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Kenneth G. Caulton, Ph.D. - Publications

Affiliations: 
Chemistry Indiana University, Bloomington, Bloomington, IN, United States 
Area:
Catalysis, transition metal hydride chemistry
Website:
http://caulton.chem.indiana.edu/
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350 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2021 Beagan DM, Cabelof AC, Pepin R, Pink M, Carta V, Caulton KG. An Integrated View of Nitrogen Oxyanion Deoxygenation in Solution Chemistry and Electrospray Ion Production. Inorganic Chemistry. 60: 17241-17248. PMID 34705459 DOI: 10.1021/acs.inorgchem.1c02591  0.319
2021 Caulton KG, Beagan DM, Maciulis NA, Pink M, Carta V, Huerfano IJ, Chen CH. A Redox-active Tetrazine-based Pincer Ligand for the Reduction of N-oxyanions Using a Redox-inert Metal. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 34008888 DOI: 10.1002/chem.202101302  0.389
2021 Cabelof AC, Carta V, Caulton KG. A proton-responsive ligand becomes a dimetal linker for multisubstrate assembly nitrate deoxygenation. Chemical Communications (Cambridge, England). PMID 33598673 DOI: 10.1039/d0cc07886g  0.307
2021 Beagan DM, Cabelof AC, Caulton KG. Back donation, intramolecular electron transfer and N-O bond scission targeting nitrogen oxyanion reduction: how can a metal complex assist? Dalton Transactions (Cambridge, England : 2003). PMID 33491695 DOI: 10.1039/d0dt03430d  0.32
2020 Cabelof AC, Carta V, Chen CH, Caulton KG. Nitrogen oxyanion reduction by Co(ii) augmented by a proton responsive ligand: recruiting multiple metals. Dalton Transactions (Cambridge, England : 2003). PMID 32478346 DOI: 10.1039/D0Dt01298J  0.429
2020 Labrum NS, Cabelof AC, Caulton KG. A Dimeric Chromium(II) Pincer as an Electron Shuttle for N=N Bond Scission. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32428366 DOI: 10.1002/Chem.202001749  0.354
2020 Sorsche DU, Miehlich M, Searles K, Gouget G, Zolnhofer EM, Fortier S, Chen CH, Gau MR, Carroll PJ, Murray CB, Caulton KG, Khusniyarov MM, Meyer K, Mindiola DJ. Unusual Dinitrogen Binding and Electron Storage in Dinuclear Iron Complexes. Journal of the American Chemical Society. PMID 32239927 DOI: 10.1021/Jacs.0C01488  0.368
2020 Labrum NS, Curtin GM, Jakubikova E, Caulton KG. The Influence of Nucleophilic and Redox Pincer Character, and Alkali Metals, on Capture of Oxygen Substrates: The Case of Chromium(II). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 32189384 DOI: 10.1002/Chem.202000457  0.361
2020 Beagan DM, Carta V, Caulton KG. A reagent for heteroatom borylation, including iron mediated reductive deoxygenation of nitrate yielding a dinitrosyl complex. Dalton Transactions (Cambridge, England : 2003). PMID 31956885 DOI: 10.1039/D0Dt00077A  0.322
2019 Labrum NS, Caulton KG. [Cr(pincer)] as an electron shuttle for reductively promoted hydrazine disproportionation. Dalton Transactions (Cambridge, England : 2003). PMID 31310268 DOI: 10.1039/C9Dt02300C  0.438
2019 Beagan DM, Huerfano IJ, Polezhaev AV, Caulton KG. Reductive Silylation using a bis-silylated diaza-2,5-cyclohexadiene. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30994211 DOI: 10.1002/Chem.201900879  0.326
2019 Labrum NS, Chen CH, Caulton KG. A bis-pyrazolate Pincer on Reduced Cr Deoxygenates CO2: Selective Capture of the Derived Oxide by Cr(II). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30964571 DOI: 10.1002/Chem.201901134  0.309
2019 Morris TW, Huerfano IJ, Wang M, Wisman DL, Cabelof AC, Din NU, Tempas CD, Le D, Polezhaev AV, Rahman TS, Caulton KG, Tait SL. Multi-electron Reduction Capacity and Multiple Binding Pockets in Metal-organic Redox Assembly at Surfaces. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30746807 DOI: 10.1002/Chem.201900002  0.361
2019 Seo J, Cabelof AC, Chen CH, Caulton KG. Selective deoxygenation of nitrate to nitrosyl using trivalent chromium and the Mashima reagent: reductive silylation. Chemical Science. 10: 475-479. PMID 30746094 DOI: 10.1039/C8Sc02979B  0.316
2019 Cook BJ, Chen C, Pink M, Caulton KG. Gross rearrangement of Fe(II) aggregate structure by replacement of two H+ by two Li+: Visualizing altered structure of acid versus conjugate base Polyhedron. 174: 114152. DOI: 10.1016/J.Poly.2019.114152  0.34
2019 Labrum NS, Seo J, Chen C, Pink M, Beagan DM, Caulton KG. Di- and trivalent chromium bis(pyrazol-3-yl)pyridine pincer complexes with good leaving groups Inorganica Chimica Acta. 486: 483-491. DOI: 10.1016/J.Ica.2018.11.007  0.404
2019 Labrum NS, Chen C, Caulton KG. A new face for bis(pyrazol-3-yl)pyridine: Incompatible geometric preferences dictates unprecedented pincer ligand connectivity Inorganica Chimica Acta. 485: 54-57. DOI: 10.1016/J.Ica.2018.09.058  0.344
2019 Cook BJ, Lord RL, Chen C, Caulton KG. Gauging the Redox Non-Innocence of a Highly Pi-Acidic Bis-Tetrazine Pincer Ligand European Journal of Inorganic Chemistry. 2019: 2535-2542. DOI: 10.1002/Ejic.201900186  0.306
2019 Labrum NS, Pink M, Chen C, Caulton KG. Reactivity of an Unusual Divalent Chromium Aggregate Supported by a Multifunctional Bis(pyrazolate) Pincer Ligand European Journal of Inorganic Chemistry. 2019: 1932-1940. DOI: 10.1002/Ejic.201900033  0.328
2018 Labrum NS, Losovyj Y, Caulton KG. A new access route to dimetal sandwich complexes, including a radical anion. Chemical Communications (Cambridge, England). 54: 12397-12399. PMID 30328415 DOI: 10.1039/C8Cc05204B  0.355
2018 Maciulis NA, Schaugaard RN, Losovyj Y, Chen CH, Pink M, Caulton KG. Seeking Redox Activity in a Tetrazinyl Pincer Ligand: Installing Zerovalent Cr and Mo. Inorganic Chemistry. PMID 30281295 DOI: 10.1021/Acs.Inorgchem.8B01761  0.353
2018 Tempas CD, Skomski D, Cook BJ, Le D, Smith KA, Rahman TS, Caulton KG, Tait SL. Redox Isomeric Surface Structures are Preferred over Odd-electron Pt(1+). Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 30028543 DOI: 10.1002/Chem.201802943  0.341
2018 Cook BJ, Pink M, Pal K, Caulton KG. Electron and Oxygen Atom Transfer Chemistry of Co(II) in a Proton Responsive, Redox Active Ligand Environment. Inorganic Chemistry. PMID 29741888 DOI: 10.1021/Acs.Inorgchem.8B00816  0.655
2018 Tempas CD, Morris TW, Wisman DL, Le D, Din NU, Williams CG, Wang M, Polezhaev AV, Rahman TS, Caulton KG, Tait SL. Redox-active ligand controlled selectivity of vanadium oxidation on Au(100). Chemical Science. 9: 1674-1685. PMID 29675215 DOI: 10.1039/C7Sc04752E  0.323
2018 Polezhaev AV, Beagan DM, Cabelof AC, Chen CH, Caulton KG. A substituent-tolerant synthetic approach to N/P-"loaded" heteroarenes. Dalton Transactions (Cambridge, England : 2003). PMID 29658560 DOI: 10.1039/C8Dt00533H  0.419
2018 Cook BJ, Chen CG, Caulton KG. A Multifunctional Pincer Ligand for Cobalt-promoted Oxidation by N2O. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29437249 DOI: 10.1002/Chem.201800086  0.367
2018 Cook BJ, Chen CH, Pink M, Caulton KG. Dehydrohalogenation of proton responsive complexes: versatile aggregation via pyrazolate pincer ligand arms. Dalton Transactions (Cambridge, England : 2003). PMID 29354830 DOI: 10.1039/C7Dt04253A  0.443
2018 Cook BJ, Polezhaev AV, Chen C, Pink M, Caulton KG. A multimetal-ligand cooperative approach to CO2 activation Inorganica Chimica Acta. 483: 510-515. DOI: 10.1016/J.Ica.2018.08.039  0.385
2017 Polezhaev AV, Liss CJ, Telser J, Chen CH, Caulton KG. A PNNH Pincer Ligand Allows Access to Monovalent Iron. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 29105162 DOI: 10.1002/Chem.201703795  0.381
2017 Polezhaev AV, Chen CH, Kinne AS, Cabelof AC, Lord RL, Caulton KG. Ligand Design toward Multifunctional Substrate Reductive Transformations. Inorganic Chemistry. PMID 28763211 DOI: 10.1021/Acs.Inorgchem.7B00785  0.419
2017 Polezhaev AV, Chen CH, Losovyj Y, Caulton KG. A Multifunctional Pincer Ligand Supports Unsaturated Cobalt: Five Functionalities in One Pincer. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 28370572 DOI: 10.1002/Chem.201700859  0.421
2017 Cook BJ, Polezhaev AV, Chen C, Pink M, Caulton KG. Deprotonation, Chloride Abstraction, and Dehydrohalogenation as Synthetic Routes to Bis-Pyrazolate Pyridyl Iron(II) Complexes European Journal of Inorganic Chemistry. 2017: 3999-4012. DOI: 10.1002/Ejic.201700558  0.438
2016 Polezhaev AV, Maciulis NA, Chen CH, Pink M, Lord RL, Caulton KG. Tetrazine Assists Reduction of Water by Phosphines: Application in the Mitsunobu Reaction. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27535201 DOI: 10.1002/Chem.201600913  0.342
2016 Cook BJ, Chen C, Pink M, Lord RL, Caulton KG. Coordination and electronic characteristics of a nitrogen heterocycle pincer ligand Inorganica Chimica Acta. 451: 82-91. DOI: 10.1016/J.Ica.2016.07.011  0.413
2015 Skomski D, Tempas CD, Cook BJ, Polezhaev AV, Smith KA, Caulton KG, Tait SL. Two- and Three-Electron Oxidation of Single-Site Vanadium Centers at Surfaces by Ligand Design. Journal of the American Chemical Society. 137: 7898-902. PMID 26029790 DOI: 10.1021/Jacs.5B03706  0.338
2014 Hui AK, Lord RL, Caulton KG. In search of redox non-innocence between a tetrazine pincer ligand and monovalent copper. Dalton Transactions (Cambridge, England : 2003). 43: 7958-63. PMID 24718554 DOI: 10.1039/C3Dt52490F  0.328
2014 Benson CR, Hui AK, Parimal K, Cook BJ, Chen CH, Lord RL, Flood AH, Caulton KG. Multiplying the electron storage capacity of a bis-tetrazine pincer ligand. Dalton Transactions (Cambridge, England : 2003). 43: 6513-24. PMID 24623103 DOI: 10.1039/C4Dt00341A  0.346
2014 Hui AK, Cook BJ, Mindiola DJ, Caulton KG. Transition metal chlorides are Lewis acids toward terminal chloride attached to late transition metals. Inorganic Chemistry. 53: 3307-10. PMID 24611984 DOI: 10.1021/Ic402107Z  0.336
2014 Hui AK, Losovyj Y, Lord RL, Caulton KG. Chemical implications of incompatible ligand versus metal coordination geometry preferences. Inorganic Chemistry. 53: 3039-47. PMID 24601536 DOI: 10.1021/Ic402866E  0.369
2014 Hui AK, Chen CH, Terwilliger AM, Lord RL, Caulton KG. A tale of hydrogen abstraction, initially detected via X-ray diffraction. Acta Crystallographica. Section C, Structural Chemistry. 70: 250-5. PMID 24594711 DOI: 10.1107/S2053229614003234  0.453
2014 Komine N, Buell RW, Chen CH, Hui AK, Pink M, Caulton KG. Probing the steric and electronic characteristics of a new bis-pyrrolide pincer ligand. Inorganic Chemistry. 53: 1361-9. PMID 24410079 DOI: 10.1021/Ic402120R  0.417
2014 Flores JA, Pal K, Carroll ME, Pink M, Karty JA, Mindiola DJ, Caulton KG. Mechanistic understanding of a silver pyridylpyrrolide as a catalyst for 3 + 2 cyclization of a nitrile with diazo ester Organometallics. 33: 1544-1552. DOI: 10.1021/Om400756T  0.649
2013 Fortier S, Le Roy JJ, Chen CH, Vieru V, Murugesu M, Chibotaru LF, Mindiola DJ, Caulton KG. A dinuclear cobalt complex featuring unprecedented anodic and cathodic redox switches for single-molecule magnet activity. Journal of the American Chemical Society. 135: 14670-8. PMID 23991708 DOI: 10.1021/Ja405284T  0.325
2013 Tsvetkov NP, Chen CH, Andino JG, Lord RL, Pink M, Buell RW, Caulton KG. Synthesis and oxidative reactivity of 2,2'-pyridylpyrrolide complexes of Ni(II). Inorganic Chemistry. 52: 9511-21. PMID 23909696 DOI: 10.1021/Ic4011746  0.437
2013 Searles K, Das AK, Buell RW, Pink M, Chen CH, Pal K, Morgan DG, Mindiola DJ, Caulton KG. 2,2'-Pyridylpyrrolide ligand redistribution following reduction. Inorganic Chemistry. 52: 5611-9. PMID 23601057 DOI: 10.1021/Ic400803E  0.681
2013 Tsvetkov NP, Andino JG, Fan H, Verat AY, Caulton KG. Reactivity of the terminal oxo species (((t)Bu2PCH2SiMe2)2N)RhO. Dalton Transactions (Cambridge, England : 2003). 42: 6745-55. PMID 23571602 DOI: 10.1039/C3Dt31972E  0.417
2013 Andino JG, Mazumder S, Pal K, Caulton KG. New approaches to functionalizing metal-coordinated N2. Angewandte Chemie (International Ed. in English). 52: 4726-32. PMID 23554010 DOI: 10.1002/Anie.201209168  0.684
2013 Komine N, Flores JA, Pal K, Caulton KG, Mindiola DJ. Büchner reactions catalyzed by a silver(I) pyridylpyrrolide: Understanding arene C=C insertion selectivity Organometallics. 32: 3185-3191. DOI: 10.1021/Om301240D  0.675
2013 Searles K, Das AK, Buell RW, Pink M, Chen C, Pal K, Morgan DG, Mindiola DJ, Caulton KG. Correction to 2,2′-Pyridylpyrrolide Ligand Redistribution Following Reduction Inorganic Chemistry. 52: 6231-6231. DOI: 10.1021/Ic401081M  0.647
2013 Andino JG, Mazumder S, Pal K, Caulton KG. Neue Ansätze zur Funktionalisierung von metallkoordiniertem N2 Angewandte Chemie. 125: 4824-4831. DOI: 10.1002/Ange.201209168  0.595
2012 Fortier S, González-del Moral O, Chen CH, Pink M, Le Roy JJ, Murugesu M, Mindiola DJ, Caulton KG. Probing the redox non-innocence of dinuclear, three-coordinate Co(II) nindigo complexes: not simply β-diketiminate variants. Chemical Communications (Cambridge, England). 48: 11082-4. PMID 23042486 DOI: 10.1039/C2Cc34560A  0.353
2012 Searles K, Pink M, Caulton KG, Mindiola DJ. An iridium-pyridylpyrrolide complex exhibiting reversible binding of H2. Dalton Transactions (Cambridge, England : 2003). 41: 9619-22. PMID 22766760 DOI: 10.1039/C2Dt30981E  0.463
2012 Flores JA, Komine N, Pal K, Pinter B, Pink M, Chen CH, Caulton KG, Mindiola DJ. Silver(I)-catalyzed insertion of carbene into alkane C-H bonds and the origin of the special challenge of methane activation using DFT as a mechanistic probe Acs Catalysis. 2: 2066-2078. DOI: 10.1021/Cs300256B  0.674
2012 Caulton KG. Systematics and future projections concerning redox-noninnocent amide/imine ligands European Journal of Inorganic Chemistry. 435-443. DOI: 10.1002/Ejic.201100623  0.369
2011 Flores JA, Andino JG, Tsvetkov NP, Pink M, Wolfe RJ, Head AR, Lichtenberger DL, Massa J, Caulton KG. Assessment of the electronic structure of 2,2'-pyridylpyrrolides as ligands. Inorganic Chemistry. 50: 8121-31. PMID 21776969 DOI: 10.1021/Ic2005503  0.6
2011 Andino JG, Caulton KG. Mechanism of N/O bond scission of N2O by an unsaturated rhodium transient. Journal of the American Chemical Society. 133: 12576-83. PMID 21696206 DOI: 10.1021/Ja202439G  0.351
2011 Fullmer BC, Fan H, Pink M, Huffman JC, Tsvetkov NP, Caulton KG. Three-coordinate NiII: tracing the origin of an unusual, facile Si-C(sp3) bond cleavage in [(tBu2PCH2SiMe2)2N]Ni+. Journal of the American Chemical Society. 133: 2571-82. PMID 21306156 DOI: 10.1021/Ja108426F  0.424
2011 Tsvetkov N, Fan H, Caulton KG. An evaluation of monovalent osmium supported by the PNP ligand environment. Dalton Transactions (Cambridge, England : 2003). 40: 1105-10. PMID 21165461 DOI: 10.1039/C0Dt00989J  0.443
2011 Laird MF, Tsvetkov NP, Pink M, He T, Buell RW, Caulton KG. Selectivity of attack on a Si-C(sp3) sigma bond coordinated to NiII Inorganica Chimica Acta. 374: 79-87. DOI: 10.1016/J.Ica.2010.12.061  0.442
2011 Fullmer BC, Fan H, Pink M, Caulton KG. Evaluating the reducing power of 3-coordinate T-shaped NiI Inorganica Chimica Acta. 369: 49-54. DOI: 10.1016/J.Ica.2010.12.059  0.465
2010 Andino JG, Flores JA, Karty JA, Massa JP, Park H, Tsvetkov NP, Wolfe RJ, Caulton KG. Ligand influence on metal aggregation: a unique bonding mode for pyridylpyrrolides. Inorganic Chemistry. 49: 7626-8. PMID 20687530 DOI: 10.1021/Ic100878S  0.378
2010 He T, Tsvetkov NP, Andino JG, Gao X, Fullmer BC, Caulton KG. Mechanism of heterolysis of H2 by an unsaturated d8 nickel center: via tetravalent nickel? Journal of the American Chemical Society. 132: 910-1. PMID 20043681 DOI: 10.1021/Ja908674X  0.449
2010 Walstrom A, Fan H, Pink M, Caulton KG. Unexpected selectivity in electrophilic attack on (PNP)RuN Inorganica Chimica Acta. 363: 633-636. DOI: 10.1016/J.Ica.2008.11.010  0.41
2010 Tsvetkov N, Pink M, Fan H, Lee JH, Caulton KG. Redox and lewis acid reactivity of unsaturated OsII European Journal of Inorganic Chemistry. 4790-4800. DOI: 10.1002/Ejic.201000503  0.597
2009 Walstrom AG, Pink M, Yang X, Caulton KG. Synthesis and reactivity of a Ru(I) dimer devoid of pi-acid ligands. Dalton Transactions (Cambridge, England : 2003). 6001-6. PMID 19623400 DOI: 10.1039/B902759A  0.649
2009 Tsvetkov NP, Laird MF, Fan H, Pink M, Caulton KG. Surprising isomer preference on Ir(III), favoring facile H-C(sp(3)) bond cleavage. Chemical Communications (Cambridge, England). 4578-80. PMID 19617989 DOI: 10.1039/B908954C  0.443
2008 Fan H, Fullmer BC, Pink M, Caulton KG. [Ni{N(SiMe2CH2PtBu2)2}]+: direct observation of transannular Si-C(sp3) bond coordination. Angewandte Chemie (International Ed. in English). 47: 9112-4. PMID 18925605 DOI: 10.1002/Anie.200802654  0.328
2008 Walstrom AN, Fullmer BC, Fan H, Pink M, Buschhorn DT, Caulton KG. Influence of the metal orbital occupancy and principal quantum number on organoazide (RN3) conversion to transition-metal imide complexes. Inorganic Chemistry. 47: 9002-9. PMID 18759426 DOI: 10.1021/Ic801035Z  0.357
2008 Verat AY, Fan H, Pink M, Chen YS, Caulton KG. Spin state, structure, and reactivity of terminal oxo and dioxygen complexes of the (PNP)Rh moiety. Chemistry (Weinheim An Der Bergstrasse, Germany). 14: 7680-6. PMID 18680118 DOI: 10.1002/chem.200800573  0.303
2008 Buschhorn D, Pink M, Fan H, Caulton KG. Nitrogen-ligated iron complexes: photolytic approach to the FeN+ moiety. Inorganic Chemistry. 47: 5129-35. PMID 18479124 DOI: 10.1021/Ic702279B  0.341
2008 Fullmer BC, Pink M, Fan H, Yang X, Baik MH, Caulton KG. The effect of one valence electron: contrasting (PNP)Ni(CO) with (PNP)Ni(NO) to understand the half-bent NiNO unit. Inorganic Chemistry. 47: 3888-92. PMID 18355049 DOI: 10.1021/Ic702503M  0.556
2008 Ingleson MJ, Pink M, Fan H, Caulton KG. Redox chemistry of the triplet complex (PNP)Co(I). Journal of the American Chemical Society. 130: 4262-76. PMID 18331026 DOI: 10.1021/Ja074378+  0.671
2008 Fullmer BC, Fan H, Pink M, Caulton KG. O/C bond cleavage of CO2 by NiI. Inorganic Chemistry. 47: 1865-7. PMID 18284191 DOI: 10.1021/Ic701843U  0.342
2008 Ingleson MJ, Fullmer BC, Buschhorn DT, Fan H, Pink M, Huffman JC, Caulton KG. Influence of the d-Electron Count on CO binding by three-coordinate [(tBu2PCH2SiMe2)2N]Fe, -Co, and -Ni. Inorganic Chemistry. 47: 407-9. PMID 18154331 DOI: 10.1021/Ic7023764  0.605
2008 Verat AY, Pink M, Fan H, Tomaszewski J, Caulton KG. [(tBu2PCH2SiMe2) 2N]Rhi? Rapidly reversible H-C(sp3) and H-C(sp2) bond cleavage by rhodium(I) Organometallics. 27: 166-168. DOI: 10.1021/Om701165N  0.443
2008 Lee JH, Caulton KG. Coupling of terminal alkynes by RuHXL2 (X = Cl or N(SiMe3)2, L = PiPr3) Journal of Organometallic Chemistry. 693: 1664-1673. DOI: 10.1016/J.Jorganchem.2007.12.016  0.537
2008 Lee JH, Pink M, Smurnyy YD, Caulton KG. Mechanism of alkyne conversion to carbyne by 14- or 16-electron Os(H)2ClL2X (L = PiPr3; X = OTf or B(C6H3(CF3)2)4) Journal of Organometallic Chemistry. 693: 1426-1438. DOI: 10.1016/J.Jorganchem.2007.07.031  0.588
2008 Verat AY, Pink M, Fan H, Fullmer BC, Telser J, Caulton KG. Reactivity of the radical NO with a masked form of 14 valence electron (PNP)Rh: Forming Rh(0, I or II)? European Journal of Inorganic Chemistry. 4704-4709. DOI: 10.1002/Ejic.200800256  0.408
2007 Ingleson MJ, Pink M, Fan H, Caulton KG. Exploring the reactivity of four-coordinate PNPCoX with access to three-coordinate spin triplet PNPCo. Inorganic Chemistry. 46: 10321-34. PMID 17956087 DOI: 10.1021/Ic701171P  0.64
2007 Walstrom A, Pink M, Fan H, Tomaszewski J, Caulton KG. Radical (NO) and nonradical (N(2)O) reagents convert a ruthenium(IV) nitride to the same nitrosyl complex. Inorganic Chemistry. 46: 7704-6. PMID 17705469 DOI: 10.1021/Ic700789Y  0.371
2007 Lee JH, Pink M, Tomaszewski J, Fan H, Caulton KG. Facile hydrogenation of N2O by an operationally unsaturated osmium polyhydride. Journal of the American Chemical Society. 129: 8706-7. PMID 17580865 DOI: 10.1021/Ja071452F  0.565
2007 Yang X, Walstrom A, Tsvetkov N, Pink M, Caulton KG. Influence of chelate substituents on the structure and spin state of unsaturated [N(SiMe2CH2PtBu2)2]Ru-X. Inorganic Chemistry. 46: 4612-6. PMID 17461579 DOI: 10.1021/Ic070283X  0.586
2007 Ozerov OV, Watson LA, Pink M, Caulton KG. Operationally unsaturated pincer/rhenium complexes form metal carbenes from cycloalkenes and metal carbynes from alkanes. Journal of the American Chemical Society. 129: 6003-16. PMID 17429964 DOI: 10.1021/Ja062327R  0.787
2007 Lee JH, Fan H, Pink M, Caulton KG. Reactivity of •NO with an osmium polyhydride: Reductive elimination and reductive nitrosylation on the path from odd- to even-electron molecules New Journal of Chemistry. 31: 838-840. DOI: 10.1039/B702078C  0.565
2007 Fan H, Caulton KG. 2-Electron reduction of N2O yields a new ligand binding mode: N-Nitrosoimide Polyhedron. 26: 4731-4736. DOI: 10.1016/J.Poly.2007.05.035  0.379
2007 Lee JH, Vedernikov AN, Dye D, Caulton KG. NO binds to unsaturated Os(IV) polyhydrides as a redox reagent Journal of Organometallic Chemistry. 692: 3121-3132. DOI: 10.1016/J.Jorganchem.2007.01.059  0.709
2007 Kuhlman RL, Vaartstra BA, Caulton KG, Tanner PS, Hanusa TP. Bis(1,1,1,3,3,3‐Hexamethyldisilazanato)‐Bis(Tetrahydrofuran)Barium Inorganic Syntheses. 31: 8-10. DOI: 10.1002/9780470132623.Ch2  0.321
2006 Walstrom A, Pink M, Caulton KG. Si-N bond hydrolysis furnishes a planar 4-coordinate 14-electron Ru(II) complex with a triplet ground state. Inorganic Chemistry. 45: 5617-20. PMID 16813426 DOI: 10.1021/Ic0601743  0.439
2006 Ingleson MJ, Pink M, Caulton KG. Reducing power of three-coordinate cobalt(I). Journal of the American Chemical Society. 128: 4248-9. PMID 16568998 DOI: 10.1021/Ja0607279  0.591
2006 Ingleson M, Fan H, Pink M, Tomaszewski J, Caulton KG. Three-coordinate Co(I) provides access to unsaturated dihydrido-Co(III) and seven-coordinate Co(V). Journal of the American Chemical Society. 128: 1804-5. PMID 16464075 DOI: 10.1021/Ja0572452  0.682
2006 Lee JH, Pink M, Caulton KG. Triple benzylic dehydrogenation by osmium in an amide ligand environment Organometallics. 25: 802-804. DOI: 10.1021/Om050916K  0.581
2006 Ingleson MJ, Pink M, Huffman JC, Fan H, Caulton KG. [( tBu 2PC 2HSiMe 2) 2N]RuMe 2: Synthesis and reactivity of an unsaturated ruthenium dialkyl radical species Organometallics. 25: 1112-1119. DOI: 10.1021/Om0508536  0.678
2006 Huang D, Renkema KB, Caulton KG. Cleavage of F-C(sp2) bonds by MHR(CO)(PtBu 2Me)2 (M = Os and Ru; R = H, CH3 or Aryl): Product dependence on M and R Polyhedron. 25: 459-468. DOI: 10.1016/J.Poly.2005.08.012  0.818
2005 Walstrom A, Pink M, Tsvetkov NP, Fan H, Ingleson M, Caulton KG. N2 provides insight into the mechanism of H-C(sp3) bond cleavage. Journal of the American Chemical Society. 127: 16780-1. PMID 16316212 DOI: 10.1021/Ja0547580  0.688
2005 Ingleson MJ, Yang X, Pink M, Caulton KG. [(tBu2PCH2SiMe2)2N]RuCH3: the origin of extremely facile, double H-C(sp3) activation generating a "hydrido-carbene" complex. Journal of the American Chemical Society. 127: 10846-7. PMID 16076187 DOI: 10.1021/Ja052973A  0.751
2005 Bibal C, Smurnyy YD, Pink M, Caulton KG. Exceptionally facile CO addition to a saturated ruthenium complex. Journal of the American Chemical Society. 127: 8944-5. PMID 15969559 DOI: 10.1021/Ja051296H  0.456
2005 Walstrom A, Pink M, Yang X, Tomaszewski J, Baik MH, Caulton KG. A facile approach to a d4 RuN: moiety. Journal of the American Chemical Society. 127: 5330-1. PMID 15826165 DOI: 10.1021/Ja050361K  0.611
2005 Ferrando-Miguel G, Wu P, Huffman JC, Caulton KG. New d4 dihydrides of Ru(IV) and Os(IV) with π-donor ligands: M(H)2(chelate)(PiPr3)2 with chelate = ortho-XYC6H4 with X, Y = O, NR; R = H or CH3 New Journal of Chemistry. 29: 193-204. DOI: 10.1039/B411487F  0.833
2005 Smurnyy Y, Bibal C, Pink M, Caulton KG. New features of bis(phosphinimine)-"carbene" binding to Ru II Organometallics. 24: 3849-3855. DOI: 10.1021/Om050180R  0.438
2004 Clot E, Eisenstein O, Weng TC, Penner-Hahn J, Caulton KG. Is the allylpalladium structure altered between solid and solutions? Journal of the American Chemical Society. 126: 9079-84. PMID 15264841 DOI: 10.1021/Ja049091G  0.426
2004 Vedernikov AN, Pink M, Caulton KG. Influence of the [2.1.1]-(2,6)-pyridinophane macrocycle ring size constraint on the structure and reactivity of copper complexes. Inorganic Chemistry. 43: 4300-5. PMID 15236543 DOI: 10.1021/Ic049886O  0.622
2004 Vedernikov AN, Pink M, Caulton KG. Hydrocarbyl ligand "tuning" of the PtII/IV redox potential. Inorganic Chemistry. 43: 3642-6. PMID 15180418 DOI: 10.1021/Ic034731M  0.625
2004 Ozerov OV, Watson LA, Pink M, Caulton KG. Transformation of acyclic alkenes to hydrido carbynes by (PNP(R))Re complexes. Journal of the American Chemical Society. 126: 6363-78. PMID 15149234 DOI: 10.1021/Ja031617U  0.747
2004 Bibal C, Pink M, Smurnyy YD, Tomaszewski J, Caulton KG. Multifunctional behavior by a Bis-(phosphinimino)methanide ligand: eta 2- vs eta 3-coordination vs Bronsted basicity. Journal of the American Chemical Society. 126: 2312-3. PMID 14982428 DOI: 10.1021/Ja039711Y  0.47
2004 Ozerov OV, Pink M, Watson LA, Caulton KG. Aromatic vs aliphatic C-H cleavage of alkyl-substituted pyridines by (PNPiPr)Re compounds. Journal of the American Chemical Society. 126: 2105-13. PMID 14971945 DOI: 10.1021/Ja036999I  0.801
2004 Vedernikov AN, Caulton KG. Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane-PhINTs systems. Chemical Communications (Cambridge, England). 162-3. PMID 14737529 DOI: 10.1039/b309519c  0.594
2004 Marchenko AV, Vedernikov AN, Dye DF, Pink M, Zaleski JM, Caulton KG. Reactivity of the hydrido/nitrosyl radical MHCl(NO)(CO)(P(i)Pr(3))(2), M = Ru, Os. Inorganic Chemistry. 43: 351-60. PMID 14704087 DOI: 10.1021/Ic0349407  0.759
2004 Walstrom AN, Watson LA, Pink M, Caulton KG. Facile insertion of terminal acetylenes into the Ru II-NR 2 bond of a 14-valence-electron complex Organometallics. 23: 4814-4816. DOI: 10.1021/Om049435B  0.695
2004 Ozerov OV, Watson LA, Pink M, Baik MH, Caulton KG. Terminal acetylenes react to increase unsaturation in [( tBu 2PCH 2SiMe 2) 2N]Re(H) 4 Organometallics. 23: 4934-4943. DOI: 10.1021/Om049424I  0.777
2004 Renkema KB, Werner-Zwanziger U, Pagel MD, Caulton KG. Room-temperature hydrosilylation of the CF bond of vinyl fluoride catalyzed by osmium hydrides Journal of Molecular Catalysis a: Chemical. 224: 125-131. DOI: 10.1016/J.Molcata.2004.07.028  0.825
2004 Watson LA, Pink M, Caulton KG. The fate of nitric oxide in its reaction with the 14-valence-electron planar species [( tBu 2PCH 2SiMe 2) 2N]RuCl Journal of Molecular Catalysis a: Chemical. 224: 51-59. DOI: 10.1016/J.Molcata.2004.06.035  0.681
2004 Vedernikov AN, Caulton KG. Facile alkane functionalization in copper-[2.1.1]-(2,6)-pyridinophane- PhINTs systems Chemical Communications. 10: 162-163.  0.41
2003 Ozerov OV, Watson LA, Pink M, Caulton KG. A pi-basic rhenium center that effects cyclohexene isomerization to a beta-agostic carbene ligand. Journal of the American Chemical Society. 125: 9604-5. PMID 12904023 DOI: 10.1021/Ja035165X  0.791
2003 Vedernikov AN, Caulton KG. Angular ligand constraint yields an improved olefin aziridination catalyst. Organic Letters. 5: 2591-4. PMID 12868866 DOI: 10.1021/ol034681p  0.592
2003 Watson LA, Ozerov OV, Pink M, Caulton KG. Four-coordinate, planar RuII. A triplet state as a response to a 14-valence electron configuration. Journal of the American Chemical Society. 125: 8426-7. PMID 12848535 DOI: 10.1021/Ja035166P  0.726
2003 Vedernikov AN, Pink M, Caulton KG. Design and synthesis of tridentate facially chelating ligands of the [2.n.1]-(2,6)-pyridinophane family. The Journal of Organic Chemistry. 68: 4806-14. PMID 12790585 DOI: 10.1021/jo034268v  0.566
2003 Vedernikov AN, Caulton KG. N-PtIV-H/N-H...PtII intramolecular redox equilibrium in a product of H-C(sp2) cleavage and unusual alkane/arene C-H bond selectivity of ([2.1.1]pyridinophane)PtII(CH3)+. Chemical Communications (Cambridge, England). 358-9. PMID 12613611 DOI: 10.1039/B207797N  0.677
2003 Ferrando G, Coalter JN, Gérard H, Huang D, Eisenstein O, Caulton KG. Facile C(sp2)/O2CR bond cleavage by Ru or Os New Journal of Chemistry. 27: 1451-1462. DOI: 10.1039/B306111F  0.817
2003 Watson LA, Franzman B, Bollinger JC, Caulton KG. π-Donor olefin substituents alter olefin binding to CpFe(CO) 2 + New Journal of Chemistry. 27: 1769-1774. DOI: 10.1039/B305252D  0.641
2003 Ho VM, Watson LA, Huffman JC, Caulton KG. Double C(sp3) dehydrogenation as a route to coordinated Arduengo carbenes: Experiment and computation on comparative π-acidity New Journal of Chemistry. 27: 1446-1450. DOI: 10.1039/B305249D  0.672
2003 Vedernikov AN, Huffman JC, Caulton KG. [2.1.1]-(2,6)-pyridinophane(L)-controlled alkane C-H bond cleavage: (L)PtMe2H+ as a precursor to the geometrically "tense" transient (L)PtMe+ New Journal of Chemistry. 27: 665-667. DOI: 10.1039/B302055J  0.635
2003 Marchenko AV, Vedernikov AN, Huffman JC, Caulton KG. Evaluation of energies of isomeric SO2 complexes New Journal of Chemistry. 27: 680-683. DOI: 10.1039/B212025A  0.735
2003 Watson LA, Coalter JN, Ozerov O, Pink M, Huffman JC, Caulton KG. Amido/phosphine pincer hydrides of ruthenium New Journal of Chemistry. 27: 263-273. DOI: 10.1039/B206202J  0.827
2003 Ozerov OV, Huffman JC, Watson LA, Caulton KG. Conversion of ethylene to hydride and ethylidyne by an amido rhenium polyhydride Organometallics. 22: 2539-2541. DOI: 10.1021/Om0210412  0.771
2002 Vedernikov AN, Huffman JC, Caulton KG. [N.1.1]-(2,6)-Pyridinophanes: a new ligand type imposing unusual metal coordination geometries. Inorganic Chemistry. 41: 6867-74. PMID 12470085 DOI: 10.1021/Ic020430L  0.619
2002 Ferrando-Miguel G, Gérard H, Eisenstein O, Caulton KG. Vinyl C-F cleavage by Os(H)3Cl(P(i)Pr3)2. Inorganic Chemistry. 41: 6440-9. PMID 12444789 DOI: 10.1021/Ic020365F  0.824
2002 Vedernikov AN, Huffman JC, Caulton KG. Coordination chemistry of tripyridinedimethane. Inorganic Chemistry. 41: 6244-8. PMID 12444766 DOI: 10.1021/Ic025708O  0.62
2002 Vedernikov AN, Caulton KG. Control of H-C(sp3) bond cleavage stoichiometry: clean reversible alkyl ligand exchange with alkane in [LPt(Alk)(H)2]+ (L=[2.1.1]-(2,6)-pyridinophane). Angewandte Chemie (International Ed. in English). 41: 4102-4. PMID 12412095 DOI: 10.1002/1521-3773(20021104)41:21<4102::Aid-Anie4102>3.0.Co;2-#  0.68
2002 Ozerov OV, Gerard HF, Watson LA, Huffman JC, Caulton KG. Double silyl migration converting ORe[N(SiMe(2)CH(2)PCy(2))(2)] to NRe[O(SiMe(2)CH(2)PCy(2))(2)] substructures. Inorganic Chemistry. 41: 5615-25. PMID 12377062 DOI: 10.1021/Ic020424P  0.765
2002 Marchenko AV, Vedernikov AN, Dye DF, Pink M, Zaleski JM, Caulton KG. An electron-excessive nitrosyl complex: reactivity of a ligand-centered radical leading to coordinated HNO. Inorganic Chemistry. 41: 4087-9. PMID 12160389 DOI: 10.1021/Ic025699J  0.763
2002 Watson LA, Caulton KG. Assessing isomeric structures of pincer-ligated ruthenium and osmium polyhydrides using density functional calculations Molecular Physics. 100: 385-395. DOI: 10.1080/00268970110055303  0.69
2002 Vedernikov AN, Caulton KG. Evolving approaches to integration of computational with experimental chemistry: An example from osmium hydrido (η1/η2-)nitrosyl/nitroxyl chemistry New Journal of Chemistry. 26: 1267-1269. DOI: 10.1039/B205506F  0.549
2002 Yandulov DV, Caulton KG. Electrophilic (Li+) acceleration of C-H reductive elimination and oxidative addition reactions of Os(II)/Os(0) nitrosyl complexes New Journal of Chemistry. 26: 498-502. DOI: 10.1039/B200180M  0.804
2002 Ferrando-Miguel G, Coalter JN, Gérard H, Huffman JC, Eisenstein O, Caulton KG. Geminal dehydrogenation of ether and amine C(sp3)H2 groups by electron-rich Ru(II) and Os New Journal of Chemistry. 26: 687-700. DOI: 10.1039/B200168N  0.825
2002 Yandulov DV, Huffman JC, Caulton KG. Conventional lithium bases as unconventional sources of methyl anion: Facile Me-Si and Me-C bond cleavage in RLi, R2NLi, and BR4 - by an electrophilic osmium dihydride Organometallics. 21: 4030-4049. DOI: 10.1021/Om0200104  0.76
2002 Vedernikov AN, Wu P, Huffman JC, Caulton KG. Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand Inorganica Chimica Acta. 330: 103-110. DOI: 10.1016/S0020-1693(01)00825-8  0.562
2001 Ferrando G, Gérard H, Spivak GJ, Coalter JN, Huffman JC, Eisenstein O, Caulton KG. Facile C(sp(2))/OR bond cleavage by Ru or Os. Inorganic Chemistry. 40: 6610-21. PMID 11735470 DOI: 10.1021/Ic010729O  0.814
2001 Marchenko AV, Huffman JC, Valerga P, Tenorio MJ, Puerta MC, Caulton KG. Effect of Lewis acidity on the synthesis of RuHCl(CO)(phosphine)(2): subtle influence of steric and electronic effects among P(i)Pr(3), P(i)Pr(2)(3,5-(CF(3))(2)C(6)H(3)), and P(i)Pr(2)Me. Inorganic Chemistry. 40: 6444-50. PMID 11720500 DOI: 10.1021/ic000500t  0.638
2001 Watson LA, Yandulov DV, Caulton KG. C-D(0) (D(0) = pi-donor, F) Cleavage in H(2)C=CH(D(0)) by (Cp(2)ZrHCl)(n): mechanism, agostic fluorines, and a carbene of Zr(IV). Journal of the American Chemical Society. 123: 603-11. PMID 11456572 DOI: 10.1021/Ja0024340  0.824
2001 Marchenko AV, Gérard H, Eisenstein O, Caulton KG. A comprehensive view of M-H addition across the RC≡CH bond: Frustration culminating in ultimate union New Journal of Chemistry. 25: 1244-1255. DOI: 10.1039/B103815J  0.695
2001 Marchenkoa AV, Gérard H, Eisenstein O, Caulton KG. A comparative study of olefin or acetylene insertion into Ru-H or Os-H of MHCl(CO)(phosphine)2 New Journal of Chemistry. 25: 1382-1388. DOI: 10.1039/B103113A  0.476
2001 Coalter JN, Huffman JC, Caulton KG. Carbene transposition involving double dehydrogenation of an sp3 carbon Chemical Communications. 1158-1159. DOI: 10.1039/B102422C  0.77
2001 Coalter JN, Caulton KG. ROMP using heterocyclic carbenes bearing a hydride ligand. An improved synthesis of RuCl2 (PR3)2(=CHMe) New Journal of Chemistry. 25: 679-684. DOI: 10.1039/B009931G  0.797
2001 Baxter DV, Caulton KG, Chiang WC, Chisholm MH, DiStasi VF, Dutremez SG, Martin JD, Streib WE. Synthesis and structural characterization of tricarbomethoxymethanate complexes of copper(II) and barium(II) and evaluation of their suitability for MOCVD applications New Journal of Chemistry. 25: 400-407. DOI: 10.1039/B008147G  0.448
2001 Yandulov DV, Bollinger JC, Streib WE, Caulton KG. Os(H)2NO(PiPr3)2 + : Mechanism and energetics of a room temperature reversible ethyl/hydridoethylene equilibrium and contrasting double insertion of acetylene Organometallics. 20: 2040-2046. DOI: 10.1021/Om000901G  0.793
2001 Baxter DV, Caulton KG, Chiang WC, Chisholm MH, DiStasi VF, Dutremez SG, Folting K. Synthesis, structural characterization, thermolysis and volatility study of the Schiff base complex Cu[CH3C(O)CHC(NCH2CH2OCH3) CH3]2 Polyhedron. 20: 2589-2595. DOI: 10.1016/S0277-5387(01)00825-7  0.394
2001 Caulton KG. Factors governing the equilibrium between metal-alkyl, alkylidene and alkylidyne: MCX2R, X-M=CXR and X2MCR Journal of Organometallic Chemistry. 617: 56-64. DOI: 10.1016/S0022-328X(00)00706-3  0.509
2000 Gemel C, Folting K, Caulton KG. New approach to Ru(II) pincer ligand chemistry. Bis(tert-butylaminomethyl)pyridine coordinated to ruthenium(II). Inorganic Chemistry. 39: 1593-7. PMID 12526470 DOI: 10.1021/Ic990737T  0.43
2000 Yandulov DV, Huang D, Huffman JC, Caulton KG. Structural distortions in mer-M(H)3(NO)L2 (M = Ru, Os) and their influence on intramolecular fluxionality and quantum exchange coupling. Inorganic Chemistry. 39: 1919-32. PMID 11428112 DOI: 10.1021/Ic991452J  0.817
2000 Gottschalk-Gaudig T, Huffman JC, Gérard H, Eisenstein O, Caulton KG. Unsaturated Ru(0) species with a constrained bis-phosphine ligand: [Ru(CO)2(tBu2PCH2CH2PtBu2)]2. Comparison to [Ru(CO)2(PtBu2Me)2]. Inorganic Chemistry. 39: 3957-62. PMID 11198847 DOI: 10.1021/Ic9911320  0.506
2000 Coalter JN, Huffman JC, Streib WE, Caulton KG. A new class of electron-rich unsaturated molecules: Ru2HnX4-n(PiPr3)4, X = anion. Inorganic Chemistry. 39: 3757-64. PMID 11196766 DOI: 10.1021/ic991112y  0.769
2000 Coalter JN, Streib WE, Caulton KG. Reactivity of [RuHCl(PiPr3)2]2 with functionalized vinyl substrates. The H2 ligand as a sensitive probe of electronic structure. Inorganic Chemistry. 39: 3749-56. PMID 11196765 DOI: 10.1021/Ic9905998  0.806
2000 Coalter JN, Ferrando G, Caulton KG. Geminal dehydrogenation of a C(sp3) CH2 group by unsaturated Ru(II) or Os(II) New Journal of Chemistry. 24: 835-836. DOI: 10.1039/B007200L  0.815
2000 Coalter JN, Bollinger JC, Eisenstein O, Caulton KG. R-Group reversal of isomer stability for RuH(X)L2(CCHR) vs. Ru(X)L2(CCH2R): Access to four-coordinate ruthenium carbenes and carbynes New Journal of Chemistry. 24: 925-927. DOI: 10.1039/B006971J  0.799
2000 Yandulov DV, Huffman JC, Caulton KG. An osmium hydrido methyl species via an unconventional methyl transfer New Journal of Chemistry. 24: 649-650. DOI: 10.1039/B004484I  0.785
2000 Coalter JN, Bollinger JC, Huffman JC, Werner-Zwanziger U, Caulton KG, Davidson ER, Gérard H, Clot E, Eisenstein O. Coordinated carbenes from electron-rich olefins on RuHCl(PPr3/(i))2 New Journal of Chemistry. 24: 9-26. DOI: 10.1039/A907624G  0.814
2000 Gérard H, Clot E, Giessner-Prettre C, Caulton KG, Davidson ER, Eisenstein O. Fate of CH2 double bond CHE (E = H, OMe) in the presence of unsaturated Ru(X) (H)L2 q+ (X = Cl, q = 0; X = CO, q = 1): highly sensitive to X and E Organometallics. 19: 2291-2298. DOI: 10.1021/Om991002Z  0.41
2000 Huang D, Bollinger JC, Streib WE, Folting K, Young V, Eisenstein O, Caulton KG. 14-electron ruthenium(II) hydride, [RuH(CO)(PtBu2Me)2]BAr′4 (Ar′ = 3,5-(C6H3)(CF3)2): synthesis, structure, and reactivity toward alkenes and oxygen ligands Organometallics. 19: 2281-2290. DOI: 10.1021/Om9910017  0.447
2000 Huang D, Streib WE, Eisenstein O, Caulton KG. 16-Electron ruthenium(0) complexes containing the Ru(NO)L2 + substructure: Planar RuCH3(NO)L2 vs sawhorse [Ru(NO)(C=C(SiMe3)2)L2]+ Organometallics. 19: 1967-1972. DOI: 10.1021/Om9909892  0.611
2000 Coalter JN, Huffman JC, Caulton KG. Cleavage of H-C(sp2) and C(sp2)-X Bonds (X = Alkyl, Aryl, OR, NR2): Facile decarbonylation, isonitrile abstraction, or dehydrogenation of aldehydes, esters, amides, amines, and imines by [RuHCl(PiPr3)2]2 Organometallics. 19: 3569-3578. DOI: 10.1021/Om000390Y  0.823
2000 Huang D, Koren PR, Folting K, Davidson ER, Caulton KG. Facile and reversible cleavage of C-F bonds. Contrasting thermodynamic selectivity for Ru-CF2H vs F-Os=CFH Journal of the American Chemical Society. 122: 8916-8931. DOI: 10.1021/Ja001646U  0.583
2000 Coalter JN, Streib WE, Caulton KG. Reactivity of [RuHCl(P(i)Pr3)2]2 with functionalized vinyl substrates. The H2 ligand as a sensitive probe of electronic structure Inorganic Chemistry. 39: 3749-3756. DOI: 10.1021/ic9905998  0.766
2000 Gemel C, Huffman JC, Caulton KG, Mauthner K, Kirchner K. Solution and solid-gas reactivity of unsaturated [RuCp(tmeda)]+ (tmeda=Me2NC2H4NMe2) Journal of Organometallic Chemistry. 593: 342-353. DOI: 10.1016/S0022-328X(99)00545-8  0.498
1999 Oliván M, Caulton KG. C-(Halide) Oxidative Addition Routes to Ruthenium Carbenes. Inorganic Chemistry. 38: 566-570. PMID 11673963 DOI: 10.1021/Ic980070V  0.499
1999 Renkema KB, Caulton KG. Reactivity patterns of the unsaturated Os(0) species Os(NO)(CO)(PBu2/(t)Me)2 + New Journal of Chemistry. 23: 1027-1032. DOI: 10.1039/A903799C  0.801
1999 Huang D, Gérard H, Clot E, Young V, Streib WE, Eisenstein O, Caulton KG. L′ = CO vs Cl- transposition: Remarkable consequences for the product of (L′)-Ru(L)2-(H) and vinyl ether Organometallics. 18: 5441-5443. DOI: 10.1021/Om990649G  0.455
1999 Huang D, Folting K, Caulton KG. Silyl migration of Me3SiCCPh coordinated to [RuH(CO)(P(t)Bu2Me)2]BAr'4 can be reversed: Synthesis and structure of [Ru(CH=C(SiMe3)(Ph))(CO)(P(t)Bu2Me)2]BAr'4 Journal of the American Chemical Society. 121: 10318-10322. DOI: 10.1021/Ja991351K  0.613
1999 Huang D, Streib WE, Bollinger JC, Caulton KG, Winter RF, Scheiring T. 14-electron four-coordinate Ru(II) carbyl complexes and their five- coordinate precursors: Synthesis, double agostic interactions, and reactivity Journal of the American Chemical Society. 121: 8087-8097. DOI: 10.1021/Ja990621W  0.647
1999 Renkema KB, Bosque R, Streib WE, Maseras F, Eisenstein O, Caulton KG. Phosphine dissociation mediates C-H cleavage of fluoroarenes by OsH(C6H5) (CO) (P(t)Bu2Me)2 Journal of the American Chemical Society. 121: 10895-10907. DOI: 10.1021/Ja990523A  0.816
1999 Cooper AC, Clot E, Huffman JC, Streib WE, Maseras F, Eisenstein O, Caulton KG. Computational and experimental test of steric influence on agostic interactions: A homologous series for Ir(III) Journal of the American Chemical Society. 121: 97-106. DOI: 10.1021/Ja981727E  0.476
1999 Gottschalk-Gaudig T, Folting K, Caulton KG. Synthesis and reactivity of Ru(II)/chloro/hydrido/carbonyls with cis bulky phosphines: An unsaturated Ru(II) monohydride Inorganic Chemistry. 38: 5241-5245. DOI: 10.1021/Ic9902020  0.481
1999 Ferrando G, Caulton KG. Dehydrohalogenation as a source of OsHnCl(PPh3)3 (n = 1, 3) Inorganic Chemistry. 38: 4168-4170. DOI: 10.1021/Ic981402Z  0.34
1999 Renkema KB, Huffman JC, Caulton KG. Characterization and structure of OsH(OH)(CO)(PtBu2Me)2 Polyhedron. 18: 2575-2578. DOI: 10.1016/S0277-5387(99)00146-1  0.813
1999 Renkema KB, Ogasawara M, Streib WE, Huffman JC, Caulton KG. Synthetic approaches to Fe(II) complexes of the bulky phosphine PtBu2Me Inorganica Chimica Acta. 291: 226-230. DOI: 10.1016/S0020-1693(99)00104-8  0.783
1999 Ferrando G, Coalter JN, Spivak GJ, Caulton KG. Unprecedented C-O- or C-CL-bond cleavage of vinyl acetates or vinyl chloroformate by osmium- and ruthenium-unsaturated compounds Acs National Meeting Book of Abstracts. INOR-59.  0.75
1998 Huang D, Spivak GJ, Caulton KG. Mechanistic and thermodynamic aspects of methylene transfer from CH2N2 to MHCl(CO)L2 (M = Ru, Os; L = tertiary phosphine): Non-least motion behavior and extreme dependence on phosphine identity New Journal of Chemistry. 22: 1023-1025. DOI: 10.1039/A803432J  0.569
1998 Cooper AC, Eisenstein O, Caulton KG. 16-Electron, non-π-stabilized Ir(H)2(H2)(PBu2 tPh)2 + and 18-electron Ir(H)2(H2)2(PBu2 tPh) 2 +: Fluxionality and H/D exchange as independent processes New Journal of Chemistry. 22: 307-309. DOI: 10.1039/A801330F  0.428
1998 Cooper AC, Bollinger JC, Huffman JC, Caulton KG. HX elimination from Ir(H)2X(PBu2 tPh)2 promoted by CO coordination: Assessment of X ligand influence New Journal of Chemistry. 22: 473-480. DOI: 10.1039/A800525G  0.468
1998 Spivak GJ, Caulton KG. Hydrogen migration and HCl elimination promoted by metal-centered nucleophilic attack on osmium hydrido-carbynes Organometallics. 17: 5260-5266. DOI: 10.1021/Om980597F  0.437
1998 Spivak GJ, Coalter JN, Oliván M, Eisenstein O, Caulton KG. Osmium converts terminal olefins to carbynes: α-hydrogen migration redox isomers with reversed stability for ruthenium and for osmium Organometallics. 17: 999-1001. DOI: 10.1021/Om9711382  0.805
1998 Oliván M, Clot E, Eisenstein O, Caulton KG. Hydride is not a spectator ligand in the formation of hydrido vinylidene from terminal alkyne and ruthenium and osmium hydrides: Mechanistic differences Organometallics. 17: 3091-3100. DOI: 10.1021/Om971109R  0.469
1998 Huang D, Oliván M, Huffman JC, Eisenstein O, Caulton KG. CO-induced C(sp2)/C(sp) coupling on Ru and Os: A comparative study Organometallics. 17: 4700-4706. DOI: 10.1021/Om970961V  0.605
1998 Oliván M, Clot E, Eisenstein O, Caulton KG. Isomeric hydrido/vinylidene, MH(halide)(C=CH2)L2, and ethylidyne, M(halide) (C-CH3)L2 (M = Os, Ru; L = phosphine), are energetically similar but not interconverting Organometallics. 17: 897-901. DOI: 10.1021/Om9709493  0.44
1998 Bosque R, Clot E, Fantacci S, Maseras F, Eisenstein O, Perutz RN, Renkema KB, Caulton KG. Inertness of the Aryl−F Bond toward Oxidative Addition to Osmium and Rhodium Complexes:  Thermodynamic or Kinetic Origin? Journal of the American Chemical Society. 120: 12634-12640. DOI: 10.1021/Ja9824573  0.787
1998 Yandulov DV, Caulton KG. Diminishing π-stabilization of an unsaturated metal center: Hydrogen bonding to OsHCL(CO)(P(t)Bu2Me)2 Journal of the American Chemical Society. 120: 12553-12563. DOI: 10.1021/Ja980751P  0.768
1998 Coalter JN, Spivak GJ, Gerard H, Clot E, Davidson ER, Eisenstein O, Caulton KG. Carbene complexes from olefins, using RuHCl(P(i)Pr3)2. Influence of the olefin substituent [14] Journal of the American Chemical Society. 120: 9388-9389. DOI: 10.1021/Ja980518R  0.757
1998 Ujaque G, Cooper AC, Maseras F, Eisenstein O, Caulton KG. Computational evidence of the importance of substituent bulk on agostic interactions in Ir(H)2(P(t)Bu2Ph)2 + Journal of the American Chemical Society. 120: 361-365. DOI: 10.1021/Ja9729894  0.443
1998 Zechmann CA, Huffman JC, Folting K, Caulton KG. Controlled Stoichiometric Incorporation of Ti(IV) into a Zr(IV) Pinacolate Inorganic Chemistry. 37: 5856-5861. DOI: 10.1021/Ic980714Z  0.327
1998 Cooper AC, Caulton KG. Relationship of Hydride Fluxionality in Ir(H)2L(phosphine)2n+to Properties of L:  An Exceptional Range of Barrier Heights Inorganic Chemistry. 37: 5938-5940. DOI: 10.1021/Ic971625+  0.46
1998 Xue Z, Chuang S, Caulton KG, Chisholm MH. Molecular Routes to Metal−Carbides, −Nitrides, and −Oxides. 3.1 Chemical Vapor Deposition Employing X3W⋮*CCMe3, Where X = CH2CMe3, OtBu, and OtBu-d9 and *C = 12C or 13C, and a Comparison with the Chemistry of (tBuO)3W⋮N Chemistry of Materials. 10: 2365-2370. DOI: 10.1021/Cm970675+  0.31
1998 Zechmann CA, Folting K, Caulton KG. Synthesis of Zirconium Pinacolate and Mechanism of Its Thermal Transformation to ZrO2: Impact of a Vicinal Diol Ligand Chemistry of Materials. 10: 2348-2357. DOI: 10.1021/Cm970644E  0.32
1998 Yandulov DV, Streib WE, Caulton KG. Electrophilic abstractions on Os(H)2X(NO)L2: Selective access to new unsaturated cationic Os(II) hydrides Inorganica Chimica Acta. 280: 125-137. DOI: 10.1016/S0020-1693(98)00057-7  0.801
1998 Cooper AC, Huffman JC, Caulton KG. Silyl reagents (Me3Si-X) efficiently transfer X to Ir(H)2F(PtBu2Ph)2 Inorganica Chimica Acta. 270: 261-272. DOI: 10.1016/S0020-1693(97)05851-9  0.466
1997 Teff DJ, Huffman JC, Caulton KG. &mgr;-Benzene in a Heterobimetallic Fluoroalkoxide: CH.FC Hydrogen Bonding? Inorganic Chemistry. 36: 4372-4380. PMID 11670095 DOI: 10.1021/Ic970633N  0.444
1997 Pinkas J, Huffman JC, Bollinger JC, Streib WE, Baxter DV, Chisholm MH, Caulton KG. Syntheses, Structures, and Thermal Behavior of Cu(hfacac) Complexes Derived from Ethanolamines. Inorganic Chemistry. 36: 2930-2937. PMID 11669939 DOI: 10.1021/Ic960370H  0.361
1997 Oliván M, Caulton KG. The first double oxidative addition of CH2Cl2 to a metal complex: Facile synthesis of [Ru(CH2)Cl2{P(C6H11)3}2] Chemical Communications. 1733-1734. DOI: 10.1039/A703097E  0.485
1997 Li C, Oliván M, Nolan SP, Caulton KG. Ligand (L) Influence on CO Binding Enthalpies to Ru(CO)2L2 Organometallics. 16: 4223-4225. DOI: 10.1021/Om970220U  0.392
1997 Oliván M, Eisenstein O, Caulton KG. New access to vinylidenes from ruthenium polyhydrides Organometallics. 16: 2227-2229. DOI: 10.1021/Om970095M  0.436
1997 Ogasawara M, Maseras F, Gallego-Planas N, Kawamura K, Ito K, Toyota K, Streib WE, Komiya S, Eisenstein O, Caulton KG. Competition between steric and electronic control of structure in Ru(CO) 2L 2L′ complexes Organometallics. 16: 1979-1993. DOI: 10.1021/Om9700775  0.393
1997 Huang D, Heyn RH, Bollinger JC, Caulton KG. Oxidative addition of a Si-C(sp) bond to ruthenium: Synthesis and reactivity of Ru(SiMe3)(C≡CSiMe3)(CO)(PtBu 2Me)2 Organometallics. 16: 292-293. DOI: 10.1021/Om9609776  0.601
1997 Cooper AC, Huffman JC, Caulton KG. A case of C-H activation (ortho metalation) which is reversible at 25 °C Organometallics. 16: 1974-1978. DOI: 10.1021/Om9607107  0.466
1997 Cooper AC, Folting K, Huffman JC, Caulton KG. Fluoro-Ligand Promotion of C-H Activation Organometallics. 16: 505-507. DOI: 10.1021/Om9605488  0.44
1997 Olivan M, Marchenko AV, Coalter JN, Caulton KG. Gas/solid reactivity of unsaturated ruthenium-containing molecular solids Journal of the American Chemical Society. 119: 8389-8390. DOI: 10.1021/Ja971608J  0.755
1997 Kuhlman R, Clot E, Leforestier C, Streib WE, Eisenstein O, Caulton KG. Quantum exchange coupling: A hypersensitive indicator of weak interactions Journal of the American Chemical Society. 119: 10153-10169. DOI: 10.1021/Ja970603J  0.395
1997 Ogasawara M, Huang D, Streib WE, Huffman JC, Gallego-Planas N, Maseras F, Eisenstein O, Caulton KG. RuX(CO)(NO)L2 and Ru(CO)(NO)L2 +: Ru(0) or Ru(II) or in between? Journal of the American Chemical Society. 119: 8642-8651. DOI: 10.1021/Ja970563J  0.621
1997 Huang D, Huffman JC, Bollinger JC, Eisenstein O, Caulton KG. The first η2-CH2Cl2 adduct of Ru(II):[RuH(η2-CH2Cl2)(CO)(P(t)Bu2Me)2][BAr'4] (Ar' = 3,5-C6H3(CF3)2) and its RuH(CO)(P(t)Bu2Me)2 + precursor Journal of the American Chemical Society. 119: 7398-7399. DOI: 10.1021/Ja970240N  0.521
1997 Huang D, Caulton KG. New entries to and new reactions of fluorocarbon ligands Journal of the American Chemical Society. 119: 3185-3186. DOI: 10.1021/Ja963903U  0.502
1997 Borup B, Streib WE, Caulton KG. Heterometallic Fluoroalkoxides of Barium and Copper(I). Syntheses and Structures of [(Me3NO)2Ba2Cu4(TFTB)8] and [(THF)2Ba2Cu2(HFTB)6] Inorganic Chemistry. 36: 5058-5063. DOI: 10.1021/Ic970234S  0.33
1997 Borup B, Folting K, Caulton KG. Lewis Base Adducts of Barium/Copper tert-Butoxides: Synthesis and Thermolysis of [BaCu2(OtBu)4]n and [L2Ba2Cu4(OtBu)8] (L = Me3NO and Et3PO). X-ray Crystal Structure of [(Me3NO)2Ba2Cu4(O tBu)8] Chemistry of Materials. 9: 1021-1029. DOI: 10.1021/Cm9606134  0.395
1997 Kuhlman R, Gusev DG, Eremenko IL, Berke H, Huffman JC, Caulton KG. Dihydrogen addition to (pipr3) 2osxnh4-n Journal of Organometallic Chemistry. 536: 139-147. DOI: 10.1016/S0022-328X(96)06914-8  0.477
1997 Heyn RH, Macgregor SA, Nadasdi TT, Ogasawara M, Eisenstein O, Caulton KG. Is π-donation the only way? Unprecedented unsaturated Ru(II) species devoid of π-donor ligands Inorganica Chimica Acta. 259: 5-26. DOI: 10.1016/S0020-1693(97)05439-X  0.495
1997 Huang D, Streib WE, Eisenstein O, Caulton KG. [Ru(Ph)(CO)(PtBu2Me)2]+: A Unique 14-Electron Ru11 Complex with Two Agostic Interactions† Angewandte Chemie. 36: 2004-2006. DOI: 10.1002/Anie.199720041  0.321
1996 Huang D, Folting K, Caulton KG. Reactivity of RuCl(2)(CO)(P(t)()Bu(2)Me)(2) toward H(2) and Brønsted Acids: Aggregation Triggered by Protonation and Phosphine Loss. Inorganic Chemistry. 35: 7035-7040. PMID 11666884 DOI: 10.1021/Ic9605837  0.622
1996 Gusev DG, Kuhlman RL, Renkema KB, Eisenstein O, Caulton KG. Structure and H(2)-Loss Energies of OsHX(H(2))(CO)L(2) Complexes (L = P(t-Bu)(2)Me, P(i-Pr)(3); X = Cl, I, H): Attempted Correlation of (1)J(H-D), T(1min), and DeltaG(). Inorganic Chemistry. 35: 6775-6783. PMID 11666842 DOI: 10.1021/Ic960693D  0.812
1996 Gusev DG, Nadasdi TT, Caulton KG. Intramolecular Hydrogen Site Exchange in an HRu(SiHPh(2)) Moiety. Inorganic Chemistry. 35: 6772-6774. PMID 11666841 DOI: 10.1021/Ic960584Z  0.39
1996 Li C, Ogasawara M, Nolan SP, Caulton KG. Estimating the Effective Steric Impact of PtBu2Me, PiPr3, and PCy3 Organometallics. 15: 4900-4903. DOI: 10.1021/Om960380Q  0.423
1996 Hauger BE, Huffman aJC, Caulton KG. Alkoxide Attack on Coordinated Olefin Can Be Reversible Organometallics. 15: 1856-1864. DOI: 10.1021/Om950905Z  0.373
1996 Ogasawara M, Macgregor SA, Streib WE, Folting K, Eisenstein O, Caulton KG. Characterization and Reactivity of an Unprecedented Unsaturated Zero-Valent Ruthenium Species:  Isolable, Yet Highly Reactive Journal of the American Chemical Society. 118: 10189-10199. DOI: 10.1021/Ja960967W  0.442
1996 Kuhlman R, Streib WE, Huffman JC, Caulton KG. Site Selectivity in Electrophilic (H+, CH3+) Abstraction on Os(H)2X2(PiPr3)2 Journal of the American Chemical Society. 118: 6934-6945. DOI: 10.1021/Ja960369H  0.47
1996 Ogasawara M, Maseras F, Gallego-Planas N, Streib WE, Eisenstein O, Caulton KG. Unexpected Coexistence of Isomeric Forms and Unusual Structures of Ru(CO)2L3 Inorganic Chemistry. 35: 7468-7469. DOI: 10.1021/Ic960742M  0.327
1996 Teff DJ, Huffman JC, Caulton KG. Heterometallic alkoxides of zirconium with tin(II) or lead(II) Inorganic Chemistry. 35: 2981-2987. DOI: 10.1021/Ic951413H  0.339
1996 Cooper AC, Caulton KG. Identification of an elusive catalyst: IrH(η2-C6H4PtBu2) (Cl)(PtBu2Ph) as a precursor for C=C bond migration Inorganica Chimica Acta. 251: 41-51. DOI: 10.1016/S0020-1693(96)05249-8  0.43
1996 Borup B, Streib WE, Caulton KG. A YBa2 cluster based on simple ligands (OtBu) Chemische Berichte. 129: 1003-1005. DOI: 10.1002/Cber.19961290905  0.388
1996 Gusev DG, Kuhlman RL, Renkema KB, Eisenstein O, Caulton KG. Structure and H2-Loss Energies of OsHX(H2)(CO)L2 Complexes (L = P(t-Bu)2Me, P(i-Pr)3; X = Cl, I, H): Attempted Correlation of 1J(H-D), T1min, and ΔG Inorganic Chemistry. 35: 6775-6783.  0.804
1995 Kuhlman R, Folting K, Caulton KG. An Unusual Example of CH Oxidative Addition following Phosphine Association: Mechanism of Formation and Reactivity of Cp*Ru(.mu.-H)(.mu.-.eta.3,.eta.1-iPrNC(Me)CHHagostic)RuCp* Organometallics. 14: 3188-3195. DOI: 10.1021/Om00007A020  0.421
1995 Bianchini C, Caulton KG, Johnson TJ, Meli A, Peruzzini M, Vizza F. Mechanistic Study of Ir(H)2-Assisted Transformations of Ethyne: Cyclotrimerization, Cooligomerization with Ethene, and Reductive Coupling Organometallics. 14: 933-943. DOI: 10.1021/Om00002A046  0.329
1995 Smith K, Tilset M, Kuhlman R, Caulton KG. Reactions of (PiPr3)2OsH6 Involving Addition of Protons and Removal of Electrons. Characterization of (PiPr3)2Os(NCMe)xHyz+ (x = 0, 2, 3; y = 1, 2, 3, 4, 7; z = 1, 2), Including Dicationic .eta.2-H2 Complexes Journal of the American Chemical Society. 117: 9473-9480. DOI: 10.1021/Ja00142A013  0.419
1995 Ogasawara M, Macgregor SA, Streib WE, Folting K, Eisenstein O, Caulton KG. Isolable, Unsaturated Ru(0) in Ru(CO)2(PtBu2Me)2: Not Isostructural with Rh(I) in Rh(CO)2(PR3)2+ Journal of the American Chemical Society. 117: 8869-8870. DOI: 10.1021/Ja00139A028  0.341
1995 Gusev DG, Kuhlman R, Rambo JR, Berke H, Eisenstein O, Caulton KG. Structural and Dynamic Properties of OsH2X2L2 (X = Cl, Br, I; L = PiPr3) Complexes: Interconversion between Remarkable Non-Octahedral Isomers Journal of the American Chemical Society. 117: 281-292. DOI: 10.1021/Ja00106A031  0.387
1995 Pinkas J, Huffman JC, Chisholm MH, Caulton KG. Origin of Different Coordination Polyhedra for Cu[CF3C(O)CHC(O)CF3]2L (L = H2O, NH3) Inorganic Chemistry. 34: 5314-5318. DOI: 10.1021/Ic00125A034  0.35
1995 Rothfuss H, Gusev DG, Caulton KG. Low Temperature Multinuclear NMR Study of the Mechanism of Protonation of W(H)2Cl2(PMe2Ph)4 Inorganic Chemistry. 34: 2894-2901. DOI: 10.1021/Ic00115A017  0.384
1995 Kuhlman R, Streib WE, Caulton KG. Protonation of Chloride in Os(H)2Cl2(PiPr3)2: Synthesis of [(PiPr3)2H2Os(.mu.-Cl)3OsH2(PiPr3)2]CF3SO3 Inorganic Chemistry. 34: 1788-1792. DOI: 10.1021/Ic00111A028  0.439
1995 Johnson TJ, Folting K, Streib WE, Martin JD, Huffman JC, Jackson SA, Eisenstein O, Caulton KG. Pi -Stabilized, Yet Reactive, Half-Sandwich Cp*Ru(Pr3)X Compounds : Synthesis, Structure, And Bonding Inorganic Chemistry. 34: 488-499. DOI: 10.1021/Ic00106A010  0.354
1995 Pinkas J, Huffman JC, Baxter DV, Chisholm MH, Caulton KG. Mechanistic Role of H2O and the Ligand in the Chemical Vapor Deposition of Cu, Cu2O, CuO, and Cu3N from Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato)copper(II) Chemistry of Materials. 7: 1589-1596. DOI: 10.1021/Cm00056A028  0.341
1995 Notheis JU, Heyn RH, Caulton KG. Hindered Rotation About Single Bonds In Ruhx(Co)(Ptbu2Me)2 And Irhcl2(Ptbu2Me)2 Inorganica Chimica Acta. 229: 187-193. DOI: 10.1016/0020-1693(94)04244-P  0.467
1994 Bianchini C, Caulton KG, Chardon C, Doublet M, Eisenstein O, Jackson SA, Johnson TJ, Meli A, Peruzzini M. The Mechanism of Acetylene Cyclotrimerization Catalyzed by the fac-IrP3+ Fragment: The Relationship between Fluxionality and Catalysis Organometallics. 13: 2010-2023. DOI: 10.1021/Om00017A067  0.33
1994 Gusev DG, Kuhlman R, Sini G, Eisenstein O, Caulton KG. Distinct structures for ruthenium and osmium hydrido halides: Os(H)3X(PiPr3)2 (X = Cl, Br, I) are nonoctahedral classical trihydrides with exchange coupling Journal of the American Chemical Society. 116: 2685-2686. DOI: 10.1021/Ja00085A085  0.369
1994 Hauger BE, Gusev D, Caulton KG. Hydrogen binding to and fluxional behavior of Ir(H)2X(P-tert-Bu2R)2 (X = Cl, Br, I; R = Me, Ph) Journal of the American Chemical Society. 116: 208-214. DOI: 10.1021/Ja00080A024  0.392
1994 Johnson TJ, Albinati A, Koetzle TF, Ricci J, Eisenstein O, Huffman JC, Caulton KG. OsH5(PMe2Ph)3+: Structure, Reactivity, and Its Use as a Catalyst Precursor for Olefin Hydrogenation and Hydroformylation Inorganic Chemistry. 33: 4966-4976. DOI: 10.1021/Ic00100A021  0.348
1994 Poulton JT, Hauger BE, Kuhlman RL, Caulton KG. Ligand Redistribution Reactions of Five-Coordinate d6 Species: RuHX(CO)P2, IrH2XP2, and Cp*RuXP Inorganic Chemistry. 33: 3325-3330. DOI: 10.1021/Ic00093A021  0.337
1994 Poulton JT, Sigalas MP, Folting K, Streib WE, Eisenstein O, Caulton KG. RuHX(CO)(PR3)2: Can .nu.CO Be a Probe for the Nature of the Ru-X Bond? Inorganic Chemistry. 33: 1476-1485. DOI: 10.1021/Ic00085A043  0.323
1994 Bickford CC, Johnson TJ, Davidson ER, Caulton KG. Assessment of the Bonding in CpRu(PR3)X (X = F, Cl, OSiH3, OCH3) Inorganic Chemistry. 33: 1080-1086. DOI: 10.1021/Ic00084A018  0.369
1994 Rothfuss H, Huffman JC, Caulton KG. Correlation among alkoxide .fwdarw. tungsten .pi.-bonding, spin state, and reactivity in W(OCH2CF3)2Cl2(PMe2Ph)2 Inorganic Chemistry. 33: 187-191. DOI: 10.1021/Ic00080A003  0.399
1993 Albinati A, Bakhmutov VI, Caulton KG, Clot E, Eckert J, Eisenstein O, Gusev DG, Grushin VV, Hauger BE. Reaction of molecular hydrogen (H2) with chlorohydridoiridium phosphines IrHCl2P2 (P = PPr-iso3 or PBu-tert2Ph): stereoelectronic control of the stability of molecular H2 transition metal complexes Journal of the American Chemical Society. 115: 7300-7312. DOI: 10.1021/Ja00069A032  0.404
1993 Kuhlman R, Streib K, Caulton KG. .beta.- and .gamma.-Dehydrogenation of diisopropylamide in the formation of the azaallyl (Cp*Ru)2(iso-PrNC3H5)(.mu.-H) Journal of the American Chemical Society. 115: 5813-5814. DOI: 10.1021/Ja00066A055  0.328
1993 Tilset M, Zlota AA, Folting K, Caulton KG. A loss of innocence? Charge-transfer interactions with bis(triphenylphosphoranylidene)ammonium cation (Ph3PNPPh3+) as electron acceptor Journal of the American Chemical Society. 115: 4113-4119. DOI: 10.1021/Ja00063A032  0.333
1993 Poulton JT, Sigalas MP, Eisenstein O, Caulton KG. Modulation of reactivity and stereochemistry of substrate binding by the group X in RuHX(CO)(P-tert-Bu2Me)2 Inorganic Chemistry. 32: 5490-5501. DOI: 10.1021/Ic00076A015  0.41
1993 Johnson TJ, Coan PS, Caulton KG. Spectroscopic investigation of the reactivity of Cp*Ru(PPr-iso2Ph)X toward molecular hydrogen and silanes: formation in solution of Cp*Ru(PPr-iso2Ph)(H)3 and Cp*Ru(PPr-iso2Ph)(H)2Y (Y = halide, OR, and SiR'3) Inorganic Chemistry. 32: 4594-4599. DOI: 10.1021/Ic00073A021  0.471
1993 Rothfuss H, Barry JT, Huffman JC, Caulton KG, Chisholm MH. Two isomers of trichlorotris(dimethylphenylphosphine)tungsten and their potential for equilibration with W2Cl6(PMe2Ph)n Inorganic Chemistry. 32: 4573-4577. DOI: 10.1021/Ic00073A018  0.422
1993 Zlota AA, Tilset M, Caulton KG. Attempted oxidative generation of a dihydrogen complex Inorganic Chemistry. 32: 3816-3821. DOI: 10.1021/Ic00070A009  0.452
1993 Caulton KG, Chisholm MH, Drake SR, Folting K, Huffman JC, Streib WE. Triangular phenoxide aggregates of calcium, strontium, and barium: a comparison Inorganic Chemistry. 32: 1970-1976. DOI: 10.1021/Ic00062A016  0.344
1993 Kuhlman R, Vaartstra BA, Streib WE, Huffman JC, Caulton KG. Primary steps in the hydrolyses of two heterometallic alkoxides. Characterization of lithium-titanium and barium-zirconium isopropoxides [LiTiO(O-iso-Pr)3]4 and BaZr4(OH)(O-iso-Pr)17 Inorganic Chemistry. 32: 1272-1278. DOI: 10.1021/Ic00059A040  0.31
1993 Caulton KG, Chisholm MH, Drake SR, Folting K, Huffman JC. Synthesis and structural characterization of the alkaline earth aryloxide aggregates H2Ba8(.mu.5-O)2(OPh)14(HMPA)6 and H2Sr6Ba2(.mu.5-O)2(OPh)14(HMPA)6. A new structural type displaying metal ion site selectivity Inorganic Chemistry. 32: 816-820. DOI: 10.1021/Ic00058A011  0.349
1993 Barash EH, Coan PS, Lobkovsky EB, Streib WE, Caulton KG. Anhydrous yttrium acetylacetonate and the course of thermal "dehydration" of Y(acac)3.3H2O Inorganic Chemistry. 32: 497-501. DOI: 10.1021/Ic00057A003  0.308
1993 Rothfuss H, Folting K, Caulton KG. A chain copolymer from WCl2(PMe2Ph)4 and [TlOCH2CF3]4 Inorganica Chimica Acta. 212: 165-173. DOI: 10.1016/S0020-1693(00)92322-3  0.323
1993 Dutremez S, Leslie D, Streib W, Chisholm M, Caulton K. HB(3,5-Me2pyrazolyl)3− as an encapsulating ligand for BaII Journal of Organometallic Chemistry. 462: C1-C2. DOI: 10.1016/0022-328X(93)83380-E  0.334
1993 Hauger B, Caulton KG. Ethylene hydrogenation by the hydride alkoxide species Ir(H)2(OCH2CF3)(PtBu2Ph)2. Ethylene-induced reductive elimination of alcohol from IrIII Journal of Organometallic Chemistry. 450: 253-261. DOI: 10.1016/0022-328X(93)80164-7  0.424
1993 Vaartstra BA, Samuels JA, Barash EH, Martin JD, Streib WE, Gasser C, Caulton KG. A comparison of heterometallic alkoxide molecules containing copper(I) or copper(II) and zirconium Journal of Organometallic Chemistry. 449: 191-201. DOI: 10.1016/0022-328X(93)80123-S  0.353
1992 Caulton KG, Cayton RH, Chisholm MH, Huffman JC, Lobkovsky EB, Xue Z. Structure and bonding of (.mu.-dicarbido)hexa-tert-butoxyditungsten, (tert-BuO)3W.tplbond.CC.tplbond.W(O-tert-Bu)3 Organometallics. 11: 321-326. DOI: 10.1021/Om00037A055  0.314
1992 Johnson TJ, Huffman JC, Caulton KG. Enhanced reactivity from noninnocent behavior by an alkoxide ligand in Cp*RuP(OR): toward the mechanism of alcohol elimination Journal of the American Chemical Society. 114: 2725-2726. DOI: 10.1021/Ja00033A060  0.339
1992 Alvarez D, Caulton KG, Evans WJ, Ziller JW. Synthesis, structure, and reactivity of heterometallic polyhydride complexes of rhenium with yttrium and lutetium Inorganic Chemistry. 31: 5500-5508. DOI: 10.1021/Ic00052A028  0.344
1992 Coan PS, Huffman JC, Caulton KG. Strategy for synthesis of an yttrium/copper(I) complex with an oxo ligand environment Inorganic Chemistry. 31: 4207-4209. DOI: 10.1021/Ic00046A041  0.325
1992 Drake SR, Streib WE, Folting K, Chisholm MH, Caulton KG. Dinuclear barium alkoxides and siloxides displaying variable coordination numbers and asymmetric dispositions of ligands Inorganic Chemistry. 31: 3205-3210. DOI: 10.1021/Ic00041A008  0.405
1992 Poulton JT, Folting K, Streib WE, Caulton KG. Spectroscopic assessment of the degree of .pi.-stabilization of unsaturation in ruthenium complex, RuH(X)CO(P-tert-Bu2Me)2 Inorganic Chemistry. 31: 3190-3191. DOI: 10.1021/Ic00041A004  0.316
1992 McGeary MJ, Cayton RH, Folting K, Huffman JC, Caulton KG. Potassium triphenylsiloxide “-ate” compounds of tin(II): Molecular and separated ion forms and variable potassium coordination numbers Polyhedron. 11: 1369-1382. DOI: 10.1016/S0277-5387(00)83368-9  0.365
1992 Rhodes LF, Huffman JC, Caulton KG. Heterometallic species containing Cp2MH2 (MMo and W) and Cu+ or Ag+ are inner sphere redox intermediates Inorganica Chimica Acta. 198: 639-649. DOI: 10.1016/S0020-1693(00)92409-5  0.32
1992 Johnson TJ, Hauger BE, Lobkovsky EB, Caulton KG. Protonation of cationic hydride and alkyl complexes of Ir(III) Journal of Organometallic Chemistry. 424: 371-380. DOI: 10.1016/0022-328X(92)80011-L  0.37
1991 Rauscher DJ, Thaler EG, Huffman JC, Caulton KG. Acidolysis of rhodium complexes [MeC(CH2PPh2)3]Rh(CH3)n: controlled creation of unsaturation Organometallics. 10: 2209-2216. DOI: 10.1021/Om00053A025  0.439
1991 Sluys LSVD, Kubas GJ, Caulton KG. Reactivity of (dihydrogen)dihydridotris(triphenylphosphine)ruthenium. Dimerization to form (PPh3)2(H)Ru(.mu.-H)3Ru(PPh3)3 and decarbonylation of ethanol under mild conditions Organometallics. 10: 1033-1038. DOI: 10.1021/Om00050A039  0.436
1991 Caulton KG, Chisholm MH, Streib WE, Xue Z. Direct observation of .alpha.-hydrogen transfer from alkyl to alkylidyne ligands in (Me3CCH2)3W:CSiMe3. Kinetic and mechanistic studies of alkyl-alkylidyne exchange Journal of the American Chemical Society. 113: 6082-6090. DOI: 10.1021/Ja00016A024  0.317
1991 Sluys LSVd, Miller MM, Kubas GJ, Caulton KG. Deprotonation of uncharged transition-metal dihydrogen complexes with copper alkoxides, characterization of the heterometallic complexes (PR3)xMHyCu(PR3) (M = iron, tungsten), and x-ray crystal structure of (PEtPh2)3FeH3Cu(PEtPh2) Journal of the American Chemical Society. 113: 2513-2520. DOI: 10.1021/Ja00007A027  0.313
1991 Coan PS, McGeary MJ, Lobkovsky EB, Caulton KG. Low-coordinate yttrium in an oxygen ligand environment. Solid-state and solution characterization of hexakis(triphenylsiloxo)diyttrium Inorganic Chemistry. 30: 3570-3572. DOI: 10.1021/Ic00018A035  0.335
1991 Caulton KG, Chisholm MH, Drake SR, Folting K. Synthesis and molecular structure of a mononuclear barium aryloxide-ethanolamine complex, Ba(2,6-tert-Bu2C6H3O)2(HOCH2CH2NMe2)4.cntdot.2C7H8, exhibiting extensive hydrogen bonding Inorganic Chemistry. 30: 1500-1503. DOI: 10.1021/Ic00007A015  0.441
1991 Fuentes GR, Coan PS, Streib WE, Caulton KG. Eta-6 bonding of benzene to potassium in [(C6H6)KOSiMe2Ph]4 Polyhedron. 10: 2371-2375. DOI: 10.1016/S0277-5387(00)86197-5  0.434
1991 McGeary MJ, Folting K, Streib WE, Huffman JC, Caulton KG. Oligomerization and structural variation of alkali metal silyloxides Polyhedron. 10: 2699-2709. DOI: 10.1016/S0277-5387(00)86170-7  0.353
1991 Folting K, Streib WE, Caulton KG, Poncelet O, Hubert-Pfalzgraf LG. Characterization of aluminium isopropoxide and aluminosiloxanes Polyhedron. 10: 1639-1646. DOI: 10.1016/S0277-5387(00)83775-4  0.311
1990 Vaartstra BA, Huffman JC, Streib WE, Caulton KG. Rational construction of mixed-metal alkoxides Journal of the Chemical Society, Chemical Communications. 1750-1751. DOI: 10.1039/C39900001750  0.356
1990 Caulton KG, Chisholm MH, Drake SR, Huffman JC. Preparation, crystal and molecular structure of a hydrocarbon soluble, volatile oxo-alkoxide of barium: H4Ba6(μ6-O) (OCH2CH2OCH3)14 Journal of the Chemical Society, Chemical Communications. 1498-1499. DOI: 10.1039/C39900001498  0.376
1990 Caulton KG, Chisholm MH, Drake SR, Folting K. Synthesis and structural characterization of the first examples of molecular aggregates of barium supported by aryloxide and alkoxide ligands: [HBa5(O)(OPh)9(thf)8] and [H3Ba 6(O)(OBut)11(OCEt2CH 2O)(thf)3] (thf=tetrahydrofuran) Journal of the Chemical Society, Chemical Communications. 1349-1351. DOI: 10.1039/C39900001349  0.316
1990 Bruno JW, Huffman JC, Green MA, Zubkowski JD, Hatfield WE, Caulton KG. Simultaneous photodissociation of hydrogen and dimethylphenylphosphine from OsH4(PMe2Ph)3: production of dimeric and paramagnetic osmium polyhydrides Organometallics. 9: 2556-2567. DOI: 10.1021/Om00159A026  0.385
1990 Thaler EG, Caulton KG. Tetraethylborate as an ethyl transfer reagent Organometallics. 9: 1871-1876. DOI: 10.1021/Om00156A028  0.454
1990 Alvarez D, Caulton KG, Evans WJ, Ziller JW. Reversible opening and closing of hetero trimetallic units in (C5H5)2Y(THF)Re2H7(PMe2Ph)4 and (C5H5)2LuRe2H7(PMe2Ph)4 Journal of the American Chemical Society. 112: 5674-5676. DOI: 10.1021/Ja00170A061  0.343
1990 Van der Sluys LS, Eckert J, Eisenstein O, Hall JH, Huffman JC, Jackson SA, Koetzle TF, Kubas GJ, Vergamini PJ, Caulton KG. An attractive cis-effect of hydride on neighbor ligands: experimental and theoretical studies on the structure and intramolecular rearrangements of Fe(H)2(.eta.2-H2)(PEtPh2)3 Journal of the American Chemical Society. 112: 4831-4841. DOI: 10.1021/Ja00168A030  0.368
1990 Thaler EG, Folting K, Caulton KG. .eta.3-MeC(CH2PPh2)3/rhodium complexes utilize phosphine arm dissociation mechanisms at 25.degree. Journal of the American Chemical Society. 112: 2664-2672. DOI: 10.1021/Ja00163A029  0.406
1990 Lundquist EG, Folting K, Streib WE, Huffman JC, Eisenstein O, Caulton KG. Reactivity of the molecular hydrogen complex [IrH4(PMe2Ph)3]BF4 towards olefins. The origin of stereochemical rigidity of M(PR3)3(olefin)2 species Journal of the American Chemical Society. 112: 855-863. DOI: 10.1021/Ja00158A054  0.418
1990 Lemmen TH, Goeden GV, Huffman JC, Geerts RL, Caulton KG. Alcohol elimination chemistry of tetrakis(tert-butoxocopper) Inorganic Chemistry. 29: 3680-3685. DOI: 10.1021/Ic00344A012  0.341
1990 Vaartstra BA, Huffman JC, Gradeff PS, Hubert-Pfalzgraf LG, Daran JC, Parraud S, Yunlu K, Caulton KG. Alcohol adducts of alkoxides: intramolecular hydrogen bonding as a general structural feature Inorganic Chemistry. 29: 3126-3131. DOI: 10.1021/Ic00342A014  0.335
1990 Lundquist EG, Huffman JC, Folting K, Mann BE, Caulton KG. Synthesis and reactivity of a heterometallic carbon dioxide complex Inorganic Chemistry. 29: 128-134. DOI: 10.1021/Ic00326A026  0.402
1990 Marinelli G, Streib WE, Huffman JC, Caulton KG, Gagné MR, Takats J, Dartiguenave M, Chardon C, Jackson SA, Eisenstein O. The origin of structural variety of alkyne complexes of d8 metals. An example of structural isomerism Polyhedron. 9: 1867-1881. DOI: 10.1016/S0277-5387(00)83999-6  0.651
1990 Caulton KG, Chisholm MH, Drake SR, Streib WE. [Ba3(OSiPh3)6(THF)] · 0.5 THF — Synthese und Struktur eines dreikernigen Bariumsiloxids mit niedrig koordiniertem Barium Angewandte Chemie. 102: 1492-1493. DOI: 10.1002/Ange.19901021236  0.301
1989 Coan PS, Folting K, Huffman JC, Caulton KG. Characterization and structure of some four-coordinate methylcopper(I) compounds Organometallics. 8: 2724-2728. DOI: 10.1021/Om00113A032  0.365
1989 Johnson TJ, Huffman JC, Caulton KG, Jackson SA, Eisenstein O. Facile olefin hydrogenation with an osmium dihydrogen complex Organometallics. 8: 2073-2074. DOI: 10.1021/Om00110A044  0.403
1989 Alvarez D, Lundquist EG, Ziller JW, Evans WJ, Caulton KG. Synthesis, structure and applications of transition-metal polyhydride anions Journal of the American Chemical Society. 111: 8392-8398. DOI: 10.1021/Ja00204A010  0.383
1989 Marinelli G, Rachidi IEI, Streib WE, Eisenstein O, Caulton KG. Alkyne hydrogenation by a dihydrogen complex: synthesis and structure of an unusual iridium-butyne complex Journal of the American Chemical Society. 111: 2346-2347. DOI: 10.1021/Ja00188A083  0.342
1989 Thaler EG, Lundquist EG, Caulton KG. Selectivity in multiple methylation of MCln(Pr3)m compounds Polyhedron. 8: 2689-2692. DOI: 10.1016/S0277-5387(00)80440-4  0.453
1989 Sartain WJ, Huffman JC, Lundquist EG, Streib WG, Caulton KG. Synthesis of Zr-Re-containing polyhydrides by amine elimination Journal of Molecular Catalysis. 56: 20-35. DOI: 10.1016/0304-5102(89)80169-5  0.384
1989 Thaler EG, Folting K, Huffman JC, Caulton KG. A mixed halo / n-alkyl compound of chromium(III): synthesis, structure, and reactivity of Cr(n-Bu)2Cl[(Me2PCH2)3CMe] Journal of Organometallic Chemistry. 376: 343-351. DOI: 10.1016/0022-328X(89)85144-7  0.435
1988 Lundquist EG, Folting K, Huffman JC, Caulton KG. A single bond covalent radius for IrIII: Crystal and molecular structure of fac-Ir(CH3)3(PMe2Ph)3 Polyhedron. 7: 2171-2173. DOI: 10.1016/S0277-5387(00)81798-2  0.361
1988 Alvarez D, Caulton KG. Methyl transfer in the reaction of IrMe3(PMe2Ph)3 with Cu(NCMe)4 Polyhedron. 7: 1285-1287. DOI: 10.1016/S0277-5387(00)81225-5  0.301
1988 Lundquist EG, Huffman JC, Folting K, Caulton KG. Mechanism of Ethylene Hydrogenation by the Molecular Hydrogen Complex [Ir(H)2(H2)(PMe2Ph)3]⊕—Characterization of Intermediates Angewandte Chemie. 27: 1165-1167. DOI: 10.1002/Anie.198811651  0.405
1988 Lundquist EG, Huffman JC, Folting K, Caulton KG. Hydrierung von Ethylen durch den H2‐Komplex [Ir(H)2(H2)(PMe2Ph)3]⊕ – Mechanismus und Charakterisierung von Zwischenstufen Angewandte Chemie. 100: 1236-1238. DOI: 10.1002/Ange.19881000931  0.391
1987 Hessen B, Lemmen TH, Luttikhedde HJG, Teuben JH, Petersen JL, Huffman JC, Jagner S, Caulton KG. Paramagnetic monocyclopentadienyl hydrocarbyl and borohydride compounds of vanadium(II) and vanadium(III): Synthesis, structure, and reactivity Organometallics. 6: 2354-2362. DOI: 10.1021/Om00154A015  0.44
1987 Thaler E, Folting K, Huffman JC, Caulton KG. Bis[tris(dimethylphosphinomethyl)ethane]hydridochromium(1+) tetraethylborate(1-): the first synthesis of a cationic hydride complex from triethylborate(1-) Inorganic Chemistry. 26: 374-377. DOI: 10.1021/Ic00250A007  0.378
1986 Goeden GV, Huffman JC, Caulton KG. A copper-(.mu.2-hydrogen) bond can be stronger than an intramolecular phosphorus .fwdarw. copper bond. Synthesis and structure of di-.mu.-hydridobis[.eta.2-1,1,1-tris(diphenylphosphinomethyl)ethane]dicopper Inorganic Chemistry. 25: 2484-2485. DOI: 10.1021/Ic00235A002  0.31
1986 Rhodes LF, Caulton KG, Rybak WK, Ziółkowski JJ. Synthesis, characterization and reactivity of some rhenium phosphite complexes Polyhedron. 5: 1891-1893. DOI: 10.1016/S0277-5387(00)84874-3  0.339
1986 Bruno JW, Caulton KG. Mechanistic studies on the oxidation of an anionic rhenium polyhydride complex: Generation and reactivity of the transient radical [ReH6(PMePh2)2] Journal of Organometallic Chemistry. 315. DOI: 10.1016/0022-328X(86)80422-3  0.329
1986 Lemmen TH, Huffman JC, Caulton KG. Darstellung von [Cu3Os3H9(PMe2Ph)9], einer Bimetallverbindung mit Floßstruktur, durch reduktive Eliminierung von Alkohol oder H2 Angewandte Chemie. 98: 267-268. DOI: 10.1002/Ange.19860980317  0.375
1985 DeWit DG, Folting K, Streib WE, Caulton KG. Selective hydrogenation of acenapthylene by ReH7(PCy3)2 Organometallics. 4: 1149-1153. DOI: 10.1021/Om00126A001  0.42
1985 Hessen B, Teuben JH, Lemmen TH, Huffman JC, Caulton KG. Cyclopentadienylvanadium(III) and -vanadium(II) methyl, phenyl, and borohydride compounds Organometallics. 4: 946-948. DOI: 10.1021/Om00124A030  0.408
1985 Marsella JA, Huffman JC, Folting K, Caulton KG. Hydride transfer from transition metal hydrides to dihapto acyl ligands Inorganica Chimica Acta. 96: 161-170. DOI: 10.1016/S0020-1693(00)87576-3  0.418
1985 Zeiher EHK, Dewit DG, Caulton KG. Mechanistic features of carbon-hydrogen bond activation by the rhenium complex ReH7[P(C6H11)3]2 Cheminform. 16. DOI: 10.1002/Chin.198510314  0.363
1984 Zeiher EHK, DeWit DG, Caulton KG. Mechanistic features of carbon-hydrogen bond activation by the rhenium complex ReH7[P(C6H11)3]2 Journal of the American Chemical Society. 106: 7006-7011. DOI: 10.1021/Ja00335A024  0.356
1984 Emge TJ, Koetzle TF, Bruno JW, Caulton KG. Pentahydridorhenium: crystal and molecular structure of ReH5(PMePh2)3 Inorganic Chemistry. 23: 4012-4017. DOI: 10.1021/Ic00192A034  0.322
1984 Jung CW, Garrou PE, Hoffman PR, Caulton KG. Reexamination of the reactions of Ph2P(CH2)nPPh2 (n = 1-4) with RuCl2(PPh3)3 Inorganic Chemistry. 23: 726-729. DOI: 10.1021/Ic00174A018  0.364
1984 Huffman JC, Wells NJ, Caulton KG. Molecular structure of an extremely crowded iron(II) dihydride complex: FeH2(PMePh2)4 Journal of Chemical Crystallography. 14: 581-587. DOI: 10.1007/Bf01182145  0.318
1984 Huffman JC, Geerts RL, Caulton KG. Aggregation and solvation of a lithium aryloxide Journal of Crystallographic and Spectroscopic Research. 14: 541-547. DOI: 10.1007/Bf01182140  0.379
1983 Muralidharan S, Ferraudi G, Green MA, Caulton KG. The photochemistry of rhenium hydrides. A flash photolytic investigation of the transients in the photochemistry of tris(dimethylphenylphosphine)pentahydridorhenium(V) Journal of Organometallic Chemistry. 244: 47-59. DOI: 10.1016/S0022-328X(00)98632-7  0.393
1983 Green MA, Huffman JC, Caulton KG. Photochechemistry of transition-metal polyhydrides: dimerization of OsH4 (PMe2Ph)3 following photodissociation of dihydrogen Journal of Organometallic Chemistry. 243. DOI: 10.1016/S0022-328X(00)98584-X  0.429
1983 Nieman J, Teuben JH, Huffman JC, Caulton KG. Preparation and characterization of mono-cyclopentadienylvanadium dihalide bis-phosphine complexes; crystal structure of (η5-C5H5)VCL2(PMe3)2 Journal of Organometallic Chemistry. 255: 193-204. DOI: 10.1016/0022-328X(83)87022-3  0.471
1983 Lewis LN, Caulton KG. The reactivity of Cp2V2(CO)5 towards alkynes Journal of Organometallic Chemistry. 252: 57-69. DOI: 10.1016/0022-328X(83)80058-8  0.395
1982 Marsella JA, Huffman JC, Caulton KG, Longato B, Norton JR. Dinuclear elimination as a route to unusual bridging carbonyls and acetyls in heterobimetallic complexes Journal of the American Chemical Society. 104: 6360-6368. DOI: 10.1021/Ja00387A034  0.392
1981 Green MA, Huffman JC, Caulton KG, Rybak WK, Ziólkówski JJ. Ligand Scavenging and Catalytic Utilization of the Phototransient ReH5(PMe2Ph)2 Journal of Organometallic Chemistry. 218. DOI: 10.1016/S0022-328X(00)86115-X  0.396
1981 Wells NJ, Huffman JC, Caulton KG. Monocyclopentadienyl zirconium(IV) complexes Journal of Organometallic Chemistry. 213: C17-C20. DOI: 10.1016/S0022-328X(00)82962-9  0.449
1981 Caulton KG. Coordination chemistry of the manganese and rhenium fragments (C5H5)M(CO)2 Coordination Chemistry Reviews. 38: 1-43. DOI: 10.1016/S0010-8545(00)80498-1  0.333
1980 Huffman JC, Moloy KG, Marsella JA, Caulton KG. Molecular structure of (.eta.5-C5H5)2Ti(OC2H5)Cl and [(.eta.5-C5H5)Cl2Ti]2O2C2(CH3)4. A structural basis for deoxygenation using titanium Journal of the American Chemical Society. 102: 3009-3014. DOI: 10.1021/Ja00529A022  0.337
1980 Marsella JA, Caulton KG. Heterobimetallic hydrogen transfer in the reduction of metal acyl complexes Journal of the American Chemical Society. 102: 1747-1748. DOI: 10.1021/Ja00525A058  0.316
1980 Lewis LN, Caulton KG. Mobility of the .mu.3:.eta.2-carbonyl ligand in tris(cyclopentadienyl)heptacarbonyltriniobium Inorganic Chemistry. 19: 3201-3203. DOI: 10.1021/Ic50212A081  0.318
1980 Tsipis C, Manoussakis GE, Kessissoglou DP, Huffman JC, Lewis LN, Adams MA, Caulton KG. Molecular structure and solution dynamics of (.eta.5-C5H5)Ni(PPh3)S2COC2H5 Inorganic Chemistry. 19: 1458-1462. DOI: 10.1021/Ic50208A008  0.316
1980 Lewis LN, Huffman JC, Caulton KG. Allene formation within the coordination sphere. Synthesis and crystal structure of (C5H5)2Mn2(CO)3(H2CCCH2) Inorganic Chemistry. 19: 1246-1249. DOI: 10.1021/Ic50207A027  0.336
1980 Marsella JA, Moloy KG, Caulton KG. Ligand redistribution and carbonyl insertion: The effect of competitive π-donation Journal of Organometallic Chemistry. 201: 389-398. DOI: 10.1016/S0022-328X(00)87924-3  0.4
1980 TSIPIS C, MANOUSSAKIS GE, KESSISSOGLOU DP, HUFFMAN JC, LEWIS LN, ADAMS MA, CAULTON KG. ChemInform Abstract: MOLECULAR STRUCTURE AND SOLUTION DYNAMICS OF (η5-C5H5)NI(PPH3)S2COC2H5 Chemischer Informationsdienst. 11. DOI: 10.1002/Chin.198036076  0.328
1980 Marsella JA, Caulton KG. Heterobimetallic Hydrogen Transfer In The Reduction Of Metal Acyl Complexes Cheminform. 11. DOI: 10.1002/Chin.198023288  0.316
1979 Folting K, Huffman JC, Lewis LN, Caulton KG. Acetylene isomerization by manganese(I): preparation and structure of (C5H5)2Mn2(CO)4CCH2 Inorganic Chemistry. 18: 3483-3486. DOI: 10.1021/Ic50202A038  0.344
1979 Adams MA, Folting K, Huffman JC, Caulton KG. Mechanism of the carbonylation of dicyclopentadienylmolybdenum dihydride Journal of Organometallic Chemistry. 164. DOI: 10.1016/S0022-328X(00)81704-0  0.387
1976 Caulton KG, Adair P. Kinetic characteristics of the four-electron bridging carbonyl Journal of Organometallic Chemistry. 114. DOI: 10.1016/S0022-328X(00)87357-X  0.319
1975 Ungermann CB, Caulton KG. A nonrigid mixed-chelate complex of iron(0) Journal of Organometallic Chemistry. 94: C9-C13. DOI: 10.1016/S0022-328X(00)82541-3  0.351
1974 Hoffman PR, Miller JS, Ungermann CB, Caulton KG. Intramolecular rearrangement of pentacoordinate nitrosyl complexes Cheminform. 5. DOI: 10.1002/Chin.197404327  0.324
1973 Gwost D, Caulton KG. Reductive nitrosylation of Group VIIIB metals Journal of the Chemical Society, Chemical Communications. DOI: 10.1039/C3973000064A  0.316
1973 Hoffman PR, Miller JS, Ungermann CB, Caulton KG. Intramolecular rearrangement of pentacoordinate nitrosyl complexes Journal of the American Chemical Society. 95: 7902-7904. DOI: 10.1021/Ja00804A076  0.324
1973 Caulton KG. The barrier to ring inversion in tetrahedral complexes of N,N,N′,N′ - tetramethylethylenediamine Inorganic and Nuclear Chemistry Letters. 9: 533-538. DOI: 10.1016/0020-1650(73)80186-2  0.301
1971 Cotton FA, Caulton KG. Crystal and molecular structure of bis(triphenyylphosphine)tetrakis(dimethylglyoximato)dirhodium. Length of a rhodium(II)-to-rhodium(II) single bond Journal of the American Chemical Society. 93: 1914-1918. DOI: 10.1021/Ja00737A014  0.401
1970 Caulton KG, DeKock RL, Fenske RF. Comparison of carbon monoxide and nitrogen as ligands in transition metal complexes Journal of the American Chemical Society. 92: 515-518. DOI: 10.1021/ja00706a015  0.574
1970 Caulton KG, DeKock RL, Fenske RF. A comparison of carbon monoxide and nitrogen as ligands in transition metal complexes Journal of the American Chemical Society. 92: 515-518. DOI: 10.1021/Ja00706A015  0.621
1970 CAULTON KG, DEKOCK RL, FENSKE RF. ChemInform Abstract: VERGLEICH VON KOHLENMONOXID UND STICKSTOFF ALS LIGAND IN UEBERGANGSMETALLKOMPLEXEN Chemischer Informationsdienst. Organische Chemie. 1: no-no. DOI: 10.1002/Chin.197018049  0.717
1969 Caulton KG, Cotton FA. Rhodium(II)-to-rhodium(II) single bond in bis(triphenylphosphine)tetrakis(dimethylglyoximato)dirhodium Journal of the American Chemical Society. 91: 6517-6518. DOI: 10.1021/Ja01051A074  0.399
1969 Bennett MJ, Caulton KG, Cotton FA. Structure of tetra-n-butyratodiruthenium chloride, a compound with a strong metal-metal bond Inorganic Chemistry. 8: 1-6. DOI: 10.1021/Ic50071A001  0.414
1968 Caulton KG, Fenske RF. Electronic structure and bonding in hexacarbonylvanadium(1-), hexacarbonylchromium, hexacarbonylmanganese(1+) Inorganic Chemistry. 7: 1273-1284. DOI: 10.1021/Ic50065A003  0.612
1967 Caulton KG, Fenske RF. Electronic spectra of hexanitrometallates Inorganic Chemistry. 6: 562-568. DOI: 10.1021/Ic50049A030  0.575
1966 Fenske RF, Caulton KG, Radtke DD, Sweeney CC. Energy levels, spin densities, and the nephelauxetic effect in metal hexafluorides Inorganic Chemistry. 5: 960-964. DOI: 10.1021/Ic50040A002  0.569
1966 Fenske RF, Caulton KG, Radtke DD, Sweeney CC. A method for molecular orbital calculations for metal complexes Inorganic Chemistry. 5: 951-960. DOI: 10.1021/Ic50040A001  0.606
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