Patrick L. Holland - Publications

Affiliations: 
Chemistry Yale University, New Haven, CT 
Area:
transition-metal complexes
Website:
http://www.chem.yale.edu/faculty/holland.html

160 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2019 DeRosha DE, Chilkuri VG, Van Stappen C, Bill E, Mercado BQ, DeBeer S, Neese F, Holland PL. Planar three-coordinate iron sulfide in a synthetic [4Fe-3S] cluster with biomimetic reactivity. Nature Chemistry. PMID 31611632 DOI: 10.1038/s41557-019-0341-7  0.68
2019 Speelman AL, Čorić I, Van Stappen C, DeBeer S, Mercado BQ, Holland PL. Nitrogenase-Relevant Reactivity of a Synthetic Iron-Sulfur-Carbon Site. Journal of the American Chemical Society. PMID 31403298 DOI: 10.1021/jacs.9b05353  0.6
2019 Connor GP, Mercado BQ, Lant HMC, Mayer JM, Holland PL. Chemical Oxidation of a Coordinated PNP-Pincer Ligand Forms Unexpected Re-Nitroxide Complexes with Reversal of Nitride Reactivity. Inorganic Chemistry. PMID 31389243 DOI: 10.1021/acs.inorgchem.9b01075  0.56
2019 DeRosha DE, Arnet NA, Mercado BQ, Holland PL. A [2Fe-1S] Complex That Affords Access to Bimetallic and Higher-Nuclearity Iron-Sulfur Clusters. Inorganic Chemistry. PMID 31247861 DOI: 10.1021/acs.inorgchem.9b01212  0.56
2019 Kim D, Rahaman SMW, Mercado BQ, Poli R, Holland PL. Roles of Iron Complexes in Catalytic Radical Alkene Cross-Coupling: A Computational and Mechanistic Study. Journal of the American Chemical Society. PMID 31025567 DOI: 10.1021/jacs.9b02117  0.56
2019 Roy L, Al-Afyouni MH, DeRosha DE, Mondal B, DiMucci IM, Lancaster KM, Shearer J, Bill E, Brennessel WW, Neese F, Ye S, Holland PL. Reduction of CO by a masked two-coordinate cobalt(i) complex and characterization of a proposed oxodicobalt(ii) intermediate. Chemical Science. 10: 918-929. PMID 30774886 DOI: 10.1039/c8sc02599a  0.76
2018 McWilliams SF, Bunting PC, Kathiresan V, Mercado BQ, Hoffman BM, Long JR, Holland PL. Isolation and characterization of a high-spin mixed-valent iron dinitrogen complex. Chemical Communications (Cambridge, England). PMID 30403226 DOI: 10.1039/c8cc07294a  0.56
2018 McWilliams SF, Bill E, Lukat-Rodgers G, Rodgers KR, Mercado BQ, Holland PL. Effects of N Binding Mode on Iron-Based Functionalization of Dinitrogen to Form an Iron(III) Hydrazido Complex. Journal of the American Chemical Society. PMID 29957940 DOI: 10.1021/jacs.8b04828  0.68
2018 Pelmenschikov V, Gee LB, Wang H, MacLeod KC, McWilliams SF, Skubi KL, Cramer SP, Holland PL. High-Frequency Fe-H Vibrations in a Bridging Hydride Complex Characterized by NRVS and DFT. Angewandte Chemie (International Ed. in English). PMID 29847703 DOI: 10.1002/anie.201804601  0.64
2018 Bonyhady SJ, DeRosha DE, Vela J, Vinyard DJ, Cowley RE, Mercado BQ, Brennessel WW, Holland PL. Iron and Cobalt Diazoalkane Complexes Supported by β-Diketiminate Ligands: A Synthetic, Spectroscopic, and Computational Investigation. Inorganic Chemistry. PMID 29741884 DOI: 10.1021/acs.inorgchem.8b00468  0.96
2018 DeRosha DE, Holland PL. Incorporating light atoms into synthetic analogues of FeMoco. Proceedings of the National Academy of Sciences of the United States of America. PMID 29712851 DOI: 10.1073/pnas.1805700115  0.56
2018 Broere D, Mercado B, Lukens J, Vilbert A, Banerjee G, Lant H, Lee SH, Bill E, Lancaster K, Sproules S, Holland P. Reversible Ligand-Centered Reduction in Low- Coordinate Iron Formazanate Complexes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29663542 DOI: 10.1002/chem.201801298  0.68
2018 Broere D, Mercado BQ, Holland PL. Selective Conversion of CO2 to Isocyanate by Low-Coordinate Fe. Angewandte Chemie (International Ed. in English). PMID 29633494 DOI: 10.1002/anie.201802357  0.56
2018 Broere DLJ, Mercado BQ, Bill E, Lancaster KM, Sproules S, Holland PL. Alkali Cation Effects on Redox-Active Formazanate Ligands in Iron Chemistry. Inorganic Chemistry. PMID 29629752 DOI: 10.1021/acs.inorgchem.8b00226  0.68
2017 McWilliams SF, Brennan-Wydra E, MacLeod KC, Holland PL. Correction to "Density Functional Calculations for Prediction of Fe Mossbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes". Acs Omega. 2: 5973. PMID 31457850 DOI: 10.1021/acsomega.7b01252  0.64
2017 Rozen E, Erlich Y, Reesbeck ME, Holland PL, Sukenik CN. Functionalized Self-Assembled Monolayers Bearing Diiminate Complexes Immobilized through Covalently Anchored Ligands. Langmuir : the Acs Journal of Surfaces and Colloids. PMID 29048903 DOI: 10.1021/acs.langmuir.7b00984  0.64
2017 Horitani M, Grubel K, McWilliams SF, Stubbert BD, Mercado BQ, Yu Y, Gurubasavaraj PM, Lees NS, Holland PL, Hoffman BM. ENDOR characterization of an iron-alkene complex provides insight into a corresponding organometallic intermediate of nitrogenase. Chemical Science. 8: 5941-5948. PMID 28989623 DOI: 10.1039/c7sc01602f  0.68
2017 Arnet NA, McWilliams SF, DeRosha DE, Mercado BQ, Holland PL. Synthesis and Mechanism of Formation of Hydride-Sulfide Complexes of Iron. Inorganic Chemistry. 56: 9185-9193. PMID 28726395 DOI: 10.1021/acs.inorgchem.7b01230  0.56
2017 McWilliams SF, Brennan-Wydra E, MacLeod KC, Holland PL. Density Functional Calculations for Prediction of (57)Fe Mössbauer Isomer Shifts and Quadrupole Splittings in β-Diketiminate Complexes. Acs Omega. 2: 2594-2606. PMID 28691111 DOI: 10.1021/acsomega.7b00595  0.64
2017 Broere DL, Čorić I, Brosnahan A, Holland PL. Quantitation of the THF Content in Fe[N(SiMe3)2]2·xTHF. Inorganic Chemistry. PMID 28248496 DOI: 10.1021/acs.inorgchem.7b00056  0.6
2017 DeRosha DE, Mercado BQ, Lukat-Rodgers G, Rodgers KR, Holland PL. Enhancement of C-H Oxidizing Ability in Co-O2  Complexes through an Isolated Heterobimetallic Oxo Intermediate. Angewandte Chemie (International Ed. in English). 56: 3211-3215. PMID 28194845 DOI: 10.1002/anie.201612010  0.68
2017 Lo JC, Kim D, Pan CM, Edwards JT, Yabe Y, Gui J, Qin T, Gutiérrez S, Giacoboni J, Smith MW, Holland PL, Baran PS. Fe-Catalyzed C-C Bond Construction from Olefins via Radicals. Journal of the American Chemical Society. PMID 28094980 DOI: 10.1021/jacs.6b13155  0.52
2017 Reesbeck ME, Grubel K, Kim D, Brennessel WW, Mercado BQ, Holland PL. Diazoalkanes in Low-Coordinate Iron Chemistry: Bimetallic Diazoalkyl and Alkylidene Complexes of Iron(II). Inorganic Chemistry. 56: 1019-1022. PMID 28067506 DOI: 10.1021/acs.inorgchem.6b01952  0.76
2017 MacLeod KC, Lewis RA, DeRosha DE, Mercado BQ, Holland PL. C-H and C-N Activation at Redox-Active Pyridine Complexes of Iron. Angewandte Chemie (International Ed. in English). 56: 1069-1072. PMID 28000416 DOI: 10.1002/anie.201610679  0.64
2016 Bellows SM, Brennessel WW, Holland PL. Effects of Ligand Halogenation on the Electron Localization, Geometry and Spin State of Low-Coordinate (β-Diketiminato)iron Complexes. European Journal of Inorganic Chemistry. 2016: 3344-3355. PMID 28835739 DOI: 10.1002/ejic.201600112  0.88
2016 MacLeod KC, McWilliams SF, Mercado BQ, Holland PL. Stepwise N-H Bond Formation From N2-Derived Iron Nitride, Imide and Amide Intermediates to Ammonia. Chemical Science. 7: 5736-5746. PMID 28066537 DOI: 10.1039/C6SC00423G  0.64
2016 Liu Y, Vinyard DJ, Reesbeck ME, Suzuki T, Manakongtreecheep K, Holland PL, Brudvig GW, Söll D. A [3Fe-4S] cluster is required for tRNA thiolation in archaea and eukaryotes. Proceedings of the National Academy of Sciences of the United States of America. PMID 27791189 DOI: 10.1073/pnas.1615732113  0.64
2016 Bellows SM, Arnet NA, Gurubasavaraj PM, Brennessel WW, Bill E, Cundari TR, Holland PL. The Mechanism of N-N Double Bond Cleavage by an Iron(II) Hydride Complex. Journal of the American Chemical Society. PMID 27598037 DOI: 10.1021/jacs.6b04654  1
2016 MacLeod KC, Menges FS, McWilliams SF, Craig SM, Mercado BQ, Johnson MA, Holland PL. Alkali-Controlled C-H Cleavage or N-C Bond Formation by N2-Derived Iron Nitrides and Imides. Journal of the American Chemical Society. 138: 11185-91. PMID 27571271 DOI: 10.1021/jacs.6b04984  0.64
2016 Čorić I, Holland PL. Insight into the FeMoco of nitrogenase from synthetic iron complexes with sulfur, carbon, and hydride ligands. Journal of the American Chemical Society. PMID 27171599 DOI: 10.1021/jacs.6b00747  1
2016 McWilliams SF, Rodgers KR, Lukat-Rodgers G, Mercado BQ, Grubel K, Holland PL. Alkali Metal Variation and Twisting of the FeNNFe Core in Bridging Diiron Dinitrogen Complexes. Inorganic Chemistry. 55: 2960-8. PMID 26925968 DOI: 10.1021/acs.inorgchem.5b02841  0.68
2015 Arnet NA, Dugan TR, Menges FS, Mercado BQ, Brennessel WW, Bill E, Johnson MA, Holland PL. Synthesis, Characterization, and Nitrogenase-Relevant Reactions of an Iron Sulfide Complex with a Bridging Hydride. Journal of the American Chemical Society. 137: 13220-3. PMID 26457740 DOI: 10.1021/jacs.5b06841  1
2015 Chen C, Hecht MB, Kavara A, Brennessel WW, Mercado BQ, Weix DJ, Holland PL. Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst. Journal of the American Chemical Society. 137: 13244-7. PMID 26444496 DOI: 10.1021/jacs.5b08611  0.76
2015 Čorić I, Mercado BQ, Bill E, Vinyard DJ, Holland PL. Binding of dinitrogen to an iron-sulfur-carbon site. Nature. 526: 96-9. PMID 26416755 DOI: 10.1038/nature15246  0.68
2015 Al-Afyouni MH, Suturina E, Pathak S, Atanasov M, Bill E, DeRosha DE, Brennessel WW, Neese F, Holland PL. Spin Isomers and Ligand Isomerization in a Three-Coordinate Cobalt(I) Carbonyl Complex. Journal of the American Chemical Society. PMID 26267848 DOI: 10.1021/jacs.5b06078  1
2015 Chen C, Bellows SM, Holland PL. Tuning steric and electronic effects in transition-metal β-diketiminate complexes. Dalton Transactions (Cambridge, England : 2003). PMID 26244489 DOI: 10.1039/c5dt02215k  1
2015 McWilliams SF, Holland PL. Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes. Accounts of Chemical Research. PMID 26099821 DOI: 10.1021/acs.accounts.5b00213  1
2015 Reesbeck ME, Rodriguez MM, Brennessel WW, Mercado BQ, Vinyard D, Holland PL. Oxidized and reduced [2Fe-2S] clusters from an iron(I) synthon. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 20: 875-83. PMID 26044124 DOI: 10.1007/s00775-015-1272-4  0.76
2015 Holland PL. Distinctive Reaction Pathways at Base Metals in High-Spin Organometallic Catalysts. Accounts of Chemical Research. 48: 1696-702. PMID 25989357 DOI: 10.1021/acs.accounts.5b00036  1
2015 Bonyhady SJ, Goldberg JM, Wedgwood N, Dugan TR, Eklund AG, Brennessel WW, Holland PL. Cobalt(II) Complex of a Diazoalkane Radical Anion. Inorganic Chemistry. 54: 5148-50. PMID 25986783 DOI: 10.1021/acs.inorgchem.5b00673  1
2015 Das A, Han Z, Brennessel WW, Holland PL, Eisenberg R. Nickel complexes for robust light-driven and electrocatalytic hydrogen production from water Acs Catalysis. 5: 1397-1406. DOI: 10.1021/acscatal.5b00045  1
2015 Schofield JA, Brennessel WW, Urnezius E, Rokhsana D, Boshart MD, Juers DH, Holland PL, Machonkin TE. Metal-Halogen Secondary Bonding in a 2,5-Dichlorohydroquinonate Cobalt(II) Complex: Insight into Substrate Coordination in the Chlorohydroquinone Dioxygenase PcpA European Journal of Inorganic Chemistry. 2015: 4643-4647. DOI: 10.1002/ejic.201500845  1
2014 Grubel K, Brennessel WW, Mercado BQ, Holland PL. Alkali metal control over N-N cleavage in iron complexes. Journal of the American Chemical Society. 136: 16807-16. PMID 25412468 DOI: 10.1021/ja507442b  0.76
2014 Machonkin TE, Boshart MD, Schofield JA, Rodriguez MM, Grubel K, Rokhsana D, Brennessel WW, Holland PL. Structural and spectroscopic characterization of iron(II), cobalt(II), and nickel(II) ortho-dihalophenolate complexes: insights into metal-halogen secondary bonding. Inorganic Chemistry. 53: 9837-48. PMID 25167329 DOI: 10.1021/ic501424e  1
2014 Lewis RA, MacLeod KC, Mercado BQ, Holland PL. Geometric and redox flexibility of pyridine as a redox-active ligand that can reversibly accept one or two electrons. Chemical Communications (Cambridge, England). 50: 11114-7. PMID 25111358 DOI: 10.1039/c4cc05495d  0.64
2014 MacLeod KC, Vinyard DJ, Holland PL. A multi-iron system capable of rapid N2 formation and N2 cleavage. Journal of the American Chemical Society. 136: 10226-9. PMID 25004280 DOI: 10.1021/ja505193z  1
2014 Dugan TR, Bill E, MacLeod KC, Brennessel WW, Holland PL. Synthesis, spectroscopy, and hydrogen/deuterium exchange in high-spin iron(II) hydride complexes. Inorganic Chemistry. 53: 2370-80. PMID 24555749 DOI: 10.1021/ic4013137  1
2014 Chen C, Dugan TR, Brennessel WW, Weix DJ, Holland PL. Z-selective alkene isomerization by high-spin cobalt(II) complexes. Journal of the American Chemical Society. 136: 945-55. PMID 24386941 DOI: 10.1021/ja408238n  1
2014 Chiang KP, Bellows SM, Brennessel WW, Holland PL. Multimetallic Cooperativity in Activation of Dinitrogen at Iron-Potassium Sites. Chemical Science (Royal Society of Chemistry : 2010). 5. PMID 24379972 DOI: 10.1039/C3SC52487F  1
2014 Gladysz JA, Bedford RB, Fujita M, Gabbaï FP, Goldberg KI, Holland PL, Kiplinger JL, Krische MJ, Louie J, Lu CC, Norton JR, Petrukhina MA, Ren T, Stahl SS, Tilley TD, et al. Organometallics roundtable 2013-2014 Organometallics. 33: 1505-1527. DOI: 10.1021/om500253z  1
2014 Yao W, Gurubasavaraj PM, Holland PL. All-ferrous iron-sulfur clusters Structure and Bonding. 160: 1-38. DOI: 10.1007/430-2012-81  1
2013 Stubbert BD, Vela J, Brennessel WW, Holland PL. A Sulfide-Bridged Diiron(II) Complex with a cis-N2H4Ligand. Zeitschrift Fur Anorganische Und Allgemeine Chemie. 639: 1351-1355. PMID 24678131 DOI: 10.1002/zaac.201300163  1
2013 Dugan TR, Macleod KC, Brennessel WW, Holland PL. Cobalt-Magnesium and Iron-Magnesium Complexes with Weakened Dinitrogen Bridges. European Journal of Inorganic Chemistry. 2013. PMID 24367236 DOI: 10.1002/ejic.201300187  1
2013 Han Z, Shen L, Brennessel WW, Holland PL, Eisenberg R. Nickel pyridinethiolate complexes as catalysts for the light-driven production of hydrogen from aqueous solutions in noble-metal-free systems. Journal of the American Chemical Society. 135: 14659-69. PMID 24004329 DOI: 10.1021/ja405257s  1
2013 Davydov RM, McLaughlin MP, Bill E, Hoffman BM, Holland PL. Generation of high-spin iron(I) in a protein environment using cryoreduction. Inorganic Chemistry. 52: 7323-5. PMID 24004284 DOI: 10.1021/ic4011339  1
2013 Pollock CJ, Grubel K, Holland PL, DeBeer S. Experimentally quantifying small-molecule bond activation using valence-to-core X-ray emission spectroscopy. Journal of the American Chemical Society. 135: 11803-8. PMID 23862983 DOI: 10.1021/ja3116247  1
2013 Macleod KC, Holland PL. Recent developments in the homogeneous reduction of dinitrogen by molybdenum and iron. Nature Chemistry. 5: 559-65. PMID 23787744 DOI: 10.1038/nchem.1620  1
2013 Chen Z, Glasson CR, Holland PL, Meyer TJ. Electrogenerated polypyridyl ruthenium hydride and ligand activation for water reduction to hydrogen and acetone to iso-propanol. Physical Chemistry Chemical Physics : Pccp. 15: 9503-7. PMID 23681418 DOI: 10.1039/c3cp51946e  1
2013 Chandrasekaran P, Chiang KP, Nordlund D, Bergmann U, Holland PL, DeBeer S. Sensitivity of X-ray core spectroscopy to changes in metal ligation: a systematic study of low-coordinate, high-spin ferrous complexes. Inorganic Chemistry. 52: 6286-98. PMID 23662855 DOI: 10.1021/ic3021723  1
2013 Cowley RE, Golder MR, Eckert NA, Al-Afyouni MH, Holland PL. Mechanism of catalytic nitrene transfer using Iron(I)-isocyanide complexes Organometallics. 32: 5289-5298. DOI: 10.1021/om400379p  1
2013 Bellows SM, Cundari TR, Holland PL. Spin Crossover during β-Hydride Elimination in High-Spin Iron(II)- and Cobalt(II)-Alkyl Complexes Organometallics. 32: 4741-4751. DOI: 10.1021/om400325x  1
2012 Dugan TR, Bill E, MacLeod KC, Christian GJ, Cowley RE, Brennessel WW, Ye S, Neese F, Holland PL. Reversible C-C bond formation between redox-active pyridine ligands in iron complexes. Journal of the American Chemical Society. 134: 20352-64. PMID 23181620 DOI: 10.1021/ja305679m  1
2012 McLaughlin MP, Retegan M, Bill E, Payne TM, Shafaat HS, Peña S, Sudhamsu J, Ensign AA, Crane BR, Neese F, Holland PL. Azurin as a protein scaffold for a low-coordinate nonheme iron site with a small-molecule binding pocket. Journal of the American Chemical Society. 134: 19746-57. PMID 23167247 DOI: 10.1021/ja308346b  1
2012 Han Z, Qiu F, Eisenberg R, Holland PL, Krauss TD. Robust photogeneration of H2 in water using semiconductor nanocrystals and a nickel catalyst. Science (New York, N.Y.). 338: 1321-4. PMID 23138979 DOI: 10.1126/science.1227775  1
2012 Glasson CR, Song W, Ashford DL, Vannucci A, Chen Z, Concepcion JJ, Holland PL, Meyer TJ. Self-assembled bilayers on indium-tin oxide (SAB-ITO) electrodes: a design for chromophore-catalyst photoanodes. Inorganic Chemistry. 51: 8637-9. PMID 22856323 DOI: 10.1021/ic300636w  1
2012 Rodriguez MM, Stubbert BD, Scarborough CC, Brennessel WW, Bill E, Holland PL. Isolation and characterization of stable iron(I) sulfide complexes. Angewandte Chemie (International Ed. in English). 51: 8247-50. PMID 22821816 DOI: 10.1002/anie.201202211  1
2012 Cowley RE, Holland PL. Ligand effects on hydrogen atom transfer from hydrocarbons to three-coordinate iron imides. Inorganic Chemistry. 51: 8352-61. PMID 22800175 DOI: 10.1021/ic300870y  1
2012 Figg TM, Holland PL, Cundari TR. Cooperativity between low-valent iron and potassium promoters in dinitrogen fixation. Inorganic Chemistry. 51: 7546-50. PMID 22734966 DOI: 10.1021/ic300150u  1
2012 McNamara WR, Han Z, Yin CJ, Brennessel WW, Holland PL, Eisenberg R. Cobalt-dithiolene complexes for the photocatalytic and electrocatalytic reduction of protons in aqueous solutions. Proceedings of the National Academy of Sciences of the United States of America. 109: 15594-9. PMID 22691494 DOI: 10.1073/pnas.1120757109  1
2012 Chiang KP, Scarborough CC, Horitani M, Lees NS, Ding K, Dugan TR, Brennessel WW, Bill E, Hoffman BM, Holland PL. Characterization of the Fe-H bond in a three-coordinate terminal hydride complex of iron(I). Angewandte Chemie (International Ed. in English). 51: 3658-62. PMID 22374689 DOI: 10.1002/anie.201109204  1
2012 Grubel K, Holland PL. New iron-sulfur clusters help hydrogenases tolerate oxygen. Angewandte Chemie (International Ed. in English). 51: 3308-10. PMID 22323270 DOI: 10.1002/anie.201108761  1
2012 Han Z, McNamara WR, Eum MS, Holland PL, Eisenberg R. A nickel thiolate catalyst for the long-lived photocatalytic production of hydrogen in a noble-metal-free system. Angewandte Chemie (International Ed. in English). 51: 1667-70. PMID 22237945 DOI: 10.1002/anie.201107329  1
2012 Edelbach BL, Pharoah BM, Bellows SM, Thayer PR, Fennie CN, Cowley RE, Holland PL. An expedient synthesis of 2,4,6-tris(trifluoromethyl)aniline Synthesis (Germany). 44: 3595-3597. DOI: 10.1055/s-0032-1316809  1
2012 Dugan TR, Goldberg JM, Brennessel WW, Holland PL. Low-coordinate cobalt fluoride complexes: Synthesis, reactions, and production from C-F activation reactions Organometallics. 31: 1349-1360. DOI: 10.1021/om200991k  1
2012 Cowley RE, Christian GJ, Brennessel WW, Neese F, Holland PL. A reduced (β-diketiminato)iron complex with end-on and side-on nitriles: Strong backbonding or ligand non-innocence? European Journal of Inorganic Chemistry. 479-483. DOI: 10.1002/ejic.201100787  1
2011 Rodriguez MM, Bill E, Brennessel WW, Holland PL. N₂reduction and hydrogenation to ammonia by a molecular iron-potassium complex. Science (New York, N.Y.). 334: 780-3. PMID 22076372 DOI: 10.1126/science.1211906  1
2011 McLaughlin MP, Darrah TH, Holland PL. Palladium(II) and platinum(II) bind strongly to an engineered blue copper protein. Inorganic Chemistry. 50: 11294-6. PMID 22026434 DOI: 10.1021/ic2017648  1
2011 McCormick TM, Han Z, Weinberg DJ, Brennessel WW, Holland PL, Eisenberg R. Impact of ligand exchange in hydrogen production from cobaloxime-containing photocatalytic systems. Inorganic Chemistry. 50: 10660-6. PMID 21980978 DOI: 10.1021/ic2010166  1
2011 Delgado-Jaime MU, Dible BR, Chiang KP, Brennessel WW, Bergmann U, Holland PL, DeBeer S. Identification of a single light atom within a multinuclear metal cluster using valence-to-core X-ray emission spectroscopy. Inorganic Chemistry. 50: 10709-17. PMID 21954894 DOI: 10.1021/ic201173j  1
2011 McNamara WR, Han Z, Alperin PJ, Brennessel WW, Holland PL, Eisenberg R. A cobalt-dithiolene complex for the photocatalytic and electrocatalytic reduction of protons. Journal of the American Chemical Society. 133: 15368-71. PMID 21863808 DOI: 10.1021/ja207842r  1
2011 Holland PL. Techniques for functional and structural modeling of nitrogenase. Methods in Molecular Biology (Clifton, N.J.). 766: 249-63. PMID 21833873 DOI: 10.1007/978-1-61779-194-9_17  1
2011 Dugan TR, Sun X, Rybak-Akimova EV, Olatunji-Ojo O, Cundari TR, Holland PL. A masked two-coordinate cobalt(I) complex that activates C-F bonds. Journal of the American Chemical Society. 133: 12418-21. PMID 21770365 DOI: 10.1021/ja2052914  1
2011 Holland PL. Coordination chemistry: all square for high-spin iron(II). Nature Chemistry. 3: 507-8. PMID 21697870 DOI: 10.1038/nchem.1078  1
2011 McLaughlin MP, McCormick TM, Eisenberg R, Holland PL. A stable molecular nickel catalyst for the homogeneous photogeneration of hydrogen in aqueous solution. Chemical Communications (Cambridge, England). 47: 7989-91. PMID 21681322 DOI: 10.1039/c1cc12347e  1
2011 Holland PL. Two-coordinate transition-metal centers with metal-metal bonds. Angewandte Chemie (International Ed. in English). 50: 6213-4. PMID 21671318 DOI: 10.1002/anie.201101209  1
2011 Cowley RE, Eckert NA, Vaddadi S, Figg TM, Cundari TR, Holland PL. Selectivity and mechanism of hydrogen atom transfer by an isolable imidoiron(III) complex. Journal of the American Chemical Society. 133: 9796-811. PMID 21563763 DOI: 10.1021/ja2005303  1
2011 Dible BR, Cowley RE, Holland PL. Remote substitution on N-heterocyclic carbenes heightens the catalytic reactivity of their palladium complexes Organometallics. 30: 5123-5132. DOI: 10.1021/om200349y  1
2011 Cowley RE, Holland PL. C-H activation by a terminal imidoiron(III) complex to form a cyclopentadienyliron(II) product Inorganica Chimica Acta. 369: 40-44. DOI: 10.1016/j.ica.2010.11.031  1
2010 Rocks SS, Brennessel WW, Machonkin TE, Holland PL. Solution and structural characterization of iron(II) complexes with ortho-halogenated phenolates: insights into potential substrate binding modes in hydroquinone dioxygenases. Inorganic Chemistry. 49: 10914-29. PMID 21058671 DOI: 10.1021/ic101377u  1
2010 Cowley RE, DeYonker NJ, Eckert NA, Cundari TR, DeBeer S, Bill E, Ottenwaelder X, Flaschenriem C, Holland PL. Three-coordinate terminal imidoiron(III) complexes: structure, spectroscopy, and mechanism of formation. Inorganic Chemistry. 49: 6172-87. PMID 20524625 DOI: 10.1021/ic100846b  1
2010 Holland PL. Metal-dioxygen and metal-dinitrogen complexes: where are the electrons? Dalton Transactions (Cambridge, England : 2003). 39: 5415-25. PMID 20361098 DOI: 10.1039/c001397h  1
2010 Machonkin TE, Holland PL, Smith KN, Liberman JS, Dinescu A, Cundari TR, Rocks SS. Determination of the active site of Sphingobium chlorophenolicum 2,6-dichlorohydroquinone dioxygenase (PcpA). Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 15: 291-301. PMID 19924449 DOI: 10.1007/s00775-009-0602-9  1
2010 Mindiola DJ, Holland PL, Warren TH. Introduction Inorganic Syntheses. 35: i.  1
2009 Clark MM, Brennessel WW, Holland PL. Bis(η-penta-methyl-cyclo-penta-dien-yl)cobalt(II). Acta Crystallographica. Section E, Structure Reports Online. 65: m391. PMID 21582340 DOI: 10.1107/S1600536809007971  1
2009 Dugan TR, Holland PL. New Routes to Low-Coordinate Iron Hydride Complexes: The Binuclear Oxidative Addition of H(2). Journal of Organometallic Chemistry. 694: nihms111237. PMID 20161197 DOI: 10.1016/j.jorganchem.2009.04.005  1
2009 Ding K, Brennessel WW, Holland PL. Three-coordinate and four-coordinate cobalt hydride complexes that react with dinitrogen. Journal of the American Chemical Society. 131: 10804-5. PMID 19621923 DOI: 10.1021/ja902812y  1
2009 Ding K, Pierpont AW, Brennessel WW, Lukat-Rodgers G, Rodgers KR, Cundari TR, Bill E, Holland PL. Cobalt-dinitrogen complexes with weakened N-N bonds. Journal of the American Chemical Society. 131: 9471-2. PMID 19537787 DOI: 10.1021/ja808783u  1
2009 Chiang KP, Barrett PM, Ding F, Smith JM, Kingsley S, Brennessel WW, Clark MM, Lachicotte RJ, Holland PL. Ligand dependence of binding to three-coordinate Fe(II) complexes. Inorganic Chemistry. 48: 5106-16. PMID 19438179 DOI: 10.1021/ic802440h  1
2009 Sadique AR, Brennessel WW, Holland PL. A diketiminate-bound diiron complex with a bridging carbonate ligand. Acta Crystallographica. Section C, Crystal Structure Communications. 65: m174-6. PMID 19407402 DOI: 10.1107/S0108270109011275  1
2009 Cowley RE, Bill E, Neese F, Brennessel WW, Holland PL. Iron(II) complexes with redox-active tetrazene (RNNNNR) ligands. Inorganic Chemistry. 48: 4828-36. PMID 19397284 DOI: 10.1021/ic900001y  1
2009 Cowley RE, Eckert NA, Elhaïk J, Holland PL. Catalytic nitrene transfer from an imidoiron(III) complex to form carbodiimides and isocyanates. Chemical Communications (Cambridge, England). 1760-2. PMID 19294287 DOI: 10.1039/b820620a  1
2009 Ding K, Dugan TR, Brennessel WW, Bill E, Holland PL. Synthesis, properties, and reactivity of diketiminate-supported cobalt fluoride complexes Organometallics. 28: 6650-6656. DOI: 10.1021/om900394t  1
2009 Ding K, Zannat F, Morris JC, Brennessel WW, Holland PL. Coordination of N-methylpyrrolidone to iron(II) Journal of Organometallic Chemistry. 694: 4204-4208. DOI: 10.1016/j.jorganchem.2009.09.005  1
2009 Rocks SS, Brennessel WW, Machonkin TE, Holland PL. Solid-state and proton NMR characterization of an iron(II) complex of a tridentate, facially coordinating N,N,O donor ligand Inorganica Chimica Acta. 362: 1387-1390. DOI: 10.1016/j.ica.2008.05.037  1
2008 Stoian SA, Smith JM, Holland PL, Münck E, Bominaar EL. Mössbauer, electron paramagnetic resonance, and theoretical study of a high-spin, four-coordinate Fe(II) diketiminate complex. Inorganic Chemistry. 47: 8687-95. PMID 18781730 DOI: 10.1021/ic8004568  1
2008 Holland PL. Electronic structure and reactivity of three-coordinate iron complexes. Accounts of Chemical Research. 41: 905-14. PMID 18646779 DOI: 10.1021/ar700267b  1
2008 Yu Y, Sadique AR, Smith JM, Dugan TR, Cowley RE, Brennessel WW, Flaschenriem CJ, Bill E, Cundari TR, Holland PL. The reactivity patterns of low-coordinate iron-hydride complexes. Journal of the American Chemical Society. 130: 6624-38. PMID 18444648 DOI: 10.1021/ja710669w  1
2008 Cowley RE, Elhaïk J, Eckert NA, Brennessel WW, Bill E, Holland PL. A bridging hexazene (RNNNNNNR) ligand from reductive coupling of azides. Journal of the American Chemical Society. 130: 6074-5. PMID 18419120 DOI: 10.1021/ja801375g  1
2008 Sadique AR, Brennessel WW, Holland PL. Reduction of CO2 to CO using low-coordinate iron: formation of a four-coordinate iron dicarbonyl complex and a bridging carbonate complex. Inorganic Chemistry. 47: 784-6. PMID 18171059 DOI: 10.1021/ic701914m  1
2008 Lees NS, McNaughton RL, Gregory WV, Holland PL, Hoffman BM. ENDOR characterization of a synthetic diiron hydrazido complex as a model for nitrogenase intermediates. Journal of the American Chemical Society. 130: 546-55. PMID 18092774 DOI: 10.1021/ja073934x  1
2007 Vela J, Zhu L, Flaschenriem CJ, Brennessel WW, Lachicotte RJ, Holland PL. Macrocyclic Binucleating β-Diketiminate Ligands and their Lithium, Aluminum, and Zinc Complexes. Organometallics. 26: 3416-3423. PMID 19132137 DOI: 10.1021/om0700258  1
2007 Yu Y, Brennessel WW, Holland PL. Borane B-C Bond Cleavage by a Low-Coordinate Iron Hydride Complex and N-N Bond Cleavage by the Hydridoborate Product. Organometallics. 26: 3217-3226. PMID 18725998 DOI: 10.1021/om7003805  1
2007 Sadique AR, Gregory EA, Brennessel WW, Holland PL. Mechanistic insight into N=N cleavage by a low-coordinate iron(II) hydride complex. Journal of the American Chemical Society. 129: 8112-21. PMID 17564444 DOI: 10.1021/ja069199r  1
2007 Vela J, Cirera J, Smith JM, Lachicotte RJ, Flaschenriem CJ, Alvarez S, Holland PL. Quantitative geometric descriptions of the belt iron atoms of the iron-molybdenum cofactor of nitrogenase and synthetic iron(II) model complexes. Inorganic Chemistry. 46: 60-71. PMID 17198413 DOI: 10.1021/ic0609148  1
2006 Eckert NA, Vaddadi S, Stoian S, Lachicotte RJ, Cundari TR, Holland PL. Coordination-number dependence of reactivity in an imidoiron(III) complex. Angewandte Chemie (International Ed. in English). 45: 6868-71. PMID 16991160 DOI: 10.1002/anie.200601927  1
2006 Hebden TJ, Brennessel WW, Flaschenriem CJ, Holland PL. A dinucleating ligand related to the beta-diketiminates. Dalton Transactions (Cambridge, England : 2003). 3855-7. PMID 16896444 DOI: 10.1039/b607440e  1
2006 Stoian SA, Vela J, Smith JM, Sadique AR, Holland PL, Münck E, Bominaar EL. Mössbauer and computational study of an N2-bridged diiron diketiminate complex: parallel alignment of the iron spins by direct antiferromagnetic exchange with activated dinitrogen. Journal of the American Chemical Society. 128: 10181-92. PMID 16881648 DOI: 10.1021/ja062051n  1
2006 Yu Y, Smith JM, Flaschenriem CJ, Holland PL. Binding affinity of alkynes and alkenes to low-coordinate iron. Inorganic Chemistry. 45: 5742-51. PMID 16841977 DOI: 10.1021/ic052136+  1
2006 Vela J, Vaddadi S, Kingsley S, Flaschenriem CJ, Lachicotte RJ, Cundari TR, Holland PL. Bidentate coordination of pyrazolate in low-coordinate iron(II) and nickel(II) complexes. Angewandte Chemie (International Ed. in English). 45: 1607-11. PMID 16470750 DOI: 10.1002/anie.200503535  1
2006 Smith JM, Sadique AR, Cundari TR, Rodgers KR, Lukat-Rodgers G, Lachicotte RJ, Flaschenriem CJ, Vela J, Holland PL. Studies of low-coordinate iron dinitrogen complexes. Journal of the American Chemical Society. 128: 756-69. PMID 16417365 DOI: 10.1021/ja052707x  1
2005 Eckert NA, Dinescu A, Cundari TR, Holland PL. A T-shaped three-coordinate nickel(I) carbonyl complex and the geometric preferences of three-coordinate d9 complexes. Inorganic Chemistry. 44: 7702-4. PMID 16241116 DOI: 10.1021/ic0510213  1
2005 Stoian SA, Yu Y, Smith JM, Holland PL, Bominaar EL, Münck E. Mössbauer, electron paramagnetic resonance, and crystallographic characterization of a high-spin Fe(I) diketiminate complex with orbital degeneracy. Inorganic Chemistry. 44: 4915-22. PMID 15998018 DOI: 10.1021/ic050321h  1
2005 Eckert NA, Stoian S, Smith JM, Bominaar EL, Münck E, Holland PL. Synthesis, structure, and spectroscopy of an oxodiiron(II) complex. Journal of the American Chemical Society. 127: 9344-5. PMID 15984842 DOI: 10.1021/ja0436704  1
2005 Vela J, Smith JM, Yu Y, Ketterer NA, Flaschenriem CJ, Lachicotte RJ, Holland PL. Synthesis and reactivity of low-coordinate iron(II) fluoride complexes and their use in the catalytic hydrodefluorination of fluorocarbons. Journal of the American Chemical Society. 127: 7857-70. PMID 15913376 DOI: 10.1021/ja042672l  1
2005 Holland PL. Low-coordinate iron complexes as synthetic models of nitrogenase Canadian Journal of Chemistry. 83: 296-301. DOI: 10.1139/v05-005  1
2005 Gregory EA, Lachicotte RJ, Holland PL. A cationic three-coordinate iron(II) complex and the reaction of β-diketiminate with ethyl diazoacetate Organometallics. 24: 1803-1805. DOI: 10.1021/om0489913  1
2004 Eckert NA, Smith JM, Lachicotte RJ, Holland PL. Low-coordinate iron(II) amido complexes of beta-diketiminates: synthesis, structure, and reactivity. Inorganic Chemistry. 43: 3306-21. PMID 15132641 DOI: 10.1021/ic035483x  1
2004 Vela J, Stoian S, Flaschenriem CJ, Münck E, Holland PL. A sulfido-bridged diiron(II) compound and its reactions with nitrogenase-relevant substrates. Journal of the American Chemical Society. 126: 4522-3. PMID 15070362 DOI: 10.1021/ja049417l  1
2004 Vela J, Vaddadi S, Cundari TR, Smith JM, Gregory EA, Lachicotte RJ, Flaschenriem CJ, Holland PL. Reversible beta-hydrogen elimination of three-coordinate iron(II) alkyl complexes: Mechanistic and thermodynamic studies Organometallics. 23: 5226-5239. DOI: 10.1021/om049415+  1
2004 Holland PL. Nitrogen Fixation Comprehensive Coordination Chemistry Ii. 8: 569-599. DOI: 10.1016/B0-08-043748-6/08140-8  1
2003 Smith JM, Lachicotte RJ, Holland PL. N=N bond cleavage by a low-coordinate ironII hydride complex. Journal of the American Chemical Society. 125: 15752-3. PMID 14677959 DOI: 10.1021/ja038152s  1
2003 Jazdzewski BA, Reynolds AM, Holland PL, Young VG, Kaderli S, Zuberbühler AD, Tolman WB. Copper(I)-phenolate complexes as models of the reduced active site of galactose oxidase: synthesis, characterization, and O2 reactivity. Journal of Biological Inorganic Chemistry : Jbic : a Publication of the Society of Biological Inorganic Chemistry. 8: 381-93. PMID 12761659 DOI: 10.1007/s00775-002-0420-9  1
2003 Eckert NA, Bones EM, Lachicotte RJ, Holland PL. Nickel complexes of a bulky beta-diketiminate ligand. Inorganic Chemistry. 42: 1720-5. PMID 12611544 DOI: 10.1021/ic025986n  1
2002 Vela J, Smith JM, Lachicotte RJ, Holland PL. Alkyl isomerisation in three-coordinate iron(II) complexes. Chemical Communications (Cambridge, England). 2886-7. PMID 12478796  1
2002 Holland PL, Cundari TR, Perez LL, Eckert NA, Lachicotte RJ. Electronically unsaturated three-coordinate chloride and methyl complexes of iron, cobalt, and nickel. Journal of the American Chemical Society. 124: 14416-24. PMID 12452717 DOI: 10.1021/ja025583m  1
2002 Spencer DJ, Reynolds AM, Holland PL, Jazdzewski BA, Duboc-Toia C, Le Pape L, Yokota S, Tachi Y, Itoh S, Tolman WB. Copper chemistry of beta-diketiminate ligands: monomer/dimer equilibria and a new class of bis(mu-oxo)dicopper compounds. Inorganic Chemistry. 41: 6307-21. PMID 12444774 DOI: 10.1021/ic020369k  1
2002 Andres H, Bominaar EL, Smith JM, Eckert NA, Holland PL, Münck E. Planar three-coordinate high-spin Fe(II) complexes with large orbital angular momentum: Mössbauer, electron paramagnetic resonance, and electronic structure studies. Journal of the American Chemical Society. 124: 3012-25. PMID 11902893 DOI: 10.1021/ja012327l  1
2002 Spencer DJ, Aboelella NW, Reynolds AM, Holland PL, Tolman WB. beta-diketiminate ligand backbone structural effects on Cu(I)/O(2) reactivity: unique copper-superoxo and bis(mu-oxo) complexes. Journal of the American Chemical Society. 124: 2108-9. PMID 11878952 DOI: 10.1021/ja017820b  1
2002 Smith JM, Lachicotte RJ, Holland PL. Three-coordinate, 12-electron organometallic complexes of iron(II) supported by a bulky β-diketiminate ligand: Synthesis and insertion of CO to give square-pyramidal complexes Organometallics. 21: 4808-4814. DOI: 10.1021/om020571v  1
2002 Chowdhury A, Peteanu LA, Holland PL, Tolman WB. The electronic properties of a model active site for blue copper proteins as probed by Stark spectroscopy Journal of Physical Chemistry B. 106: 3007-3012. DOI: 10.1021/jp0115751  1
2001 Smith JM, Lachicotte RJ, Holland PL. Tuning metal coordination number by ancillary ligand steric effects: synthesis of a three-coordinate iron(II) complex. Chemical Communications (Cambridge, England). 1542-3. PMID 12240372  1
2001 Jazdzewski BA, Holland PL, Pink M, Young VG, Spencer DJ, Tolman WB. Three-coordinate copper(II)-phenolate complexes. Inorganic Chemistry. 40: 6097-107. PMID 11703106 DOI: 10.1021/ic010615c  1
2001 Smith JM, Lachicotte RJ, Pittard KA, Cundari TR, Lukat-Rodgers G, Rodgers KR, Holland PL. Stepwise reduction of dinitrogen bond order by a low-coordinate iron complex. Journal of the American Chemical Society. 123: 9222-3. PMID 11552855 DOI: 10.1021/ja016094+  1
2000 Lam BM, Halfen JA, Young VG, Hagadorn JR, Holland PL, Lledós A, Cucurull-Sánchez L, Novoa JJ, Alvarez S, Tolman WB. Ligand macrocycle structural effects on copper-dioxygen reactivity. Inorganic Chemistry. 39: 4059-72. PMID 11198861 DOI: 10.1021/ic000248p  1
2000 Itoh S, Taki M, Nakao H, Holland PL, Tolman WB, Que Jr, Fukuzumi S. Aliphatic Hydroxylation by a Bis(µ-oxo)dicopper(III) Complex. Angewandte Chemie (International Ed. in English). 39: 398-400. PMID 10649424 DOI: 10.1002/(SICI)1521-3773(20000117)39:2<398::AID-ANIE398>3.0.CO;2-2  1
2000 Holland PL, Cramer CJ, Wilkinson EC, Mahapatra S, Rodgers KR, Itoh S, Taki M, Fukuzumi S, Que L, Tolman WB. Resonance Raman spectroscopy as a probe of the bis(μ-oxo)dicopper core Journal of the American Chemical Society. 122: 792-802. DOI: 10.1021/ja992003l  1
2000 Meggers E, Holland PL, Tolman WB, Romesberg FE, Schultz PG. A novel copper-mediated DNA base pair [6] Journal of the American Chemical Society. 122: 10714-10715. DOI: 10.1021/ja0025806  1
2000 Randall DW, George SD, Holland PL, Hedman B, Hodgson KO, Tolman WB, Solomon EI. Spectroscopic and electronic structural studies of blue copper model complexes. 2. Comparison of three-and four-coordinate Cu(II)-thiolate complexes and fungal laccase Journal of the American Chemical Society. 122: 11632-11648. DOI: 10.1021/ja001592o  1
2000 Holland PL, Tolman WB. A structural model of the type 1 copper protein active site: N2S(thiolate)s(thioether) ligation in a Cu(II) complex [23] Journal of the American Chemical Society. 122: 6331-6332. DOI: 10.1021/ja001328v  1
1999 Holland PL, Rodgers KR, Tolman WB. Is the Bis(μ-oxo)dicopper Core Capable of Hydroxylating an Arene? Angewandte Chemie (International Ed. in English). 38: 1139-42. PMID 25138522 DOI: 10.1002/(SICI)1521-3773(19990419)38:8<1139::AID-ANIE1139>3.0.CO;2-0  1
1999 Cahoy J, Holland PL, Tolman WB. Experimental Studies of the Interconversion of &mgr;-eta(2):eta(2)-Peroxo- and Bis(&mgr;-oxo)dicopper Complexes. Inorganic Chemistry. 38: 2161-2168. PMID 11671001  1
1999 Holland PL, Tolman WB. Three-coordinate Cu(II) complexes: Structural models of trigonal-planar type 1 copper protein active sites [5] Journal of the American Chemical Society. 121: 7270-7271. DOI: 10.1021/ja991533e  1
1999 Holland PL, Tolman WB. Dioxygen activation by copper sites: Relative stability and reactivity of (μ-η2:η2-peroxo)- and bis(μ-oxo)dicopper cores Coordination Chemistry Reviews. 190: 855-869. DOI: 10.1016/S0010-8545(99)00125-3  1
1999 Holland PL, Andersen RA, Bergman RG. Application of the E-C approach to understanding the bond energies thermodynamics of late-metal amido, aryloxo and alkoxo complexes: An alternative to pπ/dπ repulsion Comments On Inorganic Chemistry. 21: 115-129.  1
1999 Cahoy J, Holland PL, Tolman WB. Experimental studies of the interconversion of μ-η2:η2-peroxo- and bis(μ-oxo)dicopper complexes Inorganic Chemistry. 38: 2161-2168.  1
1998 Golden JT, Peterson TH, Holland PL, Bergman RG, Andersen RA. Adduct formation and single and double deprotonation of Cp*(PMe3)Ir(H)2 with main group metal alkyls and aryls: Synthesis and structure of three novel Ir-Al and Ir-Mg heterobimetallics Journal of the American Chemical Society. 120: 223-224. DOI: 10.1021/ja973230v  1
1998 Holland PL, Andersen RA, Bergman RG. Cyclopentadienyl and imide ligand transfer from zirconium to iridium: Can early transition metal imido compounds be used as imide transfer reagents? Organometallics. 17: 433-437.  1
1997 Holland PL, Smith ME, Andersen RA, Bergman RG. X-ray crystal structures of Cp*Ni(PEt3)X [X = Br, O(p-C6H4Me), NH(p- C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3 +]. Understanding distortions and trans influences in cyclopentadienyl complexes Journal of the American Chemical Society. 119: 12815-12823. DOI: 10.1021/ja971830o  1
1997 Holland PL, Andersen RA, Bergman RG, Huang J, Nolan SP. Monomeric cyclopentadienylnickel methoxo and amido complexes: Synthesis, characterization, reactivity, and use for exploring the relationship between H-X and M-X bond energies Journal of the American Chemical Society. 119: 12800-12814. DOI: 10.1021/ja971829p  1
1996 Holland PL, Andersen RA, Bergman RG. Synthesis, characterization, isomerization, and reactivity of dimeric cyclopentadienylnickel amido complexes Journal of the American Chemical Society. 118: 1092-1104. DOI: 10.1021/ja952882l  1
Show low-probability matches.