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Seth N. Brown - Publications

Affiliations: 
Chemistry and Biochemistry University of Notre Dame, Notre Dame, IN, United States 
Area:
oxidation reactions, chemical synthesis
Website:
http://chemistry.nd.edu/faculty/detail/sbrown3/
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70 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2023 Carbonel H, Mikulski TD, Nugraha K, Johnston J, Wang Y, Brown SN. Optically active bis(aminophenols) and their metal complexes. Dalton Transactions (Cambridge, England : 2003). PMID 37668189 DOI: 10.1039/d3dt02436a  0.307
2023 Ayson PRH, Brown SN. Slip to π Ru: structural distortions due to metal-iminoxolene π bonding. Chemical Communications (Cambridge, England). PMID 37462618 DOI: 10.1039/d3cc02943c  0.36
2023 Do TH, Haungs DA, Chin WY, Jerit JT, VanderZwaag A, Brown SN. Modulation of Isomerization and Ligand Exchange Rates by π Bonding in Bis(iminoxolene)iridium Pyridine Complexes. Inorganic Chemistry. PMID 37437186 DOI: 10.1021/acs.inorgchem.3c01717  0.374
2022 Do TH, Brown SN. Mono- and Bis(iminoxolene)iridium Complexes: Synthesis and Covalency in π Bonding. Inorganic Chemistry. 61: 5547-5562. PMID 35357169 DOI: 10.1021/acs.inorgchem.1c04005  0.479
2021 Erickson AN, Gianino J, Markovitz SJ, Brown SN. Amphiphilicity in Oxygen Atom Transfer Reactions of Oxobis(iminoxolene)osmium Complexes. Inorganic Chemistry. PMID 33657323 DOI: 10.1021/acs.inorgchem.1c00068  0.416
2020 Do TH, Brown SN. Synthesis, dynamics and redox properties of eight-coordinate zirconium catecholate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 32785310 DOI: 10.1039/D0Dt02487B  0.54
2020 Gianino J, Erickson AN, Markovitz SJ, Brown SN. High-valent osmium iminoxolene complexes. Dalton Transactions (Cambridge, England : 2003). PMID 32525176 DOI: 10.1039/D0Dt01735C  0.569
2020 Gianino J, Brown SN. Highly covalent metal-ligand π bonding in chelated bis- and tris(iminoxolene) complexes of osmium and ruthenium. Dalton Transactions (Cambridge, England : 2003). PMID 32367103 DOI: 10.1039/D0Dt01287D  0.541
2019 Liu R, Krchnak V, Brown SN, Miller MJ. Deuteration of BTZ043 Extends the Lifetime of Meisenheimer Intermediates to the Antituberculosis Nitroso Oxidation State. Acs Medicinal Chemistry Letters. 10: 1462-1466. PMID 31620234 DOI: 10.1021/Acsmedchemlett.9B00308  0.372
2019 Do TH, Brown SN. Mono- and bimetallic pentacoordinate silicon complexes of a chelating bis(catecholimine) ligand. Dalton Transactions (Cambridge, England : 2003). PMID 31297499 DOI: 10.1039/C9Dt02475A  0.455
2019 Marshall-Roth T, Yao K, Parkhill JA, Brown SN. On the border between localization and delocalization: tris(iminoxolene)titanium(iv). Dalton Transactions (Cambridge, England : 2003). PMID 30628607 DOI: 10.1039/C8Dt04528C  0.488
2018 Erickson AN, Brown SN. Molybdenum(vi) tris(amidophenoxide) complexes. Dalton Transactions (Cambridge, England : 2003). PMID 30346454 DOI: 10.1039/C8Dt03392G  0.551
2018 Conner KM, Arostegui AC, Swanson DD, Brown SN. When Do Strongly Coupled Diradicals Show Strongly Coupled Reactivity? Thermodynamics and Kinetics of Hydrogen Atom Transfer Reactions of Palladium and Platinum Bis(iminosemiquinone) Complexes. Inorganic Chemistry. PMID 29517233 DOI: 10.1021/Acs.Inorgchem.8B00068  0.479
2018 Conner KM, Perugini AL, Malabute M, Brown SN. Group 10 Bis(iminosemiquinone) Complexes: Measurement of Singlet-Triplet Gaps and Analysis of the Effects of Metal and Geometry on Electronic Structure. Inorganic Chemistry. PMID 29509423 DOI: 10.1021/Acs.Inorgchem.8B00062  0.46
2017 Swanson DD, Conner KM, Brown SN. A chelating bis(aminophenol) ligand bridged by a 1,1'-ferrocene-bis(para-phenylene) linker. Dalton Transactions (Cambridge, England : 2003). PMID 28660932 DOI: 10.1039/C7Dt01945A  0.447
2017 Hoffman JM, Oliver AG, Brown SN. The Metal or the Ligand? The Preferred Locus for Redox Changes in Oxygen Atom Transfer Reactions of Rhenium Amidodiphenoxides. Journal of the American Chemical Society. PMID 28257202 DOI: 10.1021/Jacs.7B00985  0.476
2015 Marshall-Roth T, Brown SN. Redox activity and π bonding in a tripodal seven-coordinate molybdenum(VI) tris(amidophenolate). Dalton Transactions (Cambridge, England : 2003). 44: 677-85. PMID 25385437 DOI: 10.1039/C4Dt02936D  0.512
2014 Shekar S, Brown SN. Mechanism and selectivity of methyl and phenyl migrations in hypervalent silylated iminoquinones. The Journal of Organic Chemistry. 79: 12047-55. PMID 25289545 DOI: 10.1021/Jo501888R  0.383
2014 Ranis LG, Werellapatha K, Pietrini NJ, Bunker BA, Brown SN. Metal and ligand effects on bonding in group 6 complexes of redox-active amidodiphenoxides. Inorganic Chemistry. 53: 10203-16. PMID 25247396 DOI: 10.1021/Ic501222N  0.5
2014 Cipressi J, Brown SN. Octahedral to trigonal prismatic distortion driven by subjacent orbital π antibonding interactions and modulated by ligand redox noninnocence. Chemical Communications (Cambridge, England). 50: 7956-9. PMID 24918862 DOI: 10.1039/C4Cc03404J  0.424
2014 Shekar S, Brown SN. Mixed amidophenolate-catecholates of molybdenum(VI). Dalton Transactions (Cambridge, England : 2003). 43: 3601-11. PMID 24406464 DOI: 10.1039/C3Dt53496K  0.462
2013 Wright DD, Brown SN. Nonclassical oxygen atom transfer as a synthetic strategy: preparation of an oxorhenium(V) complex of the bis(3,5-di-tert-butyl-2-phenoxo)amide ligand. Inorganic Chemistry. 52: 7831-3. PMID 23815641 DOI: 10.1021/Ic4010592  0.491
2013 Shekar S, Brown SN. Migrations of alkyl and aryl groups from silicon to nitrogen in silylated aryloxyiminoquinones Organometallics. 32: 556-564. DOI: 10.1021/Om301028C  0.428
2012 Marshall-Roth T, Liebscher SC, Rickert K, Seewald NJ, Oliver AG, Brown SN. Nonclassical oxygen atom transfer reactions of oxomolybdenum(VI) bis(catecholate). Chemical Communications (Cambridge, England). 48: 7826-8. PMID 22785616 DOI: 10.1039/C2Cc33523A  0.461
2012 Brown SN. Metrical oxidation states of 2-amidophenoxide and catecholate ligands: structural signatures of metal-ligand π bonding in potentially noninnocent ligands. Inorganic Chemistry. 51: 1251-60. PMID 22260321 DOI: 10.1021/Ic202764J  0.483
2012 Kopec JA, Shekar S, Brown SN. Molybdenum(VI) complexes of a 2,2'-biphenyl-bridged bis(amidophenoxide): competition between metal-ligand and metal-amidophenoxide π bonding. Inorganic Chemistry. 51: 1239-50. PMID 22260301 DOI: 10.1021/Ic201736H  0.513
2011 Quiroz-Guzman M, Oliver AG, Loza AJ, Brown SN. Redox-active tetrahydrosalen (salan) complexes of titanium. Dalton Transactions (Cambridge, England : 2003). 40: 11458-68. PMID 21935551 DOI: 10.1039/C1Dt11228G  0.527
2011 Kongprakaiwoot N, Quiroz-Guzman M, Oliver AG, Brown SN. Gauging electronic dissymmetry in bis-chelates of titanium(IV) using sterically and electronically variable 2,2′-biphenoxides Chemical Science. 2: 331-336. DOI: 10.1039/C0Sc00468E  0.515
2010 Kongprakaiwoot N, Armstrong JB, Noll BC, Brown SN. Optically active bis(β-diketonate) complexes of titanium. Dalton Transactions (Cambridge, England : 2003). 39: 10105-15. PMID 20830404 DOI: 10.1039/C0Dt00828A  0.47
2010 Quiroz-Guzman M, Brown SN. Tris(4-bromophenyl)aminium hexachloridoantimonate ('Magic Blue'): a strong oxidant with low inner-sphere reorganization. Acta Crystallographica. Section C, Crystal Structure Communications. 66: m171-3. PMID 20603548 DOI: 10.1107/S0108270110019748  0.414
2010 Lionetti D, Medvecz AJ, Ugrinova V, Quiroz-Guzman M, Noll BC, Brown SN. Redox-active tripodal aminetris(aryloxide) complexes of titanium(IV). Inorganic Chemistry. 49: 4687-97. PMID 20397715 DOI: 10.1021/Ic100347H  0.766
2009 Dulatas LT, Brown SN, Ojomo E, Noll BC, Cavo MJ, Holt PB, Wopperer MM. Intermetallic communication in titanium(IV) ferrocenyldiketonates. Inorganic Chemistry. 48: 10789-99. PMID 19845328 DOI: 10.1021/Ic901683C  0.476
2009 Hurley ER, He X, Brown SN, Henderson KW. Dramatic effect of aggregation on rates and thermodynamics of stereoisomerization of magnesium enolates. Journal of the American Chemical Society. 131: 6056-7. PMID 19400589 DOI: 10.1021/Ja809716J  0.342
2008 Kongprakaiwoot N, Noll BC, Brown SN. Tetradentate bis(hydroxamate) and hydroxamate-diketonate ligands and their titanium(IV) complexes. Inorganic Chemistry. 47: 11902-9. PMID 19006387 DOI: 10.1021/Ic8016479  0.49
2007 Fortner KC, Laitar DS, Muldoon J, Pu L, Braun-Sand SB, Wiest O, Brown SN. Ultrafast and ultraslow oxygen atom transfer reactions between late metal centers. Journal of the American Chemical Society. 129: 588-600. PMID 17227022 DOI: 10.1021/Ja065713H  0.624
2006 Ugrinova V, Noll BC, Brown SN. Mononucleating bis(beta-diketonate) ligands and their titanium(IV) complexes. Inorganic Chemistry. 45: 10309-20. PMID 17140240 DOI: 10.1021/Ic061201S  0.803
2006 Seymore SB, Brown SN. Kinetic effects in heterometallic dinitrogen cleavage. Inorganic Chemistry. 45: 9540-50. PMID 17083256 DOI: 10.1021/Ic061153B  0.789
2006 He X, Morris JJ, Noll BC, Brown SN, Henderson KW. Kinetics and mechanism of ketone enolization mediated by magnesium bis(hexamethyldisilazide). Journal of the American Chemical Society. 128: 13599-610. PMID 17031975 DOI: 10.1021/Ja064927W  0.418
2006 Schroeder T, Ugrinova V, Noll BC, Brown SN. A chelating beta-diketonate/phenoxide ligand and its coordination behavior toward titanium and scandium. Dalton Transactions (Cambridge, England : 2003). 1030-40. PMID 16474889 DOI: 10.1039/B511915D  0.779
2005 Brown SN, Chu ET, Hull MW, Noll BC. Electronic dissymmetry in chiral recognition. Journal of the American Chemical Society. 127: 16010-1. PMID 16287272 DOI: 10.1021/Ja055598V  0.488
2005 Fortner KC, Bigi JP, Brown SN. Six-coordinate titanium complexes of a tripodal aminetris(phenoxide) ligand: synthesis, structure, and dynamics. Inorganic Chemistry. 44: 2803-14. PMID 15819569 DOI: 10.1021/Ic048403D  0.518
2004 Maestri AG, Brown SN. Titanatranes derailed: static and dynamic triethanolamine slippage induced by polyphenoxide chelation. Inorganic Chemistry. 43: 6995-7004. PMID 15500337 DOI: 10.1021/Ic0492901  0.78
2004 Ugrinova V, Ellis GA, Brown SN. Remarkable thermodynamic stability toward hydrolysis of tripodal titanium alkoxides. Chemical Communications (Cambridge, England). 468-9. PMID 14765262 DOI: 10.1039/B315092E  0.778
2004 Maestri AG, Taylor SD, Schuck SM, Brown SN. Cleavage of Conjugated Alkenes by Cationic Osmium Nitrides: Scope of the Reaction and Dynamics of the Azaallenium Products Organometallics. 23: 1932-1946. DOI: 10.1021/Om034404M  0.807
2003 Muldoon J, Brown SN. Unsymmetrically bridging aryls of iridium Organometallics. 22: 4480-4489. DOI: 10.1021/Om0304816  0.697
2002 Jacobi BG, Laitar DS, Pu L, Wargocki MF, DiPasquale AG, Fortner KC, Schuck SM, Brown SN. Stoichiometric and catalytic oxygen activation by trimesityliridium(III). Inorganic Chemistry. 41: 4815-23. PMID 12206710 DOI: 10.1021/Ic025700E  0.649
2002 Boon JM, Lambert TN, Smith BD, Beatty AM, Ugrinova V, Brown SN. Structure/activity study of tris(2-aminoethyl)amine-derived translocases for phosphatidylcholine. The Journal of Organic Chemistry. 67: 2168-74. PMID 11925224 DOI: 10.1021/Jo016416S  0.763
2002 Muldoon J, Brown SN. Practical Os/Cu-cocatalyzed air oxidation of allyl and benzyl alcohols at room temperature and atmospheric pressure. Organic Letters. 4: 1043-5. PMID 11893217 DOI: 10.1021/Ol025648Q  0.555
2002 Seymore SB, Brown SN. Polar effects in nitride coupling reactions. Inorganic Chemistry. 41: 462-9. PMID 11825072 DOI: 10.1021/Ic010844Z  0.811
2001 Seymore SB, Brown SN. Synthesis and cleavage reactions of metal-metal-bonded [Mo(2)(S(2)CNR(2))(6)](OTf)(2), a source of the Tris(dithiocarbamato)molybdenum(IV) fragment. Inorganic Chemistry. 40: 6676-83. PMID 11735478 DOI: 10.1021/Ic010673Y  0.81
2001 Maestri AG, Cherry KS, Toboni JJ, Brown SN. [4 + 1] Cycloadditions of cyclohexadienes with osmium nitrides. Journal of the American Chemical Society. 123: 7459-60. PMID 11472192 DOI: 10.1021/Ja016111V  0.739
2000 Brown SN. Oxidative azavinylidene formation in the reaction of 1,3-diphenylisobenzofuran with osmium nitride complexes. Inorganic Chemistry. 39: 378-81. PMID 11272551 DOI: 10.1021/Ic990815C  0.507
2000 Seymore SB, Brown SN. Charge effects on oxygen atom transfer. Inorganic Chemistry. 39: 325-32. PMID 11272542 DOI: 10.1021/Ic990851B  0.802
2000 Butler GM, Brown SN, Boger RM, Ferfolia MT, Fitzgibbons AC, Jongeling AC, Kelleher SJ, Malec AD, Malerich J, Weltner AN. Stereoselective cyclotetramerization of a 3-(Hydroxymethyl)salicylaldehyde Organic Letters. 2: 4125-8. PMID 11150180 DOI: 10.1021/Ol006630N  0.338
1998 Brown SN, Myers AW, Fulton JR, Mayer JM. On the mechanism of C-H bond activation in the photochemical arylation of rhenium (V) oxo iodide complexes Organometallics. 17: 3364-3374. DOI: 10.1021/Om980216Y  0.697
1998 Brown SN, Myers AW, Fulton JR, Mayer JM. On the Mechanism of C−H Bond Activation in the Photochemical Arylation of Rhenium(V) Oxo Iodide Complexes Organometallics. 17: 3364-3374. DOI: 10.1021/om980216y  0.544
1998 Matano Y, Brown SN, Northcutt TO, Mayer JM. Synthesis and reactions of rhenium(V) oxo-hydride complexes Organometallics. 17: 2939-2941. DOI: 10.1021/Om980184E  0.4
1998 Matano Y, Brown SN, Northcutt TO, Mayer JM. Synthesis and Reactions of Rhenium(V) Oxo−Hydride Complexes Organometallics. 17: 2939-2941. DOI: 10.1021/om980184e  0.539
1997 Wilhelm TE, Belderrain TR, Brown SN, Grubbs RH. Reactivity of Ru(H)(H2)Cl(PCy3)2with Propargyl and Vinyl Chlorides:  New Methodology To Give Metathesis-Active Ruthenium Carbenes Organometallics. 16: 3867-3869. DOI: 10.1021/Om9705259  0.536
1996 Brown SN, Mayer JM. Phenyl-to-oxo migration in an electrophilic rhenium(VII) dioxo complex Journal of the American Chemical Society. 118: 12119-12133. DOI: 10.1021/Ja962087N  0.616
1995 Brown SN, Mayer JM. Photochemical Metal-to-Oxo Migrations of Aryl and Alkyl Ligands Organometallics. 14: 2951-2960. DOI: 10.1021/om00006a045  0.526
1995 Brown SN, Mayer JM. Photochemical metal-to-oxo migrations of aryl and alkyl ligands Organometallics. 14: 2951-2960. DOI: 10.1021/Om00006A045  0.416
1995 Brown SN, Mayer JM. Self-Assembly of a Complex Fluorinated Metallacycle from Hexafluoroacetone and Acetonitrile on Aerobic Photolysis of (HB(pz)3)ReO(C2O4) Inorganic Chemistry. 34: 3560-3562. DOI: 10.1021/ic00117a030  0.45
1995 Brown SN, Mayer JM. Self-assembly of a complex fluorinated metallacycle from hexafluoroacetone and acetonitrile on aerobic photolysis of (HBpz3)ReO(C2O4) Inorganic Chemistry. 34: 3560-3562. DOI: 10.1021/Ic00117A030  0.316
1994 Brown SN, Mayer JM. Formation of rhenium phenoxides from arenes via C-H activation and aryl-to-oxo migration Journal of the American Chemical Society. 116: 2219-2220. DOI: 10.1021/Ja00084A102  0.311
1994 Brown SN, Mayer JM. Formation of Rhenium Phenoxides from Arenes Via C-H Activation and Aryl-to-Oxo Migration Journal of the American Chemical Society. 116: 2219-2220. DOI: 10.1021/ja00084a102  0.441
1994 Turowski PN, Armstrong WH, Liu S, Brown SN, Lippard SJ. Synthesis and characterization of hydroxo-bridged diiron(III) complexes containing carboxylate or phosphate ester bridges: comparisons to diiron(III) proteins Inorganic Chemistry. 33: 636-645. DOI: 10.1021/Ic00082A006  0.465
1994 Turowski PN, Armstrong WH, Liu S, Brown SN, Lippard SJ. Synthesis and characterization of hydroxo-bridged diiron(III) complexes containing carboxylate or phosphate ester bridges: Comparisons to diiron(III) proteins Inorganic Chemistry. 33: 636-645.  0.309
1992 Brown SN, Mayer JM. Photochemical generation of a reactive rhenium(III) oxo complex and its curious mode of cleavage of dioxygen Inorganic Chemistry. 31: 4091-4100. DOI: 10.1021/ic00046a020  0.495
1992 Brown SN, Mayer JM. Photochemical generation of a reactive rhenium(III) oxo complex and its curious mode of cleavage of dioxygen Inorganic Chemistry. 31: 4091-4100. DOI: 10.1021/Ic00046A020  0.483
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