Evans DA, Rovis T, Johnson JS. ChemInform Abstract: Chiral Copper(II) Complexes as Lewis Acids for Catalyzed Cycloaddition, Carbonyl Addition, and Conjugate Addition Reactions Cheminform. 31: no-no. DOI: 10.1002/chin.200031287  0.01
2010 Lautens M, Rovis T. ChemInform Abstract: Hydroalumination of Carbon-Carbon Double Bonds Cheminform. 31: no-no. DOI: 10.1002/chin.200018249  0.01
2010 Lautens M, Rovis T. ChemInform Abstract: Selective Functionalization of 1,2-Dihydronaphthalenols Leads to a Concise, Stereoselective Synthesis of Sertraline. Cheminform. 30: no-no. DOI: 10.1002/chin.199946235  0.01
2010 LAUTENS M, ROVIS T. ChemInform Abstract: Scope of the Nickel Catalyzed Asymmetric Reductive Ring Opening Reaction. Synthesis of Enantiomerically Enriched Cyclohexenols. Cheminform. 29: no-no. DOI: 10.1002/chin.199823035  0.01
2010 LAUTENS M, ROVIS T. ChemInform Abstract: A New Route to the Enantioselective Synthesis of Cycloheptenols. Temperature Effects in the Asymmetric Reductive Ring Opening of [3.2.1] Oxabicycloalkenes. Cheminform. 29: no-no. DOI: 10.1002/chin.199810093  0.01
2010 LAUTENS M, ROVIS T. ChemInform Abstract: General Strategy Toward the Tetrahydronaphthalene Skeleton. An Expedient Total Synthesis of Sertraline. Cheminform. 28: no-no. DOI: 10.1002/chin.199752115  0.01
2010 LAUTENS M, CHIU P, MA S, ROVIS T. ChemInform Abstract: Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity. Cheminform. 26: no-no. DOI: 10.1002/chin.199527076  0.08
2010 Vora HU, Lathrop SP, Reynolds NT, Kerr MS, De Alaniz JR, Rovis T, Chennamadhavuni S, Davies HML. Preparation of chiral and achiral triazolium salts: Carbene precursors with demonstrated synthetic utility Organic Syntheses. 87: 350-361. DOI: 10.1002/0471264229.Os087.37  1
2009 Oberg KM, Lee EE, Rovis T. Regioselective rhodium-catalyzed intermolecular [2+2+2] cycloaddition of alkynes and isocyanates to form pyridones. Tetrahedron. 65: 5056-5061. PMID 21927511 DOI: 10.1016/J.Tet.2009.02.021  1
2009 Friedman RK, Oberg KM, Dalton DM, Rovis T. Phosphoramidite-Rhodium Complexes as Catalysts for the Asymmetric [2+2+2] Cycloaddition of Alkenyl Isocyanates and Alkynes. Pure and Applied Chemistry. Chimie Pure Et Appliquee. 82: 1353-1364. PMID 20622923 DOI: 10.1351/Pac-Con-09-12-09  1
2009 de Alaniz JR, Rovis T. The Catalytic Asymmetric Intramolecular Stetter Reaction. Synlett : Accounts and Rapid Communications in Synthetic Organic Chemistry. 8: 1189-1207. PMID 20585467 DOI: 10.1055/S-0029-1216654  1
2009 Perreault S, Rovis T. Multi-component cycloaddition approaches in the catalytic asymmetric synthesis of alkaloid targets. Chemical Society Reviews. 38: 3149-59. PMID 19847348 DOI: 10.1039/B816702H  1
2009 Dalton DM, Oberg KM, Yu RT, Lee EE, Perreault S, Oinen ME, Pease ML, Malik G, Rovis T. Enantioselective rhodium-catalyzed [2 + 2 + 2] cycloadditions of terminal alkynes and alkenyl isocyanates: mechanistic insights lead to a unified model that rationalizes product selectivity. Journal of the American Chemical Society. 131: 15717-28. PMID 19817441 DOI: 10.1021/Ja905065J  1
2009 Oinen ME, Yu RT, Rovis T. Excess substrate is a spectator ligand in a rhodium-catalyzed asymmetric [2 + 2 + 2] cycloaddition of alkenyl isocyanates with tolanes. Organic Letters. 11: 4934-7. PMID 19803471 DOI: 10.1021/Ol9020805  1
2009 Lathrop SP, Rovis T. Asymmetric synthesis of functionalized cyclopentanones via a multicatalytic secondary amine/N-heterocyclic carbene catalyzed cascade sequence. Journal of the American Chemical Society. 131: 13628-30. PMID 19731910 DOI: 10.1021/Ja905342E  1
2009 DiRocco DA, Oberg KM, Dalton DM, Rovis T. Catalytic asymmetric intermolecular stetter reaction of heterocyclic aldehydes with nitroalkenes: backbone fluorination improves selectivity. Journal of the American Chemical Society. 131: 10872-4. PMID 19722669 DOI: 10.1021/Ja904375Q  1
2009 Yu RT, Friedman RK, Rovis T. Enantioselective rhodium-catalyzed [4+2+2] cycloaddition of dienyl isocyanates for the synthesis of bicyclic azocine rings. Journal of the American Chemical Society. 131: 13250-1. PMID 19711950 DOI: 10.1021/Ja906641D  1
2009 Friedman RK, Rovis T. Predictable and regioselective insertion of internal unsymmetrical alkynes in rhodium-catalyzed cycloadditions with alkenyl isocyanates. Journal of the American Chemical Society. 131: 10775-82. PMID 19569692 DOI: 10.1021/Ja903899C  1
2009 Liu Q, Rovis T. Enantio- and diastereoselective intermolecular Stetter reaction of glyoxamide and alkylidene ketoamides. Organic Letters. 11: 2856-9. PMID 19507841 DOI: 10.1021/Ol901081A  1
2009 Galan BR, Rovis T. Beyond Reppe: building substituted arenes by [2+2+2] cycloadditions of alkynes. Angewandte Chemie (International Ed. in English). 48: 2830-4. PMID 19229917 DOI: 10.1002/Anie.200804651  1
2009 Yu RT, Lee EE, Malik G, Rovis T. Total synthesis of indolizidine alkaloid (-)-209D: overriding substrate bias in the asymmetric rhodium-catalyzed [2+2+2] cycloaddition. Angewandte Chemie (International Ed. in English). 48: 2379-82. PMID 19229912 DOI: 10.1002/Anie.200805455  1
2009 Rovis T, Yu R, Friedman R. Synthesis of Bicyclic Azocine Rings via Rh-Catalyzed [4+2+2] Cycloaddition Synfacts. 2009: 1355-1355. DOI: 10.1055/s-0029-1218313  0.01
2009 Cook MJ, Rovis T. Enantioselective rhodium-catalyzed alkylative desymmetrization of 3,5-dimethylglutaric anhydride Synthesis. 335-338. DOI: 10.1055/S-0028-1083275  1
2009 Johnson JB, Cook MJ, Rovis T. Ligand differentiated complementary Rh-catalyst systems for the enantioselective desymmetrization of meso-cyclic anhydrides Tetrahedron. 65: 3202-3210. DOI: 10.1016/J.Tet.2008.10.075  1
2009 Galan B, Rovis T. Über Reppe hinaus: Aufbau substituierter Arene durch [2+2+2]-Cycloaddition von Alkinen Angewandte Chemie. 121: 2870-2874. DOI: 10.1002/Ange.200804651  0.01
2008 Vora HU, Moncecchi JR, Epstein O, Rovis T. Nucleophilic carbene catalyzed synthesis of 1,2 amino alcohols via azidation of epoxy aldehydes. The Journal of Organic Chemistry. 73: 9727-31. PMID 18989930 DOI: 10.1021/Jo8020055  1
2008 Williams CM, Johnson JB, Rovis T. Nickel-catalyzed reductive carboxylation of styrenes using CO2. Journal of the American Chemical Society. 130: 14936-7. PMID 18928253 DOI: 10.1021/Ja8062925  1
2008 Liu Q, Perreault S, Rovis T. Catalytic asymmetric intermolecular Stetter reaction of glyoxamides with alkylidenemalonates. Journal of the American Chemical Society. 130: 14066-7. PMID 18834123 DOI: 10.1021/Ja805680Z  1
2008 Cullen SC, Rovis T. Catalytic asymmetric stetter reaction onto vinylphosphine oxides and vinylphosphonates. Organic Letters. 10: 3141-4. PMID 18549233 DOI: 10.1021/Ol801047K  1
2008 Orellana A, Rovis T. Towards the total synthesis of FD-838: modular enantioselective assembly of the core. Chemical Communications (Cambridge, England). 730-2. PMID 18478705 DOI: 10.1039/B716445A  1
2008 de Alaniz JR, Kerr MS, Moore JL, Rovis T. Scope of the asymmetric intramolecular stetter reaction catalyzed by chiral nucleophilic triazolinylidene carbenes. The Journal of Organic Chemistry. 73: 2033-40. PMID 18302407 DOI: 10.1021/Jo702313F  1
2008 Yu RT, Rovis T. Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides. Journal of the American Chemical Society. 130: 3262-3. PMID 18302377 DOI: 10.1021/Ja710065H  1
2008 Lee EE, Rovis T. Enantioselective synthesis of indolizidines bearing quaternary substituted stereocenters via rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes. Organic Letters. 10: 1231-4. PMID 18284249 DOI: 10.1021/Ol800086S  1
2008 Johnson JB, Rovis T. Enantioselective cross-coupling of anhydrides with organozinc reagents: the controlled formation of carbon-carbon bonds through the nucleophilic interception of metalacycles. Accounts of Chemical Research. 41: 327-38. PMID 18232665 DOI: 10.1021/Ar700176T  1
2008 Nasveschuk CG, Rovis T. The [1, 3] O-to-C rearrangement: opportunities for stereoselective synthesis. Organic & Biomolecular Chemistry. 6: 240-54. PMID 18174990 DOI: 10.1039/B714881J  1
2008 Nasveschuk CG, Rovis T. A diastereoselective ring contraction of 1,3-dioxepins to 2,3,4-trisubstituted and tetrasubstituted tetrahydrofurans. The Journal of Organic Chemistry. 73: 612-7. PMID 18088144 DOI: 10.1021/Jo702071V  1
2008 Johnson JB, Rovis T. More than bystanders: the effect of olefins on transition-metal-catalyzed cross-coupling reactions. Angewandte Chemie (International Ed. in English). 47: 840-71. PMID 18081111 DOI: 10.1002/Anie.200700278  1
2008 Rovis T. Development of chiral bicyclic triazolium salt organic catalysts: The importance of the N-aryl substituent Chemistry Letters. 37: 2-7. DOI: 10.1246/Cl.2008.2  1
2008 Nasveschuk CG, Rovis T. A rapid total synthesis of (±)-sylvone Synlett. 0126-0128. DOI: 10.1055/S-2007-990926  1
2008 Rovis T. Book Review of Six-Membered Transition States in Organic Synthesis Six-Membered Transition States in Organic Synthesis . By Jaemoon Yang  (Montana State University).  John Wiley & Sons, Inc. :  Hoboken, NJ . 2008 . x + 210 pp. $125.00. ISBN 978-0-470-17883-6 . Journal of the American Chemical Society. 130: 8567-8567. DOI: 10.1021/Ja803438J  0.01
2008 Yu RT, Rovis T. ChemInform Abstract: Asymmetric Synthesis of Bicyclic Amidines via Rhodium-Catalyzed [2 + 2 + 2] Cycloaddition of Carbodiimides. Cheminform. 39. DOI: 10.1002/chin.200831169  0.01
2008 Nasveschuk CG, Rovis T. ChemInform Abstract: A Rapid Total Synthesis of (.+-.)-Sylvone. Cheminform. 39. DOI: 10.1002/chin.200822206  0.01
2008 Johnson J, Rovis T. Nicht ganz unbeteiligt: der Einfluss von Olefinen auf übergangsmetallkatalysierte Kreuzkupplungen Angewandte Chemie. 120: 852-884. DOI: 10.1002/Ange.200700278  0.01
2007 Liu Q, Rovis T. Enantioselective Synthesis of Hydrobenzofuranones Using an Asymmetric Desymmetrizing Intramolecular Stetter Reaction of Cyclohexadienones. Organic Process Research & Development. 11: 598-604. PMID 19603085 DOI: 10.1021/op600278f  1
2007 Rogers RL, Moore JL, Rovis T. Alkene-directed regioselective nickel-catalyzed cross-coupling of cyclic anhydrides with diorganozinc reagents. Angewandte Chemie (International Ed. in English). 46: 9301-4. PMID 17985335 DOI: 10.1002/Anie.200703124  1
2007 Nasveschuk CG, Frein JD, Jui NT, Rovis T. A diastereoselective intermolecular heck reaction of 1,3-dioxepins. Organic Letters. 9: 5099-102. PMID 17958436 DOI: 10.1021/Ol702294U  1
2007 Vora HU, Rovis T. Nucleophilic carbene and HOAt relay catalysis in an amide bond coupling: an orthogonal peptide bond forming reaction. Journal of the American Chemical Society. 129: 13796-7. PMID 17929821 DOI: 10.1021/Ja0764052  1
2007 Cook MJ, Rovis T. Rhodium-catalyzed enantioselective desymmetrization of meso-3,5-dimethyl glutaric anhydride: a general strategy to syn-deoxypolypropionate synthons. Journal of the American Chemical Society. 129: 9302-3. PMID 17622150 DOI: 10.1021/Ja073269S  1
2007 Johnson JB, Bercot EA, Williams CM, Rovis T. A concise synthesis of eupomatilones 4, 6, and 7 by rhodium-catalyzed enantioselective desymmetrization of cyclic meso anhydrides with organozinc reagents generated in situ. Angewandte Chemie (International Ed. in English). 46: 4514-8. PMID 17492814 DOI: 10.1002/Anie.200700816  1
2007 Johnson JB, Bercot EA, Rowley JM, Coates GW, Rovis T. Ligand-dependent catalytic cycle and role of styrene in nickel-catalyzed anhydride cross-coupling: evidence for turnover-limiting reductive elimination. Journal of the American Chemical Society. 129: 2718-25. PMID 17295486 DOI: 10.1021/Ja067845G  1
2006 Frein JD, Rovis T. Surveying approaches to the formation of carbon-carbon bonds between a pyran and an adjacent ring. Tetrahedron. 62: 4573-4583. PMID 17710219 DOI: 10.1016/J.Tet.2006.02.042  1
2006 Epstein OL, Rovis T. A Sakurai-Prins-Ritter sequence for the three-component diastereoselective synthesis of 4-amino tetrahydropyrans. Journal of the American Chemical Society. 128: 16480-1. PMID 17177379 DOI: 10.1021/Ja066794K  1
2006 Yu RT, Rovis T. Enantioselective rhodium-catalyzed [2+2+2] cycloaddition of alkenyl isocyanates and terminal alkynes: application to the total synthesis of (+)-lasubine II. Journal of the American Chemical Society. 128: 12370-1. PMID 16984159 DOI: 10.1021/Ja064868M  1
2006 Johnson JB, Yu RT, Fink P, Bercot EA, Rovis T. Selective substituent transfer from mixed zinc reagents in Ni-catalyzed anhydride alkylation. Organic Letters. 8: 4307-10. PMID 16956213 DOI: 10.1021/Ol0616337  1
2006 Nasveschuk CG, Jui NT, Rovis T. A modular approach to the synthesis of 2,3,4-trisubstituted tetrahydrofurans. Chemical Communications (Cambridge, England). 3119-21. PMID 16855705 DOI: 10.1039/B605438B  1
2006 Yu RT, Rovis T. Rhodium-catalyzed [2 + 2 + 2] cycloaddition of alkenyl isocyanates and alkynes. Journal of the American Chemical Society. 128: 2782-3. PMID 16506740 DOI: 10.1021/Ja057803C  1
2006 Liu Q, Rovis T. Asymmetric synthesis of hydrobenzofuranones via desymmetrization of cyclohexadienones using the intramolecular Stetter reaction. Journal of the American Chemical Society. 128: 2552-3. PMID 16492036 DOI: 10.1021/Ja058337U  1
2006 Rovis T, Yu R. Indolizinone and Quinolizinone via Asymmetric [2+2+2] Cycloaddition Synfacts. 2006: 1209-1209. DOI: 10.1055/s-2006-955576  0.01
2006 Rovis T, Liu Q. Asymmetric Synthesis of Hydrobenzofuranones via Enantioselective Stetter Reaction Synfacts. 2006: 0508-0508. DOI: 10.1055/s-2006-934454  0.04
2006 Rovis T. Quaternary Stereocenters:  Challenges and Solutions for Organic Synthesis Edited by Jens Christoffers and Angelika Baro (Universität Stuttgart). Wiley-VCH Verlag GmbH & Co. KGA:  Weinheim. 2005. xxiv + 336 pp. $170. ISBN 3-527-31107-6. Journal of the American Chemical Society. 128: 8095-8095. DOI: 10.1021/Ja0598917  0.01
2006 Moore JL, Kerr MS, Rovis T. Enantioselective formation of quaternary stereocenters using the catalytic intramolecular Stetter reaction Tetrahedron. 62: 11477-11482. DOI: 10.1016/J.Tet.2006.06.042  1
2006 Rovis T. Recent Advances in Catalytic Asymmetric Desymmetrization Reactions New Frontiers in Asymmetric Catalysis. 275-311. DOI: 10.1002/0470098007.ch10  1
2005 Reynolds NT, Rovis T. Enantioselective protonation of catalytically generated chiral enolates as an approach to the synthesis of alpha-chloroesters. Journal of the American Chemical Society. 127: 16406-7. PMID 16305222 DOI: 10.1021/Ja055918A  1
2005 Kerr MS, Read de Alaniz J, Rovis T. An efficient synthesis of achiral and chiral 1,2,4-triazolium salts: bench stable precursors for N-heterocyclic carbenes. The Journal of Organic Chemistry. 70: 5725-8. PMID 15989360 DOI: 10.1021/Jo050645N  1
2005 Nasveschuk CG, Rovis T. Regioselective Lewis acid-mediated [1,3] rearrangement of allylvinyl ethers. Organic Letters. 7: 2173-6. PMID 15901162 DOI: 10.1021/Ol0505151  1
2005 Read de Alaniz J, Rovis T. A highly enantio- and diastereoselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 127: 6284-9. PMID 15853335 DOI: 10.1021/Ja0425132  1
2005 Nasveschuk CG, Rovis T. Stereoselective Lewis acid mediated [1,3] ring contraction of 2,5-dihydrooxepins as a route to polysubstituted cyclopentenes. Angewandte Chemie (International Ed. in English). 44: 3264-7. PMID 15844118 DOI: 10.1002/Anie.200500088  1
2005 Bercot EA, Rovis T. Highly efficient nickel-catalyzed cross-coupling of succinic and glutaric anhydrides with organozinc reagents. Journal of the American Chemical Society. 127: 247-54. PMID 15631474 DOI: 10.1021/Ja044588B  1
2005 Bercot EA, Kindrachuk DE, Rovis T. Complementary diastereoselective reduction of cyclic gamma-keto acids: efficient access to trisubsituted gamma-lactones. Organic Letters. 7: 107-10. PMID 15624989 DOI: 10.1021/Ol047821J  1
2005 Lund TD, Rovis T, Chung WC, Handa RJ. Novel actions of estrogen receptor-beta on anxiety-related behaviors. Endocrinology. 146: 797-807. PMID 15514081 DOI: 10.1210/En.2004-1158  1
2005 Rovis T, Reynolds N. Organocatalytic Asymmetric Synthesis of α-Chloroesters Synfacts. 2006: 0078-0078. DOI: 10.1055/s-2005-921718  0.01
2005 Rovis T. The Comprehensive e-Book of Named Organic Reactions and Their Mechanisms By Elbertus Kruiswijk. The Chemical Bookstore:  Aberaman, U.K. 2005. http://www.namedorganicreactions.co.uk. 1980 pp. Approximately $23.00. Journal of the American Chemical Society. 127: 17567-17568. DOI: 10.1021/ja0597653  0.01
2005 Reynolds NT, Rovis T. The effect of pre-existing stereocenters in the intramolecular asymmetric Stetter reaction Tetrahedron. 61: 6368-6378. DOI: 10.1016/J.Tet.2005.03.121  1
2005 Bercot EA, Kindrachuk DE, Rovis T. Complementary Diastereoselective Reduction of Cyclic ?-Keto Acids: Efficient Access to Trisubstituted ?-Lactones. Cheminform. 36. DOI: 10.1002/chin.200517114  0.01
2004 Zhang Y, Rovis T. A unique catalyst effects the rapid room-temperature cross-coupling of organozinc reagents with carboxylic acid fluorides, chlorides, anhydrides, and thioesters. Journal of the American Chemical Society. 126: 15964-5. PMID 15584721 DOI: 10.1021/Ja044113K  1
2004 Bercot EA, Rovis T. A palladium-catalyzed enantioselective alkylative desymmetrization of meso-succinic anhydrides. Journal of the American Chemical Society. 126: 10248-9. PMID 15315429 DOI: 10.1021/Ja046528B  1
2004 Reynolds NT, Read de Alaniz J, Rovis T. Conversion of alpha-haloaldehydes into acylating agents by an internal redox reaction catalyzed by nucleophilic carbenes. Journal of the American Chemical Society. 126: 9518-9. PMID 15291537 DOI: 10.1021/Ja046991O  1
2004 Kerr MS, Rovis T. Enantioselective synthesis of quaternary stereocenters via a catalytic asymmetric Stetter reaction. Journal of the American Chemical Society. 126: 8876-7. PMID 15264801 DOI: 10.1021/Ja047644H  1
2004 Zhang Y, Rovis T. Use of acid fluorides increases the scope of the reductive acylation of esters. Organic Letters. 6: 1877-9. PMID 15151437 DOI: 10.1021/Ol049333H  1
2003 O'Brien EM, Bercot EA, Rovis T. Decarbonylative cross-coupling of cyclic anhydrides: introducing stereochemistry at an sp3 carbon in the cross-coupling event. Journal of the American Chemical Society. 125: 10498-9. PMID 12940714 DOI: 10.1021/Ja036290B  1
2003 Kerr MS, Rovis T. Effect of the Michael Acceptor in the Asymmetric Intramolecular Stetter Reaction Synlett. 1934-1936. DOI: 10.1055/S-2003-41458  1
2003 Zhang Y, Rovis T. 1,3-Polyol arrays via the stereoselective rearrangement of vinyl acetals Tetrahedron. 59: 8979-8987. DOI: 10.1016/J.Tet.2003.03.004  1
2003 Rovis T. Metal and Nonmetal Catalysts for Carbon-Carbon Bond-Forming Reactions Leading to Desymmetrized 1,4-Dicarbonyl Compounds Chemtracts. 16: 542-553.  1
2002 Kerr MS, Read de Alaniz J, Rovis T. A highly enantioselective catalytic intramolecular Stetter reaction. Journal of the American Chemical Society. 124: 10298-9. PMID 12197730 DOI: 10.1021/Ja027411V  1
2002 Zhang Y, Reynolds NT, Manju K, Rovis T. Stereoretentive O-to-C rearrangement of vinyl acetals: solvent cage effects as a stereocontrol element. Journal of the American Chemical Society. 124: 9720-1. PMID 12175226 DOI: 10.1021/Ja026972J  1
2002 Bercot EA, Rovis T. A mild and efficient catalytic alkylative monofunctionalization of cyclic anhydrides. Journal of the American Chemical Society. 124: 174-5. PMID 11782160 DOI: 10.1021/Ja017086W  1
2001 Evans DA, Sweeney ZK, Rovis T, Tedrow JS. Highly enantioselective syntheses of homopropargylic alcohols and dihydrofurans catalyzed by a bis(oxazolinyl)pyridine-scandium triflate complex. Journal of the American Chemical Society. 123: 12095-6. PMID 11724622 DOI: 10.1021/Ja011983I  1
2001 Lautens M, Fagnou K, Taylor M, Rovis T. Rhodium-catalysed asymmetric ring opening of oxabicyclic alkenes with heteroatom nucleophiles Journal of Organometallic Chemistry. 624: 259-270. DOI: 10.1016/S0022-328X(00)00904-9  1
2001 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. ChemInform Abstract: Enantioselective Lewis Acid Catalyzed Michael Reactions of Alkylidene Malonates. Catalysis by C2-Symmetric Bis(oxazoline) Copper(II) Complexes in the Synthesis of Chiral, Differentiated Glutarate Esters. Cheminform. 32: no-no. DOI: 10.1002/chin.200103030  0.01
2001 Rovis T, Evans DA. Structural and mechanistic investigations in asymmetric copper(I) and copper(II) catalyzed reactions Progress in Inorganic Chemistry. 50: 1-150.  1
2000 Evans DA, Rovis T, Kozlowski MC, Downey CW, Tedrow JS. Enantioselective Lewis acid catalyzed Michael reactions of alkylidene malonates. Catalysis by C2-symmetric bis(oxazoline) copper(II) complexes in the synthesis of chiral, differentiated glutarate esters Journal of the American Chemical Society. 122: 9134-9142. DOI: 10.1021/Ja002246+  1
2000 Lautens M, Fagnou K, Rovis T. Rhodium-catalyzed asymmetric alcoholysis and aminolysis of oxabenzonorbornadiene: A new enantioselective carbon-heteroatom bond forming process [8] Journal of the American Chemical Society. 122: 5650-5651. DOI: 10.1021/Ja000134C  1
2000 Lautens M, Fagnou K, Rovis T. ChemInform Abstract: Rhodium-Catalyzed Asymmetric Alcoholysis and Aminolysis of Oxabenzonorbornadiene: A New Enantioselective Carbon-Heteroatom Bond Forming Process. Cheminform. 31: no-no. DOI: 10.1002/chin.200040088  0.01
1999 Evans DA, Rovis T, Johnson JS. Chiral copper(∥) complexes as Lewis acids for catalyzed cycloaddition, carbonyl addition, and conjugate addition reactions Pure and Applied Chemistry. 71: 1407-1415. DOI: 10.1351/Pac199971081407  1
1999 Evans DA, Rovis T, Kozlowski MC, Tedrow JS. C2-symmetric Cu(II) complexes as chiral Lewis acids. Catalytic enantioselective Michael addition of silylketene acetals to alkylidene malonates [21] Journal of the American Chemical Society. 121: 1994-1995. DOI: 10.1021/Ja983864H  1
1999 Lautens M, Rovis T. Selective functionalization of 1,2-dihydronaphthalenols leads to a concise, stereoselective synthesis of sertraline Tetrahedron. 55: 8967-8976. DOI: 10.1016/S0040-4020(99)00456-1  1
1998 Lautens M, Rovis T, Smith ND, Ostrovsky D. Metal catalyzed hydrometalations and their applications in synthesis Pure and Applied Chemistry. 70: 1059-1064. DOI: 10.1351/Pac199870051059  0.01
1998 Lautens M, Rovis T. Scope of the nickel catalyzed asymmetric reductive ring opening reaction. Synthesis of enantiomerically enriched cyclohexenols Tetrahedron. 54: 1107-1116. DOI: 10.1016/S0040-4020(97)10211-3  1
1998 Lautens M, Rovis T, Smith ND, Ostrovsky D. Metal catalyzed hydrometalations and their applications in synthesis Pure and Applied Chemistry. 70: 1059-1064.  1
1997 Lautens M, Rovis T. General strategy toward the tetrahydronaphthalene skeleton. An expedient total synthesis of sertraline Journal of Organic Chemistry. 62: 5246-5247. DOI: 10.1021/Jo971115X  1
1997 Lautens M, Rovis T. A new route to the enantioselective synthesis of cycloheptenols. Temperature effects in the asymmetric reductive ring opening [3.2.1] oxabicycloalkenes Journal of the American Chemical Society. 119: 11090-11091. DOI: 10.1021/Ja971770M  1
1995 Lautens M, Chiu P, Ma S, Rovis T. Nickel-Catalyzed Hydroalumination of Oxabicyclic Alkenes. Ligand Effects on the Regio- and Enantioselectivity Journal of the American Chemical Society. 117: 532-533. DOI: 10.1021/Ja00106A062  0.01
1995 Lautens M, Chiu P, Ma S, Rovis T. Nickel-catalyzed hydroalumination of oxabicyclic alkenes. Ligand effects on the regio- and enantioselectivity Journal of the American Chemical Society. 117: 532-533.  1
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