Robert H. Crabtree, Ph.D. - Publications

Affiliations: 
Chemistry Yale University, New Haven, CT 
Area:
organometallics, inorganic
Website:
http://www.chem.yale.edu/faculty/crabtree.html

233 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 Lee SH, Matula AJ, Hu G, Troiano J, Karpovich C, Crabtree RH, Batista VS, Brudvig GW. Strongly Coupled Phenazine-Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage. Acs Applied Materials & Interfaces. PMID 30698407 DOI: 10.1021/acsami.8b20996  1
2018 Wang J, Liu Z, Crabtree RH, Frank J, Moore PB. On the damage done to the structure of the T. acidophilum proteasome by electron radiation. Protein Science : a Publication of the Protein Society. PMID 30242932 DOI: 10.1002/pro.3511  0.32
2018 Materna KL, Jiang J, Crabtree RH, Brudvig GW. Silatrane Anchors for Metal Oxide Surfaces: Optimization for Potential Photocatalytic and Electrocatalytic Applications. Acs Applied Materials & Interfaces. PMID 29893542 DOI: 10.1021/acsami.8b04138  1
2018 Shopov DY, Sharninghausen LS, Sinha SB, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH. A Dinuclear Iridium(V,V) Oxo-Bridged Complex Characterized Using a Bulk Electrolysis Technique for Crystallizing Highly Oxidizing Compounds. Inorganic Chemistry. PMID 29634253 DOI: 10.1021/acs.inorgchem.8b00757  1
2017 Materna KL, Jiang J, Regan KP, Schmuttenmaer CA, Crabtree RH, Brudvig G. Optimization of Photoanodes for Photocatalytic Water Oxidation by Combining a Heterogenized Iridium Water-Oxidation Catalyst with a High-Potential Porphyrin Photosensitizer. Chemsuschem. PMID 28876510 DOI: 10.1002/cssc.201701693  1
2017 Sharninghausen LS, Sinha SB, Shopov DY, Mercado BQ, Balcells D, Brudvig GW, Crabtree RH. Synthesis and Characterization of Iridium(V) Coordination Complexes With an N,O-Donor Organic Ligand. Angewandte Chemie (International Ed. in English). 56: 13047-13051. PMID 28815915 DOI: 10.1002/anie.201707593  1
2017 Crabtree RH, Lei A. Introduction: CH Activation. Chemical Reviews. 117: 8481-8482. PMID 28697603 DOI: 10.1021/acs.chemrev.7b00307  0.52
2017 Sinha SB, Shopov DY, Sharninghausen LS, Stein CJ, Mercado BQ, Balcells D, Pedersen TB, Reiher M, Brudvig GW, Crabtree RH. Redox Activity of Oxo-Bridged Iridium Dimers in an N,O-Donor Environment: Characterization of Remarkably Stable Ir(IV,V) Complexes. Journal of the American Chemical Society. 139: 9672-9683. PMID 28648068 DOI: 10.1021/jacs.7b04874  1
2017 Materna KL, Crabtree RH, Brudvig GW. Anchoring groups for photocatalytic water oxidation on metal oxide surfaces. Chemical Society Reviews. PMID 28640299 DOI: 10.1039/c7cs00314e  1
2017 Jiang J, Materna K, Hedström S, Yang K, Crabtree R, Batista V, Brudvig G. Molecular Antimony Complexes for Electrocatalysis: Activity of a Main Group Element in Proton Reduction. Angewandte Chemie (International Ed. in English). PMID 28628943 DOI: 10.1002/anie.201704700  0.88
2017 Shopov DY, Rudshteyn B, Campos J, Vinyard DJ, Batista VS, Brudvig GW, Crabtree RH. A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties. Chemical Science. 8: 1642-1652. PMID 28451293 DOI: 10.1039/c6sc03758e  1
2017 Michaelos TK, Shopov DY, Sinha SB, Sharninghausen LS, Fisher KJ, Lant HM, Crabtree RH, Brudvig GW. A Pyridine Alkoxide Chelate Ligand That Promotes Both Unusually High Oxidation States and Water-Oxidation Catalysis. Accounts of Chemical Research. PMID 28272869 DOI: 10.1021/acs.accounts.6b00652  1
2016 Sharninghausen LS, Sinha SB, Shopov DY, Choi B, Mercado BQ, Roy X, Balcells D, Brudvig GW, Crabtree RH. High Oxidation State Iridium Mono-μ-oxo Dimers Related to Water Oxidation Catalysis. Journal of the American Chemical Society. 138: 15917-15926. PMID 27960326 DOI: 10.1021/jacs.6b07716  1
2016 Koepf M, Koenigsmann C, Ding W, Batra A, Negre CF, Venkataraman L, Brudvig GW, Batista VS, Schmuttenmaer CA, Crabtree RH. Controlling the rectification properties of molecular junctions through molecule-electrode coupling. Nanoscale. 8: 16357-16362. PMID 27722662 DOI: 10.1039/c6nr04830g  1
2016 Jiang J, Crabtree RH, Brudvig GW. One-Step Trimethylstannylation of Benzyl and Alkyl Halides. The Journal of Organic Chemistry. PMID 27643532 DOI: 10.1021/acs.joc.6b01883  1
2016 Bloomfield AJ, Matula AJ, Mercado BQ, Batista VS, Crabtree RH. Organometallic Iridium Complex Containing a Dianionic, Tridentate, Mixed Organic-Inorganic Ligand. Inorganic Chemistry. 55: 8121-9. PMID 27462911 DOI: 10.1021/acs.inorgchem.6b01218  1
2016 Jiang J, Swierk JR, Hedström S, Matula AJ, Crabtree RH, Batista VS, Schmuttenmaer CA, Brudvig GW. Molecular design of light-harvesting photosensitizers: effect of varied linker conjugation on interfacial electron transfer. Physical Chemistry Chemical Physics : Pccp. 18: 18678-82. PMID 27364769 DOI: 10.1039/c6cp04377a  1
2016 Yang KR, Matula AJ, Kwon G, Hong J, Sheehan SW, Thomsen JM, Brudvig GW, Crabtree RH, Tiede DM, Chen LX, Batista VS. Solution Structures of Highly Active Molecular Ir Water-Oxidation Catalysts from Density Functional Theory Combined with High-Energy X-Ray Scattering and EXAFS Spectroscopy. Journal of the American Chemical Society. PMID 27087202 DOI: 10.1021/jacs.6b01750  1
2016 Huang DL, Beltrán-Suito R, Thomsen JM, Hashmi SM, Materna KL, Sheehan SW, Mercado BQ, Brudvig GW, Crabtree RH. New Ir Bis-Carbonyl Precursor for Water Oxidation Catalysis. Inorganic Chemistry. 55: 2427-35. PMID 26901517 DOI: 10.1021/acs.inorgchem.5b02809  1
2016 Brennan BJ, Chen J, Rudshteyn B, Chaudhuri S, Mercado BQ, Batista VS, Crabtree RH, Brudvig GW. Molecular titanium-hydroxamate complexes as models for TiO2 surface binding. Chemical Communications (Cambridge, England). 52: 2972-5. PMID 26781247 DOI: 10.1039/c5cc09857b  1
2015 Ding W, Koepf M, Koenigsmann C, Batra A, Venkataraman L, Negre CF, Brudvig GW, Crabtree RH, Schmuttenmaer CA, Batista VS. Computational Design of Intrinsic Molecular Rectifiers Based on Asymmetric Functionalization of N-Phenylbenzamide. Journal of Chemical Theory and Computation. 11: 5888-96. PMID 26642992 DOI: 10.1021/acs.jctc.5b00823  1
2015 Sinha SB, Shopov DY, Sharninghausen LS, Vinyard DJ, Mercado BQ, Brudvig GW, Crabtree RH. A Stable Coordination Complex of Rh(IV) in an N,O-Donor Environment. Journal of the American Chemical Society. 137: 15692-5. PMID 26641941 DOI: 10.1021/jacs.5b12148  1
2015 Sharninghausen LS, Mercado BQ, Crabtree RH, Balcells D, Campos J. Gel-assisted crystallization of [Ir4(IMe)7(CO)H10](2+) and [Ir4(IMe)8H9](3+) clusters derived from catalytic glycerol dehydrogenation. Dalton Transactions (Cambridge, England : 2003). 44: 18403-10. PMID 26435314 DOI: 10.1039/c5dt03302k  0.84
2015 Sharninghausen LS, Mercado BQ, Crabtree RH, Hazari N. Selective conversion of glycerol to lactic acid with iron pincer precatalysts. Chemical Communications (Cambridge, England). 51: 16201-4. PMID 26399400 DOI: 10.1039/c5cc06857f  1
2015 Koepf M, Lee SH, Brennan BJ, Méndez-Hernández DD, Batista VS, Brudvig GW, Crabtree RH. Preparation of Halogenated Fluorescent Diaminophenazine Building Blocks. The Journal of Organic Chemistry. PMID 26390117 DOI: 10.1021/acs.joc.5b01339  1
2015 Blakemore JD, Crabtree RH, Brudvig GW. Molecular Catalysts for Water Oxidation. Chemical Reviews. PMID 26151088 DOI: 10.1021/acs.chemrev.5b00122  1
2015 Shopov DY, Rudshteyn B, Campos J, Batista VS, Crabtree RH, Brudvig GW. Stable Iridium(IV) Complexes of an Oxidation-Resistant Pyridine-Alkoxide Ligand: Highly Divergent Redox Properties Depending on the Isomeric Form Adopted. Journal of the American Chemical Society. 137: 7243-50. PMID 25988658 DOI: 10.1021/jacs.5b04185  1
2015 Thomsen JM, Huang DL, Crabtree RH, Brudvig GW. Iridium-based complexes for water oxidation. Dalton Transactions (Cambridge, England : 2003). PMID 25978192 DOI: 10.1039/c5dt00863h  1
2015 Brennan BJ, Durrell AC, Koepf M, Crabtree RH, Brudvig GW. Towards multielectron photocatalysis: a porphyrin array for lateral hole transfer and capture on a metal oxide surface. Physical Chemistry Chemical Physics : Pccp. 17: 12728-34. PMID 25904199 DOI: 10.1039/c5cp01683e  1
2015 Sheehan SW, Thomsen JM, Hintermair U, Crabtree RH, Brudvig GW, Schmuttenmaer CA. A molecular catalyst for water oxidation that binds to metal oxide surfaces. Nature Communications. 6: 6469. PMID 25757425 DOI: 10.1038/ncomms7469  1
2015 Campos J, Sharninghausen LS, Manas MG, Crabtree RH. Methanol dehydrogenation by iridium N-heterocyclic carbene complexes. Inorganic Chemistry. 54: 5079-84. PMID 25615426 DOI: 10.1021/ic502521c  1
2015 Crabtree RH. Deactivation in homogeneous transition metal catalysis: causes, avoidance, and cure. Chemical Reviews. 115: 127-50. PMID 25493420 DOI: 10.1021/cr5004375  1
2015 Manas MG, Campos J, Sharninghausen LS, Lin E, Crabtree RH. Selective catalytic oxidation of sugar alcohols to lactic acid Green Chemistry. 17: 594-600. DOI: 10.1039/c4gc01694g  0.88
2015 Manas MG, Sharninghausen LS, Lin E, Crabtree RH. Iridium catalyzed reversible dehydrogenation - Hydrogenation of quinoline derivatives under mild conditions Journal of Organometallic Chemistry. DOI: 10.1016/j.jorganchem.2015.04.015  1
2015 Crabtree RH. A. E. Shilov's influence on early work in organometallic CH activation and functionalization Journal of Organometallic Chemistry. DOI: 10.1016/j.jorganchem.2015.02.031  1
2014 Negre CF, Young KJ, Oviedo MB, Allen LJ, Sánchez CG, Jarzembska KN, Benedict JB, Crabtree RH, Coppens P, Brudvig GW, Batista VS. Photoelectrochemical hole injection revealed in polyoxotitanate nanocrystals functionalized with organic adsorbates. Journal of the American Chemical Society. 136: 16420-9. PMID 25337894 DOI: 10.1021/ja509270f  1
2014 Sharninghausen LS, Campos J, Manas MG, Crabtree RH. Efficient selective and atom economic catalytic conversion of glycerol to lactic acid. Nature Communications. 5: 5084. PMID 25278373 DOI: 10.1038/ncomms6084  1
2014 Campos J, Sharninghausen LS, Crabtree RH, Balcells D. A carbene-rich but carbonyl-poor [Ir6 (IMe)8 (CO)2 H14 ](2+) polyhydride cluster as a deactivation product from catalytic glycerol dehydrogenation. Angewandte Chemie (International Ed. in English). 53: 12808-11. PMID 25252028 DOI: 10.1002/anie.201407997  1
2014 Thomsen JM, Sheehan SW, Hashmi SM, Campos J, Hintermair U, Crabtree RH, Brudvig GW. Electrochemical activation of Cp* iridium complexes for electrode-driven water-oxidation catalysis. Journal of the American Chemical Society. 136: 13826-34. PMID 25188635 DOI: 10.1021/ja5068299  1
2014 Koenigsmann C, Ripolles TS, Brennan BJ, Negre CF, Koepf M, Durrell AC, Milot RL, Torre JA, Crabtree RH, Batista VS, Brudvig GW, Bisquert J, Schmuttenmaer CA. Substitution of a hydroxamic acid anchor into the MK-2 dye for enhanced photovoltaic performance and water stability in a DSSC. Physical Chemistry Chemical Physics : Pccp. 16: 16629-41. PMID 24993024 DOI: 10.1039/c4cp02405b  1
2014 Ding W, Negre CF, Palma JL, Durrell AC, Allen LJ, Young KJ, Milot RL, Schmuttenmaer CA, Brudvig GW, Crabtree RH, Batista VS. Linker rectifiers for covalent attachment of transition-metal catalysts to metal-oxide surfaces. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 15: 1138-47. PMID 24668518 DOI: 10.1002/cphc.201400063  1
2014 Huang J, Blakemore JD, Fazi D, Kokhan O, Schley ND, Crabtree RH, Brudvig GW, Tiede DM. Domain structure for an amorphous iridium-oxide water-oxidation catalyst characterized by X-ray pair distribution function analysis. Physical Chemistry Chemical Physics : Pccp. 16: 1814-9. PMID 24336574 DOI: 10.1039/c3cp54878c  1
2014 Ingram AJ, Wolk AB, Flender C, Zhang J, Johnson CJ, Hintermair U, Crabtree RH, Johnson MA, Zare RN. Modes of activation of organometallic iridium complexes for catalytic water and C-H oxidation. Inorganic Chemistry. 53: 423-33. PMID 24228617 DOI: 10.1021/ic402390t  1
2014 Sinha SB, Campos J, Brudvig GW, Crabtree RH. Co(ii), a catalyst for selective conversion of phenyl rings to carboxylic acid groups Rsc Advances. 4: 49395-49399. DOI: 10.1039/c4ra10510a  1
2014 Campos J, Goforth SK, Crabtree RH, Gunnoe TB. Metal-free amidation of ether sp3 C-H bonds with sulfonamides using PhI(OAc)2 Rsc Advances. 4: 47951-47957. DOI: 10.1039/c4ra09665g  1
2014 Manas MG, Sharninghausen LS, Balcells D, Crabtree RH. Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of C=O and C=N functionalities including esters, amides and heteroarenes New Journal of Chemistry. 38: 1694-1700. DOI: 10.1039/c3nj01485a  1
2014 Bloomfield AJ, Sheehan SW, Collom SL, Crabtree RH, Anastas PT. A heterogeneous water oxidation catalyst from dicobalt octacarbonyl and 1,2-bis(diphenylphosphino)ethane New Journal of Chemistry. 38: 1540-1545. DOI: 10.1039/c3nj01298k  1
2014 Chen J, Campos J, Mercado BQ, Crabtree RH, Balcells D. Distortional effects of noncovalent interactions in the crystal lattice of a Cp∗Ir(III) acylhydroxamic acid complex: A joint experimental-computational study Organometallics. 33: 4417-4424. DOI: 10.1021/om500625c  1
2014 Campos J, Hintermair U, Brewster TP, Takase MK, Crabtree RH. Catalyst activation by loss of cyclopentadienyl ligands in hydrogen transfer catalysis with Cp*IrIII complexes Acs Catalysis. 4: 973-985. DOI: 10.1021/cs401138f  1
2014 Hintermair U, Campos J, Brewster TP, Pratt LM, Schley ND, Crabtree RH. Hydrogen-transfer catalysis with Cp*IrIII complexes: The influence of the ancillary ligands Acs Catalysis. 4: 99-108. DOI: 10.1021/cs400834q  1
2014 Luca OR, Konezny SJ, Hunsinger GB, Müller P, Takase MK, Crabtree RH. Ni complexes of redox-active pincers with pendant H-bonding sites as precursors for hydrogen production electrocatalysis Polyhedron. 82: 2-6. DOI: 10.1016/j.poly.2013.12.003  1
2014 Crabtree RH. The stability of organometallic ligands in oxidation catalysis Journal of Organometallic Chemistry. 751: 174-180. DOI: 10.1016/j.jorganchem.2013.07.061  1
2014 Durrell AC, Li G, Koepf M, Young KJ, Negre CFA, Allen LJ, McNamara WR, Song HE, Batista VS, Crabtree RH, Brudvig GW. Photoelectrochemical oxidation of a turn-on fluorescent probe mediated by a surface MnII catalyst covalently attached to TiO2 nanoparticles Journal of Catalysis. 310: 37-44. DOI: 10.1016/j.jcat.2013.07.001  1
2014 Crabtree RH. The Organometallic Chemistry of the Transition Metals: Sixth Edition The Organometallic Chemistry of the Transition Metals: Sixth Edition. 1-504. DOI: 10.1002/9781118788301  1
2013 Graeupner J, Hintermair U, Huang DL, Thomsen JM, Takase M, Campos J, Hashmi SM, Elimelech M, Brudvig GW, Crabtree RH. Probing the Viability of Oxo-Coupling Pathways in Iridium-Catalyzed Oxygen Evolution. Organometallics. 32: 5384-5390. PMID 24474842 DOI: 10.1021/om400658a  1
2013 Habib F, Luca OR, Vieru V, Shiddiq M, Korobkov I, Gorelsky SI, Takase MK, Chibotaru LF, Hill S, Crabtree RH, Murugesu M. Influence of the ligand field on slow magnetization relaxation versus spin crossover in mononuclear cobalt complexes. Angewandte Chemie (International Ed. in English). 52: 11290-3. PMID 24009214 DOI: 10.1002/anie.201303005  1
2013 Hintermair U, Sheehan SW, Parent AR, Ess DH, Richens DT, Vaccaro PH, Brudvig GW, Crabtree RH. Precursor transformation during molecular oxidation catalysis with organometallic iridium complexes. Journal of the American Chemical Society. 135: 10837-51. PMID 23822646 DOI: 10.1021/ja4048762  1
2013 Brewster TP, Konezny SJ, Sheehan SW, Martini LA, Schmuttenmaer CA, Batista VS, Crabtree RH. Hydroxamate anchors for improved photoconversion in dye-sensitized solar cells. Inorganic Chemistry. 52: 6752-64. PMID 23687967 DOI: 10.1021/ic4010856  1
2013 Luca OR, Konezny SJ, Paulson EK, Habib F, Luthy KM, Murugesu M, Crabtree RH, Batista VS. Study of an S = 1 Ni(II) pincer electrocatalyst precursor for aqueous hydrogen production based on paramagnetic 1H NMR. Dalton Transactions (Cambridge, England : 2003). 42: 8802-7. PMID 23640289 DOI: 10.1039/c3dt50528f  1
2013 Crabtree RH. How far have we come? Dalton Transactions (Cambridge, England : 2003). 42: 4104. PMID 23423563 DOI: 10.1039/c3dt90013d  1
2013 Blakemore JD, Mara MW, Kushner-Lenhoff MN, Schley ND, Konezny SJ, Rivalta I, Negre CF, Snoeberger RC, Kokhan O, Huang J, Stickrath A, Tran LA, Parr ML, Chen LX, Tiede DM, ... ... Crabtree RH, et al. Characterization of an amorphous iridium water-oxidation catalyst electrodeposited from organometallic precursors. Inorganic Chemistry. 52: 1860-71. PMID 23383971 DOI: 10.1021/ic301968j  1
2013 Kushner-Lenhoff MN, Blakemore JD, Schley ND, Crabtree RH, Brudvig GW. Effects of aqueous buffers on electrocatalytic water oxidation with an iridium oxide material electrodeposited in thin layers from an organometallic precursor. Dalton Transactions (Cambridge, England : 2003). 42: 3617-22. PMID 23292194 DOI: 10.1039/c2dt32326e  1
2013 Luca OR, Crabtree RH. Redox-active ligands in catalysis. Chemical Society Reviews. 42: 1440-59. PMID 22975722 DOI: 10.1039/c2cs35228a  1
2013 Parent AR, Crabtree RH, Brudvig GW. Comparison of primary oxidants for water-oxidation catalysis. Chemical Society Reviews. 42: 2247-52. PMID 22975690 DOI: 10.1039/c2cs35225g  1
2013 Luca OR, Huang DL, Takase MK, Crabtree RH. Redox-active cyclopentadienyl Ni complexes with quinoid N-heterocyclic carbene ligands for the electrocatalytic hydrogen release from chemical fuels New Journal of Chemistry. 37: 3402-3405. DOI: 10.1039/c3nj00276d  1
2013 Eisenstein O, Crabtree RH. Outer sphere hydrogenation catalysis New Journal of Chemistry. 37: 21-27. DOI: 10.1039/c2nj40659d  1
2013 McKeown BA, Gonzalez HE, Michaelos T, Gunnoe TB, Cundari TR, Crabtree RH, Sabat M. Control of olefin hydroarylation catalysis via a sterically and electronically flexible platinum(II) catalyst scaffold Organometallics. 32: 3903-3913. DOI: 10.1021/om400390e  1
2013 Manas MG, Graeupner J, Allen LJ, Dobereiner GE, Rippy KC, Hazari N, Crabtree RH. Hydrogenation of quinaldine and benzylic aldehydes both separately and combined in a tandem hydrogenation-reductive alkylation of quinaldine by aldehydes with iridium benzoquinoline catalysts Organometallics. 32: 4501-4506. DOI: 10.1021/om400267n  1
2013 Zhou M, Hintermair U, Hashiguchi BG, Parent AR, Hashmi SM, Elimelech M, Periana RA, Brudvig GW, Crabtree RH. Cp* iridium precatalysts for selective C-h oxidation with sodium periodate as the terminal oxidant Organometallics. 32: 957-965. DOI: 10.1021/om301252w  1
2013 Negre CFA, Milot RL, Martini LA, Ding W, Crabtree RH, Schmuttenmaer CA, Batista VS. Efficiency of interfacial electron transfer from Zn-porphyrin dyes into TiO2 correlated to the linker single molecule conductance Journal of Physical Chemistry C. 117: 24462-24470. DOI: 10.1021/jp408738b  1
2013 Milot RL, Moore GF, Crabtree RH, Brudvig GW, Schmuttenmaer CA. Electron injection dynamics from photoexcited porphyrin dyes into SnO 2 and TiO2 nanoparticles Journal of Physical Chemistry C. 117: 21662-21670. DOI: 10.1021/jp406734t  1
2013 Martini LA, Moore GF, Milot RL, Cai LZ, Sheehan SW, Schmuttenmaer CA, Brudvig GW, Crabtree RH. Modular assembly of high-potential zinc porphyrin photosensitizers attached to TiO2 with a series of anchoring groups Journal of Physical Chemistry C. 117: 14526-14533. DOI: 10.1021/jp4053456  1
2013 Collom SL, Anastas PT, Beach ES, Crabtree RH, Hazari N, Sommer TJ. Differing selectivities in mechanochemical versus conventional solution oxidation using Oxone Tetrahedron Letters. 54: 2344-2347. DOI: 10.1016/j.tetlet.2013.02.056  1
2013 Luca OR, Thompson BA, Takase MK, Crabtree RH. Synthesis and electrochemistry of a series of cyclopentadienyl Ni N-heterocyclic carbene compounds Journal of Organometallic Chemistry. 730: 79-83. DOI: 10.1016/j.jorganchem.2012.10.038  1
2013 Crabtree RH. Abnormal, mesoionic and remote N-heterocyclic carbene complexes Coordination Chemistry Reviews. 257: 755-766. DOI: 10.1016/j.ccr.2012.09.006  1
2012 Young KJ, Martini LA, Milot RL, Iii RC, Batista VS, Schmuttenmaer CA, Crabtree RH, Brudvig GW. Light-driven water oxidation for solar fuels. Coordination Chemistry Reviews. 256: 2503-2520. PMID 25364029 DOI: 10.1016/j.ccr.2012.03.031  1
2012 Graeupner J, Brewster TP, Blakemore JD, Schley ND, Thomsen JM, Brudvig GW, Hazari N, Crabtree RH. Electron-Rich CpIr(biphenyl-2,2'-diyl) Complexes with π-Accepting Carbon Donor Ligands. Organometallics. 31: 7158-7164. PMID 24474841 DOI: 10.1021/om300696t  1
2012 Schley ND, Halbert S, Raynaud C, Eisenstein O, Crabtree RH. Symmetrical hydrogen bonds in iridium(III) alkoxides with relevance to outer sphere hydrogen transfer. Inorganic Chemistry. 51: 12313-23. PMID 23106391 DOI: 10.1021/ic301601c  1
2012 Dobereiner GE, Wu J, Manas MG, Schley ND, Takase MK, Crabtree RH, Hazari N, Maseras F, Nova A. Mild, reversible reaction of iridium(III) amido complexes with carbon dioxide. Inorganic Chemistry. 51: 9683-93. PMID 22928527 DOI: 10.1021/ic300923c  1
2012 Luca OR, Blakemore JD, Konezny SJ, Praetorius JM, Schmeier TJ, Hunsinger GB, Batista VS, Brudvig GW, Hazari N, Crabtree RH. Organometallic Ni pincer complexes for the electrocatalytic production of hydrogen. Inorganic Chemistry. 51: 8704-9. PMID 22849660 DOI: 10.1021/ic300009a  1
2012 Garand E, Fournier JA, Kamrath MZ, Schley ND, Crabtree RH, Johnson MA. Characterization of an activated iridium water splitting catalyst using infrared photodissociation of H2 tagged ions. Physical Chemistry Chemical Physics : Pccp. 14: 10109-13. PMID 22735550 DOI: 10.1039/c2cp41490b  1
2012 Blakemore JD, Schley ND, Kushner-Lenhoff MN, Winter AM, D'Souza F, Crabtree RH, Brudvig GW. Comparison of amorphous iridium water-oxidation electrocatalysts prepared from soluble precursors. Inorganic Chemistry. 51: 7749-63. PMID 22725667 DOI: 10.1021/ic300764f  1
2012 Sokolow JD, Trzop E, Chen Y, Tang J, Allen LJ, Crabtree RH, Benedict JB, Coppens P. Binding modes of carboxylate- and acetylacetonate-linked chromophores to homodisperse polyoxotitanate nanoclusters. Journal of the American Chemical Society. 134: 11695-700. PMID 22709348 DOI: 10.1021/ja303692r  1
2012 Hintermair U, Hashmi SM, Elimelech M, Crabtree RH. Particle formation during oxidation catalysis with Cp* iridium complexes. Journal of the American Chemical Society. 134: 9785-95. PMID 22594951 DOI: 10.1021/ja3033026  1
2012 Parent AR, Brewster TP, De Wolf W, Crabtree RH, Brudvig GW. Sodium periodate as a primary oxidant for water-oxidation catalysts. Inorganic Chemistry. 51: 6147-52. PMID 22587015 DOI: 10.1021/ic300154x  1
2012 Vagnini MT, Smeigh AL, Blakemore JD, Eaton SW, Schley ND, D'Souza F, Crabtree RH, Brudvig GW, Co DT, Wasielewski MR. Ultrafast photodriven intramolecular electron transfer from an iridium-based water-oxidation catalyst to perylene diimide derivatives. Proceedings of the National Academy of Sciences of the United States of America. 109: 15651-6. PMID 22586073 DOI: 10.1073/pnas.1202075109  1
2012 Blakemore JD, Hull JF, Crabtree RH, Brudvig GW. Aqueous speciation and electrochemical properties of a water-soluble manganese phthalocyanine complex. Dalton Transactions (Cambridge, England : 2003). 41: 7681-8. PMID 22585306 DOI: 10.1039/c2dt30371j  1
2012 Snoeberger RC, Young KJ, Tang J, Allen LJ, Crabtree RH, Brudvig GW, Coppens P, Batista VS, Benedict JB. Interfacial electron transfer into functionalized crystalline polyoxotitanate nanoclusters. Journal of the American Chemical Society. 134: 8911-7. PMID 22548416 DOI: 10.1021/ja301238t  1
2012 Gao Y, Crabtree RH, Brudvig GW. Water oxidation catalyzed by the tetranuclear Mn complex [Mn(IV)4O5(terpy)4(H2O)2](ClO4)6. Inorganic Chemistry. 51: 4043-50. PMID 22435651 DOI: 10.1021/ic2021897  1
2012 Guard LM, Palma JL, Stratton WP, Allen LJ, Brudvig GW, Crabtree RH, Batista VS, Hazari N. Synthesis and computational studies of Mg complexes supported by 2,2':6,2''-terpyridine ligands. Dalton Transactions (Cambridge, England : 2003). 41: 8098-110. PMID 22430933 DOI: 10.1039/c2dt12426b  1
2012 Araujo CM, Doherty MD, Konezny SJ, Luca OR, Usyatinsky A, Grade H, Lobkovsky E, Soloveichik GL, Crabtree RH, Batista VS. Tuning redox potentials of bis(imino)pyridine cobalt complexes: an experimental and theoretical study involving solvent and ligand effects. Dalton Transactions (Cambridge, England : 2003). 41: 3562-73. PMID 22318461 DOI: 10.1039/c2dt12195f  1
2012 Crabtree RH. Resolving heterogeneity problems and impurity artifacts in operationally homogeneous transition metal catalysts. Chemical Reviews. 112: 1536-54. PMID 22023323 DOI: 10.1021/cr2002905  1
2012 Batista VS, Crabtree RH, Konezny SJ, Luca OR, Praetorius JM. Oxidative functionalization of benzylic C-H bonds by DDQ New Journal of Chemistry. 36: 1141-1144. DOI: 10.1039/c2nj40021a  1
2012 Luca OR, Konezny SJ, Blakemore JD, Colosi DM, Saha S, Brudvig GW, Batista VS, Crabtree RH. A tridentate Ni pincer for aqueous electrocatalytic hydrogen production New Journal of Chemistry. 36: 1149-1152. DOI: 10.1039/c2nj20912h  1
2012 Araujo CM, Simone DL, Konezny SJ, Shim A, Crabtree RH, Soloveichik GL, Batista VS. Fuel selection for a regenerative organic fuel cell/flow battery: Thermodynamic considerations Energy and Environmental Science. 5: 9534-9542. DOI: 10.1039/c2ee22749e  1
2012 Konezny SJ, Doherty MD, Luca OR, Crabtree RH, Soloveichik GL, Batista VS. Reduction of systematic uncertainty in DFT redox potentials of transition-metal complexes Journal of Physical Chemistry C. 116: 6349-6356. DOI: 10.1021/jp300485t  1
2012 Moore GF, Konezny SJ, Song HE, Milot RL, Blakemore JD, Lee ML, Batista VS, Schmuttenmaer CA, Crabtree RH, Brudvig GW. Bioinspired high-potential porphyrin photoanodes Journal of Physical Chemistry C. 116: 4892-4902. DOI: 10.1021/jp210096m  1
2012 Zhou M, Balcells D, Parent AR, Crabtree RH, Eisenstein O. Cp* iridium precatalysts for selective C-H oxidation via direct oxygen insertion: A joint experimental/computational study Acs Catalysis. 2: 208-218. DOI: 10.1021/cs2005899  1
2011 Brewster TP, Ding W, Schley ND, Hazari N, Batista VS, Crabtree RH. Thiocyanate linkage isomerism in a ruthenium polypyridyl complex. Inorganic Chemistry. 50: 11938-46. PMID 22066656 DOI: 10.1021/ic200950e  1
2011 Parent AR, Blakemore JD, Brudvig GW, Crabtree RH. Wilkinson's iridium acetate trimer as a water-oxidation catalyst. Chemical Communications (Cambridge, England). 47: 11745-7. PMID 21952476 DOI: 10.1039/c1cc15501f  1
2011 Schley ND, Blakemore JD, Subbaiyan NK, Incarvito CD, D'Souza F, Crabtree RH, Brudvig GW. Distinguishing homogeneous from heterogeneous catalysis in electrode-driven water oxidation with molecular iridium complexes. Journal of the American Chemical Society. 133: 10473-81. PMID 21671679 DOI: 10.1021/ja2004522  1
2011 Schmeier TJ, Dobereiner GE, Crabtree RH, Hazari N. Secondary coordination sphere interactions facilitate the insertion step in an iridium(III) CO2 reduction catalyst. Journal of the American Chemical Society. 133: 9274-7. PMID 21612297 DOI: 10.1021/ja2035514  1
2011 Xiao D, Martini LA, Snoeberger RC, Crabtree RH, Batista VS. Inverse design and synthesis of acac-coumarin anchors for robust TiO2 sensitization. Journal of the American Chemical Society. 133: 9014-22. PMID 21553881 DOI: 10.1021/ja2020313  1
2011 Dobereiner GE, Nova A, Schley ND, Hazari N, Miller SJ, Eisenstein O, Crabtree RH. Iridium-catalyzed hydrogenation of N-heterocyclic compounds under mild conditions by an outer-sphere pathway. Journal of the American Chemical Society. 133: 7547-62. PMID 21510610 DOI: 10.1021/ja2014983  1
2011 Zhou M, Crabtree RH. C-H oxidation by platinum group metal oxo or peroxo species. Chemical Society Reviews. 40: 1875-84. PMID 21240429 DOI: 10.1039/c0cs00099j  1
2011 Arunan E, Desiraju GR, Klein RA, Sadlej J, Scheiner S, Alkorta I, Clary DC, Crabtree RH, Dannenberg JJ, Hobza P, Kjaergaard HG, Legon AC, Mennucci B, Nesbitt DJ. Defining the hydrogen bond: An account (IUPAC Technical Report) Pure and Applied Chemistry. 83: 1619-1636. DOI: 10.1351/PAC-REP-10-01-01  1
2011 Arunan E, Desiraju GR, Klein RA, Sadlej J, Scheiner S, Alkorta I, Clary DC, Crabtree RH, Dannenber JJ, Hobza P, Kjaergaard HG, Legon AC, Mennucci B, Nesbitt DJ. Definition of the hydrogen bond (IUPAC Recommendations 2011) Pure and Applied Chemistry. 83: 1637-1641. DOI: 10.1351/PAC-REC-10-01-02  1
2011 Driscoll PF, Deunf E, Rubin L, Luca O, Crabtree R, Chidsey C, Arnold J, Kerr JB. Redox catalysis for dehydrogenation of liquid hydrogen carrier fuels for energy storage and conversion Ecs Transactions. 35: 3-17. DOI: 10.1149/1.3641814  1
2011 Moore GF, Blakemore JD, Milot RL, Hull JF, Song HE, Cai L, Schmuttenmaer CA, Crabtree RH, Brudvig GW. A visible light water-splitting cell with a photoanode formed by codeposition of a high-potential porphyrin and an iridium water-oxidation catalyst Energy and Environmental Science. 4: 2389-2392. DOI: 10.1039/c1ee01037a  1
2011 Blakemore JD, Schley ND, Olack GW, Incarvito CD, Brudvig GW, Crabtree RH. Anodic deposition of a robust iridium-based water-oxidation catalyst from organometallic precursors Chemical Science. 2: 94-98. DOI: 10.1039/c0sc00418a  1
2011 Luca OR, Wang T, Konezny SJ, Batista VS, Crabtree RH. DDQ as an electrocatalyst for amine dehydrogenation, a model system for virtual hydrogen storage New Journal of Chemistry. 35: 998-999. DOI: 10.1039/c0nj01011a  1
2011 Crabtree RH. Multifunctional ligands in transition metal catalysis New Journal of Chemistry. 35: 18-23. DOI: 10.1039/c0nj00776e  1
2011 Schley ND, Dobereiner GE, Crabtree RH. Oxidative synthesis of amides and pyrroles via dehydrogenative alcohol oxidation by ruthenium diphosphine diamine complexes Organometallics. 30: 4174-4179. DOI: 10.1021/om2004755  1
2011 Brewster TP, Blakemore JD, Schley ND, Incarvito CD, Hazari N, Brudvig GW, Crabtree RH. An iridium(IV) species, [Cp*Ir(NHC)Cl]+, related to a water-oxidation catalyst Organometallics. 30: 965-973. DOI: 10.1021/om101016s  1
2011 Crabtree RH. An organometallic future in green and energy chemistry? Organometallics. 30: 17-19. DOI: 10.1021/om1009439  1
2011 Crabtree RH. Introduction and history Topics in Organometallic Chemistry. 34: 1-10. DOI: 10.1007/978-3-642-15334-1_1  1
2011 Zhou M, Crabtree RH, Eisenstein O, Balcells D, Schley ND. Cp*Ir complexes in catalytic alkane hydroxylation Acs National Meeting Book of Abstracts 1
2011 Palma JL, Kim KE, Stratton WP, Brudvig GW, Crabtree RH, Hazari N, Batista VS. Biomimetic CO2 reduction based on Mg complexes Acs National Meeting Book of Abstracts 1
2010 Crabtree RH. Chemistry. Creating ligands with multiple personalities. Science (New York, N.Y.). 330: 455-6. PMID 20966237 DOI: 10.1126/science.1197652  1
2010 Blakemore JD, Schley ND, Balcells D, Hull JF, Olack GW, Incarvito CD, Eisenstein O, Brudvig GW, Crabtree RH. Half-sandwich iridium complexes for homogeneous water-oxidation catalysis. Journal of the American Chemical Society. 132: 16017-29. PMID 20964386 DOI: 10.1021/ja104775j  1
2010 Song G, Chen D, Pan CL, Crabtree RH, Li X. Rh-catalyzed oxidative coupling between primary and secondary benzamides and alkynes: synthesis of polycyclic amides. The Journal of Organic Chemistry. 75: 7487-90. PMID 20923219 DOI: 10.1021/jo101596d  1
2010 Zhou M, Schley ND, Crabtree RH. Cp* iridium complexes give catalytic alkane hydroxylation with retention of stereochemistry. Journal of the American Chemical Society. 132: 12550-1. PMID 20731395 DOI: 10.1021/ja1058247  1
2010 Hull JF, Balcells D, Sauer EL, Raynaud C, Brudvig GW, Crabtree RH, Eisenstein O. Manganese catalysts for C-H activation: an experimental/theoretical study identifies the stereoelectronic factor that controls the switch between hydroxylation and desaturation pathways. Journal of the American Chemical Society. 132: 7605-16. PMID 20481432 DOI: 10.1021/ja908744w  1
2010 Cady CW, Shinopoulos KE, Crabtree RH, Brudvig GW. [(H2O)(terpy)Mn(mu-O)2Mn(terpy)(OH2)](NO3)3 (terpy = 2,2':6,2''-terpyridine) and its relevance to the oxygen-evolving complex of photosystem II examined through pH dependent cyclic voltammetry. Dalton Transactions (Cambridge, England : 2003). 39: 3985-9. PMID 20372724 DOI: 10.1039/b922087a  1
2010 Crabtree RH. Introduction to selective functionalization of C-H bonds. Chemical Reviews. 110: 575. PMID 20143875 DOI: 10.1021/cr900388d  1
2010 Song G, Su Y, Periana RA, Crabtree RH, Han K, Zhang H, Li X. Anion-exchange-triggered 1,3-shift of an NH proton to iridium in protic n-heterocyclic carbenes: hydrogen-bonding and ion-pairing effects. Angewandte Chemie (International Ed. in English). 49: 912-7. PMID 20039244 DOI: 10.1002/anie.200905691  1
2010 Dobereiner GE, Crabtree RH. Dehydrogenation as a substrate-activating strategy in homogeneous transition-metal catalysis. Chemical Reviews. 110: 681-703. PMID 19938813 DOI: 10.1021/cr900202j  1
2010 Li G, Sproviero EM, McNamara WR, Snoeberger RC, Crabtree RH, Brudvig GW, Batista VS. Reversible visible-light photooxidation of an oxomanganese water-oxidation catalyst covalently anchored to TiO2 nanoparticles. The Journal of Physical Chemistry. B. 114: 14214-22. PMID 19924873 DOI: 10.1021/jp908925z  1
2010 Allen LJ, Crabtree RH. Green alcohol couplings without transition metal catalysts: Base-mediated β-alkylation of alcohols in aerobic conditions Green Chemistry. 12: 1362-1364. DOI: 10.1039/c0gc00079e  1
2010 McNamara WR, Milot RL, Song HE, Snoeberger RC, Batista VS, Schmuttenmaer CA, Brudvig GW, Crabtree RH. Water-stable, hydroxamate anchors for functionalization of TiO2 surfaces with ultrafast interfacial electron transfer Energy and Environmental Science. 3: 917-923. DOI: 10.1039/c001065k  1
2010 Nova A, Balcells D, Schley ND, Dobereiner GE, Crabtree RH, Eisenstein O. An experimental-theoretical study of the factors that affect the switch between ruthenium-catalyzed dehydrogenative amide formation versus amine alkylation Organometallics. 29: 6548-6558. DOI: 10.1021/om101015u  1
2010 Dobereiner GE, Chamberlin CA, Schley ND, Crabtree RH. Acyl protection strategy for synthesis of a protic NHC complex via N-acyl methanolysis Organometallics. 29: 5728-5731. DOI: 10.1021/om100452g  1
2010 Hull JF, Hilton ST, Crabtree RH. A simple Ru catalyst for the conversion of aldehydes or oximes to primary amides Inorganica Chimica Acta. 363: 1243-1245. DOI: 10.1016/j.ica.2009.08.022  1
2010 Hull JF, Meyer TJ, Brudvig GW, Crabtree RH. Using organometallic catalysts as oxidants for fuels and devices Acs National Meeting Book of Abstracts 1
2010 Xiao D, Snoeberger RC, Martini L, Crabtree RH, Batista VS. Inverse design of molecular chromophores for dye-sensitized solar cells Acs National Meeting Book of Abstracts 1
2009 Crabtree RH. C-H bond activation: A radical non-metal solution. Nature Chemistry. 1: 348-9. PMID 21378885 DOI: 10.1038/nchem.311  1
2009 Das S, Brudvig GW, Crabtree RH. In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond. Inorganica Chimica Acta. 362: 1229-1233. PMID 20617108  1
2009 Li G, Richter CP, Milot RL, Cai L, Schmuttenmaer CA, Crabtree RH, Brudvig GW, Batista VS. Synergistic effect between anatase and rutile TiO2 nanoparticles in dye-sensitized solar cells. Dalton Transactions (Cambridge, England : 2003). 10078-85. PMID 19904436 DOI: 10.1039/b908686b  1
2009 Balcells D, Moles P, Blakemore JD, Raynaud C, Brudvig GW, Crabtree RH, Eisenstein O. Molecular recognition in Mn-catalyzed C-H oxidation. Reaction mechanism and origin of selectivity from a DFT perspective. Dalton Transactions (Cambridge, England : 2003). 5989-6000. PMID 19623399 DOI: 10.1039/b905317d  1
2009 Hull JF, Balcells D, Blakemore JD, Incarvito CD, Eisenstein O, Brudvig GW, Crabtree RH. Highly active and robust Cp* iridium complexes for catalytic water oxidation. Journal of the American Chemical Society. 131: 8730-1. PMID 19496565 DOI: 10.1021/ja901270f  1
2009 Balcells D, Raynaud C, Crabtree RH, Eisenstein O. C-H oxidation by hydroxo manganese(v) porphyrins: a DFT study. Chemical Communications (Cambridge, England). 1772-4. PMID 19294291 DOI: 10.1039/b821029b  1
2009 Hull JF, Sauer EL, Incarvito CD, Faller JW, Brudvig GW, Crabtree RH. Manganese catalysts with molecular recognition functionality for selective alkene epoxidation. Inorganic Chemistry. 48: 488-95. PMID 19093854 DOI: 10.1021/ic8013464  1
2009 McNamara WR, Snoeberger RC, Li G, Richter C, Allen LJ, Milot RL, Schmuttenmaer CA, Crabtree RH, Brudvig GW, Batista VS. Hydroxamate anchors for water-stable attachment to TiO2 nanoparticles Energy and Environmental Science. 2: 1173-1175. DOI: 10.1039/b910241h  1
2009 Li G, Sproviero EM, Snoeberger RC, Iguchi N, Blakemore JD, Crabtree RH, Brudvig GW, Batista VS. Deposition of an oxomanganese water oxidation catalyst on TiO2 nanoparticles: Computational modeling, assembly and characterization Energy and Environmental Science. 2: 230-238. DOI: 10.1039/b818708h  1
2009 Gnanamgari D, Crabtree RH. Terpyridine ruthenium-catalyzed one-pot conversion of aldehydes into amides Organometallics. 28: 922-924. DOI: 10.1021/om8010678  1
2009 Gnanamgari D, Sauer ELO, Schley ND, Butler C, Incarvito CD, Crabtree RH. Indium and ruthenium complexes with chelating N-heterocyclic carbenes: Efficient catalysts for transfer hydrogenation, β-alkylation of alcohols, and N-alkylation of amines Organometallics. 28: 321-325. DOI: 10.1021/om800821q  1
2009 Voutchkova AM, Crabtree RH. Iridium-catalyzed benzylic C-H activation and functionalization of alkyl arenes Journal of Molecular Catalysis a: Chemical. 312: 1-6. DOI: 10.1016/j.molcata.2009.07.019  1
2009 Das S, Brudvig GW, Crabtree RH. In situ dimanganese catalyst for fast screening of molecular recognition catalysts for regioselective oxygenation of an sp3 C-H bond Inorganica Chimica Acta. 362: 1229-1233. DOI: 10.1016/j.ica.2008.06.009  1
2009 Peris E, Crabtree RH. Iridium N-Heterocyclic Carbene Complexes and Their Application as Homogeneous Catalysts Iridium Complexes in Organic Synthesis. 39-54. DOI: 10.1002/9783527623075.ch3  1
2009 Schmuttenmaer CA, Brudvig GW, Crabtree RH, Batista VS. The role of terahertz spectroscopy in relation to the goal of catalytic water photooxidation Acs National Meeting Book of Abstracts 1
2008 Cady CW, Crabtree RH, Brudvig GW. Functional Models for the Oxygen-Evolving Complex of Photosystem II. Coordination Chemistry Reviews. 252: 444-455. PMID 21037800 DOI: 10.1016/j.ccr.2007.06.002  1
2008 Voutchkova A, Coplin A, Leadbeater NE, Crabtree RH. Palladium-catalyzed decarboxylative coupling of aromatic acids with aryl halides or unactivated arenes using microwave heating. Chemical Communications (Cambridge, England). 6312-4. PMID 19048139 DOI: 10.1039/b813998a  1
2008 Gnanamgari D, Leung CH, Schley ND, Hilton ST, Crabtree RH. Alcohol cross-coupling reactions catalyzed by Ru and Ir terpyridine complexes. Organic & Biomolecular Chemistry. 6: 4442-5. PMID 19005605 DOI: 10.1039/b815547j  1
2008 McNamara WR, Snoeberger RC, Li G, Schleicher JM, Cady CW, Poyatos M, Schmuttenmaer CA, Crabtree RH, Brudvig GW, Batista VS. Acetylacetonate anchors for robust functionalization of TiO2 nanoparticles with Mn(II)-terpyridine complexes. Journal of the American Chemical Society. 130: 14329-38. PMID 18831585 DOI: 10.1021/ja805498w  1
2008 Balcells D, Raynaud C, Crabtree RH, Eisenstein O. A rational basis for the axial ligand effect in C-H oxidation by [MnO(porphyrin)(X)]+ (X = H2O, OH-, O2-) from a DFT study. Inorganic Chemistry. 47: 10090-9. PMID 18788735 DOI: 10.1021/ic8013706  1
2008 Balcells D, Raynaud C, Crabtree RH, Eisenstein O. The rebound mechanism in catalytic C-H oxidation by MnO(tpp)Cl from DFT studies: electronic nature of the active species. Chemical Communications (Cambridge, England). 744-6. PMID 18478710 DOI: 10.1039/b715939k  1
2008 Tagore R, Crabtree RH, Brudvig GW. Oxygen evolution catalysis by a dimanganese complex and its relation to photosynthetic water oxidation. Inorganic Chemistry. 47: 1815-23. PMID 18330972 DOI: 10.1021/ic062218d  1
2008 Das S, Brudvig GW, Crabtree RH. High turnover remote catalytic oxygenation of alkyl groups: how steric exclusion of unbound substrate contributes to high molecular recognition selectivity. Journal of the American Chemical Society. 130: 1628-37. PMID 18197664 DOI: 10.1021/ja076039m  1
2008 Das S, Brudvig GW, Crabtree RH. Molecular recognition in homogeneous transition metal catalysis: a biomimetic strategy for high selectivity. Chemical Communications (Cambridge, England). 413-24. PMID 18188458 DOI: 10.1039/b710355g  1
2008 Iguchi N, Cady C, Snoeberger RC, Hunter BM, Sproviero EM, Schmuttenmaer CA, Crabtree RH, Brudvig GW, Batista VS. Characterization of siloxane adsorbates covalently attached to TiO 2 Proceedings of Spie - the International Society For Optical Engineering. 7034. DOI: 10.1117/12.798938  1
2008 Crabtree RH. Hydrogen storage in liquid organic heterocycles Energy and Environmental Science. 1: 134-138. DOI: 10.1039/b805644g  1
2008 Balcells D, Nova A, Clot E, Gnanamgari D, Crabtree RH, Eisenstein O. Mechanism of homogeneous iridium-catalyzed alkylation of amines with alcohols from a DFT study Organometallics. 27: 2529-2535. DOI: 10.1021/om800134d  1
2008 Poyatos M, McNamara W, Incarvito C, Clot E, Peris E, Crabtree RH. A weak donor, planar chelating bitriazole N-heterocyclic carbene ligand for ruthenium(II), palladium(II), and rhodium Organometallics. 27: 2128-2136. DOI: 10.1021/om800021c  1
2008 Appelhans LN, Incarvito CD, Crabtree RH. Synthesis of monodentate bis(N-heterocyclic carbene) complexes of iridium: Mixed complexes of abnormal NHCs, normal NHCs, and triazole NHCs Journal of Organometallic Chemistry. 693: 2761-2766. DOI: 10.1016/j.jorganchem.2008.05.024  1
2008 Voutchkova AM, Gnanamgari D, Jakobsche CE, Butler C, Miller SJ, Parr J, Crabtree RH. Selective partial reduction of quinolines: Hydrosilylation vs. transfer hydrogenation Journal of Organometallic Chemistry. 693: 1815-1821. DOI: 10.1016/j.jorganchem.2008.02.004  1
2008 Stavropoulos P, Çelenligil-Çetin R, Kiani S, Tapper A, Pinnapareddy D, Paraskevopoulou P, Adam W, Zhao CG, Bühler B, Schmid A, Bhalla G, Mironov O, Jones CJ, Tenn WJ, Nakamura S, ... ... Crabtree RH, et al. C-H Transformation at Unfunctionalized Alkanes Handbook of C-H Transformations: Applications in Organic Synthesis. 2: 497-651. DOI: 10.1002/9783527619450.ch9  1
2007 Tagore R, Chen H, Zhang H, Crabtree RH, Brudvig GW. Homogenous Water Oxidation by a Di-μ-Oxo Dimanganese Complex in the Presence of Ce. Inorganica Chimica Acta. 360: 2983-2989. PMID 18542709 DOI: 10.1016/j.ica.2007.02.020  1
2007 Crabtree RH. Chemistry. No protection required. Science (New York, N.Y.). 318: 756-7. PMID 17975055 DOI: 10.1126/science.1150982  1
2007 Voutchkova AM, Feliz M, Clot E, Eisenstein O, Crabtree RH. Imidazolium carboxylates as versatile and selective N-heterocyclic carbene transfer agents: synthesis, mechanism, and applications. Journal of the American Chemical Society. 129: 12834-46. PMID 17900114 DOI: 10.1021/ja0742885  1
2007 Poyatos M, McNamara W, Incarvito C, Peris E, Crabtree RH. A planar chelating bitriazole N-heterocyclic carbene ligand and its rhodium(III) and dirhodium(II) complexes. Chemical Communications (Cambridge, England). 2267-9. PMID 17534512 DOI: 10.1039/b705246d  1
2007 Clot E, Eisenstein O, Crabtree RH. Computational structure-activity relationships in H2 storage: how placement of N atoms affects release temperatures in organic liquid storage materials. Chemical Communications (Cambridge, England). 2231-3. PMID 17534500 DOI: 10.1039/b705037b  1
2007 Tagore R, Crabtree RH, Brudvig GW. Distinct mechanisms of bridging-oxo exchange in di-mu-O dimanganese complexes with and without water-binding sites: implications for water binding in the O(2)-evolving complex of photosystem II. Inorganic Chemistry. 46: 2193-203. PMID 17295472 DOI: 10.1021/ic061968k  1
2007 Chen H, Tagore R, Olack G, Vrettos JS, Weng TC, Penner-Hahn J, Crabtree RH, Brudvig GW. Speciation of the catalytic oxygen evolution system: [MnIII/IV2(mu-O)2(terpy)2(H2O)2](NO3)3 + HSO5-. Inorganic Chemistry. 46: 34-43. PMID 17198410 DOI: 10.1021/ic060499j  1
2007 Crabtree RH. Carbenes in synthesis and homogeneous catalysis Oil and Gas Science and Technology. 62: 739-744. DOI: 10.2516/ogst:2007037  1
2007 Leung CH, Voutchkova AM, Crabtree RH, Balcells D, Eisenstein O. Atom economic synthesis of amides via transition metal catalyzed rearrangement of oxaziridines Green Chemistry. 9: 976-979. DOI: 10.1039/b706164a  1
2007 Gnanamgari D, Moores A, Rajaseelan E, Crabtree RH. Transfer hydrogenation of imines and alkenes and direct reductive amination of aldehydes catalyzed by triazole-derived iridium(I) carbene complexes Organometallics. 26: 1226-1230. DOI: 10.1021/om060938m  1
2007 Abuabara SG, Cady CW, Baxter JB, Schmuttenmaer CA, Crabtree RH, Brudvig GW, Batista VS. Ultrafast photooxidation of Mn(II)-terpyridine complexes covalently attached to TiO2 nanoparticles Journal of Physical Chemistry C. 111: 11982-11990. DOI: 10.1021/jp072380h  1
2007 Crabtree RH. Recent developments in the organometallic chemistry of N-heterocyclic carbenes Coordination Chemistry Reviews. 251: 595. DOI: 10.1016/j.ccr.2006.08.005  1
2007 Peris E, Crabtree RH. 'Pincer'-Carbene Complexes The Chemistry of Pincer Compounds. 107-124. DOI: 10.1016/B978-044453138-4/50007-6  1
2007 Crabtree RH, Michael D, Mingos P. Comprehensive organometallic chemistry III Comprehensive Organometallic Chemistry Iii. 1: 1-8798.  1
2007 Michael D, Mingos P, Crabtree RH. Preface Comprehensive Organometallic Chemistry Iii. 1: xxi.  1
2006 Tagore R, Chen H, Crabtree RH, Brudvig GW. Determination of mu-oxo exchange rates in di-mu-oxo dimanganese complexes by electrospray ionization mass spectrometry. Journal of the American Chemical Society. 128: 9457-65. PMID 16848483 DOI: 10.1021/ja061348i  1
2006 Das S, Incarvito CD, Crabtree RH, Brudvig GW. Molecular recognition in the selective oxygenation of saturated C-H bonds by a dimanganese catalyst. Science (New York, N.Y.). 312: 1941-3. PMID 16809537 DOI: 10.1126/science.1127899  1
2006 Crabtree RH. Chemistry: a catalytic knight's move. Nature. 441: 165-6. PMID 16688161 DOI: 10.1038/441165a  1
2006 Crabtree RH. Rhodium and iridium in organometallic catalysis: Work in the laboratory of our rhodium bicentenary competition winner Platinum Metals Review. 50: 171-176. DOI: 10.1595/147106706X153117  1
2006 Moores A, Poyatos M, Luo Y, Crabtree RH. Catalysed low temperature H2 release from nitrogen heterocycles New Journal of Chemistry. 30: 1675-1678. DOI: 10.1039/b608914c  1
2006 Chin HL, Incarvito CD, Crabtree RH. Interplay of linker, N-substituent, and counterion effects in the formation and geometrical distortion of N-heterocyclic biscarbene complexes of rhodium(I) Organometallics. 25: 6099-6107. DOI: 10.1021/om0607189  1
2006 Crabtree RH. Some chelating C-donor ligands in hydrogen transfer and related catalysis Journal of Organometallic Chemistry. 691: 3146-3150. DOI: 10.1016/j.jorganchem.2006.01.032  1
2006 Cady CW, Incarvito C, Brudvig GW, Crabtree RH. Secondary bonding in a six-coordinate Mn(II) complex as a model of associative substitution Inorganica Chimica Acta. 359: 2509-2512. DOI: 10.1016/j.ica.2006.02.005  1
2006 Duboc C, Astier-Perret V, Chen H, Pécaut J, Crabtree RH, Brudvig GW, Collomb MN. A multifrequency high-field EPR (9-285 GHz) investigation of a series of dichloride mononuclear penta-coordinated Mn(II) complexes Inorganica Chimica Acta. 359: 1541-1548. DOI: 10.1016/j.ica.2005.10.027  1
2006 Rivera G, Crabtree RH. Chelate and Pincer Carbene Complexes N-Heterocyclic Carbenes in Synthesis. 223-239. DOI: 10.1002/9783527609451.ch9  1
2006 Baxter JB, Abuabara SG, Cady CW, Brudvig GW, Crabtree RH, Schmuttenmaer CA, Batista VS. Photocatalytic water splitting using titania nanoparticles functionalized with high-valent oxomanganese complexes Aiche Annual Meeting, Conference Proceedings 1
2006 Abuabara SG, Cady CW, Schleicher JM, Baxter J, Sproviero EM, Brudvig GW, Crabtree RH, Schmuttenmaer CA, Batista VS. Green chemistry based on TiO2 functionalized with oxo-manganese catalysts Acs National Meeting Book of Abstracts. 231.  1
2005 Voutchkova AM, Appelhans LN, Chianese AR, Crabtree RH. Disubstituted imidazolium-2-carboxylates as efficient precursors to N-heterocyclic carbene complexes of Rh, Ru, Ir, and Pd. Journal of the American Chemical Society. 127: 17624-5. PMID 16351090 DOI: 10.1021/ja056625k  1
2005 Chen H, Collomb MN, Duboc C, Blondin G, Rivière E, Faller JW, Crabtree RH, Brudvig GW. New linear high-valent tetranuclear manganese-oxo cluster relevant to the oxygen-evolving complex of photosystem II with oxo, hydroxo, and aqua coordinated to a single Mn(IV). Inorganic Chemistry. 44: 9567-73. PMID 16323946 DOI: 10.1021/ic051462m  1
2005 Li X, Chianese AR, Vogel T, Crabtree RH. Intramolecular alkyne hydroalkoxylation and hydroamination catalyzed by iridium hydrides. Organic Letters. 7: 5437-40. PMID 16288525 DOI: 10.1021/ol052186i  1
2005 Appelhans LN, Zuccaccia D, Kovacevic A, Chianese AR, Miecznikowski JR, Macchioni A, Clot E, Eisenstein O, Crabtree RH. An anion-dependent switch in selectivity results from a change of C-H activation mechanism in the reaction of an imidazolium salt with IrH5(PPh3)2. Journal of the American Chemical Society. 127: 16299-311. PMID 16287324 DOI: 10.1021/ja055317j  1
2005 Chen H, Tagore R, Das S, Incarvito C, Faller JW, Crabtree RH, Brudvig GW. General synthesis of di-mu-oxo dimanganese complexes as functional models for the oxygen evolving complex of photosystem II. Inorganic Chemistry. 44: 7661-70. PMID 16212393 DOI: 10.1021/ic0509940  1
2005 Mantel C, Chen H, Crabtree RH, Brudvig GW, Pécaut J, Collomb MN, Duboc C. High-spin chloro mononuclear MnIII complexes: a multifrequency high-field EPR study. Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry. 6: 541-6. PMID 15799481 DOI: 10.1002/cphc.200400484  1
2005 Viciano M, Mas-Marzá E, Poyatos M, Sanaú M, Crabtree RH, Peris E. An N-heterocyclic carbene/iridium hydride complex from the oxidative addition of a ferrocenyl-bisimidazolium salt: implications for synthesis. Angewandte Chemie (International Ed. in English). 44: 444-7. PMID 15624155 DOI: 10.1002/anie.200461918  1
2005 Li X, Chen P, Faller JW, Crabtree RH. Cycloiridation of α,β-unsaturated ketones, esters, and acetophenone Organometallics. 24: 4810-4815. DOI: 10.1021/om050441x  1
2005 Chianese AR, Crabtree RH. Axially chiral bidentate N-heterocyclic carbene ligands derived from BINAM: Rhodium and iridium complexes in asymmetric ketone hydrosilylation Organometallics. 24: 4432-4436. DOI: 10.1021/om050323+  1
2005 Li X, Incarvito CD, Vogel T, Crabtree RH. Intramolecular oxygen transfer from nitro groups to C≡C bonds mediated by iridium hydrides Organometallics. 24: 3066-3073. DOI: 10.1021/om050116+  1
2005 Li X, Vogel T, Incarvito CD, Crabtree RH. Electronic and steric effects in the insertion of alkynes into an iridium(III) hydride Organometallics. 24: 62-76. DOI: 10.1021/om049271z  1
2005 Crabtree RH. NHC ligands versus cyclopentadienyls and phosphines as spectator ligands in organometallic catalysis Journal of Organometallic Chemistry. 690: 5451-5457. DOI: 10.1016/j.jorganchem.2005.07.099  1
2004 Chianese AR, Zeglis BM, Crabtree RH. Unexpected oxidative C-C cleavage in the metallation of 2-substituted imidazolium salts to give N-heterocyclic carbene complexes. Chemical Communications (Cambridge, England). 2176-7. PMID 15467859 DOI: 10.1039/b409672j  1
2004 Clot E, Chen J, Lee DH, Sung SY, Appelhans LN, Faller JW, Crabtree RH, Eisenstein O. Double geminal C-H activation and reversible alpha-elimination in 2-aminopyridine iridium(III) complexes: the role of hydrides and solvent in flattening the free energy surface. Journal of the American Chemical Society. 126: 8795-804. PMID 15250733 DOI: 10.1021/ja048473j  1
2004 Chen H, Faller JW, Crabtree RH, Brudvig GW. Dimer-of-dimers model for the oxygen-evolving complex of photosystem II. Synthesis and properties of [MnIV4O5(terpy)4(H2O)2](ClO4)6. Journal of the American Chemical Society. 126: 7345-9. PMID 15186173 DOI: 10.1021/ja037389l  1
2004 Chianese AR, Kovacevic A, Zeglis BM, Faller JW, Crabtree RH. Abnormal C5-bound N-heterocyclic carbenes: Extremely strong electron donor ligands and their iridium(I) and iridium(III) complexes Organometallics. 23: 2461-2468. DOI: 10.1021/om049903h  1
2004 Li X, Appelhans LN, Faller JW, Crabtree RH. Stoichiometric C-C coupling reactions in the coordination sphere of an iridium(III) alkyl Organometallics. 23: 3378-3387. DOI: 10.1021/om049837j  1
2004 Miecznikowski JR, Crabtree RH. Transfer hydrogenation reduction of ketones, aldehydes and imines using chelated iridium(III) N-heterocyclic bis-carbene complexes Polyhedron. 23: 2857-2872. DOI: 10.1016/j.poly.2004.07.001  1
2004 Rivera G, Crabtree RH. Hydrogen bonding ligand functionality and catalytic selectivity in homogeneous hydrosilylation of enones with rhodium complexes Journal of Molecular Catalysis a: Chemical. 222: 59-73. DOI: 10.1016/j.molcata.2004.08.006  1
2004 Crabtree RH. Organometallic alkane CH activation Journal of Organometallic Chemistry. 689: 4083-4091. DOI: 10.1016/j.jorganchem.2004.07.034  1
2004 Salman HMA, Mahmoud MR, Abou-El-Wafa MHM, Rabie UM, Crabtree RH. Redox reactions via outer sphere charge transfer complexation: The interaction of ferrocenes with σ- and π-type acceptors Inorganic Chemistry Communications. 7: 1209-1212. DOI: 10.1016/j.inoche.2004.07.023  1
2004 Peris E, Crabtree RH. Recent homogeneous catalytic applications of chelate and pincer N-heterocyclic carbenes Coordination Chemistry Reviews. 248: 2239-2246. DOI: 10.1016/j.ccr.2004.04.014  1
2003 Li X, Incarvito CD, Crabtree RH. A rare eta2-butadienyl complex from an alkyne double insertion with double vinylidene rearrangement. Journal of the American Chemical Society. 125: 3698-9. PMID 12656590 DOI: 10.1021/ja0297281  1
2003 Mata JA, Peris E, Incarvito C, Crabtree RH. A methylene-bis-triazolium ligand precursor in an unusual rearrangement of norbornadiene to nortricyclyl. Chemical Communications (Cambridge, England). 184-5. PMID 12585382  0.76
2002 Dubé T, Faller JW, Crabtree RH. A cis-IrL(CO) group responds to increasing steric bulk of L by M-L stretching, not M-C-O tilting or bending. Inorganic Chemistry. 41: 5561-5. PMID 12377054 DOI: 10.1021/ic020144+  1
2002 Gründemann S, Kovacevic A, Albrecht M, Faller JW, Crabtree RH. Abnormal ligand binding and reversible ring hydrogenation in the reaction of imidazolium salts with IrH(5)(PPh(3))(2). Journal of the American Chemical Society. 124: 10473-81. PMID 12197749 DOI: 10.1021/ja026735g  1
2002 Albrecht M, Crabtree RH, Mata J, Peris E. Chelating bis-carbene rhodium(III) complexes in transfer hydrogenation of ketones and imines. Chemical Communications (Cambridge, England). 32-3. PMID 12120296  1
2002 Pelmenschikov V, Blomberg MR, Siegbahn PE, Crabtree RH. A mechanism from quantum chemical studies for methane formation in methanogenesis. Journal of the American Chemical Society. 124: 4039-49. PMID 11942842 DOI: 10.1021/ja011664r  1
2002 Baffert C, Collomb MN, Deronzier A, Pécaut J, Limburg J, Crabtree RH, Brudvig GW. Two new terpyridine dimanganese complexes: a manganese(III,III) complex with a single unsupported oxo bridge and a manganese(III,IV) complex with a dioxo bridge. Synthesis, structure, and redox properties. Inorganic Chemistry. 41: 1404-11. PMID 11896708 DOI: 10.1021/ic0107375  1
2002 Sini G, Eisenstein O, Crabtree RH. Preferential C-binding versus N-binding in imidazole depends on the metal fragment involved. Inorganic Chemistry. 41: 602-4. PMID 11825090 DOI: 10.1021/ic010714q  1
2001 Gründemann S, Kovacevic A, Albrecht M, Faller JW, Crabtree RH. Abnormal binding in a carbene complex formed from an imidazolium salt and a metal hydride complex. Chemical Communications (Cambridge, England). 2274-5. PMID 12240147  1
2001 Perrin L, Clot E, Eisenstein O, Loch J, Crabtree RH. Computed ligand electronic parameters from quantum chemistry and their relation to Tolman parameters, Lever parameters, and Hammett constants. Inorganic Chemistry. 40: 5806-11. PMID 11681889 DOI: 10.1021/ic0105258  1
2001 Limburg J, Vrettos JS, Chen H, de Paula JC, Crabtree RH, Brudvig GW. Characterization of the O(2)-evolving reaction catalyzed by [(terpy)(H2O)Mn(III)(O)2Mn(IV)(OH2)(terpy)](NO3)3 (terpy = 2,2':6,2"-terpyridine). Journal of the American Chemical Society. 123: 423-30. PMID 11456544 DOI: 10.1021/ja001090a  1
2001 Siegbahn PE, Blomberg MR, Wirstam née Pavlov M, Crabtree RH. The mechanism of the Ni-Fe hydrogenases: a quantum chemical perspective. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 6: 460-6. PMID 11372205 DOI: 10.1007/s007750100226  1
2001 Limburg J, Vrettos JS, Crabtree RH, Brudvig GW, de Paula JC, Hassan A, Barra AL, Duboc-Toia C, Collomb MN. High-frequency EPR study of a new mononuclear manganese(III) complex:. [(terpy)Mn(N3)3] (terpy = 2,2':6',2''-terpyridine). Inorganic Chemistry. 40: 1698-703. PMID 11261982 DOI: 10.1021/ic001118j  1
1999 Kavallieratos K, Bertao CM, Crabtree RH. Hydrogen Bonding in Anion Recognition: A Family of Versatile, Nonpreorganized Neutral and Acyclic Receptors. The Journal of Organic Chemistry. 64: 1675-1683. PMID 11674235  0.64
1999 Kavallieratos K, Hwang S, Crabtree RH. Aminoferrocene Derivatives in Chloride Recognition and Electrochemical Sensing. Inorganic Chemistry. 38: 5184-5186. PMID 11671267  0.64
1999 Limburg J, Vrettos JS, Liable-Sands LM, Rheingold AL, Crabtree RH, Brudvig GW. A functional model for O-O bond formation by the O2-evolving complex in photosystem II. Science (New York, N.Y.). 283: 1524-7. PMID 10066173 DOI: 10.1126/science.283.5407.1524  1
1996 Crabtree RH, Siegbahn PE, Eisenstein O, Rheingold AL, Koetzle TF. A new intermolecular interaction: unconventional hydrogen bonds with element-hydride bonds as proton acceptor. Accounts of Chemical Research. 29: 348-54. PMID 19904922 DOI: 10.1021/ar950150s  1
1986 Brudvig GW, Crabtree RH. Mechanism for photosynthetic O2 evolution. Proceedings of the National Academy of Sciences of the United States of America. 83: 4586-8. PMID 3460059  1
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